FINAL
Assessment of Contaminated Sediments
River Rouge/Ecorse Shoreline
Site Characterization Report
Detroit River Area of Concern, Wayne County, Michigan
Great Lakes Architect-Engineer Services
Contract: EP-R5-11-10
Preparedfor
U.S. Environmental Protection Agency
Region 5
77 West Jackson Boulevard
Chicago, Illinois 60604-3507
Prepared by
EA Science and Technology and Its Affiliate
EA Engineering, Science, and Technology, (MI) PLC
455 East Eisenhower Parkway
Suite 50
Ann Arbor, Michigan 48108
August 2014
Version: FINAL
EA Project No. 6256115.10
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EA Project No.: 6256115.10
Version: FINAL
EA Science and Technology and Its Affiliate Page i
EA Engineering, Science, and Technology, (MI) PLC August 2014
TABLE OF CONTENTS
Page
LIST OF FIGURES iv
LIST OF TABLES vii
LIST OF ACRONYMS AND ABBREVIATIONS viii
EXECUTIVE SUMMARY 1
ES.l SAMPLING RESULTS 1
ES.2 SPATIAL ANALYSIS AND VOLUME ESTIMATION
ES.3 CONCLUSIONS
1. INTRODUCTION
1.1 WORK SCOPE AND OBJECTIVES
1.1.1 Proj ect Obj ectives
1.1.2 Obj ectives of the Site Characterization Report
1.2 SITE LOCATION AND HISTORY
1.2.1 Detroit River and Rouge River AOC s
1.2.2 River Rouge/Ecorse Shoreline
2. RIVER ROUGE/ECORSE SHORELINE SITE INVESTIGATION 2-1
2.1 SAMPLING PROGRAM DESIGN AND RATIONALE 2-1
2.1.1 Sample Locations 2-1
2.1.2 Number of Samples 2-1
2.2 NAVIGATION AND SURVEY 2-2
2.3 SEDIMENT SAMPLING 2-2
2.3.1 Vibracore Sampling 2-3
2.3.2 Ponar Grab Sampling 2-3
2.3.3 Sediment Processing 2-3
2.4 ANALYTICAL PROGRAM 2-4
2.5 SAMPLE HANDLING, CHAIN-OF-CUSTODY, AND QUALITY
ASSURANCE/QUALITY CONTROL 2-5
2.5.1 Sample Handling, Chain-of-Custody and Documentation 2-5
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Project No.: 6256115.10
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EA Engineering, Science, and Technology, (MI) PLC August 2014
2.5.2 Quality Control 2-5
2.6 DECONTAMINATION 2-6
2.7 INVESTIGATION-DERIVED WASTE 2-6
2.8 DEVIATIONS FROM THE QAPP AND FSP 2-6
2.8.1 Sampling Locations 2-6
2.8.2 Proposed Analytical Program 2-7
2.8.3 Sample Collection and Processing 2-7
3. RESULTS 3-1
3.1 DATA EVALUATION 3-1
3.1.1 Comparison to Sediment Quality Guidelines 3-1
3.1.2 Calculation of Total Polycyclic Aromatic Hydrocarbons and Total
Polychlorinated Biphenyls 3-2
3.1.3 Simultaneously Extracted Metals/Acid Volatile Sulfide Ratio 3-2
3 .2 RESULTS FROM THE RIVER ROUGE/ECORSE SHORELINE SEDIMENT
INVESTIGATION 3-3
3.2.1 Core Recovery 3-3
3.2.2 Lithology 3-3
3.2.2.1 Area A 3-3
3.2.2.2 Boat Slips 3-4
3.2.2.3 Area B 3-4
3.2.3 Bulk Sediment Results 3-4
3.2.3.1 Grain Size, Particle Size, and Density 3-5
3.2.3.2 Polychlorinated Biphenyls (Aroclors) 3-5
3.2.3.3 Polycyclic Aromatic Hydrocarbons 3-6
3.2.3.4 Total Organic Carbon 3-6
3.2.3.5 Metals 3-7
3.2.3.6 Equilibrium Partitioning Sediment Benchmarks based on Acid
Volatile Sulfide (ESBavs) 3-12
3.2.3.7 Total Petroleum Hydrocarbons - Diesel Range Organics and
Mid-Range Organics 3-12
4. EQUILIBRIUM PARTITIONING SEDIMENT BENCHMARKS AND ORGANIC
CARBON NORMALIZED METALS 4-1
4.1 PAHS 4-1
4.2 METALS 4-2
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Project No.: 6256115.10
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EA Engineering, Science, and Technology, (MI) PLC August 2014
5. SPATIAL ANALYSIS TO DETERMINE HOTSPOTS WITHIN THE RIVER
ROUGE/ECORSE SHORELINE AREA 5-1
5.1 METHODOLOGY 5-1
5.2 MODEL RESULTS FOR ALL CONSTITUENTS IN THE RIVER
ROUGE/ECORSE SHORELINE STUDY AREA 5-2
5.3 DETERMINATION OF PRIORITY HOTSPOT AREAS IN THE RIVER
ROUGE/ECORSE SHORELINE AREA 5-3
5.3.1 Major Hotspot Locations 5-3
5.3.1.1 Hotspot 1: River Rouge Shoreline 5-3
5.3.1.2 Hotspot 3: Ecorse Shoreline 5-3
5.3.2 Other Hotspot Locations 5-4
5.3.2.1 Hotspot 2: Nicholson North (aka. Allied Oil) Boat Slip 5-4
5.4 MODEL RESULTS FOR PAH AND ORGANIC CARBON NORMALIZED
METALS FOR THE RIVER ROUGE/ECORSE SHORELINE STUDY AREA 5-
4
6. CONCLUSIONS 6-1
7. REFERENCES 7-1
APPENDIX A
APPENDIX B
APPENDIX C
APPENDIX D
FIELD LOGBOOK AND DATA COLLECTION FORMS
LITHOLOGIC CORE LOGS
CORE PHOTOGRAPHS
PARTICLE SIZE CHARTS
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Science and Technology and Its Affiliate
EA Engineering, Science, and Technology, (MI) PLC
EA Project No.: 6256115.10
Version: FINAL
Page iv
August 2014
LIST OF FIGURES
Number
1-1
1-2
2-1
3-1A
3-1B
3-2 A
3-2B
3-3A
3-3B
3-4 A
3-4B
3-5A
3-5B
3-6 A
Project Site Location.
River Rouge/Ecorse Shoreline Area.
Sample Locations, River Rouge/Ecorse Shoreline Assessment of
Contaminated Sediments.
Total (ND=0) PCB Aroclor Concentrations (|_ig/kg) Detected in Area A -
River Rouge/Ecorse Shoreline Assessment of Contaminated Sediments.
Total (ND=0) PCB Aroclor Concentrations (ng/kg) Detected in Area B -
River Rouge/Ecorse Shoreline Assessment of Contaminated Sediments.
Total (ND=1/2RL) 17PAH Concentrations (ng/kg) Detected in Area A - River
Rouge/Ecorse Shoreline Assessment of Contaminated Sediments.
Total (ND=1/2RL) 17PAH Concentrations (ng/kg) Detected in Area B - River
Rouge/Ecorse Shoreline Assessment of Contaminated Sediments.
Arsenic Concentrations (mg/kg) Detected in Area A - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Arsenic Concentrations (mg/kg) Detected in Area B - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Cadmium Concentrations (mg/kg) Detected in Area A - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Cadmium Concentrations (mg/kg) Detected in Area B - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Chromium Concentrations (mg/kg) Detected in Area A- River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Chromium Concentrations (mg/kg) Detected in Area B - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Copper Concentrations (mg/kg) Detected in Area A - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Science and Technology and Its Affiliate
EA Engineering, Science, and Technology, (MI) PLC
EA Project No.: 6256115.10
Version: FINAL
Page v
August 2014
3-6B
3-7 A
3-7B
3-8A
3-8B
3-9 A
3-9B
3-10A
3-10B
3-11A
3-1 IB
3-12
4-1A
4-1B
Copper Concentrations (mg/kg) Detected in Area B - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Iron Concentrations (mg/kg) Detected in Area A - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Iron Concentrations (mg/kg) Detected in Area B - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Lead Concentrations (mg/kg) Detected in Area A- River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Lead Concentrations (mg/kg) Detected in Area B - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Mercury Concentrations (mg/kg) Detected in Area A - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Mercury Concentrations (mg/kg) Detected in Area B - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Nickel Concentrations (mg/kg) Detected in Area A- River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Nickel Concentrations (mg/kg) Detected in Area B - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Zinc Concentrations (mg/kg) Detected in Area A - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Zinc Concentrations (mg/kg) Detected in Area B - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Total Petroleum Hydrocarbons - River Rouge/Ecorse Shoreline Assessment
of Contaminated Sediments.
Equilibrium Sediment Benchmark Toxic Units for Polycyclic Aromatic
Hydrocarbons in Area A- River Rouge/Ecorse Shoreline Assessment of
Contaminated Sediments.
Equilibrium Sediment Benchmark Toxic Units for Polycyclic Aromatic
Hydrocarbons in Area B- River Rouge/Ecorse Shoreline Assessment of
Contaminated Sediments.
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Science and Technology and Its Affiliate
EA Engineering, Science, and Technology, (MI) PLC
EA Project No.: 6256115.10
Version: FINAL
Page vi
August 2014
5-1A
5-1B
5-2
5-3
5-4
5-5A
5-5B
5-6 A
5-6B
Spatial Analysis for all Constituents in Area A - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Spatial Analysis for all Constituents in Area B - River Rouge/Ecorse
Shoreline Assessment of Contaminated Sediments.
Hotspot 1 - River Rouge/Ecorse Shoreline Site Characterization Report.
Hotspot 2 - River Rouge/Ecorse Shoreline Site Characterization Report.
Hotspot 3 - River Rouge/Ecorse Shoreline Site Characterization Report.
Spatial Analysis for PAH ESBTUs in Area A - River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments.
Spatial Analysis for PAH ESBTUs in Area B - River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments.
Spatial Analysis for Organic Carbon Normalized Metals in Area A - River
Rouge/Ecorse Shoreline Assessment of Contaminated Sediments.
Spatial Analysis for Organic Carbon Normalized Metals in Area B - River
Rouge/Ecorse Shoreline Assessment of Contaminated Sediments.
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Project No.: 6256115.10
Version: FINAL
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EA Engineering, Science, and Technology, (MI) PLC August 2014
LIST OF TABLES
Number Title
2-1 River Rouge/Ecorse Shoreline Site Characterization Coordinates, Detroit River
Area of Concern, Ecorse, Michigan (November 2013).
2-2 River Rouge/Ecorse Shoreline Site Characterization Analytical Program, Detroit
River Area of Concern, Ecorse, Michigan (November 2013).
3-1 River Rouge/Ecorse Shoreline Site Characterization Sample Collection Data,
Detroit River Area of Concern, Ecorse, Michigan (November 2013).
3-2 Sediment Results for Grain Size, River Rouge/Ecorse Shoreline Area Site
Characterization, Detroit River Area of Concern, Ecorse, Michigan (November
2013).
3-3 Sediment Results for PCB-Aroclors, River Rouge/Ecorse Shoreline Area Site
Characterization, Detroit River Area of Concern, Ecorse, Michigan (November
2013).
3-4 Sediment Results for PAHs, River Rouge/Ecorse Shoreline Area Site
Characterization, Detroit River Area of Concern, Ecorse, Michigan (November
2013).
3-5 Sediment Results for Metals and Total Organic Carbon, River Rouge/Ecorse
Shoreline Area Site Characterization, Detroit River Area of Concern, Ecorse,
Michigan (November 2013).
3-6 Sediment Results for SEM/AVS Ratio, River Rouge/Ecorse Shoreline Area Site
Characterization, Detroit River Area of Concern, Ecorse, Michigan (November
2013).
3-7 Sediment Results for Diesel Range Organics and Mid-Range Organics, River
Rouge/Ecorse Shoreline Area Site Characterization, Detroit River Area of
Concern, Ecorse, Michigan (November 2013).
4-1 Equilibrium Sediment Benchmark Toxic Units for Polycyclic Aromatic
Hydrocarbons, River Rouge/Ecorse Shoreline Area, Detroit River Area of
Concern, Ecorse, Michigan (November 2013).
4-2 Organic Carbon Normalized Metals, River Rouge/Ecorse Shoreline Area Site
Characterization, Detroit River Area of Concern, Ecorse, Michigan (November
2013).
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Project No.: 6256115.10
Version: FINAL
LIST OF ACRONYMS AND ABBREVIATIONS
|ig/kg Microgram(s) per kilogram
|iinol Micromole(s)
|amol/goc Micromole(s) per gram organic carbon
aka Also known as
AOC Area of Concern
AVS Acid volatile sulfide
BUI Beneficial use impairment
cfs Cubic feet per second
COC Constituent of concern
cy Cubic yard(s)
DQO Data quality objective
DRO Diesel range organics
DTE DTE Energy Corporation
DWSD Detroit Water and Sewerage Department
EA EA Engineering, Science, and Technology (MI), PLC
EPA U.S. Environmental Protection Agency
ESBavs Equilibrium partitioning sediment benchmark based on acid volatile sulfide
ESBTU Equilibrium partitioning sediment benchmark toxic unit
EVS Environmental Visualization System
FCV Final chronic value
FD Field duplicate
FSP Field Sampling Plan
ft Foot (feet)
GLNPO Great Lakes National Program Office
g Gram
goc Gram organic carbon
GPS Global positioning system
IGLD International Great Lakes Datum
in Inch(es)
Koc Organic carbon-water partition coefficient
MDEQ Michigan Department of Environmental Quality
MDNR Michigan Department of Natural Resources
mg/kg Milligram(s) per kilogram
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Project No.: 6256115.10
Version: FINAL
Page ix
August 2014
MRO
Mid-range organics
MS
Matrix spike
MSD
Matrix spike duplicate
ND
Non-detect
NO A A
National Oceanic and Atmospheric Administration
PAH
Polycyclic aromatic hydrocarbon
PCB
Polychlorinated biphenyl
PEC
Probable effects concentration
ppb
Part(s) per billion
ppm
Part(s) per million
QAPP
Quality Assurance Project Plan
RL
Reporting limit
R/V
Research Vessel
SEM
Simultaneously extracted metals
SIM
Selected ion monitoring
SOP
Standard Operating Procedure
SQG
Sediment Quality Guidelines
TEC
Threshold effects concentration
TOC
Total organic carbon
TPH
Total petroleum hydrocarbons
U.S. Steel
United States Steel Corporation
WDNR
Wisconsin Department of Natural Resources
WGS84
World Geodetic System 1984
EA Science and Technology and Its Affiliate
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River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Science and Technology and Its Affiliate
EA Engineering, Science, and Technology, (MI) PLC
EA Project No.: 6256115.10
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Page ES-1
August 2014
EXECUTIVE SUMMARY
This report presents the contaminated sediments site characterization for the River Rouge/Ecorse
Shoreline (the Site), located within the Detroit River Area of Concern (AOC), Wayne County,
Michigan (Figure 1-1). This work was conducted by EA Science and Technology and its
affiliate EA Engineering, Science, and Technology, (MI) PLC (EA)1 and the U.S. Environmental
Protection Agency's (EPA) Great Lakes National Program Office (GLNPO) in accordance with
the Quality Assurance Project Plan (QAPP) (EA 2013) and Field Sampling Plan (FSP) (EA
2013, Appendix A) for the River Rouge/Ecorse Shoreline Site Characterization, Detroit River
AOC, Wayne County, Michigan, finalized December 2013. The purpose of the field
investigation was to determine the nature and extent of chemical contamination in the areas of
soft sediment deposition within the Site. Primary objectives were to determine depth of
contamination, provide information about depositional areas, and identify high priority areas for
remediation or for further investigation in the River Rouge/Ecorse Shoreline area. This Site
Characterization Report summarizes the findings from the field investigation, including data
tables and maps, and data interpretation. The results of the field investigation were evaluated to
assess the sediment quality for the River Rouge/Ecorse Shoreline area. This Executive Summary
presents a summary of the findings of the Site Characterization Report; details on the site
background and methodology, as well as further details of the findings, are presented within the
report itself.
ES.l SAMPLING RESULTS
Lithology
Sediment cores collected within the Rouge River/Ecorse Shoreline site contained sediment types
consistent with a fluvial system. Most cores were characterized by thick alternating layers of
clay and silty clay interspersed with smaller amounts of sandy or gravelly material. Native and
non-native material such as shells, roots and organic material, hydrocarbon odor, and woody
debris were frequently observed within various sediment types and depths.
Bulk Chemistry
The validated data collected under this investigation were compared to the consensus-based
threshold effects concentrations (TECs) and the probable effects concentrations (PECs) of the
Sediment Quality Guidelines (SQG) for Freshwater Systems (MacDonald et al. 2000) to address
the objectives of this assessment.
Polychlorinated biphenyl (PCB)-Aroclors were detected in 81 percent of the samples submitted
for analysis, and more than a third of the locations sampled had PCB-Aroclor concentrations
exceeding 10 times the PEC in at least one depth interval. Polycyclic aromatic hydrocarbons
1 EA Engineering, Science, and Technology, Inc. does business as EA Science and Technology in the State of
Michigan and EA is affiliated with EA Engineering, Science, and Technology, (MI) PLC.
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Science and Technology and Its Affiliate
EA Engineering, Science, and Technology, (MI) PLC
EA Project No.: 6256115.10
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Page ES-2
August 2014
(PAHs) were detected in all of the samples analyzed, and PAH concentrations exceeded 5 times
the PEC in at least one depth interval for more than one-quarter of the locations sampled. PEC
exceedances for metal concentrations varied across the suite of metals analyzed. Less than
25 percent of samples analyzed had arsenic or mercury concentrations that exceeded the PEC.
Concentrations of copper, chromium, and cadmium each exceeded the PEC in approximately
half of the samples analyzed. For iron, lead, nickel, and zinc, the majority of samples analyzed
contained concentrations that exceeded the respective PEC.
Further analysis of COC concentrations was performed by calculation of various benchmarks for
both PAHs and metals. PAH equilibrium partitioning sediment benchmark toxic units
(ESBTUs) were calculated as an additional tool for evaluating potential risk associated with
sediment contamination (EPA 2003). For PAH ESBTUs, 57 percent of samples had values
greater than 1.
The ratio of simultaneously extracted metals to acid-volatile sulfide (SEM/AVS), which has been
termed an Equilibrium Partitioning Sediment Benchmark based on AVS (ESBavs), provides a
method to predict the lack of toxicity in divalent metals (cadmium, copper, lead, nickel, silver
and zinc) contaminated sediments. When SEM/AVS ratios are less than 1 the sediment is
predicted to be non-toxic. When the ratio of SEM/AVS is greater than 1 the metals
contaminated sediment is either toxic or toxicity is uncertain. Within the Detroit River AOC
ESBavs was calculated, resulting in 44% of the samples with ratios of less than 1 indicating that
the sediment at these locations was not toxic. ESBavs ratios were greater than 1 in 56 percent of
samples, which indicates that these samples may or may not be toxic to benthic organisms (EPA
2005). A modification to the ESBavs method was also performed to improve the prediction of
mortality by accounting for the presence of total organic carbon and the ability of metals to
partition to the organic carbon as well as the AVS. This further refinement of the toxicity
predictions accounts for the presence of organic carbon in addition to AVS, and their effect on
metals bioavailability, and it involves taking the SEM-AVS difference and normalizing by
organic carbon (EPA 2005). When this calculation was performed, 11 percent of samples
exhibited organic carbon normalized metals values exceeding the threshold value of 130
micromoles (|imol) per gram organic carbon (goc) for uncertain toxicity, and no samples
exceeded the threshold value of 3,000 |iinol/g(lc for likely toxicity. This would indicate that
sediment organic carbon at the site plays an important role in reducing bioavailability and
toxicity from divalent metals.
ES.2 SPATIAL ANALYSIS AND VOLUME ESTIMATION
To determine the location of hotspots within the Detroit River AOC, the dataset of all individual
constituents exceeding their respective PECs in sediment samples was spatially interpolated to
develop an estimate of the level and distribution of elevated concentrations of constituents across
the study area. Potential hotspots identified by the all constituent analysis were then verified by
comparison to spatial interpolations of two additional datasets: (1) the calculated PAH ESBTUs;
and (2) the calculated organic carbon normalized metal concentrations. Hotspot determination
allows priority areas to be targeted for further investigation or remediation. Interpolation was
performed by using a spatial statistical method called kriging, which determined that for the
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Science and Technology and Its Affiliate
EA Engineering, Science, and Technology, (MI) PLC
EA Project No.: 6256115.10
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Page ES-3
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majority of the study area one or more analytes were present in concentrations exceeding the
PEC. The areas containing PEC exceedances were divided into two large hotspots (Hotspots 1
and 3) and one smaller hotspot (Hotspot 2).
The River Rouge shoreline area (Hotspot 1) includes the mouth of the Rouge River and stretches
south to the mouth of the Nicholson North (also known as Allied Oil) boat slip. The majority of
this area has constituent concentrations exceeding 3 times the PEC, about one-quarter of the area
has constituent concentrations between 2 and 3 times the PEC, and the remaining portion (less
than one-quarter) has constituent concentrations between 1 and 2 times the PEC. The estimated
volume of sediment concentrations of at least one constituent of concern (COC) exceeding the
PEC is 794,000 cubic yards (cy) for Hotspot 1. The COCs present in Hotspot 1 with
concentrations greater than 3 times their respective PECs include total 17PAHs, total PCBs,
cadmium, chromium, copper, iron, lead, nickel, and zinc.
Hotspot 2 consists of the western two-thirds of the Nicholson North (aka. Allied Oil) boat slip.
PEC exceedances in Hotspot 2 include total 17PAHs, total PCBs, arsenic, cadmium, chromium,
copper, iron, lead, mercury, nickel, and zinc. Total PCB concentrations exceeded 2 times the
PEC at all 4 of the sampling locations within Hotspot 2. The estimated volume of impacted
sediment in Hotspot 2 is 56,000 cy.
The Ecorse Shoreline area (Hotspot 3) has constituent concentrations exceeding 3 times the PEC
in the majority of the hotspot, including all of the Nicholson South boat slip. Constituent
concentrations exceeding 1 or 2 times the PEC are present primarily in the southern end of the
hotspot in the areas surrounding Mud Island. The estimated volume of sediment with constituent
concentrations exceeding the PEC is 1,338,000 cy. The COCs present in portions of Hotspot 3
include total 17PAHs, total PCBs, arsenic, cadmium, chromium, copper, iron, lead, mercury,
nickel, and zinc. The southern end of this hotspot includes the mouth of the Ecorse River, near
which concentrations of total 17PAHs exceeded 3 times the PEC, and concentrations of total
PCBs exceeded 10 times the PEC.
ES.3 CONCLUSIONS
Based on the data collected during the River Rouge/Ecorse Shoreline sediment investigation, a
large portion of the site contains elevated constituent concentrations that are potentially harmful
to benthic organisms. The 3 hotspots identified have an estimated total volume of 2,188,000 cy
of sediment with COC concentrations exceeding PECs, and they should be considered as priority
areas for further investigation and potential remediation efforts.
Model results indicated that each of the 3 hotspots has significant volumes of sediment with
elevated COC concentrations exceeding 2 or 3 times PEC levels. Modeling of the PAH ESBTUs
also showed elevated values reflecting impacted sediment throughout most of the hotspot areas
that were identified by modeling of all COCs with concentrations above the PEC. Modeling of
organic carbon normalized metals indicated three areas where the threshold value of 130
|amol/goc, were exceeded and these three areas all fell within the identified hotspots. This
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Science and Technology and Its Affiliate
EA Engineering, Science, and Technology, (MI) PLC
EA Project No.: 6256115.10
Version: FINAL
Page ES-4
August 2014
reinforces that these 3 hotspots should be considered priority areas for additional assessment and
potential remediation.
Further investigation is recommended in part because estimates regarding the areal extent of the
3 hotspots and the volumes of sediment with elevated concentrations of COCs contain significant
uncertainty. This uncertainty stems in part from the limited number of samples, as well as the
occurrence of PEC exceedances in the bottom interval of some cores that were not collected to
refusal due to field conditions. Although further assessment should improve estimates, the
present study serves to effectively characterize much of the River Rouge/Ecorse Shoreline Site
as containing sediment impacted by elevated levels of COCs.
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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EA Project No.: 6256115.10
Version: FINAL
Page 1-1
August 2014
1. INTRODUCTION
EA Science and Technology and Its Affiliate
EA Engineering, Science, and Technology, (MI) PLC
This report presents the contaminated sediments site characterization for the River Rouge/Ecorse
Shoreline (the Site), located within the Detroit River Area of Concern (AOC), Wayne County,
Michigan (Figure 1-1). This work was conducted by EA Science and Technology and its
affiliate EA Engineering, Science, and Technology, (MI) PLC (EA)1 and the U.S. Environmental
Protection Agency's (EPA) Great Lakes National Program Office (GLNPO) in accordance with
the Quality Assurance Project Plan (QAPP) (EA 2013) and Field Sampling Plan (FSP) (EA
2013, Appendix A) for the River Rouge/Ecorse Shoreline Site Characterization, Detroit River
AOC, Wayne County, Michigan, finalized December 2013.
1.1 WORK SCOPE AND OBJECTIVES
1.1.1 Project Objectives
The purpose of the field investigation was to determine the nature and extent of chemical
contamination in the areas of soft sediment deposition within the site. Primary objectives were
to determine depth of contamination, provide information about depositional areas, and identify
high priority areas for remediation or for further investigation in the River Rouge/Ecorse
Shoreline area.
1.1.2 Objectives of the Site Characterization Report
This Site Characterization Report summarizes the findings from the field investigation, including
data tables and maps, and data interpretations. The results of this site characterization were
evaluated to assess the sediment quality for the River Rouge/Ecorse Shoreline area. The overall
objectives of this report are to define the spatial extent of contaminants and soft sediment,
develop a preliminary estimate of the volume of contaminated soft sediment, and identify
priority areas within the River Rouge/Ecorse Shoreline area at which remediation efforts should
be initiated.
1.2 SITE LOCATION AND HISTORY
1.2.1 Detroit River and Rouge River AOCs
The Detroit River has a drainage area of 700 square miles of land in Michigan and Ontario, as
well as the 107-square-mile City of Detroit sewershed. A part of the international connecting
waterway that also includes the St. Clair River and Lake St. Clair, the 32-mile strait of the
Detroit River links Lake Erie to the Upper Great Lakes, which include Lakes Huron, Michigan,
and Superior (Figure 1-1). The mean discharge of the Detroit River into Lake Erie is 185,000
1 EA Engineering, Science, and Technology, Inc. does business as EA Science and Technology in the State of
Michigan and EA is affiliated with EA Engineering, Science, and Technology, (MI) PLC.
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cubic feet per second (cfs). It has five tributaries, although greater than 95 percent of its total
flow comes from Lake Huron via the St. Clair River and Lake St. Clair. The most significant
tributary to the Detroit River is the Rouge River. Like the Detroit River, the Rouge River is a
Great Lakes AOC.
The Detroit River has a past and present use as an industrial and drinking water source. It is
believed that contaminated sediments in the study area contribute to beneficial use impairments
(BUIs) in the AOC. Impairment of beneficial use means an unacceptable change in the
chemical, physical, or biological integrity of the Great Lakes ecosystem. A Detroit River Stage 1
Remedial Action Plan was completed by the Michigan Department of Natural Resources
(MDNR) in 1991, and it identifies the following 11 BUIs for the Detroit River AOC:
1. Restrictions on fish and wildlife consumption
2. Tainting of fish and wildlife flavor
3. Restrictions on drinking water consumption, or taste and odor
4. Degradation of fish and wildlife populations
5. Beach closings
6. Fish tumors or other deformities
7. Degradation of aesthetics
8. Bird or animal deformities or reproduction problems
9. Degradation of benthos
10. Restriction on dredging activities
11. Loss of fish and wildlife habitat.
At the time the Stage 1 Remedial Action Plan was drafted, six municipal drinking water intakes
serving approximately 4.1 million people in nearly 100 communities and approximately
25 industries withdrew water from the Detroit River. In addition to serving as a water source,
approximately 30 industries and power plants discharged cooling water and/or process water to
the Detroit River, and 10 municipal wastewater treatment plants discharged industrial and
domestic wastewater. The principal industrial discharges were on the Michigan shoreline along
the lower 15 miles of the river from Zug Island downstream through the Trenton Channel to the
mouth of Lake Erie.
Major industries included steel mills, petroleum refineries, electrical power generating plants,
chemical manufacturing plants, and automotive part manufacturers. The largest discharger to the
river was the Detroit Water and Sewerage Department (DWSD), which discharged an average of
715 million gallons per day, including waste from more than 700 industrial users. An additional
46 facilities discharged to Detroit River tributaries. The river also received urban and industrial
runoff directly and through its tributaries and storm sewer systems (MDNR 1991).
Use of the river today is similar to 1991 except that there are fewer industries and wastewater
treatment plants. Currently along the Michigan shoreline, there are four municipal drinking
water intakes serving about 4.2 million people in nearly 127 communities. Approximately
20 industries and power plants discharge cooling water and/or process water to the river, and
about 29 additional facilities discharge to the tributaries. There are five municipal wastewater
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treatment plants. DWSD is still the largest discharger, discharging an average of 1.3 billion
gallons per day, including waste from about 400 industrial users (EPA 2013).
The Stage 1 Remedial Action Plan and subsequent studies found that sediment contaminant
concentrations in the Detroit River are generally much greater along the Michigan shoreline
compared to the middle portion of the river and the Ontario shoreline. The Michigan shoreline
from the Rouge River downstream through the mouth of the Trenton Channel appears to be the
most impacted. Contaminant distributions in sediment are reflective of a combination of
historical point sources and hydrological effects (MDNR 1991).
Because there is little lateral mixing in the Detroit River, contaminated sediments are believed to
deposit according to long-shore water flow following a longitudinal vector. This has resulted in
high contaminant levels in nearshore zones, particularly downstream of point sources and
tributaries, while large areas of the Detroit River exhibit moderate to low levels of contamination
further away from the Michigan shore (EPA 2013).
1.2.2 River Rouge/Ecorse Shoreline
Located in the Detroit River along the shorelines of the cities of River Rouge and Ecorse,
Michigan, the area of investigation is bounded on the upstream by the Rouge River cut-off
channel and extends downstream approximately 3 river miles to below Mud Island (Figure 1-2).
Nicholson North (also known as Allied Oil) and Nicholson South boat slips are included in the
project footprint.
The River Rouge/Ecorse Shoreline project area is considered one of the most highly impacted
areas of contaminated sediment in the Detroit River. The area is located adjacent and directly
downstream of the confluence of the Detroit and Rouge Rivers, and is therefore immediately
influenced by two AOCs. Historically, the City of Ecorse's municipal waste outfall and
15 industrial outfalls discharged within the project area. There are currently 14 industrial
discharges. Roughly 1,000 feet (ft) directly upstream of the River Rouge/Ecorse Shoreline site is
DWSD's main outfall, the largest point source discharge in the Great Lakes, discharging
1.3 billion gallons per day of municipal and industrial wastewater. The mouth of the Rouge
River is also directly upstream of the site, discharging about 1,090 cfs. The Rouge River is not
only another AOC, but due to the concentration of industry in the lower Rouge, more than
50 percent of its flow when it reaches the Detroit River is comprised of continuous industrial
discharge.
In addition to being influenced by Rouge River outflow and the DWSD outfall, the River
Rouge/Ecorse Shoreline is dominated by a DTE Energy Corporation (DTE) power plant, and
United States Steel Corporation's (U.S. Steel) Main Plant and 80" Mill. Eleven of the 14 current
outfalls are from U.S. Steel, 2 belong to DTE, and 1 is from Praxair that discharges into the
Nicholson North (aka. Allied Oil) boat slip. The combined discharge from all facilities is about
1 billion gallons per day.
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To address the delisting criteria and allow for the eventual removal of the Degradation of
Benthos BUI, EPA GLNPO, Michigan Department of Environmental Quality (MDEQ), Detroit
River Public Advisory Committee, and Friends of the Detroit River initiated an effort in 2012 to
define the "known contaminated sediment sites" in the Detroit River. The group conducted a
content analysis of a number of contaminant studies and established six sediment target sites.
The River Rouge/Ecorse Shoreline is one of the six target areas (EPA 2013).
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2. RIVER ROUGE/ECORSE SHORELINE SITE INVESTIGATION
The purpose of this field investigation was to determine the nature and extent of chemical
contamination in the areas of soft sediment deposition. Primary objectives were to determine
depth of contamination, provide information about depositional areas, and identify high priority
areas for remediation or for further investigation in the River Rouge/Ecorse Shoreline area.
The River Rouge/Ecorse Shoreline site characterization was conducted in coordination with
EPA. The investigations, including all sampling activities and analytical testing, were carried
out in accordance with procedures outlined in the QAPP (EA 2013) and FSP (EA 2013,
Appendix A).
2.1 SAMPLING PROGRAM DESIGN AND RATIONALE
The site-specific QAPP details the project data quality objectives (DQOs) and outlines how the
sample collection program fulfills the project objectives (EA 2013). Sampling was conducted to
delineate the nature and extent of sediment contamination in the River Rouge/Ecorse Shoreline
area of the Detroit River AOC.
2.1.1 Sample Locations
The sample locations for the River Rouge/Ecorse Shoreline site characterization were chosen
based on historical sampling data, location of historic and current outfalls (Figure 1-2), water
depths, and proximity to the shipping channel. Input from MDEQ and the Detroit Riverkeeper
was also received prior to finalization of sample locations. Additional information regarding the
analytical program is included in the QAPP (EA 2013).
A total of 50 sample locations were attempted using a vibracoring system and ponar grab
sampler (Figure 2-1) onboard the GLNPO Research Vessel (R/V) Mudpuppy II. Several sample
locations were abandoned; therefore, 1 core sample was collected from 43 locations and 1 grab
sample was collected from 45 locations for physical and chemical analysis. The onboard global
positioning system (GPS) of the R/VMudpuppy II was used to navigate to each location. Target
coordinates for each subsurface sediment sample location were provided to EA by EPA.
Variance from these coordinates was calculated and documented; the actual coordinates sampled
are provided in Table 2-1. Sample locations that needed to be moved or abandoned in the field
are described in Section 2.8.
2.1.2 Number of Samples
Sediment core samples were collected from 43 sample locations. The deviation from the
50 target sample locations is described in Section 2.8. Core samples were taken from up to six
intervals at each location. A total of 188 core sediment samples (not including quality control
samples) were submitted for analysis (Table 2-2). The sampling interval depths were as follows:
0-1 ft, 1-3 ft, and every 2 feet (ft) thereafter until refusal. Sediment from each interval was
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homogenized prior to separation into individual containers for submittal to the laboratory.
Sediment cores varied in length from 0.5 to 9.9 ft.
A surface sample of the top 6 inches (in.) (0-0.5 ft) of sediment was also collected with a ponar
grab/dredge sampler at 45 of the proposed coring locations. Approximately 42 ounces was
needed from each location in order to provide sufficient sample volume to support analysis of
this uppermost interval. A total of 45 grab samples (not including quality control samples) were
submitted for analysis (Table 2-2).
2.2 NAVIGATION AND SURVEY
The R/VMudpuppy II navigated to each proposed sampling location using GPS with sub-meter
accuracy. The onboard GPS of the R/VMudpuppy II utilized the World Geodetic System 1984
(WGS84) to navigate and record each individual sampling location. The unit was checked daily
for accuracy prior to use in accordance with EPA's Interim Guidance for Developing Global
Positioning System Data Collection Standard Operating Procedures and Quality Assurance
Project Plans (EPA 2008) and the procedures outlined in the QAPP (EA 2013). The sample
locations are presented in Table 2-1. Once the vessel navigated to the sample location, the
sampling team visually confirmed that the proximal location or surroundings agreed with the
proposed sample location map (Figure 2-1) prior to sampling.
Sediment elevation was calculated by normalizing measured water depths to the International
Great Lakes Datum (IGLD) 1985 height above sea level using the National Oceanic and
Atmospheric Administration (NOAA) buoy Station ID 9044020, located in Gibraltar, Michigan,
proximal to the study area (http://glakesonline.nos.noaa.gov/monitor.html). Water depths were
measured in the field using the depth finder onboard the R/VMudpuppy and verified manually by
lowering a weighted tape measure to the sediment surface. NOAA buoy Station ID 9044020
collects real-time water surface elevation in reference to IGLD85 in six-minute intervals. The
water depth measured at the time of core collection was subtracted from the calculated sea
surface elevation at time of core collection to determine the sediment surface elevation at each
core location.
2.3 SEDIMENT SAMPLING
Mobilization for the River Rouge/Ecorse Shoreline sediment sampling commenced on
27 October 2013. Sample collection was initiated on 28 October 2013 and continued through
5 November 2013. Staging for the field effort took place at the EPA Large Lakes Research
Station on Grosse lie, Michigan. Modified Level D personal protective equipment (i.e., Saranex-
coated Tyvek, safety glasses, work boots, and Nitrile gloves) were worn during core collection
(EA 2013). In addition, all personnel aboard the R/VMudpuppy II had a respirator fit test within
the last year and respirators were onboard for each individual.
Field books and sample collection data sheets were prepared in accordance with the procedures
outlined in the FSP (EA 2013, Appendix A) and EA Standard Operating Procedures (SOPs) 016
and 059 (Appendix B of the FSP) throughout sample collection and processing.
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2.3.1 Vibracore Sampling
A total of 43 sediment cores were collected using a vibracoring system onboard the GLNPO
sampling vessel R/VMudpuppy II. The vibracoring system consisted of a core liner with an
inside diameter of 4 inches (in.). A core liner with a length of 5, 7.5, or 10 ft was fitted into the
vibracoring unit with a one-way valve at the top to retain sediment during retrieval and a plastic
or stainless steel catcher inserted into the bottom of the core. Coring operations were conducted
using an onboard crane, winch, and generator.
To obtain sediment samples, a dedicated, decontaminated cellulose acetate butyrate core liner
was inserted directly into the vibracore unit and secured. The core was penetrated to the depth of
refusal (except in instances where soft sediment depth exceeded the length of available core
liners) and then retrieved using the winch system. The core liner was removed from the
vibracore unit and excess liner was cut to the sediment interface with an electric saw. The core
was capped at both ends, sealed, and measured. Each core was labeled with the location number
and the direction of the top and bottom of the core.
Following collection, sediment cores were transferred to a refrigeration truck (cooled to
4 degrees Celsius) and then transported to the onshore staging area at the EPA's Grosse Isle
facility. The cores were stored in the secured refrigeration truck until they could be processed.
A log of coring activities, sampling locations, water depths, and core recoveries was recorded in
permanently bound logbooks in indelible ink. Personnel names, local weather conditions, and
other information that impacted the field sampling program were also recorded. Each page of
the logbook was numbered and dated by the personnel entering information. Copies of the field
logbooks are provided in Appendix A.
2.3.2 Ponar Grab Sampling
A total of 45 surface sediment samples (not including quality control samples) were successfully
collected using a ponar onboard the R/V Mudpuppy II The ponar sampler was mechanically
deployed and retrieved as described in SOP MP102 (EA 2013, Appendix A). The procedure
included deploying the sampler off of the gunwale of the boat, retrieving the sampler to the boat
deck, decanting water at the top of the sampler, and emptying the sediment into an appropriate
pan. Decontaminated stainless-steel pans and bowls were used to capture the sediment as it was
emptied from the dredge. Multiple deployments were sometimes necessary to collect sufficient
volume. Samples to be analyzed for simultaneously extracted metals/acid volatile sulfide
(SEM/AVS) were placed directly into jars as the ponar sample was collected. Sediment was
transferred to the sample processing area located onshore.
2.3.3 Sediment Processing
Sediment sample processing was performed onshore at a temporary location at EPA's Grosse
Isle facility. At the processing facility, cores were split lengthwise in the liner for examination.
Sediment was then removed from the liner by subsample intervals. The cores were logged and
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photographed from the top of the core (sediment surface) to the bottom (recovery depth),
representing a vertical profile of the soft sediment. Sediments were classified in general
accordance with the Unified Soil Classification System under ASTM International D2487-11.
These sediment logging activities were performed in accordance with SOP 016 (EA 2013,
Appendix A).
After the log was completed, the sediment from each subsample interval was removed from the
core or grab sampler with a clean stainless-steel spatula or spoon and placed in a clean
disposable pan or stainless steel tray. Cores collected via vibracoring were subsampled at
several depth intervals. Core samples were homogenized by removing all material collected
from the designated depth interval in a single core and mixing until consistency was uniform.
Sediment samples were packaged and shipped in accordance with EA SOPs (EA 2013,
Appendix A). Equipment that was re-used (e.g., cutting tools, broad knife, spatula, bowls, etc.)
was decontaminated in accordance with the decontamination procedures described in Section
2.6. Lithologic and photographic logs of sediment cores are included in Appendices B and C,
respectively.
2.4 ANALYTICAL PROGRAM
The analytical program is summarized in Table 2-2. Each sediment core and ponar grab sample
underwent the following analyses:
• Total polychlorinated biphenyls (PCBs) (Aroclors)
• 34 polycyclic aromatic hydrocarbons (PAHs)
• Michigan 10 metals (arsenic, barium, cadmium, chromium, copper, lead, mercury,
selenium, silver, and zinc) plus iron and nickel
• Total organic carbon (TOC)
• Percent solids.
In addition to the above analytical parameters, ponar grab sediment samples from the 0 to 0.5 ft
interval were also analyzed for:
• SEM/AVS
• Grain size
• Total petroleum hydrocarbons (TPH).
These analyses were only performed on surface sediment because the data they yield are useful
for assessing toxicity to organisms in the biologically active zone that typically is represented by
the surface sediments (top 6 in.). Field duplicates were not collected for grain size analysis.
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2.5 SAMPLE HANDLING, CHAIN-OF-CUSTODY, AND QUALITY
ASSURANCE/QUALITY CONTROL
2.5.1 Sample Handling, Chain-of-Custody and Documentation
Sediment samples analyzed for PCBs (Aroclors), 34PAHs, Michigan 10 metals (arsenic, barium,
cadmium, chromium, copper, lead, mercury, selenium, silver, and zinc) plus iron and nickel,
TOC, percent solids, SEM/AVS, TPH and grain size were shipped from the site to
TestAmerica's Burlington laboratory. Samples were placed in the appropriate sample containers
(obtained from TestAmerica), preserved, and labeled in accordance with the QAPP/FSP (EA
2013). In preparation for shipment to the laboratories, all samples were packaged in accordance
with the procedures outlined in the FSP (EA 2013, Appendix A).
Sample labeling was performed in accordance with SOP 001 (EA 2013, Appendix A).
Individual sample containers were labeled with a unique designation that corresponded to the
specific geographic location, year of collection, and subsample depth interval. The FSP (EA
2013, Appendix A) outlines the specific sample identification procedures that were implemented.
Sample identifications included River Rouge/Ecorse, the year of sampling, the location number,
and the targeted end point of the interval in feet. "RREC" was used for River Rouge/Ecorse and
"13" was used to identify the sampling year 2013. An example of a sample identifier is
"RREC 13-01-0001." This identifier describes a sample taken at River Rouge/Ecorse in 2013 at
the depth interval of 0-1 ft below the sediment surface. Sample depths were at intervals of
0-0.5 ft (ponar grab for SEM/AVS and grain size), 0-1 ft, and every 2 ft thereafter; therefore, the
depth intervals were as follows: SURF (ponar grab), 0001, 0103, 0305, 0507, 0709 and 0911.
Field duplicates (FDs) were designated by adding "FD" to the end of the sample designation.
Matrix spikes (MSs) and matrix spike duplicates (MSDs) were designated by adding "MS" and
"MSD" to the end of the sample designation. For example: RREC 13-01 -0001FD or RREC13-
01-0001MS.
Chain-of-custody forms were completed and used to track samples from the time of sampling to
the arrival of samples at the laboratory. Completed chain-of-custody forms are available in
Appendix A of the Data Usability Assessment Report, which has been provided under separate
cover.
2.5.2 Quality Control
Throughout the project, various measures were implemented to ensure the overall quality,
credibility, and usability of the collected data. The field investigation activities included
collection of additional quality control samples (e.g., FDs, MS/MSDs) sufficient to meet the
requirements of the DQOs as defined in Section A.7 of the QAPP (EA 2013). Duplicate samples
were submitted as described in the FSP (EA 2013, Appendix A), and field and laboratory quality
control requirements were completed in accordance with Section B.5 of the QAPP (EA 2013).
Deviations from the QAPP/FSP (EA 2013) are discussed in Section 2.8.
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2.6 DECONTAMINATION
Decontamination procedures were implemented during the field investigation to prevent cross-
contamination between sampling locations. During sampling activities, disposable or dedicated
sampling tools and materials were utilized whenever possible to minimize the decontamination
efforts. Decontamination procedures were carried out in accordance with Section 4.6 of the FSP
(EA 2013, Appendix A).
2.7 INVESTIGATION-DERIVED WASTE
Following collection of the sediment samples, investigation-derived waste was managed in
accordance with the procedures described in Section 4.7 of the FSP (EA 2013, Appendix A). In
general, residual sediments and decontamination water were returned to the respective sample
location onsite. Disposable materials and personal protective equipment that came into contact
with site sediments were bagged and disposed of as general municipal waste.
2.8 DEVIATIONS FROM THE QAPP AND FSP
2.8.1 Sampling Locations
Actual coordinates are presented in Table 2-1. A total of 24 of the target sample locations were
moved during the field activities (Table 2-1). A total of 3 locations (RREC13-03, -06, and -11)
were moved offshore from the proposed locations due to close proximity of large rocks along
shore at the proposed locations. Location RREC13-33 was moved due to pilings at the proposed
location. A total of 3 locations were moved slightly offshore due to shallow water (RREC13-01,
-05, and -41). A total of 5 locations (RREC13-14, -26, -27, -29, and -46) were moved inshore
from the proposed locations and away from the channel. Location RREC13-07 was moved
because the strong current at the proposed location prevented sampling. A total of 8 locations
(RREC13-09, -13, -24, -25, -35, -42, -44, and -47) were moved slightly by EPA to areas of
greater deposition. Location RREC13-39 was moved slightly because of a steep slope at the
proposed location. Location RREC13-15 was moved because a ship was docking in the area of
the proposed location, and location RREC13-22 was moved because a barge was tied off at the
proposed location. All moves were approved by EPA at the time of sampling.
A total of 5 sample locations were abandoned (RREC13-04, -08, -10,-12, and -43) and no core
or grab samples were collected. After consultation with EPA, in accordance with the QAPP (EA
2013), vibracoring and ponar attempts were abandoned at RREC13-04 and RREC13-43 after
three attempts. Locations RREC13-08, -10, and -12 were abandoned after consultation with
EPA due to lack of soft sediments at the proposed locations. Core penetration and recovery for
each subsurface coring location were recorded in a field logbook (Appendix A) and are presented
in Table 3-1.
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2.8.2 Proposed Analytical Program
Table 2-2 compares the proposed and actual analytical program for the River Rouge/Ecorse
Shoreline area. The QAPP and FSP assumed that an average of 5 analytical samples would be
collected from each location with MS/MSDs and FDs submitted for 5 and 10 percent of total
samples submitted, respectively. Therefore, it was proposed that a total of 250 samples would be
submitted for PCB-Aroclors, selected ion monitoring (SIM) 34PAHs (SIM 34PAHs),
Michigan 10 metals plus iron and nickel, TOC, and percent solids. Fifty of the 250 samples
(surface samples only) were also to be submitted for analysis of the ratio of SEM to AVS and
grain size analysis. Actual core lengths varied (Table 3-1); however, the average length was less
than 10 ft. A total of 233 samples (not including quality control samples) were submitted for
PCB-Aroclors, SIM 34PAHs, Michigan 10 metals (plus iron and nickel), TOC, and percent
solids; 45 samples (surface samples only and not including quality control duplicates) were
submitted for grain size and SEM/AVS. FDs and MS/MSDs were submitted for 10 and
5 percent of the samples submitted, respectively, with two exceptions: grain size samples were
not submitted for FD or MS/MSD analyses and percent solids were not submitted for MS/MSD
analysis, as specified in the QAPP/FSP (EA 2013).
2.8.3 Sample Collection and Processing
A total of 27 cores (RREC13-02, -03, -13, -14, -17, -18, -21, -22, -23, -25, -26, -27, -28, -29, -30,
-31, -33, -35, -37, -38, -39, -41, -46, -47, -48, -49, and -50) were not collected to refusal, at the
discretion of an EPA official at the time of sampling, because soft sediment deposition extended
deeper than the length of available core tubes. To reduce the overall number of samples to be
submitted for analysis, the 7 to 9 ft interval and 9 tol 1 ft interval were combined into a 7 to 10 ft
interval for 6 locations (RREC13-14, -25, -27, -46, -48, and -49). This was noted in the sample
identification and approved by EPA in the field at the time of sample processing.
The QAPP and FSP (EA 2013) stated that surface samples would be collected and processed
onboard the R/VMudpuppy II. Once in the field, EPA deemed it more efficient to transfer the
ponar sample to a container and process it at the onshore staging area with the cores. Surface
sample volume was transported to shore in stainless steel containers with lids, and noted in the
core processing logbook in Appendix A. The SEM/AVS samples were an exception to this as
they were placed into jars directly after the ponar sample was taken.
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3. RESULTS
3.1 DATA EVALUATION
The overall DQO for the project was to provide data of known and documented quality to
characterize current site conditions at the River Rouge/Ecorse Shoreline area. Data collected
from the River Rouge/Ecorse Shoreline area were validated by evaluating the completeness,
correctness, and conformance of the data set against the method, SOP, or contract requirements
documented in the QAPP/FSP (EA 2013). The overall data review and validation program
attained the project objectives.
The validated data collected under this investigation were compared to the consensus-based
threshold effects concentrations (TECs) and the probable effects concentrations (PECs) of the
Sediment Quality Guidelines (SQG) for Freshwater Systems (MacDonald et al. 2000) to address
the goals of this assessment. Contaminant concentrations exceeding the applicable sediment
quality criteria were identified. Figures were prepared to visually present contaminant
concentrations and identify potential hotspots or focus areas within the study area.
Detected values greater than or equal to the Method Detection Limit, but less than the laboratory
Reporting Limit (RL), were identified as "J" qualified and are estimated. Analytes that were not
detected were identified as "U" qualified. For samples submitted with FDs, the maximum
concentration between the sample and its FD was used in reporting the bulk chemistry and
modeling results.
3.1.1 Comparison to Sediment Quality Guidelines
The SQG were developed as informal (non-regulatory) guidelines for use in interpreting
chemical data from analyses of sediments. Several biological-effects approaches have been used
to assess freshwater sediment quality relative to the potential for adverse effects on benthic
organisms, including the TEC/PEC (MacDonald et al. 2000) approach. The TEC and PEC levels
were derived using concentrations with both effects and no observed effects (MacDonald et al.
2000). TECs typically represent concentrations below which adverse biological effects were
rarely observed, while PECs typically represent concentrations in the middle of the effects range
and above which effects were more frequently observed (MacDonald et al. 2000).
Concentrations that are between the TEC and PEC represent the concentrations at which adverse
biological effects occasionally occur.
TEC and PEC levels for iron were not available from the MacDonald et al. document. Iron
concentrations in sediment from the River Rouge/Ecorse Shoreline area were compared to the
iron TEC and PEC values documented in the Ontario effect-based freshwater sediment quality
guidelines (Persaud et al. 1993). This iron benchmark was also recommended for use by the
Wisconsin Department of Natural Resources (WDNR 2003).
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3.1.2 Calculation of Total Polycyclic Aromatic Hydrocarbons and Total Polychlorinated
Biphenyls
When calculating total PAHs, J-qualified results were used and results that were U-qualified
were calculated using one-half the RL. Substituting one-half the RL (non-detect [ND] = ^RL)
for each non-detect provides a conservative estimate of the concentration. This method,
however, tends to produce results that are biased high, especially in data sets where many
samples are non-detects. This overestimation is important to consider when comparing
calculated total values to criteria. Due to the frequency of non-detects for individual PCB-
Aroclors, total PCB-Aroclor concentrations were calculated by summing the concentrations of
each PCB-Aroclor with non-detects set equal to zero (ND=0).
3.1.3 Simultaneously Extracted Metals/Acid Volatile Sulfide Ratio
The SEM/AVS approach, termed the Equilibrium Partitioning Sediment Benchmark based on
Acid Volatile Sulfide (ESBavs), has been recommended by EPA as a predictor of the
bioavailability and toxicity of some divalent metals in sediment (EPA 2005). The bioavailability
of divalent metals to aquatic organisms is influenced by the presence of AVS. In low
oxygenated (anaerobic) environments metals may precipitate with sulfides, making them
unavailable for uptake by aquatic organisms. Using this method, six metals (cadmium, copper,
lead, nickel, mercury, and zinc) were extracted using dilute cold acid, measured, and added
together (including any values that were "J" qualified) to calculate SEM. If a metal was not
detected, it was considered a zero in the calculation. The sum of the concentrations of these six
metals was then compared to the amount of AVS detected in the same sediment sample. If AVS
was not detected in the sample, the ESBAvs ratio was not calculated. The reaction between SEM
and AVS is on a molar basis, consequently the standard unit for each of these parameters is
micromoles (|imol) per gram (g) sediment, and the ratio of SEM/AVS is therefore dimensionless.
An ESBavs ratio less than 1 indicates a high degree of probability that the metals are bound to
material and not bioavailable to aquatic organisms. If the ESBavs is greater than 1, then the
metals in sediment exceed the sulfide binding ability and may have a higher probability of being
bioavailable to aquatic organisms. The ESBavs ratio provides a dimensionless value that can
serve as an indicator of potential toxicity such that when SEM/AVS ratios are less than 1 the
sediment is predicted to be non-toxic. When the ratio of SEM/AVS is greater than 1 the metals
contaminated sediment is either toxic or toxicity is uncertain. These ESBAvs ratios can be used
to predict the lack of toxicity but not the presence of toxicity, as the method does not allow for a
prediction of the onset of toxicity at values greater than 1. In addition, toxicity due to metals has
been shown to be heavily influenced by the presence of organic carbon; which removes
additional metal from the bioavailable pool (EPA 2005). In order to further reduce uncertainty in
toxicity predictions, the relationship between SEM and AVS can be normalized based on the
fraction of organic carbon present in the sediment sample. Further details regarding this
calculation are presented in Section 4.2.
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3.2 RESULTS FROM THE RIVER ROUGE/ECORSE SHORELINE SEDIMENT
INVESTIGATION
For reporting and visual presentation of the results of the sediment investigation, the River
Rouge/Ecorse Shoreline area was divided into two separate areas (Figure 2-1). Area A includes
the lower section of the Rouge River Cut-off Channel below the DT&I railroad bridge, and
continues downriver to slightly beyond the Nicholson North (aka. Allied Oil) and South slips.
Area B begins just north of the Nicholson boat slips and extends downriver past the southern
shore of Mud Island, ending just below the mouth of the Ecorse River. The two areas overlap
such that the Nicholson boat slips are included within both Area A and Area B (Figure 2-1).
3.2.1 Core Recovery
Cores were collected from 43 of the 50 locations. Vibracore samples could not be collected at
locations RREC13-04, RREC13-07, RREC13-08, and RREC13-11 because the vibracore could
not penetrate the substrate at these proposed locations. However, ponar samples were able to be
collected at locations RREC13-07 andRREC13-ll. Locations RREC13-10 andRREC13-12
were abandoned by EPA and not sampled. Location RREC 13-43 could not be sampled due to
the strong current. The remaining 43 cores were collected aboard the R/VMudpuppy. Core
recovery ranged from 0.5 ft (RREC13-19) to 9.9 ft (RREC13-23) (Table 3-1). Sediment cores
were collected to refusal or to a maximum of 10 ft. Detailed lithographic descriptions of the
43 collected cores are presented in Appendix B.
3.2.2 Lithology
The sediment cores collected within the Rouge River/Ecorse Shoreline site contained sediment
types consistent with a fluvial system. Most cores were characterized by thick alternating layers
of clay and silty clay interspersed with smaller amounts of sandy or gravelly material. Native
and non-native material such as shells, roots and organic material, hydrocarbon odor, and woody
debris were frequently observed in various sediment types and depths.
Complete core logs and photographs are included in Appendices B and C, respectively. A
general description of cores collected during the investigation is included in the text that follows.
3.2.2.1 Area A
Cores collected in Area A between the Rouge River outfall and the northernmost boat slip
included RREC 13-01 through -14, -46 and -50. These cores were comprised mostly of 2 to 6 ft
thick layers of clay and silty clay interspersed with some 0.5 tol.5 ft layers of sandy clay,
although the thickest clay layer was greater than 9 ft at RREC13-14. Hydrocarbon odor was
detected for all but two of the cores (RREC 13-05 and RREC 13-46) in Area A and was present at
depths ranging from 0 to7 ft. A sour or sewage odor was detected in the top 1 ft of sediment in
the cores collected from RREC 13-46 and in the 4 to7 ft depth range of RREC13-13. Organic
debris, shell fragments, or wood pieces were noted in all but one of the cores (RREC13-09) from
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Area A. A crimson colored streak was noted in the 0.5 tol ft range of the core from RREC13-
06, and RREC13-50 contained pieces of cement and asphalt throughout the length of the core.
3.2.2.2 Boat Slips
Cores collected within or near the four primary boat slips in the middle of the site included
RREC13-15 through -23, as well as cores from RREC13-42, -44, 45, -47, -48, and 49. The
majority of cores from the boat slip area were comprised of layers of clay or silty clay with
gravel. Silt and clay was generally darker and sometimes black in these cores, compared to the
generally gray colored layers in the rest of the cores from Areas A and B. Hydrocarbon odor
was detected in 11 of the 15 cores from near the boat slips; RREC13-47 had a particularly strong
hydrocarbon odor throughout the length of the core. Asphalt pieces were present in the first 3 ft
of RREC13-16, -18, and -45, and throughout most of RREC13-21 and -49. The cores from
RREC13-18, -21, and -45 had dark soupy silt in the first 1-2 ft of the core. Red or orange
striations were visible in four cores (RREC13-15, -18, -21, and -42) at various depths, and
charcoal was present in a small layer at 9 ft in the core collected from RREC13-48.
3.2.2.3 Area B
Cores collected in Area B between the boat slips and the southern edge of the site included
RREC13-24 through -41. The majority of these cores consisted of 1 to 9 ft layers of gray or dark
gray clay or silty clay interspersed with a few smaller layers (mostly less than 1 ft) of sand or
sandy clay. Hydrocarbon odor was present in all but 4 of the cores (RREC13-25, -31, -38, and
40). In the southern portion of Area B around Mud Island, sewage odor was detected in four
cores (RREC13-32, -35, -36, -38), mostly from depths near 2 to3 ft. Organic debris, wood, or
shell fragments were present in all but two cores from Area B (RREC13-29 and RREC13-31) at
depths ranging from the surface to greater than 9 ft. Yellow, orange, or red striations were
present in the core from RREC13-24 between 2.5 and 3.5 ft, and in the core from RREC13-32
between 2 and 4 ft.
3.2.3 Bulk Sediment Results
For bulk sediment chemistry analysis, 233 sediment samples and 37 quality control samples
(270 samples total) were submitted for PCB-Aroclors, SIM 34PAHs, metals and TOC;
45 sediment samples and 8 quality control samples (53 samples total) were submitted for
analysis of the SEM/AVS ratio and TPH; and 45 samples were submitted for grain size analysis
(Table 2-2). Of the 233 sediment samples (not including quality control samples), 188 were
sediment core samples and 45 were ponar grab samples.
Analytical data were submitted to a subcontracted data validator, Environmental Data Services,
Inc., for 100 percent Tier I and 20 percent Tier II data validation as specified in the Great Lakes
Legacy Act Data Reporting Standard (Version 1.0, March 2010). Data validation included
completeness and compliance checks, data assessment, and validation at Stage 2 following
Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund Use
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(Office of Solid Waste and Emergency Response No. 9200.1-85, EPA 540-R-08-005, 13 January
2009) to assess compliance with the Laboratory Statement of Work.
3.2.3.1 Grain Size, Particle Size, and Density
Analytical results for grain size are presented in Table 3-2. A total of 22 samples (49 percent)
were composed primarily (greater than 50 percent) of sand and gravel. The remaining
23 samples (51 percent) were composed primarily of silt and clay. The samples composed
primarily of silt and clay were collected from the southern end of Area A, the boat slips, and
throughout Area B. All of the samples collected from the northern half of Area A were
dominated by sand and gravel. Particle size distribution graphs for each sample are presented in
Appendix D.
3.2.3.2 Polychlorinated Biphenyls (Aroclors)
Total PCB-Aroclor concentrations were calculated by summing the concentrations of individual
PCB-Aroclors with NDs treated as equal to zero, as shown in Table 3-3. PCB-Aroclors were
detected in 188 of the 233 total samples submitted (81 percent). Figures 3-1A and 3-1B display
the distribution of total PCB-Aroclor SQG exceedances for all surface grab samples and
sediment core samples at each location and depth interval. Results from the surface grab are
shown on the aerial photo, and results from the core depth intervals are shown on the associated
graphs. Total PCB-Aroclor concentrations exceeding the PEC were found at locations
throughout the site.
PCB-Aroclors were detected in all ponar surface samples. Ninety-three percent of the ponar
samples had total PCB concentrations that exceeded the TEC (59.8 ng/kg [parts per billion
(ppb)]) and 42 percent of the ponar samples had total PCB concentrations that exceeded the PEC
(676 ppb). Total PCB concentrations ranged from 16 ppb in RREC13-01-SURF to 9,900 ppb in
RREC13-30-SURF. The highest total PCB concentration was detected at location RREC13-30
in the southern section of Area B (Figure 3-1B). Elevated total PCB concentrations (greater than
3 times the PEC) were also detected near the Nicholson boat slips (RREC13-15 and RREC13-
23) along the middle and southern portions of the shoreline in Area B (RREC13-26 and
RREC13-29) and in the southern end of Area B between the main shore and Mud Island
(RREC13-34).
PCB-Aroclors were detected in 143 of the 188 sediment core samples (76 percent). Sixty-seven
percent of the core samples had total PCB concentrations that exceeded the TEC (59.8 ppb) and
57 percent of the core samples had total PCB concentrations that exceeded the PEC (676 ppb).
The highest total PCB concentration (26,200 ppb) was detected in the top foot of sediment at
location RREC13-30 in the southern section of Area B (Figure 3-1B). Total PCB concentrations
exceeded 10 times the PEC around the two smaller boat slips in Area A (RREC13-14, -47, -48,
and -49) and throughout the Nicholson South boat slip (RREC13-21, -22, -23, and -44) at
multiple depth intervals (Figure 3-1 A; Table 3-3). Elevated total PCB concentrations of greater
than 10 times the PEC were also detected at locations throughout the length of the shoreline in
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Area B in multiple depth intervals (RREC13-25, -26, -28, -29, -30, -33, -35, and -36) (Figure 3-
1B; Table 3-3).
3.2.3.3 Polycyclic Aromatic Hydrocarbons
Individual results and total PAHs are provided in Table 3-4. Individual 34PAHs were detected
in each of the sediment samples submitted for analysis. Of the individual analyzed PAHs,
9 [anthracene, benzo(a)anthracene, benzo(a)pyrene, chrysene, fluoranthene, fluorene,
naphthalene, phenanthrene, and pyrene] have TEC/PEC values. Dibenzo(a,h)anthracene has a
TEC value only. More than 70 percent of the submitted samples had concentrations of
individual PAHs that exceeded respective TEC values. More than 40 percent of the submitted
samples had concentrations of individual PAHs that exceeded respective PEC values.
Total 17PAHs (ND=1/2RL) were calculated using 17 individual PAHs to be consistent with the
derivation of the TEC/PEC values. Figures 3-2A and 3-2B display the total 17PAH
concentrations for the surface grab samples and for the core samples at each depth interval at
each location. These data will be used for derivation of equilibrium partitioning sediment
benchmarks (ESBs) presented in Chapter 4. Total 17PAH concentrations exceeding the PEC
were found at locations throughout the site.
All of the ponar samples had total 17PAH concentrations that exceeded the TEC (1,610 ppb) and
58 percent of the ponar samples had total 17PAH concentrations that exceeded the PEC
(22,800 ppb). Total 17PAH concentrations ranged from 4,335 ppb in RREC13-20-SURF to
226,840 ppb in RREC13-16-SURF. The highest total 17PAH concentration was detected at
RREC13-16 near the west end of the Nicholson North (aka. Allied Oil) boat slip. In addition,
total 17PAH concentrations elevated 5 times the PEC were detected in surface samples from
locations near the Rouge River outfall at RREC13-03 and RREC13-46 (Figure 3-2A; Table 3-4).
Eighty percent of the core samples had total 17PAH concentrations that exceeded the TEC
(1,610 ppb) and 61 percent of the core samples had total 17PAH concentrations that exceeded
the PEC (22,800 ppb). Total 17PAH concentrations in core samples ranged from 27.6 ppb in
RREC13-42-0305 to 300,000 ppb in RREC13-01-0103. The highest total 17PAH
concentration was detected in the 1 ft to 3 ft depth interval at location RREC13-01, collected
from just south of the Rouge River outfall (Figure 3-2A). Core samples from 10 locations
(RREC13-01, -02, -03, -13, -29, -33, -39, -41, -46, and -50) had at least one depth interval with
Total 17PAH concentrations exceeding 5 times the PEC. Five of these locations were in the
north end of Area A near the Rouge River outfall (RREC-01, -02, -03, -46 and -50)
(Figure 3-2 A) and 4 were located in the south end of Area B near Mud Island (RREC13-29, -33,
-39, and -41) (Figure 3-2B).
3.2.3.4 Total Organic Carbon
TOC results are provided in Table 3-5. In the surface grab samples, TOC ranged from
1.5 percent at location RREC13-50-SURF in Area A near the Rouge River outfall, to
13.9 percent at location RREC13-36-SURF at the southernmost point in Area B. In the core
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samples, TOC ranged from 0.1 percent in sample RREC13-35-0305 collected from the southern
end of Area B near Mud Island, to 21 percent in sample RREC13-17-0507 collected from within
the Nicholson North (aka. Allied Oil) boat slip.
3.2.3.5 Metals
Metals results were compared to respective TEC and PEC values and are presented in Table 3-5.
Of the 12 analyzed metals, 3 (barium, selenium, and silver) do not have TEC or PEC values.
The detected concentrations for each metal with TEC/PEC exceedances at each location are
displayed in the following figures: Figures 3-3A and 3-3B (arsenic), Figures 3-4A and 3-4B
(cadmium), Figures 3-5A and 3-5B (chromium), Figures 3-6A and 3-6B (copper), Figures 3-7A
and 3-7B (iron), Figures 3-8A and 3-8B (lead), Figures 3-9A and 3-9B (mercury), Figures 3-10A
and 3-10B (nickel), and Figures 3-11A and 3-1 IB (zinc). Results from the surface grab samples
(0 to 0.5 ft interval) are shown on aerial photos and results from the core samples are shown on
the associated graphs.
Figures 3-3 A and 3-3B show the distribution of the arsenic SQG exceedances for surface grab
samples and for core samples in Areas A and B, respectively.
Arsenic concentrations in the surface grab samples ranged from 3.5 mg/kg (parts per million
[ppm]) at RREC13-40-SURF to 15.9 ppm in RREC13-50-SURF in Area A near the Rouge River
outfall. Of the 45 surface grab samples submitted for arsenic analysis, 31 percent (14 out of 45)
had concentrations that exceeded the TEC (9.79 ppm) and none had concentrations that exceeded
the PEC (33 ppm) (Table 3-5). The majority of samples exceeding the TEC in Area A occurred
near the Rouge River outfall. Arsenic PEC exceedances were found near the boat slips and
along the Ecorse shoreline from the boat slips downriver to just north of Mud Island
(Figures 3-3A and 3-3B).
In the core samples, arsenic concentrations ranged from 2.1 ppm in RREC13-38-0001 and
RREC13-39-0305 to 54.9 ppm at RREC13-21-0305 located within the Nicholson South boat
slip. Sixty-four percent of the grab samples had concentrations that exceeded the TEC (9.79
ppm) and 2.7 percent had concentrations that exceeded the PEC (33 ppm) (Table 3-5). Samples
with arsenic concentrations greater than the PEC were collected at 3 locations: RREC13-19
(0-1 ft), RREC13-21 (1-5 ft) and RREC13-44 (3 to7 ft). All of these locations were located
within the Nicholson boat slips (Figures 3-3 A and 3-3B).
Figures 3-4A and 3-4B show the distribution of the cadmium SQG exceedances for surface grab
samples and for core samples in Areas A and B, respectively.
Cadmium concentrations in the surface grab samples ranged from 0.43 ppm at RREC13-24-
SURF to 18 ppm at RREC13-34-SURF located in Area B along the Ecorse shoreline opposite
Arsenic
Cadmium
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Mud Island. Seventy-one percent of the grab samples had concentrations that exceeded the TEC
(0.99 ppm) and 20 percent had concentrations that exceeded the PEC (4.98 ppm) (Table 3-5).
The majority of samples with concentrations of cadmium exceeding the PEC occurred in Area A
near the Rouge River outfall and along the southern portion of the River Rouge shoreline to just
north of the Nicholson North (aka. Allied Oil) boat slip, as well as in Area B along the Ecorse
shoreline just north of Mud Island (Figures 3-4A and 3-4B). Of these, the grab sample collected
from RREC13-34 was the only one to exceed 3 times the PEC.
The highest cadmium concentration in core samples (28.3 ppm) was detected in sample
RREC13-41-0305 in the southern portion of Area B along the Ecorse shoreline north of Mud
Island. Seventy-four percent of the core samples had concentrations that exceeded the TEC
(0.99 ppm) and 56 percent had concentrations that exceeded the PEC (4.98 ppm) (Table 3-5).
Twelve different locations had at least 1 sample where cadmium concentrations exceeded
3 times the PEC. These major exceedances occurred across all depth intervals throughout
Areas A and B, with the exception of the area south of Mud Island (Figures 3-4A and 3-4B).
Figures 3-5A and 3-5B show the distribution of the chromium SQG exceedances for surface grab
samples and for core samples in Areas A and B, respectively.
Chromium concentrations in surface grab samples ranged from 18.9 ppm in sample RREC13-42-
SURF to 810 ppm in sample RREC13-34-SURF collected in the southern portion of Area B
between the Ecorse shoreline and Mud Island (Figure 3-5B). Seventy-eight percent of the grab
samples had chromium concentrations that exceeded the TEC (43.4 ppm) and 29 percent had
concentrations that exceeded the PEC (111 ppm) (Table 3-5). Concentrations of chromium
exceeding the PEC were detected in locations stretching from the middle of Area A downriver to
just north of Mud Island in Area B (Figures 3-5A and 3-5B).
Chromium concentrations in sediment core samples ranged from 5.3 ppm in sample RREC13-
35-0103 to 994 ppm in the 7 to 10 ft interval of sample RREC13-25-0710 (Table 3-5). Sixty-
nine percent of core samples had chromium concentrations that exceeded the TEC (43.4 ppm)
and 55 percent had concentrations that exceeded the PEC (111 ppm) (Table 3-5). The majority
of samples in which chromium concentrations exceeded 3 times the PEC were collected in the
area around the boat slips and throughout Area B with the exception of the area south of Mud
Island. Exceedances of 3 times the PEC were present throughout the sediment profile
(Figures 3-5A and 3-5B).
Copper
Figures 3-6A and 3-6B show the distribution of the copper SQG exceedances for surface grab
samples and for core samples in Areas A and B, respectively.
Copper concentrations in surface grab samples ranged from 22.9 ppm at RREC13-50-SURF to
261 ppm at RREC13-34-SURF in the southern portion of Area B in between the Ecorse
Chromium
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shoreline and Mud Island. Ninety-three percent of the grab samples had copper concentrations
that exceeded the TEC (31.6 ppm) and 13 percent had concentrations that exceeded the PEC
(149 ppm). Copper concentrations exceeded the PEC at locations in both Areas A and B. In
Area A, PEC exceedances occurred near the Rouge River outfall, in the middle of Area A, and
near the smaller boat slips. In Area B, PEC exceedances occurred in the middle of Area B and
along the Ecorse shoreline near Mud Island (Figures 3-6A and 3-6B).
Copper concentrations in sediment core samples ranged from 6.2 ppm in sample RREC13-39-
0709 to 798 ppm in sample RREC13-41-0305 collected from the southern portion of Area B near
the Ecorse shoreline north of Mud Island (Figure 3-6B). Seventy-three percent of the core
samples had concentrations that exceeded the TEC (31.6 ppm) and 55 percent had concentrations
that exceeded the PEC (149 ppm) (Table 3-5). Copper concentrations exceeding the PEC were
widespread throughout the site. Copper concentrations exceeding 3 times the PEC were detected
at sample locations in the Nicholson South boat slip (typically in the 3 to 5 and 5 to 7 ft depth
intervals). Concentrations that exceeded 3 times the PEC also occurred throughout the sediment
profile in cores collected along the Ecorse shoreline north of Mud Island.
Figures 3-7A and 3-7B show the distribution of the iron SQG exceedances for surface grab
samples and for core samples in Areas A and B, respectively.
Iron concentrations in the surface grab samples ranged from 13,700 ppm in sample RREC13-45-
SURF to 409,000 ppm in RREC13-13-SURF collected in the central portion of Area A near the
River Rouge shoreline (Figure 3-7A). Ninety-one percent of the grab samples had
concentrations that exceeded the TEC (20,000 ppm) and 62 percent had concentrations that
exceeded the PEC (40,000 ppm). The majority of iron concentrations exceeding 3 times the PEC
were detected in samples from locations along the River Rouge shoreline in Area A, starting near
the middle of Area A and stretching downriver to just north of the first boat slip (Figure 3-7A).
Iron concentrations in the sediment core samples ranged from 3,490 ppm in sample RREC13-35-
0103 to 373,000 ppm in sample RREC13-13-0103. Seventy-four percent of the core samples
had concentrations that exceeded the TEC (20,000 ppm) and 62 percent had concentrations that
exceeded the PEC (40,000 ppm) (Table 3-5). The majority of iron concentrations exceeding
3 times the PEC occurred in three areas: along the River Rouge shoreline running from the
middle of Area A to just north of the boat slips; within the boat slips; and along the Ecorse
shoreline in the middle of Area B. In these areas, iron concentrations exceeded 3 times the PEC
throughout the sediment profile (Figures 3-7A and 3-7B).
Figures 3-8A and 3-8B show the distribution of the lead SQG exceedances for surface grab
samples and for core samples in Areas A and B, respectively.
Iron
Lead
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Lead concentrations in the surface grab samples ranged from 23.6 ppm at RREC 13-20-SURF to
577 ppm at RREC13-11-SURF collected in the central portion of Area A near the River Rouge
shoreline (Figure 3-8A). Eighty-seven percent of the grab samples had lead concentrations that
exceeded the TEC (35.8 ppm) and 38 percent had concentrations that exceeded the PEC
(128 ppm). Lead concentrations exceeding the PEC were widespread along the shoreline in
Areas A and B, with the exception of the middle section of Area A where lead concentrations in
surface grabs fell between the TEC and PEC. Lead concentrations exceeding 3 times the PEC
were detected in 2 samples collected from the southern portion of Area A upriver from the
smaller boat slips (Figures 3-8A and 3-8B).
Lead concentrations in the sediment core samples ranged from 5.8 ppm in samples RREC 13-39-
0507 and RREC 13-39-0709 to 1,490 ppm in sample RREC13-13-0103. Seventy-four percent of
core samples had concentrations that exceeded the TEC (35.8 ppm) and 68 percent had
concentrations that exceeded the PEC (128 ppm) (Table 3-5). Lead concentrations exceeding
3 times the PEC were detected at sample locations near the Rouge River outfall and along a
stretch of the River Rouge and Ecorse shorelines from the middle of Area A to south of the boat
slips. In Area B, concentrations exceeding 3 times the PEC occurred in samples collected along
the Ecorse shoreline just north of Mud Island. Within these areas, lead concentrations exceeding
3 times the PEC were present throughout the sediment profile (Figures 3-8A and 3-8B).
Mercury
Figures 3-9A and 3-9B show the distribution of the mercury SQG exceedances for surface grab
samples and for core samples in Areas A and B, respectively.
Mercury concentrations in surface grab samples ranged from 0.042 ppm in sample RREC13-50-
SURF to 1.5 ppm in sample RREC13-34-SURF collected from the southern portion of Area B
between the Ecorse shoreline and Mud Island. Seventy-three percent of the grab samples had
concentrations that exceeded the TEC (0.18 ppm) and 4.4 percent had concentrations that
exceeded the PEC (1.06 ppm) (Table 3-5). PEC exceedances were detected in samples collected
from the northern portion of Area A near the Rouge River outfall (RREC 13-01) and in the
southern portion of Area B along the Ecorse shoreline opposite Mud Island (RREC13-34)
(Figures 3-9A and 3-9B).
The highest mercury concentration (3.3 ppm) was detected in sample RREC13-41-0911-FD.
Seventy-six percent of the core samples had concentrations that exceeded the TEC (0.18 ppm)
and 24 percent had concentrations that exceeded the PEC (1.06 ppm) (Table 3-5). The highest
concentrations of mercury in core samples were detected in the northern portion of Area A near
the Rouge River outfall, and in the southern portion of Area B along the Ecorse shoreline just
north of Mud Island. Other locations where mercury concentrations exceeded the PEC included
the southern portion of Area A, the area in and around the boat slips, and along the Ecorse
shoreline throughout the central portion of Area B. PEC exceedances in these areas occurred
throughout the sediment profile (Figures 3-9A and 3-9B).
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Nickel
Figures 3-10A and 3-10B show the distribution of the nickel SQG exceedances for surface grab
samples and for core samples in Areas A and B, respectively.
Nickel concentrations in surface grab samples ranged from 17 ppm in sample RREC13-42-SURF
to 314 ppm in sample RREC13-34-SURF collected from the southern portion of Area B between
the Ecorse shoreline and Mud Island (Figure 3-1 OB). Eighty percent of the grab samples had
concentrations that exceeded the TEC (22.7 ppm) and 40 percent had concentrations that
exceeded the PEC (48.6 ppm) (Table 3-5). The majority of the nickel PEC exceedances
occurred along the River Rouge shoreline from the middle of Area A to south of the boat slips,
within the boat slips, and along the Ecorse shoreline from the middle of Area B to Mud Island
(Figures 3-10A and 3-10B).
Nickel concentrations in sediment core samples ranged from 4.7 ppm in sample RREC13-35-
0103 to 388 ppm in sample RREC13-23-0305. Seventy-eight percent of the core samples had
concentrations that exceeded the TEC (22.7 ppm), and 60 percent had concentrations that
exceeded the PEC (48.6 ppm) (Table 3-5). Concentrations of nickel exceeding 3 times the PEC
were detected throughout the sediment profile in cores from many locations in Area B, extending
from north of the first boat slip downriver to just north of Mud Island (Figures 3-10A and
3-10B).
Figures 3-11A and 3-1 IB show the distribution of the zinc SQG exceedances for surface grab
samples and for core samples in Areas A and B, respectively.
Zinc concentrations in surface grab samples ranged from 89.7 ppm in sample RREC13-20-SURF
to 3,630 ppm in sample RREC13-11-SURF collected from the central portion of Area A near the
River Rouge shoreline (Figure 3-11 A). Ninety-eight percent of the grab samples had
concentrations that exceeded the TEC (121 ppm) and 31 percent had concentrations that
exceeded the PEC (459 ppm). Zinc concentrations exceeded 3 times the PEC in samples
collected along the River Rouge shoreline in the southern portion of Area A (Figure 3-11 A).
Zinc concentrations in sediment core samples ranged from 27.3 ppm (RREC13-39-0709) to
11,800 ppm (RREC13-13-0103). Seventy-three percent of the core samples had concentrations
that exceeded the TEC (121 ppm) and 64 percent had concentrations that exceeded the PEC
(459 ppm) (Table 3-5). Excluding the area around Mud Island, all but 4 of the remaining sample
locations had zinc concentrations exceeding the PEC in at least one depth interval. Most of the
zinc concentrations exceeding 3 times the PEC occurred throughout Area A along the River
Rouge shoreline (Figure 3-11 A).
Zinc
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3.2.3.6 Equilibrium Partitioning Sediment Benchmarks based on Acid Volatile Sulfide
(ESBavs)
All ESBavs results are presented in Table 3-6. SEM and AVS data, along with sample-specific
TOC, will be used for derivation of organic carbon normalized metal toxicity predictors
presented in Section 4.2. As discussed in Section 3.1.3, this current analysis addresses only the
effect of sulfide on bioavailability of SEM. When AVS exceeds SEM, the ESBavs ratio is less
than 1 and the metals are unlikely to be available for toxicity. Alternatively, ESBavs ratios
greater than 1 indicate that metals may, or may not, be available to result in toxic effects. Fifty-
six percent of the samples analyzed for SEM and AVS had ESBavs ratios greater than 1, with the
maximum of 18.2 occurring at RREC13-13 in the southern portion of Area A. The descending
rank order for the top five locations is RREC13-13, -14, -25, -47, and -09 with ESBavs ratio
values of 18.2, 6.83, 6.53, 5.53, and 4.31, respectively.
3.2.3.7 Total Petroleum Hydrocarbons - Diesel Range Organics and Mid-Range Organics
Results for diesel range organics (DRO) and mid-range organics (MRO) are presented in
Table 3-7. The highest concentration of DRO (C10-C20) (8,800 ppm) was detected at location
RREC13-34. Concentrations of DRO (C10-C28) ranged from 180 ppm at RREC13-07 to 23,000
ppm at RREC13-34. Concentrations of MRO (C20-C36) ranged from 220 ppm at RREC13-50
to 29,000 ppm at RREC13-34 and RREC13-41.
The TPH concentration was determined for each location by summing DRO (C10-C28) and
MRO (C20-C36) concentrations. Samples in which TPH was greater than 10,000 ppm were
considered to constitute major exceedances. A total of 7 locations (RREC13-01, -15, -21, -23, -
30, -34, and -41) had TPH values that indicated major exceedances. These elevated TPH values
occurred in Area A near the Rouge River outfall, around the boat slips, and in the southern
portion of Area B along the Ecorse shoreline (Figure 3-12).
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4. EQUILIBRIUM PARTITIONING SEDIMENT BENCHMARKS AND ORGANIC
CARBON NORMALIZED METALS
PAH ESB toxic units (ESBTUs) were calculated as an additional tool for evaluating potential
risk associated with sediment contamination. ESBTUs are used to estimate whether there is
potential ecological risk associated with exposure to pore water that is in equilibrium with a
measured concentration of the contaminant in the sediment. Thus, ESBTUs are calculated using
an assumed relationship for partitioning between sediment and water and are discussed in
Section 4.1.
Similarly, organic carbon normalized metal concentrations have been calculated as a tool for
evaluating potential risk from divalent metals using the bioavailability and toxicity effects of
both AVS and TOC (EPA 2005), and are discussed in Section 4.2.
4.1 PAHS
ESBs for total 34PAHs were calculated following the methods outlined in Procedures for the
Derivation of Equilibrium Partitioning Sediment Benchmarks (ESBs) for the Protection of
Benthic Organisms: PAH Mixtures (EPA 2003). Based on this guidance, individual PAH
concentrations in sediment were first divided by the fraction of organic carbon measured in the
sediment sample, resulting in an organic carbon-based PAH concentration or normalized
concentration. This value was then compared to the maximum solubility of that PAH in
sediment on an organic carbon basis. If the organic carbon normalized PAH concentration was
greater than the maximum solubility concentration, then the maximum solubility concentration
was used to calculate the PAH ESBTU instead of the normalized concentration. If the organic
carbon normalized PAH concentration was less than the maximum solubility, the normalized
concentration was used. This value was then divided by the individual PAH's effective
concentration in sediment, defined as the product of its final chronic value (FCV) and organic
carbon-water partition coefficient (Koc), resulting in an ESB for each individual PAH. The PAH
ESB for a sediment sample is the sum of the 34 individual PAH's ESBTUs (Table 4-1).
Typically, a PAH ESBTU less than or equal to 1.0 indicates that benthic organisms are not
expected to be harmed by contamination present in the sediments, while samples with PAH
ESBTUs greater than 1.0 may be toxic to aquatic life (EPA 2003). Of the 233 total sediment
samples, 100 had a PAH ESBTU less than 1.0 and 133 samples had a PAH ESBTU greater than
or equal to 1.0 (Table 4-1).
Twenty-two ponar grab samples had a PAH ESBTU greater than 1 (Figures 4-1A and 4-1B), and
eight had PAH ESBTUs greater than 2. Of those eight samples, all but one occurred either in
Area A along the River Rouge Shoreline or near the boat slips. The highest PAH ESBTUs
occurred at locations RREC13-16 (ESBTU = 6.348) in the west end of the Nicholson North (aka.
Allied Oil) boat slip, and RREC13-24 (ESBTU = 3.161) along the Ecorse shoreline, just south of
the Nicholson South boat slip (Table 4-1).
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In the sediment core samples, PAH ESBTUs greater than 3 were found in at least one depth
at 15 of the 43 locations where cores were collected (Table 4-1). PAH ESBTUs greater than 7.5
were present in two samples: RREC13-01-0305 (ESBTU = 7.954) near the Rouge River outfall
and RREC13-23-0305 (ESBTU = 8.215) at the mouth of the Nicholson South boat slip (Figures
4-1A and 4-1B). No ESBTUs greater than 10 were calculated at any locations.
4.2 METALS
Metal toxicity was evaluated through an indirect estimate of bioavailability based on the
concentrations of AVS and SEM (ESBavs as discussed in Section 3.2.3.6), and TOC in the
sediments. Predictors of metal bioavailability and toxicity using AVS, SEM, and TOC were
calculated following the methods outlined in Procedures for the Derivation of Equilibrium
Partitioning Sediment Benchmarks (ESBs) for the Protection ofBenthic Organisms: Metal
Mixtures (Cadmium, Copper, Lead, Nickel, Silver, and Zinc) (EPA 2005). This calculation
accounts for the relationship between SEM and AVS, and also provides a normalized value that
incorporates the influence of organic carbon present in the sediment, resulting in a more accurate
predictor of sediment toxicity. The molar concentration of AVS was subtracted from the molar
concentration of the sum of the SEM measured in each sediment sample, and the result was
divided by the fraction of organic carbon, accounting for preferential sorption of metals to
organic carbon.
Where
£SEM = Sum of Simultaneously Extracted Meals (|imol/g sediment)
AVS = Acid Volatile Sulfide (|imol/g sediment)
foc = Fraction of organic carbon
Units of this predictor are |imol per gram organic carbon (goc)- It should be noted that if the
particular sample has excess AVS such that all SEM is accounted for, the numerator can be
negative. As discussed in EPA (2005), when this method is used, a value less than 130 |amol
(including negative values) of residual SEM per goc indicates that the sediment poses a low risk
of adverse biological effects associated with metals. Values between 130 and 3,000 |amol/goc
may have adverse effects, and values over 3,000 |amol/goc are expected to be associated with
adverse effects. These results for metals were above the threshold of 130 |amol of residual
SEM/goc in 5 of the 45 ponar grab samples (RREC13-13, -14, -15, -25, and -27) (Table 4-2).
The highest result was 955 |amol/goc from RREC13-13 in Area A along the River Rouge
shoreline just north of the first boat slip, which is also the sample that exhibited the highest
ESBavs ratio (Section 3.2.3.6). The locations that produced samples exceeding the 130 |amol/goc
were located in the southern portion of Area A near the boat slips, and along the Ecorse shoreline
in the northern portion of Area B. None of the samples had values greater than 3,000 |imol/g„c.
(ZSEM -AVS)
foc
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5. SPATIAL ANALYSIS TO DETERMINE HOTSPOTS WITHIN THE RIVER
ROUGE/ECORSE SHORELINE AREA
To determine the location of hotspots within the Detroit River AOC, the dataset of all individual
constituents exceeding their respective PECs in sediment samples (Section 3.2) was spatially
interpolated to develop an estimate of the level and distribution of elevated concentrations of
constituents across the study area. Potential hotspots identified by the all constituent analysis
were then verified by comparison to spatial interpolations of two additional datasets: (1) the
calculated PAH ESBTUs (Section 4.1); and (2) the calculated organic carbon normalized metals
concentrations (Section 4.2). This hotspot determination allows for prioritizing areas to be
targeted for remediation.
Interpolation was performed by using a spatially explicit statistical method called kriging.
Section 5.3 describes the kriging analysis results for all constituents and Section 5.4 describes the
kriging analysis results for PAH ESBTUs and organic carbon normalized simultaneously
extracted metals.
5.1 METHODOLOGY
A three-dimensional model of each analyte measured in the sediment samples was constructed
using the statistical interpolation method of kriging with C-Tech's Environmental Visualization
System (EVS) Pro Version. The model region excluded the navigation channel and was
bounded on the bottom by the observed recovery depth at each core location. Input included
each analyte's concentration at every location and the results were combined to identify all areas
with one or more analyte concentrations above the respective PEC levels, 2 times above the PEC
levels, and 3 times above the PEC levels. To supplement the identification of hotspots identified
from modeling all constituents, PAH ESBTUs were modeled separately and those areas with
PAH ESBTU values of greater than 1, and between 1 and 10, were identified. Kriging models
were also produced for organic carbon normalized simultaneously extracted metals, and areas
where these values exceeded 130 |imol/goc were identified.
The kriging methodology is subject to some uncertainties which can potentially impact the
resulting volume estimations. Kriging assumes that the variogram does not change over the
model domain (i.e., the variogram is stationary). In order to minimize the impact from violating
this assumption, the study area was divided into several zones that were kriged independently.
The kriging model used to estimate contaminated sediment volume is also particularly sensitive
to the directional dependency parameter. Results of the sediment core data showed a higher
degree of spatial correlation in the horizontal versus vertical directions, and this observation was
incorporated into the kriging model. The assumed relative difference between horizontal and
vertical directional dependence of the data had the effect of smearing the interpolated sediment
plume in the horizontal direction, and this assumption therefore could result in higher volume
estimates.
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5.2 MODEL RESULTS FOR ALL CONSTITUENTS IN THE RIVER
ROUGE/ECORSE SHORELINE STUDY AREA
Concentrations of all individual constituents were input into the model, and the kriging analysis
identified any areas that contained PEC exceedances of total PCBs, total PAHs, and/or any of the
nine metals for which PECs were available (MacDonald et al. 2000, Persaud et al. 1993).
This kriging analysis determined that for the majority of the study area one or more analytes
were present in concentrations exceeding the PEC. Three hotspots (two larger hotspots and
one smaller hotspot) containing PEC exceedances were identified. Figures 5-1A and 5-1B
present the results for all constituents exceeding the respective PECs in Areas A and B. Section
5.3.1 describes the two major hotspots; major hotspots are defined as areas having concentrations
of at least one contaminant exceeding three times the PEC and estimated sediment volumes
exceeding 100,000 cubic yards (cy). These two major hotspots have the largest estimated
volumes of sediment with constituents of concern (COCs) exceeding the PEC. Section 5.3.2
describes the one smaller hotspot area that has similarly elevated COC concentrations, but a
smaller estimated sediment volume (below 100,000 cy) containing PEC exceedances.
The volume estimations presented on Figures 5-1A and 5-1B are based on the data and methods
used in geostatistical modeling as described in Section 5.1 and, as such, are subject to a number
of limitations and uncertainties which include the following factors:
• Limitations in data coverage: Accuracy of the models is dependent upon the sample
design; areas of limited sample coverage, areas where sediments may be heterogeneous at
small scales and areas where physical features interrupt spatial patterns in chemical
distribution may not be accurately represented by model predictions. If required, such
uncertainty can be addressed by additional sampling guided by geostatistical
results. Statistical accuracy is also limited by the available information regarding
sediment surface elevation and depth of soft sediments, which may change the geometry
used in spatial statistics.
• Uncertainties associated with comparison criteria: Volumes are based on statistical
analysis of chemical concentrations exceeding sediment quality benchmarks. While
these benchmarks are consensus and risk-based and were approved for use in the site
characterization additional interpretation may be required to fully assess the risks
associated with the contaminants of concern. As such, the relevance of estimated volumes
is dependent on the application of benchmarks.
• Limited relevance to remediation: As stated above, volumes are based solely on
statistical analysis of chemical concentrations exceeding sediment quality
benchmarks. While these volumes provide an indicator of the in situ volume that exceeds
guidelines and could require remedial action, they are considered preliminary and
additional information would improve the estimate. For example remediation by
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dredging would require removal of additional volume, including overburden, horizontal
and vertical overdredge, contingency associated with statistical uncertainty.
Additionally, both the combining of the deepest subsampling intervals at some locations to
reduce total samples and the number of locations where PEC exceedances occurred in the bottom
interval of cores that were not collected to refusal are potential contributors to uncertainty in the
sediment volume estimations. In summary, the volumes presented here are initial indicators of
sediments that may require action, but involve uncertainties and limitations that may require
refinement prior to use in remedial decision-making.
5.3 DETERMINATION OF PRIORITY HOTSPOT AREAS IN THE RIVER
ROUGE/ECORSE SHORELINE AREA
5.3.1 Major Hotspot Locations
Based on the interpolation results, 2 major hotspot areas are identified: the River Rouge
shoreline area (Hotspot 1); and the Ecorse shoreline area (Hotspot 3).
5.3.1.1 Hotspot 1: River Rouge Shoreline
The River Rouge shoreline area hotspot includes the mouth of the Rouge River and stretches
south to the mouth of the Nicholson North (aka. Allied Oil) boat slip (Figure 5-1 A). The model
estimates that the majority of this area has constituent concentrations exceeding 3 times the PEC,
about one-quarter of the area has constituent concentrations between 2 and 3 times the PEC, and
the remaining portion (less than one-quarter) has constituent concentrations between 1 and 2
times the PEC (Figure 5-1 A). The estimated volume of sediment with constituent concentrations
exceeding the PEC is 794,000 cy for Hotspot 1 (Figure 5-1 A).
The COCs present in Hotspot 1 at concentrations greater than 3 times their respective PECs
include total 17PAHs, total PCBs, cadmium, chromium, iron, lead, nickel and zinc. Mercury
concentrations exceeded 2 times the PEC near the Rouge River outfall. The northern portion of
Hotspot 1 around the mouth of the Rouge River was dominated by concentrations of cadmium,
lead, total PCBs, and total 17PAHs. Total PCBs, total 17PAHs, and lead concentrations
continued to exceed 3 times their respective PECs throughout the central portion of Hotspot 1,
and concentrations of iron, nickel and zinc also exceeded 3 times their PECs in this section of the
River Rouge shoreline. The southern portion of Hotspot 1 extending downriver to the mouth of
the Nicholson North (aka. Allied Oil) boat slip had concentrations of total PCBs, iron, lead, and
nickel that exceeded 3 times their respective PECs (Figure 5-2).
5.3.1.2 Hotspot 3: Ecorse Shoreline
The Ecorse shoreline area (Figure 5-1B) has constituent concentrations exceeding 3 times the
PEC in the majority of the hotspot, including all of the Nicholson South boat slip. The model
estimates that approximately two-thirds of this hotspot has constituent concentrations exceeding
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3 times the PEC, while the remaining one-third has concentrations exceeding the PEC or 2 times
the PEC. Constituent concentrations exceeding 1 or 2 times the PEC are present primarily in the
southern end of the hotspot in the areas surrounding Mud Island (Figure 5-4). The estimated
volume of sediment with contaminant concentrations exceeding the PEC is 1,338,000 cy
(Figure 5-1B).
The COCs present in Hotspot 3 include total PAHs, total PCBs, arsenic, cadmium, chromium,
copper, iron, lead, mercury, nickel, and zinc. Arsenic concentrations exceeding the PEC were
detected only at 2 sampling locations within the Nicholson South boat slip. All other COCs had
concentrations exceeding their respective PECs throughout the majority of Hotspot 3. In
particular, concentrations of total PCBs, cadmium, chromium, iron, nickel and lead exceeded
2 and 3 times their respective PECs throughout most of Hotspot 3. Concentrations of total
17PAHs exceeding 3 times the PEC were detected mostly in the southern half of the hotspot
(Figure 5-4).
The southern end of Hotspot 3 includes sampling location RREC13-36 at the mouth of the
Ecorse River. COCs exceeding their PECs near the Ecorse River outfall include total 17PAHs,
total PCBs, cadmium, chromium, copper, lead, mercury, nickel and zinc. Concentrations of total
17PAHs exceeded 3 times the PEC at the mouth of Ecorse River, and concentrations of total
PCBs exceeded 10 times the PEC (Figure 5-4).
5.3.2 Other Hotspot Locations
Spatial analysis identified one smaller area that also contained measured concentrations of one or
more constituents above PECs (Figures 5-1A and 5-1B).
5.3.2.1 Hotspot 2: Nicholson North (aka. Allied Oil) Boat Slip
Hotspot 2 consists of the western two-thirds of the Nicholson North (aka. Allied Oil) boat slip,
and includes sampling locations RREC13-16, -17, -18 and -19 (Figure 5-4). The model
estimates that approximately one-quarter of the area has constituent concentrations that exceed 3
times the PEC. PEC exceedances in Hotspot 2 included total PAHs, total PCBs, arsenic,
cadmium, chromium, copper, iron, lead, mercury, nickel, and zinc. Total PCB concentrations
exceeded 2 times the PEC at all four of the sampling locations within this hotspot. The PEC
exceedances for PCBs in this hotspot were limited to the top 5 ft of sediment. Concentrations of
total 17 PAHs, cadmium, chromium, copper, iron, lead, nickel, and zinc that exceeded the PEC
occurred in the 0 to 5 ft depth interval, with PEC exceedances also extending down to the 10 ft
limit of core recovery. The presence of elevated constituent concentrations near refusal depth
results in an estimated volume of impacted sediment in Hotspot 2 of 56,000 cy (Figures 5-1A
and 5-3).
5.4 MODEL RESULTS FOR PAH AND ORGANIC CARBON NORMALIZED
METALS FOR THE RIVER ROUGE/ECORSE SHORELINE STUDY AREA
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PAH ESBTUs were also modeled using the kriging statistical method. This analysis identified
the areas within the River Rouge/Ecorse Shoreline site with ESBTUs greater than 1
(Figures 5-5A and 5-5B). The results mirror almost exactly the hotspots identified in the
cumulative COC model, with the exception of a gap in the middle section of Hotspot 1 where the
PAH ESBTUs were determined to be less than 1.
The spatial analysis for PAH ESBTUs in Area A identified three areas where sediment samples
had PAH ESBTUs greater than 1. Figure 5-5 A presents the areas identified along with the
maximum PAH ESBTU in each area. These areas with elevated PAH ESBTUs in Area A are in
the same location as Hotspots 1 and 2, as identified in Section 5.3 (Figure 5-1 A). PAH ESBTUs
were all between 1 and 10. The highest PAH ESBTU in Area A (7.95) was present in the 3- to
5-ft depth interval at location RREC13-01 within Hotspot 1 in the northern portion of Area A.
The PAH ESBTU kriging results for Area A almost exactly match the hotspots identified in the
cumulative COC model, with the exception of a gap in the middle section of Hotspot 1 where the
PAH ESBTUs were determined to be less than 1 (Figure 5-5 A).
The spatial analysis for PAH ESBTUs in Area B identified one large area along the Ecorse
shoreline where sediment samples had PAH ESBTUs greater than 1. Figure 5-5B presents the
areas identified along with the maximum PAH ESBTU in each area. This area with elevated
PAH ESBTUs is in the same location as Hotspot 1 (Figure 5-1 A). PAH ESBTUs were all
between 1 and 10. The highest PAH ESBTU in Area B (8.22) was present in the 3- to 5-ft depth
interval at location RREC13-23.
Additionally, organic carbon normalized metals were modeled using the kriging statistical
method. This analysis identified 3 areas where organic carbon normalized metals exceeded the
threshold value of 130 |amol/goc (Figures 5-6A and 5-6B). The largest of these three areas of
exceedance occurred within Hotspot 1 (Figure 5-6A). The other two areas where organic carbon
normalized metals exceeded 130 |amol/goc occurred within Hotspot 3 (Figure 5-6B). These
results therefore reinforce the previously identified hotspots and serve to further distinguish
locations where bioavailable metals may be present at concentrations that are potentially harmful
to benthic organisms.
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6. CONCLUSIONS
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Based on the data collected during the River Rouge/Ecorse Shoreline sediment investigation, a
large portion of the site contains elevated concentrations of constituents that are potentially
harmful to benthic communities. The impacted areas of the site are identified as 2 major
hotspots (Hotspots 1 and 3) and 1 smaller hotspot (Hotspots 2). These 3 hotspots have an
estimated total of 2,188,000 cy of sediment with COC concentrations exceeding PECs, and they
should be considered as priority areas for further investigation and potential remediation efforts.
Model results indicated that each of the 3 hotspots has significant volumes of sediment with
elevated COC concentrations exceeding 2 or 3 times PEC levels. Further delineation of the
extent of sediment with elevated concentrations of COCs is recommended. Modeling of the
PAH ESBTUs also showed elevated values reflecting impacted sediment throughout most of the
hotspot areas that were identified by modeling of all COCs with concentrations above the PEC.
This confirms that these 3 hotspots should be considered priority areas for additional assessment
and potential remediation.
Further investigation in each hotspot is recommended in part because estimates regarding the
areal extent of the 3 hotspots and the volumes of sediment containing elevated concentrations of
COCs are subject to significant uncertainty due to the limited number of samples analyzed.
Estimates regarding the extent of impaired sediment conditions stretching away from shore into
the shipping channel could be improved with additional sampling locations. Sampling locations
where cores were not collected to refusal and where elevated COC concentrations were detected
in the deepest interval present uncertainty regarding the extent of contamination below the
sediment surface that could be addressed through further investigation.
Although additional assessment should improve estimates, the present study serves to provide an
effective initial characterization indicating that much of the River Rouge/Ecorse Shoreline Site
contains sediment impacted by elevated levels of COCs.
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EA Project No.: 6256114.10
Version: FINAL
Page 7-1
August 2014
7. REFERENCES
EA Science and Technology and Its Affiliate
EA Engineering, Science, and Technology, (MI) PLC
EA Engineering, Science, and Technology (MI), PLC (EA). 2013. Quality Assurance Project
Plan, River Rouge/Ecorse Shoreline Area Site Characterization, Detroit River Area of
Concern, Detroit, Michigan. May.
Great Lakes Legacy Act Data Reporting Standard (Version 1.0, March 2010).
MacDonald D.D., C.G. Ingersoll, and T.A. Berger. 2000. Development and evaluation of
consensus-based sediment quality guidelines for freshwater ecosystems. Archives of
Environmental Contamination and Toxicology 39:20-31.
Michigan Department of Natural Resources (MDNR). 1991. Detroit River Remedial Action
Plan Stage 1. Surface Water Quality Division, Lansing, Michigan. June.
Persaud, D.R., R. Jaagumagi, and A. Hayton. 1993. Guidelines for the protection and
management of aquatic sediments in Ontario. Standards Development Branch. Ontario
Ministry of Environment and Energy. Toronto, Canada.
U.S. Environmental Protection Agency (EPA). 2003. Procedures for the Derivation of
Equilibrium Partitioning Sediment Benchmarks (ESBs) for the Protection ofBenthic
Organisms: PAH Mixtures. EPA-600-R-02-013. Office of Research and Development,
Washington, DC 20460.
. 2005. Procedures for the Derivation of Equilibrium Partitioning Sediment Benchmarks
(ESBs) for the Protection ofBenthic Organisms: Metal Mixtures (Cadmium, Copper,
Lead, Nickel, Silver, and Zinc). EPA-600-R-02-011. Office of Research and
Development, Washington, DC 20460. January.
. 2008. Interim Guidance for Developing Global Positioning System Data Collection
Standard Operating Procedures and Quality Assurance Project Plans. EPA/600/R-
08/020.
. 2009. Guidance for Labeling Externally Validated Laboratory Analytical Data for
Superfund Use. Office of Solid Waste and Emergency Response No. 9200.1-85, EPA
540-R-08-005. 13 January 2009.
. 2013. Assessment of Contaminated Sediments for the River Rouge/Ecorse Shoreline
Area Site Characterization in the Detroit River Area of Concern.
Wisconsin Department of Natural Resources (WDNR). 2003. Consensus Based Sediment
Quality Guidelines, Recommendations for Use and Application. WT 732-2003.
December.
River Rouge/Ecorse Shoreline Site Characterization
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
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Figures
-------
FIGURE 1-1
Project Site Location
River Rouge/Ecorse Shoreline Assessment
of Contaminated Sediments
-------
RIVER ROUGE, Ml
Nicholson North
Boat Slip
Nicholson South
Boat Slip
Mud Island
y«* -4 ^ . .
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Project Area
Toledo
Legend
River Rouge/Ecorse Shoreline Area
0 Outfalls
River Rouge/Ecorse Shoreline Area
Detroit River Area of Concern
e
0.25
."'j'"
Data Sources: EPA 2013, USGS 2013
ArcGIS Online 2012
Map Date: July 2014
FIGURE 1-2
River Rouge/Ecorse Shoreline Area
River Rouge/Ecorse Shoreline Assessment
of Contaminated Sediments
-------
RREC13-46
RREC13-01
RREC13-21
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RREC13-26
RREC13-41
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RREC13-33
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| RREC13-27 |
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@ * 1 RREC13-29 |
1 RREC13-30 |
RREC13-32
RREC13-39
RREC13-38 |
I RREC13-40|
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Legend
Surface and Subsurface
- Sample Location
Surface Sample Location
1 per EPA Field Guidance
Location Abandoned
* per EPA Field Guidance
Zone
Area A
Area B
Area A/B Overlap
Detroit River Area of Concern
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Data Sources: EPA 2013, USGS 2013
Aerial Source: ESRI ArcGIS Online
Map Date: July 2014
FIGURE 2-1
Sample Locations
River Rouge/Ecorse Shoreline Assessment
of Contaminated Sediments
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Total (ND= 0) PCB-Aroclor
Concentrations (ug/kg)
Detected in Area A
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
-------
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A Area A (east side)
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Ponar sample results are shown
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Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon Total (ND = % RL) 17PAH results.
Total (ND = V2 RL) 17PAH
Concentrations
~
I
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> 2x PEC (45,600 pg/kg)
> PEC (22,800 pg/kg)
> TEC (1,610 pg/kg)
< TEC
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0 250 500 750 1,000
Feet
Map Created: 7/22/2014
Basemap: ESRI 2012
FIGURE 3-2A
Total (ND= Vi RL) 17PAH Concentrations
(ug/kg) Detected in Area A
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
-------
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A Area A (east side)
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on the map.
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shown on the graphs.
Locations are color coded based
upon arsenic results.
Arsenic
Concentrations
I
:
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> 2x PEC (66 mg/kg)
> PEC (33 mg/kg)
> TEC (9.79 mg/kg)
< TEC
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0 250 500 750 1,000
Feet
Map Created: 7/22/2014
Basemap: ESRI 2012
FIGURE 3-3A
Arsenic Concentrations (mg/kg)
Detected in Area A
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
-------
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A Area B (east side)
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on the map,
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon arsenic results.
Arsenic
Concentrations
> 3x PEC (99 mg/kg)
> 2x PEC (66 mg/kg)
> PEC (33 mg/kg)
> TEC (9.79 mg/kg)
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Legend
A Area A (east side)
O Area A (west side)
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on the map.
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon cadmium results.
Cadmium
Concentrations
>3x PEC (14.94 mg/kg)
> 2x PEC (9.96 mg/kg)
> PEC (4.98 mg/kg)
> TEC (0.99 mg/kg)
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on the map,
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shown on the graphs.
Locations are color coded based
upon cadmium results.
Cadmium
Concentrations
>3x PEC (14.94 mg/kg)
> 2x PEC (9.96 mg/kg)
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FIGURE 3-5A
Chromium Concentrations (mg/kg)
Detected in Area A
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
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A Area A (east side)
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on the map.
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon copper results.
Copper
Concentrations
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> 2x PEC (298 mg/kg)
> PEC (149 mg/kg)
> TEC (31.6 mg/kg)
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A Area B (east side)
O Area B (west side)
Poriar sample results are shown
on the map,
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon copper results.
Copper
Concentrations
> 3x PEC (447 mg/kg)
> 2x PEC (298 mg/kg)
> PEC (149 mg/kg)
> TEC (31.6 mg/kg)
D
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Legend
A Area A (east side)
O Area A (west side)
Ponar sample results are shown
on the map.
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon iron results.
Iron
Concentrations
I
:
>3x PEC (120.000 mg/kg)
> 2x PEC (80,000 mg/kg)
> PEC (40,000 mg/kg)
> TEC (20,000 mg/kg)
< TEC
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FIGURE 3-7A
Iron Concentrations (mg/kg)
Detected in Area A
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
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A Area B (east side)
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on the map,
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon iron results.
Iron
Concentrations
I
>3x PEC (120,000 mg/kg)
> 2x PEC (80,000 mg/kg)
> PEC (40,000 mg/kg)
> TEC (20,000 mg/kg)
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Legend
A Area A (east side)
O Area A (west side)
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on the map.
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon lead results.
Lead
Concentrations
> 3x PEC (384 mg/kg)
> 2x PEC (256 mg/kg)
> PEC (128 mg/kg)
> TEC (35.8 mg/kg)
-------
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Legend
A Area A (east side)
O Area A (west side)
Ponar sample results are shown
on the map.
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon mercury results.
Mercury
Concentrations
I
:
>3x PEC (3.18 mg/kg)
>2x PEC (2.12 mg/kg)
> PEC (1.06 mg/kg)
> TEC (0.18 mg/kg)
< TEC
©
0 250 500 750 1,000
Feet
Map Created: 7/22/2014
Basemap: ESRI 2012
FIGURE 3-9A
Mercury Concentrations (mg/kg)
Detected in Area A
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
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A Area B (east side)
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Poriar sample results are shown
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Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon mercury results.
Mercury
Concentrations
I
>3x PEC (3.18 mg/kg)
>2x PEC (2.12 mg/kg)
> PEC (1.06 mg/kg)
> TEC (0.18 mg/kg)
D
-------
Legend
A Area A (east side)
O Area A (west side)
Ponar sample results are shown
on the map.
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon nickel results.
Nickel
Concentrations
>3x PEC (145.8 mg/kg)
> 2x PEC (97.2 mg/kg)
> PEC (48.6 mg/kg)
> TEC (22.7 mg/kg)
~
-------
Document Path: \\Lovetonfederal\GISData\MidwesftMichigan\Ecorse\MXD\EVS\Area B\RRE_Figure3-10B_Nickel_AreaB.mxd
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A Area B (east side)
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Poriar sample results are shown
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Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon nickel results.
Nickel
Concentrations
>3x PEC (145.8 mg/kg)
> 2x PEC (97.2 mg/kg)
> PEC (48.6 mg/kg)
> TEC (22.7 mg/kg)
DVW
RR EC 13-44
~
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Document Path: \\Lovetonfederal\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Area A\RRE_Figure3-11 A_Zinc_AreaA.mxd
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A Area A (east side)
O Area A (west side)
Ponar sample results are shown
on the map.
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon zinc results.
Zinc
Concentrations
> 3x PEC (1,377 mg/kg)
>2x PEC (918 mg/kg)
> PEC (459 mg/kg)
> TEC (121 mg/kg)
< TEC
0 250 500 750 1,000
Feet
Map Created: 7/22/2014
Basemap: ESRI 2012
WESjTi
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FIGURE 3-11A
Zinc Concentrations (mg/kg)
Detected in Area A
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
-------
Document Path: \\Lovetonfederal\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Area B\RRE_Figure3-11 B_Zinc_AreaB.mxd
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Legend
A Area B (east side)
O Area B (west side)
Poriar sample results are shown
on the map,
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon zinc results.
Zinc
Concentrations
I
> 3x PEC (1,377 mg/kg)
>2x PEC (918 mg/kg)
> PEC (459 mg/kg)
> TEC (121 mg/kg)
D
-------
RREC13-46
RREC13-50
RREC13-03
RREC13-05
RREC13-06
RREC13-13
RREC13-47
RREC13-19
RREC13-21
RREC13-44
RREC13-26
RREC13-34
RREC13-35
RREC13-37
RREC13-36
RREC13-01
I RREC13-02]
| RREC13-41
RREC13-31
I RREC13-33I
| RREC13-17 |
| RREC13-16~|
RREC13-18 |
I RREC13-20 |
RREC13-07
RREC13-09 |
RREC13-11
I RREC13-14|
I RREC13-49I
| RREC13-48 |
RREC13-15 |
| RREC13-45 I
RREC13-42 |
RREC13-22 |
- RREC13-231
¦ RREC13-24
— RREC13-25
RREC13-27
RREC13-:
13-28 I
RREC13-29
RREC13-30
RREC13-32
| RREC13-38
I RREC13-40
RREC 3-39
VICINITY MAP
Toledo
Leamington
O
Project Area
Legend
TPH Concentrations*
< 100 mg/kg
m
< 1,000 mg/kg
<•>
< 5,000 mg/kg
< 10,000 mg/kg
<•>
> 10,000 mg/kg
River Rouge/Ecorse Shoreline Area
Detroit River Area of Concern
"Total Petroleum Hydrocarbons (TPH) were analyzed,
in the surface interval (0-0.5 ft) only.
TPH analysis range - C10 through C36
Sample Date: October and November 2013
mg/kg = milligrams per kilogram
ft = foot/feet
©
0 1,500 3,000
1 I I
Feet
Data Sources: EPA 2013, USGS 2013
Aerial Source: ESRI ArcGIS Online
Map Date: July 2014
FIGURE 3-12
Total Petroleum Hydrocarbons
River Rouge/Ecorse Shoreline Assessment
of Contaminated Sediments
-------
Document Path: L:\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Area A\RRE_Figure4-1 A_ESBTU_AreaA.mxd
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VICINITY MAP
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Legend
A Area A (east side)
O Area A (west side)
Ponar sample results are shown
on the map.
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon ESBTU results.
ESBTU
> 10
7.5-10
1 -7.5
< 1
:
©
0 250 500 750 1,000
Feet
Map Created: 8/6/2014
Basemap: ESRI 2012
&
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FIGURE 4-1A
Equilibrium Sediment Benchmark
Toxic Units for Polycyclic Aromatic
Hydrocarbons in Area A
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
-------
Document Path: L:\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Area A\RRE_Figure4-1 B_ESBTU_AreaB.mxd
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Legend
A Area B (east side)
O Area B (west side)
Ponar sample results are shown
on the map.
Vibracore sample results are
shown on the graphs.
Locations are color coded based
upon ESBTU results.
ESBTU
> 10
7.5-10
:
1 -7.5
< 1
©
400 800 1.200 1,600
Feet
Map Created: 8/7/2014
Basernap: ESRI2012
550
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Equilibrium Sediment Benchmark
Toxic Units for Polycyclic Aromatic
Hydrocarbons in Area B
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
RREC13-44
RREC13-18
RREC13-21
RR EC 13-48
RR EC 13-47 RR EC 13-45
ARREC13-42
RREC13-20 RREC13-23 RREC13-24
RREC13-">? RREC13-25
RREC13-27
RR EC 13-28
RR EC 13-29
RREC13-30
RR EC 13-32
RREC13-39
RREC13-31
RREC13-38
RREC13-41
RREC13-33
RREC13-34
RREC1
RR EC 13-37
RREC13-40
RR EC 13-36
RR EC 13-26
-------
Document Path: \\Lovetonfederal\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Krigs\RRE_Figure 5-1A Spatial Analysis for All Const in Area A.mxd
VICINITY MAP
Legend
O Sample Locations-Area A
All Constituents
> 3x PEC
> 2x PEC
> PEC
©
0 250 500 750 1,000
Feet
Map Created: 7/22/2014
Basemap: ESRI 2012
FIGURE 5-1A
Spatial Analysis for All Constituents
in Area A
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
RR EC 13-50
RR EC 13-03
RREC1
RREC13-0'
RREC13-09 RREC13-10
RREC13-46
RREC13-11
RREC13-14
RREC13-13
RREC13-48 O
RREC13-47
RREC13-42
RREC13-45
RREC13-23
RREC13-19
RREC13-44
RREC13-17 O
Hotspot 1
794,000 cu yd
Hotspot 2
56,000 cu yd
— _ - _ - i_.
RR EC 13-43
O
-------
Document Path: \\Lovetonfederal\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Krigs\RRE_Figure 5-1B Spatial Analysis for All Const in Area B.mxd
VICINITY MAP
Legend
A Sample Locations-Area B
All Constituents
L
> 3x PEC
> 2x PEC
> PEC
©
0 250 500 750 1,000
Feet
Map Created: 7/22/2014
Basemap: ESRI 2012
FIGURE 5-1B
Spatial Analysis for All Constituents
in Area B
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
RR£C13-1
RR EC 13-47
RREC13-45
RR EC 13-20
RREC13-23
RREC13-19
RR EC 13-22
J
RREC13.-44
RREC13-21
. :•
Hotspot 2
56,000 cu yd
RREC13-27
RR EC 13-2:
RREC13-30
RREC13-3!
RREC13-41
RREC13-33
RR EC 13-3'
RREC1
Hotspot 3
1,338,000 cu yd
RREC13-40
A
-------
Document Path: \\Lovetonfederal\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Krigs\RRE_Figure 5-2 Hotspot l.mxd
RREC13-50
Analyte
Result
Cadmium
14 . 2
Chromium
112
Copper
237
Iron
100000
Lead
259
Mercury
1. 4
Nickel
51.6
Zinc
1420
PAHs
270000
RREC13-02
Analyte
Result
Cadmium
5 . 9
Chromium
135
Copper
172
Iron
102000
Lead
305
Nickel
71.7
Zinc
1140
PAHs
184210
PCBs
3360
RREC13-06
Analyte Result
Chromium
637
Iron
76600
Lead
228
Nickel
60.5
Zinc
863
PAHs
36070
PCBs
2300
RREC13-01
Analyte Result
Cadmium
Copper
Lead
Mercury
Zinc
PAHs
RREC13-
05
Analyte
Result
Iron
135000
Lead
362
Nickel
53 . 7
Zinc
1540
PAHs
70980
PCBs
1580
RREC13-09
Analyte
Result
Cadmium
10.2
Chromium
254
Copper
202
Iron
235000
Lead
831
Nickel
139
Zinc
1570
PAHs
93350
PCBs
4250
RREC13-11
Analyte Result
r
mfmm
J
key *4—
\ i '
9 ^
I '
RREC13-08
No Recovery
RREC13-03
Analyte
Result
Cadmium
21.2
Chromium
124
Copper
225
Iron
58800
Lead
222
Mercury
1. 4
Nickel
61.1
Zinc
792
PAHs
162400
ICadmium
IChromium
I Copper
I Iron
Lead
Nickel
Zinc
PAHs
7 . 6
157
180
2 63 000|
577
91. 6
3630
26470
J' ^'/t
m -Mm
7 ju 1
JRREC13-04
INo Recovery
IJ
~
REEC13-07
Analyte Result
Chromium
Iron
Sediment Benchmarks for Contaminants
Analyte
Unit
PEC
PEC x2
PEC x3
Arsenic
mg/kg
33
66
99
Cadmium
mg/kg
4.98
9.96
14.94
Chromium
mg/kg
111
222
333
Copper
mg/kg
149
298
447
Iron
mg/kg
40000
80000
120000
Lead
mg/kg
128
256
384
Me rcu ry
mg/kg
1.06
2.12
3.18
1 Nickel
mg/kg
48.6
97.2
145.8
Zinc
mg/kg
459
918
1377
Total PAHs ND=l/2 RL
M-g/lT.
/
RREC13-13
Analyte
Result
Cadmium
31
Chromium
272
Copper
271
Iron
409000
Lead
1490
Mercury
1. 9
Nickel
178
Zinc
11800
PAHs
210200
PCBs
2490
v JB
RREC13-14
Analyte
Result
Cadmium
9.2
Chromium
282
Copper
256
Iron
181000
Lead
403
Mercury
1 .1
Nickel
217
Zinc
1460
PAHs
53680
PCBs
11200
RREC13-49
Analyte Result
Cadmium
Chromium
Copper
Iron
Lead
Mercury
Nickel
Zinc
PAHs
PCBs
9.6
287
203
113000
367
1.3
194
1380
50930
10200
RREC13-12
No Recovery|
RREC13-47
Analyte
Result
Cadmium
10.4
Chromium
300
Copper
221
Iron
1230001
Lead
447 i
Mercury
1.2 ,
Nickel
182
Zinc
1270
PAHs
36680 1
PCBs
11500 I
>.
0
RREC13-15
Analyte
Result
Cadmium
9 . 1
Chromium
2 67
Copper
177
Iron
76300
Lead
360
Nickel
123
Zinc
1260
PAHs
44685
PCBs
4320
KREC13-45
Analyte
Result
Cadmium
5
Chromium
136
Iron
44900
Lead
209
Nickel
67 . 7
Zinc
669
PAHs
32310
PCBs
850
O
o
o
RREC13-48
Analyte
Result
Cadmium
O
Cn
Chromium
304
Copper
197
Iron
100000
Lead
402
Mercury
1.2
Nickel
220
Zinc
1270
PAHs
35670
PCBs
7230
n
o
A
o
u/7jgVm^/
r / i
VICINITY MAP
Legend
O Sample Locations-Area A
All Constituents
> 3x PEC
> 2x PEC
> PEC
0 250 500 750 1,000
Feet
Map Created: 7/22/2014
Basemap: ESRI 2012
FIGURE 5-2
Hotspot 1
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
-------
Document Path: \\Lovetonfederal\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Krigs\RRE_Figure 5-3 Hotspot 2.mxd
VICINITY MAP
Legend
O Sample Locations-Area A
All Constituents
I
> 3x PEC
> 2x PEC
> PEC
©
0 50 100 150 200
Feet
Map Created: 7/22/2014
Basemap: ESRI 2012
FIGURE 5-3
Hotspot 2
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
Sediment Benchmarks for Contaminants
2028
| Analyte
|Arsenic
|Cadmium
Chromium
|Copper
| Me rcu ry
Nickel
Total PAHs ND=l/2 RL
Total PCBs ND=0
mg/kg
mg/kg
mg/kg
1377
68400
PEC x2
PEC x3
mg/kg
mg/kg
mg/kg
mg/kg
14.94
12000
mg/kg
4000
8000
145.8
22800
45600
mg/kg
'Jz- *
^ »-
RREC13-17
Analyte
Resu 11
Cadm i um
14.2
Chrom i um
253
Copper
247
I ron
104000
Lead
475
Mercury
1.1
Ni eke I
109 1
Z i nc
997
PAHs
83310
PCBs
4750
RREC13-16
Analyte
ResuIt
Cadmium
6 :
Chrom i um
166
I ron
52300
Lead
282 1
N i eke I
75
Z i nc
716
PAHs
226840
PCBs
2080
RREC13-19
Analyte Resultl
I Arseri i c
I ron
INi eke I
PCBs
35
54800
52
2650
RREC13-18
Analyte Result!
Cadm i um
Chrom i um
I ron
Lead
N i eke I
Z i nc
PAHs
PCBs
8.2
118
64700
227
54.2
494
34930
1650
-------
Document Path: \\Lovetonfederal\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Krigs\RRE_Figure 5-4 Hotspot3.mxd
VICINITY MAP
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• ¦" 'mZ
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I
Legend
O Sample Locations-Area A
A Sample Locations-Area B
All Constituents
> 3x PEC
> 2x PEC
> PEC
©
0 250 500 7501,000
Feet
Map Created: 7/22/2014
Basemap: ESRI 2012
FIGURE 5-4
Hotspot 3
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
iUVL! • I J"AJ
RREC13-31
Ana Iyte Resu11
Mb 28;79S
RREC13-35
Ana Iyte Resu 11
RREC13-22
Ana Iyte
ResuIt
Cadm i um
18.4
Chromi um
843
Copper
414
I ron
131000
Lead
492
Mercury
1 .7
Nickel
343
Z i nc
1140
PAHs
30250
PCBs
22400
Ana Iyte Resu 11
Cadm i um 21
Chromium 646
Copper 309
Iron 709C
Lead 394
Mercury 1 .3
Ni eke I 388
Zinc 117C
PAHs 5584
PCBs 868C
RREC13-24
Ana Iyte Resu11
I ron
PAHs
44500
42420
RREC13-25
Ana Iyte
ResuIt
Cadm i um
24. 9
Chrom i um
994
Copper
432
I ron
103000
Lead
397
Mercury
1 .3
Nickel
306
Z i nc
1220
PAHs
60060
PCBs
20100
RREC13-21
Ana Iyte
ResuIt
Arsen i c
54.9
Cadm i um
11.8
Chromi um
439
Copper
612
I ron
301000
Lead
519
Nickel
289
Z i nc
1340
PAHs
43190
PCBs
10700
RREC13-26
Ana Iyte
ResuIt
Cadm i um
10
Chromi um
326
Copper
291
I ron
195000
Lead
359
Nickel
202
Z i nc
1080
PAHs
49880
PCBs
25700
RREC13-27
Ana Iyte
ResuIt
Cadm i um
11 .6
Chromi um
389
Copper
328
I ron
167000
Lead
374
Mercury
1 . 7
N i eke I
190
Z i nc
1190
PAHs
69330
PCBs
6230
Sediment Benchmarks for Contaminants
Analyte
Unit
PEC
PEC x2
PEC x3
Arsenic
mg/kg
33
66
99
Cadmium
mg/kg
4.98
9.96
14.94
Chromium
mg/kg
111
222
333
Copper
mg/kg
149
298
447
Iron
mg/kg
40000
80000
120000
Lead
mg/kg
128
256
384
Me rcu ry
mg/kg
1.06
2.12
3.18
Nickel
mg/kg
48.6
97,2
145.8
Zinc
mg/kg
459
918
1377
Total PAHs ND=l/2 RL
Mg/kg
22800
45600
68400
Total PCBs ND=0
Mg/kg
676
1352
2028
RREC13-28
Ana Iyte
Resu 11
Cadm i um
19.8
Chrom i um
331 |
Copper
365
I ron
163000
Lead
265 |
Mercury
1.1
N i eke I
198
Z i nc
931
PAHs
54100
PCBs
13400
RREC13-44
Ana Iyte
ResuIt
Arsen ic
51 .1
Cadm i um
11.4
Chrom i um
431
Copper
663
I ron
358000
Lead
472
Nickel
287
Z i nc
797
PAHs
23150
PCBs
8000
RREC13-41
Ana 1yte
Resu 11
Cadm i um
28.3 '
Chrom i um
192 '
Copper
798
1 ron
88600 |
Lead
450
Mercury
3.3 1
Ni eke 1
107
Z i nc
1340
PAHs
213600
PCBs
870
RREC13-30
Ana Iyte
Resu 11
Cadm i um
27
Chromium
830
Copper
374
I ron
136000
lead
576
Mercury
2
Ni eke I
337
Z i nc
1440
PAHs
81600
PCBs
26200
RREC13-29
Ana Iyte
Resu 11
Cadm i um
21 . 3
Chrom i um
343
Copper
386
I ron
173000
Lead
345
N i eke I
198
Z i nc
932
PAHs
137000
PCBs
9480
RREC13-32
Ana Iyte
ResuIt
Chromi um
160
I ron
86700
Lead
168
Nickel
109
Z i nc
724
PAHs
63820
PCBs
5340
RREC13-39
Ana Iyte
Resu 11
I ron
54100
Lead
147
N i eke I
83. 5
Z i nc
571
PAHs
121240
PCBs
5350
IRREC13-33
Ana Iyte
Resu 11
Cadm i um
15.4
Chrom i um
485
Copper
293
I ron
56200
j Lead
357
Mercury
1.5
INi eke I
239
Z i nc
1090
! PAHs
135460
PCBs
9200
RREC13-37
Ana Iyte Resu11
PAHs 73870
RREC13-34
Ana Iyte
ResuIt
I Cadm i um
19.4
Chromium
810
Copper
360
I I ron
89800
j Lead
497
Mercury
2.1
Nickel
314
Z i nc
1680
PAHs
99900
PCBs
11400
RREC13-36
Ana Iyte
ResuIt
Cadm i um
7.8
Chrom i um
287
Copper
169
I ron
52100
Lead
383
Mercury
1 ,1
N i eke I
106
Z i nc
698
PAHs
71191
PCBs
8250
_Copper
Lead
Mercury
PAHs
161
196
1 .3
87340
-------
Document Path: \\Lovetonfederal\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Krigs\RRE_Figure 5-5A Spatial Analysis for ESBTUs in Area A.mxd
VICINITY MAP
<' v m,T
- Jr - ¦ ' . is - •'> lyL. *\f.
ft* vjSBE? w tifpT
H/.V 1
¦^«m|
,,vv:- ?¦;&& -m Mmgju
f^gJ^kgnKS)
I
• #- p
i v^< S* vgjJJwj
M-V _ hi
.yl^T-r
ImmmEs
Legend
O Sample Locations-Area A
PAH ESBTUs
0
~
> 10
7.5-10
1 -7.5
©
0 250 500 750 1,000
Feet
Map Created: 7/22/2014
Basemap: ESRI 2012
FIGURE 5-5A
Spatial Analysis for PAH ESBTUs in
Area A
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
RREC13-06
RREC13-02
Ratio (5-7 ft): 4.11
RREC13-07
RREC13-46
Ratio (0-1 ft): 3.61
RREC13-14
Ratio (7-10 ft): 1.44
RREC13-42
RREC13-49
Ratio (3-5 ft): 1.61
RREC13-45
RREC13-23
RREC13-47
Ratio (9-11 ft): 1.22
RREC13-19
RR EC 13-44
RREC13-21
RREC13-18
Ratio (1-3 ft): 1.67
RREC13-01
Ratio (3-5 ft): 7.95
RREC13-50
Ratio (0-1 ft): 6.06
RREC13-03
Ratio (3-5 ft): 4.07
RREC13-04
No Recovery
RREC13-09
Ratio (0-1 ft): 3.40
RREC13-05
Ratio (0-1 ft): 2.35
RREC13-10
No Recovery
RREC13-08
No Recovery
RREC13-17
Ratio (9-11 ft): 2.94
RREC13-11
Ratio (0-0.5 ft): 2.13
RREC13-13
Ratio (5-7 ft): 6.94
RREC13-48
Ratio (3-5 ft): 1.41
RREC13-15
Ratio (0-1 ft): 1.44
RREC13-16
Ratio (0-0.5 ft): 6.351
RREC13-12
No Recovery
-------
Document Path: L:\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Krigs\RRE_Figure5-5B Spatial Analysis for ESBTUs in Area B.mxd
VICINITY MAP
Legend
& Sample Locations-Area B
PAH ESBTUs
> 10
7.5-10
1 -7,5
O
0 250 500 750 1,000
Feet
Map Created: 8/1/2014
Basermap: ESRI 2012
FIGURE 5-5B
Spatial Analysis for PAH ESBTUs in
Area B
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
RREC13-47
RREC13-45
RREC13-42
RREC13-20
RREC13-19
RREC13-22
Ratio (9-11 ft): 1.61
RREci3-ira.
RREC13-44
Ratio (5-7 ft): 1.25
RREC13-21
Ratio (3-5 ft): 1.53
RREC13-27
Ratio (3-5 ft): 2.90
RREC13-28
Ratio (1-3 ft): 3.16
RREC13-29
Ratio (9-11 ft): 3.44
RREC13-30
Ratio (5-7 ft): 2.37
RREC13-31
RREC13-41
Ratio (9-11 ft): 6.64
RREC13-33
Ratio (3-5 ft): 6.48
RREC13-34
Ratio (9-11 ft): 3.09
RREC13-38
Ratio (0-1 ft): 1.05
RREC13-37
Ratio (0-1 ft): 2.83
RREC13-32
Ratio (0-1 ft): 1.52
RREC13-23
Ratio (3-5 ft): 8.22
RREC13-25
Ratio (5-7 ft): 1.83
RREC13-24
Ratio (0-0.5 ft): 3.16
RREC13-35
Ratio (1-3 ft): 4.56
RREC13-36
Ratio (1-3 ft): 1.14
RREC13-39
Ratio (0-1 ft): 3.151
RREC13-26
Ratio (1-3 ft): 1.57
-------
Document Path: L:\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Krigs\RRE_Figure5-6A Spatial Analysis for ESBTUs Metals in Area A.mxd
VICINITY MAP
Sample Locations- Area
Value Not Calculated (due to
insufficient AVS value)
A Value Was Negative
A No Recovery
Ml < 130 pmol/goc
A 130 - 3,000 (jmol/goc
Organic Carbon Normalized
Metals in (jmol/goc
> 3,000
130-3,000
< 130
NOTE: All sample depths are 0-0.5 ft
©
0 250 500 750 1,000
Feet
Map Created: 8/7/2014
Basemap: ESRI 2012
FIGURE 5-6A
Spatial Analysis for Organic Carbon
Normalized Metals in Area A
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
K * ¦ '
HI ^
RREC13-01
24 |jmol/goc
RREC13-03
63 jjmol/goc
RREC13-43
RREC13-07
16 (jmol/goc
RREC13-05
22 jjmol/goc
R REG 13-04
~ - 1
RREC13-02
22 |jmol/goc
RR EC 13-06
RR EC 13-08
RR EC 13-46
RREC13-10
RR EC 13-11
*fb^. A
RREC13-15
167 jjmol/g0(
RREC13-09
112 (jmol/goc
RREC13-42
53 jjmol/goc
RREC13-14
203 |jmol/g0(
RREC13-49
78 |jmol/goc
RREC13-45
RREC13-47
92 Limol/goc
EC 13-23
RREC13-19
RREC1
REC13-16
RREC13-44
13 |jmol/goc
RREC13-22
17 jjmol/goc
^ . '/I
RREC13-50
88 |jmol/goc
RREC13-13
955 fjrmol/goc
-------
Document Path: \\lovetonfederal\GISData\Midwest\Michigan\Ecorse\MXD\EVS\Krigs\RRE_Figure5-6B Spatial Analysis for ESBTUs Metals in Area B.mxd
VICINITY MAP
Sample Locations- Area B
A Value Was Negative
& No Recovery
A < 130 [jmol/goc
A 130 - 3,000 |jmol/goc
Organic Carbon Normalized
Metals in pmol/goc
> 3,000
130-3,000
< 130
NOTE: All sample depths are 0-0.5 ft
o
0 250 500 750 1,000
Feet
Map Created: 8/7/2014
Basermap: ESRI 2012
FIGURE 5-6B
Spatial Analysis for Organic Carbon
Normalized Metals in Area B
River Rouge/Ecorse Shoreline
Assessment of Contaminated Sediments
RREC13-19
RREC13-22
17 |jmol/goc
RREC13-25
143 |jmo!/goc
REC13-1
RREC13-44
13 |jmol/goc
RREC13-26
66 (jmol/goc
RREC13-27
188 |jmol/goc
RREC13-28
7 |jmol/goc
RREC13-29
22 Mmo!/goc
RREC13-30
79 iJmol/goc
RREC13-39
48 |jmol/goc
RREC13-38
9 |jnnol/goc
RR EC 13-40
RREC13-15
167 |jmol/g0
RREC13-47
92 pmol/goc
RREC13-45
)RREC13-42|
153 |jmol/g0
R EC 13-23
RR EC 13-24
A
'—V
RREC13-411
56 |jmol/g0
RREC13-32
RREC13-31
RREC13-33
A
a
RREC13-34
87 |jmol/goc
£L
-
s RR EC 13-35
VjJ 1 'ft
-------
Tables
-------
EA Science and Technology and Its Affiliate
EA Engineering, Science, and Technology, (Ml) PLC
TABLE 2-1. RIVER ROUGE/ECORSE SHORELINE SITE CHARACTERIZATION COORDINATES
DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN ( NOVEMBER 2013)
Location ID
Date
Collected
Time
Collected
Latitude
Longitude
Distance from
Target
Coordinate (ft)
NOTES
RREC13-01
10/30/13
9:54
42° 16.4079
-83° 06.6083
51.40
Location moved slightly offshore by EPA (R. Ellison)
RREC13-02
10/30/13
10:31
42° 16.3670
-83° 06.6333
9.68
Did not encounter refusal
RREC13-03
11/5/13
10:48
42° 16.3229
-83° 06.6321
64.68
Location moved slightly offshore by EPA (R. Ellison) due to rocks near
proposed location; did not encounter refusal
RREC13-04
11/5/13
--
--
--
--
Location abandoned by EPA (R. Ellison) after failed attempts at recovery
with vibracore and ponar
RREC13-05
11/5/13
10:13
42° 16.1596
-83° 06.7085
39.65
Location moved slightly offshore by EPA (R. Ellison)
RREC13-06
11/5/13
9:36
42° 16.1026
-83° 06.7361
42.78
Location moved slightly offshore by EPA (R. Ellison) due to rocks near
proposed location
RREC13-07
11/5/13
8:56
42° 16.0176
-83° 06.7739
42.18
Location moved slightly by EPA (R. Ellison) due to strong current
RREC13-08
-
-
-
-
Location abandoned by EPA (R. Ellison)
RREC13-09
11/4/13
16:11
42° 15.9326
-83° 06.8201
21.12
Location moved slightly by EPA (R. Ellison)
RREC13-10
-
-
-
-
Location abandoned by EPA (R. Ellison)
RREC13-11
11/4/13
15:25
42° 15.8280
-83° 06.8943
95.97
Location moved slightly by EPA (R. Ellison) due to rocks near proposed
location. Vibracore attempts unsuccessful — ponar collected only
RREC13-12
-
-
-
-
Location abandoned by EPA (R. Ellison)
RREC13-13
11/4/13
14:47
42° 15.7470
-83° 06.9614
72.67
Location moved slightly by EPA (R. Ellison); no refusal
RREC13-14
11/4/13
14:07
42° 15.6877
-83° 06.9863
18.95
Location moved inshore by EPA (R. Ellison) away from channel; no refusal
RREC13-15
11/4/13
13:29
42° 15.5124
-83° 07.0950
32.24
Location moved because a ship was docking in the area of the proposed
location
RREC13-16
10/29/13
8:39
42° 15.6176
-83° 07.5062
3.56
RREC13-17
10/29/13
15:21
42° 15.5956
-83° 07.3997
7.54
Returned to location to collect core with double catcher. No refusal.
RREC13-18
10/29/13
10:17
42° 15.5613
-83° 07.3893
8.42
No refusal
RREC13-19
10/29/13
11:04
42° 15.5331
-83° 07.2826
12.68
RREC13-20
10/29/13
13:29
42° 15.4866
-83° 07.2205
22.53
Lost approximately 16 inches out of bottom of core on retrieval
RREC13-21
10/29/13
16:05
42° 15.4348
-83° 07.4484
34.71
No refusal
RREC13-22
10/29/13
16:38
42° 15.3818
-83° 07.3237
132.81
Location moved because a barge was tied off at proposed location; no refusal
RREC13-23
10/30/13
9:02
42° 15.3300
-83° 07.2630
26.01
No refusal
RREC13-24
11/4/13
9:56
42° 15.1944
-83° 07.3252
96.41
Location moved slightly by EPA (R. Ellison)
RREC13-25
11/4/13
9:04
42° 15.1300
-83° 07.3973
47.41
Location moved slightly by EPA (R. Ellison); no refusal
RREC13-26
11/4/13
8:11
42° 14.9291
-83° 07.6209
106.19
Location moved inshore by EPA (R. Ellison) away from channel; no refusal
RREC13-27
11/4/13
7:34
42° 14.8520
-83° 07.7260
109.48
Location moved inshore by EPA (R. Ellison) away from channel; no refusal
RREC13-28
11/1/13
17:40
42° 14.7693
-83° 07.8486
148.40
Location approximately 75 feet downstream of outfall; no refusal
RREC13-29
11/1/13
17:00
42° 14.6218
-83° 08.0718
169.81
Location moved closer to shore by EPA (R. Ellison); no refusal
RREC13-30
11/1/13
16:15
42° 14.5253
-83° 08.2418
35.83
No refusal
RREC13-31
10/30/13
15:40
42° 14.4205
-83° 08.4118
13.46
No refusal
RREC13-32
10/30/13
14:55
42° 14.3860
-83° 08.3116
9.69
RREC13-33
10/30/13
16:45
42° 14.4929
-83° 08.5782
32.27
Location moved slightly by EPA (R. Ellison) due to pilings at proposed
location; no refusal
RREC13-34
11/1/13
15:40
42° 14.4403
-83° 08.6289
4.25
RREC13-35
10/30/13
17:25
42° 14.3934
-83° 08.6793
62.15
Location moved slightly by EPA (R. Ellison). No refusal
RREC13-36
10/28/13
15:33
42° 14.0963
-83° 08.8892
15.41
RREC13-37
10/28/13
16:39
42° 14.2855
-83° 08.5958
8.48
No refusal
RREC13-38
10/30/13
13:40
42° 14.2395
-83° 08.5045
36.70
No refusal
RREC13-39
10/30/13
14:20
42° 14.2497
-83° 08.3972
130.90
Location moved by EPA (R. Ellison) due to steep slope at proposed location;
no refusal
RREC13-40
10/28/13
16:04
42° 14.1417
-83° 08.6605
7.53
RREC12-41
10/30/13
16:13
42° 14.5261
-83° 08.4540
23.12
Location moved slightly way from shore by EPA (R. Ellison); no refusal
RREC13-42
11/4/13
10:46
42° 15.3669
-83° 07.1948
148.35
Location moved slightly by EPA (R. Ellison)
RREC13-43
11/5/13
-
-
-
0.09
Location abandoned by EPA (R. Ellison) due to very strong current
RREC13-44
10/30/13
8:25
42° 15.3855
-83° 07.3724
-
Location moved slightly by EPA (R. Ellison)
RREC13-45
10/29/13
14:38
42° 15.4340
-83° 07.1805
39.20
RREC13-46
11/5/13
15:32
42° 16.5942
-83° 06.8372
179.64
Location moved inshore away from channel by EPA (R. Ellison); no refusal
RREC13-47
10/30/13
11:19
42° 15.6007
-83° 07.1160
129.61
Location moved slightly by EPA (R. Ellison); no refusal
RREC13-48
11/5/13
7:42
42° 15.5722
-83° 07.0724
16.89
No refusal
RREC13-49
11/5/13
8:19
42° 15.6119
-83° 07.0358
67.90
No refusal
RREC13-50
11/5/13
14:53
42° 16.3952
-83° 06.5955
55.42
No refusal
EA Project No. 6256115.10
Version: FINAL
August 2014
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Assessment of Contaminated Sediments
Site Characterization Report
-------
EA Science and Technology, and Its Affiliate
EA Engineering, Science, and Technology, (MI) PLC
EA Project No.: 6256115.10
Version: FINAL
August 2014
TABLE 2-2 RIVER ROUGE/ECORSE SHORELINE SITE CHARACTERIZATION ANALYTICAL
PROGRAM
DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Proposed AlluKlicul Siiinplc ( oiilll
At liiiil AnuKlicul Siiinplc Comil
. =
/ I
1
-
^ 2 7
mold)
-
5 ¦= '
Suniph- Loculion Suinplc II)
£•
/
7 —
Tolul 1 *<' 1 is
341'AI Is. M
nieluls. Iron
TOC
/
£•
/ -V
7 —
Tolul l'(' lis
341'Alls. M
nu-luls. 1 rou
IOC
/
..
.
.
RREC 13-02
1
1
5
5
1
1
7
7
RREC13-03
1
1
5
5
1
1
5
5
RREC 13-04
1
1
5
5
0
0
RREC 13-05
1
1
5
5
1
1
3
3
RREC 13-06
1
1
5
5
1
1
3
3
RREC 13-07
1
1
5
5
1
1
1
1
RREC 13-08
1
1
5
5
0
0
RREC 13-09
1
1
5
5
1
1
4
4
RREC13-10
1
1
5
5
0
0
RREC 13-11
1
1
5
5
1
1
1
1
RREC13-12
1
1
5
5
0
0
RREC13-13
1
1
5
5
1
1
5
5
RREC 13-14
1
1
5
5
1
1
6
6
RREC13-15
1
1
5
5
1
1
3
3
RREC13-16
1
1
5
5
1
1
7
7
RREC13-17
1
1
5
5
1
1
7
7
RREC13-18
1
1
5
5
1
1
7
7
RREC13-19
1
1
5
5
1
1
2
2
RREC 13-20
1
1
5
5
1
1
4
4
RREC13-21
1
1
5
5
1
1
7
7
RREC 13-22
1
1
5
5
1
1
7
7
RREC 13-23
1
1
5
5
1
1
7
7
RREC 13-24
1
1
5
5
1
1
3
3
RREC 13-25
1
1
5
5
1
1
6
6
RREC 13-26
1
1
5
5
1
1
5
5
RREC 13-27
1
1
5
5
1
1
6
6
RREC 13-28
1
1
5
5
1
1
7
7
RREC 13-29
1
1
5
5
1
1
7
7
RREC13-30
1
1
5
5
1
1
5
5
RREC 13-31
1
1
5
5
1
1
5
5
RREC 13-32
1
1
5
5
1
1
4
4
RREC 13-33
1
1
5
5
1
1
7
7
RREC 13-34
1
1
5
5
1
1
7
7
RREC 13-35
1
1
5
5
1
1
4
4
RREC 13-36
1
1
5
5
1
1
3
3
RREC 13-37
1
1
5
5
1
1
7
7
RREC 13-38
1
1
5
5
1
1
5
5
RREC 13-39
1
1
5
5
1
1
7
7
RREC1340
1
1
5
5
1
1
5
5
RREC 13-41
1
1
5
5
1
1
7
7
RREC1342
1
1
5
5
1
1
4
4
RREC 13-43
1
1
5
5
0
0
RREC 13-44
1
1
5
5
1
1
5
5
RREC 13-45
1
1
5
5
1
1
4
4
RREC1346
1
1
5
5
1
1
6
6
RREC1347
1
1
5
5
1
1
7
7
RREC1348
1
1
5
5
1
1
6
6
RREC1349
1
1
5
5
1
1
6
6
RREC 13-50
1
1
5
5
1
1
5
5
Total Sediment Samples
50
50
250
250
45
45
233
233
Field Quality Control Samples
Field Duplicates (assume 10% of
samples)
0
5
25
25
0
5
25
25
Matrix Spike/Matrix Spike Duplicate
(assume 5% of samples)
0
3
13
0
0
3
12
0
Tolul Fit'l
-------
TABLE 3-1. RIVER ROUGE/ECORSE SHORELINE SITE CHARACTERIZATION SAMPLE COLLECTION DATA
DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
Sample
Date
Sample
Time
Collected By
Water
Depth (ft)
Sediment
Surface
Elevation*
IGLD 1985 (ft)
Ponar Sample
Collected (Y/N)
Sediment Core
Field Duplicate Samples
MS/MSD Samples
Penetration
Depth (ft)
Sediment
Recovery
(in.)
Sediment
Recovery
(ft)
Percent
Recovery
Collected to
Refusal
(Y/N)
RREC13-01
10/30/13
9:54
R/V Mudpuppy II
12.3
536.4
Y
5.5
45.6
3.8
69.6
Y
RREC13-02
10/30/13
10:31
R/V Mudpuppy II
5.5
542.7
Y
10.0
114.0
9.5
95.0
N
RREC13-03
11/5/13
10:48
R/V Mudpuppy II
23.0
521.4
Y
7.5
82.8
6.9
92.0
N
RREC13-05
11/5/13
10:13
R/V Mudpuppy II
12.1
532.1
Y
RREC13-06
11/5/13
9:36
R/V Mudpuppy II
10.8
532.7
Y
RREC13-07
-
-
R/V Mudpuppy II
9.9
RRI>'13-'
11 113
R/V Mudpuppy II
6.6
RRIV13-1"
__ /
RREC13-13
11/4/13
14:47
R/V Mudpuppy II
2.1
542.0
Y
7.5
84.0
7.0
93.3
N
RRLC13-13-0305-MS/MSD
RREC13-14
11/4/13
14:07
R/V Mudpuppy II
5.4
539.1
Y
10.0
114.0
9.5
95.0
N
RREC13-14-SURF-FD
RREC13-14-0103-MS/MSD
RREC13-15
11/4/13
13:29
R/V Mudpuppy II
20.6
525.3
Y
3.5
36.0
3.0
85.7
Y
RREC13-15-0103-MS/MSD
RREC13-16
10/29/13
8:39
R/V Mudpuppy II
19.0
528.5
Y
9.0
112.8
9.4
104.4
Y
RREC13-17
10/29/13
15:21
R/V Mudpuppy II
17.4
530.1
Y
10.0
114.0
9.5
95.0
N
RREC13-18
10/29/13
10:17
R/V Mudpuppy II
21.5
527.8
Y
10.0
112.8
9.4
94.0
N
RREC13-18-0103-MS/MSD
RREC13-19
10/29/13
11:04
R/V Mudpuppy II
17.3
532.4
Y
1.5
6.0
0.5
33.3
Y
RREC13-19-SURF-MS/MSD
RREC13-20
10/29/13
13:29
R/V Mudpuppy II
24.0
525.5
Y
7.0
76.8
6.4
91.4
Y
RREC13-21
10/29/13
16:05
R/V Mudpuppy II
17.8
528.8
Y
10.0
114.0
9.5
95.0
N
RREC13-21-0001-FD; RREC13-21-
0103-FD; RREC13-21-0305-FD;
RREC13-21-0507-FD; RREC13-21-
0709-FD; RREC13-21-0911-FD
RREC13-22
10/29/13
16:38
R/V Mudpuppy II
13.6
531.9
Y
10.0
117.6
9.8
97.5
N
RREC13-23
10/30/13
9:02
R/V Mudpuppy II
13.6
535.1
Y
10.0
118.8
9.9
99.0
N
RREC13-24
11/4/13
9:56
R/V Mudpuppy II
18.6
523.1
Y
3.5
39.6
3.3
94.3
Y
RREC13-25
11/4/13
9:04
R/V Mudpuppy II
19.0
520.5
Y
10.0
117.6
9.8
97.5
N
NOTES:
* Sediment elevation calculated using NOAA buoy Station ID 9044020, located in Gibraltar, MI
Shaded cells indicate locations where no sample was collected
MS/MSD = Matrix Spike/Matrix Spike Duplicate Pa§e 1 of 2
-------
TABLE 3-1. RIVER ROUGE/ECORSE SHORELINE SITE CHARACTERIZATION SAMPLE COLLECTION DATA
DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
Sample
Date
Sample
Time
Collected By
Water
Depth (ft)
Sediment
Surface
Elevation*
IGLD 1985 (ft)
Ponar Sample
Collected (Y/N)
Sediment Core
Field Duplicate Samples
MS/MSD Samples
Penetration
Depth (ft)
Sediment
Recovery
(in.)
