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December 2023

United States	Office of Chemical Safety and

Environmental Protection Agency	Pollution Prevention

xvEPA

Draft Risk Evaluation for
for Tris(2-chloroethyl) Phosphate (TCEP)

Supplemental File:

Exposure Monitoring Tornado Figures, Supplemental Tables and Data
Integration Methods and Approach for TCEP
CASRN: 115-96-8

December 2023


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TABLE OF CONTENTS

1 ENVIRONMENTAL MONITORING CONCENTRATIONS REPORTED BY MEDIA

TYPE	8

1.1	Ambient Air	8

1.1.1	Ambient Air (ng/g) - Particulate Fraction	8

1.1.2	Ambient Air (ng/m3) - All Fractions	8

1.2	Aquatic Organisms - Fish	11

1.2.1 Aquatic Organisms - Fish (ng/g) - All Fractions	11

1.3	Aquatic Organisms - Mammal	13

1.3.1 Aquatic Organisms - Mammal (ng/g) - Lipid Fraction	13

1.4	Aquatic Organisms - Mollusk	14

1.4.1 Aquatic Organisms - Mollusk (ng/g) - All Fractions	14

1.5	Aquatic Organisms - Other	15

1.5.1 Aquatic Organisms - Other (ng/g) - Wet Fraction	15

1.6	Dietary	16

1.6.1	Dietary (ng/g) - Wet Fraction	16

1.6.2	Dietary (ng/g) - Wet Fraction	19

1.7	Drinking Water	20

1.7,1 Drinking Water (ng/L) - Not Specified Fraction	20

1.8	Dust (Indoor)	22

1.8.1	Dust (Indoor) (ng/g) - Dry Fraction	22

1.8.2	Dust (Indoor) (ng/g) - Dry Fraction	28

1.8.3	Dust (Indoor) (ng/m2) - Dry Fraction	29

1.9	Groundwater	30

1.9.1 Groundwater (ng/L) - Not Specified Fraction	30

1.10	Human Biomonitoring - Breastmilk	32

1.10.1	Human Biomonitoring - Breastmilk (ng/L) - wet Fraction	32

1.10.2	Human Biomonitoring - Breastmilk (ng/g) - Lipid Fraction	32

1.11	Human Biomonitoring - Hair	33

1.11.1 Human Biomonitoring - Hair (ng/g) - Dry Fraction	33

1.12	Human Biomonitoring - Nails	34

1.12.1 Human Biomonitoring - Nails (ng/g) - Dry Fraction	34

1.13	Human Biomonitoring - Other	34

1.13.1	Human Biomonitoring - Other (ng/g) - Dry Fraction	34

1.13.2	Human Biomonitoring - Other (ng/g) - Dry Fraction	35

1.14	Human Biomonitoring - Plasma	35

1.14,1 Human Biomonitoring - Plasma (ng/L) - Wet Fraction	35

1.15	Human Biomonitoring - Serum	36

1.15,1 Human Biomonitoring - Serum (ng/g) - Lipid Fraction	36

1.16	Human Biomonitoring - SkinDermal Wipe	37

1.16.1	Human Biomonitoring - Skin Dermal Wipe (ng/g) - Dry Fraction	37

1.16.2	Human Biomonitoring - Skin Dermal Wipe (ng/wipe) - Dry Fraction	37

1.17	Human Biomonitoring - Urine	38

1.17.1	Human Biomonitoring - Urine (ng/g) - Creatinine Adjusted Fraction	38

1.17.2	Human Biomonitoring - Urine (ng/L) - Unadjusted Fraction	39

1.17.3	Human Biomonitoring - Urine (ng/L) - All Fractions	39

1.18	Human Biomonitoring - Silicone Wristbands	40

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1.18.1 Human Biomonitoring - Silicone Wristbands (ng/g) - Not Specified Fraction	40

1.19	Indoor Air	41

1.19.1 Indoor Air (ng/m3) - All Fractions	41

1.20	Leachate	45

1.20.1 Leachate (ng/L) - Not Specified Fraction	45

1.21	Other	46

1.21.1	Other (ng/g) - Dry Fraction	46

1.21.2	Other (ng/g) - All Fractions	47

1.21.3	Other (ng/L) - Not Specified Fraction	48

1.22	Personal Inhalation	48

1.22.1 Personal Inhalation (ng/m3) - All Fractions	48

1.23	Precipitation	49

1.23.1 Precipitation (ng/L) - Wet Fraction	49

1.24	Sediment	51

1.24.1 Sediment (ng/g) - All Fractions	51

1.25	Soil	53

1.25.1 Soil (ng/g) - Dry Fraction	53

1.26	Surface Water	54

1.26.1 Surface Water (ng/L) - Not Specified Fraction	54

1.27	Terrestrial Organisms - Bird	57

1.27.1	Terrestrial Organisms - Bird (ng/g) - All Fractions	57

1.27.2	Terrestrial Organisms - Bird (ng/g) - Wet Fraction	59

1.28	Terrestrial Organisms - Mammal	60

1.28.1 Terrestrial Organisms - Mammal (ng/g) - All Fractions	60

1.29	Terrestrial Organisms - Plant	61

1.29.1 Terrestrial Organisms - Plant (ng/g) - Wet Fraction	61

1.30	Wastewater	61

1.30.1	Wastewater (ng/g) - Wet Fraction	61

1.30.2	Wastewater (ng/L) - Wet Fraction	62

2	METHODS AND APPROACH	66

2.1	Data Integration Methods and Approach	66

2.2	Statistical Approach of Exposure Estimates Derived from Measured Concentrations	67

2.2.1	Aggregation of Statistical Estimates	68

2.2.2	Fitting Lognormal Distributions	69

2.2.3	Fitting Normal Distributions	69

2.2.4	Quality Control of Derived Exposure Estimates	70

2.2.5	Final Exposure Estimates by Media and Pollution Source Receptor Type	70

3	REFERENCES	71

LIST OF TABLES

Table 1-1. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Particulate

Fraction of Ambient Air	8

Table 1-2. Summary of Peer-Reviewed Literature that Measured TCEP (ng/m3) Levels in Ambient Air

	10

Table 1-3. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in Aquatic
Organisms - Fish	12

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Table 1-4. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Lipid

Fraction of Aquatic Organisms - Mammal	14

Table 1-5. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in Aquatic

Organisms - Mollusk	15

Table 1-6. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Wet

Fraction of Aquatic Organisms - Other	16

Table 1-7. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Wet

Fraction of Dietary	17

Table 1-8. Summary of Peer-Reviewed Literature that Measured BCEP (ng/g) Levels in the Wet

Fraction of Dietary	20

Table 1-9. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Not

Specified Fraction of Drinking Water	21

Table 1-10. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry

Fraction of Dust (Indoor)	25

Table 1-11. Summary of Peer-Reviewed Literature that Measured BCEP (ng/g) Levels in the Dry

Fraction of Dust (Indoor)	29

Table 1-12. Summary of Peer-Reviewed Literature that Measured TCEP (ng/m2) Levels in the Dry

Fraction of Dust (Indoor)	29

Table 1-13. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Not

Specified Fraction of Groundwater	31

Table 1-14. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the wet

Fraction of Human Biomonitoring - Breastmilk	32

Table 1-15. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Lipid

Fraction of Human Biomonitoring - Breastmilk	33

Table 1-16. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry

Fraction of Human Biomonitoring - Hair	33

Table 1-17. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry

Fraction of Human Biomonitoring - Nails	34

Table 1-18. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry

Fraction of Human Biomonitoring - Other	35

Table 1-19. Summary of Peer-Reviewed Literature that Measured BCEP (ng/g) Levels in the Dry

Fraction of Human Biomonitoring - Other	35

Table 1-20. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Wet

Fraction of Human Biomonitoring - Plasma	36

Table 1-21. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Lipid

Fraction of Human Biomonitoring - Serum	36

Table 1-22. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry

Fraction of Human Biomonitoring - SkinDermal Wipe	37

Table 1-23. Summary of Peer-Reviewed Literature that Measured TCEP (ng/wipe) Levels in the Dry

Fraction of Human Biomonitoring - Skin Dermal Wipe	38

Table 1-24. Summary of Peer-Reviewed Literature that Measured BCEP (ng/g) Levels in the Creatinine

Adjusted Fraction of Human Biomonitoring - Urine	38

Table 1-25. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the

Unadjusted Fraction of Human Biomonitoring - Urine	39

Table 1-26. Summary of Peer-Reviewed Literature that Measured BCEP (ng/L) Levels in Human

Biomonitoring - Urine	40

Table 1-27. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Not
Specified Fraction of Human Biomonitoring - Silicone Wristbands	41

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Table 1-28. Summary of Peer-Reviewed Literature that Measured TCEP (ng/m3) Levels in Indoor Air 43

Table 1-29. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Not

Specified Fraction of Leachate	46

Table 1-30. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry

Fraction of Other	47

Table 1-31. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in Other	47

Table 1-32. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Not

Specified Fraction of Other	48

Table 1-33. Summary of Peer-Reviewed Literature that Measured TCEP (ng/m3) Levels in Personal

Inhalation	49

Table 1-34. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Wet

Fraction of Precipitation	50

Table 1-35. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in Sediment.... 52
Table 1-36. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry

Fraction of Soil	53

Table 1-37. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Not

Specified Fraction of Surface Water	55

Table 1-38. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in Terrestrial

Organisms - Bird	58

Table 1-39. Summary of Peer-Reviewed Literature that Measured BCEP (ng/g) Levels in the Wet

Fraction of Terrestrial Organisms - Bird	60

Table 1-40. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in Terrestrial

Organisms - Mammal	60

Table 1-41. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Wet

Fraction of Terrestrial Organisms - Plant	61

Table 1-42. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Wet

Fraction of Wastewater	62

Table 1-43. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Wet

Fraction of Wastewater	63

Table 2-1. Statistics and Methods for Data Aggregation	68

Table 2-2. Distributions Preferred Depending on Available Reported Statistics	69

Table 2-3. Assumed Percentile for Calculating Error by Statistical Estimate Type	69

LIST OF FIGURES

Figure 1-1. Concentrations of TCEP (ng/g) in the Particulate Fraction of Ambient Air in General

Population (Background) Locations in 2018	8

Figure 1-2. Concentrations of TCEP (ng/m3) in Ambient Air from 2000 to 2019	9

Figure 1-3. Concentrations of TCEP (ng/g) in Aquatic Organisms - Fish from 2003 to 2016	12

Figure 1-4. Concentrations of TCEP (ng/g) in the Lipid Fraction of Aquatic Organisms - Mammal from

2004 to 2010	14

Figure 1-5. Concentrations of TCEP (ng/g) in Aquatic Organisms - Mollusk in Near Facility (Highly

Exposed) Locations from 2008 to 2017	15

Figure 1-6. Concentrations of TCEP (ng/g) in the Wet Fraction of Aquatic Organisms - Other from

2008 to 2018	16

Figure 1-7. Concentrations of TCEP (ng/g) in the Wet Fraction of Dietary from 1982 to 2018	17

Figure 1-8. Concentrations of BCEP (ng/g) in the Wet Fraction of Dietary in 2018	19

Figure 1-9. Concentrations of TCEP (ng/L) in the Not Specified Fraction of Drinking Water from 1982
to 2014	21

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Figure 1-10. Concentrations of TCEP (ng/g) in the Dry Fraction of Dust (Indoor) from 2000 to 2019.. 24
Figure 1-11. Concentrations of BCEP (ng/g) in the Dry Fraction of Dust (Indoor) in Residential

Locations in 2019	29

Figure 1-12. Concentrations of TCEP (ng/m2) in the Dry Fraction of Dust (Indoor) from 2000 to 2016 29
Figure 1-13. Concentrations of TCEP (ng/L) in the Not Specified Fraction of Groundwater from 1978 to

2017	30

Figure 1-14. Concentrations of TCEP (ng/L) in the wet Fraction of Human Biomonitoring - Breastmilk

in General Population (Background) Locations from 2014 to 2015	32

Figure 1-15. Concentrations of TCEP (ng/g) in the Lipid Fraction of Human Biomonitoring -