Sediment
Recovery
(ft)
Percent
Recovery
Collected to
Refusal
(Y/N)
RREC13-26
11/4/13
8:11
R/V Mudpuppy II
17.5
520.5
Y
7.5
87.6
7.3
96.7
N
RREC13-27
11/4/13
7:34
R/V Mudpuppy II
4.6
532.8
Y
10.0
114.0
9.5
95.0
N
RREC13-28
11/1/13
17:40
R/V Mudpuppy II
3.9
537.5
Y
10.0
112.8
9.4
94.0
N
RREC13-28-0305-MS/MSD
RREC13-29
11/1/13
17:00
R/V Mudpuppy II
4.3
535.8
Y
10.0
112.8
9.4
94.0
N
RREC13-29-SURF-MS/MSD
RREC13-30
11/1/13
16:15
R/V Mudpuppy II
11.5
528.6
Y
7.5
85.2
7.1
94.7
N
RREC13-30-0001-FD; RREC13-30-
0103-FD; RREC13-30-0305-FD;
RREC13-30-0507-FD
RREC13-31
10/30/13
15:40
R/V Mudpuppy II
3.8
543.8
Y
7.5
85.2
7.1
94.7
N
RREC13-31-0305-MS/MSD
RREC13-32
10/30/13
14:55
R/V Mudpuppy II
3.8
543.8
Y
4.3
46.8
3.9
91.8
Y
RREC13-33
10/30/13
16:45
R/V Mudpuppy II
2.8
545.1
Y
10.0
117.6
9.8
97.5
N
RREC13-34
11/1/13
15:40
R/V Mudpuppy II
6.5
533.6
Y
9.0
111.6
9.3
102.8
Y
RREC13-34-SURF-MS/MSD
RREC13-35
10/30/13
17:25
R/V Mudpuppy II
17.6
529.2
Y
5.5
55.2
4.6
83.6
N
RREC13-36
10/28/13
15:33
R/V Mudpuppy II
8.6
533.5
Y
3.0
33.6
2.8
93.3
Y
RREC13-37
10/28/13
16:39
R/V Mudpuppy II
3.1
541.3
Y
10.0
114.0
9.5
95.0
N
RREC13-38
10/30/13
13:40
R/V Mudpuppy II
2.9
545.1
Y
7.5
70.8
5.9
78.7
N
RREC13-38-SURF-FD
RREC13-39
10/30/13
14:20
R/V Mudpuppy II
3.5
544.5
Y
10.0
114.0
9.5
95.0
N
RREC13-40
10/28/13
16:04
R/V Mudpuppy II
3.5
539.2
Y
7.0
85.2
7.1
101.4
Y
RREC13-41
10/30/13
16:13
R/V Mudpuppy II
8.2
540.0
Y
10.0
114.0
9.5
95.0
N
RREC13-41-0103-FD; RREC13-41-
0305-FD; RREC13-41-0507-FD;
RREC13-41-0709-FD; RREC13-41-
0911-FD
RREC13-42
11/4/13
10:46
R/V Mudpuppy II
31.6
536.4
Y
4.5
49.2
4.1
91.1
Y
RREC13-43 ••
RREC13-44
10/30/13
8:25
R/V Mudpuppy II
13.3
543.5
Y
7.5
87.6
7.3
96.7
Y
RREC13-45
10/29/13
14:38
R/V Mudpuppy II
30.58
538.2
Y
5.5
63.6
5.3
95.5
Y
RREC13-45-0001-MS/MSD
RREC13-46
11/5/13
15:32
R/V Mudpuppy II
13.2
537.9
Y
10.0
102.0
8.5
85.0
N
RREC13-47
10/30/13
11:19
R/V Mudpuppy II
17.25
546.3
Y
10.0
117.6
9.8
98.0
N
RREC13-47-SURF-FD; RREC13-47-
0103-FD; RREC13-47-0305-FD
RREC13-47-0709-MS/MSD
RREC13-48
11/5/2013
7:42
R/V Mudpuppy II
11.8
532.9
Y
10.0
114.0
9.5
95.0
N
RREC13-48-SURF-FD
RREC13-49
11/5/2013
8:19
R/V Mudpuppy II
9.5
535.2
Y
10.0
117.6
9.8
98.0
N
RREC13-49-SURF-FD
RREC13-50
11/5/2013
14:53
R/V Mudpuppy II
29.4
520.9
Y
7.5
74.4
6.2
82.7
N
NOTES:
* Sediment elevation calculated using NOAA buoy Station ID 9044020, located in Gibraltar, MI
Shaded cells indicate locations where no sample was collected
MS/MSD = Matrix Spike/Matrix Spike Duplicate Pa§e 2 of 2
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-01
RREC 13-02
RREC 13-03
Sample Name:
RREC13-01 -SURF
RREC13-02-SURF
RREC 13-03-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
Date Sampled:
10/30/13
10/30/13
11/5/13
Analyte
Units
Gravel
0/
/o
12.4
1.5
0.8
Sand
0/
/o
41.4
79.3
52.8
Coarse Sand
0/
/o
10.7
1
0.6
Medium Sand
0/
/o
8.2
7.9
4.2
Fine Sand
0/
/o
22.5
70.4
48
Silt
0/
/o
27.9
14.3
35
Clay
0/
/o
18.3
4.9
11.4
Silt + Clay
0/
/o
46.2
19.2
46.4
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
96.9
100
100
Sieve Size #4 - Percent Finer
% passed
87.6
98.5
99.2
Sieve Size #10 - Percent Finer
% passed
76.9
97.5
98.6
Sieve Size #20 - Percent Finer
% passed
71.5
95.8
97.5
Sieve Size #40 - Percent Finer
% passed
68.7
89.6
94.4
Sieve Size #60 - Percent Finer
% passed
59.4
76.7
86.9
Sieve Size #80 - Percent Finer
% passed
55
64
77.9
Sieve Size #100 - Percent Finer
% passed
52.4
52.3
69.5
Sieve Size #200 - Percent Finer
% passed
46.2
19.2
46.4
Hydrometer Reading 1 - Percent Finer
% passed
33.4
10.1
27.7
Hydrometer Reading 2 - Percent Finer
% passed
31.7
8.8
23.6
Hydrometer Reading 3 - Percent Finer
% passed
25
7.5
16.8
Hydrometer Reading 4 - Percent Finer
% passed
21.6
6.2
14.1
Hydrometer Reading 5 - Percent Finer
% passed
18.3
4.9
11.4
Hydrometer Reading 6 - Percent Finer
% passed
12.9
4.7
8.6
Hydrometer Reading 7 - Percent Finer
% passed
8.6
3.3
4.5
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 1 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-05
RREC13-06
RREC13-07
RREC13-05-SURF
RREC13-06-SURF
RREC13-07-SURF
0-0.5
0-0.5
0-0.5
11/5/13
11/5/13
11/5/13
Analyte
Units
Gravel
0/
/o
15.6
7.2
39.4
Sand
0/
/o
78.3
48
51.9
Coarse Sand
0/
/o
13.6
11.9
14.7
Medium Sand
0/
/o
18
18.5
13.1
Fine Sand
0/
/o
46.7
17.6
24.1
Silt
0/
/o
4.9
34.4
5.7
Clay
0/
/o
1.2
10.4
3
Silt + Clay
0/
/o
6.1
44.8
8.7
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
96.2
100
84.3
Sieve Size #4 - Percent Finer
% passed
84.4
92.8
60.6
Sieve Size #10 - Percent Finer
% passed
70.8
80.9
45.9
Sieve Size #20 - Percent Finer
% passed
61.8
72
39.2
Sieve Size #40 - Percent Finer
% passed
52.8
62.4
32.8
Sieve Size #60 - Percent Finer
% passed
39.7
56.1
24.5
Sieve Size #80 - Percent Finer
% passed
32.4
54
20.5
Sieve Size #100 - Percent Finer
% passed
26.8
52.8
18
Sieve Size #200 - Percent Finer
% passed
6.1
44.8
8.7
Hydrometer Reading 1 - Percent Finer
% passed
3.7
22.2
6.4
Hydrometer Reading 2 - Percent Finer
% passed
3.7
19.5
5.8
Hydrometer Reading 3 - Percent Finer
% passed
2.2
14.9
4.2
Hydrometer Reading 4 - Percent Finer
% passed
1.7
13.1
3.6
Hydrometer Reading 5 - Percent Finer
% passed
1.2
10.4
3
Hydrometer Reading 6 - Percent Finer
% passed
1.2
7.6
2.5
Hydrometer Reading 7 - Percent Finer
% passed
1.2
5.8
1.9
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 2 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-09
RREC13-11
RREC13-13
RREC13-09-SURF
RREC13-11-SURF
RREC13-13-SURF
0-0.5
0-0.5
0-0.5
11/4/13
11/4/13
11/4/13
Analyte
Units
Gravel
0/
/o
12.5
12
0
Sand
0/
/o
80
66.9
39.2
Coarse Sand
0/
/o
13.1
4
0
Medium Sand
0/
/o
18.1
8.9
0.9
Fine Sand
0/
/o
48.8
54
38.3
Silt
0/
/o
5.6
19
59.2
Clay
0/
/o
1.9
2.1
1.6
Silt + Clay
0/
/o
7.5
21.1
60.8
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
96.9
90.2
100
Sieve Size #4 - Percent Finer
% passed
87.5
88
100
Sieve Size #10 - Percent Finer
% passed
74.4
84
100
Sieve Size #20 - Percent Finer
% passed
66.8
80.3
99.4
Sieve Size #40 - Percent Finer
% passed
56.3
75.1
99.1
Sieve Size #60 - Percent Finer
% passed
34
67.9
97
Sieve Size #80 - Percent Finer
% passed
22.5
60.2
93.4
Sieve Size #100 - Percent Finer
% passed
16.8
51.9
89.4
Sieve Size #200 - Percent Finer
% passed
7.5
21.1
60.8
Hydrometer Reading 1 - Percent Finer
% passed
4.6
4.6
9
Hydrometer Reading 2 - Percent Finer
% passed
4.2
4
6.5
Hydrometer Reading 3 - Percent Finer
% passed
3.3
3.4
2.9
Hydrometer Reading 4 - Percent Finer
% passed
2.4
2.1
1.6
Hydrometer Reading 5 - Percent Finer
% passed
1.9
2.1
1.6
Hydrometer Reading 6 - Percent Finer
% passed
1.4
1.4
0.2
Hydrometer Reading 7 - Percent Finer
% passed
1
0.7
0.2
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 3 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-14
RREC13-15
RREC13-16
RREC13-14-SURF
RREC13-15-SURF
RREC13-16-SURF
0-0.5
0-0.5
0-0.5
11/4/13
11/4/13
10/29/13
Analyte
Units
Gravel
0/
/o
1.1
0
0
Sand
0/
/o
34.4
11.9
2.6
Coarse Sand
0/
/o
0.5
0
0.2
Medium Sand
0/
/o
1.8
1.2
0.1
Fine Sand
0/
/o
32.1
10.7
2.3
Silt
0/
/o
51.8
56.8
58.3
Clay
0/
/o
12.7
31.3
39.1
Silt + Clay
0/
/o
64.5
88.1
97.4
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
100
100
100
Sieve Size #4 - Percent Finer
% passed
98.9
100
100
Sieve Size #10 - Percent Finer
% passed
98.4
100
99.8
Sieve Size #20 - Percent Finer
% passed
97.7
99.2
99.7
Sieve Size #40 - Percent Finer
% passed
96.6
98.8
99.7
Sieve Size #60 - Percent Finer
% passed
94.5
97.8
99.4
Sieve Size #80 - Percent Finer
% passed
91.5
96.8
99.3
Sieve Size #100 - Percent Finer
% passed
88.5
95.9
99.2
Sieve Size #200 - Percent Finer
% passed
64.5
88.1
97.4
Hydrometer Reading 1 - Percent Finer
% passed
27.3
54.8
84.2
Hydrometer Reading 2 - Percent Finer
% passed
24
48.9
74.3
Hydrometer Reading 3 - Percent Finer
% passed
18.3
41.6
56
Hydrometer Reading 4 - Percent Finer
% passed
15
35.7
46
Hydrometer Reading 5 - Percent Finer
% passed
12.7
31.3
39.1
Hydrometer Reading 6 - Percent Finer
% passed
10.5
24
28.8
Hydrometer Reading 7 - Percent Finer
% passed
6
16.6
18.8
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 4 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-17
RREC13-18
RREC13-19
RREC13-17-SURF
RREC13-18-SURF
RREC13-19-SURF
0-0.5
0-0.5
0-0.5
10/29/13
10/29/13
10/29/13
Analyte
Units
Gravel
0/
/o
0
0
33
Sand
0/
/o
5.2
7.8
44.7
Coarse Sand
0/
/o
0
0.1
13.9
Medium Sand
0/
/o
0.2
0.3
12.4
Fine Sand
0/
/o
5
7.4
18.4
Silt
0/
/o
63.6
64.4
13.9
Clay
0/
/o
31.2
27.8
8.4
Silt + Clay
0/
/o
94.8
92.2
22.3
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
100
100
79
Sieve Size #4 - Percent Finer
% passed
100
100
67
Sieve Size #10 - Percent Finer
% passed
100
99.9
53.1
Sieve Size #20 - Percent Finer
% passed
99.9
99.7
46.5
Sieve Size #40 - Percent Finer
% passed
99.8
99.6
40.7
Sieve Size #60 - Percent Finer
% passed
99.2
98.6
31.7
Sieve Size #80 - Percent Finer
% passed
98.5
97.7
27.5
Sieve Size #100 - Percent Finer
% passed
97.9
96.9
25.6
Sieve Size #200 - Percent Finer
% passed
94.8
92.2
22.3
Hydrometer Reading 1 - Percent Finer
% passed
74.4
67.8
21.4
Hydrometer Reading 2 - Percent Finer
% passed
60.6
57.7
18.3
Hydrometer Reading 3 - Percent Finer
% passed
57.8
42.1
12.1
Hydrometer Reading 4 - Percent Finer
% passed
37
33.5
9.7
Hydrometer Reading 5 - Percent Finer
% passed
31.2
27.8
8.4
Hydrometer Reading 6 - Percent Finer
% passed
24
20.4
7
Hydrometer Reading 7 - Percent Finer
% passed
15.7
13.3
5.8
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 5 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-20
RREC13-21
RREC 13-22
RREC13-20-SURF
RREC13-21 -SURF
RREC 13 -22-SURF
0-0.5
0-0.5
0-0.5
10/29/13
10/29/13
10/29/13
Analyte
Units
Gravel
0/
/o
10.9
0
0
Sand
0/
/o
41
0.7
8.9
Coarse Sand
0/
/o
9.9
0
0.1
Medium Sand
0/
/o
15.7
0.1
1
Fine Sand
0/
/o
15.4
0.6
7.8
Silt
0/
/o
25.5
61.4
64.5
Clay
0/
/o
22.6
37.9
26.6
Silt + Clay
0/
/o
48.1
99.3
91.1
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
97.2
100
100
Sieve Size #4 - Percent Finer
% passed
89.1
100
100
Sieve Size #10 - Percent Finer
% passed
79.2
100
99.9
Sieve Size #20 - Percent Finer
% passed
70.5
99.9
99.5
Sieve Size #40 - Percent Finer
% passed
63.5
99.9
98.9
Sieve Size #60 - Percent Finer
% passed
56.6
99.6
97.6
Sieve Size #80 - Percent Finer
% passed
53.8
99.6
96.5
Sieve Size #100 - Percent Finer
% passed
52.3
99.6
95.5
Sieve Size #200 - Percent Finer
% passed
48.1
99.3
91.1
Hydrometer Reading 1 - Percent Finer
% passed
40.1
97.1
69.8
Hydrometer Reading 2 - Percent Finer
% passed
36
83.6
53.6
Hydrometer Reading 3 - Percent Finer
% passed
29.4
60
38.8
Hydrometer Reading 4 - Percent Finer
% passed
25.1
46.6
32
Hydrometer Reading 5 - Percent Finer
% passed
22.6
37.9
26.6
Hydrometer Reading 6 - Percent Finer
% passed
16.7
25.8
20.7
Hydrometer Reading 7 - Percent Finer
% passed
12.6
17.4
14
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 6 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-23
RREC13-24
RREC 13-25
Sample Name:
RREC13-23-SURF
RREC13 -24-SURF
RREC 13-25-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
Date Sampled:
10/30/13
11/4/13
11/4/13
Analyte
Units
Gravel
0/
/o
0
28.1
4.9
Sand
0/
/o
12.5
61.3
89
Coarse Sand
0/
/o
0.3
16.3
1.3
Medium Sand
0/
/o
0.9
10.9
5.3
Fine Sand
0/
/o
11.3
34.1
82.4
Silt
0/
/o
60.6
6.8
4.8
Clay
0/
/o
26.9
3.8
1.3
Silt + Clay
0/
/o
87.5
10.6
6.1
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
91.8
100
Sieve Size 0.375 inch - Percent Finer
% passed
100
85.9
98.4
Sieve Size #4 - Percent Finer
% passed
100
71.9
95.1
Sieve Size #10 - Percent Finer
% passed
99.7
55.6
93.8
Sieve Size #20 - Percent Finer
% passed
99.3
49.1
92.6
Sieve Size #40 - Percent Finer
% passed
98.8
44.7
88.5
Sieve Size #60 - Percent Finer
% passed
97.2
33
70
Sieve Size #80 - Percent Finer
% passed
96.3
22.6
44.7
Sieve Size #100 - Percent Finer
% passed
95.4
17.6
29.4
Sieve Size #200 - Percent Finer
% passed
87.5
10.6
6.1
Hydrometer Reading 1 - Percent Finer
% passed
54.2
6.5
2.9
Hydrometer Reading 2 - Percent Finer
% passed
46
6.5
2.9
Hydrometer Reading 3 - Percent Finer
% passed
36.4
5.6
2.3
Hydrometer Reading 4 - Percent Finer
% passed
29.6
4.7
1.8
Hydrometer Reading 5 - Percent Finer
% passed
26.9
3.8
1.3
Hydrometer Reading 6 - Percent Finer
% passed
19.6
3
0.7
Hydrometer Reading 7 - Percent Finer
% passed
13.9
1.9
0.6
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 7 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-26
RREC13-27
RREC13-28
Sample Name:
RREC13-26-SURF
RREC13-27-SURF
RREC13-28-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
Date Sampled:
11/4/13
11/4/13
11/1/13
Analyte
Units
Gravel
0/
/o
13.3
5
1
Sand
0/
/o
56.2
39
46.6
Coarse Sand
0/
/o
6.8
1.9
0.5
Medium Sand
0/
/o
5.7
5.8
2.6
Fine Sand
0/
/o
43.7
31.3
43.5
Silt
0/
/o
24.7
50.5
43
Clay
0/
/o
5.8
5.5
9.4
Silt + Clay
0/
/o
30.5
56
52.4
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
94.9
98.7
100
Sieve Size #4 - Percent Finer
% passed
86.7
95
99
Sieve Size #10 - Percent Finer
% passed
79.9
93.1
98.5
Sieve Size #20 - Percent Finer
% passed
77.2
90.3
97.9
Sieve Size #40 - Percent Finer
% passed
74.2
87.3
95.9
Sieve Size #60 - Percent Finer
% passed
69.2
81.9
84.2
Sieve Size #80 - Percent Finer
% passed
63.6
76.9
74.6
Sieve Size #100 - Percent Finer
% passed
56.7
73.2
69.9
Sieve Size #200 - Percent Finer
% passed
30.5
56
52.4
Hydrometer Reading 1 - Percent Finer
% passed
11.3
16.9
23.1
Hydrometer Reading 2 - Percent Finer
% passed
10.2
13.1
17.6
Hydrometer Reading 3 - Percent Finer
% passed
8
9.3
12.2
Hydrometer Reading 4 - Percent Finer
% passed
6.9
6.8
10.3
Hydrometer Reading 5 - Percent Finer
% passed
5.8
5.5
9.4
Hydrometer Reading 6 - Percent Finer
% passed
3.5
4
6.7
Hydrometer Reading 7 - Percent Finer
% passed
2.4
2.7
5.8
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 8 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-29
RREC13-30
RREC13-31
RREC13-29-SURF
RREC13-30-SURF
RREC13-31 -SURF
0-0.5
0-0.5
0-0.5
11/1/13
11/1/13
10/30/13
Analyte
Units
Gravel
0/
/o
0
0.5
0
Sand
0/
/o
18.4
43.9
24.7
Coarse Sand
0/
/o
0
1.5
0.6
Medium Sand
0/
/o
0.9
4.2
1.3
Fine Sand
0/
/o
17.5
38.2
22.8
Silt
0/
/o
62.8
33.3
60.1
Clay
0/
/o
18.8
22.3
15.2
Silt + Clay
0/
/o
81.6
55.6
75.3
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
100
100
100
Sieve Size #4 - Percent Finer
% passed
100
99.5
100
Sieve Size #10 - Percent Finer
% passed
100
98
99.4
Sieve Size #20 - Percent Finer
% passed
99.4
96.5
98.7
Sieve Size #40 - Percent Finer
% passed
99.1
93.8
98.1
Sieve Size #60 - Percent Finer
% passed
98.6
89.2
94.9
Sieve Size #80 - Percent Finer
% passed
97.5
85.1
90.6
Sieve Size #100 - Percent Finer
% passed
95.9
79.9
85.9
Sieve Size #200 - Percent Finer
% passed
81.6
55.6
75.3
Hydrometer Reading 1 - Percent Finer
% passed
40
41.1
51.1
Hydrometer Reading 2 - Percent Finer
% passed
32.9
34.8
42.1
Hydrometer Reading 3 - Percent Finer
% passed
25.9
30.1
29.6
Hydrometer Reading 4 - Percent Finer
% passed
21.6
27
20.6
Hydrometer Reading 5 - Percent Finer
% passed
18.8
22.3
15.2
Hydrometer Reading 6 - Percent Finer
% passed
13.2
16.1
11.4
Hydrometer Reading 7 - Percent Finer
% passed
10.1
11.2
9.6
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 9 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-32
RREC13-33
RREC13-34
RREC13-32-SURF
RREC13-33 -SURF
RREC13-34-SURF
0-0.5
0-0.5
0-0.5
10/30/13
10/30/13
10/30/13
Analyte
Units
Gravel
0/
/o
0.1
0.3
1.2
Sand
0/
/o
84.2
6.3
35.3
Coarse Sand
0/
/o
0.4
0.3
4.8
Medium Sand
0/
/o
8.4
0.3
14
Fine Sand
0/
/o
75.4
5.7
16.5
Silt
0/
/o
12.2
79.6
38.5
Clay
0/
/o
3.5
13.8
25
Silt + Clay
0/
/o
15.7
93.4
63.5
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
100
100
100
Sieve Size #4 - Percent Finer
% passed
99.9
99.7
98.8
Sieve Size #10 - Percent Finer
% passed
99.5
99.4
94
Sieve Size #20 - Percent Finer
% passed
97.3
99.2
86.5
Sieve Size #40 - Percent Finer
% passed
91.1
99.1
80
Sieve Size #60 - Percent Finer
% passed
81.8
98.3
72.7
Sieve Size #80 - Percent Finer
% passed
65.4
97.8
68.7
Sieve Size #100 - Percent Finer
% passed
45.7
97.3
66.9
Sieve Size #200 - Percent Finer
% passed
15.7
93.4
63.5
Hydrometer Reading 1 - Percent Finer
% passed
8.2
48
51.3
Hydrometer Reading 2 - Percent Finer
% passed
6.6
37.5
45.7
Hydrometer Reading 3 - Percent Finer
% passed
5.9
24.3
36.3
Hydrometer Reading 4 - Percent Finer
% passed
3.5
19.1
30.6
Hydrometer Reading 5 - Percent Finer
% passed
3.5
13.8
25
Hydrometer Reading 6 - Percent Finer
% passed
2.6
11
17.2
Hydrometer Reading 7 - Percent Finer
% passed
2.6
8.3
11.6
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 10 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-35
RREC13-36
RREC13-37
RREC13-35-SURF
RREC13-36-SURF
RREC13-37-SURF
0-0.5
0-0.5
0-0.5
10/30/13
10/28/13
10/28/13
Analyte
Units
Gravel
0/
/o
44.8
4.1
0
Sand
0/
/o
42.4
19.5
35.5
Coarse Sand
0/
/o
3
6.2
0.3
Medium Sand
0/
/o
3.7
1.3
0.7
Fine Sand
0/
/o
35.7
12
34.5
Silt
0/
/o
8.9
55.1
59.1
Clay
0/
/o
3.9
21.3
5.4
Silt + Clay
0/
/o
12.8
76.4
64.5
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
60.7
100
100
Sieve Size #4 - Percent Finer
% passed
55.2
95.9
100
Sieve Size #10 - Percent Finer
% passed
52.2
89.7
99.7
Sieve Size #20 - Percent Finer
% passed
50.6
89.4
99.3
Sieve Size #40 - Percent Finer
% passed
48.5
88.4
99
Sieve Size #60 - Percent Finer
% passed
41.6
86.7
97
Sieve Size #80 - Percent Finer
% passed
31.8
85.3
95.3
Sieve Size #100 - Percent Finer
% passed
25.2
83.2
93.3
Sieve Size #200 - Percent Finer
% passed
12.8
76.4
64.5
Hydrometer Reading 1 - Percent Finer
% passed
8.6
50.3
19.2
Hydrometer Reading 2 - Percent Finer
% passed
6.8
43.6
15.3
Hydrometer Reading 3 - Percent Finer
% passed
5.7
34.7
9.4
Hydrometer Reading 4 - Percent Finer
% passed
4.5
28
7.5
Hydrometer Reading 5 - Percent Finer
% passed
3.9
21.3
5.4
Hydrometer Reading 6 - Percent Finer
% passed
2.6
16.4
5
Hydrometer Reading 7 - Percent Finer
% passed
2.6
9.7
4.1
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 11 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-38
RREC13-39
RREC13-40
Sample Name:
RREC13-38-SURF
RREC13-39-SURF
RREC13-40-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
Date Sampled:
10/30/13
10/30/13
10/28/13
Analyte
Units
Gravel
0/
/o
0
0
0.9
Sand
0/
/o
67.3
71.6
61.3
Coarse Sand
0/
/o
0.4
0
0.7
Medium Sand
0/
/o
0.6
3.1
1.7
Fine Sand
0/
/o
66.3
68.5
58.9
Silt
0/
/o
28.9
23.6
34
Clay
0/
/o
3.8
4.8
3.8
Silt + Clay
0/
/o
32.7
28.4
37.8
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
100
100
100
Sieve Size #4 - Percent Finer
% passed
100
100
99.1
Sieve Size #10 - Percent Finer
% passed
99.6
100
98.4
Sieve Size #20 - Percent Finer
% passed
99.2
99.3
98
Sieve Size #40 - Percent Finer
% passed
99
96.9
96.7
Sieve Size #60 - Percent Finer
% passed
96.2
90.9
93.1
Sieve Size #80 - Percent Finer
% passed
90.3
83.3
OO
00
00
Sieve Size #100 - Percent Finer
% passed
77
72
83.5
Sieve Size #200 - Percent Finer
% passed
32.7
28.4
37.8
Hydrometer Reading 1 - Percent Finer
% passed
12.2
10.9
9.4
Hydrometer Reading 2 - Percent Finer
% passed
8.8
9.2
7.3
Hydrometer Reading 3 - Percent Finer
% passed
6.3
7.4
5.3
Hydrometer Reading 4 - Percent Finer
% passed
4.6
5.7
4.6
Hydrometer Reading 5 - Percent Finer
% passed
3.8
4.8
3.8
Hydrometer Reading 6 - Percent Finer
% passed
2
2.9
3.6
Hydrometer Reading 7 - Percent Finer
% passed
2
2.9
2.2
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 12 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-41
RREC 13-42
RREC 13-44
Sample Name:
RREC13-41 -SURF
RREC 13 -42-SURF
RREC 13 -44-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
Date Sampled:
10/30/13
11/4/13
10/30/13
Analyte
Units
Gravel
0/
/o
6.9
42.7
0
Sand
0/
/o
40.4
52.9
5.8
Coarse Sand
0/
/o
16.3
7.9
0
Medium Sand
0/
/o
12.8
15.3
0.3
Fine Sand
0/
/o
11.3
29.7
5.5
Silt
0/
/o
34.5
3.1
70
Clay
0/
/o
18.2
1.3
24.2
Silt + Clay
0/
/o
52.7
4.4
94.2
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
100
72.1
100
Sieve Size #4 - Percent Finer
% passed
93.1
57.3
100
Sieve Size #10 - Percent Finer
% passed
76.8
49.4
100
Sieve Size #20 - Percent Finer
% passed
66.2
43.2
99.8
Sieve Size #40 - Percent Finer
% passed
64
34.1
99.7
Sieve Size #60 - Percent Finer
% passed
54.3
20.9
99.2
Sieve Size #80 - Percent Finer
% passed
53.5
14.3
98.7
Sieve Size #100 - Percent Finer
% passed
53.4
10.8
98.1
Sieve Size #200 - Percent Finer
% passed
52.7
4.4
94.2
Hydrometer Reading 1 - Percent Finer
% passed
40.2
3.2
64.6
Hydrometer Reading 2 - Percent Finer
% passed
35.2
2.8
52.2
Hydrometer Reading 3 - Percent Finer
% passed
27.5
2
35.5
Hydrometer Reading 4 - Percent Finer
% passed
22.4
1.7
30
Hydrometer Reading 5 - Percent Finer
% passed
18.2
1.3
24.2
Hydrometer Reading 6 - Percent Finer
% passed
10.4
0.8
18.5
Hydrometer Reading 7 - Percent Finer
% passed
6.2
0.4
12.7
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 13 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-45
RREC13-46
RREC13-47
Sample Name:
RREC13-45-SURF
RREC13-46-SURF
RREC13-47-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
Date Sampled:
10/29/13
11/5/13
10/30/13
Analyte
Units
Gravel
0/
/o
1
35.2
0
Sand
0/
/o
20.9
55.6
5.3
Coarse Sand
0/
/o
1
11.2
0.1
Medium Sand
0/
/o
1.5
15.4
0.4
Fine Sand
0/
/o
18.4
29
4.8
Silt
0/
/o
54.4
5.8
69.1
Clay
0/
/o
23.7
3.4
25.6
Silt + Clay
0/
/o
78.1
9.2
94.7
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
85.4
100
Sieve Size 0.375 inch - Percent Finer
% passed
99.8
75
100
Sieve Size #4 - Percent Finer
% passed
99
64.8
100
Sieve Size #10 - Percent Finer
% passed
98
53.6
99.9
Sieve Size #20 - Percent Finer
% passed
97.4
45.1
99.6
Sieve Size #40 - Percent Finer
% passed
96.5
38.2
99.5
Sieve Size #60 - Percent Finer
% passed
91.9
27.5
98.8
Sieve Size #80 - Percent Finer
% passed
89.6
21.1
98.4
Sieve Size #100 - Percent Finer
% passed
87.7
17.2
98.1
Sieve Size #200 - Percent Finer
% passed
78.1
9.2
94.7
Hydrometer Reading 1 - Percent Finer
% passed
50.2
8.8
71.2
Hydrometer Reading 2 - Percent Finer
% passed
41.8
6.7
52.2
Hydrometer Reading 3 - Percent Finer
% passed
32.2
5
40.5
Hydrometer Reading 4 - Percent Finer
% passed
27.3
3.9
31.7
Hydrometer Reading 5 - Percent Finer
% passed
23.7
3.4
25.6
Hydrometer Reading 6 - Percent Finer
% passed
17.3
2.8
19.5
Hydrometer Reading 7 - Percent Finer
% passed
11.3
1.7
13.4
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 14 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-2 SEDIMENT RESULTS FOR GRAIN SIZE
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-48
RREC13-49
RREC13-50
Sample Name:
RREC13-48-SURF
RREC13-49-SURF
RREC13-50-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
Date Sampled:
11/5/13
11/5/13
11/5/13
Analyte
Units
Gravel
0/
/o
6.6
6.6
8.6
Sand
0/
/o
25.8
53.6
85.1
Coarse Sand
0/
/o
2
7.3
7.3
Medium Sand
0/
/o
6.4
4.6
17.6
Fine Sand
0/
/o
17.4
41.7
60.2
Silt
0/
/o
48.5
30.4
5.1
Clay
0/
/o
19.1
9.4
1.2
Silt + Clay
0/
/o
67.6
39.8
6.3
Sieve Size 3 inch - Percent Finer
% passed
100
100
100
Sieve Size 2 inch - Percent Finer
% passed
100
100
100
Sieve Size 1.5 inch - Percent Finer
% passed
100
100
100
Sieve Size 1 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.75 inch - Percent Finer
% passed
100
100
100
Sieve Size 0.375 inch - Percent Finer
% passed
97.3
100
98.1
Sieve Size #4 - Percent Finer
% passed
93.4
93.4
91.4
Sieve Size #10 - Percent Finer
% passed
91.4
86.1
84.1
Sieve Size #20 - Percent Finer
% passed
88.7
84.2
77.5
Sieve Size #40 - Percent Finer
% passed
85
81.5
66.5
Sieve Size #60 - Percent Finer
% passed
81.3
75.7
45
Sieve Size #80 - Percent Finer
% passed
78.8
70.5
28.3
Sieve Size #100 - Percent Finer
% passed
77
65.7
18.7
Sieve Size #200 - Percent Finer
% passed
67.6
39.8
6.3
Hydrometer Reading 1 - Percent Finer
% passed
39.1
20.6
2.8
Hydrometer Reading 2 - Percent Finer
% passed
33.7
17.3
2.3
Hydrometer Reading 3 - Percent Finer
% passed
27.1
12.8
1.7
Hydrometer Reading 4 - Percent Finer
% passed
23.1
10.5
1.2
Hydrometer Reading 5 - Percent Finer
% passed
19.1
9.4
1.2
Hydrometer Reading 6 - Percent Finer
% passed
13.8
7.1
1.2
Hydrometer Reading 7 - Percent Finer
% passed
11.1
6
0.6
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, MI
Page 15 of 15
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-3 SEDIMENT RESULTS FOR PCB-AROCLORS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan
(November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-01
RREC13-01
RREC13-01
RREC 13-01
RREC 13-02
RREC 13-02
RREC 13-02
RREC 13-02
RREC 13-02
RREC 13-02
RREC13-01-SURF
RREC 13-01-0001
RREC13-01-0103
RREC 13-01-03 05
RREC13-02-SURF
RREC 13-02-0001
RREC 13-02-0103
RREC 13-02-0305
RREC 13-02-0507
RREC 13-02-0709
0-0.5
0-1
1-3
3-5
0-0.5
0-1
1-3
3-5
5-7
7-9
10/30/13
10/31/13
10/31/13
10/31/13
10/30/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Hg/kg
61 U
64 U
81 U
60 U
47 U
230 U
340 U
300 U
300 U
240 U
Aroclor-1221
NSL
NSL
Hg/kg
61 U
64 U
81 U
60 U
47 U
230 U
340 U
300 U
300 U
240 U
Aroclor-1232
NSL
NSL
Hg/kg
61 U
64 U
81 U
60 U
47 U
230 U
340 U
300 U
300 U
240 U
Aroclor-1242
NSL
NSL
Hg/kg
61 U
64 U
81 U
60 U
91
550
1300
810
1300
410
Aroclor-1248
NSL
NSL
Hg/kg
61 U
64 U
81 U
60 U
47 U
230 U
340 U
300 U
300 U
240 U
Aroclor-1254
NSL
NSL
Hg/kg
61 U
64 U
81 U
60 U
150
1100
1700
1700
1500
1000
Aroclor-1260
NSL
NSL
Hg/kg
16 J
17 J
81 U
60 U
100
260
360
420
500
360
Aroclor-1262
NSL
NSL
Hg/kg
61 U
64 U
81 U
60 U
47 U
230 U
340 U
300 U
300 U
240 U
Aroclor-1268
NSL
NSL
Mg/kg
61 U
64 U
81 U
60 U
47 U
230 U
340 U
300 U
300 U
240 U
Total PCBs ND=0
59.8
676
Hg/kg
16
17
0
0
341
1,910
3,360
2,930
3,300
1,770
Total PCBs ND=1/2RL
59.8
676
Hg/kg
260
273
365
270
482
2,600
4,380
3,830
4,200
2,490
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-02
RREC 13-03
RREC 13-03
RREC 13-03
RREC 13-03
RREC 13-03
RREC 13-05
RREC 13-05
RREC 13-05
RREC 13-06
RREC 13-02-0911
RREC 13-03-SURF
RREC 13-03-0001
RREC 13-03-0103
RREC 13-03-0305
RREC 13-03-0507
RREC 13-05-SURF
RREC 13-05-0001
RREC13-05-0103
RREC13-06-SURF
9-11
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-1
1-3
0-0.5
11/2/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
160 U
64 U
83 U
94 U
74 U
42 U
43 U
240 U
260 U
64 U
Aroclor-1221
NSL
NSL
Mg/kg
160 U
64 U
83 U
94 U
74 U
42 U
43 U
240 U
260 U
64 U
Aroclor-1232
NSL
NSL
Mg/kg
160 U
64 U
83 U
94 U
74 U
42 U
43 U
240 U
260 U
64 U
Aroclor-1242
NSL
NSL
Mg/kg
150 J
37 J
83 U
94 U
74 U
42 U
25 J
490
410
33 J
Aroclor-1248
NSL
NSL
Mg/kg
160 U
64 U
83 U
94 U
74 U
42 U
43 U
240 U
260 U
64 U
Aroclor-1254
NSL
NSL
Mg/kg
510
100 J
83 U
28 J
74 U
42 U
27 J
700 J
870 J
40 J
Aroclor-1260
NSL
NSL
Mg/kg
230
120
83 U
15 J
74 U
42 U
36 J
220 J
300
74
Aroclor-1262
NSL
NSL
Mg/kg
160 U
64 U
83 U
94 U
74 U
42 U
43 U
240 U
260 U
64 U
Aroclor-1268
NSL
NSL
Mg/kg
160 U
64 U
83 U
94 U
74 U
42 U
43 U
240 U
260 U
64 U
Total PCBs ND=0
59.8
676
Mg/kg
890
257
0
43
0
0
88
1,410
1,580
147
Total PCBs ND=1/2RL
59.8
676
Mg/kg
1,370
449
374
372
333
189
217
2,130
2,360
339
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-06
RREC 13-06
RREC 13-07
RREC 13-09
RREC 13-09
RREC 13-09
RREC 13-09
RREC 13-09
RREC 13-09
RREC 13-09
RREC 13-06-0001
RREC 13-06-0103
RREC13-07-SURF
RREC13-09-SURF
RREC 13-09-0001
RREC 13-09-0001-FD
RREC 13-09-0103
RREC 13-09-0103-FD
RREC 13-09-0305
RREC 13-09-03 05-FD
0-1
1-3
0-0.5
0-0.5
0-1
0-1
1-3
1-3
3-5
3-5
11/5/13
11/5/13
11/5/13
11/4/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
96 U
270 U
45 U
47 U
260 U
270 U
640 U
320 U
650 U
330 U
Aroclor-1221
NSL
NSL
Mg/kg
96 U
270 U
45 U
47 U
260 U
270 U
640 U
320 U
650 U
330 U
Aroclor-1232
NSL
NSL
Mg/kg
96 U
270 U
45 U
47 U
260 U
270 U
640 U
320 U
650 U
330 U
Aroclor-1242
NSL
NSL
Mg/kg
380
940
45 U
12 J
780
600
970
770
950
440
Aroclor-1248
NSL
NSL
Mg/kg
96 U
270 U
45 U
47 U
260 U
270 U
640 U
320 U
650 U
330 U
Aroclor-1254
NSL
NSL
Mg/kg
300
930
24 J
41 J
1300
1100
2000
1600
2200 J
1100 J
Aroclor-1260
NSL
NSL
Mg/kg
190
430
29 J
45 J
500 J
370
600 J
490
1100 J
480
Aroclor-1262
NSL
NSL
Mg/kg
96 U
270 U
45 U
47 U
260 U
270 U
640 U
320 U
650 U
330 U
Aroclor-1268
NSL
NSL
Mg/kg
96 U
270 U
45 U
47 U
260 U
270 U
640 U
320 U
650 U
330 U
Total PCBs ND=0
59.8
676
Mg/kg
870
2,300
53
98
2,580
2,070
3,570
2,860
4,250
2,020
Total PCBs ND=1/2RL
59.8
676
Mg/kg
1,158
3,110
211
239
3,360
2,880
5,490
3,820
6,200
3,010
NOTES:
J = Result is less than the Reporting Limit (RL) but greater than or equal to the Method
Detection Limit (MDL) and the concentration is an approximate value.
P = the percent difference between the original and confirmation analysis is greater than
40%
U = Indicates the analyte was analyzed for but not detected.
RL=Reporting limit
|ig/kg = Micrograms per kilogram.
NSL = No Screening Level.
TEC = Threshold effect concentration. Development and Evaluation of Consensus-Based
Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of Consensus-Based
Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 1 of9
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-3 SEDIMENT RESULTS FOR PCB-AROCLORS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan
(November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-11
RREC13-13
RREC13-13
RREC13-13
RREC13-13
RREC13-13
RREC13-14
RREC13-14
RREC13-14
RREC13-14
RREC13-11-SURF
RREC13-13-SURF
RREC13-13-0001
RREC 13-13-0103
RREC13-13-0305
RREC 13-13-0507
RREC13-14-SURF
RREC 13 -14-SURF-FD
RREC 13-14-0001
RREC13-14-0103
0-0.5
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-0.5
0-1
1-3
11/4/13
11/4/13
11/5/13
11/5/13
11/5/13
11/5/13
11/4/13
11/4/13
11/5/13
11/5/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
46 U
44 U
150 U
280 U
120 U
59 U
260 U
270 U
490 U
1100 U
Aroclor-1221
NSL
NSL
Mg/kg
46 U
44 U
150 U
280 U
120 U
59 U
260 U
270 U
490 U
1100 U
Aroclor-1232
NSL
NSL
Mg/kg
46 U
44 U
150 U
280 U
120 U
59 U
260 U
270 U
490 U
1100 U
Aroclor-1242
NSL
NSL
Mg/kg
27 J
26 J
220
1100
330
59 U
270
310
590
1800
Aroclor-1248
NSL
NSL
Mg/kg
46 U
44 U
150 U
280 U
120 U
59 U
260 U
270 U
490 U
1100 U
Aroclor-1254
NSL
NSL
Mg/kg
58
48
280 J
930
260 J
59 U
330
330
650
2100
Aroclor-1260
NSL
NSL
Mg/kg
71
60
320 J
460
96 J
59 U
410
470
760 J
2700
Aroclor-1262
NSL
NSL
Mg/kg
46 U
44 U
150 U
280 U
120 U
59 U
260 U
270 U
490 U
1100 U
Aroclor-1268
NSL
NSL
Mg/kg
46 U
44 U
150 U
280 U
120 U
59 U
260 U
270 U
490 U
1100 U
Total PCBs ND=0
59.8
676
Mg/kg
156
134
820
2,490
686
0
1,010
1,110
2,000
6,600
Total PCBs ND=1/2RL
59.8
676
Mg/kg
294
266
1,270
3,330
1,046
266
1,790
1,920
3,470
9,900
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-14
RREC13-14
RREC13-14
RREC13-15
RREC13-15
RREC13-15
RREC13-16
RREC13-16
RREC13-16
RREC13-16
RREC13-14-0305
RREC 13-14-0507
RREC13-14-0710
RREC13-15-SURF
RREC13-15-0001
RREC13-15-0103
RREC 13-16-SURF
RREC 13-16-0001
RREC13-16-0103
RREC 13-16-0305
3-5
5-7
7-10
0-0.5
0-1
1-3
0-0.5
0-1
1-3
3-5
11/5/13
11/5/13
11/5/13
11/4/13
11/5/13
11/5/13
10/29/13
10/31/13
10/31/13
10/31/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
1100U
1100U
550 U
610 U
580 U
210 U
180 U
370 U
220 U
43 U
Aroclor-1221
NSL
NSL
Mg/kg
1100U
1100U
550 U
610 U
580 U
210 U
180 U
370 U
220 U
43 U
Aroclor-1232
NSL
NSL
Mg/kg
1100U
1100U
550 U
610 U
580 U
210 U
180 U
370 U
220 U
43 U
Aroclor-1242
NSL
NSL
Mg/kg
6100
5100
2400
610 U
1300
290
210
440
180 J
5.2 J
Aroclor-1248
NSL
NSL
Mg/kg
1100U
1100U
550 U
2200
580 U
210 U
180 U
370 U
220 U
43 U
Aroclor-1254
NSL
NSL
Mg/kg
3500
3400
2100
610 U
2200
580
400
780
380
9.8 J
Aroclor-1260
NSL
NSL
Mg/kg
1600 J
1100 J
510 J
630 J
820
230
380
860
380
8.5 J
Aroclor-1262
NSL
NSL
Mg/kg
1100U
1100U
550 U
610 U
580 U
210 U
180 U
370 U
220 U
43 U
Aroclor-1268
NSL
NSL
Mg/kg
1100U
1100U
550 U
610 U
580 U
210 U
180 U
370 U
220 U
43 U
Total PCBs ND=0
59.8
676
Mg/kg
11,200
9,600
5,010
2,830
4,320
1,100
990
2,080
940
24
Total PCBs ND=1/2RL
59.8
676
Mg/kg
14,500
12,900
6,660
4,965
6,060
1,730
1,530
3,190
1,600
153
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-16
RREC13-16
RREC13-16
RREC13-17
RREC13-17
RREC13-17
RREC13-17
RREC13-17
RREC13-17
RREC13-17
RREC 13-16-0507
RREC 13-16-0709
RREC13-16-0911
RREC13-17-SURF
RREC 13-17-0001
RREC13-17-0103
RREC 13-17-0305
RREC 13-17-0507
RREC 13-17-0709
RREC13-17-0911
5-7
7-9
9-11
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
10/31/13
10/31/13
10/31/13
10/29/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
41 U
39 U
40 U
87 U
340 U
640 U
220 U
140 U
67 U
62 U
Aroclor-1221
NSL
NSL
Mg/kg
41 U
39 U
40 U
87 U
340 U
640 U
220 U
140 U
67 U
62 U
Aroclor-1232
NSL
NSL
Mg/kg
41 U
39 U
40 U
87 U
340 U
640 U
220 U
140 U
67 U
62 U
Aroclor-1242
NSL
NSL
Mg/kg
6.6 J
39 U
40 U
120
530
1600
54 J
50 J
67 U
62 U
Aroclor-1248
NSL
NSL
Mg/kg
41 U
39 U
40 U
87 U
340 U
640 U
220 U
140 U
67 U
62 U
Aroclor-1254
NSL
NSL
Mg/kg
12 J
39 U
40 U
250
660
2500
310 J
340
67 U
62 U
Aroclor-1260
NSL
NSL
Mg/kg
10 J
39 U
40 U
190
420
650
510
120 J
29 J
62 U
Aroclor-1262
NSL
NSL
Mg/kg
41 U
39 U
40 U
87 U
340 U
640 U
220 U
140 U
67 U
62 U
Aroclor-1268
NSL
NSL
Mg/kg
41 U
39 U
40 U
87 U
340 U
640 U
220 U
140 U
67 U
62 U
Total PCBs ND=0
59.8
676
Mg/kg
29
0
0
560
1,610
4,750
874
510
29
0
Total PCBs ND=1/2RL
59.8
676
Mg/kg
152
176
180
821
2,630
6,670
1,534
930
297
279
NOTES:
J = Result is less than the Reporting Limit (RL) but greater than or equal to the Method
Detection Limit (MDL) and the concentration is an approximate value.
P = the percent difference between the original and confirmation analysis is greater than
40%
U = Indicates the analyte was analyzed for but not detected.
RL=Reporting limit
|ig/kg = Micrograms per kilogram.
NSL = No Screening Level.
TEC = Threshold effect concentration. Development and Evaluation of Consensus-
Based Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of Consensus-Based
Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 2 of 9
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-3 SEDIMENT RESULTS FOR PCB-AROCLORS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan
(November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-18
RREC13-18
RREC13-18
RREC13-18
RREC13-18
RREC13-18
RREC13-18
RREC13-19
RREC13-19
RREC 13-20
RREC13-18-SURF
RREC13-18-0001
RREC13-18-0103
RREC13-18-0305
RREC 13-18-0507
RREC13-18-0709
RREC13-18-0911
RREC13-19-SURF
RREC 13-19-0001
RREC13-20-SURF
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
0-1
0-0.5
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/29/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
83 U
140 U
310 U
53 U
50 U
44 U
46 U
56 U
420 U
49 U
Aroclor-1221
NSL
NSL
Mg/kg
83 U
140 U
310 U
53 U
50 U
44 U
46 U
56 U
420 U
49 U
Aroclor-1232
NSL
NSL
Mg/kg
83 U
140 U
310 U
53 U
50 U
44 U
46 U
56 U
420 U
49 U
Aroclor-1242
NSL
NSL
Mg/kg
160
220
250 J
17 J
4.9 J
44 U
46 U
96
1200
50
Aroclor-1248
NSL
NSL
Mg/kg
83 U
140 U
310 U
53 U
50 U
44 U
46 U
56 U
420 U
49 U
Aroclor-1254
NSL
NSL
Mg/kg
330
310 J
900 J
130 J
26 J
44 U
46 U
190
1200
89
Aroclor-1260
NSL
NSL
Mg/kg
260
250 J
500 J
76 J
11 J
44 U
46 U
94 J
250 J
59 J
Aroclor-1262
NSL
NSL
Mg/kg
83 U
140 U
310 U
53 U
50 U
44 U
46 U
56 U
420 U
49 U
Aroclor-1268
NSL
NSL
Mg/kg
83 U
140 U
310 U
53 U
50 U
44 U
46 U
56 U
420 U
49 U
Total PCBs ND=0
59.8
676
Mg/kg
750
780
1,650
223
42
0
0
380
2,650
198
Total PCBs ND=1/2RL
59.8
676
Mg/kg
999
1,200
2,580
382
192
198
207
548
3,910
345
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-20
RREC 13-20
RREC 13-20
RREC13-21
RREC13-21
RREC13-21
RREC 13-21
RREC13-21
RREC13-21
RREC13-21
RREC13-20-0001
RREC 13-20-0103
RREC 13-20-0305
RREC 13-21-SURF
RREC 13-21-0001
RREC13-21-0001-FD
RREC13-21-0103
RREC13-21-0103-FD
RREC 13-21-03 05
RREC 13-21-03 05-FD
0-1
1-3
3-5
0-0.5
0-1
0-1
1-3
1-3
3-5
3-5
11/1/13
11/1/13
11/1/13
10/29/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
41 U
41 U
40 U
210 U
190 U
180 U
770 U
400 U
350 U
350 U
Aroclor-1221
NSL
NSL
Mg/kg
41 U
41 U
40 U
210 U
190 U
180 U
770 U
400 U
350 U
350 U
Aroclor-1232
NSL
NSL
Mg/kg
41 U
41 U
40 U
210 U
190 U
180 U
770 U
400 U
350 U
350 U
Aroclor-1242
NSL
NSL
Mg/kg
41 U
41 U
40 U
240
260
280
780
600
1700
1900
Aroclor-1248
NSL
NSL
Mg/kg
41 U
41 U
40 U
210 U
190 U
180 U
770 U
400 U
350 U
350 U
Aroclor-1254
NSL
NSL
Mg/kg
41 U
41 U
40 U
430
320
400
830
570
1400
1400
Aroclor-1260
NSL
NSL
Mg/kg
41 U
41 U
40 U
440
400
500
1600
1200
3100
1400
Aroclor-1262
NSL
NSL
Mg/kg
41 U
41 U
40 U
210 U
190 U
180 U
770 U
400 U
350 U
350 U
Aroclor-1268
NSL
NSL
Mg/kg
41 U
41 U
40 U
210 U
190 U
180 U
770 U
400 U
350 U
350 U
Total PCBs ND=0
59.8
676
Mg/kg
0
0
0
1,110
980
1,180
3,210
2,370
6,200
4,700
Total PCBs ND=1/2RL
59.8
676
Mg/kg
185
185
180
1,740
1,550
1,720
5,520
3,570
7,250
5,750
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-21
RREC13-21
RREC13-21
RREC13-21
RREC13-21
RREC13-21
RREC 13-22
RREC 13-22
RREC 13-22
RREC 13-22
RREC 13-21-05 07
RREC13-21-0507-FD
RREC 13-21-0709
RREC13-21-0709-FD
RREC13-21-0911
RREC13-21-0911-FD
RREC13-22-SURF
RREC 13-22-0001
RREC 13-22-0103
RREC 13-22-0305
5-7
5-7
7-9
7-9
9-11
9-11
0-0.5
0-1
1-3
3-5
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
10/29/13
11/1/13
11/1/13
11/1/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
1300 U
1300 U
160 U
51 U
40 U
41 U
160 U
210 U
590 U
630 U
Aroclor-1221
NSL
NSL
Mg/kg
1300 U
1300 U
160 U
51 U
40 U
41 U
160 U
210 U
590 U
630 U
Aroclor-1232
NSL
NSL
Mg/kg
1300 U
1300 U
160 U
51 U
40 U
41 U
160 U
210 U
590 U
630 U
Aroclor-1242
NSL
NSL
Mg/kg
5100
4800
200
81
40 U
14 J
180
330
900
2200
Aroclor-1248
NSL
NSL
Mg/kg
1300 U
1300 U
160 U
51 U
40 U
41 U
160 U
210 U
590 U
630 U
Aroclor-1254
NSL
NSL
Mg/kg
4400
4200
620
270
11 J
24 J
220
370 J
770 J
1700 J
Aroclor-1260
NSL
NSL
Mg/kg
1200 J
1200 J
270
110 J
40 U
8.7 J
310
630
1600
1500 J
Aroclor-1262
NSL
NSL
Mg/kg
1300 U
1300 U
160 U
51 U
40 U
41 U
160 U
210 U
590 U
630 U
Aroclor-1268
NSL
NSL
Mg/kg
1300 U
1300 U
160 U
51 U
40 U
41 U
160 U
210 U
590 U
630 U
Total PCBs ND=0
59.8
676
Mg/kg
10,700
10,200
1,090
461
11
47
710
1,330
3,270
5,400
Total PCBs ND=1/2RL
59.8
676
Mg/kg
14,600
14,100
1,570
614
171
170
1,190
1,960
5,040
7,290
NOTES:
J = Result is less than the Reporting Limit (RL) but greater than or equal to the Method
Detection Limit (MDL) and the concentration is an approximate value.
P = the percent difference between the original and confirmation analysis is greater than
40%
U = Indicates the analyte was analyzed for but not detected.
RL=Reporting limit
|ig/kg = Micrograms per kilogram.
NSL = No Screening Level.
TEC = Threshold effect concentration. Development and Evaluation of Consensus-
Based Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al.
2000).
PEC = Probable effect concentration. Development and Evaluation of Consensus-Based
Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 3 of 9
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-3 SEDIMENT RESULTS FOR PCB-AROCLORS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan
(November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-22
RREC 13-22
RREC 13-22
RREC 13-23
RREC 13-23
RREC 13-23
RREC 13-23
RREC 13-23
RREC 13-23
RREC 13-23
RREC13-22-0507
RREC 13-22-0709
RREC 13-22-0911
RREC 13-23-SURF
RREC 13-23-0001
RREC13-23-0103
RREC 13-23-0305
RREC 13-23-0507
RREC 13-23-0709
RREC 13-23-0911
5-7
7-9
9-11
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
11/1/13
11/1/13
11/1/13
10/30/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
2600 U
1500 U
48 U
1600 U
680 U
1600 U
900 U
860 U
850 U
1500 U
Aroclor-1221
NSL
NSL
Mg/kg
2600 U
1500 U
48 U
1600 U
680 U
1600 U
900 U
860 U
850 U
1500 U
Aroclor-1232
NSL
NSL
Mg/kg
2600 U
1500 U
48 U
1600 U
680 U
1600 U
900 U
860 U
850 U
1500 U
Aroclor-1242
NSL
NSL
Mg/kg
13000
3900
63
650 J
430 J
1800
2300
4500
3100
3900
Aroclor-1248
NSL
NSL
Mg/kg
2600 U
1500 U
48 U
1600 U
680 U
1600 U
900 U
860 U
850 U
1500 U
Aroclor-1254
NSL
NSL
Mg/kg
7000
3900 J
67 J
770 J
430 J
1500 J
1700
2900
2900
3900
Aroclor-1260
NSL
NSL
Mg/kg
2400 J
1000 J
22 J
3500
1200
3600
2000 J
640 J
430 J
880 J
Aroclor-1262
NSL
NSL
Mg/kg
2600 U
1500 U
48 U
1600 U
680 U
1600 U
900 U
860 U
850 U
1500 U
Aroclor-1268
NSL
NSL
Mg/kg
2600 U
1500 U
48 U
1600 U
680 U
1600 U
900 U
860 U
850 U
1500 U
Total PCBs ND=0
59.8
676
Mg/kg
22,400
8,800
152
4,920
2,060
6,900
6,000
8,040
6,430
8,680
Total PCBs ND=1/2RL
59.8
676
Mg/kg
30,200
13,300
296
9,720
4,100
11,700
8,700
10,620
8,980
13,180
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-24
RREC 13-24
RREC 13-24
RREC 13-25
RREC 13-25
RREC 13-25
RREC 13-25
RREC 13-25
RREC 13-25
RREC 13-26
RREC13-24-SURF
RREC 13-24-0001
RREC13-24-0103
RREC 13-25-SURF
RREC 13-25-0001
RREC13-25-0103
RREC 13-25-0305
RREC 13-25-0507
RREC 13-25-0710
RREC13-26-SURF
0-0.5
0-1
1-3
0-0.5
0-1
1-3
3-5
5-7
7-10
0-0.5
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
39 U
41 U
41 U
43 U
540 U
520 U
620 U
1800 U
2200 U
250 U
Aroclor-1221
NSL
NSL
Mg/kg
39 U
41 U
41 U
43 U
540 U
520 U
620 U
1800 U
2200 U
250 U
Aroclor-1232
NSL
NSL
Mg/kg
39 U
41 U
41 U
43 U
540 U
520 U
620 U
1800 U
2200 U
250 U
Aroclor-1242
NSL
NSL
Mg/kg
27 J
41 U
41 U
87
1200
2900
4200
11000
12000
1000
Aroclor-1248
NSL
NSL
Mg/kg
39 U
41 U
41 U
43 U
540 U
520 U
620 U
1800 U
2200 U
250 U
Aroclor-1254
NSL
NSL
Mg/kg
33 J
41 U
41 U
93
1300
1900
2300
5200
6000
880
Aroclor-1260
NSL
NSL
Mg/kg
23 J
41 U
41 U
50
1200 J
950 J
850 J
1500 J
2100 J
360
Aroclor-1262
NSL
NSL
Mg/kg
39 U
41 U
41 U
43 U
540 U
520 U
620 U
1800 U
2200 U
250 U
Aroclor-1268
NSL
NSL
Mg/kg
39 U
41 U
41 U
43 U
540 U
520 U
620 U
1800 U
2200 U
250 U
Total PCBs ND=0
59.8
676
Mg/kg
83
0
0
230
3,700
5,750
7,350
17,700
20,100
2,240
Total PCBs ND=1/2RL
59.8
676
Mg/kg
200
185
185
359
5,320
7,310
9,210
23,100
26,700
2,990
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-26
RREC 13-26
RREC 13-26
RREC 13-26
RREC 13-27
RREC 13-27
RREC 13-27
RREC 13-27
RREC 13-27
RREC 13-27
RREC13-26-0001
RREC 13-26-0103
RREC 13-26-0305
RREC 13-26-05 07
RREC13-27-SURF
RREC 13-27-0001
RREC 13-27-0103
RREC 13-27-0305
RREC 13-27-0507
RREC 13-27-0710
0-1
1-3
3-5
5-7
0-0.5
0-1
1-3
3-5
5-7
7-10
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
960 U
2700 U
560 U
510 U
120 U
760 U
800 U
580 U
290 U
620 U
Aroclor-1221
NSL
NSL
Mg/kg
960 U
2700 U
560 U
510 U
120 U
760 U
800 U
580 U
290 U
620 U
Aroclor-1232
NSL
NSL
Mg/kg
960 U
2700 U
560 U
510 U
120 U
760 U
800 U
580 U
290 U
620 U
Aroclor-1242
NSL
NSL
Mg/kg
5400
16000
560 U
510 U
210
3100
2700
1600
510
610 J
Aroclor-1248
NSL
NSL
Mg/kg
960 U
2700 U
3100
2700
120 U
760 U
800 U
580 U
290 U
620 U
Aroclor-1254
NSL
NSL
Mg/kg
3600
8200
560 U
510 U
210
2300
2800
2500 J
1000 J
1500 J
Aroclor-1260
NSL
NSL
Mg/kg
890 J
1500 J
540 J
400 J
230
600 J
730 J
900 J
500 J
580 J
Aroclor-1262
NSL
NSL
Mg/kg
960 U
2700 U
560 U
510 U
120 U
760 U
800 U
580 U
290 U
620 U
Aroclor-1268
NSL
NSL
Mg/kg
960 U
2700 U
560 U
510 U
120 U
760 U
800 U
580 U
290 U
620 U
Total PCBs ND=0
59.8
676
Mg/kg
9,890
25,700
3,640
3,100
650
6,000
6,230
5,000
2,010
2,690
Total PCBs ND=1/2RL
59.8
676
Mg/kg
12,770
33,800
5,600
4,885
1,010
8,280
8,630
6,740
2,880
4,550
NOTES:
J = Result is less than the Reporting Limit (RL) but greater than or equal to the Method
Detection Limit (MDL) and the concentration is an approximate value.
P = the percent difference between the original and confirmation analysis is greater than
40%
U = Indicates the analyte was analyzed for but not detected.
RL=Reporting limit
|ig/kg = Micrograms per kilogram.
NSL = No Screening Level.
TEC = Threshold effect concentration. Development and Evaluation of Consensus-
Based Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al.
2000).
PEC = Probable effect concentration. Development and Evaluation of Consensus-Based
Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 4 of 9
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-3 SEDIMENT RESULTS FOR PCB-AROCLORS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan
(November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-28
RREC 13-28
RREC 13-28
RREC 13-28
RREC 13-28
RREC 13-28
RREC 13-28
RREC 13-29
RREC 13-29
RREC13-29
RREC13-28-SURF
RREC13-28-0001
RREC13-28-0103
RREC 13-28-0305
RREC 13-28-0507
RREC 13-28-0709
RREC 13-28-0911
RREC13-29-SURF
RREC 13-29-0001
RREC 13-29-0103
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
0-1
1-3
11/1/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/1/13
11/4/13
11/4/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
53 U
1500 U
160 U
62 U
61 U
60 U
60 U
320 U
1200 U
630 U
Aroclor-1221
NSL
NSL
Mg/kg
53 U
1500 U
160 U
62 U
61 U
60 U
60 U
320 U
1200 U
630 U
Aroclor-1232
NSL
NSL
Mg/kg
53 U
1500 U
160 U
62 U
61 U
60 U
60 U
320 U
1200 U
630 U
Aroclor-1242
NSL
NSL
Mg/kg
320
7300 J
240
44 J
26 J
60 U
60 U
1600
5000
1800
Aroclor-1248
NSL
NSL
Mg/kg
53 U
1500 U
160 U
62 U
61 U
60 U
60 U
320 U
1200 U
630 U
Aroclor-1254
NSL
NSL
Mg/kg
240
5000
540 J
98 J
55 J
53 J
60 U
870
3500
2000
Aroclor-1260
NSL
NSL
Mg/kg
120
1100 J
200
89 J
60 J
70
26 J
270 J
980 J
630 J
Aroclor-1262
NSL
NSL
Mg/kg
53 U
1500 U
160 U
62 U
61 U
60 U
60 U
320 U
1200 U
630 U
Aroclor-1268
NSL
NSL
Mg/kg
53 U
1500 U
160 U
62 U
61 U
60 U
60 U
320 U
1200 U
630 U
Total PCBs ND=0
59.8
676
Mg/kg
680
13,400
980
231
141
123
26
2,740
9,480
4,430
Total PCBs ND=1/2RL
59.8
676
Mg/kg
839
17,900
1,460
417
324
333
266
3,700
13,080
6,320
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-29
RREC 13-29
RREC 13-29
RREC 13-29
RREC 13-30
RREC 13-30
RREC 13-30
RREC 13-30
RREC 13-30
RREC13-30
RREC 13-29-0305
RREC 13-29-0507
RREC 13-29-0709
RREC13-29-0911
RREC13-30-SURF
RREC 13-3 0-0001
RREC13-30-0001-FD
RREC 13-3 0-0103
RREC 13-30-0103-FD
RREC 13-30-0305
3-5
5-7
7-9
9-11
0-0.5
0-1
0-1
1-3
1-3
3-5
11/4/13
11/4/13
11/4/13
11/4/13
11/1/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
290 U
290 U
170 U
200 U
690 U
3000 U
1900 U
1800 U
1300 U
1600 U
Aroclor-1221
NSL
NSL
Mg/kg
290 U
290 U
170 U
200 U
690 U
3000 U
1900 U
1800 U
1300 U
1600 U
Aroclor-1232
NSL
NSL
Mg/kg
290 U
290 U
170 U
200 U
690 U
3000 U
1900 U
1800 U
1300 U
1600 U
Aroclor-1242
NSL
NSL
Mg/kg
610
280 J
160 J
41 J
6100
12000
11000
11000
7300
12000
Aroclor-1248
NSL
NSL
Mg/kg
290 U
290 U
170 U
200 U
690 U
3000 U
1900 U
1800 U
1300 U
1600 U
Aroclor-1254
NSL
NSL
Mg/kg
1100 J
760 J
550 J
500 J
3100
9500
8900
9900
5700
6300
Aroclor-1260
NSL
NSL
Mg/kg
460 J
350 J
190 J
180 J
700
4700
4300
3700
2000
1500 J
Aroclor-1262
NSL
NSL
Mg/kg
290 U
290 U
170 U
200 U
690 U
3000 U
1900 U
1800 U
1300 U
1600 U
Aroclor-1268
NSL
NSL
Mg/kg
290 U
290 U
170 U
200 U
690 U
3000 U
1900 U
1800 U
1300 U
1600 U
Total PCBs ND=0
59.8
676
Mg/kg
2,170
1,390
900
721
9,900
26,200
24,200
24,600
15,000
19,800
Total PCBs ND=1/2RL
59.8
676
Mg/kg
3,040
2,260
1,410
1,321
11,970
35,200
29,900
30,000
18,900
24,600
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-30
RREC 13-30
RREC 13-30
RREC 13-31
RREC 13-31
RREC 13-31
RREC 13-31
RREC 13-31
RREC 13-32
RREC13-32
RREC 13-3 0-03 05-FD
RREC 13-30-0507
RREC 13-30-0507-FD
RREC 13-31-SURF
RREC 13-31-0001
RREC13-31-0103
RREC 13-31-0305
RREC 13-31-0507
RREC13-32-SURF
RREC13-32-0001
3-5
5-7
5-7
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-1
11/4/13
11/4/13
11/4/13
10/30/13
10/31/13
10/31/13
10/31/13
10/31/13
10/30/13
11/1/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
1100 U
160 U
170 U
61 U
48 U
47 U
48 U
44 U
140 U
560 U
Aroclor-1221
NSL
NSL
Mg/kg
1100 U
160 U
170 U
61 U
48 U
47 U
48 U
44 U
140 U
560 U
Aroclor-1232
NSL
NSL
Mg/kg
1100 U
160 U
170 U
61 U
48 U
47 U
48 U
44 U
140 U
560 U
Aroclor-1242
NSL
NSL
Mg/kg
7900
780
700
52 J
48 U
47 U
48 U
44 U
170
2900
Aroclor-1248
NSL
NSL
Mg/kg
1100 U
160 U
170 U
61 U
48 U
47 U
48 U
44 U
140 U
560 U
Aroclor-1254
NSL
NSL
Mg/kg
4600
680
690
79
48 U
47 U
48 U
44 U
500
1900
Aroclor-1260
NSL
NSL
Mg/kg
940 J
190
190
85
48 U
47 U
48 U
44 U
170
540 J
Aroclor-1262
NSL
NSL
Mg/kg
1100 U
160 U
170 U
61 U
48 U
47 U
48 U
44 U
140 U
560 U
Aroclor-1268
NSL
NSL
Mg/kg
1100 U
160 U
170 U
61 U
48 U
47 U
48 U
44 U
140 U
560 U
Total PCBs ND=0
59.8
676
Mg/kg
13,440
1,650
1,580
216
0
0
0
0
840
5,340
Total PCBs ND=1/2RL
59.8
676
Mg/kg
16,740
2,130
2,090
399
216
212
216
198
1,260
7,020
NOTES:
J = Result is less than the Reporting Limit (RL) but greater than or equal to the Method
Detection Limit (MDL) and the concentration is an approximate value.
P = the percent difference between the original and confirmation analysis is greater than
40%
U = Indicates the analyte was analyzed for but not detected.
RL=Reporting limit
|ig/kg = Micrograms per kilogram.
NSL = No Screening Level.
TEC = Threshold effect concentration. Development and Evaluation of Consensus-
Based Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al.
2000).
PEC = Probable effect concentration. Development and Evaluation of Consensus-Based
Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 5 of 9
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-3 SEDIMENT RESULTS FOR PCB-AROCLORS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan
(November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-32
RREC13-32
RREC 13-33
RREC13-33
RREC 13-33
RREC 13-33
RREC13-33
RREC 13-33
RREC 13-33
RREC 13-34
RREC13-32-0103
RREC 13-32-0305
RREC 13-3 3-SURF
RREC 13-3 3-0001
RREC13-33-0103
RREC 13-33-0305
RREC 13-33-0507
RREC 13-33-0709
RREC13-33-0911
RREC13-34-SURF
1-3
3-5
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
11/1/13
11/1/13
10/30/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
11/1/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
60 U
55 U
170 U
730 U
990 U
630 U
62 U
56 U
55 U
780 U
Aroclor-1221
NSL
NSL
Mg/kg
60 U
55 U
170 U
730 U
990 U
630 U
62 U
56 U
55 U
780 U
Aroclor-1232
NSL
NSL
Mg/kg
60 U
55 U
170 U
730 U
990 U
630 U
62 U
56 U
55 U
780 U
Aroclor-1242
NSL
NSL
Mg/kg
92
90
300
1200
4300
2200
77
17 J
41 J
1300
Aroclor-1248
NSL
NSL
Mg/kg
60 U
55 U
170 U
730 U
990 U
630 U
62 U
56 U
55 U
780 U
Aroclor-1254
NSL
NSL
Mg/kg
68
66
370
1200
2800
1700
63 J
14 J
30 J
1200
Aroclor-1260
NSL
NSL
Mg/kg
16 J
15 J
260
2100
2100
1500
66
12 J
37 J
1200 J
Aroclor-1262
NSL
NSL
Mg/kg
60 U
55 U
170 U
730 U
990 U
630 U
62 U
56 U
55 U
780 U
Aroclor-1268
NSL
NSL
Mg/kg
60 U
55 U
170 U
730 U
990 U
630 U
62 U
56 U
55 U
780 U
Total PCBs ND=0
59.8
676
Mg/kg
176
171
930
4,500
9,200
5,400
206
43
108
3,700
Total PCBs ND=1/2RL
59.8
676
Mg/kg
356
336
1,440
6,690
12,170
7,290
392
211
273
6,040
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-34
RREC13-34
RREC 13-34
RREC13-34
RREC 13-34
RREC 13-34
RREC13-35
RREC 13-35
RREC 13-35
RREC 13-35
RREC13-34-0001
RREC 13-34-0103
RREC 13-34-0305
RREC 13-34-0507
RREC 13-34-0709
RREC13-34-0911
RREC 13-3 5-SURF
RREC13-35-0001
RREC13-35-0103
RREC 13-35-0305
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
0-1
1-3
3-5
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
10/30/13
10/31/13
10/31/13
10/31/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
410 U
670 U
1300 U
290 U
280 U
300 U
51 U
61 U
42 U
41 U
Aroclor-1221
NSL
NSL
Mg/kg
410 U
670 U
1300 U
290 U
280 U
300 U
51 U
61 U
42 U
41 U
Aroclor-1232
NSL
NSL
Mg/kg
410 U
670 U
1300 U
290 U
280 U
300 U
51 U
61 U
42 U
41 U
Aroclor-1242
NSL
NSL
Mg/kg
1400
3700
5700
680
290
93 J
46 J
61 U
42 U
41 U
Aroclor-1248
NSL
NSL
Mg/kg
410 U
670 U
1300 U
290 U
280 U
300 U
51 U
61 U
42 U
41 U
Aroclor-1254
NSL
NSL
Mg/kg
1100 J
2600
4700
1500
1100
1200 J
64
61 U
42 U
41 U
Aroclor-1260
NSL
NSL
Mg/kg
1100 J
1000 J
1000 J
540
370
390
35 J
61 U
42 U
41 U
Aroclor-1262
NSL
NSL
Mg/kg
410 U
670 U
1300 U
290 U
280 U
300 U
51 U
61 U
42 U
41 U
Aroclor-1268
NSL
NSL
Mg/kg
410 U
670 U
1300 U
290 U
280 U
300 U
51 U
61 U
42 U
41 U
Total PCBs ND=0
59.8
676
Mg/kg
3,600
7,300
11,400
2,720
1,760
1,683
145
0
0
0
Total PCBs ND=1/2RL
59.8
676
Mg/kg
4,830
9,310
15,300
3,590
2,600
2,583
298
275
189
185
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-36
RREC13-36
RREC 13-36
RREC13-37
RREC 13-37
RREC 13-37
RREC13-37
RREC 13-37
RREC 13-37
RREC 13-37
RREC13-36-SURF
RREC 13-3 6-0001
RREC 13-3 6-0103
RREC 13-37-SURF
RREC 13-3 7-0001
RREC13-37-0103
RREC 13-37-0305
RREC 13-37-0507
RREC 13-37-0709
RREC 13-3 7-0911
0-0.5
0-1
1-3
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
10/28/13
10/31/13
10/31/13
10/28/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
330 UJ
390 U
1000 U
66 U
53 U
53 U
52 U
51 U
50 U
50 U
Aroclor-1221
NSL
NSL
Mg/kg
330 UJ
390 U
1000 U
66 U
53 U
53 U
52 U
51 U
50 U
50 U
Aroclor-1232
NSL
NSL
Mg/kg
330 UJ
390 U
1000 U
66 U
53 U
53 U
52 U
51 U
50 U
50 U
Aroclor-1242
NSL
NSL
Mg/kg
170 J
1200
3800
75
7 J
53 U
52 U
51 U
50 U
50 U
Aroclor-1248
NSL
NSL
Mg/kg
330 UJ
390 U
1000 U
66 U
53 U
53 U
52 U
51 U
50 U
50 U
Aroclor-1254
NSL
NSL
Mg/kg
330 J
1000
3600
92
15 J
53 U
52 U
51 U
50 U
50 U
Aroclor-1260
NSL
NSL
Mg/kg
640 J
380 J
850 J
75
7.1 J
53 U
52 U
51 U
50 U
50 U
Aroclor-1262
NSL
NSL
Mg/kg
330 UJ
390 U
1000 U
66 U
53 U
53 U
52 U
51 U
50 U
50 U
Aroclor-1268
NSL
NSL
Mg/kg
330 UJ
390 U
1000 U
66 U
53 U
53 U
52 U
51 U
50 U
50 U
Total PCBs ND=0
59.8
676
Mg/kg
1,140
2,580
8,250
242
29
0
0
0
0
0
Total PCBs ND=1/2RL
59.8
676
Mg/kg
2,130
3,750
11,250
440
188
239
234
230
225
225
NOTES:
J = Result is less than the Reporting Limit (RL) but greater than or equal to the Method
Detection Limit (MDL) and the concentration is an approximate value.
P = the percent difference between the original and confirmation analysis is greater than
40%
U = Indicates the analyte was analyzed for but not detected.
RL=Reporting limit
|ig/kg = Micrograms per kilogram.
NSL = No Screening Level.
TEC = Threshold effect concentration. Development and Evaluation of Consensus-
Based Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al.
2000).
PEC = Probable effect concentration. Development and Evaluation of Consensus-Based
Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 6 of 9
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-3 SEDIMENT RESULTS FOR PCB-AROCLORS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan
(November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-38
RREC13-38
RREC13-38
RREC13-38
RREC13-38
RREC13-38
RREC 13-39
RREC 13-39
RREC13-39
RREC13-39
RREC13-38 -SURF
RREC 13-3 8-SURF-FD
RREC13-38-0001
RREC13-38-0103
RREC 13-38-0305
RREC 13-38-0507
RREC13-39-SURF
RREC13-39-0001
RREC 13-3 9-0103
RREC 13-3 9-03 05
0-0.5
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-1
1-3
3-5
10/30/13
10/30/13
11/2/13
11/2/13
11/2/13
11/2/13
10/30/13
11/2/13
11/2/13
11/2/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
48 U
49 U
47 U
47 U
43 U
46 U
100 U
490 U
40 U
44 U
Aroclor-1221
NSL
NSL
Mg/kg
48 U
49 U
47 U
47 U
43 U
46 U
100 U
490 U
40 U
44 U
Aroclor-1232
NSL
NSL
Mg/kg
48 U
49 U
47 U
47 U
43 U
46 U
100 U
490 U
40 U
44 U
Aroclor-1242
NSL
NSL
Mg/kg
37 J
50
47 U
47 U
43 U
46 U
410
2900
39 J
44 U
Aroclor-1248
NSL
NSL
Mg/kg
48 U
49 U
47 U
47 U
43 U
46 U
100 U
490 U
40 U
44 U
Aroclor-1254
NSL
NSL
Mg/kg
48
41 J
47 U
47 U
43 U
46 U
300
2000
27 J
44 U
Aroclor-1260
NSL
NSL
Mg/kg
38 J
35 J
47 U
47 U
43 U
46 U
160
450 J
40 U
44 U
Aroclor-1262
NSL
NSL
Mg/kg
48 U
49 U
47 U
47 U
43 U
46 U
100 U
490 U
40 U
44 U
Aroclor-1268
NSL
NSL
Mg/kg
48 U
49 U
47 U
47 U
43 U
46 U
100 U
490 U
40 U
44 U
Total PCBs ND=0
59.8
676
Mg/kg
123
126
0
0
0
0
870
5,350
66
0
Total PCBs ND=1/2RL
59.8
676
Mg/kg
267
273
212
212
194
207
1,170
6,820
206
198
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-39
RREC 13-39
RREC 13-39
RREC 13-40
RREC13-40
RREC 13-40
RREC 13-40
RREC 13-40
RREC 13-41
RREC 13-41
RREC 13-39-0507
RREC 13-39-0709
RREC 13-3 9-0911
RREC13-40-SURF
RREC 13-40-0001
RREC 13-40-0103
RREC 13-40-0305
RREC 13-40-0507
RREC 13-41-SURF
RREC 13-41-0001
5-7
7-9
9-11
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-1
11/2/13
11/2/13
11/2/13
10/28/13
11/1/13
11/1/13
11/1/13
11/1/13
10/30/13
10/31/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
43 U
44 U
46 U
53 U
49 U
50 U
50 U
52 U
170 U
64 UJ
Aroclor-1221
NSL
NSL
Mg/kg
43 U
44 U
46 U
53 U
49 U
50 U
50 U
52 U
170 U
64 UJ
Aroclor-1232
NSL
NSL
Mg/kg
43 U
44 U
46 U
53 U
49 U
50 U
50 U
52 U
170 U
64 UJ
Aroclor-1242
NSL
NSL
Mg/kg
43 U
44 U
46 U
87
49 U
50 U
50 U
52 U
110 J
64 UJ
Aroclor-1248
NSL
NSL
Mg/kg
43 U
44 U
46 U
53 U
49 U
50 U
50 U
52 U
170 U
64 UJ
Aroclor-1254
NSL
NSL
Mg/kg
43 U
44 U
46 U
82
4.3 J
50 U
50 U
52 U
500
64 UJ
Aroclor-1260
NSL
NSL
Mg/kg
43 U
44 U
46 U
75
49 U
50 U
50 U
52 U
260 J
7 J
Aroclor-1262
NSL
NSL
Mg/kg
43 U
44 U
46 U
53 U
49 U
50 U
50 U
52 U
170 U
64 UJ
Aroclor-1268
NSL
NSL
Mg/kg
43 U
44 U
46 U
53 U
49 U
50 U
50 U
52 U
170 U
64 UJ
Total PCBs ND=0
59.8
676
Mg/kg
0
0
0
244
4
0
0
0
870
7
Total PCBs ND=1/2RL
59.8
676
Mg/kg
194
198
207
403
200
225
225
234
1,380
263
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-41
RREC 13-41
RREC13-41
RREC13-41
RREC13-41
RREC 13-41
RREC13-41
RREC 13-41
RREC 13-41
RREC 13-41
RREC13-41-0103
RREC 13-41-0103-FD
RREC 13-41-03 05
RREC 13-41-03 05-FD
RREC 13-41-05 07
RREC13-41-0507-FD
RREC 13-41-0709
RREC13-41-0709-FD
RREC13-41-0911
RREC13-41-0911-FD
1-3
1-3
3-5
3-5
5-7
5-7
7-9
7-9
9-11
9-11
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
66 U
65 U
64 U
67 U
65 U
65 U
72 U
70 U
64 U
61 U
Aroclor-1221
NSL
NSL
Mg/kg
66 U
65 U
64 U
67 U
65 U
65 U
72 U
70 U
64 U
61 U
Aroclor-1232
NSL
NSL
Mg/kg
66 U
65 U
64 U
67 U
65 U
65 U
72 U
70 U
64 U
61 U
Aroclor-1242
NSL
NSL
Mg/kg
66 U
65 U
64 U
67 U
65 U
65 U
72 U
70 U
64 U
61 U
Aroclor-1248
NSL
NSL
Mg/kg
66 U
65 U
64 U
67 U
65 U
65 U
72 U
70 U
64 U
61 U
Aroclor-1254
NSL
NSL
Mg/kg
66 U
65 U
64 U
67 U
65 U
65 U
72 U
70 U
64 U
61 U
Aroclor-1260
NSL
NSL
Mg/kg
66 U
65 U
88
66 J
24 J
23 J
72 U
70 U
64 U
61 U
Aroclor-1262
NSL
NSL
Mg/kg
66 U
65 U
64 U
67 U
65 U
65 U
72 U
70 U
64 U
61 U
Aroclor-1268
NSL
NSL
Mg/kg
66 U
65 U
64 U
67 U
65 U
65 U
72 U
70 U
64 U
61 U
Total PCBs ND=0
59.8
676
Mg/kg
0
0
88
66
24
23
0
0
0
0
Total PCBs ND=1/2RL
59.8
676
Mg/kg
297
293
344
334
284
283
324
315
288
275
NOTES:
J = Result is less than the Reporting Limit (RL) but greater than or equal to the Method
Detection Limit (MDL) and the concentration is an approximate value.
P = the percent difference between the original and confirmation analysis is greater than
40%
U = Indicates the analyte was analyzed for but not detected.
RL=Reporting limit
|ig/kg = Micrograms per kilogram.
NSL = No Screening Level.
TEC = Threshold effect concentration. Development and Evaluation of Consensus-
Based Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al.
2000).
PEC = Probable effect concentration. Development and Evaluation of Consensus-Based
Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 7 of 9
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-3 SEDIMENT RESULTS FOR PCB-AROCLORS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan
(November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-42
RREC 13-42
RREC 13-42
RREC 13-42
RREC 13-44
RREC 13-44
RREC 13-44
RREC 13-44
RREC 13-44
RREC 13-45
RREC13 -42-SURF
RREC 13-42-0001
RREC 13-42-0103
RREC 13-42-0305
RREC 13 -44-SURF
RREC 13-44-0001
RREC 13-44-0103
RREC 13-44-0305
RREC 13-44-0507
RREC 13-45-SURF
0-0.5
0-1
1-3
3-5
0-0.5
0-1
1-3
3-5
5-7
0-0.5
11/4/13
11/4/13
11/4/13
11/4/13
10/30/13
11/1/13
11/1/13
11/1/13
11/1/13
10/29/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
44 U
45 U
43 U
46 U
87 U
150 U
350 U
990 U
610 U
80 U
Aroclor-1221
NSL
NSL
Mg/kg
44 U
45 U
43 U
46 U
87 U
150 U
350 U
990 U
610 U
80 U
Aroclor-1232
NSL
NSL
Mg/kg
44 U
45 U
43 U
46 U
87 U
150 U
350 U
990 U
610 U
80 U
Aroclor-1242
NSL
NSL
Mg/kg
100
4.6 J
43 U
46 U
110
270
410
1600
4300
160
Aroclor-1248
NSL
NSL
Mg/kg
44 U
45 U
43 U
46 U
87 U
150 U
350 U
990 U
610 U
80 U
Aroclor-1254
NSL
NSL
Mg/kg
94
45 U
43 U
46 U
170
340
490
1600
2400
240
Aroclor-1260
NSL
NSL
Mg/kg
42 J
45 U
43 U
46 U
250
490
1000
4600
1300
160
Aroclor-1262
NSL
NSL
Mg/kg
44 U
45 U
43 U
46 U
87 U
150 U
350 U
990 U
610 U
80 U
Aroclor-1268
NSL
NSL
Mg/kg
44 U
45 U
43 U
46 U
87 U
150 U
350 U
990 U
610 U
80 U
Total PCBs ND=0
59.8
676
Mg/kg
236
5
0
0
530
1,100
1,900
7,800
8,000
560
Total PCBs ND=1/2RL
59.8
676
Mg/kg
368
185
194
207
791
1,550
2,950
10,770
9,830
800
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-45
RREC 13-45
RREC 13-45
RREC 13-46
RREC 13-46
RREC 13-46
RREC 13-46
RREC 13-46
RREC 13-46
RREC 13-47
RREC 13-45-0001
RREC 13-45-0103
RREC 13-45-03 05
RREC13-46-SURF
RREC 13-46-0001
RREC 13-46-0103
RREC 13-46-0305
RREC 13-46-0507
RREC 13-46-0710
RREC13-47-SURF
0-1
1-3
3-5
0-0.5
0-1
1-3
3-5
5-7
7-10
0-0.5
11/1/13
11/1/13
11/1/13
11/5/13
11/6/13
11/6/13
11/6/13
11/6/13
11/6/13
10/30/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
120 U
82 U
40 U
48 U
130 U
44 U
42 U
42 U
43 U
440 U
Aroclor-1221
NSL
NSL
Mg/kg
120 U
82 U
40 U
48 U
130 U
44 U
42 U
42 U
43 U
440 U
Aroclor-1232
NSL
NSL
Mg/kg
120 U
82 U
40 U
48 U
130 U
44 U
42 U
42 U
43 U
440 U
Aroclor-1242
NSL
NSL
Mg/kg
260
190
16 J
54
270
37 J
5.5 J
3.8 J
43 U
220 J
Aroclor-1248
NSL
NSL
Mg/kg
120 U
82 U
40 U
48 U
130 U
44 U
42 U
42 U
43 U
440 U
Aroclor-1254
NSL
NSL
Mg/kg
390
310
25 J
41 J
250 J
26 J
4.6 J
2.2 J
43 U
350 J
Aroclor-1260
NSL
NSL
Mg/kg
200 J
100
40 U
43 J
500
39 J
5.7 J
3.4 J
43 U
620
Aroclor-1262
NSL
NSL
Mg/kg
120 U
82 U
40 U
48 U
130 U
44 U
42 U
42 U
43 U
440 U
Aroclor-1268
NSL
NSL
Mg/kg
120 U
82 U
40 U
48 U
130 U
44 U
42 U
42 U
43 U
440 U
Total PCBs ND=0
59.8
676
Mg/kg
850
600
41
138
1,020
102
16
9
0
1,190
Total PCBs ND=1/2RL
59.8
676
Mg/kg
1,210
846
181
282
1,410
234
142
135
194
2,510
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-47
RREC 13-47
RREC 13-47
RREC 13-47
RREC 13-47
RREC 13-47
RREC 13-47
RREC 13-47
RREC 13-47
RREC 13-48
RREC13-47-SURF-FD
RREC 13-47-0001
RREC 13-47-0103
RREC 13-47-0103-FD
RREC 13-47-0305
RREC 13-47-03 05-FD
RREC 13-47-0507
RREC 13-47-0709
RREC 13-47-0911
RREC13-48-SURF
0-0.5
0-1
1-3
1-3
3-5
3-5
5-7
7-9
9-11
0-0.5
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
11/5/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
180 U
360 U
330 U
330 U
630 U
630 U
610 U
580 U
1200 U
230 U
Aroclor-1221
NSL
NSL
Mg/kg
180 U
360 U
330 U
330 U
630 U
630 U
610 U
580 U
1200 U
230 U
Aroclor-1232
NSL
NSL
Mg/kg
180 U
360 U
330 U
330 U
630 U
630 U
610 U
580 U
1200 U
230 U
Aroclor-1242
NSL
NSL
Mg/kg
130 J
200 J
370
430
400 J
400 J
530 J
2100
6100
240
Aroclor-1248
NSL
NSL
Mg/kg
180 U
360 U
330 U
330 U
630 U
630 U
610 U
580 U
1200 U
230 U
Aroclor-1254
NSL
NSL
Mg/kg
210
280 J
410 J
480 J
650 J
510 J
650
1400
3900 J
170 J
Aroclor-1260
NSL
NSL
Mg/kg
380
780 J
700 J
1000 J
1300 J
1300 J
2100
810
1500 J
320
Aroclor-1262
NSL
NSL
Mg/kg
180 U
360 U
330 U
330 U
630 U
630 U
610 U
580 U
1200 U
230 U
Aroclor-1268
NSL
NSL
Mg/kg
180 U
360 U
330 U
330 U
630 U
630 U
610 U
580 U
1200 U
230 U
Total PCBs ND=0
59.8
676
Mg/kg
720
1,260
1,480
1,910
2,350
2,210
3,280
4,310
11,500
730
Total PCBs ND=1/2RL
59.8
676
Mg/kg
1,260
2,340
2,470
2,900
4,240
4,100
5,110
6,050
15,100
1,420
NOTES:
J = Result is less than the Reporting Limit (RL) but greater than or equal to the Method
Detection Limit (MDL) and the concentration is an approximate value.
P = the percent difference between the original and confirmation analysis is greater than
40%
U = Indicates the analyte was analyzed for but not detected.
RL=Reporting limit
|ig/kg = Micrograms per kilogram.
NSL = No Screening Level.
TEC = Threshold effect concentration. Development and Evaluation of Consensus-
Based Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al.
2000).
PEC = Probable effect concentration. Development and Evaluation of Consensus-Based
Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 8 of 9
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-3 SEDIMENT RESULTS FOR PCB-AROCLORS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan
(November 2013)
Sample Location:
RREC13-48
RREC13-48
RREC13-48
RREC13-48
RREC13-48
RREC13-48
RREC 13-49
RREC 13-49
RREC13-49
Sample Name:
RREC13-48-SURF-FD
RREC13-48-0001
RREC13-48-0103
RREC13-48-0305
RREC 13-48-0507
RREC 13-48-0710
RREC13-49-SURF
RREC13-49-SURF-FD
RREC 13-49-0001
Sample Depth (ft):
0-0.5
0-1
1-3
3-5
5-7
7-10
0-0.5
0-0.5
0-1
Date Sampled:
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
230 U
130 U
190 U
130 U
240 U
800 U
62 U
65 U
170 U
Aroclor-1221
NSL
NSL
Mg/kg
230 U
130 U
190 U
130 U
240 U
800 U
62 U
65 U
170 U
Aroclor-1232
NSL
NSL
Mg/kg
230 U
130 U
190 U
130 U
240 U
800 U
62 U
65 U
170 U
Aroclor-1242
NSL
NSL
Mg/kg
250
160
320
420
1600
3800
100
110
860
Aroclor-1248
NSL
NSL
Mg/kg
230 U
130 U
190 U
130 U
240 U
800 U
62 U
65 U
170 U
Aroclor-1254
NSL
NSL
Mg/kg
200 J
170 J
380 J
470
970
2500
110 J
120 J
750
Aroclor-1260
NSL
NSL
Mg/kg
340
220
1400 J
580
520 J
930
150
140
480 J
Aroclor-1262
NSL
NSL
Mg/kg
230 U
130 U
190 U
130 U
240 U
800 U
62 U
65 U
170 U
Aroclor-1268
NSL
NSL
Mg/kg
230 U
130 U
190 U
130 U
240 U
800 U
62 U
65 U
170 U
Total PCBs ND=0
59.8
676
Mg/kg
790
550
2.100
1,470
3,090
7,230
360
370
2.090
Total PCBs ND=1/2RL
59.8
676
Mg/kg
1,480
040
2,670
1.860
3.810
9,630
546
565
2.600
Sample Location:
RREC13-49
RREC 13-49
RREC 13-49
RREC13-49
RREC13-50
RREC13-50
RREC13-50
RREC13-50
RREC13-50
Sample Name:
RREC13-49-0103
RREC 13-49-03 05
RREC 13-49-0507
RREC 13-49-0710
RREC13-50-SURF
RREC 13-5 0-0001
RREC 13-5 0-0103
RREC 13-5 0-03 05
RREC 13-50-0507
Sample Depth (ft):
1-3
3-5
5-7
7-10
0-0.5
0-1
1-3
3-5
5-7
Date Sampled:
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/6/13
11/6/13
11/6/13
11/6/13
Analyte
TEC
PEC
Units
Aroclor-1016
NSL
NSL
Mg/kg
560 U
850 U
550 U
300 U
44 U
82 U
75 U
52 U
58 U
Aroclor-1221
NSL
NSL
Mg/kg
560 U
850 U
550 U
300 U
44 U
82 U
75 U
52 U
58 U
Aroclor-1232
NSL
NSL
Mg/kg
560 U
850 U
550 U
300 U
44 U
82 U
75 U
52 U
58 U
Aroclor-1242
NSL
NSL
Mg/kg
3200
5300
2700
1600
21 J
27 J
75 U
25 J
12 J
Aroclor-1248
NSL
NSL
Mg/kg
560 U
850 U
550 U
300 U
44 U
82 U
75 U
52 U
58 U
Aroclor-1254
NSL
NSL
Mg/kg
1600
3200
2200
1500
14 J
48 J
41 J
67
60
Aroclor-1260
NSL
NSL
Mg/kg
690 J
1700
610
430
16 J
50 J
57 J
41 J
22 J
Aroclor-1262
NSL
NSL
Mg/kg
5^0 IT
850 U
550 U
300 U
44 U
82 U
75 U
52 U
58 U
Aroclor-1268
NSL
NSL
Mg/kg
5mi I
850 U
550 U
300 U
44 U
82 U
75 U
52 U
58 U
Total PCBs ND=0
59.8
676
Mg/kg
5.400
10.200
5,510
3,530
51
125
98
133
94
Total PCBs ND=1/2RL
59.8
676
Mg/kg
7.170
12,750
7,160
4.430
183
371
361
289
268
N0TES:
Detection Limit (MDL) and the concentration is an approximate value.
40%
U = Indicates the analyte was analyzed for but not detected.
RL=Reporting limit
Hg/kg = Micrograms per kilogram.
NSL = No Screening Level.
Based Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al.
Sediment Quality Guidelines for Freshwater Ecosystems (MacDonald et al. 2000).
Bolded values exceed the TEC.
linlded iind shiided \ nines cxcml Hie Pl.( .
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 9 of 9
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-01
RREC13-01
RREC13-01
RREC13-01
RREC13-02
RREC13-02
RREC13-02
RREC13-02
RREC13-02
RREC13-02
Sample Name:
RREC13-01-SURF
RREC13-01-0001
RREC13-01-0103
RREC13-01-0305
RREC13-02-SURF
RREC13-02-0001
RREC13-02-0103
RREC13-02-0305
RREC13-02-0507
RREC13-02-0709
Sample Depth (ft):
0-0.5
0-1
1-3
3-5
0-0.5
0-0.5
1-3
3-5
5-7
7-9
Date Sampled:
10/30/13
10/31/13
10/31/13
10/31/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
Analvte
TEC
PEC
Units
l-Methvlnaohthalene(b)
NSL
NSL
2000 J
3100
8500
13000
290 J
320 J
550 J
580 J
2500 J
1200 J
2-Methvlnaohthalene(a) 031
NSL
NSL
2700
4200
13000
21000
490 J
780 U
1400 U
2000 U
4300
2400 U
Acenaohthene'3'
NSL
NSL
1700 J
1700 J
3500 J
10000
540 J
440 J
890 J
1700 J
5500
1800 J
Acenaohthvlene !a'
NSL
NSL
....
....
....
Anthracene !a'
57.2
845
4500
4900
1X000
1X000
1600
X90
3"00
"100
Benzo(a)anthracene!a'
108
1050
6700
9000
2"?000
19000
5X00
3100
5300
7400
9000
Benzolalovrene !a'
150
1450
451)0
6000
12000
5600
2"00
4000
91100
Benzo(b)fluoranthene !a'
NSL
NSL
4000
5700
14000
8600 J
5400
2900
4800
6400
7600
6700
Benzo(e)Dvrene
NSL
NSL
ua/ka
3200
4400
13000
7300 J
3600
1900
3000
3900
5700
4300
Benzo(sJi,i)pervlene !a'
NSL
NSL
ua/ka
1500 J
3600
9000
4500 J
2000
1200
1800
2600
4300
2900
Benzo(k)fluoranthene!a'
NSL
NSL
ua/ka
4100
4500
15000
10000
5000
2700
4400
6000
9900
5600
CI Chrvsenes
NSL
NSL
6100 J
11000 J
30000 J
18000 J
3000 J
2100 J
3400 J
3400 J
5900 J
4700 J
CI Fluorenes
NSL
NSL
ua/ka
960 J
1500 J
5300 J
3900 J
170 J
320 J
520 J
390 J
1300 J
840 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
12000 J
15000 J
50000 J
38000 J
5700 J
4800 J
7500 J
8300 J
14000 J
11000 J
Cl-Naohthalenes
NSL
NSL
ua/ka
3100 J
5200 J
15000 J
22000 J
540 J
530 J
940 J
1100 J
4700 J
2100 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
15000 J
17000 J
58000 J
52000 J
3200 J
4100 J
6900 J
5900 J
14000 J
9600 J
C2 Chrvsenes
NSL
NSL
ua/ka
7100 J
10000 J
21000 J
17000 J
2300 J
2400 J
3700 J
3700 J
5100 J
3300 J
C2 Fluorenes
NSL
NSL
1400 J
2400 J
7300 J
4300 J
210 J
690 J
1100 J
780 J
2000 J
1300 J
C2-Fluoranthenes/Pvrenes(b)
NSL
NSL
7400 J
11000 J
28000 J
19000 J
2400 J
2900 J
4300 J
3900 J
6700 J
5000 J
C2-Naohthalenes
NSL
NSL
ua/ka
10000 J
14000 J
42000 J
53000 J
1300 J
1400 J
2900 J
2200 J
9700 J
4600 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
10000 J
17000 J
46000 J
29000 J
1700 J
3800 J
6600 J
4900 J
10000 J
8000 J
C3 Chrvsenes
NSL
NSL
ua/ka
2700 J
5400 J
9000 J
7200 J
780 J
950 J
1200 J
1200 J
1700 J
1200 J
C3 Fluorenes
NSL
NSL
3100 J
4500 J
8800 J
7000 J
320 J
1300 J
2300 J
1500 J
3500 J
2600 J
CS-Fluoranthenes/Pvrenes03'
NSL
NSL
4900 J
7900 J
13000 J
11000 J
1100 J
1600 J
2400 J
2100 J
3800 J
2900 J
C3-Naohthalenes
NSL
NSL
ua/ka
9500 J
13000 J
39000 J
31000 J
1100 J
2900 J
6100 J
3700 J
14000 J
7400 J
C3-Phenanthrenes/Anthracenes
NSL
NSL
9700 J
19000 J
27000 J
25000 J
1100 J
4300 J
6600 J
5500 J
9800 J
7800 J
C4 Chrvsenes
NSL
NSL
ua/ka
1500 J
2700 J
3000 J
3300 J
180 J
340 J
530 J
340 J
710 J
580 J
C4-Naohthalenes
NSL
NSL
5200 J
7800 J
18000 J
13000 J
500 J
2300 J
4500 J
3000 J
8600 J
5400 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
ua/ka
I3MMM.T
iiSn .T
Chrvsene (a)
166
1290
5900
X300
25000
16000
5200
3200
5500
"100
11000
X-00
Dibenzo(aJi)anthracene !a'
33
NSL
400.1
1400 .1
3200.1
1400 .1
5~0 .1
350.1
520 .1
090 .1
1300 .1
"60 .1
Fluoranthene
423
2230
ua/ka
14000
12000
41000
39000
9000
5400
11000
rooo
Fluorene !a'
77.4
536
ua/ka
3300
3~00
14000
"40 .1
630.1
1100.1
2200
5500
2900
Indeno(l,2J3-cd)pvrene !a'
NSL
NSL
ua/ka
1300 J
3000
4000 J
1800
1600
2500
4000 J
Naphthalene !a'
176
561
4000
6000
14000
2"000
1600
3500
2400
Pervlene
NSL
NSL
920 J
- ¦'
1-MM.I
Phenanthrene!a'
204
1170
14000
12000
32000
51000
4500
3600
6600
12000
Pyrene (a)
195
1520
l-Lg/kg
11000
15000
53000
34000
6300
4500
"300
11000
1X000
13000
Total PAH17 ND=1/2RL
1601
22800
X4340.0
102300
300000
292100
55460.0
34900.0
61520.0
X9520.0
1X4210
106291)
Total PAH34 ND=1/2RL
1601
22800
ua/ka
144100
193300
522500
456400
"3050.0
59100.0
101160
125090
249310
15"630
NOTES
Presented results are not normalized to organic carbon
w Included in calculation oftotal 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
lig/kg = Micrograms per kilogram
NSI^No screening level
TEC = Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC =Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 1 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-02
RREC13-03
RREC13-03
RREC13-03
RREC13-03
RREC13-03
RREC13-05
RREC13-05
RREC13-05
RREC13-06
Sample Name:
RREC13-02-0911
RREC13-03-SURF
RREC13-03 -0001
RREC13-03 -0103
RREC13-03 -0305
RREC13-03-0507
RREC13-05-SURF
RREC13-05-0001
RREC13-05-0103
RREC13-06-SURF
Sample Depth (ft):
9-11
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-1
1-3
0-0.5
Date Sampled:
11/2/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
1700
1000 J
1300 J
1900
1600
29 J
680 J
380 J
360 J
120 J
2-MethvinaDhthalene(a)(b)
NSL
NSL
2600
1800 J
2100
3200
2900
42
1000
630 J
550 J
210 J
Acenaohthene'3'
NSL
NSL
2100
1300 J
1200 J
1600 J
1400 J
30 J
360 J
680 J
540 J
180 J
Acenaohthvlene!a'
NSL
NSL
19 J
....
Anthracene !a'
57.2
845
3X00
7100
4000
4400
4500
81
1400
1900
"50
Benzo(a)anthracene !a'
108
1050
5600
16000
"72-00
X400
6600
130
3000
6200
4200
2300
Benzolalovrene!a'
150
1450
4300
13000
4900
5-00
93
2300
3400
2300
Benzo(b)fluoranthene!a'
NSL
NSL
3800
9600
3900
4300
3500
73
1800
4500
3000
1900
Benzo(e)Dvrene
NSL
NSL
3100
7500
3300
3800
2800
59
1600
3100
2200
1400
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
2700
6000
2300
2800
2300
45
1200
2900
1900
1300
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
3700
13000
4000
4500
3800
74
1900
4300
3000
1900
CI Chrvsenes
NSL
NSL
4900 J
3200 U
7000 J
8000 J
5800 J
120 J
2800 J
2900 J
2400 J
1300
CI Fluorenes
NSL
NSL
840 J
830 J
800 J
930 J
790 J
18 J
370 J
400 J
400 J
76 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
7200 J
18000 J
12000 J
14000 J
12000 J
210 J
4800 J
6400 J
5000 J
2600 J
Cl-Naohthalenes
NSL
NSL
3200 J
2000 J
2300 J
3500 J
3000 J
49 J
1200 J
730 J
640 J
230 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
9000 J
13000 J
13000 J
16000 J
12000 J
230 J
5900 J
4600 J
4300 J
1400 J
C2 Chrvsenes
NSL
NSL
3100 J
3200 U
6300 J
6600 J
5600 J
95 J
2300 J
1600 J
1600 J
780 J
C2 Fluorenes
NSL
NSL
1400 J
880 J
1300 J
1500 J
1100 J
22 J
690 J
560 J
630 J
100 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
4300 J
7800 J
8100 J
9000 J
6700 J
130 J
3200 J
2700 J
2600 J
1200 J
C2-Naohthalenes
NSL
NSL
7300 J
4800 J
7000 J
8000 J
7300 J
140 J
3800 J
1900 J
1900 J
520 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
8300 J
7000 J
10000 J
12000 J
8400 J
140 J
4800 J
3300 J
3800 J
760 J
C3 Chrvsenes
NSL
NSL
1400 J
3200 U
3000 J
3400 J
2800 J
43 J
1100 J
640 J
690 J
280 J
C3 Fluorenes
NSL
NSL
2800 J
1500 J
2700 J
3500 J
2400 J
40 J
1500 J
1100 J
1500 J
160 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
2600 J
3600 J
5100 J
5600 J
4800 J
79 J
2300 J
1600 J
1600 J
530 J
C3-Naohthalenes
NSL
NSL
8700 J
4400 J
7200 J
8000 J
6900 J
200 J
4500 J
3000 J
3000 J
470 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
7500 J
5500 J
10000 J
14000 J
9400 J
160 J
4800 J
3700 J
4400 J
570 J
C4 Chrvsenes
NSL
NSL
680 J
3200 U
1600 J
1700 J
1400 J
23 J
610 J
340 J
360 J
120 J
C4-Naohthalenes
NSL
NSL
6100 J
2500 J
4600 J
5500 J
4300 J
160 J
2900 J
2800 J
2900 J
240 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
5100 J
3500 J
7900 J
8800 J
95 J
'-mi l
Chrvsene(a)
166
1290
5600
13000
6400
-600
120
2X00
5"00
Dibenzo(a,h)anthracene!a'
33
NSL
96ft .T
IQftft J
7S0.T
9S0.T
700 J
13 J
340.1
"40 .1
520.1
320.1
Fluoranthene!a'
423
2230
11000
26000
12000
12000
11000
210
4900
—oo
Fluorene!a'
77.4
536
4300
3000
2300
2"00
'600
48
"SO
1-00.1
1100 .1
250.1
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
us/ks
2600
5800
37 J
1100
1700
1100
Naphthalene!a'
176
561
X500
4400
5X00
SI 00
XX00
110
1600
2100 U
630 U
Pervlene
NSL
NSL
J
41 J
Phenanthrene !a'
204
1170
10000
21000
11000
12000
240
3900
6100
1~00
Pyrene(a)
195
1520
10000
1"000
9500
11000
9400
190
3X00
9100
5X00
2"00
Total PAH17 ND=1/2RL
1601.0
ffffffffffff
X2210.0
162400
X0150.0
92"X0.0
X25XO.O
1555.00
32460M
"09X0.0
4"900.0
22X55.0
Total PAID 4 ND=1/2RL
1601.0
ffffffffffff
125950
221510
140150
165410
1362_T0
2528.00
59~20J)
9"610
"34X0.0
30601 J)
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
pg/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 2 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-06
RREC13-06
RREC13-07
RREC13-09
RREC13-09
RREC13-09
RREC13-09
RREC13-09
RREC13-09
RREC13-09
RREC13-06-0001
RREC13-06-0103
RREC13-07-SURF
RREC13-09-SURF
RREC13-09-0001
RREC13-09-0001-FD
RREC13-09-0103
RREC13-09-0103-FD
RREC13-09-0305
RREC13-09-0305-FD
Sample Depth (ft):
0-1
1-3
0-0.5
0-0.5
0-1
0-1
1-3
1-3
3-5
3-5
Date Sampled:
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
170 J
550 J
76 J
250 J
770 J
550 J
970 J
970 J
1200 J
1200 J
2-MethvinaDhthalene(a)(b)
NSL
NSL
490 U
800
140 J
1900 U
1700 U
1300 U
1600 U
1600 U
2200 U
2100
Acenaohthene'3'
NSL
NSL
230 J
570 J
99 J
840 J
1200 J
920 J
1300 J
1300 J
1700 J
1700
Acenaohthvlene!a'
NSL
NSL
75 J
....
57.2
845
330
1400 1
'ooo
7400
2000
3'00
V00
Benzo(a)anthracene !a'
108
1050
1-00
1000
4900
6000
4X00
5300
4300
7ooo
6600
Benzolalovrene!a'
150
1450
2600
1100
4100
4600
4000
4200
3000
5000
Benzo(b)fluoranthene!a'
NSL
NSL
1700
2900
920
4300
5300
3400
4100
3500
4500
4800
Benzo(e)Dvrene
NSL
NSL
1100
1800
660
2800
3300
2700
2800
2200
3400
3300
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
770
920
580
2100 J
2300 J
1800 J
1900 J
1400 J
3000
2600
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
1400 J
2500 J
830
3900
4200
4200
3900
2900
4800
4200
CI Chrvsenes
NSL
NSL
940 J
1900 J
590 J
2000 J
3000 J
2400 J
3100 J
2800 J
3900 J
3800 J
CI Fluorenes
NSL
NSL
77 J
300 J
35 J
1900 U
770 J
510 J
850 J
890 J
870 J
900 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
2000 J
3900 J
990 J
3600 J
6100 J
4700 J
7000 J
6300 J
8900 J
8500 J
Cl-Naohthalenes
NSL
NSL
300 J
920 J
150 J
470 J
1400 J
1000 J
1800 J
1700 J
2200 J
2200 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
1200 J
4000 J
590 J
1900 J
6800 J
5100 J
7900 J
8200 J
8300 J
8200 J
C2 Chrvsenes
NSL
NSL
840 J
2300 J
310 J
1000 J
1900 J
1800 J
2300 J
2500 J
2600 J
2800 J
C2 Fluorenes
NSL
NSL
140 J
580 J
37 J
1900 U
1100 J
740 J
1400 J
1300 J
1200 J
1200 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
980 J
2300 J
470 J
2000 J
3500 J
2700 J
3900 J
3600 J
4200 J
4300 J
C2-Naohthalenes
NSL
NSL
520 J
2700 J
310 J
470 J
5100 J
3500 J
5600 J
5700 J
6200 J
6100 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
880 J
3300 J
300 J
720 J
5300 J
3900 J
6800 J
7100 J
6400 J
6700 J
C3 Chrvsenes
NSL
NSL
280 J
750 J
120 J
280 J
840 J
670 J
1100 J
1000 J
1100 J
1100 J
C3 Fluorenes
NSL
NSL
280 J
1100 J
69 J
1900 U
2100 J
1400 J
2700 J
2700 J
2300 J
2500 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
490 J
1300 J
230 J
790 J
2100 J
1400 J
2300 J
2400 J
2400 J
2700 J
C3-Naohthalenes
NSL
NSL
720 J
4200 J
270 J
400 J
8300 J
5300 J
9700 J
9800 J
8400 J
8400 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
880 J
3000 J
210 J
550 J
5400 J
3800 J
7600 J
7300 J
7200 J
7900 J
C4 Chrvsenes
NSL
NSL
120 J
370 J
47 J
1900 U
420 J
370 J
560 J
550 J
600 J
660 J
C4-NaDhthalenes
NSL
NSL
470 J
2500 J
130 J
210 J
5700 J
3800 J
6700 J
6400 J
5900 J
6200 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
130 J
Chrvsene(a)
166
1290
ua/ks
1600
2000
930
5000
6000
4600
5400
4300
5000
Dibenzo(a,h)anthracene!a'
33
NSL
ua/ks
200.1
260 .1
170 J
520 .1
570 .1
510 .1
400 .1
360 .1
880 .1
""O.I
Fluoranthene!a'
423
2230
ua/ks
3400
6100
1600
12000
14000
11000
11000
11000
14000
12000
Fluorene!a'
77.4
536
3X0.1
810
170 J
"30 .1
1000
1600
2300
2600
2"00
2"00
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
ua/ks
680
830
540
1900 J
2400
Naphthalene!a'
176
561
ua/ks
1100
1000
380
1900 U
4000
3000
5800
5500
12000
Pervlene
NSL
NSL
270
I-""-'
Phenanthrene !a'
204
1170
2100
4300
970
601)0
11000
sooo
0800
11000
12000
Pyrene(a)
195
1520
2500
4200
1200
SI 00
0500
"300
8100
"100
10000 .1
0500 .1
Total PAH17 ND=1/2RL
1601.0
22800.0
20135.0
360"0.0
11034.0
50540.0
"600.0
61040.0
60440.0
63010.0
03350.0
88320.0
Total PAID 4 ND=1/2RL
1601.0
22800.0
2~40~.0
558"0.0
14185.0
-2~2ll.il
112210
86040
111490
104880
136020
131120
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
pg/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 3 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-11
RREC13-13
RREC13-13
RREC13-13
RREC13-13
RREC13-13
RREC13-14
RREC13-14
RREC13-14
RREC13-14
RREC13-11-SURF
RREC13-13-SURF
RREC13-13-0001
RREC13-13-0103
RREC13-13-0305
RREC13-13-0507
RREC13-14-SURF
?REC13-14-SURF-FI
RREC13-14-0001
RREC13-14-0103
Sample Depth (ft):
0-0.5
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-0.5
0-1
1-3
Date Sampled:
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
11/5/13
10/30/13
Analvte
TEC
PEC
Units
l-Methvlnaohthalene(b)
NSL
NSL
95 J
46 J
1100
1300
2100
6700
330 J
300 J
930
800 J
2-Methvlnaohthalene(a) 031
NSL
NSL
920 U
170 U
1600
2100
3100
10000
870 U
870 U
1100
1300
Acenaohthene'3'
NSL
NSL
140 J
58 J
460 J
340 J
980 J
4100 J
400 J
420 J
720 J
460 J
Acenaohthvlene !a'
NSL
NSL
150 J
60 J
....
2 If. J
Anthracene !a'
57.2
845
45ft J
220
940
000
4000
15000
x-0
Benzo(a)anthracene!a'
108
1050
2"00
870
2400
1500
X400
P000
3400
3500
3200
3500
Benzolalovrene !a'
150
1450
890
2200
1400
6200
13000
3500
2-00
3100
Benzo(b)fluoranthene !a'
NSL
NSL
1800
840
2200
1400
5000
8500
3300
3400
2800
2700
Benzo(e)Dvrene
NSL
NSL
1600
580
1400
1000
4200
7000
2300
2300
2000
2100
Benzo(sJi,i)pervlene !a'
NSL
NSL
us/ks
1200 J
610
1300
800
3500
5500
1700 J
1700 J
1500
2200
Benzo(k)fluoranthene!a'
NSL
NSL
us/ks
2400
640
1700
1100
4700
8400
3000
2800
2600
2600
CI Chrvsenes
NSL
NSL
1300 J
460 J
1600
1500
7800
14000
2100 J
2000 J
2100 J
2400 J
CI Fluorenes
NSL
NSL
920 U
23 J
780 J
610 J
1100 J
3100 J
270 J
280 J
700 J
690 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
2300 J
770 J
3300 J
3100 J
15000 J
32000 J
3500 J
3600 J
4000 J
4700 J
Cl-Naohthalenes
NSL
NSL
180 J
97 J
1800 J
2300 J
3500 J
12000 J
570 J
540 J
1400 J
1400 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
1200 J
380 J
5300 J
5600 J
18000 J
42000 J
3100 J
3000 J
5400 J
6600 J
C2 Chrvsenes
NSL
NSL
750 J
270 J
1400 J
1900 J
7100 J
10000 J
1300 J
1400 J
1800 J
2000 J
C2 Fluorenes
NSL
NSL
920 U
37 J
1800 J
1300 J
1700 J
3000 J
590 J
620 J
1500 J
1800 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
1100 J
410 J
2100 J
2800 J
9600 J
14000 J
2000 J
2000 J
2600 J
3300 J
C2-Naohthalenes
NSL
NSL
420 J
240 J
15000 J
13000 J
10000 J
28000 J
3500 J
3500 J
12000 J
9800 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
610 J
230 J
5000 J
5000 J
13000 J
18000 J
2400 J
2400 J
5200 J
6700 J
C3 Chrvsenes
NSL
NSL
200 J
120 J
680 J
980 J
3500 J
4300 J
520 J
560 J
850 J
880 J
C3 Fluorenes
NSL
NSL
120 J
80 J
3200 J
2500 J
4100 J
3600 J
1100 J
1100 J
2900 J
3800 J
C3-Fluoranthenes/Pvrenes
NSL
NSL
490 J
210 J
1400 J
1800 J
6100 J
7400 J
1100 J
1200 J
1800 J
2200 J
C3-Naohthalenes
NSL
NSL
400 J
210 J
22000 J
15000 J
12000 J
21000 J
5800 J
5800 J
20000 J
16000 J
C3-Phenanthrenes/Anthracenes
NSL
NSL
430 J
200 J
4500 J
4900 J
14000 J
13000 J
2100 J
2200 J
5300 J
7100 J
C4 Chrvsenes
NSL
NSL
100 J
48 J
410 J
540 J
1800 J
2100 J
250 J
260 J
470 J
550 J
C4-Naohthalenes
NSL
NSL
190 J
130 J
13000 J
7800 J
7200 J
8200 J
3400 J
3400 J
11000 J
12000 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
170 J
Chrvsene (a)
166
1290
231)0
820
2300
1600
"00
15000
3400
3400
3300
3400
Dibenzo(aJi)anthracene !a'
33
NSL
340 .1
160 J
3"0 .1
240.1
1100.1
1000.1
530.1
420.1
350.1
610.1
Fluoranthene
423
2230
1200
4600
2~00
13000
2~000
5"00
6400
6000
Fluorene !a'
77.4
536
170 .1
81J
X50
"50
2200
"100
610.1
550.1
1100
"X0.1
Indeno(l,2J3-cd)pvrene !a'
NSL
NSL
us/ks
1100
520
1200
690
2900
4400
1600
1500
1300
1900
Naphthalene !a'
176
561
270
1200
4200
5~00
870 U
870 U
830 U
1500
Pervlene
NSL
NSL
240
Phenanthrene!a'
204
1170
1900
590
3600
3000
11000
391)00
3500
3300
4900
4300
Pyrene (a)
195
1520
3500
990 J
3500
2600
11000
2~000
4100
4200
4"00
5300 .1
Total PAH17 ND=1/2RL
1601.0
22800.0
26470.0
8904.00
310X0.0
22200.0
X9XO0.0
210200
36"60J)
36550.0
3X465J)
40990Jl
Total PAH34 ND=1/2RL
1601.0
22800.0
34220.0
11529.0
5X410
4 0.0
16XX00
332~00
54095J)
54215.0
6X555
"X1X0
NOTES
Presented results are not normalized to organic carbon
w Included in calculation oftotal 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
lig/kg = Micrograms per kilogram
NSI^No screening level
TEC = Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC =Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 4 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-14
RREC13-14
RREC13-14
RREC13-15
RREC13-15
RREC13-15
RREC13-16
RREC13-16
RREC13-16
RREC13-16
Sample Name:
RREC13-14-0305
RREC13-14-0507
RREC13-14-0710
RREC13-15-SURF
RREC13-15-0001
RREC13-15-0103
RREC13-16-SURF
RREC13-16-0001
RREC13-16-0103
RREC13-16-0305
Sample Depth (ft):
3-5
5-7
7-10
0-0.5
0-1
1-3
0-0.5
0-1
1-3
3-5
Date Sampled:
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
11/5/13
10/29/13
10/31/13
10/31/13
10/31/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
1000 J
810 J
440 J
440 J
510 J
200 J
1100 J
100 J
30 J
7.5
2-MethvinaDhthalene(a)(b)
NSL
NSL
1700
1300
710 J
1000 U
950 U
420 U
1000 J
160 J
42 J
9.2
Acenaohthene'3'
NSL
NSL
600 J
540 J
700 J
580 J
860 J
310 J
740 J
320 J
56 J
2.1 J
Acenaohthvlene!a'
NSL
NSL
....
....
....
...
.....
93 U
4 U
Anthracene !a'
57.2
845
1-00
1200
2000
1-00
1600
620
6600
640
92 J
5.2
Benzo(a)anthracene !a'
108
1050
4700
3700
1200
290
18
Benzolalovrene!a'
150
1450
351)1)
241)0
4000
3200
3000
22000
1X00
210
14
Benzo(b)fluoranthene!a'
NSL
NSL
2900
2700
3700
3000
2900
950
22000
1700
240
17
Benzo(e)Dvrene
NSL
NSL
2300
2100
2500
2100
2000
630
14000
1600
210
19
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
2100
1900
2200
1400 J
1600
440
10000
1400
190
22
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
2700
2100
3300
2800
2500
790
20000
1400
180
9.4
CI Chrvsenes
NSL
NSL
3300 J
2700 J
2800
2500 J
2400 J
770 J
14000 J
3300 J
650 J
60 J
CI Fluorenes
NSL
NSL
940 J
810 J
510 J
450 J
580 J
180 J
1100 J
310 J
65 J
13 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
6200 J
5000 J
5700 J
4500 J
4700 J
1600 J
28000 J
3200 J
640 J
56 J
Cl-Naohthalenes
NSL
NSL
1800 J
1400 J
800 J
840 J
970 J
360 J
1400 J
200 J
55 J
13 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
10000 J
8400 J
6100 J
5000 J
6000 J
1900 J
18000 J
3500 J
790 J
140 J
C2 Chrvsenes
NSL
NSL
3400 J
2400 J
2300 J
1800 J
2100 J
630 J
16000 J
3300 J
790 J
91 J
C2 Fluorenes
NSL
NSL
2400 J
1800 J
1000 J
960 J
1200 J
340 J
1800 J
790 J
170 J
32 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
4800 J
3700 J
3400 J
2900 J
3100 J
940 J
17000 J
4200 J
890 J
82 J
C2-Naohthalenes
NSL
NSL
12000 J
9900 J
3600 J
2900 J
4100 J
1200 J
8200 J
1700 J
470 J
80 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
9800 J
7600 J
5600 J
4900 J
5900 J
1700 J
13000 J
4800 J
1200 J
160 J
C3 Chrvsenes
NSL
NSL
1600 J
1200 J
880 J
840 J
990 J
260 J
7700 J
2000 J
450 J
57 J
C3 Fluorenes
NSL
NSL
4400 J
3400 J
2400 J
1900 J
2700 J
650 J
3000 J
2100 J
440 J
69 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
3400 J
2600 J
2200 J
1900 J
2200 J
590 J
10000 J
3700 J
800 J
77 J
C3-Naohthalenes
NSL
NSL
20000 J
16000 J
7000 J
6200 J
7900 J
2400 J
10000 J
4600 J
1300 J
240 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
9600 J
7300 J
5900 J
5100 J
7300 J
1900 J
12000 J
6900 J
1700 J
210 J
C4 Chrvsenes
NSL
NSL
810 J
640 J
520 J
480 J
550 J
120 J
2900 J
1000 J
200 J
24 J
C4-Naohthalenes
NSL
NSL
13000 J
10000 J
6000 J
4800 J
6800 J
1600 J
5500 J
3400 J
1100 J
260 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
l3'-"~i.T
100 J
150 J
Chrvsene(a)
166
1290
us/ks
3*00
3200
4400
3"00
3500
1200
1X000
2200
$60
37
Dibenzo(a,h)anthracene!a'
33
NSL
550.1
440.1
OOO.I
410 .1
450 .1
110.1
2XOO.I
500
S7 J
5.4
Fluoranthene!a'
423
2230
5900
9200
"300
"200
2500
3"000
2400
370
20
Fluorene!a'
77.4
536
1100.1
910.1
1200.1
1000
1400
550
3600.1
330 .1
'6 J
6.2
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
us/ks
1700
1500
1900
1300
1500
380 J
9400
150
11
Naphthalene!a'
176
561
us/ks
1100 U
930 U
1400
1"00
2200
"20
4600 U
490 U
'3 U
4 U
Pervlene
NSL
NSL
900 J
'6 3
11
Phenanthrene !a'
204
1170
(>300
5000
6X00
5300
6500
2200
22000
1500
280
25
Pyrene(a)
195
1520
5900 .1
5000
0600
4"00
5000.1
1X00
24000
3200
530
34
Total PAH17 ND=1/2RL
1601.0
22800.0
46510.0
3X495M
536X0.1)
42530.0
446X5.0
14X54.0
226X40
21040.0
3216.00
239.500
Total PAID 4 ND=1/2RL
1601.0
22800.0
96911)
"9005
XX2X0
~15~0.0
X02X0
25034J)
330340
496X0.0
9665.0
1090.30
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
pg/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 5 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-16
RREC13-16
RREC13-16
RREC13-17
RREC13-17
RREC13-17
RREC13-17
RREC13-17
RREC13-17
RREC13-17
Sample Name:
RREC13-16-0507
RREC13-16-0709
RREC13-16-0911
RREC13-17-SURF
RREC13-17-0001
RREC13-17-0103
RREC13-17-0305
RREC13-17-0507
RREC13-17-0709
RREC13-17-0911
Sample Depth (ft):
5-7
7-9
9-11
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
Date Sampled:
10/31/13
10/31/13
10/31/13
10/29/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
Analvte
TEC
PEC
Units
l-Methvlnaohthalene(b)
NSL
NSL
14
10
8
120 J
370 U
660 U
1500 U
3700
1100 U
1800 U
2-Methvlnaohthalene(a) 031
NSL
NSL
19
14
11
190 J
370 U
660 U
1600
4000
1000 J
2000
Acenaohthene'3'
NSL
NSL
4.3 J
3 U
4 U
76 J
160 J
370 J
1100 J
2000 J
440 J
580 J
Acenaohthvlene !a'
NSL
NSL
8 U
3 U
1.6 J
47 J
Anthracene !a'
57.2
845
11
3 U
1.7 J
230 J
430
920
3200
9200
1400
1X00
Benzo(a)anthracene!a'
108
1050
25
3 U
3.1 J
1400
2500
4700
6300
3600
4700
Benzolalovrene !a'
150
1450
19
2 J
1.8 J
1200
1900
3000
4100
2600
3000
Benzo(b)fluoranthene !a'
NSL
NSL
25
5
5.7
1300
1500
1900
3300
4200
2300
2500
Benzo(e)Dvrene
NSL
NSL
26
8.1
9.9
880
1200
1600
2500
3600
2300
3500
Benzo(sJi,i)pervlene !a'
NSL
NSL
us/ks
25
14
4.6
610
1000
1200
1800
2300 U
1400
1800 U
Benzo(k)fluoranthene!a'
NSL
NSL
us/ks
13
3 U
4 U
1100
1300
1800
2600
3800
2300
2100
CI Chrvsenes
NSL
NSL
83 J
34 J
28 J
820 J
1600 J
3600 J
6200 J
9100 J
6200 J
11000 J
CI Fluorenes
NSL
NSL
21 J
18 J
15 J
54 J
120 J
480 J
1100 J
2300 J
610 J
1200 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
73 J
26 J
36 J
1300 J
1700 J
4200 J
7800 J
13000 J
7000 J
13000 J
Cl-Naohthalenes
NSL
NSL
24 J
19 J
14 J
200 J
200 J
320 J
2100 J
5400 J
1300 J
2500 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
230 J
180 J
110 J
700 J
1200 J
4200 J
9900 J
18000 J
7600 J
16000 J
C2 Chrvsenes
NSL
NSL
130 J
63 J
100 J
810 J
1700 J
4600 J
7400 J
10000 J
6500 J
12000 J
C2 Fluorenes
NSL
NSL
47 J
37 J
29 J
93 J
290 J
1400 J
2700 J
4200 J
1400 J
2800 J
C2-Fluoranthenes/Pvrenes
NSL
NSL
110 J
47 J
59 J
890 J
1800 J
4900 J
8600 J
12000 J
7300 J
13000 J
C2-Naohthalenes
NSL
NSL
150 J
95 J
78 J
710 J
880 J
3100 J
13000 J
35000 J
6300 J
12000 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
250 J
160 J
110 J
650 J
1900 J
7900 J
17000 J
21000 J
10000 J
17000 J
C3 Chrvsenes
NSL
NSL
72 J
40 J
55 J
450 J
820 J
2400 J
4800 J
6400 J
3800 J
6400 J
C3 Fluorenes
NSL
NSL
100 J
69 J
47 J
240 J
810 J
3600 J
6900 J
8800 J
3700 J
5600 J
C3-Fluoranthenes/Pvrenes
NSL
NSL
120 J
53 J
68 J
650 J
1400 J
4100 J
8000 J
9800 J
5300 J
9300 J
C3-Naohthalenes
NSL
NSL
430 J
280 J
270 J
830 J
1400 J
7800 J
19000 J
40000 J
7700 J
13000 J
C3-Phenanthrenes/Anthracenes
NSL
NSL
270 J
100 J
210 J
950 J
2500 J
11000 J
21000 J
22000 J
12000 J
16000 J
C4 Chrvsenes
NSL
NSL
32 J
18 J
26 J
180 J
460 J
1500 J
2800 J
3500 J
2100 J
3400 J
C4-Naohthalenes
NSL
NSL
430 J
350 J
340 J
560 J
1400 J
8500 J
16000 J
25000 J
6400 J
9800 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
180 J
100 J
140 J
780 J
Chrvsene (a)
166
1290
us/ks
48
20
16
1200
1600
2X00
5000
6600
3900
4~00
Dibenzo(aJi)anthracene !a'
33
NSL
us/ks
5.5 J
2.2 J
0.59 J
160 J
350 .1
440 .1
010 .1
910 .1
540 .1
660 .1
Fluoranthene
423
2230
us/ks
34
3 U
4 U
1600
1X00
3300
"300
9X00
4100
4200
Fluorene !a'
77.4
536
us/ks
7.6 J
2.8 J
4.2
130 J
2"0 .1
"0
2200
3S00
1800 U
Indeno(l,2J3-cd)pvrene !a'
NSL
NSL
us/ks
12
1.9 J
0.61 J
590
930
2300 U
1800 U
Naphthalene !a'
176
561
us/ks
8 U
3 U
4 U
2901
370 U
660 U
2000
2300 U
1800 U
Pervlene
NSL
NSL
13
7.2
6.6
350
Phenanthrene!a'
204
1170
48
27
26
750
1200
2100
6400
11000
3000
5X00
Pyrene (a)
195
1520
50
8.2
7.2
1500
2300
4X00
9400
13000
6200
9900
Total PAH17 ND=1/2RL
1601.0
22800.0
354.400
107.600
92.1000
11928.0
10205.0
26SOO.O
56660.0
X3310.0
35630.0
46440.0
Total PAH34 ND=1/2RL
1601.0
22800.0
1545.40
798.90
794.60
17735.0
2X040.0
09X00
13XX50
1X9310
XX050
131150
NOTES
Presented results are not normalized to organic carbon
w Included in calculation oftotal 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
lig/kg = Micrograms per kilogram
NSI^No screening level
TEC = Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC =Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 6 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-18
RREC13-18
RREC13-18
RREC13-18
RREC13-18
RREC13-18
RREC13-18
RREC13-19
RREC13-19
RREC13-20
RREC13-18-SURF
RREC13-18-0001
RREC13-18-0103
RREC13-18-0305
RREC13-18-0507
RREC13-18-0709
RREC13-18-0911
RREC13-19-SURF
RREC13-19-0001
RREC13-20-SURF
Sample Depth (ft):
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
0-1
0-0.5
Date Sampled:
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/29/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
130 J
68 J
210 J
710
100 J
21 J
6.1 J
92 J
170 U
51 J
2-MethvinaDhthalene(a)(b)
NSL
NSL
210 J
230 U
1000 U
860
340 U
56 U
23 U
130 J
84 J
82 J
Acenaohthene'3'
NSL
NSL
92 J
110 J
820 J
490 J
180 J
24 J
9.6 J
59 J
96 J
34 J
Acenaohthvlene!a'
NSL
NSL
52 J
....
16 J
8.8 J
40 J
170 U
21 J
Anthracene !a'
57.2
845
300 J
320
2400
530
73
43
190
210
130
Benzo(a)anthracene !a'
108
1050
1200
1200
2»00
210
93
710
610
410
Benzolalovrene!a'
150
1450
1300
2200
2000
1500
150
73
700
460
400
Benzo(b)fluoranthene!a'
NSL
NSL
1300
1400
2100
1800
1300
140
67
670
520
400
Benzo(e)Dvrene
NSL
NSL
880
940
1600
1500
1000
110
52
480
420
270
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
590
770
1100
820
650
68
39
300
350
180
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
1200
1000
1800
1700
1100
120
55
590
400
370
CI Chrvsenes
NSL
NSL
880 J
920 J
3100 J
4100 J
2700 J
250 J
98 J
600 J
770 J
270 J
CI Fluorenes
NSL
NSL
60 J
56 J
490 J
430 J
210 J
24 J
12 J
53 J
100 J
30 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
1400 J
1400 J
5400 J
6400 J
3900 J
430 J
170 J
970 J
940 J
520 J
Cl-Naohthalenes
NSL
NSL
230 J
120 J
320 J
1000 J
170 J
31 J
9.4 J
150 J
100 J
87 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
850 J
860 J
5900 J
6900 J
3600 J
390 J
170 J
660 J
940 J
370 J
C2 Chrvsenes
NSL
NSL
900 J
870 J
4000 J
4900 J
2900 J
320 J
140 J
670 J
830 J
250 J
C2 Fluorenes
NSL
NSL
100 J
130 J
1000 J
930 J
520 J
51 J
21 J
100 J
260 J
40 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
880 J
1000 J
4800 J
5600 J
3100 J
330 J
120 J
770 J
920 J
300 J
C2-Naohthalenes
NSL
NSL
760 J
490 J
4100 J
5300 J
1500 J
210 J
71 J
600 J
700 J
320 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
760 J
800 J
6400 J
7100 J
3900 J
390 J
160 J
630 J
1600 J
280 J
C3 Chrvsenes
NSL
NSL
440 J
450 J
2100 J
2500 J
1300 J
160 J
67 J
400 J
500 J
120 J
C3 Fluorenes
NSL
NSL
270 J
330 J
2700 J
2500 J
1400 J
120 J
51 J
230 J
660 J
86 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
670 J
740 J
3900 J
4500 J
2400 J
250 J
94 J
580 J
730 J
190 J
C3-Naohthalenes
NSL
NSL
840 J
640 J
7500 J
6100 J
2500 J
310 J
160 J
860 J
1600 J
460 J
C3-Phenanthrenes/Anthracenes
NSL
NSL
900 J
1000 J
9300 J
8000 J
4200 J
420 J
150 J
770 J
1900 J
310 J
C4 Chrvsenes
NSL
NSL
160 J
150 J
1100 J
1200 J
640 J
71 J
31 J
160 J
270 J
47 J
C4-Naohthalenes
NSL
NSL
560 J
480 J
5600 J
4200 J
2500 J
250 J
160 J
660 J
1500 J
360 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
720 J
800 J
300 J
130 J
540 J
1300 J
190 J
Chrvsene(a)
166
1290
1300
1200
2900
2700
200
89
700
660
410
Dibenzo(a,h)anthracene!a'
33
NSL
150 J
220 J
310 .1
290.1
220.1
19 J
10 J
91 J
120 J
49 J
Fluoranthene!a'
423
2230
us/ks
1900
2000
5600
4400
320
170
890
800
630
Fluorene!a'
77.4
536
us/ks
150 J
160 J
1100
720
210.1
43 J
23 J
110 J
170
59 J
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
us/ks
560
680
940 J
730
560
54 J
30
280
300
170
Naphthalene!a'
176
561
us/ks
340 U
230 U
640 U
340 U
56 U
23 U
170
170 U
120
Pervlene
NSL
NSL
370
350
51 J
29
190
150 J
120
Phenanthrene !a'
204
1170
850
930
4800
3000
1400
180
78
510
590
320
Pyrene(a)
195
1520
1500
1500
4800
4100
2300
300
140
790
1000
550
Total PAH17 ND=1/2RL
1601.0
22800.0
12824.0
13089.0
34930.0
28110.0
10*10.0
1973.00
951.400
6930.00
6540.00
4335.00
Total PAID 4 ND=1/2RL
1601.0
22800.0
18924.0
19640.0
"3810
6"?10.0
38430M
4231.00
1884.90
11423.0
14726.0
6469.00
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
pg/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 7 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-20
RREC13-20
RREC13-20
RREC13-21
RREC13-21
RREC13-21
RREC13-21
RREC13-21
RREC13-21
RREC13-21
Sample Name:
RREC13-20-0001
RREC13-20-0103
RREC13-20-0305
RREC13-21-SURF
RREC13-21-0001
RREC13-21-0001-FD
RREC13-21-0103
RREC13-21-0103-FD
RREC13-21-0305
RREC13-21-0305-FD
Sample Depth (ft):
Date Sampled:
0-1
1-3
3-5
0-0.5
0-1
0-1
1-3
1-3
3-5
3-5
11/1/13
11/1/13
11/1/13
10/29/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
9.9
11
8.6
86 J
99 J
83 J
250 J
370 J
920 J
1100 J
2-MethvinaDhthalene(a)(b)
NSL
NSL
13
14
10
150 J
100 J
310 U
310 U
400 U
1200
1400 U
Acenaohthene'3'
NSL
NSL
3 J
1.4 J
1.7 J
79 J
130 J
100 J
140 J
240 J
640 J
770 J
Acenaohthvlene!a'
NSL
NSL
2.2 J
4.1 U
4 U
45 J
310 U
61 J
62 J
— -
Anthracene !a'
57.2
845
4.3
3.2 J
1.9 J
190 J
310
150 J
230 J
3IIII .1
"II .1
900 .1
Benzo(a)anthracene !a'
108
1050
16
7.2
3 J
880
HOfl
800
960
1200
2200
2900
Benzolalovrene!a'
150
1450
15
6.9
3.5 J
1000
1100
840
830
1100
1X00
2300
Benzo(b)fluoranthene!a'
NSL
NSL
22
11
7.4
1500
1000
1000
900
1200
1900
2400
Benzo(e)Dvrene
NSL
NSL
17
13
9.8
930
970
690
670
880
1400
1700
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
11
8.5
7
540
1200 J
390 J
330 J
450
860 J
1000 J
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
16
4.2
1.5 J
1000
920
850
690
1100
1600
2000
CI Chrvsenes
NSL
NSL
31 J
32 J
27 J
930 J
1200 J
860 J
1400 J
1600 J
2200 J
2500 J
CI Fluorenes
NSL
NSL
15 J
17 J
14 J
77 J
140 J
120 J
290 J
420 J
1100 J
1200 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
42 J
39 J
32 J
1300 J
1500 J
1300 J
2100 J
2900 J
4000 J
5200 J
Cl-Naohthalenes
NSL
NSL
17 J
17 J
13 J
160 J
150 J
120 J
290 J
430 J
1500 J
1600 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
150 J
170 J
150 J
880 J
1500 J
1200 J
3200 J
4300 J
9300 J
11000 J
C2 Chrvsenes
NSL
NSL
110 J
100 J
95 J
1500 J
1300 J
1400 J
2900 J
3700 J
3800 J
5000 J
C2 Fluorenes
NSL
NSL
27 J
34 J
27 J
180 J
400 J
360 J
980 J
1400 J
2600 J
2900 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
57 J
61 J
55 J
1400 J
1500 J
1400 J
2600 J
3300 J
4300 J
5400 J
C2-Naohthalenes
NSL
NSL
91 J
92 J
83 J
650 J
1100 J
960 J
3300 J
5000 J
15000 J
17000 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
120 J
150 J
130 J
1300 J
1900 J
1800 J
4600 J
6700 J
10000 J
13000 J
C3 Chrvsenes
NSL
NSL
49 J
60 J
50 J
810 J
740 J
740 J
1500 J
1700 J
2500 J
3200 J
C3 Fluorenes
NSL
NSL
47 J
53 J
48 J
600 J
1100 J
1100 J
2600 J
3800 J
5900 J
6600 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
62 J
69 J
59 J
1300 J
1400 J
1200 J
3200 J
3300 J
4500 J
5600 J
C3-Naohthalenes
NSL
NSL
350 J
370 J
330 J
830 J
2500 J
2200 J
6400 J
9500 J
25000 J
27000 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
150 J
120 J
160 J
1600 J
3000 J
2400 J
6900 J
8700 J
11000 J
14000 J
C4 Chrvsenes
NSL
NSL
21 J
24 J
22 J
370 J
330 J
210 J
610 J
1000 J
1200 J
1700 J
C4-Naohthalenes
NSL
NSL
310 J
390 J
320 J
1000 J
2100 J
1900 J
5500 J
7800 J
17000 J
18000 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
100 J
110 J
100 J
1600 J
2400 J
1700 J
5000 J
Chrvsene(a)
166
1290
29
23
20
1000
1300
920
1200
1500
2300
2900
Dibenzo(a,h)anthracene!a'
33
NSL
us/ks
1.7 J
1.1 J
0.8 J
130 J
370 J
100 J
79 J
lilt .1
210 .1
250 .1
Fluoranthene!a'
423
2230
us/ks
23
8.6
4.2
1700
1500
1600
1700
2400
6600
9900
Fluorene!a'
77.4
536
us/ks
5.6
4.4
3.8 J
98 J
180 J
150 J
270 J
3211.1
1200
1400.1
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
us/ks
4.9
2.3 J
1.2 J
480
1000
380
310
410
750 J
860 J
Naphthalene!a'
176
561
us/ks
11
8
4 U
300 U
310 U
310 U
310 U
400 U
1400 U
Pervlene
NSL
NSL
10
9
7.9
370
340
320
510
Phenanthrene !a'
204
1170
32
36
33
680
1000
760
1100 1400
5900
"200
Pyrene(a)
195
1520
21
12
8.5
1300
2200
1300
1X00 2300
4900
6X00
Total PAH17 ND=1/2RL
1601.0
22800.0
230.700
153.850
111.500
10922.0
13720.0
9711.00
10011.0 145ll~.lt
33600.0
43190.0
Total PAID 4 ND=1/2RL
1601.0
22800.0
895.70
854.85
780.20
19609.0
26870.0
20546.0
57476.0 5041".!)
X6090
10X530
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
pg/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline Assessment of Contaminated Sediments
Detroit River Area of Concern, Wayne County, Michigan Page 8 of 26 Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-21
RREC13-21
RREC13-21
RREC13-21
RREC13-21
RREC13-21
RREC13-22
RREC13-22
RREC13-22
RREC13-22
Sample Name:
RREC13-21-0507
RREC13-21-0507-FD
RREC13-21-0709
RREC13-21-0709-FD
RREC13-21-0911
RREC13-21-0911-FD
RREC13-22-SURF
RREC13-22-0001
RREC13-22-0103
RREC13-22-0305
Sample Depth (ft):
5-7
5-7
7-9
7-9
9-11
9-11
0-0.5
0-1
1-3
3-5
Date Sampled:
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
10/29/13
11/1/13
11/1/13
11/1/13
Analvte
TEC
PEC
Units
l-Methvlnaohthalene(b)
NSL
NSL
550 J
630 J
270 J
180 J
21
17
82 J
86 J
140 J
450 J
2-Methvlnaohthalene(a) 031
NSL
NSL
1100 U
850 U
460 U
340 U
31
23
150 J
130 J
160 J
530 J
Acenaohthene'3'
NSL
NSL
440 J
480 J
190 J
120 J
4.4 J
5.6 J
100 J
150 J
280 J
370 J
Acenaohthvlene !a'
NSL
NSL
150 J
130 J
59 J
39 J
6.9 U
2.1 J
67 J
65 J
110 J
130 J
Anthracene !a'
57.2
845
"Oft J
"00 J
4S0
320 J
8.2
13 J
360
430 .T
5-0
560 .T
Benzo(a)anthracene!a'
108
1050
'000
2"00
950
24
35
Benzolalovrene !a'
150
1450
2400
2300
1100
710
18
26
1500
roo
2300
1500
Benzo(b)fluoranthene !a'
NSL
NSL
2600
2300
1200
790
23
31
1500
1600
2100
1700
Benzo(e)Dvrene
NSL
NSL
1800
1700
820
520
22
25
980
1200
1600
1200
Benzo(sJi,i)pervlene !a'
NSL
NSL
us/ks
1200 J
1100
470 J
330 J
15
19
660
940
1000
660
Benzo(k)fluoranthene!a'
NSL
NSL
us/ks
2100
2100
990
650
16
24
1300
1600
2100
1300
CI Chrvsenes
NSL
NSL
2600 J
2700 J
1600 J
1100 J
47 J
57 J
900 J
1100 J
2000 J
2200 J
CI Fluorenes
NSL
NSL
670 J
830 J
280 J
190 J
20 J
20 J
77 J
84 J
370 J
790 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
5000 J
5300 J
2900 J
1800 J
69 J
88 J
1700 J
1800 J
3300 J
3800 J
Cl-Naohthalenes
NSL
NSL
730 J
790 J
440 J
290 J
34 J
26 J
160 J
150 J
220 J
690 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
7100 J
8300 J
3300 J
2200 J
220 J
220 J
1000 J
1200 J
4300 J
9000 J
C2 Chrvsenes
NSL
NSL
4100 J
4600 J
2500 J
1600 J
130 J
120 J
840 J
1100 J
2500 J
3700 J
C2 Fluorenes
NSL
NSL
1800 J
2000 J
650 J
430 J
41 J
41 J
160 J
190 J
1200 J
2600 J
C2-Fluoranthenes/Pvrenes
NSL
NSL
4700 J
5500 J
2600 J
1700 J
87 J
100 J
980 J
1200 J
2700 J
4100 J
C2-Naohthalenes
NSL
NSL
7400 J
9300 J
2700 J
1800 J
180 J
190 J
580 J
600 J
2500 J
7000 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
8300 J
10000 J
4100 J
2800 J
200 J
220 J
970 J
1100 J
5200 J
12000 J
C3 Chrvsenes
NSL
NSL
2100 J
2400 J
1300 J
850 J
63 J
57 J
430 J
470 J
1200 J
2100 J
C3 Fluorenes
NSL
NSL
3900 J
5000 J
1500 J
1100 J
74 J
89 J
410 J
600 J
3100 J
6200 J
C3-Fluoranthenes/Pvrenes
NSL
NSL
3800 J
4500 J
2100 J
1400 J
92 J
97 J
730 J
830 J
2300 J
4000 J
C3-Naohthalenes
NSL
NSL
14000 J
17000 J
5600 J
3700 J
520 J
460 J
790 J
950 J
7000 J
17000 J
C3-Phenanthrenes/Anthracenes
NSL
NSL
10000 J
12000 J
5100 J
3100 J
230 J
250 J
1200 J
1400 J
5400 J
12000 J
C4 Chrvsenes
NSL
NSL
1000 J
1100 J
530 J
390 J
27 J
28 J
150 J
190 J
630 J
1100 J
C4-Naohthalenes
NSL
NSL
11000 J
13000 J
4100 J
2900 J
450 J
450 J
820 J
980 J
6300 J
15000 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
1900 J
140 J
150 J
920 J
1000 J
3900 J
8100 J
Chrvsene (a)
166
1290
2800
2900
1500
950
36
48
1400
...jSftD
2200
2100
Dibenzo(aJi)anthracene !a'
33
NSL
300.1
270.1
140.1
100 J
2.5 J
3.7 J
170 J
240 J
310 J
180 J
Fluoranthene
423
2230
6800
6500
2900
1900
43
70
2100
2600
Fluorene !a'
77.4
536
830 J
670 J
370.1
220 J
13
10 J
150 J
180 J
420 J
450 J
Indeno(l,2J3-cd)pvrene !a'
NSL
NSL
960
440 J
290 J
6 J
12 J
640
860
960
620 J
Naphthalene !a'
176
561
850 U
460 U
340 U
11
13 U
320 U
450 U
510 U
650 U
Pervlene
NSL
NSL
210 J
14
16
710
Phenanthrene!a'
204
1170
4000
3900
1600
1000
60
66
1300
2400
Pyrene (a)
195
1520
5400
5400
2300
1500
37
60
1.800
2000
3000
3100
Total PAH17 ND=1/2RL
1601.0
22800.0
34820.0
33260M
15699.11
10209.0
351.550
454.900
14427.0
1"420.0
23965.0
21X25.0
Total PAH34 ND=1/2RL
1601.0
22800.0
80350
80515
3"649.0
242X9.1)
1350.55
1550.90
22124.0
26364.0
52885.0
NOTES
Presented results are not normalized to organic carbon
w Included in calculation oftotal 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
lig/kg = Micrograms per kilogram
NSI^No screening level
TEC = Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC =Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 9 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-22
RREC13-22
RREC13-22
RREC13-23
RREC13-23
RREC13-23
RREC13-23
RREC13-23
RREC13-23
RREC13-23
RREC13-22-0507
RREC13-22-0709
RREC13-22-0911
RREC13-23-SURF
RREC13-23 -0001
RREC13-23-0103
RREC13-23 -0305
RREC13-23-0507
RREC13-23 -0709
RREC13-23 -0911
Sample Depth (ft):
5-7
7-9
9-11
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
Date Sampled:
11/1/13
11/1/13
11/1/13
10/30/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
Analvte
TEC
PEC
Units
l-Methvlnaohthalene(b)
NSL
NSL
490 J
270 J
400 J
230 J
380
970
1000
1600
1400 U
1400 U
2-Methvlnaohthalene(a) 031
NSL
NSL
750
300 J
320 J
370 J
540
1500
1500
2600
1400 U
1400 U
Acenaohthene'3'
NSL
NSL
260 J
340 J
480 J
310 J
320 J
630 J
650 J
2200
590 J
760 J
Acenaohthvlene !a'
NSL
NSL
Anthracene !a'
57.2
845
flit .1
Milt .1
1600
111)0
550
9X1)
1300
1X00
Benzo(a)anthracene!a'
108
1050
201)1)
2500
3300
1900
2X00
3000
3300
3X00
4500
Benzolalovrene !a'
150
1450
2300
roo
3000
1900
2200
2500
2500
3200
3X00
Benzo(b)fluoranthene !a'
NSL
NSL
1600
2100
1200
2800
2100
2200
2200
2300
2700
3300
Benzo(e)Dvrene
NSL
NSL
1300
1600
1100
2100
1600
1900
2100
2100
2400
2800
Benzo(sJi,i)pervlene !a'
NSL
NSL
us/ks
780
1000
700
1400
1700
2000
2100
1900
2200
2700
Benzo(k)fluoranthene!a'
NSL
NSL
us/ks
1500
2300
1300
3000
1300
1700
1900
2400
2900
2800
CI Chrvsenes
NSL
NSL
2900 J
2400 J
2600 J
2200 J
2000 J
3500 J
4000 J
3800 J
3700 J
3800 J
CI Fluorenes
NSL
NSL
910 J
450 J
450 J
220 J
390 J
1100 J
1100 J
1000 J
670 J
810 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
4700 J
4700 J
5200 J
4100 J
2600 J
4400 J
4700 J
5200 J
4800 J
5500 J
Cl-Naohthalenes
NSL
NSL
830 J
380 J
500 J
400 J
680 J
1800 J
1800 J
3100 J
1000 J
1300 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
11000 J
5400 J
6500 J
3200 J
3700 J
9500 J
10000 J
9700 J
7800 J
8400 J
C2 Chrvsenes
NSL
NSL
4800 J
2800 J
2300 J
2100 J
1700 J
3500 J
4100 J
4000 J
3600 J
3700 J
C2 Fluorenes
NSL
NSL
2900 J
1100 J
620 J
520 J
960 J
3300 J
3100 J
2500 J
1800 J
1800 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
5300 J
3700 J
2900 J
2500 J
2100 J
4800 J
5000 J
4700 J
4200 J
4200 J
C2-Naohthalenes
NSL
NSL
8900 J
3400 J
4400 J
1900 J
3900 J
12000 J
13000 J
11000 J
5900 J
6700 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
14000 J
6400 J
4100 J
2900 J
4200 J
12000 J
12000 J
11000 J
10000 J
10000 J
C3 Chrvsenes
NSL
NSL
2500 J
1300 J
1100 J
790 J
820 J
2100 J
2200 J
2000 J
1700 J
1700 J
C3 Fluorenes
NSL
NSL
6500 J
2800 J
1100 J
1200 J
2100 J
7800 J
7100 J
5100 J
4400 J
4400 J
C3-Fluoranthenes/Pvrenes
NSL
NSL
4900 J
2600 J
1800 J
1600 J
1600 J
4000 J
4000 J
3500 J
3700 J
3600 J
C3-Naohthalenes
NSL
NSL
20000 J
7300 J
4400 J
3000 J
6200 J
22000 J
22000 J
18000 J
12000 J
13000 J
C3-Phenanthrenes/Anthracenes
NSL
NSL
14000 J
7300 J
4100 J
3200 J
3900 J
14000 J
12000 J
9900 J
10000 J
9900 J
C4 Chrvsenes
NSL
NSL
1100 J
580 J
520 J
300 J
400 J
1200 J
1100 J
1000 J
950 J
950 J
C4-Naohthalenes
NSL
NSL
16000 J
6800 J
2500 J
2400 J
4800 J
18000 J
16000 J
13000 J
11000 J
11000 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
0-1111 .1
Chrvsene (a)
166
1290
2000
2000
2300
3100
2100
3100
3300
3-|)0
4000
4600
Dibenzo(aJi)anthracene !a'
33
NSL
230 .1
310 .1
210 .1
3X0 .1
5011
630.1
6X0 .1
5"0.l
620.1
Fluoranthene
423
2230
3000
5300
301)0
5400
201)0
4300
4400
5200
6-00
JPOO
Fluorene !a'
77.4
536
430 .1
"60 .1
"30
4"0 .1
4X0
1000
0X0
2400
'600
Indeno(l,2J3-cd)pvrene !a'
NSL
NSL
us/ks
970
610 J
1600
1600
Naphthalene !a'
176
561
us/ks
640 U
940 U
680 U
660 U
"SO
2000
1300
1400
1400 U
Pervlene
NSL
NSL
560 J
Phenanthrene!a'
204
1170
3100
4000
2~00
2400
4300
4-|)0
6200
6100
6"00
Pyrene (a)
195
1520
us/ks 1 3400
4300
4300
4100
3600
5X00
5"l)0
6200
"1)00
X300
Total PAH17 ND=1/2RL
1601.0
22800.0
us/ks 1 22~IHt.lt
30250.0
26300.0
33120.0
24945.0
3"235.0
3X305.0
46X20.0
4-510.0
55X40.0
Total PAH34 ND=1/2RL
1601.0
22800.0
65500.0
52140.0
53220.0
4-0X5.0
09355
0"525
0X0"0
06550
106550
NOTES
Presented results are not normalized to organic carbon
w Included in calculation oftotal 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
lig/kg = Micrograms per kilogram
NSI^No screening level
TEC = Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC =Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 10 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-24
RREC13-24
RREC13-24
RREC13-25
RREC13-25
RREC13-25
RREC13-25
RREC13-25
RREC13-25
RREC13-26
Sample Name:
RREC13-24-SURF
RREC13-24-0001
RREC13-24-0103
RREC13-25-SURF
RREC13-25-0001
RREC13-25-0103
RREC13-25-0305
RREC13-25-0507
RREC13-25-0710
RREC13-26-SURF
Sample Depth (ft):
0-0.5
0-1
1-3
0-0.5
0-1
1-3
3-5
5-7
7-10
0-0.5
Date Sampled:
10/30/13
11/4/13
11/4/13
10/30/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
Analvte
TEC
PEC
Units
l-Methvlnaohthalene 031
NSL
NSL
1300 U
92 J
42 J
310 U
490 J
630 J
530 J
850
580 J
200 J
2-MethvinaDhthalene(a)(b)
NSL
NSL
1300 U
500 U
210 U
310 U
1300 U
1000 U
700
1400
930 U
1300 U
Acenaohthene'3'
NSL
NSL
940 J
1200
350
120 J
800 J
670 J
520 J
400 J
480 J
660 J
Acenaohthvlene!a'
NSL
NSL
27 J
31'" "
1 T
Anthracene !a'
57.2
845
2300
970
320
390
2100
1500
850
1100
4600
Benzo(a)anthracene !a'
108
1050
3500
1300
480
5*700
5200
2600
2600
3900
4100
Benzolalovrene!a'
150
1450
2600
8"0
290
1300
5100
4600
2300
2100
3000
Benzo(b)fluoranthene!a'
NSL
NSL
1900
860
320
1100
4000
3500
2000
1800
2300
3800
Benzo(e)Dvrene
NSL
NSL
1600
550
220
910
3100
2900
1500
1500
1900
2500
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
1300 U
360 J
150 J
630
2300
1900
910
780
1200
1900
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
2400
770
320
1300
3800
3800
1700
1900
2500
3100
CI Chrvsenes
NSL
NSL
2100 J
670 J
280 J
780 J
3900 J
3500 J
2300 J
4000 J
3500 J
2300 J
CI Fluorenes
NSL
NSL
320 J
140 J
50 J
57 J
740 J
970 J
770 J
1400 J
1000 J
250 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
4700 J
1700 J
650 J
1500 J
7800 J
7700 J
4900 J
6000 J
7000 J
4100 J
Cl-Naohthalenes
NSL
NSL
600 J
110 J
60 J
130 J
740 J
1100 J
870 J
1500 J
1000 J
320 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
4800 J
1800 J
630 J
910 J
9500 J
11000 J
8400 J
15000 J
12000 J
3300 J
C2 Chrvsenes
NSL
NSL
1300 J
440 J
210 J
510 J
2500 J
3300 J
2100 J
5200 J
3600 J
1500 J
C2 Fluorenes
NSL
NSL
350 J
110 J
44 J
78 J
2000 J
2700 J
2100 J
4000 J
2700 J
520 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
1900 J
640 J
290 J
750 J
4500 J
4900 J
3500 J
6700 J
5300 J
2700 J
C2-Naohthalenes
NSL
NSL
2200 J
670 J
320 J
360 J
5000 J
7800 J
6800 J
13000 J
9100 J
1400 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
2200 J
710 J
300 J
570 J
9000 J
11000 J
8000 J
16000 J
12000 J
2600 J
C3 Chrvsenes
NSL
NSL
460 J
150 J
75 J
210 J
1000 J
1200 J
950 J
2600 J
1600 J
670 J
C3 Fluorenes
NSL
NSL
440 J
130 J
68 J
140 J
4200 J
5000 J
4000 J
7300 J
4900 J
1100 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
850 J
260 J
140 J
340 J
2700 J
3200 J
2300 J
5300 J
3500 J
1500 J
C3-Naohthalenes
NSL
NSL
2400 J
830 J
370 J
450 J
13000 J
19000 J
16000 J
30000 J
23000 J
3800 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
1500 J
440 J
230 J
430 J
7700 J
9500 J
7500 J
14000 J
11000 J
2500 J
C4 Chrvsenes
NSL
NSL
210 J
57 J
41 J
56 J
500 J
640 J
520 J
1000 J
710 J
280 J
C4-Naohthalenes
NSL
NSL
970 J
260 J
150 J
240 J
9200 J
13000 J
11000 J
19000 J
15000 J
2500 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
160 J
(iVin J
Chrvsene(a)
166
1290
us/ks
3100
1100
450
1300
5400
4900
2"00
3000
3600
4200
Dibenzo(a,h)anthracene!a'
33
NSL
us/ks
310.1
100.1
42 J
150 .1
610 .1
510 .1
240 .1
200.1
320.1
460.1
Fluoranthene!a'
423
2230
us/ks
sooo
3~00
1200
2400
11000
8900
4"00
4900
"600
8600
Fluorene!a'
77.4
536
us/ks
1600
1300
230
1~0 .1
1100.1
820 .1
600 .1
650
1200
660 J
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
us/ks
970 J
340 J
140 J
540
1900
770
Naphthalene!a'
176
561
us/ks
1300 U
500 U
210 U
310 U
1300 U
1400
1100
1500
1100
Pervlene
NSL
NSL
110 J
800 J
Phenanthrene !a'
204
1170
"000
4300
1200
1100
6600
5600
3"00
4400
6800
5200
Pyrene(a)
195
1520
5200
2300
820
1800
"91)0
"400
4200
391)1)
6400
6000
Total PAH17 ND=1/2RL
1601.0
22800.0
42420.0
20011.0
6549.00
14165.0
60060.0
533"0.0
29X20.0
31580.0
46"I5J)
46400J)
Total PAID 4 ND=1/2RL
1601.0
22800.0
59100M
25X61.0
8906.0
19185.0
109450
111140
"2000
1045"0
105550
65320.0
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
pg/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 11 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-26
RREC13-26
RREC13-26
RREC13-26
RREC13-27
RREC13-27
RREC13-27
RREC13-27
RREC13-27
RREC13-27
Sample Name:
RREC13-26-0001
RREC13-26-0103
RREC13-26-0305
RREC13-26-0507
RREC13-27-SURF
RREC13-27-0001
RREC13-27-0103
RREC13-27-0305
RREC13-27-0507
RREC13-27-0710
Sample Depth (ft):
0-1
1-3
3-5
5-7
0-0.5
0-1
1-3
3-5
5-7
7-10
Date Sampled:
10/30/13
10/30/13
10/30/13
10/30/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
Analvte
TEC
PEC
Units
l-Methvlnaohthalene(b)
NSL
NSL
810 J
960
1100
680 J
110 J
2400
2300
4200
2200
2200
2-Methvlnaohthalene(a) 031
NSL
NSL
1300 U
1300
1300
930
380 U
3000
2900
5800
2900
3200
Acenaohthene'3'
NSL
NSL
1100 J
740 J
480 J
400 J
140 J
430 J
490 J
1300 J
1200 J
1500
Acenaohthvlene !a'
NSL
NSL
....
IIm.T
Anthracene !a'
57.2
845
1400
1300
1100
430
710
1000.1
2100
2400
2700
Benzo(a)anthracene!a'
108
1050
4000
3400
2000
2000
2200
3000
4200
4600
5200
Benzolalovrene !a'
150
1450
3-00
3100
2600
2300
1000
roo
2300
2-00
3000
3600
Benzo(b)fluoranthene !a'
NSL
NSL
3000
3400
2600
2200
2000
1700
2400
2700
2800
3900
Benzo(e)Dvrene
NSL
NSL
2800
2400
1800
1600
1400
1300
1600
2100
2200
2400
Benzo(sJi,i)pervlene !a'
NSL
NSL
us/ks
2600
1400
1500
1000 J
1100
800
1100
1200 J
1300 J
1400
Benzo(k)fluoranthene!a'
NSL
NSL
us/ks
3400
2800
2000
2000
1800
1600
1900
2700
2800
3000
CI Chrvsenes
NSL
NSL
3600 J
3900 J
2500 J
2100 J
1300 J
2600 J
2700 J
5100 J
4000 J
4100 J
CI Fluorenes
NSL
NSL
640 J
990 J
640 J
510 J
82 J
1100 J
1100 J
1900 J
1200 J
1500 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
7000 J
7400 J
5500 J
4500 J
2200 J
5300 J
5800 J
10000 J
8300 J
8200 J
Cl-Naohthalenes
NSL
NSL
1200 J
1600 J
1600 J
1100 J
200 J
3700 J
3600 J
6700 J
3400 J
3700 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
8300 J
12000 J
6400 J
5700 J
1500 J
11000 J
11000 J
19000 J
13000 J
15000 J
C2 Chrvsenes
NSL
NSL
2800 J
4600 J
2300 J
2000 J
860 J
3600 J
2900 J
6300 J
4000 J
3600 J
C2 Fluorenes
NSL
NSL
1500 J
2700 J
1400 J
1100 J
180 J
3600 J
3200 J
4900 J
3300 J
3600 J
C2-Fluoranthenes/Pvrenes
NSL
NSL
4500 J
5900 J
3800 J
3200 J
1500 J
5300 J
4900 J
9800 J
6400 J
5700 J
C2-Naohthalenes
NSL
NSL
5500 J
8500 J
6800 J
4500 J
670 J
16000 J
17000 J
32000 J
16000 J
14000 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
7600 J
12000 J
6700 J
6200 J
1100 J
14000 J
12000 J
19000 J
14000 J
16000 J
C3 Chrvsenes
NSL
NSL
1200 J
2000 J
960 J
900 J
280 J
1800 J
1700 J
3200 J
1800 J
1800 J
C3 Fluorenes
NSL
NSL
3100 J
5600 J
2900 J
2700 J
270 J
7500 J
6800 J
9700 J
6600 J
7200 J
C3-Fluoranthenes/Pvrenes
NSL
NSL
3100 J
4500 J
2700 J
2200 J
750 J
4100 J
4400 J
7100 J
4800 J
4500 J
C3-Naohthalenes
NSL
NSL
11000 J
21000 J
9800 J
8500 J
1000 J
23000 J
26000 J
42000 J
22000 J
23000 J
C3-Phenanthrenes/Anthracenes
NSL
NSL
7200 J
13000 J
8900 J
7200 J
970 J
14000 J
14000 J
22000 J
14000 J
15000 J
C4 Chrvsenes
NSL
NSL
570 J
1000 J
560 J
500 J
130 J
930 J
880 J
1600 J
900 J
1100 J
C4-Naohthalenes
NSL
NSL
8200 J
15000 J
7600 J
6100 J
650 J
15000 J
16000 J
21000 J
13000 J
16000 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
Chrvsene (a)
166
1290
4400
4300
3200
3000
2300
2500
2000
4400
4"00
5000
Dibenzo(aJi)anthracene !a'
33
NSL
020.1
360 .1
430.1
250.1
320 .1
200.1
2X0 .1
310.1
350 .1
420.1
Fluoranthene
423
2230
~X00
*"00
6000
5X00
3X00
4200
6100
X"00
11000
12000
Fluorene !a'
77.4
536
040 J
X40 .1
1100
020
220 .1
600
1000.1
2X00
2100
3200
Indeno(l,2J3-cd)pvrene !a'
NSL
NSL
us/ks
1200
1300
880
930
970 J
1400
Naphthalene !a'
176
561
1300 U
1-00
1300
1200
380 U
6"0
1400
1900 U
4200
Pervlene
NSL
NSL
800 J
Phenanthrene!a'
204
1170
5000
5600
5200
4600
2300
4300
5500
11000
10000
11000
Pyrene (a)
195
1520
6~00 .1
6000
5200 .1
4400
2X00
3400
4"00
"600
"200
"200
Total PAH17 ND=1/2RL
1601.0
22800.0
40XX0.0
44X00.0
30110.0
34120.0
22500.0
2X040.0
3X240M
50XX0.0
5X601) J)
60330.0
Total PAH34 ND=1/2RL
1601.0
22800.0
03040
1 DM 1)0
"X550
6X320.0
31162.0
04410
101240
15X330
12X"90
146030
NOTES
Presented results are not normalized to organic carbon
w Included in calculation oftotal 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
lig/kg = Micrograms per kilogram
NSI^No screening level
TEC = Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC =Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 12 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-28
RREC13-28
RREC13-28
RREC13-28
RREC13-28
RREC13-28
RREC13-28
RREC13-29
RREC13-29
RREC13-29
Sample Name:
RREC13-28-SURF
RREC13-28-0001
RREC13-28-0103
RREC13-28-0305
RREC13-28-0507
RREC13-28-0709
RREC13-28-0911
RREC13-29-SURF
RREC13-29-0001
RREC13-29-0103
Sample Depth (ft):
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
0-1
1-3
Date Sampled:
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
11/4/13
11/4/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
76 J
2200
1400 U
1100 U
860 U
770 U
870 U
270 J
360
950
2-MethvinaDhthalene(a)(b)
NSL
NSL
350 U
2200
1400 U
1100 U
860 U
770 U
870 U
320 U
350
1200
Acenaohthene'3'
NSL
NSL
110 J
600 U
1400 U
1100 U
860 U
770 U
420 J
160 J
120 J
480 J
Acenaohthvlene!a'
NSL
NSL
---
150 "
Anthracene !a'
57.2
845
4-0
630
1000
1700
1000
300
110 .1
1600
Benzo(a)anthracene !a'
108
1050
5000
4600
4400
4000
3300
1400
500
3X00
Benzolalovrene!a'
150
1450
1500
1300
301)0
3600
201)1)
2500
380
2000
Benzo(b)fluoranthene!a'
NSL
NSL
1400
1400
3500
3000
3100
2900
2400
1500
370
2900
Benzo(e)Dvrene
NSL
NSL
1000
1300
2800
2600
2600
2300
2000
980
380
2400
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
770
1100
2500
2300
2200
1900
990
730
340
2300
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
1400
1200
3200
3100
2900
2200
2100
1200
310
2300
CI Chrvsenes
NSL
NSL
860 J
3400 J
4900 J
4700 J
4800 J
5600 J
4300 J
1200 J
800 J
4100 J
CI Fluorenes
NSL
NSL
61 J
1300 J
740 J
620 J
470 J
550 J
380 J
240 J
260 J
820 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
1700 J
4700 J
6300 J
5900 J
5700 J
5900 J
6700 J
2100 J
1100 J
5700 J
Cl-Naohthalenes
NSL
NSL
130 J
3200 J
1200 J
1200 J
830 J
950 J
750 J
330 J
520 J
1600 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
1100 J
10000 J
7600 J
7500 J
6100 J
7600 J
7300 J
2900 J
2500 J
8600 J
C2 Chrvsenes
NSL
NSL
790 J
3600 J
4500 J
4200 J
4400 J
5300 J
4800 J
1300 J
990 J
3700 J
C2 Fluorenes
NSL
NSL
130 J
3900 J
1600 J
1500 J
1100 J
1300 J
1000 J
730 J
800 J
2400 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
880 J
5500 J
4800 J
4800 J
4700 J
5900 J
5600 J
1600 J
1300 J
5300 J
C2-Naohthalenes
NSL
NSL
580 J
20000 J
6200 J
5500 J
3300 J
4000 J
2900 J
2900 J
3900 J
9400 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
910 J
16000 J
12000 J
11000 J
9000 J
12000 J
9100 J
3200 J
3500 J
11000 J
C3 Chrvsenes
NSL
NSL
320 J
1800 J
2000 J
1900 J
2300 J
3000 J
2500 J
540 J
500 J
1900 J
C3 Fluorenes
NSL
NSL
320 J
9600 J
4300 J
4100 J
3400 J
4000 J
3200 J
1700 J
1800 J
5500 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
540 J
4800 J
3900 J
3900 J
3800 J
4900 J
5000 J
1100 J
1200 J
4000 J
C3-Naohthalenes
NSL
NSL
830 J
29000 J
9700 J
7900 J
4600 J
5500 J
5000 J
5100 J
6400 J
14000 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
750 J
18000 J
12000 J
12000 J
11000 J
14000 J
12000 J
3000 J
4100 J
12000 J
C4 Chrvsenes
NSL
NSL
88 J
1300 J
1200 J
1200 J
1200 J
1600 J
1500 J
240 J
270 J
930 J
C4-Naohthalenes
NSL
NSL
560 J
24000 J
8800 J
6900 J
4300 J
5100 J
3800 J
3700 J
4800 J
11000 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
"Omm J
"
Chrvsene(a)
166
1290
1400
2500
5000
4X00
4500
4500
3300
630
4000
Dibenzo(a,h)anthracene!a'
33
NSL
220.1
600 U
1400 U
860 U
770 U
2X0 .1
220.1
120 .1
XOO.I
Fluoranthene!a'
423
2230
2300
3000
8000
6000
6500
5"00
5100
640
5500
Fluorene!a'
77.4
536
l"O.I
0X0
1400 U
1"00
1500
1300
"20 .1
1X0.1
100
1600
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
690
880
2300
1800
880
280
Naphthalene!a'
176
561
350 U
600 U
1400 U
1500
1600
1600
1200
320 U
150 u
1100
Pervlene
NSL
NSL
Phenanthrene !a'
204
1170
1100
3200
5X00
5~00
4"00
4200
3400
1400
"30
4000
Pyrene(a)
195
1520
1700
4000
X500
"600
"000
6500
4100
1"00
1000
6300
Total PAH17 ND=1/2RL
1601.0
22800.0
15167.0
25490M
54100.0
51200.0
4"520J)
42"40.0
32560J)
15356.0
6220.00
44210.0
Total PAID 4 ND=1/2RL
1601.0
22800.0
21833.0
100301)
100"40
105420
05250
100301)
X2X"5
32266.0
23150J)
1005X0
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
pg/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 13 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-29
RREC13-29
RREC13-29
RREC13-29
RREC13-30
RREC13-30
RREC13-30
RREC13-30
RREC13-30
RREC13-30
RREC13-29-0305
RREC13-29-0507
RREC13-29-0709
RREC13-29-0911
RREC13-30-SURF
RREC13-30-0001
RREC13-30-0001-FD
RREC13-30-0103
RREC13-30-0103 -FD
RREC13-30-0305
Sample Depth (ft):
3-5
5-7
7-9
9-11
0-0.5
0-1
0-1
1-3
1-3
3-5
Date Sampled:
11/4/13
11/4/13
11/4/13
11/4/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
1100 U
820 U
1800 U
2600 U
410 J
1400
1400
2400
1400
1400
2-MethvinaDhthalene(a)(b)
NSL
NSL
1200
820 U
1800 U
2900
670 U
2100
2000
3200
2000
1900
Acenaohthene'3'
NSL
NSL
640 J
440 J
1100 J
1500 J
330 J
910 U
830 U
1800
1100
880 J
Acenaohthvlene!a'
NSL
NSL
Anthracene !a'
57.2
845
1400
4300
7100
1200
910 U
930
2500
1300
1400
Benzo(a)anthracene !a'
108
1050
4600
3200
0400
11000
4200
2000
2000
4900
3300
4100
Benzolalovrene!a'
150
1450
3-00
2500
"300
X0D0
4000
2300
2400
4100
201)0
3600
Benzo(b)fluoranthene!a'
NSL
NSL
3700
2500
6200
6800
3300
2200
2300
3400
2300
3200
Benzo(e)Dvrene
NSL
NSL
2800
1900
5200
6200
2500
2100
2200
3200
2100
2500
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
2500
1700
4700
6100
1600 J
1800
2000
3000
1200
1400
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
2900
2000
5900
6800
3600
1800
1800
2800
2400
2800
CI Chrvsenes
NSL
NSL
4400 J
3400 J
8200 J
10000 J
3100 J
5500 J
5900 J
6100 J
3100 J
4600 J
CI Fluorenes
NSL
NSL
940 J
520 J
960 J
1600 J
550 J
2000 J
1900 J
2100 J
1000 J
1300 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
6300 J
4500 J
12000 J
15000 J
5900 J
6200 J
6700 J
8600 J
6400 J
8600 J
Cl-Naohthalenes
NSL
NSL
1500 J
940 J
1800 J
3600 J
680 J
2500 J
2400 J
3900 J
2300 J
2300 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
9800 J
6800 J
13000 J
19000 J
7500 J
17000 J
17000 J
18000 J
11000 J
15000 J
C2 Chrvsenes
NSL
NSL
3900 J
3000 J
6100 J
7200 J
3300 J
6800 J
7500 J
6400 J
3200 J
4700 J
C2 Fluorenes
NSL
NSL
2100 J
1500 J
2000 J
2800 J
1500 J
5600 J
5200 J
4900 J
2500 J
3400 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
5400 J
3800 J
7700 J
9200 J
4000 J
8000 J
8700 J
8400 J
5000 J
7300 J
C2-Naohthalenes
NSL
NSL
7400 J
4600 J
8500 J
14000 J
5700 J
22000 J
21000 J
25000 J
12000 J
13000 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
13000 J
9500 J
14000 J
19000 J
7400 J
23000 J
23000 J
21000 J
11000 J
16000 J
C3 Chrvsenes
NSL
NSL
1800 J
1300 J
3100 J
3000 J
1100 J
3500 J
4100 J
3100 J
1700 J
2700 J
C3 Fluorenes
NSL
NSL
5400 J
3700 J
4500 J
6700 J
3000 J
11000 J
10000 J
9700 J
4500 J
6700 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
4000 J
3000 J
4800 J
6700 J
2400 J
6800 J
7000 J
6300 J
3600 J
5700 J
C3-Naohthalenes
NSL
NSL
13000 J
8400 J
13000 J
19000 J
11000 J
39000 J
38000 J
38000 J
22000 J
28000 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
13000 J
9900 J
15000 J
20000 J
6800 J
21000 J
22000 J
18000 J
9400 J
15000 J
C4 Chrvsenes
NSL
NSL
1100 J
820 J
1400 J
1500 J
490 J
1700 J
2400 J
1700 J
760 J
1100 J
C4-Naohthalenes
NSL
NSL
11000 J
7800 J
9200 J
13000 J
7500 J
30000 J
29000 J
27000 J
13000 J
18000 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
1 I'-""""' J
Chrvsene(a)
166
1290
4"00
3400
0300
11000
3000
3600
3600
5200
3400
4300
Dibenzo(a,h)anthracene!a'
33
NSL
us/ks
XXO .1
OOO.I
1000.1
l'OO.I
4X0.1
910 U
830 U
1400 U
2X0.1
360 .1
Fluoranthene!a'
423
2230
-100
4600
13000
rooo
6300
3"00
3000
"200
5X00
6"00
Fluorene!a'
77.4
536
us/ks
1500
2X00
4600
610.1
1200
1200
2200
1000 .1
930 J
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
2300
1500
4300
4900
1500
1500
1600
2400
990 J
Naphthalene!a'
176
561
us/ks
1200
2000
4400
"X0
2000
2500
2500
1200
1300
Pervlene
NSL
NSL
910 U
Phenanthrene !a'
204
1170
5900
3400
11000
19000
3600
5100
5100
9X00
6200
6000
Pyrene(a)
195
1520
"500
5100
16000
22000
5300
5300
5"00
10000
5400
6100
Total PAH17 ND=1/2RL
1601.0
22800.0
555"0.0
35X00.0
100"00
13"000
41355.0
3X220.0
3O1"5.0
66400J)
41320.0
46X20.0
Total PAID 4 ND=1/2RL
1601.0
22800.0
11"560
X0X00
1"X260
240400
X0X"0
1364"5
13"590
160400
03X00
124020
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
pg/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 14 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-30
RREC13-30
RREC13-30
RREC13-31
RREC13-31
RREC13-31
RREC13-31
RREC13-31
RREC13-32
RREC13-32
RREC13-30-0305-FD
RREC13-30-0507
RREC13-30-0507-FD
RREC13-31-SURF
RREC13-31-0001
RREC13-31-0103
RREC13-31-0305
RREC13-31-0507
RREC13-32-SURF
RREC13-32-0001
Sample Depth (ft):
3-5
5-7
5-7
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-1
Date Sampled:
10/30/13
10/30/13
10/30/13
10/30/13
10/31/13
10/31/13
10/31/13
10/31/13
10/30/13
11/1/13
Analvte
TEC
PEC
Units
l-Methvlnaohthalene(b)
NSL
NSL
1000
1500 U
1900 U
610 U
9.4 U
4.7U
4.7 U
4.5 U
1100 U
520 J
2-Methvlnaohthalene(a) 031
NSL
NSL
1300
1500 U
1900 U
160 J
4.7 J
1.9 J
2.1 J
1.9 J
300 J
340 J
Acenaohthene'3'
NSL
NSL
970 U
1700
1900 U
210 J
2.8 J
0.9 J
1 J
0.82 J
370 J
840 J
Acenaohthvlene !a'
NSL
NSL
.....
9.4 U
4.7U
4.7 U
4.5 U
Anthracene !a'
57.2
845
1-00
3600
3000
11
4.7U
4.7 U
4.5 U
1400
201)0
Benzo(a)anthracene!a'
108
1050
5600
6400
2700
37
4.7U
4.7
4.5 U
4000
5700
Benzolalovrene !a'
150
1450
3100
4400
5300
2400
33
4.7U
4.7 U
4.5 U
3X00
4-00
Benzo(b)fluoranthene !a'
NSL
NSL
2800
3900
4800
2000
34
4.7
6.5
4.5 U
3600
4600
Benzo(e)Dvrene
NSL
NSL
2300
3000
3600
1700
25
4.7U
6.2
4.5 U
2600
3400
Benzo(sJi,i)pervlene !a'
NSL
NSL
US/ks
2100
2900
3700
1700
24
6.1
7.2
5.6
1900
2900
Benzo(k)fluoranthene!a'
NSL
NSL
US/ks
2000
3300
4000
2000
25
4.7U
4.7 U
4.5 U
2900
3700
CI Chrvsenes
NSL
NSL
4400 J
4600 J
5300 J
1900 J
39 J
14 J
17 J
14 J
2900 J
4400 J
CI Fluorenes
NSL
NSL
1100 J
630 J
690 J
120 J
3.9 J
2.3 J
2.4 J
2.2 J
150 J
650 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
5800 J
6900 J
7600 J
2800 J
49 J
11 J
14 J
11 J
3800 J
7000 J
Cl-Naohthalenes
NSL
NSL
1700 J
1600 J
1600 J
200 J
6.4 J
3.3 J
3.6 J
3.3 J
350 J
620 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
11000 J
7200 J
7800 J
2100 J
45 J
18 J
20 J
18 J
2300 J
8400 J
C2 Chrvsenes
NSL
NSL
3600 J
3000 J
3900 J
940 J
41 J
20 J
23 J
18 J
1800 J
3000 J
C2 Fluorenes
NSL
NSL
3100 J
1200 J
1200 J
160 J
6.1 J
4 J
3.8 J
3.5 J
220 J
1500 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
5400 J
4200 J
4600 J
1400 J
34 J
14 J
15 J
12 J
2000 J
4100 J
C2-Naohthalenes
NSL
NSL
12000 J
4700 J
5100 J
660 J
22 J
12 J
13 J
13 J
1100 U
3700 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
14000 J
8100 J
8900 J
1100 J
43 J
23 J
26 J
23 J
1900 J
7400 J
C3 Chrvsenes
NSL
NSL
1700 J
1300 J
1500 J
400 J
13 J
9.5 J
13 J
11 J
500 J
1300 J
C3 Fluorenes
NSL
NSL
6500 J
2900 J
3000 J
160 J
12 J
7 J
73
6.5 J
430 J
2900 J
C3-Fluoranthenes/Pvrenes
NSL
NSL
3800 J
2900 J
3200 J
610 J
23 J
14 J
16 J
14 J
930 J
2500 J
C3-Naohthalenes
NSL
NSL
22000 J
6400 J
6800 J
610 U
32 J
25 J
36 J
28 J
1100 U
8600 J
C3-Phenanthrenes/Anthracenes
NSL
NSL
11000 J
8200 J
8900 J
770 J
47 J
29 J
24 J
32 J
1300 J
5900 J
C4 Chrvsenes
NSL
NSL
840 J
770 J
780 J
610 U
5.9 J
5.1 J
5.8 J
4.1 J
1100 U
1900 U
C4-Naohthalenes
NSL
NSL
17000 J
5100 J
5600 J
300 J
34 J
29 J
33 J
33 J
610 J
6000 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
36 J
23 J
23 J
24 J
Chrvsene (a)
166
1290
us/
3"00
5300
6300
2400
37
7.1
10
6.8
3"00
Dibenzo(aJi)anthracene !a'
33
NSL
us/
1500 U
1900 U
7 J
0.79 J
1.2 J
0.71 J
610.1
040 .1
Fluoranthene 'a'
423
2230
us/
5100
4300
47
4.7U
6
4.5 U
5"00
Fluorene (a)
774
536
us/
7000
*>00
9.4 U
4.7U
4.7 U
4.5 U
1400.1
Indeno(l,2J3-cd)pvrene !a'
NSL
NSL
us/
1800
3200
1500
19
4.7U
4.7 U
4.5 U
1700
Naphthalene !a'
176
561
us/
QK0
610 U
15
4.7U
4.7 U
4.5 U
1100 U
Pervlene
NSL
NSL
lOMMl
33
29
28
27
1.1-J
Phenanthrene!a'
204
1170
5500
2600
25
4.7U
5.1
4.8
3100
Pyrene (a)
195
1520
us/
0500
11000
11000
4300
51
4.9
8.2
6100
0-00
Total PAH17 ND=1/2RL
1601.0
22800.0
42«>35 Jl
"3150.0
X1600.0
2X"95J)
381.900
49.8900
68.4500
48.1300
40X30.0
63X20.0
Total PAH34 ND=1/2RL
1601.0
22800.0
JOUUJ.U
677.200
196.640
220.750
195.680
JHO iU.U
1UJJJU
NOTES
Presented results are not normalized to organic carbon
w Included in calculation oftotal 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
Ug/kg = Micrograms per kilogram
NSI^No screening level
TEC = Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC =Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 15 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-32
RREC13-32
RREC13-33
RREC13-33
RREC13-33
RREC13-33
RREC13-33
RREC13-33
RREC13-33
RREC13-34
RREC13-32-0103
RREC13-32-0305
RREC13-33-SURF
RREC13-33-0001
RREC13-33-0103
RREC13-33-0305
RREC13-33-0507
RREC13-33-0709
RREC13-33-0911
RREC13-34-SURF
Sample Depth (ft):
1-3
3-5
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
Date Sampled:
11/1/13
11/1/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
11/1/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
140 J
33 J
170 U
150 J
940
2200
2300 J
1000
24 J
670
2-MethvinaDhthalene(a)(b)
NSL
NSL
42 J
24 J
83 J
360 U
860 U
2700
3300
1300
92 U
700
Acenaohthene'3'
NSL
NSL
350
57 J
49 J
200 J
470 J
1400 J
1800 J
1200
37 J
390 J
Acenaohthvlene!a'
NSL
NSL
330 U
110 U
170 U
"vT
....
18 J
600 U
Anthracene !a'
57.2
845
650
200
170 U
240 .1
1300
4500
6900
2400
100
600
Benzo(a)anthracene !a'
108
1050
noo
380
530
1500
3800
6800
13000
4600
350
Benzolalovrene!a'
150
1450
820
360
620
1600
2-00
4-00
10000
3500
310
1800
Benzo(b)fluoranthene!a'
NSL
NSL
510
270
800
1700
3000
3500
8700
2100
300
2000
Benzo(e)Dvrene
NSL
NSL
540
230
530
1200
2100
3100
6100
2200
240
1700
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
400
230
470
710
970
1800 J
3600
1500
130
1800
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
570
260
530
1300
2500
3900
8400
3200
300
1200
CI Chrvsenes
NSL
NSL
1100 J
340 J
640 J
2000 J
4800 J
7400 J
9600 J
4100 J
280 J
3100 J
CI Fluorenes
NSL
NSL
180 J
34 J
38 J
390 J
1300 J
2000 J
1200 J
600 J
33 J
1300 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
1900 J
500 J
670 J
3600 J
9200 J
16000 J
21000 J
9500 J
550 J
4400 J
Cl-Naohthalenes
NSL
NSL
130 J
44 J
92 J
200 J
880 J
3500 J
3800 J
1600 J
39 J
1000 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
2300 J
490 J
470 J
4500 J
17000 J
25000 J
21000 J
9100 J
450 J
14000 J
C2 Chrvsenes
NSL
NSL
670 J
190 J
780 J
3000 J
8100 J
7100 J
8700 J
3700 J
260 J
3000 J
C2 Fluorenes
NSL
NSL
230 J
57 J
110 J
1700 J
4600 J
5000 J
1500 J
860 J
52 J
4400 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
1100 J
290 J
680 J
3500 J
8200 J
11000 J
9600 J
5400 J
290 J
4900 J
C2-Naohthalenes
NSL
NSL
1000 J
210 J
350 J
1500 J
8200 J
17000 J
9000 J
5000 J
160 J
11000 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
1400 J
350 J
790 J
6800 J
21000 J
23000 J
11000 J
5000 J
300 J
19000 J
C3 Chrvsenes
NSL
NSL
240 J
60 J
420 J
1400 J
3400 J
3700 J
2500 J
1200 J
81 J
1700 J
C3 Fluorenes
NSL
NSL
290 J
100 J
380 J
3800 J
10000 J
11000 J
1900 J
930 J
94 J
9600 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
490 J
130 J
510 J
2700 J
6700 J
7300 J
4800 J
2500 J
140 J
4000 J
C3-Naohthalenes
NSL
NSL
1200 J
330 J
440 J
6900 J
24000 J
32000 J
8600 J
4900 J
270 J
24000 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
830 J
250 J
1000 J
12000 J
22000 J
24000 J
7600 J
4100 J
250 J
17000 J
C4 Chrvsenes
NSL
NSL
76 J
12 J
190 J
660 J
1900 J
2000 J
1100 J
360 J
31 J
1100 J
C4-Naohthalenes
NSL
NSL
510 J
200 J
460 J
7300 J
20000 J
22000 J
3800 J
1800 J
170 J
24000 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
420 J
160 J
860 J
"<1111.1
170 J
10000 J
Chrvsene(a)
166
1290
950
370
650
1800
3900
6100
12000
4100
340
2~00 *.*.*./•
Dibenzo(a,h)anthracene!a'
33
NSL
130 J
74 J
150 J
180 .1
280.1
430 .1
1100 .1
430 .1
34 J
600 J
Fluoranthene!a'
423
2230
1300
550
750
2100
6800
10000
70000
6400
550
Fluorene!a'
77.4
536
330 J
100 J
170 TT
1"0 .1
900
2200
3300
1500
62 J
500 J
Indeno(12 3-cd)pvrene
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-34
RREC13-34
RREC13-34
RREC13-34
RREC13-34
RREC13-34
RREC13-35
RREC13-35
RREC13-35
RREC13-35
Sample Name:
RREC13-34-0001
RREC13-34-0103
RREC13-34-0305
RREC13-34-0507
RREC13-34-0709
RREC13-34-0911
RREC13-35-SURF
RREC13-35-0001
RREC13-35-0103
RREC13-35-0305
Sample Depth (ft):
0-1
1-3
0-0.5
5-7
7-9
9-11
0-0.5
0-1
1-3
3-5
Date Sampled:
11/4/13
11/4/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/31/13
10/31/13
10/31/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
1300
2200 U
2600 U
1600 U
1600 U
1700 U
930 U
2400 U
410 U
4 U
2-MethvinaDhthalene(a)(b)
NSL
NSL
1800
2200 U
2600 U
1600 U
1600 U
1900
340 J
2400 U
410 U
4 U
Acenaohthene'3'
NSL
NSL
1000 J
1000 J
2600 U
1600 U
1600 U
1700 U
360 J
1700 J
420
4.4
Acenaohthvlene!a'
NSL
NSL
.....
4 U
Anthracene !a'
57.2
845
1300
3100
3500
2100
2600
2600
1000
5600
950
13
Benzo(a)anthracene !a'
108
1050
3600
XI00
6X00
5900
6700
6600
3000
7ooo
1300
21
Benzolalovrene!a'
150
1450
2X00
6200
4600
4200
4600
4300
2500
16
Benzo(b)fluoranthene!a'
NSL
NSL
2900
6100
4600
4100
4200
3900
2800
3800
610
12
Benzo(e)Dvrene
NSL
NSL
2500
4900
4000
3600
3700
3600
2000
3400
640
12
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
2600
5000
3300
2900
3300
3300
1400
3000
590
11
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
2200
5900
4200
3800
4100
3600
2400
3200
730
9.6
CI Chrvsenes
NSL
NSL
4000 J
6300 J
5900 J
6500 J
7900 J
9800 J
2900 J
7000 J
1200 J
21 J
CI Fluorenes
NSL
NSL
1600 J
1300 J
1600 J
1200 J
1200 J
1400 J
200 J
1200 J
240 J
3.1 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
5600 J
8500 J
9300 J
8300 J
9100 J
11000 J
3000 J
12000 J
2100 J
30 J
Cl-Naohthalenes
NSL
NSL
2200 J
1900 J
2400 J
2000 J
1500 J
2600 J
440 J
1400 J
210 J
3.7 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
15000 J
15000 J
15000 J
13000 J
15000 J
18000 J
2800 J
17000 J
2900 J
40 J
C2 Chrvsenes
NSL
NSL
4400 J
6400 J
6400 J
6200 J
6900 J
12000 J
2200 J
3800 J
660 J
12 J
C2 Fluorenes
NSL
NSL
5400 J
4100 J
4300 J
3200 J
3200 J
4200 J
370 J
1100 J
210 J
2.8 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
6500 J
7700 J
8700 J
7800 J
8500 J
13000 J
2600 J
6100 J
1000 J
16 J
C2-Naohthalenes
NSL
NSL
19000 J
14000 J
15000 J
12000 J
8200 J
14000 J
1700 J
7300 J
1000 J
15 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
22000 J
18000 J
21000 J
19000 J
25000 J
33000 J
3200 J
9100 J
1500 J
24 J
C3 Chrvsenes
NSL
NSL
2400 J
2800 J
3400 J
2800 J
3600 J
6400 J
1100 J
1800 J
280 J
5.6 J
C3 Fluorenes
NSL
NSL
12000 J
9300 J
10000 J
7700 J
8800 J
12000 J
620 J
1500 J
260 J
4.4 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
5200 J
5800 J
6900 J
6300 J
7000 J
13000 J
1500 J
2600 J
470 J
8.7 J
C3-Naohthalenes
NSL
NSL
35000 J
25000 J
27000 J
20000 J
14000 J
24000 J
2100 J
6100 J
1100 J
16 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
21000 J
17000 J
23000 J
22000 J
25000 J
44000 J
3100 J
4800 J
840 J
15 J
C4 Chrvsenes
NSL
NSL
1400 J
1600 J
1900 J
1700 J
1800 J
3600 J
420 J
750 J
120 J
2.4 J
C4-Naohthalenes
NSL
NSL
29000 J
18000 J
25000 J
18000 J
17000 J
24000 J
1500 J
2300 J
420 J
7.9 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
10 J
Chrvsene(a)
166
1290
us/1
4200
3400
6600
6100
"300
"900
3100
1200
17
Dibenzo(a,h)anthracene!a'
33
NSL
us/1
X"O.I
1500.1
2600 U
1600 U
1600 U
5X0 .1
040.1
190 .1
3.5 J
Fluoranthene!a'
423
2230
6300
14000
rooo
10000
11000
9"00
5000
2100
28
Fluorene!a'
77.4
536
1100
1000.1
4000
3200
2400
2300
930 U
2"00
7.6
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
us/1
4500
2800
2600
2900
1300
2400 J
460
.3
Naphthalene!a'
176
561
us/1
2600 U
1600 U
1600 U
1100
2400 U
410 U
U
Pervlene
NSL
NSL
910 J
'3
Phenanthrene !a'
204
1170
6500
12000
1X000
XI00
"100
X500
3100
2"00
¦n
Pyrene(a)
195
1520
u#/l
"300
15000
1X000
12000
12000
13000
4X00
15000
2X00
10
Total PAH17 ND=1/2RL
1601.0
22800.0
4 0.0
96000M
09900.0
601)00.0
"2200J)
"3"00.0
33*10.0
X"340.0
16325.0
234.400
Total PAID 4 ND=1/2RL
1601.0
22800.0
146
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-36
RREC13-36
RREC13-36
RREC13-37
RREC13-37
RREC13-37
RREC13-37
RREC13-37
RREC13-37
RREC13-37
Sample Name:
RREC13-36-SURF
RREC13-36-0001
RREC13-36-0103
RREC13-37-SURF
RREC13-37-0001
RREC13-37-0103
RREC13-37-0305
RREC13-37-0507
RREC13-37-0709
RREC13-37-0911
Sample Depth (ft):
0-0.5
0-1
1-3
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
Date Sampled:
10/28/13
10/31/13
10/31/13
10/28/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
Analvte
TEC
PEC
Units
l-Methvlnaohthalene(b)
NSL
NSL
2400 UJ
1500 U
570 U
90 J
570 J
750
49
7.7
2.9 J
3.6 J
2-Methvlnaohthalene(a) 031
NSL
NSL
81 J
140 J
240 J
140 J
270 J
140 J
13 J
2.8 J
2 J
2.5 J
Acenaohthene'3'
NSL
NSL
200 J
270 J
460 J
360 J
1700 J
2100
89
11
0.78 J
1.6 J
Acenaohthvlene !a'
NSL
NSL
2 |f""i T7
....
43 U
5 U
5 U
5 U
Anthracene (a)
57 2
845
O'O 1
150
12
0.58 J
1.6 J
Benzo(a)anthracene!a'
108
1050
4400 .1
3300
2300
190
21
5 U
5 U
Benzolalovrene !a'
150
1450
5000 .1
3300
1400
(>500
0-00
2100
170
15
1.4 J
3.2 J
Benzo(b)fluoranthene !a'
NSL
NSL
8300 J
4800
1800
5800
5200
1300
100
14
5 U
6.6
Benzo(e)Dvrene
NSL
NSL
5300 J
3300
1400
3900
4400
1300
110
13
4.4 J
5.9
Benzo(sJi,i)pervlene !a'
NSL
NSL
us/ks
3500 J
2500
1200
2700
3400
940
98
16
6.4
9
Benzo(k)fluoranthene!a'
NSL
NSL
us/ks
6900 J
3700
1300
5500
4200
1400
100
11
1.5 J
2.8 J
CI Chrvsenes
NSL
NSL
2700 J
2700 J
2400 J
3400 J
8600 J
2400 J
250 J
35 J
12 J
16 J
CI Fluorenes
NSL
NSL
2400 UJ
240 J
600 J
1600 U
810 J
490 J
42 J
6.4 J
2.3 J
3.1 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
5000 J
3400 J
3100 J
6000 J
12000 J
3900 J
380 J
44 J
11 J
15 J
Cl-Naohthalenes
NSL
NSL
2400 UJ
170 J
320 J
1600 U
600 J
640 J
44 J
7.7 J
3.6 J
4.5 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
1600 J
2400 J
4500 J
2900 J
12000 J
5200 J
500 J
72 J
24 J
31 J
C2 Chrvsenes
NSL
NSL
3100 J
2300 J
2800 J
2400 J
5300 J
1400 J
150 J
34 J
20 J
24 J
C2 Fluorenes
NSL
NSL
2400 UJ
620 J
1500 J
1600 U
1100 J
520 J
47 J
7.7 J
4 J
4.2 J
C2-Fluoranthenes/Pvrenes
NSL
NSL
3300 J
2700 J
3200 J
2400 J
7400 J
2200 J
230 J
33 J
13 J
17 J
C2-Naohthalenes
NSL
NSL
340 J
1600 J
4200 J
560 J
5300 J
4500 J
280 J
40 J
14 J
19 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
1000 J
3200 J
7100 J
1700 J
7700 J
3000 J
280 J
48 J
24 J
29 J
C3 Chrvsenes
NSL
NSL
1700 J
940 J
1400 J
990 J
2100 J
520 J
63 J
15 J
11 J
13 J
C3 Fluorenes
NSL
NSL
270 J
1600 J
3400 J
320 J
1400 J
560 J
52 J
13 J
7.2 J
9.3 J
C3-Fluoranthenes/Pvrenes
NSL
NSL
2300 J
1700 J
2500 J
1200 J
3500 J
990 J
130 J
27 J
14 J
18 J
C3-Naohthalenes
NSL
NSL
440 J
3400 J
10000 J
630 J
5500 J
3400 J
290 J
59 J
33 J
46 J
C3-Phenanthrenes/Anthracenes
NSL
NSL
1000 J
3100 J
7400 J
1500 J
5800 J
1700 J
180 J
47 J
33 J
40 J
C4 Chrvsenes
NSL
NSL
560 J
520 J
850 J
180 J
990 J
140 J
23 J
5.7 J
4.2 J
5.4 J
C4-Naohthalenes
NSL
NSL
360 J
3000 J
8900 J
400 J
2200 J
1100 J
120 J
45 J
32 J
46 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
i
00 J
27 J
20 J
23 J
Chrvsene
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-38
RREC13-38
RREC13-38
RREC13-38
RREC13-38
RREC13-38
RREC13-39
RREC13-39
RREC13-39
RREC13-39
RREC13-38-SURF
RREC13-38-SURF-FE
RREC13-38-0001
RREC13-38-0103
RREC13-38-0305
RREC13-38-0507
RREC13-39-SURF
RREC13-39-0001
RREC13-39-0103
RREC13-39-0305
Sample Depth (ft):
0-0.5
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-1
1-3
3-5
Date Sampled:
10/30/13
10/30/13
11/2/13
11/2/13
11/2/13
11/2/13
10/30/13
10/30/13
10/30/13
10/30/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
270 U
330 U
15 U
4.7U
4.4 U
4.4 U
1300 U
650 J
71 J
1.1 J
2-MethvinaDhthalene(a)(b)
NSL
NSL
67 J
65 J
15 U
4.7U
4.4 U
4.4 U
240 J
2500 U
330 U
4.3 U
Acenaohthene'3'
NSL
NSL
68 J
83 J
28
1.4 J
1.4 J
1.2 J
350 J
1100 J
280 J
1.4 J
Acenaohthvlene!a'
NSL
NSL
270 U
330 U
15 U
4.7U
4.4 U
4.4 "
0.3 J
Anthracene !a'
57.2
845
34ft
530
22
1.2 J
1.7 J
1.6
1-ftft
56ftft
"1ft
2 J
Benzo(a)anthracene !a'
108
1050
121)1)
65
5.1
9.3
4.4
6
Benzolalovrene!a'
150
1450
1300
1-00
64
4.7U
9.8
4.4
63ftft
1101)1)
151)1)
3.7 J
Benzo(b)fluoranthene!a'
NSL
NSL
1100
1400
60
6.1
11
5.1
5500
9600
800
4.9
Benzo(e)Dvrene
NSL
NSL
850
1200
48
5.7
10
4.6
4100
6100
880
4.8
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
760
1200
51
8.3
14
6.5
3500
4100
500
3.4 J
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
950
1400
45
4.7U
7.8
4.4 U
4600
10000
1100
4.3 U
CI Chrvsenes
NSL
NSL
910 J
1200 J
67 J
14 J
21 J
13 J
4600 J
6000 J
1400 J
9.1 J
CI Fluorenes
NSL
NSL
38 J
59 J
6.6 J
2.3 J
2.4 J
1.9 J
210 J
690 J
150 J
1.4 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
1100 J
1700 J
86 J
15 J
17 J
11 J
5700 J
16000 J
3300 J
17 J
Cl-Naohthalenes
NSL
NSL
76 J
77 J
7.1 J
3.3 J
3.4 J
2.4 J
290 J
720 J
77 J
1.5 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
620 J
1000 J
71 J
21 J
21 J
16 J
3300 J
11000 J
2400 J
17 J
C2 Chrvsenes
NSL
NSL
550 J
630 J
49 J
20 J
24 J
19 J
2700 J
5500 J
830 J
14 J
C2 Fluorenes
NSL
NSL
67 J
80 J
9 J
4.1 J
4.5 J
3.8 J
330 J
1300 J
230 J
2.9 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
580 J
750 J
53 J
17 J
19 J
13 J
3200 J
6800 J
1500 J
14 J
C2-Naohthalenes
NSL
NSL
270 U
330 U
26 J
11 J
12 J
9.7 J
1300 U
3800 J
600 J
7 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
530 J
640 J
62 J
27 J
28 J
22 J
2900 J
7700 J
1300 J
27 J
C3 Chrvsenes
NSL
NSL
260 J
240 J
19 J
10 J
10 J
11 J
960 J
1400 J
250 J
7 J
C3 Fluorenes
NSL
NSL
120 J
130 J
17 J
7.9 J
8.1 J
7.6 J
610 J
2200 J
180 J
4.6 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
290 J
330 J
29 J
16 J
17 J
13 J
1500 J
2900 J
630 J
11 J
C3-Naohthalenes
NSL
NSL
270 U
330 U
44 J
24 J
26 J
22 J
1300 U
9300 J
900 J
19 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
350 J
440 J
51 J
30 J
32 J
27 J
1700 J
6700 J
1000 J
19 J
C4 Chrvsenes
NSL
NSL
270 U
330 U
15 U
4.6 J
4.2 J
3.9 J
1300 U
2500 U
35 J
2.9 J
C4-Naohthalenes
NSL
NSL
150 J
160 J
37 J
30 J
31 J
29 J
840 J
5500 J
390 J
19 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
140 J
39 J
23 J
21 J
19 J
910 J
400 J
15 J
Chrvsene(a)
166
1290
1100
67
9.2
14
8.9
111)01)
1400
7.5
Dibenzo(a,h)anthracene!a'
33
NSL
260 J
43ft
17
1.2 J
3.7 J
0.92 J
1200 J
1300.1
140 J
0.75 J
Fluoranthene!a'
423
2230
1300
230ft
83
7.9
10
5.2
6900
-)(){)(){)
1800
9.4
Fluorene!a'
77.4
536
270 U
330 U
11 J
2.4 J
2.2 J
1.4 J
1300 U
1500.1
210 J
1.7 J
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
us/ks
660
1100
44
3.2 J
8.7
2.3 J
3100
420
2 J
Naphthalene!a'
176
561
us/ks
270 U
330 U
15 U
4.7U
4.4 U
4.4 U
1300 U
2500 U
330 U
4.3 U
Pervlene
NSL
NSL
320
460
39
35
37
31
1.»ii i
32
Phenanthrene !a'
204
1170
610
930
41
6.6
7
4.4
35ftft
llftftft
1401)
7.4
Pyrene(a)
195
1520
1400
220ft
95
9.3
11
6.2
"Iftft
161)1)1)
2"ftft
11
Total PAH17 ND=1/2RL
1601.0
22800.0
11520.0
l~233.ft
715.500
73.6500
118.200
54.82
5"44ft.ft
121241)
15152.11
.9000
Total PAID 4 ND=1/2RL
1601.0
22800.0
15588.0
23157.0
1136.60
242.300
297.000
196.f
"N56ft.ft
rxftXI)
2512".!)
6.450
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
pg/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 19 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-39
RREC13-39
RREC13-39
RREC13-40
RREC13-40
RREC13-40
RREC13-40
RREC13-40
RREC13-41
RREC1341
RREC13-39-0507
RREC13-39-0709
RREC13-39-0911
RREC13-40-SURF
RREC13-40-0001
RREC13 40-0103
RREC13-40-0305
RREC13 40-0507
RREC13-41-SURF
RREC1341-0001
Sample Depth (ft):
5-7
7-9
9-11
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-1
Date Sampled:
10/30/13
10/30/13
10/30/13
10/28/13
11/1/13
11/1/13
11/1/13
11/1/13
10/30/13
10/31/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
1 J
1.3 J
2 J
44 J
3.7 J
2.5 J
3.1 J
3.5 J
1100 U
5800
2-MethvinaDhthalene(a)(b)
NSL
NSL
4.3 U
4.3 U
4.6 U
85 J
4.3 J
2.1 J
2.2 J
2.5 J
900 J
8300
Acenaohthene'3'
NSL
NSL
0.22 J
0.26 J
0.42 J
83 J
11 J
1.1 J
0.68 J
0.75 J
590 J
1700 J
Acenaohthvlene!a'
NSL
NSL
4.3 U
4.3 U
0.18 J
110 J
33 U
4 U
5 U
5 U
Anthracene !a'
57.2
845
0.26 J
0.36 J
0.66 J
400
24 J
1.6 J
0.43 J
0.76 J
1600
5400
Benzo(a)anthracene !a'
108
1050
4.3 U
4.3 U
4.6 U
110
7
5 U
5 U
3500
^600
Benzolalovrene!a'
150
1450
0.59 J
0.84 J
2 J
2000
95
5.2
2.2 J
1.9 J
2400
5100
Benzo(b)fluoranthene!a'
NSL
NSL
4.3 U
4.3 U
5.1
1800
69
8.3
5.1
5.2
2600
3900
Benzo(e)Dvrene
NSL
NSL
2.4 J
2.7 J
4.3 J
1300
75
6.8
4.9 J
5.1 J
2100
3700
Benzo(a,hi)pervlene!a'
NSL
NSL
US/ks
2.3 J
2.6 J
4.1 J
750
64
9
7.5
7.8
1400
3000
Benzo(k)fluoranthene !a'
NSL
NSL
US/ks
4.3 U
4.3 U
4.6 U
1800
75
5
2.1 J
2.3 J
1800
3700
CI Chrvsenes
NSL
NSL
6.7 J
7.9 J
11 J
1200 J
130 J
23 J
16 J
16 J
5800 J
10000 J
CI Fluorenes
NSL
NSL
1.1 J
1.4 J
1.7 J
44 J
9.1 J
2.4 J
2.6 J
2.6 J
710 J
2100 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
8.7 J
10 J
15 J
2100 J
180 J
18 J
12 J
12 J
6300 J
14000 J
Cl-Naohthalenes
NSL
NSL
1.3 J
1.7 J
2.5 J
90 J
5.8 J
3.5 J
3.8 J
4.4 J
1100 J
10000 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
12 J
14 J
21 J
940 J
140 J
29 J
27 J
26 J
10000 J
23000 J
C2 Chrvsenes
NSL
NSL
12 J
14 J
21 J
1100 J
81 J
25 J
22 J
26 J
6700 J
8100 J
C2 Fluorenes
NSL
NSL
2.6 J
2.6 J
3.7 J
77 J
19 J
4.5 J
4.6 J
4.4 J
2100 J
2800 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
10 J
11 J
16 J
970 J
110 J
17 J
14 J
14 J
7000 J
10000 J
C2-Naohthalenes
NSL
NSL
5.1 J
5.8 J
8.9 J
240 J
29 J
13 J
14 J
17 J
6300 J
21000 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
14 J
15 J
22 J
660 J
120 J
28 J
26 J
27 J
18000 J
19000 J
C3 Chrvsenes
NSL
NSL
5.7 J
6.6 J
9.1 J
350 J
30 J
12 J
11 J
13 J
3200 J
4400 J
C3 Fluorenes
NSL
NSL
4.1 J
4.3 J
6.3 J
160 J
29 J
8.8 J
9.1 J
8.3 J
5700 J
5200 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
9.5 J
11 J
16 J
440 J
62 J
18 J
15 J
17 J
6400 J
6600 J
C3-Naohthalenes
NSL
NSL
16 J
18 J
30 J
300 J
69 J
35 J
36 J
39 J
10000 J
15000 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
22 J
26 J
36 J
590 J
91 J
36 J
38 J
37 J
22000 J
15000 J
C4 Chrvsenes
NSL
NSL
3.3 J
3.2 J
5 J
64 J
7.9 J
5.2 J
5.8 J
5.8 J
1900 J
2100 J
C4-Naohthalenes
NSL
NSL
18 J
23 J
32 J
190 J
52 J
37 J
36 J
38 J
9000 J
9300 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
us/ks
14 J
17 J
22 J
">70 J
45 J
21 J
20 J
20 J
Chrvsene(a)
166
1290
4.4
5.4
8.2
1700
110
11
87
87
4300
"200
Dibenzo(a,h)anthracene!a'
33
NSL
US/ks
0.26 J
0.35 J
0.52 J
220 J
18 J
1.8 J
0.93 J
1 J
4X0.1
1100.1
Fluoranthene!a'
423
2230
us/ks
4.3 U
4.3 U
5.3
2200
140
9.7
5.6
5 U
4X00
12000
Fluorene!a'
77.4
536
us/ks
0.89 J
1.3 J
1.5 J
110 J
8.6 J
2.1 J
2.6 J
2.8 J
1500
3100
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
us/ks
0.64 J
0.79 J
1.3 J
680
45
4.7 J
2.5 J
2.6 J
1300
Naphthalene!a'
176
561
us/ks
4.3 U
4.3 U
4.6 U
340 U
33 U
4 U
5 U
5 U
5400
Pervlene
NSL
NSL
32
27
37
490
42
43
45
36
Phenanthrene !a'
204
1170
4.3 U
4.3 U
4.8
Sfll
40
7
6.5
7.8
5100
14000
Pyrene(a)
195
1520
4.3 U
4.3 U
6.5
1X01)
190
13
6.3
5.4
6100
14000
Total PAH17 ND=1/2RL
1601.0
22800.0
28.9100
31.2500
49.7800
1005S.0
1036.90
92.6000
60.8400
59.5100
3*>4—0.0
100500
Total PAID 4 ND=1/2RL
1601.0
22800.0
139.660
149.100
216.480
-23204*0
1782.70
288.000
247.840
235.410
121100
INK100
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
Ug/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 20 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41-0103
RREC13-41-0103-FD
RREC13-41-0305
RREC13-41-0305-FD
RREC13-41-0507
RREC13-41-0507-FD
RREC13-41-0709
RREC13-41-0709-FD
RREC13-41-0911
RREC13-41-0911-FD
Sample Depth (ft):
1-3
1-3
3-5
3-5
5-7
5-7
7-9
7-9
9-11
9-11
Date Sampled:
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
5900
3700
920 U
830
2400
2500
9400
8400
10000
10000
2-MethvinaDhthalene(a)(b)
NSL
NSL
8600
5300
1200
1200
3400
3600
14000
12000
15000
15000
Acenaohthene'3'
NSL
NSL
1800 J
1200 J
690 J
620 J
800 J
940 J
2400 J
2100 J
4300 J
4400 J
Acenaohthvlene!a'
NSL
NSL
....
....
....
Anthracene !a'
57.2
845
NODI)
4900
1600
1600
10000
xxoo
15000
14000
Benzo(a)anthracene (a)
108
1050
us/ks
0X00
-TJ00
3600
301)0
10000
oi oo
16000
16000
Benzolalovrene!a'
150
1450
(MM
4000
2600
2900
4200
"300
6300
11000
12000
Benzo(b)fluoranthene!a'
NSL
NSL
5100
3600
2500
2500
2900
3200
5100
4400
7700
8300
Benzo(e)Dvrene
NSL
NSL
4400
3300
2100
2200
2900
3200
4700
4000
6700
7200
Benzo(a,hi)pervlene!a'
NSL
NSL
US/ks
3800
2800
1700
1600
2300
2600
4100
3000 J
4800 J
4800 J
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
4400
3100
2100
2500
2800
3000
4600
4500
7600
8400
CI Chrvsenes
NSL
NSL
12000 J
8600 J
5200 J
5500 J
7100 J
8200 J
13000 J
10000 J
19000 J
19000 J
CI Fluorenes
NSL
NSL
2500 J
1500 J
690 J
560 J
970 J
1000 J
3100 J
2800 J
4700 J
4500 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
19000 J
12000 J
5700 J
5900 J
8500 J
9900 J
19000 J
18000 J
31000 J
31000 J
Cl-Naohthalenes
NSL
NSL
10000 J
6400 J
1400 J
1400 J
4100 J
4300 J
16000 J
15000 J
18000 J
18000 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
26000 J
17000 J
9800 J
7400 J
12000 J
14000 J
30000 J
24000 J
43000 J
42000 J
C2 Chrvsenes
NSL
NSL
8200 J
6600 J
5100 J
5600 J
6000 J
6800 J
9600 J
9300 J
13000 J
14000 J
C2 Fluorenes
NSL
NSL
2700 J
1800 J
1800 J
1400 J
1500 J
1800 J
3000 J
2700 J
4300 J
4700 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
11000 J
7700 J
5600 J
5500 J
7000 J
8300 J
12000 J
11000 J
17000 J
17000 J
C2-Naohthalenes
NSL
NSL
24000 J
14000 J
5100 J
5000 J
10000 J
11000 J
34000 J
31000 J
45000 J
42000 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
17000 J
13000 J
14000 J
11000 J
11000 J
13000 J
19000 J
17000 J
28000 J
29000 J
C3 Chrvsenes
NSL
NSL
4000 J
3300 J
2900 J
2400 J
3200 J
3400 J
4800 J
4600 J
5300 J
5700 J
C3 Fluorenes
NSL
NSL
4100 J
3000 J
4700 J
4100 J
3500 J
4000 J
4600 J
4000 J
5400 J
5700 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
6400 J
5000 J
4700 J
4600 J
5100 J
5900 J
7000 J
5800 J
8700 J
8700 J
C3-Naohthalenes
NSL
NSL
16000 J
10000 J
6500 J
6200 J
8500 J
9700 J
21000 J
19000 J
26000 J
25000 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
14000 J
11000 J
13000 J
14000 J
12000 J
13000 J
14000 J
14000 J
18000 J
19000 J
C4 Chrvsenes
NSL
NSL
1800 J
1600 J
1400 J
1600 J
1600 J
1900 J
2100 J
2100 J
2400 J
2700 J
C4-Naohthalenes
NSL
NSL
7100 J
5300 J
6100 J
5500 J
5600 J
6200 J
9300 J
8600 J
11000 J
11000 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
" Inn J
Chrvsene(a)
166
1290
0100
6300
3X00
4100
4"00
5"00
9200
X200
14000
15000
Dibenzo(a,h)anthracene!a'
33
NSL
us/1
1300.1
1000 .1
630 .1
640 .1
1500 .1
1200.1
1X00 .1
2000.1
Fluoranthene!a'
423
2230
13000
9000
6600
5200
6900
-xoo
15000
12000
21000
22000
Fluorene!a'
77.4
536
4600
201)0
1400
1500
1500
X200
6000
X400
XOOO
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
3000 J
2400
1500
1500
1900
2300
3400 J
Naphthalene!a'
176
561
us/1
4~00
3500
2300
2400
3400
XI00
6900
"900
X"00
Pervlene
NSL
NSL
SHU
'Mi i.l
Phenanthrene !a'
204
1170
20000
12000
5100
4500
25000
22000
36000
35000
Pyrene(a)
195
1520
US/1
1X000
12000
5"00
6200
xooo
0500
20000
1X000
33000
33000
Total PAH17 ND=1/2RL
1601.0
22800.0
125500
X2450.0
434X0M
432"0.0
59900.0
6X440M
153000
131400
210950
213600
Total PAID 4 ND=1/2RL
1601.0
22800.0
21"000
14X140
103500
99220
11"610
134—0
24"300
216200
350150
356000
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
Ug/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 21 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-42
RREC1342
RREC13-42
RREC13-42
RREC1344
RREC13-44
RREC1344
RREC13-44
RREC1344
RREC13-45
Sample Name:
RREC13-42-SURF
RREC13 42-0001
RREC13-42-0103
RREC13-42-0305
RREC1344-SURF
RREC13-44-0001
RREC13 44-0103
RREC13-44-0305
RREC13 44-0507
RREC13-45-SURF
Sample Depth (ft):
0-0.5
0-1
1-3
3-5
0-0.5
0-1
1-3
3-5
5-7
0-0.5
Date Sampled:
11/4/13
11/4/13
11/4/13
11/4/13
10/30/13
11/1/13
11/1/13
11/1/13
11/1/13
10/29/13
Analvte
TEC
PEC
Units
l-Methvlnaohthalene(b)
NSL
NSL
99 J
5.6 J
1.7 J
0.44 J
69 J
77 J
100 J
310 J
410 J
200 J
2-Methvlnaohthalene(a) 031
NSL
NSL
250 U
11 U
4.2 U
4.6 U
130 J
380 U
350 U
420
610 J
350 J
Acenaohthene'3'
NSL
NSL
150 J
12
1.2 J
0.44 J
82 J
140 J
120 J
220 J
320 J
230 J
Acenaohthvlene !a'
NSL
NSL
92 J
2.4 J
0.43 J
0.16 J
72 J
89 J
64 J
100 J
Anthracene !a'
57.2
845
420
20
1.8 J
0.57 J
400
430
220 J
230 J
410 .1
1000
Benzo(a)anthracene!a'
108
1050
1300
22
5
1.3 J
<1100 <
980
1000
3400
Benzolalovrene !a'
150
1450
1100
17
3.1 J
1.2 J
1200
1700
930
890
1500
3600
Benzo(b)fluoranthene !a'
NSL
NSL
920
11 J
5.6
5.5
1100
1900
1100
1100
1500
3000
Benzo(e)Dvrene
NSL
NSL
730
13
5.7
3.4 J
920
1200
730
760
1200
2200
Benzo(sJi,i)pervlene !a'
NSL
NSL
us/ks
540
9.5 J
4.9
0.83 J
810
700
350
360
670 J
1500
Benzo(k)fluoranthene!a'
NSL
NSL
us/ks
990
15
3.5 J
2.5 J
1200
1600
780
770
1500
2700
CI Chrvsenes
NSL
NSL
700 J
16 J
12 J
2.1 J
820 J
1100 J
1200 J
1500 J
2500 J
2100
CI Fluorenes
NSL
NSL
69 J
5.6 J
1.1 J
4.6 U
49 J
92 J
170 J
440 J
720 J
130
Cl-Fluoranthenes/Pvrenes
NSL
NSL
1400 J
35 J
14 J
2.5 J
1300 J
1800 J
1800 J
2700 J
4300 J
3900
Cl-Naohthalenes
NSL
NSL
170 J
9.6 J
2.5 J
0.69 J
130 J
160 J
160 J
490 J
690 J
370
Cl-Phenanthrenes/Anthracenes
NSL
NSL
990 J
52 J
13 J
3.1 J
750 J
1300 J
2400 J
4600 J
8500 J
2100
C2 Chrvsenes
NSL
NSL
420 J
7.8 J
21 J
2.3 J
780 J
1500 J
2800 J
3400 J
4800 J
1400
C2 Fluorenes
NSL
NSL
85 J
7.2 J
2.1 J
0.5 J
100 J
250 J
680 J
1600 J
2500 J
170
C2-Fluoranthenes/Pvrenes
NSL
NSL
640 J
16 J
14 J
2.1 J
930 J
1300 J
2200 J
3400 J
4800 J
1700
C2-Naohthalenes
NSL
NSL
500 J
55 J
9.8 J
2.9 J
410 J
480 J
1000 J
3500 J
6100 J
1100
C2-Phenanthrenes/Anthracenes
NSL
NSL
540 J
26 J
14 J
3.1 J
670 J
1300 J
3600 J
7100 J
13000 J
1300
C3 Chrvsenes
NSL
NSL
130 J
2.6 J
9.6 J
1.2 J
410 J
750 J
1300 J
1900 J
2700 J
530
C3 Fluorenes
NSL
NSL
80 J
8.5 J
5 J
4.6 U
280 J
620 J
2000 J
3800 J
6800 J
300
C3-Fluoranthenes/Pvrenes
NSL
NSL
280 J
7.3 J
14 J
1.7 J
720 J
1100 J
2400 J
3400 J
5300 J
950
C3-Naohthalenes
NSL
NSL
650 J
64 J
20 J
4.7 J
480 J
840 J
3300 J
9600 J
14000 J
1000
C3-Phenanthrenes/Anthracenes
NSL
NSL
400 J
18 J
22 J
2.8 J
840 J
1300 J
4600 J
10000 J
13000 J
1100
C4 Chrvsenes
NSL
NSL
54 J
1.4 J
3.1 J
4.6 U
180 J
330 J
550 J
1000 J
1600 J
130
C4-Naohthalenes
NSL
NSL
310 J
29 J
15 J
3.1 J
350 J
850 J
3300 J
7900 J
14000 J
650
C4-Phenanthrenes/Anthracenes
NSL
NSL
200 J
10 J
15 J
2.3 J
740 J
1100 J
3600 J
7600 J
Chrvsene (a)
166
1290
1100
21
88
2.2 J
1200
1600
1100
1100
2000
3200
Dibenzo(aJi)anthracene !a'
33
NSL
150 J
2 J
0.58 J
0.19 J
210 J
220 J
85 J
85 J
170 .1
400.1
Fluoranthene
423
2230
2100
47
8.2
4.6 U
1800
3200
1800
5100
4300
Fluorene !a'
77.4
536
190 J
16
18 J
0.74 J
130 J
180 J
120 J
340
390 .1
370.1
Indeno(l,2J3-cd)pvrene !a'
NSL
NSL
470
6.8 J
1.7 J
0.49 J
690
670
330 J
300 J
Naphthalene !a'
176
561
330
11 U
4.2 U
4.6 U
290 U
380 U
350 U
320 U
690
Pervlene
NSL
NSL
310
72
3.9 J
5.8
370
500
380
[--
"I..
Phenanthrene!a'
204
1170
1100
65
6.2
4.6 U
780
1000
770
1300
2400
2200
Pyrene (a)
195
1520
1600
39
10
4.6 U
1400
1800
1500
2000
3700
3800
Total PAH17 ND=1/2RL
1601.0
22800.0
12677.0
316.700
67.0100
27.6200
12449.0
1720*) .0
10599.11
123"?.0
23150J)
32310.0
Total PAH34 ND=1/2RL
1601.0
22800.0
17356.0
558.500
160.710
53.4200
18338.0
26481.0
30384J)
51035.0
82140
44O80.0
NOTES
Presented results are not normalized to organic carbon
w Included in calculation oftotal 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
lig/kg = Micrograms per kilogram
NSI^No screening level
TEC = Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC =Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 22 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
RREC13-45
RREC1345
RREC13-45
RREC13-46
RREC1346
RREC13-46
RREC1346
RREC13-46
RREC1346
RREC13-47
Sample Name:
RREC13-45-0001
RREC1345-0103
RREC13-45-0305
RREC13-46-SURF
RREC13 46-0001
RREC13-46-0103
RREC13 46-0305
RREC13-46-0507
RREC13 46-0710
RREC13-47-SURF
Sample Depth (ft):
0-1
1-3
3-5
0-0.5
0-1
1-3
3-5
5-7
7-10
0-0.5
Date Sampled:
11/1/13
11/1/13
11/1/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
Analvte
TEC
PEC
Units
l-Methvlnaohthalene(b)
NSL
NSL
190 J
91 J
21
440 J
280 J
46 J
5.6 J
4.6 J
3.9 J
150 J
2-Methvlnaohthalene(a) 031
NSL
NSL
510 U
210 U
24
2400 U
2700 U
360 U
11 U
21 U
4 U
280 J
Acenaohthene'3'
NSL
NSL
220 J
180 J
13
1400 J
1500 J
82 J
7.6 J
6.9 J
2.4 J
120 J
Acenaohthvlene !a'
NSL
NSL
110 J
33 J
4.2 ~
-i-
2.3 J
2 J
0.67 J
86 J
Anthracene !a'
57.2
845
65ft
400
1!
42ft
11 U
21 U
4 U
360
Benzo(a)anthracene!a'
108
1050
r»»
520
4!
Iftftftft
15ftftft
13ftft
50
64
15
150ft
Benzolalovrene !a'
150
1450
16ftft
380
3:
SOW)
13ftftft
SOU
40
50
15
16ftft
Benzo(b)fluoranthene !a'
NSL
NSL
1800
410
34
8600
12000
900
53
60
17
1800
Benzo(e)Dvrene
NSL
NSL
1100
250
33
5400
8100
670
38
42
16
1200
Benzo(sJi,i)pervlene !a'
NSL
NSL
us/ks
700
150 J
25
5500
8000
640
39
44
14
880
Benzo(k)fluoranthene!a'
NSL
NSL
us/ks
1300
340
29
7200
11000
1100
39
44
13
1300
CI Chrvsenes
NSL
NSL
1000 J
370 J
71 J
4200 J
6600
520 J
42 J
42 J
25 J
1100 J
CI Fluorenes
NSL
NSL
130 J
110 J
23 J
300 J
450 J
44 J
3.7 J
3.8 J
2.5 J
84 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
2300 J
840 J
110 J
9100 J
12000 J
1200 J
72 J
72 J
32 J
1800 J
Cl-Naohthalenes
NSL
NSL
280 J
110 J
32 J
780 J
550 J
74 J
8.1 J
6.7 J
5 J
290 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
1800 J
1100 J
240 J
4800 J
3400 J
470 J
42 J
46 J
35 J
1100 J
C2 Chrvsenes
NSL
NSL
1100 J
510 J
98 J
2200 J
3700 J
320 J
51 J
50 J
46 J
1200 J
C2 Fluorenes
NSL
NSL
200 J
170 J
51 J
250 J
1000 J
76 J
11 J
11 J
6.4 J
200 J
C2-Fluoranthenes/Pvrenes
NSL
NSL
1200 J
510 J
110 J
3100 J
5500 J
450 J
56 J
55 J
41 J
1300 J
C2-Naohthalenes
NSL
NSL
1200 J
830 J
180 J
2400 U
2700 U
360 U
24 J
22 J
19 J
920 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
1400 J
1000 J
200 J
2400 U
2700 U
360 U
52 J
54 J
44 J
1100 J
C3 Chrvsenes
NSL
NSL
440 J
240 J
53 J
680 J
1400 J
120 J
31 J
26 J
26 J
520 J
C3 Fluorenes
NSL
NSL
460 J
370 J
73 J
2400 U
2300 J
180 J
29 J
27 J
16 J
530 J
C3-Fluoranthenes/Pvrenes
NSL
NSL
660 J
370 J
110 J
1200 J
3100 J
230 J
49 J
45 J
40 J
930 J
C3-Naohthalenes
NSL
NSL
1600 J
1500 J
570 J
2400 U
2700 U
360 U
48 J
47 J
46 J
1300 J
C3-Phenanthrenes/Anthracenes
NSL
NSL
1400 J
1100 J
300 J
2400 U
2700 U
360 U
93 J
96 J
78 J
1400 J
C4 Chrvsenes
NSL
NSL
180 J
110 J
28 J
2400 U
550 J
48 J
9.6 J
9.5 J
14 J
220 J
C4-Naohthalenes
NSL
NSL
1000 J
1200 J
420 J
2400 U
3800 J
360 U
69 J
68 J
61 J
1100 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
670 J
20(
67 J
69 J
54 J
1100 J
Chrvsene (a)
166
1290
480
6'
8901)
14000
llftft
52
62
24
1600
Dibenzo(aJi)anthracene !a'
33
NSL
2211.1
49 J
4.9
16011.1
2500.1
1811.1
8 8 J
11 J
2.4 J
230 J
Fluoranthene
423
2230
1300
7:
'0000
21000
261)0 ; o
83
110
19
2400
Fluorene !a'
77.4
536
3511.1
280
2:
2000 .1
1100.1
260.1
7.4 J
6.9 J
3 J
180 J
Indeno(l,2J3-cd)pvrene !a'
NSL
NSL
us/ks
140 J
1'
5000
29
34
7.4
800
Naphthalene !a'
176
561
us/ks
510 U
210 U
1:
2600
12
21 U
4 U
390
Pervlene
NSL
NSL
i:to.i
120 J
1!
27
29
15
460
Phenanthrene!a'
204
1170
1000
11
140011
7100
1700
34
36
12
llftft
Pyrene (a)
195
1520
2400
870
7:
1401111
1501111
1800
72
91
23
19ftft
Total PAH17 ND=1/2RL
1601.0
22800.0
1X53ft.ll
6742.00
611.
115~lft
13493ft
13966.0
540.100
653.300
173.870
16526.11
Total PAH34 ND=1/2RL
1601.0
22800.0
2S355.0
12367.0
1836.1ft
141"6ft
16493ft
17146.0
969.30
1092.60
470.770
2522ft.ft
NOTES
Presented results are not normalized to organic carbon
w Included in calculation oftotal 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
lig/kg = Micrograms per kilogram
NSI^No screening level
TEC = Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC =Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 23 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-47
RREC13-47
RREC13-47
RREC13-47
RREC13-47
RREC1347
RREC13-47
RREC1347
RREC13-47
RREC1348
RREC1347-SURF-FT
RREC13-47-0001
RREC13 47-0103
RREC13 47-0103-FD
RREC13-47-0305
RREC13 47-0305-FD
RREC13-47-0507
RREC13 47-0709
RREC13-47-0911
RREC1348-SURF
Sample Depth (ft):
0-0.5
0-1
1-3
1-3
3-5
3-5
5-7
7-9
9-11
0-0.5
Date Sampled:
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
150 J
150 J
99 J
90 J
250 J
150 J
610
590 U
930 J
240 J
2-MethvinaDhthalene(a)(b)
NSL
NSL
280 J
290 U
450 U
430 U
620 U
520 U
450
590 U
1200
420 J
Acenaohthene'3'
NSL
NSL
140 J
140 J
210 J
200 J
270 J
250 J
340 J
490 J
550 J
310 J
Acenaohthvlene!a'
NSL
NSL
Anthracene !a'
57.2
845
400
310
430 .1
490
490.1
560
5X0
6X0
900.1
900
Benzo(a)anthracene !a'
108
1050
1900
1400
1900
2000
2000
2300
1X00
2100
3100
3500
Benzolalovrene!a'
150
1450
2000
If 00
2000
2000
2000
2400
1600
2100
2X00
3600
Benzo(b)fluoranthene!a'
NSL
NSL
1800
1500
2000
1900
2000
2400
1800
1900
2700
3000
Benzo(e)Dvrene
NSL
NSL
1400
1100
1400
1400
1400
1700
1300
1600
2000
2200
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
1000
850
1000
1100
940
1300
1300
1400
1100
2200
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
1900
1500
1900
1800
2000
2200
1200
1500
2600
3000
CI Chrvsenes
NSL
NSL
1200 J
960 J
1400 J
1300 J
1500 J
1600 J
1800 J
2300 J
2800 J
2100 J
CI Fluorenes
NSL
NSL
86 J
78 J
120 J
130 J
230 J
170 J
320 J
620 J
900 J
170 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
2100 J
1600 J
2200 J
2200 J
2800 J
2900 J
2300 J
2900 J
6200 J
3700 J
Cl-Naohthalenes
NSL
NSL
290 J
260 J
190 J
170 J
310 J
220 J
750 J
740 J
1500 J
470 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
1300 J
1100 J
1700 J
1700 J
2900 J
2300 J
2800 J
4700 J
10000 J
2400 J
C2 Chrvsenes
NSL
NSL
1200 J
930 J
1500 J
1300 J
2200 J
1800 J
2200 J
2400 J
4400 J
1400 J
C2 Fluorenes
NSL
NSL
210 J
190 J
340 J
320 J
740 J
520 J
1100 J
1800 J
2400 J
300 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
1200 J
1100 J
1600 J
1500 J
2200 J
2100 J
2300 J
2900 J
5500 J
2000 J
C2-Naohthalenes
NSL
NSL
960 J
1000 J
840 J
770 J
2000 J
1200 J
5200 J
7300 J
14000 J
1600 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
1200 J
1100 J
1900 J
1800 J
3500 J
2700 J
4700 J
7200 J
11000 J
1700 J
C3 Chrvsenes
NSL
NSL
510 J
490 J
690 J
590 J
990 J
830 J
1300 J
1200 J
1800 J
640 J
C3 Fluorenes
NSL
NSL
600 J
580 J
950 J
900 J
2100 J
1600 J
2700 J
4000 J
4900 J
640 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
900 J
750 J
1100 J
1000 J
1700 J
1600 J
2100 J
2300 J
3800 J
1100 J
C3-Naohthalenes
NSL
NSL
1300 J
1400 J
1700 J
1400 J
4100 J
2400 J
7400 J
13000 J
21000 J
2200 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
1400 J
1400 J
2200 J
2000 J
4200 J
3300 J
6000 J
7700 J
11000 J
1600 J
C4 Chrvsenes
NSL
NSL
180 J
160 J
270 J
250 J
460 J
390 J
760 J
720 J
890 J
250 J
C4-Naohthalenes
NSL
NSL
1100 J
1100 J
1800 J
1700 J
3700 J
2500 J
6600 J
12000 J
15000 J
1500 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
Chrvsene(a)
166
1290
1900
1500
1900
2000
1900
2300
1900
2200
3000
3400
Dibenzo(a,h)anthracene!a'
33
NSL
us/ks
290 .1
260.1
310 .1
330 .1
240.1
390 .1
420.1
4~0 .1
360.1
650 .1
Fluoranthene!a'
423
2230
3100
2200
3200
3500
3~00
4400
2400
3100
5900
4X00
Fluorene!a'
77.4
536
us/ks
200 .1
140.1
250 .1
1~0 .1
240.1
260 .1
490
420 .1
6~0.1
3X0 .1
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
us/ks
810
970
890
1300
Naphthalene!a'
176
561
us/ks
290 U
450 U
430 U
620 U
520 U
450
590 U
980 U
"X0
Pervlene
NSL
NSL
Phenanthrene !a'
204
1170
1.300
1100
1200
1400
1X00
roo
2000
2"00
4600
2600
Pyrene(a)
195
1520
2300
1X00
2300
2300
2900
3200
3300
4200
5400
3900
Total PAH17 ND=1/2RL
1601.0
22800.0
19X60.0
153X4.0
20120.0
20"20JI
22120.0
25500.0
21350.0
25445.0
366X0.0
356"0J)
Total PAID 4 ND=1/2RL
1601.0
22800.0
20426.0
23",2"\0
329X5J)
33145.0
43320.0
43560J)
46X40.0
61360
91320
50190J)
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
pg/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 24 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-48
RREC13-48
RREC13-48
RREC13-48
RREC13-48
RREC1348
RREC13-49
RREC1349
RREC13-49
RREC1349
RREC1348-SURF-FT
RREC13-48-0001
RREC13 48-0103
RREC13 48-0305
RREC13-48-0507
RREC13 48-0710
RREC13-49-SURF
RREC1349-SURF-FT
RREC13-49-0001
RREC13 49-0103
Sample Depth (ft):
0-0.5
0-1
1-3
3-5
5-7
7-10
0-0.5
0-0.5
0-1
1-3
Date Sampled:
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
180 J
100 J
630
880
820
620
220 J
250 J
300 J
850
2-MethvinaDhthalene(a)(b)
NSL
NSL
320 J
190 J
1100
1500
1300
980
400 J
440 J
560 U
1300
Acenaohthene'3'
NSL
NSL
270 J
170 J
310 J
700 J
420 J
420 J
320 J
400 J
310 J
570 J
Acenaohthvlene!a'
NSL
NSL
Anthracene !a'
57.2
845
020 .1
540
610
970
"SO
600
1100
1400
6~0
1000
Benzo(a)anthracene !a'
108
1050
2400
2300
2*700
2400
2000
4600
5100
2600
3400
Benzolalovrene!a'
150
1450
2X00
2000
2400
2400
2400
2000
4-00
5600
2400
3300
Benzo(b)fluoranthene!a'
NSL
NSL
2200
1800
2500
2200
2600
1900
4400
4600
2300
3200
Benzo(e)Dvrene
NSL
NSL
1700
1300
1800
1700
1700
1300
3000
3400
1600
2200
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
1900
1300
910
1100
840
720
3100
3500
1300
1100
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
2100
1600
2600 J
2200
2300 J
1800 J
3700
4200
2000
3300 J
CI Chrvsenes
NSL
NSL
1600 J
1300 J
1600 J
2100 J
2000 J
1900 J
2700 J
3100 J
1800 J
2700 J
CI Fluorenes
NSL
NSL
130 J
79 J
360 J
660 J
910 J
620 J
140 J
150 J
390 J
770 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
2600 J
2100 J
3100 J
3800 J
4100 J
3600 J
4800 J
5000 J
3400 J
5700 J
Cl-Naohthalenes
NSL
NSL
350 J
210 J
1200 J
1600 J
1500 J
1100 J
430 J
480 J
400 J
1500 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
1800 J
1100 J
3700 J
6000 J
8900 J
7300 J
2300 J
2500 J
4100 J
8200 J
C2 Chrvsenes
NSL
NSL
1000 J
800 J
2500 J
1800 J
3200 J
3300 J
1500 J
1700 J
1500 J
4000 J
C2 Fluorenes
NSL
NSL
260 J
130 J
990 J
1800 J
2500 J
1700 J
210 J
210 J
1000 J
2000 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
1500 J
1100 J
2200 J
3000 J
3100 J
3000 J
2300 J
2600 J
2200 J
4000 J
C2-Naohthalenes
NSL
NSL
1300 J
590 J
5000 J
10000 J
10000 J
7100 J
1100 J
1200 J
3500 J
8900 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
1400 J
750 J
3900 J
6400 J
8800 J
7400 J
1300 J
1500 J
3900 J
8700 J
C3 Chrvsenes
NSL
NSL
410 J
330 J
1100 J
1100 J
1300 J
1300 J
600 J
620 J
640 J
1600 J
C3 Fluorenes
NSL
NSL
570 J
260 J
2100 J
3700 J
4500 J
3200 J
350 J
400 J
2200 J
3800 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
880 J
600 J
1500 J
2300 J
2300 J
2300 J
1100 J
1300 J
1500 J
2800 J
C3-Naohthalenes
NSL
NSL
1900 J
670 J
8200 J
17000 J
19000 J
14000 J
1100 J
1200 J
8400 J
17000 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
1400 J
790 J
3800 J
6600 J
7100 J
5900 J
1200 J
1300 J
4200 J
8000 J
C4 Chrvsenes
NSL
NSL
190 J
130 J
530 J
610 J
660 J
660 J
270 J
280 J
360 J
800 J
C4-Naohthalenes
NSL
NSL
1400 J
470 J
5400 J
10000 J
13000 J
9300 J
660 J
670 J
5900 J
11000 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
Chrvsene(a)
166
1290
2400
1000
2400
2000
2500
2100
4400
4X00
2~00
3600
Dibenzo(a,h)anthracene!a'
33
NSL
460 .1
300.1
240 .1
200 .1
220.1
100 .1
"50.1
OXO .1
200.1
300 .1
Fluoranthene!a'
423
2230
4400
5~00
5200
4300
5~00
6600
4200
6~00
Fluorene!a'
77.4
536
2"0 .1
220.1
400 .1
060
600.1
400 .1
420.1
460 .1
4X0.1
X00 .1
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
1600
1100
850
780
650
2600
3000
Naphthalene!a'
176
561
620 U
460 U
510 U
800 U
610 U
550 U
560 U
Pervlene
NSL
NSL
680
Phenanthrene !a'
204
1170
1"00
1500
2500
4400
3~00
3300
3100
3400
2~00
4600
Pyrene(a)
195
1520
2400
3100
4300
3500
2000
5300
5600
3~00
5100
Total PAH17 ND=1/2RL
1601.0
22800.0
25420.1)
20240.0
2"045J)
33940M
30065.0
24X05J)
45360.0
50030J)
2~4"0.0
309-5J)
Total PAID 4 ND=1/2RL
1601.0
22800.0
36"60.0
2 60.0
492X5.0
6X550.0
-2~65
50535J)
60000.0
6~100J)
51660.0
X39"5
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
pg/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 25 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-4 SEDIMENT RESULTS FORPAHs
River Rouge/E corse Shoreline Area Site Characterization
Detroit River Area of Concern, E corse, Michigan (November 2013)
Sample Location:
RREC13-49
RREC13-49
RREC13-49
RREC13-50
RREC13-50
RREC13-50
RREC13-50
RREC13-50
RREC13 49-0305
RREC13-49-0507
RREC13-49-0710
RREC13-50-SURF
RREC13-50-0001
RREC13-50-0103
RREC13-50-0305
RREC13-50-0507
Sample Depth (ft):
3-5
5-7
7-10
0-0.5
0-1
1-3
3-5
5-7
Date Sampled:
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
Analvte
TEC
PEC
Units
1 -Methvlnaohthalene 031
NSL
NSL
860
340 J
460 J
120 J
2000 J
2700 J
1200 J
1200
2-MethvinaDhthalene(a)(b)
NSL
NSL
1400
560
850 U
220 U
5400 U
5200
2400 U
1900
Acenaohthene'3'
NSL
NSL
650 J
360 J
550 J
160 J
3900 J
5200
2300 J
1300
Acenaohthvlene!a'
NSL
NSL
....
....
Anthracene !a'
57.2
845
XW)
060
300
13000
9900
5900
3000
Benzo(a)anthracene !a'
108
1050
3600
24000
1X000
12000
5900
Benzolalovrene!a'
150
1450
3400
2500
2600
620
16000
12000
X000
3-00
Benzo(b)fluoranthene!a'
NSL
NSL
3200
2700
2700
980
14000
10000
8700
3700
Benzo(e)Dvrene
NSL
NSL
2400
1700
1800
620
10000
8100
5600
2700
Benzo(a,hi)pervlene!a'
NSL
NSL
us/ks
1200
1000
870
560
7500
6500
4600
2200
Benzo(k)fluoranthene !a'
NSL
NSL
us/ks
3100 J
2200 J
2700 J
850
17000
13000
7300
3300
CI Chrvsenes
NSL
NSL
3100 J
1900 J
1900 J
500
12000
11000 J
6900 J
4800 J
CI Fluorenes
NSL
NSL
820 J
310 J
480 J
52 J
1800 J
1500 J
720 J
610 J
Cl-Fluoranthenes/Pvrenes
NSL
NSL
5800 J
4400 J
4000 J
1100 J
26000 J
23000 J
14000 J
8800 J
Cl-Naohthalenes
NSL
NSL
1500 J
620 J
880 J
220 J
3400 J
5400 J
2200 J
2100 J
Cl-Phenanthrenes/Anthracenes
NSL
NSL
10000 J
4200 J
5200 J
650 J
20000 J
19000 J
10000 J
9900 J
C2 Chrvsenes
NSL
NSL
4300 J
2500 J
2700 J
300 J
7400 J
8200 J
4600 J
4500 J
C2 Fluorenes
NSL
NSL
2200 J
790 J
1100 J
55 J
1500 J
1700 J
900 J
1100 J
C2-Fluoranthenes/I>vrenes
NSL
NSL
4500 J
2800 J
2800 J
460 J
11000 J
12000 J
6700 J
5800 J
C2-Naohthalenes
NSL
NSL
9500 J
2400 J
3500 J
530 J
7500 J
12000 J
4300 J
5500 J
C2-Phenanthrenes/Anthracenes
NSL
NSL
9800 J
4600 J
5900 J
330 J
13000 J
13000 J
7300 J
8100 J
C3 Chrvsenes
NSL
NSL
1800 J
930 J
1100 J
82 J
3100 J
3300 J
1800 J
2300 J
C3 Fluorenes
NSL
NSL
4000 J
1800 J
2300 J
57 J
3300 J
4000 J
2000 J
2500 J
C3 -Fluoranthenes/Pvrenes
NSL
NSL
3100 J
1700 J
1900 J
210 J
5900 J
6500 J
3700 J
4400 J
C3-Naohthalenes
NSL
NSL
19000 J
5300 J
8100 J
460 J
7800 J
9800 J
4500 J
6400 J
C3 -Phenanthrenes/Anthracenes
NSL
NSL
8600 J
4800 J
6100 J
270 J
13000 J
15000 J
7400 J
8600 J
C4 Chrvsenes
NSL
NSL
910 J
470 J
510 J
39 J
1200 J
1800 J
800 J
1200 J
C4-Naohthalenes
NSL
NSL
12000 J
3900 J
5900 J
240 J
6200 J
6200 J
3200 J
4200 J
C4-Phenanthrenes/Anthracenes
NSL
NSL
Chrvsene(a)
166
1290
3"00
2"00
21000
rooo
Dibenzo(a,h)anthracene!a'
33
NSL
320 .1
300.1
240.1
1X0 .1
2600 .1
2200.1
15IIII .1
6"0 .1
Fluoranthene!a'
423
2230
4"000
32000
Fluorene!a'
77.4
536
K00 .1
400.1
230
*200
0X00
3000
'500
Indeno(l_2,3-cd)pvrene!a'
NSL
NSL
1100
890
830 J
540
7600
4200
176
561
14000
P000
Pervlene
NSL
NSL
If
< |ini 1
-
Phenanthrene !a'
204
1170
5400
241)0
4200
41000
32000
Pyrene(a)
195
1520
5300
3000
4300
1300
201)00
23000
14000
X300
Total PAH17 ND=1/2RL
1601.0
22800.0
42230M
20530.0
36X05.0
11542.0
2"0000
216000
130X00
"2560J)
Total PAID 4 ND=1/2RL
1601.0
22800.0
90440
55550.0
6N0I0.0
14<»10.0
36"000
30X000
1X3520
1199"0
NOTES
Presented results are not normalized to organic carbon
<41 Included in calculation of total 17PAH
Excluded from calculation oftotal 34PAH
B = Method Blank Contamination
E = Value exceeds the highest standard in the initial calibration range Value is estimated
J = Indicates that the concentration is an estimated value
U = Indicates the analyte was analyzed for but not detected
Ug/kg = Micrograms per kilogram
NSD= No screening level
TEC =Threshold effect concentration
Development and Evaluation of Consensus-Based Sediment
Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
PEC = Probable effect concentration
Development and Evaluation of Consensus-Based Sediment
Quality Guidelines for Freshwater Ecosystems (MacDonald et al 2000)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 26 of 26
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-5 SEDIMENT RESULTS FOR METALS AND TOTAL ORGANIC CARBON
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-01
RREC13-01
RREC13-01
RREC13-01
RREC 13-02
RREC 13-02
RREC 13-02
RREC 13-02
RREC 13-02
Sample Name:
RREC13-01 -SURF
RREC 13-01-0001
RREC13-01-0103
RREC 13-01-03 05
RREC13-02-SURF
RREC 13-02-0001
RREC 13-02-0103
RREC 13-02-03 05
RREC 13-02-0507
Sample Depth (ft):
0-0.5
0-1
1-3
3-5
0-0.5
0-1
1-3
3-5
5-7
Date Sampled:
10/31/13
10/30/13
10/31/13
10/31/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
13.5
10.5
10.2
15.2
10.6
12.3
18.8
14.9
17.3
Barium
NSL
NSL
mg/kg
142
158 J
180 J
230 J
50
70.4 J
111 J
114 J
152 J
Cadmium
0.99
4.98
mg/kg
8.7
16.2
4.4
4 J
0.71
1.9 J
3 J
3.7 J
4.5 J
Chromium
43.4
111
mg/kg
66.2
97 J
43 J
40.9
30.2
51.9 J
91.2 J
84.9 J
135 J
Copper
31.6
149
mg/kg
209 J
250
300
332
52.4 J
70.3
115
108
155
Iron
20000
40000
mg/kg
30500
32800 J
23000 J
26400
37000
81900
102000
59200
89100
Lead
35.8
128
mg/kg
229 J
301
401
451
49.2 J
161
276
218
305
Mercury
0.18
1.06
mg/kg
1.2
1.5
2.1
2.2
0.13 J
0.37 J
0.5 J
0.18 UJ
0.66 J
Nickel
22.7
48.6
mg/kg
38.9
46.8 J
43.4 J
40.1 J
22.1
42.2
66.6
62.8
71.7
Selenium
NSL
NSL
mg/kg
2.4 J
4.5 J
3.3 J
4.6 J
2.5 J
7.9
11.2
24.2
11.5
Silver
NSL
NSL
mg/kg
1.6
2
1.9
2
0.77 J
1.3
1.9
1.9
2.5
Zinc
121
459
mg/kg
577
648 J
907 J
997
219
740
1040
748
938
Total Organic Carbon
NSL
NSL
0/
/O
9.87
11.6
10.9
8.42 J
9.04
10.2 J
9.17 J
10.7 J
9.1 J
Sample Location:
RREC 13-02
RREC 13-02
RREC 13-03
RREC 13-03
RREC 13-03
RREC 13-03
RREC 13-03
RREC 13-05
RREC 13-05
Sample Name:
RREC 13-02-0709
RREC 13-02-0911
RREC 13-03-SURF
RREC 13-03-0001
RREC 13-03-0103
RREC 13-03-0305
RREC 13-03-0507
RREC 13-05-SURF
RREC13-05-0001
Sample Depth (ft):
7-9
0-0.5
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-1
Date Sampled:
11/2/13
10/30/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
17.6
18.1
7.2
9
7.6
7.6
3.3
4.1
5.9
Barium
NSL
NSL
mg/kg
137 J
112
90.1 J
167 J
162 J
164 J
49.7 J
158 J
135 J
Cadmium
0.99
4.98
mg/kg
5.9 J
4.2
6.3 J
17.1 J
21.2 J
18.1 J
0.24 J
1 J
3.1 J
Chromium
43.4
111
mg/kg
112 J
85.7
62.2 J
124 J
112 J
75.4 J
13.4 J
68.2 J
96 J
Copper
31.6
149
mg/kg
172
144
109 J
222 J
225 J
148 J
12.8 J
57.3 J
92.4 J
Iron
20000
40000
mg/kg
89600
80000
58800
43400
34100
31900
14300
47700
61200
Lead
35.8
128
mg/kg
283
240
132
222
218
150
9.1
97.7
218
Mercury
0.18
1.06
mg/kg
0.11 J
0.48
0.46 J
1.1 J
1.4 J
0.9 J
0.015 J
0.11 J
0.43 J
Nickel
22.7
48.6
mg/kg
47.9
37.3 J
35 J
60.2 J
61.1 J
37.7 J
16 J
17.6 J
49.9 J
Selenium
NSL
NSL
mg/kg
6.6
6
3.4 J
2.6 J
2.4 J
2.3 J
0.74 J
2.8 J
4.4 J
Silver
NSL
NSL
mg/kg
2.6
1.9 J
1.1 J
2 J
2 J
1.3 J
1 UJ
0.38 J
1.6 J
Zinc
121
459
mg/kg
1140
1030 J
483 J
792 J
717 J
430 J
34 J
178 J
746 J
Total Organic Carbon
NSL
NSL
0/
/O
14.2 J
16.4 J
11.6
6.06
6.97
4.76
0.68
7.01
5.49
NOTES:
E = Value exceeds the highest standard in the initial calibration range.
Value is estimated.
J = Result is less than the Reporting Limit (RL) but greater than or equal to
the Method Detection Limit and the concentration is an approximate value.
N = Spiked sample recovery not within control limits.
U = Indicates the analyte was analyzed for but not detected,
mg/kg = Milligrams per kilogram.
NSL=No Screening Level
TEC = Threshold effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline Assessment of Contaminated Sediments
Detroit River Area of Concern, Wayne County, Michigan Page 1 of 12 Site Characterization Report
-------
TABLE 3-5 SEDIMENT RESULTS FOR METALS AND TOTAL ORGANIC CARBON
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-05
RREC 13-06
RREC 13-06
RREC 13-06
RREC 13-07
RREC 13-09
RREC 13-09
RREC 13-09
RREC 13-09
RREC 13-09
RREC 13-09
RREC 13-09
RREC13-11
RREC13-05-0103
RREC13-06-SURF
RREC 13-06-0001
RREC 13-06-0103
RREC13-07-SURF
RREC13-09-SURF
RREC 13-09-0001
RREC 13-09-0001-FD
RREC 13-09-0103
3REC13-09-0103-FI
RREC 13-09-03 05
RREC 13-09-03 05-FD
RREC 13-11-SURF
1-3
0-0.5
0-1
1-3
0-0.5
0-0.5
0-1
0-1
1-3
1-3
3-5
3-5
0-0.5
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/4/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/4/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
9
7.9
13.8
13
5
3.9
8.7
7.1
14.2
14.3
15.6
13.2
7.9
Barium
NSL
NSL
mg/kg
145 J
197 J
106
116
86.9 J
59.4
150
150
169
457
278
202
67.5
Cadmium
0.99
4.98
mg/kg
4.1 J
1.6 J
2.1
3
0.89 J
0.95
4.7
3.9
7.5
7.9
10.2
7.3
7.6
Chromium
43.4
111
mg/kg
110 J
109 J
637
119
242 J
212
183
254
167
252
203
139
157
Copper
31.6
149
mg/kg
139 J
114 J
84.2
94.6
37 J
110 J
169 J
164 J
179 J
182 J
202 J
163 J
180 J
Iron
20000
40000
mg/kg
135000
69500
73600
76600
67500
235000
190000
196000
145000
138000
102000
110000
263000
Lead
35.8
128
mg/kg
362
76.2
128 J
228 J
44.2
67.1 J
257 J
236 J
448 J
831 J
513 J
386 J
577 J
Mercury
0.18
1.06
mg/kg
0.6 J
0.17 J
0.37
0.82
0.055 J
0.17
0.51
0.46
0.62
0.56
0.86
0.81
0.21
Nickel
22.7
48.6
mg/kg
53.7 J
25.7 J
44.6
60.5
19.4 J
110 J
134 J
139 J
90.6 J
89.3 J
99.9 J
65.8 J
91.6 J
Selenium
NSL
NSL
mg/kg
7
4.4 J
3.2 J
3.3 J
4.2
9.3
7.7
8.8
7.3
6.8
9.4
10.7
8.8
Silver
NSL
NSL
mg/kg
2 J
0.41 J
1.7 J
3.6 J
0.72 J
1.2
2.3
2.2
2.8
2.9
3.6
2.7
4.2
Zinc
121
459
mg/kg
1540 J
189 J
533
863
184 J
223
957
863
1520
1510
1570
1510
3630
Total Organic Carbon
NSL
NSL
0/
/O
7.42
5.5
8.6
7.81
4.34
3.53 J
4.56 J
9.24 J
9.08 J
7.18 J
10.2 J
9.35 J
2.05 J
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-13
RREC13-13
RREC13-13
RREC13-13
RREC13-13
RREC13-14
RREC13-14
RREC13-14
RREC13-14
RREC13-14
RREC13-14
RREC13-14
RREC13-15
RREC 13-13-SURF
RREC13-13-0001
RREC13-13-0103
RREC 13-13-0305
RREC 13-13-0507
RREC13-14-SURF
3REC13-14-SURF-FE
RREC 13-14-0001
RREC13-14-0103
RREC 13-14-0305
RREC 13-14-0507
RREC13-14-0710
RREC13-15-SURF
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-0.5
0-1
1-3
3-5
5-7
7-10
0-0.5
11/4/13
11/5/13
11/5/13
11/5/13
11/5/13
11/4/13
11/4/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/4/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
10.4
4.6
7.3
10.5
13.2
5.6
4.2
19.8 J
10.9
12.5
10.5
10.2
10.7
Barium
NSL
NSL
mg/kg
52.1
86.7 J
132 J
191 J
129 J
96.9
75.3
168 J
189
177
160
181 J
201
Cadmium
0.99
4.98
mg/kg
6.3
24.6 J
31 J
20 J
4.7 J
5.4
4.6
6.8
9.2
8.4
8.1
6.1 J
7.9
Chromium
43.4
111
mg/kg
170
220 J
272 J
161 J
57.2 J
137
107
273 J
282
231
224
194 J
232
Copper
31.6
149
mg/kg
142 J
241 J
260 J
263 J
271 J
145 J
117 J
256 J
205 J
187 J
188 J
161 J
175 J
Iron
20000
40000
mg/kg
409000
370000
373000
82000
30300
152000
132000
181000 J
112000
129000
125000
125000
76300
Lead
35.8
128
mg/kg
488 J
1230
1490
363
266
254 J
205 J
295 J
403 J
369 J
383 J
266
360 J
Mercury
0.18
1.06
mg/kg
0.13
0.25 J
0.49 J
1.5 J
1.9 J
0.65
0.53
0.54 J
0.75
1.1
0.66
0.73 J
0.77
Nickel
22.7
48.6
mg/kg
132 J
154 J
178 J
98.1 J
36.1 J
113 J
84.4 J
217 J
183 J
157 J
156 J
144 J
123 J
Selenium
NSL
NSL
mg/kg
8.3
12.3
11.9
4.2 J
2.2 J
5.8
5.4
3.7 U
5.5
6.6
6
6.4
4.1
Silver
NSL
NSL
mg/kg
5.1
8.5 J
10.3 J
3.1 J
1.8 J
2.8
2.2
3.7
4.1
4.1
3.8
2.9 J
3.5
Zinc
121
459
mg/kg
3610
9410 J
11800 J
1710 J
689 J
1270
1120
1040 J
1290
1310
1460
1080 J
1260
Total Organic Carbon
NSL
NSL
0/
/O
3.44 J
7.8
5.0
8.71
6.69
9.91 J
8.79 J
8.8
7.76 J
10.2 J
9.73 J
8.1
8.79 J
NOTES:
E = Value exceeds the highest standard in the initial calibration range.
Value is estimated.
J = Result is less than the Reporting Limit (RL) but greater than or equal to
the Method Detection Limit and the concentration is an approximate value.
N = Spiked sample recovery not within control limits.
U = Indicates the analyte was analyzed for but not detected,
mg/kg = Milligrams per kilogram.
NSL=No Screening Level
TEC = Threshold effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 2 of 12
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-5 SEDIMENT RESULTS FOR METALS AND TOTAL ORGANIC CARBON
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-15
RREC13-15
RREC13-16
RREC13-16
RREC13-16
RREC13-16
RREC13-16
RREC13-16
RREC13-16
Sample Name:
RREC13-15-0001
RREC13-15-0103
RREC 13-16-SURF
RREC 13-16-0001
RREC13-16-0103
RREC 13-16-0305
RREC 13-16-0507
RREC 13-16-0709
RREC13-16-0911
Sample Depth (ft):
0-1
1-3
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
Date Sampled:
11/5/13
11/5/13
10/31/13
10/29/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
10.2
11.5 J
9.9
11.1
11.1
5.2
5.4
4.8
5.4
Barium
NSL
NSL
mg/kg
213
129 J
115
150 J
89.4 J
71.8 J
70.7 J
45 J
56.7 J
Cadmium
0.99
4.98
mg/kg
9.1
4.2
3.2
6
0.66
0.31 J
0.26 J
0.18 J
0.25 J
Chromium
43.4
111
mg/kg
267
106 J
95.7
166 J
25.4 J
19.4 J
15.7 J
11 J
15.2 J
Copper
31.6
149
mg/kg
177 J
98.2 J
102 J
134 J
31 J
18.6 J
15.7 J
13.9 J
15 J
Iron
20000
40000
mg/kg
66100
46700 J
43400
52300 J
24800 J
19000 J
16100 J
12300 J
16400 J
Lead
35.8
128
mg/kg
281 J
172 J
140 J
282 J
29.7 J
13.2 J
10.2 J
8.2 J
9 J
Mercury
0.18
1.06
mg/kg
0.84
0.18 J
0.4
0.54
0.22
0.021 J
0.021 J
0.015 J
0.02 J
Nickel
22.7
48.6
mg/kg
114 J
59.5 J
57.4
75 J
36 J
25.8 J
21.3 J
15.9 J
21.4 J
Selenium
NSL
NSL
mg/kg
3.7
7.2
2.8 J
6.8
2.8 J
2 J
1.8 J
1.3 J
1.8 J
Silver
NSL
NSL
mg/kg
3.5
1.3
1.8 J
2.6
0.46 J
0.3 J
0.24 J
0.19 J
0.21 J
Zinc
121
459
mg/kg
922
713 J
455
716 J
98.8 J
52.5 J
50.1 J
30.2 J
42 J
Total Organic Carbon
NSL
NSL
0/
/O
7.51 J
5.0
6.7
6.83
7.42
2.4
2.89
2.6
2.96
Sample Location:
RREC13-17
RREC13-17
RREC13-17
RREC13-17
RREC13-17
RREC13-17
RREC13-17
RREC13-18
RREC13-18
Sample Name:
RREC13-17-SURF
RREC13-17-0001
RREC13-17-0103
RREC 13-17-0305
RREC 13-17-0507
RREC 13-17-0709
RREC13-17-0911
RREC 13-18-SURF
RREC13-18-0001
Sample Depth (ft):
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
0-1
Date Sampled:
10/31/13
10/29/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
7.8
7.6
17.2
18.7
15.9
12.3
12.4
8
9
Barium
NSL
NSL
mg/kg
89
93.8 J
162 J
118 J
133 J
109 J
104 J
81.2
84.6 J
Cadmium
0.99
4.98
mg/kg
2
4
9.2
9.4
12.5
14.2
10.2
1.9
2.7 J
Chromium
43.4
111
mg/kg
63
93
253
183
159 J
128 J
112 J
57.6
64.2
Copper
31.6
149
mg/kg
78.9 J
96.6
247
231
211
197
182
71.2 J
75.2
Iron
20000
40000
mg/kg
35800
104000
82400
99400
91700 J
59300 J
65700 J
33900
36600
Lead
35.8
128
mg/kg
97.4 J
139 J
475 J
359 J
461
226
234
114 J
102
Mercury
0.18
1.06
mg/kg
0.33
0.49 J
0.93 J
0.95 J
1.1
0.99
1
0.36
0.36
Nickel
22.7
48.6
mg/kg
45.1
88.3 J
109 J
49.1 J
44.3 J
48 J
49.5 J
42.6
46.5 J
Selenium
NSL
NSL
mg/kg
2.5 J
4.6 J
4.9
5.3 J
9.3
6.9
6.7
2.7 J
6.1 J
Silver
NSL
NSL
mg/kg
0.97 J
2.2
3.5
2.4
2.1
1.8
1.7
0.93 J
1.4 J
Zinc
121
459
mg/kg
305
424 J
997 J
612 J
659 J
535 J
488 J
285
323
Total Organic Carbon
NSL
NSL
0/
/O
6.23
6.6
9.2
10.10
21.00
6.26 J
5.91 J
5.7
5.07 J
NOTES:
E = Value exceeds the highest standard in the initial calibration range.
Value is estimated.
J = Result is less than the Reporting Limit (RL) but greater than or equal to
the Method Detection Limit and the concentration is an approximate value.
N = Spiked sample recovery not within control limits.
U = Indicates the analyte was analyzed for but not detected,
mg/kg = Milligrams per kilogram.
NSL=No Screening Level
TEC = Threshold effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 3 of 12
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-5 SEDIMENT RESULTS FOR METALS AND TOTAL ORGANIC CARBON
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-18
RREC13-18
RREC13-18
RREC13-18
RREC13-18
RREC13-19
RREC13-19
RREC 13-20
RREC 13-20
RREC 13-20
Sample Name:
RREC13-18-0103
RREC13-18-0305
RREC13-18-0507
RREC13-18-0709
RREC13-18-0911
RREC13-19-SURF
RREC13-19-0001
RREC13-20-SURF
RREC 13-20-0001
RREC 13-20-0103
Sample Depth (ft):
1-3
3-5
5-7
7-9
9-11
0-0.5
0-1
0-0.5
0-1
1-3
Date Sampled:
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
11/1/13
10/29/13
11/1/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
14
12.2
9.7
6.8
6.6
5.8
35.4
6.4
5.7
6.1
Barium
NSL
NSL
mg/kg
124 J
96.5 J
93.5 J
58.7 J
69 J
73.5
77 J
34.3
51.3
53.5
Cadmium
0.99
4.98
mg/kg
6.6 J
8.2 J
3.2 J
0.6 J
0UJ
0.84
1.9
0.58
0.25 J
0.26 J
Chromium
43.4
111
mg/kg
118
86.4
45.5
18.9
17.9
27
64.8 J
19.8
14.1 J
14.5 J
Copper
31.6
149
mg/kg
146
138
86.2
21.3
18.4
37.3 J
92
23.2 J
15.1
16.3
Iron
20000
40000
mg/kg
64700
53200
27300
18500
18400
19500
54800 J
17000
16300
17200
Lead
35.8
128
mg/kg
227
189
121
31.9
20.5
67.8 J
112
23.6 J
9.8
10
Mercury
0.18
1.06
mg/kg
0.6
0.76
0.41
0.088 J
0.046 J
0.16
0.26
0.11 J
0.013 J
0.011 J
Nickel
22.7
48.6
mg/kg
54.2 J
39 J
32.2 J
23.8 J
23.6 J
23.9
52.7 J
21.3
21.3
22.8
Selenium
NSL
NSL
mg/kg
8.7
6.5
4.2 J
2.8 J
2.8 J
1.2 J
6.5
1.1 J
1.3 J
1.4 J
Silver
NSL
NSL
mg/kg
2
1.4
0.87 J
0.24 J
0.19 J
0.34 J
1.1
0.33 J
0.061 J
0.096 J
Zinc
121
459
mg/kg
494
397
242
70.2
57
169
289 J
89.7
44.1
43.4
Total Organic Carbon
NSL
NSL
0/
/O
5.86 J
5.36 J
4.46 J
2.65 J
3.77 J
4.4
3.62 J
5.1
6.07
4.1
Sample Location:
RREC13-20
RREC13-21
RREC13-21
RREC13-21
RREC13-21
RREC 13-21
RREC13-21
RREC13-21
RREC13-21
RREC13-21
Sample Name:
RREC13-20-0305
RREC 13-21-SURF
RREC 13-21-0001
RREC13-21-0001-FD
RREC13-21-0103
RREC 13-21-0103-FD
RREC 13-21-03 05
RREC 13-21-03 05-FD
RREC 13-21-05 07
RREC13-21-0507-FD
Sample Depth (ft):
3-5
0-0.5
0-1
0-1
1-3
1-3
3-5
3-5
5-7
5-7
Date Sampled:
11/1/13
11/1/13
10/29/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
6.3
11.2
15.5
17.6
34.6
33.1
54.9
53
20.5
25.9
Barium
NSL
NSL
mg/kg
55.4
106
98.3 J
100
150
138
189
205
213
199
Cadmium
0.99
4.98
mg/kg
0.4 J
3.6
4.6
4.6
10.1
8.9
10.2
11.1
11.8
11.8
Chromium
43.4
111
mg/kg
15.1 J
125
121 J
134 J
321 J
286 J
401 J
439 J
360 J
362 J
Copper
31.6
149
mg/kg
15.7
140 J
218 J
231
446
424
612
609
294
339
Iron
20000
40000
mg/kg
17300
59900
100000 J
107000
183000
177000
299000
301000
100000
139000
Lead
35.8
128
mg/kg
9.2
153 J
159 J
181
328
312
519
503
441
450
Mercury
0.18
1.06
mg/kg
0.12 UJ
0.36
0.37
0.37 J
0.49 J
0.57 J
0.52 J
0.6 J
0.96 J
0.93 J
Nickel
22.7
48.6
mg/kg
23.7
74.9
94.2 J
101
237
212
268
289
158
170
Selenium
NSL
NSL
mg/kg
1.3 J
4.2 J
9.3
7.4 J
10.7
10.9
16.7
15
6.7
7.9
Silver
NSL
NSL
mg/kg
0.12 J
2 J
3
2.8
5.9
5.4
6.8
7.3
4.7
4.9
Zinc
121
459
mg/kg
51.5
482
647 J
682
896
836
813
845
1340
1330
Total Organic Carbon
NSL
NSL
0/
/O
3.26
6.9
7.1
7.36 J
10.2 J
10.6 J
9.13 J
9.49 J
10.4 J
11.5 J
NOTES:
E = Value exceeds the highest standard in the initial calibration range.
Value is estimated.
J = Result is less than the Reporting Limit (RL) but greater than or equal to
the Method Detection Limit and the concentration is an approximate value.
N = Spiked sample recovery not within control limits.
U = Indicates the analyte was analyzed for but not detected,
mg/kg = Milligrams per kilogram.
NSL=No Screening Level
TEC = Threshold effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 4 of 12
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-5 SEDIMENT RESULTS FOR METALS AND TOTAL ORGANIC CARBON
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-21
RREC13-21
RREC13-21
RREC13-21
RREC 13-22
RREC 13-22
RREC 13-22
RREC 13-22
RREC 13-22
RREC 13-22
RREC 13-22
Sample Name:
RREC13-21-0709
RREC13-21-0709-FD
RREC13-21-0911
RREC13-21-0911-FD
RREC13-22-SURF
RREC13-22-0001
RREC 13-22-0103
RREC 13-22-0305
RREC 13-22-0507
RREC 13-22-0709
RREC 13-22-0911
Sample Depth (ft):
7-9
7-9
9-11
9-11
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
Date Sampled:
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
10/29/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
11.8
10.8
7
7.2
9.2
9.1
19.6
27.6
27.6
14.1
8.3
Barium
NSL
NSL
mg/kg
142
134
61.2
62
111
103 J
161 J
355 J
334 J
195 J
81.4 J
Cadmium
0.99
4.98
mg/kg
7.4
6.5
0.41 J
0.33 J
3
3.4 J
9.2 J
17.2 J
18.4 J
7.7 J
1.6 J
Chromium
43.4
111
mg/kg
159 J
142 J
18.1 J
16.2 J
102
95.4
266
843
542
202
28
Copper
31.6
149
mg/kg
182
161
18.4
17.3
92.8 J
92.9
255
414
350
202
98.6
Iron
20000
40000
mg/kg
39100
42300
18200
18500
43000
41000
121000
131000
131000
66800
20500
Lead
35.8
128
mg/kg
286
257
14.8
10.5
123 J
156
261
476
492
330
116
Mercury
0.18
1.06
mg/kg
0.37 J
0.35 J
0.017 J
0.019 J
0.42
0.42
0.64
0.81
1.7
1
0.65
Nickel
22.7
48.6
mg/kg
64.6
60.7
25.7
24.7
69
65 J
188 J
343 J
268 J
102 J
30.2 J
Selenium
NSL
NSL
mg/kg
3.7 J
3.4 J
1.5 J
1.5 J
2.9 J
6.6 J
14.6
16.1
16.2
8.2
3.2 J
Silver
NSL
NSL
mg/kg
2.3
2
0.14 J
0.13 J
2.4
1.8 J
5.4
9.7
9.9
3.9
0.85 J
Zinc
121
459
mg/kg
721
657
55.9
57.5
388
367
707
1080
1140
893
271
Total Organic Carbon
NSL
NSL
0/
/O
11.3 J
7.88 J
3.42 J
3.62 J
5.89
7.18 J
8.53 J
9.59 J
9.55 J
8.3 J
4.36 J
Sample Location:
RREC13-23
RREC 13-23
RREC 13-23
RREC 13-23
RREC 13-23
RREC 13-23
RREC 13-23
RREC 13-24
RREC 13-24
RREC 13-24
RREC 13-25
Sample Name:
RREC13 -23 -SURF
RREC 13-23-0001
RREC 13-23-0103
RREC 13-23-0305
RREC 13-23-0507
RREC 13-23-0709
RREC 13-23-0911
RREC 13 -24-SURF
RREC13-24-0001
RREC 13-24-0103
RREC 13-25-SURF
Sample Depth (ft):
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
0-1
1-3
0-0.5
Date Sampled:
11/2/13
10/30/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
11/4/13
11/4/13
11/4/13
11/4/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
11.2
11.1
17.9
16.7
12.6
11.2
13.1
6.1
4.7 J
4.6 J
13.5
Barium
NSL
NSL
mg/kg
118
142
320
315
210
235
260
28.4 J
93.2 J
85.2 J
43.3 J
Cadmium
0.99
4.98
mg/kg
4.4
7.2
12:00 AM
20
10.1
8.4
9
0.43 J
0.47 U
0.43 U
0.82
Chromium
43.4
111
mg/kg
115
132
646
613
298
289
333
44.4 J
11.8 J
12.9 J
63 J
Copper
31.6
149
mg/kg
122 J
121
309
289
183
172
207
27.8
16.2 J
13.6 J
45.9
Iron
20000
40000
mg/kg
40000
33200
70900
67900
53500
48000
51400
44500
12400 J
15200 J
103000
Lead
35.8
128
mg/kg
204 J
206
394
390
333
308
338
32.7 J
26.3 J
21.5 J
61.6 J
Mercury
0.18
1.06
mg/kg
0.81
0.62
1.3
1.1
0.98
0.86
1
0.2
0.13 J
0.064 J
0.096 J
Nickel
22.7
48.6
mg/kg
86.2
71.2 J
380 J
388 J
191 J
144 J
147 J
19 J
14.2 J
15.2 J
41.1 J
Selenium
NSL
NSL
mg/kg
3.2 J
3.2 J
4.9
4.9
3.7 J
3.3 J
3.7 J
2.5 J
0.89 J
0.76 J
4.2
Silver
NSL
NSL
mg/kg
3
2.7 J
10.5 J
9.3 J
4.7 J
4.5 J
4.6 J
0.52 J
0.11 J
0.097 J
0.74 J
Zinc
121
459
mg/kg
501
481 J
1160 J
1170 J
956 J
772 J
874 J
181
59.9 J
52.2 J
436
Total Organic Carbon
NSL
NSL
0/
/O
7.40
13.2 J
11.7 J
1.57 J
2.58 J
9.56 J
10.3 J
2.6
2.30
3.0
3.09
NOTES:
E = Value exceeds the highest standard in the initial calibration range.
Value is estimated.
J = Result is less than the Reporting Limit (RL) but greater than or equal to
the Method Detection Limit and the concentration is an approximate value.
N = Spiked sample recovery not within control limits.
U = Indicates the analyte was analyzed for but not detected,
mg/kg = Milligrams per kilogram.
NSL=No Screening Level
TEC = Threshold effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 5 of 12
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-5 SEDIMENT RESULTS FOR METALS AND TOTAL ORGANIC CARBON
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-25
RREC 13-25
RREC 13-25
RREC 13-25
RREC 13-25
RREC 13-26
RREC13-26
RREC 13-26
RREC 13-26
RREC 13-26
RREC 13-27
RREC 13-27
RREC13-25-0001
RREC 13-25-0103
RREC 13-25-0305
RREC 13-25-0507
RREC 13-25-0710
RREC13-26-SURF
RREC 13-26-0001
RREC 13-26-0103
RREC 13-26-03 05
RREC 13-26-0507
RREC13-27-SURF
RREC 13-27-0001
0-1
1-3
3-5
5-7
7-10
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-1
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
10.5 J
10.6 J
12.8 J
12.3 J
16.5 J
13.2 J
10
9
12.3
12.3
10.1 J
15.3 J
Barium
NSL
NSL
mg/kg
148 J
221 J
320 J
335 J
355 J
89.5 J
172
229
182
151
88.2 J
144 J
Cadmium
0.99
4.98
mg/kg
7.5
8.9
11.8
16.4
24.9
3.1
7.6
10
6.7
9.9
3.8
6.6
Chromium
43.4
111
mg/kg
212 J
312 J
503 J
532 J
994 J
161 J
250
326
294
171
178 J
232 J
Copper
31.6
149
mg/kg
134 J
162 J
209 J
227 J
432 J
110 J
218 J
261 J
291 J
229 J
190 J
200 J
Iron
20000
40000
mg/kg
86300 J
71600 J
52900 J
37200 J
58500 J
132000 J
152000
172000
195000
110000
118000 J
128000 J
Lead
35.8
128
mg/kg
189 J
274 J
304 J
397 J
396 J
136 J
321 J
359 J
272 J
198 J
145 J
260 J
Mercury
0.18
1.06
mg/kg
0.77 J
0.83 J
1.1 J
1.3 J
1.2 J
0.4 J
0.89
0.95
0.74
0.73
0.65 J
1 J
Nickel
22.7
48.6
mg/kg
129 J
190 J
247 J
239 J
306 J
79.2 J
143 J
202 J
177 J
105 J
62.9 J
145 J
Selenium
NSL
NSL
mg/kg
4.2
3.8 J
3.8 J
3.5 J
4.4
5.3
6.3
7.5
7.7
4.2
5.3
5.4
Silver
NSL
NSL
mg/kg
3.6
4.6
6.8
9
13.1
1.9
4.9
5.3
3.5
2.3
1.6
3.2
Zinc
121
459
mg/kg
611 J
684 J
843 J
911 J
1220 J
520 J
1020
1080
925
684
1120 J
845 J
Total Organic Carbon
NSL
NSL
0/
/O
8.81
13.5
7.2
7.65
8.73
6.1
11.6 J
9.12 J
7 J
8.98 J
4.76
10.0
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-27
RREC 13-27
RREC 13-27
RREC 13-27
RREC 13-28
RREC 13-28
RREC13-28
RREC 13-28
RREC 13-28
RREC 13-28
RREC 13-28
RREC 13-29
RREC 13-27-0103
RREC 13-27-03 05
RREC 13-27-0507
RREC 13-27-0710
RREC13-28-SURF
RREC13-28-0001
RREC13-28-0103
RREC 13-28-0305
RREC 13-28-0507
RREC 13-28-0709
RREC13-28-0911
RREC13-29-SURF
1-3
3-5
5-7
7-10
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
11/4/13
11/4/13
11/4/13
11/4/13
11/1/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/1/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
17 J
20.6 J
27.8 J
29.5 J
8.5
18.1
23
29.7
19.9
22.6
14
9.3
Barium
NSL
NSL
mg/kg
246 J
223 J
165 J
285 J
83.1 J
213 J
168 J
173 J
149 J
211 J
162 J
78.9 J
Cadmium
0.99
4.98
mg/kg
8.3
11.1
9.7
11.6
2.4 J
8.2
8.6
12
11.8
19.8
19.3
2.8 J
Chromium
43.4
111
mg/kg
389 J
346 J
280 J
329 J
84.3 J
331 J
281 J
294 J
163 J
189 J
123 J
107 J
Copper
31.6
149
mg/kg
248 J
261 J
274 J
328 J
67.9
238
365
323
225
292
224
82.1
Iron
20000
40000
mg/kg
140000 J
121000 J
167000 J
148000 J
67700
150000
143000
163000
101000
109000
52000
61000
Lead
35.8
128
mg/kg
278 J
374 J
349 J
362 J
74.2
265 J
234 J
240 J
212 J
262 J
229 J
96.7
Mercury
0.18
1.06
mg/kg
1.7 J
1.2 J
1.1 J
1.2 J
0.26 J
1.1
0.65
0.7
0.61
1
1.1
0.91 J
Nickel
22.7
48.6
mg/kg
190 J
153 J
150 J
173 J
41
198 J
146 J
189 J
118 J
145 J
87.2 J
57.4
Selenium
NSL
NSL
mg/kg
5.8
5.9
6.5
6.6
3.2 J
6.8
6.3
7
5.2
5.8
3.5 J
3.7 J
Silver
NSL
NSL
mg/kg
4.6
4.7
3.6
4.4
0.93 J
4.6 J
4 J
4 J
2.6 J
3.1 J
2.6 J
1.3 J
Zinc
121
459
mg/kg
827 J
1030 J
1190 J
1000 J
440
878
679
662
790
931
658
423
Total Organic Carbon
NSL
NSL
0/
/O
9.52
7.3
7.5
8.50
8.74 J
10.1
4.52
7.6
6.71
5.9
5.11
10.6 J
NOTES:
E = Value exceeds the highest standard in the initial calibration range.
Value is estimated.
J = Result is less than the Reporting Limit (RL) but greater than or equal to
the Method Detection Limit and the concentration is an approximate value.
N = Spiked sample recovery not within control limits.
U = Indicates the analyte was analyzed for but not detected,
mg/kg = Milligrams per kilogram.
NSL=No Screening Level
TEC = Threshold effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 6 of 12
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-5 SEDIMENT RESULTS FOR METALS AND TOTAL ORGANIC CARBON
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-29
RREC 13-29
RREC 13-29
RREC 13-29
RREC 13-29
RREC 13-29
RREC 13-30
RREC 13-30
RREC 13-30
RREC13-30
RREC 13-30
Sample Name:
RREC13-29-0001
RREC 13-29-0103
RREC 13-29-0305
RREC 13-29-05 07
RREC 13-29-0709
RREC13-29-0911
RREC13-30-SURF
RREC13-30-0001
RREC 13-3 0-0001-FD
RREC 13-3 0-0103
RREC 13-30-0103 -FD
Sample Depth (ft):
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
0-1
0-1
1-3
1-3
Date Sampled:
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/4/13
11/1/13
11/4/13
11/4/13
11/4/13
11/4/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
17.6
18.1
21.1
16.8
28
18.2
12.6
19.6
16.7
17.3
10.3
Barium
NSL
NSL
mg/kg
195
199
228
166
159
255
188 J
428 J
360 J
325 J
99.7 J
Cadmium
0.99
4.98
mg/kg
8.9
8.2
10
9.6
7.5
21.3
5.3 J
27
21.1
23.6 J
5.7 J
Chromium
43.4
111
mg/kg
337
274
299
239
274
343
206 J
830 J
564 J
621 J
164 J
Copper
31.6
149
mg/kg
225
207
342
303
386
378
128
374
306
242
86.4
Iron
20000
40000
mg/kg
117000
120000
105000
77400
173000
50100
79700
64500
56600
63800
29600
Lead
35.8
128
mg/kg
278
271
281
240
225
345
181
576 J
480 J
373 J
186 J
Mercury
0.18
1.06
mg/kg
1
0.84
0.78
0.8
0.71
0.85
1 J
2
1.9
1.6
1.5
Nickel
22.7
48.6
mg/kg
198 J
139 J
151 J
108 J
160 J
171 J
99.6
337 J
300 J
215 J
169 J
Selenium
NSL
NSL
mg/kg
5.9
5.9
4.9
4.3 J
5.3
4.7 J
4.5 J
5.6
5 .2 J
5 .2 J
2.4 J
Silver
NSL
NSL
mg/kg
4.7 J
3.8 J
3.9 J
3.8 J
3.3 J
6.1 J
3
10.6 J
9 J
7.4 J
2.2 J
Zinc
121
459
mg/kg
829 J
835 J
932 J
663 J
634 J
786 J
638
1440
1190
1060
395
Total Organic Carbon
NSL
NSL
0/
/O
7.53 J
8.09 J
9.58 J
8.39 J
8.5 J
9.38 J
7.06 J
11.1
10.80
10.4
9.82
Sample Location:
RREC13-30
RREC 13-30
RREC 13-30
RREC 13-30
RREC 13-31
RREC 13-31
RREC 13-31
RREC 13-31
RREC 13-31
RREC13-32
RREC 13-32
Sample Name:
RREC 13-3 0-03 05
RREC 13-30-0305-FD
RREC 13-30-0507
RREC 13-30-0507-FD
RREC 13-31-SURF
RREC 13-31-0001
RREC13-31-0103
RREC 13-31-0305
RREC 13-31-0507
RREC13-32-SURF
RREC13-32-0001
Sample Depth (ft):
3-5
3-5
5-7
5-7
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-1
Date Sampled:
11/4/13
11/4/13
11/4/13
11/4/13
10/31/13
10/30/13
10/31/13
10/31/13
10/31/13
10/30/13
11/1/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
14.3
12.1
12.4
12
6.4
3.9
3.6
3.1
2.8
5.6
9.9
Barium
NSL
NSL
mg/kg
230 J
171 J
121 J
112 J
68.5 J
25.9 J
34.8 J
36.1 J
31.2 J
39.6 J
147 J
Cadmium
0.99
4.98
mg/kg
10.8
7.6
6.8
6.6
1.5
0.19 J
0.24 J
0.25 J
0.22 J
1.1
4.7
Chromium
43.4
111
mg/kg
354 J
251 J
151 J
141 J
40.3 J
13 J
14.2 J
14.7 J
12.5 J
47.7 J
160 J
Copper
31.6
149
mg/kg
205
159
155
157
48.2
9.6
10.4
11.2
10.5
53.9
123 J
Iron
20000
40000
mg/kg
77500
74200
136000
104000
32300 J
10500 J
12800 J
13700 J
13600 J
64300 J
86700 J
Lead
35.8
128
mg/kg
355 J
250 J
158 J
153 J
41.2
7.6
8.5
8.6
8.1
49.5
168 J
Mercury
0.18
1.06
mg/kg
1.2
1.1
0.42
0.45
0.2 J
0.016 J
0.023 J
0.022 J
0.022 J
0.15
0.63
Nickel
22.7
48.6
mg/kg
200 J
153 J
84.5 J
82.5 J
32.4 J
15.1 J
15.9 J
16.8 J
15.6 J
35.1 J
109 J
Selenium
NSL
NSL
mg/kg
5.2
5
5.8
4.7
4.3 J
0.98 J
1.5 J
1.6 J
1.7 J
6.2
7.8
Silver
NSL
NSL
mg/kg
5 .2 J
3.7 J
2.6 J
2.1 J
0.82 J
1.1 U
0.99 U
1.1 U
0.18 J
0.82 J
2.6
Zinc
121
459
mg/kg
1060
796
642
528
207 J
35 J
36.9 J
37.4 J
35.4 J
273 J
724 J
Total Organic Carbon
NSL
NSL
0/
/O
8.76
9.9
7.3
7.38
6.19 J
3.9
3.21
4.2
3.32
5.95 J
9.14
NOTES:
E = Value exceeds the highest standard in the initial calibration range.
Value is estimated.
J = Result is less than the Reporting Limit (RL) but greater than or equal to
the Method Detection Limit and the concentration is an approximate value.
N = Spiked sample recovery not within control limits.
U = Indicates the analyte was analyzed for but not detected,
mg/kg = Milligrams per kilogram.
NSL=No Screening Level
TEC = Threshold effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 7 of 12
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-5 SEDIMENT RESULTS FOR METALS AND TOTAL ORGANIC CARBON
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-32
RREC 13-32
RREC 13-33
RREC13-33
RREC13-33
RREC 13-33
RREC 13-33
RREC 13-33
RREC 13-33
RREC 13-34
RREC13-34
RREC 13-34
RREC13-32-0103
RREC 13-32-0305
RREC 13-3 3-SURF
RREC 13-3 3-0001
RREC13-33-0103
RREC 13-33-0305
RREC 13-33-0507
RREC 13-33-0709
RREC13-33-0911
RREC13-34-SURF
RREC13-34-0001
RREC13-34-0103
1-3
3-5
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
0-1
1-3
11/1/13
11/1/13
10/30/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
11/4/13
11/1/13
11/4/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
3.3
3.1
6.3
11.6
12.9
14.2
12.7
10.1
4.1
14.5
20.3
14.9
Barium
NSL
NSL
mg/kg
46.1 J
136 J
101 J
205 J
241 J
295 J
95 J
87 J
54.7 J
315
333
261
Cadmium
0.99
4.98
mg/kg
0.49 J
0.48 J
2.1
9.2 J
12.9 J
15.4 J
1.5 J
0.82 J
0.53 J
18
18.4
12.5
Chromium
43.4
111
mg/kg
20.4 J
29.9 J
87.5 J
272 J
279 J
485 J
42.3 J
27.2 J
22.2 J
810
656
403
Copper
31.6
149
mg/kg
19.2 J
19.5 J
65.1
176
286
293
201
118
23.8
261
359
259
Iron
20000
40000
mg/kg
16800 J
26100 J
33600 J
56200
46800
46600
21100
16500
17400
43700
89800
64900
Lead
35.8
128
mg/kg
17.2 J
19.4 J
68.6
246
312
357
201
143
37.6
376
436
369
Mercury
0.18
1.06
mg/kg
0.089 J
0.061 J
0.33
0.69 J
0.96 J
1.2 J
1.3 J
1.5 J
0.38 J
1.5
1.5
2.1
Nickel
22.7
48.6
mg/kg
22.2 J
34.2 J
41 J
151
142
239
27.3
21.2
22.9
314 J
275 J
205 J
Selenium
NSL
NSL
mg/kg
2 J
3.2 J
4.7 J
4.1 J
3.7 J
3.5 J
1.7 J
1.2 J
1.2 J
4.1 J
5.8 J
4.7 J
Silver
NSL
NSL
mg/kg
0.28 J
0.32 J
1.2 J
4.6
4.7
7.3
1.1 J
0.9 J
0.22 J
11.3 J
8.5 J
6.9 J
Zinc
121
459
mg/kg
82.4 J
109 J
380 J
778
924
1090
369
198
81.1
1210 J
1680 J
1040 J
Total Organic Carbon
NSL
NSL
0/
/O
2.97
2.4
7.83 J
3.55 J
3.19 J
4.1 J
7.73 J
6.5 J
9.63 J
5.74 J
11.4 J
13.3 J
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-34
RREC 13-34
RREC 13-34
RREC13-34
RREC13-35
RREC 13-35
RREC 13-35
RREC 13-35
RREC 13-36
RREC 13-36
RREC13-36
RREC 13-37
RREC 13-34-0305
RREC 13-34-0507
RREC 13-34-0709
RREC13-34-0911
RREC 13-3 5-SURF
RREC13-35-0001
RREC13-35-0103
RREC 13-35-0305
RREC 13-3 6-SURF
RREC13-36-0001
RREC13-36-0103
RREC13-37-SURF
3-5
5-7
7-9
9-11
0-0.5
0-1
1-3
3-5
0-0.5
0-1
1-3
0-0.5
11/4/13
11/4/13
11/4/13
11/4/13
10/31/13
10/30/13
10/31/13
10/31/13
10/31/13
10/28/13
10/31/13
11/1/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
14.6
14.6
16.4
18.2
5.2
7.4
1.2
2.9
9.6
10.9
14.1
5.5
Barium
NSL
NSL
mg/kg
264 J
332 J
219 J
253 J
169 J
131 J
14.4 J
49.4 J
145
166 J
246 J
50.3
Cadmium
0.99
4.98
mg/kg
11.1
8.4
10.4
19.4
4.5
2.7
0.35 J
0.19 J
2.2
4.7
7.8
2.8
Chromium
43.4
111
mg/kg
324 J
242 J
239 J
319 J
45.7 J
29.5
5.3
14.6
74.9
147 J
287 J
45.8
Copper
31.6
149
mg/kg
221
360
309
345
70.3
161
12.4
10.5
81.1 J
119
169
61.4 J
Iron
20000
40000
mg/kg
79200
70400
73200
65900
17200 J
17800
3490
14200
28700
33500 J
52100 J
38900
Lead
35.8
128
mg/kg
319 J
497 J
286 J
260 J
140
196 J
13.1 J
7.2 J
177 J
302
383
46.5 J
Mercury
0.18
1.06
mg/kg
1.2
1.9
0.89
1.4
0.63
1.3 J
0.16 J
0.016 J
0.99
1.1
1.1
0.31
Nickel
22.7
48.6
mg/kg
145 J
90.2 J
97.1 J
120 J
27.5 J
24.3 J
4.7 J
17.6 J
28.8
56.3 J
106 J
29.3
Selenium
NSL
NSL
mg/kg
5.1
4.5
4.5
4.6
2.4 J
1.6 J
3 U
0.66 J
2.6 J
5 J
6.1
2.2 J
Silver
NSL
NSL
mg/kg
4.7 J
4.8 J
5.1 J
6.3 J
1.7
1.1 J
0.069 J
0.097 J
0.65 J
1.9
3.8
0.62 J
Zinc
121
459
mg/kg
773
715
675
685
392 J
442 J
35.8 J
34.5 J
508
665 J
698 J
256
Total Organic Carbon
NSL
NSL
0/
/O
9.72
12.1
9.0
9.72
5.03
4.9
0.78
0.1
13.90
8.08 J
6.74 J
6.0
NOTES:
E = Value exceeds the highest standard in the initial calibration range.
Value is estimated.
J = Result is less than the Reporting Limit (RL) but greater than or equal to
the Method Detection Limit and the concentration is an approximate value.
N = Spiked sample recovery not within control limits.
U = Indicates the analyte was analyzed for but not detected,
mg/kg = Milligrams per kilogram.
NSL=No Screening Level
TEC = Threshold effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 8 of 12
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-5 SEDIMENT RESULTS FOR METALS AND TOTAL ORGANIC CARBON
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-37
RREC 13-37
RREC 13-37
RREC13-37
RREC 13-37
RREC 13-37
RREC13-38
RREC13-38
RREC13-38
RREC13-38
RREC13-38
RREC13-38
Sample Name:
RREC13-37-0001
RREC13-37-0103
RREC 13-37-0305
RREC 13-3 7-05 07
RREC 13-37-0709
RREC 13-3 7-0911
RREC13-38-SURF
*REC13-38-SURF-FI
RREC13-38-0001
RREC13-38-0103
RREC13-38-0305
RREC13-38-0507
Sample Depth (ft):
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
0-0.5
0-1
1-3
3-5
5-7
Date Sampled:
10/28/13
11/1/13
11/1/13
11/1/13
11/1/13
11/1/13
11/2/13
11/2/13
10/30/13
10/30/13
11/2/13
11/2/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
6.3
3.4
3.5
3.2
3.4
3.1
3.9
4
2.1
2.9
2.7
2.9
Barium
NSL
NSL
mg/kg
59.9 J
45.5 J
45.6 J
40.1 J
40 J
39.7 J
34.4 J
36.8 J
25.2
25.2
24.2
31
Cadmium
0.99
4.98
mg/kg
1.3
0.31 J
0.34 J
0.28 J
0.25 J
0.24 J
1.2
0.96
0.22 J
0.24 J
0.23 J
0.23 J
Chromium
43.4
111
mg/kg
29.2 J
17.9 J
19.3 J
17.3 J
16.6 J
16.6 J
37.5 J
35.6 J
11.8
11.7
10.4
12
Copper
31.6
149
mg/kg
71.2 J
16.8 J
17.9 J
11.5 J
10.7 J
11.3 J
47.6
44.6
8.6
8.8
8.1
9.9
Iron
20000
40000
mg/kg
20600 J
14300 J
16400 J
16200 J
15600 J
15100 J
40900 J
38700 J
10300
11300
10500
13100
Lead
35.8
128
mg/kg
72.8 J
16.1 J
13.5 J
9.8 J
8.5 J
8.7 J
31.7
27.8
7.4
7.3
7.1
7.8
Mercury
0.18
1.06
mg/kg
0.78
0.36
0.071 J
0.033 J
0.015 J
0.03 J
0.17
0.18
0.022 J
0.013 J
0.015 J
0.01 J
Nickel
22.7
48.6
mg/kg
21.9 J
18.4 J
20.4 J
18.6 J
18.7 J
19 J
25.7 J
22.2 J
14.2 J
14.1 J
14.1 J
14.8 J
Selenium
NSL
NSL
mg/kg
2.8 J
1.6 J
1.6 J
1.9 J
1.7 J
1.7 J
4.1
4.2
1.1 J
0.87 J
1 J
0.98 J
Silver
NSL
NSL
mg/kg
0.67 J
0.21 J
0.22 J
0.16 J
0.16 J
0.13 J
0.51 J
0.44 J
1.2 UJ
0.95 UJ
0.081 J
0.07 J
Zinc
121
459
mg/kg
174 J
50.7 J
55 J
45 J
45.2 J
47 J
191 J
174 J
33.1 J
33.8 J
30.2 J
34 J
Total Organic Carbon
NSL
NSL
0/
/O
5.73
3.6
4.2
4.31
3.40
3.7
2.33
2.7
2.27 J
3.57 J
4.15 J
3.37 J
Sample Location:
RREC 13-39
RREC 13-39
RREC 13-39
RREC13-39
RREC 13-39
RREC 13-39
RREC 13-39
RREC 13-40
RREC 13-40
RREC 13-40
RREC 13-40
RREC 13-40
Sample Name:
RREC13-39-SURF
RREC 13-39-0001
RREC 13-3 9-0103
RREC 13-39-0305
RREC 13-39-0507
RREC 13-39-0709
RREC 13-3 9-0911
RREC13-40-SURF
RREC 13-40-0001
RREC 13-40-0103
RREC 13-40-03 05
RREC 13-40-0507
Sample Depth (ft):
0-0.5
0-1
1-3
3-5
5-7
7-9
9-11
0-0.5
0-1
1-3
3-5
5-7
Date Sampled:
10/30/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
11/2/13
11/1/13
10/28/13
11/1/13
11/1/13
11/1/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
7.5
7.9
2.3
2.1
3
2.7
3
3.5
2.6
2.9
2.8
2.8
Barium
NSL
NSL
mg/kg
57.4 J
108 J
14.7 J
20.5 J
20.3 J
20.5 J
25.8 J
31.9
26.1 J
36.7 J
40.7 J
41.8 J
Cadmium
0.99
4.98
mg/kg
1.7
3.6 J
0.23 J
0.22 J
0.22 J
0.23 J
0.23 J
0.97
0.27 J
0.26 J
0.25 J
0.24 J
Chromium
43.4
111
mg/kg
53.9 J
109 J
7.1 J
9.9 J
9.5 J
9.8 J
11.9 J
32
13.3 J
15.6 J
16 J
17.1 J
Copper
31.6
149
mg/kg
65.3
112
9.5
7
6.7
6.2
9.5
41.3 J
9.6 J
11.2 J
10.6 J
11.7 J
Iron
20000
40000
mg/kg
47800 J
54100
6430
10100
9580
9320
11900
34400
11600 J
13400 J
14800 J
16000 J
Lead
35.8
128
mg/kg
74.2
147
18.4
6
5.8
5.8
7.6
34.9 J
11.3 J
8.5 J
8.4 J
9.1 J
Mercury
0.18
1.06
mg/kg
0.26
0.61 J
0.11 UJ
0.12 UJ
0.12 UJ
0.11 UJ
0.12 UJ
0.19
0.063 J
0.023 J
0.022 J
0.02 J
Nickel
22.7
48.6
mg/kg
40.8 J
83.5
7.3
11.8
11.2
11.2
14.7
22.3
12.5 J
16.5 J
17.7 J
20 J
Selenium
NSL
NSL
mg/kg
5
3.1 J
0.49 J
0.71 J
0.54 J
0.73 J
0.82 J
1.8 J
1.2 J
1.4 J
1.7 J
1.8 J
Silver
NSL
NSL
mg/kg
0.79 J
1.4
0.89 U
0.93 U
0.91 U
1.1 U
0.074 J
0.54 J
0.12 J
0.17 J
0.13 J
0.21 J
Zinc
121
459
mg/kg
347 J
571
31.8
28.1
27.5
27.3
34.4
169
40 J
41.3 J
44.1 J
47.4 J
Total Organic Carbon
NSL
NSL
0/
/O
7.93
7.32 J
7.23 J
8.84 J
7.18 J
6.8 J
2.53 J
4.7
2.48
3.1
3.26
3.3
NOTES:
E = Value exceeds the highest standard in the initial calibration range.
Value is estimated.
J = Result is less than the Reporting Limit (RL) but greater than or equal to
the Method Detection Limit and the concentration is an approximate value.
N = Spiked sample recovery not within control limits.
U = Indicates the analyte was analyzed for but not detected,
mg/kg = Milligrams per kilogram.
NSL=No Screening Level
TEC = Threshold effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 9 of 12
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-5 SEDIMENT RESULTS FOR METALS AND TOTAL ORGANIC CARBON
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41
RREC13-41 -SURF
RREC13-41-0001
RREC13-41-0103
RREC 13-41-0103-FD
RREC 13-41-0305
RREC 13-41-03 05-FD
RREC 13-41-05 07
3REC13-41-0507-FI
RREC13-41-0709
RREC13-41-0709-FD
RREC13-41-0911
3REC13-41-0911-FD
0-0.5
0-1
1-3
1-3
3-5
3-5
5-7
5-7
7-9
7-9
9-11
9-11
10/31/13
10/30/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
10/31/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
10.2
11.2
10.2
11.4
15.4
19.7
10.9
12.7
9.9
10.2
11
11.5
Barium
NSL
NSL
mg/kg
187 J
177 J
151 J
147 J
164 J
167 J
147 J
163 J
153 J
148 J
168 J
162 J
Cadmium
0.99
4.98
mg/kg
7.3
27.3
10.6
14.8
28.3
19.4
12.9
18.5
8.8
7.4
3.7
3.3
Chromium
43.4
111
mg/kg
159 J
109
76.1
97.6
171
192
94
117
77.2
61.7
41.6
41.2
Copper
31.6
149
mg/kg
186
718
419
564
798
512
326
466
328
293
437
370
Iron
20000
40000
mg/kg
27700 J
32400
27100
33900
52600
88600
32000
38600
23300
23500
25100
23500
Lead
35.8
128
mg/kg
162
450 J
276 J
308 J
410 J
297 J
242 J
299 J
298 J
307 J
388 J
368 J
Mercury
0.18
1.06
mg/kg
0.65
1.6 J
1.3 J
1.4 J
0.98 J
1.2 J
1.4 J
1.5 J
1.7 J
1.7 J
3 J
3.3 J
Nickel
22.7
48.6
mg/kg
48.2 J
62.2 J
51 J
62.8 J
70.6 J
107 J
58.8 J
71.8 J
53.5 J
47.2 J
38.3 J
39.9 J
Selenium
NSL
NSL
mg/kg
4 J
2.5 J
1.8 J
2.3 J
4.1 J
4.2 J
2.5 J
2.6 J
2 J
1.5 J
2 J
0.82 J
Silver
NSL
NSL
mg/kg
2.6
2.9
1.5
1.7
2.7
2.8
2.2
2.2
2
1.9
2.8
2.2
Zinc
121
459
mg/kg
422 J
1220 J
873 J
1080 J
1340 J
1050 J
744 J
946 J
832 J
793 J
983 J
896 J
Total Organic Carbon
NSL
NSL
0/
/O
12.10
8.2
8.2
8.34
8.45
10.3
7.95
8.7
8.47
8.3
7.48
7.5
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-42
RREC 13-42
RREC 13-42
RREC 13-42
RREC 13-44
RREC 13-44
RREC 13-44
RREC 13-44
RREC 13-44
RREC 13-45
RREC 13-45
RREC 13-45
RREC 13 -42-SURF
RREC13-42-0001
RREC 13-42-0103
RREC 13-42-0305
RREC13-44-SURF
RREC 13-44-0001
RREC 13-44-0103
RREC 13-44-0305
RREC 13-44-0507
RREC 13-45-SURF
RREC 13-45-0001
RREC 13-45-0103
0-0.5
0-1
1-3
3-5
0-0.5
0-1
1-3
3-5
5-7
0-0.5
0-1
1-3
11/4/13
11/4/13
11/4/13
11/4/13
11/1/13
10/30/13
11/1/13
11/1/13
11/1/13
11/1/13
10/29/13
11/1/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
7 J
4.2 J
5 .2 J
3.9 J
8.9
12.1
25.1
51.1
44.4
7.8
13
5.3
Barium
NSL
NSL
mg/kg
30.8 J
72.2 J
56.2 J
86.3 J
90.3
87.1
91.9
155
204 J
66.2
146
62.4
Cadmium
0.99
4.98
mg/kg
0.46 U
0.48 U
0.47 U
0.49 U
2.9
4.4
5.3
9.6
11.4 J
1.4
5
0.39 J
Chromium
43.4
111
mg/kg
18.9 J
16.7 J
16.4 J
21.8 J
100
121 J
229 J
378 J
431
39.9
136 J
16.3 J
Copper
31.6
149
mg/kg
68 J
9.8 J
15.1 J
21.1 J
105 J
164
355
663
470
53 J
131
16.2
Iron
20000
40000
mg/kg
38000 J
12800 J
17800 J
16100 J
59700
98700
248000
358000
300000
31100
44900
14800
Lead
35.8
128
mg/kg
30.7 J
10.4 J
10.3 J
12.8 J
119 J
157
180
472
462
64.1 J
209
19.5
Mercury
0.18
1.06
mg/kg
0.19 J
0.023 J
0.025 J
0.045 J
0.42
0.36 J
0.38 J
0.47 J
0.74
0.36
0.59 J
0.017 J
Nickel
22.7
48.6
mg/kg
17 J
21.2 J
20.2 J
23.4 J
61.5
81.2
155
287
246 J
33.6
67.7
19.5
Selenium
NSL
NSL
mg/kg
2.3 J
0.99 J
0.98 J
1.2 J
3.7 J
5.8
11.8
16.7
33.3
2.2 J
6.7
1.3 J
Silver
NSL
NSL
mg/kg
0.29 J
0.96 U
0.089 J
0.06 J
1.8
2.7
4.2
6.7
8
0.92 J
1.9
0.17 J
Zinc
121
459
mg/kg
200 J
48.8 J
44.8 J
46.8 J
410
547
589
734
797
282
669
56.7
Total Organic Carbon
NSL
NSL
0/
/O
3.29
1.4
0.9
2.48
6.98
6.0
7.00
8.5
8.56 J
7.0
7.56
3.4
NOTES:
E = Value exceeds the highest standard in the initial calibration range.
Value is estimated.
J = Result is less than the Reporting Limit (RL) but greater than or equal to
the Method Detection Limit and the concentration is an approximate value.
N = Spiked sample recovery not within control limits.
U = Indicates the analyte was analyzed for but not detected,
mg/kg = Milligrams per kilogram.
NSL=No Screening Level
TEC = Threshold effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 10 of 12
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-5 SEDIMENT RESULTS FOR METALS AND TOTAL ORGANIC CARBON
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
• Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-45
RREC 13-46
RREC 13-46
RREC 13-46
RREC 13-46
RREC 13-46
RREC 13-46
RREC 13-47
RREC 13-47
RREC 13-47
RREC 13-47
RREC 13-47
RREC13-45-0305
RREC13-46-SURF
RREC13-46-0001
RREC 13-46-0103
RREC 13-46-03 05
RREC 13-46-0507
RREC 13-46-0710
RREC13-47-SURF
LREC13-47-SURF-F1
RREC 13-47-0001
RREC 13-47-0103
RREC 13-47-0103-FD
3-5
0-0.5
0-1
1-3
3-5
5-7
7-10
0-0.5
0-0.5
0-1
1-3
1-3
11/1/13
11/5/13
11/6/13
11/6/13
11/6/13
11/6/13
11/6/13
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
6.3
5.4
8.8
5
6.3
6.1
4.5
7.7
8.5
9.9
10.5
11.4
Barium
NSL
NSL
mg/kg
52.4
81.9 J
112 J
34.7 J
54.7 J
52.3 J
56.8 J
80.6
83.7
101 J
101 J
109 J
Cadmium
0.99
4.98
mg/kg
0.3 J
0.58
5.1
0.79
0U
0U
0U
2.4
2.6
3.5 J
4.5 J
5.5 J
Chromium
43.4
111
mg/kg
15.4 J
30 J
111 J
22.8 J
13.3 J
12.9 J
13.8 J
79
87.6
97.2
105
141
Copper
31.6
149
mg/kg
16.6
43.6
128
27.6
14.5
14.6
14.3
76.4 J
82.3 J
94.1
99.5
124
Iron
20000
40000
mg/kg
16600
13700 J
24500 J
14300 J
14900 J
15200 J
16100 J
45600
49300
51200
66100
84100
Lead
35.8
128
mg/kg
13.2
54.2
209
42.3
10.6
11.1
10.1
128 J
123 J
149
196
240
Mercury
0.18
1.06
mg/kg
0.013 J
0.53 J
0.48 J
0.028 J
0.011 J
0UJ
0.014 J
0.41
0.35
0.38
0.51
0.82
Nickel
22.7
48.6
mg/kg
22.7
17.4 J
60.9 J
19.5 J
18.1 J
17.7 J
19.3 J
56.9
66.7
74.1 J
68.3 J
86 J
Selenium
NSL
NSL
mg/kg
1.4 J
0.97 J
1.2 J
0.64 J
3 U
3 U
3 U
3.3 J
2.8 J
8.3
8.5
9.7
Silver
NSL
NSL
mg/kg
0.14 J
1 U
2
0U
0U
0U
0U
1.2 J
1.4 J
1.8 J
2.5
3.1
Zinc
121
459
mg/kg
46.4
125 J
433 J
111 J
44.4 J
44.9 J
45.9 J
373
418
457
550
684
Total Organic Carbon
NSL
NSL
0/
/O
2.97
8.2
5.8
5.59
2.34
1.8
3.23
8.3
6.30
6.08 J
7.06 J
7.89 J
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC 13-47
RREC 13-47
RREC 13-47
RREC 13-47
RREC 13-47
RREC 13-48
RREC 13-48
RREC 13-48
RREC 13-48
RREC 13-48
RREC 13-48
RREC 13-48
RREC 13-47-0305
RREC13-47-0305-FD
RREC 13-47-0507
RREC 13-47-0709
RREC 13-47-0911
RREC13-48-SURF
RREC13-48-SURF-FD
RREC13-48-0001
RREC13-48-0103
RREC 13-48-0305
RREC 13-48-0507
RREC 13-48-0710
3-5
3-5
5-7
7-9
9-11
0-0.5
0-0.5
0-1
1-3
3-5
5-7
7-10
10/30/13
10/30/13
10/30/13
10/30/13
10/30/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
13.6
13.3
12.5
14.2
19.9
4.7
5.7
5
13.1
15.4
14.9
14.9
Barium
NSL
NSL
mg/kg
123 J
114 J
140 J
176 J
213 J
82.1 J
83 J
70.3 J
168
251
240
204
Cadmium
0.99
4.98
mg/kg
7.6 J
7.1 J
7.8
8.3
10.4 J
1.9 J
2 J
2.6 J
7.4
9.1
10.5
9.7
Chromium
43.4
111
mg/kg
159
151
218
266
300
67.2 J
69.3 J
49.4 J
204
276
304
285
Copper
31.6
149
mg/kg
155
146
162
191
221
68.9 J
69.8 J
56.7 J
158
197
196
196
Iron
20000
40000
mg/kg
84100
88800
86400
99300
123000
46600
58600
44900
79500
87800
100000
92200
Lead
35.8
128
mg/kg
307
304
267 J
401 J
447
107
99.5
94.7
232 J
337 J
402 J
356 J
Mercury
0.18
1.06
mg/kg
0.68
0.61
0.69 J
0.74 J
1.2
0.26 J
0.29 J
0.22 J
0.51
0.73
0.96
1.2
Nickel
22.7
48.6
mg/kg
108 J
106 J
180 J
162 J
182 J
50.2 J
53.5 J
40.6 J
174
220
181
186
Selenium
NSL
NSL
mg/kg
9.6
10.3
3.7 J
4.5 J
14.7
2.9 J
3.1 J
2.7 J
2.3 J
2.3 J
2.1 J
3 J
Silver
NSL
NSL
mg/kg
3.5
3.3
4.1
4.1
5.4
0.9 J
0.94 J
0.74 J
4 J
5.3 J
5.6 J
4.9 J
Zinc
121
459
mg/kg
911
937
802 J
970 J
1270
338 J
376 J
392 J
767
966
1270
1220
Total Organic Carbon
NSL
NSL
0/
/O
7.79 J
7.1 J
8.6
8.72
9.81 J
5.9
6.31
6.0
7.55
6.4
7.92
16.9
NOTES:
E = Value exceeds the highest standard in the initial calibration range.
Value is estimated.
J = Result is less than the Reporting Limit (RL) but greater than or equal to
the Method Detection Limit and the concentration is an approximate value.
N = Spiked sample recovery not within control limits.
U = Indicates the analyte was analyzed for but not detected,
mg/kg = Milligrams per kilogram.