Breastmilk from 1997 to 2011	32

Figure 1-16. Concentrations of TCEP (ng/g) in the Dry Fraction of Human Biomonitoring - Hair in

General Population (Background) Locations from 2014 to 2015	33

Figure 1-17. Concentrations of TCEP (ng/g) in the Dry Fraction of Human Biomonitoring - Nails in

General Population (Background) Locations from 2014 to 2015	34

Figure 1-18. Concentrations of TCEP (ng/g) in the Dry Fraction of Human Biomonitoring - Other in

General Population (Background) Locations from 2014 to 2016	35

Figure 1-19. Concentrations of BCEP (ng/g) in the Dry Fraction of Human Biomonitoring - Other in

General Population (Background) Locations from 2014 to 2016	35

Figure 1-20. Concentrations of TCEP (ng/L) in the Wet Fraction of Human Biomonitoring - Plasma in

General Population (Background) Locations from 2014 to 2016	36

Figure 1-21. Concentrations of TCEP (ng/g) in the Lipid Fraction of Human Biomonitoring - Serum in

General Population (Background) Locations in 2016	36

Figure 1-22. Concentrations of TCEP (ng/g) in the Dry Fraction of Human Biomonitoring -

SkinDermal Wipe in General Population (Background) Locations in 2012	37

Figure 1-23. Concentrations of TCEP (ng/wipe) in the Dry Fraction of Human Biomonitoring -

Skin Dermal Wipe in General Population (Background) Locations from 2012 to 2016	37

Figure 1-24. Concentrations of BCEP (ng/g) in the Creatinine Adjusted Fraction of Human

Biomonitoring - Urine in General Population (Background) Locations in 2018	38

Figure 1-25. Concentrations of TCEP (ng/L) in the Unadjusted Fraction of Human Biomonitoring -

Urine in General Population (Background) Locations from 2010 to 2015	39

Figure 1-26. Concentrations of BCEP (ng/L) in Human Biomonitoring - Urine in General Population

(Background) Locations from 2011 to 2018	40

Figure 1-27. Concentrations of TCEP (ng/g) in the Not Specified Fraction of Human Biomonitoring -

Silicone Wristbands in General Population (Background) Locations from 2012 to 2015	41

Figure 1-28. Concentrations of TCEP (ng/m3) in Indoor Air from 2000 to 2016	43

Figure 1-29. Concentrations of TCEP (ng/L) in the Not Specified Fraction of Leachate from 1994 to

1995	46

Figure 1-30. Concentrations of TCEP (ng/g) in the Dry Fraction of Other in Unknown/Not Specified

Locations in 2003	46

Figure 1-31. Concentrations of TCEP (ng/g) in Other from 2001 to 2008	47

Figure 1-32. Concentrations of TCEP (ng/L) in the Not Specified Fraction of Other in General

Population (Background) Locations in 2016	48

Figure 1-33. Concentrations of TCEP (ng/m3) in Personal Inhalation in General Population

(Background) Locations from 2013 to 2016	49

Figure 1-34. Concentrations of TCEP (ng/L) in the Wet Fraction of Precipitation from 1994 to 2014... 50

Figure 1-35. Concentrations of TCEP (ng/g) in Sediment from 1980 to 2017	52

Figure 1-36. Concentrations of TCEP (ng/g) in the Dry Fraction of Soil in General Population
(Background) Locations from 2010 to 2014	53

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Figure 1-37. Concentrations of TCEP (ng/L) in the Not Specified Fraction of Surface Water from 1980

to 2017	55

Figure 1-38. Concentrations of TCEP (ng/g) in Terrestrial Organisms - Bird from 2000 to 2016	58

Figure 1-39. Concentrations of BCEP (ng/g) in the Wet Fraction of Terrestrial Organisms - Bird in

General Population (Background) Locations from 2000 to 2012	60

Figure 1-40. Concentrations of TCEP (ng/g) in Terrestrial Organisms - Mammal from 2008 to 2018 .. 60
Figure 1-41. Concentrations of TCEP (ng/g) in the Wet Fraction of Terrestrial Organisms - Plant in

Remote (Not Near Source) Locations from 1993 to 1994	 61

Figure 1-42. Concentrations of TCEP (ng/g) in the Wet Fraction of Wastewater from 2013 to 2018	62

Figure 1-43. Concentrations of TCEP (ng/L) in the Wet Fraction of Wastewater from 2001 to 2018 .... 63

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1 ENVIRONMENTAL MONITORING CONCENTRATIONS
REPORTED BY MEDIA TYPE

1.1 Ambient Air

1.1.1 Ambient Air (ng/g) - Particulate Fraction

Measured concentrations of TCEP in Ambient Air with unit of ng/g, extracted from one source, are
summarized in Figure 1-1 and supplemental information is provided in Table 1-1. Overall,
concentrations were 300 ng/g from 18 samples collected in 2018 in one country, PL. Location types
were categorized as General Population (Background). Reported detection frequency was 0.11.





g General Population (Background)



NonUS Particulate



A Normal Distribution (CT and 90th percentile)





5043433 - Fabia ska et al., 2019 - PL

<1





10

100

1000





Concentration (ng/g)



Figure 1-1. Concentrations of TCEP (ng/g) in the Particulate Fraction of Ambient Air in General
Population (Background) Locations in 2018

Table 1-1. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the
Particulate Fraction of Ambient Air

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Fabianska et
al. (2019)

PL

General
Population
(Background)

2018

18 (0.11)

N/R

Medium

Abbreviations: N/R, Not reported

1.1.2 Ambient Air (ng/m3) - All Fractions

Measured concentrations of TCEP in Ambient Air with unit of ng/m3, extracted from 17 sources, are
summarized in Figure 1-2 and supplemental information is provided in Table 1-2. More than one weight
fraction was reported and summarized separately below:

Overall, concentrations for Combined Vapor/Gas and Particulate ranged from not detected to 58.4 ng/m3
from 152 samples collected between 2000 and 2018 in 11 countries, AR, BO, BR, CA, CL, CO, CR, JP,
MX, NO and US. Location types were categorized as General Population (Background), Near Facility
(Highly Exposed) and Remote (Not Near Source). Reported detection frequency ranged from 0.55 to
0.94.

Overall, concentrations for Particulate ranged from not detected to 3.532 ng/m3 from 855 samples
collected between 2002 and 2019 in seven countries, AQ, CA, ES, FI, JP, SE and US. Location types
were categorized as Unknown/Not Specified, General Population (Background), Near Facility (Highly
Exposed) and Remote (Not Near Source). Reported detection frequency ranged from 0.0 to 1.0.

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Overall, concentrations for Vapor/Gas ranged from not detected to 0.143 ng/nr from 49 samples
collected in 2014 in two countries, AQ and TR. Location types were categorized as General Population
(Background), Near Facility (Highly Exposed) and Remote (Not Near Source). Reported detection
frequency ranged from 0.8 to 1.0.

Mix Combined Vapor/Gas and Particulate

3985267 - Guo ct al., 2017 - CA,US

NonUS Combined Vapor/Gas and Particulate

6994279 - Bohlin-Nizzetto et al., 2019 - NO

5386424 - Rauert et al., 2018 - AR,BR,CL,MX
5386424 - Rauert et al., 2018 - AR,BO,BR,CL.CO.CR,MX
632484 - Ohura et al., 2006 - JP

US Particulate

NonUS Particulate

2939998 - Peverly et al., 2015 - US
5163441 - Salamova et al., 2016-US
3864979 - Clark et al., 2017 - US
3027503 - Salamova et al., 2014 - US
3027503 - Salamova et al., 2014 - US
2539068 - Bradman et al., 2014 - US

6816026 - Maceira et al., 2020 - ES
5163827 - Wong et al., 2018 - SE
3862723-Li et al., 2017-AQ
5469544 - Siihring et al., 2016 - CA
3466615 - Abdollahi et al., 2017 - CA
5176506 - Marklund et al., 2005 - FI
1927779 - Saito et al., 2007 - JP

NonUS Vapor/Gas

3862723-Li et al., 2017-AQ
5017070 - Kurt-Karakus et al., 2018 - TR
5017070 - Kurt-Karakus et al., 2018 - TR

10*-5

U	I General Population (Background)

| Remote (Not Near Source)

Near Facility (Highly Exposed)

I	r Unknown/Not Specified
V Lognormal Distribution (CT and 90th percentile)
A Normal Distribution (CT and 90th percentile)
gf Non-Detect

v

|A

V V

D v

A A

V



0.01	0.1

Concentration (ng/m3)

Figure 1-2. Concentrations of TCEP (ng/m3) in Ambient Air from 2000 to 2019

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Table 1-2. Summary of Peer-Reviewed Literature that Measured TCEP (ng/m3) Levels in
Ambient Air

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/m3)

Overall
Quality
Level

Combined Vapor/Gas and Particulate

Guo et al.
(2017)

CA, US

General
Population
(Background)

2013

20 (0.55)

0.0602

High

Bohlin-

Nizzetto et
al. (2019)

NO

Remote (Not
Near Source)

2017-2018

36 (0.56)

0.045

Medium

Rauert et al.
(2018)

AR, BR, CL,

MX

General
Population
(Background)

2014-2016

14 (0.93)

0.08

High

Rauert et al.
(2018)

AR, BO, BR,
CL, CO, CR,

MX

Remote (Not
Near Source)

2014-2016

36 (0.94)

0.05

High

Ohuraet al.
(2006)

JP

Near Facility
(Highly '
Exposed)

2000-2001

46 (0.91)

N/R

Medium

Particulate

Peverlv et al.
(2015)

US

General
Population
(Background)

2012-2014

161 (0.87)

N/R

High

Salamova et
al. (2016)

us

General
Population
(Background)

2012-2014

359 (0.60)

N/R

Medium

Clark et al.
(2017)

us

General
Population
(Background)

2013

45 (0.93)

N/R

High

Salamova et
al. (2014)

us

General
Population
(Background)

2012

81 (0.74)

N/R

Medium

Salamova et
al. (2014)

us

General
Population
(Background)

2012

16 (0.62)

N/R

Medium

Bradman et
al. (2014)

us

General
Population
(Background)

2010-2011

14 (0.50)

0.3

High

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/m3)

Overall
Quality
Level

Maceira et al.
(2020)

ES

Near Facility
(Highly '
Exposed)

2018-2019

24 (0.62)

0.0014

High

Wong et al.
(2018)

SE

General
Population
(Background)

2014-2015

24 (0.96)

0.044

Medium

Li et al.
(2017)

AQ

Remote (Not
Near Source)

2014

9(1.00)

0.0038

High

Suhrine et al.
(2016)

CA

Unknown/Not
Specified

2007-2013

92 (0.87)

N/R

Medium

Abdollahi et
al. (2017)

CA

General
Population
(Background)

2010

21 (N/R)

0.0003

High

Marklund et
al. (2005b)

FI

Remote (Not
Near Source)

2003

1 (1.00)

N/R

Medium

Saito et al.
(2007)

JP

Unknown/Not
Specified

2002

8 (0.00)

0.67

Medium

Vapor/Gas

Li et al.
(2017)

AQ

Remote (Not
Near Source)

2014

9(1.00)

0.0012

High

Kurt-Karakus
et al. (2018)

TR

General
Population
(Background)

2014

30 (0.80)

0.073

High

Kurt-Karakus
et al. (2018)

TR

Near Facility
(Highly '
Exposed)

2014

10 (0.80)

0.073

High

Abbreviations: N/R, Not reported

1.2 Aquatic Organisms - Fish

1.2.1 Aquatic Organisms - Fish (ng/g) - All Fractions	

Measured concentrations of TCEP in Aquatic Organisms - Fish with unit of ng/g, extracted from eight
sources, are summarized in Figure 1-3 and supplemental information is provided in Table 1-3. More
than one weight fraction was reported and summarized separately below:

Overall, concentrations for Lipid ranged from not detected to 187.0 ng/g from 55 samples collected
between 2003 and 2016 in five countries, CA, ES, NO, SE and US. Location types were categorized as
General Population (Background), Near Facility (Highly Exposed) and Remote (Not Near Source).

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Reported detection frequency ranged from 0.21 to 1.0.

Overall, concentrations for Wet ranged from not detected to 26.0 ng/g from 186 samples collected
between 2004 and 2015 in four countries, CA, KR, NL and NO. Location types were categorized as
General Population (Background), Near Facility (Highly Exposed) and Remote (Not Near Source).
Reported detection frequency ranged from 0.12 to 1.0.

Mix Lipid

3985267 - Guo et si., 2017 - CA.US - Other

NonUS Lipid

5164308 - Santin et al., 2016 - ES - Whole Organism
5162922 - Hallanger et al., 2015 - NO - Other
2586188 - Sundkvist et al., 2010 - SE - Muscle/Filet
2586188 - Sundkvist et al., 2010 - SE - Muscle/Filet
2586188 - Sundkvist et al., 2010 - SE - Muscle/Filet

NonUS Wet

5469301 - Choo et al., 2018 - KR - Liver
5469301 - Choo et al., 2018 - KR - Muscle/Filet
5469301 - Choo et al., 2018 - KR - Other
5469297 - McGoldrick et al., 2014 - CA - Other
2935128 - Brandsma et al., 2015 - NL - Other
6992056 - Evenset et al., 2009 - NO - Liver
6992056 - Evenset et al., 2009 - NO - Muscle/Fillet
6992056 - Evenset et al., 2009 - NO - Whole Organism

0.001

0.01

0.1

IB General Population (Background)

| Remote (Not Near Source)

Near Facility (Highly Exposed)

A Normal Distribution (CT and 90th percentile)
V Lognormal Distribution (CT and 90th percentile)

Al

&

EE

V7

V

w

^7

D v

1

100

Concentration (ng/g)

1000

Figure 1-3. Concentrations of TCEP (ng/g) in Aquatic Organisms - Fish from 2003 to 2016

Table 1-3. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in Aquatic
Organisms - Fish						

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Lipid

Guo et al.
(2017)

CA, US

General
Population
(Background)

2010

14 (0.21)

20.9

High

Santin et al.
(2016)

ES

General
Population
(Background)

2016

12 (0.25)

1.39

High

Hallanser et
al. (2015)

NO

Remote (Not
Near Source)

2009

10 (0.70)

N/R

High

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Sundkvist et
al. (2010)

SE

General
Population
(Background)

2007

7(0.57)

2.8

High

Sundkvist et
al. (2010)

SE

Near Facility
(Highly '
Exposed)

2003-2007

4(1.00)

2.8

High

Sundkvist et
al. (2010)

SE

Remote (Not
Near Source)

2005-2007

8 (1.00)

2.8

High

Wet

Choo et al.
(2018)

KR

General
Population
(Background)

2015

20 (1.00)

0.22

High

Choo et al.
(2018)

KR

General
Population
(Background)

2015

30 (1.00)

0.06

High

Choo et al.
(2018)

KR

General
Population
(Background)

2015

20 (1.00)

0.09

High

McGoldrick
et al. (2014)

CA

General
Population
(Background)

2009-2010

72 (0.12)

0.03

High

Brandsma et
al. (2015)

NL

Near Facility
(Highly '
Exposed)

2008

19 (0.42)

0.21

High

Evenset et al.
(2009)

NO

Remote (Not
Near Source)

2004-2008

3 (1.00)

N/R

Medium

Evenset et al.
(2009)

NO

Remote (Not
Near Source)

2004-2008

5 (1.00)

0.47

Medium

Evenset et al.
(2009)

NO

Remote (Not
Near Source)

2008

17 (0.94)

N/R

Medium

Abbreviations: N/R, Not reported

1.3 Aquatic Organisms - Mammal

1.3.1 Aquatic Organisms - Mammal (ng/g) - Lipid Fraction

Measured concentrations of TCEP in Aquatic Organisms - Mammal with unit of ng/g, extracted from
two sources, are summarized in Figure 1-4 and supplemental information is provided in Table 1-4.
Overall, concentrations ranged from not detected to 115.0 ng/g from 63 samples collected between 2004

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and 2010 in two countries, ES and NO. Location types were categorized as General Population
(Background) and Remote (Not Near Source). Reported detection frequency ranged from 0.0 to 0.44.

NonUS Lipid

5162922 - Hallanger et al., 2015 - NO - Adipose Tissue





| Remote (Not Near Source)
¦m General Population (Background)
ja Non-Detect

•



5469393 - Sala et al., 2019 - ES - Adipose Tissue









5162922 - Hallanger et al., 2015 - NO - Blood





1



5469393 - Sala et al., 2019 - ES - Liver
5469393 - Sala et al., 2019 - ES - Muscle/Filet
5469393 - Sala et al., 2019 - ES - Other









0.001

0.01

0.1

1 10 100
Concentration (ng/g)

1000

Figure 1-4. Concentrations of TCEP (ng/g) in the Lipid Fraction of Aquatic Organisms - Mammal
from 2004 to 2010

Table 1-4. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Lipid

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Hallanger et
al. (2015)

NO

Remote (Not
Near Source)

2010

10 (0.00)

4.5

High

Sala et al.
(2019)

ES

General
Population
(Background)

2004-2010

9(0.11)

1.39

Medium

Hallanser et
al. (2015)

NO

Remote (Not
Near Source)

2009

10 (0.10)

N/R

High

Sala et al.
(2019)

ES

General
Population
(Background)

2004-2010

9 (0.44)

1.39

Medium

Sala et al.
(2019)

ES

General
Population
(Background)

2004-2010

10 (0.10)

1.39

Medium

Sala et al.
(2019)

ES

General
Population
(Background)

2004-2010

15 (0.13)

1.39

Medium

Abbreviations: N/R, Not reported

1.4 Aquatic Organisms - Mollusk	

1.4.1 Aquatic Organisms - Mollusk (ng/g) - All Fractions	

Measured concentrations of TCEP in Aquatic Organisms - Mollusk with unit of ng/g, extracted from
two sources, are summarized in Figure 1-5 and supplemental information is provided in Table 1-5. More

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than one weight fraction was reported and summarized separately below:

Overall, concentrations for Lipid were not detected ng/g from 80 samples collected between 2016 and
2017 in one country, PT. Location types were categorized as Near Facility (Highly Exposed). Reported
detection frequency was 0.25.

Overall, concentrations for Wet ranged from not detected to 0.82 ng/g from five samples collected in
2008 in one country, NL. Location types were categorized as Near Facility (Highly Exposed). Reported
detection frequency was 0.4.

NonUS Lipid

5305891 - Gadelha et al„ 2019 - PT - Other

NonUS Wet

2935128 - Brandsma el al., 2015 - NL - Other





Near Facility (Highly Exposed)
gj Non-Detect

A Normal Distribution (CT and 90th percentile)

*















0.001 0.01 0.1 1 10 100 1000

Concentration (ng/g)

Figure 1-5. Concentrations of TCEP (ng/g) in Aquatic Organisms - Mollusk in Near Facility
(Highly Exposed) Locations from 2008 to 2017

Table 1-5. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in Aquatic
Organisms - Mollusk						

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Lipid

Gadelha et
al. (2019)

PT

Near Facility
(Highly '
Exposed)

2016-2017

80 (0.25)

1.2

High

Wet

Brandsma et
al. (2015)

NL

Near Facility
(Highly '
Exposed)

2008

5 (0.40)

0.2

High

1.5 Aquatic Organisms - Other

1.5.1 Aquatic Organisms - Other (ng/g) - Wet Fraction

Measured concentrations of TCEP in Aquatic Organisms - Other with unit of ng/g, extracted from two
sources, are summarized in Figure 1-6 and supplemental information is provided in Table 1-6. Overall,
concentrations ranged from not detected to 0.33 ng/g from 61 samples collected between 2008 and 2018
in two countries, NL and NO. Location types were categorized as General Population (Background) and
Near Facility (Highly Exposed). Reported detection frequency ranged from 0.0 to 0.2.

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NonUS Wet

Near Facility (Highly Exposed)
g General Population (Background)
g Non-Detect

V Lognormal Distribution (CT and 90th percentile)

2935128 - Brandsma et al., 2015 - NL - Other
7002468 - Norwegian Environment et.al. 2019 - NO - Whole Organism
2935128 - Brandsma et al„ 2015 - NL - Other

0.001

0.01

0.1

1

Concentration (ng/g)

100

1000

Figure 1-6. Concentrations of TCEP (ng/g) in the Wet Fraction of Aquatic Organisms - Other
from 2008 to 2018

Table 1-6. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Wet

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Brandsma et
al. (2015)

NL

Near Facility
(Highly '
Exposed)

2008

5 (0.20)

0.2

High

Norwegian
Environment
(2019b)

NO

General
Population
(Background)

2018

51 (0.00)

0.5

High

Brandsma et
al. (2015)

NL

Near Facility
(Highly '
Exposed)

2008

5 (0.20)

0.42

High

1.6 Dietary

1.6.1 Dietary (ng/g) - Wet Fraction

Measured concentrations of TCEP in Dietary with unit of ng/g, extracted from four sources, are
summarized in Figure 1-7 and supplemental information is provided in Table 1-7. Overall,
concentrations ranged from not detected to 113.0 ng/g from 363 samples collected between 1982 and
2018 in four countries, AU, BE, SE and US. Location types were categorized as fruit, dairy, grain, baby
food-infant formula, vegetables, other, non-dairy beverages, meat, fish and shellfish and fats and oils.
Reported detection frequency ranged from 0.0 to 0.67.

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| fruit





| dairy





¦¦¦1 fch aiu' shellfish



grain





HHI meat





¦¦¦) non-dairy beverages



other





mg vegetables





i—baby food-infant formula



| fats and oils



V Lognormal Distribution (CT and 90th percentile)



A Normal Distribution (CT and 90th percentile)

US Wet



g Non-Detect



659041 - Fda, 1995 - US









I





NonUS Wet















5423396 - He el al., 2018 - AU













5423396-He el al.,2018-AU

























5423396 - He el al., 2018 - AU























5423396-He el al., 2018-AU





mxsmi







5423396 - He el al., 2018 - AU













5423396 - He el al., 2018 - AU

















Hi







5423396 - He el al., 2018 - AU

















HE30







4292130 - Poma el al., 2018 - BE





















m





4292130 - Poma el al., 2018 - BE













4292130 - Poma el al., 2018 - BE









mA





4292130 - Poma el al., 2018 - BE





H./ V





4292130 - Poma el al., 2018 - BE















^¦1 T T





4292130 - Poma el al., 2018 - BE















nj







4292130 - Poma el al., 2018 - BE























4292130 - Poma et al., 2018 - BE



«











5166285 - Poma et al., 2017 - SE





W







5166285 - Poma el al., 2017 - SE







m





5166285 - Poma et al., 2017 - SE





*







5166285 - Poma el al., 2017 - SE













5166285 - Poma et al., 2017 - SE







•







5166285 - Pomaetal.,2017-SE





m







5166285 - Poma et al., 2017 - SE







•







5166285 - Poma el al., 2017 - SE





•









5166285 - Poma et al., 2017 - SE













10A-5 10A-4 0.001 0.01 0.1 1

10 100 1000



Concentralion (ng/g)



Figure 1-7. Concentrations of TCEP (ng/g) in the Wet Fraction of Dietary from 1982 to 2018

Table 1-7. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Wet
Fraction of Dietary					

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

FDA (1995)

US

fruit

1982-1991

74 (0.04)

N/R

Medium

He et al.
(2018b)

AU

dairy

2018

9 (0.56)

0.06

Medium

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

He et al.
(2018b)

AU

fish and
shellfish

2018

9 (0.22)

0.06

Medium

He et al.
(2018b)

AU

grain

2018

12 (0.67)

0.06

Medium

He et al.
(2018b)

AU

meat

2018

12 (0.25)

0.06

Medium

He et al.
(2018b)

AU

non-dairy
beverages

2018

12 (0.08)

0.021

Medium

He et al.
(2018b)

AU

other

2018

3 (0.33)

0.06

Medium

He et al.
(2018b)

AU

vegetables

2018

15 (0.60)

0.06

Medium

Poma et al.
(2018)

BE

baby food-infant
formula

2015-2016

17 (N/R)

0.34

High

Poma et al.
(2018)

BE

dairy

2015-2016

27 (N/R)

0.45

High

Poma et al.
(2018)