NSL=No Screening Level
TEC = Threshold effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems
(MacDonald et al. 2000).
Bolded values exceed the TEC.
Bolded and gray shaded values exceed the PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 11 of 12
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-5 SEDIMENT RESULTS FOR METALS AND TOTAL ORGANIC CARBON
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-49
RREC13-49
RREC13-49
RREC 13-49
RREC 13-49
RREC 13-49
Sample Name:
RREC13-49-SURF
RREC13-49-SURF-FD
RREC13-49-0001
RREC 13-49-0103
RREC 13-49-03 05
RREC 13-49-05 07
Sample Depth (ft):
0-0.5
0-0.5
0-1
1-3
3-5
5-7
Date Sampled:
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
4.6
4.7
12.9
15.3
16.4
16.6
Barium
NSL
NSL
mg/kg
74.9 J
80 J
7/20/00
7/23/00
8/1/00
6/17/00
Cadmium
0.99
4.98
mg/kg
2.5 .1
2.8 J
8.6
8.3
9.6
6
Chromium
43.4
111
mg/kg
73.5 .1
75.5 J
255
254
287
168
Copper
31.6
149
mg/kg
lllll.l
102 .1
170
183
203
162
Iron
20000
40000
mg/kg
94900
107000
92400
101000
1 13000
106000
Lead
35.8
128
mg/kg
142
155
308 J
339 J
367 J
291 .1
Mercury
0.18
1.06
mg/kg
0.35 .1
0.46 .1
0.8
0.85
1.3
0.84
Nickel
22.7
48.6
mg/kg
48.8 .1
54.3 J
147
178
194
145
Selenium
NSL
NSL
mg/kg
4 4.1
4.6 J
2.5 J
2.3 J
2.5 J
1 S .1
Silver
NSL
NSL
mg/kg
1 4.1
1.6 J
4.9 J
4.6 J
5.1 J
3 h .1
Zinc
121
459
mg/kg
727 J
764 J
1 140
1 260
1380
1040
Total Organic
NSL
NSL
0/
/O
9.04
6.9
12.4
7.47
7.44
8.1
Sample Location:
RREC13-49
RREC13-50
RREC13-50
RREC13-50
RREC13-50
RREC13-50
Sample Name:
RREC13-49-0710
RREC13-50-SURF
RREC 13-5 0-0001
RREC 13-5 0-0103
RREC 13-5 0-03 05
RREC 13-5 0-05 07
Sample Depth (ft):
7-10
0-0.5
0-1
1-3
3-5
5-7
Date Sampled:
11/5/13
11/5/13
11/6/13
11/6/13
11/6/13
11/6/13
Analyte
TEC
PEC
Units
Arsenic
9.79
33
mg/kg
15
15.9
18.4
17.3
13.6
11.2
Barium
NSL
NSL
mg/kg
211
75 J
172 J
174 J
108 J
103 J
Cadmium
0.99
4.98
mg/kg
7
0.45 J
11.7
14.2
8.5
5
Chromium
43.4
111
mg/kg
253
21.3 J
111 .1
112 .1
64.7 J
62.6 .1
Copper
31.6
149
mg/kg
175
22.9
237
231
124
92.8
Iron
20000
40000
mg/kg
91600
52000 J
100000 J
95600 .1
82600 J
52100 J
Lead
35.8
128
mg/kg
306 J
25
259
245
146
118
Mercury
0.18
1.06
mg/kg
0.81
0.042 J
0.74 J
1.4 J
0.46 .1
0.5 .1
Nickel
22.7
48.6
mg/kg
150
18.9 J
41.6.1
51.6.1
37.8 J
35.9 J
Selenium
NSL
NSL
mg/kg
: 5 j
0.75 J
2.2 J
2.3 J
1.1 J
1 1 .1
Silver
NSL
NSL
mg/kg
3 7 .1
0 U
2.4
2.5
1.7
0 w J
Zinc
121
459
mg/kg
1090
172 J
1420 J
1280 J
746 J
453 .1
Total Organic
NSL
NSL
0/
/O
7.75
1.5
8.4
8.05
6.35
10.4
NOTES:
E = Value exceeds the highest standard in the initial calibration
range. Value is estimated.
J = Result is less than the Reporting Limit (RL) but greater than or
equal to the Method Detection Limit and the concentration is an
approximate value.
N = Spiked sample recovery not within control limits.
U = Indicates the analyte was analyzed for but not detected,
mg/kg = Milligrams per kilogram.
NSL=No Screening Level
TEC = Threshold effect concentration. Development and Evaluation
of Consensus-Based Sediment Quality Guidelines for Freshwater
Ecosystems (MacDonald et al. 2000).
PEC = Probable effect concentration. Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater
Ecosystems (MacDonald et al. 2000).
Bnlded values exceed the TEC.
liulded iiud shiided \nines exceed (lie PEC.
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 12 of 12
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-6 SEDIMENT RESULTS FOR SEM/AVS RATIO
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-01
RREC13-02
RREC13-03
RREC13-05
RREC13-06
RREC13-07
RREC13-09
RREC13-11
RREC13-13
Sample Name:
RREC13-01-SURF
RREC13-02-SURF
RREC13-03-SURF
RREC13-05-SURF
RREC13-06-SURF
RREC13-07-SURF
RREC13-09-SURF
RREC13-11-SURF
RREC13-13-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/30/13
10/30/13
11/5/13
11/5/13
11/5/13
11/5/13
11/4/13
11/4/13
11/4/13
Analyte
Units
Cadmium
umol/2 drv
0.059
0.0062 J
0.088
0.0092 J
0.011 J
0.0053 J
0.0055 J
0.034
0.046
Copper
umol/2 drv
2
0.46
1.8
0.6
0.45
0.35
1.6
1
0.88
Lead
umol/2 drv
0.77 J
0.17 J
0.75
0.3
0.47
0.19
0.36
1.8
1.9
Mercury
umol/2 drv
0.00018
0.00017
0.000069
0.000045
0.000034 J
0.000056
0.000099
0.00025
0.00016
Nickel
umol/2 drv
0.36
0.17 J
0.43
0.23
0.19 J
0.14 J
1
0.68
0.72
Zinc
umol/2 drv
6.1
2.3
7.7
2
2.1
1.5
2.2
23.4
31.2
E SEM
umol/2 drv
9.289
3.1062
10.768
3.1392
3.221
2.1853
5.1655
26.914
34.746
AVS
umol/2 drv
6.9
1.1
3.5
1.6
5.4
1.5
1.2
0.67 U
1.9
foe
fraction
0.0987
0.0904
0.116
0.0701
0.0553
0.0434
0.0353
0.0205
0.0344
SEM/AVS Ratio
none
1.35 J
2.99 J
3.03
2
0.593
1.47
4.31
18.2
Sample Location:
RREC13-18
RREC13-19
RREC13-20
RREC13-21
RREC13-22
RREC13-23
RREC13-24
RREC13-25
RREC13-26
Sample Name:
RREC13-18-SURF
RREC13-19-SURF
RREC13-20-SURF
RREC13-21-SURF
RREC13-22-SURF
RREC13-23-SURF
RREC13-24-SURF
RREC13-25-SURF
RREC13-26-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/29/13
10/29/13
10/29/13
10/29/13
10/29/13
10/30/13
11/4/13
11/4/13
11/04/13
Analyte
Units
Cadmium
umol/2 drv
0.013 J
0.0071 J
0.0051 J
0.024 J
0.019 J
0.031
0.0078 J
0.0051 J
0.014 J
Copper
umol/2 drv
0.77
0.35
0.22
0.99
0.77
1.2
1.3
0.39
1.1
Lead
umol/2 drv
0.32 J
0.37 J
0.11 J
0.51 J
0.36 J
0.71 J
0.44
0.31
0.43
Mercury
umol/2 drv
0.000053 J
0.000062
0.00003 J
0.000046 J
0.00014
0.00017
0.00026
0.00015
0.00019
Nickel
umol/2 drv
0.31 J
0.19 J
0.12 J
0.54 J
0.45
0.86
0.21
0.3
0.58
Zinc
umol/2 drv
3.1
1.7
1.1
4.5
3.7
5.4
4.4
4.2
4.8
E SEM
umol/2 drv
4.513
2.6171
1.5551
6.564
5.299
8.201
6.3578
5.2051
6.924
AVS
umol/p drv
8.5
14.9
2.4
23.8
4.3
11.8
7.1
0.8
2.9
foe
fraction
0.0573
0.0444
0.0513
0.0691
0.0589
0.074
0.0259
0.0309
0.0609
SEM/AVS Ratio
none
0.53 J
0.174 J
0.632 J
0.276 J
1.24 J
0.692 J
0.904
6.53
2.37
NOTES:
Bolded values exceed 1 SEM/AVS ratio
J = Indicates that the concentration is an estimated value.
U = Indicates the analyte was analyzed for but not detected.
SEM/AVS not calculated because AVS was not detected
AVS = Acid Volatile Sulfides
SEM = Simultaneously Extracted Metals
foe = fraction organic carbon
jjmol/g dry = micromole per gram dry weight
River Rouge/Ecorse Shoreline Assessment of Contaminated Sediments
Detroit River Area of Concern, Wayne County, Michigan Page 1 of 3 Site Characterization Report
-------
TABLE 3-6 SEDIMENT RESULTS FOR SEM/AVS RATIO
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-14
RREC13-14
RREC13-15
RREC13-16
RREC13-17
RREC13-32
RREC13-33
RREC13-34
RREC13-35
Sample Name:
RREC13-14-SURF
RREC13-14- SURF-FD
RREC13-15-SURF
RREC13-16-SURF
RREC13-17-SURF
RREC13-32-SURF
RREC13-33-SURF
RREC13-34-SURF
RREC13-35-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
11/4/13
11/4/13
11/4/13
10/29/13
10/29/13
10/30/13
10/30/13
10/30/13
10/30/13
Analyte
Units
Cadmium
umol/2 drv
0.035
0.045
0.074
0.022 J
0.013 J
0.0079 J
0.02 J
0.12
0.037
Copper
umol/2 drv
1.2
1.5
2.1
0.96
0.62
0.4
0.7
2.8
0.68
Lead
umol/2 drv
1.1
1.4
2
0.47 J
0.33 J
0.19
0.31
1.6
1.2
Mercury
umol/2 drv
0.00005
0.000074
0.000037 J
0.00021
0.000048 J
0.00026
0.00017
0.00015 J
0.00019
Nickel
umol/2 drv
1.1
1.4
1.3
0.5
0.31 J
0.32
0.46
3.8
0.26
Zinc
umol/2 drv
12.7
16.5
17.5
4.8
3
3.1
5.5
15.5
5.4
E SEM
umol/2 drv
16.135
20.845
22.974
6.752
4.273
4.0179
6.99
23.82
7.577
AVS
umol/2 drv
4.2
3
8.3
14.7
11.4
31.7
16
18.8
24.2
foe
fraction
0.0991
0.0879
0.0879
0.0665
0.0623
0.0595
0.0783
0.0574
0.0503
SEM/AVS Ratio
none
3.86
6.83
2.77
0.461 J
0.376 J
0.127
0.438
1.27 J
0.315
Sample Location:
RREC13-27
RREC13-28
RREC13-29
RREC13-30
RREC13-31
RREC13-42
RREC13-44
RREC13-45
RREC13-46
Sample Name:
RREC13-27-SURF
RREC13-28-SURF
RREC13-29-SURF
RREC13-30-SURF
RREC13-31-SURF
RREC13-42-SURF
RREC13-44-SURF
RREC13-45-SURF
RREC13-46-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
11/04/13
11/1/13
11/1/13
11/1/13
10/30/13
11/04/13
10/30/13
10/29/13
11/5/13
Analyte
Units
Cadmium
umol/2 drv
0.022
0.012 J
0.018 J
0.045
0.0057 J
0.0041 J
0.022 J
0.014 J
0.0035 J
Copper
umol/2 drv
1.6
0.64 J
0.82 J
1.3 J
0.38
0.47
1.1
0.57
0.21
Lead
umol/2 drv
0.59
0.29
0.35
0.7
0.12
0.23
0.42 J
0.28 J
0.089
Mercury
umol/2 drv
0.00021
0.000099
0.0002
0.00027
0.00016
0.00014
0.000074
0.000066
0.000035 U
Nickel
umol/2 drv
0.42
0.36
0.51
0.92
0.26 J
0.18 J
0.57
0.31 J
0.074 J
Zinc
umol/2 drv
9.3
4.4 J
4.9 J
6.7 J
1.8
1.7
4.4
3
0.78
E SEM
umol/2 drv
11.932
5.702
6.598
9.665
2.5657
2.5841
6.512
4.174
1.1565
AVS
umol/p drv
3
5.1
4.3
4.1
14.8
0.85
5.6
4.3
4.4
foe
fraction
0.0476
0.0874
0.106
0.0706
0.0619
0.0329
0.0698
0.07
0.0822
SEM/AVS Ratio
none
3.98
1.12
1.54
2.34
0.17
3.02
1.15 J
0.962 J
0.264
NOTES:
Bolded values exceed 1 SEM/AVS ratio
J = Indicates that the concentration is an estimated value.
U = Indicates the analyte was analyzed for but not detecti
SEM/AVS not calculated because AVS was not dete
AVS = Acid Volatile Sulfides
SEM = Simultaneously Extracted Metals
foe = fraction organic carbon
jjmol/g dry = micromole per gram dry weight
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 2 of 3
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-6 SEDIMENT RESULTS FOR SEM/AVS RATIO
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-36
RREC13-37
RREC13-38
RREC13-38
RREC13-39
RREC13-40
RREC13-41
Sample Name:
RREC13-36-SURF
RREC13-37-SURF
RREC13-38-SURF
RREC13-38-SURF-FD
RREC13-39-SURF
RREC13-40-SURF
RREC13-41-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/28/13
10/28/13
10/30/13
10/30/13
10/30/13
10/28/13
10/30/13
Analyte
Units
Cadmium
umol/2 drv
0.015 J
0.013 J
0.0086 J
0.012 J
0.014 J
0.009 J
0.06
Copper
umol/2 drv
0.57
0.43
0.37
0.53
0.66
0.36
2.3
Lead
umol/2 drv
0.48 J
0.17 J
0.12
0.16
0.32
0.15 J
0.7
Mercury
umol/2 drv
0.00012 U
0.000066
0.00023
0.00023
0.0002
0.00019
0.00011
Nickel
umol/2 drv
0.2 J
0.18 J
0.18 J
0.25
0.42
0.17 J
0.62
Zinc
umol/2 drv
5.1
2.5
1.9
2.6
4.3
2.1
5.4
E SEM
umol/2 drv
6.365
3.293
2.5786
3.552
5.714
2.789
9.08
AVS
umol/2 drv
55.6
3.6
2.4
3.3
1.9
4
2.3
foe
fraction
0.139
0.06
0.0233
0.0274
0.0793
0.0468
0.121
SEM/AVS Ratio
none
0.115 J
0.902 J
1.08
1.08
3.02
0.696 J
3.99
Sample Location:
RREC13-47
RREC13-47
RREC13-48
RREC13-48
RREC13-49
RREC13-49
RREC13-50
Sample Name:
RREC13-47-SURF
RREC13-47-SURF-FD
RREC13-48-SURF
RREC13-48-SURF-FD
RREC13-49-SURF
RREC13-49-SURF-FD
RREC13-50-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/30/13
10/30/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
Analyte
Units
Cadmium
umol/2 drv
0.021 J
0.02 J
0.016 J
0.016 J
0.017 J
0.019 J
0.0029 J
Copper
umol/2 drv
0.97
1
0.7
0.68
0.85
0.77
0.23
Lead
umol/2 drv
0.49 J
0.54 J
0.44
0.42
0.56
0.58
0.13
Mercury
umol/2 drv
0.00021
0.00016
0.000033 J
0.000023 J
0.000074
0.000095
0.000049
Nickel
umol/2 drv
0.62
0.65
0.48
0.45
0.41
0.4
0.12 J
Zinc
umol/2 drv
4.8
4.9
4.1
4.1
7
6.9
1.8
E SEM
umol/2 drv
6.901
7.11
5.736
5.666
8.837
8.669
2.2829
AVS
umol/p drv
6 J
1.3 J
6.1
16.6
2.3
3.3
0.96
foe
fraction
0.0833
0.063
0.0592
0.0631
0.0904
0.0691
0.0151
SEM/AVS Ratio
none
1.15 J
5.53 J
0.938
0.34
3.81
2.59
2.35
NOTES:
Bolded values exceed 1 SEM/AVS ratio
J = Indicates that the concentration is an estimated value.
U = Indicates the analyte was analyzed for but not detectt
" SEM/AVS not calculated because AVS was not dete
AVS = Acid Volatile Sulfides
SEM = Simultaneously Extracted Metals
foe = fraction organic carbon
jjmol/g dry = micromole per gram dry weight
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 3 of 3
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-7 SEDIMENT RESULTS FOR DIESEL RANGE ORGANICS AND MID-RANGE ORGANICS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-01
RREC 13-02
RREC 13-03
RREC 13-05
Sample Name:
RREC13-01-SURF
RREC13-02-SURF
RREC 13-03-SURF
RREC13-05-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/30/13
10/30/13
11/5/13
11/5/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
2700 J
290 UJ
1300 U
86 U
Diesel Range Organics (C10-C28)
mg/kg
8500 J
660 J
3,400
240
Mid Range Organics (C20-C36)
mg/kg
11000 J
1000 J
5,100
390
2 TPH
mg/kg
13700
1290
6400
476
Sample Location:
RREC13-11
RREC13-13
RREC13-14
RREC13-14
Sample Name:
RREC13-11-SURF
RREC13-13-SURF
RREC13-14-SURF
RREC13-14-SURF-FD
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
11/4/13
11/4/13
11/4/13
11/4/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
180 UJ
170 UJ
1000 U
1100U
Diesel Range Organics (C10-C28)
mg/kg
630 J
590 J
2,800
2,300
Mid Range Organics (C20-C36)
mg/kg
1100 J
1,100
4,000
3,400
2 TPH
mg/kg
1280
1270
5000
4500
NOTES:
U = Indicates the analyte was analyzed for but not detected.
Z TPH = Total Petroleum Hydrocarbons
Z TPH = DRO (C10-C28) + MRO (C20-C36)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 1 of 8
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-7 SEDIMENT RESULTS FOR DIESEL RANGE ORGANICS AND MID-RANGE ORGANICS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-06
RREC 13-07
RREC 13-09
Sample Name:
RREC13-06-SURF
RREC13-07-SURF
RREC13-09-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
Date Sampled:
11/5/13
11/5/13
11/4/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
170
48
470 UJ
Diesel Range Organics (C10-C28)
mg/kg
590
180
1200 J
Mid Range Organics (C20-C36)
mg/kg
1,000
320
2100 J
2 TPH
mg/kg
1170
368
2570
Sample Location:
RREC13-15
RREC13-16
RREC13-17
Sample Name:
RREC13-15-SURF
RREC13-16-SURF
RREC13-17-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
Date Sampled:
11/4/13
10/29/13
10/29/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
2400 U
1900 UJ
540 UJ
Diesel Range Organics (C10-C28)
mg/kg
6,700
3800 J
1700 J
Mid Range Organics (C20-C36)
mg/kg
9,100
6100 J
3000 J
2 TPH
mg/kg
11500
8000
3540
NOTES:
U = Indicates the analyte was analyzed for but not detected.
Z TPH = Total Petroleum Hydrocarbons
Z TPH = DRO (C10-C28) + MRO (C20-C36)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 2 of 8
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-7 SEDIMENT RESULTS FOR DIESEL RANGE ORGANICS AND MID-RANGE ORGANICS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-18
RREC13-19
RREC 13-20
RREC13-21
Sample Name:
RREC13-18-SURF
RREC 13-19-SURF
RREC13-20-SURF
RREC 13-21-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/29/13
10/29/13
10/29/13
10/29/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
680 UJ
240
200 U
2200 U
Diesel Range Organics (C10-C28)
mg/kg
1900 J
780
510
4,800
Mid Range Organics (C20-C36)
mg/kg
3200 J
1,200
860
8,700
2 TPH
mg/kg
3880
1440
1060
10900
Sample Location:
RREC13-26
RREC 13-27
RREC 13-28
RREC 13-29
Sample Name:
RREC13-26-SURF
RREC13-27-SURF
RREC13-28-SURF
RREC13-29-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
11/04/13
11/04/13
11/1/13
11/1/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
1400 J
440 J
550 U
1,900
Diesel Range Organics (C10-C28)
mg/kg
3700 J
1300 J
1,400
5,100
Mid Range Organics (C20-C36)
mg/kg
5,300
2,000
2,100
7,000
2 TPH
mg/kg
6700
2440
2650
8900
NOTES:
U = Indicates the analyte was analyzed for but not detected.
Z TPH = Total Petroleum Hydrocarbons
Z TPH = DRO (C10-C28) + MRO (C20-C36)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 3 of 8
Assessment of Contaminated Sediments
Site Characterization Report
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TABLE 3-7 SEDIMENT RESULTS FOR DIESEL RANGE ORGANICS AND MID-RANGE ORGANICS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-22
RREC 13-23
RREC 13-24
RREC 13-25
Sample Name:
RREC13-22-SURF
RREC 13-23-SURF
RREC13-24-SURF
RREC13-25-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/29/13
10/30/13
11/4/13
11/4/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
970
2000 J
310
170 U
Diesel Range Organics (C10-C28)
mg/kg
3,100
6300 J
790
250
Mid Range Organics (C20-C36)
mg/kg
5,000
10000 J
980
400
2 TPH
mg/kg
5970
12000
1290
570
Sample Location:
RREC 13-30
RREC13-31
RREC13-32
RREC13-33
Sample Name:
RREC13-30-SURF
RREC 13-31-SURF
RREC13-32-SURF
RREC13-33-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
11/1/13
10/30/13
10/30/13
10/30/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
2,900
250 U
190
1,100
Diesel Range Organics (C10-C28)
mg/kg
7,800
530
530
3,400
Mid Range Organics (C20-C36)
mg/kg
10,000
910 J
800 J
5200 J
2 TPH
mg/kg
12900
1160
990
6300
NOTES:
U = Indicates the analyte was analyzed for but not detected.
Z TPH = Total Petroleum Hydrocarbons
Z TPH = DRO (C10-C28) + MRO (C20-C36)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 4 of 8
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-7 SEDIMENT RESULTS FOR DIESEL RANGE ORGANICS AND MID-RANGE ORGANICS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-34
RREC13-34-SURF
0-0.5
10/30/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
8,800
Diesel Range Organics (C10-C28)
mg/kg
23,000
Mid Range Organics (C20-C36)
mg/kg
29,000
2 TPH
mg/kg
37800
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-44
RREC13-44-SURF
0-0.5
10/30/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
1800 UJ
Diesel Range Organics (C10-C28)
mg/kg
3000 J
Mid Range Organics (C20-C36)
mg/kg
5200 J
2 TPH
mg/kg
7000
NOTES:
U = Indicates the analyte was analyzed for but not detected.
Z TPH = Total Petroleum Hydrocarbons
Z TPH = DRO (C10-C28) + MRO (C20-C36)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 5 of 8
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 3-7 SEDIMENT RESULTS FOR DIESEL RANGE ORGANICS AND MID-RANGE ORGANICS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-35
RREC13-36
RREC13-37
RREC13-38
Sample Name:
RREC13-35-SURF
RREC13-36-SURF
RREC13-37-SURF
RREC13-38-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/30/13
10/28/13
10/28/13
10/30/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
530
1700 UJ
260 UJ
190 U
Diesel Range Organics (C10-C28)
mg/kg
1,800
3000 J
810 J
340
Mid Range Organics (C20-C36)
mg/kg
2500 J
7200 J
1300 J
550 J
2 TPH
mg/kg
3030
8900
1560
740
Sample Location:
RREC13-45
RREC13-46
RREC 13-47
RREC 13-47
Sample Name:
RREC13-45-SURF
RREC13-46-SURF
RREC13-47-SURF
RREC13-47-SURF-FD
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/29/13
11/5/13
10/30/13
10/30/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
490 U
460
1,100
970
Diesel Range Organics (C10-C28)
mg/kg
1,400
1,400
3,600
3,000
Mid Range Organics (C20-C36)
mg/kg
2,600
2,100
5600 J
4800 J
2 TPH
mg/kg
3090
2560
6700
5770
NOTES:
U = Indicates the analyte was analyzed for but not detected.
Z TPH = Total Petroleum Hydrocarbons
Z TPH = DRO (C10-C28) + MRO (C20-C36)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 6 of 8
Assessment of Contaminated Sediments
Site Characterization Report
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TABLE 3-7 SEDIMENT RESULTS FOR DIESEL RANGE ORGANICS AND MID-RANGE ORGANICS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-38
RREC13-39
RREC13-40
RREC 13-41
Sample Name:
RREC13-38-SURF-FD
RREC13-39-SURF
RREC13-40-SURF
RREC 13-41-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/30/13
10/30/13
10/28/13
10/30/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
110
350
210 UJ
5600 UJ
Diesel Range Organics (C10-C28)
mg/kg
360
1,000
470 J
21000 J
Mid Range Organics (C20-C36)
mg/kg
610
1,600
780 J
29000 J
2 TPH
mg/kg
720
1950
990
34600
Sample Location:
RREC13-48
RREC13-48
RREC 13-49
RREC 13-49
Sample Name:
RREC13-48-SURF
RREC13-48-SURF-FD
RREC13-49-SURF
RREC13-49-SURF-FD
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
11/5/13
11/5/13
11/5/13
11/5/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
550
560
330
410
Diesel Range Organics (C10-C28)
mg/kg
2,000
2,000
1,300
1,700
Mid Range Organics (C20-C36)
mg/kg
3,200
3,200
2,400
2,900
2 TPH
mg/kg
3750
3760
2730
3310
NOTES:
U = Indicates the analyte was analyzed for but not detected.
Z TPH = Total Petroleum Hydrocarbons
Z TPH = DRO (C10-C28) + MRO (C20-C36)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 7 of 8
Assessment of Contaminated Sediments
Site Characterization Report
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TABLE 3-7 SEDIMENT RESULTS FOR DIESEL RANGE ORGANICS AND MID-RANGE ORGANICS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-42
RREC13-42-SURF
0-0.5
11/04/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
130 J
Diesel Range Organics (C10-C28)
mg/kg
320 J
Mid Range Organics (C20-C36)
mg/kg
430
2 TPH
mg/kg
560
Sample Location:
Sample Name:
Sample Depth (ft):
Date Sampled:
RREC13-50
RREC13-50-SURF
0-0.5
11/5/13
Analyte
Units
Diesel Range Organics (C10-C20)
mg/kg
73
Diesel Range Organics (C10-C28)
mg/kg
180
Mid Range Organics (C20-C36)
mg/kg
220
2 TPH
mg/kg
293
NOTES:
U = Indicates the analyte was analyzed for but not detected.
Z TPH = Total Petroleum Hydrocarbons
Z TPH = DRO (C10-C28) + MRO (C20-C36)
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 8 of 8
Assessment of Contaminated Sediments
Site Characterization Report
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TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-01
Field Sample ID
RREC13-01-SURF
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.87
0.0987
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
2.00
20.26
446.00
0.05
2-Methylnaphthalene
447.00
154800
2.70
27.36
447.00
0.06
Acenaphthene (a)
491.00
33400
1.70
17.22
491.00
0.04
Acenaphthylene (a)
452.00
24000
0.68
6.89
452.00
0.02
Anthracene (a)
594.00
1300
4.50
45.59
594.00
0.08
Benzo(a)anthracene (a)
841.00
4153
6.70
67.88
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
4.50
45.59
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
4.00
40.53
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
3.20
32.42
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.50
15.20
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
4.10
41.54
981.00
0.04
CI Chrysenes (a)
929.00
6.10
61.80
929.00
0.07
CI Fluorenes(a)
611.00
0.96
9.73
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
12.00
121.58
770.00
0.16
CI-Naphthalenes (a)
444.00
3.10
31.41
444.00
0.07
Cl-Phenanthrenes/Anthracenes (a)
670.00
15.00
151.98
670.00
0.23
C2 Chrysenes (a)
1008.00
7.10
71.94
1008.00
0.07
C2 Fluorenes (a)
686.00
1.40
14.18
686.00
0.02
C2-Fluoranthenes/Pyrenes
7.40
74.97
C2-Naphthalenes (a)
510.00
10.00
101.32
510.00
0.20
C2-Phenanthrenes/Anthracenes (a)
746
10.00
101.32
746.00
0.14
C3 Chrysenes (a)
1112.00
2.70
27.36
1112.00
0.02
C3 Fluorenes (a)
769.00
3.10
31.41
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
4.90
49.65
949.00
0.05
C3-Naphthalenes(a)
581.00
9.50
96.25
581.00
0.17
C3-Phenanthrenes/Anthracenes (a)
829.00
9.70
98.28
829.00
0.12
C4 Chrysenes (a)
1214.00
1.50
15.20
1214.00
0.01
C4-Naphthalenes (a)
657.00
5.20
52.68
657.00
0.08
C4-Phenanthrenes/Anthracenes (a)
913.00
6.10
61.80
913.00
0.07
Chrysene ,a)
844.00
826
5.90
59.78
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.46
4.66
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
14.00
141.84
707.00
0.20
Fluorene ,a)
538.00
26,000.00
3.30
33.43
538.00
0.06
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.30
13.17
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
4.00
40.53
385.00
0.11
Perylene(a)
967.00
431.00
1.00
10.13
967.00
0.01
Phenanthrene ,a)
596
34300
14.00
141.84
596.00
0.24
Pyrene ,d'
697.00
9,090.00
11.00
111.45
697.00
0.16
ESBTU FCVi
2.03
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 1 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-01
Field Sample ID
RREC13-01-0001
Sample Depth
0-1
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
11.6
0.116
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
3.10
26.72
446.00
0.06
2-Methylnaphthalene
447.00
154800
4.20
36.21
447.00
0.08
Acenaphthene (a)
491.00
33400
1.70
14.66
491.00
0.03
Acenaphthylene (a)
452.00
24000
1.30
11.21
452.00
0.02
Anthracene (a)
594.00
1300
4.90
42.24
594.00
0.07
Benzo(a)anthracene (a)
841.00
4153
9.00
77.59
841.00
0.09
Benzo(a)pyrene (a)
965.00
3840
6.00
51.72
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
5.70
49.14
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
4.40
37.93
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
3.60
31.03
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
4.50
38.79
981.00
0.04
CI Chrysenes (a)
929.00
11.00
94.83
929.00
0.10
CI Fluorenes(a)
611.00
1.50
12.93
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
15.00
129.31
770.00
0.17
CI-Naphthalenes (a)
444.00
5.20
44.83
444.00
0.10
Cl-Phenanthrenes/Anthracenes (a)
670.00
17.00
146.55
670.00
0.22
C2 Chrysenes (a)
1008.00
10.00
86.21
1008.00
0.09
C2 Fluorenes (a)
686.00
2.40
20.69
686.00
0.03
C2-Fluoranthenes/Pyrenes
11.00
94.83
C2-Naphthalenes (a)
510.00
14.00
120.69
510.00
0.24
C2-Phenanthrenes/Anthracenes (a)
746
17.00
146.55
746.00
0.20
C3 Chrysenes (a)
1112.00
5.40
46.55
1112.00
0.04
C3 Fluorenes (a)
769.00
4.50
38.79
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
7.90
68.10
949.00
0.07
C3-Naphthalenes(a)
581.00
13.00
112.07
581.00
0.19
C3-Phenanthrenes/Anthracenes (a)
829.00
19.00
163.79
829.00
0.20
C4 Chrysenes (a)
1214.00
2.70
23.28
1214.00
0.02
C4-Naphthalenes (a)
657.00
7.80
67.24
657.00
0.10
C4-Phenanthrenes/Anthracenes (a)
913.00
13.00
112.07
913.00
0.12
Chrysene ,a)
844.00
826
8.30
71.55
844.00
0.08
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.40
12.07
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
12.00
103.45
707.00
0.15
Fluorene ,a)
538.00
26,000.00
3.70
31.90
538.00
0.06
Indeno(l,2,3-cd)pyrene ,a)
1115.00
3.00
25.86
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
6.00
51.72
385.00
0.13
Perylene(a)
967.00
431.00
1.40
12.07
967.00
0.01
Phenanthrene ,a)
596
34300
12.00
103.45
596.00
0.17
Pyrene ,d'
697.00
9,090.00
15.00
129.31
697.00
0.19
ESBTU FCVi
2.26
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 2 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-01
Field Sample ID
RREC13-01-0103
Sample Depth
1-3
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.9
0.109
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
8.50
77.98
446.00
0.17
2-Methylnaphthalene
447.00
154800
13.00
119.27
447.00
0.27
Acenaphthene (a)
491.00
33400
3.50
32.11
491.00
0.07
Acenaphthylene (a)
452.00
24000
4.10
37.61
452.00
0.08
Anthracene (a)
594.00
1300
18.00
165.14
594.00
0.28
Benzo(a)anthracene (a)
841.00
4153
27.00
247.71
841.00
0.29
Benzo(a)pyrene (a)
965.00
3840
20.00
183.49
965.00
0.19
Benzo(b)fluoranthene (a)
979.00
2169
14.00
128.44
979.00
0.13
Benzo(e)pyrene (a)
967.00
4300
13.00
119.27
967.00
0.12
Benzo(g,h,i)perylene (a)
1095.00
648
9.00
82.57
1095.00
0.08
Benzo(k)fluoranthene (a)
981.00
1220
15.00
137.61
981.00
0.14
CI Chrysenes (a)
929.00
30.00
275.23
929.00
0.30
CI Fluorenes(a)
611.00
5.30
48.62
611.00
0.08
Cl-Fluoranthenes/Pyrenes (a)
770.00
50.00
458.72
770.00
0.60
CI-Naphthalenes (a)
444.00
15.00
137.61
444.00
0.31
Cl-Phenanthrenes/Anthracenes (a)
670.00
58.00
532.11
670.00
0.79
C2 Chrysenes (a)
1008.00
21.00
192.66
1008.00
0.19
C2 Fluorenes (a)
686.00
7.30
66.97
686.00
0.10
C2-Fluoranthenes/Pyrenes
28.00
256.88
C2-Naphthalenes (a)
510.00
42.00
385.32
510.00
0.76
C2-Phenanthrenes/Anthracenes (a)
746
46.00
422.02
746.00
0.57
C3 Chrysenes (a)
1112.00
9.00
82.57
1112.00
0.07
C3 Fluorenes (a)
769.00
8.80
80.73
769.00
0.10
C3-Fluoranthenes/Pyrenes
949.00
13.00
119.27
949.00
0.13
C3-Naphthalenes(a)
581.00
39.00
357.80
581.00
0.62
C3-Phenanthrenes/Anthracenes (a)
829.00
27.00
247.71
829.00
0.30
C4 Chrysenes (a)
1214.00
3.00
27.52
1214.00
0.02
C4-Naphthalenes (a)
657.00
18.00
165.14
657.00
0.25
C4-Phenanthrenes/Anthracenes (a)
913.00
16.00
146.79
913.00
0.16
Chrysene ,a)
844.00
826
25.00
229.36
844.00
0.27
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
3.20
29.36
1123.00
0.03
Fluoranthene ,a)
707.00
23,870.00
41.00
376.15
707.00
0.53
Fluorene ,a)
538.00
26,000.00
4.10
37.61
538.00
0.07
Indeno(l,2,3-cd)pyrene ,a)
1115.00
4.10
37.61
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
14.00
128.44
385.00
0.33
Perylene(a)
967.00
431.00
4.10
37.61
967.00
0.04
Phenanthrene ,a)
596
34300
32.00
293.58
596.00
0.49
Pyrene ,d'
697.00
9,090.00
53.00
486.24
697.00
0.70
ESBTU FCVi
6.58
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 3 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-01
Field Sample ID
RREC13-01-0305
Sample Depth
3-5
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.42
0.0842
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
13.00
154.39
446.00
0.35
2-Methylnaphthalene
447.00
154800
21.00
249.41
447.00
0.56
Acenaphthene (a)
491.00
33400
10.00
118.76
491.00
0.24
Acenaphthylene (a)
452.00
24000
2.60
30.88
452.00
0.07
Anthracene (a)
594.00
1300
18.00
213.78
594.00
0.36
Benzo(a)anthracene (a)
841.00
4153
19.00
225.65
841.00
0.27
Benzo(a)pyrene (a)
965.00
3840
12.00
142.52
965.00
0.15
Benzo(b)fluoranthene (a)
979.00
2169
8.60
102.14
979.00
0.10
Benzo(e)pyrene (a)
967.00
4300
7.30
86.70
967.00
0.09
Benzo(g,h,i)perylene (a)
1095.00
648
4.50
53.44
1095.00
0.05
Benzo(k)fluoranthene (a)
981.00
1220
10.00
118.76
981.00
0.12
CI Chrysenes (a)
929.00
18.00
213.78
929.00
0.23
CI Fluorenes(a)
611.00
3.90
46.32
611.00
0.08
Cl-Fluoranthenes/Pyrenes (a)
770.00
38.00
451.31
770.00
0.59
CI-Naphthalenes (a)
444.00
22.00
261.28
444.00
0.59
Cl-Phenanthrenes/Anthracenes (a)
670.00
52.00
617.58
670.00
0.92
C2 Chrysenes (a)
1008.00
17.00
201.90
1008.00
0.20
C2 Fluorenes (a)
686.00
4.30
51.07
686.00
0.07
C2-Fluoranthenes/Pyrenes
19.00
225.65
C2-Naphthalenes (a)
510.00
53.00
629.45
510.00
1.23
C2-Phenanthrenes/Anthracenes (a)
746
29.00
344.42
746.00
0.46
C3 Chrysenes (a)
1112.00
7.20
85.51
1112.00
0.08
C3 Fluorenes (a)
769.00
7.00
83.14
769.00
0.11
C3-Fluoranthenes/Pyrenes
949.00
11.00
130.64
949.00
0.14
C3-Naphthalenes(a)
581.00
31.00
368.17
581.00
0.63
C3-Phenanthrenes/Anthracenes (a)
829.00
25.00
296.91
829.00
0.36
C4 Chrysenes (a)
1214.00
3.30
39.19
1214.00
0.03
C4-Naphthalenes (a)
657.00
13.00
154.39
657.00
0.23
C4-Phenanthrenes/Anthracenes (a)
913.00
16.00
190.02
913.00
0.21
Chrysene ,a)
844.00
826
16.00
190.02
844.00
0.23
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.40
16.63
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
39.00
463.18
707.00
0.66
Fluorene ,a)
538.00
26,000.00
14.00
166.27
538.00
0.31
Indeno(l,2,3-cd)pyrene ,a)
1115.00
4.00
47.51
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
27.00
320.67
385.00
0.83
Perylene(a)
967.00
431.00
2.80
33.25
967.00
0.03
Phenanthrene ,a)
596
34300
51.00
605.70
596.00
1.02
Pyrene ,d'
697.00
9,090.00
34.00
403.80
697.00
0.58
ESBTU FCVi
7.95
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 4 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-02
Field Sample ID
RREC13-02-SURF
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.04
0.0904
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.29
3.21
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.49
5.42
447.00
0.01
Acenaphthene (a)
491.00
33400
0.54
5.97
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.32
3.54
452.00
0.01
Anthracene (a)
594.00
1300
1.60
17.70
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
5.80
64.16
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
5.60
61.95
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
5.40
59.73
979.00
0.06
Benzo(e)pyrene (a)
967.00
4300
3.60
39.82
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.00
22.12
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
5.00
55.31
981.00
0.06
CI Chrysenes (a)
929.00
3.00
33.19
929.00
0.04
CI Fluorenes(a)
611.00
0.17
1.88
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.70
63.05
770.00
0.08
CI-Naphthalenes (a)
444.00
0.54
5.97
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.20
35.40
670.00
0.05
C2 Chrysenes (a)
1008.00
2.30
25.44
1008.00
0.03
C2 Fluorenes (a)
686.00
0.21
2.32
686.00
0.00
C2-Fluoranthenes/Pyrenes
2.40
26.55
C2-Naphthalenes (a)
510.00
1.30
14.38
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
1.70
18.81
746.00
0.03
C3 Chrysenes (a)
1112.00
0.78
8.63
1112.00
0.01
C3 Fluorenes (a)
769.00
0.32
3.54
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
1.10
12.17
949.00
0.01
C3-Naphthalenes(a)
581.00
1.10
12.17
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
1.10
12.17
829.00
0.01
C4 Chrysenes (a)
1214.00
0.18
1.99
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.50
5.53
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.68
7.52
913.00
0.01
Chrysene ,a)
844.00
826
5.20
57.52
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.57
6.31
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
9.00
99.56
707.00
0.14
Fluorene ,a)
538.00
26,000.00
0.74
8.19
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.80
19.91
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.60
6.64
385.00
0.02
Perylene(a)
967.00
431.00
1.40
15.49
967.00
0.02
Phenanthrene ,a)
596
34300
4.50
49.78
596.00
0.08
Pyrene ,d'
697.00
9,090.00
6.30
69.69
697.00
0.10
ESBTU FCVi
1.03
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 5 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-02
Field Sample ID
RREC13-02-0001
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.2
0.102
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.32
3.14
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.39
3.82
447.00
0.01
Acenaphthene (a)
491.00
33400
0.44
4.31
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.20
1.96
452.00
0.00
Anthracene (a)
594.00
1300
0.89
8.73
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
3.10
30.39
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.70
26.47
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.90
28.43
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.90
18.63
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.20
11.76
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.70
26.47
981.00
0.03
CI Chrysenes (a)
929.00
2.10
20.59
929.00
0.02
CI Fluorenes(a)
611.00
0.32
3.14
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.80
47.06
770.00
0.06
CI-Naphthalenes (a)
444.00
0.53
5.20
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.10
40.20
670.00
0.06
C2 Chrysenes (a)
1008.00
2.40
23.53
1008.00
0.02
C2 Fluorenes (a)
686.00
0.69
6.76
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.90
28.43
C2-Naphthalenes (a)
510.00
1.40
13.73
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
3.80
37.25
746.00
0.05
C3 Chrysenes (a)
1112.00
0.95
9.31
1112.00
0.01
C3 Fluorenes (a)
769.00
1.30
12.75
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.60
15.69
949.00
0.02
C3-Naphthalenes(a)
581.00
2.90
28.43
581.00
0.05
C3-Phenanthrenes/Anthracenes (a)
829.00
4.30
42.16
829.00
0.05
C4 Chrysenes (a)
1214.00
0.34
3.33
1214.00
0.00
C4-Naphthalenes (a)
657.00
2.30
22.55
657.00
0.03
C4-Phenanthrenes/Anthracenes (a)
913.00
2.60
25.49
913.00
0.03
Chrysene ,a)
844.00
826
3.20
31.37
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.35
3.43
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.40
52.94
707.00
0.07
Fluorene ,a)
538.00
26,000.00
0.63
6.18
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
10.78
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.60
15.69
385.00
0.04
Perylene(a)
967.00
431.00
0.78
7.65
967.00
0.01
Phenanthrene ,a)
596
34300
3.60
35.29
596.00
0.06
Pyrene ,d'
697.00
9,090.00
4.50
44.12
697.00
0.06
ESBTU FCVi
0.77
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 6 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-02
Field Sample ID
RREC13-02-0103
Sample Depth
1-3
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.17
0.0917
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.55
6.00
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.70
7.63
447.00
0.02
Acenaphthene (a)
491.00
33400
0.89
9.71
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.31
3.38
452.00
0.01
Anthracene (a)
594.00
1300
2.20
23.99
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
5.30
57.80
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
4.00
43.62
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
4.80
52.34
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
3.00
32.72
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.80
19.63
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
4.40
47.98
981.00
0.05
CI Chrysenes (a)
929.00
3.40
37.08
929.00
0.04
CI Fluorenes(a)
611.00
0.52
5.67
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
7.50
81.79
770.00
0.11
CI-Naphthalenes (a)
444.00
0.94
10.25
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
6.90
75.25
670.00
0.11
C2 Chrysenes (a)
1008.00
3.70
40.35
1008.00
0.04
C2 Fluorenes (a)
686.00
1.10
12.00
686.00
0.02
C2-Fluoranthenes/Pyrenes
4.30
46.89
C2-Naphthalenes (a)
510.00
2.90
31.62
510.00
0.06
C2-Phenanthrenes/Anthracenes (a)
746
6.60
71.97
746.00
0.10
C3 Chrysenes (a)
1112.00
1.20
13.09
1112.00
0.01
C3 Fluorenes (a)
769.00
2.30
25.08
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
2.40
26.17
949.00
0.03
C3-Naphthalenes(a)
581.00
6.10
66.52
581.00
0.11
C3-Phenanthrenes/Anthracenes (a)
829.00
6.60
71.97
829.00
0.09
C4 Chrysenes (a)
1214.00
0.53
5.78
1214.00
0.00
C4-Naphthalenes (a)
657.00
4.50
49.07
657.00
0.07
C4-Phenanthrenes/Anthracenes (a)
913.00
4.90
53.44
913.00
0.06
Chrysene ,a)
844.00
826
5.50
59.98
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.52
5.67
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
11.00
119.96
707.00
0.17
Fluorene ,a)
538.00
26,000.00
1.10
12.00
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.60
17.45
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
3.50
38.17
385.00
0.10
Perylene(a)
967.00
431.00
0.92
10.03
967.00
0.01
Phenanthrene ,a)
596
34300
6.60
71.97
596.00
0.12
Pyrene ,d'
697.00
9,090.00
7.30
79.61
697.00
0.11
ESBTU FCVi
1.48
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 7 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-02
Field Sample ID
RREC13-02-0305
Sample Depth
3-5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.7
0.107
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.58
5.42
446.00
0.01
2-Methylnaphthalene
447.00
154800
1.00
9.35
447.00
0.02
Acenaphthene (a)
491.00
33400
1.70
15.89
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.43
4.02
452.00
0.01
Anthracene (a)
594.00
1300
3.70
34.58
594.00
0.06
Benzo(a)anthracene (a)
841.00
4153
7.40
69.16
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
5.40
50.47
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
6.40
59.81
979.00
0.06
Benzo(e)pyrene (a)
967.00
4300
3.90
36.45
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.60
24.30
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
6.00
56.07
981.00
0.06
CI Chrysenes (a)
929.00
3.40
31.78
929.00
0.03
CI Fluorenes(a)
611.00
0.39
3.64
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
8.30
77.57
770.00
0.10
CI-Naphthalenes (a)
444.00
1.10
10.28
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
5.90
55.14
670.00
0.08
C2 Chrysenes (a)
1008.00
3.70
34.58
1008.00
0.03
C2 Fluorenes (a)
686.00
0.78
7.29
686.00
0.01
C2-Fluoranthenes/Pyrenes
3.90
36.45
C2-Naphthalenes (a)
510.00
2.20
20.56
510.00
0.04
C2-Phenanthrenes/Anthracenes (a)
746
4.90
45.79
746.00
0.06
C3 Chrysenes (a)
1112.00
1.20
11.21
1112.00
0.01
C3 Fluorenes (a)
769.00
1.50
14.02
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
2.10
19.63
949.00
0.02
C3-Naphthalenes(a)
581.00
3.70
34.58
581.00
0.06
C3-Phenanthrenes/Anthracenes (a)
829.00
5.50
51.40
829.00
0.06
C4 Chrysenes (a)
1214.00
0.34
3.18
1214.00
0.00
C4-Naphthalenes (a)
657.00
3.00
28.04
657.00
0.04
C4-Phenanthrenes/Anthracenes (a)
913.00
4.10
38.32
913.00
0.04
Chrysene ,a)
844.00
826
7.10
66.36
844.00
0.08
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.69
6.45
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
17.00
158.88
707.00
0.22
Fluorene ,a)
538.00
26,000.00
2.20
20.56
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.50
23.36
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
2.40
22.43
385.00
0.06
Perylene(a)
967.00
431.00
1.30
12.15
967.00
0.01
Phenanthrene ,a)
596
34300
12.00
112.15
596.00
0.19
Pyrene ,d'
697.00
9,090.00
11.00
102.80
697.00
0.15
ESBTU FCVi
1.57
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 8 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-02
Field Sample ID
RREC13-02-0507
Sample Depth
5-7
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.1
0.091
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
2.50
27.47
446.00
0.06
2-Methylnaphthalene
447.00
154800
4.30
47.25
447.00
0.11
Acenaphthene (a)
491.00
33400
5.50
60.44
491.00
0.12
Acenaphthylene (a)
452.00
24000
0.71
7.80
452.00
0.02
Anthracene (a)
594.00
1300
7.10
78.02
594.00
0.13
Benzo(a)anthracene (a)
841.00
4153
11.00
120.88
841.00
0.14
Benzo(a)pyrene (a)
965.00
3840
9.00
98.90
965.00
0.10
Benzo(b)fluoranthene (a)
979.00
2169
7.60
83.52
979.00
0.09
Benzo(e)pyrene (a)
967.00
4300
5.70
62.64
967.00
0.06
Benzo(g,h,i)perylene (a)
1095.00
648
4.30
47.25
1095.00
0.04
Benzo(k)fluoranthene (a)
981.00
1220
9.90
108.79
981.00
0.11
CI Chrysenes (a)
929.00
5.90
64.84
929.00
0.07
CI Fluorenes(a)
611.00
1.30
14.29
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
14.00
153.85
770.00
0.20
CI-Naphthalenes (a)
444.00
4.70
51.65
444.00
0.12
Cl-Phenanthrenes/Anthracenes (a)
670.00
14.00
153.85
670.00
0.23
C2 Chrysenes (a)
1008.00
5.10
56.04
1008.00
0.06
C2 Fluorenes (a)
686.00
2.00
21.98
686.00
0.03
C2-Fluoranthenes/Pyrenes
6.70
73.63
C2-Naphthalenes (a)
510.00
9.70
106.59
510.00
0.21
C2-Phenanthrenes/Anthracenes (a)
746
10.00
109.89
746.00
0.15
C3 Chrysenes (a)
1112.00
1.70
18.68
1112.00
0.02
C3 Fluorenes (a)
769.00
3.50
38.46
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
3.80
41.76
949.00
0.04
C3-Naphthalenes(a)
581.00
14.00
153.85
581.00
0.26
C3-Phenanthrenes/Anthracenes (a)
829.00
9.80
107.69
829.00
0.13
C4 Chrysenes (a)
1214.00
0.71
7.80
1214.00
0.01
C4-Naphthalenes (a)
657.00
8.60
94.51
657.00
0.14
C4-Phenanthrenes/Anthracenes (a)
913.00
6.70
73.63
913.00
0.08
Chrysene ,a)
844.00
826
11.00
120.88
844.00
0.14
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.30
14.29
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
29.00
318.68
707.00
0.45
Fluorene ,a)
538.00
26,000.00
5.50
60.44
538.00
0.11
Indeno(l,2,3-cd)pyrene ,a)
1115.00
4.00
43.96
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
30.00
329.67
385.00
0.86
Perylene(a)
967.00
431.00
2.40
26.37
967.00
0.03
Phenanthrene ,a)
596
34300
26.00
285.71
596.00
0.48
Pyrene ,d'
697.00
9,090.00
18.00
197.80
697.00
0.28
ESBTU FCVi
4.12
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 9 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-02
Field Sample ID
RREC13-02-0709
Sample Depth
7-9
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
14.2
0.142
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.20
8.45
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.20
8.45
447.00
0.02
Acenaphthene (a)
491.00
33400
1.80
12.68
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.63
4.44
452.00
0.01
Anthracene (a)
594.00
1300
4.20
29.58
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
9.00
63.38
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
6.30
44.37
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
6.70
47.18
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
4.30
30.28
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
2.90
20.42
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
5.60
39.44
981.00
0.04
CI Chrysenes (a)
929.00
4.70
33.10
929.00
0.04
CI Fluorenes(a)
611.00
0.84
5.92
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
11.00
77.46
770.00
0.10
CI-Naphthalenes (a)
444.00
2.10
14.79
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
9.60
67.61
670.00
0.10
C2 Chrysenes (a)
1008.00
3.30
23.24
1008.00
0.02
C2 Fluorenes (a)
686.00
1.30
9.15
686.00
0.01
C2-Fluoranthenes/Pyrenes
5.00
35.21
C2-Naphthalenes (a)
510.00
4.60
32.39
510.00
0.06
C2-Phenanthrenes/Anthracenes (a)
746
8.00
56.34
746.00
0.08
C3 Chrysenes (a)
1112.00
1.20
8.45
1112.00
0.01
C3 Fluorenes (a)
769.00
2.60
18.31
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
2.90
20.42
949.00
0.02
C3-Naphthalenes(a)
581.00
7.40
52.11
581.00
0.09
C3-Phenanthrenes/Anthracenes (a)
829.00
7.80
54.93
829.00
0.07
C4 Chrysenes (a)
1214.00
0.58
4.08
1214.00
0.00
C4-Naphthalenes (a)
657.00
5.40
38.03
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
5.40
38.03
913.00
0.04
Chrysene ,a)
844.00
826
8.70
61.27
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.76
5.35
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
18.00
126.76
707.00
0.18
Fluorene ,a)
538.00
26,000.00
2.90
20.42
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.60
18.31
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
9.00
63.38
385.00
0.16
Perylene(a)
967.00
431.00
1.70
11.97
967.00
0.01
Phenanthrene ,a)
596
34300
13.00
91.55
596.00
0.15
Pyrene ,d'
697.00
9,090.00
13.00
91.55
697.00
0.13
ESBTU FCVi
1.55
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 10 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-02
Field Sample ID
RREC13-02-0911
Sample Depth
9-11
Sample Date
11/02/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
16.4
0.164
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.70
10.37
446.00
0.02
2-Methylnaphthalene
447.00
154800
2.60
15.85
447.00
0.04
Acenaphthene (a)
491.00
33400
2.10
12.80
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.65
3.96
452.00
0.01
Anthracene (a)
594.00
1300
3.80
23.17
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
5.60
34.15
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
4.30
26.22
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
3.80
23.17
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
3.10
18.90
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
2.70
16.46
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
3.70
22.56
981.00
0.02
CI Chrysenes (a)
929.00
4.90
29.88
929.00
0.03
CI Fluorenes(a)
611.00
0.84
5.12
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
7.20
43.90
770.00
0.06
CI-Naphthalenes (a)
444.00
3.20
19.51
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
9.00
54.88
670.00
0.08
C2 Chrysenes (a)
1008.00
3.10
18.90
1008.00
0.02
C2 Fluorenes (a)
686.00
1.40
8.54
686.00
0.01
C2-Fluoranthenes/Pyrenes
4.30
26.22
C2-Naphthalenes (a)
510.00
7.30
44.51
510.00
0.09
C2-Phenanthrenes/Anthracenes (a)
746
8.30
50.61
746.00
0.07
C3 Chrysenes (a)
1112.00
1.40
8.54
1112.00
0.01
C3 Fluorenes (a)
769.00
2.80
17.07
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
2.60
15.85
949.00
0.02
C3-Naphthalenes(a)
581.00
8.70
53.05
581.00
0.09
C3-Phenanthrenes/Anthracenes (a)
829.00
7.50
45.73
829.00
0.06
C4 Chrysenes (a)
1214.00
0.68
4.15
1214.00
0.00
C4-Naphthalenes (a)
657.00
6.10
37.20
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
5.10
31.10
913.00
0.03
Chrysene ,a)
844.00
826
5.60
34.15
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.96
5.85
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
11.00
67.07
707.00
0.09
Fluorene ,a)
538.00
26,000.00
4.30
26.22
538.00
0.05
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.60
15.85
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
8.50
51.83
385.00
0.13
Perylene(a)
967.00
431.00
1.10
6.71
967.00
0.01
Phenanthrene ,a)
596
34300
10.00
60.98
596.00
0.10
Pyrene ,d'
697.00
9,090.00
10.00
60.98
697.00
0.09
ESBTU FCVi
1.10
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 11 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-03
Field Sample ID
RREC13-03-SURF
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
11.6
0.116
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.00
8.62
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.80
15.52
447.00
0.03
Acenaphthene (a)
491.00
33400
1.30
11.21
491.00
0.02
Acenaphthylene (a)
452.00
24000
1.60
13.79
452.00
0.03
Anthracene (a)
594.00
1300
7.10
61.21
594.00
0.10
Benzo(a)anthracene (a)
841.00
4153
16.00
137.93
841.00
0.16
Benzo(a)pyrene (a)
965.00
3840
13.00
112.07
965.00
0.12
Benzo(b)fluoranthene (a)
979.00
2169
9.60
82.76
979.00
0.08
Benzo(e)pyrene (a)
967.00
4300
7.50
64.66
967.00
0.07
Benzo(g,h,i)perylene (a)
1095.00
648
6.00
51.72
1095.00
0.05
Benzo(k)fluoranthene (a)
981.00
1220
13.00
112.07
981.00
0.11
CI Chrysenes (a)
929.00
1.60
13.79
929.00
0.01
CI Fluorenes(a)
611.00
0.83
7.16
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
18.00
155.17
770.00
0.20
CI-Naphthalenes (a)
444.00
2.00
17.24
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
13.00
112.07
670.00
0.17
C2 Chrysenes (a)
1008.00
1.60
13.79
1008.00
0.01
C2 Fluorenes (a)
686.00
0.88
7.59
686.00
0.01
C2-Fluoranthenes/Pyrenes
7.80
67.24
C2-Naphthalenes (a)
510.00
4.80
41.38
510.00
0.08
C2-Phenanthrenes/Anthracenes (a)
746
7.00
60.34
746.00
0.08
C3 Chrysenes (a)
1112.00
1.60
13.79
1112.00
0.01
C3 Fluorenes (a)
769.00
1.50
12.93
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
3.60
31.03
949.00
0.03
C3-Naphthalenes(a)
581.00
4.40
37.93
581.00
0.07
C3-Phenanthrenes/Anthracenes (a)
829.00
5.50
47.41
829.00
0.06
C4 Chrysenes (a)
1214.00
1.60
13.79
1214.00
0.01
C4-Naphthalenes (a)
657.00
2.50
21.55
657.00
0.03
C4-Phenanthrenes/Anthracenes (a)
913.00
3.50
30.17
913.00
0.03
Chrysene ,a)
844.00
826
13.00
112.07
844.00
0.13
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.90
16.38
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
26.00
224.14
707.00
0.32
Fluorene ,a)
538.00
26,000.00
3.90
33.62
538.00
0.06
Indeno(l,2,3-cd)pyrene ,a)
1115.00
5.80
50.00
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
4.40
37.93
385.00
0.10
Perylene(a)
967.00
431.00
3.20
27.59
967.00
0.03
Phenanthrene ,a)
596
34300
21.00
181.03
596.00
0.30
Pyrene ,d'
697.00
9,090.00
17.00
146.55
697.00
0.21
ESBTU FCVi
2.54
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 12 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-03
Field Sample ID
RREC13-03-0001
Sample Depth
0-1
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.06
0.0606
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.30
21.45
446.00
0.05
2-Methylnaphthalene
447.00
154800
2.10
34.65
447.00
0.08
Acenaphthene (a)
491.00
33400
1.20
19.80
491.00
0.04
Acenaphthylene (a)
452.00
24000
0.77
12.71
452.00
0.03
Anthracene (a)
594.00
1300
4.00
66.01
594.00
0.11
Benzo(a)anthracene (a)
841.00
4153
7.20
118.81
841.00
0.14
Benzo(a)pyrene (a)
965.00
3840
4.90
80.86
965.00
0.08
Benzo(b)fluoranthene (a)
979.00
2169
3.90
64.36
979.00
0.07
Benzo(e)pyrene (a)
967.00
4300
3.30
54.46
967.00
0.06
Benzo(g,h,i)perylene (a)
1095.00
648
2.30
37.95
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
4.00
66.01
981.00
0.07
CI Chrysenes (a)
929.00
7.00
115.51
929.00
0.12
CI Fluorenes(a)
611.00
0.80
13.20
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
12.00
198.02
770.00
0.26
CI-Naphthalenes (a)
444.00
2.30
37.95
444.00
0.09
Cl-Phenanthrenes/Anthracenes (a)
670.00
13.00
214.52
670.00
0.32
C2 Chrysenes (a)
1008.00
6.30
103.96
1008.00
0.10
C2 Fluorenes (a)
686.00
1.30
21.45
686.00
0.03
C2-Fluoranthenes/Pyrenes
8.10
133.66
C2-Naphthalenes (a)
510.00
7.00
115.51
510.00
0.23
C2-Phenanthrenes/Anthracenes (a)
746
10.00
165.02
746.00
0.22
C3 Chrysenes (a)
1112.00
3.00
49.50
1112.00
0.04
C3 Fluorenes (a)
769.00
2.70
44.55
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
5.10
84.16
949.00
0.09
C3-Naphthalenes(a)
581.00
7.20
118.81
581.00
0.20
C3-Phenanthrenes/Anthracenes (a)
829.00
10.00
165.02
829.00
0.20
C4 Chrysenes (a)
1214.00
1.60
26.40
1214.00
0.02
C4-Naphthalenes (a)
657.00
4.60
75.91
657.00
0.12
C4-Phenanthrenes/Anthracenes (a)
913.00
7.90
130.36
913.00
0.14
Chrysene ,a)
844.00
826
6.40
105.61
844.00
0.13
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.78
12.87
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
12.00
198.02
707.00
0.28
Fluorene ,a)
538.00
26,000.00
2.30
37.95
538.00
0.07
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.00
33.00
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
5.80
95.71
385.00
0.25
Perylene(a)
967.00
431.00
1.10
18.15
967.00
0.02
Phenanthrene ,a)
596
34300
11.00
181.52
596.00
0.30
Pyrene ,d'
697.00
9,090.00
9.50
156.77
697.00
0.22
ESBTU FCVi
3.19
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 13 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-03
Field Sample ID
RREC13-03-0103
Sample Depth
1-3
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.97
0.0697
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.90
27.26
446.00
0.06
2-Methylnaphthalene
447.00
154800
3.20
45.91
447.00
0.10
Acenaphthene (a)
491.00
33400
1.60
22.96
491.00
0.05
Acenaphthylene (a)
452.00
24000
1.10
15.78
452.00
0.03
Anthracene (a)
594.00
1300
4.40
63.13
594.00
0.11
Benzo(a)anthracene (a)
841.00
4153
8.40
120.52
841.00
0.14
Benzo(a)pyrene (a)
965.00
3840
5.70
81.78
965.00
0.08
Benzo(b)fluoranthene (a)
979.00
2169
4.30
61.69
979.00
0.06
Benzo(e)pyrene (a)
967.00
4300
3.80
54.52
967.00
0.06
Benzo(g,h,i)perylene (a)
1095.00
648
2.80
40.17
1095.00
0.04
Benzo(k)fluoranthene (a)
981.00
1220
4.50
64.56
981.00
0.07
CI Chrysenes (a)
929.00
8.00
114.78
929.00
0.12
CI Fluorenes(a)
611.00
0.93
13.34
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
14.00
200.86
770.00
0.26
CI-Naphthalenes (a)
444.00
3.50
50.22
444.00
0.11
Cl-Phenanthrenes/Anthracenes (a)
670.00
16.00
229.56
670.00
0.34
C2 Chrysenes (a)
1008.00
6.60
94.69
1008.00
0.09
C2 Fluorenes (a)
686.00
1.50
21.52
686.00
0.03
C2-Fluoranthenes/Pyrenes
9.00
129.12
C2-Naphthalenes (a)
510.00
8.00
114.78
510.00
0.23
C2-Phenanthrenes/Anthracenes (a)
746
12.00
172.17
746.00
0.23
C3 Chrysenes (a)
1112.00
3.40
48.78
1112.00
0.04
C3 Fluorenes (a)
769.00
3.50
50.22
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
5.60
80.34
949.00
0.08
C3-Naphthalenes(a)
581.00
8.00
114.78
581.00
0.20
C3-Phenanthrenes/Anthracenes (a)
829.00
14.00
200.86
829.00
0.24
C4 Chrysenes (a)
1214.00
1.70
24.39
1214.00
0.02
C4-Naphthalenes (a)
657.00
5.50
78.91
657.00
0.12
C4-Phenanthrenes/Anthracenes (a)
913.00
8.80
126.26
913.00
0.14
Chrysene ,a)
844.00
826
7.60
109.04
844.00
0.13
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.98
14.06
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
12.00
172.17
707.00
0.24
Fluorene ,a)
538.00
26,000.00
2.70
38.74
538.00
0.07
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.40
34.43
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
8.10
116.21
385.00
0.30
Perylene(a)
967.00
431.00
1.30
18.65
967.00
0.02
Phenanthrene ,a)
596
34300
12.00
172.17
596.00
0.29
Pyrene ,d'
697.00
9,090.00
11.00
157.82
697.00
0.23
ESBTU FCVi
3.30
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 14 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-03
Field Sample ID
RREC13-03-0305
Sample Depth
3-5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.76
0.0476
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.60
33.61
446.00
0.08
2-Methylnaphthalene
447.00
154800
2.90
60.92
447.00
0.14
Acenaphthene (a)
491.00
33400
1.40
29.41
491.00
0.06
Acenaphthylene (a)
452.00
24000
0.78
16.39
452.00
0.04
Anthracene (a)
594.00
1300
4.50
94.54
594.00
0.16
Benzo(a)anthracene (a)
841.00
4153
6.60
138.66
841.00
0.16
Benzo(a)pyrene (a)
965.00
3840
4.60
96.64
965.00
0.10
Benzo(b)fluoranthene (a)
979.00
2169
3.50
73.53
979.00
0.08
Benzo(e)pyrene (a)
967.00
4300
2.80
58.82
967.00
0.06
Benzo(g,h,i)perylene (a)
1095.00
648
2.30
48.32
1095.00
0.04
Benzo(k)fluoranthene (a)
981.00
1220
3.80
79.83
981.00
0.08
CI Chrysenes (a)
929.00
5.80
121.85
929.00
0.13
CI Fluorenes(a)
611.00
0.79
16.60
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
12.00
252.10
770.00
0.33
CI-Naphthalenes (a)
444.00
3.00
63.03
444.00
0.14
Cl-Phenanthrenes/Anthracenes (a)
670.00
12.00
252.10
670.00
0.38
C2 Chrysenes (a)
1008.00
5.60
117.65
1008.00
0.12
C2 Fluorenes (a)
686.00
1.10
23.11
686.00
0.03
C2-Fluoranthenes/Pyrenes
6.70
140.76
C2-Naphthalenes (a)
510.00
7.30
153.36
510.00
0.30
C2-Phenanthrenes/Anthracenes (a)
746
8.40
176.47
746.00
0.24
C3 Chrysenes (a)
1112.00
2.80
58.82
1112.00
0.05
C3 Fluorenes (a)
769.00
2.40
50.42
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
4.80
100.84
949.00
0.11
C3-Naphthalenes(a)
581.00
6.90
144.96
581.00
0.25
C3-Phenanthrenes/Anthracenes (a)
829.00
9.40
197.48
829.00
0.24
C4 Chrysenes (a)
1214.00
1.40
29.41
1214.00
0.02
C4-Naphthalenes (a)
657.00
4.30
90.34
657.00
0.14
C4-Phenanthrenes/Anthracenes (a)
913.00
6.60
138.66
913.00
0.15
Chrysene ,a)
844.00
826
5.70
119.75
844.00
0.14
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.70
14.71
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
11.00
231.09
707.00
0.33
Fluorene ,a)
538.00
26,000.00
2.60
54.62
538.00
0.10
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.00
42.02
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
8.80
184.87
385.00
0.48
Perylene(a)
967.00
431.00
1.10
23.11
967.00
0.02
Phenanthrene ,a)
596
34300
12.00
252.10
596.00
0.42
Pyrene ,d'
697.00
9,090.00
9.40
197.48
697.00
0.28
ESBTU FCVi
4.07
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 15 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-03
Field Sample ID
RREC13-03-0507
Sample Depth
5-7
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
0.68
0.0068
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.03
4.28
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.04
6.19
447.00
0.01
Acenaphthene (a)
491.00
33400
0.03
4.42
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.02
2.80
452.00
0.01
Anthracene (a)
594.00
1300
0.08
11.95
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
0.13
19.17
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
0.09
13.72
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
0.07
10.77
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.06
8.70
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.05
6.64
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
0.07
10.91
981.00
0.01
CI Chrysenes (a)
929.00
0.12
17.70
929.00
0.02
CI Fluorenes(a)
611.00
0.02
2.65
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.21
30.97
770.00
0.04
CI-Naphthalenes (a)
444.00
0.05
7.23
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.23
33.92
670.00
0.05
C2 Chrysenes (a)
1008.00
0.10
14.01
1008.00
0.01
C2 Fluorenes (a)
686.00
0.02
3.24
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.13
19.17
C2-Naphthalenes (a)
510.00
0.14
20.65
510.00
0.04
C2-Phenanthrenes/Anthracenes (a)
746
0.14
20.65
746.00
0.03
C3 Chrysenes (a)
1112.00
0.04
6.34
1112.00
0.01
C3 Fluorenes (a)
769.00
0.04
5.90
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.08
11.65
949.00
0.01
C3-Naphthalenes(a)
581.00
0.20
29.50
581.00
0.05
C3-Phenanthrenes/Anthracenes (a)
829.00
0.16
23.60
829.00
0.03
C4 Chrysenes (a)
1214.00
0.02
3.39
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.16
23.60
657.00
0.04
C4-Phenanthrenes/Anthracenes (a)
913.00
0.10
14.01
913.00
0.02
Chrysene ,a)
844.00
826
0.12
17.70
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.01
1.92
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.21
30.97
707.00
0.04
Fluorene ,a)
538.00
26,000.00
0.05
7.08
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.04
5.46
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.11
16.22
385.00
0.04
Perylene(a)
967.00
431.00
0.04
6.05
967.00
0.01
Phenanthrene ,a)
596
34300
0.24
35.40
596.00
0.06
Pyrene ,d'
697.00
9,090.00
0.19
28.02
697.00
0.04
ESBTU FCVi
0.52
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 16 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-05
Field Sample ID
RREC13-05-SURF
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.01
0.0701
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.68
9.70
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.00
14.27
447.00
0.03
Acenaphthene (a)
491.00
33400
0.36
5.14
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.28
3.99
452.00
0.01
Anthracene (a)
594.00
1300
1.40
19.97
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.00
42.80
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
2.30
32.81
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
1.80
25.68
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.60
22.82
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.20
17.12
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.90
27.10
981.00
0.03
CI Chrysenes (a)
929.00
2.80
39.94
929.00
0.04
CI Fluorenes(a)
611.00
0.37
5.28
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.80
68.47
770.00
0.09
CI-Naphthalenes (a)
444.00
1.20
17.12
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
5.90
84.17
670.00
0.13
C2 Chrysenes (a)
1008.00
2.30
32.81
1008.00
0.03
C2 Fluorenes (a)
686.00
0.69
9.84
686.00
0.01
C2-Fluoranthenes/Pyrenes
3.20
45.65
C2-Naphthalenes (a)
510.00
3.80
54.21
510.00
0.11
C2-Phenanthrenes/Anthracenes (a)
746
4.80
68.47
746.00
0.09
C3 Chrysenes (a)
1112.00
1.10
15.69
1112.00
0.01
C3 Fluorenes (a)
769.00
1.50
21.40
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
2.30
32.81
949.00
0.03
C3-Naphthalenes(a)
581.00
4.50
64.19
581.00
0.11
C3-Phenanthrenes/Anthracenes (a)
829.00
4.80
68.47
829.00
0.08
C4 Chrysenes (a)
1214.00
0.61
8.70
1214.00
0.01
C4-Naphthalenes (a)
657.00
2.90
41.37
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
3.20
45.65
913.00
0.05
Chrysene ,a)
844.00
826
2.80
39.94
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.34
4.85
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.90
69.90
707.00
0.10
Fluorene ,a)
538.00
26,000.00
0.78
11.13
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
15.69
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.60
22.82
385.00
0.06
Perylene(a)
967.00
431.00
0.60
8.56
967.00
0.01
Phenanthrene ,a)
596
34300
3.90
55.63
596.00
0.09
Pyrene ,d'
697.00
9,090.00
3.80
54.21
697.00
0.08
ESBTU FCVi
1.15
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 17 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-05
Field Sample ID
RREC13-05-0001
Sample Depth
0-1
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.49
0.0549
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.38
6.92
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.63
11.48
447.00
0.03
Acenaphthene (a)
491.00
33400
0.68
12.39
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.48
8.74
452.00
0.02
Anthracene (a)
594.00
1300
3.20
58.29
594.00
0.10
Benzo(a)anthracene (a)
841.00
4153
6.20
112.93
841.00
0.13
Benzo(a)pyrene (a)
965.00
3840
5.20
94.72
965.00
0.10
Benzo(b)fluoranthene (a)
979.00
2169
4.50
81.97
979.00
0.08
Benzo(e)pyrene (a)
967.00
4300
3.10
56.47
967.00
0.06
Benzo(g,h,i)perylene (a)
1095.00
648
2.90
52.82
1095.00
0.05
Benzo(k)fluoranthene (a)
981.00
1220
4.30
78.32
981.00
0.08
CI Chrysenes (a)
929.00
2.90
52.82
929.00
0.06
CI Fluorenes(a)
611.00
0.40
7.29
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.40
116.58
770.00
0.15
CI-Naphthalenes (a)
444.00
0.73
13.30
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.60
83.79
670.00
0.13
C2 Chrysenes (a)
1008.00
1.60
29.14
1008.00
0.03
C2 Fluorenes (a)
686.00
0.56
10.20
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.70
49.18
C2-Naphthalenes (a)
510.00
1.90
34.61
510.00
0.07
C2-Phenanthrenes/Anthracenes (a)
746
3.30
60.11
746.00
0.08
C3 Chrysenes (a)
1112.00
0.64
11.66
1112.00
0.01
C3 Fluorenes (a)
769.00
1.10
20.04
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
1.60
29.14
949.00
0.03
C3-Naphthalenes(a)
581.00
3.00
54.64
581.00
0.09
C3-Phenanthrenes/Anthracenes (a)
829.00
3.70
67.40
829.00
0.08
C4 Chrysenes (a)
1214.00
0.34
6.19
1214.00
0.01
C4-Naphthalenes (a)
657.00
2.80
51.00
657.00
0.08
C4-Phenanthrenes/Anthracenes (a)
913.00
2.70
49.18
913.00
0.05
Chrysene ,a)
844.00
826
5.70
103.83
844.00
0.12
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.74
13.48
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
12.00
218.58
707.00
0.31
Fluorene ,a)
538.00
26,000.00
1.70
30.97
538.00
0.06
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.60
47.36
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
1.05
19.13
385.00
0.05
Perylene(a)
967.00
431.00
1.40
25.50
967.00
0.03
Phenanthrene ,a)
596
34300
10.00
182.15
596.00
0.31
Pyrene ,d'
697.00
9,090.00
9.10
165.76
697.00
0.24
ESBTU FCVi
2.35
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 18 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-05
Field Sample ID
RREC13-05-0103
Sample Depth
1-3
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.42
0.0742
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.36
4.85
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.55
7.41
447.00
0.02
Acenaphthene (a)
491.00
33400
0.54
7.28
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.29
3.91
452.00
0.01
Anthracene (a)
594.00
1300
1.90
25.61
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
4.20
56.60
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
3.40
45.82
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
3.00
40.43
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.20
29.65
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.90
25.61
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
3.00
40.43
981.00
0.04
CI Chrysenes (a)
929.00
2.40
32.35
929.00
0.03
CI Fluorenes(a)
611.00
0.40
5.39
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.00
67.39
770.00
0.09
CI-Naphthalenes (a)
444.00
0.64
8.63
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.30
57.95
670.00
0.09
C2 Chrysenes (a)
1008.00
1.60
21.56
1008.00
0.02
C2 Fluorenes (a)
686.00
0.63
8.49
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.60
35.04
C2-Naphthalenes (a)
510.00
1.90
25.61
510.00
0.05
C2-Phenanthrenes/Anthracenes (a)
746
3.80
51.21
746.00
0.07
C3 Chrysenes (a)
1112.00
0.69
9.30
1112.00
0.01
C3 Fluorenes (a)
769.00
1.50
20.22
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
1.60
21.56
949.00
0.02
C3-Naphthalenes(a)
581.00
3.00
40.43
581.00
0.07
C3-Phenanthrenes/Anthracenes (a)
829.00
4.40
59.30
829.00
0.07
C4 Chrysenes (a)
1214.00
0.36
4.85
1214.00
0.00
C4-Naphthalenes (a)
657.00
2.90
39.08
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
3.00
40.43
913.00
0.04
Chrysene ,a)
844.00
826
4.10
55.26
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.52
7.01
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
7.70
103.77
707.00
0.15
Fluorene ,a)
538.00
26,000.00
1.10
14.82
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.70
22.91
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
2.10
28.30
385.00
0.07
Perylene(a)
967.00
431.00
0.90
12.13
967.00
0.01
Phenanthrene ,a)
596
34300
6.10
82.21
596.00
0.14
Pyrene ,d'
697.00
9,090.00
5.80
78.17
697.00
0.11
ESBTU FCVi
1.33
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 19 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-06
Field Sample ID
RREC13-06-SURF
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.53
0.0553
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.12
2.17
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.21
3.80
447.00
0.01
Acenaphthene (a)
491.00
33400
0.18
3.25
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.13
2.35
452.00
0.01
Anthracene (a)
594.00
1300
0.75
13.56
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.30
41.59
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
2.30
41.59
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
1.90
34.36
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
1.40
25.32
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.30
23.51
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.90
34.36
981.00
0.04
CI Chrysenes (a)
929.00
1.30
23.51
929.00
0.03
CI Fluorenes(a)
611.00
0.08
1.37
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.60
47.02
770.00
0.06
CI-Naphthalenes (a)
444.00
0.23
4.16
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.40
25.32
670.00
0.04
C2 Chrysenes (a)
1008.00
0.78
14.10
1008.00
0.01
C2 Fluorenes (a)
686.00
0.10
1.81
686.00
0.00
C2-Fluoranthenes/Pyrenes
1.20
21.70
C2-Naphthalenes (a)
510.00
0.52
9.40
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
0.76
13.74
746.00
0.02
C3 Chrysenes (a)
1112.00
0.28
5.06
1112.00
0.00
C3 Fluorenes (a)
769.00
0.16
2.89
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.53
9.58
949.00
0.01
C3-Naphthalenes(a)
581.00
0.47
8.50
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.57
10.31
829.00
0.01
C4 Chrysenes (a)
1214.00
0.12
2.17
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.24
4.34
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.34
6.15
913.00
0.01
Chrysene ,a)
844.00
826
2.20
39.78
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.32
5.79
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
3.30
59.67
707.00
0.08
Fluorene ,a)
538.00
26,000.00
0.25
4.52
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
19.89
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.32
5.70
385.00
0.01
Perylene(a)
967.00
431.00
0.55
9.95
967.00
0.01
Phenanthrene ,a)
596
34300
1.70
30.74
596.00
0.05
Pyrene ,d'
697.00
9,090.00
2.70
48.82
697.00
0.07
ESBTU FCVi
0.70
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 20 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-06
Field Sample ID
RREC13-06-0001
Sample Depth
0-1
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.57
0.0857
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.17
1.98
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.25
2.86
447.00
0.01
Acenaphthene (a)
491.00
33400
0.23
2.68
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.15
1.75
452.00
0.00
Anthracene (a)
594.00
1300
0.58
6.77
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.70
19.84
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.40
16.34
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.70
19.84
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.10
12.84
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.77
8.98
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.40
16.34
981.00
0.02
CI Chrysenes (a)
929.00
0.94
10.97
929.00
0.01
CI Fluorenes(a)
611.00
0.08
0.90
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.00
23.34
770.00
0.03
CI-Naphthalenes (a)
444.00
0.30
3.50
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.20
14.00
670.00
0.02
C2 Chrysenes (a)
1008.00
0.84
9.80
1008.00
0.01
C2 Fluorenes (a)
686.00
0.14
1.63
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.98
11.44
C2-Naphthalenes (a)
510.00
0.52
6.07
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.88
10.27
746.00
0.01
C3 Chrysenes (a)
1112.00
0.28
3.27
1112.00
0.00
C3 Fluorenes (a)
769.00
0.28
3.27
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.49
5.72
949.00
0.01
C3-Naphthalenes(a)
581.00
0.72
8.40
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.88
10.27
829.00
0.01
C4 Chrysenes (a)
1214.00
0.12
1.40
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.47
5.48
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.63
7.35
913.00
0.01
Chrysene ,a)
844.00
826
1.60
18.67
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.20
2.33
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.40
39.67
707.00
0.06
Fluorene ,a)
538.00
26,000.00
0.38
4.43
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.68
7.93
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.10
12.84
385.00
0.03
Perylene(a)
967.00
431.00
0.33
3.85
967.00
0.00
Phenanthrene ,a)
596
34300
2.10
24.50
596.00
0.04
Pyrene ,d'
697.00
9,090.00
2.50
29.17
697.00
0.04
ESBTU FCVi
0.43
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 21 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-06
Field Sample ID
RREC13-06-0103
Sample Depth
1-3
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.81
0.0781
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.55
7.04
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.80
10.24
447.00
0.02
Acenaphthene (a)
491.00
33400
0.57
7.30
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.28
3.59
452.00
0.01
Anthracene (a)
594.00
1300
1.30
16.65
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
2.90
37.13
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.60
33.29
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.90
37.13
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
1.80
23.05
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.92
11.78
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.50
32.01
981.00
0.03
CI Chrysenes (a)
929.00
1.90
24.33
929.00
0.03
CI Fluorenes(a)
611.00
0.30
3.84
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.90
49.94
770.00
0.06
CI-Naphthalenes (a)
444.00
0.92
11.78
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.00
51.22
670.00
0.08
C2 Chrysenes (a)
1008.00
2.30
29.45
1008.00
0.03
C2 Fluorenes (a)
686.00
0.58
7.43
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.30
29.45
C2-Naphthalenes (a)
510.00
2.70
34.57
510.00
0.07
C2-Phenanthrenes/Anthracenes (a)
746
3.30
42.25
746.00
0.06
C3 Chrysenes (a)
1112.00
0.75
9.60
1112.00
0.01
C3 Fluorenes (a)
769.00
1.10
14.08
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.30
16.65
949.00
0.02
C3-Naphthalenes(a)
581.00
4.20
53.78
581.00
0.09
C3-Phenanthrenes/Anthracenes (a)
829.00
3.00
38.41
829.00
0.05
C4 Chrysenes (a)
1214.00
0.37
4.74
1214.00
0.00
C4-Naphthalenes (a)
657.00
2.50
32.01
657.00
0.05
C4-Phenanthrenes/Anthracenes (a)
913.00
2.00
25.61
913.00
0.03
Chrysene ,a)
844.00
826
2.90
37.13
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.26
3.33
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
6.10
78.10
707.00
0.11
Fluorene ,a)
538.00
26,000.00
0.81
10.37
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.83
10.63
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.90
24.33
385.00
0.06
Perylene(a)
967.00
431.00
0.62
7.94
967.00
0.01
Phenanthrene ,a)
596
34300
4.30
55.06
596.00
0.09
Pyrene ,d'
697.00
9,090.00
4.20
53.78
697.00
0.08
ESBTU FCVi
0.97
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 22 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-07
Field Sample ID
RREC13-07-SURF
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.34
0.0434
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.08
1.75
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.14
3.23
447.00
0.01
Acenaphthene (a)
491.00
33400
0.10
2.28
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.08
1.73
452.00
0.00
Anthracene (a)
594.00
1300
0.33
7.60
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.00
23.04
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.10
25.35
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
0.92
21.20
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
0.66
15.21
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.58
13.36
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
0.83
19.12
981.00
0.02
CI Chrysenes (a)
929.00
0.59
13.59
929.00
0.01
CI Fluorenes(a)
611.00
0.04
0.81
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.99
22.81
770.00
0.03
CI-Naphthalenes (a)
444.00
0.15
3.46
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.59
13.59
670.00
0.02
C2 Chrysenes (a)
1008.00
0.31
7.14
1008.00
0.01
C2 Fluorenes (a)
686.00
0.04
0.85
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.47
10.83
C2-Naphthalenes (a)
510.00
0.31
7.14
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.30
6.91
746.00
0.01
C3 Chrysenes (a)
1112.00
0.12
2.76
1112.00
0.00
C3 Fluorenes (a)
769.00
0.07
1.59
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.23
5.30
949.00
0.01
C3-Naphthalenes(a)
581.00
0.27
6.22
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.21
4.84
829.00
0.01
C4 Chrysenes (a)
1214.00
0.05
1.08
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.13
3.00
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.13
3.00
913.00
0.00
Chrysene ,a)
844.00
826
0.93
21.43
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.17
3.92
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.60
36.87
707.00
0.05
Fluorene ,a)
538.00
26,000.00
0.17
3.92
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.54
12.44
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.38
8.76
385.00
0.02
Perylene(a)
967.00
431.00
0.27
6.22
967.00
0.01
Phenanthrene ,a)
596
34300
0.97
22.35
596.00
0.04
Pyrene ,d'
697.00
9,090.00
1.20
27.65
697.00
0.04
ESBTU FCVi
0.42
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 23 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-09
Field Sample ID
RREC13-09-SURF
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.53
0.0353
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.25
7.08
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.95
26.91
447.00
0.06
Acenaphthene (a)
491.00
33400
0.84
23.80
491.00
0.05
Acenaphthylene (a)
452.00
24000
0.95
26.91
452.00
0.06
Anthracene (a)
594.00
1300
1.40
39.66
594.00
0.07
Benzo(a)anthracene (a)
841.00
4153
4.90
138.81
841.00
0.17
Benzo(a)pyrene (a)
965.00
3840
4.10
116.15
965.00
0.12
Benzo(b)fluoranthene (a)
979.00
2169
4.30
121.81
979.00
0.12
Benzo(e)pyrene (a)
967.00
4300
2.80
79.32
967.00
0.08
Benzo(g,h,i)perylene (a)
1095.00
648
2.10
59.49
1095.00
0.05
Benzo(k)fluoranthene (a)
981.00
1220
3.90
110.48
981.00
0.11
CI Chrysenes (a)
929.00
2.00
56.66
929.00
0.06
CI Fluorenes(a)
611.00
0.95
26.91
611.00
0.04
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.60
101.98
770.00
0.13
CI-Naphthalenes (a)
444.00
0.47
13.31
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.90
53.82
670.00
0.08
C2 Chrysenes (a)
1008.00
1.00
28.33
1008.00
0.03
C2 Fluorenes (a)
686.00
0.95
26.91
686.00
0.04
C2-Fluoranthenes/Pyrenes
2.00
56.66
C2-Naphthalenes (a)
510.00
0.47
13.31
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
0.72
20.40
746.00
0.03
C3 Chrysenes (a)
1112.00
0.28
7.93
1112.00
0.01
C3 Fluorenes (a)
769.00
0.95
26.91
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
0.79
22.38
949.00
0.02
C3-Naphthalenes(a)
581.00
0.40
11.33
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.55
15.58
829.00
0.02
C4 Chrysenes (a)
1214.00
0.95
26.91
1214.00
0.02
C4-Naphthalenes (a)
657.00
0.21
5.95
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.31
8.78
913.00
0.01
Chrysene ,a)
844.00
826
5.00
141.64
844.00
0.17
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.52
14.73
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
12.00
339.94
707.00
0.48
Fluorene ,a)
538.00
26,000.00
0.73
20.68
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.90
53.82
1115.00
0.05
Naphthalene ,a)
385.00
61,700.00
0.95
26.91
385.00
0.07
Perylene(a)
967.00
431.00
1.40
39.66
967.00
0.04
Phenanthrene ,a)
596
34300
6.90
195.47
596.00
0.33
Pyrene ,d'
697.00
9,090.00
8.10
229.46
697.00
0.33
ESBTU FCVi
2.74
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 24 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-09
Field Sample ID
RREC13-09-0001
Sample Depth
0-1
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.56
0.0456
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.77
16.89
446.00
0.04
2-Methylnaphthalene
447.00
154800
0.85
18.64
447.00
0.04
Acenaphthene (a)
491.00
33400
1.20
26.32
491.00
0.05
Acenaphthylene (a)
452.00
24000
0.37
8.11
452.00
0.02
Anthracene (a)
594.00
1300
2.90
63.60
594.00
0.11
Benzo(a)anthracene (a)
841.00
4153
6.00
131.58
841.00
0.16
Benzo(a)pyrene (a)
965.00
3840
4.60
100.88
965.00
0.10
Benzo(b)fluoranthene (a)
979.00
2169
5.30
116.23
979.00
0.12
Benzo(e)pyrene (a)
967.00
4300
3.30
72.37
967.00
0.07
Benzo(g,h,i)perylene (a)
1095.00
648
2.30
50.44
1095.00
0.05
Benzo(k)fluoranthene (a)
981.00
1220
4.20
92.11
981.00
0.09
CI Chrysenes (a)
929.00
3.00
65.79
929.00
0.07
CI Fluorenes(a)
611.00
0.77
16.89
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.10
133.77
770.00
0.17
CI-Naphthalenes (a)
444.00
1.40
30.70
444.00
0.07
Cl-Phenanthrenes/Anthracenes (a)
670.00
6.80
149.12
670.00
0.22
C2 Chrysenes (a)
1008.00
1.90
41.67
1008.00
0.04
C2 Fluorenes (a)
686.00
1.10
24.12
686.00
0.04
C2-Fluoranthenes/Pyrenes
3.50
76.75
C2-Naphthalenes (a)
510.00
5.10
111.84
510.00
0.22
C2-Phenanthrenes/Anthracenes (a)
746
5.30
116.23
746.00
0.16
C3 Chrysenes (a)
1112.00
0.84
18.42
1112.00
0.02
C3 Fluorenes (a)
769.00
2.10
46.05
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
2.10
46.05
949.00
0.05
C3-Naphthalenes(a)
581.00
8.30
182.02
581.00
0.31
C3-Phenanthrenes/Anthracenes (a)
829.00
5.40
118.42
829.00
0.14
C4 Chrysenes (a)
1214.00
0.42
9.21
1214.00
0.01
C4-Naphthalenes (a)
657.00
5.70
125.00
657.00
0.19
C4-Phenanthrenes/Anthracenes (a)
913.00
3.40
74.56
913.00
0.08
Chrysene ,a)
844.00
826
6.00
131.58
844.00
0.16
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.57
12.50
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
14.00
307.02
707.00
0.43
Fluorene ,a)
538.00
26,000.00
1.90
41.67
538.00
0.08
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.10
46.05
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
4.90
107.46
385.00
0.28
Perylene(a)
967.00
431.00
1.10
24.12
967.00
0.02
Phenanthrene ,a)
596
34300
11.00
241.23
596.00
0.40
Pyrene ,d'
697.00
9,090.00
9.50
208.33
697.00
0.30
ESBTU FCVi
3.40
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 25 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-09
Field Sample ID
RREC13-09-0001- FD
Sample Depth
0-1
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.24
0.0924
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.55
5.95
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.65
7.03
447.00
0.02
Acenaphthene (a)
491.00
33400
0.92
9.96
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.26
2.81
452.00
0.01
Anthracene (a)
594.00
1300
2.40
25.97
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
4.80
51.95
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
4.00
43.29
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
3.40
36.80
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.70
29.22
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.80
19.48
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
4.20
45.45
981.00
0.05
CI Chrysenes (a)
929.00
2.40
25.97
929.00
0.03
CI Fluorenes(a)
611.00
0.51
5.52
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.70
50.87
770.00
0.07
CI-Naphthalenes (a)
444.00
1.00
10.82
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
5.10
55.19
670.00
0.08
C2 Chrysenes (a)
1008.00
1.80
19.48
1008.00
0.02
C2 Fluorenes (a)
686.00
0.74
8.01
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.70
29.22
C2-Naphthalenes (a)
510.00
3.50
37.88
510.00
0.07
C2-Phenanthrenes/Anthracenes (a)
746
3.90
42.21
746.00
0.06
C3 Chrysenes (a)
1112.00
0.67
7.25
1112.00
0.01
C3 Fluorenes (a)
769.00
1.40
15.15
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.40
15.15
949.00
0.02
C3-Naphthalenes(a)
581.00
5.30
57.36
581.00
0.10
C3-Phenanthrenes/Anthracenes (a)
829.00
3.80
41.13
829.00
0.05
C4 Chrysenes (a)
1214.00
0.37
4.00
1214.00
0.00
C4-Naphthalenes (a)
657.00
3.80
41.13
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
2.30
24.89
913.00
0.03
Chrysene ,a)
844.00
826
4.60
49.78
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.51
5.52
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
11.00
119.05
707.00
0.17
Fluorene ,a)
538.00
26,000.00
1.60
17.32
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.70
18.40
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
3.00
32.47
385.00
0.08
Perylene(a)
967.00
431.00
1.40
15.15
967.00
0.02
Phenanthrene ,a)
596
34300
8.90
96.32
596.00
0.16
Pyrene ,d'
697.00
9,090.00
7.30
79.00
697.00
0.11
ESBTU FCVi
1.29
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 26 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-09
Field Sample ID
RREC13-09-0103
Sample Depth
1-3
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.08
0.0908
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.97
10.68
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.80
8.81
447.00
0.02
Acenaphthene (a)
491.00
33400
1.30
14.32
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.45
4.96
452.00
0.01
Anthracene (a)
594.00
1300
2.90
31.94
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
5.30
58.37
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
4.20
46.26
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
4.10
45.15
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
2.80
30.84
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.90
20.93
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
3.90
42.95
981.00
0.04
CI Chrysenes (a)
929.00
3.10
34.14
929.00
0.04
CI Fluorenes(a)
611.00
0.85
9.36
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
7.00
77.09
770.00
0.10
CI-Naphthalenes (a)
444.00
1.80
19.82
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.90
87.00
670.00
0.13
C2 Chrysenes (a)
1008.00
2.30
25.33
1008.00
0.03
C2 Fluorenes (a)
686.00
1.40
15.42
686.00
0.02
C2-Fluoranthenes/Pyrenes
3.90
42.95
C2-Naphthalenes (a)
510.00
5.60
61.67
510.00
0.12
C2-Phenanthrenes/Anthracenes (a)
746
6.80
74.89
746.00
0.10
C3 Chrysenes (a)
1112.00
1.10
12.11
1112.00
0.01
C3 Fluorenes (a)
769.00
2.70
29.74
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
2.30
25.33
949.00
0.03
C3-Naphthalenes(a)
581.00
9.70
106.83
581.00
0.18
C3-Phenanthrenes/Anthracenes (a)
829.00
7.60
83.70
829.00
0.10
C4 Chrysenes (a)
1214.00
0.56
6.17
1214.00
0.01
C4-Naphthalenes (a)
657.00
6.70
73.79
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
4.50
49.56
913.00
0.05
Chrysene ,a)
844.00
826
5.40
59.47
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.49
5.40
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
11.00
121.15
707.00
0.17
Fluorene ,a)
538.00
26,000.00
2.30
25.33
538.00
0.05
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.70
18.72
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
5.80
63.88
385.00
0.17
Perylene(a)
967.00
431.00
1.30
14.32
967.00
0.01
Phenanthrene ,a)
596
34300
9.80
107.93
596.00
0.18
Pyrene ,d'
697.00
9,090.00
8.10
89.21
697.00
0.13
ESBTU FCVi
1.71
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 27 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-09
Field Sample ID
RREC13-09-0103-FD
Sample Depth
1-3
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.18
0.0718
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.97
13.51
446.00
0.03
2-Methylnaphthalene
447.00
154800
0.80
11.14
447.00
0.02
Acenaphthene (a)
491.00
33400
1.30
18.11
491.00
0.04
Acenaphthylene (a)
452.00
24000
0.45
6.27
452.00
0.01
Anthracene (a)
594.00
1300
3.20
44.57
594.00
0.08
Benzo(a)anthracene (a)
841.00
4153
4.30
59.89
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
3.00
41.78
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
3.50
48.75
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
2.20
30.64
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.40
19.50
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.90
40.39
981.00
0.04
CI Chrysenes (a)
929.00
2.80
39.00
929.00
0.04
CI Fluorenes(a)
611.00
0.89
12.40
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.30
87.74
770.00
0.11
CI-Naphthalenes (a)
444.00
1.70
23.68
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.20
114.21
670.00
0.17
C2 Chrysenes (a)
1008.00
2.50
34.82
1008.00
0.03
C2 Fluorenes (a)
686.00
1.30
18.11
686.00
0.03
C2-Fluoranthenes/Pyrenes
3.60
50.14
C2-Naphthalenes (a)
510.00
5.70
79.39
510.00
0.16
C2-Phenanthrenes/Anthracenes (a)
746
7.10
98.89
746.00
0.13
C3 Chrysenes (a)
1112.00
1.00
13.93
1112.00
0.01
C3 Fluorenes (a)
769.00
2.70
37.60
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
2.40
33.43
949.00
0.04
C3-Naphthalenes(a)
581.00
9.80
136.49
581.00
0.23
C3-Phenanthrenes/Anthracenes (a)
829.00
7.30
101.67
829.00
0.12
C4 Chrysenes (a)
1214.00
0.55
7.66
1214.00
0.01
C4-Naphthalenes (a)
657.00
6.40
89.14
657.00
0.14
C4-Phenanthrenes/Anthracenes (a)
913.00
5.10
71.03
913.00
0.08
Chrysene ,a)
844.00
826
4.30
59.89
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.36
5.01
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
11.00
153.20
707.00
0.22
Fluorene ,a)
538.00
26,000.00
2.60
36.21
538.00
0.07
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.20
16.71
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
5.50
76.60
385.00
0.20
Perylene(a)
967.00
431.00
0.68
9.47
967.00
0.01
Phenanthrene ,a)
596
34300
11.00
153.20
596.00
0.26
Pyrene ,d'
697.00
9,090.00
7.10
98.89
697.00
0.14
ESBTU FCVi
2.08
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 28 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-09
Field Sample ID
RREC13-09-0305
Sample Depth
3-5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.2
0.102
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.20
11.76
446.00
0.03
2-Methylnaphthalene
447.00
154800
1.10
10.78
447.00
0.02
Acenaphthene (a)
491.00
33400
1.70
16.67
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.37
3.63
452.00
0.01
Anthracene (a)
594.00
1300
4.10
40.20
594.00
0.07
Benzo(a)anthracene (a)
841.00
4153
7.00
68.63
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
5.20
50.98
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
4.50
44.12
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
3.40
33.33
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
3.00
29.41
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
4.80
47.06
981.00
0.05
CI Chrysenes (a)
929.00
3.90
38.24
929.00
0.04
CI Fluorenes(a)
611.00
0.87
8.53
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
8.90
87.25
770.00
0.11
CI-Naphthalenes (a)
444.00
2.20
21.57
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.30
81.37
670.00
0.12
C2 Chrysenes (a)
1008.00
2.60
25.49
1008.00
0.03
C2 Fluorenes (a)
686.00
1.20
11.76
686.00
0.02
C2-Fluoranthenes/Pyrenes
4.20
41.18
C2-Naphthalenes (a)
510.00
6.20
60.78
510.00
0.12
C2-Phenanthrenes/Anthracenes (a)
746
6.40
62.75
746.00
0.08
C3 Chrysenes (a)
1112.00
1.10
10.78
1112.00
0.01
C3 Fluorenes (a)
769.00
2.30
22.55
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
2.40
23.53
949.00
0.02
C3-Naphthalenes(a)
581.00
8.40
82.35
581.00
0.14
C3-Phenanthrenes/Anthracenes (a)
829.00
7.20
70.59
829.00
0.09
C4 Chrysenes (a)
1214.00
0.60
5.88
1214.00
0.00
C4-Naphthalenes (a)
657.00
5.90
57.84
657.00
0.09
C4-Phenanthrenes/Anthracenes (a)
913.00
4.90
48.04
913.00
0.05
Chrysene ,a)
844.00
826
6.40
62.75
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.88
8.63
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
14.00
137.25
707.00
0.19
Fluorene ,a)
538.00
26,000.00
2.70
26.47
538.00
0.05
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.60
25.49
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
12.00
117.65
385.00
0.31
Perylene(a)
967.00
431.00
1.20
11.76
967.00
0.01
Phenanthrene ,a)
596
34300
13.00
127.45
596.00
0.21
Pyrene ,d'
697.00
9,090.00
10.00
98.04
697.00
0.14
ESBTU FCVi
1.94
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 29 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-09
Field Sample ID
RREC13-09-0305-FD
Sample Depth
3-5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.35
0.0935
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.20
12.83
446.00
0.03
2-Methylnaphthalene
447.00
154800
2.10
22.46
447.00
0.05
Acenaphthene (a)
491.00
33400
1.70
18.18
491.00
0.04
Acenaphthylene (a)
452.00
24000
0.35
3.74
452.00
0.01
Anthracene (a)
594.00
1300
3.70
39.57
594.00
0.07
Benzo(a)anthracene (a)
841.00
4153
6.60
70.59
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
5.00
53.48
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
4.80
51.34
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
3.30
35.29
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.60
27.81
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
4.20
44.92
981.00
0.05
CI Chrysenes (a)
929.00
3.80
40.64
929.00
0.04
CI Fluorenes(a)
611.00
0.90
9.63
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
8.50
90.91
770.00
0.12
CI-Naphthalenes (a)
444.00
2.20
23.53
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.20
87.70
670.00
0.13
C2 Chrysenes (a)
1008.00
2.80
29.95
1008.00
0.03
C2 Fluorenes (a)
686.00
1.20
12.83
686.00
0.02
C2-Fluoranthenes/Pyrenes
4.30
45.99
C2-Naphthalenes (a)
510.00
6.10
65.24
510.00
0.13
C2-Phenanthrenes/Anthracenes (a)
746
6.70
71.66
746.00
0.10
C3 Chrysenes (a)
1112.00
1.10
11.76
1112.00
0.01
C3 Fluorenes (a)
769.00
2.50
26.74
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
2.70
28.88
949.00
0.03
C3-Naphthalenes(a)
581.00
8.40
89.84
581.00
0.15
C3-Phenanthrenes/Anthracenes (a)
829.00
7.90
84.49
829.00
0.10
C4 Chrysenes (a)
1214.00
0.66
7.06
1214.00
0.01
C4-Naphthalenes (a)
657.00
6.20
66.31
657.00
0.10
C4-Phenanthrenes/Anthracenes (a)
913.00
4.40
47.06
913.00
0.05
Chrysene ,a)
844.00
826
5.90
63.10
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.77
8.24
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
12.00
128.34
707.00
0.18
Fluorene ,a)
538.00
26,000.00
2.70
28.88
538.00
0.05
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.40
25.67
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
12.00
128.34
385.00
0.33
Perylene(a)
967.00
431.00
1.30
13.90
967.00
0.01
Phenanthrene ,a)
596
34300
12.00
128.34
596.00
0.22
Pyrene ,d'
697.00
9,090.00
9.50
101.60
697.00
0.15
ESBTU FCVi
2.03
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 30 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-11
Field Sample ID
RREC13-11-SURF
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.05
0.0205
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.10
4.63
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.46
22.44
447.00
0.05
Acenaphthene (a)
491.00
33400
0.14
6.83
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.15
7.32
452.00
0.02
Anthracene (a)
594.00
1300
0.45
21.95
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
2.70
131.71
841.00
0.16
Benzo(a)pyrene (a)
965.00
3840
2.40
117.07
965.00
0.12
Benzo(b)fluoranthene (a)
979.00
2169
1.80
87.80
979.00
0.09
Benzo(e)pyrene (a)
967.00
4300
1.60
78.05
967.00
0.08
Benzo(g,h,i)perylene (a)
1095.00
648
1.20
58.54
1095.00
0.05
Benzo(k)fluoranthene (a)
981.00
1220
2.40
117.07
981.00
0.12
CI Chrysenes (a)
929.00
1.30
63.41
929.00
0.07
CI Fluorenes(a)
611.00
0.46
22.44
611.00
0.04
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.30
112.20
770.00
0.15
CI-Naphthalenes (a)
444.00
0.18
8.78
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.20
58.54
670.00
0.09
C2 Chrysenes (a)
1008.00
0.75
36.59
1008.00
0.04
C2 Fluorenes (a)
686.00
0.46
22.44
686.00
0.03
C2-Fluoranthenes/Pyrenes
1.10
53.66
C2-Naphthalenes (a)
510.00
0.42
20.49
510.00
0.04
C2-Phenanthrenes/Anthracenes (a)
746
0.61
29.76
746.00
0.04
C3 Chrysenes (a)
1112.00
0.20
9.76
1112.00
0.01
C3 Fluorenes (a)
769.00
0.12
5.85
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.49
23.90
949.00
0.03
C3-Naphthalenes(a)
581.00
0.40
19.51
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
0.43
20.98
829.00
0.03
C4 Chrysenes (a)
1214.00
0.10
4.88
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.19
9.27
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.28
13.66
913.00
0.02
Chrysene ,a)
844.00
826
2.30
112.20
844.00
0.13
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.34
16.59
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
5.00
243.90
707.00
0.34
Fluorene ,a)
538.00
26,000.00
0.17
8.29
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
53.66
1115.00
0.05
Naphthalene ,a)
385.00
61,700.00
0.46
22.44
385.00
0.06
Perylene(a)
967.00
431.00
0.75
36.59
967.00
0.04
Phenanthrene ,a)
596
34300
1.90
92.68
596.00
0.16
Pyrene ,d'
697.00
9,090.00
3.50
170.73
697.00
0.24
ESBTU FCVi
2.13
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 31 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-13
Field Sample ID
RREC13-13-SURF
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.44
0.0344
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.05
1.34
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.09
2.47
447.00
0.01
Acenaphthene (a)
491.00
33400
0.06
1.69
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.06
1.74
452.00
0.00
Anthracene (a)
594.00
1300
0.22
6.40
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
0.87
25.29
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
0.89
25.87
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
0.84
24.42
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
0.58
16.86
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.61
17.73
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
0.64
18.60
981.00
0.02
CI Chrysenes (a)
929.00
0.46
13.37
929.00
0.01
CI Fluorenes(a)
611.00
0.02
0.67
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.77
22.38
770.00
0.03
CI-Naphthalenes (a)
444.00
0.10
2.82
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.38
11.05
670.00
0.02
C2 Chrysenes (a)
1008.00
0.27
7.85
1008.00
0.01
C2 Fluorenes (a)
686.00
0.04
1.08
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.41
11.92
C2-Naphthalenes (a)
510.00
0.24
6.98
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.23
6.69
746.00
0.01
C3 Chrysenes (a)
1112.00
0.12
3.49
1112.00
0.00
C3 Fluorenes (a)
769.00
0.08
2.33
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.21
6.10
949.00
0.01
C3-Naphthalenes(a)
581.00
0.21
6.10
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.20
5.81
829.00
0.01
C4 Chrysenes (a)
1214.00
0.05
1.40
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.13
3.78
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.17
4.94
913.00
0.01
Chrysene ,a)
844.00
826
0.82
23.84
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.16
4.65
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.20
34.88
707.00
0.05
Fluorene ,a)
538.00
26,000.00
0.08
2.35
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.52
15.12
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.27
7.85
385.00
0.02
Perylene(a)
967.00
431.00
0.24
6.98
967.00
0.01
Phenanthrene ,a)
596
34300
0.59
17.15
596.00
0.03
Pyrene ,d'
697.00
9,090.00
0.99
28.78
697.00
0.04
ESBTU FCVi
0.42
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 32 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-13
Field Sample ID
RREC13-13-0001
Sample Depth
0-1
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.76
0.0776
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.10
14.18
446.00
0.03
2-Methylnaphthalene
447.00
154800
1.60
20.62
447.00
0.05
Acenaphthene (a)
491.00
33400
0.46
5.93
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.26
3.35
452.00
0.01
Anthracene (a)
594.00
1300
0.94
12.11
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.40
30.93
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.20
28.35
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.20
28.35
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.40
18.04
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.30
16.75
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.70
21.91
981.00
0.02
CI Chrysenes (a)
929.00
1.60
20.62
929.00
0.02
CI Fluorenes(a)
611.00
0.78
10.05
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.30
42.53
770.00
0.06
CI-Naphthalenes (a)
444.00
1.80
23.20
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
5.30
68.30
670.00
0.10
C2 Chrysenes (a)
1008.00
1.40
18.04
1008.00
0.02
C2 Fluorenes (a)
686.00
1.80
23.20
686.00
0.03
C2-Fluoranthenes/Pyrenes
2.10
27.06
C2-Naphthalenes (a)
510.00
15.00
193.30
510.00
0.38
C2-Phenanthrenes/Anthracenes (a)
746
5.00
64.43
746.00
0.09
C3 Chrysenes (a)
1112.00
0.68
8.76
1112.00
0.01
C3 Fluorenes (a)
769.00
3.20
41.24
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
1.40
18.04
949.00
0.02
C3-Naphthalenes(a)
581.00
22.00
283.51
581.00
0.49
C3-Phenanthrenes/Anthracenes (a)
829.00
4.50
57.99
829.00
0.07
C4 Chrysenes (a)
1214.00
0.41
5.28
1214.00
0.00
C4-Naphthalenes (a)
657.00
13.00
167.53
657.00
0.25
C4-Phenanthrenes/Anthracenes (a)
913.00
3.10
39.95
913.00
0.04
Chrysene ,a)
844.00
826
2.30
29.64
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.37
4.77
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.60
59.28
707.00
0.08
Fluorene ,a)
538.00
26,000.00
0.85
10.95
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.20
15.46
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.60
20.62
385.00
0.05
Perylene(a)
967.00
431.00
0.55
7.09
967.00
0.01
Phenanthrene ,a)
596
34300
3.60
46.39
596.00
0.08
Pyrene ,d'
697.00
9,090.00
3.50
45.10
697.00
0.06
ESBTU FCVi
1.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 33 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-13
Field Sample ID
RREC13-13-0103
Sample Depth
1-3
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Cone
Hg/g oc
Hg/g oc
Hg/g Dry
wt
Hg/g oc
Cocb
ESBTU FCVi
Hg/g Dry wt
Total Organic Carbon**
5
0.05
8.71
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.30
26.00
446.00
0.06
2.10
2-Methylnaphthalene
447.00
154800
2.10
42.00
447.00
0.09
3.10
Acenaphthene (a)
491.00
33400
0.34
6.80
491.00
0.01
0.98
Acenaphthylene (a)
452.00
24000
0.18
3.60
452.00
0.01
0.88
Anthracene (a)
594.00
1300
0.60
12.00
594.00
0.02
4.00
Benzo(a)anthracene (a)
841.00
4153
1.50
30.00
841.00
0.04
8.40
Benzo(a)pyrene (a)
965.00
3840
1.40
28.00
965.00
0.03
6.20
Benzo(b)fluoranthene (a)
979.00
2169
1.40
28.00
979.00
0.03
5.00
Benzo(e)pyrene (a)
967.00
4300
1.00
20.00
967.00
0.02
4.20
Benzo(g,h,i)perylene (a)
1095.00
648
0.80
16.00
1095.00
0.01
3.50
Benzo(k)fluoranthene (a)
981.00
1220
1.10
22.00
981.00
0.02
4.70
CI Chrysenes (a)
929.00
1.50
30.00
929.00
0.03
7.80
CI Fluorenes(a)
611.00
0.61
12.20
611.00
0.02
1.10
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.10
62.00
770.00
0.08
15.00
CI-Naphthalenes (a)
444.00
2.30
46.00
444.00
0.10
3.50
Cl-Phenanthrenes/Anthracenes (a)
670.00
5.60
112.00
670.00
0.17
18.00
C2 Chrysenes (a)
1008.00
1.90
38.00
1008.00
0.04
7.10
C2 Fluorenes (a)
686.00
1.30
26.00
686.00
0.04
1.70
C2-Fluoranthenes/Pyrenes
2.80
56.00
9.60
C2-Naphthalenes (a)
510.00
13.00
260.00
510.00
0.51
10.00
C2-Phenanthrenes/Anthracenes (a)
746
5.00
100.00
746.00
0.13
13.00
C3 Chrysenes (a)
1112.00
0.98
19.60
1112.00
0.02
3.50
C3 Fluorenes (a)
769.00
2.50
50.00
769.00
0.07
4.10
C3-Fluoranthenes/Pyrenes
949.00
1.80
36.00
949.00
0.04
6.10
C3-Naphthalenes(a)
581.00
15.00
300.00
581.00
0.52
12.00
C3-Phenanthrenes/Anthracenes (a)
829.00
4.90
98.00
829.00
0.12
14.00
C4 Chrysenes (a)
1214.00
0.54
10.80
1214.00
0.01
1.80
C4-Naphthalenes (a)
657.00
7.80
156.00
657.00
0.24
7.20
C4-Phenanthrenes/Anthracenes (a)
913.00
3.20
64.00
913.00
0.07
9.60
Chrysene ,a)
844.00
826
1.60
32.00
844.00
0.04
7.70
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.24
4.80
1123.00
0.00
1.10
Fluoranthene ,a)
707.00
23,870.00
2.70
54.00
707.00
0.08
13.00
Fluorene ,a)
538.00
26,000.00
0.75
15.00
538.00
0.03
2.20
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.69
13.80
1115.00
0.01
2.90
Naphthalene ,a)
385.00
61,700.00
1.20
24.00
385.00
0.06
4.20
Perylene(a)
967.00
431.00
0.46
9.20
967.00
0.01
1.40
Phenanthrene ,a)
596
34300
3.00
60.00
596.00
0.10
11.00
Pyrene ,d'
697.00
9,090.00
2.60
52.00
697.00
0.07
11.00
ESBTU FCVi
1.29
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 34 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-13
Field Sample ID
RREC13-13-0305
Sample Depth
3-5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Coc
Final
Cone
Hg/g oc
Hg/g oc
Hg/g oc
Cocb
ESBTU FCVi
Hg/g Dry wt
Total Organic Carbon**
0.0871
6.69
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
24.11
446.00
0.05
6.70
2-Methylnaphthalene
447.00
154800
35.59
447.00
0.08
10.00
Acenaphthene (a)
491.00
33400
11.25
491.00
0.02
4.10
Acenaphthylene (a)
452.00
24000
10.10
452.00
0.02
1.90
Anthracene (a)
594.00
1300
45.92
594.00
0.08
15.00
Benzo(a)anthracene (a)
841.00
4153
96.44
841.00
0.11
17.00
Benzo(a)pyrene (a)
965.00
3840
71.18
965.00
0.07
13.00
Benzo(b)fluoranthene (a)
979.00
2169
57.41
979.00
0.06
8.50
Benzo(e)pyrene (a)
967.00
4300
48.22
967.00
0.05
7.00
Benzo(g,h,i)perylene (a)
1095.00
648
40.18
1095.00
0.04
5.50
Benzo(k)fluoranthene (a)
981.00
1220
53.96
981.00
0.06
8.40
CI Chrysenes (a)
929.00
89.55
929.00
0.10
14.00
CI Fluorenes(a)
611.00
12.63
611.00
0.02
3.10
Cl-Fluoranthenes/Pyrenes (a)
770.00
172.22
770.00
0.22
32.00
CI-Naphthalenes (a)
444.00
40.18
444.00
0.09
12.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
206.66
670.00
0.31
42.00
C2 Chrysenes (a)
1008.00
81.52
1008.00
0.08
10.00
C2 Fluorenes (a)
686.00
19.52
686.00
0.03
3.00
C2-Fluoranthenes/Pyrenes
110.22
14.00
C2-Naphthalenes (a)
510.00
114.81
510.00
0.23
28.00
C2-Phenanthrenes/Anthracenes (a)
746
149.25
746.00
0.20
18.00
C3 Chrysenes (a)
1112.00
40.18
1112.00
0.04
4.30
C3 Fluorenes (a)
769.00
47.07
769.00
0.06
3.60
C3-Fluoranthenes/Pyrenes
949.00
70.03
949.00
0.07
7.40
C3-Naphthalenes(a)
581.00
137.77
581.00
0.24
21.00
C3-Phenanthrenes/Anthracenes (a)
829.00
160.73
829.00
0.19
13.00
C4 Chrysenes (a)
1214.00
20.67
1214.00
0.02
2.10
C4-Naphthalenes (a)
657.00
82.66
657.00
0.13
8.20
C4-Phenanthrenes/Anthracenes (a)
913.00
110.22
913.00
0.12
8.50
Chrysene ,a)
844.00
826
88.40
844.00
0.10
15.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
12.63
1123.00
0.01
1.60
Fluoranthene ,a)
707.00
23,870.00
149.25
707.00
0.21
27.00
Fluorene ,a)
538.00
26,000.00
25.26
538.00
0.05
7.10
Indeno(l,2,3-cd)pyrene ,a)
1115.00
33.30
1115.00
0.03
4.40
Naphthalene ,a)
385.00
61,700.00
48.22
385.00
0.13
5.70
Perylene(a)
967.00
431.00
16.07
967.00
0.02
2.30
Phenanthrene ,a)
596
34300
126.29
596.00
0.21
39.00
Pyrene ,d'
697.00
9,090.00
126.29
697.00
0.18
27.00
ESBTU FCVi
2.61
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 35 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-13
Field Sample ID
RREC13-13-0507
Sample Depth
5-7
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Coc
Final
Hg/g oc
Hg/g oc
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
0.0669
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
100.15
446.00
0.22
2-Methylnaphthalene
447.00
154800
149.48
447.00
0.33
Acenaphthene (a)
491.00
33400
61.29
491.00
0.12
Acenaphthylene (a)
452.00
24000
28.40
452.00
0.06
Anthracene (a)
594.00
1300
224.22
594.00
0.38
Benzo(a)anthracene (a)
841.00
4153
254.11
841.00
0.30
Benzo(a)pyrene (a)
965.00
3840
194.32
965.00
0.20
Benzo(b)fluoranthene (a)
979.00
2169
127.06
979.00
0.13
Benzo(e)pyrene (a)
967.00
4300
104.63
967.00
0.11
Benzo(g,h,i)perylene (a)
1095.00
648
82.21
1095.00
0.08
Benzo(k)fluoranthene (a)
981.00
1220
125.56
981.00
0.13
CI Chrysenes (a)
929.00
209.27
929.00
0.23
CI Fluorenes(a)
611.00
46.34
611.00
0.08
Cl-Fluoranthenes/Pyrenes (a)
770.00
478.33
770.00
0.62
CI-Naphthalenes (a)
444.00
179.37
444.00
0.40
Cl-Phenanthrenes/Anthracenes (a)
670.00
627.80
670.00
0.94
C2 Chrysenes (a)
1008.00
149.48
1008.00
0.15
C2 Fluorenes (a)
686.00
44.84
686.00
0.07
C2-Fluoranthenes/Pyrenes
209.27
C2-Naphthalenes (a)
510.00
418.54
510.00
0.82
C2-Phenanthrenes/Anthracenes (a)
746
269.06
746.00
0.36
C3 Chrysenes (a)
1112.00
64.28
1112.00
0.06
C3 Fluorenes (a)
769.00
53.81
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
110.61
949.00
0.12
C3-Naphthalenes(a)
581.00
313.90
581.00
0.54
C3-Phenanthrenes/Anthracenes (a)
829.00
194.32
829.00
0.23
C4 Chrysenes (a)
1214.00
31.39
1214.00
0.03
C4-Naphthalenes (a)
657.00
122.57
657.00
0.19
C4-Phenanthrenes/Anthracenes (a)
913.00
127.06
913.00
0.14
Chrysene ,a)
844.00
826
224.22
844.00
0.27
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
23.92
1123.00
0.02
Fluoranthene ,a)
707.00
23,870.00
403.59
707.00
0.57
Fluorene ,a)
538.00
26,000.00
106.13
538.00
0.20
Indeno(l,2,3-cd)pyrene ,a)
1115.00
65.77
1115.00
0.06
Naphthalene ,a)
385.00
61,700.00
85.20
385.00
0.22
Perylene(a)
967.00
431.00
34.38
967.00
0.04
Phenanthrene ,a)
596
34300
582.96
596.00
0.98
Pyrene ,d'
697.00
9,090.00
403.59
697.00
0.58
ESBTU FCVi
6.94
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 36 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-14
Field Sample ID
RREC13-14-SURF
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.91
0.0991
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.33
3.33
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.44
4.39
447.00
0.01
Acenaphthene (a)
491.00
33400
0.40
4.04
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.18
1.82
452.00
0.00
Anthracene (a)
594.00
1300
0.87
8.78
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
3.40
34.31
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
3.30
33.30
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
3.30
33.30
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.30
23.21
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.70
17.15
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
3.00
30.27
981.00
0.03
CI Chrysenes (a)
929.00
2.10
21.19
929.00
0.02
CI Fluorenes(a)
611.00
0.27
2.72
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.50
35.32
770.00
0.05
CI-Naphthalenes (a)
444.00
0.57
5.75
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.10
31.28
670.00
0.05
C2 Chrysenes (a)
1008.00
1.30
13.12
1008.00
0.01
C2 Fluorenes (a)
686.00
0.59
5.95
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.00
20.18
C2-Naphthalenes (a)
510.00
3.50
35.32
510.00
0.07
C2-Phenanthrenes/Anthracenes (a)
746
2.40
24.22
746.00
0.03
C3 Chrysenes (a)
1112.00
0.52
5.25
1112.00
0.00
C3 Fluorenes (a)
769.00
1.10
11.10
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
1.10
11.10
949.00
0.01
C3-Naphthalenes(a)
581.00
5.80
58.53
581.00
0.10
C3-Phenanthrenes/Anthracenes (a)
829.00
2.10
21.19
829.00
0.03
C4 Chrysenes (a)
1214.00
0.25
2.52
1214.00
0.00
C4-Naphthalenes (a)
657.00
3.40
34.31
657.00
0.05
C4-Phenanthrenes/Anthracenes (a)
913.00
1.50
15.14
913.00
0.02
Chrysene ,a)
844.00
826
3.40
34.31
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.53
5.35
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
6.00
60.54
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.61
6.16
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.60
16.15
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.44
4.39
385.00
0.01
Perylene(a)
967.00
431.00
0.91
9.18
967.00
0.01
Phenanthrene ,a)
596
34300
3.50
35.32
596.00
0.06
Pyrene ,d'
697.00
9,090.00
4.10
41.37
697.00
0.06
ESBTU FCVi
0.70
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 37 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-14
Field Sample ID
RREC13-14-SURF-FD
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.79
0.0879
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.30
3.41
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.44
4.95
447.00
0.01
Acenaphthene (a)
491.00
33400
0.42
4.78
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.19
2.16
452.00
0.00
Anthracene (a)
594.00
1300
1.10
12.51
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
3.50
39.82
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
3.50
39.82
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
3.40
38.68
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.30
26.17
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.70
19.34
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.80
31.85
981.00
0.03
CI Chrysenes (a)
929.00
2.00
22.75
929.00
0.02
CI Fluorenes(a)
611.00
0.28
3.19
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.60
40.96
770.00
0.05
CI-Naphthalenes (a)
444.00
0.54
6.14
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.00
34.13
670.00
0.05
C2 Chrysenes (a)
1008.00
1.40
15.93
1008.00
0.02
C2 Fluorenes (a)
686.00
0.62
7.05
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.00
22.75
C2-Naphthalenes (a)
510.00
3.50
39.82
510.00
0.08
C2-Phenanthrenes/Anthracenes (a)
746
2.40
27.30
746.00
0.04
C3 Chrysenes (a)
1112.00
0.56
6.37
1112.00
0.01
C3 Fluorenes (a)
769.00
1.10
12.51
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.20
13.65
949.00
0.01
C3-Naphthalenes(a)
581.00
5.80
65.98
581.00
0.11
C3-Phenanthrenes/Anthracenes (a)
829.00
2.20
25.03
829.00
0.03
C4 Chrysenes (a)
1214.00
0.26
2.96
1214.00
0.00
C4-Naphthalenes (a)
657.00
3.40
38.68
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
1.60
18.20
913.00
0.02
Chrysene ,a)
844.00
826
3.40
38.68
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.42
4.78
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.70
64.85
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.55
6.26
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.50
17.06
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.44
4.95
385.00
0.01
Perylene(a)
967.00
431.00
1.00
11.38
967.00
0.01
Phenanthrene ,a)
596
34300
3.30
37.54
596.00
0.06
Pyrene ,d'
697.00
9,090.00
4.20
47.78
697.00
0.07
ESBTU FCVi
0.79
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 38 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-14
Field Sample ID
RREC13-14-0001
Sample Depth
0-1
Sample Date
11/05/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.77
0.0877
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.93
10.60
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.10
12.54
447.00
0.03
Acenaphthene (a)
491.00
33400
0.72
8.21
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.28
3.19
452.00
0.01
Anthracene (a)
594.00
1300
1.10
12.54
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
3.20
36.49
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.70
30.79
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.80
31.93
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.00
22.81
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.50
17.10
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.60
29.65
981.00
0.03
CI Chrysenes (a)
929.00
2.10
23.95
929.00
0.03
CI Fluorenes(a)
611.00
0.70
7.98
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.00
45.61
770.00
0.06
CI-Naphthalenes (a)
444.00
1.40
15.96
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
5.40
61.57
670.00
0.09
C2 Chrysenes (a)
1008.00
1.80
20.52
1008.00
0.02
C2 Fluorenes (a)
686.00
1.50
17.10
686.00
0.02
C2-Fluoranthenes/Pyrenes
2.60
29.65
C2-Naphthalenes (a)
510.00
12.00
136.83
510.00
0.27
C2-Phenanthrenes/Anthracenes (a)
746
5.20
59.29
746.00
0.08
C3 Chrysenes (a)
1112.00
0.85
9.69
1112.00
0.01
C3 Fluorenes (a)
769.00
2.90
33.07
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
1.80
20.52
949.00
0.02
C3-Naphthalenes(a)
581.00
20.00
228.05
581.00
0.39
C3-Phenanthrenes/Anthracenes (a)
829.00
5.30
60.43
829.00
0.07
C4 Chrysenes (a)
1214.00
0.47
5.36
1214.00
0.00
C4-Naphthalenes (a)
657.00
11.00
125.43
657.00
0.19
C4-Phenanthrenes/Anthracenes (a)
913.00
3.50
39.91
913.00
0.04
Chrysene ,a)
844.00
826
3.30
37.63
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.35
3.99
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
6.40
72.98
707.00
0.10
Fluorene ,a)
538.00
26,000.00
1.10
12.54
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.30
14.82
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.42
4.73
385.00
0.01
Perylene(a)
967.00
431.00
0.69
7.87
967.00
0.01
Phenanthrene ,a)
596
34300
4.90
55.87
596.00
0.09
Pyrene ,d'
697.00
9,090.00
4.70
53.59
697.00
0.08
ESBTU FCVi
1.03
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 39 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-14
Field Sample ID
RREC13-14-0103
Sample Depth
1-3
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.76
0.0776
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.80
10.31
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.30
16.75
447.00
0.04
Acenaphthene (a)
491.00
33400
0.46
5.93
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.24
3.09
452.00
0.01
Anthracene (a)
594.00
1300
1.10
14.18
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
3.50
45.10
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
3.10
39.95
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.70
34.79
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.10
27.06
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
2.20
28.35
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
2.60
33.51
981.00
0.03
CI Chrysenes (a)
929.00
2.40
30.93
929.00
0.03
CI Fluorenes(a)
611.00
0.69
8.89
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.70
60.57
770.00
0.08
CI-Naphthalenes (a)
444.00
1.40
18.04
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
6.60
85.05
670.00
0.13
C2 Chrysenes (a)
1008.00
2.00
25.77
1008.00
0.03
C2 Fluorenes (a)
686.00
1.80
23.20
686.00
0.03
C2-Fluoranthenes/Pyrenes
3.30
42.53
C2-Naphthalenes (a)
510.00
9.80
126.29
510.00
0.25
C2-Phenanthrenes/Anthracenes (a)
746
6.70
86.34
746.00
0.12
C3 Chrysenes (a)
1112.00
0.88
11.34
1112.00
0.01
C3 Fluorenes (a)
769.00
3.80
48.97
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
2.20
28.35
949.00
0.03
C3-Naphthalenes(a)
581.00
16.00
206.19
581.00
0.35
C3-Phenanthrenes/Anthracenes (a)
829.00
7.10
91.49
829.00
0.11
C4 Chrysenes (a)
1214.00
0.55
7.09
1214.00
0.01
C4-Naphthalenes (a)
657.00
12.00
154.64
657.00
0.24
C4-Phenanthrenes/Anthracenes (a)
913.00
4.20
54.12
913.00
0.06
Chrysene ,a)
844.00
826
3.40
43.81
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.61
7.86
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.00
77.32
707.00
0.11
Fluorene ,a)
538.00
26,000.00
0.78
10.05
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.90
24.48
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
1.50
19.33
385.00
0.05
Perylene(a)
967.00
431.00
0.80
10.31
967.00
0.01
Phenanthrene ,a)
596
34300
4.30
55.41
596.00
0.09
Pyrene ,d'
697.00
9,090.00
5.30
68.30
697.00
0.10
ESBTU FCVi
1.33
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 40 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-14
Field Sample ID
RREC13-14-0305
Sample Depth
3-5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.2
0.102
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.00
9.80
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.70
16.67
447.00
0.04
Acenaphthene (a)
491.00
33400
0.60
5.88
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.31
3.04
452.00
0.01
Anthracene (a)
594.00
1300
1.70
16.67
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.90
38.24
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
3.50
34.31
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.90
28.43
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.30
22.55
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
2.10
20.59
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.70
26.47
981.00
0.03
CI Chrysenes (a)
929.00
3.30
32.35
929.00
0.03
CI Fluorenes(a)
611.00
0.94
9.22
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.20
60.78
770.00
0.08
CI-Naphthalenes (a)
444.00
1.80
17.65
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
10.00
98.04
670.00
0.15
C2 Chrysenes (a)
1008.00
3.40
33.33
1008.00
0.03
C2 Fluorenes (a)
686.00
2.40
23.53
686.00
0.03
C2-Fluoranthenes/Pyrenes
4.80
47.06
C2-Naphthalenes (a)
510.00
12.00
117.65
510.00
0.23
C2-Phenanthrenes/Anthracenes (a)
746
9.80
96.08
746.00
0.13
C3 Chrysenes (a)
1112.00
1.60
15.69
1112.00
0.01
C3 Fluorenes (a)
769.00
4.40
43.14
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
3.40
33.33
949.00
0.04
C3-Naphthalenes(a)
581.00
20.00
196.08
581.00
0.34
C3-Phenanthrenes/Anthracenes (a)
829.00
9.60
94.12
829.00
0.11
C4 Chrysenes (a)
1214.00
0.81
7.94
1214.00
0.01
C4-Naphthalenes (a)
657.00
13.00
127.45
657.00
0.19
C4-Phenanthrenes/Anthracenes (a)
913.00
5.50
53.92
913.00
0.06
Chrysene ,a)
844.00
826
3.80
37.25
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.55
5.39
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
7.20
70.59
707.00
0.10
Fluorene ,a)
538.00
26,000.00
1.10
10.78
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.70
16.67
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.55
5.39
385.00
0.01
Perylene(a)
967.00
431.00
0.96
9.41
967.00
0.01
Phenanthrene ,a)
596
34300
6.30
61.76
596.00
0.10
Pyrene ,d'
697.00
9,090.00
5.90
57.84
697.00
0.08
ESBTU FCVi
1.25
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 41 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-14
Field Sample ID
RREC13-14-0507
Sample Depth
5-7
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.73
0.0973
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.81
8.32
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.30
13.36
447.00
0.03
Acenaphthene (a)
491.00
33400
0.54
5.55
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.24
2.47
452.00
0.01
Anthracene (a)
594.00
1300
1.20
12.33
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
3.20
32.89
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.90
29.80
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.70
27.75
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.10
21.58
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.90
19.53
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.10
21.58
981.00
0.02
CI Chrysenes (a)
929.00
2.70
27.75
929.00
0.03
CI Fluorenes(a)
611.00
0.81
8.32
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.00
51.39
770.00
0.07
CI-Naphthalenes (a)
444.00
1.40
14.39
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.40
86.33
670.00
0.13
C2 Chrysenes (a)
1008.00
2.40
24.67
1008.00
0.02
C2 Fluorenes (a)
686.00
1.80
18.50
686.00
0.03
C2-Fluoranthenes/Pyrenes
3.70
38.03
C2-Naphthalenes (a)
510.00
9.90
101.75
510.00
0.20
C2-Phenanthrenes/Anthracenes (a)
746
7.60
78.11
746.00
0.10
C3 Chrysenes (a)
1112.00
1.20
12.33
1112.00
0.01
C3 Fluorenes (a)
769.00
3.40
34.94
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
2.60
26.72
949.00
0.03
C3-Naphthalenes(a)
581.00
16.00
164.44
581.00
0.28
C3-Phenanthrenes/Anthracenes (a)
829.00
7.30
75.03
829.00
0.09
C4 Chrysenes (a)
1214.00
0.64
6.58
1214.00
0.01
C4-Naphthalenes (a)
657.00
10.00
102.77
657.00
0.16
C4-Phenanthrenes/Anthracenes (a)
913.00
4.50
46.25
913.00
0.05
Chrysene ,a)
844.00
826
3.20
32.89
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.44
4.52
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.90
60.64
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.91
9.35
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.50
15.42
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.47
4.78
385.00
0.01
Perylene(a)
967.00
431.00
0.90
9.25
967.00
0.01
Phenanthrene ,a)
596
34300
5.00
51.39
596.00
0.09
Pyrene ,d'
697.00
9,090.00
5.00
51.39
697.00
0.07
ESBTU FCVi
1.07
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 42 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-14
Field Sample ID
RREC13-14-0710
Sample Depth
7-10
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.12
0.0812
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.44
5.42
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.71
8.74
447.00
0.02
Acenaphthene (a)
491.00
33400
0.70
8.62
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.27
3.33
452.00
0.01
Anthracene (a)
594.00
1300
2.00
24.63
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
4.70
57.88
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
4.00
49.26
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
3.70
45.57
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
2.50
30.79
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
2.20
27.09
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
3.30
40.64
981.00
0.04
CI Chrysenes (a)
929.00
2.80
34.48
929.00
0.04
CI Fluorenes(a)
611.00
0.51
6.28
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.70
70.20
770.00
0.09
CI-Naphthalenes (a)
444.00
0.80
9.85
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
6.10
75.12
670.00
0.11
C2 Chrysenes (a)
1008.00
2.30
28.33
1008.00
0.03
C2 Fluorenes (a)
686.00
1.00
12.32
686.00
0.02
C2-Fluoranthenes/Pyrenes
3.40
41.87
C2-Naphthalenes (a)
510.00
3.60
44.33
510.00
0.09
C2-Phenanthrenes/Anthracenes (a)
746
5.60
68.97
746.00
0.09
C3 Chrysenes (a)
1112.00
0.88
10.84
1112.00
0.01
C3 Fluorenes (a)
769.00
2.40
29.56
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
2.20
27.09
949.00
0.03
C3-Naphthalenes(a)
581.00
7.00
86.21
581.00
0.15
C3-Phenanthrenes/Anthracenes (a)
829.00
5.90
72.66
829.00
0.09
C4 Chrysenes (a)
1214.00
0.52
6.40
1214.00
0.01
C4-Naphthalenes (a)
657.00
6.00
73.89
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
4.40
54.19
913.00
0.06
Chrysene ,a)
844.00
826
4.40
54.19
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.60
7.39
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
9.20
113.30
707.00
0.16
Fluorene ,a)
538.00
26,000.00
1.20
14.78
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.90
23.40
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
1.40
17.24
385.00
0.04
Perylene(a)
967.00
431.00
1.20
14.78
967.00
0.02
Phenanthrene ,a)
596
34300
6.80
83.74
596.00
0.14
Pyrene ,d'
697.00
9,090.00
6.60
81.28
697.00
0.12
ESBTU FCVi
1.44
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 43 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-15
Field Sample ID
RREC13-15-SURF
Sample Depth
0-0.5
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.79
0.0879
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.44
5.01
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.50
5.69
447.00
0.01
Acenaphthene (a)
491.00
33400
0.58
6.60
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.24
2.73
452.00
0.01
Anthracene (a)
594.00
1300
1.70
19.34
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.70
42.09
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
3.20
36.41
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
3.00
34.13
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.10
23.89
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.40
15.93
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.80
31.85
981.00
0.03
CI Chrysenes (a)
929.00
2.50
28.44
929.00
0.03
CI Fluorenes(a)
611.00
0.45
5.12
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.50
51.19
770.00
0.07
CI-Naphthalenes (a)
444.00
0.84
9.56
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
5.00
56.88
670.00
0.08
C2 Chrysenes (a)
1008.00
1.80
20.48
1008.00
0.02
C2 Fluorenes (a)
686.00
0.96
10.92
686.00
0.02
C2-Fluoranthenes/Pyrenes
2.90
32.99
C2-Naphthalenes (a)
510.00
2.90
32.99
510.00
0.06
C2-Phenanthrenes/Anthracenes (a)
746
4.90
55.75
746.00
0.07
C3 Chrysenes (a)
1112.00
0.84
9.56
1112.00
0.01
C3 Fluorenes (a)
769.00
1.90
21.62
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
1.90
21.62
949.00
0.02
C3-Naphthalenes(a)
581.00
6.20
70.53
581.00
0.12
C3-Phenanthrenes/Anthracenes (a)
829.00
5.10
58.02
829.00
0.07
C4 Chrysenes (a)
1214.00
0.48
5.46
1214.00
0.00
C4-Naphthalenes (a)
657.00
4.80
54.61
657.00
0.08
C4-Phenanthrenes/Anthracenes (a)
913.00
3.80
43.23
913.00
0.05
Chrysene ,a)
844.00
826
3.70
42.09
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.41
4.66
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
7.30
83.05
707.00
0.12
Fluorene ,a)
538.00
26,000.00
1.00
11.38
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.30
14.79
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.70
19.34
385.00
0.05
Perylene(a)
967.00
431.00
0.83
9.44
967.00
0.01
Phenanthrene ,a)
596
34300
5.30
60.30
596.00
0.10
Pyrene ,d'
697.00
9,090.00
4.70
53.47
697.00
0.08
ESBTU FCVi
1.09
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 44 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-15
Field Sample ID
RREC13-15-0001
Sample Depth
0-1
Sample Date
10/30/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.51
0.0751
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.51
6.79
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.48
6.32
447.00
0.01
Acenaphthene (a)
491.00
33400
0.86
11.45
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.20
2.66
452.00
0.01
Anthracene (a)
594.00
1300
1.60
21.30
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
3.80
50.60
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
3.00
39.95
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.90
38.62
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.00
26.63
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.60
21.30
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.50
33.29
981.00
0.03
CI Chrysenes (a)
929.00
2.40
31.96
929.00
0.03
CI Fluorenes(a)
611.00
0.58
7.72
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.70
62.58
770.00
0.08
CI-Naphthalenes (a)
444.00
0.97
12.92
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
6.00
79.89
670.00
0.12
C2 Chrysenes (a)
1008.00
2.10
27.96
1008.00
0.03
C2 Fluorenes (a)
686.00
1.20
15.98
686.00
0.02
C2-Fluoranthenes/Pyrenes
3.10
41.28
C2-Naphthalenes (a)
510.00
4.10
54.59
510.00
0.11
C2-Phenanthrenes/Anthracenes (a)
746
5.90
78.56
746.00
0.11
C3 Chrysenes (a)
1112.00
0.99
13.18
1112.00
0.01
C3 Fluorenes (a)
769.00
2.70
35.95
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
2.20
29.29
949.00
0.03
C3-Naphthalenes(a)
581.00
7.90
105.19
581.00
0.18
C3-Phenanthrenes/Anthracenes (a)
829.00
7.30
97.20
829.00
0.12
C4 Chrysenes (a)
1214.00
0.55
7.32
1214.00
0.01
C4-Naphthalenes (a)
657.00
6.80
90.55
657.00
0.14
C4-Phenanthrenes/Anthracenes (a)
913.00
4.90
65.25
913.00
0.07
Chrysene ,a)
844.00
826
3.50
46.60
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.45
5.99
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
7.20
95.87
707.00
0.14
Fluorene ,a)
538.00
26,000.00
1.40
18.64
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.50
19.97
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
2.20
29.29
385.00
0.08
Perylene(a)
967.00
431.00
0.79
10.52
967.00
0.01
Phenanthrene ,a)
596
34300
6.50
86.55
596.00
0.15
Pyrene ,d'
697.00
9,090.00
5.00
66.58
697.00
0.10
ESBTU FCVi
1.44
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 45 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-15
Field Sample ID
RREC13-15-0103
Sample Depth
1-3
Sample Date
11/05/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.97
0.0497
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.20
4.02
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.21
4.23
447.00
0.01
Acenaphthene (a)
491.00
33400
0.31
6.24
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.07
1.49
452.00
0.00
Anthracene (a)
594.00
1300
0.62
12.47
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
1.20
24.14
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
0.80
16.10
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
0.95
19.11
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
0.63
12.68
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.44
8.85
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
0.79
15.90
981.00
0.02
CI Chrysenes (a)
929.00
0.77
15.49
929.00
0.02
CI Fluorenes(a)
611.00
0.18
3.62
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.60
32.19
770.00
0.04
CI-Naphthalenes (a)
444.00
0.36
7.24
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.90
38.23
670.00
0.06
C2 Chrysenes (a)
1008.00
0.63
12.68
1008.00
0.01
C2 Fluorenes (a)
686.00
0.34
6.84
686.00
0.01
C2-Fluoranthenes/Pyrenes
0.94
18.91
C2-Naphthalenes (a)
510.00
1.20
24.14
510.00
0.05
C2-Phenanthrenes/Anthracenes (a)
746
1.70
34.21
746.00
0.05
C3 Chrysenes (a)
1112.00
0.26
5.23
1112.00
0.00
C3 Fluorenes (a)
769.00
0.65
13.08
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
0.59
11.87
949.00
0.01
C3-Naphthalenes(a)
581.00
2.40
48.29
581.00
0.08
C3-Phenanthrenes/Anthracenes (a)
829.00
1.90
38.23
829.00
0.05
C4 Chrysenes (a)
1214.00
0.12
2.41
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.60
32.19
657.00
0.05
C4-Phenanthrenes/Anthracenes (a)
913.00
1.30
26.16
913.00
0.03
Chrysene ,a)
844.00
826
1.20
24.14
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.11
2.21
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.50
50.30
707.00
0.07
Fluorene ,a)
538.00
26,000.00
0.55
11.07
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.38
7.65
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.72
14.49
385.00
0.04
Perylene(a)
967.00
431.00
0.19
3.82
967.00
0.00
Phenanthrene ,a)
596
34300
2.20
44.27
596.00
0.07
Pyrene ,d'
697.00
9,090.00
1.80
36.22
697.00
0.05
ESBTU FCVi
0.69
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 46 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-16
Field Sample ID
RREC13-16-SURF
Sample Depth
0-0.5
Sample Date
10/29/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.65
0.0665
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.10
16.54
446.00
0.04
2-Methylnaphthalene
447.00
154800
1.00
15.04
447.00
0.03
Acenaphthene (a)
491.00
33400
0.74
11.13
491.00
0.02
Acenaphthylene (a)
452.00
24000
3.40
51.13
452.00
0.11
Anthracene (a)
594.00
1300
6.60
99.25
594.00
0.17
Benzo(a)anthracene (a)
841.00
4153
22.00
330.83
841.00
0.39
Benzo(a)pyrene (a)
965.00
3840
22.00
330.83
965.00
0.34
Benzo(b)fluoranthene (a)
979.00
2169
22.00
330.83
979.00
0.34
Benzo(e)pyrene (a)
967.00
4300
14.00
210.53
967.00
0.22
Benzo(g,h,i)perylene (a)
1095.00
648
10.00
150.38
1095.00
0.14
Benzo(k)fluoranthene (a)
981.00
1220
20.00
300.75
981.00
0.31
CI Chrysenes (a)
929.00
14.00
210.53
929.00
0.23
CI Fluorenes(a)
611.00
1.10
16.54
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
28.00
421.05
770.00
0.55
CI-Naphthalenes (a)
444.00
1.40
21.05
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
18.00
270.68
670.00
0.40
C2 Chrysenes (a)
1008.00
16.00
240.60
1008.00
0.24
C2 Fluorenes (a)
686.00
1.80
27.07
686.00
0.04
C2-Fluoranthenes/Pyrenes
17.00
255.64
C2-Naphthalenes (a)
510.00
8.20
123.31
510.00
0.24
C2-Phenanthrenes/Anthracenes (a)
746
13.00
195.49
746.00
0.26
C3 Chrysenes (a)
1112.00
7.70
115.79
1112.00
0.10
C3 Fluorenes (a)
769.00
3.00
45.11
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
10.00
150.38
949.00
0.16
C3-Naphthalenes(a)
581.00
10.00
150.38
581.00
0.26
C3-Phenanthrenes/Anthracenes (a)
829.00
12.00
180.45
829.00
0.22
C4 Chrysenes (a)
1214.00
2.90
43.61
1214.00
0.04
C4-Naphthalenes (a)
657.00
5.50
82.71
657.00
0.13
C4-Phenanthrenes/Anthracenes (a)
913.00
7.20
108.27
913.00
0.12
Chrysene ,a)
844.00
826
18.00
270.68
844.00
0.32
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
2.80
42.11
1123.00
0.04
Fluoranthene ,a)
707.00
23,870.00
37.00
556.39
707.00
0.79
Fluorene ,a)
538.00
26,000.00
3.60
54.14
538.00
0.10
Indeno(l,2,3-cd)pyrene ,a)
1115.00
9.40
141.35
1115.00
0.13
Naphthalene ,a)
385.00
61,700.00
2.30
34.59
385.00
0.09
Perylene(a)
967.00
431.00
6.40
96.24
967.00
0.10
Phenanthrene ,a)
596
34300
22.00
330.83
596.00
0.56
Pyrene ,d'
697.00
9,090.00
24.00
360.90
697.00
0.52
ESBTU FCVi
6.35
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 47 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-16
Field Sample ID
RREC13-16-0001
Sample Depth
0-1
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.83
0.0683
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.10
1.46
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.16
2.34
447.00
0.01
Acenaphthene (a)
491.00
33400
0.32
4.69
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.25
3.59
452.00
0.01
Anthracene (a)
594.00
1300
0.64
9.37
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
1.80
26.35
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.80
26.35
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
1.70
24.89
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.60
23.43
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.40
20.50
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.40
20.50
981.00
0.02
CI Chrysenes (a)
929.00
3.30
48.32
929.00
0.05
CI Fluorenes(a)
611.00
0.31
4.54
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.20
46.85
770.00
0.06
CI-Naphthalenes (a)
444.00
0.20
2.93
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.50
51.24
670.00
0.08
C2 Chrysenes (a)
1008.00
3.30
48.32
1008.00
0.05
C2 Fluorenes (a)
686.00
0.79
11.57
686.00
0.02
C2-Fluoranthenes/Pyrenes
4.20
61.49
C2-Naphthalenes (a)
510.00
1.70
24.89
510.00
0.05
C2-Phenanthrenes/Anthracenes (a)
746
4.80
70.28
746.00
0.09
C3 Chrysenes (a)
1112.00
2.00
29.28
1112.00
0.03
C3 Fluorenes (a)
769.00
2.10
30.75
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
3.70
54.17
949.00
0.06
C3-Naphthalenes(a)
581.00
4.60
67.35
581.00
0.12
C3-Phenanthrenes/Anthracenes (a)
829.00
6.90
101.02
829.00
0.12
C4 Chrysenes (a)
1214.00
1.00
14.64
1214.00
0.01
C4-Naphthalenes (a)
657.00
3.40
49.78
657.00
0.08
C4-Phenanthrenes/Anthracenes (a)
913.00
5.10
74.67
913.00
0.08
Chrysene ,a)
844.00
826
2.20
32.21
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.50
7.32
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
2.40
35.14
707.00
0.05
Fluorene ,a)
538.00
26,000.00
0.33
4.83
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.20
17.57
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.25
3.59
385.00
0.01
Perylene(a)
967.00
431.00
0.50
7.32
967.00
0.01
Phenanthrene ,a)
596
34300
1.50
21.96
596.00
0.04
Pyrene ,d'
697.00
9,090.00
3.20
46.85
697.00
0.07
ESBTU FCVi
0.92
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 48 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-16
Field Sample ID
RREC13-16-0103
Sample Depth
1-3
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.47
0.0747
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.03
0.40
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.04
0.56
447.00
0.00
Acenaphthene (a)
491.00
33400
0.06
0.75
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.05
0.62
452.00
0.00
Anthracene (a)
594.00
1300
0.09
1.23
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.29
3.88
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.21
2.81
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.24
3.21
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.21
2.81
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.19
2.54
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.18
2.41
981.00
0.00
CI Chrysenes (a)
929.00
0.65
8.70
929.00
0.01
CI Fluorenes(a)
611.00
0.07
0.87
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.64
8.57
770.00
0.01
CI-Naphthalenes (a)
444.00
0.06
0.74
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.79
10.58
670.00
0.02
C2 Chrysenes (a)
1008.00
0.79
10.58
1008.00
0.01
C2 Fluorenes (a)
686.00
0.17
2.28
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.89
11.91
C2-Naphthalenes (a)
510.00
0.47
6.29
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
1.20
16.06
746.00
0.02
C3 Chrysenes (a)
1112.00
0.45
6.02
1112.00
0.01
C3 Fluorenes (a)
769.00
0.44
5.89
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.80
10.71
949.00
0.01
C3-Naphthalenes(a)
581.00
1.30
17.40
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
1.70
22.76
829.00
0.03
C4 Chrysenes (a)
1214.00
0.20
2.68
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.10
14.73
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
1.20
16.06
913.00
0.02
Chrysene ,a)
844.00
826
0.36
4.82
844.00
0.01
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.06
0.76
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.37
4.95
707.00
0.01
Fluorene ,a)
538.00
26,000.00
0.08
1.02
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.15
2.01
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.05
0.62
385.00
0.00
Perylene(a)
967.00
431.00
0.08
1.02
967.00
0.00
Phenanthrene ,a)
596
34300
0.28
3.75
596.00
0.01
Pyrene ,d'
697.00
9,090.00
0.53
7.10
697.00
0.01
ESBTU FCVi
0.17
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 49 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-16
Field Sample ID
RREC13-16-0305
Sample Depth
3-5
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.43
0.0243
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.01
0.31
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.01
0.38
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.09
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.08
452.00
0.00
Anthracene (a)
594.00
1300
0.01
0.21
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.02
0.74
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.01
0.58
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.02
0.70
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.02
0.78
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.02
0.91
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.01
0.39
981.00
0.00
CI Chrysenes (a)
929.00
0.06
2.47
929.00
0.00
CI Fluorenes(a)
611.00
0.01
0.53
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.06
2.30
770.00
0.00
CI-Naphthalenes (a)
444.00
0.01
0.53
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.14
5.76
670.00
0.01
C2 Chrysenes (a)
1008.00
0.09
3.74
1008.00
0.00
C2 Fluorenes (a)
686.00
0.03
1.32
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.08
3.37
C2-Naphthalenes (a)
510.00
0.08
3.29
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.16
6.58
746.00
0.01
C3 Chrysenes (a)
1112.00
0.06
2.35
1112.00
0.00
C3 Fluorenes (a)
769.00
0.07
2.84
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.08
3.17
949.00
0.00
C3-Naphthalenes(a)
581.00
0.24
9.88
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.21
8.64
829.00
0.01
C4 Chrysenes (a)
1214.00
0.02
0.99
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.26
10.70
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.15
6.17
913.00
0.01
Chrysene ,a)
844.00
826
0.04
1.52
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.01
0.22
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.02
0.82
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.01
0.26
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.01
0.45
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.08
385.00
0.00
Perylene(a)
967.00
431.00
0.01
0.45
967.00
0.00
Phenanthrene ,a)
596
34300
0.03
1.03
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.03
1.40
697.00
0.00
ESBTU FCVi
0.06
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 50 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-16
Field Sample ID
RREC13-16-0507
Sample Depth
5-7
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.89
0.0289
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.01
0.48
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.02
0.66
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.15
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.14
452.00
0.00
Anthracene (a)
594.00
1300
0.01
0.38
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.03
0.87
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.02
0.66
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.03
0.87
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.03
0.90
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.03
0.87
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.01
0.45
981.00
0.00
CI Chrysenes (a)
929.00
0.08
2.87
929.00
0.00
CI Fluorenes(a)
611.00
0.02
0.73
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.07
2.53
770.00
0.00
CI-Naphthalenes (a)
444.00
0.02
0.83
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.23
7.96
670.00
0.01
C2 Chrysenes (a)
1008.00
0.13
4.50
1008.00
0.00
C2 Fluorenes (a)
686.00
0.05
1.63
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.11
3.81
C2-Naphthalenes (a)
510.00
0.15
5.19
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.25
8.65
746.00
0.01
C3 Chrysenes (a)
1112.00
0.07
2.49
1112.00
0.00
C3 Fluorenes (a)
769.00
0.10
3.46
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.12
4.15
949.00
0.00
C3-Naphthalenes(a)
581.00
0.43
14.88
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
0.27
9.34
829.00
0.01
C4 Chrysenes (a)
1214.00
0.03
1.11
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.43
14.88
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.18
6.23
913.00
0.01
Chrysene ,a)
844.00
826
0.05
1.66
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.01
0.19
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.03
1.18
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.01
0.26
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.01
0.42
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.14
385.00
0.00
Perylene(a)
967.00
431.00
0.01
0.45
967.00
0.00
Phenanthrene ,a)
596
34300
0.05
1.66
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.05
1.73
697.00
0.00
ESBTU FCVi
0.07
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 51 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-16
Field Sample ID
RREC13-16-0709
Sample Depth
7-9
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.57
0.0257
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.01
0.39
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.01
0.54
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.06
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.06
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.06
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.06
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.08
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.19
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.32
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.54
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.06
981.00
0.00
CI Chrysenes (a)
929.00
0.03
1.32
929.00
0.00
CI Fluorenes(a)
611.00
0.02
0.70
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.03
1.01
770.00
0.00
CI-Naphthalenes (a)
444.00
0.02
0.74
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.18
7.00
670.00
0.01
C2 Chrysenes (a)
1008.00
0.06
2.45
1008.00
0.00
C2 Fluorenes (a)
686.00
0.04
1.44
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.05
1.83
C2-Naphthalenes (a)
510.00
0.10
3.70
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.16
6.23
746.00
0.01
C3 Chrysenes (a)
1112.00
0.04
1.56
1112.00
0.00
C3 Fluorenes (a)
769.00
0.07
2.68
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.05
2.06
949.00
0.00
C3-Naphthalenes(a)
581.00
0.28
10.89
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.10
3.89
829.00
0.00
C4 Chrysenes (a)
1214.00
0.02
0.70
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.35
13.62
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.10
3.89
913.00
0.00
Chrysene ,a)
844.00
826
0.02
0.78
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.09
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.00
0.06
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.11
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.07
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.06
385.00
0.00
Perylene(a)
967.00
431.00
0.01
0.28
967.00
0.00
Phenanthrene ,a)
596
34300
0.03
1.05
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.32
697.00
0.00
ESBTU FCVi
0.04
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 52 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-16
Field Sample ID
RREC13-16-0911
Sample Depth
9-11
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.96
0.0296
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.01
0.27
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.01
0.37
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.07
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.05
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.06
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.10
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.06
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.19
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.33
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.00
0.16
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.07
981.00
0.00
CI Chrysenes (a)
929.00
0.03
0.95
929.00
0.00
CI Fluorenes(a)
611.00
0.02
0.51
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.04
1.22
770.00
0.00
CI-Naphthalenes (a)
444.00
0.01
0.47
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.11
3.72
670.00
0.01
C2 Chrysenes (a)
1008.00
0.10
3.38
1008.00
0.00
C2 Fluorenes (a)
686.00
0.03
0.98
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.06
1.99
C2-Naphthalenes (a)
510.00
0.08
2.64
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.11
3.72
746.00
0.00
C3 Chrysenes (a)
1112.00
0.06
1.86
1112.00
0.00
C3 Fluorenes (a)
769.00
0.05
1.59
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.07
2.30
949.00
0.00
C3-Naphthalenes(a)
581.00
0.27
9.12
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.21
7.09
829.00
0.01
C4 Chrysenes (a)
1214.00
0.03
0.88
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.34
11.49
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.14
4.73
913.00
0.01
Chrysene ,a)
844.00
826
0.02
0.54
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.02
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.00
0.07
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.14
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.02
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.07
385.00
0.00
Perylene(a)
967.00
431.00
0.01
0.22
967.00
0.00
Phenanthrene ,a)
596
34300
0.03
0.88
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.24
697.00
0.00
ESBTU FCVi
0.03
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 53 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-17
Field Sample ID
RREC13-17-SURF
Sample Depth
0-0.5
Sample Date
10/29/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.23
0.0623
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.12
1.93
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.19
3.05
447.00
0.01
Acenaphthene (a)
491.00
33400
0.08
1.22
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.05
0.75
452.00
0.00
Anthracene (a)
594.00
1300
0.23
3.69
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.10
17.66
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.20
19.26
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.30
20.87
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
0.88
14.13
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.61
9.79
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.10
17.66
981.00
0.02
CI Chrysenes (a)
929.00
0.82
13.16
929.00
0.01
CI Fluorenes(a)
611.00
0.05
0.87
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.30
20.87
770.00
0.03
CI-Naphthalenes (a)
444.00
0.20
3.21
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.70
11.24
670.00
0.02
C2 Chrysenes (a)
1008.00
0.81
13.00
1008.00
0.01
C2 Fluorenes (a)
686.00
0.09
1.49
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.89
14.29
C2-Naphthalenes (a)
510.00
0.71
11.40
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
0.65
10.43
746.00
0.01
C3 Chrysenes (a)
1112.00
0.45
7.22
1112.00
0.01
C3 Fluorenes (a)
769.00
0.24
3.85
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.65
10.43
949.00
0.01
C3-Naphthalenes(a)
581.00
0.83
13.32
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.95
15.25
829.00
0.02
C4 Chrysenes (a)
1214.00
0.18
2.89
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.56
8.99
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.78
12.52
913.00
0.01
Chrysene ,a)
844.00
826
1.20
19.26
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.16
2.57
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.60
25.68
707.00
0.04
Fluorene ,a)
538.00
26,000.00
0.13
2.09
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.59
9.47
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.15
2.33
385.00
0.01
Perylene(a)
967.00
431.00
0.35
5.62
967.00
0.01
Phenanthrene ,a)
596
34300
0.75
12.04
596.00
0.02
Pyrene ,d'
697.00
9,090.00
1.50
24.08
697.00
0.03
ESBTU FCVi
0.35
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 54 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-17
Field Sample ID
RREC13-17-0001
Sample Depth
0-1
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.61
0.0661
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.19
2.80
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.19
2.80
447.00
0.01
Acenaphthene (a)
491.00
33400
0.16
2.42
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.19
2.80
452.00
0.01
Anthracene (a)
594.00
1300
0.43
6.51
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.40
21.18
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.50
22.69
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.50
22.69
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.20
18.15
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.00
15.13
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.30
19.67
981.00
0.02
CI Chrysenes (a)
929.00
1.60
24.21
929.00
0.03
CI Fluorenes(a)
611.00
0.12
1.82
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.70
25.72
770.00
0.03
CI-Naphthalenes (a)
444.00
0.20
3.03
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.20
18.15
670.00
0.03
C2 Chrysenes (a)
1008.00
1.70
25.72
1008.00
0.03
C2 Fluorenes (a)
686.00
0.29
4.39
686.00
0.01
C2-Fluoranthenes/Pyrenes
1.80
27.23
C2-Naphthalenes (a)
510.00
0.88
13.31
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
1.90
28.74
746.00
0.04
C3 Chrysenes (a)
1112.00
0.82
12.41
1112.00
0.01
C3 Fluorenes (a)
769.00
0.81
12.25
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.40
21.18
949.00
0.02
C3-Naphthalenes(a)
581.00
1.40
21.18
581.00
0.04
C3-Phenanthrenes/Anthracenes (a)
829.00
2.50
37.82
829.00
0.05
C4 Chrysenes (a)
1214.00
0.46
6.96
1214.00
0.01
C4-Naphthalenes (a)
657.00
1.40
21.18
657.00
0.03
C4-Phenanthrenes/Anthracenes (a)
913.00
1.80
27.23
913.00
0.03
Chrysene ,a)
844.00
826
1.60
24.21
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.35
5.30
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.80
27.23
707.00
0.04
Fluorene ,a)
538.00
26,000.00
0.27
4.08
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.93
14.07
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.19
2.80
385.00
0.01
Perylene(a)
967.00
431.00
0.41
6.20
967.00
0.01
Phenanthrene ,a)
596
34300
1.20
18.15
596.00
0.03
Pyrene ,d'
697.00
9,090.00
2.30
34.80
697.00
0.05
ESBTU FCVi
0.53
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 55 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-17
Field Sample ID
RREC13-17-0103
Sample Depth
1-3
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.24
0.0924
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.33
3.57
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.33
3.57
447.00
0.01
Acenaphthene (a)
491.00
33400
0.37
4.00
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.33
3.57
452.00
0.01
Anthracene (a)
594.00
1300
0.92
9.96
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.50
27.06
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.90
20.56
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.90
20.56
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.60
17.32
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.20
12.99
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.80
19.48
981.00
0.02
CI Chrysenes (a)
929.00
3.60
38.96
929.00
0.04
CI Fluorenes(a)
611.00
0.48
5.19
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.20
45.45
770.00
0.06
CI-Naphthalenes (a)
444.00
0.32
3.46
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.20
45.45
670.00
0.07
C2 Chrysenes (a)
1008.00
4.60
49.78
1008.00
0.05
C2 Fluorenes (a)
686.00
1.40
15.15
686.00
0.02
C2-Fluoranthenes/Pyrenes
4.90
53.03
C2-Naphthalenes (a)
510.00
3.10
33.55
510.00
0.07
C2-Phenanthrenes/Anthracenes (a)
746
7.90
85.50
746.00
0.11
C3 Chrysenes (a)
1112.00
2.40
25.97
1112.00
0.02
C3 Fluorenes (a)
769.00
3.60
38.96
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
4.10
44.37
949.00
0.05
C3-Naphthalenes(a)
581.00
7.80
84.42
581.00
0.15
C3-Phenanthrenes/Anthracenes (a)
829.00
11.00
119.05
829.00
0.14
C4 Chrysenes (a)
1214.00
1.50
16.23
1214.00
0.01
C4-Naphthalenes (a)
657.00
8.50
91.99
657.00
0.14
C4-Phenanthrenes/Anthracenes (a)
913.00
8.30
89.83
913.00
0.10
Chrysene ,a)
844.00
826
2.80
30.30
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.44
4.76
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.30
35.71
707.00
0.05
Fluorene ,a)
538.00
26,000.00
0.77
8.33
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
11.90
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.33
3.57
385.00
0.01
Perylene(a)
967.00
431.00
0.56
6.06
967.00
0.01
Phenanthrene ,a)
596
34300
2.10
22.73
596.00
0.04
Pyrene ,d'
697.00
9,090.00
4.80
51.95
697.00
0.07
ESBTU FCVi
0.97
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 56 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-17
Field Sample ID
RREC13-17-0305
Sample Depth
3-5
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.1
0.101
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.75
7.43
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.60
15.84
447.00
0.04
Acenaphthene (a)
491.00
33400
1.10
10.89
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.75
7.43
452.00
0.02
Anthracene (a)
594.00
1300
3.20
31.68
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
4.70
46.53
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
3.00
29.70
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
3.30
32.67
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.50
24.75
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.80
17.82
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.60
25.74
981.00
0.03
CI Chrysenes (a)
929.00
6.20
61.39
929.00
0.07
CI Fluorenes(a)
611.00
1.10
10.89
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
7.80
77.23
770.00
0.10
CI-Naphthalenes (a)
444.00
2.10
20.79
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
9.90
98.02
670.00
0.15
C2 Chrysenes (a)
1008.00
7.40
73.27
1008.00
0.07
C2 Fluorenes (a)
686.00
2.70
26.73
686.00
0.04
C2-Fluoranthenes/Pyrenes
8.60
85.15
C2-Naphthalenes (a)
510.00
13.00
128.71
510.00
0.25
C2-Phenanthrenes/Anthracenes (a)
746
17.00
168.32
746.00
0.23
C3 Chrysenes (a)
1112.00
4.80
47.52
1112.00
0.04
C3 Fluorenes (a)
769.00
6.90
68.32
769.00
0.09
C3-Fluoranthenes/Pyrenes
949.00
8.00
79.21
949.00
0.08
C3-Naphthalenes(a)
581.00
19.00
188.12
581.00
0.32
C3-Phenanthrenes/Anthracenes (a)
829.00
21.00
207.92
829.00
0.25
C4 Chrysenes (a)
1214.00
2.80
27.72
1214.00
0.02
C4-Naphthalenes (a)
657.00
16.00
158.42
657.00
0.24
C4-Phenanthrenes/Anthracenes (a)
913.00
14.00
138.61
913.00
0.15
Chrysene ,a)
844.00
826
5.00
49.50
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.61
6.04
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
7.30
72.28
707.00
0.10
Fluorene ,a)
538.00
26,000.00
2.20
21.78
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.70
16.83
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
2.00
19.80
385.00
0.05
Perylene(a)
967.00
431.00
0.89
8.81
967.00
0.01
Phenanthrene ,a)
596
34300
6.40
63.37
596.00
0.11
Pyrene ,d'
697.00
9,090.00
9.40
93.07
697.00
0.13
ESBTU FCVi
1.82
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 57 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-17
Field Sample ID
RREC13-17-0507
Sample Depth
5-7
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry
wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
21
0.21
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
3.70
17.62
446.00
0.04
2-Methylnaphthalene
447.00
154800
4.00
19.05
447.00
0.04
Acenaphthene (a)
491.00
33400
2.00
9.52
491.00
0.02
Acenaphthylene (a)
452.00
24000
1.15
5.48
452.00
0.01
Anthracene (a)
594.00
1300
9.20
43.81
594.00
0.07
Benzo(a)anthracene (a)
841.00
4153
6.30
30.00
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
4.10
19.52
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
4.20
20.00
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
3.60
17.14
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.15
5.48
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
3.80
18.10
981.00
0.02
CI Chrysenes (a)
929.00
9.10
43.33
929.00
0.05
CI Fluorenes(a)
611.00
2.30
10.95
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
13.00
61.90
770.00
0.08
CI-Naphthalenes (a)
444.00
5.40
25.71
444.00
0.06
Cl-Phenanthrenes/Anthracenes (a)
670.00
18.00
85.71
670.00
0.13
C2 Chrysenes (a)
1008.00
10.00
47.62
1008.00
0.05
C2 Fluorenes (a)
686.00
4.20
20.00
686.00
0.03
C2-Fluoranthenes/Pyrenes
12.00
57.14
C2-Naphthalenes (a)
510.00
35.00
166.67
510.00
0.33
C2-Phenanthrenes/Anthracenes (a)
746
21.00
100.00
746.00
0.13
C3 Chrysenes (a)
1112.00
6.40
30.48
1112.00
0.03
C3 Fluorenes (a)
769.00
8.80
41.90
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
9.80
46.67
949.00
0.05
C3-Naphthalenes(a)
581.00
40.00
190.48
581.00
0.33
C3-Phenanthrenes/Anthracenes (a)
829.00
22.00
104.76
829.00
0.13
C4 Chrysenes (a)
1214.00
3.50
16.67
1214.00
0.01
C4-Naphthalenes (a)
657.00
25.00
119.05
657.00
0.18
C4-Phenanthrenes/Anthracenes (a)
913.00
16.00
76.19
913.00
0.08
Chrysene ,a)
844.00
826
6.60
31.43
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.91
4.33
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
9.80
46.67
707.00
0.07
Fluorene ,a)
538.00
26,000.00
3.80
18.10
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.15
5.48
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
1.15
5.48
385.00
0.01