BE

fats and oils

2015-2016

10 (0.40)

2.55

High

Poma et al.
(2018)

BE

fish and
shellfish

2015-2016

53 (N/R)

0.07

High

Poma et al.
(2018)

BE

grain

2015-2016

7 (N/R)

0.09

High

Poma et al.
(2018)

BE

meat

2015-2016

38 (N/R)

0.14

High

Poma et al.
(2018)

BE

other

2015-2016

11 (N/R)

0.44

High

Poma et al.
(2018)

BE

vegetables

2015-2016

2 (0.00)

0.01

High

Poma et al.
(2017)

SE

dairy

2015

9 (0.22)

0.3

High

Poma et al.
(2017)

SE

fats and oils

2015

4 (0.00)

2.0

High

Poma et al.
(2017)

SE

fish and
shellfish

2015

5 (0.00)

0.2

High

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Poma et al.
(2017)

SE

fruit

2015

5 (0.20)

0.15

High

Poma et al.
(2017)

SE

grain

2015

5 (0.00)

0.5

High

Poma et al.
(2017)

SE

meat

2015

5 (0.00)

0.2

High

Poma et al.
(2017)

SE

non-dairy
beverages

2015

2 (0.00)

0.45

High

Poma et al.
(2017)

SE

other

2015

8 (0.00)

0.5

High

Poma et al.
(2017)

SE

vegetables

2015

9 (0.67)

0.3

High

Abbreviations: N/R, Not reported

1.6.2 Dietary (ng/g)-Wet Fraction

Measured concentrations of BCEP in Dietary with unit of ng/g, extracted from one source, are
summarized in Figure 1-8 and supplemental information is provided in Table 1-8. Overall,
concentrations ranged from not detected to 10.0 ng/g from 85 samples collected in 2018 in one country,
AU. Location types were categorized as fruit, dairy, grain, vegetables, other, non-dairy beverages, meat
and fish and shellfish. Reported detection frequency ranged from 0.0 to 0.33.





BIB dairy





fish and shellfish





¦ fruit







grain





meat





non-dairy beverages





other





vegetables





A Normal Distribution (CT and 90th percentile)

NonUS Wet



gf Non-Detect

5423396 - He et al., 2018 - AU

















5423396-He et al., 2018-AU





*











5423396 - He et al., 2018 - AU





ft











5423396-He et al., 2018-AU





*











5423396 - He et al., 2018 - AU





*











5423396-He et al.,2018-AU



*













5423396 - He et al., 2018 - AU





«











5423396-He et al.,2018-AU





*











1(V

x-5 10

%-4 0.001 0.01 0.1

10 100



Concentration (ng/g)

Figure 1-8. Concentrations of BCEP (ng/g) in the Wet Fraction of Dietary in 2018

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Table 1-8. Summary of Peer-Reviewed Literature that Measured BCEP (ng/g) Levels in the Wet
Fraction of Dietary						

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

He et al.
(2018b)

AU

dairy

2018

9(0.33)

0.004

Medium

He et al.
(2018b)

AU

fish and
shellfish

2018

9 (0.00)

0.004

Medium

He et al.
(2018b)

AU

fruit

2018

15 (0.00)

0.004

Medium

He et al.
(2018b)

AU

grain

2018

12 (0.00)

0.004

Medium

He et al.
(2018b)

AU

meat

2018

12 (0.00)

0.004

Medium

He et al.
(2018b)

AU

non-dairy
beverages

2018

10 (0.00)

0.0013

Medium

He et al.
(2018b)

AU

other

2018

3 (0.00)

0.004

Medium

He et al.
(2018b)

AU

vegetables

2018

15 (0.00)

0.004

Medium

1.7 Drinking Water

1.7.1 Drinking Water (ng/L) - Not Specified Fraction

Measured concentrations of TCEP in Drinking Water with unit of ng/L, extracted from nine sources, are
summarized in Figure 1-9 and supplemental information is provided in Table 1-9. Overall,
concentrations ranged from not detected to 1,400.0 ng/L from 675 samples collected between 1982 and
2014 in six countries, CA, ES, JP, KR, PR and US. Location types were categorized as General
Population (Background) and Unknown/Not Specified. Reported detection frequency ranged from 0.0 to
0.88.

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us

4253347 - Padhye et al., 2014 - US

3975066 - Hopple et al., 2009 - US
3364193 - Kingsbury et al., 2008 - US

Mix

3559503 - Focazio et al., 2008 - PR,US
1487184 - Lebel et al., 1987 - CA,US

NonUS

3455908 - Lee et al., 2016 - KR

5469210 - Valcarcel et al., 2018 - ES

1250860 - Rodil et al., 2012 - ES

5469582 - Yasuhara, 1994 - JP

10*-6	10A-4	0.01	1

Concentration (ng/L)

Figure 1-9. Concentrations of TCEP (ng/L) in the Not Specified Fraction of Drinking Water from
1982 to 2014

Table 1-9. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Not
Specified Fraction of Drinking Water					

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Padhve et al.
(2014)

US

General
Population
(Background)

2009-2010

8 (0.88)

N/R

Medium

Hopple et al.
(2009)

US

General
Population
(Background)

2004-2005

57 (0.02)

500.0

High

Kinssburv et
al. (2008)

us

General
Population
(Background)

2002-2004

337 (0.33)

500.0

High

Focazio et al.
(2008)

PR, US

Unknown/Not
Specified

2001

73 (0.21)

100.0

Medium

Lebel et al.
(1987)

CA, US

General
Population
(Background)

1982-1983

20 (0.55)

N/R

Medium

Lee et al.
(2016)

KR

General
Population
(Background)

2014

127 (0.75)

0.7

Medium

Valcarcel et
al. (2018)

ES

General
Population
(Background)

2013

28 (0.75)

0.03

Medium

Page 21 of 83

General Population (Background)
¦ Unknown/Not Specified
V Lognormal Distribution (CT and 90th percentile)
gs Non-Detect

I?v

ft

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Rodil et al.
(2012)

ES

General
Population
(Background)

2007-2008

24 (0.71)

4.0

Medium

Yasuhara
(1994)

JP

General
Population
(Background)

1994

1 (0.00)

67.5

Medium

Abbreviations: N/R, Not reported

1.8 Dust (Indoor)

1.8.1 Dust (Indoor) (ng/g) - Dry Fraction

Measured concentrations of TCEP in Dust (Indoor) with unit of ng/g, extracted from 45 sources, are
summarized in Figure 1-10 and supplemental information is provided in Table 1-10. Overall,
concentrations ranged from not detected to 1,800,000.0 ng/g from 4,578 samples collected between
2000 and 2019 in 20 countries, AT, AU, BE, CA, CN, DE, DK, ES, FI, GB, GR, JP, KR, NL, NO, NZ,
PT, RO, SE and US. Location types were categorized as Vehicle, Other, Public Space and Residential.
Reported detection frequency ranged from 0.17 to 1.0.

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us

Mix

NonUS

4161719 - Hoffman et al., 2017 - US
5163584 - Phillips et al., 2018 - US
6968217 - Shin et al., 2019 - US
3012534 - La Guardia and Hale, 2015 - US
3012534 - La Guardia and Hale, 2015 - US
2343712 - Stapleton et al., 2014 - US
2528320 - Schreder and La Guardia, 2014 - US
2539068 - Bradman et al., 2014 - US
2215665 - Shin et al., 2014 - US
1676728 - Fang et al., 2013 - US
1676728 - Fang et al., 2013 - US
3864462 - Castorina et al., 2017 - US

5184432 - Tan et al., 2019 - CN,US

5043338 - Velazquez-Gomez et al., 2019 - ES
5043338 - Velazquez-Gomez et al., 2019 - ES
5043338 - Velazquez-Gomez et al., 2019 - ES
5163693 - Rantakokko et al., 2019 - FI
5165944 - Liu and Mabury, 2019 - CA
5412073 - Giovanoulis et al., 2019 - SE
3223090 - Langer et al., 2016 - DK
3223090 - Langer et al., 2016 - DK
4292121 - Christia et al., 2018 - GR
4292129 - Deng et al., 2018 - CN
4292133 - Persson et al., 2018 - SE
3862555 - Zhou el al., 2017 - DE
3862555 - Zhou et al., 2017 - DE
3862555 - Zhou et al., 2017 - DE
4285929-He et al., 2018-AU

0.01

| Residential
¦ Public Space
¦Bl Vehicle
V Lognormal Distribution (CT and 90th percentile)
A Normal Distribution (CT and 90th percentile)

¦xa:

ED

¦za

t7 V

V
> V

S7V

V

W

IV V

IV V

I V V

I vv

I V V

~ v

IV

Pv

I V V

10	100	1000	10A4

Concentration (ng/g) (pt 1)

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NonUS

4285929-He ct al., 2018-AU
4285929-He et al., 2018-AU
4292136 - Larsson et al., 2018 - SE
3005686 - Takeuchi et al., 2015 - JP
3357642 - Xu et al., 2016 - NO
4178500 - Kim and Tanabe, 2017 - KR
4178500 - Kim and Tanabe, 2017 - KR
4433160 - Kademoglou et al., 2017 - GB.NO
1313395 - Wallner et al., 2012 - AT
3604490 - Tokumura et al., 2017 - JP
3975074 - Sugeng et al., 2017 - NL
4433160 - Kademoglou et al., 2017 - GB
4829235 - Ait Bamai et al., 2018 - JP
1927602-Ali et al., 2012-NZ
2537005 - Fromme et al., 2014 - DE
2540527 - Brandsma et al., 2014 - NL
2540527 - Brandsma el al., 2014 - NL
3350460 - Coelho et al., 2016 - PT
5164389 - Brommer et al., 2012 - DE
788335 - Bergh et al., 2011 - SE
788335 - Bergh et al., 2011 - SE
1927614 - Van den Eede et al., 2012 - BE,ES,RO
2542290 - Tajima et al., 2014 - JP
2543095 - Fan et al., 2014 - CA
3015040 - Mizouchi et al., 2015 - JP
5469392 - Bastiaensen et al., 2019 - JP
5469670 - Luongo and Oestman, 2016 - SE
697390 - Kanazawa et al., 2010 - JP
2919501 - Marklund et al., 2003 - SE
2919501 - Marklund et al., 2003 - SE

0.01

| Residential
¦ Public Space
Vehicle
Other

V Lognormal Distribution (CT and 90th percentile)
A Normal Distribution (CT and 90th percentile)

^57



m

I V V

I vv

Bv

W

E2 v

¦7 V

V

V

w

HW 1*1 !<¦

m

hd

10	100	1000	10A4

Concentration (ng/g) (pt 2)

NonUS

¦—i Residential
Vehicle

A Normal Distribution (CT and 90th percentile)

2919501 - Marklund et al.. 2003 - SE
2919501 - Marklund et al., 2003 - SE
4731349 - Ingerowski et al.. 2001 - DE

0.01











i













¦	



10	100	1000	10A4

Concentration (ng/g) (pt 3)

Figure 1-10. Concentrations of TCEP (ng/g) in the Dry Fraction of Dust (Indoor) from 2000 to
2019

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Table 1-10. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry
Fraction of Dust (Indoor) 					

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Hoffman et
al. (2017)

US

Residential

2014-2016

140 (N/R)

N/R

Medium

Phillips et al.
(2018)

US

Residential

2014-2016

188 (0.98)

18.7

High

Shin et al.
(2019)

us

Residential

2015-2016

38 (0.97)

25.0

Medium

La Guardia
and Hale
(2015)

us

Public Space

2013

4(1.00)

100.0

Medium

La Guardia
and Hale
(2015)

us

Residential

2013

4(1.00)

100.0

Medium

Stapleton et
al. (2014)

us

Residential

2012

30 (1.00)

N/R

High

Schreder and
La Guardia
(2014)

us

Residential

2011-2012

20 (0.95)

1.0

High

Bradman et
al. (2014)

us

Public Space

2010-2011

39 (1.00)

1.0

High

Shin et al.
(2014)

us

Residential

2009-2010

30 (1.00)

1.0

High

Fans et al.
(2013)

us

Residential

2009

20 (0.50)

20.0

Medium

Fans et al.
(2013)

us

Vehicle

2009

20 (0.95)