Perylene(a)
967.00
431.00
1.10
5.24
967.00
0.01
Phenanthrene ,a)
596
34300
11.00
52.38
596.00
0.09
Pyrene ,d'
697.00
9,090.00
13.00
61.90
697.00
0.09
ESBTU FCVi
1.22
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 58 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-17
Field Sample ID
RREC13-17-0709
Sample Depth
7-9
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.26
0.0626
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.55
8.79
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.00
15.97
447.00
0.04
Acenaphthene (a)
491.00
33400
0.44
7.03
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.55
8.79
452.00
0.02
Anthracene (a)
594.00
1300
1.40
22.36
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
3.60
57.51
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
2.60
41.53
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.30
36.74
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.30
36.74
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
1.40
22.36
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.30
36.74
981.00
0.04
CI Chrysenes (a)
929.00
6.20
99.04
929.00
0.11
CI Fluorenes(a)
611.00
0.61
9.74
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
7.00
111.82
770.00
0.15
CI-Naphthalenes (a)
444.00
1.30
20.77
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.60
121.41
670.00
0.18
C2 Chrysenes (a)
1008.00
6.50
103.83
1008.00
0.10
C2 Fluorenes (a)
686.00
1.40
22.36
686.00
0.03
C2-Fluoranthenes/Pyrenes
7.30
116.61
C2-Naphthalenes (a)
510.00
6.30
100.64
510.00
0.20
C2-Phenanthrenes/Anthracenes (a)
746
10.00
159.74
746.00
0.21
C3 Chrysenes (a)
1112.00
3.80
60.70
1112.00
0.05
C3 Fluorenes (a)
769.00
3.70
59.11
769.00
0.08
C3-Fluoranthenes/Pyrenes
949.00
5.30
84.66
949.00
0.09
C3-Naphthalenes(a)
581.00
7.70
123.00
581.00
0.21
C3-Phenanthrenes/Anthracenes (a)
829.00
12.00
191.69
829.00
0.23
C4 Chrysenes (a)
1214.00
2.10
33.55
1214.00
0.03
C4-Naphthalenes (a)
657.00
6.40
102.24
657.00
0.16
C4-Phenanthrenes/Anthracenes (a)
913.00
8.20
130.99
913.00
0.14
Chrysene ,a)
844.00
826
3.90
62.30
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.54
8.63
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
4.10
65.50
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.55
8.79
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.20
19.17
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.55
8.79
385.00
0.02
Perylene(a)
967.00
431.00
0.61
9.74
967.00
0.01
Phenanthrene ,a)
596
34300
3.00
47.92
596.00
0.08
Pyrene ,d'
697.00
9,090.00
6.20
99.04
697.00
0.14
ESBTU FCVi
1.82
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 59 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-17
Field Sample ID
RREC13-17-0911
Sample Depth
9-11
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.91
0.0591
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.90
15.23
446.00
0.03
2-Methylnaphthalene
447.00
154800
2.00
33.84
447.00
0.08
Acenaphthene (a)
491.00
33400
0.58
9.81
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.90
15.23
452.00
0.03
Anthracene (a)
594.00
1300
1.80
30.46
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
4.70
79.53
841.00
0.09
Benzo(a)pyrene (a)
965.00
3840
3.00
50.76
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
2.50
42.30
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
3.50
59.22
967.00
0.06
Benzo(g,h,i)perylene (a)
1095.00
648
0.90
15.23
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.10
35.53
981.00
0.04
CI Chrysenes (a)
929.00
11.00
186.13
929.00
0.20
CI Fluorenes(a)
611.00
1.20
20.30
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
13.00
219.97
770.00
0.29
CI-Naphthalenes (a)
444.00
2.50
42.30
444.00
0.10
Cl-Phenanthrenes/Anthracenes (a)
670.00
16.00
270.73
670.00
0.40
C2 Chrysenes (a)
1008.00
12.00
203.05
1008.00
0.20
C2 Fluorenes (a)
686.00
2.80
47.38
686.00
0.07
C2-Fluoranthenes/Pyrenes
13.00
219.97
C2-Naphthalenes (a)
510.00
12.00
203.05
510.00
0.40
C2-Phenanthrenes/Anthracenes (a)
746
17.00
287.65
746.00
0.39
C3 Chrysenes (a)
1112.00
6.40
108.29
1112.00
0.10
C3 Fluorenes (a)
769.00
5.60
94.75
769.00
0.12
C3-Fluoranthenes/Pyrenes
949.00
9.30
157.36
949.00
0.17
C3-Naphthalenes(a)
581.00
13.00
219.97
581.00
0.38
C3-Phenanthrenes/Anthracenes (a)
829.00
16.00
270.73
829.00
0.33
C4 Chrysenes (a)
1214.00
3.40
57.53
1214.00
0.05
C4-Naphthalenes (a)
657.00
9.80
165.82
657.00
0.25
C4-Phenanthrenes/Anthracenes (a)
913.00
11.00
186.13
913.00
0.20
Chrysene ,a)
844.00
826
4.70
79.53
844.00
0.09
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.66
11.17
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
4.20
71.07
707.00
0.10
Fluorene ,a)
538.00
26,000.00
0.90
15.23
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.90
15.23
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.90
15.23
385.00
0.04
Perylene(a)
967.00
431.00
0.61
10.32
967.00
0.01
Phenanthrene ,a)
596
34300
5.80
98.14
596.00
0.16
Pyrene ,d'
697.00
9,090.00
9.90
167.51
697.00
0.24
ESBTU FCVi
2.94
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 60 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-18
Field Sample ID
RREC13-18-SURF
Sample Depth
0-0.5
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.73
0.0573
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.13
2.27
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.21
3.66
447.00
0.01
Acenaphthene (a)
491.00
33400
0.09
1.61
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.05
0.91
452.00
0.00
Anthracene (a)
594.00
1300
0.30
5.24
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.20
20.94
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.30
22.69
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.30
22.69
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
0.88
15.36
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.59
10.30
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.20
20.94
981.00
0.02
CI Chrysenes (a)
929.00
0.88
15.36
929.00
0.02
CI Fluorenes(a)
611.00
0.06
1.05
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.40
24.43
770.00
0.03
CI-Naphthalenes (a)
444.00
0.23
4.01
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.85
14.83
670.00
0.02
C2 Chrysenes (a)
1008.00
0.90
15.71
1008.00
0.02
C2 Fluorenes (a)
686.00
0.10
1.75
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.88
15.36
C2-Naphthalenes (a)
510.00
0.76
13.26
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
0.76
13.26
746.00
0.02
C3 Chrysenes (a)
1112.00
0.44
7.68
1112.00
0.01
C3 Fluorenes (a)
769.00
0.27
4.71
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.67
11.69
949.00
0.01
C3-Naphthalenes(a)
581.00
0.84
14.66
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
0.90
15.71
829.00
0.02
C4 Chrysenes (a)
1214.00
0.16
2.79
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.56
9.77
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.72
12.57
913.00
0.01
Chrysene ,a)
844.00
826
1.30
22.69
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.15
2.62
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.90
33.16
707.00
0.05
Fluorene ,a)
538.00
26,000.00
0.15
2.62
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.56
9.77
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.17
2.97
385.00
0.01
Perylene(a)
967.00
431.00
0.37
6.46
967.00
0.01
Phenanthrene ,a)
596
34300
0.85
14.83
596.00
0.02
Pyrene ,d'
697.00
9,090.00
1.50
26.18
697.00
0.04
ESBTU FCVi
0.41
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 61 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-18
Field Sample ID
RREC13-18-0001
Sample Depth
0-1
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.07
0.0507
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.07
1.34
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.12
2.27
447.00
0.01
Acenaphthene (a)
491.00
33400
0.11
2.17
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.07
1.36
452.00
0.00
Anthracene (a)
594.00
1300
0.32
6.31
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.20
23.67
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.30
25.64
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
1.40
27.61
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
0.94
18.54
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.77
15.19
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.00
19.72
981.00
0.02
CI Chrysenes (a)
929.00
0.92
18.15
929.00
0.02
CI Fluorenes(a)
611.00
0.06
1.10
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.40
27.61
770.00
0.04
CI-Naphthalenes (a)
444.00
0.12
2.37
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.86
16.96
670.00
0.03
C2 Chrysenes (a)
1008.00
0.87
17.16
1008.00
0.02
C2 Fluorenes (a)
686.00
0.13
2.56
686.00
0.00
C2-Fluoranthenes/Pyrenes
1.00
19.72
C2-Naphthalenes (a)
510.00
0.49
9.66
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
0.80
15.78
746.00
0.02
C3 Chrysenes (a)
1112.00
0.45
8.88
1112.00
0.01
C3 Fluorenes (a)
769.00
0.33
6.51
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.74
14.60
949.00
0.02
C3-Naphthalenes(a)
581.00
0.64
12.62
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
1.00
19.72
829.00
0.02
C4 Chrysenes (a)
1214.00
0.15
2.96
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.48
9.47
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.80
15.78
913.00
0.02
Chrysene ,a)
844.00
826
1.20
23.67
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.22
4.34
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.00
39.45
707.00
0.06
Fluorene ,a)
538.00
26,000.00
0.16
3.16
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.68
13.41
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.12
2.27
385.00
0.01
Perylene(a)
967.00
431.00
0.35
6.90
967.00
0.01
Phenanthrene ,a)
596
34300
0.93
18.34
596.00
0.03
Pyrene ,d'
697.00
9,090.00
1.50
29.59
697.00
0.04
ESBTU FCVi
0.48
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 62 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-18
Field Sample ID
RREC13-18-0103
Sample Depth
1-3
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.86
0.0586
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.21
3.58
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.50
8.53
447.00
0.02
Acenaphthene (a)
491.00
33400
0.82
13.99
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.16
2.73
452.00
0.01
Anthracene (a)
594.00
1300
2.40
40.96
594.00
0.07
Benzo(a)anthracene (a)
841.00
4153
2.90
49.49
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
2.20
37.54
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.10
35.84
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
1.60
27.30
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.10
18.77
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.80
30.72
981.00
0.03
CI Chrysenes (a)
929.00
3.10
52.90
929.00
0.06
CI Fluorenes(a)
611.00
0.49
8.36
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.40
92.15
770.00
0.12
CI-Naphthalenes (a)
444.00
0.32
5.46
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
5.90
100.68
670.00
0.15
C2 Chrysenes (a)
1008.00
4.00
68.26
1008.00
0.07
C2 Fluorenes (a)
686.00
1.00
17.06
686.00
0.02
C2-Fluoranthenes/Pyrenes
4.80
81.91
C2-Naphthalenes (a)
510.00
4.10
69.97
510.00
0.14
C2-Phenanthrenes/Anthracenes (a)
746
6.40
109.22
746.00
0.15
C3 Chrysenes (a)
1112.00
2.10
35.84
1112.00
0.03
C3 Fluorenes (a)
769.00
2.70
46.08
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
3.90
66.55
949.00
0.07
C3-Naphthalenes(a)
581.00
7.50
127.99
581.00
0.22
C3-Phenanthrenes/Anthracenes (a)
829.00
9.30
158.70
829.00
0.19
C4 Chrysenes (a)
1214.00
1.10
18.77
1214.00
0.02
C4-Naphthalenes (a)
657.00
5.60
95.56
657.00
0.15
C4-Phenanthrenes/Anthracenes (a)
913.00
6.00
102.39
913.00
0.11
Chrysene ,a)
844.00
826
2.90
49.49
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.31
5.29
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.60
95.56
707.00
0.14
Fluorene ,a)
538.00
26,000.00
1.10
18.77
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.94
16.04
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.50
8.53
385.00
0.02
Perylene(a)
967.00
431.00
0.59
10.07
967.00
0.01
Phenanthrene ,a)
596
34300
4.80
81.91
596.00
0.14
Pyrene ,d'
697.00
9,090.00
4.80
81.91
697.00
0.12
ESBTU FCVi
1.67
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 63 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-18
Field Sample ID
RREC13-18-0305
Sample Depth
3-5
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.36
0.0536
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.71
13.25
446.00
0.03
2-Methylnaphthalene
447.00
154800
0.86
16.04
447.00
0.04
Acenaphthene (a)
491.00
33400
0.49
9.14
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.18
3.36
452.00
0.01
Anthracene (a)
594.00
1300
1.10
20.52
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
2.90
54.10
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
2.00
37.31
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
1.80
33.58
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.50
27.99
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
0.82
15.30
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.70
31.72
981.00
0.03
CI Chrysenes (a)
929.00
4.10
76.49
929.00
0.08
CI Fluorenes(a)
611.00
0.43
8.02
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.40
119.40
770.00
0.16
CI-Naphthalenes (a)
444.00
1.00
18.66
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
6.90
128.73
670.00
0.19
C2 Chrysenes (a)
1008.00
4.90
91.42
1008.00
0.09
C2 Fluorenes (a)
686.00
0.93
17.35
686.00
0.03
C2-Fluoranthenes/Pyrenes
5.60
104.48
C2-Naphthalenes (a)
510.00
5.30
98.88
510.00
0.19
C2-Phenanthrenes/Anthracenes (a)
746
7.10
132.46
746.00
0.18
C3 Chrysenes (a)
1112.00
2.50
46.64
1112.00
0.04
C3 Fluorenes (a)
769.00
2.50
46.64
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
4.50
83.96
949.00
0.09
C3-Naphthalenes(a)
581.00
6.10
113.81
581.00
0.20
C3-Phenanthrenes/Anthracenes (a)
829.00
8.00
149.25
829.00
0.18
C4 Chrysenes (a)
1214.00
1.20
22.39
1214.00
0.02
C4-Naphthalenes (a)
657.00
4.20
78.36
657.00
0.12
C4-Phenanthrenes/Anthracenes (a)
913.00
6.00
111.94
913.00
0.12
Chrysene ,a)
844.00
826
2.70
50.37
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.29
5.41
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.40
82.09
707.00
0.12
Fluorene ,a)
538.00
26,000.00
0.72
13.43
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.73
13.62
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.32
5.97
385.00
0.02
Perylene(a)
967.00
431.00
0.50
9.33
967.00
0.01
Phenanthrene ,a)
596
34300
3.00
55.97
596.00
0.09
Pyrene ,d'
697.00
9,090.00
4.10
76.49
697.00
0.11
ESBTU FCVi
1.65
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 64 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-18
Field Sample ID
RREC13-18-0507
Sample Depth
5-7
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.46
0.0446
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.10
2.24
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.17
3.81
447.00
0.01
Acenaphthene (a)
491.00
33400
0.18
4.04
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.12
2.69
452.00
0.01
Anthracene (a)
594.00
1300
0.53
11.88
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
1.90
42.60
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
1.50
33.63
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
1.30
29.15
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.00
22.42
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.65
14.57
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.10
24.66
981.00
0.03
CI Chrysenes (a)
929.00
2.70
60.54
929.00
0.07
CI Fluorenes(a)
611.00
0.21
4.71
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.90
87.44
770.00
0.11
CI-Naphthalenes (a)
444.00
0.17
3.81
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.60
80.72
670.00
0.12
C2 Chrysenes (a)
1008.00
2.90
65.02
1008.00
0.06
C2 Fluorenes (a)
686.00
0.52
11.66
686.00
0.02
C2-Fluoranthenes/Pyrenes
3.10
69.51
C2-Naphthalenes (a)
510.00
1.50
33.63
510.00
0.07
C2-Phenanthrenes/Anthracenes (a)
746
3.90
87.44
746.00
0.12
C3 Chrysenes (a)
1112.00
1.30
29.15
1112.00
0.03
C3 Fluorenes (a)
769.00
1.40
31.39
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
2.40
53.81
949.00
0.06
C3-Naphthalenes(a)
581.00
2.50
56.05
581.00
0.10
C3-Phenanthrenes/Anthracenes (a)
829.00
4.20
94.17
829.00
0.11
C4 Chrysenes (a)
1214.00
0.64
14.35
1214.00
0.01
C4-Naphthalenes (a)
657.00
2.50
56.05
657.00
0.09
C4-Phenanthrenes/Anthracenes (a)
913.00
2.80
62.78
913.00
0.07
Chrysene ,a)
844.00
826
1.80
40.36
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.22
4.93
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.60
58.30
707.00
0.08
Fluorene ,a)
538.00
26,000.00
0.21
4.71
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.56
12.56
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.17
3.81
385.00
0.01
Perylene(a)
967.00
431.00
0.36
8.07
967.00
0.01
Phenanthrene ,a)
596
34300
1.40
31.39
596.00
0.05
Pyrene ,d'
697.00
9,090.00
2.30
51.57
697.00
0.07
ESBTU FCVi
1.11
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 65 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-18
Field Sample ID
RREC13-18-0709
Sample Depth
7-9
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.65
0.0265
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.02
0.79
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.03
1.06
447.00
0.00
Acenaphthene (a)
491.00
33400
0.02
0.91
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.02
0.60
452.00
0.00
Anthracene (a)
594.00
1300
0.07
2.75
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.21
7.92
841.00
0.01
Benzo(a)pyrene (a)
965.00
3840
0.15
5.66
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
0.14
5.28
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.11
4.15
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.07
2.57
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.12
4.53
981.00
0.00
CI Chrysenes (a)
929.00
0.25
9.43
929.00
0.01
CI Fluorenes(a)
611.00
0.02
0.91
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.43
16.23
770.00
0.02
CI-Naphthalenes (a)
444.00
0.03
1.17
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.39
14.72
670.00
0.02
C2 Chrysenes (a)
1008.00
0.32
12.08
1008.00
0.01
C2 Fluorenes (a)
686.00
0.05
1.92
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.33
12.45
C2-Naphthalenes (a)
510.00
0.21
7.92
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
0.39
14.72
746.00
0.02
C3 Chrysenes (a)
1112.00
0.16
6.04
1112.00
0.01
C3 Fluorenes (a)
769.00
0.12
4.53
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.25
9.43
949.00
0.01
C3-Naphthalenes(a)
581.00
0.31
11.70
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.42
15.85
829.00
0.02
C4 Chrysenes (a)
1214.00
0.07
2.68
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.25
9.43
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.30
11.32
913.00
0.01
Chrysene ,a)
844.00
826
0.20
7.55
844.00
0.01
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.02
0.72
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.32
12.08
707.00
0.02
Fluorene ,a)
538.00
26,000.00
0.04
1.62
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.05
2.04
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.03
1.06
385.00
0.00
Perylene(a)
967.00
431.00
0.05
1.92
967.00
0.00
Phenanthrene ,a)
596
34300
0.18
6.79
596.00
0.01
Pyrene ,d'
697.00
9,090.00
0.30
11.32
697.00
0.02
ESBTU FCVi
0.21
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 66 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-18
Field Sample ID
RREC13-18-0911
Sample Depth
9-11
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.77
0.0377
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.01
0.16
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.01
0.31
447.00
0.00
Acenaphthene (a)
491.00
33400
0.01
0.25
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.01
0.23
452.00
0.00
Anthracene (a)
594.00
1300
0.04
1.14
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.09
2.47
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.07
1.94
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.07
1.78
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.05
1.38
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.04
1.03
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.06
1.46
981.00
0.00
CI Chrysenes (a)
929.00
0.10
2.60
929.00
0.00
CI Fluorenes(a)
611.00
0.01
0.32
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.17
4.51
770.00
0.01
CI-Naphthalenes (a)
444.00
0.01
0.25
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.17
4.51
670.00
0.01
C2 Chrysenes (a)
1008.00
0.14
3.71
1008.00
0.00
C2 Fluorenes (a)
686.00
0.02
0.56
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.12
3.18
C2-Naphthalenes (a)
510.00
0.07
1.88
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.16
4.24
746.00
0.01
C3 Chrysenes (a)
1112.00
0.07
1.78
1112.00
0.00
C3 Fluorenes (a)
769.00
0.05
1.35
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.09
2.49
949.00
0.00
C3-Naphthalenes(a)
581.00
0.16
4.24
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.15
3.98
829.00
0.00
C4 Chrysenes (a)
1214.00
0.03
0.82
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.16
4.24
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.13
3.45
913.00
0.00
Chrysene ,a)
844.00
826
0.09
2.36
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.01
0.27
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.17
4.51
707.00
0.01
Fluorene ,a)
538.00
26,000.00
0.02
0.61
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.03
0.80
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.01
0.31
385.00
0.00
Perylene(a)
967.00
431.00
0.03
0.77
967.00
0.00
Phenanthrene ,a)
596
34300
0.08
2.07
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.14
3.71
697.00
0.01
ESBTU FCVi
0.07
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 67 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-19
Field Sample ID
RREC13-19-SURF
Sample Depth
0-0.5
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.44
0.0444
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.09
2.07
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.13
2.93
447.00
0.01
Acenaphthene (a)
491.00
33400
0.06
1.33
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.04
0.90
452.00
0.00
Anthracene (a)
594.00
1300
0.19
4.28
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
0.71
15.99
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
0.70
15.77
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
0.67
15.09
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
0.48
10.81
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.30
6.76
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
0.59
13.29
981.00
0.01
CI Chrysenes (a)
929.00
0.60
13.51
929.00
0.01
CI Fluorenes(a)
611.00
0.05
1.19
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.97
21.85
770.00
0.03
CI-Naphthalenes (a)
444.00
0.15
3.38
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.66
14.86
670.00
0.02
C2 Chrysenes (a)
1008.00
0.67
15.09
1008.00
0.02
C2 Fluorenes (a)
686.00
0.10
2.25
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.77
17.34
C2-Naphthalenes (a)
510.00
0.60
13.51
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
0.63
14.19
746.00
0.02
C3 Chrysenes (a)
1112.00
0.40
9.01
1112.00
0.01
C3 Fluorenes (a)
769.00
0.23
5.18
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.58
13.06
949.00
0.01
C3-Naphthalenes(a)
581.00
0.86
19.37
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
0.77
17.34
829.00
0.02
C4 Chrysenes (a)
1214.00
0.16
3.60
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.66
14.86
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.54
12.16
913.00
0.01
Chrysene ,a)
844.00
826
0.70
15.77
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.09
2.05
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.89
20.05
707.00
0.03
Fluorene ,a)
538.00
26,000.00
0.11
2.48
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.28
6.31
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.17
3.83
385.00
0.01
Perylene(a)
967.00
431.00
0.19
4.28
967.00
0.00
Phenanthrene ,a)
596
34300
0.51
11.49
596.00
0.02
Pyrene ,d'
697.00
9,090.00
0.79
17.79
697.00
0.03
ESBTU FCVi
0.33
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 68 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-19
Field Sample ID
RREC13-19-0001
Sample Depth
0-1
Sample Date
10/31/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.62
0.0362
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.09
2.35
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.08
2.32
447.00
0.01
Acenaphthene (a)
491.00
33400
0.10
2.65
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.09
2.35
452.00
0.01
Anthracene (a)
594.00
1300
0.21
5.80
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
0.61
16.85
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
0.46
12.71
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
0.52
14.36
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.42
11.60
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.35
9.67
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
0.40
11.05
981.00
0.01
CI Chrysenes (a)
929.00
0.77
21.27
929.00
0.02
CI Fluorenes(a)
611.00
0.10
2.76
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.94
25.97
770.00
0.03
CI-Naphthalenes (a)
444.00
0.10
2.76
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.94
25.97
670.00
0.04
C2 Chrysenes (a)
1008.00
0.83
22.93
1008.00
0.02
C2 Fluorenes (a)
686.00
0.26
7.18
686.00
0.01
C2-Fluoranthenes/Pyrenes
0.92
25.41
C2-Naphthalenes (a)
510.00
0.70
19.34
510.00
0.04
C2-Phenanthrenes/Anthracenes (a)
746
1.60
44.20
746.00
0.06
C3 Chrysenes (a)
1112.00
0.50
13.81
1112.00
0.01
C3 Fluorenes (a)
769.00
0.66
18.23
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
0.73
20.17
949.00
0.02
C3-Naphthalenes(a)
581.00
1.60
44.20
581.00
0.08
C3-Phenanthrenes/Anthracenes (a)
829.00
1.90
52.49
829.00
0.06
C4 Chrysenes (a)
1214.00
0.27
7.46
1214.00
0.01
C4-Naphthalenes (a)
657.00
1.50
41.44
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
1.30
35.91
913.00
0.04
Chrysene ,a)
844.00
826
0.66
18.23
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.12
3.31
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.80
22.10
707.00
0.03
Fluorene ,a)
538.00
26,000.00
0.17
4.70
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.30
8.29
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.09
2.35
385.00
0.01
Perylene(a)
967.00
431.00
0.15
4.14
967.00
0.00
Phenanthrene ,a)
596
34300
0.59
16.30
596.00
0.03
Pyrene ,d'
697.00
9,090.00
1.00
27.62
697.00
0.04
ESBTU FCVi
0.52
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 69 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-20
Field Sample ID
RREC13-20-SURF
Sample Depth
0-0.5
Sample Date
10/29/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.13
0.0513
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.05
0.99
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.08
1.60
447.00
0.00
Acenaphthene (a)
491.00
33400
0.03
0.66
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.02
0.41
452.00
0.00
Anthracene (a)
594.00
1300
0.13
2.53
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.41
7.99
841.00
0.01
Benzo(a)pyrene (a)
965.00
3840
0.40
7.80
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
0.40
7.80
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.27
5.26
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.18
3.51
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.37
7.21
981.00
0.01
CI Chrysenes (a)
929.00
0.27
5.26
929.00
0.01
CI Fluorenes(a)
611.00
0.03
0.58
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.52
10.14
770.00
0.01
CI-Naphthalenes (a)
444.00
0.09
1.70
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.37
7.21
670.00
0.01
C2 Chrysenes (a)
1008.00
0.25
4.87
1008.00
0.00
C2 Fluorenes (a)
686.00
0.04
0.78
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.30
5.85
C2-Naphthalenes (a)
510.00
0.32
6.24
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.28
5.46
746.00
0.01
C3 Chrysenes (a)
1112.00
0.12
2.34
1112.00
0.00
C3 Fluorenes (a)
769.00
0.09
1.68
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.19
3.70
949.00
0.00
C3-Naphthalenes(a)
581.00
0.46
8.97
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.31
6.04
829.00
0.01
C4 Chrysenes (a)
1214.00
0.05
0.92
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.36
7.02
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.19
3.70
913.00
0.00
Chrysene ,a)
844.00
826
0.41
7.99
844.00
0.01
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.05
0.96
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.63
12.28
707.00
0.02
Fluorene ,a)
538.00
26,000.00
0.06
1.15
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.17
3.31
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.12
2.34
385.00
0.01
Perylene(a)
967.00
431.00
0.12
2.34
967.00
0.00
Phenanthrene ,a)
596
34300
0.32
6.24
596.00
0.01
Pyrene ,d'
697.00
9,090.00
0.55
10.72
697.00
0.02
ESBTU FCVi
0.16
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 70 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-20
Field Sample ID
RREC13-20-0001
Sample Depth
0-1
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.07
0.0607
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.01
0.16
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.01
0.21
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.05
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.04
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.07
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.02
0.26
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.02
0.25
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.02
0.36
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.02
0.28
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.18
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.02
0.26
981.00
0.00
CI Chrysenes (a)
929.00
0.03
0.51
929.00
0.00
CI Fluorenes(a)
611.00
0.02
0.25
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.04
0.69
770.00
0.00
CI-Naphthalenes (a)
444.00
0.02
0.28
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.15
2.47
670.00
0.00
C2 Chrysenes (a)
1008.00
0.11
1.81
1008.00
0.00
C2 Fluorenes (a)
686.00
0.03
0.44
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.06
0.94
C2-Naphthalenes (a)
510.00
0.09
1.50
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.12
1.98
746.00
0.00
C3 Chrysenes (a)
1112.00
0.05
0.81
1112.00
0.00
C3 Fluorenes (a)
769.00
0.05
0.77
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.06
1.02
949.00
0.00
C3-Naphthalenes(a)
581.00
0.35
5.77
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.15
2.47
829.00
0.00
C4 Chrysenes (a)
1214.00
0.02
0.35
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.31
5.11
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.10
1.65
913.00
0.00
Chrysene ,a)
844.00
826
0.03
0.48
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.03
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.02
0.38
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.01
0.09
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.08
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.01
0.18
385.00
0.00
Perylene(a)
967.00
431.00
0.01
0.16
967.00
0.00
Phenanthrene ,a)
596
34300
0.03
0.53
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.02
0.35
697.00
0.00
ESBTU FCVi
0.02
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 71 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-20
Field Sample ID
RREC13-20-0103
Sample Depth
1-3
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.1
0.041
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.01
0.27
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.01
0.34
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.03
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.05
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.08
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.01
0.18
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.01
0.17
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.27
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.32
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.21
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.10
981.00
0.00
CI Chrysenes (a)
929.00
0.03
0.78
929.00
0.00
CI Fluorenes(a)
611.00
0.02
0.41
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.04
0.95
770.00
0.00
CI-Naphthalenes (a)
444.00
0.02
0.41
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.17
4.15
670.00
0.01
C2 Chrysenes (a)
1008.00
0.10
2.44
1008.00
0.00
C2 Fluorenes (a)
686.00
0.03
0.83
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.06
1.49
C2-Naphthalenes (a)
510.00
0.09
2.24
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.15
3.66
746.00
0.00
C3 Chrysenes (a)
1112.00
0.06
1.46
1112.00
0.00
C3 Fluorenes (a)
769.00
0.05
1.29
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.07
1.68
949.00
0.00
C3-Naphthalenes(a)
581.00
0.37
9.02
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.12
2.93
829.00
0.00
C4 Chrysenes (a)
1214.00
0.02
0.59
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.39
9.51
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.11
2.68
913.00
0.00
Chrysene ,a)
844.00
826
0.02
0.56
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.03
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.01
0.21
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.11
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.06
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.01
0.20
385.00
0.00
Perylene(a)
967.00
431.00
0.01
0.22
967.00
0.00
Phenanthrene ,a)
596
34300
0.04
0.88
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.29
697.00
0.00
ESBTU FCVi
0.03
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 72 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-20
Field Sample ID
RREC13-20-0305
Sample Depth
3-5
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.26
0.0326
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.01
0.26
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.01
0.31
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.05
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.06
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.06
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.09
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.11
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.23
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.30
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.21
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.05
981.00
0.00
CI Chrysenes (a)
929.00
0.03
0.83
929.00
0.00
CI Fluorenes(a)
611.00
0.01
0.43
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.03
0.98
770.00
0.00
CI-Naphthalenes (a)
444.00
0.01
0.40
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.15
4.60
670.00
0.01
C2 Chrysenes (a)
1008.00
0.10
2.91
1008.00
0.00
C2 Fluorenes (a)
686.00
0.03
0.83
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.06
1.69
C2-Naphthalenes (a)
510.00
0.08
2.55
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.13
3.99
746.00
0.01
C3 Chrysenes (a)
1112.00
0.05
1.53
1112.00
0.00
C3 Fluorenes (a)
769.00
0.05
1.47
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.06
1.81
949.00
0.00
C3-Naphthalenes(a)
581.00
0.33
10.12
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.16
4.91
829.00
0.01
C4 Chrysenes (a)
1214.00
0.02
0.67
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.32
9.82
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.10
3.07
913.00
0.00
Chrysene ,a)
844.00
826
0.02
0.61
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.02
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.00
0.13
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.12
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.04
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.06
385.00
0.00
Perylene(a)
967.00
431.00
0.01
0.24
967.00
0.00
Phenanthrene ,a)
596
34300
0.03
1.01
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.26
697.00
0.00
ESBTU FCVi
0.03
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 73 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-SURF
Sample Depth
0-0.5
Sample Date
10/29/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.91
0.0691
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.09
1.24
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.15
2.17
447.00
0.00
Acenaphthene (a)
491.00
33400
0.08
1.14
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.05
0.65
452.00
0.00
Anthracene (a)
594.00
1300
0.19
2.75
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.88
12.74
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.00
14.47
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.50
21.71
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
0.93
13.46
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.54
7.81
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.00
14.47
981.00
0.01
CI Chrysenes (a)
929.00
0.93
13.46
929.00
0.01
CI Fluorenes(a)
611.00
0.08
1.11
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.30
18.81
770.00
0.02
CI-Naphthalenes (a)
444.00
0.16
2.32
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.88
12.74
670.00
0.02
C2 Chrysenes (a)
1008.00
1.50
21.71
1008.00
0.02
C2 Fluorenes (a)
686.00
0.18
2.60
686.00
0.00
C2-Fluoranthenes/Pyrenes
1.40
20.26
C2-Naphthalenes (a)
510.00
0.65
9.41
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
1.30
18.81
746.00
0.03
C3 Chrysenes (a)
1112.00
0.81
11.72
1112.00
0.01
C3 Fluorenes (a)
769.00
0.60
8.68
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
1.30
18.81
949.00
0.02
C3-Naphthalenes(a)
581.00
0.83
12.01
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
1.60
23.15
829.00
0.03
C4 Chrysenes (a)
1214.00
0.37
5.35
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.00
14.47
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
1.60
23.15
913.00
0.03
Chrysene ,a)
844.00
826
1.00
14.47
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.13
1.88
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.70
24.60
707.00
0.03
Fluorene ,a)
538.00
26,000.00
0.10
1.42
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.48
6.95
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.15
2.17
385.00
0.01
Perylene(a)
967.00
431.00
0.37
5.35
967.00
0.01
Phenanthrene ,a)
596
34300
0.68
9.84
596.00
0.02
Pyrene ,d'
697.00
9,090.00
1.30
18.81
697.00
0.03
ESBTU FCVi
0.35
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 74 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-0001
Sample Depth
0-1
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.07
0.0707
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.10
1.40
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.10
1.41
447.00
0.00
Acenaphthene (a)
491.00
33400
0.13
1.84
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.16
2.19
452.00
0.00
Anthracene (a)
594.00
1300
0.31
4.38
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.10
15.56
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.10
15.56
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.00
14.14
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.97
13.72
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
1.20
16.97
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
0.92
13.01
981.00
0.01
CI Chrysenes (a)
929.00
1.20
16.97
929.00
0.02
CI Fluorenes(a)
611.00
0.14
1.98
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.50
21.22
770.00
0.03
CI-Naphthalenes (a)
444.00
0.15
2.12
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.50
21.22
670.00
0.03
C2 Chrysenes (a)
1008.00
1.30
18.39
1008.00
0.02
C2 Fluorenes (a)
686.00
0.40
5.66
686.00
0.01
C2-Fluoranthenes/Pyrenes
1.50
21.22
C2-Naphthalenes (a)
510.00
1.10
15.56
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
1.90
26.87
746.00
0.04
C3 Chrysenes (a)
1112.00
0.74
10.47
1112.00
0.01
C3 Fluorenes (a)
769.00
1.10
15.56
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.40
19.80
949.00
0.02
C3-Naphthalenes(a)
581.00
2.50
35.36
581.00
0.06
C3-Phenanthrenes/Anthracenes (a)
829.00
3.00
42.43
829.00
0.05
C4 Chrysenes (a)
1214.00
0.33
4.67
1214.00
0.00
C4-Naphthalenes (a)
657.00
2.10
29.70
657.00
0.05
C4-Phenanthrenes/Anthracenes (a)
913.00
2.40
33.95
913.00
0.04
Chrysene ,a)
844.00
826
1.30
18.39
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.37
5.23
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.50
21.22
707.00
0.03
Fluorene ,a)
538.00
26,000.00
0.18
2.55
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.00
14.14
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.16
2.19
385.00
0.01
Perylene(a)
967.00
431.00
0.34
4.81
967.00
0.00
Phenanthrene ,a)
596
34300
1.00
14.14
596.00
0.02
Pyrene ,d'
697.00
9,090.00
2.20
31.12
697.00
0.04
ESBTU FCVi
0.48
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 75 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-0001-FD
Sample Depth
0-1
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.36
0.0736
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.08
1.13
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.16
2.11
447.00
0.00
Acenaphthene (a)
491.00
33400
0.10
1.36
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.06
0.83
452.00
0.00
Anthracene (a)
594.00
1300
0.15
2.04
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.80
10.87
841.00
0.01
Benzo(a)pyrene (a)
965.00
3840
0.84
11.41
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
1.00
13.59
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.69
9.38
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.39
5.30
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.85
11.55
981.00
0.01
CI Chrysenes (a)
929.00
0.86
11.68
929.00
0.01
CI Fluorenes(a)
611.00
0.12
1.63
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.30
17.66
770.00
0.02
CI-Naphthalenes (a)
444.00
0.12
1.63
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.20
16.30
670.00
0.02
C2 Chrysenes (a)
1008.00
1.40
19.02
1008.00
0.02
C2 Fluorenes (a)
686.00
0.36
4.89
686.00
0.01
C2-Fluoranthenes/Pyrenes
1.40
19.02
C2-Naphthalenes (a)
510.00
0.96
13.04
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
1.80
24.46
746.00
0.03
C3 Chrysenes (a)
1112.00
0.74
10.05
1112.00
0.01
C3 Fluorenes (a)
769.00
1.10
14.95
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.20
16.30
949.00
0.02
C3-Naphthalenes(a)
581.00
2.20
29.89
581.00
0.05
C3-Phenanthrenes/Anthracenes (a)
829.00
2.40
32.61
829.00
0.04
C4 Chrysenes (a)
1214.00
0.21
2.85
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.90
25.82
657.00
0.04
C4-Phenanthrenes/Anthracenes (a)
913.00
1.70
23.10
913.00
0.03
Chrysene ,a)
844.00
826
0.92
12.50
844.00
0.01
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.10
1.36
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.60
21.74
707.00
0.03
Fluorene ,a)
538.00
26,000.00
0.15
2.04
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.38
5.16
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.16
2.11
385.00
0.01
Perylene(a)
967.00
431.00
0.32
4.35
967.00
0.00
Phenanthrene ,a)
596
34300
0.76
10.33
596.00
0.02
Pyrene ,d'
697.00
9,090.00
1.30
17.66
697.00
0.03
ESBTU FCVi
0.35
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 76 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-0103
Sample Depth
1-3
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.2
0.102
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.25
2.45
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.16
1.52
447.00
0.00
Acenaphthene (a)
491.00
33400
0.14
1.37
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.06
0.61
452.00
0.00
Anthracene (a)
594.00
1300
0.23
2.25
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.96
9.41
841.00
0.01
Benzo(a)pyrene (a)
965.00
3840
0.83
8.14
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
0.90
8.82
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.67
6.57
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.33
3.24
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.69
6.76
981.00
0.01
CI Chrysenes (a)
929.00
1.40
13.73
929.00
0.01
CI Fluorenes(a)
611.00
0.29
2.84
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.10
20.59
770.00
0.03
CI-Naphthalenes (a)
444.00
0.29
2.84
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.20
31.37
670.00
0.05
C2 Chrysenes (a)
1008.00
2.90
28.43
1008.00
0.03
C2 Fluorenes (a)
686.00
0.98
9.61
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.60
25.49
C2-Naphthalenes (a)
510.00
3.30
32.35
510.00
0.06
C2-Phenanthrenes/Anthracenes (a)
746
4.60
45.10
746.00
0.06
C3 Chrysenes (a)
1112.00
1.50
14.71
1112.00
0.01
C3 Fluorenes (a)
769.00
2.60
25.49
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
3.20
31.37
949.00
0.03
C3-Naphthalenes(a)
581.00
6.40
62.75
581.00
0.11
C3-Phenanthrenes/Anthracenes (a)
829.00
6.90
67.65
829.00
0.08
C4 Chrysenes (a)
1214.00
0.61
5.98
1214.00
0.00
C4-Naphthalenes (a)
657.00
5.50
53.92
657.00
0.08
C4-Phenanthrenes/Anthracenes (a)
913.00
5.00
49.02
913.00
0.05
Chrysene ,a)
844.00
826
1.20
11.76
844.00
0.01
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.08
0.77
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.70
16.67
707.00
0.02
Fluorene ,a)
538.00
26,000.00
0.27
2.65
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.31
3.04
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.16
1.52
385.00
0.00
Perylene(a)
967.00
431.00
0.38
3.73
967.00
0.00
Phenanthrene ,a)
596
34300
1.10
10.78
596.00
0.02
Pyrene ,d'
697.00
9,090.00
1.80
17.65
697.00
0.03
ESBTU FCVi
0.47
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 77 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-0103-FD
Sample Depth
1-3
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.6
0.106
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.37
3.49
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.20
1.89
447.00
0.00
Acenaphthene (a)
491.00
33400
0.24
2.26
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.08
0.73
452.00
0.00
Anthracene (a)
594.00
1300
0.30
2.83
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
1.20
11.32
841.00
0.01
Benzo(a)pyrene (a)
965.00
3840
1.10
10.38
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
1.20
11.32
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.88
8.30
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.45
4.25
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
1.10
10.38
981.00
0.01
CI Chrysenes (a)
929.00
1.60
15.09
929.00
0.02
CI Fluorenes(a)
611.00
0.42
3.96
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.90
27.36
770.00
0.04
CI-Naphthalenes (a)
444.00
0.43
4.06
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.30
40.57
670.00
0.06
C2 Chrysenes (a)
1008.00
3.70
34.91
1008.00
0.03
C2 Fluorenes (a)
686.00
1.40
13.21
686.00
0.02
C2-Fluoranthenes/Pyrenes
3.30
31.13
C2-Naphthalenes (a)
510.00
5.00
47.17
510.00
0.09
C2-Phenanthrenes/Anthracenes (a)
746
6.70
63.21
746.00
0.08
C3 Chrysenes (a)
1112.00
1.70
16.04
1112.00
0.01
C3 Fluorenes (a)
769.00
3.80
35.85
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
3.30
31.13
949.00
0.03
C3-Naphthalenes(a)
581.00
9.50
89.62
581.00
0.15
C3-Phenanthrenes/Anthracenes (a)
829.00
8.70
82.08
829.00
0.10
C4 Chrysenes (a)
1214.00
1.00
9.43
1214.00
0.01
C4-Naphthalenes (a)
657.00
7.80
73.58
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
6.50
61.32
913.00
0.07
Chrysene ,a)
844.00
826
1.50
14.15
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.11
1.04
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.40
22.64
707.00
0.03
Fluorene ,a)
538.00
26,000.00
0.32
3.02
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.41
3.87
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.20
1.89
385.00
0.00
Perylene(a)
967.00
431.00
0.51
4.81
967.00
0.00
Phenanthrene ,a)
596
34300
1.40
13.21
596.00
0.02
Pyrene ,d'
697.00
9,090.00
2.30
21.70
697.00
0.03
ESBTU FCVi
0.61
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 78 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-0305
Sample Depth
3-5
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.13
0.0913
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.92
10.08
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.20
13.14
447.00
0.03
Acenaphthene (a)
491.00
33400
0.64
7.01
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.17
1.86
452.00
0.00
Anthracene (a)
594.00
1300
0.77
8.43
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.20
24.10
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.80
19.72
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.90
20.81
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.40
15.33
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.86
9.42
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.60
17.52
981.00
0.02
CI Chrysenes (a)
929.00
2.20
24.10
929.00
0.03
CI Fluorenes(a)
611.00
1.10
12.05
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.00
43.81
770.00
0.06
CI-Naphthalenes (a)
444.00
1.50
16.43
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
9.30
101.86
670.00
0.15
C2 Chrysenes (a)
1008.00
3.80
41.62
1008.00
0.04
C2 Fluorenes (a)
686.00
2.60
28.48
686.00
0.04
C2-Fluoranthenes/Pyrenes
4.30
47.10
C2-Naphthalenes (a)
510.00
15.00
164.29
510.00
0.32
C2-Phenanthrenes/Anthracenes (a)
746
10.00
109.53
746.00
0.15
C3 Chrysenes (a)
1112.00
2.50
27.38
1112.00
0.02
C3 Fluorenes (a)
769.00
5.90
64.62
769.00
0.08
C3-Fluoranthenes/Pyrenes
949.00
4.50
49.29
949.00
0.05
C3-Naphthalenes(a)
581.00
25.00
273.82
581.00
0.47
C3-Phenanthrenes/Anthracenes (a)
829.00
11.00
120.48
829.00
0.15
C4 Chrysenes (a)
1214.00
1.20
13.14
1214.00
0.01
C4-Naphthalenes (a)
657.00
17.00
186.20
657.00
0.28
C4-Phenanthrenes/Anthracenes (a)
913.00
7.70
84.34
913.00
0.09
Chrysene ,a)
844.00
826
2.30
25.19
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.21
2.30
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
6.60
72.29
707.00
0.10
Fluorene ,a)
538.00
26,000.00
1.20
13.14
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.75
8.21
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.60
6.57
385.00
0.02
Perylene(a)
967.00
431.00
0.69
7.56
967.00
0.01
Phenanthrene ,a)
596
34300
5.90
64.62
596.00
0.11
Pyrene ,d'
697.00
9,090.00
4.90
53.67
697.00
0.08
ESBTU FCVi
1.26
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 79 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-0305-FD
Sample Depth
3-5
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.49
0.0949
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.10
11.59
446.00
0.03
2-Methylnaphthalene
447.00
154800
0.70
7.38
447.00
0.02
Acenaphthene (a)
491.00
33400
0.77
8.11
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.21
2.21
452.00
0.00
Anthracene (a)
594.00
1300
0.90
9.48
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.90
30.56
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.30
24.24
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.40
25.29
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.70
17.91
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.00
10.54
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.00
21.07
981.00
0.02
CI Chrysenes (a)
929.00
2.50
26.34
929.00
0.03
CI Fluorenes(a)
611.00
1.20
12.64
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.20
54.79
770.00
0.07
CI-Naphthalenes (a)
444.00
1.60
16.86
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
11.00
115.91
670.00
0.17
C2 Chrysenes (a)
1008.00
5.00
52.69
1008.00
0.05
C2 Fluorenes (a)
686.00
2.90
30.56
686.00
0.04
C2-Fluoranthenes/Pyrenes
5.40
56.90
C2-Naphthalenes (a)
510.00
17.00
179.14
510.00
0.35
C2-Phenanthrenes/Anthracenes (a)
746
13.00
136.99
746.00
0.18
C3 Chrysenes (a)
1112.00
3.20
33.72
1112.00
0.03
C3 Fluorenes (a)
769.00
6.60
69.55
769.00
0.09
C3-Fluoranthenes/Pyrenes
949.00
5.60
59.01
949.00
0.06
C3-Naphthalenes(a)
581.00
27.00
284.51
581.00
0.49
C3-Phenanthrenes/Anthracenes (a)
829.00
14.00
147.52
829.00
0.18
C4 Chrysenes (a)
1214.00
1.70
17.91
1214.00
0.01
C4-Naphthalenes (a)
657.00
18.00
189.67
657.00
0.29
C4-Phenanthrenes/Anthracenes (a)
913.00
9.60
101.16
913.00
0.11
Chrysene ,a)
844.00
826
2.90
30.56
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.25
2.63
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
9.90
104.32
707.00
0.15
Fluorene ,a)
538.00
26,000.00
1.40
14.75
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.86
9.06
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.70
7.38
385.00
0.02
Perylene(a)
967.00
431.00
0.84
8.85
967.00
0.01
Phenanthrene ,a)
596
34300
7.20
75.87
596.00
0.13
Pyrene ,d'
697.00
9,090.00
6.80
71.65
697.00
0.10
ESBTU FCVi
1.53
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 80 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-0507
Sample Depth
5-7
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.4
0.104
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.55
5.29
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.55
5.29
447.00
0.01
Acenaphthene (a)
491.00
33400
0.44
4.23
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.15
1.44
452.00
0.00
Anthracene (a)
594.00
1300
0.70
6.73
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.90
27.88
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
2.40
23.08
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
2.60
25.00
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.80
17.31
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.20
11.54
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.10
20.19
981.00
0.02
CI Chrysenes (a)
929.00
2.60
25.00
929.00
0.03
CI Fluorenes(a)
611.00
0.67
6.44
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.00
48.08
770.00
0.06
CI-Naphthalenes (a)
444.00
0.73
7.02
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.10
68.27
670.00
0.10
C2 Chrysenes (a)
1008.00
4.10
39.42
1008.00
0.04
C2 Fluorenes (a)
686.00
1.80
17.31
686.00
0.03
C2-Fluoranthenes/Pyrenes
4.70
45.19
C2-Naphthalenes (a)
510.00
7.40
71.15
510.00
0.14
C2-Phenanthrenes/Anthracenes (a)
746
8.30
79.81
746.00
0.11
C3 Chrysenes (a)
1112.00
2.10
20.19
1112.00
0.02
C3 Fluorenes (a)
769.00
3.90
37.50
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
3.80
36.54
949.00
0.04
C3-Naphthalenes(a)
581.00
14.00
134.62
581.00
0.23
C3-Phenanthrenes/Anthracenes (a)
829.00
10.00
96.15
829.00
0.12
C4 Chrysenes (a)
1214.00
1.00
9.62
1214.00
0.01
C4-Naphthalenes (a)
657.00
11.00
105.77
657.00
0.16
C4-Phenanthrenes/Anthracenes (a)
913.00
6.70
64.42
913.00
0.07
Chrysene ,a)
844.00
826
2.80
26.92
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.30
2.88
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
6.80
65.38
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.83
7.98
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
10.58
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.55
5.29
385.00
0.01
Perylene(a)
967.00
431.00
0.81
7.79
967.00
0.01
Phenanthrene ,a)
596
34300
4.00
38.46
596.00
0.06
Pyrene ,d'
697.00
9,090.00
5.40
51.92
697.00
0.07
ESBTU FCVi
1.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 81 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-0507-FD
Sample Depth
5-7
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
11.5
0.115
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.63
5.48
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.43
3.70
447.00
0.01
Acenaphthene (a)
491.00
33400
0.48
4.17
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.13
1.13
452.00
0.00
Anthracene (a)
594.00
1300
0.70
6.09
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.70
23.48
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
2.30
20.00
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
2.30
20.00
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.70
14.78
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.10
9.57
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.10
18.26
981.00
0.02
CI Chrysenes (a)
929.00
2.70
23.48
929.00
0.03
CI Fluorenes(a)
611.00
0.83
7.22
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.30
46.09
770.00
0.06
CI-Naphthalenes (a)
444.00
0.79
6.87
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.30
72.17
670.00
0.11
C2 Chrysenes (a)
1008.00
4.60
40.00
1008.00
0.04
C2 Fluorenes (a)
686.00
2.00
17.39
686.00
0.03
C2-Fluoranthenes/Pyrenes
5.50
47.83
C2-Naphthalenes (a)
510.00
9.30
80.87
510.00
0.16
C2-Phenanthrenes/Anthracenes (a)
746
10.00
86.96
746.00
0.12
C3 Chrysenes (a)
1112.00
2.40
20.87
1112.00
0.02
C3 Fluorenes (a)
769.00
5.00
43.48
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
4.50
39.13
949.00
0.04
C3-Naphthalenes(a)
581.00
17.00
147.83
581.00
0.25
C3-Phenanthrenes/Anthracenes (a)
829.00
12.00
104.35
829.00
0.13
C4 Chrysenes (a)
1214.00
1.10
9.57
1214.00
0.01
C4-Naphthalenes (a)
657.00
13.00
113.04
657.00
0.17
C4-Phenanthrenes/Anthracenes (a)
913.00
7.80
67.83
913.00
0.07
Chrysene ,a)
844.00
826
2.90
25.22
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.27
2.35
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
6.50
56.52
707.00
0.08
Fluorene ,a)
538.00
26,000.00
0.67
5.83
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.96
8.35
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.43
3.70
385.00
0.01
Perylene(a)
967.00
431.00
0.75
6.52
967.00
0.01
Phenanthrene ,a)
596
34300
3.90
33.91
596.00
0.06
Pyrene ,d'
697.00
9,090.00
5.40
46.96
697.00
0.07
ESBTU FCVi
0.98
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 82 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-0709
Sample Depth
7-9
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
11.3
0.113
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.27
2.39
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.23
2.04
447.00
0.00
Acenaphthene (a)
491.00
33400
0.19
1.68
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.06
0.52
452.00
0.00
Anthracene (a)
594.00
1300
0.48
4.25
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.50
13.27
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.10
9.73
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
1.20
10.62
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.82
7.26
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.47
4.16
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.99
8.76
981.00
0.01
CI Chrysenes (a)
929.00
1.60
14.16
929.00
0.02
CI Fluorenes(a)
611.00
0.28
2.48
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.90
25.66
770.00
0.03
CI-Naphthalenes (a)
444.00
0.44
3.89
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.30
29.20
670.00
0.04
C2 Chrysenes (a)
1008.00
2.50
22.12
1008.00
0.02
C2 Fluorenes (a)
686.00
0.65
5.75
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.60
23.01
C2-Naphthalenes (a)
510.00
2.70
23.89
510.00
0.05
C2-Phenanthrenes/Anthracenes (a)
746
4.10
36.28
746.00
0.05
C3 Chrysenes (a)
1112.00
1.30
11.50
1112.00
0.01
C3 Fluorenes (a)
769.00
1.50
13.27
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
2.10
18.58
949.00
0.02
C3-Naphthalenes(a)
581.00
5.60
49.56
581.00
0.09
C3-Phenanthrenes/Anthracenes (a)
829.00
5.10
45.13
829.00
0.05
C4 Chrysenes (a)
1214.00
0.53
4.69
1214.00
0.00
C4-Naphthalenes (a)
657.00
4.10
36.28
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
3.20
28.32
913.00
0.03
Chrysene ,a)
844.00
826
1.50
13.27
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.14
1.24
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.90
25.66
707.00
0.04
Fluorene ,a)
538.00
26,000.00
0.37
3.27
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.44
3.89
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.23
2.04
385.00
0.01
Perylene(a)
967.00
431.00
0.33
2.92
967.00
0.00
Phenanthrene ,a)
596
34300
1.60
14.16
596.00
0.02
Pyrene ,d'
697.00
9,090.00
2.30
20.35
697.00
0.03
ESBTU FCVi
0.43
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 83 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-0709-FD
Sample Depth
7-9
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.88
0.0788
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.18
2.28
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.17
2.16
447.00
0.00
Acenaphthene (a)
491.00
33400
0.12
1.52
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.04
0.49
452.00
0.00
Anthracene (a)
594.00
1300
0.32
4.06
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
0.95
12.06
841.00
0.01
Benzo(a)pyrene (a)
965.00
3840
0.71
9.01
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
0.79
10.03
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.52
6.60
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.33
4.19
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.65
8.25
981.00
0.01
CI Chrysenes (a)
929.00
1.10
13.96
929.00
0.02
CI Fluorenes(a)
611.00
0.19
2.41
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.80
22.84
770.00
0.03
CI-Naphthalenes (a)
444.00
0.29
3.68
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.20
27.92
670.00
0.04
C2 Chrysenes (a)
1008.00
1.60
20.30
1008.00
0.02
C2 Fluorenes (a)
686.00
0.43
5.46
686.00
0.01
C2-Fluoranthenes/Pyrenes
1.70
21.57
C2-Naphthalenes (a)
510.00
1.80
22.84
510.00
0.04
C2-Phenanthrenes/Anthracenes (a)
746
2.80
35.53
746.00
0.05
C3 Chrysenes (a)
1112.00
0.85
10.79
1112.00
0.01
C3 Fluorenes (a)
769.00
1.10
13.96
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.40
17.77
949.00
0.02
C3-Naphthalenes(a)
581.00
3.70
46.95
581.00
0.08
C3-Phenanthrenes/Anthracenes (a)
829.00
3.10
39.34
829.00
0.05
C4 Chrysenes (a)
1214.00
0.39
4.95
1214.00
0.00
C4-Naphthalenes (a)
657.00
2.90
36.80
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
1.90
24.11
913.00
0.03
Chrysene ,a)
844.00
826
0.95
12.06
844.00
0.01
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.10
1.27
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.90
24.11
707.00
0.03
Fluorene ,a)
538.00
26,000.00
0.22
2.79
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.29
3.68
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.17
2.16
385.00
0.01
Perylene(a)
967.00
431.00
0.21
2.66
967.00
0.00
Phenanthrene ,a)
596
34300
1.00
12.69
596.00
0.02
Pyrene ,d'
697.00
9,090.00
1.50
19.04
697.00
0.03
ESBTU FCVi
0.40
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 84 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-0911
Sample Depth
9-11
Sample Date
11/01/2013
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.42
0.0342
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.02
0.61
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.03
0.91
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.13
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.10
452.00
0.00
Anthracene (a)
594.00
1300
0.01
0.24
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.02
0.70
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.02
0.53
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.02
0.67
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.02
0.64
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.02
0.44
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.02
0.47
981.00
0.00
CI Chrysenes (a)
929.00
0.05
1.37
929.00
0.00
CI Fluorenes(a)
611.00
0.02
0.58
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.07
2.02
770.00
0.00
CI-Naphthalenes (a)
444.00
0.03
0.99
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.22
6.43
670.00
0.01
C2 Chrysenes (a)
1008.00
0.13
3.80
1008.00
0.00
C2 Fluorenes (a)
686.00
0.04
1.20
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.09
2.54
C2-Naphthalenes (a)
510.00
0.18
5.26
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.20
5.85
746.00
0.01
C3 Chrysenes (a)
1112.00
0.06
1.84
1112.00
0.00
C3 Fluorenes (a)
769.00
0.07
2.16
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.09
2.69
949.00
0.00
C3-Naphthalenes(a)
581.00
0.52
15.20
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
0.23
6.73
829.00
0.01
C4 Chrysenes (a)
1214.00
0.03
0.79
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.45
13.16
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.14
4.09
913.00
0.00
Chrysene ,a)
844.00
826
0.04
1.05
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.07
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.04
1.26
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.01
0.38
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.01
0.18
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.01
0.32
385.00
0.00
Perylene(a)
967.00
431.00
0.01
0.41
967.00
0.00
Phenanthrene ,a)
596
34300
0.06
1.75
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.04
1.08
697.00
0.00
ESBTU FCVi
0.05
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 85 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-21
Field Sample ID
RREC13-21-0911-FD
Sample Depth
9-11
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.62
0.0362
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.02
0.47
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.02
0.64
447.00
0.00
Acenaphthene (a)
491.00
33400
0.01
0.15
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.06
452.00
0.00
Anthracene (a)
594.00
1300
0.01
0.36
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.04
0.97
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.03
0.72
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.03
0.86
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.03
0.69
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.02
0.52
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.02
0.66
981.00
0.00
CI Chrysenes (a)
929.00
0.06
1.57
929.00
0.00
CI Fluorenes(a)
611.00
0.02
0.55
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.09
2.43
770.00
0.00
CI-Naphthalenes (a)
444.00
0.03
0.72
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.22
6.08
670.00
0.01
C2 Chrysenes (a)
1008.00
0.12
3.31
1008.00
0.00
C2 Fluorenes (a)
686.00
0.04
1.13
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.10
2.76
C2-Naphthalenes (a)
510.00
0.19
5.25
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.22
6.08
746.00
0.01
C3 Chrysenes (a)
1112.00
0.06
1.57
1112.00
0.00
C3 Fluorenes (a)
769.00
0.09
2.46
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.10
2.68
949.00
0.00
C3-Naphthalenes(a)
581.00
0.46
12.71
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.25
6.91
829.00
0.01
C4 Chrysenes (a)
1214.00
0.03
0.77
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.45
12.43
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.15
4.14
913.00
0.00
Chrysene ,a)
844.00
826
0.05
1.33
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.10
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.07
1.93
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.01
0.28
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.01
0.33
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.01
0.18
385.00
0.00
Perylene(a)
967.00
431.00
0.02
0.44
967.00
0.00
Phenanthrene 'd'
596
34300
0.07
1.82
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.06
1.66
697.00
0.00
ESBTU FCVi
0.06
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 1 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-22
Field Sample ID
RREC13-22-SURF
Sample Depth
0-0.5
Sample Date
10/29/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.89
0.0589
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.08
1.39
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.15
2.55
447.00
0.01
Acenaphthene (a)
491.00
33400
0.10
1.70
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.07
1.14
452.00
0.00
Anthracene (a)
594.00
1300
0.36
6.11
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.40
23.77
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.50
25.47
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
1.50
25.47
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
0.98
16.64
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.66
11.21
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.30
22.07
981.00
0.02
CI Chrysenes (a)
929.00
0.90
15.28
929.00
0.02
CI Fluorenes(a)
611.00
0.08
1.31
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.70
28.86
770.00
0.04
CI-Naphthalenes (a)
444.00
0.16
2.72
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.00
16.98
670.00
0.03
C2 Chrysenes (a)
1008.00
0.84
14.26
1008.00
0.01
C2 Fluorenes (a)
686.00
0.16
2.72
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.98
16.64
C2-Naphthalenes (a)
510.00
0.58
9.85
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
0.97
16.47
746.00
0.02
C3 Chrysenes (a)
1112.00
0.43
7.30
1112.00
0.01
C3 Fluorenes (a)
769.00
0.41
6.96
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.73
12.39
949.00
0.01
C3-Naphthalenes(a)
581.00
0.79
13.41
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
1.20
20.37
829.00
0.02
C4 Chrysenes (a)
1214.00
0.15
2.55
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.82
13.92
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.92
15.62
913.00
0.02
Chrysene ,a)
844.00
826
1.40
23.77
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.17
2.89
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.10
35.65
707.00
0.05
Fluorene ,a)
538.00
26,000.00
0.15
2.55
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.64
10.87
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.16
2.72
385.00
0.01
Perylene(a)
967.00
431.00
0.43
7.30
967.00
0.01
Phenanthrene 'd'
596
34300
0.97
16.47
596.00
0.03
Pyrene ,d'
697.00
9,090.00
1.80
30.56
697.00
0.04
ESBTU FCVi
0.47
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 2 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-22
Field Sample ID
RREC13-22-0001
Sample Depth
0-1
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.18
0.0718
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.09
1.20
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.13
1.81
447.00
0.00
Acenaphthene (a)
491.00
33400
0.15
2.09
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.07
0.91
452.00
0.00
Anthracene (a)
594.00
1300
0.43
5.99
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.70
23.68
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.70
23.68
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.60
22.28
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.20
16.71
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.94
13.09
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.60
22.28
981.00
0.02
CI Chrysenes (a)
929.00
1.10
15.32
929.00
0.02
CI Fluorenes(a)
611.00
0.08
1.17
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.80
25.07
770.00
0.03
CI-Naphthalenes (a)
444.00
0.15
2.09
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.20
16.71
670.00
0.02
C2 Chrysenes (a)
1008.00
1.10
15.32
1008.00
0.02
C2 Fluorenes (a)
686.00
0.19
2.65
686.00
0.00
C2-Fluoranthenes/Pyrenes
1.20
16.71
C2-Naphthalenes (a)
510.00
0.60
8.36
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
1.10
15.32
746.00
0.02
C3 Chrysenes (a)
1112.00
0.47
6.55
1112.00
0.01
C3 Fluorenes (a)
769.00
0.60
8.36
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.83
11.56
949.00
0.01
C3-Naphthalenes(a)
581.00
0.95
13.23
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
1.40
19.50
829.00
0.02
C4 Chrysenes (a)
1214.00
0.19
2.65
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.98
13.65
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
1.00
13.93
913.00
0.02
Chrysene ,a)
844.00
826
1.70
23.68
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.24
3.34
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.60
36.21
707.00
0.05
Fluorene ,a)
538.00
26,000.00
0.18
2.51
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.86
11.98
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.23
3.13
385.00
0.01
Perylene(a)
967.00
431.00
0.50
6.96
967.00
0.01
Phenanthrene 'd'
596
34300
1.30
18.11
596.00
0.03
Pyrene ,d'
697.00
9,090.00
2.00
27.86
697.00
0.04
ESBTU FCVi
0.46
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 3 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-22
Field Sample ID
RREC13-22-0103
Sample Depth
1-3
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.53
0.0853
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.14
1.64
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.16
1.88
447.00
0.00
Acenaphthene (a)
491.00
33400
0.28
3.28
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.11
1.29
452.00
0.00
Anthracene (a)
594.00
1300
0.57
6.68
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.30
26.96
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
2.30
26.96
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.10
24.62
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.60
18.76
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.00
11.72
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.10
24.62
981.00
0.03
CI Chrysenes (a)
929.00
2.00
23.45
929.00
0.03
CI Fluorenes(a)
611.00
0.37
4.34
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.30
38.69
770.00
0.05
CI-Naphthalenes (a)
444.00
0.22
2.58
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.30
50.41
670.00
0.08
C2 Chrysenes (a)
1008.00
2.50
29.31
1008.00
0.03
C2 Fluorenes (a)
686.00
1.20
14.07
686.00
0.02
C2-Fluoranthenes/Pyrenes
2.70
31.65
C2-Naphthalenes (a)
510.00
2.50
29.31
510.00
0.06
C2-Phenanthrenes/Anthracenes (a)
746
5.20
60.96
746.00
0.08
C3 Chrysenes (a)
1112.00
1.20
14.07
1112.00
0.01
C3 Fluorenes (a)
769.00
3.10
36.34
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
2.30
26.96
949.00
0.03
C3-Naphthalenes(a)
581.00
7.00
82.06
581.00
0.14
C3-Phenanthrenes/Anthracenes (a)
829.00
5.40
63.31
829.00
0.08
C4 Chrysenes (a)
1214.00
0.63
7.39
1214.00
0.01
C4-Naphthalenes (a)
657.00
6.30
73.86
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
3.90
45.72
913.00
0.05
Chrysene ,a)
844.00
826
2.20
25.79
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.31
3.63
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.90
45.72
707.00
0.06
Fluorene ,a)
538.00
26,000.00
0.42
4.92
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.96
11.25
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.26
2.99
385.00
0.01
Perylene(a)
967.00
431.00
0.71
8.32
967.00
0.01
Phenanthrene 'd'
596
34300
2.00
23.45
596.00
0.04
Pyrene ,d'
697.00
9,090.00
3.00
35.17
697.00
0.05
ESBTU FCVi
0.79
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 4 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-22
Field Sample ID
RREC13-22-0305
Sample Depth
3-5
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.59
0.0959
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.45
4.69
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.53
5.53
447.00
0.01
Acenaphthene (a)
491.00
33400
0.37
3.86
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.13
1.36
452.00
0.00
Anthracene (a)
594.00
1300
0.56
5.84
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.90
19.81
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.50
15.64
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.70
17.73
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.20
12.51
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.66
6.88
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.30
13.56
981.00
0.01
CI Chrysenes (a)
929.00
2.20
22.94
929.00
0.02
CI Fluorenes(a)
611.00
0.79
8.24
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.80
39.62
770.00
0.05
CI-Naphthalenes (a)
444.00
0.69
7.19
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
9.00
93.85
670.00
0.14
C2 Chrysenes (a)
1008.00
3.70
38.58
1008.00
0.04
C2 Fluorenes (a)
686.00
2.60
27.11
686.00
0.04
C2-Fluoranthenes/Pyrenes
4.10
42.75
C2-Naphthalenes (a)
510.00
7.00
72.99
510.00
0.14
C2-Phenanthrenes/Anthracenes (a)
746
12.00
125.13
746.00
0.17
C3 Chrysenes (a)
1112.00
2.10
21.90
1112.00
0.02
C3 Fluorenes (a)
769.00
6.20
64.65
769.00
0.08
C3-Fluoranthenes/Pyrenes
949.00
4.00
41.71
949.00
0.04
C3-Naphthalenes(a)
581.00
17.00
177.27
581.00
0.31
C3-Phenanthrenes/Anthracenes (a)
829.00
12.00
125.13
829.00
0.15
C4 Chrysenes (a)
1214.00
1.10
11.47
1214.00
0.01
C4-Naphthalenes (a)
657.00
15.00
156.41
657.00
0.24
C4-Phenanthrenes/Anthracenes (a)
913.00
8.10
84.46
913.00
0.09
Chrysene ,a)
844.00
826
2.10
21.90
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.18
1.88
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.00
41.71
707.00
0.06
Fluorene ,a)
538.00
26,000.00
0.45
4.69
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.62
6.47
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.33
3.39
385.00
0.01
Perylene(a)
967.00
431.00
0.57
5.94
967.00
0.01
Phenanthrene 'd'
596
34300
2.40
25.03
596.00
0.04
Pyrene ,d'
697.00
9,090.00
3.10
32.33
697.00
0.05
ESBTU FCVi
1.06
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 5 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-22
Field Sample ID
RREC13-22-0507
Sample Depth
5-7
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.55
0.0955
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.49
5.13
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.75
7.85
447.00
0.02
Acenaphthene (a)
491.00
33400
0.26
2.72
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.12
1.26
452.00
0.00
Anthracene (a)
594.00
1300
0.51
5.34
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.00
20.94
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.70
17.80
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.60
16.75
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.30
13.61
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.78
8.17
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.50
15.71
981.00
0.02
CI Chrysenes (a)
929.00
2.90
30.37
929.00
0.03
CI Fluorenes(a)
611.00
0.91
9.53
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.70
49.21
770.00
0.06
CI-Naphthalenes (a)
444.00
0.83
8.69
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
11.00
115.18
670.00
0.17
C2 Chrysenes (a)
1008.00
4.80
50.26
1008.00
0.05
C2 Fluorenes (a)
686.00
2.90
30.37
686.00
0.04
C2-Fluoranthenes/Pyrenes
5.30
55.50
C2-Naphthalenes (a)
510.00
8.90
93.19
510.00
0.18
C2-Phenanthrenes/Anthracenes (a)
746
14.00
146.60
746.00
0.20
C3 Chrysenes (a)
1112.00
2.50
26.18
1112.00
0.02
C3 Fluorenes (a)
769.00
6.50
68.06
769.00
0.09
C3-Fluoranthenes/Pyrenes
949.00
4.90
51.31
949.00
0.05
C3-Naphthalenes(a)
581.00
20.00
209.42
581.00
0.36
C3-Phenanthrenes/Anthracenes (a)
829.00
14.00
146.60
829.00
0.18
C4 Chrysenes (a)
1214.00
1.10
11.52
1214.00
0.01
C4-Naphthalenes (a)
657.00
16.00
167.54
657.00
0.26
C4-Phenanthrenes/Anthracenes (a)
913.00
8.00
83.77
913.00
0.09
Chrysene ,a)
844.00
826
2.00
20.94
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.23
2.41
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.90
40.84
707.00
0.06
Fluorene ,a)
538.00
26,000.00
0.43
4.50
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.70
7.33
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.32
3.35
385.00
0.01
Perylene(a)
967.00
431.00
0.56
5.86
967.00
0.01
Phenanthrene 'd'
596
34300
2.50
26.18
596.00
0.04
Pyrene ,d'
697.00
9,090.00
3.40
35.60
697.00
0.05
ESBTU FCVi
1.17
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 6 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-22
Field Sample ID
RREC13-22-0709
Sample Depth
7-9
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.3
0.083
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.27
3.25
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.30
3.61
447.00
0.01
Acenaphthene (a)
491.00
33400
0.34
4.10
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.10
1.20
452.00
0.00
Anthracene (a)
594.00
1300
0.80
9.64
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.90
34.94
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.30
27.71
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.10
25.30
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.60
19.28
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.00
12.05
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.30
27.71
981.00
0.03
CI Chrysenes (a)
929.00
2.40
28.92
929.00
0.03
CI Fluorenes(a)
611.00
0.45
5.42
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.70
56.63
770.00
0.07
CI-Naphthalenes (a)
444.00
0.38
4.58
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
5.40
65.06
670.00
0.10
C2 Chrysenes (a)
1008.00
2.80
33.73
1008.00
0.03
C2 Fluorenes (a)
686.00
1.10
13.25
686.00
0.02
C2-Fluoranthenes/Pyrenes
3.70
44.58
C2-Naphthalenes (a)
510.00
3.40
40.96
510.00
0.08
C2-Phenanthrenes/Anthracenes (a)
746
6.40
77.11
746.00
0.10
C3 Chrysenes (a)
1112.00
1.30
15.66
1112.00
0.01
C3 Fluorenes (a)
769.00
2.80
33.73
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
2.60
31.33
949.00
0.03
C3-Naphthalenes(a)
581.00
7.30
87.95
581.00
0.15
C3-Phenanthrenes/Anthracenes (a)
829.00
7.30
87.95
829.00
0.11
C4 Chrysenes (a)
1214.00
0.58
6.99
1214.00
0.01
C4-Naphthalenes (a)
657.00
6.80
81.93
657.00
0.12
C4-Phenanthrenes/Anthracenes (a)
913.00
5.20
62.65
913.00
0.07
Chrysene ,a)
844.00
826
2.90
34.94
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.31
3.73
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.30
63.86
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.76
9.16
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.97
11.69
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.47
5.66
385.00
0.01
Perylene(a)
967.00
431.00
0.69
8.31
967.00
0.01
Phenanthrene 'd'
596
34300
3.10
37.35
596.00
0.06
Pyrene ,d'
697.00
9,090.00
4.30
51.81
697.00
0.07
ESBTU FCVi
1.03
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 7 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-22
Field Sample ID
RREC13-22-0911
Sample Depth
9-11
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.36
0.0436
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.40
9.17
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.32
7.34
447.00
0.02
Acenaphthene (a)
491.00
33400
0.48
11.01
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.11
2.52
452.00
0.01
Anthracene (a)
594.00
1300
1.60
36.70
594.00
0.06
Benzo(a)anthracene (a)
841.00
4153
2.50
57.34
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
1.70
38.99
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
1.20
27.52
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.10
25.23
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
0.70
16.06
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.30
29.82
981.00
0.03
CI Chrysenes (a)
929.00
2.60
59.63
929.00
0.06
CI Fluorenes(a)
611.00
0.45
10.32
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.20
119.27
770.00
0.15
CI-Naphthalenes (a)
444.00
0.50
11.47
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
6.50
149.08
670.00
0.22
C2 Chrysenes (a)
1008.00
2.30
52.75
1008.00
0.05
C2 Fluorenes (a)
686.00
0.62
14.22
686.00
0.02
C2-Fluoranthenes/Pyrenes
2.90
66.51
C2-Naphthalenes (a)
510.00
4.40
100.92
510.00
0.20
C2-Phenanthrenes/Anthracenes (a)
746
4.10
94.04
746.00
0.13
C3 Chrysenes (a)
1112.00
1.10
25.23
1112.00
0.02
C3 Fluorenes (a)
769.00
1.10
25.23
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
1.80
41.28
949.00
0.04
C3-Naphthalenes(a)
581.00
4.40
100.92
581.00
0.17
C3-Phenanthrenes/Anthracenes (a)
829.00
4.10
94.04
829.00
0.11
C4 Chrysenes (a)
1214.00
0.52
11.93
1214.00
0.01
C4-Naphthalenes (a)
657.00
2.50
57.34
657.00
0.09
C4-Phenanthrenes/Anthracenes (a)
913.00
2.60
59.63
913.00
0.07
Chrysene ,a)
844.00
826
2.30
52.75
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.21
4.82
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.90
89.45
707.00
0.13
Fluorene ,a)
538.00
26,000.00
0.73
16.74
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.61
13.99
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.34
7.80
385.00
0.02
Perylene(a)
967.00
431.00
0.39
8.94
967.00
0.01
Phenanthrene 'd'
596
34300
4.00
91.74
596.00
0.15
Pyrene ,d'
697.00
9,090.00
4.30
98.62
697.00
0.14
ESBTU FCVi
1.61
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 8 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-23
Field Sample ID
RREC13-23-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.4
0.074
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.23
3.11
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.37
5.00
447.00
0.01
Acenaphthene (a)
491.00
33400
0.31
4.19
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.16
2.16
452.00
0.00
Anthracene (a)
594.00
1300
1.10
14.86
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.30
44.59
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
3.00
40.54
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.80
37.84
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.10
28.38
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.40
18.92
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
3.00
40.54
981.00
0.04
CI Chrysenes (a)
929.00
2.20
29.73
929.00
0.03
CI Fluorenes(a)
611.00
0.22
2.97
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.10
55.41
770.00
0.07
CI-Naphthalenes (a)
444.00
0.40
5.41
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.20
43.24
670.00
0.06
C2 Chrysenes (a)
1008.00
2.10
28.38
1008.00
0.03
C2 Fluorenes (a)
686.00
0.52
7.03
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.50
33.78
C2-Naphthalenes (a)
510.00
1.90
25.68
510.00
0.05
C2-Phenanthrenes/Anthracenes (a)
746
2.90
39.19
746.00
0.05
C3 Chrysenes (a)
1112.00
0.79
10.68
1112.00
0.01
C3 Fluorenes (a)
769.00
1.20
16.22
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.60
21.62
949.00
0.02
C3-Naphthalenes(a)
581.00
3.00
40.54
581.00
0.07
C3-Phenanthrenes/Anthracenes (a)
829.00
3.20
43.24
829.00
0.05
C4 Chrysenes (a)
1214.00
0.30
4.05
1214.00
0.00
C4-Naphthalenes (a)
657.00
2.40
32.43
657.00
0.05
C4-Phenanthrenes/Anthracenes (a)
913.00
2.20
29.73
913.00
0.03
Chrysene ,a)
844.00
826
3.10
41.89
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.38
5.14
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.40
72.97
707.00
0.10
Fluorene ,a)
538.00
26,000.00
0.47
6.35
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.20
16.22
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.33
4.46
385.00
0.01
Perylene(a)
967.00
431.00
0.83
11.22
967.00
0.01
Phenanthrene 'd'
596
34300
2.70
36.49
596.00
0.06
Pyrene ,d'
697.00
9,090.00
4.10
55.41
697.00
0.08
ESBTU FCVi
0.92
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 9 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-23
Field Sample ID
RREC13-23-0001
Sample Depth
0-1
Sample Date
11/2/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
13.2
0.132
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.38
2.88
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.54
4.09
447.00
0.01
Acenaphthene (a)
491.00
33400
0.32
2.42
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.19
1.40
452.00
0.00
Anthracene (a)
594.00
1300
0.55
4.17
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.90
14.39
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.90
14.39
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
2.10
15.91
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.60
12.12
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
1.70
12.88
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.30
9.85
981.00
0.01
CI Chrysenes (a)
929.00
2.00
15.15
929.00
0.02
CI Fluorenes(a)
611.00
0.39
2.95
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.60
19.70
770.00
0.03
CI-Naphthalenes (a)
444.00
0.68
5.15
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.70
28.03
670.00
0.04
C2 Chrysenes (a)
1008.00
1.70
12.88
1008.00
0.01
C2 Fluorenes (a)
686.00
0.96
7.27
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.10
15.91
C2-Naphthalenes (a)
510.00
3.90
29.55
510.00
0.06
C2-Phenanthrenes/Anthracenes (a)
746
4.20
31.82
746.00
0.04
C3 Chrysenes (a)
1112.00
0.82
6.21
1112.00
0.01
C3 Fluorenes (a)
769.00
2.10
15.91
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.60
12.12
949.00
0.01
C3-Naphthalenes(a)
581.00
6.20
46.97
581.00
0.08
C3-Phenanthrenes/Anthracenes (a)
829.00
3.90
29.55
829.00
0.04
C4 Chrysenes (a)
1214.00
0.40
3.03
1214.00
0.00
C4-Naphthalenes (a)
657.00
4.80
36.36
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
2.70
20.45
913.00
0.02
Chrysene ,a)
844.00
826
2.10
15.91
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.59
4.47
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.90
21.97
707.00
0.03
Fluorene ,a)
538.00
26,000.00
0.48
3.64
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.60
12.12
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.78
5.91
385.00
0.02
Perylene(a)
967.00
431.00
0.53
4.02
967.00
0.00
Phenanthrene 'd'
596
34300
2.40
18.18
596.00
0.03
Pyrene ,d'
697.00
9,090.00
3.60
27.27
697.00
0.04
ESBTU FCVi
0.46
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 10 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-23
Field Sample ID
RREC13-23-0103
Sample Depth
1-3
Sample Date
11/2/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
11.7
0.117
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.97
8.29
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.50
12.82
447.00
0.03
Acenaphthene (a)
491.00
33400
0.63
5.38
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.40
3.38
452.00
0.01
Anthracene (a)
594.00
1300
0.98
8.38
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.80
23.93
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
2.20
18.80
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
2.20
18.80
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.90
16.24
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
2.00
17.09
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.70
14.53
981.00
0.01
CI Chrysenes (a)
929.00
3.50
29.91
929.00
0.03
CI Fluorenes(a)
611.00
1.10
9.40
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.40
37.61
770.00
0.05
CI-Naphthalenes (a)
444.00
1.80
15.38
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
9.50
81.20
670.00
0.12
C2 Chrysenes (a)
1008.00
3.50
29.91
1008.00
0.03
C2 Fluorenes (a)
686.00
3.30
28.21
686.00
0.04
C2-Fluoranthenes/Pyrenes
4.80
41.03
C2-Naphthalenes (a)
510.00
12.00
102.56
510.00
0.20
C2-Phenanthrenes/Anthracenes (a)
746
12.00
102.56
746.00
0.14
C3 Chrysenes (a)
1112.00
2.10
17.95
1112.00
0.02
C3 Fluorenes (a)
769.00
7.80
66.67
769.00
0.09
C3-Fluoranthenes/Pyrenes
949.00
4.00
34.19
949.00
0.04
C3-Naphthalenes(a)
581.00
22.00
188.03
581.00
0.32
C3-Phenanthrenes/Anthracenes (a)
829.00
14.00
119.66
829.00
0.14
C4 Chrysenes (a)
1214.00
1.20
10.26
1214.00
0.01
C4-Naphthalenes (a)
657.00
18.00
153.85
657.00
0.23
C4-Phenanthrenes/Anthracenes (a)
913.00
8.90
76.07
913.00
0.08
Chrysene ,a)
844.00
826
3.10
26.50
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.63
5.38
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.30
36.75
707.00
0.05
Fluorene ,a)
538.00
26,000.00
1.00
8.55
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.70
14.53
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
2.00
17.09
385.00
0.04
Perylene(a)
967.00
431.00
0.72
6.15
967.00
0.01
Phenanthrene 'd'
596
34300
4.30
36.75
596.00
0.06
Pyrene ,d'
697.00
9,090.00
5.80
49.57
697.00
0.07
ESBTU FCVi
1.13
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 11 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-23
Field Sample ID
RREC13-23-0305
Sample Depth
3-5
Sample Date
11/2/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
1.57
0.0157
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.00
63.69
446.00
0.14
2-Methylnaphthalene
447.00
154800
1.50
95.54
447.00
0.21
Acenaphthene (a)
491.00
33400
0.65
41.40
491.00
0.08
Acenaphthylene (a)
452.00
24000
0.49
30.89
452.00
0.07
Anthracene (a)
594.00
1300
1.30
82.80
594.00
0.14
Benzo(a)anthracene (a)
841.00
4153
3.00
191.08
841.00
0.23
Benzo(a)pyrene (a)
965.00
3840
2.50
159.24
965.00
0.17
Benzo(b)fluoranthene (a)
979.00
2169
2.20
140.13
979.00
0.14
Benzo(e)pyrene (a)
967.00
4300
2.10
133.76
967.00
0.14
Benzo(g,h,i)perylene (a)
1095.00
648
2.10
133.76
1095.00
0.12
Benzo(k)fluoranthene (a)
981.00
1220
1.90
121.02
981.00
0.12
CI Chrysenes (a)
929.00
4.00
254.78
929.00
0.27
CI Fluorenes(a)
611.00
1.10
70.06
611.00
0.11
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.70
299.36
770.00
0.39
CI-Naphthalenes (a)
444.00
1.80
114.65
444.00
0.26
Cl-Phenanthrenes/Anthracenes (a)
670.00
10.00
636.94
670.00
0.95
C2 Chrysenes (a)
1008.00
4.10
261.15
1008.00
0.26
C2 Fluorenes (a)
686.00
3.10
197.45
686.00
0.29
C2-Fluoranthenes/Pyrenes
5.00
318.47
C2-Naphthalenes (a)
510.00
13.00
828.03
510.00
1.62
C2-Phenanthrenes/Anthracenes (a)
746
12.00
764.33
746.00
1.02
C3 Chrysenes (a)
1112.00
2.20
140.13
1112.00
0.13
C3 Fluorenes (a)
769.00
7.10
452.23
769.00
0.59
C3-Fluoranthenes/Pyrenes
949.00
4.00
254.78
949.00
0.27
C3-Naphthalenes(a)
581.00
22.00
1401.27
581.00
2.41
C3-Phenanthrenes/Anthracenes (a)
829.00
12.00
764.33
829.00
0.92
C4 Chrysenes (a)
1214.00
1.10
70.06
1214.00
0.06
C4-Naphthalenes (a)
657.00
16.00
1019.11
657.00
1.55
C4-Phenanthrenes/Anthracenes (a)
913.00
7.80
496.82
913.00
0.54
Chrysene ,a)
844.00
826
3.30
210.19
844.00
0.25
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.68
43.31
1123.00
0.04
Fluoranthene ,a)
707.00
23,870.00
4.40
280.25
707.00
0.40
Fluorene ,a)
538.00
26,000.00
0.98
62.42
538.00
0.12
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.70
108.28
1115.00
0.10
Naphthalene ,a)
385.00
61,700.00
1.30
82.80
385.00
0.22
Perylene(a)
967.00
431.00
0.73
46.50
967.00
0.05
Phenanthrene 'd'
596
34300
4.70
299.36
596.00
0.50
Pyrene ,d'
697.00
9,090.00
5.70
363.06
697.00
0.52
ESBTU FCVi
8.22
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 12 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-23
Field Sample ID
RREC13-23-0507
Sample Depth
5-7
Sample Date
11/2/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.58
0.0258
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.60
62.02
446.00
0.14
2-Methylnaphthalene
447.00
154800
2.60
100.78
447.00
0.23
Acenaphthene (a)
491.00
33400
2.20
85.27
491.00
0.17
Acenaphthylene (a)
452.00
24000
0.55
21.32
452.00
0.05
Anthracene (a)
594.00
1300
1.80
69.77
594.00
0.12
Benzo(a)anthracene (a)
841.00
4153
3.30
127.91
841.00
0.15
Benzo(a)pyrene (a)
965.00
3840
2.50
96.90
965.00
0.10
Benzo(b)fluoranthene (a)
979.00
2169
2.30
89.15
979.00
0.09
Benzo(e)pyrene (a)
967.00
4300
2.10
81.40
967.00
0.08
Benzo(g,h,i)perylene (a)
1095.00
648
1.90
73.64
1095.00
0.07
Benzo(k)fluoranthene (a)
981.00
1220
2.40
93.02
981.00
0.09
CI Chrysenes (a)
929.00
3.80
147.29
929.00
0.16
CI Fluorenes(a)
611.00
1.00
38.76
611.00
0.06
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.20
201.55
770.00
0.26
CI-Naphthalenes (a)
444.00
3.10
120.16
444.00
0.27
Cl-Phenanthrenes/Anthracenes (a)
670.00
9.70
375.97
670.00
0.56
C2 Chrysenes (a)
1008.00
4.00
155.04
1008.00
0.15
C2 Fluorenes (a)
686.00
2.50
96.90
686.00
0.14
C2-Fluoranthenes/Pyrenes
4.70
182.17
C2-Naphthalenes (a)
510.00
11.00
426.36
510.00
0.84
C2-Phenanthrenes/Anthracenes (a)
746
11.00
426.36
746.00
0.57
C3 Chrysenes (a)
1112.00
2.00
77.52
1112.00
0.07
C3 Fluorenes (a)
769.00
5.10
197.67
769.00
0.26
C3-Fluoranthenes/Pyrenes
949.00
3.50
135.66
949.00
0.14
C3-Naphthalenes(a)
581.00
18.00
697.67
581.00
1.20
C3-Phenanthrenes/Anthracenes (a)
829.00
9.90
383.72
829.00
0.46
C4 Chrysenes (a)
1214.00
1.00
38.76
1214.00
0.03
C4-Naphthalenes (a)
657.00
13.00
503.88
657.00
0.77
C4-Phenanthrenes/Anthracenes (a)
913.00
6.60
255.81
913.00
0.28
Chrysene ,a)
844.00
826
3.70
143.41
844.00
0.17
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.57
22.09
1123.00
0.02
Fluoranthene ,a)
707.00
23,870.00
5.20
201.55
707.00
0.29
Fluorene ,a)
538.00
26,000.00
2.40
93.02
538.00
0.17
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.60
62.02
1115.00
0.06
Naphthalene ,a)
385.00
61,700.00
1.40
54.26
385.00
0.14
Perylene(a)
967.00
431.00
0.75
29.07
967.00
0.03
Phenanthrene 'd'
596
34300
6.20
240.31
596.00
0.40
Pyrene ,d'
697.00
9,090.00
6.20
240.31
697.00
0.34
ESBTU FCVi
5.15
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 13 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-23
Field Sample ID
RREC13-23-0709
Sample Depth
7-9
Sample Date
11/2/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.86
0.0986
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.70
7.10
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.70
7.10
447.00
0.02
Acenaphthene (a)
491.00
33400
0.59
5.98
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.70
7.10
452.00
0.02
Anthracene (a)
594.00
1300
2.00
20.28
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.80
38.54
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
3.20
32.45
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.70
27.38
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.40
24.34
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
2.20
22.31
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.90
29.41
981.00
0.03
CI Chrysenes (a)
929.00
3.70
37.53
929.00
0.04
CI Fluorenes(a)
611.00
0.67
6.80
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.80
48.68
770.00
0.06
CI-Naphthalenes (a)
444.00
1.00
10.14
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.80
79.11
670.00
0.12
C2 Chrysenes (a)
1008.00
3.60
36.51
1008.00
0.04
C2 Fluorenes (a)
686.00
1.80
18.26
686.00
0.03
C2-Fluoranthenes/Pyrenes
4.20
42.60
C2-Naphthalenes (a)
510.00
5.90
59.84
510.00
0.12
C2-Phenanthrenes/Anthracenes (a)
746
10.00
101.42
746.00
0.14
C3 Chrysenes (a)
1112.00
1.70
17.24
1112.00
0.02
C3 Fluorenes (a)
769.00
4.40
44.62
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
3.70
37.53
949.00
0.04
C3-Naphthalenes(a)
581.00
12.00
121.70
581.00
0.21
C3-Phenanthrenes/Anthracenes (a)
829.00
10.00
101.42
829.00
0.12
C4 Chrysenes (a)
1214.00
0.95
9.63
1214.00
0.01
C4-Naphthalenes (a)
657.00
11.00
111.56
657.00
0.17
C4-Phenanthrenes/Anthracenes (a)
913.00
6.90
69.98
913.00
0.08
Chrysene ,a)
844.00
826
4.00
40.57
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.62
6.29
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.70
67.95
707.00
0.10
Fluorene ,a)
538.00
26,000.00
1.60
16.23
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.00
20.28
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.70
7.10
385.00
0.02
Perylene(a)
967.00
431.00
0.97
9.84
967.00
0.01
Phenanthrene 'd'
596
34300
6.10
61.87
596.00
0.10
Pyrene ,d'
697.00
9,090.00
7.00
70.99
697.00
0.10
ESBTU FCVi
1.29
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 14 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-23
Field Sample ID
RREC13-23-0911
Sample Depth
9-11
Sample Date
11/2/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.3
0.103
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.70
6.80
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.70
6.80
447.00
0.02
Acenaphthene (a)
491.00
33400
0.76
7.38
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.70
6.80
452.00
0.02
Anthracene (a)
594.00
1300
2.30
22.33
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
4.50
43.69
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
3.80
36.89
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
3.30
32.04
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.80
27.18
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
2.70
26.21
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.80
27.18
981.00
0.03
CI Chrysenes (a)
929.00
3.80
36.89
929.00
0.04
CI Fluorenes(a)
611.00
0.81
7.86
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.50
53.40
770.00
0.07
CI-Naphthalenes (a)
444.00
1.30
12.62
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.40
81.55
670.00
0.12
C2 Chrysenes (a)
1008.00
3.70
35.92
1008.00
0.04
C2 Fluorenes (a)
686.00
1.80
17.48
686.00
0.03
C2-Fluoranthenes/Pyrenes
4.20
40.78
C2-Naphthalenes (a)
510.00
6.70
65.05
510.00
0.13
C2-Phenanthrenes/Anthracenes (a)
746
10.00
97.09
746.00
0.13
C3 Chrysenes (a)
1112.00
1.70
16.50
1112.00
0.01
C3 Fluorenes (a)
769.00
4.40
42.72
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
3.60
34.95
949.00
0.04
C3-Naphthalenes(a)
581.00
13.00
126.21
581.00
0.22
C3-Phenanthrenes/Anthracenes (a)
829.00
9.90
96.12
829.00
0.12
C4 Chrysenes (a)
1214.00
0.95
9.22
1214.00
0.01
C4-Naphthalenes (a)
657.00
11.00
106.80
657.00
0.16
C4-Phenanthrenes/Anthracenes (a)
913.00
6.70
65.05
913.00
0.07
Chrysene ,a)
844.00
826
4.60
44.66
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.78
7.57
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
8.20
79.61
707.00
0.11
Fluorene ,a)
538.00
26,000.00
2.60
25.24
538.00
0.05
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.40
23.30
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.70
6.80
385.00
0.02
Perylene(a)
967.00
431.00
1.10
10.68
967.00
0.01
Phenanthrene 'd'
596
34300
6.70
65.05
596.00
0.11
Pyrene ,d'
697.00
9,090.00
8.30
80.58
697.00
0.12
ESBTU FCVi
1.37
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 15 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-24
Field Sample ID
RREC13-24-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.59
0.0259
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.65
25.10
446.00
0.06
2-Methylnaphthalene
447.00
154800
0.65
25.10
447.00
0.06
Acenaphthene (a)
491.00
33400
0.94
36.29
491.00
0.07
Acenaphthylene (a)
452.00
24000
0.65
25.10
452.00
0.06
Anthracene (a)
594.00
1300
2.30
88.80
594.00
0.15
Benzo(a)anthracene (a)
841.00
4153
3.50
135.14
841.00
0.16
Benzo(a)pyrene (a)
965.00
3840
2.60
100.39
965.00
0.10
Benzo(b)fluoranthene (a)
979.00
2169
1.90
73.36
979.00
0.07
Benzo(e)pyrene (a)
967.00
4300
1.60
61.78
967.00
0.06
Benzo(g,h,i)perylene (a)
1095.00
648
0.65
25.10
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.40
92.66
981.00
0.09
CI Chrysenes (a)
929.00
2.10
81.08
929.00
0.09
CI Fluorenes(a)
611.00
0.32
12.36
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.70
181.47
770.00
0.24
CI-Naphthalenes (a)
444.00
0.60
23.17
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.80
185.33
670.00
0.28
C2 Chrysenes (a)
1008.00
1.30
50.19
1008.00
0.05
C2 Fluorenes (a)
686.00
0.35
13.51
686.00
0.02
C2-Fluoranthenes/Pyrenes
1.90
73.36
C2-Naphthalenes (a)
510.00
2.20
84.94
510.00
0.17
C2-Phenanthrenes/Anthracenes (a)
746
2.20
84.94
746.00
0.11
C3 Chrysenes (a)
1112.00
0.46
17.76
1112.00
0.02
C3 Fluorenes (a)
769.00
0.44
16.99
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
0.85
32.82
949.00
0.03
C3-Naphthalenes(a)
581.00
2.40
92.66
581.00
0.16
C3-Phenanthrenes/Anthracenes (a)
829.00
1.50
57.92
829.00
0.07
C4 Chrysenes (a)
1214.00
0.21
8.11
1214.00
0.01
C4-Naphthalenes (a)
657.00
0.97
37.45
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
0.79
30.50
913.00
0.03
Chrysene ,a)
844.00
826
3.10
119.69
844.00
0.14
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.31
11.97
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
8.00
308.88
707.00
0.44
Fluorene ,a)
538.00
26,000.00
1.60
61.78
538.00
0.11
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.97
37.45
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
0.65
25.10
385.00
0.07
Perylene(a)
967.00
431.00
0.63
24.32
967.00
0.03
Phenanthrene 'd'
596
34300
7.00
270.27
596.00
0.45
Pyrene ,d'
697.00
9,090.00
5.20
200.77
697.00
0.29
ESBTU FCVi
3.16
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 16 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-24
Field Sample ID
RREC13-24-0001
Sample Depth
0-1
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.3
0.023
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.09
4.00
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.25
10.87
447.00
0.02
Acenaphthene (a)
491.00
33400
1.20
52.17
491.00
0.11
Acenaphthylene (a)
452.00
24000
0.04
1.78
452.00
0.00
Anthracene (a)
594.00
1300
0.97
42.17
594.00
0.07
Benzo(a)anthracene (a)
841.00
4153
1.30
56.52
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
0.87
37.83
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
0.86
37.39
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
0.55
23.91
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.36
15.65
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
0.77
33.48
981.00
0.03
CI Chrysenes (a)
929.00
0.67
29.13
929.00
0.03
CI Fluorenes(a)
611.00
0.14
6.09
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.70
73.91
770.00
0.10
CI-Naphthalenes (a)
444.00
0.11
4.78
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.80
78.26
670.00
0.12
C2 Chrysenes (a)
1008.00
0.44
19.13
1008.00
0.02
C2 Fluorenes (a)
686.00
0.11
4.78
686.00
0.01
C2-Fluoranthenes/Pyrenes
0.64
27.83
C2-Naphthalenes (a)
510.00
0.67
29.13
510.00
0.06
C2-Phenanthrenes/Anthracenes (a)
746
0.71
30.87
746.00
0.04
C3 Chrysenes (a)
1112.00
0.15
6.52
1112.00
0.01
C3 Fluorenes (a)
769.00
0.13
5.65
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.26
11.30
949.00
0.01
C3-Naphthalenes(a)
581.00
0.83
36.09
581.00
0.06
C3-Phenanthrenes/Anthracenes (a)
829.00
0.44
19.13
829.00
0.02
C4 Chrysenes (a)
1214.00
0.06
2.48
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.26
11.30
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.24
10.43
913.00
0.01
Chrysene ,a)
844.00
826
1.10
47.83
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.10
4.35
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.70
160.87
707.00
0.23
Fluorene ,a)
538.00
26,000.00
1.30
56.52
538.00
0.11
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.34
14.78
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.25
10.87
385.00
0.03
Perylene(a)
967.00
431.00
0.28
12.17
967.00
0.01
Phenanthrene 'd'
596
34300
4.30
186.96
596.00
0.31
Pyrene ,d'
697.00
9,090.00
2.30
100.00
697.00
0.14
ESBTU FCVi
1.62
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 17 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-24
Field Sample ID
RREC13-24-0103
Sample Depth
1-3
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.02
0.0302
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.04
1.39
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.11
3.48
447.00
0.01
Acenaphthene (a)
491.00
33400
0.35
11.59
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.03
0.89
452.00
0.00
Anthracene (a)
594.00
1300
0.32
10.60
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
0.48
15.89
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
0.29
9.60
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
0.32
10.60
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.22
7.28
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.15
4.97
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.32
10.60
981.00
0.01
CI Chrysenes (a)
929.00
0.28
9.27
929.00
0.01
CI Fluorenes(a)
611.00
0.05
1.66
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.65
21.52
770.00
0.03
CI-Naphthalenes (a)
444.00
0.06
1.99
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.63
20.86
670.00
0.03
C2 Chrysenes (a)
1008.00
0.21
6.95
1008.00
0.01
C2 Fluorenes (a)
686.00
0.04
1.46
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.29
9.60
C2-Naphthalenes (a)
510.00
0.32
10.60
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
0.30
9.93
746.00
0.01
C3 Chrysenes (a)
1112.00
0.08
2.48
1112.00
0.00
C3 Fluorenes (a)
769.00
0.07
2.25
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.14
4.64
949.00
0.00
C3-Naphthalenes(a)
581.00
0.37
12.25
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.23
7.62
829.00
0.01
C4 Chrysenes (a)
1214.00
0.04
1.36
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.15
4.97
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.16
5.30
913.00
0.01
Chrysene ,a)
844.00
826
0.45
14.90
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.04
1.39
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.20
39.74
707.00
0.06
Fluorene ,a)
538.00
26,000.00
0.23
7.62
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.14
4.64
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.11
3.48
385.00
0.01
Perylene(a)
967.00
431.00
0.11
3.64
967.00
0.00
Phenanthrene 'd'
596
34300
1.20
39.74
596.00
0.07
Pyrene ,d'
697.00
9,090.00
0.82
27.15
697.00
0.04
ESBTU FCVi
0.41
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 18 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-25
Field Sample ID
RREC13-25-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.09
0.0309
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.16
5.02
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.16
5.02
447.00
0.01
Acenaphthene (a)
491.00
33400
0.12
3.88
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.16
5.02
452.00
0.01
Anthracene (a)
594.00
1300
0.39
12.62
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
1.40
45.31
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
1.30
42.07
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
1.10
35.60
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
0.91
29.45
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
0.63
20.39
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.30
42.07
981.00
0.04
CI Chrysenes (a)
929.00
0.78
25.24
929.00
0.03
CI Fluorenes(a)
611.00
0.06
1.84
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.50
48.54
770.00
0.06
CI-Naphthalenes (a)
444.00
0.13
4.21
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.91
29.45
670.00
0.04
C2 Chrysenes (a)
1008.00
0.51
16.50
1008.00
0.02
C2 Fluorenes (a)
686.00
0.08
2.52
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.75
24.27
C2-Naphthalenes (a)
510.00
0.36
11.65
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
0.57
18.45
746.00
0.02
C3 Chrysenes (a)
1112.00
0.21
6.80
1112.00
0.01
C3 Fluorenes (a)
769.00
0.14
4.53
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.34
11.00
949.00
0.01
C3-Naphthalenes(a)
581.00
0.45
14.56
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
0.43
13.92
829.00
0.02
C4 Chrysenes (a)
1214.00
0.06
1.81
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.24
7.77
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.27
8.74
913.00
0.01
Chrysene ,a)
844.00
826
1.30
42.07
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.15
4.85
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.40
77.67
707.00
0.11
Fluorene ,a)
538.00
26,000.00
0.17
5.50
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.54
17.48
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.16
5.02
385.00
0.01
Perylene(a)
967.00
431.00
0.31
10.03
967.00
0.01
Phenanthrene 'd'
596
34300
1.10
35.60
596.00
0.06
Pyrene ,d'
697.00
9,090.00
1.80
58.25
697.00
0.08
ESBTU FCVi
0.79
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 19 of85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-25
Field Sample ID
RREC13-25-0001
Sample Depth
0-1
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.81
0.0881
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.49
5.56
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.65
7.38
447.00
0.02
Acenaphthene (a)
491.00
33400
0.80
9.08
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.45
5.11
452.00
0.01
Anthracene (a)
594.00
1300
2.10
23.84
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
5.70
64.70
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
5.10
57.89
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
4.00
45.40
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
3.10
35.19
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.30
26.11
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
3.80
43.13
981.00
0.04
CI Chrysenes (a)
929.00
3.90
44.27
929.00
0.05
CI Fluorenes(a)
611.00
0.74
8.40
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
7.80
88.54
770.00
0.11
CI-Naphthalenes (a)
444.00
0.74
8.40
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
9.50
107.83
670.00
0.16
C2 Chrysenes (a)
1008.00
2.50
28.38
1008.00
0.03
C2 Fluorenes (a)
686.00
2.00
22.70
686.00
0.03
C2-Fluoranthenes/Pyrenes
4.50
51.08
C2-Naphthalenes (a)
510.00
5.00
56.75
510.00
0.11
C2-Phenanthrenes/Anthracenes (a)
746
9.00
102.16
746.00
0.14
C3 Chrysenes (a)
1112.00
1.00
11.35
1112.00
0.01
C3 Fluorenes (a)
769.00
4.20
47.67
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
2.70
30.65
949.00
0.03
C3-Naphthalenes(a)
581.00
13.00
147.56
581.00
0.25
C3-Phenanthrenes/Anthracenes (a)
829.00
7.70
87.40
829.00
0.11
C4 Chrysenes (a)
1214.00
0.50
5.68
1214.00
0.00
C4-Naphthalenes (a)
657.00
9.20
104.43
657.00
0.16
C4-Phenanthrenes/Anthracenes (a)
913.00
4.70
53.35
913.00
0.06
Chrysene ,a)
844.00
826
5.40
61.29
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.61
6.92
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
11.00
124.86
707.00
0.18
Fluorene ,a)
538.00
26,000.00
1.10
12.49
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.90
21.57
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.65
7.38
385.00
0.02
Perylene(a)
967.00
431.00
1.30
14.76
967.00
0.02
Phenanthrene 'd'
596
34300
6.60
74.91
596.00
0.13
Pyrene ,d'
697.00
9,090.00
7.90
89.67
697.00
0.13
ESBTU FCVi
1.63
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 20 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-25
Field Sample ID
RREC13-25-0103
Sample Depth
1-3
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
13.5
0.135
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.63
4.67
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.50
3.70
447.00
0.01
Acenaphthene (a)
491.00
33400
0.67
4.96
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.47
3.48
452.00
0.01
Anthracene (a)
594.00
1300
1.50
11.11
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
5.20
38.52
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
4.60
34.07
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
3.50
25.93
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.90
21.48
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.90
14.07
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
3.80
28.15
981.00
0.03
CI Chrysenes (a)
929.00
3.50
25.93
929.00
0.03
CI Fluorenes(a)
611.00
0.97
7.19
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
7.70
57.04
770.00
0.07
CI-Naphthalenes (a)
444.00
1.10
8.15
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
11.00
81.48
670.00
0.12
C2 Chrysenes (a)
1008.00
3.30
24.44
1008.00
0.02
C2 Fluorenes (a)
686.00
2.70
20.00
686.00
0.03
C2-Fluoranthenes/Pyrenes
4.90
36.30
C2-Naphthalenes (a)
510.00
7.80
57.78
510.00
0.11
C2-Phenanthrenes/Anthracenes (a)
746
11.00
81.48
746.00
0.11
C3 Chrysenes (a)
1112.00
1.20
8.89
1112.00
0.01
C3 Fluorenes (a)
769.00
5.00
37.04
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
3.20
23.70
949.00
0.03
C3-Naphthalenes(a)
581.00
19.00
140.74
581.00
0.24
C3-Phenanthrenes/Anthracenes (a)
829.00
9.50
70.37
829.00
0.08
C4 Chrysenes (a)
1214.00
0.64
4.74
1214.00
0.00
C4-Naphthalenes (a)
657.00
13.00
96.30
657.00
0.15
C4-Phenanthrenes/Anthracenes (a)
913.00
6.20
45.93
913.00
0.05
Chrysene ,a)
844.00
826
4.90
36.30
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.51
3.78
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
8.90
65.93
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.82
6.07
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.70
12.59
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.40
10.37
385.00
0.03
Perylene(a)
967.00
431.00
1.30
9.63
967.00
0.01
Phenanthrene 'd'
596
34300
5.60
41.48
596.00
0.07
Pyrene ,d'
697.00
9,090.00
7.40
54.81
697.00
0.08
ESBTU FCVi
1.08
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 21 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-25
Field Sample ID
RREC13-25-0305
Sample Depth
3-5
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.18
0.0718
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.53
7.38
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.70
9.75
447.00
0.02
Acenaphthene (a)
491.00
33400
0.52
7.24
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.23
3.20
452.00
0.01
Anthracene (a)
594.00
1300
0.85
11.84
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.60
36.21
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.30
32.03
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.00
27.86
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.50
20.89
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.91
12.67
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.70
23.68
981.00
0.02
CI Chrysenes (a)
929.00
2.30
32.03
929.00
0.03
CI Fluorenes(a)
611.00
0.77
10.72
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.90
68.25
770.00
0.09
CI-Naphthalenes (a)
444.00
0.87
12.12
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.40
116.99
670.00
0.17
C2 Chrysenes (a)
1008.00
2.10
29.25
1008.00
0.03
C2 Fluorenes (a)
686.00
2.10
29.25
686.00
0.04
C2-Fluoranthenes/Pyrenes
3.50
48.75
C2-Naphthalenes (a)
510.00
6.80
94.71
510.00
0.19
C2-Phenanthrenes/Anthracenes (a)
746
8.00
111.42
746.00
0.15
C3 Chrysenes (a)
1112.00
0.95
13.23
1112.00
0.01
C3 Fluorenes (a)
769.00
4.00
55.71
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
2.30
32.03
949.00
0.03
C3-Naphthalenes(a)
581.00
16.00
222.84
581.00
0.38
C3-Phenanthrenes/Anthracenes (a)
829.00
7.50
104.46
829.00
0.13
C4 Chrysenes (a)
1214.00
0.52
7.24
1214.00
0.01
C4-Naphthalenes (a)
657.00
11.00
153.20
657.00
0.23
C4-Phenanthrenes/Anthracenes (a)
913.00
5.10
71.03
913.00
0.08
Chrysene ,a)
844.00
826
2.70
37.60
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.24
3.34
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.70
65.46
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.60
8.36
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.77
10.72
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.10
15.32
385.00
0.04
Perylene(a)
967.00
431.00
0.61
8.50
967.00
0.01
Phenanthrene 'd'
596
34300
3.70
51.53
596.00
0.09
Pyrene ,d'
697.00
9,090.00
4.20
58.50
697.00
0.08
ESBTU FCVi
1.34
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 22 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-25
Field Sample ID
RREC13-25-0507
Sample Depth
5-7
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.65
0.0765
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.85
11.11
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.40
18.30
447.00
0.04
Acenaphthene (a)
491.00
33400
0.40
5.23
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.25
3.27
452.00
0.01
Anthracene (a)
594.00
1300
1.10
14.38
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.60
33.99
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.10
27.45
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
1.80
23.53
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.50
19.61
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.78
10.20
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.90
24.84
981.00
0.03
CI Chrysenes (a)
929.00
4.00
52.29
929.00
0.06
CI Fluorenes(a)
611.00
1.40
18.30
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.00
78.43
770.00
0.10
CI-Naphthalenes (a)
444.00
1.50
19.61
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
15.00
196.08
670.00
0.29
C2 Chrysenes (a)
1008.00
5.20
67.97
1008.00
0.07
C2 Fluorenes (a)
686.00
4.00
52.29
686.00
0.08
C2-Fluoranthenes/Pyrenes
6.70
87.58
C2-Naphthalenes (a)
510.00
13.00
169.93
510.00
0.33
C2-Phenanthrenes/Anthracenes (a)
746
16.00
209.15
746.00
0.28
C3 Chrysenes (a)
1112.00
2.60
33.99
1112.00
0.03
C3 Fluorenes (a)
769.00
7.30
95.42
769.00
0.12
C3-Fluoranthenes/Pyrenes
949.00
5.30
69.28
949.00
0.07
C3-Naphthalenes(a)
581.00
30.00
392.16
581.00
0.67
C3-Phenanthrenes/Anthracenes (a)
829.00
14.00
183.01
829.00
0.22
C4 Chrysenes (a)
1214.00
1.00
13.07
1214.00
0.01
C4-Naphthalenes (a)
657.00
19.00
248.37
657.00
0.38
C4-Phenanthrenes/Anthracenes (a)
913.00
8.70
113.73
913.00
0.12
Chrysene ,a)
844.00
826
3.00
39.22
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.20
2.61
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.90
64.05
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.65
8.50
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.70
9.15
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.50
19.61
385.00
0.05
Perylene(a)
967.00
431.00
0.49
6.41
967.00
0.01
Phenanthrene 'd'
596
34300
4.40
57.52
596.00
0.10
Pyrene ,d'
697.00
9,090.00
3.90
50.98
697.00
0.07
ESBTU FCVi
1.83
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 23 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-25
Field Sample ID
RREC13-25-0710
Sample Depth
7-10
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.73
0.0873
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.58
6.64
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.47
5.33
447.00
0.01
Acenaphthene (a)
491.00
33400
0.48
5.50
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.25
2.86
452.00
0.01
Anthracene (a)
594.00
1300
4.60
52.69
594.00
0.09
Benzo(a)anthracene (a)
841.00
4153
3.90
44.67
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
3.00
34.36
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.30
26.35
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.90
21.76
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.20
13.75
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.50
28.64
981.00
0.03
CI Chrysenes (a)
929.00
3.50
40.09
929.00
0.04
CI Fluorenes(a)
611.00
1.00
11.45
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
7.00
80.18
770.00
0.10
CI-Naphthalenes (a)
444.00
1.00
11.45
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
12.00
137.46
670.00
0.21
C2 Chrysenes (a)
1008.00
3.60
41.24
1008.00
0.04
C2 Fluorenes (a)
686.00
2.70
30.93
686.00
0.05
C2-Fluoranthenes/Pyrenes
5.30
60.71
C2-Naphthalenes (a)
510.00
9.10
104.24
510.00
0.20
C2-Phenanthrenes/Anthracenes (a)
746
12.00
137.46
746.00
0.18
C3 Chrysenes (a)
1112.00
1.60
18.33
1112.00
0.02
C3 Fluorenes (a)
769.00
4.90
56.13
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
3.50
40.09
949.00
0.04
C3-Naphthalenes(a)
581.00
23.00
263.46
581.00
0.45
C3-Phenanthrenes/Anthracenes (a)
829.00
11.00
126.00
829.00
0.15
C4 Chrysenes (a)
1214.00
0.71
8.13
1214.00
0.01
C4-Naphthalenes (a)
657.00
15.00
171.82
657.00
0.26
C4-Phenanthrenes/Anthracenes (a)
913.00
6.00
68.73
913.00
0.08
Chrysene ,a)
844.00
826
3.60
41.24
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.32
3.67
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
7.60
87.06
707.00
0.12
Fluorene ,a)
538.00
26,000.00
1.20
13.75
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.00
11.45
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.10
12.60
385.00
0.03
Perylene(a)
967.00
431.00
0.80
9.16
967.00
0.01
Phenanthrene 'd'
596
34300
6.80
77.89
596.00
0.13
Pyrene ,d'
697.00
9,090.00
6.40
73.31
697.00
0.11
ESBTU FCVi
1.63
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 24 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-26
Field Sample ID
RREC13-26-SURF
Sample Depth
0-0.5
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.09
0.0609
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.20
3.28
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.65
10.67
447.00
0.02
Acenaphthene (a)
491.00
33400
0.66
10.84
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.12
1.97
452.00
0.00
Anthracene (a)
594.00
1300
1.10
18.06
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
4.10
67.32
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
3.60
59.11
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
3.80
62.40
979.00
0.06
Benzo(e)pyrene (a)
967.00
4300
2.50
41.05
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
1.90
31.20
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
3.10
50.90
981.00
0.05
CI Chrysenes (a)
929.00
2.30
37.77
929.00
0.04
CI Fluorenes(a)
611.00
0.25
4.11
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.10
67.32
770.00
0.09
CI-Naphthalenes (a)
444.00
0.32
5.25
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.30
54.19
670.00
0.08
C2 Chrysenes (a)
1008.00
1.50
24.63
1008.00
0.02
C2 Fluorenes (a)
686.00
0.52
8.54
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.70
44.33
C2-Naphthalenes (a)
510.00
1.40
22.99
510.00
0.05
C2-Phenanthrenes/Anthracenes (a)
746
2.60
42.69
746.00
0.06
C3 Chrysenes (a)
1112.00
0.67
11.00
1112.00
0.01
C3 Fluorenes (a)
769.00
1.10
18.06
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.50
24.63
949.00
0.03
C3-Naphthalenes(a)
581.00
3.80
62.40
581.00
0.11
C3-Phenanthrenes/Anthracenes (a)
829.00
2.50
41.05
829.00
0.05
C4 Chrysenes (a)
1214.00
0.28
4.60
1214.00
0.00
C4-Naphthalenes (a)
657.00
2.50
41.05
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
1.70
27.91
913.00
0.03
Chrysene ,a)
844.00
826
4.20
68.97
844.00
0.08
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.46
7.55
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
8.60
141.22
707.00
0.20
Fluorene ,a)
538.00
26,000.00
0.66
10.84
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.60
26.27
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.65
10.67
385.00
0.03
Perylene(a)
967.00
431.00
1.00
16.42
967.00
0.02
Phenanthrene 'd'
596
34300
5.20
85.39
596.00
0.14
Pyrene ,d'
697.00
9,090.00
6.00
98.52
697.00
0.14
ESBTU FCVi
1.39
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 25 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-26
Field Sample ID
RREC13-26-0001
Sample Depth
0-1
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
11.6
0.116
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.81
6.98
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.65
5.60
447.00
0.01
Acenaphthene (a)
491.00
33400
1.10
9.48
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.32
2.76
452.00
0.01
Anthracene (a)
594.00
1300
1.40
12.07
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
4.60
39.66
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
3.70
31.90
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
3.00
25.86
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.80
24.14
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
2.60
22.41
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
3.40
29.31
981.00
0.03
CI Chrysenes (a)
929.00
3.60
31.03
929.00
0.03
CI Fluorenes(a)
611.00
0.64
5.52
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
7.00
60.34
770.00
0.08
CI-Naphthalenes (a)
444.00
1.20
10.34
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.30
71.55
670.00
0.11
C2 Chrysenes (a)
1008.00
2.80
24.14
1008.00
0.02
C2 Fluorenes (a)
686.00
1.50
12.93
686.00
0.02
C2-Fluoranthenes/Pyrenes
4.50
38.79
C2-Naphthalenes (a)
510.00
5.50
47.41
510.00
0.09
C2-Phenanthrenes/Anthracenes (a)
746
7.60
65.52
746.00
0.09
C3 Chrysenes (a)
1112.00
1.20
10.34
1112.00
0.01
C3 Fluorenes (a)
769.00
3.10
26.72
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
3.10
26.72
949.00
0.03
C3-Naphthalenes(a)
581.00
11.00
94.83
581.00
0.16
C3-Phenanthrenes/Anthracenes (a)
829.00
7.20
62.07
829.00
0.07
C4 Chrysenes (a)
1214.00
0.57
4.91
1214.00
0.00
C4-Naphthalenes (a)
657.00
8.20
70.69
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
4.70
40.52
913.00
0.04
Chrysene ,a)
844.00
826
4.40
37.93
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.62
5.34
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
7.80
67.24
707.00
0.10
Fluorene ,a)
538.00
26,000.00
0.94
8.10
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.10
18.10
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.65
5.60
385.00
0.01
Perylene(a)
967.00
431.00
0.97
8.36
967.00
0.01
Phenanthrene 'd'
596
34300
5.90
50.86
596.00
0.09
Pyrene ,a'
697.00
9,090.00
6.70
57.76
697.00
0.08
ESBTU FCVi
1.05
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 26 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-26
Field Sample ID
RREC13-26-0103
Sample Depth
1-3
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.12
0.0912
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.96
10.53
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.30
14.25
447.00
0.03
Acenaphthene (a)
491.00
33400
0.74
8.11
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.26
2.85
452.00
0.01
Anthracene (a)
594.00
1300
1.10
12.06
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
4.00
43.86
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
3.10
33.99
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
3.40
37.28
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.40
26.32
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.40
15.35
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.80
30.70
981.00
0.03
CI Chrysenes (a)
929.00
3.90
42.76
929.00
0.05
CI Fluorenes(a)
611.00
0.99
10.86
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
7.40
81.14
770.00
0.11
CI-Naphthalenes (a)
444.00
1.60
17.54
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
12.00
131.58
670.00
0.20
C2 Chrysenes (a)
1008.00
4.60
50.44
1008.00
0.05
C2 Fluorenes (a)
686.00
2.70
29.61
686.00
0.04
C2-Fluoranthenes/Pyrenes
5.90
64.69
C2-Naphthalenes (a)
510.00
8.50
93.20
510.00
0.18
C2-Phenanthrenes/Anthracenes (a)
746
12.00
131.58
746.00
0.18
C3 Chrysenes (a)
1112.00
2.00
21.93
1112.00
0.02
C3 Fluorenes (a)
769.00
5.60
61.40
769.00
0.08
C3-Fluoranthenes/Pyrenes
949.00
4.50
49.34
949.00
0.05
C3-Naphthalenes(a)
581.00
21.00
230.26
581.00
0.40
C3-Phenanthrenes/Anthracenes (a)
829.00
13.00
142.54
829.00
0.17
C4 Chrysenes (a)
1214.00
1.00
10.96
1214.00
0.01
C4-Naphthalenes (a)
657.00
15.00
164.47
657.00
0.25
C4-Phenanthrenes/Anthracenes (a)
913.00
7.80
85.53
913.00
0.09
Chrysene ,a)
844.00
826
4.30
47.15
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.36
3.95
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
6.70
73.46
707.00
0.10
Fluorene ,a)
538.00
26,000.00
0.84
9.21
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.20
13.16
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.70
18.64
385.00
0.05
Perylene(a)
967.00
431.00
0.71
7.79
967.00
0.01
Phenanthrene 'd'
596
34300
5.60
61.40
596.00
0.10
Pyrene ,d'
697.00
9,090.00
6.00
65.79
697.00
0.09
ESBTU FCVi
1.57
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 27 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-26
Field Sample ID
RREC13-26-0305
Sample Depth
3-5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry
wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7
0.07
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.10
15.71
446.00
0.04
2-Methylnaphthalene
447.00
154800
1.30
18.57
447.00
0.04
Acenaphthene (a)
491.00
33400
0.48
6.86
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.20
2.86
452.00
0.01
Anthracene (a)
594.00
1300
1.30
18.57
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.40
48.57
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
2.60
37.14
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.60
37.14
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
1.80
25.71
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.50
21.43
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.00
28.57
981.00
0.03
CI Chrysenes (a)
929.00
2.50
35.71
929.00
0.04
CI Fluorenes(a)
611.00
0.64
9.14
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.50
78.57
770.00
0.10
CI-Naphthalenes (a)
444.00
1.60
22.86
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
6.40
91.43
670.00
0.14
C2 Chrysenes (a)
1008.00
2.30
32.86
1008.00
0.03
C2 Fluorenes (a)
686.00
1.40
20.00
686.00
0.03
C2-Fluoranthenes/Pyrenes
3.80
54.29
C2-Naphthalenes (a)
510.00
6.80
97.14
510.00
0.19
C2-Phenanthrenes/Anthracenes (a)
746
6.70
95.71
746.00
0.13
C3 Chrysenes (a)
1112.00
0.96
13.71
1112.00
0.01
C3 Fluorenes (a)
769.00
2.90
41.43
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
2.70
38.57
949.00
0.04
C3-Naphthalenes(a)
581.00
9.80
140.00
581.00
0.24
C3-Phenanthrenes/Anthracenes (a)
829.00
8.90
127.14
829.00
0.15
C4 Chrysenes (a)
1214.00
0.56
8.00
1214.00
0.01
C4-Naphthalenes (a)
657.00
7.60
108.57
657.00
0.17
C4-Phenanthrenes/Anthracenes (a)
913.00
5.80
82.86
913.00
0.09
Chrysene ,a)
844.00
826
3.20
45.71
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.43
6.14
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.00
85.71
707.00
0.12
Fluorene ,a)
538.00
26,000.00
1.10
15.71
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.30
18.57
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
1.30
18.57
385.00
0.05
Perylene(a)
967.00
431.00
0.70
10.00
967.00
0.01
Phenanthrene 'd'
596
34300
5.20
74.29
596.00
0.12
Pyrene ,d'
697.00
9,090.00
5.20
74.29
697.00
0.11
ESBTU FCVi
1.49
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 28 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-26
Field Sample ID
RREC13-26-0507
Sample Depth
5-7
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.98
0.0898
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.68
7.57
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.93
10.36
447.00
0.02
Acenaphthene (a)
491.00
33400
0.40
4.45
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.24
2.67
452.00
0.01
Anthracene (a)
594.00
1300
1.10
12.25
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.90
32.29
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.30
25.61
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.20
24.50
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.60
17.82
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.00
11.14
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.00
22.27
981.00
0.02
CI Chrysenes (a)
929.00
2.10
23.39
929.00
0.03
CI Fluorenes(a)
611.00
0.51
5.68
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.50
50.11
770.00
0.07
CI-Naphthalenes (a)
444.00
1.10
12.25
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
5.70
63.47
670.00
0.09
C2 Chrysenes (a)
1008.00
2.00
22.27
1008.00
0.02
C2 Fluorenes (a)
686.00
1.10
12.25
686.00
0.02
C2-Fluoranthenes/Pyrenes
3.20
35.63
C2-Naphthalenes (a)
510.00
4.50
50.11
510.00
0.10
C2-Phenanthrenes/Anthracenes (a)
746
6.20
69.04
746.00
0.09
C3 Chrysenes (a)
1112.00
0.90
10.02
1112.00
0.01
C3 Fluorenes (a)
769.00
2.70
30.07
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
2.20
24.50
949.00
0.03
C3-Naphthalenes(a)
581.00
8.50
94.65
581.00
0.16
C3-Phenanthrenes/Anthracenes (a)
829.00
7.20
80.18
829.00
0.10
C4 Chrysenes (a)
1214.00
0.50
5.57
1214.00
0.00
C4-Naphthalenes (a)
657.00
6.10
67.93
657.00
0.10
C4-Phenanthrenes/Anthracenes (a)
913.00
4.90
54.57
913.00
0.06
Chrysene ,a)
844.00
826
3.00
33.41
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.25
2.78
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.80
64.59
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.92
10.24
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.88
9.80
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.20
13.36
385.00
0.03
Perylene(a)
967.00
431.00
0.72
8.02
967.00
0.01
Phenanthrene 'd'
596
34300
4.60
51.22
596.00
0.09
Pyrene ,d'
697.00
9,090.00
4.40
49.00
697.00
0.07
ESBTU FCVi
1.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 29 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-27
Field Sample ID
RREC13-27-SURF
Sample Depth
0-0.5
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.76
0.0476
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.11
2.31
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.19
3.99
447.00
0.01
Acenaphthene (a)
491.00
33400
0.14
2.94
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.08
1.68
452.00
0.00
Anthracene (a)
594.00
1300
0.43
9.03
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.00
42.02
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
1.90
39.92
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.00
42.02
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
1.40
29.41
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.10
23.11
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.80
37.82
981.00
0.04
CI Chrysenes (a)
929.00
1.30
27.31
929.00
0.03
CI Fluorenes(a)
611.00
0.08
1.72
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.20
46.22
770.00
0.06
CI-Naphthalenes (a)
444.00
0.20
4.20
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.50
31.51
670.00
0.05
C2 Chrysenes (a)
1008.00
0.86
18.07
1008.00
0.02
C2 Fluorenes (a)
686.00
0.18
3.78
686.00
0.01
C2-Fluoranthenes/Pyrenes
1.50
31.51
C2-Naphthalenes (a)
510.00
0.67
14.08
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
1.10
23.11
746.00
0.03
C3 Chrysenes (a)
1112.00
0.28
5.88
1112.00
0.01
C3 Fluorenes (a)
769.00
0.27
5.67
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.75
15.76
949.00
0.02
C3-Naphthalenes(a)
581.00
1.00
21.01
581.00
0.04
C3-Phenanthrenes/Anthracenes (a)
829.00
0.97
20.38
829.00
0.02
C4 Chrysenes (a)
1214.00
0.13
2.73
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.65
13.66
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.68
14.29
913.00
0.02
Chrysene ,a)
844.00
826
2.30
48.32
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.32
6.72
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
3.80
79.83
707.00
0.11
Fluorene ,a)
538.00
26,000.00
0.22
4.62
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.93
19.54
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.19
3.99
385.00
0.01
Perylene(a)
967.00
431.00
0.47
9.87
967.00
0.01
Phenanthrene 'd'
596
34300
2.30
48.32
596.00
0.08
Pyrene ,d'
697.00
9,090.00
2.80
58.82
697.00
0.08
ESBTU FCVi
0.83
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 30 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-27
Field Sample ID
RREC13-27-0001
Sample Depth
0-1
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Cone
Hg/g oc
Hg/g oc
Hg/g Dry
wt
Hg/g oc
Cocb
ESBTU FCVi
Hg/g Dry wt
Total Organic Carbon**
10
0.1
9.52
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
2.40
24.00
446.00
0.05
2.30
2-Methylnaphthalene
447.00
154800
3.00
30.00
447.00
0.07
2.90
Acenaphthene (a)
491.00
33400
0.43
4.30
491.00
0.01
0.49
Acenaphthylene (a)
452.00
24000
0.23
2.30
452.00
0.01
0.30
Anthracene (a)
594.00
1300
0.71
7.10
594.00
0.01
1.00
Benzo(a)anthracene (a)
841.00
4153
2.20
22.00
841.00
0.03
3.00
Benzo(a)pyrene (a)
965.00
3840
1.70
17.00
965.00
0.02
2.30
Benzo(b)fluoranthene (a)
979.00
2169
1.70
17.00
979.00
0.02
2.40
Benzo(e)pyrene (a)
967.00
4300
1.30
13.00
967.00
0.01
1.60
Benzo(g,h,i)perylene (a)
1095.00
648
0.80
8.00
1095.00
0.01
1.10
Benzo(k)fluoranthene (a)
981.00
1220
1.60
16.00
981.00
0.02
1.90
CI Chrysenes (a)
929.00
2.60
26.00
929.00
0.03
2.70
CI Fluorenes(a)
611.00
1.10
11.00
611.00
0.02
1.10
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.30
53.00
770.00
0.07
5.80
CI-Naphthalenes (a)
444.00
3.70
37.00
444.00
0.08
3.60
Cl-Phenanthrenes/Anthracenes (a)
670.00
11.00
110.00
670.00
0.16
11.00
C2 Chrysenes (a)
1008.00
3.60
36.00
1008.00
0.04
2.90
C2 Fluorenes (a)
686.00
3.60
36.00
686.00
0.05
3.20
C2-Fluoranthenes/Pyrenes
5.30
53.00
4.90
C2-Naphthalenes (a)
510.00
16.00
160.00
510.00
0.31
17.00
C2-Phenanthrenes/Anthracenes (a)
746
14.00
140.00
746.00
0.19
12.00
C3 Chrysenes (a)
1112.00
1.80
18.00
1112.00
0.02
1.70
C3 Fluorenes (a)
769.00
7.50
75.00
769.00
0.10
6.80
C3-Fluoranthenes/Pyrenes
949.00
4.10
41.00
949.00
0.04
4.40
C3-Naphthalenes(a)
581.00
23.00
230.00
581.00
0.40
26.00
C3-Phenanthrenes/Anthracenes (a)
829.00
14.00
140.00
829.00
0.17
14.00
C4 Chrysenes (a)
1214.00
0.93
9.30
1214.00
0.01
0.88
C4-Naphthalenes (a)
657.00
15.00
150.00
657.00
0.23
16.00
C4-Phenanthrenes/Anthracenes (a)
913.00
10.00
100.00
913.00
0.11
9.60
Chrysene ,a)
844.00
826
2.50
25.00
844.00
0.03
2.90
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.20
2.00
1123.00
0.00
0.28
Fluoranthene ,a)
707.00
23,870.00
4.20
42.00
707.00
0.06
6.10
Fluorene ,a)
538.00
26,000.00
0.60
6.00
538.00
0.01
1.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.70
7.00
1115.00
0.01
0.97
Naphthalene ,a)
385.00
61,700.00
0.67
6.70
385.00
0.02
1.40
Perylene(a)
967.00
431.00
0.67
6.70
967.00
0.01
0.80
Phenanthrene 'd'
596
34300
4.30
43.00
596.00
0.07
5.50
Pyrene ,d'
697.00
9,090.00
3.40
34.00
697.00
0.05
4.70
ESBTU FCVi
1.24
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 31 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-27
Field Sample ID
RREC13-27-0103
Sample Depth
1-3
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Coc
Final
Hg/g oc
Hg/g oc
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
0.0952
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
24.16
446.00
0.05
2-Methylnaphthalene
447.00
154800
30.46
447.00
0.07
Acenaphthene (a)
491.00
33400
5.15
491.00
0.01
Acenaphthylene (a)
452.00
24000
3.15
452.00
0.01
Anthracene (a)
594.00
1300
10.50
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
31.51
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
24.16
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
25.21
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
16.81
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
11.55
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
19.96
981.00
0.02
CI Chrysenes (a)
929.00
28.36
929.00
0.03
CI Fluorenes(a)
611.00
11.55
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
60.92
770.00
0.08
CI-Naphthalenes (a)
444.00
37.82
444.00
0.09
Cl-Phenanthrenes/Anthracenes (a)
670.00
115.55
670.00
0.17
C2 Chrysenes (a)
1008.00
30.46
1008.00
0.03
C2 Fluorenes (a)
686.00
33.61
686.00
0.05
C2-Fluoranthenes/Pyrenes
51.47
C2-Naphthalenes (a)
510.00
178.57
510.00
0.35
C2-Phenanthrenes/Anthracenes (a)
746
126.05
746.00
0.17
C3 Chrysenes (a)
1112.00
17.86
1112.00
0.02
C3 Fluorenes (a)
769.00
71.43
769.00
0.09
C3-Fluoranthenes/Pyrenes
949.00
46.22
949.00
0.05
C3-Naphthalenes(a)
581.00
273.11
581.00
0.47
C3-Phenanthrenes/Anthracenes (a)
829.00
147.06
829.00
0.18
C4 Chrysenes (a)
1214.00
9.24
1214.00
0.01
C4-Naphthalenes (a)
657.00
168.07
657.00
0.26
C4-Phenanthrenes/Anthracenes (a)
913.00
100.84
913.00
0.11
Chrysene ,a)
844.00
826
30.46
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
2.94
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
64.08
707.00
0.09
Fluorene ,a)
538.00
26,000.00
10.50
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
10.19
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
14.71
385.00
0.04
Perylene(a)
967.00
431.00
8.40
967.00
0.01
Phenanthrene 'd'
596
34300
57.77
596.00
0.10
Pyrene ,d'
697.00
9,090.00
49.37
697.00
0.07
ESBTU FCVi
1.41
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 32 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-27
Field Sample ID
RREC13-27-0305
Sample Depth
3-5
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.33
0.0733
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
4.20
57.30
446.00
0.13
2-Methylnaphthalene
447.00
154800
5.80
79.13
447.00
0.18
Acenaphthene (a)
491.00
33400
1.30
17.74
491.00
0.04
Acenaphthylene (a)
452.00
24000
0.32
4.37
452.00
0.01
Anthracene (a)
594.00
1300
2.10
28.65
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
4.20
57.30
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
2.70
36.83
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.70
36.83
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.10
28.65
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.20
16.37
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.70
36.83
981.00
0.04
CI Chrysenes (a)
929.00
5.10
69.58
929.00
0.07
CI Fluorenes(a)
611.00
1.90
25.92
611.00
0.04
Cl-Fluoranthenes/Pyrenes (a)
770.00
10.00
136.43
770.00
0.18
CI-Naphthalenes (a)
444.00
6.70
91.41
444.00
0.21
Cl-Phenanthrenes/Anthracenes (a)
670.00
19.00
259.21
670.00
0.39
C2 Chrysenes (a)
1008.00
6.30
85.95
1008.00
0.09
C2 Fluorenes (a)
686.00
4.90
66.85
686.00
0.10
C2-Fluoranthenes/Pyrenes
9.80
133.70
C2-Naphthalenes (a)
510.00
32.00
436.56
510.00
0.86
C2-Phenanthrenes/Anthracenes (a)
746
19.00
259.21
746.00
0.35
C3 Chrysenes (a)
1112.00
3.20
43.66
1112.00
0.04
C3 Fluorenes (a)
769.00
9.70
132.33
769.00
0.17
C3-Fluoranthenes/Pyrenes
949.00
7.10
96.86
949.00
0.10
C3-Naphthalenes(a)
581.00
42.00
572.99
581.00
0.99
C3-Phenanthrenes/Anthracenes (a)
829.00
22.00
300.14
829.00
0.36
C4 Chrysenes (a)
1214.00
1.60
21.83
1214.00
0.02
C4-Naphthalenes (a)
657.00
21.00
286.49
657.00
0.44
C4-Phenanthrenes/Anthracenes (a)
913.00
15.00
204.64
913.00
0.22
Chrysene ,a)
844.00
826
4.40
60.03
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.31
4.23
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
8.70
118.69
707.00
0.17
Fluorene ,a)
538.00
26,000.00
2.80
38.20
538.00
0.07
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
15.01
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.95
12.96
385.00
0.03
Perylene(a)
967.00
431.00
0.65
8.87
967.00
0.01
Phenanthrene 'd'
596
34300
11.00
150.07
596.00
0.25
Pyrene ,d'
697.00
9,090.00
7.60
103.68
697.00
0.15
ESBTU FCVi
2.90
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 33 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-27
Field Sample ID
RREC13-27-0507
Sample Depth
5-7
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.49
0.0749
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
2.20
29.37
446.00
0.07
2-Methylnaphthalene
447.00
154800
2.90
38.72
447.00
0.09
Acenaphthene (a)
491.00
33400
1.20
16.02
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.29
3.87
452.00
0.01
Anthracene (a)
594.00
1300
2.40
32.04
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
4.60
61.42
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
3.00
40.05
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.80
37.38
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.20
29.37
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.30
17.36
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.80
37.38
981.00
0.04
CI Chrysenes (a)
929.00
4.00
53.40
929.00
0.06
CI Fluorenes(a)
611.00
1.20
16.02
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
8.30
110.81
770.00
0.14
CI-Naphthalenes (a)
444.00
3.40
45.39
444.00
0.10
Cl-Phenanthrenes/Anthracenes (a)
670.00
13.00
173.56
670.00
0.26
C2 Chrysenes (a)
1008.00
4.00
53.40
1008.00
0.05
C2 Fluorenes (a)
686.00
3.30
44.06
686.00
0.06
C2-Fluoranthenes/Pyrenes
6.40
85.45
C2-Naphthalenes (a)
510.00
16.00
213.62
510.00
0.42
C2-Phenanthrenes/Anthracenes (a)
746
14.00
186.92
746.00
0.25
C3 Chrysenes (a)
1112.00
1.80
24.03
1112.00
0.02
C3 Fluorenes (a)
769.00
6.60
88.12
769.00
0.11
C3-Fluoranthenes/Pyrenes
949.00
4.80
64.09
949.00
0.07
C3-Naphthalenes(a)
581.00
22.00
293.72
581.00
0.51
C3-Phenanthrenes/Anthracenes (a)
829.00
14.00
186.92
829.00
0.23
C4 Chrysenes (a)
1214.00
0.90
12.02
1214.00
0.01
C4-Naphthalenes (a)
657.00
13.00
173.56
657.00
0.26
C4-Phenanthrenes/Anthracenes (a)
913.00
9.60
128.17
913.00
0.14
Chrysene ,a)
844.00
826
4.70
62.75
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.35
4.67
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
11.00
146.86
707.00
0.21
Fluorene ,a)
538.00
26,000.00
2.10
28.04
538.00
0.05
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
14.69
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.95
12.68
385.00
0.03
Perylene(a)
967.00
431.00
0.80
10.68
967.00
0.01
Phenanthrene 'd'
596
34300
10.00
133.51
596.00
0.22
Pyrene ,d'
697.00
9,090.00
7.20
96.13
697.00
0.14
ESBTU FCVi
2.31
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 34 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-27
Field Sample ID
RREC13-27-0710
Sample Depth
7-10
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.5
0.085
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
2.20
25.88
446.00
0.06
2-Methylnaphthalene
447.00
154800
3.20
37.65
447.00
0.08
Acenaphthene (a)
491.00
33400
1.50
17.65
491.00
0.04
Acenaphthylene (a)
452.00
24000
0.41
4.82
452.00
0.01
Anthracene (a)
594.00
1300
2.70
31.76
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
5.20
61.18
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
3.60
42.35
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
3.90
45.88
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
2.40
28.24
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.40
16.47
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
3.00
35.29
981.00
0.04
CI Chrysenes (a)
929.00
4.10
48.24
929.00
0.05
CI Fluorenes(a)
611.00
1.50
17.65
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
8.20
96.47
770.00
0.13
CI-Naphthalenes (a)
444.00
3.70
43.53
444.00
0.10
Cl-Phenanthrenes/Anthracenes (a)
670.00
15.00
176.47
670.00
0.26
C2 Chrysenes (a)
1008.00
3.60
42.35
1008.00
0.04
C2 Fluorenes (a)
686.00
3.60
42.35
686.00
0.06
C2-Fluoranthenes/Pyrenes
5.70
67.06
C2-Naphthalenes (a)
510.00
14.00
164.71
510.00
0.32
C2-Phenanthrenes/Anthracenes (a)
746
16.00
188.24
746.00
0.25
C3 Chrysenes (a)
1112.00
1.80
21.18
1112.00
0.02
C3 Fluorenes (a)
769.00
7.20
84.71
769.00
0.11
C3-Fluoranthenes/Pyrenes
949.00
4.50
52.94
949.00
0.06
C3-Naphthalenes(a)
581.00
23.00
270.59
581.00
0.47
C3-Phenanthrenes/Anthracenes (a)
829.00
15.00
176.47
829.00
0.21
C4 Chrysenes (a)
1214.00
1.10
12.94
1214.00
0.01
C4-Naphthalenes (a)
657.00
16.00
188.24
657.00
0.29
C4-Phenanthrenes/Anthracenes (a)
913.00
10.00
117.65
913.00
0.13
Chrysene ,a)
844.00
826
5.00
58.82
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.42
4.94
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
12.00
141.18
707.00
0.20
Fluorene ,a)
538.00
26,000.00
3.20
37.65
538.00
0.07
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.40
16.47
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
4.20
49.41
385.00
0.13
Perylene(a)
967.00
431.00
1.00
11.76
967.00
0.01
Phenanthrene 'd'
596
34300
11.00
129.41
596.00
0.22
Pyrene ,d'
697.00
9,090.00
7.20
84.71
697.00
0.12
ESBTU FCVi
2.37
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 35 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-28
Field Sample ID
RREC13-28-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.74
0.0874
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.08
0.87
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.18
2.00
447.00
0.00
Acenaphthene (a)
491.00
33400
0.11
1.26
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.09
1.00
452.00
0.00
Anthracene (a)
594.00
1300
0.47
5.38
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.50
17.16
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.50
17.16
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.40
16.02
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.00
11.44
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.77
8.81
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.40
16.02
981.00
0.02
CI Chrysenes (a)
929.00
0.86
9.84
929.00
0.01
CI Fluorenes(a)
611.00
0.06
0.70
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.70
19.45
770.00
0.03
CI-Naphthalenes (a)
444.00
0.13
1.49
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.10
12.59
670.00
0.02
C2 Chrysenes (a)
1008.00
0.79
9.04
1008.00
0.01
C2 Fluorenes (a)
686.00
0.13
1.49
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.88
10.07
C2-Naphthalenes (a)
510.00
0.58
6.64
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.91
10.41
746.00
0.01
C3 Chrysenes (a)
1112.00
0.32
3.66
1112.00
0.00
C3 Fluorenes (a)
769.00
0.32
3.66
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.54
6.18
949.00
0.01
C3-Naphthalenes(a)
581.00
0.83
9.50
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.75
8.58
829.00
0.01
C4 Chrysenes (a)
1214.00
0.09
1.01
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.56
6.41
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.49
5.61
913.00
0.01
Chrysene ,a)
844.00
826
1.40
16.02
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.22
2.52
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.30
26.32
707.00
0.04
Fluorene ,a)
538.00
26,000.00
0.17
1.95
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.69
7.89
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.18
2.00
385.00
0.01
Perylene(a)
967.00
431.00
0.38
4.35
967.00
0.00
Phenanthrene 'd'
596
34300
1.10
12.59
596.00
0.02
Pyrene ,d'
697.00
9,090.00
1.70
19.45
697.00
0.03
ESBTU FCVi
0.32
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 36 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-28
Field Sample ID
RREC13-28-0001
Sample Depth
0-1
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.1
0.101
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
2.20
21.78
446.00
0.05
2-Methylnaphthalene
447.00
154800
2.20
21.78
447.00
0.05
Acenaphthene (a)
491.00
33400
0.30
2.97
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.30
2.97
452.00
0.01
Anthracene (a)
594.00
1300
0.63
6.24
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.90
18.81
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.30
12.87
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
1.40
13.86
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
1.30
12.87
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
1.10
10.89
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.20
11.88
981.00
0.01
CI Chrysenes (a)
929.00
3.40
33.66
929.00
0.04
CI Fluorenes(a)
611.00
1.30
12.87
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.70
46.53
770.00
0.06
CI-Naphthalenes (a)
444.00
3.20
31.68
444.00
0.07
Cl-Phenanthrenes/Anthracenes (a)
670.00
10.00
99.01
670.00
0.15
C2 Chrysenes (a)
1008.00
3.60
35.64
1008.00
0.04
C2 Fluorenes (a)
686.00
3.90
38.61
686.00
0.06
C2-Fluoranthenes/Pyrenes
5.50
54.46
C2-Naphthalenes (a)
510.00
20.00
198.02
510.00
0.39
C2-Phenanthrenes/Anthracenes (a)
746
16.00
158.42
746.00
0.21
C3 Chrysenes (a)
1112.00
1.80
17.82
1112.00
0.02
C3 Fluorenes (a)
769.00
9.60
95.05
769.00
0.12
C3-Fluoranthenes/Pyrenes
949.00
4.80
47.52
949.00
0.05
C3-Naphthalenes(a)
581.00
29.00
287.13
581.00
0.49
C3-Phenanthrenes/Anthracenes (a)
829.00
18.00
178.22
829.00
0.21
C4 Chrysenes (a)
1214.00
1.30
12.87
1214.00
0.01
C4-Naphthalenes (a)
657.00
24.00
237.62
657.00
0.36
C4-Phenanthrenes/Anthracenes (a)
913.00
12.00
118.81
913.00
0.13
Chrysene ,a)
844.00
826
2.50
24.75
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.30
2.97
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.00
29.70
707.00
0.04
Fluorene ,a)
538.00
26,000.00
0.98
9.70
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.88
8.71
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.30
2.97
385.00
0.01
Perylene(a)
967.00
431.00
0.30
2.97
967.00
0.00
Phenanthrene 'd'
596
34300
3.20
31.68
596.00
0.05
Pyrene ,d'
697.00
9,090.00
4.00
39.60
697.00
0.06
ESBTU FCVi
1.30
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 37 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-28
Field Sample ID
RREC13-28-0103
Sample Depth
1-3
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.52
0.0452
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.70
15.49
446.00
0.03
2-Methylnaphthalene
447.00
154800
0.70
15.49
447.00
0.03
Acenaphthene (a)
491.00
33400
0.70
15.49
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.70
15.49
452.00
0.03
Anthracene (a)
594.00
1300
2.20
48.67
594.00
0.08
Benzo(a)anthracene (a)
841.00
4153
5.00
110.62
841.00
0.13
Benzo(a)pyrene (a)
965.00
3840
3.90
86.28
965.00
0.09
Benzo(b)fluoranthene (a)
979.00
2169
3.50
77.43
979.00
0.08
Benzo(e)pyrene (a)
967.00
4300
2.80
61.95
967.00
0.06
Benzo(g,h,i)perylene (a)
1095.00
648
2.50
55.31
1095.00
0.05
Benzo(k)fluoranthene (a)
981.00
1220
3.20
70.80
981.00
0.07
CI Chrysenes (a)
929.00
4.90
108.41
929.00
0.12
CI Fluorenes(a)
611.00
0.74
16.37
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.30
139.38
770.00
0.18
CI-Naphthalenes (a)
444.00
1.20
26.55
444.00
0.06
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.60
168.14
670.00
0.25
C2 Chrysenes (a)
1008.00
4.50
99.56
1008.00
0.10
C2 Fluorenes (a)
686.00
1.60
35.40
686.00
0.05
C2-Fluoranthenes/Pyrenes
4.80
106.19
C2-Naphthalenes (a)
510.00
6.20
137.17
510.00
0.27
C2-Phenanthrenes/Anthracenes (a)
746
12.00
265.49
746.00
0.36
C3 Chrysenes (a)
1112.00
2.00
44.25
1112.00
0.04
C3 Fluorenes (a)
769.00
4.30
95.13
769.00
0.12
C3-Fluoranthenes/Pyrenes
949.00
3.90
86.28
949.00
0.09
C3-Naphthalenes(a)
581.00
9.70
214.60
581.00
0.37
C3-Phenanthrenes/Anthracenes (a)
829.00
12.00
265.49
829.00
0.32
C4 Chrysenes (a)
1214.00
1.20
26.55
1214.00
0.02
C4-Naphthalenes (a)
657.00
8.80
194.69
657.00
0.30
C4-Phenanthrenes/Anthracenes (a)
913.00
8.30
183.63
913.00
0.20
Chrysene ,a)
844.00
826
5.00
110.62
844.00
0.13
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.70
15.49
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
8.00
176.99
707.00
0.25
Fluorene ,a)
538.00
26,000.00
0.70
15.49
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.30
50.88
1115.00
0.05
Naphthalene ,a)
385.00
61,700.00
0.70
15.49
385.00
0.04
Perylene(a)
967.00
431.00
0.70
15.49
967.00
0.02
Phenanthrene 'd'
596
34300
5.80
128.32
596.00
0.22
Pyrene ,d'
697.00
9,090.00
8.50
188.05
697.00
0.27
ESBTU FCVi
3.16
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 38 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-28
Field Sample ID
RREC13-28-0305
Sample Depth
3-5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.59
0.0759
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.55
7.25
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.55
7.25
447.00
0.02
Acenaphthene (a)
491.00
33400
0.55
7.25
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.55
7.25
452.00
0.02
Anthracene (a)
594.00
1300
2.10
27.67
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
4.60
60.61
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
3.60
47.43
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
3.00
39.53
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.60
34.26
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.30
30.30
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
3.10
40.84
981.00
0.04
CI Chrysenes (a)
929.00
4.70
61.92
929.00
0.07
CI Fluorenes(a)
611.00
0.62
8.17
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.90
77.73
770.00
0.10
CI-Naphthalenes (a)
444.00
1.20
15.81
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.50
98.81
670.00
0.15
C2 Chrysenes (a)
1008.00
4.20
55.34
1008.00
0.05
C2 Fluorenes (a)
686.00
1.50
19.76
686.00
0.03
C2-Fluoranthenes/Pyrenes
4.80
63.24
C2-Naphthalenes (a)
510.00
5.50
72.46
510.00
0.14
C2-Phenanthrenes/Anthracenes (a)
746
11.00
144.93
746.00
0.19
C3 Chrysenes (a)
1112.00
1.90
25.03
1112.00
0.02
C3 Fluorenes (a)
769.00
4.10
54.02
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
3.90
51.38
949.00
0.05
C3-Naphthalenes(a)
581.00
7.90
104.08
581.00
0.18
C3-Phenanthrenes/Anthracenes (a)
829.00
12.00
158.10
829.00
0.19
C4 Chrysenes (a)
1214.00
1.20
15.81
1214.00
0.01
C4-Naphthalenes (a)
657.00
6.90
90.91
657.00
0.14
C4-Phenanthrenes/Anthracenes (a)
913.00
9.00
118.58
913.00
0.13
Chrysene ,a)
844.00
826
4.80
63.24
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.55
7.25
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.90
90.91
707.00
0.13
Fluorene ,a)
538.00
26,000.00
1.70
22.40
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.10
27.67
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
1.50
19.76
385.00
0.05
Perylene(a)
967.00
431.00
0.55
7.25
967.00
0.01
Phenanthrene 'd'
596
34300
5.70
75.10
596.00
0.13
Pyrene ,d'
697.00
9,090.00
7.60
100.13
697.00
0.14
ESBTU FCVi
1.82
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 39 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-28
Field Sample ID
RREC13-28-0507
Sample Depth
5-7
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.71
0.0671
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.43
6.41
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.43
6.41
447.00
0.01
Acenaphthene (a)
491.00
33400
0.43
6.41
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.43
6.41
452.00
0.01
Anthracene (a)
594.00
1300
1.90
28.32
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
4.40
65.57
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
3.40
50.67
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
3.10
46.20
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
2.60
38.75
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.20
32.79
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
2.90
43.22
981.00
0.04
CI Chrysenes (a)
929.00
4.80
71.54
929.00
0.08
CI Fluorenes(a)
611.00
0.47
7.00
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.70
84.95
770.00
0.11
CI-Naphthalenes (a)
444.00
0.83
12.37
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
6.10
90.91
670.00
0.14
C2 Chrysenes (a)
1008.00
4.40
65.57
1008.00
0.07
C2 Fluorenes (a)
686.00
1.10
16.39
686.00
0.02
C2-Fluoranthenes/Pyrenes
4.70
70.04
C2-Naphthalenes (a)
510.00
3.30
49.18
510.00
0.10
C2-Phenanthrenes/Anthracenes (a)
746
9.00
134.13
746.00
0.18
C3 Chrysenes (a)
1112.00
2.30
34.28
1112.00
0.03
C3 Fluorenes (a)
769.00
3.40
50.67
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
3.80
56.63
949.00
0.06
C3-Naphthalenes(a)
581.00
4.60
68.55
581.00
0.12
C3-Phenanthrenes/Anthracenes (a)
829.00
11.00
163.93
829.00
0.20
C4 Chrysenes (a)
1214.00
1.20
17.88
1214.00
0.01
C4-Naphthalenes (a)
657.00
4.30
64.08
657.00
0.10
C4-Phenanthrenes/Anthracenes (a)
913.00
7.90
117.73
913.00
0.13
Chrysene ,a)
844.00
826
4.50
67.06
844.00
0.08
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.43
6.41
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.50
96.87
707.00
0.14
Fluorene ,a)
538.00
26,000.00
1.50
22.35
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.10
31.30
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
1.60
23.85
385.00
0.06
Perylene(a)
967.00
431.00
0.89
13.26
967.00
0.01
Phenanthrene 'd'
596
34300
4.70
70.04
596.00
0.12
Pyrene ,d'
697.00
9,090.00
7.00
104.32
697.00
0.15
ESBTU FCVi
1.86
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 40 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-28
Field Sample ID
RREC13-28-0709
Sample Depth
7-9
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.9
0.059
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.39
6.53
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.39
6.53
447.00
0.01
Acenaphthene (a)
491.00
33400
0.39
6.53
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.39
6.53
452.00
0.01
Anthracene (a)
594.00
1300
1.70
28.81
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
4.00
67.80
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
2.90
49.15
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
2.90
49.15
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
2.30
38.98
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
1.90
32.20
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
2.20
37.29
981.00
0.04
CI Chrysenes (a)
929.00
5.60
94.92
929.00
0.10
CI Fluorenes(a)
611.00
0.55
9.32
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.90
100.00
770.00
0.13
CI-Naphthalenes (a)
444.00
0.95
16.10
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.60
128.81
670.00
0.19
C2 Chrysenes (a)
1008.00
5.30
89.83
1008.00
0.09
C2 Fluorenes (a)
686.00
1.30
22.03
686.00
0.03
C2-Fluoranthenes/Pyrenes
5.90
100.00
C2-Naphthalenes (a)
510.00
4.00
67.80
510.00
0.13
C2-Phenanthrenes/Anthracenes (a)
746
12.00
203.39
746.00
0.27
C3 Chrysenes (a)
1112.00
3.00
50.85
1112.00
0.05
C3 Fluorenes (a)
769.00
4.00
67.80
769.00
0.09
C3-Fluoranthenes/Pyrenes
949.00
4.90
83.05
949.00
0.09
C3-Naphthalenes(a)
581.00
5.50
93.22
581.00
0.16
C3-Phenanthrenes/Anthracenes (a)
829.00
14.00
237.29
829.00
0.29
C4 Chrysenes (a)
1214.00
1.60
27.12
1214.00
0.02
C4-Naphthalenes (a)
657.00
5.10
86.44
657.00
0.13
C4-Phenanthrenes/Anthracenes (a)
913.00
10.00
169.49
913.00
0.19
Chrysene ,a)
844.00
826
4.50
76.27
844.00
0.09
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.39
6.53
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
5.70
96.61
707.00
0.14
Fluorene ,a)
538.00
26,000.00
1.30
22.03
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.80
30.51
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
1.60
27.12
385.00
0.07
Perylene(a)
967.00
431.00
0.39
6.53
967.00
0.01
Phenanthrene 'd'
596
34300
4.20
71.19
596.00
0.12
Pyrene ,d'
697.00
9,090.00
6.50
110.17
697.00
0.16
ESBTU FCVi
2.22
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 41 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-28
Field Sample ID
RREC13-28-0911
Sample Depth
9-11
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.11
0.0511
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.44
8.51
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.44
8.51
447.00
0.02
Acenaphthene (a)
491.00
33400
0.42
8.22
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.44
8.51
452.00
0.02
Anthracene (a)
594.00
1300
1.00
19.57
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.30
64.58
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
2.50
48.92
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
2.40
46.97
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
2.00
39.14
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
0.99
19.37
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.10
41.10
981.00
0.04
CI Chrysenes (a)
929.00
4.30
84.15
929.00
0.09
CI Fluorenes(a)
611.00
0.38
7.44
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.70
131.12
770.00
0.17
CI-Naphthalenes (a)
444.00
0.75
14.68
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.30
142.86
670.00
0.21
C2 Chrysenes (a)
1008.00
4.80
93.93
1008.00
0.09
C2 Fluorenes (a)
686.00
1.00
19.57
686.00
0.03
C2-Fluoranthenes/Pyrenes
5.60
109.59
C2-Naphthalenes (a)
510.00
2.90
56.75
510.00
0.11
C2-Phenanthrenes/Anthracenes (a)
746
9.10
178.08
746.00
0.24
C3 Chrysenes (a)
1112.00
2.50
48.92
1112.00
0.04
C3 Fluorenes (a)
769.00
3.20
62.62
769.00
0.08
C3-Fluoranthenes/Pyrenes
949.00
5.00
97.85
949.00
0.10
C3-Naphthalenes(a)
581.00
5.00
97.85
581.00
0.17
C3-Phenanthrenes/Anthracenes (a)
829.00
12.00
234.83
829.00
0.28
C4 Chrysenes (a)
1214.00
1.50
29.35
1214.00
0.02
C4-Naphthalenes (a)
657.00
3.80
74.36
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
8.50
166.34
913.00
0.18
Chrysene ,a)
844.00
826
3.30
64.58
844.00
0.08
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.28
5.48
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.10
99.80
707.00
0.14
Fluorene ,a)
538.00
26,000.00
0.72
14.09
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.88
17.22
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
1.20
23.48
385.00
0.06
Perylene(a)
967.00
431.00
0.57
11.15
967.00
0.01
Phenanthrene 'd'
596
34300
3.40
66.54
596.00
0.11
Pyrene ,d'
697.00
9,090.00
4.10
80.23
697.00
0.12
ESBTU FCVi
2.12
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 42 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-29
Field Sample ID
RREC13-29-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.6
0.106
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.27
2.55
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.16
1.51
447.00
0.00
Acenaphthene (a)
491.00
33400
0.16
1.51
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.09
0.81
452.00
0.00
Anthracene (a)
594.00
1300
0.39
3.68
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.40
13.21
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.50
14.15
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
1.50
14.15
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.98
9.25
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.73
6.89
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.20
11.32
981.00
0.01
CI Chrysenes (a)
929.00
1.20
11.32
929.00
0.01
CI Fluorenes(a)
611.00
0.24
2.26
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.10
19.81
770.00
0.03
CI-Naphthalenes (a)
444.00
0.33
3.11
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.90
27.36
670.00
0.04
C2 Chrysenes (a)
1008.00
1.30
12.26
1008.00
0.01
C2 Fluorenes (a)
686.00
0.73
6.89
686.00
0.01
C2-Fluoranthenes/Pyrenes
1.60
15.09
C2-Naphthalenes (a)
510.00
2.90
27.36
510.00
0.05
C2-Phenanthrenes/Anthracenes (a)
746
3.20
30.19
746.00
0.04
C3 Chrysenes (a)
1112.00
0.54
5.09
1112.00
0.00
C3 Fluorenes (a)
769.00
1.70
16.04
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.10
10.38
949.00
0.01
C3-Naphthalenes(a)
581.00
5.10
48.11
581.00
0.08
C3-Phenanthrenes/Anthracenes (a)
829.00
3.00
28.30
829.00
0.03
C4 Chrysenes (a)
1214.00
0.24
2.26
1214.00
0.00
C4-Naphthalenes (a)
657.00
3.70
34.91
657.00
0.05
C4-Phenanthrenes/Anthracenes (a)
913.00
1.80
16.98
913.00
0.02
Chrysene ,a)
844.00
826
1.40
13.21
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.22
2.08
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.50
23.58
707.00
0.03
Fluorene ,a)
538.00
26,000.00
0.18
1.70
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.67
6.32
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.16
1.51
385.00
0.00
Perylene(a)
967.00
431.00
0.42
3.96
967.00
0.00
Phenanthrene 'd'
596
34300
1.40
13.21
596.00
0.02
Pyrene ,d'
697.00
9,090.00
1.70
16.04
697.00
0.02
ESBTU FCVi
0.39
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 43 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-29
Field Sample ID
RREC13-29-0001
Sample Depth
0-1
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.53
0.0753
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.36
4.78
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.35
4.65
447.00
0.01
Acenaphthene (a)
491.00
33400
0.12
1.59
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.08
1.00
452.00
0.00
Anthracene (a)
594.00
1300
0.11
1.46
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.50
6.64
841.00
0.01
Benzo(a)pyrene (a)
965.00
3840
0.38
5.05
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
0.37
4.91
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.38
5.05
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.34
4.52
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.31
4.12
981.00
0.00
CI Chrysenes (a)
929.00
0.80
10.62
929.00
0.01
CI Fluorenes(a)
611.00
0.26
3.45
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.10
14.61
770.00
0.02
CI-Naphthalenes (a)
444.00
0.52
6.91
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.50
33.20
670.00
0.05
C2 Chrysenes (a)
1008.00
0.99
13.15
1008.00
0.01
C2 Fluorenes (a)
686.00
0.80
10.62
686.00
0.02
C2-Fluoranthenes/Pyrenes
1.30
17.26
C2-Naphthalenes (a)
510.00
3.90
51.79
510.00
0.10
C2-Phenanthrenes/Anthracenes (a)
746
3.50
46.48
746.00
0.06
C3 Chrysenes (a)
1112.00
0.50
6.64
1112.00
0.01
C3 Fluorenes (a)
769.00
1.80
23.90
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
1.20
15.94
949.00
0.02
C3-Naphthalenes(a)
581.00
6.40
84.99
581.00
0.15
C3-Phenanthrenes/Anthracenes (a)
829.00
4.10
54.45
829.00
0.07
C4 Chrysenes (a)
1214.00
0.27
3.59
1214.00
0.00
C4-Naphthalenes (a)
657.00
4.80
63.75
657.00
0.10
C4-Phenanthrenes/Anthracenes (a)
913.00
2.70
35.86
913.00
0.04
Chrysene ,a)
844.00
826
0.63
8.37
844.00
0.01
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.12
1.59
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.64
8.50
707.00
0.01
Fluorene ,a)
538.00
26,000.00
0.19
2.52
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.28
3.72
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.08
1.00
385.00
0.00
Perylene(a)
967.00
431.00
0.14
1.86
967.00
0.00
Phenanthrene 'd'
596
34300
0.73
9.69
596.00
0.02
Pyrene ,d'
697.00
9,090.00
1.00
13.28
697.00
0.02
ESBTU FCVi
0.40
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 44 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-29
Field Sample ID
RREC13-29-0103
Sample Depth
1-3
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.09
0.0809
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.95
11.74
446.00
0.03
2-Methylnaphthalene
447.00
154800
1.20
14.83
447.00
0.03
Acenaphthene (a)
491.00
33400
0.48
5.93
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.43
5.32
452.00
0.01
Anthracene (a)
594.00
1300
1.60
19.78
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.80
46.97
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
2.90
35.85
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.90
35.85
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.40
29.67
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
2.30
28.43
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
2.30
28.43
981.00
0.03
CI Chrysenes (a)
929.00
4.10
50.68
929.00
0.05
CI Fluorenes(a)
611.00
0.82
10.14
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.70
70.46
770.00
0.09
CI-Naphthalenes (a)
444.00
1.60
19.78
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.60
106.30
670.00
0.16
C2 Chrysenes (a)
1008.00
3.70
45.74
1008.00
0.05
C2 Fluorenes (a)
686.00
2.40
29.67
686.00
0.04
C2-Fluoranthenes/Pyrenes
5.30
65.51
C2-Naphthalenes (a)
510.00
9.40
116.19
510.00
0.23
C2-Phenanthrenes/Anthracenes (a)
746
11.00
135.97
746.00
0.18
C3 Chrysenes (a)
1112.00
1.90
23.49
1112.00
0.02
C3 Fluorenes (a)
769.00
5.50
67.99
769.00
0.09
C3-Fluoranthenes/Pyrenes
949.00
4.00
49.44
949.00
0.05
C3-Naphthalenes(a)
581.00
14.00
173.05
581.00
0.30
C3-Phenanthrenes/Anthracenes (a)
829.00
12.00
148.33
829.00
0.18
C4 Chrysenes (a)
1214.00
0.93
11.50
1214.00
0.01
C4-Naphthalenes (a)
657.00
11.00
135.97
657.00
0.21
C4-Phenanthrenes/Anthracenes (a)
913.00
8.30
102.60
913.00
0.11
Chrysene ,a)
844.00
826
4.00
49.44
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.80
9.89
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
5.50
67.99
707.00
0.10
Fluorene ,a)
538.00
26,000.00
1.60
19.78
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.10
25.96
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
1.10
13.60
385.00
0.04
Perylene(a)
967.00
431.00
0.85
10.51
967.00
0.01
Phenanthrene 'd'
596
34300
4.90
60.57
596.00
0.10
Pyrene ,d'
697.00
9,090.00
6.30
77.87
697.00
0.11
ESBTU FCVi
1.63
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 45 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-29
Field Sample ID
RREC13-29-0305
Sample Depth
3-5
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.58
0.0958
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.55
5.74
446.00
0.01
2-Methylnaphthalene
447.00
154800
1.20
12.53
447.00
0.03
Acenaphthene (a)
491.00
33400
0.64
6.68
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.55
5.74
452.00
0.01
Anthracene (a)
594.00
1300
2.10
21.92
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
4.60
48.02
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
3.70
38.62
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
3.70
38.62
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.80
29.23
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
2.50
26.10
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.90
30.27
981.00
0.03
CI Chrysenes (a)
929.00
4.40
45.93
929.00
0.05
CI Fluorenes(a)
611.00
0.94
9.81
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.30
65.76
770.00
0.09
CI-Naphthalenes (a)
444.00
1.50
15.66
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
9.80
102.30
670.00
0.15
C2 Chrysenes (a)
1008.00
3.90
40.71
1008.00
0.04
C2 Fluorenes (a)
686.00
2.10
21.92
686.00
0.03
C2-Fluoranthenes/Pyrenes
5.40
56.37
C2-Naphthalenes (a)
510.00
7.40
77.24
510.00
0.15
C2-Phenanthrenes/Anthracenes (a)
746
13.00
135.70
746.00
0.18
C3 Chrysenes (a)
1112.00
1.80
18.79
1112.00
0.02
C3 Fluorenes (a)
769.00
5.40
56.37
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
4.00
41.75
949.00
0.04
C3-Naphthalenes(a)
581.00
13.00
135.70
581.00
0.23
C3-Phenanthrenes/Anthracenes (a)
829.00
13.00
135.70
829.00
0.16
C4 Chrysenes (a)
1214.00
1.10
11.48
1214.00
0.01
C4-Naphthalenes (a)
657.00
11.00
114.82
657.00
0.17
C4-Phenanthrenes/Anthracenes (a)
913.00
8.90
92.90
913.00
0.10
Chrysene ,a)
844.00
826
4.70
49.06
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.88
9.19
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
7.10
74.11
707.00
0.10
Fluorene ,a)
538.00
26,000.00
3.20
33.40
538.00
0.06
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.30
24.01
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
2.10
21.92
385.00
0.06
Perylene(a)
967.00
431.00
0.95
9.92
967.00
0.01
Phenanthrene 'd'
596
34300
5.90
61.59
596.00
0.10
Pyrene ,d'
697.00
9,090.00
7.50
78.29
697.00
0.11
ESBTU FCVi
1.63
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 46 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-29
Field Sample ID
RREC13-29-0507
Sample Depth
5-7
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.39
0.0839
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.41
4.89
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.41
4.89
447.00
0.01
Acenaphthene (a)
491.00
33400
0.44
5.24
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.41
4.89
452.00
0.01
Anthracene (a)
594.00
1300
1.40
16.69
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.20
38.14
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
2.50
29.80
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.50
29.80
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.90
22.65
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.70
20.26
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.00
23.84
981.00
0.02
CI Chrysenes (a)
929.00
3.40
40.52
929.00
0.04
CI Fluorenes(a)
611.00
0.52
6.20
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.50
53.64
770.00
0.07
CI-Naphthalenes (a)
444.00
0.94
11.20
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
6.80
81.05
670.00
0.12
C2 Chrysenes (a)
1008.00
3.00
35.76
1008.00
0.04
C2 Fluorenes (a)
686.00
1.50
17.88
686.00
0.03
C2-Fluoranthenes/Pyrenes
3.80
45.29
C2-Naphthalenes (a)
510.00
4.60
54.83
510.00
0.11
C2-Phenanthrenes/Anthracenes (a)
746
9.50
113.23
746.00
0.15
C3 Chrysenes (a)
1112.00
1.30
15.49
1112.00
0.01
C3 Fluorenes (a)
769.00
3.70
44.10
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
3.00
35.76
949.00
0.04
C3-Naphthalenes(a)
581.00
8.40
100.12
581.00
0.17
C3-Phenanthrenes/Anthracenes (a)
829.00
9.90
118.00
829.00
0.14
C4 Chrysenes (a)
1214.00
0.82
9.77
1214.00
0.01
C4-Naphthalenes (a)
657.00
7.80
92.97
657.00
0.14
C4-Phenanthrenes/Anthracenes (a)
913.00
6.40
76.28
913.00
0.08
Chrysene ,a)
844.00
826
3.40
40.52
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.60
7.15
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
4.60
54.83
707.00
0.08
Fluorene ,a)
538.00
26,000.00
1.50
17.88
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.50
17.88
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
1.20
14.30
385.00
0.04
Perylene(a)
967.00
431.00
0.63
7.51
967.00
0.01
Phenanthrene 'd'
596
34300
3.40
40.52
596.00
0.07
Pyrene ,d'
697.00
9,090.00
5.10
60.79
697.00
0.09
ESBTU FCVi
1.27
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 47 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-29
Field Sample ID
RREC13-29-0709
Sample Depth
7-9
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.5
0.085
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.90
10.59
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.90
10.59
447.00
0.02
Acenaphthene (a)
491.00
33400
1.10
12.94
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.90
10.59
452.00
0.02
Anthracene (a)
594.00
1300
4.30
50.59
594.00
0.09
Benzo(a)anthracene (a)
841.00
4153
9.40
110.59
841.00
0.13
Benzo(a)pyrene (a)
965.00
3840
7.30
85.88
965.00
0.09
Benzo(b)fluoranthene (a)
979.00
2169
6.20
72.94
979.00
0.07
Benzo(e)pyrene (a)
967.00
4300
5.20
61.18
967.00
0.06
Benzo(g,h,i)perylene (a)
1095.00
648
4.70
55.29
1095.00
0.05
Benzo(k)fluoranthene (a)
981.00
1220
5.90
69.41
981.00
0.07
CI Chrysenes (a)
929.00
8.20
96.47
929.00
0.10
CI Fluorenes(a)
611.00
0.96
11.29
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
12.00
141.18
770.00
0.18
CI-Naphthalenes (a)
444.00
1.80
21.18
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
13.00
152.94
670.00
0.23
C2 Chrysenes (a)
1008.00
6.10
71.76
1008.00
0.07
C2 Fluorenes (a)
686.00
2.00
23.53
686.00
0.03
C2-Fluoranthenes/Pyrenes
7.70
90.59
C2-Naphthalenes (a)
510.00
8.50
100.00
510.00
0.20
C2-Phenanthrenes/Anthracenes (a)
746
14.00
164.71
746.00
0.22
C3 Chrysenes (a)
1112.00
3.10
36.47
1112.00
0.03
C3 Fluorenes (a)
769.00
4.50
52.94
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
4.80
56.47
949.00
0.06
C3-Naphthalenes(a)
581.00
13.00
152.94
581.00
0.26
C3-Phenanthrenes/Anthracenes (a)
829.00
15.00
176.47
829.00
0.21
C4 Chrysenes (a)
1214.00
1.40
16.47
1214.00
0.01
C4-Naphthalenes (a)
657.00
9.20
108.24
657.00
0.16
C4-Phenanthrenes/Anthracenes (a)
913.00
10.00
117.65
913.00
0.13
Chrysene ,a)
844.00
826
9.30
109.41
844.00
0.13
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.60
18.82
1123.00
0.02
Fluoranthene ,a)
707.00
23,870.00
13.00
152.94
707.00
0.22
Fluorene ,a)
538.00
26,000.00
2.80
32.94
538.00
0.06
Indeno(l,2,3-cd)pyrene ,a)
1115.00
4.30
50.59
1115.00
0.05
Naphthalene ,a)
385.00
61,700.00
2.00
23.53
385.00
0.06
Perylene(a)
967.00
431.00
1.80
21.18
967.00
0.02
Phenanthrene 'd'
596
34300
11.00
129.41
596.00
0.22
Pyrene ,d'
697.00
9,090.00
16.00
188.24
697.00
0.27
ESBTU FCVi
2.75
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 48 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-29
Field Sample ID
RREC13-29-0911
Sample Depth
9-11
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.38
0.0938
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.30
13.86
446.00
0.03
2-Methylnaphthalene
447.00
154800
2.90
30.92
447.00
0.07
Acenaphthene (a)
491.00
33400
1.50
15.99
491.00
0.03
Acenaphthylene (a)
452.00
24000
1.30
13.86
452.00
0.03
Anthracene (a)
594.00
1300
7.10
75.69
594.00
0.13
Benzo(a)anthracene (a)
841.00
4153
11.00
117.27
841.00
0.14
Benzo(a)pyrene (a)
965.00
3840
8.90
94.88
965.00
0.10
Benzo(b)fluoranthene (a)
979.00
2169
6.80
72.49
979.00
0.07
Benzo(e)pyrene (a)
967.00
4300
6.20
66.10
967.00
0.07
Benzo(g,h,i)perylene (a)
1095.00
648
6.10
65.03
1095.00
0.06
Benzo(k)fluoranthene (a)
981.00
1220
6.80
72.49
981.00
0.07
CI Chrysenes (a)
929.00
10.00
106.61
929.00
0.11
CI Fluorenes(a)
611.00
1.60
17.06
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
15.00
159.91
770.00
0.21
CI-Naphthalenes (a)
444.00
3.60
38.38
444.00
0.09
Cl-Phenanthrenes/Anthracenes (a)
670.00
19.00
202.56
670.00
0.30
C2 Chrysenes (a)
1008.00
7.20
76.76
1008.00
0.08
C2 Fluorenes (a)
686.00
2.80
29.85
686.00
0.04
C2-Fluoranthenes/Pyrenes
9.20
98.08
C2-Naphthalenes (a)
510.00
14.00
149.25
510.00
0.29
C2-Phenanthrenes/Anthracenes (a)
746
19.00
202.56
746.00
0.27
C3 Chrysenes (a)
1112.00
3.00
31.98
1112.00
0.03
C3 Fluorenes (a)
769.00
6.70
71.43
769.00
0.09
C3-Fluoranthenes/Pyrenes
949.00
6.70
71.43
949.00
0.08
C3-Naphthalenes(a)
581.00
19.00
202.56
581.00
0.35
C3-Phenanthrenes/Anthracenes (a)
829.00
20.00
213.22
829.00
0.26
C4 Chrysenes (a)
1214.00
1.50
15.99
1214.00
0.01
C4-Naphthalenes (a)
657.00
13.00
138.59
657.00
0.21
C4-Phenanthrenes/Anthracenes (a)
913.00
14.00
149.25
913.00
0.16
Chrysene ,a)
844.00
826
11.00
117.27
844.00
0.14
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.70
18.12
1123.00
0.02
Fluoranthene ,a)
707.00
23,870.00
17.00
181.24
707.00
0.26
Fluorene ,a)
538.00
26,000.00
4.60
49.04
538.00
0.09
Indeno(l,2,3-cd)pyrene ,a)
1115.00
4.90
52.24
1115.00
0.05
Naphthalene ,a)
385.00
61,700.00
4.40
46.91
385.00
0.12
Perylene(a)
967.00
431.00
2.00
21.32
967.00
0.02
Phenanthrene 'd'
596
34300
19.00
202.56
596.00
0.34
Pyrene ,d'
697.00
9,090.00
22.00
234.54
697.00
0.34
ESBTU FCVi
3.44
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 49 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-30
Field Sample ID
RREC13-30-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.06
0.0706
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.41
5.81
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.34
4.75
447.00
0.01
Acenaphthene (a)
491.00
33400
0.33
4.67
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.32
4.53
452.00
0.01
Anthracene (a)
594.00
1300
1.20
17.00
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
4.20
59.49
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
4.00
56.66
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
3.30
46.74
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
2.50
35.41
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
1.60
22.66
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
3.60
50.99
981.00
0.05
CI Chrysenes (a)
929.00
3.10
43.91
929.00
0.05
CI Fluorenes(a)
611.00
0.55
7.79
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.90
83.57
770.00
0.11
CI-Naphthalenes (a)
444.00
0.68
9.63
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.50
106.23
670.00
0.16
C2 Chrysenes (a)
1008.00
3.30
46.74
1008.00
0.05
C2 Fluorenes (a)
686.00
1.50
21.25
686.00
0.03
C2-Fluoranthenes/Pyrenes
4.00
56.66
C2-Naphthalenes (a)
510.00
5.70
80.74
510.00
0.16
C2-Phenanthrenes/Anthracenes (a)
746
7.40
104.82
746.00
0.14
C3 Chrysenes (a)
1112.00
1.10
15.58
1112.00
0.01
C3 Fluorenes (a)
769.00
3.00
42.49
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
2.40
33.99
949.00
0.04
C3-Naphthalenes(a)
581.00
11.00
155.81
581.00
0.27
C3-Phenanthrenes/Anthracenes (a)
829.00
6.80
96.32
829.00
0.12
C4 Chrysenes (a)
1214.00
0.49
6.94
1214.00
0.01
C4-Naphthalenes (a)
657.00
7.50
106.23
657.00
0.16
C4-Phenanthrenes/Anthracenes (a)
913.00
3.70
52.41
913.00
0.06
Chrysene ,a)
844.00
826
3.90
55.24
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.48
6.80
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.30
89.24
707.00
0.13
Fluorene ,a)
538.00
26,000.00
0.61
8.64
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.50
21.25
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.78
11.05
385.00
0.03
Perylene(a)
967.00
431.00
1.00
14.16
967.00
0.01
Phenanthrene 'd'
596
34300
3.60
50.99
596.00
0.09
Pyrene ,d'
697.00
9,090.00
5.30
75.07
697.00
0.11
ESBTU FCVi
1.48
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 50 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-30
Field Sample ID
RREC13-30-0001
Sample Depth
0-1
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
11.1
0.111
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.40
12.61
446.00
0.03
2-Methylnaphthalene
447.00
154800
2.10
18.92
447.00
0.04
Acenaphthene (a)
491.00
33400
0.46
4.10
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.46
4.10
452.00
0.01
Anthracene (a)
594.00
1300
0.46
4.10
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.90
26.13
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
2.30
20.72
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
2.20
19.82
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
2.10
18.92
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.80
16.22
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.80
16.22
981.00
0.02
CI Chrysenes (a)
929.00
5.50
49.55
929.00
0.05
CI Fluorenes(a)
611.00
2.00
18.02
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.20
55.86
770.00
0.07
CI-Naphthalenes (a)
444.00
2.50
22.52
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
17.00
153.15
670.00
0.23
C2 Chrysenes (a)
1008.00
6.80
61.26
1008.00
0.06
C2 Fluorenes (a)
686.00
5.60
50.45
686.00
0.07
C2-Fluoranthenes/Pyrenes
8.00
72.07
C2-Naphthalenes (a)
510.00
22.00
198.20
510.00
0.39
C2-Phenanthrenes/Anthracenes (a)
746
23.00
207.21
746.00
0.28
C3 Chrysenes (a)
1112.00
3.50
31.53
1112.00
0.03
C3 Fluorenes (a)
769.00
11.00
99.10
769.00
0.13
C3-Fluoranthenes/Pyrenes
949.00
6.80
61.26
949.00
0.06
C3-Naphthalenes(a)
581.00
39.00
351.35
581.00
0.60
C3-Phenanthrenes/Anthracenes (a)
829.00
21.00
189.19
829.00
0.23
C4 Chrysenes (a)
1214.00
1.70
15.32
1214.00
0.01
C4-Naphthalenes (a)
657.00
30.00
270.27
657.00
0.41
C4-Phenanthrenes/Anthracenes (a)
913.00
12.00
108.11
913.00
0.12
Chrysene ,a)
844.00
826
3.60
32.43
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.46
4.10
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.70
33.33
707.00
0.05
Fluorene ,a)
538.00
26,000.00
1.20
10.81
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.50
13.51
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
2.90
26.13
385.00
0.07
Perylene(a)
967.00
431.00
0.46
4.10
967.00
0.00
Phenanthrene 'd'
596
34300
5.10
45.95
596.00
0.08
Pyrene ,d'
697.00
9,090.00
5.30
47.75
697.00
0.07
ESBTU FCVi
1.64
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 51 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-30
Field Sample ID
RREC13-30-0001-FD
Sample Depth
0-1
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.8
0.108
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.40
12.96
446.00
0.03
2-Methylnaphthalene
447.00
154800
2.00
18.52
447.00
0.04
Acenaphthene (a)
491.00
33400
0.42
3.84
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.42
3.84
452.00
0.01
Anthracene (a)
594.00
1300
0.93
8.61
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.90
26.85
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
2.40
22.22
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
2.30
21.30
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
2.20
20.37
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
2.00
18.52
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.80
16.67
981.00
0.02
CI Chrysenes (a)
929.00
5.90
54.63
929.00
0.06
CI Fluorenes(a)
611.00
1.90
17.59
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.70
62.04
770.00
0.08
CI-Naphthalenes (a)
444.00
2.40
22.22
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
17.00
157.41
670.00
0.23
C2 Chrysenes (a)
1008.00
7.50
69.44
1008.00
0.07
C2 Fluorenes (a)
686.00
5.20
48.15
686.00
0.07
C2-Fluoranthenes/Pyrenes
8.70
80.56
C2-Naphthalenes (a)
510.00
21.00
194.44
510.00
0.38
C2-Phenanthrenes/Anthracenes (a)
746
23.00
212.96
746.00
0.29
C3 Chrysenes (a)
1112.00
4.10
37.96
1112.00
0.03
C3 Fluorenes (a)
769.00
10.00
92.59
769.00
0.12
C3-Fluoranthenes/Pyrenes
949.00
7.00
64.81
949.00
0.07
C3-Naphthalenes(a)
581.00
38.00
351.85
581.00
0.61
C3-Phenanthrenes/Anthracenes (a)
829.00
22.00
203.70
829.00
0.25
C4 Chrysenes (a)
1214.00
2.40
22.22
1214.00
0.02
C4-Naphthalenes (a)
657.00
29.00
268.52
657.00
0.41
C4-Phenanthrenes/Anthracenes (a)
913.00
12.00
111.11
913.00
0.12
Chrysene ,a)
844.00
826
3.60
33.33
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.42
3.84
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.90
36.11
707.00
0.05
Fluorene ,a)
538.00
26,000.00
1.20
11.11
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.60
14.81
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
2.50
23.15
385.00
0.06
Perylene(a)
967.00
431.00
0.42
3.84
967.00
0.00
Phenanthrene 'd'
596
34300
5.10
47.22
596.00
0.08
Pyrene ,d'
697.00
9,090.00
5.70
52.78
697.00
0.08
ESBTU FCVi
1.70
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 52 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-30
Field Sample ID
RREC13-30-0103
Sample Depth
1-3
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.4
0.104
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
2.40
23.08
446.00
0.05
2-Methylnaphthalene
447.00
154800
3.20
30.77
447.00
0.07
Acenaphthene (a)
491.00
33400
1.80
17.31
491.00
0.04
Acenaphthylene (a)
452.00
24000
0.70
6.73
452.00
0.01
Anthracene (a)
594.00
1300
2.50
24.04
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
4.90
47.12
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
4.10
39.42
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
3.40
32.69
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
3.20
30.77
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
3.00
28.85
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
2.80
26.92
981.00
0.03
CI Chrysenes (a)
929.00
6.10
58.65
929.00
0.06
CI Fluorenes(a)
611.00
2.10
20.19
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
8.60
82.69
770.00
0.11
CI-Naphthalenes (a)
444.00
3.90
37.50
444.00
0.08
Cl-Phenanthrenes/Anthracenes (a)
670.00
18.00
173.08
670.00
0.26
C2 Chrysenes (a)
1008.00
6.40
61.54
1008.00
0.06
C2 Fluorenes (a)
686.00
4.90
47.12
686.00
0.07
C2-Fluoranthenes/Pyrenes
8.40
80.77
C2-Naphthalenes (a)
510.00
25.00
240.38
510.00
0.47
C2-Phenanthrenes/Anthracenes (a)
746
21.00
201.92
746.00
0.27
C3 Chrysenes (a)
1112.00
3.10
29.81
1112.00
0.03
C3 Fluorenes (a)
769.00
9.70
93.27
769.00
0.12
C3-Fluoranthenes/Pyrenes
949.00
6.30
60.58
949.00
0.06
C3-Naphthalenes(a)
581.00
38.00
365.38
581.00
0.63
C3-Phenanthrenes/Anthracenes (a)
829.00
18.00
173.08
829.00
0.21
C4 Chrysenes (a)
1214.00
1.70
16.35
1214.00
0.01
C4-Naphthalenes (a)
657.00
27.00
259.62
657.00
0.40
C4-Phenanthrenes/Anthracenes (a)
913.00
11.00
105.77
913.00
0.12
Chrysene ,a)
844.00
826
5.20
50.00
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.70
6.73
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
7.20
69.23
707.00
0.10
Fluorene ,a)
538.00
26,000.00
2.20
21.15
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.40
23.08
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
2.50
24.04
385.00
0.06
Perylene(a)
967.00
431.00
0.70
6.73
967.00
0.01
Phenanthrene 'd'
596
34300
9.80
94.23
596.00
0.16
Pyrene ,d'
697.00
9,090.00
10.00
96.15
697.00
0.14
ESBTU FCVi
2.08
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 53 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-30
Field Sample ID
RREC13-30-0103-FD
Sample Depth
1-3
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.82
0.0982
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.40
14.26
446.00
0.03
2-Methylnaphthalene
447.00
154800
2.00
20.37
447.00
0.05
Acenaphthene (a)
491.00
33400
1.10
11.20
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.55
5.60
452.00
0.01
Anthracene (a)
594.00
1300
1.30
13.24
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
3.30
33.60
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.90
29.53
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.30
23.42
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
2.10
21.38
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.20
12.22
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.40
24.44
981.00
0.02
CI Chrysenes (a)
929.00
3.10
31.57
929.00
0.03
CI Fluorenes(a)
611.00
1.00
10.18
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.40
65.17
770.00
0.08
CI-Naphthalenes (a)
444.00
2.30
23.42
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
11.00
112.02
670.00
0.17
C2 Chrysenes (a)
1008.00
3.20
32.59
1008.00
0.03
C2 Fluorenes (a)
686.00
2.50
25.46
686.00
0.04
C2-Fluoranthenes/Pyrenes
5.00
50.92
C2-Naphthalenes (a)
510.00
12.00
122.20
510.00
0.24
C2-Phenanthrenes/Anthracenes (a)
746
11.00
112.02
746.00
0.15
C3 Chrysenes (a)
1112.00
1.70
17.31
1112.00
0.02
C3 Fluorenes (a)
769.00
4.50
45.82
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
3.60
36.66
949.00
0.04
C3-Naphthalenes(a)
581.00
22.00
224.03
581.00
0.39
C3-Phenanthrenes/Anthracenes (a)
829.00
9.40
95.72
829.00
0.12
C4 Chrysenes (a)
1214.00
0.76
7.74
1214.00
0.01
C4-Naphthalenes (a)
657.00
13.00
132.38
657.00
0.20
C4-Phenanthrenes/Anthracenes (a)
913.00
5.80
59.06
913.00
0.06
Chrysene ,a)
844.00
826
3.40
34.62
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.28
2.85
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.80
59.06
707.00
0.08
Fluorene ,a)
538.00
26,000.00
1.00
10.18
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.99
10.08
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.20
12.22
385.00
0.03
Perylene(a)
967.00
431.00
0.78
7.94
967.00
0.01
Phenanthrene 'd'
596
34300
6.20
63.14
596.00
0.11
Pyrene ,d'
697.00
9,090.00
5.40
54.99
697.00
0.08
ESBTU FCVi
1.29
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 54 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-30
Field Sample ID
RREC13-30-0305
Sample Depth
3-5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.76
0.0876
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.40
15.98
446.00
0.04
2-Methylnaphthalene
447.00
154800
1.90
21.69
447.00
0.05
Acenaphthene (a)
491.00
33400
0.88
10.05
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.65
7.42
452.00
0.02
Anthracene (a)
594.00
1300
1.40
15.98
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
4.10
46.80
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
3.60
41.10
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
3.20
36.53
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.50
28.54
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.40
15.98
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.80
31.96
981.00
0.03
CI Chrysenes (a)
929.00
4.60
52.51
929.00
0.06
CI Fluorenes(a)
611.00
1.30
14.84
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
8.60
98.17
770.00
0.13
CI-Naphthalenes (a)
444.00
2.30
26.26
444.00
0.06
Cl-Phenanthrenes/Anthracenes (a)
670.00
15.00
171.23
670.00
0.26
C2 Chrysenes (a)
1008.00
4.70
53.65
1008.00
0.05
C2 Fluorenes (a)
686.00
3.40
38.81
686.00
0.06
C2-Fluoranthenes/Pyrenes
7.30
83.33
C2-Naphthalenes (a)
510.00
13.00
148.40
510.00
0.29
C2-Phenanthrenes/Anthracenes (a)
746
16.00
182.65
746.00
0.24
C3 Chrysenes (a)
1112.00
2.70
30.82
1112.00
0.03
C3 Fluorenes (a)
769.00
6.70
76.48
769.00
0.10
C3-Fluoranthenes/Pyrenes
949.00
5.70
65.07
949.00
0.07
C3-Naphthalenes(a)
581.00
28.00
319.63
581.00
0.55
C3-Phenanthrenes/Anthracenes (a)
829.00
15.00
171.23
829.00
0.21
C4 Chrysenes (a)
1214.00
1.10
12.56
1214.00
0.01
C4-Naphthalenes (a)
657.00
18.00
205.48
657.00
0.31
C4-Phenanthrenes/Anthracenes (a)
913.00
9.60
109.59
913.00
0.12
Chrysene ,a)
844.00
826
4.30
49.09
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.36
4.11
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
6.70
76.48
707.00
0.11
Fluorene ,a)
538.00
26,000.00
0.93
10.62
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.20
13.70
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
1.30
14.84
385.00
0.04
Perylene(a)
967.00
431.00
1.00
11.42
967.00
0.01
Phenanthrene 'd'
596
34300
6.00
68.49
596.00
0.11
Pyrene ,d'
697.00
9,090.00
6.10
69.63
697.00
0.10
ESBTU FCVi
1.88
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 55 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-30
Field Sample ID
RREC13-30-0305-FD
Sample Depth
3-5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.88
0.0988
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.00
10.12
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.30
13.16
447.00
0.03
Acenaphthene (a)
491.00
33400
0.49
4.91
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.49
4.91
452.00
0.01
Anthracene (a)
594.00
1300
1.70
17.21
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.60
36.44
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
3.10
31.38
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.80
28.34
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.30
23.28
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
2.10
21.26
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.00
20.24
981.00
0.02
CI Chrysenes (a)
929.00
4.40
44.53
929.00
0.05
CI Fluorenes(a)
611.00
1.10
11.13
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.80
58.70
770.00
0.08
CI-Naphthalenes (a)
444.00
1.70
17.21
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
11.00
111.34
670.00
0.17
C2 Chrysenes (a)
1008.00
3.60
36.44
1008.00
0.04
C2 Fluorenes (a)
686.00
3.10
31.38
686.00
0.05
C2-Fluoranthenes/Pyrenes
5.40
54.66
C2-Naphthalenes (a)
510.00
12.00
121.46
510.00
0.24
C2-Phenanthrenes/Anthracenes (a)
746
14.00
141.70
746.00
0.19
C3 Chrysenes (a)
1112.00
1.70
17.21
1112.00
0.02
C3 Fluorenes (a)
769.00
6.50
65.79
769.00
0.09
C3-Fluoranthenes/Pyrenes
949.00
3.80
38.46
949.00
0.04
C3-Naphthalenes(a)
581.00
22.00
222.67
581.00
0.38
C3-Phenanthrenes/Anthracenes (a)
829.00
11.00
111.34
829.00
0.13
C4 Chrysenes (a)
1214.00
0.84
8.50
1214.00
0.01
C4-Naphthalenes (a)
657.00
17.00
172.06
657.00
0.26
C4-Phenanthrenes/Anthracenes (a)
913.00
7.60
76.92
913.00
0.08
Chrysene ,a)
844.00
826
3.70
37.45
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.49
4.91
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.10
51.62
707.00
0.07
Fluorene ,a)
538.00
26,000.00
1.30
13.16
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.80
18.22
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.98
9.92
385.00
0.03
Perylene(a)
967.00
431.00
0.49
4.91
967.00
0.01
Phenanthrene 'd'
596
34300
5.50
55.67
596.00
0.09
Pyrene ,d'
697.00
9,090.00
6.50
65.79
697.00
0.09
ESBTU FCVi
1.40
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 56 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-30
Field Sample ID
RREC13-30-0507
Sample Depth
5-7
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.32
0.0732
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.75
10.25
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.75
10.25
447.00
0.02
Acenaphthene (a)
491.00
33400
1.70
23.22
491.00
0.05
Acenaphthylene (a)
452.00
24000
0.75
10.25
452.00
0.02
Anthracene (a)
594.00
1300
3.60
49.18
594.00
0.08
Benzo(a)anthracene (a)
841.00
4153
5.60
76.50
841.00
0.09
Benzo(a)pyrene (a)
965.00
3840
4.40
60.11
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
3.90
53.28
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
3.00
40.98
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.90
39.62
1095.00
0.04
Benzo(k)fluoranthene (a)
981.00
1220
3.30
45.08
981.00
0.05
CI Chrysenes (a)
929.00
4.60
62.84
929.00
0.07
CI Fluorenes(a)
611.00
0.63
8.61
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.90
94.26
770.00
0.12
CI-Naphthalenes (a)
444.00
1.60
21.86
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.20
98.36
670.00
0.15
C2 Chrysenes (a)
1008.00
3.00
40.98
1008.00
0.04
C2 Fluorenes (a)
686.00
1.20
16.39
686.00
0.02
C2-Fluoranthenes/Pyrenes
4.20
57.38
C2-Naphthalenes (a)
510.00
4.70
64.21
510.00
0.13
C2-Phenanthrenes/Anthracenes (a)
746
8.10
110.66
746.00
0.15
C3 Chrysenes (a)
1112.00
1.30
17.76
1112.00
0.02
C3 Fluorenes (a)
769.00
2.90
39.62
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
2.90
39.62
949.00
0.04
C3-Naphthalenes(a)
581.00
6.40
87.43
581.00
0.15
C3-Phenanthrenes/Anthracenes (a)
829.00
8.20
112.02
829.00
0.14
C4 Chrysenes (a)
1214.00
0.77
10.52
1214.00
0.01
C4-Naphthalenes (a)
657.00
5.10
69.67
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
5.60
76.50
913.00
0.08
Chrysene ,a)
844.00
826
5.30
72.40
844.00
0.09
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.75
10.25
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
11.00
150.27
707.00
0.21
Fluorene ,a)
538.00
26,000.00
2.90
39.62
538.00
0.07
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.60
35.52
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
2.80
38.25
385.00
0.10
Perylene(a)
967.00
431.00
0.75
10.25
967.00
0.01
Phenanthrene 'd'
596
34300
9.90
135.25
596.00
0.23
Pyrene ,d'
697.00
9,090.00
11.00
150.27
697.00
0.22
ESBTU FCVi
2.18
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 57 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-30
Field Sample ID
RREC13-30-0507- FD
Sample Depth
5-7
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.38
0.0738
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.95
12.87
446.00
0.03
2-Methylnaphthalene
447.00
154800
0.95
12.87
447.00
0.03
Acenaphthene (a)
491.00
33400
0.95
12.87
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.95
12.87
452.00
0.03
Anthracene (a)
594.00
1300
3.90
52.85
594.00
0.09
Benzo(a)anthracene (a)
841.00
4153
6.40
86.72
841.00
0.10
Benzo(a)pyrene (a)
965.00
3840
5.30
71.82
965.00
0.07
Benzo(b)fluoranthene (a)
979.00
2169
4.80
65.04
979.00
0.07
Benzo(e)pyrene (a)
967.00
4300
3.60
48.78
967.00
0.05
Benzo(g,h,i)perylene (a)
1095.00
648
3.70
50.14
1095.00
0.05
Benzo(k)fluoranthene (a)
981.00
1220
4.00
54.20
981.00
0.06
CI Chrysenes (a)
929.00
5.30
71.82
929.00
0.08
CI Fluorenes(a)
611.00
0.69
9.35
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
7.60
102.98
770.00
0.13
CI-Naphthalenes (a)
444.00
1.60
21.68
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.80
105.69
670.00
0.16
C2 Chrysenes (a)
1008.00
3.90
52.85
1008.00
0.05
C2 Fluorenes (a)
686.00
1.20
16.26
686.00
0.02
C2-Fluoranthenes/Pyrenes
4.60
62.33
C2-Naphthalenes (a)
510.00
5.10
69.11
510.00
0.14
C2-Phenanthrenes/Anthracenes (a)
746
8.90
120.60
746.00
0.16
C3 Chrysenes (a)
1112.00
1.50
20.33
1112.00
0.02
C3 Fluorenes (a)
769.00
3.00
40.65
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
3.20
43.36
949.00
0.05
C3-Naphthalenes(a)
581.00
6.80
92.14
581.00
0.16
C3-Phenanthrenes/Anthracenes (a)
829.00
8.90
120.60
829.00
0.15
C4 Chrysenes (a)
1214.00
0.78
10.57
1214.00
0.01
C4-Naphthalenes (a)
657.00
5.60
75.88
657.00
0.12
C4-Phenanthrenes/Anthracenes (a)
913.00
6.60
89.43
913.00
0.10
Chrysene ,a)
844.00
826
6.30
85.37
844.00
0.10
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.95
12.87
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
12.00
162.60
707.00
0.23
Fluorene ,a)
538.00
26,000.00
3.20
43.36
538.00
0.08
Indeno(l,2,3-cd)pyrene ,a)
1115.00
3.20
43.36
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
3.00
40.65
385.00
0.11
Perylene(a)
967.00
431.00
0.95
12.87
967.00
0.01
Phenanthrene 'd'
596
34300
11.00
149.05
596.00
0.25
Pyrene ,d'
697.00
9,090.00
11.00
149.05
697.00
0.21
ESBTU FCVi
2.37
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 58 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-31
Field Sample ID
RREC13-31-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.19
0.0619
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.31
4.93
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.16
2.58
447.00
0.01
Acenaphthene (a)
491.00
33400
0.21
3.39
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.31
4.93
452.00
0.01
Anthracene (a)
594.00
1300
1.00
16.16
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
2.70
43.62
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
2.40
38.77
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.00
32.31
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.70
27.46
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.70
27.46
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
2.00
32.31
981.00
0.03
CI Chrysenes (a)
929.00
1.90
30.69
929.00
0.03
CI Fluorenes(a)
611.00
0.12
1.94
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.80
45.23
770.00
0.06
CI-Naphthalenes (a)
444.00
0.20
3.23
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.10
33.93
670.00
0.05
C2 Chrysenes (a)
1008.00
0.94
15.19
1008.00
0.02
C2 Fluorenes (a)
686.00
0.16
2.58
686.00
0.00
C2-Fluoranthenes/Pyrenes
1.40
22.62
C2-Naphthalenes (a)
510.00
0.66
10.66
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
1.10
17.77
746.00
0.02
C3 Chrysenes (a)
1112.00
0.40
6.46
1112.00
0.01
C3 Fluorenes (a)
769.00
0.16
2.58
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.61
9.85
949.00
0.01
C3-Naphthalenes(a)
581.00
0.31
4.93
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.77
12.44
829.00
0.02
C4 Chrysenes (a)
1214.00
0.31
4.93
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.30
4.85
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.42
6.79
913.00
0.01
Chrysene ,a)
844.00
826
2.40
38.77
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.61
9.85
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
4.30
69.47
707.00
0.10
Fluorene ,a)
538.00
26,000.00
0.31
4.93
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.50
24.23
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.31
4.93
385.00
0.01
Perylene(a)
967.00
431.00
0.64
10.34
967.00
0.01
Phenanthrene 'd'
596
34300
2.60
42.00
596.00
0.07
Pyrene ,d'
697.00
9,090.00
4.30
69.47
697.00
0.10
ESBTU FCVi
0.80
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 59 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-31
Field Sample ID
RREC13-31-0001
Sample Depth
0-1
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.93
0.0393
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.12
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.12
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.07
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.12
452.00
0.00
Anthracene (a)
594.00
1300
0.01
0.28
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.04
0.94
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.03
0.84
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.03
0.87
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.03
0.64
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.02
0.61
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.03
0.64
981.00
0.00
CI Chrysenes (a)
929.00
0.04
0.99
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.10
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.05
1.25
770.00
0.00
CI-Naphthalenes (a)
444.00
0.01
0.16
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.05
1.15
670.00
0.00
C2 Chrysenes (a)
1008.00
0.04
1.04
1008.00
0.00
C2 Fluorenes (a)
686.00
0.01
0.16
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.03
0.87
C2-Naphthalenes (a)
510.00
0.02
0.56
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.04
1.09
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.33
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.31
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.02
0.59
949.00
0.00
C3-Naphthalenes(a)
581.00
0.03
0.81
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.05
1.20
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.15
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.03
0.87
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.04
0.92
913.00
0.00
Chrysene ,a)
844.00
826
0.04
0.94
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.01
0.18
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.05
1.20
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.12
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.02
0.48
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.02
0.38
385.00
0.00
Perylene(a)
967.00
431.00
0.03
0.84
967.00
0.00
Phenanthrene 'd'
596
34300
0.03
0.64
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.05
1.30
697.00
0.00
ESBTU FCVi
0.02
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 60 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-31
Field Sample ID
RREC13-31-0103
Sample Depth
1-3
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
ng/g OC
Cocb
ESBTU FCVi
Total Organic Carbon**
3.21
0.0321
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.07
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.06
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.03
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.07
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.07
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.07
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.07
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.00
0.15
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.00
0.07
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.19
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.07
981.00
0.00
CI Chrysenes (a)
929.00
0.01
0.44
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.07
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.01
0.34
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.10
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.02
0.56
670.00
0.00
C2 Chrysenes (a)
1008.00
0.02
0.62
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.12
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.01
0.44
C2-Naphthalenes (a)
510.00
0.01
0.37
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.02
0.72
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.30
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.22
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.01
0.44
949.00
0.00
C3-Naphthalenes(a)
581.00
0.03
0.78
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.03
0.90
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.16
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.03
0.90
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.72
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.22
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.02
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.00
0.07
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.07
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.07
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.07
385.00
0.00
Perylene(a)
967.00
431.00
0.03
0.90
967.00
0.00
Phenanthrene 'd'
596
34300
0.00
0.07
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.00
0.15
697.00
0.00
ESBTU FCVi
0.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 61 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-31
Field Sample ID
RREC13-31-0305
Sample Depth
3-5
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.19
0.0419
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.06
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.05
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.02
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.06
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.06
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.11
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.06
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.16
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.15
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.17
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.06
981.00
0.00
CI Chrysenes (a)
929.00
0.02
0.41
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.06
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.01
0.33
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.09
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.02
0.48
670.00
0.00
C2 Chrysenes (a)
1008.00
0.02
0.55
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.09
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.02
0.36
C2-Naphthalenes (a)
510.00
0.01
0.31
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.03
0.62
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.31
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.17
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.02
0.38
949.00
0.00
C3-Naphthalenes(a)
581.00
0.04
0.86
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.02
0.57
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.14
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.03
0.79
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.55
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.24
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.03
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.01
0.14
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.06
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.06
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.06
385.00
0.00
Perylene(a)
967.00
431.00
0.03
0.67
967.00
0.00
Phenanthrene 'd'
596
34300
0.01
0.12
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.20
697.00
0.00
ESBTU FCVi
0.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 62 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-31
Field Sample ID
RREC13-31-0507
Sample Depth
5-7
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.32
0.0332
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.07
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.06
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.02
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.07
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.07
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.07
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.07
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.00
0.07
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.00
0.07
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.17
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.07
981.00
0.00
CI Chrysenes (a)
929.00
0.01
0.42
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.07
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.01
0.33
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.10
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.02
0.54
670.00
0.00
C2 Chrysenes (a)
1008.00
0.02
0.54
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.11
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.01
0.36
C2-Naphthalenes (a)
510.00
0.01
0.39
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.02
0.69
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.33
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.20
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.01
0.42
949.00
0.00
C3-Naphthalenes(a)
581.00
0.03
0.84
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.03
0.96
829.00
0.00
C4 Chrysenes (a)
1214.00
0.00
0.12
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.03
0.99
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.72
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.20
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.02
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.00
0.07
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.07
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.07
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.07
385.00
0.00
Perylene(a)
967.00
431.00
0.03
0.81
967.00
0.00
Phenanthrene 'd'
596
34300
0.00
0.14
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.15
697.00
0.00
ESBTU FCVi
0.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 63 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-32
Field Sample ID
RREC13-32-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.95
0.0595
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.55
9.24
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.30
5.04
447.00
0.01
Acenaphthene (a)
491.00
33400
0.37
6.22
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.55
9.24
452.00
0.02
Anthracene (a)
594.00
1300
1.40
23.53
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
4.00
67.23
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
3.80
63.87
965.00
0.07
Benzo(b)fluoranthene (a)
979.00
2169
3.60
60.50
979.00
0.06
Benzo(e)pyrene (a)
967.00
4300
2.60
43.70
967.00
0.05
Benzo(g,h,i)perylene (a)
1095.00
648
1.90
31.93
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
2.90
48.74
981.00
0.05
CI Chrysenes (a)
929.00
2.90
48.74
929.00
0.05
CI Fluorenes(a)
611.00
0.15
2.52
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.80
63.87
770.00
0.08
CI-Naphthalenes (a)
444.00
0.35
5.88
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.30
38.66
670.00
0.06
C2 Chrysenes (a)
1008.00
1.80
30.25
1008.00
0.03
C2 Fluorenes (a)
686.00
0.22
3.70
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.00
33.61
C2-Naphthalenes (a)
510.00
0.55
9.24
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
1.90
31.93
746.00
0.04
C3 Chrysenes (a)
1112.00
0.50
8.40
1112.00
0.01
C3 Fluorenes (a)
769.00
0.43
7.23
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.93
15.63
949.00
0.02
C3-Naphthalenes(a)
581.00
0.55
9.24
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
1.30
21.85
829.00
0.03
C4 Chrysenes (a)
1214.00
0.55
9.24
1214.00
0.01
C4-Naphthalenes (a)
657.00
0.61
10.25
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.63
10.59
913.00
0.01
Chrysene ,a)
844.00
826
3.70
62.18
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.61
10.25
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
5.70
95.80
707.00
0.14
Fluorene ,a)
538.00
26,000.00
0.55
9.24
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.70
28.57
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
0.55
9.24
385.00
0.02
Perylene(a)
967.00
431.00
0.96
16.13
967.00
0.02
Phenanthrene 'd'
596
34300
3.10
52.10
596.00
0.09
Pyrene ,d'
697.00
9,090.00
6.10
102.52
697.00
0.15
ESBTU FCVi
1.18
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 64 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-32
Field Sample ID
RREC13-32-0001
Sample Depth
0-1
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.14
0.0914
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.52
5.69
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.34
3.72
447.00
0.01
Acenaphthene (a)
491.00
33400
0.84
9.19
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.95
10.39
452.00
0.02
Anthracene (a)
594.00
1300
2.90
31.73
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
5.70
62.36
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
4.70
51.42
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
4.60
50.33
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
3.40
37.20
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.90
31.73
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
3.70
40.48
981.00
0.04
CI Chrysenes (a)
929.00
4.40
48.14
929.00
0.05
CI Fluorenes(a)
611.00
0.65
7.11
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
7.00
76.59
770.00
0.10
CI-Naphthalenes (a)
444.00
0.62
6.78
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.40
91.90
670.00
0.14
C2 Chrysenes (a)
1008.00
3.00
32.82
1008.00
0.03
C2 Fluorenes (a)
686.00
1.50
16.41
686.00
0.02
C2-Fluoranthenes/Pyrenes
4.10
44.86
C2-Naphthalenes (a)
510.00
3.70
40.48
510.00
0.08
C2-Phenanthrenes/Anthracenes (a)
746
7.40
80.96
746.00
0.11
C3 Chrysenes (a)
1112.00
1.30
14.22
1112.00
0.01
C3 Fluorenes (a)
769.00
2.90
31.73
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
2.50
27.35
949.00
0.03
C3-Naphthalenes(a)
581.00
8.60
94.09
581.00
0.16
C3-Phenanthrenes/Anthracenes (a)
829.00
5.90
64.55
829.00
0.08
C4 Chrysenes (a)
1214.00
0.95
10.39
1214.00
0.01
C4-Naphthalenes (a)
657.00
6.00
65.65
657.00
0.10
C4-Phenanthrenes/Anthracenes (a)
913.00
3.60
39.39
913.00
0.04
Chrysene ,a)
844.00
826
5.50
60.18
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.94
10.28
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
9.60
105.03
707.00
0.15
Fluorene ,a)
538.00
26,000.00
1.40
15.32
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.50
27.35
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.95
10.39
385.00
0.03
Perylene(a)
967.00
431.00
1.30
14.22
967.00
0.01
Phenanthrene 'd'
596
34300
6.60
72.21
596.00
0.12
Pyrene ,d'
697.00
9,090.00
9.70
106.13
697.00
0.15
ESBTU FCVi
1.52
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 65 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-32
Field Sample ID
RREC13-32-0103
Sample Depth
1-3
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.97
0.0297
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.14
4.71
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.04
1.41
447.00
0.00
Acenaphthene (a)
491.00
33400
0.35
11.78
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.17
5.56
452.00
0.01
Anthracene (a)
594.00
1300
0.65
21.89
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
1.10
37.04
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
0.82
27.61
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
0.51
17.17
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
0.54
18.18
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.40
13.47
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
0.57
19.19
981.00
0.02
CI Chrysenes (a)
929.00
1.10
37.04
929.00
0.04
CI Fluorenes(a)
611.00
0.18
6.06
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.90
63.97
770.00
0.08
CI-Naphthalenes (a)
444.00
0.13
4.38
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.30
77.44
670.00
0.12
C2 Chrysenes (a)
1008.00
0.67
22.56
1008.00
0.02
C2 Fluorenes (a)
686.00
0.23
7.74
686.00
0.01
C2-Fluoranthenes/Pyrenes
1.10
37.04
C2-Naphthalenes (a)
510.00
1.00
33.67
510.00
0.07
C2-Phenanthrenes/Anthracenes (a)
746
1.40
47.14
746.00
0.06
C3 Chrysenes (a)
1112.00
0.24
8.08
1112.00
0.01
C3 Fluorenes (a)
769.00
0.29
9.76
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.49
16.50
949.00
0.02
C3-Naphthalenes(a)
581.00
1.20
40.40
581.00
0.07
C3-Phenanthrenes/Anthracenes (a)
829.00
0.83
27.95
829.00
0.03
C4 Chrysenes (a)
1214.00
0.08
2.56
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.51
17.17
657.00
0.03
C4-Phenanthrenes/Anthracenes (a)
913.00
0.42
14.14
913.00
0.02
Chrysene ,a)
844.00
826
0.95
31.99
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.13
4.38
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.30
43.77
707.00
0.06
Fluorene ,a)
538.00
26,000.00
0.33
11.11
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.31
10.44
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.17
5.56
385.00
0.01
Perylene(a)
967.00
431.00
0.23
7.74
967.00
0.01
Phenanthrene 'd'
596
34300
1.40
47.14
596.00
0.08
Pyrene ,d'
697.00
9,090.00
1.90
63.97
697.00
0.09
ESBTU FCVi
0.89
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 66 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-32
Field Sample ID
RREC13-32-0305
Sample Depth
3-5
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.36
0.0236
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.03
1.40
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.02
1.02
447.00
0.00
Acenaphthene (a)
491.00
33400
0.06
2.42
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.06
2.33
452.00
0.01
Anthracene (a)
594.00
1300
0.20
8.47
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
0.38
16.10
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
0.36
15.25
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
0.27
11.44
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.23
9.75
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.23
9.75
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
0.26
11.02
981.00
0.01
CI Chrysenes (a)
929.00
0.34
14.41
929.00
0.02
CI Fluorenes(a)
611.00
0.03
1.44
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.50
21.19
770.00
0.03
CI-Naphthalenes (a)
444.00
0.04
1.86
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.49
20.76
670.00
0.03
C2 Chrysenes (a)
1008.00
0.19
8.05
1008.00
0.01
C2 Fluorenes (a)
686.00
0.06
2.42
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.29
12.29
C2-Naphthalenes (a)
510.00
0.21
8.90
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
0.35
14.83
746.00
0.02
C3 Chrysenes (a)
1112.00
0.06
2.54
1112.00
0.00
C3 Fluorenes (a)
769.00
0.10
4.24
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.13
5.51
949.00
0.01
C3-Naphthalenes(a)
581.00
0.33
13.98
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.25
10.59
829.00
0.01
C4 Chrysenes (a)
1214.00
0.01
0.51
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.20
8.47
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.16
6.78
913.00
0.01
Chrysene ,a)
844.00
826
0.37
15.68
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.07
3.14
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.55
23.31
707.00
0.03
Fluorene ,a)
538.00
26,000.00
0.10
4.24
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.20
8.47
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.06
2.33
385.00
0.01
Perylene(a)
967.00
431.00
0.32
13.56
967.00
0.01
Phenanthrene 'd'
596
34300
0.42
17.80
596.00
0.03
Pyrene ,d'
697.00
9,090.00
0.56
23.73
697.00
0.03
ESBTU FCVi
0.36
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 67 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-33
Field Sample ID
RREC13-33-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.83
0.0783
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.09
1.09
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.08
1.06
447.00
0.00
Acenaphthene (a)
491.00
33400
0.05
0.63
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.09
1.09
452.00
0.00
Anthracene (a)
594.00
1300
0.09
1.09
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.53
6.77
841.00
0.01
Benzo(a)pyrene (a)
965.00
3840
0.62
7.92
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
0.80
10.22
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.53
6.77
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.47
6.00
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
0.53
6.77
981.00
0.01
CI Chrysenes (a)
929.00
0.64
8.17
929.00
0.01
CI Fluorenes(a)
611.00
0.04
0.49
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.67
8.56
770.00
0.01
CI-Naphthalenes (a)
444.00
0.09
1.17
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.47
6.00
670.00
0.01
C2 Chrysenes (a)
1008.00
0.78
9.96
1008.00
0.01
C2 Fluorenes (a)
686.00
0.11
1.40
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.68
8.68
C2-Naphthalenes (a)
510.00
0.35
4.47
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.79
10.09
746.00
0.01
C3 Chrysenes (a)
1112.00
0.42
5.36
1112.00
0.00
C3 Fluorenes (a)
769.00
0.38
4.85
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.51
6.51
949.00
0.01
C3-Naphthalenes(a)
581.00
0.44
5.62
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
1.00
12.77
829.00
0.02
C4 Chrysenes (a)
1214.00
0.19
2.43
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.46
5.87
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.86
10.98
913.00
0.01
Chrysene ,a)
844.00
826
0.65
8.30
844.00
0.01
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.15
1.92
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.75
9.58
707.00
0.01
Fluorene ,a)
538.00
26,000.00
0.09
1.09
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.41
5.24
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.09
1.09
385.00
0.00
Perylene(a)
967.00
431.00
0.19
2.43
967.00
0.00
Phenanthrene 'd'
596
34300
0.40
5.11
596.00
0.01
Pyrene ,d'
697.00
9,090.00
0.92
11.75
697.00
0.02
ESBTU FCVi
0.18
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 68 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-33
Field Sample ID
RREC13-33-0001
Sample Depth
0-1
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.55
0.0355
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.15
4.23
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.18
5.07
447.00
0.01
Acenaphthene (a)
491.00
33400
0.20
5.63
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.08
2.11
452.00
0.00
Anthracene (a)
594.00
1300
0.24
6.76
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.50
42.25
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
1.60
45.07
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
1.70
47.89
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
1.20
33.80
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
0.71
20.00
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.30
36.62
981.00
0.04
CI Chrysenes (a)
929.00
2.00
56.34
929.00
0.06
CI Fluorenes(a)
611.00
0.39
10.99
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.60
101.41
770.00
0.13
CI-Naphthalenes (a)
444.00
0.20
5.63
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.50
126.76
670.00
0.19
C2 Chrysenes (a)
1008.00
3.00
84.51
1008.00
0.08
C2 Fluorenes (a)
686.00
1.70
47.89
686.00
0.07
C2-Fluoranthenes/Pyrenes
3.50
98.59
C2-Naphthalenes (a)
510.00
1.50
42.25
510.00
0.08
C2-Phenanthrenes/Anthracenes (a)
746
6.80
191.55
746.00
0.26
C3 Chrysenes (a)
1112.00
1.40
39.44
1112.00
0.04
C3 Fluorenes (a)
769.00
3.80
107.04
769.00
0.14
C3-Fluoranthenes/Pyrenes
949.00
2.70
76.06
949.00
0.08
C3-Naphthalenes(a)
581.00
6.90
194.37
581.00
0.33
C3-Phenanthrenes/Anthracenes (a)
829.00
12.00
338.03
829.00
0.41
C4 Chrysenes (a)
1214.00
0.66
18.59
1214.00
0.02
C4-Naphthalenes (a)
657.00
7.30
205.63
657.00
0.31
C4-Phenanthrenes/Anthracenes (a)
913.00
7.50
211.27
913.00
0.23
Chrysene ,a)
844.00
826
1.80
50.70
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.18
5.07
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.10
59.15
707.00
0.08
Fluorene ,a)
538.00
26,000.00
0.17
4.79
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.65
18.31
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.18
5.07
385.00
0.01
Perylene(a)
967.00
431.00
0.52
14.65
967.00
0.02
Phenanthrene 'd'
596
34300
1.30
36.62
596.00
0.06
Pyrene ,d'
697.00
9,090.00
2.50
70.42
697.00
0.10
ESBTU FCVi
2.07
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 69 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-33
Field Sample ID
RREC13-33-0103
Sample Depth
1-3
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.19
0.0319
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.94
29.47
446.00
0.07
2-Methylnaphthalene
447.00
154800
0.43
13.48
447.00
0.03
Acenaphthene (a)
491.00
33400
0.47
14.73
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.33
10.34
452.00
0.02
Anthracene (a)
594.00
1300
1.30
40.75
594.00
0.07
Benzo(a)anthracene (a)
841.00
4153
3.80
119.12
841.00
0.14
Benzo(a)pyrene (a)
965.00
3840
2.70
84.64
965.00
0.09
Benzo(b)fluoranthene (a)
979.00
2169
3.00
94.04
979.00
0.10
Benzo(e)pyrene (a)
967.00
4300
2.10
65.83
967.00
0.07
Benzo(g,h,i)perylene (a)
1095.00
648
0.97
30.41
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
2.50
78.37
981.00
0.08
CI Chrysenes (a)
929.00
4.80
150.47
929.00
0.16
CI Fluorenes(a)
611.00
1.30
40.75
611.00
0.07
Cl-Fluoranthenes/Pyrenes (a)
770.00
9.20
288.40
770.00
0.37
CI-Naphthalenes (a)
444.00
0.88
27.59
444.00
0.06
Cl-Phenanthrenes/Anthracenes (a)
670.00
17.00
532.92
670.00
0.80
C2 Chrysenes (a)
1008.00
8.10
253.92
1008.00
0.25
C2 Fluorenes (a)
686.00
4.60
144.20
686.00
0.21
C2-Fluoranthenes/Pyrenes
8.20
257.05
C2-Naphthalenes (a)
510.00
8.20
257.05
510.00
0.50
C2-Phenanthrenes/Anthracenes (a)
746
21.00
658.31
746.00
0.88
C3 Chrysenes (a)
1112.00
3.40
106.58
1112.00
0.10
C3 Fluorenes (a)
769.00
10.00
313.48
769.00
0.41
C3-Fluoranthenes/Pyrenes
949.00
6.70
210.03
949.00
0.22
C3-Naphthalenes(a)
581.00
24.00
752.35
581.00
1.29
C3-Phenanthrenes/Anthracenes (a)
829.00
22.00
689.66
829.00
0.83
C4 Chrysenes (a)
1214.00
1.90
59.56
1214.00
0.05
C4-Naphthalenes (a)
657.00
20.00
626.96
657.00
0.95
C4-Phenanthrenes/Anthracenes (a)
913.00
16.00
501.57
913.00
0.55
Chrysene ,a)
844.00
826
3.90
122.26
844.00
0.14
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.28
8.78
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.80
213.17
707.00
0.30
Fluorene ,a)
538.00
26,000.00
0.90
28.21
538.00
0.05
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.95
29.78
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
0.43
13.48
385.00
0.04
Perylene(a)
967.00
431.00
0.98
30.72
967.00
0.03
Phenanthrene 'd'
596
34300
4.80
150.47
596.00
0.25
Pyrene ,d'
697.00
9,090.00
5.60
175.55
697.00
0.25
ESBTU FCVi
5.85
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 70 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-33
Field Sample ID
RREC13-33-0305
Sample Depth
3-5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.1
0.041
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
2.20
53.66
446.00
0.12
2-Methylnaphthalene
447.00
154800
2.70
65.85
447.00
0.15
Acenaphthene (a)
491.00
33400
1.40
34.15
491.00
0.07
Acenaphthylene (a)
452.00
24000
0.54
13.17
452.00
0.03
Anthracene (a)
594.00
1300
4.50
109.76
594.00
0.18
Benzo(a)anthracene (a)
841.00
4153
6.80
165.85
841.00
0.20
Benzo(a)pyrene (a)
965.00
3840
4.70
114.63
965.00
0.12
Benzo(b)fluoranthene (a)
979.00
2169
3.50
85.37
979.00
0.09
Benzo(e)pyrene (a)
967.00
4300
3.10
75.61
967.00
0.08
Benzo(g,h,i)perylene (a)
1095.00
648
1.80
43.90
1095.00
0.04
Benzo(k)fluoranthene (a)
981.00
1220
3.90
95.12
981.00
0.10
CI Chrysenes (a)
929.00
7.40
180.49
929.00
0.19
CI Fluorenes(a)
611.00
2.00
48.78
611.00
0.08
Cl-Fluoranthenes/Pyrenes (a)
770.00
16.00
390.24
770.00
0.51
CI-Naphthalenes (a)
444.00
3.50
85.37
444.00
0.19
Cl-Phenanthrenes/Anthracenes (a)
670.00
25.00
609.76
670.00
0.91
C2 Chrysenes (a)
1008.00
7.10
173.17
1008.00
0.17
C2 Fluorenes (a)
686.00
5.00
121.95
686.00
0.18
C2-Fluoranthenes/Pyrenes
11.00
268.29
C2-Naphthalenes (a)
510.00
17.00
414.63
510.00
0.81
C2-Phenanthrenes/Anthracenes (a)
746
23.00
560.98
746.00
0.75
C3 Chrysenes (a)
1112.00
3.70
90.24
1112.00
0.08
C3 Fluorenes (a)
769.00
11.00
268.29
769.00
0.35
C3-Fluoranthenes/Pyrenes
949.00
7.30
178.05
949.00
0.19
C3-Naphthalenes(a)
581.00
32.00
780.49
581.00
1.34
C3-Phenanthrenes/Anthracenes (a)
829.00
24.00
585.37
829.00
0.71
C4 Chrysenes (a)
1214.00
2.00
48.78
1214.00
0.04
C4-Naphthalenes (a)
657.00
22.00
536.59
657.00
0.82
C4-Phenanthrenes/Anthracenes (a)
913.00
16.00
390.24
913.00
0.43
Chrysene ,a)
844.00
826
6.10
148.78
844.00
0.18
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.43
10.49
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
10.00
243.90
707.00
0.34
Fluorene ,a)
538.00
26,000.00
2.20
53.66
538.00
0.10
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.50
36.59
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
1.05
25.61
385.00
0.07
Perylene(a)
967.00
431.00
0.88
21.46
967.00
0.02
Phenanthrene 'd'
596
34300
13.00
317.07
596.00
0.53
Pyrene ,d'
697.00
9,090.00
11.00
268.29
697.00
0.38
ESBTU FCVi
6.48
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 71 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-33
Field Sample ID
RREC13-33-0507
Sample Depth
5-7
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.73
0.0773
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
2.30
29.75
446.00
0.07
2-Methylnaphthalene
447.00
154800
3.30
42.69
447.00
0.10
Acenaphthene (a)
491.00
33400
1.80
23.29
491.00
0.05
Acenaphthylene (a)
452.00
24000
0.61
7.89
452.00
0.02
Anthracene (a)
594.00
1300
6.90
89.26
594.00
0.15
Benzo(a)anthracene (a)
841.00
4153
13.00
168.18
841.00
0.20
Benzo(a)pyrene (a)
965.00
3840
10.00
129.37
965.00
0.13
Benzo(b)fluoranthene (a)
979.00
2169
8.70
112.55
979.00
0.11
Benzo(e)pyrene (a)
967.00
4300
6.10
78.91
967.00
0.08
Benzo(g,h,i)perylene (a)
1095.00
648
3.60
46.57
1095.00
0.04
Benzo(k)fluoranthene (a)
981.00
1220
8.40
108.67
981.00
0.11
CI Chrysenes (a)
929.00
9.60
124.19
929.00
0.13
CI Fluorenes(a)
611.00
1.20
15.52
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
21.00
271.67
770.00
0.35
CI-Naphthalenes (a)
444.00
3.80
49.16
444.00
0.11
Cl-Phenanthrenes/Anthracenes (a)
670.00
21.00
271.67
670.00
0.41
C2 Chrysenes (a)
1008.00
8.70
112.55
1008.00
0.11
C2 Fluorenes (a)
686.00
1.50
19.40
686.00
0.03
C2-Fluoranthenes/Pyrenes
9.60
124.19
C2-Naphthalenes (a)
510.00
9.00
116.43
510.00
0.23
C2-Phenanthrenes/Anthracenes (a)
746
11.00
142.30
746.00
0.19
C3 Chrysenes (a)
1112.00
2.50
32.34
1112.00
0.03
C3 Fluorenes (a)
769.00
1.90
24.58
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
4.80
62.10
949.00
0.07
C3-Naphthalenes(a)
581.00
8.60
111.25
581.00
0.19
C3-Phenanthrenes/Anthracenes (a)
829.00
7.60
98.32
829.00
0.12
C4 Chrysenes (a)
1214.00
1.10
14.23
1214.00
0.01
C4-Naphthalenes (a)
657.00
3.80
49.16
657.00
0.07
C4-Phenanthrenes/Anthracenes (a)
913.00
5.20
67.27
913.00
0.07
Chrysene ,a)
844.00
826
12.00
155.24
844.00
0.18
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.10
14.23
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
20.00
258.73
707.00
0.37
Fluorene ,a)
538.00
26,000.00
3.30
42.69
538.00
0.08
Indeno(l,2,3-cd)pyrene ,a)
1115.00
3.20
41.40
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
1.55
20.05
385.00
0.05
Perylene(a)
967.00
431.00
1.90
24.58
967.00
0.03
Phenanthrene 'd'
596
34300
19.00
245.80
596.00
0.41
Pyrene ,d'
697.00
9,090.00
19.00
245.80
697.00
0.35
ESBTU FCVi
3.65
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 72 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-33
Field Sample ID
RREC13-33-0709
Sample Depth
7-9
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.5
0.065
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.00
15.38
446.00
0.03
2-Methylnaphthalene
447.00
154800
1.30
20.00
447.00
0.04
Acenaphthene (a)
491.00
33400
1.20
18.46
491.00
0.04
Acenaphthylene (a)
452.00
24000
0.20
3.08
452.00
0.01
Anthracene (a)
594.00
1300
2.40
36.92
594.00
0.06
Benzo(a)anthracene (a)
841.00
4153
4.60
70.77
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
3.50
53.85
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
2.10
32.31
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.20
33.85
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
1.50
23.08
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
3.20
49.23
981.00
0.05
CI Chrysenes (a)
929.00
4.10
63.08
929.00
0.07
CI Fluorenes(a)
611.00
0.60
9.23
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
9.50
146.15
770.00
0.19
CI-Naphthalenes (a)
444.00
1.60
24.62
444.00
0.06
Cl-Phenanthrenes/Anthracenes (a)
670.00
9.10
140.00
670.00
0.21
C2 Chrysenes (a)
1008.00
3.70
56.92
1008.00
0.06
C2 Fluorenes (a)
686.00
0.86
13.23
686.00
0.02
C2-Fluoranthenes/Pyrenes
5.40
83.08
C2-Naphthalenes (a)
510.00
5.00
76.92
510.00
0.15
C2-Phenanthrenes/Anthracenes (a)
746
5.00
76.92
746.00
0.10
C3 Chrysenes (a)
1112.00
1.20
18.46
1112.00
0.02
C3 Fluorenes (a)
769.00
0.93
14.31
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
2.50
38.46
949.00
0.04
C3-Naphthalenes(a)
581.00
4.90
75.38
581.00
0.13
C3-Phenanthrenes/Anthracenes (a)
829.00
4.10
63.08
829.00
0.08
C4 Chrysenes (a)
1214.00
0.36
5.54
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.80
27.69
657.00
0.04
C4-Phenanthrenes/Anthracenes (a)
913.00
2.10
32.31
913.00
0.04
Chrysene ,a)
844.00
826
4.10
63.08
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.43
6.62
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.40
98.46
707.00
0.14
Fluorene ,a)
538.00
26,000.00
1.50
23.08
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.30
20.00
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.47
7.23
385.00
0.02
Perylene(a)
967.00
431.00
0.74
11.38
967.00
0.01
Phenanthrene 'd'
596
34300
6.70
103.08
596.00
0.17
Pyrene ,d'
697.00
9,090.00
6.80
104.62
697.00
0.15
ESBTU FCVi
1.69
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 73 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-33
Field Sample ID
RREC13-33-0911
Sample Depth
9-11
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.63
0.0963
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.02
0.25
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.05
0.48
447.00
0.00
Acenaphthene (a)
491.00
33400
0.04
0.38
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.02
0.19
452.00
0.00
Anthracene (a)
594.00
1300
0.10
1.04
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.35
3.63
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.31
3.22
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.30
3.12
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.24
2.49
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.13
1.35
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.30
3.12
981.00
0.00
CI Chrysenes (a)
929.00
0.28
2.91
929.00
0.00
CI Fluorenes(a)
611.00
0.03
0.34
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.55
5.71
770.00
0.01
CI-Naphthalenes (a)
444.00
0.04
0.40
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.45
4.67
670.00
0.01
C2 Chrysenes (a)
1008.00
0.26
2.70
1008.00
0.00
C2 Fluorenes (a)
686.00
0.05
0.54
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.29
3.01
C2-Naphthalenes (a)
510.00
0.16
1.66
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.30
3.12
746.00
0.00
C3 Chrysenes (a)
1112.00
0.08
0.84
1112.00
0.00
C3 Fluorenes (a)
769.00
0.09
0.98
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.14
1.45
949.00
0.00
C3-Naphthalenes(a)
581.00
0.27
2.80
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.25
2.60
829.00
0.00
C4 Chrysenes (a)
1214.00
0.03
0.32
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.17
1.77
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.17
1.77
913.00
0.00
Chrysene ,a)
844.00
826
0.34
3.53
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.03
0.35
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.55
5.71
707.00
0.01
Fluorene ,a)
538.00
26,000.00
0.06
0.64
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.11
1.14
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.05
0.48
385.00
0.00
Perylene(a)
967.00
431.00
0.12
1.25
967.00
0.00
Phenanthrene 'd'
596
34300
0.38
3.95
596.00
0.01
Pyrene ,d'
697.00
9,090.00
0.51
5.30
697.00
0.01
ESBTU FCVi
0.08
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 74 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-34
Field Sample ID
RREC13-34-SURF
Sample Depth
0-0.5
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.74
0.0574
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.67
11.67
446.00
0.03
2-Methylnaphthalene
447.00
154800
0.70
12.20
447.00
0.03
Acenaphthene (a)
491.00
33400
0.39
6.79
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.30
5.23
452.00
0.01
Anthracene (a)
594.00
1300
0.60
10.45
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.20
38.33
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
1.80
31.36
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.00
34.84
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
1.70
29.62
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.80
31.36
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
1.20
20.91
981.00
0.02
CI Chrysenes (a)
929.00
3.10
54.01
929.00
0.06
CI Fluorenes(a)
611.00
1.30
22.65
611.00
0.04
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.40
76.66
770.00
0.10
CI-Naphthalenes (a)
444.00
1.00
17.42
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
14.00
243.90
670.00
0.36
C2 Chrysenes (a)
1008.00
3.00
52.26
1008.00
0.05
C2 Fluorenes (a)
686.00
4.40
76.66
686.00
0.11
C2-Fluoranthenes/Pyrenes
4.90
85.37
C2-Naphthalenes (a)
510.00
11.00
191.64
510.00
0.38
C2-Phenanthrenes/Anthracenes (a)
746
19.00
331.01
746.00
0.44
C3 Chrysenes (a)
1112.00
1.70
29.62
1112.00
0.03
C3 Fluorenes (a)
769.00
9.60
167.25
769.00
0.22
C3-Fluoranthenes/Pyrenes
949.00
4.00
69.69
949.00
0.07
C3-Naphthalenes(a)
581.00
24.00
418.12
581.00
0.72
C3-Phenanthrenes/Anthracenes (a)
829.00
17.00
296.17
829.00
0.36
C4 Chrysenes (a)
1214.00
1.10
19.16
1214.00
0.02
C4-Naphthalenes (a)
657.00
24.00
418.12
657.00
0.64
C4-Phenanthrenes/Anthracenes (a)
913.00
10.00
174.22
913.00
0.19
Chrysene ,a)
844.00
826
2.70
47.04
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.60
10.45
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
3.70
64.46
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.50
8.71
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.60
27.87
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
0.30
5.23
385.00
0.01
Perylene(a)
967.00
431.00
0.58
10.10
967.00
0.01
Phenanthrene 'd'
596
34300
3.00
52.26
596.00
0.09
Pyrene ,d'
697.00
9,090.00
4.70
81.88
697.00
0.12
ESBTU FCVi
2.49
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 75 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-34
Field Sample ID
RREC13-34-0001
Sample Depth
0-1
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
11.4
0.114
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.30
11.40
446.00
0.03
2-Methylnaphthalene
447.00
154800
1.80
15.79
447.00
0.04
Acenaphthene (a)
491.00
33400
1.00
8.77
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.55
4.82
452.00
0.01
Anthracene (a)
594.00
1300
1.30
11.40
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
3.60
31.58
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.80
24.56
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.90
25.44
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.50
21.93
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
2.60
22.81
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.20
19.30
981.00
0.02
CI Chrysenes (a)
929.00
4.00
35.09
929.00
0.04
CI Fluorenes(a)
611.00
1.60
14.04
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.60
49.12
770.00
0.06
CI-Naphthalenes (a)
444.00
2.20
19.30
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
15.00
131.58
670.00
0.20
C2 Chrysenes (a)
1008.00
4.40
38.60
1008.00
0.04
C2 Fluorenes (a)
686.00
5.40
47.37
686.00
0.07
C2-Fluoranthenes/Pyrenes
6.50
57.02
C2-Naphthalenes (a)
510.00
19.00
166.67
510.00
0.33
C2-Phenanthrenes/Anthracenes (a)
746
22.00
192.98
746.00
0.26
C3 Chrysenes (a)
1112.00
2.40
21.05
1112.00
0.02
C3 Fluorenes (a)
769.00
12.00
105.26
769.00
0.14
C3-Fluoranthenes/Pyrenes
949.00
5.20
45.61
949.00
0.05
C3-Naphthalenes(a)
581.00
35.00
307.02
581.00
0.53
C3-Phenanthrenes/Anthracenes (a)
829.00
21.00
184.21
829.00
0.22
C4 Chrysenes (a)
1214.00
1.40
12.28
1214.00
0.01
C4-Naphthalenes (a)
657.00
29.00
254.39
657.00
0.39
C4-Phenanthrenes/Anthracenes (a)
913.00
15.00
131.58
913.00
0.14
Chrysene ,a)
844.00
826
4.20
36.84
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.87
7.63
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.30
55.26
707.00
0.08
Fluorene ,a)
538.00
26,000.00
1.10
9.65
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.20
19.30
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.55
4.82
385.00
0.01
Perylene(a)
967.00
431.00
0.91
7.98
967.00
0.01
Phenanthrene 'd'
596
34300
6.50
57.02
596.00
0.10
Pyrene ,d'
697.00
9,090.00
7.30
64.04
697.00
0.09
ESBTU FCVi
1.69
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 76 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-34
Field Sample ID
RREC13-34-0103
Sample Depth
1-3
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
13.3
0.133
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.10
8.27
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.10
8.27
447.00
0.02
Acenaphthene (a)
491.00
33400
1.00
7.52
491.00
0.02
Acenaphthylene (a)
452.00
24000
1.10
8.27
452.00
0.02
Anthracene (a)
594.00
1300
3.10
23.31
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
8.10
60.90
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
6.20
46.62
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
6.10
45.86
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
4.90
36.84
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
5.00
37.59
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
5.90
44.36
981.00
0.05
CI Chrysenes (a)
929.00
6.30
47.37
929.00
0.05
CI Fluorenes(a)
611.00
1.30
9.77
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
8.50
63.91
770.00
0.08
CI-Naphthalenes (a)
444.00
1.90
14.29
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
15.00
112.78
670.00
0.17
C2 Chrysenes (a)
1008.00
6.40
48.12
1008.00
0.05
C2 Fluorenes (a)
686.00
4.10
30.83
686.00
0.04
C2-Fluoranthenes/Pyrenes
7.70
57.89
C2-Naphthalenes (a)
510.00
14.00
105.26
510.00
0.21
C2-Phenanthrenes/Anthracenes (a)
746
18.00
135.34
746.00
0.18
C3 Chrysenes (a)
1112.00
2.80
21.05
1112.00
0.02
C3 Fluorenes (a)
769.00
9.30
69.92
769.00
0.09
C3-Fluoranthenes/Pyrenes
949.00
5.80
43.61
949.00
0.05
C3-Naphthalenes(a)
581.00
25.00
187.97
581.00
0.32
C3-Phenanthrenes/Anthracenes (a)
829.00
17.00
127.82
829.00
0.15
C4 Chrysenes (a)
1214.00
1.60
12.03
1214.00
0.01
C4-Naphthalenes (a)
657.00
18.00
135.34
657.00
0.21
C4-Phenanthrenes/Anthracenes (a)
913.00
12.00
90.23
913.00
0.10
Chrysene ,a)
844.00
826
8.40
63.16
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.50
11.28
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
14.00
105.26
707.00
0.15
Fluorene ,a)
538.00
26,000.00
1.90
14.29
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
4.50
33.83
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
1.10
8.27
385.00
0.02
Perylene(a)
967.00
431.00
2.00
15.04
967.00
0.02
Phenanthrene 'd'
596
34300
12.00
90.23
596.00
0.15
Pyrene ,d'
697.00
9,090.00
15.00
112.78
697.00
0.16
ESBTU FCVi
1.84
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 77 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-34
Field Sample ID
RREC13-34-0305
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.72
0.0972
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.30
13.37
446.00
0.03
2-Methylnaphthalene
447.00
154800
1.30
13.37
447.00
0.03
Acenaphthene (a)
491.00
33400
1.30
13.37
491.00
0.03
Acenaphthylene (a)
452.00
24000
1.30
13.37
452.00
0.03
Anthracene (a)
594.00
1300
3.50
36.01
594.00
0.06
Benzo(a)anthracene (a)
841.00
4153
6.80
69.96
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
4.60
47.33
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
4.60
47.33
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
4.00
41.15
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
3.30
33.95
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
4.20
43.21
981.00
0.04
CI Chrysenes (a)
929.00
5.90
60.70
929.00
0.07
CI Fluorenes(a)
611.00
1.60
16.46
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
9.30
95.68
770.00
0.12
CI-Naphthalenes (a)
444.00
2.40
24.69
444.00
0.06
Cl-Phenanthrenes/Anthracenes (a)
670.00
15.00
154.32
670.00
0.23
C2 Chrysenes (a)
1008.00
6.40
65.84
1008.00
0.07
C2 Fluorenes (a)
686.00
4.30
44.24
686.00
0.06
C2-Fluoranthenes/Pyrenes
8.70
89.51
C2-Naphthalenes (a)
510.00
15.00
154.32
510.00
0.30
C2-Phenanthrenes/Anthracenes (a)
746
21.00
216.05
746.00
0.29
C3 Chrysenes (a)
1112.00
3.40
34.98
1112.00
0.03
C3 Fluorenes (a)
769.00
10.00
102.88
769.00
0.13
C3-Fluoranthenes/Pyrenes
949.00
6.90
70.99
949.00
0.07
C3-Naphthalenes(a)
581.00
27.00
277.78
581.00
0.48
C3-Phenanthrenes/Anthracenes (a)
829.00
23.00
236.63
829.00
0.29
C4 Chrysenes (a)
1214.00
1.90
19.55
1214.00
0.02
C4-Naphthalenes (a)
657.00
25.00
257.20
657.00
0.39
C4-Phenanthrenes/Anthracenes (a)
913.00
15.00
154.32
913.00
0.17
Chrysene ,a)
844.00
826
6.60
67.90
844.00
0.08
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.30
13.37
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
17.00
174.90
707.00
0.25
Fluorene ,a)
538.00
26,000.00
4.00
41.15
538.00
0.08
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.80
28.81
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
1.30
13.37
385.00
0.03
Perylene(a)
967.00
431.00
1.30
13.37
967.00
0.01
Phenanthrene 'd'
596
34300
18.00
185.19
596.00
0.31
Pyrene ,d'
697.00
9,090.00
18.00
185.19
697.00
0.27
ESBTU FCVi
2.81
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 78 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-34
Field Sample ID
RREC13-34-0507
Sample Depth
5-7
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
12.1
0.121
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.80
6.61
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.80
6.61
447.00
0.01
Acenaphthene (a)
491.00
33400
0.80
6.61
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.80
6.61
452.00
0.01
Anthracene (a)
594.00
1300
2.10
17.36
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
5.90
48.76
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
4.20
34.71
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
4.10
33.88
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
3.60
29.75
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
2.90
23.97
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
3.80
31.40
981.00
0.03
CI Chrysenes (a)
929.00
6.50
53.72
929.00
0.06
CI Fluorenes(a)
611.00
1.20
9.92
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
8.30
68.60
770.00
0.09
CI-Naphthalenes (a)
444.00
2.00
16.53
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
13.00
107.44
670.00
0.16
C2 Chrysenes (a)
1008.00
6.20
51.24
1008.00
0.05
C2 Fluorenes (a)
686.00
3.20
26.45
686.00
0.04
C2-Fluoranthenes/Pyrenes
7.80
64.46
C2-Naphthalenes (a)
510.00
12.00
99.17
510.00
0.19
C2-Phenanthrenes/Anthracenes (a)
746
19.00
157.02
746.00
0.21
C3 Chrysenes (a)
1112.00
2.80
23.14
1112.00
0.02
C3 Fluorenes (a)
769.00
7.70
63.64
769.00
0.08
C3-Fluoranthenes/Pyrenes
949.00
6.30
52.07
949.00
0.05
C3-Naphthalenes(a)
581.00
20.00
165.29
581.00
0.28
C3-Phenanthrenes/Anthracenes (a)
829.00
22.00
181.82
829.00
0.22
C4 Chrysenes (a)
1214.00
1.70
14.05
1214.00
0.01
C4-Naphthalenes (a)
657.00
18.00
148.76
657.00
0.23
C4-Phenanthrenes/Anthracenes (a)
913.00
13.00
107.44
913.00
0.12
Chrysene ,a)
844.00
826
6.10
50.41
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.80
6.61
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
10.00
82.64
707.00
0.12
Fluorene ,a)
538.00
26,000.00
3.20
26.45
538.00
0.05
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.60
21.49
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.80
6.61
385.00
0.02
Perylene(a)
967.00
431.00
0.80
6.61
967.00
0.01
Phenanthrene 'd'
596
34300
8.10
66.94
596.00
0.11
Pyrene ,d'
697.00
9,090.00
12.00
99.17
697.00
0.14
ESBTU FCVi
1.73
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 79 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-34
Field Sample ID
RREC13-34-0709
Sample Depth
7-9
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.98
0.0898
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.80
8.91
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.80
8.91
447.00
0.02
Acenaphthene (a)
491.00
33400
0.80
8.91
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.80
8.91
452.00
0.02
Anthracene (a)
594.00
1300
2.60
28.95
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
6.70
74.61
841.00
0.09
Benzo(a)pyrene (a)
965.00
3840
4.60
51.22
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
4.20
46.77
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
3.70
41.20
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
3.30
36.75
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
4.10
45.66
981.00
0.05
CI Chrysenes (a)
929.00
7.90
87.97
929.00
0.09
CI Fluorenes(a)
611.00
1.20
13.36
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
9.10
101.34
770.00
0.13
CI-Naphthalenes (a)
444.00
1.50
16.70
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
15.00
167.04
670.00
0.25
C2 Chrysenes (a)
1008.00
6.90
76.84
1008.00
0.08
C2 Fluorenes (a)
686.00
3.20
35.63
686.00
0.05
C2-Fluoranthenes/Pyrenes
8.50
94.65
C2-Naphthalenes (a)
510.00
8.20
91.31
510.00
0.18
C2-Phenanthrenes/Anthracenes (a)
746
25.00
278.40
746.00
0.37
C3 Chrysenes (a)
1112.00
3.60
40.09
1112.00
0.04
C3 Fluorenes (a)
769.00
8.80
98.00
769.00
0.13
C3-Fluoranthenes/Pyrenes
949.00
7.00
77.95
949.00
0.08
C3-Naphthalenes(a)
581.00
14.00
155.90
581.00
0.27
C3-Phenanthrenes/Anthracenes (a)
829.00
25.00
278.40
829.00
0.34
C4 Chrysenes (a)
1214.00
1.80
20.04
1214.00
0.02
C4-Naphthalenes (a)
657.00
17.00
189.31
657.00
0.29
C4-Phenanthrenes/Anthracenes (a)
913.00
18.00
200.45
913.00
0.22
Chrysene ,a)
844.00
826
7.30
81.29
844.00
0.10
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.80
8.91
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
11.00
122.49
707.00
0.17
Fluorene ,a)
538.00
26,000.00
2.40
26.73
538.00
0.05
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.90
32.29
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
0.80
8.91
385.00
0.02
Perylene(a)
967.00
431.00
0.80
8.91
967.00
0.01
Phenanthrene 'd'
596
34300
7.10
79.06
596.00
0.13
Pyrene ,d'
697.00
9,090.00
12.00
133.63
697.00
0.19
ESBTU FCVi
2.62
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 80 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-34
Field Sample ID
RREC13-34-0911
Sample Depth
9-11
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.72
0.0972
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.85
8.74
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.90
19.55
447.00
0.04
Acenaphthene (a)
491.00
33400
0.85
8.74
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.85
8.74
452.00
0.02
Anthracene (a)
594.00
1300
2.60
26.75
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
6.60
67.90
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
4.30
44.24
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
3.90
40.12
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
3.60
37.04
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
3.30
33.95
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
3.60
37.04
981.00
0.04
CI Chrysenes (a)
929.00
9.80
100.82
929.00
0.11
CI Fluorenes(a)
611.00
1.40
14.40
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
11.00
113.17
770.00
0.15
CI-Naphthalenes (a)
444.00
2.60
26.75
444.00
0.06
Cl-Phenanthrenes/Anthracenes (a)
670.00
18.00
185.19
670.00
0.28
C2 Chrysenes (a)
1008.00
12.00
123.46
1008.00
0.12
C2 Fluorenes (a)
686.00
4.20
43.21
686.00
0.06
C2-Fluoranthenes/Pyrenes
13.00
133.74
C2-Naphthalenes (a)
510.00
14.00
144.03
510.00
0.28
C2-Phenanthrenes/Anthracenes (a)
746
33.00
339.51
746.00
0.46
C3 Chrysenes (a)
1112.00
6.40
65.84
1112.00
0.06
C3 Fluorenes (a)
769.00
12.00
123.46
769.00
0.16
C3-Fluoranthenes/Pyrenes
949.00
13.00
133.74
949.00
0.14
C3-Naphthalenes(a)
581.00
24.00
246.91
581.00
0.42
C3-Phenanthrenes/Anthracenes (a)
829.00
44.00
452.67
829.00
0.55
C4 Chrysenes (a)
1214.00
3.60
37.04
1214.00
0.03
C4-Naphthalenes (a)
657.00
24.00
246.91
657.00
0.38
C4-Phenanthrenes/Anthracenes (a)
913.00
33.00
339.51
913.00
0.37
Chrysene ,a)
844.00
826
7.90
81.28
844.00
0.10
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.85
8.74
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
9.70
99.79
707.00
0.14
Fluorene ,a)
538.00
26,000.00
2.30
23.66
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.70
27.78
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.85
8.74
385.00
0.02
Perylene(a)
967.00
431.00
0.85
8.74
967.00
0.01
Phenanthrene 'd'
596
34300
8.50
87.45
596.00
0.15
Pyrene ,d'
697.00
9,090.00
13.00
133.74
697.00
0.19
ESBTU FCVi
3.08
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 81 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-35
Field Sample ID
RREC13-35-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.03
0.0503
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.47
9.24
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.34
6.76
447.00
0.02
Acenaphthene (a)
491.00
33400
0.36
7.16
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.47
9.24
452.00
0.02
Anthracene (a)
594.00
1300
1.00
19.88
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.00
59.64
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
2.50
49.70
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
2.80
55.67
979.00
0.06
Benzo(e)pyrene (a)
967.00
4300
2.00
39.76
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
1.40
27.83
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
2.40
47.71
981.00
0.05
CI Chrysenes (a)
929.00
2.90
57.65
929.00
0.06
CI Fluorenes(a)
611.00
0.20
3.98
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.00
59.64
770.00
0.08
CI-Naphthalenes (a)
444.00
0.44
8.75
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.80
55.67
670.00
0.08
C2 Chrysenes (a)
1008.00
2.20
43.74
1008.00
0.04
C2 Fluorenes (a)
686.00
0.37
7.36
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.60
51.69
C2-Naphthalenes (a)
510.00
1.70
33.80
510.00
0.07
C2-Phenanthrenes/Anthracenes (a)
746
3.20
63.62
746.00
0.09
C3 Chrysenes (a)
1112.00
1.10
21.87
1112.00
0.02
C3 Fluorenes (a)
769.00
0.62
12.33
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.50
29.82
949.00
0.03
C3-Naphthalenes(a)
581.00
2.10
41.75
581.00
0.07
C3-Phenanthrenes/Anthracenes (a)
829.00
3.10
61.63
829.00
0.07
C4 Chrysenes (a)
1214.00
0.42
8.35
1214.00
0.01
C4-Naphthalenes (a)
657.00
1.50
29.82
657.00
0.05
C4-Phenanthrenes/Anthracenes (a)
913.00
2.40
47.71
913.00
0.05
Chrysene ,a)
844.00
826
3.10
61.63
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.58
11.53
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
5.00
99.40
707.00
0.14
Fluorene ,a)
538.00
26,000.00
0.47
9.24
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.30
25.84
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
1.10
21.87
385.00
0.06
Perylene(a)
967.00
431.00
0.65
12.92
967.00
0.01
Phenanthrene 'd'
596
34300
3.10
61.63
596.00
0.10
Pyrene ,d'
697.00
9,090.00
4.80
95.43
697.00
0.14
ESBTU FCVi
1.34
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 82 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-35
Field Sample ID
RREC13-35-0001
Sample Depth
0-1
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.91
0.0491
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.20
24.44
446.00
0.05
2-Methylnaphthalene
447.00
154800
1.20
24.44
447.00
0.05
Acenaphthene (a)
491.00
33400
1.70
34.62
491.00
0.07
Acenaphthylene (a)
452.00
24000
1.20
24.44
452.00
0.05
Anthracene (a)
594.00
1300
5.60
114.05
594.00
0.19
Benzo(a)anthracene (a)
841.00
4153
7.00
142.57
841.00
0.17
Benzo(a)pyrene (a)
965.00
3840
5.00
101.83
965.00
0.11
Benzo(b)fluoranthene (a)
979.00
2169
3.80
77.39
979.00
0.08
Benzo(e)pyrene (a)
967.00
4300
3.40
69.25
967.00
0.07
Benzo(g,h,i)perylene (a)
1095.00
648
3.00
61.10
1095.00
0.06
Benzo(k)fluoranthene (a)
981.00
1220
3.20
65.17
981.00
0.07
CI Chrysenes (a)
929.00
7.00
142.57
929.00
0.15
CI Fluorenes(a)
611.00
1.20
24.44
611.00
0.04
Cl-Fluoranthenes/Pyrenes (a)
770.00
12.00
244.40
770.00
0.32
CI-Naphthalenes (a)
444.00
1.40
28.51
444.00
0.06
Cl-Phenanthrenes/Anthracenes (a)
670.00
17.00
346.23
670.00
0.52
C2 Chrysenes (a)
1008.00
3.80
77.39
1008.00
0.08
C2 Fluorenes (a)
686.00
1.10
22.40
686.00
0.03
C2-Fluoranthenes/Pyrenes
6.10
124.24
C2-Naphthalenes (a)
510.00
7.30
148.68
510.00
0.29
C2-Phenanthrenes/Anthracenes (a)
746
9.10
185.34
746.00
0.25
C3 Chrysenes (a)
1112.00
1.80
36.66
1112.00
0.03
C3 Fluorenes (a)
769.00
1.50
30.55
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
2.60
52.95
949.00
0.06
C3-Naphthalenes(a)
581.00
6.10
124.24
581.00
0.21
C3-Phenanthrenes/Anthracenes (a)
829.00
4.80
97.76
829.00
0.12
C4 Chrysenes (a)
1214.00
0.75
15.27
1214.00
0.01
C4-Naphthalenes (a)
657.00
2.30
46.84
657.00
0.07
C4-Phenanthrenes/Anthracenes (a)
913.00
4.60
93.69
913.00
0.10
Chrysene ,a)
844.00
826
6.40
130.35
844.00
0.15
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.94
19.14
1123.00
0.02
Fluoranthene ,a)
707.00
23,870.00
11.00
224.03
707.00
0.32
Fluorene ,a)
538.00
26,000.00
2.70
54.99
538.00
0.10
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.40
48.88
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
1.20
24.44
385.00
0.06
Perylene(a)
967.00
431.00
1.00
20.37
967.00
0.02
Phenanthrene 'd'
596
34300
16.00
325.87
596.00
0.55
Pyrene ,d'
697.00
9,090.00
15.00
305.50
697.00
0.44
ESBTU FCVi
3.98
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 83 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-35
Field Sample ID
RREC13-35-0103
Sample Depth
1-3
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
0.78
0.0078
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.21
26.45
446.00
0.06
2-Methylnaphthalene
447.00
154800
0.21
26.45
447.00
0.06
Acenaphthene (a)
491.00
33400
0.42
54.19
491.00
0.11
Acenaphthylene (a)
452.00
24000
0.21
26.45
452.00
0.06
Anthracene (a)
594.00
1300
0.95
122.58
594.00
0.21
Benzo(a)anthracene (a)
841.00
4153
1.30
167.74
841.00
0.20
Benzo(a)pyrene (a)
965.00
3840
1.00
129.03
965.00
0.13
Benzo(b)fluoranthene (a)
979.00
2169
0.61
78.71
979.00
0.08
Benzo(e)pyrene (a)
967.00
4300
0.64
82.58
967.00
0.09
Benzo(g,h,i)perylene (a)
1095.00
648
0.59
76.13
1095.00
0.07
Benzo(k)fluoranthene (a)
981.00
1220
0.73
94.19
981.00
0.10
CI Chrysenes (a)
929.00
1.20
154.84
929.00
0.17
CI Fluorenes(a)
611.00
0.24
30.97
611.00
0.05
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.10
270.97
770.00
0.35
CI-Naphthalenes (a)
444.00
0.21
27.10
444.00
0.06
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.90
374.19
670.00
0.56
C2 Chrysenes (a)
1008.00
0.66
85.16
1008.00
0.08
C2 Fluorenes (a)
686.00
0.21
27.10
686.00
0.04
C2-Fluoranthenes/Pyrenes
1.00
129.03
C2-Naphthalenes (a)
510.00
1.00
129.03
510.00
0.25
C2-Phenanthrenes/Anthracenes (a)
746
1.50
193.55
746.00
0.26
C3 Chrysenes (a)
1112.00
0.28
36.13
1112.00
0.03
C3 Fluorenes (a)
769.00
0.26
33.55
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
0.47
60.65
949.00
0.06
C3-Naphthalenes(a)
581.00
1.10
141.94
581.00
0.24
C3-Phenanthrenes/Anthracenes (a)
829.00
0.84
108.39
829.00
0.13
C4 Chrysenes (a)
1214.00
0.12
15.48
1214.00
0.01
C4-Naphthalenes (a)
657.00
0.42
54.19
657.00
0.08
C4-Phenanthrenes/Anthracenes (a)
913.00
0.58
74.84
913.00
0.08
Chrysene ,a)
844.00
826
1.20
154.84
844.00
0.18
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.19
24.52
1123.00
0.02
Fluoranthene ,a)
707.00
23,870.00
2.10
270.97
707.00
0.38
Fluorene ,a)
538.00
26,000.00
0.66
85.16
538.00
0.16
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.46
59.35
1115.00
0.05
Naphthalene ,a)
385.00
61,700.00
0.21
26.45
385.00
0.07
Perylene(a)
967.00
431.00
0.22
28.39
967.00
0.03
Phenanthrene 'd'
596
34300
2.70
348.39
596.00
0.58
Pyrene ,d'
697.00
9,090.00
2.80
361.29
697.00
0.52
ESBTU FCVi
4.56
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 84 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-35
Field Sample ID
RREC13-35-0305
Sample Depth
3-5
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
0.13
0.0013
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
1.55
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
1.55
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
3.41
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.00
1.55
452.00
0.00
Anthracene (a)
594.00
1300
0.01
10.08
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
0.02
16.28
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
0.02
12.40
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
0.01
9.30
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.01
9.30
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
8.53
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
0.01
7.44
981.00
0.01
CI Chrysenes (a)
929.00
0.02
16.28
929.00
0.02
CI Fluorenes(a)
611.00
0.00
2.40
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.03
23.26
770.00
0.03
CI-Naphthalenes (a)
444.00
0.00
2.87
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.04
31.01
670.00
0.05
C2 Chrysenes (a)
1008.00
0.01
9.30
1008.00
0.01
C2 Fluorenes (a)
686.00
0.00
2.17
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.02
12.40
C2-Naphthalenes (a)
510.00
0.02
11.63
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
0.02
18.60
746.00
0.02
C3 Chrysenes (a)
1112.00
0.01
4.34
1112.00
0.00
C3 Fluorenes (a)
769.00
0.00
3.41
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.01
6.74
949.00
0.01
C3-Naphthalenes(a)
581.00
0.02
12.40
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.02
11.63
829.00
0.01
C4 Chrysenes (a)
1214.00
0.00
1.86
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.01
6.12
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.01
7.75
913.00
0.01
Chrysene ,a)
844.00
826
0.02
13.18
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
2.71
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.03
21.71
707.00
0.03
Fluorene ,a)
538.00
26,000.00
0.01
5.89
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.01
6.43
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.00
1.55
385.00
0.00
Perylene(a)
967.00
431.00
0.03
25.58
967.00
0.03
Phenanthrene 'd'
596
34300
0.04
28.68
596.00
0.05
Pyrene ,d'
697.00
9,090.00
0.04
31.01
697.00
0.04
ESBTU FCVi
0.42
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
I:\WO\START3\451\41807TBL3 -4 .XLS
1 of 1
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 85 of 85
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-36
Field Sample ID
RREC13-36-SURF
Sample Depth
0-0.5
Sample Date
10/28/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
13.9
0.139
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
1.20
8.63
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.08
0.58
447.00
0.00
Acenaphthene (a)
491.00
33400
0.20
1.44
491.00
0.00
Acenaphthylene (a)
452.00
24000
1.20
8.63
452.00
0.02
Anthracene (a)
594.00
1300
0.62
4.46
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
4.40
31.65
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
5.00
35.97
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
8.30
59.71
979.00
0.06
Benzo(e)pyrene (a)
967.00
4300
5.30
38.13
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
3.50
25.18
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
6.90
49.64
981.00
0.05
CI Chrysenes (a)
929.00
2.70
19.42
929.00
0.02
CI Fluorenes(a)
611.00
1.20
8.63
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.00
35.97
770.00
0.05
CI-Naphthalenes (a)
444.00
1.20
8.63
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.60
11.51
670.00
0.02
C2 Chrysenes (a)
1008.00
3.10
22.30
1008.00
0.02
C2 Fluorenes (a)
686.00
1.20
8.63
686.00
0.01
C2-Fluoranthenes/Pyrenes
3.30
23.74
C2-Naphthalenes (a)
510.00
0.34
2.45
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
1.00
7.19
746.00
0.01
C3 Chrysenes (a)
1112.00
1.70
12.23
1112.00
0.01
C3 Fluorenes (a)
769.00
0.27
1.94
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
2.30
16.55
949.00
0.02
C3-Naphthalenes(a)
581.00
0.44
3.17
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
1.00
7.19
829.00
0.01
C4 Chrysenes (a)
1214.00
0.56
4.03
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.36
2.59
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.65
4.68
913.00
0.01
Chrysene ,a)
844.00
826
7.10
51.08
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.69
4.96
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
15.00
107.91
707.00
0.15
Fluorene ,a)
538.00
26,000.00
0.30
2.16
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.90
20.86
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
1.20
8.63
385.00
0.02
Perylene(a)
967.00
431.00
1.40
10.07
967.00
0.01
Phenanthrene 'd'
596
34300
4.20
30.22
596.00
0.05
Pyrene ,d'
697.00
9,090.00
9.60
69.06
697.00
0.10
ESBTU FCVi
0.82
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 1 of87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-36
Field Sample ID
RREC13-36-0001
Sample Depth
0-1
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.08
0.0808
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.75
9.28
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.14
1.73
447.00
0.00
Acenaphthene (a)
491.00
33400
0.27
3.34
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.75
9.28
452.00
0.02
Anthracene (a)
594.00
1300
0.75
9.28
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
3.30
40.84
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
3.30
40.84
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
4.80
59.41
979.00
0.06
Benzo(e)pyrene (a)
967.00
4300
3.30
40.84
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.50
30.94
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
3.70
45.79
981.00
0.05
CI Chrysenes (a)
929.00
2.70
33.42
929.00
0.04
CI Fluorenes(a)
611.00
0.24
2.97
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.40
42.08
770.00
0.05
CI-Naphthalenes (a)
444.00
0.17
2.10
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.40
29.70
670.00
0.04
C2 Chrysenes (a)
1008.00
2.30
28.47
1008.00
0.03
C2 Fluorenes (a)
686.00
0.62
7.67
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.70
33.42
C2-Naphthalenes (a)
510.00
1.60
19.80
510.00
0.04
C2-Phenanthrenes/Anthracenes (a)
746
3.20
39.60
746.00
0.05
C3 Chrysenes (a)
1112.00
0.94
11.63
1112.00
0.01
C3 Fluorenes (a)
769.00
1.60
19.80
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
1.70
21.04
949.00
0.02
C3-Naphthalenes(a)
581.00
3.40
42.08
581.00
0.07
C3-Phenanthrenes/Anthracenes (a)
829.00
3.10
38.37
829.00
0.05
C4 Chrysenes (a)
1214.00
0.52
6.44
1214.00
0.01
C4-Naphthalenes (a)
657.00
3.00
37.13
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
2.20
27.23
913.00
0.03
Chrysene ,a)
844.00
826
4.50
55.69
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.82
10.15
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
8.00
99.01
707.00
0.14
Fluorene ,a)
538.00
26,000.00
0.75
9.28
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.40
29.70
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
0.75
9.28
385.00
0.02
Perylene(a)
967.00
431.00
0.91
11.26
967.00
0.01
Phenanthrene 'd'
596
34300
3.30
40.84
596.00
0.07
Pyrene ,d'
697.00
9,090.00
7.90
97.77
697.00
0.14
ESBTU FCVi
1.09
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 2 of87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-36
Field Sample ID
RREC13-36-0103
Sample Depth
1-3
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.74
0.0674
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.29
4.23
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.24
3.56
447.00
0.01
Acenaphthene (a)
491.00
33400
0.46
6.82
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.29
4.23
452.00
0.01
Anthracene (a)
594.00
1300
0.60
8.90
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
1.90
28.19
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.40
20.77
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.80
26.71
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.40
20.77
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.20
17.80
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.30
19.29
981.00
0.02
CI Chrysenes (a)
929.00
2.40
35.61
929.00
0.04
CI Fluorenes(a)
611.00
0.60
8.90
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.10
45.99
770.00
0.06
CI-Naphthalenes (a)
444.00
0.32
4.75
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.50
66.77
670.00
0.10
C2 Chrysenes (a)
1008.00
2.80
41.54
1008.00
0.04
C2 Fluorenes (a)
686.00
1.50
22.26
686.00
0.03
C2-Fluoranthenes/Pyrenes
3.20
47.48
C2-Naphthalenes (a)
510.00
4.20
62.31
510.00
0.12
C2-Phenanthrenes/Anthracenes (a)
746
7.10
105.34
746.00
0.14
C3 Chrysenes (a)
1112.00
1.40
20.77
1112.00
0.02
C3 Fluorenes (a)
769.00
3.40
50.45
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
2.50
37.09
949.00
0.04
C3-Naphthalenes(a)
581.00
10.00
148.37
581.00
0.26
C3-Phenanthrenes/Anthracenes (a)
829.00
7.40
109.79
829.00
0.13
C4 Chrysenes (a)
1214.00
0.85
12.61
1214.00
0.01
C4-Naphthalenes (a)
657.00
8.90
132.05
657.00
0.20
C4-Phenanthrenes/Anthracenes (a)
913.00
5.00
74.18
913.00
0.08
Chrysene ,a)
844.00
826
2.30
34.12
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.43
6.38
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
3.30
48.96
707.00
0.07
Fluorene ,a)
538.00
26,000.00
0.92
13.65
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
16.32
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.29
4.23
385.00
0.01
Perylene(a)
967.00
431.00
0.50
7.42
967.00
0.01
Phenanthrene 'd'
596
34300
3.10
45.99
596.00
0.08
Pyrene ,d'
697.00
9,090.00
3.80
56.38
697.00
0.08
ESBTU FCVi
1.14
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 3 of87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-37
Field Sample ID
RREC13-37-SURF
Sample Depth
0-0.5
Sample Date
10/28/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry
wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6
0.06
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.09
1.50
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.14
2.33
447.00
0.01
Acenaphthene (a)
491.00
33400
0.36
6.00
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.37
6.17
452.00
0.01
Anthracene (a)
594.00
1300
1.60
26.67
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
6.50
108.33
841.00
0.13
Benzo(a)pyrene (a)
965.00
3840
6.50
108.33
965.00
0.11
Benzo(b)fluoranthene (a)
979.00
2169
5.80
96.67
979.00
0.10
Benzo(e)pyrene (a)
967.00
4300
3.90
65.00
967.00
0.07
Benzo(g,h,i)perylene (a)
1095.00
648
2.70
45.00
1095.00
0.04
Benzo(k)fluoranthene (a)
981.00
1220
5.50
91.67
981.00
0.09
CI Chrysenes (a)
929.00
3.40
56.67
929.00
0.06
CI Fluorenes(a)
611.00
0.80
13.33
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.00
100.00
770.00
0.13
CI-Naphthalenes (a)
444.00
0.80
13.33
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.90
48.33
670.00
0.07
C2 Chrysenes (a)
1008.00
2.40
40.00
1008.00
0.04
C2 Fluorenes (a)
686.00
0.80
13.33
686.00
0.02
C2-Fluoranthenes/Pyrenes
2.40
40.00
C2-Naphthalenes (a)
510.00
0.56
9.33
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
1.70
28.33
746.00
0.04
C3 Chrysenes (a)
1112.00
0.99
16.50
1112.00
0.01
C3 Fluorenes (a)
769.00
0.32
5.33
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
1.20
20.00
949.00
0.02
C3-Naphthalenes(a)
581.00
0.63
10.50
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
1.50
25.00
829.00
0.03
C4 Chrysenes (a)
1214.00
0.18
3.00
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.40
6.67
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.78
13.00
913.00
0.01
Chrysene ,a)
844.00
826
5.40
90.00
844.00
0.11
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.68
11.33
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
11.00
183.33
707.00
0.26
Fluorene ,a)
538.00
26,000.00
0.65
10.83
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.40
40.00
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
0.80
13.33
385.00
0.03
Perylene(a)
967.00
431.00
1.70
28.33
967.00
0.03
Phenanthrene 'd'
596
34300
5.40
90.00
596.00
0.15
Pyrene ,d'
697.00
9,090.00
6.90
115.00
697.00
0.16
ESBTU FCVi
1.76
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 4 of87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-37
Field Sample ID
RREC13-37-0001
Sample Depth
0-1
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.73
0.0573
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.57
9.95
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.27
4.71
447.00
0.01
Acenaphthene (a)
491.00
33400
1.70
29.67
491.00
0.06
Acenaphthylene (a)
452.00
24000
0.90
15.71
452.00
0.03
Anthracene (a)
594.00
1300
3.30
57.59
594.00
0.10
Benzo(a)anthracene (a)
841.00
4153
7.50
130.89
841.00
0.16
Benzo(a)pyrene (a)
965.00
3840
6.70
116.93
965.00
0.12
Benzo(b)fluoranthene (a)
979.00
2169
5.20
90.75
979.00
0.09
Benzo(e)pyrene (a)
967.00
4300
4.40
76.79
967.00
0.08
Benzo(g,h,i)perylene (a)
1095.00
648
3.40
59.34
1095.00
0.05
Benzo(k)fluoranthene (a)
981.00
1220
4.20
73.30
981.00
0.07
CI Chrysenes (a)
929.00
8.60
150.09
929.00
0.16
CI Fluorenes(a)
611.00
0.81
14.14
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
12.00
209.42
770.00
0.27
CI-Naphthalenes (a)
444.00
0.60
10.47
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
12.00
209.42
670.00
0.31
C2 Chrysenes (a)
1008.00
5.30
92.50
1008.00
0.09
C2 Fluorenes (a)
686.00
1.10
19.20
686.00
0.03
C2-Fluoranthenes/Pyrenes
7.40
129.14
C2-Naphthalenes (a)
510.00
5.30
92.50
510.00
0.18
C2-Phenanthrenes/Anthracenes (a)
746
7.70
134.38
746.00
0.18
C3 Chrysenes (a)
1112.00
2.10
36.65
1112.00
0.03
C3 Fluorenes (a)
769.00
1.40
24.43
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
3.50
61.08
949.00
0.06
C3-Naphthalenes(a)
581.00
5.50
95.99
581.00
0.17
C3-Phenanthrenes/Anthracenes (a)
829.00
5.80
101.22
829.00
0.12
C4 Chrysenes (a)
1214.00
0.99
17.28
1214.00
0.01
C4-Naphthalenes (a)
657.00
2.20
38.39
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
3.80
66.32
913.00
0.07
Chrysene ,a)
844.00
826
7.00
122.16
844.00
0.14
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.20
20.94
1123.00
0.02
Fluoranthene ,a)
707.00
23,870.00
8.20
143.11
707.00
0.20
Fluorene ,a)
538.00
26,000.00
1.50
26.18
538.00
0.05
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.90
50.61
1115.00
0.05
Naphthalene ,a)
385.00
61,700.00
0.90
15.71
385.00
0.04
Perylene(a)
967.00
431.00
1.30
22.69
967.00
0.02
Phenanthrene 'd'
596
34300
6.70
116.93
596.00
0.20
Pyrene ,d'
697.00
9,090.00
12.00
209.42
697.00
0.30
ESBTU FCVi
2.83
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 5 of87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-37
Field Sample ID
RREC13-37-0103
Sample Depth
1-3
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.62
0.0362
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.75
20.72
446.00
0.05
2-Methylnaphthalene
447.00
154800
0.14
3.87
447.00
0.01
Acenaphthene (a)
491.00
33400
2.10
58.01
491.00
0.12
Acenaphthylene (a)
452.00
24000
0.33
9.12
452.00
0.02
Anthracene (a)
594.00
1300
1.60
44.20
594.00
0.07
Benzo(a)anthracene (a)
841.00
4153
2.30
63.54
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
2.10
58.01
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
1.30
35.91
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
1.30
35.91
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
0.94
25.97
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.40
38.67
981.00
0.04
CI Chrysenes (a)
929.00
2.40
66.30
929.00
0.07
CI Fluorenes(a)
611.00
0.49
13.54
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.90
107.73
770.00
0.14
CI-Naphthalenes (a)
444.00
0.64
17.68
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
5.20
143.65
670.00
0.21
C2 Chrysenes (a)
1008.00
1.40
38.67
1008.00
0.04
C2 Fluorenes (a)
686.00
0.52
14.36
686.00
0.02
C2-Fluoranthenes/Pyrenes
2.20
60.77
C2-Naphthalenes (a)
510.00
4.50
124.31
510.00
0.24
C2-Phenanthrenes/Anthracenes (a)
746
3.00
82.87
746.00
0.11
C3 Chrysenes (a)
1112.00
0.52
14.36
1112.00
0.01
C3 Fluorenes (a)
769.00
0.56
15.47
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
0.99
27.35
949.00
0.03
C3-Naphthalenes(a)
581.00
3.40
93.92
581.00
0.16
C3-Phenanthrenes/Anthracenes (a)
829.00
1.70
46.96
829.00
0.06
C4 Chrysenes (a)
1214.00
0.14
3.87
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.10
30.39
657.00
0.05
C4-Phenanthrenes/Anthracenes (a)
913.00
0.87
24.03
913.00
0.03
Chrysene ,a)
844.00
826
2.10
58.01
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.31
8.56
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
2.90
80.11
707.00
0.11
Fluorene ,a)
538.00
26,000.00
1.20
33.15
538.00
0.06
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.76
20.99
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.33
9.12
385.00
0.02
Perylene(a)
967.00
431.00
0.43
11.88
967.00
0.01
Phenanthrene 'd'
596
34300
3.90
107.73
596.00
0.18
Pyrene ,d'
697.00
9,090.00
4.40
121.55
697.00
0.17
ESBTU FCVi
1.76
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 6 of87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-37
Field Sample ID
RREC13-37-0305
Sample Depth
3-5
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.2
0.042
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.05
1.17
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.01
0.31
447.00
0.00
Acenaphthene (a)
491.00
33400
0.09
2.12
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.02
0.51
452.00
0.00
Anthracene (a)
594.00
1300
0.15
3.57
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
0.19
4.52
841.00
0.01
Benzo(a)pyrene (a)
965.00
3840
0.17
4.05
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.10
2.38
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.11
2.62
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.10
2.33
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.10
2.38
981.00
0.00
CI Chrysenes (a)
929.00
0.25
5.95
929.00
0.01
CI Fluorenes(a)
611.00
0.04
1.00
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.38
9.05
770.00
0.01
CI-Naphthalenes (a)
444.00
0.04
1.05
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.50
11.90
670.00
0.02
C2 Chrysenes (a)
1008.00
0.15
3.57
1008.00
0.00
C2 Fluorenes (a)
686.00
0.05
1.12
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.23
5.48
C2-Naphthalenes (a)
510.00
0.28
6.67
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.28
6.67
746.00
0.01
C3 Chrysenes (a)
1112.00
0.06
1.50
1112.00
0.00
C3 Fluorenes (a)
769.00
0.05
1.24
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.13
3.10
949.00
0.00
C3-Naphthalenes(a)
581.00
0.29
6.90
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.18
4.29
829.00
0.01
C4 Chrysenes (a)
1214.00
0.02
0.55
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.12
2.86
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.10
2.38
913.00
0.00
Chrysene ,a)
844.00
826
0.18
4.29
844.00
0.01
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.03
0.76
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.24
5.71
707.00
0.01
Fluorene ,a)
538.00
26,000.00
0.08
1.83
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.08
1.90
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.02
0.51
385.00
0.00
Perylene(a)
967.00
431.00
0.08
1.83
967.00
0.00
Phenanthrene 'd'
596
34300
0.30
7.14
596.00
0.01
Pyrene ,d'
697.00
9,090.00
0.38
9.05
697.00
0.01
ESBTU FCVi
0.13
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 7 of87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-37
Field Sample ID
RREC13-37-0507
Sample Depth
5-7
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.31
0.0431
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.01
0.18
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.07
447.00
0.00
Acenaphthene (a)
491.00
33400
0.01
0.26
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.06
452.00
0.00
Anthracene (a)
594.00
1300
0.01
0.28
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.02
0.49
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.02
0.35
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.32
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.30
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.02
0.37
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.01
0.26
981.00
0.00
CI Chrysenes (a)
929.00
0.04
0.81
929.00
0.00
CI Fluorenes(a)
611.00
0.01
0.15
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.04
1.02
770.00
0.00
CI-Naphthalenes (a)
444.00
0.01
0.18
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.07
1.67
670.00
0.00
C2 Chrysenes (a)
1008.00
0.03
0.79
1008.00
0.00
C2 Fluorenes (a)
686.00
0.01
0.18
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.03
0.77
C2-Naphthalenes (a)
510.00
0.04
0.93
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.05
1.11
746.00
0.00
C3 Chrysenes (a)
1112.00
0.02
0.35
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.30
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.03
0.63
949.00
0.00
C3-Naphthalenes(a)
581.00
0.06
1.37
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.05
1.09
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.13
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.05
1.04
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.03
0.63
913.00
0.00
Chrysene ,a)
844.00
826
0.02
0.53
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.10
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.03
0.60
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.01
0.22
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.01
0.23
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.06
385.00
0.00
Perylene(a)
967.00
431.00
0.03
0.72
967.00
0.00
Phenanthrene 'd'
596
34300
0.04
0.86
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.04
0.90
697.00
0.00
ESBTU FCVi
0.02
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 8 of87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-37
Field Sample ID
RREC13-37-0709
Sample Depth
7-9
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.4
0.034
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.09
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.06
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.02
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.07
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.02
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.07
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.04
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.00
0.07
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.00
0.13
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.19
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.04
981.00
0.00
CI Chrysenes (a)
929.00
0.01
0.35
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.07
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.01
0.32
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.11
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.02
0.71
670.00
0.00
C2 Chrysenes (a)
1008.00
0.02
0.59
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.12
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.01
0.38
C2-Naphthalenes (a)
510.00
0.01
0.41
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.02
0.71
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.32
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.21
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.01
0.41
949.00
0.00
C3-Naphthalenes(a)
581.00
0.03
0.97
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.03
0.97
829.00
0.00
C4 Chrysenes (a)
1214.00
0.00
0.12
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.03
0.94
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.59
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.22
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.02
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.00
0.07
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.07
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.06
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.07
385.00
0.00
Perylene(a)
967.00
431.00
0.02
0.71
967.00
0.00
Phenanthrene 'd'
596
34300
0.01
0.20
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.15
697.00
0.00
ESBTU FCVi
0.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 9 of87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-37
Field Sample ID
RREC13-37-0911
Sample Depth
9-11
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.68
0.0368
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.10
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.07
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.04
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.07
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.04
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.07
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.09
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.18
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.16
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.24
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.08
981.00
0.00
CI Chrysenes (a)
929.00
0.02
0.43
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.08
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.02
0.41
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.12
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.03
0.84
670.00
0.00
C2 Chrysenes (a)
1008.00
0.02
0.65
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.11
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.02
0.46
C2-Naphthalenes (a)
510.00
0.02
0.52
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.03
0.79
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.35
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.25
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.02
0.49
949.00
0.00
C3-Naphthalenes(a)
581.00
0.05
1.25
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.04
1.09
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.15
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.05
1.25
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.63
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.30
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.04
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.01
0.19
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.10
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.09
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.07
385.00
0.00
Perylene(a)
967.00
431.00
0.03
0.92
967.00
0.00
Phenanthrene 'd'
596
34300
0.01
0.30
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.24
697.00
0.00
ESBTU FCVi
0.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 10 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-38
Field Sample ID
RREC13-38-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.33
0.0233
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.14
5.79
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.07
2.88
447.00
0.01
Acenaphthene (a)
491.00
33400
0.07
2.92
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.14
5.79
452.00
0.01
Anthracene (a)
594.00
1300
0.34
14.59
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
1.20
51.50
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
1.30
55.79
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
1.10
47.21
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
0.85
36.48
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
0.76
32.62
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
0.95
40.77
981.00
0.04
CI Chrysenes (a)
929.00
0.91
39.06
929.00
0.04
CI Fluorenes(a)
611.00
0.04
1.63
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.10
47.21
770.00
0.06
CI-Naphthalenes (a)
444.00
0.08
3.26
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.62
26.61
670.00
0.04
C2 Chrysenes (a)
1008.00
0.55
23.61
1008.00
0.02
C2 Fluorenes (a)
686.00
0.07
2.88
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.58
24.89
C2-Naphthalenes (a)
510.00
0.14
5.79
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.53
22.75
746.00
0.03
C3 Chrysenes (a)
1112.00
0.26
11.16
1112.00
0.01
C3 Fluorenes (a)
769.00
0.12
5.15
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.29
12.45
949.00
0.01
C3-Naphthalenes(a)
581.00
0.14
5.79
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.35
15.02
829.00
0.02
C4 Chrysenes (a)
1214.00
0.14
5.79
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.15
6.44
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.14
6.01
913.00
0.01
Chrysene ,a)
844.00
826
1.10
47.21
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.26
11.16
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
1.30
55.79
707.00
0.08
Fluorene ,a)
538.00
26,000.00
0.14
5.79
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.66
28.33
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
0.14
5.79
385.00
0.02
Perylene(a)
967.00
431.00
0.32
13.73
967.00
0.01
Phenanthrene 'd'
596
34300
0.61
26.18
596.00
0.04
Pyrene ,d'
697.00
9,090.00
1.40
60.09
697.00
0.09
ESBTU FCVi
0.83
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 11 of87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-38
Field Sample ID
RREC13-38-SURF-FD
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.74
0.0274
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.17
6.02
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.07
2.37
447.00
0.01
Acenaphthene (a)
491.00
33400
0.08
3.03
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.17
6.02
452.00
0.01
Anthracene (a)
594.00
1300
0.53
19.34
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
1.80
65.69
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
1.70
62.04
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
1.40
51.09
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
1.20
43.80
967.00
0.05
Benzo(g,h,i)perylene (a)
1095.00
648
1.20
43.80
1095.00
0.04
Benzo(k)fluoranthene (a)
981.00
1220
1.40
51.09
981.00
0.05
CI Chrysenes (a)
929.00
1.20
43.80
929.00
0.05
CI Fluorenes(a)
611.00
0.06
2.15
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.70
62.04
770.00
0.08
CI-Naphthalenes (a)
444.00
0.08
2.81
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.00
36.50
670.00
0.05
C2 Chrysenes (a)
1008.00
0.63
22.99
1008.00
0.02
C2 Fluorenes (a)
686.00
0.08
2.92
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.75
27.37
C2-Naphthalenes (a)
510.00
0.17
6.02
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.64
23.36
746.00
0.03
C3 Chrysenes (a)
1112.00
0.24
8.76
1112.00
0.01
C3 Fluorenes (a)
769.00
0.13
4.74
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.33
12.04
949.00
0.01
C3-Naphthalenes(a)
581.00
0.17
6.02
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.44
16.06
829.00
0.02
C4 Chrysenes (a)
1214.00
0.17
6.02
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.16
5.84
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.28
10.22
913.00
0.01
Chrysene ,a)
844.00
826
1.60
58.39
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.43
15.69
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
2.30
83.94
707.00
0.12
Fluorene ,a)
538.00
26,000.00
0.17
6.02
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
40.15
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
0.17
6.02
385.00
0.02
Perylene(a)
967.00
431.00
0.46
16.79
967.00
0.02
Phenanthrene 'd'
596
34300
0.93
33.94
596.00
0.06
Pyrene ,d'
697.00
9,090.00
2.20
80.29
697.00
0.12
ESBTU FCVi
1.05
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 12 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-38
Field Sample ID
RREC13-38-0001
Sample Depth
0-1
Sample Date
11/2/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.27
0.0227
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.01
0.33
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.01
0.33
447.00
0.00
Acenaphthene (a)
491.00
33400
0.03
1.23
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.01
0.33
452.00
0.00
Anthracene (a)
594.00
1300
0.02
0.97
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.07
2.86
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.06
2.82
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.06
2.64
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.05
2.11
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.05
2.25
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.05
1.98
981.00
0.00
CI Chrysenes (a)
929.00
0.07
2.95
929.00
0.00
CI Fluorenes(a)
611.00
0.01
0.29
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.09
3.79
770.00
0.00
CI-Naphthalenes (a)
444.00
0.01
0.31
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.07
3.13
670.00
0.00
C2 Chrysenes (a)
1008.00
0.05
2.16
1008.00
0.00
C2 Fluorenes (a)
686.00
0.01
0.40
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.05
2.33
C2-Naphthalenes (a)
510.00
0.03
1.15
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.06
2.73
746.00
0.00
C3 Chrysenes (a)
1112.00
0.02
0.84
1112.00
0.00
C3 Fluorenes (a)
769.00
0.02
0.75
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.03
1.28
949.00
0.00
C3-Naphthalenes(a)
581.00
0.04
1.94
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.05
2.25
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.33
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.04
1.63
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.04
1.72
913.00
0.00
Chrysene ,a)
844.00
826
0.07
2.95
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.02
0.75
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.08
3.66
707.00
0.01
Fluorene ,a)
538.00
26,000.00
0.01
0.48
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.04
1.94
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.01
0.33
385.00
0.00
Perylene(a)
967.00
431.00
0.04
1.72
967.00
0.00
Phenanthrene 'd'
596
34300
0.04
1.81
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.10
4.19
697.00
0.01
ESBTU FCVi
0.06
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 13 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-38
Field Sample ID
RREC13-38-0103
Sample Depth
1-3
Sample Date
11/2/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.57
0.0357
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.07
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.07
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.04
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.07
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.03
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.01
0.14
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.07
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.17
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.16
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.23
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.07
981.00
0.00
CI Chrysenes (a)
929.00
0.01
0.39
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.06
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.02
0.42
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.09
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.02
0.59
670.00
0.00
C2 Chrysenes (a)
1008.00
0.02
0.56
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.11
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.02
0.48
C2-Naphthalenes (a)
510.00
0.01
0.31
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.03
0.76
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.28
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.22
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.02
0.45
949.00
0.00
C3-Naphthalenes(a)
581.00
0.02
0.67
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.03
0.84
829.00
0.00
C4 Chrysenes (a)
1214.00
0.00
0.13
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.03
0.84
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.64
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.26
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.03
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.01
0.22
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.07
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.09
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.07
385.00
0.00
Perylene(a)
967.00
431.00
0.04
0.98
967.00
0.00
Phenanthrene 'd'
596
34300
0.01
0.18
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.26
697.00
0.00
ESBTU FCVi
0.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 14 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-38
Field Sample ID
RREC13-38-0305
Sample Depth
3-5
Sample Date
11/2/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.15
0.0415
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.05
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.05
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.03
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.05
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.04
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.01
0.22
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.01
0.24
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.27
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.24
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.34
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.01
0.19
981.00
0.00
CI Chrysenes (a)
929.00
0.02
0.51
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.06
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.02
0.41
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.08
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.02
0.51
670.00
0.00
C2 Chrysenes (a)
1008.00
0.02
0.58
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.11
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.02
0.46
C2-Naphthalenes (a)
510.00
0.01
0.29
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.03
0.67
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.24
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.20
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.02
0.41
949.00
0.00
C3-Naphthalenes(a)
581.00
0.03
0.63
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.03
0.77
829.00
0.00
C4 Chrysenes (a)
1214.00
0.00
0.10
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.03
0.75
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.51
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.34
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.09
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.01
0.24
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.05
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.01
0.21
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.05
385.00
0.00
Perylene(a)
967.00
431.00
0.04
0.89
967.00
0.00
Phenanthrene 'd'
596
34300
0.01
0.17
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.27
697.00
0.00
ESBTU FCVi
0.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 15 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-38
Field Sample ID
RREC13-38-0507
Sample Depth
5-7
Sample Date
11/2/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
ng/g OC
Cocb
ESBTU FCVi
Total Organic Carbon**
3.37
0.0337
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.07
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.07
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.04
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.07
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.05
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.07
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.07
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.15
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.00
0.14
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.19
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.07
981.00
0.00
CI Chrysenes (a)
929.00
0.01
0.39
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.06
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.01
0.33
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.07
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.02
0.47
670.00
0.00
C2 Chrysenes (a)
1008.00
0.02
0.56
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.11
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.01
0.39
C2-Naphthalenes (a)
510.00
0.01
0.29
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.02
0.65
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.33
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.23
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.01
0.39
949.00
0.00
C3-Naphthalenes(a)
581.00
0.02
0.65
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.03
0.80
829.00
0.00
C4 Chrysenes (a)
1214.00
0.00
0.12
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.03
0.86
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.56
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.26
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.03
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.01
0.15
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.04
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.07
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.07
385.00
0.00
Perylene(a)
967.00
431.00
0.03
0.92
967.00
0.00
Phenanthrene 'd'
596
34300
0.00
0.07
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.19
697.00
0.00
ESBTU FCVi
0.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 16 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-39
Field Sample ID
RREC13-39-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.93
0.0793
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.65
8.20
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.24
3.03
447.00
0.01
Acenaphthene (a)
491.00
33400
0.35
4.41
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.65
8.20
452.00
0.02
Anthracene (a)
594.00
1300
1.70
21.44
594.00
0.04
Benzo(a)anthracene (a)
841.00
4153
5.80
73.14
841.00
0.09
Benzo(a)pyrene (a)
965.00
3840
6.30
79.45
965.00
0.08
Benzo(b)fluoranthene (a)
979.00
2169
5.50
69.36
979.00
0.07
Benzo(e)pyrene (a)
967.00
4300
4.10
51.70
967.00
0.05
Benzo(g,h,i)perylene (a)
1095.00
648
3.50
44.14
1095.00
0.04
Benzo(k)fluoranthene (a)
981.00
1220
4.60
58.01
981.00
0.06
CI Chrysenes (a)
929.00
4.60
58.01
929.00
0.06
CI Fluorenes(a)
611.00
0.21
2.65
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.70
71.88
770.00
0.09
CI-Naphthalenes (a)
444.00
0.29
3.66
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.30
41.61
670.00
0.06
C2 Chrysenes (a)
1008.00
2.70
34.05
1008.00
0.03
C2 Fluorenes (a)
686.00
0.33
4.16
686.00
0.01
C2-Fluoranthenes/Pyrenes
3.20
40.35
C2-Naphthalenes (a)
510.00
0.65
8.20
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
2.90
36.57
746.00
0.05
C3 Chrysenes (a)
1112.00
0.96
12.11
1112.00
0.01
C3 Fluorenes (a)
769.00
0.61
7.69
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
1.50
18.92
949.00
0.02
C3-Naphthalenes(a)
581.00
0.65
8.20
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
1.70
21.44
829.00
0.03
C4 Chrysenes (a)
1214.00
0.65
8.20
1214.00
0.01
C4-Naphthalenes (a)
657.00
0.84
10.59
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.91
11.48
913.00
0.01
Chrysene ,a)
844.00
826
5.70
71.88
844.00
0.09
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.20
15.13
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.90
87.01
707.00
0.12
Fluorene ,a)
538.00
26,000.00
0.65
8.20
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
3.10
39.09
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
0.65
8.20
385.00
0.02
Perylene(a)
967.00
431.00
1.60
20.18
967.00
0.02
Phenanthrene 'd'
596
34300
3.50
44.14
596.00
0.07
Pyrene ,d'
697.00
9,090.00
7.10
89.53
697.00
0.13
ESBTU FCVi
1.24
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 17 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-39
Field Sample ID
RREC13-39-0001
Sample Depth
0-1
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.32
0.0732
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.65
8.88
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.25
17.08
447.00
0.04
Acenaphthene (a)
491.00
33400
1.10
15.03
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.64
8.74
452.00
0.02
Anthracene (a)
594.00
1300
5.60
76.50
594.00
0.13
Benzo(a)anthracene (a)
841.00
4153
12.00
163.93
841.00
0.19
Benzo(a)pyrene (a)
965.00
3840
11.00
150.27
965.00
0.16
Benzo(b)fluoranthene (a)
979.00
2169
9.60
131.15
979.00
0.13
Benzo(e)pyrene (a)
967.00
4300
6.10
83.33
967.00
0.09
Benzo(g,h,i)perylene (a)
1095.00
648
4.10
56.01
1095.00
0.05
Benzo(k)fluoranthene (a)
981.00
1220
10.00
136.61
981.00
0.14
CI Chrysenes (a)
929.00
6.00
81.97
929.00
0.09
CI Fluorenes(a)
611.00
0.69
9.43
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
16.00
218.58
770.00
0.28
CI-Naphthalenes (a)
444.00
0.72
9.84
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
11.00
150.27
670.00
0.22
C2 Chrysenes (a)
1008.00
5.50
75.14
1008.00
0.07
C2 Fluorenes (a)
686.00
1.30
17.76
686.00
0.03
C2-Fluoranthenes/Pyrenes
6.80
92.90
C2-Naphthalenes (a)
510.00
3.80
51.91
510.00
0.10
C2-Phenanthrenes/Anthracenes (a)
746
7.70
105.19
746.00
0.14
C3 Chrysenes (a)
1112.00
1.40
19.13
1112.00
0.02
C3 Fluorenes (a)
769.00
2.20
30.05
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
2.90
39.62
949.00
0.04
C3-Naphthalenes(a)
581.00
9.30
127.05
581.00
0.22
C3-Phenanthrenes/Anthracenes (a)
829.00
6.70
91.53
829.00
0.11
C4 Chrysenes (a)
1214.00
1.25
17.08
1214.00
0.01
C4-Naphthalenes (a)
657.00
5.50
75.14
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
4.00
54.64
913.00
0.06
Chrysene ,a)
844.00
826
11.00
150.27
844.00
0.18
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.30
17.76
1123.00
0.02
Fluoranthene ,a)
707.00
23,870.00
20.00
273.22
707.00
0.39
Fluorene ,a)
538.00
26,000.00
1.50
20.49
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
3.90
53.28
1115.00
0.05
Naphthalene ,a)
385.00
61,700.00
1.25
17.08
385.00
0.04
Perylene(a)
967.00
431.00
2.40
32.79
967.00
0.03
Phenanthrene 'd'
596
34300
11.00
150.27
596.00
0.25
Pyrene ,d'
697.00
9,090.00
16.00
218.58
697.00
0.31
ESBTU FCVi
3.15
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 18 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-39
Field Sample ID
RREC13-39-0103
Sample Depth
1-3
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.23
0.0723
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.07
0.98
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.17
2.28
447.00
0.01
Acenaphthene (a)
491.00
33400
0.28
3.87
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.06
0.86
452.00
0.00
Anthracene (a)
594.00
1300
0.71
9.82
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
1.80
24.90
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.50
20.75
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
0.80
11.07
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.88
12.17
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.50
6.92
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.10
15.21
981.00
0.02
CI Chrysenes (a)
929.00
1.40
19.36
929.00
0.02
CI Fluorenes(a)
611.00
0.15
2.07
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.30
45.64
770.00
0.06
CI-Naphthalenes (a)
444.00
0.08
1.07
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.40
33.20
670.00
0.05
C2 Chrysenes (a)
1008.00
0.83
11.48
1008.00
0.01
C2 Fluorenes (a)
686.00
0.23
3.18
686.00
0.00
C2-Fluoranthenes/Pyrenes
1.50
20.75
C2-Naphthalenes (a)
510.00
0.60
8.30
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
1.30
17.98
746.00
0.02
C3 Chrysenes (a)
1112.00
0.25
3.46
1112.00
0.00
C3 Fluorenes (a)
769.00
0.18
2.49
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.63
8.71
949.00
0.01
C3-Naphthalenes(a)
581.00
0.90
12.45
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
1.00
13.83
829.00
0.02
C4 Chrysenes (a)
1214.00
0.04
0.48
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.39
5.39
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.40
5.53
913.00
0.01
Chrysene ,a)
844.00
826
1.40
19.36
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.14
1.94
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.80
24.90
707.00
0.04
Fluorene ,a)
538.00
26,000.00
0.21
2.90
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.42
5.81
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.17
2.28
385.00
0.01
Perylene(a)
967.00
431.00
0.30
4.15
967.00
0.00
Phenanthrene 'd'
596
34300
1.40
19.36
596.00
0.03
Pyrene ,d'
697.00
9,090.00
2.70
37.34
697.00
0.05
ESBTU FCVi
0.46
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 19 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-39
Field Sample ID
RREC13-39-0305
Sample Depth
3-5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.84
0.0884
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.01
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.02
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.02
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.00
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.02
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.01
0.07
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.04
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.00
0.06
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.00
0.05
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.00
0.04
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.02
981.00
0.00
CI Chrysenes (a)
929.00
0.01
0.10
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.02
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.02
0.19
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.02
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.02
0.19
670.00
0.00
C2 Chrysenes (a)
1008.00
0.01
0.16
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.03
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.01
0.16
C2-Naphthalenes (a)
510.00
0.01
0.08
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.03
0.31
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.08
1112.00
0.00
C3 Fluorenes (a)
769.00
0.00
0.05
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.01
0.12
949.00
0.00
C3-Naphthalenes(a)
581.00
0.02
0.21
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.02
0.21
829.00
0.00
C4 Chrysenes (a)
1214.00
0.00
0.03
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.02
0.21
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.17
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.08
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.01
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.01
0.11
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.02
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.02
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.02
385.00
0.00
Perylene(a)
967.00
431.00
0.03
0.36
967.00
0.00
Phenanthrene 'd'
596
34300
0.01
0.08
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.12
697.00
0.00
ESBTU FCVi
0.00
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 20 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-39
Field Sample ID
RREC13-39-0507
Sample Depth
5-7
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
ng/g OC
Cocb
ESBTU FCVi
Total Organic Carbon**
7.18
0.0718
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.01
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.03
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.00
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.03
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.00
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.03
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.01
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.00
0.03
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.00
0.03
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.00
0.03
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.03
981.00
0.00
CI Chrysenes (a)
929.00
0.01
0.09
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.02
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.01
0.12
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.02
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.01
0.17
670.00
0.00
C2 Chrysenes (a)
1008.00
0.01
0.17
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.04
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.01
0.14
C2-Naphthalenes (a)
510.00
0.01
0.07
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.01
0.19
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.08
1112.00
0.00
C3 Fluorenes (a)
769.00
0.00
0.06
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.01
0.13
949.00
0.00
C3-Naphthalenes(a)
581.00
0.02
0.22
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.02
0.31
829.00
0.00
C4 Chrysenes (a)
1214.00
0.00
0.05
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.02
0.25
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.01
0.19
913.00
0.00
Chrysene ,a)
844.00
826
0.00
0.06
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.00
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.00
0.03
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.01
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.01
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.03
385.00
0.00
Perylene(a)
967.00
431.00
0.03
0.45
967.00
0.00
Phenanthrene 'd'
596
34300
0.00
0.03
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.00
0.03
697.00
0.00
ESBTU FCVi
0.00
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 21 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-39
Field Sample ID
RREC13-39-0709
Sample Depth
7-9
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