20.0

Medium

Castorina et
al. (2017)

us

Residential

2000-2001

125 (1.00)

27.9

High

Tan et al.
(2019)

CN, US

Residential

2019

47 (1.00)

10.0

High

Velazauez-
Gomez et al.
(2019)

ES

Public Space

2019

33 (1.00)

N/R

Medium

Velazauez-
Gomez et al.
(2019)

ES

Residential

2019

11 (1.00)

N/R

Medium

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Velazquez-
Gomez et al.
(2019)

ES

Vehicle

2019

14 (1.00)

N/R

Medium

Rantakokko
et al. (2019)

FI

Residential

2019

40 (1.00)

3.0

Medium

Liu and
Maburv
(2019)

CA

Public Space

2018

85 (1.00)

0.4

High

Giovanoulis
et al. (2019)

SE

Public Space

2018

20 (1.00)

34.0

High

Lanser et al.
(2016)

DK

Public Space

2016

151 (0.78)

600.0

High

Lanser et al.
(2016)

DK

Residential

2016

497 (0.69)

600.0

High

Christia et al.
(2018)

GR

Vehicle

2016

25 (0.80)

N/R

High

Dens et al.
(2018)

CN

Public Space

2015-2016

22 (1.00)

N/R

Medium

Persson et al.
(2018)

SE

Public Space

2015-2016

31 (0.58)

6.9

High

Zhou et al.
(2017)

DE

Public Space

2015

48 (0.83)

115.0

High

Zhou et al.
(2017)

DE

Residential

2015

15 (0.80)

115.0

High

Zhou et al.
(2017)

DE

Vehicle

2015

11 (0.82)

115.0

High

He et al.
(2018c)

AU

Public Space

2015

30 (1.00)

10.0

High

He et al.
(2018c)

AU

Residential

2015

40 (1.00)

10.0

High

He et al.
(2018c)

AU

Vehicle

2015

15 (1.00)

10.0

High

Larsson et al.
(2018)

SE

Public Space

2015

100 (0.61)

1200.0

High

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Takeuchi et
al. (2015)

JP

Residential

2013-2014

19 (0.95)

N/R

High

Xu et al.
(2016)

NO

Residential

2013-2014

122 (0.76)

170.0

Medium

Kim and
Tanabe
(2017)

KR

Public Space

2014

6(0.17)

N/R

High

Kim and
Tanabe
(2017)

KR

Residential

2013-2014

14 (1.00)

N/R

High

Kademoalou
et al. (2017)

GB,NO

Residential

2013-2014

20 (1.00)

44.1

Medium

Wallner et al.
(2012)

AT

Public Space

2012-2013

36 (1.00)

N/R

Medium

Tokumura et
al. (2017)

JP

Vehicle

2013

37 (1.00)

180.0

High

Suaena et al.
(2017)

NL

Residential

2013

28 (0.82)

N/R

Medium

Kademoalou
et al. (2017)

GB

Public Space

2013

12 (1.00)

44.1

Medium

Ait Bamai et
al. (2018)

JP

Residential

2013

296 (0.84)

N/R

Medium

Ali et al.
(2012)

NZ

Residential

2012

50 (0.98)

20.0

Medium

Fromme et
al. (2014)

DE

Public Space

2011-2012

63 (1.00)

200.0

Medium

Brandsma et
al. (2014)

NL

Residential

2012

16 (1.00)

70.0

High

Brandsma et
al. (2014)

NL

Vehicle

2012

16 (1.00)

70.0

High

Coelho et al.
(2016)

PT

Residential

2010-2011

28 (0.82)

4.0

Medium

Brommer et
al. (2012)

DE

Residential

2010-2011

6 (N/R)

80.0

Medium

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Bersh et al.
(2011b)

SE

Public Space

2010

20 (N/R)

N/R

Medium

Bersh et al.
(2011b)

SE

Residential

2010

10 (N/R)

N/R

Medium

Van den
Eede et al.
(2012)

BE,ES,RO

Residential

2006-2010

12 (1.00)

110.0

Medium

Taiimaet al.
(2014)

JP

Residential

2009-2010

256 (0.51)

1000.0

High

Fan et al.
(2014)

CA

Residential

2010

268 (0.96)

70.0

High

Mizouchi et
al. (2015)

JP

Residential

2009-2010

10 (1.00)

10.0

High

Bastiaensen
et al. (2019a)

JP

Residential

2009-2010

196 (0.59)

N/R

High

Luonso and
Oestman
(2016)

SE

Residential

2008

62 (0.97)

190.0

Medium

Kanazawa et
al. (2010)

JP

Residential

2006

82 (0.95)

1300.0

Medium

Marklund et
al. (2003)

SE

Other

2003

5 (1.00)

N/R

Medium

Marklund et
al. (2003)

SE

Public Space

2003

9(1.00)

N/R

Medium

Marklund et
al. (2003)

SE

Residential

2003

2(1.00)

N/R

Medium

Marklund et
al. (2003)

SE

Vehicle

2003

1 (1.00)

N/R

Medium

Inserowski et
al. (2001)

DE

Residential

2001

983 (N/R)

400.0

Medium

Abbreviations: N/R, Not reported

1.8.2 Dust (Indoor) (ng/g) - Dry Fraction

Measured concentrations of BCEP in Dust (Indoor) with unit of ng/g, extracted from one source, are
summarized in Figure 1-11 and supplemental information is provided in Table 1-11. Overall,
concentrations were not detected ng/g from 47 samples collected in 2019 in two countries, CN and US.

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Location types were categorized as Residential. Reported detection frequency was 0.0.

Mix

5184432 - Tan ct al., 2019 - CN,US



•

Residential
)g Non-Detect









0.01

0.1

1 10

100 1000 10A4
Concentration (ng/g)

10A5

10A6

10A7

Figure 1-11. Concentrations of BCEP (ng/g) in the Dry Fraction of Dust (Indoor) in Residential
Locations in 2019

Table 1-11. Summary of Peer-Reviewed Literature that Measured BCEP (ng/g) Levels in the Dry
Fraction of Dust (Indoor) 					

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Tan et al.
(2019)

CN,US

Residential

2019

47 (0.00)

16

High

1.8.3 Dust (Indoor) (ng/m2) - Dry Fraction	

Measured concentrations of TCEP in Dust (Indoor) with unit of ng/m2, extracted from four sources, are
summarized in Figure 1-12 and supplemental information is provided in Table 1-12. Overall,
concentrations ranged from not detected to 1,243,900.0 ng/m2 from 180 samples collected between 2000
and 2016 in two countries, SE and US. Location types were categorized as Public Space, Unknown and
Residential. Reported detection frequency ranged from 0.0 to 1.0.

us

5755270 - Dodson et al., 2017 - US
3864462 - Castorina et al., 2017 - US

Residential
| Public Space

Unknown
gi Non-Detect

A Normal Distribution (CT and 90th percentile)
*



NonUS









4292133 - Persson et al., 2018 - SE







2919501 - Marklund et al., 2003 - SE

A





0.001 0.1

10 1000 10A5
Concentration (ng/m2)

10*7

Figure 1-12. Concentrations of TCEP (ng/m2) in the Dry Fraction of Dust (Indoor) from 2000 to
2016

Table 1-12. Summary of Peer-Reviewed Literature that Measured TCEP (ng/m2) Levels in the
Dry Fraction of Dust (Indoor)					

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/m2)

Overall
Quality
Level

Dodson et al.
(2017)

US

Residential

2013-2014

37 (0.00)

10,763.91042

High

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/m2)

Overall
Quality
Level

Castorina et
al. (2017)

US

Residential

2000-2001

125 (1.00)

27.9

High

Persson et al.
(2018)

SE

Public Space

2015-2016

16 (0.44)

0.07

High

Marklund et
al. (2003)

SE

Unknown

2003

2(1.00)

N/R

Medium

Abbreviations: N/R, Not reported

1.9 Groundwater

1.9.1 Groundwater (ng/L) - Not Specified Fraction

Measured concentrations of TCEP in Groundwater with unit of ng/L, extracted from 11 sources, are
summarized in Figure 1-13 and supplemental information is provided in Table 1-13. Overall,
concentrations ranged from not detected to 810.0 ng/L from 582 samples collected between 1978 and
2017 in four countries, DE, JP, SE and US. Location types were categorized as General Population
(Background) and Near Facility (Highly Exposed). Reported detection frequency ranged from 0.0 to 1.0.





Near Facility (Highly Exposed)







BIB General Population (Background)







V Lognormal Distribution (CT and 90th percentile)





A Normal Distribution (CT and 90th percentile)

us



g Non-Detect



5469289 - Laws et al., 2011 - US









2



3975066 - Hopple et al., 2009 - US











4912133 - Buszka et al., 2009 - US









Si



4832201 - Barnes et al., 2008 - US













5469339 - Barnes et al., 2004 - US







n v



1316091 - Hutchins et al., 1984 - US













NonUS













5428453 - Gao et al., 2019 - SE





^K7 v ¦



2579610 - Regnery et al., 2011 - DE











>

0

1











2579610 - Regnery et al., 2011 - DE







5469313 - Fries and Puttmann, 2003 - DE













5469312 - Fries and Puttmann, 2001 - DE















v

V



5469582 - Yasuhara, 1994 - JP







*





0.01 0.1

10 100 1000





Concentration (ng/L)



Figure 1-13. Concentrations of TCEP (ng/L) in the Not Specified Fraction of Groundwater from
1978 to 2017

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Table 1-13. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Not
Specified Fraction of Groundwater					

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Laws et al.
(2011)

US

Near Facility
(Highly Exposed)

2009

11 (1.00)

10.0

Medium

Hopple et al.
(2009)

US

General
Population
(Background)

2002-2005

276 (0.02)

500.0

High

Buszka et al.
(2009)

us

Near Facility
(Highly Exposed)

2000-2002

6(0.33)

500.0

Medium

Barnes et al.
(2008)

us

Near Facility
(Highly Exposed)

2000

47 (0.30)

500.0

Medium

Barnes et al.
(2004)

us

Near Facility
(Highly Exposed)

2000

5 (1.00)

40.0

Medium

Hutchins et
al. (1984)

us

Near Facility
(Highly Exposed)

1978

4 (N/R)

N/R

Medium

Gao et al.
(2019)

SE

General
Population
(Background)

2016-2017

30 (0.83)

7.2

High

Reanerv et
al. (2011)

DE

General
Population
(Background)

2009

25 (0.56)

1.0

High

Reanerv et
al. (2011)

DE

Near Facility
(Highly Exposed)

2009

11 (0.91)

1.0

High

Fries and
Puttmann
(2003)

DE

General
Population
(Background)

2000-2001

76 (N/R)

1.0

Medium

Fries and
Puttmann
(2001)

DE

General
Population
(Background)

2000

90 (N/R)

1.0

Medium

Yasuhara
(1994)

JP

General
Population
(Background)

1994

1 (0.00)

67.5

Medium

Abbreviations: N/R, Not reported

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1.10 Human Biomonitoring - Breastmilk

1.10.1 Human Biomonitoring - Breastmilk (ng/L) - wet Fraction

Measured concentrations of TCEP in Human Biomonitoring - Breastmilk with unit of ng/L, extracted
from one source, are summarized in Figure 1-14 and supplemental information is provided in Table 1-
14. Overall, concentrations ranged from not detected to 470 ng/L from three samples collected between
2014 and 2015 in one country, AU. Location types were categorized as General Population
(Background). Reported detection frequency was 0.67.

NonUS

5469782-He et al., 2018-AU

| General Population (Background)
y Lognormal Distribution (CT and 90th percentile)





10

100

Concentration (ng/L)

1000

Figure 1-14. Concentrations of TCEP (ng/L) in the wet Fraction of Human Biomonitoring -
Breastmilk in General Population (Background) Locations from 2014 to 2015

Table 1-14. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the wet
Fraction of Human Biomonitoring - Breastmilk				

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

He et al.
(2018a)

AU

General
Population
(Background)

2014-2015

3 (0.67)

260

High

1.10.2 Human Biomonitoring - Breastmilk (ng/g) - Lipid Fraction

Measured concentrations of TCEP in Human Biomonitoring - Breastmilk with unit of ng/g, extracted
from 2 sources, are summarized in Figure 1-15 and supplemental information is provided in Table 1-15.
Overall, concentrations ranged from not detected to 512.0 ng/g from 93 samples collected between 1997
and 2011 in four countries, JP, PH, SE and VN. Location types were categorized as General Population
(Background) and Near Facility (Highly Exposed). Reported detection frequency was 1.0.

NonUS





H General Population (Background)

Near Facility (Highly Exposed)

V Lognormal Distribution (CT and 90th percentile)





2921301 - Kim et al„ 2014 - JP.PH.VN









2921301 - Kim et al., 2014 - PH,VN

















2586188 - Sundkvist et al., 2010 - SE



ma





0.001

0.01

0.1 1 10 100
Concentration (ng/g)

1000

Figure 1-15. Concentrations of TCEP (ng/g) in the Lipid Fraction of Human Biomonitoring -
Breastmilk from 1997 to 2011

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Table 1-15. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the
Lipid Fraction of Human Biomonitoring - Breastmilk 			

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Kim et al.
(2014)

JP, PH, VN

General
Population
(Background)

2008-2011

46 (N/R)

0.045

Medium

Kim et al.
(2014)

PH, VN

Near Facility
(Highly '
Exposed)

2008

41 (N/R)

0.045

Medium

Sundkvist et
al. (2010)

SE

General
Population
(Background)

1997-2006

6(1.00)

0.4

High

Abbreviations: N/R, Not reported

1.11 Human Biomonitoring - Hair

1.11.1 Human Biomonitoring - Hair (ng/g) - Dry Fraction

Measured concentrations of TCEP in Human Biomonitoring - Hair with unit of ng/g, extracted from two
sources, are summarized in Figure 1-16 and supplemental information is provided in Table 1-16.

Overall, concentrations ranged from 37.5 to 2,740 ng/g from 55 samples collected between 2014 and
2015 in one country, US. Location types were categorized as General Population (Background).

Reported detection frequency ranged from 0.68 to 0.8.

US Drv

3031004 - Liuet al., 2015 - US
5176476 - Liu ctal., 2016 -US



General Population (Background)
A Normal Distribution (CT and 90th percentile)

& A





1

10

100 1000
Concentration (ng/g)

10A4

Figure 1-16. Concentrations of TCEP (ng/g) in the Dry Fraction of Human Biomonitoring - Hair
in General Population (Background) Locations from 2014 to 2015

Table 1-16. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry
Fraction of Human Biomonitoring - Hair 				

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Liu et al.
(2015)

US

General
Population
(Background)

2015

5 (0.80)

75.0

Medium

Liu et al.
(2016)

US

General
Population
(Background)

2014

50 (0.68)

N/R

Medium

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Abbreviations: N/R, Not reported

1.12 Human Bio monitoring - Nails

1.12.1 Human Biomonitoring - Nails (ng/g) - Dry Fraction

Measured concentrations of TCEP in Human Biomonitoring - Nails with unit of ng/g, extracted from
two sources, are summarized in Figure 1-17 and supplemental information is provided in Table 1-17.
Overall, concentrations ranged from not detected to 1860.0 ng/g from 105 samples collected between
2014 and 2015 in one country, US. Location types were categorized as General Population
(Background). Reported detection frequency ranged from 0.0 to 0.14.







mmu

General Population (Background)









H

Non-Detect



US Drv





V

Lognormal Distribution (CT and 90th percentile)



3031004 - Liu et al.f 2015 - US



•







5176476 - Liu et al., 2016 - US





1

<
<





1

10

100

1000

10A4







Concentration (ng/g)



Figure 1-17. Concentrations of TCEP (ng/g) in the Dry Fraction of Human Biomonitoring - Nails
in General Population (Background) Locations from 2014 to 2015

Table 1-17. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry
Fraction of Human Biomonitoring - Nails 				

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Liu et al.
(2015)

US

General
Population
(Background)

2015

5 (0.00)

150.0

Medium

Liu et al.
(2016)

US

General
Population
(Background)

2014

100 (0.14)

N/R

Medium

Abbreviations: N/R, Not reported

1.13 Human Biomonitoring - Other

1.13.1 Human Biomonitoring - Other (ng/g) - Dry Fraction

Measured concentrations of TCEP in Human Biomonitoring - Other with unit of ng/g, extracted from
one source, are summarized in Figure 1-18 and supplemental information is provided in Table 1-18.
Overall, concentrations ranged from 0.055 to 41.8 ng/g from 100 samples collected between 2014 and
2016 in one country, CN. Location types were categorized as General Population (Background).
Reported detection frequency was 0.66.

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NonUS Drv







General Population (Background)





3866506 - Zhao et a

..2017 - CN













0.001

0.01

0.1 1
Concentration (ng/g)

10

100

Figure 1-18. Concentrations of TCEP (ng/g) in the Dry Fraction of Human Biomonitoring - Other
in General Population (Background) Locations from 2014 to 2016

Table 1-18. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry
Fraction of Human Biomonitoring - Other

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Zhao et al.
(2017)

CN

General
Population
(Background)

2014-2016

100 (0.66)

0.11

High

1.13.2 Human Biomonitoring - Other (ng/g) - Dry Fraction

Measured concentrations of BCEP in Human Biomonitoring - Other with unit of ng/g, extracted from
one source, are summarized in Figure 1-19 and supplemental information is provided in Table 1-19.
Overall, concentrations ranged from 0.44 to 1,180 ng/g from 50 samples collected between 2014 and
2016 in one country, CN. Location types were categorized as General Population (Background).
Reported detection frequency was 0.88.

NonUS Drv







General Population (Background)





3866506 - Zhao et al., 2017 - CN













0.001

0.01

0.1

1 10 100

1000

10A4









Concentration (ng/g)





Figure 1-19. Concentrations of BCEP (ng/g) in the Dry Fraction of Human Biomonitoring - Other
in General Population (Background) Locations from 2014 to 2016

Table 1-19. Summary of Peer-Reviewed Literature that Measured BCEP (ng/g) Levels in the Dry
Fraction of Human Biomonitoring - Other 				

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Zhao et al.
(2017)

CN

General
Population
(Background)

2014-2016

50 (0.88)

0.88

High

1.14 Human Biomonitoring - Plasma

1.14.1 Human Biomonitoring - Plasma (ng/L) - Wet Fraction

Measured concentrations of TCEP in Human Biomonitoring - Plasma with unit of ng/L, extracted from
one source, are summarized in Figure 1-20 and supplemental information is provided in Table 1-20.
Overall, concentrations ranged from not detected to 230 ng/L from 25 samples collected between 2014
and 2016 in one country, CN. Location types were categorized as General Population (Background).

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Reported detection frequency was 0.48.

NonUS

3866506 - Zhao et ah, 2017 - CN



| | General Population (Background)
A Normal Distribution (CT and 90th percentile)





1

10

100

Concentration (ng/L)

1000

Figure 1-20. Concentrations of TCEP (ng/L) in the Wet Fraction of Human Biomonitoring -
Plasma in General Population (Background) Locations from 2014 to 2016

Table 1-20. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Wet
Fraction of Human Biomonitoring - Plasma				

Citation

Country

Location Type

Sampling
Year

Sample
Size
(Frequency
of

Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Zhao et al.
(2017)

CN

General
Population
(Background)

2014-
2016

25 (0.48)

90

High

1.15 Human Biomonitoring - Serum

1.15.1 Human Biomonitoring - Serum (ng/g) - Lipid Fraction

Measured concentrations of TCEP in Human Biomonitoring - Serum with unit of ng/g, extracted from
one source, are summarized in Figure 1-21 and supplemental information is provided in Table 1-21.
Overall, concentrations ranged from 3.12 to 3.69 ng/g from 20 samples collected in 2016 in one country,
ES. Location types were categorized as General Population (Background). Reported detection frequency
was 1.0.

NonUS Lipid

3984272 - Hcnriqucz-Hcrnandez ct al., 2017 - ES

General Population (Background)
A Normal Distribution (CT and 90th percentile)

m a



0.1

i

Concentration (ng/g)

10

Figure 1-21. Concentrations of TCEP (ng/g) in the Lipid Fraction of Human Biomonitoring -
Serum in General Population (Background) Locations in 2016

Table 1-21. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the
Lipid Fraction of Human Biomonitoring - Serum				

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Henriquez-
Hernandez et
al. (2017)

ES

General
Population
(Background)

2016

20 (1.00)

N/R

High

Abbreviations: N/R, Not reported

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1.16 Human Biomonitoring - SkinDermal Wipe

1.16.1 Human Biomonitoring - Skin Dermal Wipe (ng/g) - Dry Fraction

Measured concentrations of TCEP in Human Biomonitoring - Skin Dermal Wipe with unit of ng/g,
extracted from one source, are summarized in Figure 1-22 and supplemental information is provided in
Table 1-22. Overall, concentrations ranged from 20 to 6,920 ng/g from 30 samples collected in 2012 in
one country, US. Location types were categorized as General Population (Background). Reported
detection frequency was 1.0.

US

2343712 - Stapleton et al., 2014 - US



^¦¦Z General Population (Background)





10 100 1000 10A4
Concentration (ng/g)

Figure 1-22. Concentrations of TCEP (ng/g) in the Dry Fraction of Human Biomonitoring -
Skin Dermal Wipe in General Population (Background) Locations in 2012

Table 1-22. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry
Fraction of Human Biomonitoring - Skin Dermal Wipe 			

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Stapleton et
al. (2014)

US

General
Population
(Background)

2012

30 (1.00)

N/R

High

Abbreviations: N/R, Not reported

1.16.2 Human Biomonitoring - Skin Dermal Wipe (ng/wipe) - Dry Fraction

Measured concentrations of TCEP in Human Biomonitoring - Skin Dermal Wipe with unit of ng/wipe,
extracted from four sources, are summarized in Figure 1-23 and supplemental information is provided in
Table 1-23. Overall, concentrations ranged from not detected to 3,216 ng/wipe from 400 samples
collected between 2012 and 2016 in three countries, NO, SE and US. Location types were categorized as
General Population (Background). Reported detection frequency ranged from 0.47 to 0.87.

us

5163584 - Phillips et al., 2018 - US

General Population (Background)











2343712 - Stapleton et al., 2014 - US





NonUS

4292136 - Larsson et al., 2018 - SE
3357642 - Xu et al., 2016 - NO







0.1

10 100 1000
Concentration (ng/wipe)

10A4

Figure 1-23. Concentrations of TCEP (ng/wipe) in the Dry Fraction of Human Biomonitoring -
Skin Dermal Wipe in General Population (Background) Locations from 2012 to 2016

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Table 1-23. Summary of Peer-Reviewed Literature that Measured TCEP (ng/wipe) Levels in the
Dry Fraction of Human Biomonitoring - Skin Dermal Wipe			

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection

Limit
(ng/wipe)

Overall
Quality
Level

Phillips et al.
(2018)

US

General
Population
(Background)

2014-2016

202 (0.87)

2.7

High

Stapleton et
al. (2014)

US

General
Population
(Background)

2012

43 (0.47)

24.0

High

Larsson et al.
(2018)

SE

General
Population
(Background)

2015

100 (0.51)

4.5

High

Xu et al.
(2016)

NO

General
Population
(Background)

2013-2014

55 (0.49)

N/R

Medium

Abbreviations: N/R, Not reported

1.17 Human Biomonitoring - Urine

1.17.1 Human Biomonitoring - Urine (ng/g) - Creatinine Adjusted Fraction

Measured concentrations of BCEP in Human Biomonitoring - Urine with unit of ng/g, extracted from
one source, are summarized in Figure 1-24 and supplemental information is provided in Table 1-24.
Overall, concentrations ranged from not detected to 1900 ng/g from 213 samples collected in 2018 in
one country, US. Location types were categorized as General Population (Background). Reported
detection frequency was 0.87.