ng/g OC
Cocb
ESBTU FCVi
Total Organic Carbon**
6.8
0.068
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.02
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.03
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.00
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.03
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.01
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.03
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.01
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.00
0.03
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.00
0.04
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.00
0.04
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.03
981.00
0.00
CI Chrysenes (a)
929.00
0.01
0.12
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.02
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.01
0.15
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.03
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.01
0.21
670.00
0.00
C2 Chrysenes (a)
1008.00
0.01
0.21
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.04
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.01
0.16
C2-Naphthalenes (a)
510.00
0.01
0.09
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.02
0.22
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.10
1112.00
0.00
C3 Fluorenes (a)
769.00
0.00
0.06
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.01
0.16
949.00
0.00
C3-Naphthalenes(a)
581.00
0.02
0.26
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.03
0.38
829.00
0.00
C4 Chrysenes (a)
1214.00
0.00
0.05
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.02
0.34
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.25
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.08
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.01
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.00
0.03
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.02
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.01
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.03
385.00
0.00
Perylene(a)
967.00
431.00
0.03
0.40
967.00
0.00
Phenanthrene 'd'
596
34300
0.00
0.03
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.00
0.03
697.00
0.00
ESBTU FCVi
0.00
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 22 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-39
Field Sample ID
RREC13-39-0911
Sample Depth
9-11
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.53
0.0253
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.08
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.09
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.02
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.01
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.03
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.09
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.08
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.20
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.00
0.17
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.00
0.16
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.09
981.00
0.00
CI Chrysenes (a)
929.00
0.01
0.43
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.07
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.02
0.59
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.10
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.02
0.83
670.00
0.00
C2 Chrysenes (a)
1008.00
0.02
0.83
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.15
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.02
0.63
C2-Naphthalenes (a)
510.00
0.01
0.35
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.02
0.87
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.36
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.25
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.02
0.63
949.00
0.00
C3-Naphthalenes(a)
581.00
0.03
1.19
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.04
1.42
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.20
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.03
1.26
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.87
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.32
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.02
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.01
0.21
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.06
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.05
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.09
385.00
0.00
Perylene(a)
967.00
431.00
0.04
1.46
967.00
0.00
Phenanthrene 'd'
596
34300
0.00
0.19
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.26
697.00
0.00
ESBTU FCVi
0.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 23 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-40
Field Sample ID
RREC13-40-SURF
Sample Depth
0-0.5
Sample Date
10/28/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
4.68
0.0468
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.04
0.94
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.09
1.82
447.00
0.00
Acenaphthene (a)
491.00
33400
0.08
1.77
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.11
2.35
452.00
0.01
Anthracene (a)
594.00
1300
0.40
8.55
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.90
40.60
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
2.00
42.74
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
1.80
38.46
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
1.30
27.78
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
0.75
16.03
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.80
38.46
981.00
0.04
CI Chrysenes (a)
929.00
1.20
25.64
929.00
0.03
CI Fluorenes(a)
611.00
0.04
0.94
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.10
44.87
770.00
0.06
CI-Naphthalenes (a)
444.00
0.09
1.92
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.94
20.09
670.00
0.03
C2 Chrysenes (a)
1008.00
1.10
23.50
1008.00
0.02
C2 Fluorenes (a)
686.00
0.08
1.65
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.97
20.73
C2-Naphthalenes (a)
510.00
0.24
5.13
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.66
14.10
746.00
0.02
C3 Chrysenes (a)
1112.00
0.35
7.48
1112.00
0.01
C3 Fluorenes (a)
769.00
0.16
3.42
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.44
9.40
949.00
0.01
C3-Naphthalenes(a)
581.00
0.30
6.41
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.59
12.61
829.00
0.02
C4 Chrysenes (a)
1214.00
0.06
1.37
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.19
4.06
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.27
5.77
913.00
0.01
Chrysene ,a)
844.00
826
1.70
36.32
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.22
4.70
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.20
47.01
707.00
0.07
Fluorene ,a)
538.00
26,000.00
0.11
2.35
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.68
14.53
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.17
3.63
385.00
0.01
Perylene(a)
967.00
431.00
0.49
10.47
967.00
0.01
Phenanthrene 'd'
596
34300
0.85
18.16
596.00
0.03
Pyrene ,d'
697.00
9,090.00
1.80
38.46
697.00
0.06
ESBTU FCVi
0.61
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 24 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-40
Field Sample ID
RREC13-40-0001
Sample Depth
0-1
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.48
0.0248
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.15
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.17
447.00
0.00
Acenaphthene (a)
491.00
33400
0.01
0.44
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.02
0.67
452.00
0.00
Anthracene (a)
594.00
1300
0.02
0.97
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.11
4.44
841.00
0.01
Benzo(a)pyrene (a)
965.00
3840
0.10
3.83
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.07
2.78
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.08
3.02
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.06
2.58
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.08
3.02
981.00
0.00
CI Chrysenes (a)
929.00
0.13
5.24
929.00
0.01
CI Fluorenes(a)
611.00
0.01
0.37
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.18
7.26
770.00
0.01
CI-Naphthalenes (a)
444.00
0.01
0.23
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.14
5.65
670.00
0.01
C2 Chrysenes (a)
1008.00
0.08
3.27
1008.00
0.00
C2 Fluorenes (a)
686.00
0.02
0.77
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.11
4.44
C2-Naphthalenes (a)
510.00
0.03
1.17
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.12
4.84
746.00
0.01
C3 Chrysenes (a)
1112.00
0.03
1.21
1112.00
0.00
C3 Fluorenes (a)
769.00
0.03
1.17
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.06
2.50
949.00
0.00
C3-Naphthalenes(a)
581.00
0.07
2.78
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.09
3.67
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.32
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.05
2.10
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.05
1.81
913.00
0.00
Chrysene ,a)
844.00
826
0.11
4.44
844.00
0.01
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.02
0.73
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.14
5.65
707.00
0.01
Fluorene ,a)
538.00
26,000.00
0.01
0.35
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.05
1.81
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.02
0.67
385.00
0.00
Perylene(a)
967.00
431.00
0.04
1.69
967.00
0.00
Phenanthrene 'd'
596
34300
0.04
1.61
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.19
7.66
697.00
0.01
ESBTU FCVi
0.09
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 25 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-40
Field Sample ID
RREC13-40-0103
Sample Depth
1-3
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.11
0.0311
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.08
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.07
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.04
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.06
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.05
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.01
0.23
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.01
0.17
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.27
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.22
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.29
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.01
0.16
981.00
0.00
CI Chrysenes (a)
929.00
0.02
0.74
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.08
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.02
0.58
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.11
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.03
0.93
670.00
0.00
C2 Chrysenes (a)
1008.00
0.03
0.80
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.14
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.02
0.55
C2-Naphthalenes (a)
510.00
0.01
0.42
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.03
0.90
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.39
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.28
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.02
0.58
949.00
0.00
C3-Naphthalenes(a)
581.00
0.04
1.13
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.04
1.16
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.17
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.04
1.19
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.68
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.35
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.06
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.01
0.31
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.07
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.15
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.06
385.00
0.00
Perylene(a)
967.00
431.00
0.04
1.38
967.00
0.00
Phenanthrene 'd'
596
34300
0.01
0.23
596.00
0.00
Pyrene ,a'
697.00
9,090.00
0.01
0.42
697.00
0.00
ESBTU FCVi
0.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 26 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-40
Field Sample ID
RREC13-40-0305
Sample Depth
3-5
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.26
0.0326
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.10
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.07
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.02
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.08
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.01
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.08
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.07
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.16
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.00
0.15
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.23
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.06
981.00
0.00
CI Chrysenes (a)
929.00
0.02
0.49
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.08
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.01
0.37
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.12
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.03
0.83
670.00
0.00
C2 Chrysenes (a)
1008.00
0.02
0.67
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.14
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.01
0.43
C2-Naphthalenes (a)
510.00
0.01
0.43
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.03
0.80
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.34
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.28
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.02
0.46
949.00
0.00
C3-Naphthalenes(a)
581.00
0.04
1.10
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.04
1.17
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.18
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.04
1.10
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.61
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.27
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.03
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.01
0.17
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.08
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.08
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.08
385.00
0.00
Perylene(a)
967.00
431.00
0.05
1.38
967.00
0.00
Phenanthrene 'd'
596
34300
0.01
0.20
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.19
697.00
0.00
ESBTU FCVi
0.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 27 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-40
Field Sample ID
RREC13-40-0507
Sample Depth
5-7
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.27
0.0327
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.11
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.08
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.02
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.08
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.02
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.08
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.06
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.16
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.16
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.24
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.07
981.00
0.00
CI Chrysenes (a)
929.00
0.02
0.49
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.08
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.01
0.37
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.13
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.03
0.80
670.00
0.00
C2 Chrysenes (a)
1008.00
0.03
0.80
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.13
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.01
0.43
C2-Naphthalenes (a)
510.00
0.02
0.52
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.03
0.83
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
0.40
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.25
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.02
0.52
949.00
0.00
C3-Naphthalenes(a)
581.00
0.04
1.19
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.04
1.13
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.18
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.04
1.16
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
0.61
913.00
0.00
Chrysene ,a)
844.00
826
0.01
0.27
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.03
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.00
0.08
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.09
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.08
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.08
385.00
0.00
Perylene(a)
967.00
431.00
0.04
1.10
967.00
0.00
Phenanthrene 'd'
596
34300
0.01
0.24
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
0.17
697.00
0.00
ESBTU FCVi
0.01
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 28 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-41
Field Sample ID
RREC13-41-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
12.1
0.121
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.55
4.55
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.90
7.44
447.00
0.02
Acenaphthene (a)
491.00
33400
0.59
4.88
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.55
4.55
452.00
0.01
Anthracene (a)
594.00
1300
1.60
13.22
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
3.50
28.93
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
2.40
19.83
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
2.60
21.49
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
2.10
17.36
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.40
11.57
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.80
14.88
981.00
0.02
CI Chrysenes (a)
929.00
5.80
47.93
929.00
0.05
CI Fluorenes(a)
611.00
0.71
5.87
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.30
52.07
770.00
0.07
CI-Naphthalenes (a)
444.00
1.10
9.09
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
10.00
82.64
670.00
0.12
C2 Chrysenes (a)
1008.00
6.70
55.37
1008.00
0.05
C2 Fluorenes (a)
686.00
2.10
17.36
686.00
0.03
C2-Fluoranthenes/Pyrenes
7.00
57.85
C2-Naphthalenes (a)
510.00
6.30
52.07
510.00
0.10
C2-Phenanthrenes/Anthracenes (a)
746
18.00
148.76
746.00
0.20
C3 Chrysenes (a)
1112.00
3.20
26.45
1112.00
0.02
C3 Fluorenes (a)
769.00
5.70
47.11
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
6.40
52.89
949.00
0.06
C3-Naphthalenes(a)
581.00
10.00
82.64
581.00
0.14
C3-Phenanthrenes/Anthracenes (a)
829.00
22.00
181.82
829.00
0.22
C4 Chrysenes (a)
1214.00
1.90
15.70
1214.00
0.01
C4-Naphthalenes (a)
657.00
9.00
74.38
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
15.00
123.97
913.00
0.14
Chrysene ,a)
844.00
826
4.30
35.54
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.48
3.97
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.80
39.67
707.00
0.06
Fluorene ,a)
538.00
26,000.00
1.50
12.40
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.30
10.74
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.55
4.55
385.00
0.01
Perylene(a)
967.00
431.00
0.62
5.12
967.00
0.01
Phenanthrene 'd'
596
34300
5.10
42.15
596.00
0.07
Pyrene ,d'
697.00
9,090.00
6.10
50.41
697.00
0.07
ESBTU FCVi
1.30
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 29 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-41
Field Sample ID
RREC13-41-0001
Sample Depth
0-1
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.2
0.082
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
5.80
70.73
446.00
0.16
2-Methylnaphthalene
447.00
154800
8.30
101.22
447.00
0.23
Acenaphthene (a)
491.00
33400
1.70
20.73
491.00
0.04
Acenaphthylene (a)
452.00
24000
2.60
31.71
452.00
0.07
Anthracene (a)
594.00
1300
5.40
65.85
594.00
0.11
Benzo(a)anthracene (a)
841.00
4153
7.60
92.68
841.00
0.11
Benzo(a)pyrene (a)
965.00
3840
5.10
62.20
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
3.90
47.56
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
3.70
45.12
967.00
0.05
Benzo(g,h,i)perylene (a)
1095.00
648
3.00
36.59
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
3.70
45.12
981.00
0.05
CI Chrysenes (a)
929.00
10.00
121.95
929.00
0.13
CI Fluorenes(a)
611.00
2.10
25.61
611.00
0.04
Cl-Fluoranthenes/Pyrenes (a)
770.00
14.00
170.73
770.00
0.22
CI-Naphthalenes (a)
444.00
10.00
121.95
444.00
0.27
Cl-Phenanthrenes/Anthracenes (a)
670.00
23.00
280.49
670.00
0.42
C2 Chrysenes (a)
1008.00
8.10
98.78
1008.00
0.10
C2 Fluorenes (a)
686.00
2.80
34.15
686.00
0.05
C2-Fluoranthenes/Pyrenes
10.00
121.95
C2-Naphthalenes (a)
510.00
21.00
256.10
510.00
0.50
C2-Phenanthrenes/Anthracenes (a)
746
19.00
231.71
746.00
0.31
C3 Chrysenes (a)
1112.00
4.40
53.66
1112.00
0.05
C3 Fluorenes (a)
769.00
5.20
63.41
769.00
0.08
C3-Fluoranthenes/Pyrenes
949.00
6.60
80.49
949.00
0.08
C3-Naphthalenes(a)
581.00
15.00
182.93
581.00
0.31
C3-Phenanthrenes/Anthracenes (a)
829.00
15.00
182.93
829.00
0.22
C4 Chrysenes (a)
1214.00
2.10
25.61
1214.00
0.02
C4-Naphthalenes (a)
657.00
9.30
113.41
657.00
0.17
C4-Phenanthrenes/Anthracenes (a)
913.00
10.00
121.95
913.00
0.13
Chrysene ,a)
844.00
826
7.20
87.80
844.00
0.10
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.10
13.41
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
12.00
146.34
707.00
0.21
Fluorene ,a)
538.00
26,000.00
3.10
37.80
538.00
0.07
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.40
29.27
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
5.40
65.85
385.00
0.17
Perylene(a)
967.00
431.00
1.10
13.41
967.00
0.01
Phenanthrene 'd'
596
34300
14.00
170.73
596.00
0.29
Pyrene ,d'
697.00
9,090.00
14.00
170.73
697.00
0.24
ESBTU FCVi
3.19
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 30 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-41
Field Sample ID
RREC13-41-0103
Sample Depth
1-3
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.29
0.0829
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
5.90
71.17
446.00
0.16
2-Methylnaphthalene
447.00
154800
8.60
103.74
447.00
0.23
Acenaphthene (a)
491.00
33400
1.80
21.71
491.00
0.04
Acenaphthylene (a)
452.00
24000
3.50
42.22
452.00
0.09
Anthracene (a)
594.00
1300
8.00
96.50
594.00
0.16
Benzo(a)anthracene (a)
841.00
4153
9.80
118.21
841.00
0.14
Benzo(a)pyrene (a)
965.00
3840
6.80
82.03
965.00
0.09
Benzo(b)fluoranthene (a)
979.00
2169
5.10
61.52
979.00
0.06
Benzo(e)pyrene (a)
967.00
4300
4.40
53.08
967.00
0.05
Benzo(g,h,i)perylene (a)
1095.00
648
3.80
45.84
1095.00
0.04
Benzo(k)fluoranthene (a)
981.00
1220
4.40
53.08
981.00
0.05
CI Chrysenes (a)
929.00
12.00
144.75
929.00
0.16
CI Fluorenes(a)
611.00
2.50
30.16
611.00
0.05
Cl-Fluoranthenes/Pyrenes (a)
770.00
19.00
229.19
770.00
0.30
CI-Naphthalenes (a)
444.00
10.00
120.63
444.00
0.27
Cl-Phenanthrenes/Anthracenes (a)
670.00
26.00
313.63
670.00
0.47
C2 Chrysenes (a)
1008.00
8.20
98.91
1008.00
0.10
C2 Fluorenes (a)
686.00
2.70
32.57
686.00
0.05
C2-Fluoranthenes/Pyrenes
11.00
132.69
C2-Naphthalenes (a)
510.00
24.00
289.51
510.00
0.57
C2-Phenanthrenes/Anthracenes (a)
746
17.00
205.07
746.00
0.27
C3 Chrysenes (a)
1112.00
4.00
48.25
1112.00
0.04
C3 Fluorenes (a)
769.00
4.10
49.46
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
6.40
77.20
949.00
0.08
C3-Naphthalenes(a)
581.00
16.00
193.00
581.00
0.33
C3-Phenanthrenes/Anthracenes (a)
829.00
14.00
168.88
829.00
0.20
C4 Chrysenes (a)
1214.00
1.80
21.71
1214.00
0.02
C4-Naphthalenes (a)
657.00
7.10
85.65
657.00
0.13
C4-Phenanthrenes/Anthracenes (a)
913.00
9.00
108.56
913.00
0.12
Chrysene ,a)
844.00
826
9.10
109.77
844.00
0.13
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.30
15.68
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
13.00
156.82
707.00
0.22
Fluorene ,a)
538.00
26,000.00
4.60
55.49
538.00
0.10
Indeno(l,2,3-cd)pyrene ,a)
1115.00
3.00
36.19
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
4.70
56.69
385.00
0.15
Perylene(a)
967.00
431.00
1.40
16.89
967.00
0.02
Phenanthrene 'd'
596
34300
20.00
241.25
596.00
0.40
Pyrene ,d'
697.00
9,090.00
18.00
217.13
697.00
0.31
ESBTU FCVi
3.65
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 31 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-41
Field Sample ID
RREC13-41-0103-FD
Sample Depth
1-3
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.34
0.0834
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
3.70
44.36
446.00
0.10
2-Methylnaphthalene
447.00
154800
5.30
63.55
447.00
0.14
Acenaphthene (a)
491.00
33400
1.20
14.39
491.00
0.03
Acenaphthylene (a)
452.00
24000
1.05
12.59
452.00
0.03
Anthracene (a)
594.00
1300
4.90
58.75
594.00
0.10
Benzo(a)anthracene (a)
841.00
4153
7.10
85.13
841.00
0.10
Benzo(a)pyrene (a)
965.00
3840
4.60
55.16
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
3.60
43.17
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
3.30
39.57
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.80
33.57
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
3.10
37.17
981.00
0.04
CI Chrysenes (a)
929.00
8.60
103.12
929.00
0.11
CI Fluorenes(a)
611.00
1.50
17.99
611.00
0.03
Cl-Fluoranthenes/Pyrenes (a)
770.00
12.00
143.88
770.00
0.19
CI-Naphthalenes (a)
444.00
6.40
76.74
444.00
0.17
Cl-Phenanthrenes/Anthracenes (a)
670.00
17.00
203.84
670.00
0.30
C2 Chrysenes (a)
1008.00
6.60
79.14
1008.00
0.08
C2 Fluorenes (a)
686.00
1.80
21.58
686.00
0.03
C2-Fluoranthenes/Pyrenes
7.70
92.33
C2-Naphthalenes (a)
510.00
14.00
167.87
510.00
0.33
C2-Phenanthrenes/Anthracenes (a)
746
13.00
155.88
746.00
0.21
C3 Chrysenes (a)
1112.00
3.30
39.57
1112.00
0.04
C3 Fluorenes (a)
769.00
3.00
35.97
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
5.00
59.95
949.00
0.06
C3-Naphthalenes(a)
581.00
10.00
119.90
581.00
0.21
C3-Phenanthrenes/Anthracenes (a)
829.00
11.00
131.89
829.00
0.16
C4 Chrysenes (a)
1214.00
1.60
19.18
1214.00
0.02
C4-Naphthalenes (a)
657.00
5.30
63.55
657.00
0.10
C4-Phenanthrenes/Anthracenes (a)
913.00
7.40
88.73
913.00
0.10
Chrysene ,a)
844.00
826
6.30
75.54
844.00
0.09
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.00
11.99
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
9.00
107.91
707.00
0.15
Fluorene ,a)
538.00
26,000.00
2.60
31.18
538.00
0.06
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.40
28.78
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
3.50
41.97
385.00
0.11
Perylene(a)
967.00
431.00
0.99
11.87
967.00
0.01
Phenanthrene 'd'
596
34300
12.00
143.88
596.00
0.24
Pyrene ,d'
697.00
9,090.00
12.00
143.88
697.00
0.21
ESBTU FCVi
2.44
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 32 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-41
Field Sample ID
RREC13-41-0305
Sample Depth
3-5
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.45
0.0845
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.46
5.44
446.00
0.01
2-Methylnaphthalene
447.00
154800
1.20
14.20
447.00
0.03
Acenaphthene (a)
491.00
33400
0.69
8.17
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.46
5.44
452.00
0.01
Anthracene (a)
594.00
1300
1.60
18.93
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.60
42.60
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
2.60
30.77
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.50
29.59
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.10
24.85
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.70
20.12
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.10
24.85
981.00
0.03
CI Chrysenes (a)
929.00
5.20
61.54
929.00
0.07
CI Fluorenes(a)
611.00
0.69
8.17
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.70
67.46
770.00
0.09
CI-Naphthalenes (a)
444.00
1.40
16.57
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
9.80
115.98
670.00
0.17
C2 Chrysenes (a)
1008.00
5.10
60.36
1008.00
0.06
C2 Fluorenes (a)
686.00
1.80
21.30
686.00
0.03
C2-Fluoranthenes/Pyrenes
5.60
66.27
C2-Naphthalenes (a)
510.00
5.10
60.36
510.00
0.12
C2-Phenanthrenes/Anthracenes (a)
746
14.00
165.68
746.00
0.22
C3 Chrysenes (a)
1112.00
2.90
34.32
1112.00
0.03
C3 Fluorenes (a)
769.00
4.70
55.62
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
4.70
55.62
949.00
0.06
C3-Naphthalenes(a)
581.00
6.50
76.92
581.00
0.13
C3-Phenanthrenes/Anthracenes (a)
829.00
13.00
153.85
829.00
0.19
C4 Chrysenes (a)
1214.00
1.40
16.57
1214.00
0.01
C4-Naphthalenes (a)
657.00
6.10
72.19
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
8.80
104.14
913.00
0.11
Chrysene ,a)
844.00
826
3.80
44.97
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.63
7.46
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.60
78.11
707.00
0.11
Fluorene ,a)
538.00
26,000.00
1.40
16.57
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.50
17.75
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
2.30
27.22
385.00
0.07
Perylene(a)
967.00
431.00
0.63
7.46
967.00
0.01
Phenanthrene 'd'
596
34300
5.10
60.36
596.00
0.10
Pyrene ,d'
697.00
9,090.00
5.70
67.46
697.00
0.10
ESBTU FCVi
1.64
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 33 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-41
Field Sample ID
RREC13-41-0305-FD
Sample Depth
3-5
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.3
0.103
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.83
8.06
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.20
11.65
447.00
0.03
Acenaphthene (a)
491.00
33400
0.62
6.02
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.41
3.98
452.00
0.01
Anthracene (a)
594.00
1300
1.60
15.53
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.90
37.86
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
2.90
28.16
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.50
24.27
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
2.20
21.36
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.60
15.53
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.50
24.27
981.00
0.02
CI Chrysenes (a)
929.00
5.50
53.40
929.00
0.06
CI Fluorenes(a)
611.00
0.56
5.44
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.90
57.28
770.00
0.07
CI-Naphthalenes (a)
444.00
1.40
13.59
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.40
71.84
670.00
0.11
C2 Chrysenes (a)
1008.00
5.60
54.37
1008.00
0.05
C2 Fluorenes (a)
686.00
1.40
13.59
686.00
0.02
C2-Fluoranthenes/Pyrenes
5.50
53.40
C2-Naphthalenes (a)
510.00
5.00
48.54
510.00
0.10
C2-Phenanthrenes/Anthracenes (a)
746
11.00
106.80
746.00
0.14
C3 Chrysenes (a)
1112.00
2.40
23.30
1112.00
0.02
C3 Fluorenes (a)
769.00
4.10
39.81
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
4.60
44.66
949.00
0.05
C3-Naphthalenes(a)
581.00
6.20
60.19
581.00
0.10
C3-Phenanthrenes/Anthracenes (a)
829.00
14.00
135.92
829.00
0.16
C4 Chrysenes (a)
1214.00
1.60
15.53
1214.00
0.01
C4-Naphthalenes (a)
657.00
5.50
53.40
657.00
0.08
C4-Phenanthrenes/Anthracenes (a)
913.00
9.90
96.12
913.00
0.11
Chrysene ,a)
844.00
826
4.10
39.81
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.64
6.21
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
5.20
50.49
707.00
0.07
Fluorene ,a)
538.00
26,000.00
1.50
14.56
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.50
14.56
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
2.40
23.30
385.00
0.06
Perylene(a)
967.00
431.00
0.69
6.70
967.00
0.01
Phenanthrene 'd'
596
34300
4.50
43.69
596.00
0.07
Pyrene ,d'
697.00
9,090.00
6.20
60.19
697.00
0.09
ESBTU FCVi
1.27
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 34 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-41
Field Sample ID
RREC13-41-0507
Sample Depth
5-7
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.95
0.0795
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
2.40
30.19
446.00
0.07
2-Methylnaphthalene
447.00
154800
3.40
42.77
447.00
0.10
Acenaphthene (a)
491.00
33400
0.80
10.06
491.00
0.02
Acenaphthylene (a)
452.00
24000
1.40
17.61
452.00
0.04
Anthracene (a)
594.00
1300
2.90
36.48
594.00
0.06
Benzo(a)anthracene (a)
841.00
4153
5.10
64.15
841.00
0.08
Benzo(a)pyrene (a)
965.00
3840
3.80
47.80
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
2.90
36.48
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.90
36.48
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.30
28.93
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
2.80
35.22
981.00
0.04
CI Chrysenes (a)
929.00
7.10
89.31
929.00
0.10
CI Fluorenes(a)
611.00
0.97
12.20
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
8.50
106.92
770.00
0.14
CI-Naphthalenes (a)
444.00
4.10
51.57
444.00
0.12
Cl-Phenanthrenes/Anthracenes (a)
670.00
12.00
150.94
670.00
0.23
C2 Chrysenes (a)
1008.00
6.00
75.47
1008.00
0.07
C2 Fluorenes (a)
686.00
1.50
18.87
686.00
0.03
C2-Fluoranthenes/Pyrenes
7.00
88.05
C2-Naphthalenes (a)
510.00
10.00
125.79
510.00
0.25
C2-Phenanthrenes/Anthracenes (a)
746
11.00
138.36
746.00
0.19
C3 Chrysenes (a)
1112.00
3.20
40.25
1112.00
0.04
C3 Fluorenes (a)
769.00
3.50
44.03
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
5.10
64.15
949.00
0.07
C3-Naphthalenes(a)
581.00
8.50
106.92
581.00
0.18
C3-Phenanthrenes/Anthracenes (a)
829.00
12.00
150.94
829.00
0.18
C4 Chrysenes (a)
1214.00
1.60
20.13
1214.00
0.02
C4-Naphthalenes (a)
657.00
5.60
70.44
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
7.90
99.37
913.00
0.11
Chrysene ,a)
844.00
826
4.70
59.12
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.90
11.32
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.90
86.79
707.00
0.12
Fluorene ,a)
538.00
26,000.00
1.50
18.87
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.90
23.90
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
3.20
40.25
385.00
0.10
Perylene(a)
967.00
431.00
0.84
10.57
967.00
0.01
Phenanthrene 'd'
596
34300
7.40
93.08
596.00
0.16
Pyrene ,d'
697.00
9,090.00
8.00
100.63
697.00
0.14
ESBTU FCVi
2.00
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 35 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-41
Field Sample ID
RREC13-41-0507-FD
Sample Depth
5-7
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.73
0.0873
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
2.50
28.64
446.00
0.06
2-Methylnaphthalene
447.00
154800
3.60
41.24
447.00
0.09
Acenaphthene (a)
491.00
33400
0.94
10.77
491.00
0.02
Acenaphthylene (a)
452.00
24000
1.50
17.18
452.00
0.04
Anthracene (a)
594.00
1300
3.50
40.09
594.00
0.07
Benzo(a)anthracene (a)
841.00
4153
6.30
72.16
841.00
0.09
Benzo(a)pyrene (a)
965.00
3840
4.20
48.11
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
3.20
36.66
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
3.20
36.66
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.60
29.78
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
3.00
34.36
981.00
0.04
CI Chrysenes (a)
929.00
8.20
93.93
929.00
0.10
CI Fluorenes(a)
611.00
1.00
11.45
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
9.90
113.40
770.00
0.15
CI-Naphthalenes (a)
444.00
4.30
49.26
444.00
0.11
Cl-Phenanthrenes/Anthracenes (a)
670.00
14.00
160.37
670.00
0.24
C2 Chrysenes (a)
1008.00
6.80
77.89
1008.00
0.08
C2 Fluorenes (a)
686.00
1.80
20.62
686.00
0.03
C2-Fluoranthenes/Pyrenes
8.30
95.07
C2-Naphthalenes (a)
510.00
11.00
126.00
510.00
0.25
C2-Phenanthrenes/Anthracenes (a)
746
13.00
148.91
746.00
0.20
C3 Chrysenes (a)
1112.00
3.40
38.95
1112.00
0.04
C3 Fluorenes (a)
769.00
4.00
45.82
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
5.90
67.58
949.00
0.07
C3-Naphthalenes(a)
581.00
9.70
111.11
581.00
0.19
C3-Phenanthrenes/Anthracenes (a)
829.00
13.00
148.91
829.00
0.18
C4 Chrysenes (a)
1214.00
1.90
21.76
1214.00
0.02
C4-Naphthalenes (a)
657.00
6.20
71.02
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
9.10
104.24
913.00
0.11
Chrysene ,a)
844.00
826
5.70
65.29
844.00
0.08
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.00
11.45
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
7.80
89.35
707.00
0.13
Fluorene ,a)
538.00
26,000.00
1.60
18.33
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.30
26.35
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
3.40
38.95
385.00
0.10
Perylene(a)
967.00
431.00
0.93
10.65
967.00
0.01
Phenanthrene 'd'
596
34300
8.30
95.07
596.00
0.16
Pyrene ,d'
697.00
9,090.00
9.50
108.82
697.00
0.16
ESBTU FCVi
2.09
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 36 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-41
Field Sample ID
RREC13-41-0709
Sample Depth
7-9
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.47
0.0847
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
9.40
110.98
446.00
0.25
2-Methylnaphthalene
447.00
154800
14.00
165.29
447.00
0.37
Acenaphthene (a)
491.00
33400
2.40
28.34
491.00
0.06
Acenaphthylene (a)
452.00
24000
5.10
60.21
452.00
0.13
Anthracene (a)
594.00
1300
10.00
118.06
594.00
0.20
Benzo(a)anthracene (a)
841.00
4153
10.00
118.06
841.00
0.14
Benzo(a)pyrene (a)
965.00
3840
7.30
86.19
965.00
0.09
Benzo(b)fluoranthene (a)
979.00
2169
5.10
60.21
979.00
0.06
Benzo(e)pyrene (a)
967.00
4300
4.70
55.49
967.00
0.06
Benzo(g,h,i)perylene (a)
1095.00
648
4.10
48.41
1095.00
0.04
Benzo(k)fluoranthene (a)
981.00
1220
4.60
54.31
981.00
0.06
CI Chrysenes (a)
929.00
13.00
153.48
929.00
0.17
CI Fluorenes(a)
611.00
3.10
36.60
611.00
0.06
Cl-Fluoranthenes/Pyrenes (a)
770.00
19.00
224.32
770.00
0.29
CI-Naphthalenes (a)
444.00
16.00
188.90
444.00
0.43
Cl-Phenanthrenes/Anthracenes (a)
670.00
30.00
354.19
670.00
0.53
C2 Chrysenes (a)
1008.00
9.60
113.34
1008.00
0.11
C2 Fluorenes (a)
686.00
3.00
35.42
686.00
0.05
C2-Fluoranthenes/Pyrenes
12.00
141.68
C2-Naphthalenes (a)
510.00
34.00
401.42
510.00
0.79
C2-Phenanthrenes/Anthracenes (a)
746
19.00
224.32
746.00
0.30
C3 Chrysenes (a)
1112.00
4.80
56.67
1112.00
0.05
C3 Fluorenes (a)
769.00
4.60
54.31
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
7.00
82.64
949.00
0.09
C3-Naphthalenes(a)
581.00
21.00
247.93
581.00
0.43
C3-Phenanthrenes/Anthracenes (a)
829.00
14.00
165.29
829.00
0.20
C4 Chrysenes (a)
1214.00
2.10
24.79
1214.00
0.02
C4-Naphthalenes (a)
657.00
9.30
109.80
657.00
0.17
C4-Phenanthrenes/Anthracenes (a)
913.00
9.50
112.16
913.00
0.12
Chrysene ,a)
844.00
826
9.20
108.62
844.00
0.13
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.50
17.71
1123.00
0.02
Fluoranthene ,a)
707.00
23,870.00
15.00
177.10
707.00
0.25
Fluorene ,a)
538.00
26,000.00
8.20
96.81
538.00
0.18
Indeno(l,2,3-cd)pyrene ,a)
1115.00
3.40
40.14
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
8.10
95.63
385.00
0.25
Perylene(a)
967.00
431.00
1.40
16.53
967.00
0.02
Phenanthrene 'd'
596
34300
25.00
295.16
596.00
0.50
Pyrene ,d'
697.00
9,090.00
20.00
236.13
697.00
0.34
ESBTU FCVi
4.17
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 37 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-41
Field Sample ID
RREC13-41-0709-FD
Sample Depth
7-9
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.25
0.0825
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
8.40
101.82
446.00
0.23
2-Methylnaphthalene
447.00
154800
12.00
145.45
447.00
0.33
Acenaphthene (a)
491.00
33400
2.10
25.45
491.00
0.05
Acenaphthylene (a)
452.00
24000
4.20
50.91
452.00
0.11
Anthracene (a)
594.00
1300
8.80
106.67
594.00
0.18
Benzo(a)anthracene (a)
841.00
4153
9.10
110.30
841.00
0.13
Benzo(a)pyrene (a)
965.00
3840
6.30
76.36
965.00
0.08
Benzo(b)fluoranthene (a)
979.00
2169
4.40
53.33
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
4.00
48.48
967.00
0.05
Benzo(g,h,i)perylene (a)
1095.00
648
3.00
36.36
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
4.50
54.55
981.00
0.06
CI Chrysenes (a)
929.00
10.00
121.21
929.00
0.13
CI Fluorenes(a)
611.00
2.80
33.94
611.00
0.06
Cl-Fluoranthenes/Pyrenes (a)
770.00
18.00
218.18
770.00
0.28
CI-Naphthalenes (a)
444.00
15.00
181.82
444.00
0.41
Cl-Phenanthrenes/Anthracenes (a)
670.00
24.00
290.91
670.00
0.43
C2 Chrysenes (a)
1008.00
9.30
112.73
1008.00
0.11
C2 Fluorenes (a)
686.00
2.70
32.73
686.00
0.05
C2-Fluoranthenes/Pyrenes
11.00
133.33
C2-Naphthalenes (a)
510.00
31.00
375.76
510.00
0.74
C2-Phenanthrenes/Anthracenes (a)
746
17.00
206.06
746.00
0.28
C3 Chrysenes (a)
1112.00
4.60
55.76
1112.00
0.05
C3 Fluorenes (a)
769.00
4.00
48.48
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
5.80
70.30
949.00
0.07
C3-Naphthalenes(a)
581.00
19.00
230.30
581.00
0.40
C3-Phenanthrenes/Anthracenes (a)
829.00
14.00
169.70
829.00
0.20
C4 Chrysenes (a)
1214.00
2.10
25.45
1214.00
0.02
C4-Naphthalenes (a)
657.00
8.60
104.24
657.00
0.16
C4-Phenanthrenes/Anthracenes (a)
913.00
9.10
110.30
913.00
0.12
Chrysene ,a)
844.00
826
8.20
99.39
844.00
0.12
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.20
14.55
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
12.00
145.45
707.00
0.21
Fluorene ,a)
538.00
26,000.00
6.00
72.73
538.00
0.14
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.70
32.73
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
6.90
83.64
385.00
0.22
Perylene(a)
967.00
431.00
1.20
14.55
967.00
0.02
Phenanthrene 'd'
596
34300
22.00
266.67
596.00
0.45
Pyrene ,d'
697.00
9,090.00
18.00
218.18
697.00
0.31
ESBTU FCVi
3.73
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 38 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-41
Field Sample ID
RREC13-41-0911
Sample Depth
9-11
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.48
0.0748
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
10.00
133.69
446.00
0.30
2-Methylnaphthalene
447.00
154800
15.00
200.53
447.00
0.45
Acenaphthene (a)
491.00
33400
4.30
57.49
491.00
0.12
Acenaphthylene (a)
452.00
24000
3.05
40.78
452.00
0.09
Anthracene (a)
594.00
1300
15.00
200.53
594.00
0.34
Benzo(a)anthracene (a)
841.00
4153
16.00
213.90
841.00
0.25
Benzo(a)pyrene (a)
965.00
3840
11.00
147.06
965.00
0.15
Benzo(b)fluoranthene (a)
979.00
2169
7.70
102.94
979.00
0.11
Benzo(e)pyrene (a)
967.00
4300
6.70
89.57
967.00
0.09
Benzo(g,h,i)perylene (a)
1095.00
648
4.80
64.17
1095.00
0.06
Benzo(k)fluoranthene (a)
981.00
1220
7.60
101.60
981.00
0.10
CI Chrysenes (a)
929.00
19.00
254.01
929.00
0.27
CI Fluorenes(a)
611.00
4.70
62.83
611.00
0.10
Cl-Fluoranthenes/Pyrenes (a)
770.00
31.00
414.44
770.00
0.54
CI-Naphthalenes (a)
444.00
18.00
240.64
444.00
0.54
Cl-Phenanthrenes/Anthracenes (a)
670.00
43.00
574.87
670.00
0.86
C2 Chrysenes (a)
1008.00
13.00
173.80
1008.00
0.17
C2 Fluorenes (a)
686.00
4.30
57.49
686.00
0.08
C2-Fluoranthenes/Pyrenes
17.00
227.27
C2-Naphthalenes (a)
510.00
45.00
601.60
510.00
1.18
C2-Phenanthrenes/Anthracenes (a)
746
28.00
374.33
746.00
0.50
C3 Chrysenes (a)
1112.00
5.30
70.86
1112.00
0.06
C3 Fluorenes (a)
769.00
5.40
72.19
769.00
0.09
C3-Fluoranthenes/Pyrenes
949.00
8.70
116.31
949.00
0.12
C3-Naphthalenes(a)
581.00
26.00
347.59
581.00
0.60
C3-Phenanthrenes/Anthracenes (a)
829.00
18.00
240.64
829.00
0.29
C4 Chrysenes (a)
1214.00
2.40
32.09
1214.00
0.03
C4-Naphthalenes (a)
657.00
11.00
147.06
657.00
0.22
C4-Phenanthrenes/Anthracenes (a)
913.00
11.00
147.06
913.00
0.16
Chrysene ,a)
844.00
826
14.00
187.17
844.00
0.22
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.80
24.06
1123.00
0.02
Fluoranthene ,a)
707.00
23,870.00
21.00
280.75
707.00
0.40
Fluorene ,a)
538.00
26,000.00
8.40
112.30
538.00
0.21
Indeno(l,2,3-cd)pyrene ,a)
1115.00
4.40
58.82
1115.00
0.05
Naphthalene ,a)
385.00
61,700.00
7.90
105.61
385.00
0.27
Perylene(a)
967.00
431.00
2.10
28.07
967.00
0.03
Phenanthrene 'd'
596
34300
36.00
481.28
596.00
0.81
Pyrene ,d'
697.00
9,090.00
33.00
441.18
697.00
0.63
ESBTU FCVi
6.59
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 39 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-41
Field Sample ID
RREC13-41-0911-FD
Sample Depth
9-11
Sample Date
10/31/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.51
0.0751
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
10.00
133.16
446.00
0.30
2-Methylnaphthalene
447.00
154800
15.00
199.73
447.00
0.45
Acenaphthene (a)
491.00
33400
4.40
58.59
491.00
0.12
Acenaphthylene (a)
452.00
24000
2.60
34.62
452.00
0.08
Anthracene (a)
594.00
1300
14.00
186.42
594.00
0.31
Benzo(a)anthracene (a)
841.00
4153
16.00
213.05
841.00
0.25
Benzo(a)pyrene (a)
965.00
3840
12.00
159.79
965.00
0.17
Benzo(b)fluoranthene (a)
979.00
2169
8.30
110.52
979.00
0.11
Benzo(e)pyrene (a)
967.00
4300
7.20
95.87
967.00
0.10
Benzo(g,h,i)perylene (a)
1095.00
648
4.80
63.91
1095.00
0.06
Benzo(k)fluoranthene (a)
981.00
1220
8.40
111.85
981.00
0.11
CI Chrysenes (a)
929.00
19.00
253.00
929.00
0.27
CI Fluorenes(a)
611.00
4.50
59.92
611.00
0.10
Cl-Fluoranthenes/Pyrenes (a)
770.00
31.00
412.78
770.00
0.54
CI-Naphthalenes (a)
444.00
18.00
239.68
444.00
0.54
Cl-Phenanthrenes/Anthracenes (a)
670.00
42.00
559.25
670.00
0.83
C2 Chrysenes (a)
1008.00
14.00
186.42
1008.00
0.18
C2 Fluorenes (a)
686.00
4.70
62.58
686.00
0.09
C2-Fluoranthenes/Pyrenes
17.00
226.36
C2-Naphthalenes (a)
510.00
42.00
559.25
510.00
1.10
C2-Phenanthrenes/Anthracenes (a)
746
29.00
386.15
746.00
0.52
C3 Chrysenes (a)
1112.00
5.70
75.90
1112.00
0.07
C3 Fluorenes (a)
769.00
5.70
75.90
769.00
0.10
C3-Fluoranthenes/Pyrenes
949.00
8.70
115.85
949.00
0.12
C3-Naphthalenes(a)
581.00
25.00
332.89
581.00
0.57
C3-Phenanthrenes/Anthracenes (a)
829.00
19.00
253.00
829.00
0.31
C4 Chrysenes (a)
1214.00
2.70
35.95
1214.00
0.03
C4-Naphthalenes (a)
657.00
11.00
146.47
657.00
0.22
C4-Phenanthrenes/Anthracenes (a)
913.00
12.00
159.79
913.00
0.18
Chrysene ,a)
844.00
826
15.00
199.73
844.00
0.24
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
2.00
26.63
1123.00
0.02
Fluoranthene ,a)
707.00
23,870.00
22.00
292.94
707.00
0.41
Fluorene ,a)
538.00
26,000.00
8.00
106.52
538.00
0.20
Indeno(l,2,3-cd)pyrene ,a)
1115.00
4.40
58.59
1115.00
0.05
Naphthalene ,a)
385.00
61,700.00
8.70
115.85
385.00
0.30
Perylene(a)
967.00
431.00
2.30
30.63
967.00
0.03
Phenanthrene 'd'
596
34300
35.00
466.05
596.00
0.78
Pyrene ,d'
697.00
9,090.00
33.00
439.41
697.00
0.63
ESBTU FCVi
6.64
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 40 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-42
Field Sample ID
RREC13-42-SURF
Sample Depth
0-0.5
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.29
0.0329
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.10
3.01
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.13
3.80
447.00
0.01
Acenaphthene (a)
491.00
33400
0.15
4.56
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.09
2.80
452.00
0.01
Anthracene (a)
594.00
1300
0.42
12.77
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
1.30
39.51
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
1.10
33.43
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
0.92
27.96
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
0.73
22.19
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.54
16.41
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
0.99
30.09
981.00
0.03
CI Chrysenes (a)
929.00
0.70
21.28
929.00
0.02
CI Fluorenes(a)
611.00
0.07
2.10
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.40
42.55
770.00
0.06
CI-Naphthalenes (a)
444.00
0.17
5.17
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.99
30.09
670.00
0.04
C2 Chrysenes (a)
1008.00
0.42
12.77
1008.00
0.01
C2 Fluorenes (a)
686.00
0.09
2.58
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.64
19.45
C2-Naphthalenes (a)
510.00
0.50
15.20
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
0.54
16.41
746.00
0.02
C3 Chrysenes (a)
1112.00
0.13
3.95
1112.00
0.00
C3 Fluorenes (a)
769.00
0.08
2.43
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.28
8.51
949.00
0.01
C3-Naphthalenes(a)
581.00
0.65
19.76
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
0.40
12.16
829.00
0.01
C4 Chrysenes (a)
1214.00
0.05
1.64
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.31
9.42
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.20
6.08
913.00
0.01
Chrysene ,a)
844.00
826
1.10
33.43
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.15
4.56
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.10
63.83
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.19
5.78
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.47
14.29
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.33
10.03
385.00
0.03
Perylene(a)
967.00
431.00
0.31
9.42
967.00
0.01
Phenanthrene 'd'
596
34300
1.10
33.43
596.00
0.06
Pyrene ,d'
697.00
9,090.00
1.60
48.63
697.00
0.07
ESBTU FCVi
0.69
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 41 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-42
Field Sample ID
RREC13-42-0001
Sample Depth
0-1
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
1.38
0.0138
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.01
0.41
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.01
0.40
447.00
0.00
Acenaphthene (a)
491.00
33400
0.01
0.87
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.17
452.00
0.00
Anthracene (a)
594.00
1300
0.02
1.45
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.02
1.59
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.02
1.23
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.80
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.94
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.69
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.02
1.09
981.00
0.00
CI Chrysenes (a)
929.00
0.02
1.16
929.00
0.00
CI Fluorenes(a)
611.00
0.01
0.41
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.04
2.54
770.00
0.00
CI-Naphthalenes (a)
444.00
0.01
0.70
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.05
3.77
670.00
0.01
C2 Chrysenes (a)
1008.00
0.01
0.57
1008.00
0.00
C2 Fluorenes (a)
686.00
0.01
0.52
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.02
1.16
C2-Naphthalenes (a)
510.00
0.06
3.99
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.03
1.88
746.00
0.00
C3 Chrysenes (a)
1112.00
0.00
0.19
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.62
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.01
0.53
949.00
0.00
C3-Naphthalenes(a)
581.00
0.06
4.64
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.02
1.30
829.00
0.00
C4 Chrysenes (a)
1214.00
0.00
0.10
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.03
2.10
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.01
0.72
913.00
0.00
Chrysene ,a)
844.00
826
0.02
1.52
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.14
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.05
3.41
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.02
1.16
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.01
0.49
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.01
0.40
385.00
0.00
Perylene(a)
967.00
431.00
0.07
5.22
967.00
0.01
Phenanthrene 'd'
596
34300
0.07
4.71
596.00
0.01
Pyrene ,d'
697.00
9,090.00
0.04
2.83
697.00
0.00
ESBTU FCVi
0.06
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 42 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-42
Field Sample ID
RREC13-42-0103
Sample Depth
1-3
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
ng/g OC
Cocb
ESBTU FCVi
Total Organic Carbon**
0.88
0.0088
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.19
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.24
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.14
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.05
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.20
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.01
0.57
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.35
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.63
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.01
0.65
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.00
0.56
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.40
981.00
0.00
CI Chrysenes (a)
929.00
0.01
1.36
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.12
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.01
1.59
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.28
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.01
1.47
670.00
0.00
C2 Chrysenes (a)
1008.00
0.02
2.38
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.24
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.01
1.59
C2-Naphthalenes (a)
510.00
0.01
1.11
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.01
1.59
746.00
0.00
C3 Chrysenes (a)
1112.00
0.01
1.09
1112.00
0.00
C3 Fluorenes (a)
769.00
0.01
0.57
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.01
1.59
949.00
0.00
C3-Naphthalenes(a)
581.00
0.02
2.27
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.02
2.49
829.00
0.00
C4 Chrysenes (a)
1214.00
0.00
0.35
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.02
1.70
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.02
1.70
913.00
0.00
Chrysene ,a)
844.00
826
0.01
1.00
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.07
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.01
0.93
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.20
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.19
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.24
385.00
0.00
Perylene(a)
967.00
431.00
0.00
0.44
967.00
0.00
Phenanthrene 'd'
596
34300
0.01
0.70
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.01
1.13
697.00
0.00
ESBTU FCVi
0.02
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 43 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-42
Field Sample ID
RREC13-42-0305
Sample Depth
3-5
Sample Date
11/4/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
ng/g OC
Cocb
ESBTU FCVi
Total Organic Carbon**
2.48
0.0248
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.02
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.09
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.02
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.01
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.02
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.00
0.05
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.00
0.05
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.01
0.22
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.00
0.14
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.00
0.03
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.00
0.10
981.00
0.00
CI Chrysenes (a)
929.00
0.00
0.08
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.09
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.00
0.10
770.00
0.00
CI-Naphthalenes (a)
444.00
0.00
0.03
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.00
0.13
670.00
0.00
C2 Chrysenes (a)
1008.00
0.00
0.09
1008.00
0.00
C2 Fluorenes (a)
686.00
0.00
0.02
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.00
0.08
C2-Naphthalenes (a)
510.00
0.00
0.12
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.00
0.13
746.00
0.00
C3 Chrysenes (a)
1112.00
0.00
0.05
1112.00
0.00
C3 Fluorenes (a)
769.00
0.00
0.09
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.00
0.07
949.00
0.00
C3-Naphthalenes(a)
581.00
0.00
0.19
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.00
0.11
829.00
0.00
C4 Chrysenes (a)
1214.00
0.00
0.09
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.00
0.13
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.00
0.09
913.00
0.00
Chrysene ,a)
844.00
826
0.00
0.09
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.01
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.00
0.09
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.03
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.00
0.02
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.09
385.00
0.00
Perylene(a)
967.00
431.00
0.01
0.23
967.00
0.00
Phenanthrene 'd'
596
34300
0.00
0.09
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.00
0.09
697.00
0.00
ESBTU FCVi
0.00
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 44 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-44
Field Sample ID
RREC13-44-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.98
0.0698
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.07
0.99
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.13
1.86
447.00
0.00
Acenaphthene (a)
491.00
33400
0.08
1.17
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.07
1.03
452.00
0.00
Anthracene (a)
594.00
1300
0.40
5.73
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.10
15.76
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.20
17.19
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.10
15.76
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
0.92
13.18
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.81
11.60
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.20
17.19
981.00
0.02
CI Chrysenes (a)
929.00
0.82
11.75
929.00
0.01
CI Fluorenes(a)
611.00
0.05
0.70
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.30
18.62
770.00
0.02
CI-Naphthalenes (a)
444.00
0.13
1.86
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.75
10.74
670.00
0.02
C2 Chrysenes (a)
1008.00
0.78
11.17
1008.00
0.01
C2 Fluorenes (a)
686.00
0.10
1.43
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.93
13.32
C2-Naphthalenes (a)
510.00
0.41
5.87
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.67
9.60
746.00
0.01
C3 Chrysenes (a)
1112.00
0.41
5.87
1112.00
0.01
C3 Fluorenes (a)
769.00
0.28
4.01
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.72
10.32
949.00
0.01
C3-Naphthalenes(a)
581.00
0.48
6.88
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.84
12.03
829.00
0.01
C4 Chrysenes (a)
1214.00
0.18
2.58
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.35
5.01
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.74
10.60
913.00
0.01
Chrysene ,a)
844.00
826
1.20
17.19
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.21
3.01
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.80
25.79
707.00
0.04
Fluorene ,a)
538.00
26,000.00
0.13
1.86
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.69
9.89
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.15
2.08
385.00
0.01
Perylene(a)
967.00
431.00
0.37
5.30
967.00
0.01
Phenanthrene 'd'
596
34300
0.78
11.17
596.00
0.02
Pyrene ,d'
697.00
9,090.00
1.40
20.06
697.00
0.03
ESBTU FCVi
0.33
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 45 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-44
Field Sample ID
RREC13-44-0001
Sample Depth
0-1
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.03
0.0603
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.08
1.28
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.19
3.15
447.00
0.01
Acenaphthene (a)
491.00
33400
0.14
2.32
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.09
1.48
452.00
0.00
Anthracene (a)
594.00
1300
0.43
7.13
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.60
26.53
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.70
28.19
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
1.90
31.51
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.20
19.90
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.70
11.61
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.60
26.53
981.00
0.03
CI Chrysenes (a)
929.00
1.10
18.24
929.00
0.02
CI Fluorenes(a)
611.00
0.09
1.53
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.80
29.85
770.00
0.04
CI-Naphthalenes (a)
444.00
0.16
2.65
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.30
21.56
670.00
0.03
C2 Chrysenes (a)
1008.00
1.50
24.88
1008.00
0.02
C2 Fluorenes (a)
686.00
0.25
4.15
686.00
0.01
C2-Fluoranthenes/Pyrenes
1.30
21.56
C2-Naphthalenes (a)
510.00
0.48
7.96
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
1.30
21.56
746.00
0.03
C3 Chrysenes (a)
1112.00
0.75
12.44
1112.00
0.01
C3 Fluorenes (a)
769.00
0.62
10.28
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
1.10
18.24
949.00
0.02
C3-Naphthalenes(a)
581.00
0.84
13.93
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
1.30
21.56
829.00
0.03
C4 Chrysenes (a)
1214.00
0.33
5.47
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.85
14.10
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
1.10
18.24
913.00
0.02
Chrysene ,a)
844.00
826
1.60
26.53
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.22
3.65
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.20
53.07
707.00
0.08
Fluorene ,a)
538.00
26,000.00
0.18
2.99
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.67
11.11
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.19
3.15
385.00
0.01
Perylene(a)
967.00
431.00
0.50
8.29
967.00
0.01
Phenanthrene 'd'
596
34300
1.00
16.58
596.00
0.03
Pyrene ,d'
697.00
9,090.00
1.80
29.85
697.00
0.04
ESBTU FCVi
0.55
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 46 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-44
Field Sample ID
RREC13-44-0103
Sample Depth
1-3
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Cone
Hg/g oc
Hg/g oc
Hg/g Dry
wt
Hg/g oc
Cocb
ESBTU FCVi
Hg/g Dry wt
Total Organic Carbon**
7
0.07
8.51
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.10
1.43
446.00
0.00
0.31
2-Methylnaphthalene
447.00
154800
0.18
2.50
447.00
0.01
0.42
Acenaphthene (a)
491.00
33400
0.12
1.71
491.00
0.00
0.22
Acenaphthylene (a)
452.00
24000
0.06
0.91
452.00
0.00
0.10
Anthracene (a)
594.00
1300
0.22
3.14
594.00
0.01
0.23
Benzo(a)anthracene (a)
841.00
4153
0.98
14.00
841.00
0.02
1.00
Benzo(a)pyrene (a)
965.00
3840
0.93
13.29
965.00
0.01
0.89
Benzo(b)fluoranthene (a)
979.00
2169
1.10
15.71
979.00
0.02
1.10
Benzo(e)pyrene (a)
967.00
4300
0.73
10.43
967.00
0.01
0.76
Benzo(g,h,i)perylene (a)
1095.00
648
0.35
5.00
1095.00
0.00
0.36
Benzo(k)fluoranthene (a)
981.00
1220
0.78
11.14
981.00
0.01
0.77
CI Chrysenes (a)
929.00
1.20
17.14
929.00
0.02
1.50
CI Fluorenes(a)
611.00
0.17
2.43
611.00
0.00
0.44
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.80
25.71
770.00
0.03
2.70
CI-Naphthalenes (a)
444.00
0.16
2.29
444.00
0.01
0.49
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.40
34.29
670.00
0.05
4.60
C2 Chrysenes (a)
1008.00
2.80
40.00
1008.00
0.04
3.40
C2 Fluorenes (a)
686.00
0.68
9.71
686.00
0.01
1.60
C2-Fluoranthenes/Pyrenes
2.20
31.43
3.40
C2-Naphthalenes (a)
510.00
1.00
14.29
510.00
0.03
3.50
C2-Phenanthrenes/Anthracenes (a)
746
3.60
51.43
746.00
0.07
7.10
C3 Chrysenes (a)
1112.00
1.30
18.57
1112.00
0.02
1.90
C3 Fluorenes (a)
769.00
2.00
28.57
769.00
0.04
3.80
C3-Fluoranthenes/Pyrenes
949.00
2.40
34.29
949.00
0.04
3.40
C3-Naphthalenes(a)
581.00
3.30
47.14
581.00
0.08
9.60
C3-Phenanthrenes/Anthracenes (a)
829.00
4.60
65.71
829.00
0.08
10.00
C4 Chrysenes (a)
1214.00
0.55
7.86
1214.00
0.01
1.00
C4-Naphthalenes (a)
657.00
3.30
47.14
657.00
0.07
7.90
C4-Phenanthrenes/Anthracenes (a)
913.00
3.60
51.43
913.00
0.06
7.60
Chrysene ,a)
844.00
826
1.10
15.71
844.00
0.02
1.10
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.09
1.21
1123.00
0.00
0.09
Fluoranthene ,a)
707.00
23,870.00
1.80
25.71
707.00
0.04
2.00
Fluorene ,a)
538.00
26,000.00
0.12
1.71
538.00
0.00
0.34
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.33
4.71
1115.00
0.00
0.30
Naphthalene ,a)
385.00
61,700.00
0.18
2.50
385.00
0.01
0.16
Perylene(a)
967.00
431.00
0.38
5.43
967.00
0.01
0.48
Phenanthrene 'd'
596
34300
0.77
11.00
596.00
0.02
1.30
Pyrene ,d'
697.00
9,090.00
1.50
21.43
697.00
0.03
2.00
ESBTU FCVi
0.55
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 47 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-44
Field Sample ID
RREC13-44-0305
Sample Depth
3-5
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Coc
Final
Hg/g oc
Hg/g oc
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
0.0851
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
3.64
446.00
0.01
2-Methylnaphthalene
447.00
154800
4.94
447.00
0.01
Acenaphthene (a)
491.00
33400
2.59
491.00
0.01
Acenaphthylene (a)
452.00
24000
1.18
452.00
0.00
Anthracene (a)
594.00
1300
2.70
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
11.75
841.00
0.01
Benzo(a)pyrene (a)
965.00
3840
10.46
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
12.93
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
8.93
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
4.23
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
9.05
981.00
0.01
CI Chrysenes (a)
929.00
17.63
929.00
0.02
CI Fluorenes(a)
611.00
5.17
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
31.73
770.00
0.04
CI-Naphthalenes (a)
444.00
5.76
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
54.05
670.00
0.08
C2 Chrysenes (a)
1008.00
39.95
1008.00
0.04
C2 Fluorenes (a)
686.00
18.80
686.00
0.03
C2-Fluoranthenes/Pyrenes
39.95
C2-Naphthalenes (a)
510.00
41.13
510.00
0.08
C2-Phenanthrenes/Anthracenes (a)
746
83.43
746.00
0.11
C3 Chrysenes (a)
1112.00
22.33
1112.00
0.02
C3 Fluorenes (a)
769.00
44.65
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
39.95
949.00
0.04
C3-Naphthalenes(a)
581.00
112.81
581.00
0.19
C3-Phenanthrenes/Anthracenes (a)
829.00
117.51
829.00
0.14
C4 Chrysenes (a)
1214.00
11.75
1214.00
0.01
C4-Naphthalenes (a)
657.00
92.83
657.00
0.14
C4-Phenanthrenes/Anthracenes (a)
913.00
89.31
913.00
0.10
Chrysene ,a)
844.00
826
12.93
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.00
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
23.50
707.00
0.03
Fluorene ,a)
538.00
26,000.00
4.00
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
3.53
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
1.88
385.00
0.00
Perylene(a)
967.00
431.00
5.64
967.00
0.01
Phenanthrene 'd'
596
34300
15.28
596.00
0.03
Pyrene ,d'
697.00
9,090.00
23.50
697.00
0.03
ESBTU FCVi
0.77
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 48 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-44
Field Sample ID
RREC13-44-0507
Sample Depth
5-7
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.56
0.0856
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.41
4.79
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.61
7.13
447.00
0.02
Acenaphthene (a)
491.00
33400
0.32
3.74
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.10
1.17
452.00
0.00
Anthracene (a)
594.00
1300
0.41
4.79
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.80
21.03
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.50
17.52
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.50
17.52
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.20
14.02
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.67
7.83
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.50
17.52
981.00
0.02
CI Chrysenes (a)
929.00
2.50
29.21
929.00
0.03
CI Fluorenes(a)
611.00
0.72
8.41
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.30
50.23
770.00
0.07
CI-Naphthalenes (a)
444.00
0.69
8.06
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.50
99.30
670.00
0.15
C2 Chrysenes (a)
1008.00
4.80
56.07
1008.00
0.06
C2 Fluorenes (a)
686.00
2.50
29.21
686.00
0.04
C2-Fluoranthenes/Pyrenes
4.80
56.07
C2-Naphthalenes (a)
510.00
6.10
71.26
510.00
0.14
C2-Phenanthrenes/Anthracenes (a)
746
13.00
151.87
746.00
0.20
C3 Chrysenes (a)
1112.00
2.70
31.54
1112.00
0.03
C3 Fluorenes (a)
769.00
6.80
79.44
769.00
0.10
C3-Fluoranthenes/Pyrenes
949.00
5.30
61.92
949.00
0.07
C3-Naphthalenes(a)
581.00
14.00
163.55
581.00
0.28
C3-Phenanthrenes/Anthracenes (a)
829.00
13.00
151.87
829.00
0.18
C4 Chrysenes (a)
1214.00
1.60
18.69
1214.00
0.02
C4-Naphthalenes (a)
657.00
14.00
163.55
657.00
0.25
C4-Phenanthrenes/Anthracenes (a)
913.00
9.00
105.14
913.00
0.12
Chrysene ,a)
844.00
826
2.00
23.36
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.17
1.99
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.10
59.58
707.00
0.08
Fluorene ,a)
538.00
26,000.00
0.39
4.56
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.58
6.78
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.40
4.67
385.00
0.01
Perylene(a)
967.00
431.00
0.58
6.78
967.00
0.01
Phenanthrene 'd'
596
34300
2.40
28.04
596.00
0.05
Pyrene ,d'
697.00
9,090.00
3.70
43.22
697.00
0.06
ESBTU FCVi
1.25
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 49 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-45
Field Sample ID
RREC13-45-SURF
Sample Depth
0-0.5
Sample Date
10/29/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7
0.07
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.20
2.86
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.35
5.00
447.00
0.01
Acenaphthene (a)
491.00
33400
0.23
3.29
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.17
2.43
452.00
0.01
Anthracene (a)
594.00
1300
1.00
14.29
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
3.40
48.57
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
3.60
51.43
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
3.00
42.86
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.20
31.43
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.50
21.43
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.70
38.57
981.00
0.04
CI Chrysenes (a)
929.00
2.10
30.00
929.00
0.03
CI Fluorenes(a)
611.00
0.13
1.86
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.90
55.71
770.00
0.07
CI-Naphthalenes (a)
444.00
0.37
5.29
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.10
30.00
670.00
0.04
C2 Chrysenes (a)
1008.00
1.40
20.00
1008.00
0.02
C2 Fluorenes (a)
686.00
0.17
2.43
686.00
0.00
C2-Fluoranthenes/Pyrenes
1.70
24.29
C2-Naphthalenes (a)
510.00
1.10
15.71
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
1.30
18.57
746.00
0.02
C3 Chrysenes (a)
1112.00
0.53
7.57
1112.00
0.01
C3 Fluorenes (a)
769.00
0.30
4.29
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.95
13.57
949.00
0.01
C3-Naphthalenes(a)
581.00
1.00
14.29
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
1.10
15.71
829.00
0.02
C4 Chrysenes (a)
1214.00
0.13
1.86
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.65
9.29
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.61
8.71
913.00
0.01
Chrysene ,a)
844.00
826
3.20
45.71
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.40
5.71
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
4.30
61.43
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.37
5.29
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.40
20.00
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.69
9.86
385.00
0.03
Perylene(a)
967.00
431.00
0.91
13.00
967.00
0.01
Phenanthrene 'd'
596
34300
2.20
31.43
596.00
0.05
Pyrene ,d'
697.00
9,090.00
3.80
54.29
697.00
0.08
ESBTU FCVi
0.81
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 50 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-45
Field Sample ID
RREC13-45-0001
Sample Depth
0-1
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.56
0.0756
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.19
2.51
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.26
3.37
447.00
0.01
Acenaphthene (a)
491.00
33400
0.22
2.91
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.11
1.46
452.00
0.00
Anthracene (a)
594.00
1300
0.65
8.60
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.70
22.49
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.60
21.16
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.80
23.81
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.10
14.55
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.70
9.26
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.30
17.20
981.00
0.02
CI Chrysenes (a)
929.00
1.00
13.23
929.00
0.01
CI Fluorenes(a)
611.00
0.13
1.72
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.30
30.42
770.00
0.04
CI-Naphthalenes (a)
444.00
0.28
3.70
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.80
23.81
670.00
0.04
C2 Chrysenes (a)
1008.00
1.10
14.55
1008.00
0.01
C2 Fluorenes (a)
686.00
0.20
2.65
686.00
0.00
C2-Fluoranthenes/Pyrenes
1.20
15.87
C2-Naphthalenes (a)
510.00
1.20
15.87
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
1.40
18.52
746.00
0.02
C3 Chrysenes (a)
1112.00
0.44
5.82
1112.00
0.01
C3 Fluorenes (a)
769.00
0.46
6.08
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.66
8.73
949.00
0.01
C3-Naphthalenes(a)
581.00
1.60
21.16
581.00
0.04
C3-Phenanthrenes/Anthracenes (a)
829.00
1.40
18.52
829.00
0.02
C4 Chrysenes (a)
1214.00
0.18
2.38
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.00
13.23
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.86
11.38
913.00
0.01
Chrysene ,a)
844.00
826
1.60
21.16
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.22
2.91
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.00
39.68
707.00
0.06
Fluorene ,a)
538.00
26,000.00
0.35
4.63
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.67
8.86
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.26
3.37
385.00
0.01
Perylene(a)
967.00
431.00
0.43
5.69
967.00
0.01
Phenanthrene 'd'
596
34300
1.70
22.49
596.00
0.04
Pyrene ,d'
697.00
9,090.00
2.40
31.75
697.00
0.05
ESBTU FCVi
0.49
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 51 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-45
Field Sample ID
RREC13-45-0103
Sample Depth
1-3
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.4
0.034
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.09
2.68
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.11
3.09
447.00
0.01
Acenaphthene (a)
491.00
33400
0.18
5.29
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.03
0.97
452.00
0.00
Anthracene (a)
594.00
1300
0.40
11.76
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
0.52
15.29
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
0.38
11.18
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
0.41
12.06
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
0.25
7.35
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.15
4.41
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.34
10.00
981.00
0.01
CI Chrysenes (a)
929.00
0.37
10.88
929.00
0.01
CI Fluorenes(a)
611.00
0.11
3.24
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.84
24.71
770.00
0.03
CI-Naphthalenes (a)
444.00
0.11
3.24
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.10
32.35
670.00
0.05
C2 Chrysenes (a)
1008.00
0.51
15.00
1008.00
0.01
C2 Fluorenes (a)
686.00
0.17
5.00
686.00
0.01
C2-Fluoranthenes/Pyrenes
0.51
15.00
C2-Naphthalenes (a)
510.00
0.83
24.41
510.00
0.05
C2-Phenanthrenes/Anthracenes (a)
746
1.00
29.41
746.00
0.04
C3 Chrysenes (a)
1112.00
0.24
7.06
1112.00
0.01
C3 Fluorenes (a)
769.00
0.37
10.88
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.37
10.88
949.00
0.01
C3-Naphthalenes(a)
581.00
1.50
44.12
581.00
0.08
C3-Phenanthrenes/Anthracenes (a)
829.00
1.10
32.35
829.00
0.04
C4 Chrysenes (a)
1214.00
0.11
3.24
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.20
35.29
657.00
0.05
C4-Phenanthrenes/Anthracenes (a)
913.00
0.67
19.71
913.00
0.02
Chrysene ,a)
844.00
826
0.48
14.12
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.05
1.44
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
1.30
38.24
707.00
0.05
Fluorene ,a)
538.00
26,000.00
0.28
8.24
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.14
4.12
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.11
3.09
385.00
0.01
Perylene(a)
967.00
431.00
0.12
3.53
967.00
0.00
Phenanthrene 'd'
596
34300
1.00
29.41
596.00
0.05
Pyrene ,d'
697.00
9,090.00
0.87
25.59
697.00
0.04
ESBTU FCVi
0.49
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 52 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-45
Field Sample ID
RREC13-45-0305
Sample Depth
3-5
Sample Date
11/1/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.97
0.0297
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.02
0.71
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.02
0.81
447.00
0.00
Acenaphthene (a)
491.00
33400
0.01
0.44
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.14
452.00
0.00
Anthracene (a)
594.00
1300
0.02
0.61
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.05
1.65
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.04
1.18
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.03
1.14
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.03
1.11
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.03
0.84
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.03
0.98
981.00
0.00
CI Chrysenes (a)
929.00
0.07
2.39
929.00
0.00
CI Fluorenes(a)
611.00
0.02
0.77
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.11
3.70
770.00
0.00
CI-Naphthalenes (a)
444.00
0.03
1.08
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.24
8.08
670.00
0.01
C2 Chrysenes (a)
1008.00
0.10
3.30
1008.00
0.00
C2 Fluorenes (a)
686.00
0.05
1.72
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.11
3.70
C2-Naphthalenes (a)
510.00
0.18
6.06
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.20
6.73
746.00
0.01
C3 Chrysenes (a)
1112.00
0.05
1.78
1112.00
0.00
C3 Fluorenes (a)
769.00
0.07
2.46
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.11
3.70
949.00
0.00
C3-Naphthalenes(a)
581.00
0.57
19.19
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
0.30
10.10
829.00
0.01
C4 Chrysenes (a)
1214.00
0.03
0.94
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.42
14.14
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.20
6.73
913.00
0.01
Chrysene ,a)
844.00
826
0.06
2.15
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.16
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.08
2.53
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.02
0.74
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.01
0.47
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.02
0.51
385.00
0.00
Perylene(a)
967.00
431.00
0.02
0.64
967.00
0.00
Phenanthrene 'd'
596
34300
0.11
3.70
596.00
0.01
Pyrene ,d'
697.00
9,090.00
0.08
2.53
697.00
0.00
ESBTU FCVi
0.08
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 53 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-46
Field Sample ID
RREC13-46-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.22
0.0822
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.44
5.35
446.00
0.01
2-Methylnaphthalene
447.00
154800
1.20
14.60
447.00
0.03
Acenaphthene (a)
491.00
33400
1.40
17.03
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.61
7.42
452.00
0.02
Anthracene (a)
594.00
1300
4.50
54.74
594.00
0.09
Benzo(a)anthracene (a)
841.00
4153
10.00
121.65
841.00
0.14
Benzo(a)pyrene (a)
965.00
3840
8.60
104.62
965.00
0.11
Benzo(b)fluoranthene (a)
979.00
2169
8.60
104.62
979.00
0.11
Benzo(e)pyrene (a)
967.00
4300
5.40
65.69
967.00
0.07
Benzo(g,h,i)perylene (a)
1095.00
648
5.50
66.91
1095.00
0.06
Benzo(k)fluoranthene (a)
981.00
1220
7.20
87.59
981.00
0.09
CI Chrysenes (a)
929.00
4.20
51.09
929.00
0.06
CI Fluorenes(a)
611.00
0.30
3.65
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
9.10
110.71
770.00
0.14
CI-Naphthalenes (a)
444.00
0.78
9.49
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.80
58.39
670.00
0.09
C2 Chrysenes (a)
1008.00
2.20
26.76
1008.00
0.03
C2 Fluorenes (a)
686.00
0.25
3.04
686.00
0.00
C2-Fluoranthenes/Pyrenes
3.10
37.71
C2-Naphthalenes (a)
510.00
1.20
14.60
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
1.20
14.60
746.00
0.02
C3 Chrysenes (a)
1112.00
0.68
8.27
1112.00
0.01
C3 Fluorenes (a)
769.00
1.20
14.60
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.20
14.60
949.00
0.02
C3-Naphthalenes(a)
581.00
1.20
14.60
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
1.20
14.60
829.00
0.02
C4 Chrysenes (a)
1214.00
1.20
14.60
1214.00
0.01
C4-Naphthalenes (a)
657.00
1.20
14.60
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
1.20
14.60
913.00
0.02
Chrysene ,a)
844.00
826
8.90
108.27
844.00
0.13
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
1.60
19.46
1123.00
0.02
Fluoranthene ,a)
707.00
23,870.00
20.00
243.31
707.00
0.34
Fluorene ,a)
538.00
26,000.00
2.00
24.33
538.00
0.05
Indeno(l,2,3-cd)pyrene ,a)
1115.00
5.00
60.83
1115.00
0.05
Naphthalene ,a)
385.00
61,700.00
2.60
31.63
385.00
0.08
Perylene(a)
967.00
431.00
2.60
31.63
967.00
0.03
Phenanthrene 'd'
596
34300
14.00
170.32
596.00
0.29
Pyrene ,d'
697.00
9,090.00
14.00
170.32
697.00
0.24
ESBTU FCVi
2.27
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 54 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-46
Field Sample ID
RREC13-46-0001
Sample Depth
0-1
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.83
0.0583
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.28
4.80
446.00
0.01
2-Methylnaphthalene
447.00
154800
1.35
23.16
447.00
0.05
Acenaphthene (a)
491.00
33400
1.50
25.73
491.00
0.05
Acenaphthylene (a)
452.00
24000
0.43
7.38
452.00
0.02
Anthracene (a)
594.00
1300
3.50
60.03
594.00
0.10
Benzo(a)anthracene (a)
841.00
4153
15.00
257.29
841.00
0.31
Benzo(a)pyrene (a)
965.00
3840
13.00
222.98
965.00
0.23
Benzo(b)fluoranthene (a)
979.00
2169
12.00
205.83
979.00
0.21
Benzo(e)pyrene (a)
967.00
4300
8.10
138.94
967.00
0.14
Benzo(g,h,i)perylene (a)
1095.00
648
8.00
137.22
1095.00
0.13
Benzo(k)fluoranthene (a)
981.00
1220
11.00
188.68
981.00
0.19
CI Chrysenes (a)
929.00
6.60
113.21
929.00
0.12
CI Fluorenes(a)
611.00
0.45
7.72
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
12.00
205.83
770.00
0.27
CI-Naphthalenes (a)
444.00
0.55
9.43
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.40
58.32
670.00
0.09
C2 Chrysenes (a)
1008.00
3.70
63.46
1008.00
0.06
C2 Fluorenes (a)
686.00
1.00
17.15
686.00
0.03
C2-Fluoranthenes/Pyrenes
5.50
94.34
C2-Naphthalenes (a)
510.00
1.35
23.16
510.00
0.05
C2-Phenanthrenes/Anthracenes (a)
746
1.35
23.16
746.00
0.03
C3 Chrysenes (a)
1112.00
1.40
24.01
1112.00
0.02
C3 Fluorenes (a)
769.00
2.30
39.45
769.00
0.05
C3-Fluoranthenes/Pyrenes
949.00
3.10
53.17
949.00
0.06
C3-Naphthalenes(a)
581.00
1.35
23.16
581.00
0.04
C3-Phenanthrenes/Anthracenes (a)
829.00
1.35
23.16
829.00
0.03
C4 Chrysenes (a)
1214.00
0.55
9.43
1214.00
0.01
C4-Naphthalenes (a)
657.00
3.80
65.18
657.00
0.10
C4-Phenanthrenes/Anthracenes (a)
913.00
3.20
54.89
913.00
0.06
Chrysene ,a)
844.00
826
14.00
240.14
844.00
0.28
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
2.50
42.88
1123.00
0.04
Fluoranthene ,a)
707.00
23,870.00
21.00
360.21
707.00
0.51
Fluorene ,a)
538.00
26,000.00
1.10
18.87
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
7.10
121.78
1115.00
0.11
Naphthalene ,a)
385.00
61,700.00
1.35
23.16
385.00
0.06
Perylene(a)
967.00
431.00
3.20
54.89
967.00
0.06
Phenanthrene 'd'
596
34300
7.10
121.78
596.00
0.20
Pyrene ,d'
697.00
9,090.00
15.00
257.29
697.00
0.37
ESBTU FCVi
3.61
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 55 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-46
Field Sample ID
RREC13-46-0103
Sample Depth
1-3
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.59
0.0559
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.05
0.82
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.18
3.22
447.00
0.01
Acenaphthene (a)
491.00
33400
0.08
1.47
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.05
0.97
452.00
0.00
Anthracene (a)
594.00
1300
0.42
7.51
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.30
23.26
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
0.89
15.92
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
0.90
16.10
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
0.67
11.99
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.64
11.45
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.10
19.68
981.00
0.02
CI Chrysenes (a)
929.00
0.52
9.30
929.00
0.01
CI Fluorenes(a)
611.00
0.04
0.79
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.20
21.47
770.00
0.03
CI-Naphthalenes (a)
444.00
0.07
1.32
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.47
8.41
670.00
0.01
C2 Chrysenes (a)
1008.00
0.32
5.72
1008.00
0.01
C2 Fluorenes (a)
686.00
0.08
1.36
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.45
8.05
C2-Naphthalenes (a)
510.00
0.18
3.22
510.00
0.01
C2-Phenanthrenes/Anthracenes (a)
746
0.18
3.22
746.00
0.00
C3 Chrysenes (a)
1112.00
0.12
2.15
1112.00
0.00
C3 Fluorenes (a)
769.00
0.18
3.22
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.23
4.11
949.00
0.00
C3-Naphthalenes(a)
581.00
0.18
3.22
581.00
0.01
C3-Phenanthrenes/Anthracenes (a)
829.00
0.18
3.22
829.00
0.00
C4 Chrysenes (a)
1214.00
0.05
0.86
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.18
3.22
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.18
3.22
913.00
0.00
Chrysene ,a)
844.00
826
1.10
19.68
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.18
3.22
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.60
46.51
707.00
0.07
Fluorene ,a)
538.00
26,000.00
0.26
4.65
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.58
10.38
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.18
3.22
385.00
0.01
Perylene(a)
967.00
431.00
0.18
3.22
967.00
0.00
Phenanthrene 'd'
596
34300
1.70
30.41
596.00
0.05
Pyrene ,d'
697.00
9,090.00
1.80
32.20
697.00
0.05
ESBTU FCVi
0.40
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 56 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-46
Field Sample ID
RREC13-46-0305
Sample Depth
3-5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
2.34
0.0234
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.01
0.24
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.01
0.24
447.00
0.00
Acenaphthene (a)
491.00
33400
0.01
0.32
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.10
452.00
0.00
Anthracene (a)
594.00
1300
0.01
0.24
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.05
2.14
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.04
1.71
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.05
2.26
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.04
1.62
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.04
1.67
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.04
1.67
981.00
0.00
CI Chrysenes (a)
929.00
0.04
1.79
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.16
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.07
3.08
770.00
0.00
CI-Naphthalenes (a)
444.00
0.01
0.35
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.04
1.79
670.00
0.00
C2 Chrysenes (a)
1008.00
0.05
2.18
1008.00
0.00
C2 Fluorenes (a)
686.00
0.01
0.47
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.06
2.39
C2-Naphthalenes (a)
510.00
0.02
1.03
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.05
2.22
746.00
0.00
C3 Chrysenes (a)
1112.00
0.03
1.32
1112.00
0.00
C3 Fluorenes (a)
769.00
0.03
1.24
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.05
2.09
949.00
0.00
C3-Naphthalenes(a)
581.00
0.05
2.05
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.09
3.97
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.41
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.07
2.95
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.07
2.86
913.00
0.00
Chrysene ,a)
844.00
826
0.05
2.22
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.01
0.38
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.08
3.55
707.00
0.01
Fluorene ,a)
538.00
26,000.00
0.01
0.32
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.03
1.24
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.01
0.51
385.00
0.00
Perylene(a)
967.00
431.00
0.03
1.15
967.00
0.00
Phenanthrene 'd'
596
34300
0.03
1.45
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.07
3.08
697.00
0.00
ESBTU FCVi
0.05
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 57 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-46
Field Sample ID
RREC13-46-0507
Sample Depth
5-7
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
1.84
0.0184
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.25
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.01
0.57
447.00
0.00
Acenaphthene (a)
491.00
33400
0.01
0.38
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.11
452.00
0.00
Anthracene (a)
594.00
1300
0.01
0.57
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.06
3.48
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.05
2.72
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.06
3.26
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.04
2.28
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.04
2.39
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.04
2.39
981.00
0.00
CI Chrysenes (a)
929.00
0.04
2.28
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.21
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.07
3.91
770.00
0.01
CI-Naphthalenes (a)
444.00
0.01
0.36
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.05
2.50
670.00
0.00
C2 Chrysenes (a)
1008.00
0.05
2.72
1008.00
0.00
C2 Fluorenes (a)
686.00
0.01
0.60
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.06
2.99
C2-Naphthalenes (a)
510.00
0.02
1.20
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.05
2.93
746.00
0.00
C3 Chrysenes (a)
1112.00
0.03
1.41
1112.00
0.00
C3 Fluorenes (a)
769.00
0.03
1.47
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.05
2.45
949.00
0.00
C3-Naphthalenes(a)
581.00
0.05
2.55
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.10
5.22
829.00
0.01
C4 Chrysenes (a)
1214.00
0.01
0.52
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.07
3.70
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.07
3.75
913.00
0.00
Chrysene ,a)
844.00
826
0.06
3.37
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.01
0.60
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.11
5.98
707.00
0.01
Fluorene ,a)
538.00
26,000.00
0.01
0.38
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.03
1.85
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.01
0.57
385.00
0.00
Perylene(a)
967.00
431.00
0.03
1.58
967.00
0.00
Phenanthrene 'd'
596
34300
0.04
1.96
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.09
4.95
697.00
0.01
ESBTU FCVi
0.07
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 58 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-46
Field Sample ID
RREC13-46-0710
Sample Depth
7-10
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
3.23
0.0323
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.00
0.12
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.00
0.06
447.00
0.00
Acenaphthene (a)
491.00
33400
0.00
0.07
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.00
0.02
452.00
0.00
Anthracene (a)
594.00
1300
0.00
0.06
594.00
0.00
Benzo(a)anthracene (a)
841.00
4153
0.02
0.46
841.00
0.00
Benzo(a)pyrene (a)
965.00
3840
0.02
0.46
965.00
0.00
Benzo(b)fluoranthene (a)
979.00
2169
0.02
0.53
979.00
0.00
Benzo(e)pyrene (a)
967.00
4300
0.02
0.50
967.00
0.00
Benzo(g,h,i)perylene (a)
1095.00
648
0.01
0.43
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
0.01
0.40
981.00
0.00
CI Chrysenes (a)
929.00
0.03
0.77
929.00
0.00
CI Fluorenes(a)
611.00
0.00
0.08
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.03
0.99
770.00
0.00
CI-Naphthalenes (a)
444.00
0.01
0.15
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.04
1.08
670.00
0.00
C2 Chrysenes (a)
1008.00
0.05
1.42
1008.00
0.00
C2 Fluorenes (a)
686.00
0.01
0.20
686.00
0.00
C2-Fluoranthenes/Pyrenes
0.04
1.27
C2-Naphthalenes (a)
510.00
0.02
0.59
510.00
0.00
C2-Phenanthrenes/Anthracenes (a)
746
0.04
1.36
746.00
0.00
C3 Chrysenes (a)
1112.00
0.03
0.80
1112.00
0.00
C3 Fluorenes (a)
769.00
0.02
0.50
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.04
1.24
949.00
0.00
C3-Naphthalenes(a)
581.00
0.05
1.42
581.00
0.00
C3-Phenanthrenes/Anthracenes (a)
829.00
0.08
2.41
829.00
0.00
C4 Chrysenes (a)
1214.00
0.01
0.43
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.06
1.89
657.00
0.00
C4-Phenanthrenes/Anthracenes (a)
913.00
0.05
1.67
913.00
0.00
Chrysene ,a)
844.00
826
0.02
0.74
844.00
0.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.00
0.07
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
0.02
0.59
707.00
0.00
Fluorene ,a)
538.00
26,000.00
0.00
0.09
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.01
0.23
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.00
0.06
385.00
0.00
Perylene(a)
967.00
431.00
0.02
0.46
967.00
0.00
Phenanthrene 'd'
596
34300
0.01
0.37
596.00
0.00
Pyrene ,d'
697.00
9,090.00
0.02
0.71
697.00
0.00
ESBTU FCVi
0.02
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 59 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-47
Field Sample ID
RREC13-47-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.33
0.0833
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.15
1.80
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.28
3.36
447.00
0.01
Acenaphthene (a)
491.00
33400
0.12
1.44
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.09
1.03
452.00
0.00
Anthracene (a)
594.00
1300
0.36
4.32
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.50
18.01
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.60
19.21
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.80
21.61
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.20
14.41
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.88
10.56
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.30
15.61
981.00
0.02
CI Chrysenes (a)
929.00
1.10
13.21
929.00
0.01
CI Fluorenes(a)
611.00
0.08
1.01
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.80
21.61
770.00
0.03
CI-Naphthalenes (a)
444.00
0.29
3.48
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.10
13.21
670.00
0.02
C2 Chrysenes (a)
1008.00
1.20
14.41
1008.00
0.01
C2 Fluorenes (a)
686.00
0.20
2.40
686.00
0.00
C2-Fluoranthenes/Pyrenes
1.30
15.61
C2-Naphthalenes (a)
510.00
0.92
11.04
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
1.10
13.21
746.00
0.02
C3 Chrysenes (a)
1112.00
0.52
6.24
1112.00
0.01
C3 Fluorenes (a)
769.00
0.53
6.36
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.93
11.16
949.00
0.01
C3-Naphthalenes(a)
581.00
1.30
15.61
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
1.40
16.81
829.00
0.02
C4 Chrysenes (a)
1214.00
0.22
2.64
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.10
13.21
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
1.10
13.21
913.00
0.01
Chrysene ,a)
844.00
826
1.60
19.21
844.00
0.02
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.23
2.76
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.40
28.81
707.00
0.04
Fluorene ,a)
538.00
26,000.00
0.18
2.16
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.80
9.60
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.39
4.68
385.00
0.01
Perylene(a)
967.00
431.00
0.46
5.52
967.00
0.01
Phenanthrene 'd'
596
34300
1.10
13.21
596.00
0.02
Pyrene ,d'
697.00
9,090.00
1.90
22.81
697.00
0.03
ESBTU FCVi
0.38
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 60 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-47
Field Sample ID
RREC13-47-SURF-FD
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.3
0.063
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.15
2.38
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.28
4.44
447.00
0.01
Acenaphthene (a)
491.00
33400
0.14
2.22
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.10
1.59
452.00
0.00
Anthracene (a)
594.00
1300
0.49
7.78
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.90
30.16
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.00
31.75
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
1.80
28.57
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.40
22.22
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.00
15.87
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.90
30.16
981.00
0.03
CI Chrysenes (a)
929.00
1.20
19.05
929.00
0.02
CI Fluorenes(a)
611.00
0.09
1.37
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.10
33.33
770.00
0.04
CI-Naphthalenes (a)
444.00
0.29
4.60
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.30
20.63
670.00
0.03
C2 Chrysenes (a)
1008.00
1.20
19.05
1008.00
0.02
C2 Fluorenes (a)
686.00
0.21
3.33
686.00
0.00
C2-Fluoranthenes/Pyrenes
1.20
19.05
C2-Naphthalenes (a)
510.00
0.96
15.24
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
1.20
19.05
746.00
0.03
C3 Chrysenes (a)
1112.00
0.51
8.10
1112.00
0.01
C3 Fluorenes (a)
769.00
0.60
9.52
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.90
14.29
949.00
0.02
C3-Naphthalenes(a)
581.00
1.30
20.63
581.00
0.04
C3-Phenanthrenes/Anthracenes (a)
829.00
1.40
22.22
829.00
0.03
C4 Chrysenes (a)
1214.00
0.18
2.86
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.10
17.46
657.00
0.03
C4-Phenanthrenes/Anthracenes (a)
913.00
1.00
15.87
913.00
0.02
Chrysene ,a)
844.00
826
1.90
30.16
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.29
4.60
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.10
49.21
707.00
0.07
Fluorene ,a)
538.00
26,000.00
0.20
3.17
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.94
14.92
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.22
3.49
385.00
0.01
Perylene(a)
967.00
431.00
0.55
8.73
967.00
0.01
Phenanthrene 'd'
596
34300
1.30
20.63
596.00
0.03
Pyrene ,d'
697.00
9,090.00
2.30
36.51
697.00
0.05
ESBTU FCVi
0.58
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 61 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-47
Field Sample ID
RREC13-47-0001
Sample Depth
0-1
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.08
0.0608
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.15
2.47
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.15
2.38
447.00
0.01
Acenaphthene (a)
491.00
33400
0.14
2.30
491.00
0.00
Acenaphthylene (a)
452.00
24000
0.08
1.38
452.00
0.00
Anthracene (a)
594.00
1300
0.31
5.10
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.40
23.03
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
1.50
24.67
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
1.50
24.67
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.10
18.09
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.85
13.98
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.50
24.67
981.00
0.03
CI Chrysenes (a)
929.00
0.96
15.79
929.00
0.02
CI Fluorenes(a)
611.00
0.08
1.28
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.60
26.32
770.00
0.03
CI-Naphthalenes (a)
444.00
0.26
4.28
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.10
18.09
670.00
0.03
C2 Chrysenes (a)
1008.00
0.93
15.30
1008.00
0.02
C2 Fluorenes (a)
686.00
0.19
3.13
686.00
0.00
C2-Fluoranthenes/Pyrenes
1.10
18.09
C2-Naphthalenes (a)
510.00
1.00
16.45
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
1.10
18.09
746.00
0.02
C3 Chrysenes (a)
1112.00
0.49
8.06
1112.00
0.01
C3 Fluorenes (a)
769.00
0.58
9.54
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.75
12.34
949.00
0.01
C3-Naphthalenes(a)
581.00
1.40
23.03
581.00
0.04
C3-Phenanthrenes/Anthracenes (a)
829.00
1.40
23.03
829.00
0.03
C4 Chrysenes (a)
1214.00
0.16
2.63
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.10
18.09
657.00
0.03
C4-Phenanthrenes/Anthracenes (a)
913.00
0.89
14.64
913.00
0.02
Chrysene ,a)
844.00
826
1.50
24.67
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.26
4.28
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.20
36.18
707.00
0.05
Fluorene ,a)
538.00
26,000.00
0.14
2.30
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.81
13.32
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.15
2.38
385.00
0.01
Perylene(a)
967.00
431.00
0.45
7.40
967.00
0.01
Phenanthrene 'd'
596
34300
1.10
18.09
596.00
0.03
Pyrene ,d'
697.00
9,090.00
1.80
29.61
697.00
0.04
ESBTU FCVi
0.49
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 62 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-47
Field Sample ID
RREC13-47-0103
Sample Depth
1-3
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.06
0.0706
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.10
1.40
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.23
3.19
447.00
0.01
Acenaphthene (a)
491.00
33400
0.21
2.97
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.10
1.42
452.00
0.00
Anthracene (a)
594.00
1300
0.43
6.09
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.90
26.91
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
2.00
28.33
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.00
28.33
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.40
19.83
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.00
14.16
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.90
26.91
981.00
0.03
CI Chrysenes (a)
929.00
1.40
19.83
929.00
0.02
CI Fluorenes(a)
611.00
0.12
1.70
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.20
31.16
770.00
0.04
CI-Naphthalenes (a)
444.00
0.19
2.69
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.70
24.08
670.00
0.04
C2 Chrysenes (a)
1008.00
1.50
21.25
1008.00
0.02
C2 Fluorenes (a)
686.00
0.34
4.82
686.00
0.01
C2-Fluoranthenes/Pyrenes
1.60
22.66
C2-Naphthalenes (a)
510.00
0.84
11.90
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
1.90
26.91
746.00
0.04
C3 Chrysenes (a)
1112.00
0.69
9.77
1112.00
0.01
C3 Fluorenes (a)
769.00
0.95
13.46
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.10
15.58
949.00
0.02
C3-Naphthalenes(a)
581.00
1.70
24.08
581.00
0.04
C3-Phenanthrenes/Anthracenes (a)
829.00
2.20
31.16
829.00
0.04
C4 Chrysenes (a)
1214.00
0.27
3.82
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.80
25.50
657.00
0.04
C4-Phenanthrenes/Anthracenes (a)
913.00
1.70
24.08
913.00
0.03
Chrysene ,a)
844.00
826
1.90
26.91
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.31
4.39
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.20
45.33
707.00
0.06
Fluorene ,a)
538.00
26,000.00
0.25
3.54
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.97
13.74
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.23
3.19
385.00
0.01
Perylene(a)
967.00
431.00
0.58
8.22
967.00
0.01
Phenanthrene 'd'
596
34300
1.20
17.00
596.00
0.03
Pyrene ,d'
697.00
9,090.00
2.30
32.58
697.00
0.05
ESBTU FCVi
0.59
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 63 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-47
Field Sample ID
RREC13-47-0103-FD
Sample Depth
1-3
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.89
0.0789
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.09
1.14
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.22
2.72
447.00
0.01
Acenaphthene (a)
491.00
33400
0.20
2.53
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.10
1.27
452.00
0.00
Anthracene (a)
594.00
1300
0.49
6.21
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.00
25.35
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
2.00
25.35
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
1.90
24.08
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.40
17.74
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.10
13.94
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.80
22.81
981.00
0.02
CI Chrysenes (a)
929.00
1.30
16.48
929.00
0.02
CI Fluorenes(a)
611.00
0.13
1.65
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.20
27.88
770.00
0.04
CI-Naphthalenes (a)
444.00
0.17
2.15
444.00
0.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.70
21.55
670.00
0.03
C2 Chrysenes (a)
1008.00
1.30
16.48
1008.00
0.02
C2 Fluorenes (a)
686.00
0.32
4.06
686.00
0.01
C2-Fluoranthenes/Pyrenes
1.50
19.01
C2-Naphthalenes (a)
510.00
0.77
9.76
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
1.80
22.81
746.00
0.03
C3 Chrysenes (a)
1112.00
0.59
7.48
1112.00
0.01
C3 Fluorenes (a)
769.00
0.90
11.41
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
1.00
12.67
949.00
0.01
C3-Naphthalenes(a)
581.00
1.40
17.74
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
2.00
25.35
829.00
0.03
C4 Chrysenes (a)
1214.00
0.25
3.17
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.70
21.55
657.00
0.03
C4-Phenanthrenes/Anthracenes (a)
913.00
1.60
20.28
913.00
0.02
Chrysene ,a)
844.00
826
2.00
25.35
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.33
4.18
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.50
44.36
707.00
0.06
Fluorene ,a)
538.00
26,000.00
0.17
2.15
538.00
0.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.00
12.67
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.22
2.72
385.00
0.01
Perylene(a)
967.00
431.00
0.59
7.48
967.00
0.01
Phenanthrene 'd'
596
34300
1.40
17.74
596.00
0.03
Pyrene ,d'
697.00
9,090.00
2.30
29.15
697.00
0.04
ESBTU FCVi
0.53
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 64 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-47
Field Sample ID
RREC13-47-0305
Sample Depth
3-5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.79
0.0779
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.25
3.21
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.31
3.98
447.00
0.01
Acenaphthene (a)
491.00
33400
0.27
3.47
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.13
1.67
452.00
0.00
Anthracene (a)
594.00
1300
0.49
6.29
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.00
25.67
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
2.00
25.67
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.00
25.67
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.40
17.97
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.94
12.07
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.00
25.67
981.00
0.03
CI Chrysenes (a)
929.00
1.50
19.26
929.00
0.02
CI Fluorenes(a)
611.00
0.23
2.95
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.80
35.94
770.00
0.05
CI-Naphthalenes (a)
444.00
0.31
3.98
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.90
37.23
670.00
0.06
C2 Chrysenes (a)
1008.00
2.20
28.24
1008.00
0.03
C2 Fluorenes (a)
686.00
0.74
9.50
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.20
28.24
C2-Naphthalenes (a)
510.00
2.00
25.67
510.00
0.05
C2-Phenanthrenes/Anthracenes (a)
746
3.50
44.93
746.00
0.06
C3 Chrysenes (a)
1112.00
0.99
12.71
1112.00
0.01
C3 Fluorenes (a)
769.00
2.10
26.96
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
1.70
21.82
949.00
0.02
C3-Naphthalenes(a)
581.00
4.10
52.63
581.00
0.09
C3-Phenanthrenes/Anthracenes (a)
829.00
4.20
53.92
829.00
0.07
C4 Chrysenes (a)
1214.00
0.46
5.91
1214.00
0.00
C4-Naphthalenes (a)
657.00
3.70
47.50
657.00
0.07
C4-Phenanthrenes/Anthracenes (a)
913.00
3.00
38.51
913.00
0.04
Chrysene ,a)
844.00
826
1.90
24.39
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.24
3.08
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.70
47.50
707.00
0.07
Fluorene ,a)
538.00
26,000.00
0.24
3.08
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.89
11.42
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.31
3.98
385.00
0.01
Perylene(a)
967.00
431.00
0.64
8.22
967.00
0.01
Phenanthrene 'd'
596
34300
1.80
23.11
596.00
0.04
Pyrene ,d'
697.00
9,090.00
2.90
37.23
697.00
0.05
ESBTU FCVi
0.71
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 65 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-47
Field Sample ID
RREC13-47-0305-FD
Sample Depth
3-5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.1
0.071
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.15
2.11
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.26
3.66
447.00
0.01
Acenaphthene (a)
491.00
33400
0.25
3.52
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.12
1.69
452.00
0.00
Anthracene (a)
594.00
1300
0.56
7.89
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.30
32.39
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.40
33.80
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.40
33.80
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.70
23.94
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.30
18.31
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.20
30.99
981.00
0.03
CI Chrysenes (a)
929.00
1.60
22.54
929.00
0.02
CI Fluorenes(a)
611.00
0.17
2.39
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.90
40.85
770.00
0.05
CI-Naphthalenes (a)
444.00
0.22
3.10
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.30
32.39
670.00
0.05
C2 Chrysenes (a)
1008.00
1.80
25.35
1008.00
0.03
C2 Fluorenes (a)
686.00
0.52
7.32
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.10
29.58
C2-Naphthalenes (a)
510.00
1.20
16.90
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
2.70
38.03
746.00
0.05
C3 Chrysenes (a)
1112.00
0.83
11.69
1112.00
0.01
C3 Fluorenes (a)
769.00
1.60
22.54
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
1.60
22.54
949.00
0.02
C3-Naphthalenes(a)
581.00
2.40
33.80
581.00
0.06
C3-Phenanthrenes/Anthracenes (a)
829.00
3.30
46.48
829.00
0.06
C4 Chrysenes (a)
1214.00
0.39
5.49
1214.00
0.00
C4-Naphthalenes (a)
657.00
2.50
35.21
657.00
0.05
C4-Phenanthrenes/Anthracenes (a)
913.00
2.40
33.80
913.00
0.04
Chrysene ,a)
844.00
826
2.30
32.39
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.39
5.49
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.40
61.97
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.26
3.66
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.20
16.90
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.26
3.66
385.00
0.01
Perylene(a)
967.00
431.00
0.73
10.28
967.00
0.01
Phenanthrene 'd'
596
34300
1.70
23.94
596.00
0.04
Pyrene ,d'
697.00
9,090.00
3.20
45.07
697.00
0.06
ESBTU FCVi
0.77
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 66 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-47
Field Sample ID
RREC13-47-0507
Sample Depth
5-7
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.61
0.0861
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.61
7.08
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.45
5.23
447.00
0.01
Acenaphthene (a)
491.00
33400
0.34
3.95
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.22
2.56
452.00
0.01
Anthracene (a)
594.00
1300
0.58
6.74
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
1.80
20.91
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
1.60
18.58
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
1.80
20.91
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.30
15.10
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.30
15.10
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.20
13.94
981.00
0.01
CI Chrysenes (a)
929.00
1.80
20.91
929.00
0.02
CI Fluorenes(a)
611.00
0.32
3.72
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.30
26.71
770.00
0.03
CI-Naphthalenes (a)
444.00
0.75
8.71
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.80
32.52
670.00
0.05
C2 Chrysenes (a)
1008.00
2.20
25.55
1008.00
0.03
C2 Fluorenes (a)
686.00
1.10
12.78
686.00
0.02
C2-Fluoranthenes/Pyrenes
2.30
26.71
C2-Naphthalenes (a)
510.00
5.20
60.39
510.00
0.12
C2-Phenanthrenes/Anthracenes (a)
746
4.70
54.59
746.00
0.07
C3 Chrysenes (a)
1112.00
1.30
15.10
1112.00
0.01
C3 Fluorenes (a)
769.00
2.70
31.36
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
2.10
24.39
949.00
0.03
C3-Naphthalenes(a)
581.00
7.40
85.95
581.00
0.15
C3-Phenanthrenes/Anthracenes (a)
829.00
6.00
69.69
829.00
0.08
C4 Chrysenes (a)
1214.00
0.76
8.83
1214.00
0.01
C4-Naphthalenes (a)
657.00
6.60
76.66
657.00
0.12
C4-Phenanthrenes/Anthracenes (a)
913.00
4.20
48.78
913.00
0.05
Chrysene ,a)
844.00
826
1.90
22.07
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.42
4.88
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
2.40
27.87
707.00
0.04
Fluorene ,a)
538.00
26,000.00
0.49
5.69
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
12.78
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.45
5.23
385.00
0.01
Perylene(a)
967.00
431.00
0.52
6.04
967.00
0.01
Phenanthrene 'd'
596
34300
2.00
23.23
596.00
0.04
Pyrene ,d'
697.00
9,090.00
3.30
38.33
697.00
0.06
ESBTU FCVi
0.70
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 67 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-47
Field Sample ID
RREC13-47-0709
Sample Depth
7-9
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.72
0.0872
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.30
3.38
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.30
3.38
447.00
0.01
Acenaphthene (a)
491.00
33400
0.49
5.62
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.30
3.38
452.00
0.01
Anthracene (a)
594.00
1300
0.68
7.80
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.10
24.08
841.00
0.03
Benzo(a)pyrene (a)
965.00
3840
2.10
24.08
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
1.90
21.79
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.60
18.35
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.40
16.06
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
1.50
17.20
981.00
0.02
CI Chrysenes (a)
929.00
2.30
26.38
929.00
0.03
CI Fluorenes(a)
611.00
0.62
7.11
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.90
33.26
770.00
0.04
CI-Naphthalenes (a)
444.00
0.74
8.49
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.70
53.90
670.00
0.08
C2 Chrysenes (a)
1008.00
2.40
27.52
1008.00
0.03
C2 Fluorenes (a)
686.00
1.80
20.64
686.00
0.03
C2-Fluoranthenes/Pyrenes
2.90
33.26
C2-Naphthalenes (a)
510.00
7.30
83.72
510.00
0.16
C2-Phenanthrenes/Anthracenes (a)
746
7.20
82.57
746.00
0.11
C3 Chrysenes (a)
1112.00
1.20
13.76
1112.00
0.01
C3 Fluorenes (a)
769.00
4.00
45.87
769.00
0.06
C3-Fluoranthenes/Pyrenes
949.00
2.30
26.38
949.00
0.03
C3-Naphthalenes(a)
581.00
13.00
149.08
581.00
0.26
C3-Phenanthrenes/Anthracenes (a)
829.00
7.70
88.30
829.00
0.11
C4 Chrysenes (a)
1214.00
0.72
8.26
1214.00
0.01
C4-Naphthalenes (a)
657.00
12.00
137.61
657.00
0.21
C4-Phenanthrenes/Anthracenes (a)
913.00
5.10
58.49
913.00
0.06
Chrysene ,a)
844.00
826
2.20
25.23
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.47
5.39
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
3.10
35.55
707.00
0.05
Fluorene ,a)
538.00
26,000.00
0.42
4.82
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.30
14.91
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.30
3.38
385.00
0.01
Perylene(a)
967.00
431.00
0.59
6.77
967.00
0.01
Phenanthrene 'd'
596
34300
2.70
30.96
596.00
0.05
Pyrene ,d'
697.00
9,090.00
4.20
48.17
697.00
0.07
ESBTU FCVi
0.91
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 68 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-47
Field Sample ID
RREC13-47-0911
Sample Depth
9-11
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.81
0.0981
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.93
9.48
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.20
12.23
447.00
0.03
Acenaphthene (a)
491.00
33400
0.55
5.61
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.21
2.14
452.00
0.00
Anthracene (a)
594.00
1300
0.90
9.17
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
3.10
31.60
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.80
28.54
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.70
27.52
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
2.00
20.39
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.10
11.21
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.60
26.50
981.00
0.03
CI Chrysenes (a)
929.00
2.80
28.54
929.00
0.03
CI Fluorenes(a)
611.00
0.90
9.17
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
6.20
63.20
770.00
0.08
CI-Naphthalenes (a)
444.00
1.50
15.29
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
10.00
101.94
670.00
0.15
C2 Chrysenes (a)
1008.00
4.40
44.85
1008.00
0.04
C2 Fluorenes (a)
686.00
2.40
24.46
686.00
0.04
C2-Fluoranthenes/Pyrenes
5.50
56.07
C2-Naphthalenes (a)
510.00
14.00
142.71
510.00
0.28
C2-Phenanthrenes/Anthracenes (a)
746
11.00
112.13
746.00
0.15
C3 Chrysenes (a)
1112.00
1.80
18.35
1112.00
0.02
C3 Fluorenes (a)
769.00
4.90
49.95
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
3.80
38.74
949.00
0.04
C3-Naphthalenes(a)
581.00
21.00
214.07
581.00
0.37
C3-Phenanthrenes/Anthracenes (a)
829.00
11.00
112.13
829.00
0.14
C4 Chrysenes (a)
1214.00
0.89
9.07
1214.00
0.01
C4-Naphthalenes (a)
657.00
15.00
152.91
657.00
0.23
C4-Phenanthrenes/Anthracenes (a)
913.00
6.60
67.28
913.00
0.07
Chrysene ,a)
844.00
826
3.00
30.58
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.36
3.67
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.90
60.14
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.67
6.83
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
11.21
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.49
4.99
385.00
0.01
Perylene(a)
967.00
431.00
0.84
8.56
967.00
0.01
Phenanthrene 'd'
596
34300
4.60
46.89
596.00
0.08
Pyrene ,d'
697.00
9,090.00
5.40
55.05
697.00
0.08
ESBTU FCVi
1.22
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 69 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-48
Field Sample ID
RREC13-48-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
5.92
0.0592
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.24
4.05
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.42
7.09
447.00
0.02
Acenaphthene (a)
491.00
33400
0.31
5.24
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.23
3.89
452.00
0.01
Anthracene (a)
594.00
1300
0.90
15.20
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
3.50
59.12
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
3.60
60.81
965.00
0.06
Benzo(b)fluoranthene (a)
979.00
2169
3.00
50.68
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
2.20
37.16
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
2.20
37.16
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
3.00
50.68
981.00
0.05
CI Chrysenes (a)
929.00
2.10
35.47
929.00
0.04
CI Fluorenes(a)
611.00
0.17
2.87
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.70
62.50
770.00
0.08
CI-Naphthalenes (a)
444.00
0.47
7.94
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.40
40.54
670.00
0.06
C2 Chrysenes (a)
1008.00
1.40
23.65
1008.00
0.02
C2 Fluorenes (a)
686.00
0.30
5.07
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.00
33.78
C2-Naphthalenes (a)
510.00
1.60
27.03
510.00
0.05
C2-Phenanthrenes/Anthracenes (a)
746
1.70
28.72
746.00
0.04
C3 Chrysenes (a)
1112.00
0.64
10.81
1112.00
0.01
C3 Fluorenes (a)
769.00
0.64
10.81
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
1.10
18.58
949.00
0.02
C3-Naphthalenes(a)
581.00
2.20
37.16
581.00
0.06
C3-Phenanthrenes/Anthracenes (a)
829.00
1.60
27.03
829.00
0.03
C4 Chrysenes (a)
1214.00
0.25
4.22
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.50
25.34
657.00
0.04
C4-Phenanthrenes/Anthracenes (a)
913.00
1.30
21.96
913.00
0.02
Chrysene ,a)
844.00
826
3.40
57.43
844.00
0.07
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.65
10.98
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
4.80
81.08
707.00
0.11
Fluorene ,a)
538.00
26,000.00
0.38
6.42
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.00
33.78
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
0.78
13.18
385.00
0.03
Perylene(a)
967.00
431.00
0.93
15.71
967.00
0.02
Phenanthrene 'd'
596
34300
2.60
43.92
596.00
0.07
Pyrene ,d'
697.00
9,090.00
3.90
65.88
697.00
0.09
ESBTU FCVi
1.07
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 70 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-48
Field Sample ID
RREC13-48-SURF-FD
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.31
0.0631
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.18
2.85
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.32
5.07
447.00
0.01
Acenaphthene (a)
491.00
33400
0.27
4.28
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.17
2.69
452.00
0.01
Anthracene (a)
594.00
1300
0.62
9.83
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.40
38.03
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
2.80
44.37
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
2.20
34.87
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
1.70
26.94
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.90
30.11
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
2.10
33.28
981.00
0.03
CI Chrysenes (a)
929.00
1.60
25.36
929.00
0.03
CI Fluorenes(a)
611.00
0.13
2.06
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.60
41.20
770.00
0.05
CI-Naphthalenes (a)
444.00
0.35
5.55
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.80
28.53
670.00
0.04
C2 Chrysenes (a)
1008.00
1.00
15.85
1008.00
0.02
C2 Fluorenes (a)
686.00
0.26
4.12
686.00
0.01
C2-Fluoranthenes/Pyrenes
1.50
23.77
C2-Naphthalenes (a)
510.00
1.30
20.60
510.00
0.04
C2-Phenanthrenes/Anthracenes (a)
746
1.40
22.19
746.00
0.03
C3 Chrysenes (a)
1112.00
0.41
6.50
1112.00
0.01
C3 Fluorenes (a)
769.00
0.57
9.03
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.88
13.95
949.00
0.01
C3-Naphthalenes(a)
581.00
1.90
30.11
581.00
0.05
C3-Phenanthrenes/Anthracenes (a)
829.00
1.40
22.19
829.00
0.03
C4 Chrysenes (a)
1214.00
0.19
3.01
1214.00
0.00
C4-Naphthalenes (a)
657.00
1.40
22.19
657.00
0.03
C4-Phenanthrenes/Anthracenes (a)
913.00
1.10
17.43
913.00
0.02
Chrysene ,a)
844.00
826
2.40
38.03
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.46
7.29
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
3.20
50.71
707.00
0.07
Fluorene ,a)
538.00
26,000.00
0.27
4.28
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.60
25.36
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.31
4.91
385.00
0.01
Perylene(a)
967.00
431.00
0.70
11.09
967.00
0.01
Phenanthrene 'd'
596
34300
1.70
26.94
596.00
0.05
Pyrene ,d'
697.00
9,090.00
2.70
42.79
697.00
0.06
ESBTU FCVi
0.72
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 71 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-48
Field Sample ID
RREC13-48-0001
Sample Depth
0-1
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6
0.06
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.10
1.67
446.00
0.00
2-Methylnaphthalene
447.00
154800
0.19
3.17
447.00
0.01
Acenaphthene (a)
491.00
33400
0.17
2.83
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.10
1.67
452.00
0.00
Anthracene (a)
594.00
1300
0.54
9.00
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.00
33.33
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.00
33.33
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
1.80
30.00
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.30
21.67
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.30
21.67
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
1.60
26.67
981.00
0.03
CI Chrysenes (a)
929.00
1.30
21.67
929.00
0.02
CI Fluorenes(a)
611.00
0.08
1.32
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
2.10
35.00
770.00
0.05
CI-Naphthalenes (a)
444.00
0.21
3.50
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
1.10
18.33
670.00
0.03
C2 Chrysenes (a)
1008.00
0.80
13.33
1008.00
0.01
C2 Fluorenes (a)
686.00
0.13
2.17
686.00
0.00
C2-Fluoranthenes/Pyrenes
1.10
18.33
C2-Naphthalenes (a)
510.00
0.59
9.83
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
0.75
12.50
746.00
0.02
C3 Chrysenes (a)
1112.00
0.33
5.50
1112.00
0.00
C3 Fluorenes (a)
769.00
0.26
4.33
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
0.60
10.00
949.00
0.01
C3-Naphthalenes(a)
581.00
0.67
11.17
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
0.79
13.17
829.00
0.02
C4 Chrysenes (a)
1214.00
0.13
2.17
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.47
7.83
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.68
11.33
913.00
0.01
Chrysene ,a)
844.00
826
1.90
31.67
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.39
6.50
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
2.80
46.67
707.00
0.07
Fluorene ,a)
538.00
26,000.00
0.22
3.67
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
18.33
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.23
3.83
385.00
0.01
Perylene(a)
967.00
431.00
0.53
8.83
967.00
0.01
Phenanthrene 'd'
596
34300
1.50
25.00
596.00
0.04
Pyrene ,d'
697.00
9,090.00
2.40
40.00
697.00
0.06
ESBTU FCVi
0.58
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 72 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-48
Field Sample ID
RREC13-48-0103
Sample Depth
1-3
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.55
0.0755
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.63
8.34
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.10
14.57
447.00
0.03
Acenaphthene (a)
491.00
33400
0.31
4.11
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.17
2.25
452.00
0.00
Anthracene (a)
594.00
1300
0.61
8.08
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.30
30.46
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.40
31.79
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.50
33.11
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.80
23.84
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.91
12.05
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.60
34.44
981.00
0.04
CI Chrysenes (a)
929.00
1.60
21.19
929.00
0.02
CI Fluorenes(a)
611.00
0.36
4.77
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.10
41.06
770.00
0.05
CI-Naphthalenes (a)
444.00
1.20
15.89
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
3.70
49.01
670.00
0.07
C2 Chrysenes (a)
1008.00
2.50
33.11
1008.00
0.03
C2 Fluorenes (a)
686.00
0.99
13.11
686.00
0.02
C2-Fluoranthenes/Pyrenes
2.20
29.14
C2-Naphthalenes (a)
510.00
5.00
66.23
510.00
0.13
C2-Phenanthrenes/Anthracenes (a)
746
3.90
51.66
746.00
0.07
C3 Chrysenes (a)
1112.00
1.10
14.57
1112.00
0.01
C3 Fluorenes (a)
769.00
2.10
27.81
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
1.50
19.87
949.00
0.02
C3-Naphthalenes(a)
581.00
8.20
108.61
581.00
0.19
C3-Phenanthrenes/Anthracenes (a)
829.00
3.80
50.33
829.00
0.06
C4 Chrysenes (a)
1214.00
0.53
7.02
1214.00
0.01
C4-Naphthalenes (a)
657.00
5.40
71.52
657.00
0.11
C4-Phenanthrenes/Anthracenes (a)
913.00
2.90
38.41
913.00
0.04
Chrysene ,a)
844.00
826
2.40
31.79
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.24
3.18
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.40
58.28
707.00
0.08
Fluorene ,a)
538.00
26,000.00
0.40
5.30
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.85
11.26
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.26
3.38
385.00
0.01
Perylene(a)
967.00
431.00
0.69
9.14
967.00
0.01
Phenanthrene 'd'
596
34300
2.50
33.11
596.00
0.06
Pyrene ,d'
697.00
9,090.00
3.10
41.06
697.00
0.06
ESBTU FCVi
0.84
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 73 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-48
Field Sample ID
RREC13-48-0305
Sample Depth
3-5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.4
0.064
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.88
13.75
446.00
0.03
2-Methylnaphthalene
447.00
154800
1.50
23.44
447.00
0.05
Acenaphthene (a)
491.00
33400
0.70
10.94
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.22
3.44
452.00
0.01
Anthracene (a)
594.00
1300
0.97
15.16
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
2.70
42.19
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
2.40
37.50
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
2.20
34.38
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
1.70
26.56
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.10
17.19
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
2.20
34.38
981.00
0.04
CI Chrysenes (a)
929.00
2.10
32.81
929.00
0.04
CI Fluorenes(a)
611.00
0.66
10.31
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.80
59.38
770.00
0.08
CI-Naphthalenes (a)
444.00
1.60
25.00
444.00
0.06
Cl-Phenanthrenes/Anthracenes (a)
670.00
6.00
93.75
670.00
0.14
C2 Chrysenes (a)
1008.00
1.80
28.13
1008.00
0.03
C2 Fluorenes (a)
686.00
1.80
28.13
686.00
0.04
C2-Fluoranthenes/Pyrenes
3.00
46.88
C2-Naphthalenes (a)
510.00
10.00
156.25
510.00
0.31
C2-Phenanthrenes/Anthracenes (a)
746
6.40
100.00
746.00
0.13
C3 Chrysenes (a)
1112.00
1.10
17.19
1112.00
0.02
C3 Fluorenes (a)
769.00
3.70
57.81
769.00
0.08
C3-Fluoranthenes/Pyrenes
949.00
2.30
35.94
949.00
0.04
C3-Naphthalenes(a)
581.00
17.00
265.63
581.00
0.46
C3-Phenanthrenes/Anthracenes (a)
829.00
6.60
103.13
829.00
0.12
C4 Chrysenes (a)
1214.00
0.61
9.53
1214.00
0.01
C4-Naphthalenes (a)
657.00
10.00
156.25
657.00
0.24
C4-Phenanthrenes/Anthracenes (a)
913.00
4.70
73.44
913.00
0.08
Chrysene ,a)
844.00
826
2.90
45.31
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.29
4.53
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.70
89.06
707.00
0.13
Fluorene ,a)
538.00
26,000.00
0.96
15.00
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.00
15.63
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.40
6.25
385.00
0.02
Perylene(a)
967.00
431.00
0.75
11.72
967.00
0.01
Phenanthrene 'd'
596
34300
4.40
68.75
596.00
0.12
Pyrene ,d'
697.00
9,090.00
4.30
67.19
697.00
0.10
ESBTU FCVi
1.41
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 74 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-48
Field Sample ID
RREC13-48-0507
Sample Depth
5-7
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.92
0.0792
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.82
10.35
446.00
0.02
2-Methylnaphthalene
447.00
154800
1.30
16.41
447.00
0.04
Acenaphthene (a)
491.00
33400
0.42
5.30
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.22
2.78
452.00
0.01
Anthracene (a)
594.00
1300
0.78
9.85
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.40
30.30
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.40
30.30
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.60
32.83
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.70
21.46
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.84
10.61
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.30
29.04
981.00
0.03
CI Chrysenes (a)
929.00
2.00
25.25
929.00
0.03
CI Fluorenes(a)
611.00
0.91
11.49
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.10
51.77
770.00
0.07
CI-Naphthalenes (a)
444.00
1.50
18.94
444.00
0.04
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.90
112.37
670.00
0.17
C2 Chrysenes (a)
1008.00
3.20
40.40
1008.00
0.04
C2 Fluorenes (a)
686.00
2.50
31.57
686.00
0.05
C2-Fluoranthenes/Pyrenes
3.10
39.14
C2-Naphthalenes (a)
510.00
10.00
126.26
510.00
0.25
C2-Phenanthrenes/Anthracenes (a)
746
8.80
111.11
746.00
0.15
C3 Chrysenes (a)
1112.00
1.30
16.41
1112.00
0.01
C3 Fluorenes (a)
769.00
4.50
56.82
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
2.30
29.04
949.00
0.03
C3-Naphthalenes(a)
581.00
19.00
239.90
581.00
0.41
C3-Phenanthrenes/Anthracenes (a)
829.00
7.10
89.65
829.00
0.11
C4 Chrysenes (a)
1214.00
0.66
8.33
1214.00
0.01
C4-Naphthalenes (a)
657.00
13.00
164.14
657.00
0.25
C4-Phenanthrenes/Anthracenes (a)
913.00
4.80
60.61
913.00
0.07
Chrysene ,a)
844.00
826
2.50
31.57
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.22
2.78
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
5.20
65.66
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.60
7.58
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.78
9.85
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.31
3.85
385.00
0.01
Perylene(a)
967.00
431.00
0.69
8.71
967.00
0.01
Phenanthrene 'd'
596
34300
3.70
46.72
596.00
0.08
Pyrene ,d'
697.00
9,090.00
3.50
44.19
697.00
0.06
ESBTU FCVi
1.21
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 75 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-48
Field Sample ID
RREC13-48-0710
Sample Depth
7-10
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
16.9
0.169
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.62
3.67
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.98
5.80
447.00
0.01
Acenaphthene (a)
491.00
33400
0.42
2.49
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.18
1.07
452.00
0.00
Anthracene (a)
594.00
1300
0.69
4.08
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.00
11.83
841.00
0.01
Benzo(a)pyrene (a)
965.00
3840
2.00
11.83
965.00
0.01
Benzo(b)fluoranthene (a)
979.00
2169
1.90
11.24
979.00
0.01
Benzo(e)pyrene (a)
967.00
4300
1.30
7.69
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
0.72
4.26
1095.00
0.00
Benzo(k)fluoranthene (a)
981.00
1220
1.80
10.65
981.00
0.01
CI Chrysenes (a)
929.00
1.90
11.24
929.00
0.01
CI Fluorenes(a)
611.00
0.62
3.67
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.60
21.30
770.00
0.03
CI-Naphthalenes (a)
444.00
1.10
6.51
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
7.30
43.20
670.00
0.06
C2 Chrysenes (a)
1008.00
3.30
19.53
1008.00
0.02
C2 Fluorenes (a)
686.00
1.70
10.06
686.00
0.01
C2-Fluoranthenes/Pyrenes
3.00
17.75
C2-Naphthalenes (a)
510.00
7.10
42.01
510.00
0.08
C2-Phenanthrenes/Anthracenes (a)
746
7.40
43.79
746.00
0.06
C3 Chrysenes (a)
1112.00
1.30
7.69
1112.00
0.01
C3 Fluorenes (a)
769.00
3.20
18.93
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
2.30
13.61
949.00
0.01
C3-Naphthalenes(a)
581.00
14.00
82.84
581.00
0.14
C3-Phenanthrenes/Anthracenes (a)
829.00
5.90
34.91
829.00
0.04
C4 Chrysenes (a)
1214.00
0.66
3.91
1214.00
0.00
C4-Naphthalenes (a)
657.00
9.30
55.03
657.00
0.08
C4-Phenanthrenes/Anthracenes (a)
913.00
4.00
23.67
913.00
0.03
Chrysene ,a)
844.00
826
2.10
12.43
844.00
0.01
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.19
1.12
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.30
25.44
707.00
0.04
Fluorene ,a)
538.00
26,000.00
0.49
2.90
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.65
3.85
1115.00
0.00
Naphthalene ,a)
385.00
61,700.00
0.28
1.63
385.00
0.00
Perylene(a)
967.00
431.00
0.60
3.55
967.00
0.00
Phenanthrene 'd'
596
34300
3.30
19.53
596.00
0.03
Pyrene ,d'
697.00
9,090.00
2.90
17.16
697.00
0.02
ESBTU FCVi
0.46
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 76 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-49
Field Sample ID
RREC13-49-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
9.04
0.0904
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.22
2.43
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.40
4.42
447.00
0.01
Acenaphthene (a)
491.00
33400
0.32
3.54
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.27
2.99
452.00
0.01
Anthracene (a)
594.00
1300
1.10
12.17
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
4.60
50.88
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
4.70
51.99
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
4.40
48.67
979.00
0.05
Benzo(e)pyrene (a)
967.00
4300
3.00
33.19
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
3.10
34.29
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
3.70
40.93
981.00
0.04
CI Chrysenes (a)
929.00
2.70
29.87
929.00
0.03
CI Fluorenes(a)
611.00
0.14
1.55
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.80
53.10
770.00
0.07
CI-Naphthalenes (a)
444.00
0.43
4.76
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.30
25.44
670.00
0.04
C2 Chrysenes (a)
1008.00
1.50
16.59
1008.00
0.02
C2 Fluorenes (a)
686.00
0.21
2.32
686.00
0.00
C2-Fluoranthenes/Pyrenes
2.30
25.44
C2-Naphthalenes (a)
510.00
1.10
12.17
510.00
0.02
C2-Phenanthrenes/Anthracenes (a)
746
1.30
14.38
746.00
0.02
C3 Chrysenes (a)
1112.00
0.60
6.64
1112.00
0.01
C3 Fluorenes (a)
769.00
0.35
3.87
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
1.10
12.17
949.00
0.01
C3-Naphthalenes(a)
581.00
1.10
12.17
581.00
0.02
C3-Phenanthrenes/Anthracenes (a)
829.00
1.20
13.27
829.00
0.02
C4 Chrysenes (a)
1214.00
0.27
2.99
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.66
7.30
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.83
9.18
913.00
0.01
Chrysene ,a)
844.00
826
4.40
48.67
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.75
8.30
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
5.70
63.05
707.00
0.09
Fluorene ,a)
538.00
26,000.00
0.42
4.65
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
2.60
28.76
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
0.50
5.53
385.00
0.01
Perylene(a)
967.00
431.00
1.00
11.06
967.00
0.01
Phenanthrene 'd'
596
34300
3.10
34.29
596.00
0.06
Pyrene ,d'
697.00
9,090.00
5.30
58.63
697.00
0.08
ESBTU FCVi
0.83
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 77 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-49
Field Sample ID
RREC13-49-SURF-FD
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
6.91
0.0691
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.25
3.62
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.44
6.37
447.00
0.01
Acenaphthene (a)
491.00
33400
0.40
5.79
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.30
4.34
452.00
0.01
Anthracene (a)
594.00
1300
1.40
20.26
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
5.10
73.81
841.00
0.09
Benzo(a)pyrene (a)
965.00
3840
5.60
81.04
965.00
0.08
Benzo(b)fluoranthene (a)
979.00
2169
4.60
66.57
979.00
0.07
Benzo(e)pyrene (a)
967.00
4300
3.40
49.20
967.00
0.05
Benzo(g,h,i)perylene (a)
1095.00
648
3.50
50.65
1095.00
0.05
Benzo(k)fluoranthene (a)
981.00
1220
4.20
60.78
981.00
0.06
CI Chrysenes (a)
929.00
3.10
44.86
929.00
0.05
CI Fluorenes(a)
611.00
0.15
2.17
611.00
0.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.00
72.36
770.00
0.09
CI-Naphthalenes (a)
444.00
0.48
6.95
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
2.50
36.18
670.00
0.05
C2 Chrysenes (a)
1008.00
1.70
24.60
1008.00
0.02
C2 Fluorenes (a)
686.00
0.21
3.04
686.00
0.00
C2-Fluoranthenes/Pyrenes
2.60
37.63
C2-Naphthalenes (a)
510.00
1.20
17.37
510.00
0.03
C2-Phenanthrenes/Anthracenes (a)
746
1.50
21.71
746.00
0.03
C3 Chrysenes (a)
1112.00
0.62
8.97
1112.00
0.01
C3 Fluorenes (a)
769.00
0.40
5.79
769.00
0.01
C3-Fluoranthenes/Pyrenes
949.00
1.30
18.81
949.00
0.02
C3-Naphthalenes(a)
581.00
1.20
17.37
581.00
0.03
C3-Phenanthrenes/Anthracenes (a)
829.00
1.30
18.81
829.00
0.02
C4 Chrysenes (a)
1214.00
0.28
4.05
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.67
9.70
657.00
0.01
C4-Phenanthrenes/Anthracenes (a)
913.00
0.85
12.30
913.00
0.01
Chrysene ,a)
844.00
826
4.80
69.46
844.00
0.08
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.98
14.18
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
6.60
95.51
707.00
0.14
Fluorene ,a)
538.00
26,000.00
0.46
6.66
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
3.00
43.42
1115.00
0.04
Naphthalene ,a)
385.00
61,700.00
0.55
7.96
385.00
0.02
Perylene(a)
967.00
431.00
1.30
18.81
967.00
0.02
Phenanthrene 'd'
596
34300
3.40
49.20
596.00
0.08
Pyrene ,d'
697.00
9,090.00
5.60
81.04
697.00
0.12
ESBTU FCVi
1.20
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 78 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-49
Field Sample ID
RREC13-49-0001
Sample Depth
0-1
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
12.4
0.124
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.30
2.42
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.28
2.26
447.00
0.01
Acenaphthene (a)
491.00
33400
0.31
2.50
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.16
1.29
452.00
0.00
Anthracene (a)
594.00
1300
0.67
5.40
594.00
0.01
Benzo(a)anthracene (a)
841.00
4153
2.60
20.97
841.00
0.02
Benzo(a)pyrene (a)
965.00
3840
2.40
19.35
965.00
0.02
Benzo(b)fluoranthene (a)
979.00
2169
2.30
18.55
979.00
0.02
Benzo(e)pyrene (a)
967.00
4300
1.60
12.90
967.00
0.01
Benzo(g,h,i)perylene (a)
1095.00
648
1.30
10.48
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.00
16.13
981.00
0.02
CI Chrysenes (a)
929.00
1.80
14.52
929.00
0.02
CI Fluorenes(a)
611.00
0.39
3.15
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
3.40
27.42
770.00
0.04
CI-Naphthalenes (a)
444.00
0.40
3.23
444.00
0.01
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.10
33.06
670.00
0.05
C2 Chrysenes (a)
1008.00
1.50
12.10
1008.00
0.01
C2 Fluorenes (a)
686.00
1.00
8.06
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.20
17.74
C2-Naphthalenes (a)
510.00
3.50
28.23
510.00
0.06
C2-Phenanthrenes/Anthracenes (a)
746
3.90
31.45
746.00
0.04
C3 Chrysenes (a)
1112.00
0.64
5.16
1112.00
0.00
C3 Fluorenes (a)
769.00
2.20
17.74
769.00
0.02
C3-Fluoranthenes/Pyrenes
949.00
1.50
12.10
949.00
0.01
C3-Naphthalenes(a)
581.00
8.40
67.74
581.00
0.12
C3-Phenanthrenes/Anthracenes (a)
829.00
4.20
33.87
829.00
0.04
C4 Chrysenes (a)
1214.00
0.36
2.90
1214.00
0.00
C4-Naphthalenes (a)
657.00
5.90
47.58
657.00
0.07
C4-Phenanthrenes/Anthracenes (a)
913.00
3.00
24.19
913.00
0.03
Chrysene ,a)
844.00
826
2.70
21.77
844.00
0.03
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.29
2.34
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.20
33.87
707.00
0.05
Fluorene ,a)
538.00
26,000.00
0.48
3.87
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
8.87
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.28
2.26
385.00
0.01
Perylene(a)
967.00
431.00
0.68
5.48
967.00
0.01
Phenanthrene 'd'
596
34300
2.70
21.77
596.00
0.04
Pyrene ,d'
697.00
9,090.00
3.70
29.84
697.00
0.04
ESBTU FCVi
0.54
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 79 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-49
Field Sample ID
RREC13-49-0103
Sample Depth
1-3
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.47
0.0747
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.85
11.38
446.00
0.03
2-Methylnaphthalene
447.00
154800
1.30
17.40
447.00
0.04
Acenaphthene (a)
491.00
33400
0.57
7.63
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.29
3.88
452.00
0.01
Anthracene (a)
594.00
1300
1.00
13.39
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
3.40
45.52
841.00
0.05
Benzo(a)pyrene (a)
965.00
3840
3.30
44.18
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
3.20
42.84
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.20
29.45
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.10
14.73
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
3.30
44.18
981.00
0.05
CI Chrysenes (a)
929.00
2.70
36.14
929.00
0.04
CI Fluorenes(a)
611.00
0.77
10.31
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.70
76.31
770.00
0.10
CI-Naphthalenes (a)
444.00
1.50
20.08
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
8.20
109.77
670.00
0.16
C2 Chrysenes (a)
1008.00
4.00
53.55
1008.00
0.05
C2 Fluorenes (a)
686.00
2.00
26.77
686.00
0.04
C2-Fluoranthenes/Pyrenes
4.00
53.55
C2-Naphthalenes (a)
510.00
8.90
119.14
510.00
0.23
C2-Phenanthrenes/Anthracenes (a)
746
8.70
116.47
746.00
0.16
C3 Chrysenes (a)
1112.00
1.60
21.42
1112.00
0.02
C3 Fluorenes (a)
769.00
3.80
50.87
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
2.80
37.48
949.00
0.04
C3-Naphthalenes(a)
581.00
17.00
227.58
581.00
0.39
C3-Phenanthrenes/Anthracenes (a)
829.00
8.00
107.10
829.00
0.13
C4 Chrysenes (a)
1214.00
0.80
10.71
1214.00
0.01
C4-Naphthalenes (a)
657.00
11.00
147.26
657.00
0.22
C4-Phenanthrenes/Anthracenes (a)
913.00
5.00
66.93
913.00
0.07
Chrysene ,a)
844.00
826
3.60
48.19
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.30
4.02
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
6.70
89.69
707.00
0.13
Fluorene ,a)
538.00
26,000.00
0.80
10.71
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.00
13.39
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.42
5.56
385.00
0.01
Perylene(a)
967.00
431.00
0.93
12.45
967.00
0.01
Phenanthrene 'd'
596
34300
4.60
61.58
596.00
0.10
Pyrene ,d'
697.00
9,090.00
5.10
68.27
697.00
0.10
ESBTU FCVi
1.47
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 80 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-49
Field Sample ID
RREC13-49-0305
Sample Depth
3-5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.44
0.0744
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.86
11.56
446.00
0.03
2-Methylnaphthalene
447.00
154800
1.40
18.82
447.00
0.04
Acenaphthene (a)
491.00
33400
0.65
8.74
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.28
3.76
452.00
0.01
Anthracene (a)
594.00
1300
1.00
13.44
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
3.60
48.39
841.00
0.06
Benzo(a)pyrene (a)
965.00
3840
3.40
45.70
965.00
0.05
Benzo(b)fluoranthene (a)
979.00
2169
3.20
43.01
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
2.40
32.26
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
1.20
16.13
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
3.10
41.67
981.00
0.04
CI Chrysenes (a)
929.00
3.10
41.67
929.00
0.04
CI Fluorenes(a)
611.00
0.82
11.02
611.00
0.02
Cl-Fluoranthenes/Pyrenes (a)
770.00
5.80
77.96
770.00
0.10
CI-Naphthalenes (a)
444.00
1.50
20.16
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
10.00
134.41
670.00
0.20
C2 Chrysenes (a)
1008.00
4.30
57.80
1008.00
0.06
C2 Fluorenes (a)
686.00
2.20
29.57
686.00
0.04
C2-Fluoranthenes/Pyrenes
4.50
60.48
C2-Naphthalenes (a)
510.00
9.50
127.69
510.00
0.25
C2-Phenanthrenes/Anthracenes (a)
746
9.80
131.72
746.00
0.18
C3 Chrysenes (a)
1112.00
1.80
24.19
1112.00
0.02
C3 Fluorenes (a)
769.00
4.00
53.76
769.00
0.07
C3-Fluoranthenes/Pyrenes
949.00
3.10
41.67
949.00
0.04
C3-Naphthalenes(a)
581.00
19.00
255.38
581.00
0.44
C3-Phenanthrenes/Anthracenes (a)
829.00
8.60
115.59
829.00
0.14
C4 Chrysenes (a)
1214.00
0.91
12.23
1214.00
0.01
C4-Naphthalenes (a)
657.00
12.00
161.29
657.00
0.25
C4-Phenanthrenes/Anthracenes (a)
913.00
5.00
67.20
913.00
0.07
Chrysene ,a)
844.00
826
3.70
49.73
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.32
4.30
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
6.80
91.40
707.00
0.13
Fluorene ,a)
538.00
26,000.00
0.80
10.75
538.00
0.02
Indeno(l,2,3-cd)pyrene ,a)
1115.00
1.10
14.78
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.98
13.17
385.00
0.03
Perylene(a)
967.00
431.00
0.99
13.31
967.00
0.01
Phenanthrene 'd'
596
34300
5.40
72.58
596.00
0.12
Pyrene ,d'
697.00
9,090.00
5.30
71.24
697.00
0.10
ESBTU FCVi
1.61
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 81 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-49
Field Sample ID
RREC13-49-0507
Sample Depth
5-7
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
8.12
0.0812
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.34
4.19
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.56
6.90
447.00
0.02
Acenaphthene (a)
491.00
33400
0.36
4.43
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.15
1.85
452.00
0.00
Anthracene (a)
594.00
1300
0.86
10.59
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.60
32.02
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.50
30.79
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.70
33.25
979.00
0.03
Benzo(e)pyrene (a)
967.00
4300
1.70
20.94
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
1.00
12.32
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.20
27.09
981.00
0.03
CI Chrysenes (a)
929.00
1.90
23.40
929.00
0.03
CI Fluorenes(a)
611.00
0.31
3.82
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.40
54.19
770.00
0.07
CI-Naphthalenes (a)
444.00
0.62
7.64
444.00
0.02
Cl-Phenanthrenes/Anthracenes (a)
670.00
4.20
51.72
670.00
0.08
C2 Chrysenes (a)
1008.00
2.50
30.79
1008.00
0.03
C2 Fluorenes (a)
686.00
0.79
9.73
686.00
0.01
C2-Fluoranthenes/Pyrenes
2.80
34.48
C2-Naphthalenes (a)
510.00
2.40
29.56
510.00
0.06
C2-Phenanthrenes/Anthracenes (a)
746
4.60
56.65
746.00
0.08
C3 Chrysenes (a)
1112.00
0.93
11.45
1112.00
0.01
C3 Fluorenes (a)
769.00
1.80
22.17
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
1.70
20.94
949.00
0.02
C3-Naphthalenes(a)
581.00
5.30
65.27
581.00
0.11
C3-Phenanthrenes/Anthracenes (a)
829.00
4.80
59.11
829.00
0.07
C4 Chrysenes (a)
1214.00
0.47
5.79
1214.00
0.00
C4-Naphthalenes (a)
657.00
3.90
48.03
657.00
0.07
C4-Phenanthrenes/Anthracenes (a)
913.00
3.30
40.64
913.00
0.04
Chrysene ,a)
844.00
826
2.70
33.25
844.00
0.04
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.30
3.69
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
4.80
59.11
707.00
0.08
Fluorene ,a)
538.00
26,000.00
0.49
6.03
538.00
0.01
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.89
10.96
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
0.62
7.64
385.00
0.02
Perylene(a)
967.00
431.00
0.68
8.37
967.00
0.01
Phenanthrene 'd'
596
34300
2.90
35.71
596.00
0.06
Pyrene ,d'
697.00
9,090.00
3.90
48.03
697.00
0.07
ESBTU FCVi
0.89
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 82 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-49
Field Sample ID
RREC13-49-0710
Sample Depth
7-10
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
7.75
0.0775
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.46
5.94
446.00
0.01
2-Methylnaphthalene
447.00
154800
0.43
5.48
447.00
0.01
Acenaphthene (a)
491.00
33400
0.55
7.10
491.00
0.01
Acenaphthylene (a)
452.00
24000
0.23
2.97
452.00
0.01
Anthracene (a)
594.00
1300
0.96
12.39
594.00
0.02
Benzo(a)anthracene (a)
841.00
4153
2.90
37.42
841.00
0.04
Benzo(a)pyrene (a)
965.00
3840
2.60
33.55
965.00
0.03
Benzo(b)fluoranthene (a)
979.00
2169
2.70
34.84
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
1.80
23.23
967.00
0.02
Benzo(g,h,i)perylene (a)
1095.00
648
0.87
11.23
1095.00
0.01
Benzo(k)fluoranthene (a)
981.00
1220
2.70
34.84
981.00
0.04
CI Chrysenes (a)
929.00
1.90
24.52
929.00
0.03
CI Fluorenes(a)
611.00
0.48
6.19
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
4.00
51.61
770.00
0.07
CI-Naphthalenes (a)
444.00
0.88
11.35
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
5.20
67.10
670.00
0.10
C2 Chrysenes (a)
1008.00
2.70
34.84
1008.00
0.03
C2 Fluorenes (a)
686.00
1.10
14.19
686.00
0.02
C2-Fluoranthenes/Pyrenes
2.80
36.13
C2-Naphthalenes (a)
510.00
3.50
45.16
510.00
0.09
C2-Phenanthrenes/Anthracenes (a)
746
5.90
76.13
746.00
0.10
C3 Chrysenes (a)
1112.00
1.10
14.19
1112.00
0.01
C3 Fluorenes (a)
769.00
2.30
29.68
769.00
0.04
C3-Fluoranthenes/Pyrenes
949.00
1.90
24.52
949.00
0.03
C3-Naphthalenes(a)
581.00
8.10
104.52
581.00
0.18
C3-Phenanthrenes/Anthracenes (a)
829.00
6.10
78.71
829.00
0.09
C4 Chrysenes (a)
1214.00
0.51
6.58
1214.00
0.01
C4-Naphthalenes (a)
657.00
5.90
76.13
657.00
0.12
C4-Phenanthrenes/Anthracenes (a)
913.00
4.00
51.61
913.00
0.06
Chrysene ,a)
844.00
826
3.00
38.71
844.00
0.05
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.24
3.10
1123.00
0.00
Fluoranthene ,a)
707.00
23,870.00
6.60
85.16
707.00
0.12
Fluorene ,a)
538.00
26,000.00
1.10
14.19
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.83
10.71
1115.00
0.01
Naphthalene ,a)
385.00
61,700.00
2.60
33.55
385.00
0.09
Perylene(a)
967.00
431.00
0.75
9.68
967.00
0.01
Phenanthrene 'd'
596
34300
4.20
54.19
596.00
0.09
Pyrene ,d'
697.00
9,090.00
4.30
55.48
697.00
0.08
ESBTU FCVi
1.19
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 83 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-50
Field Sample ID
RREC13-50-SURF
Sample Depth
0-0.5
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
1.51
0.0151
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.12
7.95
446.00
0.02
2-Methylnaphthalene
447.00
154800
0.11
7.28
447.00
0.02
Acenaphthene (a)
491.00
33400
0.16
10.60
491.00
0.02
Acenaphthylene (a)
452.00
24000
0.09
6.09
452.00
0.01
Anthracene (a)
594.00
1300
0.30
19.87
594.00
0.03
Benzo(a)anthracene (a)
841.00
4153
1.10
72.85
841.00
0.09
Benzo(a)pyrene (a)
965.00
3840
0.62
41.06
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
0.98
64.90
979.00
0.07
Benzo(e)pyrene (a)
967.00
4300
0.62
41.06
967.00
0.04
Benzo(g,h,i)perylene (a)
1095.00
648
0.56
37.09
1095.00
0.03
Benzo(k)fluoranthene (a)
981.00
1220
0.85
56.29
981.00
0.06
CI Chrysenes (a)
929.00
0.50
33.11
929.00
0.04
CI Fluorenes(a)
611.00
0.05
3.44
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
1.10
72.85
770.00
0.09
CI-Naphthalenes (a)
444.00
0.22
14.57
444.00
0.03
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.65
43.05
670.00
0.06
C2 Chrysenes (a)
1008.00
0.30
19.87
1008.00
0.02
C2 Fluorenes (a)
686.00
0.06
3.64
686.00
0.01
C2-Fluoranthenes/Pyrenes
0.46
30.46
C2-Naphthalenes (a)
510.00
0.53
35.10
510.00
0.07
C2-Phenanthrenes/Anthracenes (a)
746
0.33
21.85
746.00
0.03
C3 Chrysenes (a)
1112.00
0.08
5.43
1112.00
0.00
C3 Fluorenes (a)
769.00
0.06
3.77
769.00
0.00
C3-Fluoranthenes/Pyrenes
949.00
0.21
13.91
949.00
0.01
C3-Naphthalenes(a)
581.00
0.46
30.46
581.00
0.05
C3-Phenanthrenes/Anthracenes (a)
829.00
0.27
17.88
829.00
0.02
C4 Chrysenes (a)
1214.00
0.04
2.58
1214.00
0.00
C4-Naphthalenes (a)
657.00
0.24
15.89
657.00
0.02
C4-Phenanthrenes/Anthracenes (a)
913.00
0.12
7.95
913.00
0.01
Chrysene ,a)
844.00
826
1.10
72.85
844.00
0.09
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.18
11.92
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
1.80
119.21
707.00
0.17
Fluorene ,a)
538.00
26,000.00
0.23
15.23
538.00
0.03
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.54
35.76
1115.00
0.03
Naphthalene ,a)
385.00
61,700.00
0.32
21.19
385.00
0.06
Perylene(a)
967.00
431.00
0.23
15.23
967.00
0.02
Phenanthrene 'd'
596
34300
1.30
86.09
596.00
0.14
Pyrene ,d'
697.00
9,090.00
1.30
86.09
697.00
0.12
ESBTU FCVi
1.30
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 84 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-50
Field Sample ID
RREC13-50-0001
Sample Depth
0-1
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Cone
Hg/g oc
Hg/g oc
Hg/g Dry wt
Hg/g oc
Cocb
ESBTU FCVi
ng/g Dry
wt
Total Organic Carbon**
8.38
0.0838
8.05
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
2.00
23.87
446.00
0.05
2.70
2-Methylnaphthalene
447.00
154800
2.70
32.22
447.00
0.07
5.20
Acenaphthene (a)
491.00
33400
3.90
46.54
491.00
0.09
5.20
Acenaphthylene (a)
452.00
24000
1.50
17.90
452.00
0.04
2.10
Anthracene (a)
594.00
1300
13.00
155.13
594.00
0.26
9.90
Benzo(a)anthracene (a)
841.00
4153
24.00
286.40
841.00
0.34
18.00
Benzo(a)pyrene (a)
965.00
3840
16.00
190.93
965.00
0.20
12.00
Benzo(b)fluoranthene (a)
979.00
2169
14.00
167.06
979.00
0.17
10.00
Benzo(e)pyrene (a)
967.00
4300
10.00
119.33
967.00
0.12
8.10
Benzo(g,h,i)perylene (a)
1095.00
648
7.50
89.50
1095.00
0.08
6.50
Benzo(k)fluoranthene (a)
981.00
1220
17.00
202.86
981.00
0.21
13.00
CI Chrysenes (a)
929.00
12.00
143.20
929.00
0.15
11.00
CI Fluorenes(a)
611.00
1.80
21.48
611.00
0.04
1.50
Cl-Fluoranthenes/Pyrenes (a)
770.00
26.00
310.26
770.00
0.40
23.00
CI-Naphthalenes (a)
444.00
3.40
40.57
444.00
0.09
5.40
Cl-Phenanthrenes/Anthracenes (a)
670.00
20.00
238.66
670.00
0.36
19.00
C2 Chrysenes (a)
1008.00
7.40
88.31
1008.00
0.09
8.20
C2 Fluorenes (a)
686.00
1.50
17.90
686.00
0.03
1.70
C2-Fluoranthenes/Pyrenes
11.00
131.26
12.00
C2-Naphthalenes (a)
510.00
7.50
89.50
510.00
0.18
12.00
C2-Phenanthrenes/Anthracenes (a)
746
13.00
155.13
746.00
0.21
13.00
C3 Chrysenes (a)
1112.00
3.10
36.99
1112.00
0.03
3.30
C3 Fluorenes (a)
769.00
3.30
39.38
769.00
0.05
4.00
C3-Fluoranthenes/Pyrenes
949.00
5.90
70.41
949.00
0.07
6.50
C3-Naphthalenes(a)
581.00
7.80
93.08
581.00
0.16
9.80
C3-Phenanthrenes/Anthracenes (a)
829.00
13.00
155.13
829.00
0.19
15.00
C4 Chrysenes (a)
1214.00
1.20
14.32
1214.00
0.01
1.80
C4-Naphthalenes (a)
657.00
6.20
73.99
657.00
0.11
6.20
C4-Phenanthrenes/Anthracenes (a)
913.00
8.40
100.24
913.00
0.11
10.00
Chrysene ,a)
844.00
826
21.00
250.60
844.00
0.30
17.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
2.60
31.03
1123.00
0.03
2.20
Fluoranthene ,a)
707.00
23,870.00
47.00
560.86
707.00
0.79
32.00
Fluorene ,a)
538.00
26,000.00
8.20
97.85
538.00
0.18
9.80
Indeno(l,2,3-cd)pyrene ,a)
1115.00
7.60
90.69
1115.00
0.08
6.10
Naphthalene ,a)
385.00
61,700.00
14.00
167.06
385.00
0.43
12.00
Perylene(a)
967.00
431.00
2.70
32.22
967.00
0.03
1.90
Phenanthrene 'd'
596
34300
41.00
489.26
596.00
0.82
32.00
Pyrene ,d'
697.00
9,090.00
29.00
346.06
697.00
0.50
23.00
ESBTU FCVi
6.06
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 85 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-50
RREC 13-50
Field Sample ID
RREC13-50-0103
RREC13-50-031
Sample Depth
1-3
3-5
Sample Date
10/30/13
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Coc
Final
Cone
Coc
Hg/g oc
Hg/g oc
Hg/g oc
Cocb
ESBTU FCVi
ng/g Dry
wt
Hg/g oc
Cocb
Total Organic Carbon**
0.0805
6.35
0.0635
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
33.54
446.00
0.08
1.20
18.90
446.00
2-Methylnaphthalene
447.00
154800
64.60
447.00
0.14
1.20
18.90
447.00
Acenaphthene (a)
491.00
33400
64.60
491.00
0.13
2.30
36.22
491.00
Acenaphthylene (a)
452.00
24000
26.09
452.00
0.06
0.90
14.17
452.00
Anthracene (a)
594.00
1300
122.98
594.00
0.21
5.90
92.91
594.00
Benzo(a)anthracene (a)
841.00
4153
223.60
841.00
0.27
12.00
188.98
841.00
Benzo(a)pyrene (a)
965.00
3840
149.07
965.00
0.15
8.60
135.43
965.00
Benzo(b)fluoranthene (a)
979.00
2169
124.22
979.00
0.13
8.70
137.01
979.00
Benzo(e)pyrene (a)
967.00
4300
100.62
967.00
0.10
5.60
88.19
967.00
Benzo(g,h,i)perylene (a)
1095.00
648
80.75
1095.00
0.07
4.60
72.44
1095.00
Benzo(k)fluoranthene (a)
981.00
1220
161.49
981.00
0.16
7.30
114.96
981.00
CI Chrysenes (a)
929.00
136.65
929.00
0.15
6.90
108.66
929.00
CI Fluorenes(a)
611.00
18.63
611.00
0.03
0.72
11.34
611.00
Cl-Fluoranthenes/Pyrenes (a)
770.00
285.71
770.00
0.37
14.00
220.47
770.00
CI-Naphthalenes (a)
444.00
67.08
444.00
0.15
2.20
34.65
444.00
Cl-Phenanthrenes/Anthracenes (a)
670.00
236.02
670.00
0.35
10.00
157.48
670.00
C2 Chrysenes (a)
1008.00
101.86
1008.00
0.10
4.60
72.44
1008.00
C2 Fluorenes (a)
686.00
21.12
686.00
0.03
0.90
14.17
686.00
C2-Fluoranthenes/Pyrenes
149.07
6.70
105.51
C2-Naphthalenes (a)
510.00
149.07
510.00
0.29
4.30
67.72
510.00
C2-Phenanthrenes/Anthracenes (a)
746
161.49
746.00
0.22
7.30
114.96
746.00
C3 Chrysenes (a)
1112.00
40.99
1112.00
0.04
1.80
28.35
1112.00
C3 Fluorenes (a)
769.00
49.69
769.00
0.06
2.00
31.50
769.00
C3-Fluoranthenes/Pyrenes
949.00
80.75
949.00
0.09
3.70
58.27
949.00
C3-Naphthalenes(a)
581.00
121.74
581.00
0.21
4.50
70.87
581.00
C3-Phenanthrenes/Anthracenes (a)
829.00
186.34
829.00
0.22
7.40
116.54
829.00
C4 Chrysenes (a)
1214.00
22.36
1214.00
0.02
0.80
12.60
1214.00
C4-Naphthalenes (a)
657.00
77.02
657.00
0.12
3.20
50.39
657.00
C4-Phenanthrenes/Anthracenes (a)
913.00
124.22
913.00
0.14
4.80
75.59
913.00
Chrysene ,a)
844.00
826
211.18
844.00
0.25
11.00
173.23
844.00
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
27.33
1123.00
0.02
1.50
23.62
1123.00
Fluoranthene ,a)
707.00
23,870.00
397.52
707.00
0.56
21.00
330.71
707.00
Fluorene ,a)
538.00
26,000.00
121.74
538.00
0.23
3.90
61.42
538.00
Indeno(l,2,3-cd)pyrene ,a)
1115.00
75.78
1115.00
0.07
4.20
66.14
1115.00
Naphthalene ,a)
385.00
61,700.00
149.07
385.00
0.39
6.70
105.51
385.00
Perylene(a)
967.00
431.00
23.60
967.00
0.02
1.20
18.90
967.00
Phenanthrene 'd'
596
34300
397.52
596.00
0.67
17.00
267.72
596.00
Pyrene ,d'
697.00
9,090.00
285.71
697.00
0.41
14.00
220.47
697.00
ESBTU FCVi
5.33
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 86 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-1 EQUILIBRIUM SEDIMENT BENCHMARK TOXIC UNITS FOR POLYCYCLIC AROMATIC HYDROCARBONS
RIVER ROUGE/ECORSE SHORELINE AREA, DETROIT RIVER AREA OF CONCERN, ECORSE, MICHIGAN (NOVEMBER 2013)
Location ID
RREC13-50
Field Sample ID
5
RREC13-50-0507
Sample Depth
5-7
Sample Date
10/30/13
Coc, PAHi, FCVia
Coc, PAHi, Maxi8
Cone
Coc
Final
Hg/g oc
Hg/g oc
ESBTU FCVi
ng/g
Dry wt
Hg/g oc
Cocb
ESBTU FCVi
Total Organic Carbon**
10.4
0.104
Enriched Pohcvclic Aromatic Hydrocarbons (EPAH) (ng/kg)
1 - Methylnaphthalene
446.00
165700
0.04
1.20
11.54
446.00
0.03
2-Methylnaphthalene
447.00
154800
0.04
1.90
18.27
447.00
0.04
Acenaphthene (a)
491.00
33400
0.07
1.30
12.50
491.00
0.03
Acenaphthylene (a)
452.00
24000
0.03
0.59
5.67
452.00
0.01
Anthracene (a)
594.00
1300
0.16
3.00
28.85
594.00
0.05
Benzo(a)anthracene (a)
841.00
4153
0.22
5.90
56.73
841.00
0.07
Benzo(a)pyrene (a)
965.00
3840
0.14
3.70
35.58
965.00
0.04
Benzo(b)fluoranthene (a)
979.00
2169
0.14
3.70
35.58
979.00
0.04
Benzo(e)pyrene (a)
967.00
4300
0.09
2.70
25.96
967.00
0.03
Benzo(g,h,i)perylene (a)
1095.00
648
0.07
2.20
21.15
1095.00
0.02
Benzo(k)fluoranthene (a)
981.00
1220
0.12
3.30
31.73
981.00
0.03
CI Chrysenes (a)
929.00
0.12
4.80
46.15
929.00
0.05
CI Fluorenes(a)
611.00
0.02
0.61
5.87
611.00
0.01
Cl-Fluoranthenes/Pyrenes (a)
770.00
0.29
8.80
84.62
770.00
0.11
CI-Naphthalenes (a)
444.00
0.08
2.10
20.19
444.00
0.05
Cl-Phenanthrenes/Anthracenes (a)
670.00
0.24
9.90
95.19
670.00
0.14
C2 Chrysenes (a)
1008.00
0.07
4.50
43.27
1008.00
0.04
C2 Fluorenes (a)
686.00
0.02
1.10
10.58
686.00
0.02
C2-Fluoranthenes/Pyrenes
5.80
55.77
C2-Naphthalenes (a)
510.00
0.13
5.50
52.88
510.00
0.10
C2-Phenanthrenes/Anthracenes (a)
746
0.15
8.10
77.88
746.00
0.10
C3 Chrysenes (a)
1112.00
0.03
2.30
22.12
1112.00
0.02
C3 Fluorenes (a)
769.00
0.04
2.50
24.04
769.00
0.03
C3-Fluoranthenes/Pyrenes
949.00
0.06
4.40
42.31
949.00
0.04
C3-Naphthalenes(a)
581.00
0.12
6.40
61.54
581.00
0.11
C3-Phenanthrenes/Anthracenes (a)
829.00
0.14
8.60
82.69
829.00
0.10
C4 Chrysenes (a)
1214.00
0.01
1.20
11.54
1214.00
0.01
C4-Naphthalenes (a)
657.00
0.08
4.20
40.38
657.00
0.06
C4-Phenanthrenes/Anthracenes (a)
913.00
0.08
6.40
61.54
913.00
0.07
Chrysene ,a)
844.00
826
0.21
5.40
51.92
844.00
0.06
Dibenzo(a,h)anthracene ,a)
1123.00
2,389.00
0.02
0.67
6.44
1123.00
0.01
Fluoranthene ,a)
707.00
23,870.00
0.47
12.00
115.38
707.00
0.16
Fluorene ,a)
538.00
26,000.00
0.11
2.50
24.04
538.00
0.04
Indeno(l,2,3-cd)pyrene ,a)
1115.00
0.06
1.90
18.27
1115.00
0.02
Naphthalene ,a)
385.00
61,700.00
0.27
6.30
60.58
385.00
0.16
Perylene(a)
967.00
431.00
0.02
0.60
5.77
967.00
0.01
Phenanthrene 'd'
596
34300
0.45
9.90
95.19
596.00
0.16
Pyrene ,d'
697.00
9,090.00
0.32
8.30
79.81
697.00
0.11
ESBTU FCVi
3.95
1.61
aPAHs and corresponding Coc PAH, FCVi and Coc PAH, Maxi values are from Table 3-4 in EPA, 2003).
b COC J*AHi,Maxi is the maximum solubility limited PAH concentration in sediment on an organic carbon basis;
only the contribution up to the maximum COC J*AHi,Maxi is counted in the D ESBTUFCV for the PAH mixture
(EPA, 2003, Section 4.3 and Section 6.3).