US Creatinine Adjusted

5164613-Wang et al., 2019-US



General Population (Background)
\7 Lognormal Distribution (CT and 90th percentile)



0.1

10 100 1000 10A4
Concentration (ng/g)

Figure 1-24. Concentrations of BCEP (ng/g) in the Creatinine Adjusted Fraction of Human
Biomonitoring - Urine in General Population (Background) Locations in 2018

Table 1-24. Summary of Peer-Reviewed Literature that Measured BCEP (ng/g) Levels in the
isted Fraction of Human Biomonitoring - Urine

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Wane et al.
(2019)

US

General
Population
(Background)

2018

213 (0.87)

2.7

High

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1.17.2 Human Biomonitoring - Urine (ng/L) - Unadjusted Fraction	

Measured concentrations of TCEP in Human Biomonitoring - Urine with unit of ng/L, extracted from
three sources, are summarized in Figure 1-25 and supplemental information is provided in Table 1-25.
Overall, concentrations ranged from not detected to 24500 ng/L from 594 samples collected between
2010 and 2015 in two countries, AU and BE. Location types were categorized as General Population
(Background). Reported detection frequency ranged from 0.11 to 0.55.

NonUS Unadjusted



General Population (Background)



5469782 - He et al., 2018 - AU







5562397 - Bastiaensen et al., 2019 - BE













3020426 - Van Den Eede et al., 2015 - AU







0.1

10

100 1000 10A4
Concentration (ng/L)

10A5

Figure 1-25. Concentrations of TCEP (ng/L) in the Unadjusted Fraction of Human Biomonitoring
- Urine in General Population (Background) Locations from 2010 to 2015

Table 1-25. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the
Unadjusted Fraction of Human Biomonitoring - Urine 			

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

He et al.
(2018a)

AU

General
Population
(Background)

2014-2015

400 (0.45)

22.0

High

Bastiaensen
et al. (2019b)

BE

General
Population
(Background)

2015

99 (0.55)

32.0

Medium

Van Den
Eede et al.
(2015)

AU

General
Population
(Background)

2010-2013

95 (0.11)

350.0

Medium

1.17.3 Human Biomonitoring - Urine (ng/L) - All Fractions

Measured concentrations of BCEP in Human Biomonitoring - Urine with unit of ng/L, extracted from
four sources, are summarized in Figure 1-26 and supplemental information is provided in Table 1-26.
More than one weight fraction was reported and summarized separately below:

Overall, concentrations for Creatinine Adjusted ranged from not detected to 13.5 ng/L from 213 samples
collected in 2018 in one country, US. Location types were categorized as General Population
(Background). Reported detection frequency was 0.87.

Overall, concentrations for Unadjusted ranged from not detected to 13100.0 ng/L from 728 samples
collected between 2011 and 2015 in three countries, AU, DE and US. Location types were categorized
as General Population (Background). Reported detection frequency ranged from 0.15 to 0.75.

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US Creatinine Adjusted

5164613 - Wang et al., 2019 - US

General Population (Background)
V Lognormal Distribution (CT and 90th percentile)



US Unadjusted

2533847 - Dodson et al., 2014 - US





NonUS Unadjusted

5469782 - He et al., 2018 - AU







2537005 - Fromme et al., 2014 - DE







0.1

1 10 100 1000 10"4
Concentration (ng/L)

10A5

Figure 1-26. Concentrations of BCEP (ng/L) in Human Biomonitoring - Urine in General
Population (Background) Locations from 2011 to 2018

Table 1-26. Summary of Peer-Reviewed Literature that Measured BCEP (ng/L) Levels in Human
Biomonitoring - Urine						

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Creatinine Adjusted

Wane et al.
(2019)

US

General
Population
(Background)

2018

213 (0.87)

2.7

High

Unadjusted

Dodson et al.
(2014)

US

General
Population
(Background)

2011

16 (0.75)

100.0

High

He et al.
(2018a)

AU

General
Population
(Background)

2014-2015

400 (0.15)

14.0

High

Fromme et
al. (2014)

DE

General
Population
(Background)

2011-2012

312(0.65)

200.0

Medium

1.18 Human Biomonitoring - Silicone Wristbands

1.18.1 Human Biomonitoring - Silicone Wristbands (ng/g) - Not Specified Fraction

Measured concentrations of TCEP in Human Biomonitoring - Silicone Wristbands with unit of ng/g,
extracted from two sources, are summarized in Figure 1-27 and supplemental information is provided in
Table 1-27. Overall, concentrations ranged from not detected to 719.0 ng/g from 140 samples collected
between 2012 and 2015 in one country, US. Location types were categorized as General Population
(Background). Reported detection frequency ranged from 0.83 to 0.89.

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us

5165046 - Gibson et al., 2019 - US



| General Population (Background)
gj Non-Detect













3361031 -Kilect al., 2016-US

*







0.1

1

10 100
Concentration (ng/g)

1000

Figure 1-27. Concentrations of TCEP (ng/g) in the Not Specified Fraction of Human
Biomonitoring - Silicone Wristbands in General Population (Background) Locations from 2012 to
2015

Table 1-27. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Not
Specified Fraction of Human Biomonitoring - Silicone Wristbands 		

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Gibson et al.
(2019)

US

General
Population
(Background)

2015

76 (0.83)

3.27

High

Kile et al.
(2016)

US

General
Population
(Background)

2012-2013

64 (0.89)

3.4

Medium

1.19 Indoor Air

1.19.1 Indoor Air (ng/m3) - All Fractions

Measured concentrations of TCEP in Indoor Air with unit of ng/m3, extracted from 27 sources, are
summarized in Figure 1-28 and supplemental information is provided in Table 1-28. More than one
weight fraction was reported and summarized separately below:

Overall, concentrations for Combined Vapor/Gas and Particulate ranged from not detected to 6,000.0
ng/m3 from 440 samples collected between 2000 and 2016 in seven countries, AU, BE, CA, DE, FI, JP
and US. Location types were categorized as Public Space and Residential. Reported detection frequency
ranged from 0.32 to 1.0.

Overall, concentrations for Particulate ranged from not detected to 136.0 ng/m3 from 133 samples
collected between 2002 and 2016 in four countries, CN, JP, SE and US. Location types were categorized
as Public Space and Residential. Reported detection frequency ranged from 0.0 to 1.0.

Overall, concentrations for Vapor/Gas ranged from not detected to 7,100.0 ng/m3 from 677 samples
collected between 2000 and 2016 in six countries, CH, DE, JP, NO, SE and US. Location types were
categorized as Vehicle, Public Space and Residential. Reported detection frequency ranged from 0.0 to
1.0.

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US Combined Vapor/Gas and Particulate

5432871 - Dodson ct al., 2019 - US

NonUS Combined Vapor/Gas and Particulate

4659643 - Okeme et al., 2018 - CA

4285929-He et al., 2018 -AU
4285929 - He et al., 2018 - AU
4659643 - Okeme et al., 2018 - CA
5165777 - Lazarov et al., 2015 - BE
3005686 - Takeuchi et al., 2015 - JP
2560628 - Makinen et al., 2009 - FI
2560628 - Makinen et al., 2009 - Fl
697390 - Kanazawa et al., 2010 - JP
632484 - Ohura et al., 2006 - JP
4731349 - Ingerowski et al., 2001 - DE

3012534 - La Guardia and Hale, 2015 - US
3012534 - La Guardia and Hale, 2015 - US
2539068 - Bradman et al., 2014 - US

4292129 - Deng et al., 2018 - CN
5163827 - Wong et al., 2018 - SE
1927779 - Saito et al., 2007 - JP
1927779 - Saito et al., 2007 - JP

5755270 - Dodson et al., 2017 - US

US Particulate

NonUS Particulate

US Vapor/Gas
NonUS Vapor/Gas

4292133 - Persson et al., 2018 - SE
5083520 - Sha et al., 2018 - SE
5083520-Sha et al., 2018-SE
3357642 - Xu el al., 2016 - NO
3604490 - Tokumura et al., 2017 - JP

10**4



| Public Space
I Residential
Vehicle

V Lognormal Distribution (CT and 90th percentile)
A Normal Distribution (CT and 90th percentile)
gs Non-Detecl

7 V

V

m



I v v

l_5X-5zi

I v v

0.1	1	10

Concentration (ng/m3) (pt I)

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NonUS Vapor/Gas

2537005 - Fromme et al., 2014 - DE
788335 - Bergh et al., 2011 - SE
788335 - Bergh et al., 2011 - SE
5469670 - Luongo and Oestman, 2016 - SE
1249459 - Bergh et al., 2011 - SE
779503 - Hartmann et al., 2004 - CH
779503 - Hartmann et al., 2004 - CH
1949033 - Yoshida et al., 2006 - JP
789515 - Otake et al., 2004 - JP
1598712 - Otake et al., 2001 - JP

10A-4

| Public Space
¦M Residential
Vehicle

V Lognormal Distribution (CT and 90th percentile)

I v v

V V

V V

97

0.1	1	10

Concentration (ng/m3) (pt 2)

Figure 1-28. Concentrations of TCEP (ng/m3) in Indoor Air from 2000 to 2016

Table 1-28. Summary of Peer-Reviewed Literature that Measured TCEP (ng/m3) Levels in Indoor
Air

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/m3)

Overall
Quality
Level

Combined Vapor/Gas and Particulate

Dodson et al.
(2019)

US

Public Space

2013-2015

37 (0.32)

5.6

High

Okeme et al.
(2018b)

CA

Public Space

2016

51 (0.80)

N/R

Medium

He et al.
(2018c)

AU

Public Space

2015

40 (1.00)

0.06

High

He et al.
(2018c)

AU

Residential

2015

40 (1.00)

0.06

High

Okeme et al.
(2018b)

CA

Residential

2015

102 (0.77)

N/R

Medium

Lazarov et al.
(2015)

BE

Residential

2015

6 (N/R)

0.171

Medium

Takeuchi et
al. (2015)

JP

Residential

2013-2014

21 (0.90)

0.07

High

Makinen et
al. (2009)

FI

Public Space

2008

3 (1.00)

N/R

Medium

Makinen et
al. (2009)

FI

Public Space

2008

4(0.50)

3.0

Medium

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/m3)

Overall
Quality
Level

Kanazawa et
al. (2010)

JP

Residential

2006

40 (0.60)

12.6

Medium

Ohuraet al.
(2006)

JP

Residential

2000-2001

46 (0.89)

N/R

Medium

Inserowski et
al. (2001)

DE

Residential

2001

50 (1.00)

N/R

Medium

Particulate

La Guardia
and Hale
(2015)

US

Public Space

2013

8 (0.00)

0.1

Medium

La Guardia
and Hale
(2015)

US

Residential

2013

8 (0.00)

0.1

Medium

Bradman et
al. (2014)

us

Public Space

2010-2011

40 (0.65)

0.3

High

Dens et al.
(2018)

CN

Public Space

2015-2016

22 (1.00)

N/R

Medium

Wong et al.
(2018)

SE

Public Space

2014-2015

23 (1.00)

0.022

Medium

Saito et al.
(2007)

JP

Residential

2002

18 (N/R)

0.67

Medium

Saito et al.
(2007)

JP

Public Space

2002

14 (N/R)

0.67

Medium

Vapor/Gas

Dodson et al.
(2017)

US

Residential

2013-2014

35 (0.17)

7.3

High

Persson et al.
(2018)

SE

Public Space

2015-2016

56 (0.00)

2.2

High

Sha et al.
(2018)

SE

Public Space

2016

36 (N/R)

0.0094

Low

Sha et al.
(2018)

SE

Residential

2016

9 (N/R)

0.0094

Low

Xu et al.
(2016)

NO

Residential

2013-2014

58 (0.93)

0.9

Medium

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/m3)

Overall
Quality
Level

Tokumura et
al. (2017)

JP

Vehicle

2013

9 (0.00)

0.68

High

Fromme et
al. (2014)

DE

Public Space

2011-2012

63 (0.17)

4.0

Medium

Bersh et al.
(2011b)

SE

Public Space

2010

20 (N/R)

N/R

Medium

Bersh et al.
(2011b)

SE

Residential

2010

10 (N/R)

N/R

Medium

Luoneo and
Oestman
(2016)

SE

Residential

2008

62 (0.65)

N/R

Medium

Bersh et al.
(2011a)

SE

Residential

2006-2007

169 (N/R)

1.0

Medium

Hartmann et
al. (2004)

CH

Public Space

2004

12 (1.00)

0.15

Medium

Hartmann et
al. (2004)

CH

Vehicle

2004

4(0.75)

0.15

Medium

Yoshida et
al. (2006)

JP

Vehicle

2004

101 (0.80)

N/R

Medium

Otake et al.
(2004)

JP

Residential

2000

27 (N/R)

N/R

Medium

Otake et al.
(2001)

JP

Residential

2000

6(1.00)

N/R

Medium

Abbreviations: N/R, Not reported

1.20 Leachate

1.20.1 Leachate (ng/L) - Not Specified Fraction	

Measured concentrations of TCEP in leachate with unit of ng/L, extracted from three sources, are
summarized in Figure 1-29 and supplemental information is provided in Table 1-29. Overall,
concentrations ranged from 6 to 5,430,000,000,000.0 ng/L from 20 samples collected between 1994 and
1995 in one country, JP. Location types were categorized as Unknown/Not Specified and Near Facility
(Highly Exposed). Reported detection frequency was 1.0.