"Used TOC from 10/2008 sample event for 5/2009 sample event. U-coded data was omitted fromESB calculations..
ESBTU= equilibrium sediment benchmark toxic unit.
FCV= final chronic value.
Koc = organic carbon-water partition coefficient.
|ig/kg - micrograms per kilogram.
Celeron Island Area
Detroit River Area of Concern, Grosse lie, Michigan
Page 87 of 87
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-2 ORGANIC CARBON NORMALIZED METALS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-01
RREC13-02
RREC13-03
RREC13-05
RREC13-06
RREC13-07
RREC13-09
RREC13-11
RREC13-13
Sample Name:
RREC13-01-SURF
RREC13-02-SURF
RREC13-03-SURF
RREC13-05-SURF
RREC13-06-SURF
RREC13-07-SURF
RREC13-09-SURF
RREC13-11-SURF
RREC13-13-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/30/13
10/30/13
11/5/13
11/5/13
11/5/13
11/5/13
11/4/13
11/4/13
11/4/13
Analyte
Units
E SEM
umol/2 drv
9.289
3.1062
10.768
3.1392
3.221
2.1853
5.1655
26.914
34.746
AVS
umol/2 drv
6.9
1.1
3.5
1.6
5.4
1.5
1.2
0.67 U
1.9
foe
fraction
0.0987
0.0904
0.116
0.0701
0.0553
0.0434
0.0353
0.0205
0.0344
(E SEM - AVS) / foe
umol/s drv
24
22
63
22
-39
16
112
955
Sample Location:
RREC13-18
RREC13-19
RREC13-20
RREC13-21
RREC13-22
RREC13-23
RREC13-24
RREC13-25
RREC13-26
Sample Name:
RREC13-18-SURF
RREC13-19-SURF
RREC13-20-SURF
RREC13-21-SURF
RREC13-22-SURF
RREC13-23-SURF
RREC13-24-SURF
RREC13-25-SURF
RREC13-26-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/29/13
10/29/13
10/29/13
10/29/13
10/29/13
10/30/13
11/4/13
11/4/13
11/04/13
Analyte
Units
E SEM
umol/2 drv
4.513
2.6171
1.5551
6.564
5.299
8.201
6.3578
5.2051
6.924
AVS
umol/p drv
8.5
14.9
2.4
23.8
4.3
11.8
7.1
0.8
2.9
foe
fraction
0.0573
0.0444
0.0513
0.0691
0.0589
0.074
0.0259
0.0309
0.0609
(E SEM - AVS) / foe
umol/p drv
-70
-277
-16
-249
17
-49
-29
143
66
NOTES:
Bolded values exceed 130 fjmol/g
J = Indicates that the concentration is an estimated value.
U = Indicates the analyte was analyzed for but not detected.
SEM/AVS not calculated because AVS was not detected
AVS = Acid Volatile Sulfides
SEM = Simultaneously Extracted Metals
foe = fraction organic carbon
jjmol/g dry = micromole per gram dry weight
River Rouge/Ecorse Shoreline Assessment of Contaminated Sediments
Detroit River Area of Concern, Wayne County, Michigan Page 1 of 3 Site Characterization Report
-------
TABLE 4-2 ORGANIC CARBON NORMALIZED METALS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-14
RREC13-14
RREC13-15
RREC13-16
RREC13-17
RREC13-32
RREC13-33
RREC13-34
RREC13-35
Sample Name:
RREC13-14-SURF
RREC13-14- SURF-FD
RREC13-15-SURF
RREC13-16-SURF
RREC13-17-SURF
RREC13-32-SURF
RREC13-33-SURF
RREC13-34-SURF
RREC13-35-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
11/4/13
11/4/13
11/4/13
10/29/13
10/29/13
10/30/13
10/30/13
10/30/13
10/30/13
Analyte
Units
E SEM
umol/2 drv
16.135
20.845
22.974
6.752
4.273
4.0179
6.99
23.82
7.577
AVS
umol/2 drv
4.2
3
8.3
14.7
11.4
31.7
16
18.8
24.2
foe
fraction
0.0991
0.0879
0.0879
0.0665
0.0623
0.0595
0.0783
0.0574
0.0503
(E SEM - AVS) / foe
umol/s drv
120
203
167
-120
-114
-465
-115
87
-330
Sample Location:
RREC13-27
RREC13-28
RREC13-29
RREC13-30
RREC13-31
RREC13-42
RREC13-44
RREC13-45
RREC13-46
Sample Name:
RREC13-27-SURF
RREC13-28-SURF
RREC13-29-SURF
RREC13-30-SURF
RREC13-31-SURF
RREC13-42-SURF
RREC13-44-SURF
RREC13-45-SURF
RREC13-46-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
11/04/13
11/1/13
11/1/13
11/1/13
10/30/13
11/04/13
10/30/13
10/29/13
11/5/13
Analyte
Units
E SEM
umol/2 drv
11.932
5.702
6.598
9.665
2.5657
2.5841
6.512
4.174
1.1565
AVS
umol/p drv
3
5.1
4.3
4.1
14.8
0.85
5.6
4.3
4.4
foe
fraction
0.0476
0.0874
0.106
0.0706
0.0619
0.0329
0.0698
0.07
0.0822
(E SEM - AVS) / foe
umol/p drv
188
7
22
79
-198
53
13
-2
-39
NOTES:
Bolded values exceed 130 fjmol/g
J = Indicates that the concentration is an estimated value.
U = Indicates the analyte was analyzed for but not detecti
SEM/AVS not calculated because AVS was not dete
AVS = Acid Volatile Sulfides
SEM = Simultaneously Extracted Metals
foe = fraction organic carbon
jjmol/g dry = micromole per gram dry weight
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 2 of 3
Assessment of Contaminated Sediments
Site Characterization Report
-------
TABLE 4-2 ORGANIC CARBON NORMALIZED METALS
River Rouge/Ecorse Shoreline Area Site Characterization
Detroit River Area of Concern, Ecorse, Michigan (November 2013)
Sample Location:
RREC13-36
RREC13-37
RREC13-38
RREC13-38
RREC13-39
RREC13-40
RREC13-41
Sample Name:
RREC13-36-SURF
RREC13-37-SURF
RREC13-38-SURF
RREC13-38-SURF-FD
RREC13-39-SURF
RREC13-40-SURF
RREC13-41-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/28/13
10/28/13
10/30/13
10/30/13
10/30/13
10/28/13
10/30/13
Analyte
Units
E SEM
umol/2 drv
6.365
3.293
2.5786
3.552
5.714
2.789
9.08
AVS
umol/2 drv
55.6
3.6
2.4
3.3
1.9
4
2.3
foe
fraction
0.139
0.06
0.0233
0.0274
0.0793
0.0468
0.121
(E SEM - AVS) / foe
umol/2 drv
-354
-5
8
9
48
-26
56
Sample Location:
RREC13-47
RREC13-47
RREC13-48
RREC13-48
RREC13-49
RREC13-49
RREC13-50
Sample Name:
RREC13-47-SURF
RREC13-47-SURF-FD
RREC13-48-SURF
RREC13-48-SURF-FD
RREC13-49-SURF
RREC13-49-SURF-FD
RREC13-50-SURF
Sample Depth (ft):
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
0-0.5
Date Sampled:
10/30/13
10/30/13
11/5/13
11/5/13
11/5/13
11/5/13
11/5/13
Analyte
Units
E SEM
umol/2 drv
6.901
7.11
5.736
5.666
8.837
8.669
2.2829
AVS
u.mol/p drv
6 J
1.3 J
6.1
16.6
2.3
3.3
0.96
foe
fraction
0.0833
0.063
0.0592
0.0631
0.0904
0.0691
0.0151
(E SEM - AVS) / foe
u.mol/p drv
11
92
-6
-173
72
78
88
NOTES:
Bolded values exceed 130 fjmol/g
J = Indicates that the concentration is an estimated value.
U = Indicates the analyte was analyzed for but not detectt
" SEM/AVS not calculated because AVS was not dete
AVS = Acid Volatile Sulfides
SEM = Simultaneously Extracted Metals
foe = fraction organic carbon
jjmol/g dry = micromole per gram dry weight
River Rouge/Ecorse Shoreline
Detroit River Area of Concern, Wayne County, Michigan
Page 3 of 3
Assessment of Contaminated Sediments
Site Characterization Report
-------
Appendix A
Field Logbook and Data Collection Forms
-------
Appendix A:
Field Logbooks and Data Collection Forms
-------
Al. Core Collection Logbook
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-------
A2. Field Data Collection Forms
-------
Field Data Collection Form
Project Title
River Roiige/Ecorse Shoreline Area Site
Characterization
Sampling Location:
Lat.
Date Collected:
Sample Collected By:
Water Depth:
Sediment Depth:
Sediment Recovery:
a{
I a
-2
Area
Long.
I <.?/ -A. >/i Time Collected: 1 ¦>'i
ft
r '
% Recovery: oi
UjC
O i
Degrees Decimal Minutes
Sample Technique: VV1ERACORE) GEO PRO BE (" PONAR y
Field duplicate:
YES
Sample Collected to refusal:, VES
NO
NO
Depth:
Coordinates as proposed: YES (^Ox>
(New) Lat. Vcv "i q ''1 Long. ? v
Sample Observations: (color, texture, odor)
Degrees Decimal Minutes
v:1, Oiof cMcfcUl
1
Commcnts,'Remarks: ,4" ^
4 t »L-S ^
..y
// .y ,
SIGNATURE: (
-------
Field Data Collection Form
Project Title
Sampling Location:
River Rouge/Ecorse Shoreline Area Site
Characterization
RRrcis
Area
J f ^ ..... . IM ,
Lai. i (j ->^ 'o Long.
Ja.
fes 5 J
Date Collected:
Sample Collected By;
Water Depth;
Sediment Depth:
Sediment Recovery:
Time Collected:
ft
IO
i c"-> V~l
°[ ¦ 5
a.- -.o •
% Recovery: l 3 •/%
Degrees Decimal Minutes
Sample Technique; CVTBRACOR£) GEOPROBE PONAR
field duplicate:
YES
Sample Collected to refusal: YES
NO
Nth
Depth:
Coordinates as proposed: iYES )
(New) Laf. _________
NO
Long-
Degrees Decimal Minutes
Sample Observations: (color, texture, odor)
i •».% i,
J".'-*. ^ 1 V" -y.~> V K , ¦. ^ ^ I ' ' I p
S \~\yj£.
Z 1 "< -H_ ' i ,'l ¦¦ « _T ^ 1 vV
v\R. CO ' <
Comments/Remarks: '--Vi*y.
PN
SIGNATURE:
<" ~ /
, ' ts /
c
"7 ¦ /
//^
-------
Field Data Collection Form
River Rouge/Ecorsc Shoreline Area Site
Project Title
Characterization
Sampling Location:
-* Area
Lat.
Long.
Degrees Decimal Minutes
Date Collected:
Ws71
Time Collected: ; 1 ~ S
Sample Collected By:
"aVdSS
Water Depth;
3^ w
ft
Sediment Depth:
-?7 -C
Sediment Recovery;
*-
% Recovery: t J '
Sample Technique: C
CjffiRACORE}
GEOPROBE <^ONAjT>
Field duplicate:
YES
NO Depth:
Sample Collected to refusal: YES
Coordinates as proposed: YES
!^i9)
(New) Lat
Long. 6 6 r- ? 1
Degrees Decimal Minutes
Sample Observations:
(color, texture, odor)
f) n, , I 1
C/vsi - ,-;a ¦
Comments/Remarks: (Vw pancif
I £
-i>'- ^ ¦' o W, 1 poi. "ocl'-'~j 'V'
"" //7 -""7 / x
SIGNATURE: .y^^Jy' ( L ^
-------
Field Data Collection Form
Project Title
Sampling Location:
Lat.
Date Collected:
River Rouge/Ecorse Shoreline Area Site
Characterization
r. - i -?
K:
v\
,
Sample Collected By:
Water Depth: j j
Sediment Depth: O
Sediment Recovery:
o ^
.'v
Area
Long.
Time Collected:
ft
% Recovery:
-------
Field Data Collection Form
Project Title
River Rouge/Ecorse Shoreline Area Site
Characterization
Sampling Location;
Lat.
Date Collected:
Water Depth:
Sediment Depth:
Sediment Recovery;
i Vsf.
V
c,." >
Area
> I/,
Sample Collected By: ft Ws:
- 4 1
Long,
Time Collected:
-5 ft
.> *
ft
% Recovery:
Degrees Decimal Minutes
Sample Technique; VVIBRACORE' j GEOPROBE ( PONAR
Field duplicate:
YES
Sample Collected to refusal: (^ES>
Coordinates as proposed: YES
(New)
Lat.
r
NO
NO
Pepth:
Long, So"
Degrees Decimal Minutes
Sample Observations: (color, texture, odor)
n
I- V 5Qf »•' ¦' t ^ • t '' -N j M i V'V-
Coramen ts/Rcm arks: A 1 "¦v<3- ^ , >{ f-,
/ .^,v> U
'SU iy ^ U' br A y'Ux: t l ,>r..y>
SIGNATURE:
-------
Field Data Collection. Form
Project Title
Sampling Location:
Lat.
River Rouge/Ecorse Shoreline Area Site
Characterization
Q,L I S "
Area
Sediment Recovery:
Long.
0. S ^ K
% Recovery: "TVa" '<
Date Collected:
ii/v'-
Time Collected:
J ¦&
"% 7 ^ L>
Sample Collected By:
Water Depth:
IO 7:f
ft
Sediment Depth:
Degrees Decimal Minutes
Sample Technique: CVBRACORE) GFO PROBE (fPONAR."
Field duplicate: YES
Sample Collected to refusal: ^ES)
Coordinates as proposed: YES
(New)
Lat. H.V 'i t,
NO
TviO
<$°)
Long,
Depth:
i ¦>
7S 3
o
-> (,
Degrees Decimal Minutes
Sample Observations: (color, texture, odor) f:
A:-J
Comments/Remarks: rtwYz/
l/Utl -fc> 1 -«&L~ 'o. '
¦-J ( O
/7
SIGNATURE: .
-------
Field Data Collection Form
River Kouge/Ecorse Shoreline Area Site
Project Title
Characterization
Sampling Location:
•,
- ' Area
I.at.
Long.
Degrees Decimal Minutes
Date Collected:
U/s7! A
Time Collected: 0 f>5
Sample Collected By:
Water Depth:
ft
Sediment Depth:
.. S'fv
Sediment Recovery:
% Recovery:
Sample Technique: ^
—
v^IBRACORE)
GEOPROBE (^PONAR^)
Field duplicate:
YES
NO Depth:
Sample Collected to refusal:
NO
Coordinates as proposed: YES
%Qj
(New) Lat.
*',< "0 0/^6
Long, '-s - > - ^ ^ ^ "i
Degrees Decimal Minutes
Sample Observations:
(color, texture, odor)
Vj 1 -.A , ,1^11 t
VV ^ -V.* > -V- l
Comments/Remarks: /'< 4- Ui>, i' h^.ie' i ^ yr- ^ f- f, b «"o_»
<. > t . • i v. 7
» O <-> -s •'Va'wJ'' f *Uv *>"t' -I . "It't! te 'yi-K."/^ <"<¦*<» Nf/' t , Af\ 'vli;-' * / 1L™/ |/4
'—j f— — —— ¦ 1 => ' » — —i— ——
" /? -7 //
SIGNATURE: ( [/^-^
-------
Field Data Collection Form
River Rouge/Ecorse Shoreline Area Site
Project Title Characterization
Sampling Location: <-"v - ^ ^ "f Area
Lat, Long. Degrees Decimal Minutes
Date Collected:
n,H/ i 3
Time Collected:
U> I i
Sample Collected By;
6 \/l ' *=
Water Depth:
6 b
ft
Sediment Depth:
H 5"
Sediment Recovery: Q % Recovery:
Sample Technique: •CjffiRACOR|^}
Field duplicate: YES
Sample Collected to refusalrffiftSN
Coordinates as proposed: YES
(New) JLat. ? :>, ^ A c Long. "5 '>" '-H:. , ^ X(^ \ Degrees Decimal Minutes
Sample Observations: (color, texture, odor) h-./y^r - «¦-. v ^ x,- d I
GEOPROBE C PONAR
NO
NO
Depth:
QiOj
Comments/Remarks: /-V 4.- V
-La
-O
nU
-------
Field Data Collection Form
Project Title
Sampling Location:
Lat
Date Collected:
Sediment Recovery:
Elver Kouge/Ecorse Shoreline Area Site
Characterization
1
U >-\t, >
Sample Collected By:
Water Depth:
Sediment Depth:
- V ?
Area
Long,
ft
% Recovery:
CJ
Time Collected: t S '5
Degrees Decimal Minutes
Sample Technique: yVlBRACOREp GEOPROBE (^ONAlf
Field duplicate:
YES
Sample Collected to refusal: Jr'ES)
Coordinates as proposed: YES
(New) Lat. "s'h t V%'J'
NO
NO
(NO
Long,
Depth:
5?
Sample Observations: (color, texture, odor)
-iJVJ
Degrees Decimal Minutes
:'o<- k:s
Comments/Remarks: f' '~--k ' ^ ^ -i j ,n C, ,.0w ^ l-e/vOf 5
J_ 1/ Jo fx ¦ 7"u ~ /
# — — ¦ —. ____________ - ¦ —' '¦. —*.
1-. -
/? -7 / X
SIGNATURE: , \ f ( <'y -
-------
Field Data Collection Form
Project Title
Sampling Location:
Lat.
Date Collected:
Sample Collected By:
Water Depth:
Sediment Depth:
Sediment Recovery:
River Rouge/Ecorse Shoreline Area Site
Characterization
t*\f\ tc I 3 ^
Area
Long.
Time Collected:
ft
% Recovery:
Degrees Decimal Minutes
Sample Technique:
VIBRACGRE
GEOPROBE
PON All
Field duplicate:
YES
Sample Collected to refusal: YES
NO
NO
Depth:
Coordinates as proposed: YES
(New) Lat.
NO
Long-
Degrees Decimal Minutes
Sample Observations: (color, texture, odor)
Comments/Remarks:
O
SIGNATURE:
-------
Field Data Collection Form
Project Title
River Roiige/Ecorse Shoreline Area Site
Characterization
Sampling Location: ^ ¦-> " ^
Lat.
Area
Long.
Date Collected:
i i / h /1
Time Collected: !
Sample Collected By:
*S \fo'> -¦»
Water Depth:
a i
ft
Sediment Depth:
> ^
Sediment Recovery:
1 0 ^
% Recovery:
Degrees Decimal Minutes
Sample Technique: VVIBRACORE
GEOPROBE C PONAR
Field duplicate: YES
Sample Collected to refusal: YES
NO
Depth:
Coordinates as proposed: YES (NIT)
(New) Lat 'f.\ " t ^ 1 '~f ? k ? Long. ^ ^v ^
Degrees Decimal Minutes
Sample Observations: (color, texture, odor) _£
.iWV', 'v \i"
Comments/Remarks: /V 'V ' -A~
L~
t C ' C 4 I- ' '• ij) i--y ['^4-
""7 j /
SIGNATURE; ( l/v
-------
Field Data Collection Form
Project Title
.River Rouge/Ecorse Shoreline Area Site
Characterization
Sampling Location; bk c\. i ^ ^;
Lat,
Bate Collected;
Sample Collected By:
Water Depth:
Sediment Depth:
Sediment Recovery:
>
Area
Long.
ft
% Recovery: ^
•-*),'
\ fO
x ^ '¦ ' ^ -s Time Collected; l '•/ C "7
Degrees Decimal Minutes
Sample Techuique: CviBRACORE*) GEOPROBE <"* PONAJO
Field duplicate:
YKS
Sample Collected to refusal: YES
Coordinates as proposed: YES
(New) Lat €?'"7 ' O , I r>~7
NO
NO,
Depth:
(NO)
Long. -7
Sample Observations: (color, texture, odor) 7 ^ *
i ' ¦>
11_
Degrees Decimal Minutes
i 11— , 4>~ i, ./
n i ' <*. u i \ } J>' ' ^ v--> v, \ \'/
\CXy
^ it- c * 1 'U r L,yx^ Kl* W 7v> ':\ 1 e.-Tx.
Comments/Remarks: 4- '6 t nA jf_ tUtr \ ^_\ ¦.
/> rvl AvV,:7 , H ,>V%c i~< 7> y L / 'A . o-w2.y' Li'^.v r vq Wy j
SIGNATURE:
/7/T7
-------
Field Data Collection Form
Project Title
Sampling Location:
Date Collected:
Sample Collected By:
Water Depth:
Sediment Depth:
Sediment Recovery:
River Kouge/Ecorse Shoreline Area Site
Characterization
(I D -r s I "Z
6 Vov>
1 -i
f' -<£
Sample Technique: VVIBRACORE
GEOPROBE C PONAR y
Field duplicate:
YES
Sample Collected to refiisali^JfF.S)
NO
NO
Depth:
02j
Coordinates as proposed: YES
(New) tat 'iQ'^ j.C, ^ 13 U Long, y?o 1
n . , - v . 14-
Saraple Observations: (color, texture, odor)
">~-ur - _ ti'lPCW ^ •
Degrees Decimal Minutes
Comments/Remarks: ^ la\ -,V- 'j k_J _ v.
-v 4-, ¦>
ir / -j *o v 1 < : urXi ^
K' ^ -A- O !_• .A.^ - AV.
V* ^ ErPA-
SIGNATURE:
, :\y ?l£
-------
Field Data Collection Form
Project Title
Sampling Location;
River Rouge/Ecorse Shoreline Area Site
Characterization
\ 3 - 1 O
Area
Lat. -'o Long,
Date Collected:
Sample Collected By:
Water Depth;
Sediment Depth;
Sediment Recovery:
'5, Vo'»
V?| O
i o :
-Vj !-•
Time Collected: o"'5 > "1
ft
% Recovery;
Degrees Decimal Minutes
/ y -v.
Sample Technique: VWBRACORE) GEOPROBE
Field duplicate:
YES
Sample Collected to refusal:
Coordinates as proposed: ('YES")
(New) Lat
NO
NO
NO
Long.
Depth:
Degrees Decimal Minutes
Sample Observations: (color, texture, odor) < ,¦> >
. if
Comments/Remarks: t ' MO.,'
/>
SIGNATURE; . ^
// ""7
«f -V.
-------
Field Data Collection Form
Project Title
Sampling Location:
Lat.
Date Collected:
Sample Collected By:
Water Depth:
Sediment Depth:
Sediment Recovery:
River Rouge/Ecorse Shoreline Area Site
Characterization
(•'PF-'' \ "'¦>
•,V \C - 1 -
Area
*"> ^ Long. - C
^ J
a |?
S. vf>
> iO(u
i. S ^
Degrees Decimal Minutes
Time Collected:
"X '*f "" V > , \ ! ^ f , * ,-,s"
\ > A i>'* (s . I -
ft
% Recovery;
'^6
Sample Technique: VVIBR-ACOREJ GEOPROBE (^PONARy-
Field duplicate:
YES
Sample Collected to refusal: YES
Coordinates as proposed:
/YE^
(New)
Lat.
NO
"NQ
NO
Long-
Depth:
Degrees Decimal Minutes
Sample Observations: (color, texture, odor)
^ N I ! +
Comments/Remarks: ^ 1 -iP-iH'* H, 'C\P\ w > l~U ^ t'C_
:.CLl-eV^f i-.'y <. c 'V > .i>('cc V j> ^ ^ '<¦ ?''0 10^.
SIGNATURE.;
- z'"
14'-
-------
Field Data Collection Form
Project Title
Sampling Location,"
River Rouge/Ecorse Shoreline Area Site
Characterization
Area
Lat. "i j Long. '5
Date Collected:
Sample Collected By;
o , 5 n
:A i S
Time Collected:
Degrees Decimal Minutes
Water Depth:
ft
Sediment Depth:
Sediment Recovery:
% Recovery:
Sample Technique: C^IBRACORlf) GEOPROBE PONAR~^>
Field duplicate:
YES
Sample Collected to refusal: YES
NO
Peptb:
Coordinates as proposed:
(New) Lat.
NO
Long.
Sample Observations: (color, texture, odor)
itL-niAl
Degrees Decimal Minutes
Comments/Remarks: r>c^\»- *WtI? r-
SIGNATURE:
"7' //
-------
Field Data Collection Form
River Rouge/Ecorse Shoreline Area Site
Project Title
Characterization
Sampling Location:
¦hRec \ ^ "
Area
Lat.
1 Long.
. . v *) :i} Degrees Decimal Minutes
Date Collected;
' 0/ r<'"i / 1
Time Collected:
11 (3
Sample Collected By:
Water Depth:
i I
ft
Sediment Depth:
\.s(M
Sediment Recovery:
0.5T
% Recovery:
5 j .
Sample Technique: V
.VIBRACORE)
GEOPROBE Q
'ponaji";1
Field duplicate:
YES
NO
Depth:
Sample Collected to refusal: j'YIfS,
NO
Coordinates as proposed: VYE$
(New) Lat.
NO
Long,
Degrees Decimal Minutes
Sample Observations;
{color, texture, odor)
1 1 Ai'Oi * > k.iv't il < l-cC *
Comments/Remarks: A -kW 4 ,X .) i_ { UjvV ^ -jt;
\;, i~.( a-~'-J « ,
SIGNATURE:
y
l/£^?
-------
Field Data Collection Form
Project Title
River Rouge/Ecorse Shoreline Area Site
Characterization
Sampling Location: (-%,'$ t~ ^ ^
Area
I.at. '-/ ct" '>x., S "b^i> Long, y1 v'
Sample Collected By:
"h.. V&
Y
Date Collected: 16/,^ /' ' Time Collected:
Degrees Decimal Minutes
Water Depth:
Sediment Depth:
Sediment Recovery:
' i J
-£r
a
% Recovery: rf / c-i,
Sample Technique: v^LBRACORl-^ , GHOPROBE (. PONAR~^)
Field duplicate:
YES
Sample Collected to refusal:
NO
NO
Depth:
Coordinates as proposed: vYJiSr
(New) Lat. ______
NO
Long.
Degrees Decimal Minutes
Sample Observations; (color, texture, odor) (,'v
A'V .. 11
Comments/Remarks: t y _ n\ * U
( d,v >' p'y t«~S\{ ? v ! u; * v. V X- *:>*('f*Vr, e4, U-0'0* \r
-------
Field Data Collection Form.
Project Title
Sampling Location;
River Rouge/Ecorse Shoreline Area Site
Characterization
p . '*") \
1 , > '^1 I
Area
Lat. "~i v s * I ^ . 'i ¦- < S Long, -y; 'is -3 ^
Date Collected:
Time Collected: 1 ^
Degrees Decimal Minutes
Sample Collected By:
Water Depth:
[-7 ~?£'
ft
Sediment Depth:
n \
[i*^4rr
Sediment Recovery:
. S'
% Recovery:
\ ..
'v-/3
Sample Technique: vVIBRACORE) GEOfROBE f PONAR '>
Field duplicate: YES
Sample Collected to refusal: YES
NO
(f5cT)
Depth:
Coordinates as proposed:
(New) Lat.
NO
Long,
f
Sample Observations: (color, texture, odor) | ^}/\.
— ——,—— _____ ——, ..
Degrees Decimal Minutes
n't:;. - -n
Comments/Remarks:
Xtf^
SIGNATURE:
-7 / /"
-------
Field Data Collection Form
Project Title
River Rouge/Ecorse Shoreline Area Site
Characterization
Sampling Location:
Lat.
Date Collected:
Sample Collected By:
Water Depth:
Sediment Depth:
Sediment Recovery:
i ) C) /
•kK t.
-9
Area
l o;
r\
, .-j "o
i ^ -•
|or
L4-
1- ^
Long,
Time Collected:
o
M.
ft
% Recovery:
i
Degrees Decimal Minutes
Sample Technique: VVIBRACOREJ GEOPROBE PONAR y
Field duplicate:
YES
NO
Depth:
Sample Collected to refusal: YES
/"SfO
Coordinates as proposed: YES
/no;,
(New) Lat
. '"f i * 1 : ^ « '~t- Long. 1 '' ^ ^ f *1 *
Comments/Remarks: Opm j.\>A
i r ic
rn.Vg.d"' ,Ji.V (r> ^ ^ •:>{xl
-------
Field Data Collection Form
Project Title
River Roitge/Ecorse Shoreline Area Site
Ch aracterization
Sampling Location:
Area
Lat. L I O ^ ~ ^ Long. % ^ i • >"v ~J '
Date Collected:
Sample Collected By;
Water Depth:
Sediment Depth:
Sediment Recovery:
IO/ ~'o/ : Time Collected: C^< ~y'
• /
Tx Vo >-"•>
vs
ft
ioa
c-i 4 *s
% Recovery: V^1
Degrees Decimal Minutes
Sample Technique;
GEOPROBE
Field duplicate:
YES
NO
Depth:
Sample Collected to refusal; YES
Coordinates as proposed: f^YES )
(New) Lat
NO
Lens
Sample Observations: (color, texture, odor) j ¦
Degrees Decimal Minutes
sr
'v J\ » V I \ 'v cci'c r
i/"
Comments/Remarks: ¦ ^y < -,^JV n
SIGNATURE: . S
V ; /
(A
-------
Field Data Collection Form
Project Title
River Rouge/Eeorse Shoreline Area Site
Characterization
P A ¦" ' i "7 M
Sampling Location: tyxt'- j f~-'
Lat,
Date Collected:
Sample Collected By:
Water Depth:
Sediment Depth:
Sediment Recovery:
111
S *
Area
Long,
-! i ' ^ Time Collected:
- d c~f
o i 3
ft
% Recovery:
Degrees Decimal Minutes
Sample Technique: CvffiRACOREj) GEOPROBE
Field duplicate:
YES
Sample Collected to refusal:
NO
NO
"X
NO,)
Depth:
Coordinates as proposed: YES
(New) Lat. W f *>'. ! 'i M 4 Long, ^ > ' - 7 S 3.
Degrees Decimal Minutes
Sample Observations: (color, texture, odor)
ojxsi w
•w.
"WW- j
M.- >' K > '
Comments/Remarks: A" ^ H t
.. / t .. .x ~~ ~
pC'
W
• // //
SIGNATURE: ( l/t^
-------
Field Data Collection Form
River Rouge/Ecorse Shoreline Area Site
Project Title
Characterization
Sampling Location:
0 n r •' | '? "1 „
>
Area
Lftt.
Long.
Degrees Decimal Minutes
Date Collected:
I
Time Collected:
Sample Collected Bv:
SVo-v,
Water Depth:
H
ft
Sediment Depth;
-• ?o ^
Sediment Recovery:
% Recovery :
Sample Technique:
CvffiRACORE)
GEOPROBE <
"ponar^>
Field duplicate:
YES
NO
Depth:
Sample Collected to refusal: YES
NX*
Coordinates as proposed: YES
(New) Lat. lfT'
-------
Field Data Collection Form
River Rouge/Ecorse Shoreline Area Site
Project Title
Characterization
Sampling Location:
(Y'CC .
' *
Area
Lat,
Long,
Date Collected;
\ i /h /1 3
Time Collected:
Sample Collected By:
Water Depth:
(T Y
ft
Sediment Depth:
-? 5
Sediment Recovery:
~~~j Q 1.
% Recovery:
Decimal Minutes
Sample Technique; C^^VBRACOREl GEOPROBE C PONAffy
Field duplicate: YES
Sample Collected to refusal: YES
Depth:
Coordinates as proposed: YES
(New) Lat •!3 t . j A 'H > Long. '6" ^ 7, ^ o'O f
Degrees Decimal Minutes
A 1 .
Sample Observations: (color texture, odor) to/,¦¦¦/<>. o W U <-<- *i.. '4.' * " „
t-'M v .A
Comments/Remarks: /t
Llki -4, r,1 <' "?n,, ..v v^' I —--/c v -v4"o»^
- // "~7 J /
SIGNATURE: ,<¦
-------
Field Data Collection Form
River Rouge/Ecorse Shoreline Area Site
Project Title
Characterization
Sampling Location:
<&£-: i-s - :
—t
^ Area
Lat.
Long,
Degrees Decimal Minutes
Date Collected:
{ ! , -J , i ^
Time Collected: O ^
Sample Collected By;
fXVr/^
Water Depth;
L\.<*
ft
Sediment Depth;
> io+u
Sediment Recovery;
q„r^
% Recovery: >5l "S ••£
Sample Technique;
CVBRACORE^
GEOPROBE (^PQNAR^)
Field duplicate:
YES
NO Depth:
Sample Collected to refusal: YES
Coordinates as proposed: YES
(New) Lat, '» A " > ^ ^
Long. O
Degrees Decimal Minutes
Sample Observations;
(color, texture, odor)
(1,-v.r n ^ ^ :.i+-
:U». .< ro
t r l '1
..•a, rr». V
Comments/Remarks; ,,J~ 4 ,.,vi ^ i o \ <. >
M-XO.-V- 4 ,r AA-. ,M„i,vu'i
SIGNATURE; , ^F ^
-------
Field Data Collection Form
Project Title
Characterization
Sampling Location:
m^c i3-
o
Area
Lat,
V?" W "?« 'f >
Long. 5l~> O 7,
r„ • f
Date Collected:
u./i/tT;
Time Collected:
I "7u*&
Sample Collected By:
fVvuv*
Water Depth:
3 1
ft
Sediment Depth:
Sediment Recovery:
% Recovery
; <\ h "-i
Degrees Decimal Minutes
Sample Technique; VVIbracore;> geoprobe C ponar^
Field duplicate: YES
Sample Collected to refusal: YES
Coordinates as proposed: (YE§>
(New) Lat.
NU
(NCK
NO
.LoPg-
Depth:
Degrees Decimal Minutes
Sample Observations: (color, texture, odor) -s _ - ^ v -\ ^v,4
Comments/Remarks: ¦ j. "V A^ri'V -!
-V-i .
"V wi \
— X : **N' ^ } -v ' cidU, t\ ^ t ^•y-ty't gf or
// - ' '
SIGNATURE: / (A' " "
-------
Field Data Collection Form
Project Title
River Rouge/Ecorse Shoreline Area Site
Characterization
,'-3 /\r- / j _ s Ci\
Sampling Location: t N 1
Lat.
Area
Sediment Recovery:
% Recover)':
Date Collected:
\\/1 /1 1
¦ J
Time Collected:
t "ZOO
Sample Collected By:
fWt>
Depth:
(Mew) Lat. ! j Long. C, ? { £ Degrees Decimal Minutes
"I J— _ ft 1 I I
-tadLL* _OdJ&T o1 -V-1
/I
t * t i-i
Sample Observations: (color, texture, odor)
——V '.->0 vy ,--y f - c,f^w (-c
Comments/Remarks: J.- iV - a _f \-a. , C"\ 1 / -\j-
Q- ' >0 (a' i' L tf-\ -£~rc> ^
( 1 ' flS-j ^ £U1_ ±££±£jk*. /WC-Hi W /W (\k,, i d 'wu, 1fy^A~.
SIGNATURE:
// ,— 7
/ / /
f [/ V"'"^
-------
Field Data Collection Form
Project Title
Sampling Location:
River Rouge/Ecorse Shoreline Area Site
Characterization
K(\ I- - ^ ~ v
Area
Sediment Recovery:
Date Collected:
U/i/i!
Time Collected:
! tl i 6"
Sample Collected By:
fWv,
Water Depth:
U. .c
ft
Sediment Depth:
> 7 5"
~7. f (~
% Recovery:
Degrees Decimal Minutes
Sample Technique: CVlBRACORJr,") GEOPROBE (f'pONAR^)
Field duplicate: YES
Sample Collected to refusal; YES
Coordinates as proposed: \jYES]
(New) Lai.
NO
€5>
NO
Long»
Depth:
Degrees Decimal .Minutes
Sample Observations: (color, texture, odor)
Comments/Remarks: y ieJ'^ A
/'J ~7 >/
SIGNATURE: t , -
-------
Field Data Collection Form
Project Title
Characterization
Sampling Location:
,'.'1
< .>
o \
O '
Area
Lat.
Long. ^ V '
'i If ^
Date Collected:
1"-,' v"'y' N
Time Collected:
1 *~i u
Sample Collected By:
v.V>s
Water Depth:
3-^
ft
Sediment Depth:
>
Degrees Decimal Minutes
Sediment Recovery:
% Recovery:
Sample Technique: V V1BRACX)RH") GEOPROBE (^PONAR^
Field duplicate: YES
Sample Collected to refusal; YES
Coordinates as proposed: ^ YF$)
(New) Lai
NO
\ n6\
„ >
NO
Long,
Depth:
Sample Observations: (color, texture, odor) <,, ^,41- fa, J •
Degrees Decimal Minutes
Comments/Remarks: fir
/ / / / /
SIGNATURE; . x _/- / (y
-------
Field Data Collection Form
Project Title
River Rouge/Ecorse Shoreline Area Site
Characterization
Sampling Location:
Date Collected:
Sample Collected By;
Water Depth;
Sediment Depth;
Sediment Recovery:
r"* /" - \ "
K-U. * .3
-> '^i
1
Area
Lat. "'d ! ° Long, ^ 1 o
u:>/jx:y < S Time Collected:
hi
: >
"\ / ^
L\
ft
% Recovery:
%
Degrees Decimal Minutes
Sample Technique: VVIBRACOREJ
GEOPROBE
Field duplicate:
YES
Sample Collected to refusal:
NO
NO
Depth:
Coordinates as proposed: (YES)
(New) Lat.
NO
Long.
Degrees Decimal Minutes
n , \
Sample Observations: (color, texture, odor) fao-pf ~ ^ ^ ,-xrj> r w.,' 3 a -CS.W.Lir-
SIGNATURE:
T7 /-w
-------
Field Data Collection Form
Project Title
River Rouge/Ecorse Shoreline Area Site
Characterization
Sampling Location: K [\£~C \ 3 ~ ">
Lat.
Area
t ong.
Date Collected:
!tV ?><¦>/1 3
Time Collected;
it |5"
Sample Collected By:
Water Depth:
ft
Sediment Depth:
> , cH •>
Sediment Recovery:
- V" *"
i.
% Recovery:
cl; %
Degrees Decimal Minutes
Sample Technique: vVTBRACORIp GEOPROBE (fPONARy
Field duplicate: YES
Sample Collected to refusal; YES
NO
3€3>
Depth:
Coordinates as proposed: YES
(New) Lat. "f j ex. ^ Long. *"5 ¦" " O S, "*t
Degrees Decimal Minutes
Sample Observations: (color, texture, odor) I / njj ^ 11
Comments/Remarks: 3 y »^ i^u^n
-ft •-.»/> i-vygt,/^ >.,L v, f-o p 1 j
^2 .fe i "1 4a ^ w
SIGNATURE:
-------
Field Data Collection Form
Project Title
Sampling Location:
River Rouge/Eeorse Shoreline Area Site
Characterization
r ; ^ . < Lj
» •> | \ l: >— 1 »> 0* !
Area
Sediment Recovery;
Lat.
\C-vV u\.\
-m- r—». A ,1- 'jf
' ,> Long, p ' "¦ ' ^
; < 1
Date Collected:
Time Collected:
1 Vl.j
Sample Collected By:
Water Depth:
&. 5"
ft
Sediment Depth:
H -
•i as
% Recovery:
O - /
Degrees Decimal Minutes
Sample Technique: CviBRACORE) GEOPROBE (f PON'AR
Field duplicate: YES
Sample Collected to refusal:
Coordinates as proposed: (YES)
(New) Lat.
NO
NO
NO
J °»&
Peptb:
Degrees Decimal Minutes
Sample Observations; (color, texture, odor) p-^(h
u\
Comments/Remarks: Q-v- ,yn..
"7 7 /'
SIGNATURE: . ( (/&~
-------
Field Data Collection Form
Project Title
Characterization
Sampling Location:
c_
J
Area
Lat.
Long.
Degrees Decimal Minutes
Date Collected:
!•->/'>0,.' t
Time Collected:
r-2 5"
Sample Collected By;
Vf/A
Water Depth:
11 5 ?
ft
Sediment Depth:
^ - f i
o
Sediment Recovery:
L{ £ -v-
% Recovery;
Sample Technique:
CviBRACOKii^)
GHOFROBH
"P0NAR^>
Field duplicate:
YES
NO
Depth:
Sample Collected to refusal: yfe?*,
3NO
Coordinates as proposed: YES
(New) Lat. "7>1 ?»'i
<©>
<«•, ¦> *. _ - ?
Long. ^ A T»
' •)
1 -3 Degrees Decimal Minutes
Sample Observations:
(color, texture, odor)
v 1 I
v *-» " o CiXi) ^
- - 1 i J
• -iTiA - i(j > V.€ }*,' 5s
v viv-li ^ W (1 -,l
-n
! )/> Sj£/tV-
~&*j \Axjci j
d&/'
-4: /" *-¦ SVvAiA
Comments/Remarks; <-1 trja' jV
A:~>fy
4-o.J^v
rA. -^\ ' ^t'¦ An- *u.* fM > 7 k~w ! W-.
-Z/7 "7 , ,
SIGNATURE; >' < * "
-------
Field Data Collection Form
Project Title
Characterization
Sampling Location:
mr< \ l
Area
I.at.
- Long. *t ^ o ^ '?• ^
Date Collected:
( - - t ! f ' "N
Time Collected: '< 5~ J
Sample Collected By:
fS Vr*.-
Water Depth:
'6. b
ft
Sediment Depth:
. 4-i
»> i-'
Sediment Recovery:
'"l ,? u
^ -J
% Recovery:
Degrees Decimal Minutes
Sample Technique: VVD^CORE) GEOPROBE
Field duplicate:
YES
Sample Collected to refusal:
Coordinates as proposed: / X
(A-
-------
Field Data Collection Form
Project Title
.River Rouge/Bcorse Shoreline Area Site
Characterization
Sampling Location:
-> ,•% ' - > „ ~7
t s )•> It v. I ;> :•> '
Area
Lat ^ > i ' ^ % - Long. Vi ^ v_ • t\ -\ 'a
Date Collected:
Sample Collected By;
Water Depth:
Sediment Depth:
Sediment Recovery:
to/i2g/11
jSVo'^
3-t>8
u
-ri
% S
.r.t-
Time Collected:
i < 3^
ft
% Recovery:
Degrees Decimal Minutes
Sample Technique: CviBRACORE'*) GEOPROBE (fPONAiT
Field duplicate:
YES
Sample Collected to refusal: YES
y.'> „ -
Coordinates as proposed: (yBg.)
(New) Lat.
NO
NO
Long,
Depth:
Degrees Decimal Minutes
Sample Observations: (color, texture, odor)
! ~K
T « ] V,
Comments/Remarks: -->'V y'0 x -
SIGNATURE:
-------
Field Data Collection Form
Project Title
Sampling Location:
Date Collected:
Sample Collected By:
Water Depth:
Sediment Depth:
Sediment Recovery:
River Rouge/Ecorse Shoreline Area Site
Characterization
Area
Lat, v/ ^ v ¦ "? ^ Long, 4? 3
f>!
D Time Collected:
"S.Vc
D'=^>
/•l J.
•S\ ¦ \
ft
"> 7. s
% Recovery:
—¦"} JT\ I? y
: T\ -T-
Degrees Decimal Minutes
Sample Technique: VVIBRACORH*' GEOPROBE
Field duplicate:
YES
Sample Collected to refusal: YES
Coordinates as proposed: ;YE$\
(New) Lat.
NO
NO
Long-
Sample Observations: (color, texture, odor) (-C?
Depth:
Av/ ^ 1v t./ f b,
f
Degrees Decimal Minutes
A ior>A--
-------
Field Data Collection Form.
Project Title
Characterization
Sampling Location:
ifvQ£>-- •
-
•~p -Xi
i 1 Area
Lat.
Long.
Date Collected:
i Oi "A. j '
i
I ~y
Time Collected: ^ H J o
Sample Collected By:
'\Vr^
Water Depth:
.'"1
D ^
ft
Sediment Depth:
"> lo
Sediment Recovery;
VS
v\
% Recovery:
, r
I 3
Degrees Decimal Minutes
Sample Technique: VVIBRACORfc} GEOPROBE Q PONAR
Field duplicate; YES
Sample Collected to refusal; YES
Coordinates as proposed: YES
(New)
JLaf. l!
, l_ j
NO
(fjO>
k ¦* \ 7 Long, g..
Depth:
Degrees Decimal Minutes
Sample Observations: (color, texture, odor) tcoC,1' - ;r I*¦- irjt i- > ic -
D
Comracnts/Rcmarks: Ajrv?" + j-
SIGNATURE:
-------
Field Data Collection Form
River Rouge/Ecorsc Shoreline Area Site
Project Title
Characterization
Sampling Location:
(ii t\ r~ ¦' < "(
hK t ¦ '• >
HArea
Lat.
"-1''I '' 1 1 K ! 7 Long. ? s'
Degrees Decimal Minutes
Date Collected:
. >; ^ f, / {^
Time Collected: i .:-rj
Sample Collected By;
S Vn >'>
Wafer Depth:
C~~~
- 1 >
ft
Sediment Depth:
"7 o V'1
Sediment Recovery:
T , (H
% Recovery: -•' "L
Sample Technique: C
I^RACORE)
GEOPROBE (^PONAR^/
Field duplicate:
YES
NO Depth:
Sample Collected to refusal:
NO
Coordinates as proposed: (YEj>>
(New) Lat.
NO
Long.
Degrees Decimal Minutes
Sample Observations:
(color, texture, odor)
! jf'k) i "* ( >. i\"\ ^ <,
VM ^ w ifh 51 1'
Comments/Remarks: A ^ _¦ S ijU ^
•••• /? -7 /
SIGNATURE: - ( [/
-------
Field Data Collection Form
Project Title
Sampling Location;
Lat.
Date Collected;
Sample Collected By:
Water Depth:
Sediment Depth:
Sediment Recovery:
River Rouge/Ecorse Shoreline Area Site
Characterization
m i N
Area
Long-
16
, .O t ' Time Collected: ' "S
i l
¦> / ^ ^
C f-'
ft
% Recovery;
Degrees Decimal Minutes
Sample Technique: C^VIBRACORE') GEOPROBE Q PONAR
Field duplicate:
YES
Sample Collected to refusal: YES
NO
Depth:
Coordinates as proposed: YES
(New) Lat, 1 ',-3 ' I ^ "¦
Long. r.o C , i : ' ! ^
Degrees Decimal Minutes
f\ » ,
Sample Observations: (color, texture, odor) tb?->&," - ~v H~ 1 H-> rv K H U
Comments/Remarks: f -UaiciP
'i "¦
/ ,*
->11 • , J,A , ^
-------
Field Data Collection Form
Project Title
River Rouge/Eeorse Shoreline Area Site
Characterization
Sampling Location: 'S > x ^ ^ ^
Lat.
3 - H 3.
Area
Long.
Date Collected:
U/M 1 \
Time Collected: .'C ~i 6
Sample Collected By:
t\ v'.v>
Water Depth;
~i- 6
ft
Sediment Depth:
'1- 5" f>
Sediment Recovery:
M.t '
% Recovery: 1 ..
Degrees Decimal Minutes
Sample Technique: CviBRACORE"_)
GEOPROBE
Field duplicate; YES
Sample Collected to refusal; \ KS)
Coordinates as proposed: YES
(New) Lat. 21'< iC, '
NO
NO
Depth:
Long, i', ^
Sample Observations: (color, texture, odor) ,
lU-W
. S W,
. Degrees Decimal Minutes
11 rp, v C'~Hl r ;-i( \ *~
Comments/Remarks: A ^ ,>A S , ^ • i, '
'o l ^~*y ^ ^ ' 4:'
¦~C q:--^ a f>
-------
Field Data Collection Form
Project Title
Sampling Location:
Lat
Date Collected:
Sample Collected By:
Wafer Depth;
Rn er Rouge/Ecorse Shoreline Area Site
Characterization
L 1 7, - M s
\K I • ^
r~ ~ y
Area
Long.
Time Collected:
ft
Degrees Decimal Minutes
Sediment Depth:
Sediment Recovery:
% Recovery:
Sample Technique: vV'tBRACORfQ
GEOPROBE
PONAR ;>
Field duplicate:
YES
Sample Collected to refusal: YES
NO
NO
Depth:
Coordinates as proposed: YES
(New) Lat,
NO
Long-
Sample Observations: (color, texture, odor)
Degrees Decimal Minutes
.—^ ^^ A \^, i, M y\
Comments/Remarks: ^x'^i gLVuL W oc, iW .yf- C -I! -X' Y
x;
SIGNATURE: .. ( i7t?
// -V ; /
-------
Field Data Collection Form
Project Title
liver Rouge/Ecorse Shoreline Area Site
Characterization
Sampling Location;
Lat.
i ,11 •<,- ¦-/
Area
Date Collected;
Sample Collected By:
Water Depth;
Sediment Depth:
Sediment Recovery:
Is ft
f - -A.' - •
Long-
t'i'j < Time Collected: C""Vtc>
ft
% Recovery:
^6
t. >
Degrees Decimal Minutes
Sample Technique: v^VTBRACORE"*) GEOPROBE (fPONAR V
Field duplicate:
YES
Sample Collected to refusal: ^ES>
NO
NO
Depth:
Coordinates as proposed: YES
(New) Lat. ,
Long, "'y^ s> "* •"*
Sample Observations: (color, texture, odor) t?y-,
r - -v
J i -K
Sr 14'
Degrees Decimal Minutes
A „ { I
f" O\:i/Or >- / t~
-------
Field Data Collection Form
Project Title
Sampling Location:
River Rouge/Ecorse Shoreline Area Site
Characterization
Area
Lai,
Q "I'Sr, "/ r-'-lC-
Long, i ^ ?
Degrees Decimal Minutes
Date Collected:
Time Collected:
Sample Collected By:
'S.s/oV*
Water Depth;
'"> • ~C''l
ft
Sediment Depth:
'Z, > tx
Sediment Recovery:
% Recovery:
•— —-
Sample Technique: C
IviBRAC OR]?)
GEOPROBE C
PONAR>
Field duplicate:
YES
NO
Depth:
Sample Collected to refusal: (VES>
NO
Coordinates as proposed:
NO
(New) Lat,
Long.
Degrees Decimal Minutes
Sample Observations:
(color, texture, odor)
(ur-S -V.A V
s 1V-
Comments/Remarks:
OV.
SIGNATURE:
-------
Field Data Collection Form
River Eouge/Ecorse Shoreline Area Site
Project Title
Characterization
Sampling Location:
n f> ¦- i -
t\ f\ h ^ ' .-¦>
^ to Area
Lat.
Long.
Degrees Decimal Minutes
Date Collected;
Time Collected: ' '•>
Sample Collected By:
7\Vr><*>
Water Depth;
1 3 1 4
ft
Sediment Depth:
¦> io ^
Sediment Recovery:
% Recovery: >0
Sample Technique: C
VTBRACoill
—
^
GEOPROBE QPONAlT>
'"" pT*a*"
Field duplicate:
YES
NO Depth:
Sample Collected to refusal: YES
Coordinates as proposed: YES
(New) Lat "i ,3 jC
Long. '3 CX.', ^
Degrees Decimal Minutes
Sample Observations; (color, texture, odor)
,o
^' '¦ f ^ ::^rr-4f. ^trv\ , ^ ^ ^ ><,
cVyiArv-ei b». . 0°A
^ / 'pV-W -uX^'a.y •tHCvA b-./
^ x/1
SIGNATURE; ( l/ir'
-------
Field Data Collection Form
Project Title
Sampling Location:
River Rouge/Ecorse Shoreline Area Site
Characterization
w->. i":-
Area
Sediment Recovery:
Lat.
Long.
Date Collected:
: y v,y'1
Time Collected:
t (ri
Sample Collected By:
"S 'VdV:
Water Depth:
r? ,^5
ft
Sediment Depth:
o,. -¦ -¦ -
% Recovery: , ^ V ,
Degrees Decimal Minutes
Sample Technique: v VFBRACORF"; GEOPROBE PONAR~^)
Field duplicate: YES
Sample Collected to refusal: YES
Coordinates as proposed: YES
(New) I at. 0jc
k
NO Depth:
(no)
Long. "B CjI 11
Degrees Decimal Minutes
Sample Observations: (color, texture, odor)
M-
Comments/Remarks: '1 '^v_ ,
-------
Field Data Collection Form
Project Title
Sampling Location:
River Rouge/Ecorse Shoreline Area Site
Characterization
n c- /
•S hv-
Area
I .at. > <. i 1
Degrees Decimal Minutes
Sample Technique: VVIHRACORF '
GEOPROBE
Field duplicate: YES
Sample Collected to refusal: YES
Coordinates as proposed: iYl-S)
(New) Lat.
NO
NO
Long-
Sample Observations: (color, texture, odor)
Depth:
VV
Degrees Decimal Minutes
-- < -
Comments/Remarks: /r 4^1?a \ «
1 —
/y? —7 '
SIGNATURE:
-------
Field Data Collection Form
Project Title
River Rouge/Ecorse Shoreline Area Site
Characterization
Sampling Location:
Area
Lat. V • ~ i o-
/ i I-*
Date Collected;
l i (* l~> ; • s1
Sample Collected By: S, y'/> >
Water Depth: _
Sediment Depth: _
Sediment Recovery:
i * ^
Long,
"7
cs
Time Collected:
-5 C'j
ft
% Recovery;
Degrees Decimal Minutes
Sample Technique: CvffiRACORE'
GEOPROBE C PONAlO
Field duplicate:
YES
Sample Collected to refusal: YES
Coordinates as proposed: (YE^
(New) Lat
NO
NO
Long-
Sample Observations: (color, texture, odor)
Depth:
V* ' 'H
Degrees Decimal Minutes
.r- <"J (>-' I *
Comments/Remarks: CVv
S1GNATURE:
/ j /
-------
Field Data Collection Form
Project Title
River Rouge/Ecorse Shoreline Area Site
Characterization
Sampling Location: *j ,'! ¦ ' N 1 ^
Lat, i " ¦
'7 i
O *
Date Collected:
\Z5T71 i.
• vj'i U
>
Time Collected:
I f
ft
% Recovery:
-------
A3. Core Processing Logbook
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i
o
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i
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i UJ
r^T _J_
7" -c
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3 §
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s
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JL » , Q
/\ _ O-i
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5 6 o ?
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r
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Qc) ;
s 1ft
-HM ^
-------
-------
-------
-------
Appendix B
Lithologic Core Logs
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-01
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 9/30/2013 9:54:00 AM
PROJECT NUMBER 62561.15
DATE LOGGED 10/31/2013 2:55:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 16.4079
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 06.6083
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 4ft
536.4 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
o
(/)
o
CO
_l
<
o
_l
o
X
-------
£ EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-02
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/30/2013 10:31:00 AM
PROJECT NUMBER 62561.15
DATE LOGGED 11/2/2013 10:45:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 16.3670
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 06.6333
542.7 ft
LOGGED BY M. Gelinas
<
>
0-
LLl
< c
if) o
<
W
ELEVATION
(Sediment Surface)
CORE RECOVERY 9.8 ft
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
12
24
24
24
24
10
CT
CT
CT
CT
CT
CT
RREC13-02-0001
SC
SANDY CLAY: dark gray silty soft clay and fine
sand (35%). Hydrocarbon odor
RREC13-02-0103
RREC13-02-0305
CL
CLAY: dark gray soft clay with some organic
material (20%). Hydrocarbon odor. @37" and
@53": dense organic material (~70%), causes
clay to 'break' here
RREC13-02-0507
SC
RREC13-02-0709
RREC13-02-0911
gray soft organic clay and fine sand (35%)
CL
CLAY: dark gray semi-soft clay
sc
SANDY CLAY: gray semi-soft clay and fine sand
(35%)
11
End of Boring at 9.8 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-03
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/5/2013 10:48:00 AM
PROJECT NUMBER 62561.15
DATE LOGGED 11/5/2013 2:05:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 16.3229
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 06.6321
521.4 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 7.2 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-03-0001
24
CT
RREC13-03-0103
24
CT
RREC13-03-0305
CL
SILTY CLAY: gray silty clay with little fine sand
(10%), little gravel (10%). Hydrocarbon odor.
sc
sc
CLAYEY SAND: dark gray clayey medium-coarse
sand with some shell pieces <1 cm (25%) and
some gravel (20%). Hydrocarbon odor.
26
CT
RREC13-03-0507
SC
CH
SC
SANDY CLAY: gray medium sandy clay with
some shell pieces ~1 mm (20%), trace organic
wood pieces (5%), 1 well-rounded cobble 4x3x2
cm. Hydrocarbon odor.
CLAYEY SAND: clayey medium-coarse sand with
little rounded gravel (15%), little shell fragments 1
mm (15%)
CLAY: beige/tan semi-stiff clay and gravel/coarse
sand (25%)
CLAYEY SAND: gray clayey fine-medium sand
with little gravel (10%), little pebbles/cobbles up to
3x3x2 cm (10%)
End of Boring at 7.2 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-05
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/5/2013 10:13:00 AM
PROJECT NUMBER 62561.15
DATE LOGGED 11/5/2013 3:00:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 16.1596
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 06.7085
532.1 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 3.5 ft
<
>
0-
LLl
< c
if) o
<
W
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
O
o
o
X
w
<
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-05-0001
30
CT
RREC13-05-0103
CL-ML
CLAYEY SILT: dark gray-black clayey silt with
little fine sand (15%), trace subangular gravel
(10%), trace coarse sand (5%), trace wood pieces
<1 cm (1%)
End of Boring at 3.5 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT= Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-06
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/5/2013 9:36:00 AM
PROJECT NUMBER 62561.15
DATE LOGGED 11/5/2013 4:30:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 16.1026
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.7361
532.7 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 2.8 ft
<
>
0-
LLl
< c
if) o
<
W
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
O
o
o
X
w
<
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-06-0001
SC
21.6
CT
RREC13-06-0103
SANDY CLAY: dark gray medium-coarse sandy
clay with some gravel (25%) with little shell debris
<0.5 cm (15%). @8-9": crimson streak.
Hydrocarbon odor.
End of Boring at 2.8 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT= Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-09
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/4/2013 4:11:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 11/5/2013 8:15:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 15.9326
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 06.8201
536.4 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 3.8 ft
<
>
0-
LLl
< c
if) o
<
W
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
O
o
o
X
w
<
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-09-0001
24
CT
RREC13-09-0103
10
CT
RREC13-09-0305
SC
CLAYEY SAND: black clayey fine-medium sand
and shells 1-2 cm (30%), with some
grave/pebbles (20%)
CL
SILTY CLAY; dark gray silty soft clay, trace shell
hash (1%). Faint hydrocarbon odor.
End of Boring at 3.8 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT= Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-13
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/4/2013 2:47:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 11/5/2013 10:25:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 15.7470
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 06.9614
542 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 7.3 ft
<
>
a.
LU
< c
<
w
MATERIAL DESCRIPTION
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
12
CT
RREC13-13-0001
SANDY CLAY: black fine-medium sandy clay with
little gravel (15%). Hydrocarbon odor.
24
CT
RREC13-13-0103
CL
SILTY CLAY: black silty semi-soft clay with trace
fine sand (10%). Hydrocarbon odor.
24
CT
RREC13-13-0305
CL
CLAY: gray semi-soft clay with some organics
(20%). Hydrocarbon and sewage odor.
27
CT
RREC13-13-0507
End of Boring at 7.3 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-14
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/4/2013 2:07:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 11/5/2013 9:55:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 15.6877
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 06.9863
539.1 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 9.75 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-14-0001
24
CT
RREC13-14-0103
24
CT
RREC13-14-0305
CL
CLAY: dark gray - black semi-firm clay with little
rounded-subrounded gravel (10%), little organic
debris (10%), trace fine sand (5%). Strong
hydrocarbon odor.
24
CT
RREC13-14-0507
33
CT
RREC13-14-0710
End of Boring at 9.75 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-15
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/4/2013 1:29:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 11/5/2013 8:55:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 15.5124
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.0950
525.3 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 3.2 ft
<
>
0-
LLl
< c
if) o
<
W
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
O
o
o
X
w
<
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-15-0001
26.4
CT
RREC13-15-0103
CL
CLAY: gray semi-firm clay and organics (25%).
Faint hydrocarbon odor.
CH
CLAY: stiff gray clay with re/orange farving, some
gravel/pebbles (25%)
End of Boring at 3.2 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT= Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-16
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/29/2013 8:39:00 AM
PROJECT NUMBER 62561.15
DATE LOGGED 10/31/2013 4:25:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 15.6167
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.5062
528.5 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 10 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-16-0001
CL
SILTY CLAY: soupy dark gray silty clay, water
visible in core, with little fine sand (15%) and little
asphalt pieces, gravel-sized (15%). Hydrocarbon
odor.
24
CT
RREC13-16-0103
24
CT
RREC13-16-0305
24
CT
RREC13-16-0507
CH
CLAY: stiff gray clay with some angular fine
grave/coarse sand (25%)
24
CT
RREC13-16-0709
12
CT
RREC13-16-0911
11
End of Boring at 10 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-17
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/21/2013 3:21:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 10/31/2013 9:45:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 15.5956
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.3997
530.1 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 9.75 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
11
12
CT
RREC13-17-0001
24
CT
RREC13-17-0103
24
CT
RREC13-17-0305
CL
SILTY CLAY: dark gray silty clay. @9-10":
ketchup packet. @8-10": angular coarse
sand/grave ~40%. @20-22": angular gravel.
@42-44": angular gravel (25%), clay pieces ~1cm,
pebbles ~10%. @56-57": angular gravel 25%.
@64-69": organic twigs 2-3cm long.
24
CT
RREC13-17-0507
24
CT
CT
RREC13-17-0709
RREC13-17-0911
End of Boring at 9.75 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-18
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/29/2013 10:17:00 AM
PROJECT NUMBER 62561.15
DATE LOGGED 10/31/2013 4:00:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 15.5613
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.3893
527.8 ft
LOGGED BY M. Gelinas
<
>
0-
LLl
< c
if) o
ELEVATION
(Sediment Surface)
CORE RECOVERY 10 ft
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
_1
o
w
o
w
MATERIAL DESCRIPTION
12
24
24
24
24
12
CT
RREC13-18-0001
CT
RREC13-18-0103
CL
SILTY CLAY: gray silty soft clay with little organic
debris (15%), trace fine sand (1-5%)
CL
SILTY CLAY: soupy silty clay with some
gravel-sized pieces of asphalt (30%).
Hydrocarbon odor.
CT
RREC13-18-0305
CL
CLAY: dark gray - gray semi-stiff clay with some
gravel (25%), some organic debris (25%).
Hydrocarbon odor.
CT
RREC13-18-0507
CT
RREC13-18-0709
CH
CLAY: gray still clay with red/grayish/blue farving
and gravel/coarse sand (30%).
CT
RREC13-18-0911
11
End of Boring at 10 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-19
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/29/2013 11:04:00 AM
PROJECT NUMBER 62561.15
DATELOGGED 10/31/2013 11:45:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 15.5331
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.2826
532.4 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 0.75 ft
<
>
0-
LLl
< c
if) o
<
W
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
O
o
o
X
w
<
—I
o
w
o
w
MATERIAL DESCRIPTION
CT
RREC13-19-0001
GC
GRAVELLEY CLAY: gray stiff clay with some
pebbles (25%) and some twigs 2-3 cm long
(20%). Hydrocarbon odor.
End of Boring at 0.75 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT= Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-20
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/29/2013 1:29:00 PM
PROJECT NUMBER 62561.15
DATELOGGED 11/1/2013 2:20:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 15.4866
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.2205
525.5 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 5.1 ft
<
>
a.
LU
< c
<
w
MATERIAL DESCRIPTION
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
12
CT
RREC13-20-0001
24
CT
RREC13-20-0103
25
CT
RREC13-20-0305
GC
GRAVELLEY CLAY: gray clay and gravel (30%),
little pebbles (10%).
CL
CLAY: gray semi-soft clay with little angular
coarse sand/fine grave (15%)
End of Boring at 5.1 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-21
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/29/2013 4:05:00 PM
PROJECT NUMBER 62561.15
DATELOGGED 11/1/2013 11:00:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 15.4348
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.4484
528.8 ft
LOGGED BY M. Gelinas
<
>
0-
LU
< c
if) o
ELEVATION
(Sediment Surface)
CORE RECOVERY 10 ft
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
O
O
o
x
w
_1
o
w
o
w
MATERIAL DESCRIPTION
12
24
24
24
24
12
CT
RREC13-21-0001
CT
RREC13-21 -0103
CT
RREC13-21-0305
CT
RREC13-21-0507
CT
RREC13-21-0709
ML
SILT: black silt, VERY soupy in top foot, trace fine
sand (10%). @92-98": gravel-sized pieces of
asphalt. Hydrocarbon odor.
CT
RREC13-21-0911
CH
CLAY: stiff gray clay with red farving, some coarse
sand (20%), some angular gravel (25%)
11
End of Boring at 10 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
BA EAByeering, SEDIMENT BORING RREC13-22
^¦rw Technology, Inc.
PROJECT NAME River Rouqe/Ecorse Shoreline PROJECT NUMBER 62561.15
J LOCATION Ecorse, Ml
DATE COLLECTED 10/29/2013 4:38:00 AM LATITUDE 15 3818
DATE LOGGED 11/1/2013 3:40:00 PM LONGITUDE -83° 07 3237
DRILLING CONTRACTOR Mudpuppy ELEVATION 531 9 fl
DRILLING METHOD Vibracore (Sediment Surface)
LOGGED BY M. Gelinas CORE RECOVERY 10 ft
> DEPTH (ft)
SAMPLE INTERVAL
(inches)
SAMPLE TYPE
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
GRAPHIC LOG
uses CLASS
MATERIAL DESCRIPTION
.C
Q.
0
Q
12
CT
RREC13-22-0001
CL
SILTY CLAY: dark gray-black silty soft clay with
some coarse sand/fine angular grave (20%).
Hydrocarbon odor.
fin
2 -
24
CT
RREC13-22-0103
4 -
24
CT
RREC13-22-0305
6 -
24
CT
RREC13-22-0507
8 -
24
CT
RREC13-22-0709
12
CT
RREC13-22-0911
WMrnk
CL
CLAY: gray semi-stiff clay 04
CL
CLAY: light gray semi-stiff clay , s>e
ML
SILT: black silt , aB
CL
11 -
End of Boring at 10 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT= Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-23
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/30/2013 9:02:00 AM
PROJECT NUMBER 62561.15
DATELOGGED 11/2/2013 11:25:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 15.3300
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.2630
535.1 ft
LOGGED BY M. Gelinas
<
>
0-
LLl
< c
if) o
ELEVATION
(Sediment Surface)
CORE RECOVERY 10 ft
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
12
24
24
24
24
12
CT
RREC13-23-0001
CT
RREC13-23-0103
CT
RREC13-23-0305
CL
SILTY CLAY: dark gray silty soft clay with little
angular gravel (15%), little fine-coarse sand
(15%), trace organics (10%)
CT
RREC13-23-0507
CT
RREC13-23-0709
CT
RREC13-23-0911
11
End of Boring at 10 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-24
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/4/2013 9:56:00 AM
PROJECT NUMBER 62561.15
DATELOGGED 11/4/2013 4:15:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 15.1944
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.3252
523.1 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 3.3 ft
<
>
0-
LLl
< c
if) o
<
W
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
O
o
o
X
w
<
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-24-0001
CL
SILTY CLAY: silty clay and medium sand-gravel
with some organics (20%), some cobbles (15%)
(up to 7x5x3 cm)
28
CT
RREC13-24-0103
CL
CLAY: beige/gray semi-stiff to stiff clay, trace clay
(10%)
CH
CLAY: gray stiff clay with blue tint; yellow/orange
striations/farving, some coarse sand/grave I (20%)
End of Boring at 3.3 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT= Core Tube
PAGE 1 of 1
-------
gA we-"-!* SEDIMENT BORING RREC13-25
^¦rw Technology, Inc.
PROJECT NAME River Rouqe/Ecorse Shoreline PROJECT NUMBER 62561.15
J LOCATION Ecorse, Ml
DATE COLLECTED 11/4/2013 9:04:00 AM LATITUDE 15 1300
DATE LOGGED 11/4/2013 4:00:00 PM LONGITUDE -83° 07 3973
DRILLING CONTRACTOR Mudpuppy ELEVATION 520 5 fl
DRILLING METHOD Vibracore (Sediment Surface)
LOGGED BY M. Gelinas CORE RECOVERY 9.75 ft
> DEPTH (ft)
SAMPLE INTERVAL
(inches)
SAMPLE TYPE
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
GRAPHIC LOG
uses CLASS
MATERIAL DESCRIPTION
.C
Q.
0
Q
12
CT
RREC13-25-0001
1111
CL
SILTY CLAY: dark gray silty soft clay and
fine-medium sand (30%), with some organic
debris (20%), little shell fragments (~1mm) (15%).
Hydrocarbon odor , n
2 -
24
CT
RREC13-25-0103
• o; ^ o;
CL
SILTY CLAY: dark gray silty soft clay with trace
fine-medium sand (10%) , R
SC
CLAYEY SAND: black clayey fine-medium sand
(60%) ,
CL
CLAY: dark gray soft clay 7A
OL
PEAT: dense black organic debris (70%, 1-3 cm) , ?b
1
CL
CLAY: dark gray semi-soft clay with some organic
debris 1-3 cm long (20%)
4 -
24
CT
RREC13-25-0305
6 -
24
CT
RREC13-25-0507
8 -
9 -
10 —
11 -
33
CT
RREC13-25-0710
SC
CLAYEY SAND: black clayey fine-medium sand
(65%) with some orqanic material (20%) / 7,6
ill
CL
CLAY: dark gray soft-semi-soft clay with some
organics (20%)
»»
SC
CLAYEY SAND: black clayey fine-medium sand
(50-60%), with little shell debris (10%) n?
SC
SANDY CLAY: dark gray sandy semi-soft clay
with little organics (15%), trace rounded gravel
(in°/,i j 98
(IU/uJ j
End of Boring at 9.75 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT= Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-26
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/4/2013 8:11:00 AM
PROJECT NUMBER 62561.15
DATE LOGGED 11/4/2013 5:40:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 14.9291
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.6209
520.5 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 7.3 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-26-0001
ML
CLAYEY SILT: dark gray clayey silt, very soupy,
water visible in core; trace gravel (5%). Faint
hydrocarbon odor.
24
CT
RREC13-26-0103
24
CT
RREC13-26-0305
CL
SILTY CLAY: dark gray silty clay with little coarse
sand (15%), trace shell fragments 1-3 mm (10%).
Faint hydrocarbon odor.
27
CT
RREC13-26-0507
End of Boring at 7.3 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-27
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/4/2013 7:34:00 AM
PROJECT NUMBER 62561.15
DATELOGGED 11/4/2013 2:15:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 14.8520
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.7260
532.8 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 9.9 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
o
(/)
o
CO
_l
<
o
_l
o
X
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-28
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/1/2013 5:40:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 11/4/2013 10:20:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 14.7693
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.8988
537.5 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 9.7 ft
<
>
a.
LU
< c
<
w
MATERIAL DESCRIPTION
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
11
12
CT
RREC13-28-0001
CL CLAY: gray semi-soft clay, soupy at top, water
visible in core. Hydrocarbon odor.
SANDY CLAY: black sandy (coarse, 30%) clay.
Hydrocarbon odor.
24
CT
RREC13-28-0103
24
CT
RREC13-28-0305
CL
CLAY: gray to dark gray semi-soft clay with some
organic debris (20%), little coarse sand/fine gravel
(10%). Hydrocarbon odor.
24
CT
RREC13-28-0507
24
CT
CT
RREC13-28-0709
RREC13-28-0911
End of Boring at 9.7 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-29
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/1/2013 5:00:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 11/4/2013 8:05:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 14.6219
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 08.0718
535.8 ft
LOGGED BY M. Gelinas
<
>
0-
LLl
< c
if) o
ELEVATION
(Sediment Surface)
CORE RECOVERY 9.75 ft
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
w
_i
o
w
o
w
MATERIAL DESCRIPTION
11
12
24
24
24
24
CT
RREC13-29-0001
CT
RREC13-29-0103
CT
RREC13-29-0305
CL
SILTY CLAY: dark gray semi soft silty clay with
trace gravel (5%). Strong hydrocarbon odor.
CT
RREC13-29-0507
CT
CT
RREC13-29-0709
RREC13-29-0911
SC
SANDY CLAY: dark gray sandy (fine, 30%) clay.
Hydrocarbon odor.
CL
SILTY CLAY: dark gray silty semi-soft clay.
Hydrocarbon odor.
End of Boring at 9.75 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-30
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/1/2013 4:15:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 11/4/2013 9:45:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 14.5253
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 08.2419
528.6 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 7.25 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
11
12
CT
RREC13-30-0001
24
CT
RREC13-30-0103
CL
SILTY CLAY: gray semi-soft clay and organic
debris (30%). Hydrocarbon odor.
24
CT
RREC13-30-0305
CL
CL
SILTY CLAY: gray semi-soft silty clay and organic
debris (50%). Hydrocarbon odor.
SILTY CLAY: gray semi-soft clay and organic
debris (30%). Hydrocarbon odor.
sc
SANDY CLAY: dark gray sandy (fine, 30%) clay
with some organic and shell debris 1-2 mm (20%)
27
CT
RREC13-30-0507
CL
CLAY: gray semi-soft clay with some organics
(30%). Hydrocarbon odor.
End of Boring at 7.25 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-31
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/30/2013 3:40:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 10/31/2013 2:40:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 14.4205
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 08.4118
543.8 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 7.25 ft
<
>
a.
LU
< c
<
w
MATERIAL DESCRIPTION
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
11
CL
12
CT
RREC13-31-0001
SILTY CLAY: gray silty clay, soupy water visible in
core, some organic matter (30%)
24
CT
RREC13-31 -0103
CL
24
CT
RREC13-31-0305
CLAY: gray semi-soft clay with some organic
material (25%), little gravel (10%)
27
CT
RREC13-31-0507
End of Boring at 7.25 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-32
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/30/2013 2:55:00 PM
PROJECT NUMBER 62561.15
DATELOGGED 11/1/2013 10:40:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 14.3860
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 08.3116
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 4ft
543.8 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
O
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-32-0001
24
CT
RREC13-32-0103
12
CT
RREC13-32-0305
SC
SC
SANDY CLAY: dark gray sandy (fine, 30%) clay
with some silt (25%), some organic debris (25% -
peach pit found or walnut found?). Sour
hydrocarbon odor.
SANDY CLAY: gray sandy (fine, 35-40%) clay
with some rounded-subrounded gravel and
organic debris (20%)
CL
CLAY: dark gray/black clay with wood chunks -
yellow/orange in color, solid but easily shredded
(40%), organic roots 30%. Strong sour odor -
maybe sewage
CH
CLAY: stiff gray clay with reddish striations; little
yellow/orange wood chunks (1 cm in size), little
gravel (15%)
End of Boring at 4 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-33
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/30/2013 4:45:00 PM
PROJECT NUMBER 62561.15
DATELOGGED 11/2/2013 10:15:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 14.4929
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 08.5782
545.1 ft
LOGGED BY M. Gelinas
<
>
0-
LLl
< c
if) o
<
W
ELEVATION
(Sediment Surface)
CORE RECOVERY 10 ft
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-33-0001
CL
SILTY CLAY: dark gray silty soft clay with trace
fine sand (5%). Hydrocarbon odor.
24
24
24
24
12
CT
CT
CT
CT
CT
RREC13-33-0103
CL
CLAY: dark gray semi-soft clay with some
organics (20%). Hydrocarbon odor.
RREC13-33-0305
RREC13-33-0507
CL
CLAY: gray semi-soft clay with some organics
(20%), trace shell pieces <1 cm (5%)
RREC13-33-0709
RREC13-33-0911
CL
CLAY: dark gray semi-firm clay with little white
shell pieces ~1 mm (10%)
11
End of Boring at 10 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
gA we-"-!* SEDIMENT BORING RREC13-34
^¦rw Technology, Inc.
PROJECT NAME River Rouqe/Ecorse Shoreline PROJECT NUMBER 62561.15
J LOCATION Ecorse, Ml
DATE COLLECTED 11/1/2013 3:40:00 PM LATITUDE I**0 11 1103
DATE LOGGED 11/4/2013 8:30:00 AM LONGITUDE -83° 08 6289
DRILLING CONTRACTOR Mud puppy
iv.uupuppy ELEVATION 533 6 ft
DRILLING METHOD Vibracore (Sediment Surface)
LOGGED BY M. Gelinas CORE RECOVERY 9 7 ft
> DEPTH (ft)
SAMPLE INTERVAL
(inches)
SAMPLE TYPE
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
GRAPHIC LOG
uses CLASS
MATERIAL DESCRIPTION
.C
Q.
0
Q
12
CT
RREC13-34-0001
HP
CL
SILTY CLAY: gray silty soft clay with little organic
debris (15%). Hydrocarbon odor
0.8
OL /
PEAT: dense black organic debris (70%, 1-3 cm).
Hydrocarbon odor
08
2 -
24
CT
RREC13-34-0103
CL
,3
«
OL
CL
SILTY CLAY: gray silty soft clay with little organic
debris (15%). Hydrocarbon odor
1.3
PEAT: dense black organic debris (70%, 1-3 cm).
Hydrocarbon odor
SILTY CLAY: gray silty clay with some organics
4 -
24
CT
RREC13-34-0305
Hydrocarbon odor.
45
Si!
CL
SILTY CLAY: dark gray/black silty clay and
organic debris (35-40%), some fine-medium sand
(20%). Hydrocarbon odor.
6 -
24
CT
RREC13-34-0507
Ill
CL
SILTY CLAY: dark gray silty semi-soft clay.
Hydrocarbon odor.
6.8
o ^ u „ ^ V
CL
SILTY CLAY: silty clay and fine-medium sand
(40%), some organics 1-2 cm (twigs) (25%)
8 -
24
CT
RREC13-34-0709
CL ,
7 1
CL /
CL ,
SILTY CLAY: dark gray silty semi-soft clay.
74
75
fl
CL I
CL
SILTY CLAY: silty clay and fine-medium sand
(40%), some organics 1-2 cm (twigs) (25%)
SILTY CLAY: dark gray silty semi-soft clay.
Hydrocarbon odor.
SILTY CLAY: silty clay and fine-medium sand
(40%), some organics 1-2 cm (twigs) (25%)
10 —
11 -
8
CT
RREC13-34-0911
CLAY: gray semi-soft clay
Qfi
sc
SANDY CLAY: dark gray sandy (fine-medium,
30%) semi-soft clay
9.7
End of Boring at 9.7 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT= Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-35
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/30/2013 5:25:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 10/31/2013 8:25:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 14.3934
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 08.6793
529.2 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 4.9 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-35-0001
ML
CL
24
CT
RREC13-35-0103
SC
SILT: black soupy silt, soupy, water visible in core,
with some fine sand (20%), some wood/organic
chips < 5 mm in size (20%). Strong hydrocarbon
odor.
CLAY: dark gray/black soft to semi-soft clay with
little organic debris/wood chunks ~1.5 cm (15%),
one twig 5 cm long, 2 cm diameter. Strong
hydrocarbon odor.
SAND: gray fine-medium grained sand with little
clay (10%), trace rounded gravel (5%). Sewage
odor.
23
CT
RREC13-35-0305
End of Boring at 4.9 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
£ EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-36
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/28/2013 3:33:00 PM
PROJECT NUMBER 62561.15
DATELOGGED 10/31/2013 11:55:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 14.0963
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 08.8892
533.5 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 2.6 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
<3
(/)
O
CO
_i
<
o
_l
o
X
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-37
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/28/2013 4:39:00 AM
PROJECT NUMBER 62561.15
DATE LOGGED 11/1/2013 9:10:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 14.2855
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 08.5958
541.3 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 9.8 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
11
12
CT
RREC13-37-0001
GC
GRAVELLEY CLAY: gray to dark-gray semi-soft
clay and angular gravel (30-40%), trace gastropod
shells (10%), trace fine sand (10%). Slight
hydrocarbon odor.
24
CT
RREC13-37-0103
24
CT
RREC13-37-0305
CL
CLAY: gray semi-hard clay with some organic
debris (20%) 3-4 cm long. @101": white shell
hash.
24
CT
RREC13-37-0507
24
CT
CT
RREC13-37-0709
RREC13-37-0911
End of Boring at 9.8 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-38
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/30/2013 1:40:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 11/2/2013 12:00:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 14.2395
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 08.5045
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 6ft
545.1 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
o
(/)
o
CO
_l
<
o
_l
o
X
-------
gA we-"-!* SEDIMENT BORING RREC13-39
^¦rw Technology, Inc.
PROJECT NAME River Rouqe/Ecorse Shoreline PROJECT NUMBER 62561.15
J LOCATION Ecorse, Ml
DATE COLLECTED 10/30/2013 2:20:00 PM LATITUDE 11 *M97
DATE LOGGED 11/2/2013 9:10:00 AM LONGITUDE -83° 08 3972
DRILLING CONTRACTOR Mudpuppy ELEVATION 544 5 fl
DRILLING METHOD Vibracore (Sediment Surface)
LOGGED BY M. Gelinas CORE RECOVERY 9.75 ft
> DEPTH (ft)
SAMPLE INTERVAL
(inches)
SAMPLE TYPE
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
GRAPHIC LOG
uses CLASS
MATERIAL DESCRIPTION
.C
Q.
0
Q
12
CT
RREC13-39-0001
sc
SANDY CLAY: dark gray sandy (fine-medium,
45%) clay with little organics/shell hash (15%).
Hydrocarbon odor.
1 4
2 -
24
CT
RREC13-39-0103
sc
CLAYEY SAND: gray clayey (40%) fine-medium
sand (fine-medium). @27-30": large cobble
4 -
24
CT
RREC13-39-0305
sc
SANDY CLAY: gray sandy (20%) clay with trace
rounded gravel. @100-101": white shell hash
BR
6 -
24
CT
RREC13-39-0507
8 -
24
CT
RREC13-39-0709
10 —
11 -
9
CT
RREC13-39-0911
^5^
End of Boring at 9.75 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT= Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-40
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/28/2013 4:04:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 11/1/2013 9:25:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 14.1417
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 08.6605
539.2 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 7.4 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
GC
12
CT
RREC13-40-0001
GRAVELLEY CLAY: gray gravelley soft clay with
some organic material/wood pices 2-3 cm (30%)
24
CT
RREC13-40-0103
24
CT
RREC13-40-0305
CL
CLAY: gray semi-hard clay with some organics
(25%)
28.8
CT
RREC13-40-0507
11
End of Boring at 7.4 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-41
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/30/2013 4:13:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 10/31/2013 8:50:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 14.5261
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 08.4540
540 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 9.75 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
11
CL
12
CT
RREC13-41-0001
CLAY: dark gray semi-soft clay wth some organic
material 1-2 cm (20%), trace coarse/fine sand.
Strong hydrocarbon odor.
24
CT
RREC13-41 -0103
24
CT
RREC13-41 -0305
CL
CLAY: gray soft clay with some angular gravel
(25%), little coarse sand (15%). @104-107":
angular cobble 6x6x4 cm in size. Less strong
hydrocarbon odor.
24
CT
RREC13-41-0507
24
CT
CT
RREC13-41-0709
RREC13-41-0911
End of Boring at 9.75 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
£ EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-42
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/4/2013 10:46:00 AM
PROJECT NUMBER 62561.15
DATELOGGED 11/4/2013 3:10:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 15.3669
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.1948
536.4 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 4.25 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
11
12
CT
RREC13-42-0001
24
CT
RREC13-42-0103
15
CT
RREC13-42-0305
CL
CLAY: gray semi-stiff clay with shell fragments up
to 4 cm long
CH
CLAY: stiff gray clay with red/orange
striations/farving
CL
CLAY: black semi-stiff to stiff gray clay, faint
hydrocarbon odor.
CH
CLAY: stiff gray clay with orange/light gray
striations.
End of Boring at 4.25 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-44
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/30/2013 8:25:00 AM
DATELOGGED 11/1/2013 3:20:00 PM
PROJECT NUMBER 62561.15
LOCATION Ecorse, Ml
LATITUDE 42° 15.3855
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.3724
543.5 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 7.3 ft
<
>
0-
LLl
< c
if) o
<
W
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
O
o
o
X
w
<
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-44-0001
24
CT
RREC13-44-0103
CL
24
CT
RREC13-44-0305
SILTY CLAY: black silty soft clay with trace fine
sand (10%) trace angular grave (5%).
Hydrocarbon odor.
28
CT
RREC13-44-0507
End of Boring at 7.3 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT= Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-45
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/29/2013 2:38:00 AM
PROJECT NUMBER 62561.15
DATELOGGED 11/1/2013 2:30:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 15.4340
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.1805
538.2 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 5.3 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-45-0001
24
CT
RREC13-45-0103
28
CT
RREC13-45-0305
ML
GM
SILT: gray to dark gray silt, soupy with some
angular gravel/pebbles (20%), some organic
debris (20%). Hydrocarbon odor.
GRAVELLEY SILT: black silt with 40%
gravel/coarse sand, little gravel-sized pices of
asphalt (10%). Hydrocarbon odor.
CL
CLAY: gray semi-soft clay with some coarse sand
(20%), trace gravel (10%)
End of Boring at 5.3 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-46
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/5/2013 3:32:00 PM
PROJECT NUMBER 62561.15
DATE LOGGED 11/6/2013 9:00:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 16.5942
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 06.8372
537.9 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 8.6 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
11
12
CT
RREC13-46-0001
SILTY CLAY: black silty clay with some gravel
(30%), some pieces of asphalt (20%), soupy,
water visible in core. Sour/sewage odor
SILTY CLAY: black silty soft clay with little
grave/coarse sand (15%), water visible in core.
SP
sc
SILTY SAND: silty medium-coarse sand and
woody debris (35%)
24
CT
RREC13-46-0103
GM
SANDY CLAY: gray clay and medium-coarse
sand (30%). @23": large stick, 4 cm long, 2 cm
diameter
SILTY GRAVEL: subrounded gravel in silt
24
CT
RREC13-46-0305
CL
CLAY: gray semi-stiff clay with some fine sand
(20%)
24
CT
RREC13-46-0507
18
CT
RREC13-46-0710
End of Boring at 8.6 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-47
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 10/30/2013 11:19:00 AM
PROJECT NUMBER 62561.15
DATE LOGGED 10/30/2013 5:00:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 15.6007
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.1160
546.3 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 10 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
O
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-47-0001
24
CT
RREC13-47-0103
24
CT
RREC13-47-0305
CL
SILTY CLAY: dark gray silty clay and organic
material (30%), little wood pieces <1 cm (15%).
Hydrocarbon odor throughout. @89-90": very vine
(1mm) metal shavings, possibly? @110-120":
VERY strong hydrocarbon odor - wood pices
orange/slight sheen
24
CT
RREC13-47-0507
24
CT
RREC13-47-0709
12
CT
RREC13-47-0911
11
End of Boring at 10 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-48
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/5/2013 7:42:00 AM
PROJECT NUMBER 62561.15
DATELOGGED 11/5/2013 3:15:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 15.5722
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.0724
532.9 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 9.75 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
w
_i
o
w
o
w
MATERIAL DESCRIPTION
11
CL
12
CT
RREC13-48-0001
SILTY CLAY: gray silty (40%) soft clay with litle
coarse-medium sand (15%), little gravel (10%),
grace shell fragments <1 cm.
24
CT
RREC13-48-0103
24
CT
RREC13-48-0305
CL
SILTY CLAY: gray silty (30%) soft clay with some
organics (small hair-like roots) (20%), trace wood
and shell debris < 1 cm (1%)
24
CT
RREC13-48-0507
33
CT
RREC13-48-0710
GP-GM
CL
CHARCOAL: charcoal pieces, black in color--
coarse to gravel-sized, angular in 10% gray silt.
CLAY: gray soft clay with little coarse sand (15%)
End of Boring at 9.75 ft.
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-49
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/5/2013 8:19:00 AM
PROJECT NUMBER 62561.15
DATE LOGGED 11/5/2013 4:00:00 PM
LOCATION Ecorse, Ml
LATITUDE 42° 15.6119
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 07.0358
535.2 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 9.75 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
CL
12
CT
RREC13-49-0001
CLAY: dark gray soft clay with some shell
fragments <1 cm (30%), little coarse sand/gravel
(10%), wood pieces 1-2 cm. Hydrocarbon odor
24
CT
RREC13-49-0103
24
CT
RREC13-49-0305
CL
CLAY: dark gray soft clay with trace gravel/asphalt
pieces (5%). Hydrocarbon odor.
24
CT
RREC13-49-0507
33
CT
RREC13-49-0710
End of Boring at 9.75 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
EA Engineering,
Science, and
Technology, Inc.
SEDIMENT BORING RREC13-50
PROJECT NAME River Rouge/Ecorse Shoreline
DATE COLLECTED 11/5/2013 2:53:00 AM
PROJECT NUMBER 62561.15
DATE LOGGED 11/6/2013 8:45:00 AM
LOCATION Ecorse, Ml
LATITUDE 42° 16.3952
DRILLING CONTRACTOR Mud puppy
DRILLING METHOD Vibracore
LONGITUDE -83° 06.5955
520.9 ft
LOGGED BY M. Gelinas
ELEVATION
(Sediment Surface)
CORE RECOVERY 7.1 ft
<
>
a.
LU
< c
<
w
SAMPLE SUBMITTED FOR ANALYSIS
(Sample ID at sample depth)
a
O
o
x
w
—I
o
w
o
w
MATERIAL DESCRIPTION
12
CT
RREC13-50-0001
24
CT
RREC13-50-0103
24
CT
RREC13-50-0305
ML
SANDY CLAYEY SILT: black silt with some
fine-medium sand (20%), some clay (20%), some
wood pieces 2x1 cm and organic debris
(sticks/roots) (20%) little angular asphalt/cement
pieces 5x2x3 cm (15%); shell fragment 5 cm
across. Water visible in core. Hydrocarbon odor.
25
CT
RREC13-50-0507
GC
GRAVELLY SILTY CLAY: gray silty clay and
gravel (30%), large cement/asphalt pieces, large
pices up to 6 cm long. Hydrocarbon odor.
End of Boring at 7.1 ft.
11
NOTES:
Sediment Surface elevation based on IGLD1985
CT = Core Tube
PAGE 1 of 1
-------
Appendix C
Core Photographs
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-01
*''1'wr'T'iH "i 'Wi'^y iii»i»i
RREC13-01-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/02/2013
RREC13-02
A 4. x.A
^iWifWrTy
3 8 I 8 9 ,9,0 9,1 I 9,2 9 3 ii j 95
aBS'1"" 1 -¦' "'
"if" f® I^j.'", 'WK»Hp».^il)|tW>)|
iSwMiHfiM&.yfaj
7(4 i 7i5 76
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/02/2013
RREC13-02-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-03
flW.il.
t pis... e',6, , 6:7 ,
aftjja .lib, iaJP*
-------
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-05
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-06
RREC13-06-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-07
No core photos
RREC13-07-SURF
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-09
-•
lir'lii.ii! hlfrrJuIZ
j-rpy, . •• v^Viv1|W«|'W'fifi
mmmmm .»? »foiLMLiiiiii»afa. j^jRjjaujft>L'
RREC13-09-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-11
No Core Photos
RREC13-11-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-13
PI'pfflWftlB'H'ip J,.
I'll
Aib&A i
WISJ™
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-14
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-14-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-15
RREC13-15-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-16
'¦'S"'1" T"wr "I V «n$
" ni".1 "iVj1 'iT1'1'1 r|^f'i'if§'p|i||fi'iffai|[|i|^||i|i|i|jt
¦?,USkiMaJZ.iJ&a,,.,,s;a.aakJi^
j,.'. t, iSi •,!®i®..¦
"Si I'i'd
•J2 , a
n ' "ifl
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-16-SU RF
-------
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-17
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-17-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-18
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-18-SU RF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-19
RREC13-19-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/01/2013
RREC13-20
RREC13-20-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/01/2013
RREC13-21
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/01/2013
RREC13-21-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/01/2013
RREC13-22
63 , 1^1 6.5 , Bp , 67,
I 3J7 /
"t 'S| w"i1 yrm •11 sr-psp T'sf"™
K,iS5,;,S3 ~ - J. ¦ 1 ,1* mill ilM iffHii —
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/01/2013
RREC13-22-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/02/2013
RREC13-23
fWTWT^r 'ii'"
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/02/2013
RREC13-23-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-24
;|'P|^npnpi|iTO|rppi(t
RREC13-24-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-25
r'^f'v.TO-'.-Tgf'
#«! t'W
I. ,aL mi . inU 11C
a *--MnT1T]iiflililj
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-25-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-26
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-26-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-27
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-27-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-28
§}'•
all hgiiUMudIL
WPPIw?y v.
PjfpiWpl'IJf'IfMl
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-28-SU RF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-29
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-29-SU RF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-30
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-30-SU RF
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-31
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-31 -SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/01/2013
RREC13-32
I J a. j 3.9 , '1,0 I 4,1 I 4,2 , 4 3 ¦¦ 4 4
•*2' V3/ 41 5
wlibllh/inltltltlil
7 2 8 . 2
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/02/2013
RREC13-33
iaa 101 ,ioja ,, ^3,
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/02/2013
RREC13-33-SURF
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-34
V ,I|,|VV» •• i"lp'
»o3 10'4 1 wisi j,io,!e. ... at. 1 lOifl 110y
fev/- .
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-34-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-35
RREC13-35-SURF
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/312013
RREC13-36
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/1/2013
RREC13-37
f '" T-Tsrj^nsi ¦rgrr^i'» '¦ m ^1*81 pyi m1'
3" 35 ' ?a 37 2.S 19 11 4
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/1/2013
RREC13-37-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/02/2013
RREC13-38
RREC13-38-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/02/2013
RREC13-39
u\s
"Yi'ijIW^rn^t 11' | yMi||«iWlW(
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/02/2013
RREC13-39-SU RF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/01/2013
RREC13-40
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/01/2013
RREC13-40-SU RF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-41
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/31/2013
RREC13-41-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/04/2013
RREC13-42
RREC13-42-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/01/2013
RREC13-44
if|> i •iTjTrrirp imfjWt
3 8 39 . At
MiUI
'I'l l I ,¦ I I'll,1'.,,I
fXIi lii
Mliiihi i B3 ^ is-Ib, ,B'7 siJ
ii.i ...ill; .,:,!!. 1(lil .'.hh' nl>k' nhl ' ,.1,1 (|,||| ¦,;. I,.
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/01/2013
RREC13-44-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/01/2013
RREC13-45
RREC13-45-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/06/2013
RREC13-46
VI'I' :i i' I1"' n'l'i'jjjjgl^i'FiiMrrilii'
b 10 111 v2
r.lffl fi-m r»B I Wi I tfcllftuai 1J,SSttLfl&
i Wi I ikiiiillia mhiikiiiiiM iM
V" ' i|o iTi'®1"!]
,^-j •,. u;.
«K- akjjilLhilLtJ&Lt- :I°&&
B5 BL Bl aa \ aa mdM»&
W1
7,0 i t , 7,2 I 713 , TA • 7',-5 1 Z'G, ' 7j7i ' 7j4 1 7i9
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/06/2013
RREC13-46-SURF
-------
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/30/2013
Photographic Record
RREC13-47
EA Engineering, Science,
and Technology, Inc.
-------
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
10/30/2013
RREC13-47-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-48
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-48-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-49
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/05/2013
RREC13-49-SURF
-------
Photographic Record
EA Engineering, Science,
and Technology, Inc.
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/06/2013
RREC13-50
-------
EA Engineering, Science,
and Technology, Inc.
Photographic Record
River Rouge/Ecorse Shoreline
Grosse lie, Michigan
11/06/2013
RREC13-50-SU RF
-------
Appendix D
Particle Size Charts
-------
Particle Size of Soils by ASTM D422
Sample ID:
Lab ID:"
RREC13-19-SURF
200-19207-F-1
Percent Solids:
Specific Gravity:
69.0%
2.650
Date Received:
Start Date:
End Date:
10/31/2013
11/20/2013
11/23/2013
Shape (> #10): Angular
Non-soil material: Shell; Plant
Hardness (> #10): Hard
£
C
8
\
\
\
\
£
0!
C
M-
a
c
09
o.
—
100
90
80
70
60
50
40
30
20
10
100000
10000
1000 100
Particle Size, microns (um)
10
Sieve
size
Particle
size, um
Percent
finer
Incremental
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
79.0
21.0
#4
4750
67.0
12.0
#10
2000
53.1
13.9
#20
850
46.5
6.6
#40
425
40.7
5.8
#60
250
31.7
9.0
#80
180
27.5
4.2
#100
150
25.6
1.9
#200
75
22.3
3.3
Hyd1
30.7
21.4
0.9
Hyd2
20
18.3
3.1
Hyd3
12.2
12.1
6.2
Hyd4
9
9.7
2.4
Hyd5
6.1
8.4
1.2
Hyd6
3.2
7.0
1.4
Hyd7
1.3
5.8
1.2
Soil
Classification
Percent of
sample
Gravel
33.0
Sand
44.7
Coarse Sand
13.9
Medium Sand
12.4
Fine Sand
18.4
Silt
13.9
Clay
8.4
TestAmerica Burlington
Page 295 of 352
200-19207-F-1 lfa/23/S(/ll 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-45-SURF Percent Solids: 41.8% Start Date: 11/20/2013
Lab ID: 200-19207-F-2 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (>#10): NA Non-soil material: Shell; Plant; Wool
Hardness (> #10): NA
£
C
8
Or
^
\
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
99.8
0.2
#4
4750
99.0
0.8
#10
2000
98.0
1.0
#20
850
97.4
0.6
#40
425
96.5
0.9
#60
250
91.9
4.6
#80
180
89.6
2.3
#100
150
87.7
1.9
#200
75
78.1
9.6
Hyd1
29.3
50.2
27.9
Hyd2
19.4
41.8
8.4
Hyd3
11.7
32.2
9.6
Hyd4
8.4
27.3
4.9
Hyd5
6.1
23.7
3.6
Hyd6
3.2
17.3
6.4
Hyd7
1.3
11.3
6.0
Soil
Classification
Percent of
sample
Gravel
1.0
Sand
20.9
Coarse Sand
1.0
Medium Sand
1.5
Fine Sand
18.4
Silt
54.4
Clay
23.7
TestAmerica Burlington
Page 296 of 352
200-19207-F-2 lf4V&3/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-22-SURF Percent Solids: 40.4% Start Date: 11/20/2013
Lab ID: 200-19207-F-3 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (>#10): NA Non-soil material: Shell
Hardness (>#10): NA
£
C
8
—
—
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
99.9
0.1
#20
850
99.5
0.4
#40
425
98.9
0.6
#60
250
97.6
1.3
#80
180
96.5
1.1
#100
150
95.5
1.0
#200
75
91.1
4.4
Hyd1
27.2
69.8
21.3
Hyd2
18.8
53.6
16.2
Hyd3
11.6
38.8
14.8
Hyd4
8.3
32.0
6.8
Hyd5
6.2
26.6
5.4
Hyd6
3.2
20.7
5.9
Hyd7
1.3
14.0
6.7
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
8.9
Coarse Sand
0.1
Medium Sand
1.0
Fine Sand
7.8
Silt
64.5
Clay
26.6
TestAmerica Burlington
Page 297 of 352
200-19207-F-3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-21-SURF Percent Solids: 31.3% Start Date: 11/20/2013
Lab ID: 200-19207-F-4 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (>#10): NA Non-soil material: Wood
Hardness (>#10): NA
OppO-
-0—
-0—
^—
-0=
=0=0——
\
£
s
£
\
0!
C
t
M-
s
a
c
09
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
size
Particle
size, um
Percent
finer
Incremental
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
100.0
0.0
#20
850
99.9
0.1
#40
425
99.9
0.0
#60
250
99.6
0.3
#80
180
99.6
0.0
#100
150
99.6
0.0
#200
75
99.3
0.3
Hyd1
25.9
97.1
2.2
Hyd2
17.5
83.6
13.5
Hyd3
11.1
60.0
23.6
Hyd4
8.1
46.6
13.4
Hyd5
6.1
37.9
8.7
Hyd6
3
25.8
12.1
Hyd7
1.3
17.4
8.4
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
0.7
Coarse Sand
0.0
Medium Sand
0.1
Fine Sand
0.6
Silt
61.4
Clay
37.9
TestAmerica Burlington
Page 298 of 352
200-19207-F-4 li^3/§
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-20-SURF Percent Solids: 68.1% Start Date: 11/20/2013
Lab ID: 200-19207-F-5 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (> #10): Angular Non-soil material: Plant; Wood
Hardness (> #10): Hard
£
C
8
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
97.2
2.8
#4
4750
89.1
8.1
#10
2000
79.2
9.9
#20
850
70.5
8.7
#40
425
63.5
7.0
#60
250
56.6
6.9
#80
180
53.8
2.8
#100
150
52.3
1.5
#200
75
48.1
4.2
Hyd1
27.9
40.1
8.0
Hyd2
18.3
36.0
4.1
Hyd3
11.1
29.4
6.6
Hyd4
7.9
25.1
4.3
Hyd5
5.9
22.6
2.5
Hyd6
3
16.7
5.9
Hyd7
1.3
12.6
4.1
Soil
Classification
Percent of
sample
Gravel
10.9
Sand
41.0
Coarse Sand
9.9
Medium Sand
15.7
Fine Sand
15.4
Silt
25.5
Clay
22.6
TestAmerica Burlington
Page 299 of 352
200-19207-F-5 lf4V&3/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-16-SURF Percent Solids: 38.4% Start Date: 11/20/2013
Lab ID: 200-19207-F-6 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (> #10): Subangular Non-soil material: NA
Hardness (> #10): Hard
£
C
8
o
0—
-0—
—
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
size
Particle
size, um
Percent
finer
Incremental
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
99.8
0.2
#20
850
99.7
0.1
#40
425
99.7
0.0
#60
250
99.4
0.3
#80
180
99.3
0.1
#100
150
99.2
0.1
#200
75
97.4
1.8
Hyd1
27.4
84.2
13.2
Hyd2
18.2
74.3
9.9
Hyd3
11.3
56.0
18.3
Hyd4
8.3
46.0
10.0
Hyd5
5.9
39.1
6.9
Hyd6
3
28.8
10.3
Hyd7
1.3
18.8
10.0
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
2.6
Coarse Sand
0.2
Medium Sand
0.1
Fine Sand
2.3
Silt
58.3
Clay
39.1
TestAmerica Burlington
Page 300 of 352
200-19207-F-6 lf4V&3/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-17-SURF Percent Solids: 38.2% Start Date: 11/20/2013
Lab ID: 200-19207-F-7 Specific Gravity: 2.650 End Date: 11/23/2013
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
100.0
0.0
#20
850
99.9
0.1
#40
425
99.8
0.1
#60
250
99.2
0.6
#80
180
98.5
0.7
#100
150
97.9
0.6
#200
75
94.8
3.1
Hyd1
26.8
74.4
20.4
Hyd2
18.3
60.6
13.8
Hyd3
10.7
57.8
2.8
Hyd4
8.3
37.0
20.8
Hyd5
6.2
31.2
5.8
Hyd6
3.1
24.0
7.2
Hyd7
1.3
15.7
8.3
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
5.2
Coarse Sand
0.0
Medium Sand
0.2
Fine Sand
5.0
Silt
63.6
Clay
31.2
TestAmerica Burlington
Page 301 of 352
200-19207-F-7 lf4V&3/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-18-SURF Percent Solids: 40.2% Start Date: 11/20/2013
Lab ID: 200-19207-F-8 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (> #10): Angular Non-soil material: Shell; Plant
Hardness (> #10): Hard
£
C
8
—
—
-0
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
size
Particle
size, um
Percent
finer
Incremental
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
99.9
0.1
#20
850
99.7
0.2
#40
425
99.6
0.1
#60
250
98.6
1.0
#80
180
97.7
0.9
#100
150
96.9
0.8
#200
75
92.2
4.7
Hyd1
28.2
67.8
24.4
Hyd2
18.8
57.7
10.1
Hyd3
11.6
42.1
15.6
Hyd4
8.5
33.5
8.6
Hyd5
6
27.8
5.7
Hyd6
3.2
20.4
7.4
Hyd7
1.3
13.3
7.1
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
7.8
Coarse Sand
0.1
Medium Sand
0.3
Fine Sand
7.4
Silt
64.4
Clay
27.8
TestAmerica Burlington
Page 302 of 352
200-19207-F-8 lf4V&3/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-36-SURF Percent Solids: 19.5% Start Date: 11/20/2013
Lab ID: 200-19207-F-9 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (>#10): NA Non-soil material: Plant; Wood
Hardness (> #10): NA
£
\
\
s
V
s
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
95.9
4.1
#10
2000
89.7
6.2
#20
850
89.4
0.3
#40
425
88.4
1.0
#60
250
86.7
1.7
#80
180
85.3
1.4
#100
150
83.2
2.1
#200
75
76.4
6.8
Hyd1
33.1
50.3
26.1
Hyd2
21.3
43.6
6.7
Hyd3
12.5
34.7
8.9
Hyd4
8.8
28.0
6.7
Hyd5
6.6
21.3
6.7
Hyd6
3.3
16.4
4.9
Hyd7
1.4
9.7
6.7
Soil
Classification
Percent of
sample
Gravel
4.1
Sand
19.5
Coarse Sand
6.2
Medium Sand
1.3
Fine Sand
12.0
Silt
55.1
Clay
21.3
TestAmerica Burlington
Page 303 of 352
200-19207-F-9 lf4V&3/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-37-SURF Percent Solids: 54.2% Start Date: 11/20/2013
Lab ID: 200-19207-F-10 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (>#10): NA Non-soil material: Shell; Plant
Hardness (> #10): NA
£
C
8
0—
-o—
\
\
\
£
\
0!
C
\
M-
\
a
\
c
09
o.
\
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
99.7
0.3
#20
850
99.3
0.4
#40
425
99.0
0.3
#60
250
97.0
2.0
#80
180
95.3
1.7
#100
150
93.3
2.0
#200
75
64.5
28.8
Hyd1
33.4
19.2
45.3
Hyd2
21.6
15.3
3.9
Hyd3
12.8
9.4
5.9
Hyd4
9.2
7.5
2.0
Hyd5
6.6
5.4
2.1
Hyd6
3.2
5.0
0.3
Hyd7
1.4
4.1
1.0
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
35.5
Coarse Sand
0.3
Medium Sand
0.7
Fine Sand
34.5
Silt
59.1
Clay
5.4
TestAmerica Burlington
Page 304 of 352
200-19207-F-10 lf4V&3/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-40-SURF Percent Solids: 63.5% Start Date: 11/20/2013
Lab ID: 200-19207-F-11 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (> #10): Angular Non-soil material: Shell; Plant
Hardness (> #10): Hard
£
C
8
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0
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0
£
\
0!
C
\
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\
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c
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\
\
\
s.
\
0-
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
99.1
0.9
#10
2000
98.4
0.7
#20
850
98.0
0.4
#40
425
96.7
1.3
#60
250
93.1
3.6
#80
180
88.8
4.3
#100
150
83.5
5.3
#200
75
37.8
45.7
Hyd1
34.5
9.4
28.4
Hyd2
22.1
7.3
2.1
Hyd3
13
5.3
2.1
Hyd4
9.2
4.6
0.7
Hyd5
6.7
3.8
0.8
Hyd6
3.2
3.6
0.2
Hyd7
1.4
2.2
1.4
Soil
Classification
Percent of
sample
Gravel
0.9
Sand
61.3
Coarse Sand
0.7
Medium Sand
1.7
Fine Sand
58.9
Silt
34.0
Clay
3.8
TestAmerica Burlington
Page 305 of 352
200-19207-F-11 lill/^/§
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-01-SURF Percent Solids: 56.6% Start Date: 11/20/2013
Lab ID: 200-19207-F-12 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (> #10): Angular Non-soil material: Shell; Wood
Hardness (> #10): Hard
£
C
8
£
0!
C
M-
a
c
09
o.
~~-o
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
96.9
3.1
#4
4750
87.6
9.3
#10
2000
76.9
10.7
#20
850
71.5
5.4
#40
425
68.7
2.8
#60
250
59.4
9.3
#80
180
55.0
4.4
#100
150
52.4
2.6
#200
75
46.2
6.2
Hyd1
29.7
33.4
12.8
Hyd2
19
31.7
1.7
Hyd3
11.5
25.0
6.7
Hyd4
8.5
21.6
3.4
Hyd5
6.1
18.3
3.3
Hyd6
3.1
12.9
5.4
Hyd7
1.3
8.6
4.3
Soil
Classification
Percent of
sample
Gravel
12.4
Sand
41.4
Coarse Sand
10.7
Medium Sand
8.2
Fine Sand
22.5
Silt
27.9
Clay
18.3
TestAmerica Burlington
Page 306 of 352
200-19207-F-12 lf4V&3/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-02-SURF Percent Solids: 66.5% Start Date: 11/20/2013
Lab ID: 200-19207-F-13 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (> #10): Subangular Non-soil material: Shell
Hardness (> #10): Hard
£
C
8
i
V
\
\
£
\
0!
C
\
M-
\
a
\
c
09
o.
\
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
98.5
1.5
#10
2000
97.5
1.0
#20
850
95.8
1.7
#40
425
89.6
6.2
#60
250
76.7
12.9
#80
180
64.0
12.7
#100
150
52.3
11.7
#200
75
19.2
33.1
Hyd1
34.1
10.1
9.1
Hyd2
21.8
8.8
1.3
Hyd3
12.7
7.5
1.3
Hyd4
9.2
6.2
1.3
Hyd5
6.3
4.9
1.3
Hyd6
3.2
4.7
0.2
Hyd7
1.4
3.3
1.4
Soil
Classification
Percent of
sample
Gravel
1.5
Sand
79.3
Coarse Sand
1.0
Medium Sand
7.9
Fine Sand
70.4
Silt
14.3
Clay
4.9
TestAmerica Burlington
Page 307 of 352
200-19207-F-13 lf4V&3/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-23-SURF Percent Solids: 42.8% Start Date: 11/20/2013
Lab ID: 200-19207-F-14 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (> #10): Subangular Non-soil material: Plant
Hardness (> #10): Hard
£
C
8
\
\
s
s.
\
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
99.7
0.3
#20
850
99.3
0.4
#40
425
98.8
0.5
#60
250
97.2
1.6
#80
180
96.3
0.9
#100
150
95.4
0.9
#200
75
87.5
7.9
Hyd1
29.7
54.2
33.3
Hyd2
19.5
46.0
8.2
Hyd3
11.7
36.4
9.6
Hyd4
8.4
29.6
6.8
Hyd5
6.1
26.9
2.7
Hyd6
3.2
19.6
7.3
Hyd7
1.3
13.9
5.7
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
12.5
Coarse Sand
0.3
Medium Sand
0.9
Fine Sand
11.3
Silt
60.6
Clay
26.9
TestAmerica Burlington
Page 308 of 352
200-19207-F-14 lf4V&3/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-44-SURF Percent Solids: 38.5% Start Date: 11/20/2013
Lab ID: 200-19207-G-15 Specific Gravity: 2.650 End Date: 11/23/2013
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
100.0
0.0
#20
850
99.8
0.2
#40
425
99.7
0.1
#60
250
99.2
0.5
#80
180
98.7
0.5
#100
150
98.1
0.6
#200
75
94.2
3.9
Hyd1
28.3
64.6
29.6
Hyd2
19
52.2
12.4
Hyd3
11.8
35.5
16.7
Hyd4
8.4
30.0
5.5
Hyd5
6.3
24.2
5.8
Hyd6
3.2
18.5
5.7
Hyd7
1.3
12.7
5.8
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
5.8
Coarse Sand
0.0
Medium Sand
0.3
Fine Sand
5.5
Silt
70.0
Clay
24.2
TestAmerica Burlington
Page 309 of 352
200-19207-G-15 1 iUy^8/9o^iS 013
-------
Particle Size of Soils by ASTM D422
Date Received: 10/31/2013
Sample ID: RREC13-47-SURF Percent Solids: 36.8% Start Date: 11/20/2013
Lab ID: 200-19207-F-16 Specific Gravity: 2.650 End Date: 11/23/2013
Shape (>#10): NA Non-soil material: Plant
Hardness (>#10): NA
£
C
8
=o
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
size
Particle
size, um
Percent
finer
Incremental
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
99.9
0.1
#20
850
99.6
0.3
#40
425
99.5
0.1
#60
250
98.8
0.7
#80
180
98.4
0.4
#100
150
98.1
0.3
#200
75
94.7
3.4
Hyd1
27.9
71.2
23.5
Hyd2
19.3
52.2
19.0
Hyd3
11.7
40.5
11.7
Hyd4
8.4
31.7
8.8
Hyd5
6.3
25.6
6.1
Hyd6
3
19.5
6.1
Hyd7
1.3
13.4
6.1
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
5.3
Coarse Sand
0.1
Medium Sand
0.4
Fine Sand
4.8
Silt
69.1
Clay
25.6
TestAmerica Burlington
Page 310 of 352
200-19207-F-16 lf4V&3/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/1/2013
Sample ID: RREC13-31-SURF Percent Solids: 40.8% Start Date: 11/21/2013
Lab ID: 200-19250-F-7 Specific Gravity: 2.650 End Date: 11/25/2013
Shape (>#10): NA Non-soil material: Shell; Plant
Hardness (> #10): NA
£
C
8
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0—
-o—
>=
£
0!
C
M-
a
c
09
o.
V
\
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
99.4
0.6
#20
850
98.7
0.7
#40
425
98.1
0.6
#60
250
94.9
3.2
#80
180
90.6
4.3
#100
150
85.9
4.7
#200
75
75.3
10.6
Hyd1
32.2
51.1
24.2
Hyd2
20.9
42.1
9.0
Hyd3
12.5
29.6
12.5
Hyd4
9.1
20.6
9.0
Hyd5
6.6
15.2
5.4
Hyd6
3.2
11.4
3.8
Hyd7
1.4
9.6
1.8
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
24.7
Coarse Sand
0.6
Medium Sand
1.3
Fine Sand
22.8
Silt
60.1
Clay
15.2
TestAmerica Burlington
Page 208 of 239
200-19250-F-7 l?l/^S£(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/1/2013
Sample ID: RREC13-32-SURF Percent Solids: 70.9% Start Date: 11/21/2013
Lab ID: 200-19250-F-8 Specific Gravity: 2.650 End Date: 11/25/2013
Shape (> #10): Angular Non-soil material: Plant; Shell
Hardness (> #10): Hard
£
C
8
o
0—
-0—
0-
£
0!
C
M-
a
c
09
o.
V
—o
0
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
99.9
0.1
#10
2000
99.5
0.4
#20
850
97.3
2.2
#40
425
91.1
6.2
#60
250
81.8
9.3
#80
180
65.4
16.4
#100
150
45.7
19.7
#200
75
15.7
30.0
Hyd1
35.3
8.2
7.5
Hyd2
22.6
6.6
1.6
Hyd3
13.1
5.9
0.8
Hyd4
9.4
3.5
2.3
Hyd5
6.7
3.5
0.0
Hyd6
3.2
2.6
0.9
Hyd7
1.4
2.6
0.0
Soil
Classification
Percent of
sample
Gravel
0.1
Sand
84.2
Coarse Sand
0.4
Medium Sand
8.4
Fine Sand
75.4
Silt
12.2
Clay
3.5
TestAmerica Burlington
Page 209 of 239
200-19250-F-8 l?l/^S£(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/1/2013
Sample ID: RREC13-33-SURF Percent Solids: 41.5% Start Date: 11/21/2013
Lab ID: 200-19250-F-9 Specific Gravity: 2.650 End Date: 11/25/2013
Shape (>#10): NA Non-soil material: Plant; Shell
Hardness (> #10): NA
£
TT
>—
0—
-o—
0
>
-o
-<
\
\
1
\
\
\
s
\
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
99.7
0.3
#10
2000
99.4
0.3
#20
850
99.2
0.2
#40
425
99.1
0.1
#60
250
98.3
0.8
#80
180
97.8
0.5
#100
150
97.3
0.5
#200
75
93.4
3.9
Hyd1
30.7
48.0
45.4
Hyd2
20.4
37.5
10.5
Hyd3
12.4
24.3
13.2
Hyd4
9.1
19.1
5.2
Hyd5
6.6
13.8
5.3
Hyd6
3.2
11.0
2.8
Hyd7
1.4
8.3
2.7
Soil
Classification
Percent of
sample
Gravel
0.3
Sand
6.3
Coarse Sand
0.3
Medium Sand
0.3
Fine Sand
5.7
Silt
79.6
Clay
13.8
TestAmerica Burlington
Page 210 of 239
200-19250-F-9 l?l/^S£(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/1/2013
Sample ID: RREC13-35-SURF Percent Solids: 72.1% Start Date: 11/21/2013
Lab ID: 200-19250-F-10 Specific Gravity: 2.650 End Date: 11/25/2013
Shape (> #10): Angular Non-soil material: Shell
Hardness (> #10): Hard
£
C
8
\
\
\
\
\
\
£
0!
C
M-
a
c
09
o.
0
-o-
0
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
60.7
39.3
#4
4750
55.2
5.5
#10
2000
52.2
3.0
#20
850
50.6
1.6
#40
425
48.5
2.1
#60
250
41.6
6.9
#80
180
31.8
9.8
#100
150
25.2
6.6
#200
75
12.8
12.4
Hyd1
34.7
8.6
4.2
Hyd2
22.3
6.8
1.8
Hyd3
13
5.7
1.1
Hyd4
9.4
4.5
1.2
Hyd5
6.4
3.9
0.6
Hyd6
3.3
2.6
1.3
Hyd7
1.4
2.6
0.0
Soil
Classification
Percent of
sample
Gravel
44.8
Sand
42.4
Coarse Sand
3.0
Medium Sand
3.7
Fine Sand
35.7
Silt
8.9
Clay
3.9
TestAmerica Burlington
Page 211 of 239
200-19250-F-10 l?l/2@/2(/ll013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/1/2013
Sample ID: RREC13-38-SURF Percent Solids: 68.6% Start Date: 11/21/2013
Lab ID: 200-19250-F-11 Specific Gravity: 2.650 End Date: 11/25/2013
Shape (> #10): Angular Non-soil material: Shell
Hardness (> #10): Hard
£
C
8
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—<
>
£
0!
C
\
M-
a
\
c
09
o.
0
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
99.6
0.4
#20
850
99.2
0.4
#40
425
99.0
0.2
#60
250
96.2
2.8
#80
180
90.3
5.9
#100
150
77.0
13.3
#200
75
32.7
44.3
Hyd1
34.7
12.2
20.5
Hyd2
22.4
8.8
3.4
Hyd3
13.1
6.3
2.5
Hyd4
9.2
4.6
1.7
Hyd5
6.6
3.8
0.8
Hyd6
3.4
2.0
1.8
Hyd7
1.4
2.0
0.0
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
67.3
Coarse Sand
0.4
Medium Sand
0.6
Fine Sand
66.3
Silt
28.9
Clay
3.8
TestAmerica Burlington
Page 212 of 239
200-19250-F-11 lflU*8/a
-------
Particle Size of Soils by ASTM D422
Date Received: 11/1/2013
Sample ID: RREC13-39-SURF Percent Solids: 66.3% Start Date: 11/21/2013
Lab ID: 200-19250-F-13 Specific Gravity: 2.650 End Date: 11/25/2013
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
100.0
0.0
#20
850
99.3
0.7
#40
425
96.9
2.4
#60
250
90.9
6.0
#80
180
83.3
7.6
#100
150
72.0
11.3
#200
75
28.4
43.6
Hyd1
35
10.9
17.5
Hyd2
22.4
9.2
1.7
Hyd3
13
7.4
1.7
Hyd4
9.1
5.7
1.8
Hyd5
6.7
4.8
0.9
Hyd6
3.4
2.9
1.9
Hyd7
1.4
2.9
0.0
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
71.6
Coarse Sand
0.0
Medium Sand
3.1
Fine Sand
68.5
Silt
23.6
Clay
4.8
TestAmerica Burlington
Page 213 of 239
200-19250-F-13 l?l/2@/2(/ll013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/1/2013
Sample ID: RREC13-41-SURF Percent Solids: 63.7% Start Date: 11/21/2013
Lab ID: 200-19250-F-14 Specific Gravity: 2.650 End Date: 11/25/2013
Shape (>#10): Round Non-soil material: NA
Hardness (> #10): Hard
£
C
8
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
93.1
6.9
#10
2000
76.8
16.3
#20
850
66.2
10.6
#40
425
64.0
2.2
#60
250
54.3
9.7
#80
180
53.5
0.8
#100
150
53.4
0.1
#200
75
52.7
0.7
Hyd1
28.5
40.2
12.5
Hyd2
18.8
35.2
5.0
Hyd3
11.5
27.5
7.7
Hyd4
8.3
22.4
5.1
Hyd5
6.2
18.2
4.2
Hyd6
3.1
10.4
7.8
Hyd7
1.4
6.2
4.2
Soil
Classification
Percent of
sample
Gravel
6.9
Sand
40.4
Coarse Sand
16.3
Medium Sand
12.8
Fine Sand
11.3
Silt
34.5
Clay
18.2
TestAmerica Burlington
Page 214 of 239
200-19250-F-14 l?l/2@/2(/ll 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/5/2013
Sample ID: RREC13-28-SURF Percent Solids: 64.3% Start Date: 11/25/2013
Lab ID: 200-19294-F-1 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): angular Non-soil material: plant, shell
Hardness (> #10): hard
£
C
8
—<
i
£
0!
C
\
M-
\
a
\
y
c
09
o.
\
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
99.0
1.0
#10
2000
98.5
0.5
#20
850
97.9
0.6
#40
425
95.9
2.0
#60
250
84.2
11.7
#80
180
74.6
9.6
#100
150
69.9
4.7
#200
75
52.4
17.5
Hyd1
32.7
23.1
29.3
Hyd2
21.4
17.6
5.5
Hyd3
12.7
12.2
5.4
Hyd4
9.1
10.3
1.9
Hyd5
6.5
9.4
0.9
Hyd6
3.2
6.7
2.7
Hyd7
1.3
5.8
0.9
Soil
Classification
Percent of
sample
Gravel
1.0
Sand
46.6
Coarse Sand
0.5
Medium Sand
2.6
Fine Sand
43.5
Silt
43.0
Clay
9.4
TestAmerica Burlington
Page 205 of 224
200-19294-F-1 12|i&&/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/5/2013
Sample ID: RREC13-29-SURF Percent Solids: 57.6% Start Date: 11/25/2013
Lab ID: 200-19294-F-2 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): jia Non-soil material: na
Hardness (> #10): na
£
C
8
0—
-o—
-o
\
\
\
\
£
\
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
100.0
0.0
#20
850
99.4
0.6
#40
425
99.1
0.3
#60
250
98.6
0.5
#80
180
97.5
1.1
#100
150
95.9
1.6
#200
75
81.6
14.3
Hyd1
32.2
40.0
41.6
Hyd2
20.9
32.9
7.1
Hyd3
12.4
25.9
7.0
Hyd4
8.9
21.6
4.3
Hyd5
6.5
18.8
2.8
Hyd6
3.1
13.2
5.6
Hyd7
1.3
10.1
3.1
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
18.4
Coarse Sand
0.0
Medium Sand
0.9
Fine Sand
17.5
Silt
62.8
Clay
18.8
TestAmerica Burlington
Page 206 of 224
200-19294-F-2 12|i&&/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/5/2013
Sample ID: RREC13-30-SURF Percent Solids: 53.2% Start Date: 11/25/2013
Lab ID: 200-19294-F-3 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): subangular Non-soil material: plant, shell
Hardness (> #10): hard
£
C
8
o
«—
—0—
0
—
s
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
size
Particle
size, um
Percent
finer
Incremental
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
99.5
0.5
#10
2000
98.0
1.5
#20
850
96.5
1.5
#40
425
93.8
2.7
#60
250
89.2
4.6
#80
180
85.1
4.1
#100
150
79.9
5.2
#200
75
55.6
24.3
Hyd1
32.6
41.1
14.5
Hyd2
21.1
34.8
6.3
Hyd3
12.4
30.1
4.7
Hyd4
9
27.0
3.1
Hyd5
6.4
22.3
4.7
Hyd6
3.2
16.1
6.2
Hyd7
1.3
11.2
4.9
Soil
Classification
Percent of
sample
Gravel
0.5
Sand
43.9
Coarse Sand
1.5
Medium Sand
4.2
Fine Sand
38.2
Silt
33.3
Clay
22.3
TestAmerica Burlington
Page 207 of 224
200-19294-F-3 12|i&&/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/5/2013
Sample ID: RREC13-34-SURF Percent Solids: 49.5% Start Date: 11/25/2013
Lab ID: 200-19295-F-1 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): angular Non-soil material: plant, shell
Hardness (> #10): hard
£
C
8
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
size
Particle
size, um
Percent
finer
Incremental
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
98.8
1.2
#10
2000
94.0
4.8
#20
850
86.5
7.5
#40
425
80.0
6.5
#60
250
72.7
7.3
#80
180
68.7
4.0
#100
150
66.9
1.8
#200
75
63.5
3.4
Hyd1
32.4
51.3
12.2
Hyd2
20.8
45.7
5.6
Hyd3
12.4
36.3
9.4
Hyd4
9
30.6
5.7
Hyd5
6.2
25.0
5.6
Hyd6
3.2
17.2
7.8
Hyd7
1.4
11.6
5.6
Soil
Classification
Percent of
sample
Gravel
1.2
Sand
35.3
Coarse Sand
4.8
Medium Sand
14.0
Fine Sand
16.5
Silt
38.5
Clay
25.0
TestAmerica Burlington
Page 178 of 192
200-19295-F-1 1013
-------
Particle Size of Soils by ASTM D422
Sample ID:
Lab ID:"
RREC13-24-SURF
200-19297-F-19
Percent Solids:
Specific Gravity:
82.0%
2.650
Date Received:
Start Date:
End Date:
11/5/2013
11/25/2013
12/2/2013
Shape (> #10): subangular
Non-soil material: shell
Hardness (> #10): hard
\
£
s
£
0!
C
M-
a
c
09
V
—0-
—
n—
—o
100
90
80
70
60
50
40
30
20
10
100000
10000
1000 100
Particle Size, microns (um)
10
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
91.8
8.2
3/8 inch
9500
85.9
5.9
#4
4750
71.9
14.0
#10
2000
55.6
16.3
#20
850
49.1
6.5
#40
425
44.7
4.4
#60
250
33.0
11.7
#80
180
22.6
10.4
#100
150
17.6
5.0
#200
75
10.6
7.0
Hyd1
35.9
6.5
4.1
Hyd2
22.7
6.5
0.0
Hyd3
13.2
5.6
0.9
Hyd4
9.2
4.7
0.9
Hyd5
6.6
3.8
0.9
Hyd6
3.3
3.0
0.9
Hyd7
1.4
1.9
1.0
Soil
Classification
Percent of
sample
Gravel
28.1
Sand
61.3
Coarse Sand
16.3
Medium Sand
10.9
Fine Sand
34.1
Silt
6.8
Clay
3.8
TestAmerica Burlington
Page 156 of 172
200-19297-F-19 12|M/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/5/2013
Sample ID: RREC13-25-SURF Percent Solids: 73.5% Start Date: 11/25/2013
Lab ID: 200-19297-F-20 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): angular Non-soil material: shell
Hardness (> #10): hard
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
98.4
1.6
#4
4750
95.1
3.3
#10
2000
93.8
1.3
#20
850
92.6
1.2
#40
425
88.5
4.1
#60
250
70.0
18.5
#80
180
44.7
25.3
#100
150
29.4
15.3
#200
75
6.1
23.3
Hyd1
36.2
2.9
3.2
Hyd2
22.9
2.9
0.0
Hyd3
13.3
2.3
0.5
Hyd4
9.3
1.8
0.5
Hyd5
6.8
1.3
0.5
Hyd6
3.4
0.7
0.5
Hyd7
1.4
0.6
0.1
Soil
Classification
Percent of
sample
Gravel
4.9
Sand
89.0
Coarse Sand
1.3
Medium Sand
5.3
Fine Sand
82.4
Silt
4.8
Clay
1.3
TestAmerica Burlington
Page 157 of 172
200-19297-F-20 12|M/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/5/2013
Sample ID: RREC13-26-SURF Percent Solids: 71.5% Start Date: 11/25/2013
Lab ID: 200-19299-F-1 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): angular Non-soil material: plant, shell
Hardness (> #10): hard
£
C
8
£
0!
C
M-
a
s
c
09
o.
0
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
94.9
5.1
#4
4750
86.7
8.2
#10
2000
79.9
6.8
#20
850
77.2
2.7
#40
425
74.2
3.0
#60
250
69.2
5.0
#80
180
63.6
5.6
#100
150
56.7
6.9
#200
75
30.5
26.2
Hyd1
35.4
11.3
19.2
Hyd2
22.5
10.2
1.1
Hyd3
13.1
8.0
2.2
Hyd4
9.2
6.9
1.1
Hyd5
6.7
5.8
1.1
Hyd6
3.4
3.5
2.4
Hyd7
1.4
2.4
1.1
Soil
Classification
Percent of
sample
Gravel
13.3
Sand
56.2
Coarse Sand
6.8
Medium Sand
5.7
Fine Sand
43.7
Silt
24.7
Clay
5.8
TestAmerica Burlington
Page 173 of 197
200-19299-F-1 03|i/@/4(/|3014
-------
Particle Size of Soils by ASTM D422
Date Received: 11/5/2013
Sample ID: RREC13-27-SURF Percent Solids: 65.8% Start Date: 11/25/2013
Lab ID: 200-19299-F-2 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): subangular Non-soil material: plant
Hardness (> #10): hard
£
C
8
£
0!
C
\
M-
\
a
\
c
09
o.
\
\
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
98.7
1.3
#4
4750
95.0
3.7
#10
2000
93.1
1.9
#20
850
90.3
2.8
#40
425
87.3
3.0
#60
250
81.9
5.4
#80
180
76.9
5.0
#100
150
73.2
3.7
#200
75
56.0
17.2
Hyd1
34.9
16.9
39.1
Hyd2
22.4
13.1
3.8
Hyd3
13.1
9.3
3.8
Hyd4
9.1
6.8
2.5
Hyd5
6.6
5.5
1.3
Hyd6
3.2
4.0
1.5
Hyd7
1.4
2.7
1.3
Soil
Classification
Percent of
sample
Gravel
5.0
Sand
39.0
Coarse Sand
1.9
Medium Sand
5.8
Fine Sand
31.3
Silt
50.5
Clay
5.5
TestAmerica Burlington
Page 174 of 197
200-19299-F-2 03|i/@/4(/|3014
-------
Particle Size of Soils by ASTM D422
Sample ID:
Lab ID:"
RREC13-42-SURF
200-19299-C-3
Percent Solids:
Specific Gravity:
80.2%
2.650
Date Received:
Start Date:
End Date:
11/5/2013
11/25/2013
12/2/2013
Shape (> #10): angular
Non-soil material: shell
Hardness (> #10): hard
£
C
8
\
\
\
\
\
£
0!
C
M-
a
c
09
o.
-0-
0
100000
10000
1000 100
Particle Size, microns (um)
10
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
72.1
27.9
#4
4750
57.3
14.8
#10
2000
49.4
7.9
#20
850
43.2
6.2
#40
425
34.1
9.1
#60
250
20.9
13.2
#80
180
14.3
6.6
#100
150
10.8
3.5
#200
75
4.4
6.4
Hyd1
35.7
3.2
1.2
Hyd2
22.7
2.8
0.4
Hyd3
13.2
2.0
0.8
Hyd4
9.4
1.7
0.4
Hyd5
6.5
1.3
0.4
Hyd6
3.3
0.8
0.4
Hyd7
1.4
0.4
0.4
Soil
Classification
Percent of
sample
Gravel
42.7
Sand
52.9
Coarse Sand
7.9
Medium Sand
15.3
Fine Sand
29.7
Silt
3.1
Clay
1.3
TestAmerica Burlington
Page 175 of 197
200-19299-C-3 03|i/@/4(/|3014
-------
Particle Size of Soils by ASTM D422
Date Received: 11/6/2013
Sample ID: RREC13-09-SURF Percent Solids: 75.2% Start Date: 11/25/2013
Lab ID: 200-19323-F-5 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): subangular Non-soil material: plant, shell
Hardness (> #10): hard
£
C
8
£
v
0!
C
\
M-
\
a
\
c
09
o.
\
\
—0-
-0-
—»
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
96.9
3.1
#4
4750
87.5
9.4
#10
2000
74.4
13.1
#20
850
66.8
7.6
#40
425
56.3
10.5
#60
250
34.0
22.3
#80
180
22.5
11.5
#100
150
16.8
5.7
#200
75
7.5
9.3
Hyd1
35.4
4.6
2.8
Hyd2
22.5
4.2
0.5
Hyd3
13.1
3.3
0.9
Hyd4
9.4
2.4
0.9
Hyd5
6.8
1.9
0.5
Hyd6
3.3
1.4
0.5
Hyd7
1.4
1.0
0.4
Soil
Classification
Percent of
sample
Gravel
12.5
Sand
80.0
Coarse Sand
13.1
Medium Sand
18.1
Fine Sand
48.8
Silt
5.6
Clay
1.9
TestAmerica Burlington
Page 228 of 253
200-19323-F-5 12ii/2/2(/ll 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/6/2013
Sample ID: RREC13-11-SURF Percent Solids: 75.8% Start Date: 11/25/2013
Lab ID: 200-19323-F-6 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): subangular Non-soil material: shell, plant
Hardness (> #10): hard
£
s
£
01
C
M-
E
«
a
—o-
O—-.
-O-
0
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
90.2
9.8
#4
4750
88.0
2.2
#10
2000
84.0
4.0
#20
850
80.3
3.7
#40
425
75.1
5.2
#60
250
67.9
7.2
#80
180
60.2
7.7
#100
150
51.9
8.3
#200
75
21.1
30.8
Hyd1
35.9
4.6
16.5
Hyd2
22.8
4.0
0.6
Hyd3
13.2
3.4
0.6
Hyd4
9.4
2.1
1.3
Hyd5
6.5
2.1
0.0
Hyd6
3.4
1.4
0.7
Hyd7
1.4
0.7
0.6
Soil
Classification
Percent of
sample
Gravel
12.0
Sand
66.9
Coarse Sand
4.0
Medium Sand
8.9
Fine Sand
54.0
Silt
19.0
Clay
2.1
TestAmerica Burlington
Page 229 of 253
200-19323-F-6 12ii/2/2(/ll 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/6/2013
Sample ID: RREC13-13-SURF Percent Solids: 77.3% Start Date: 11/25/2013
Lab ID: 200-19323-F-7 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): jia Non-soil material: na
Hardness (> #10): na
1 1 ——— ||M ——— ||M ——— ||M ——— r " ^-o-J——©—i- o
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
100.0
0.0
#20
850
99.4
0.6
#40
425
99.1
0.3
#60
250
97.0
2.1
#80
180
93.4
3.6
#100
150
89.4
4.0
#200
75
60.8
28.6
Hyd1
35.9
9.0
51.9
Hyd2
22.9
6.5
2.4
Hyd3
13.4
2.9
3.7
Hyd4
9.4
1.6
1.2
Hyd5
6.9
1.6
0.0
Hyd6
3.4
0.2
1.4
Hyd7
1.4
0.2
0.0
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
39.2
Coarse Sand
0.0
Medium Sand
0.9
Fine Sand
38.3
Silt
59.2
Clay
1.6
TestAmerica Burlington
Page 230 of 253
200-19323-F-7 12|i£/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/6/2013
Sample ID: RREC13-14-SURF Percent Solids: 65.2% Start Date: 11/25/2013
Lab ID: 200-19323-F-8 Specific Gravity: 2.650 End Date: 12/2/2013
Sieve
size
Particle
size, um
Percent
finer
Incremental
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
98.9
1.1
#10
2000
98.4
0.5
#20
850
97.7
0.7
#40
425
96.6
1.1
#60
250
94.5
2.1
#80
180
91.5
3.0
#100
150
88.5
3.0
#200
75
64.5
24.0
Hyd1
32.9
27.3
37.2
Hyd2
21.2
24.0
3.3
Hyd3
12.5
18.3
5.7
Hyd4
9
15.0
3.3
Hyd5
6.5
12.7
2.3
Hyd6
3.1
10.5
2.2
Hyd7
1.4
6.0
4.5
Soil
Classification
Percent of
sample
Gravel
1.1
Sand
34.4
Coarse Sand
0.5
Medium Sand
1.8
Fine Sand
32.1
Silt
51.8
Clay
12.7
TestAmerica Burlington
Page 231 of 253
200-19323-F-8 12ii/2/2(/ll 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/6/2013
Sample ID: RREC13-15-SURF Percent Solids: 60.7% Start Date: 11/25/2013
Lab ID: 200-19323-F-10 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): nja Non-soil material: n/a
Hardness (> #10): n/a
£
C
8
0—
-o—
0
\
\
\
V
\
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
size
Particle
size, um
Percent
finer
Incremental
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
100.0
0.0
#10
2000
100.0
0.0
#20
850
99.2
0.8
#40
425
98.8
0.4
#60
250
97.8
1.0
#80
180
96.8
1.0
#100
150
95.9
0.9
#200
75
88.1
7.8
Hyd1
30.5
54.8
33.3
Hyd2
19.8
48.9
5.9
Hyd3
11.8
41.6
7.3
Hyd4
8.5
35.7
5.9
Hyd5
6.2
31.3
4.4
Hyd6
3
24.0
7.3
Hyd7
1.3
16.6
7.4
Soil
Classification
Percent of
sample
Gravel
0.0
Sand
11.9
Coarse Sand
0.0
Medium Sand
1.2
Fine Sand
10.7
Silt
56.8
Clay
31.3
TestAmerica Burlington
Page 232 of 253
200-19323-F-10 12li£/l(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/6/2013
Sample ID: RREC13-03-SURF Percent Solids: 59.0% Start Date: 11/26/2013
Lab ID: 200-19327-F-6 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): subrounded Non-soil material: plant, shell
Hardness (> #10): hard
o
0—
-0—
0
—
£
s
£
V
0!
C
M-
a
c
09
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
99.2
0.8
#10
2000
98.6
0.6
#20
850
97.5
1.1
#40
425
94.4
3.1
#60
250
86.9
7.5
#80
180
77.9
9.0
#100
150
69.5
8.4
#200
75
46.4
23.1
Hyd1
33.8
27.7
18.7
Hyd2
21.7
23.6
4.1
Hyd3
12.9
16.8
6.8
Hyd4
9.2
14.1
2.7
Hyd5
6.6
11.4
2.7
Hyd6
3.2
8.6
2.8
Hyd7
1.4
4.5
4.1
Soil
Classification
Percent of
sample
Gravel
0.8
Sand
52.8
Coarse Sand
0.6
Medium Sand
4.2
Fine Sand
48.0
Silt
35.0
Clay
11.4
TestAmerica Burlington
Page 210 of 238
200-19327-F-6 1013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/6/2013
Sample ID: RREC13-05-SURF Percent Solids: 77.5% Start Date: 11/26/2013
Lab ID: 200-19327-F-7 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): angular Non-soil material: shell
Hardness (> #10): hard
£
C
8
£
0!
C
M-
a
c
09
o.
h.
—o
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
96.2
3.8
#4
4750
84.4
11.8
#10
2000
70.8
13.6
#20
850
61.8
9.0
#40
425
52.8
9.0
#60
250
39.7
13.1
#80
180
32.4
7.3
#100
150
26.8
5.6
#200
75
6.1
20.7
Hyd1
36.1
3.7
2.4
Hyd2
22.8
3.7
0.0
Hyd3
13.4
2.2
1.5
Hyd4
9.5
1.7
0.5
Hyd5
6.9
1.2
0.5
Hyd6
3.3
1.2
0.0
Hyd7
1.4
1.2
0.0
Soil
Classification
Percent of
sample
Gravel
15.6
Sand
78.3
Coarse Sand
13.6
Medium Sand
18.0
Fine Sand
46.7
Silt
4.9
Clay
1.2
TestAmerica Burlington
Page 211 of 238
200-19327-F-7 12|i£/$(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/6/2013
Sample ID: RREC13-06-SURF Percent Solids: 64.3% Start Date: 11/26/2013
Lab ID: 200-19327-F-8 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): angular Non-soil material: plant, shell
Hardness (> #10): hard
£
s
£
0!
C
M-
s
a
\
c
09
\
s
v.
V
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
92.8
7.2
#10
2000
80.9
11.9
#20
850
72.0
8.9
#40
425
62.4
9.6
#60
250
56.1
6.3
#80
180
54.0
2.1
#100
150
52.8
1.2
#200
75
44.8
8.0
Hyd1
33.1
22.2
22.6
Hyd2
21.3
19.5
2.7
Hyd3
12.6
14.9
4.6
Hyd4
9.2
13.1
1.8
Hyd5
6.6
10.4
2.7
Hyd6
3.2
7.6
2.8
Hyd7
1.4
5.8
1.8
Soil
Classification
Percent of
sample
Gravel
7.2
Sand
48.0
Coarse Sand
11.9
Medium Sand
18.5
Fine Sand
17.6
Silt
34.4
Clay
10.4
TestAmerica Burlington
Page 212 of 238
200-19327-F-8 1013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/6/2013
Sample ID: RREC13-07-SURF Percent Solids: 76.4% Start Date: 11/26/2013
Lab ID: 200-19327-F-9 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): subangular Non-soil material: shell
Hardness (> #10): hard
£
\
\
\
s
V
\
V
s
s
£
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
84.3
15.7
#4
4750
60.6
23.7
#10
2000
45.9
14.7
#20
850
39.2
6.7
#40
425
32.8
6.4
#60
250
24.5
8.3
#80
180
20.5
4.0
#100
150
18.0
2.5
#200
75
8.7
9.3
Hyd1
35.4
6.4
2.3
Hyd2
22.5
5.8
0.6
Hyd3
13.2
4.2
1.7
Hyd4
9.5
3.6
0.6
Hyd5
6.5
3.0
0.6
Hyd6
3.3
2.5
0.6
Hyd7
1.4
1.9
0.6
Soil
Classification
Percent of
sample
Gravel
39.4
Sand
51.9
Coarse Sand
14.7
Medium Sand
13.1
Fine Sand
24.1
Silt
5.7
Clay
3.0
TestAmerica Burlington
Page 213 of 238
200-19327-F-9 1013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/6/2013
Sample ID: RREC13-48-SURF Percent Solids: 54.1% Start Date: 11/26/2013
Lab ID: 200-19327-F-10 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): subangular Non-soil material: shell
Hardness (> #10): brittle
£
s
\
\
£
\
0!
C
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
97.3
2.7
#4
4750
93.4
3.9
#10
2000
91.4
2.0
#20
850
88.7
2.7
#40
425
85.0
3.7
#60
250
81.3
3.7
#80
180
78.8
2.5
#100
150
77.0
1.8
#200
75
67.6
9.4
Hyd1
32.2
39.1
28.5
Hyd2
20.8
33.7
5.4
Hyd3
12.4
27.1
6.6
Hyd4
8.7
23.1
4.0
Hyd5
6.4
19.1
4.0
Hyd6
3.2
13.8
5.3
Hyd7
1.3
11.1
2.7
Soil
Classification
Percent of
sample
Gravel
6.6
Sand
25.8
Coarse Sand
2.0
Medium Sand
6.4
Fine Sand
17.4
Silt
48.5
Clay
19.1
TestAmerica Burlington
Page 214 of 238
200-19327-F-10 12|i£/$(/|3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/6/2013
Sample ID: RREC13-49-SURF Percent Solids: 59.1% Start Date: 11/26/2013
Lab ID: 200-19327-F-12 Specific Gravity: 2.650 End Date: 12/2/2013
Shape (> #10): subangular Non-soil material: shell
Hardness (> #10): hard
£
C
8
£
0!
C
s
M-
a
c
09
o.
100000 10000 1000 100 10 1
Particle Size, microns (um)
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
100.0
0.0
#4
4750
93.4
6.6
#10
2000
86.1
7.3
#20
850
84.2
1.9
#40
425
81.5
2.7
#60
250
75.7
5.8
#80
180
70.5
5.2
#100
150
65.7
4.8
#200
75
39.8
25.9
Hyd1
34.2
20.6
19.2
Hyd2
22
17.3
3.3
Hyd3
12.9
12.8
4.5
Hyd4
9.1
10.5
2.3
Hyd5
6.6
9.4
1.1
Hyd6
3.3
7.1
2.3
Hyd7
1.4
6.0
1.1
Soil
Classification
Percent of
sample
Gravel
6.6
Sand
53.6
Coarse Sand
7.3
Medium Sand
4.6
Fine Sand
41.7
Silt
30.4
Clay
9.4
TestAmerica Burlington
Page 215 of 238
200-19327-F-12 12|i£/$(/l3 013
-------
Particle Size of Soils by ASTM D422
Date Received: 11/7/2013
Sample ID: RREC13-50-SURF Percent Solids: 78.3% Start Date: 12/2/2013
Lab ID: 200-19360-F-1 Specific Gravity: 2.650 End Date: 12/5/2013
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
100.0
0.0
3/8 inch
9500
98.1
1.9
#4
4750
91.4
6.7
#10
2000
84.1
7.3
#20
850
77.5
6.6
#40
425
66.5
11.0
#60
250
45.0
21.5
#80
180
28.3
16.7
#100
150
18.7
9.6
#200
75
6.3
12.4
Hyd1
36.5
2.8
3.5
Hyd2
23.2
2.3
0.5
Hyd3
13.4
1.7
0.5
Hyd4
9.7
1.2
0.5
Hyd5
6.6
1.2
0.0
Hyd6
3.3
1.2
0.0
Hyd7
1.4
0.6
0.5
Soil
Classification
Percent of
sample
Gravel
8.6
Sand
85.1
Coarse Sand
7.3
Medium Sand
17.6
Fine Sand
60.2
Silt
5.1
Clay
1.2
TestAmerica Burlington
Page 176 of 191
200-19360-F-1 12|i&/2(/l3 013
-------
Particle Size of Soils by ASTM D422
Sample ID:
Lab ID:"
RREC13-46-SURF
200-19360-F-2
Percent Solids:
Specific Gravity:
68.5%
2.650
Date Received:
Start Date:
End Date:
11/7/2013
12/2/2013
12/5/2013
Shape (> #10): angular
Non-soil material: shell
Hardness (> #10): brittle
£
C
8
\
\
£
0!
C
M-
a
c
09
o.
100
90
80
70
60
50
40
30
20
10
0
100000
10000
1000 100
Particle Size, microns (um)
10
Sieve
Particle
Percent
Incremental
size
size, um
finer
percent
3 inch
75000
100.0
0.0
2 inch
50000
100.0
0.0
1.5 inch
37500
100.0
0.0
1 inch
25000
100.0
0.0
3/4 inch
19000
85.4
14.6
3/8 inch
9500
75.0
10.4
#4
4750
64.8
10.2
#10
2000
53.6
11.2
#20
850
45.1
8.5
#40
425
38.2
6.9
#60
250
27.5
10.7
#80
180
21.1
6.4
#100
150
17.2
3.9
#200
75
9.2
8.0
Hyd1
34.6
8.8
0.4
Hyd2
22.3
6.7
2.2
Hyd3
13.1
5.0
1.6
Hyd4
9.2
3.9
1.1
Hyd5
6.6
3.4
0.5
Hyd6
3.3
2.8
0.6
Hyd7
1.4
1.7
1.1
Soil
Classification
Percent of
sample
Gravel
35.2
Sand
55.6
Coarse Sand
11.2
Medium Sand
15.4
Fine Sand
29.0
Silt
5.8
Clay
3.4
TestAmerica Burlington
Page 177 of 191
200-19360-F-2 12|i&/2(/l3 013
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