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NonUS

659131 - Yasuhara et al., 1999 - JP





¦ Unknown/Not Specified

Near Facility (Highly Exposed)



















5469470 - Yasuhara, 1995 - JP

























5469582 - Yasuhara, 1994 - JP













0.1

10

1000

10*5 10*7 10A9
Concentration (ng/L)

10A11

10A13

Figure 1-29. Concentrations of TCEP (ng/L) in the Not Specified Fraction of Leachate from 1994
to 1995

Table 1-29. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Not
Specified Fraction of Leachate					

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Yasuhara et
al. (1999)

JP

Unknown/Not
Specified

1995

11 (1.00)

N/R

Medium

Yasuhara
(1995)

JP

Near Facility
(Highly '
Exposed)

1995

5 (1.00)

N/R

Low

Yasuhara
(1994)

JP

Near Facility
(Highly '
Exposed)

1994

4(1.00)

67.5

Medium

Abbreviations: N/R, Not reported

1.21 Other

1.21.1 Other (ng/g) - Dry Fraction	

Measured concentrations of TCEP in Other with unit of ng/g, extracted from one source, are
summarized in Figure 1-30 and supplemental information is provided in Table 1-30. Overall,
concentrations ranged from 0.007 to 0.039 ng/g from six samples collected in 2003 in one country, SE.
Location types were categorized as Unknown/Not Specified. Reported detection frequency was 1.0.

NonUS Drv

5176506 - Marklund et al., 2005 - SE



Unknown/Not Specified



10A-4

0.001

0.01 0.1 1
Concentration (ng/g)

Figure 1-30. Concentrations of TCEP (ng/g) in the Dry Fraction of Other in Unknown/Not
Specified Locations in 2003

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Table 1-30. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry
Fraction of Other

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Marklund et
al. (2005b)

SE

Unknown/Not
Specified

2003

6(1.00)

N/R

Medium

Abbreviations: N/R, Not reported

1.21.2 Other (ng/g) - All Fractions

Measured concentrations of TCEP in Other with unit of ng/g, extracted from three sources, are
summarized in Figure 1-31 and supplemental information is provided in Table 1-31. More than one
weight fraction was reported and summarized separately below:

Overall, concentrations for Particulate ranged from 0.007 to 68,000,000.0 ng/g from 12 samples
collected between 2001 and 2003 in two countries, DE and SE. Location types were categorized as
General Population (Background) and Unknown/Not Specified. Reported detection frequency was 1.0.

Overall, concentrations for Wet ranged from not detected to 0.55 ng/g from three samples collected in
2008 in one country, NL. Location types were categorized as Near Facility (Highly Exposed). Reported
detection frequency was 0.67.

NonUS Particulate

4731349 - Ingerowski et al., 2001 - DE

NonUS Wet

2935128 - Brandsma et al., 2015 - NL

NonUS Particulate

5176506 - Marklund et al., 2005 - SE





BIB General Population (Background)

Near Facility (Highly Exposed)
I Unknown/Not Specified
V Lognormal Distribution (CT and 90th percentile)



—









w









0.01

100 10A4 10A6 10A8
Concentration (ng/g)

Figure 1-31. Concentrations of TCEP (ng/g) in Other from 2001 to 2008

Table 1-31. Summary of Peer-Reviewed Literature that IV

easured TCE

' (ng/g) Levels in Other

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Particulate

Ingerowski et
al. (2001)

DE

General
Population
(Background)

2001

6(1.00)

400.0

Medium

Marklund et
al. (2005b)

SE

Unknown/Not
Specified

2003

6(1.00)

N/R

Medium

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Wet

Brandsma et
al. (2015)

NL

Near Facility
(Highly '
Exposed)

2008

3 (0.67)

0.2

High

Abbreviations: N/R, Not reported

1.21.3 Other (ng/L) - Not Specified Fraction

Measured concentrations of TCEP in Other with unit of ng/L, extracted from one source, are
summarized in Figure 1-32 and supplemental information is provided in Table 1-32. Overall,
concentrations ranged from 2.5 to 293 ng/L from 42 samples collected in 2016 in one country, AU.
Location types were categorized as General Population (Background). Reported detection frequency was
not reported.

NonUS

3464010 - Teo et al., 2016 - AU

B General Population (Background)





0.1

1 10 100
Concentration (ng/L)

1000

Figure 1-32. Concentrations of TCEP (ng/L) in the Not Specified Fraction of Other in General
Population (Background) Locations in 2016

Table 1-32. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Not
Specified Fraction of Other					

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Teo et al.
(2016)

AU

General
Population
(Background)

2016

42 (N/R)

5

High

Abbreviations: N/R, Not reported

1.22 Personal Inhalation

1.22.1 Personal Inhalation (ng/m3) - All Fractions

Measured concentrations of TCEP in Personal Inhalation with unit of ng/m3, extracted from three
sources, are summarized in Figure 1-33 and supplemental information is provided in Table 1-33. More
than one weight fraction was reported and summarized separately below:

Overall, concentrations for Particulate ranged from not detected to 77.8 ng/m3 from 21 samples collected
between 2015 and 2016 in two countries, CA and US. Location types were categorized as General
Population (Background). Reported detection frequency ranged from 0.44 to 1.0.

Page 48 of 83


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Overall, concentrations for Vapor/Gas ranged from 0.5 to 8.1 ng/m3 from 31 samples collected between
2013 and 2014 in one country, NO. Location types were categorized as General Population
(Background). Reported detection frequency was 0.77.

US Particulate

3222316 - Schreder et al., 2016 - US

NonUS Particulate

5017615 - Okeme et al., 2018 - CA

NonUS Vapor/Gas

3357642 - Xu et al., 2016 - NO





| General Population (Background)













¦











0.001 0.01 0.1 1 10 100

Concentration (ng/m3)

Figure 1-33. Concentrations of TCEP (ng/m3) in Personal Inhalation in General Population
(Background) Locations from 2013 to 2016

Table 1-33. Summary of Peer-Reviewed Literature that Measured TCEP (ng/m3) Levels in
Personal Inha ation

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/m3)

Overall
Quality
Level

Particulate

Schreder et
al. (2016)

US

General
Population
(Background)

2015

18 (0.44)

1.5

High

Okeme et al.
(2018a)

CA

General
Population
(Background)

2016

3 (1.00)

0.012

Medium

Vapor/Gas

Xu et al.
(2016)

NO

General
Population
(Background)

2013-2014

31 (0.77)

1.0

Medium

1.23 Precipitation

1.23.1 Precipitation (ng/L) - Wet Fraction

Measured concentrations of TCEP in Precipitation with unit of ng/L, extracted from six sources, are
summarized in Figure 1-34 and supplemental information is provided in Table 1-34. Overall,
concentrations ranged from not detected to 488.0 ng/L from 313 samples collected between 1994 and
2014 in three countries, AQ, DE and US. Location types were categorized as General Population
(Background) and Remote (Not Near Source). Reported detection frequency ranged from 0.6 to 1.0.

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General Population (Background)

US

| Remote (Not Near Source)

4530235 - Scott et al., 1996 - US











NonUS











3862723 - Li et al., 2017 - AQ





















2662833 - Mihajlovic and Fries, 2012 - DE











2662833 - Mihajlovic and Fries, 2012 - DE







¦



2588430 - Regnery and Puttmann, 2010 - DE









2588430 - Regnery and Puttmann, 2010 - DE

































2598725 - Regnery and Puettmann, 2009 - DE











2598725 - Regnery and Puettmann, 2009 - DE







¦



2598725 - Regnery and Puettmann, 2009 - DE







¦



2598725 - Regnery and Puettmann, 2009 - DE











5469313 - Fries and Puttmann, 2003 - DE







m



0.01 0.1

10 100 1000



Concentration (ng/L)

Figure 1-34. Concentrations of TCEP (ng/L) in the Wet Fraction of Precipitation from 1994 to
2014

Table 1-34. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Wet
Fraction of Precipitation 					

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Scott et al.
(1996)

US

General
Population
(Background)

1994

5 (0.60)

N/R

Low

Li et al.
(2017)

AQ

Remote (Not
Near Source)

2014

6(1.00)

0.21

High

Mihailovic
and Fries
(2012)

DE

General
Population
(Background)

2011

4 (N/R)

N/R

High

Mihailovic
and Fries
(2012)

DE

General
Population
(Background)

2010

4 (N/R)

N/R

High

Reanerv and
Puttmann
(2010b)

DE

General
Population
(Background)

2007-2009

167 (N/R)

2.0

High

Reanerv and
Puttmann
(2010b)

DE

General
Population
(Background)

2007-2009

29 (1.00)

2.0

High

Reanerv and
Puettmann
(2009)

DE

General
Population
(Background)

2007-2008

30 (N/R)

2.0

High

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Reanerv and
Puettmann
(2009)

DE

Remote (Not
Near Source)

2007-2008

23 (N/R)

2.0

High

Reanerv and
Puettmann
(2009)

DE

General
Population
(Background)

2007-2008

8 (N/R)

2.0

High

Reanerv and
Puettmann
(2009)

DE

Remote (Not
Near Source)

2007-2008

34 (N/R)

2.0

High

Fries and
Puttmann
(2003)

DE

General
Population
(Background)

2001

3 (1.00)

1.0

Medium

Abbreviations: N/R, Not reported

1.24 Sediment

1.24.1 Sediment (ng/g) - All Fractions

Measured concentrations of TCEP in Sediment with unit of ng/g, extracted from seven sources, are
summarized in Figure 1-35 and supplemental information is provided in Table 1-35. More than one
weight fraction was reported and summarized separately below:

Overall, concentrations for Dry ranged from not detected to 41.0 ng/g from 91 samples collected
between 1980 and 2017 in seven countries, CZ, DE, JP, KR, PT, US and ZA. Location types were
categorized as General Population (Background), Near Facility (Highly Exposed) and Unknown/Not
Specified. Reported detection frequency ranged from 0.75 to 1.0.

Overall, concentrations for Wet ranged from not detected to 0.35 ng/g from three samples collected in
2008 in one country, NL. Location types were categorized as Near Facility (Highly Exposed). Reported
detection frequency was 0.67.

Page 51 of 83


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US Drv

4182703 - Maruya et al., 2016 - US



General Population (Background)

Near Facility (Highly Exposed)
I Unknown/Not Specified
V Lognormal Distribution (CT and 90th percentile)
A Normal Distribution (CT and 90th percentile)



NonUS Drv

5305891 - Gadelha et al., 2019 - PT

















5470119 - Chokwe and Okonkwo, 2019 - ZA



E vm\





5469301 - Choo et al., 2018 - KR



AA





5740077 - Stachel et al., 2005 - CZ,DE
2919504 - Ishikawa et al., 1985 - JP







NonUS Wet

2935128 - Brandsma et al., 2015 - NL



v





0.001

0.01

0.1 1 10
Concentration (ng/g)

100

Figure 1-35. Concentrations of TCEP (ng/g) in Sediment from 1980 to 2017

Table 1-35. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in
Sediment

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Dry

Maruva et al.
(2016)

US

General
Population
(Background)

2013

16 (0.75)

N/R

High

Gadelha et
al. (2019)

PT

Near Facility
(Highly '
Exposed)

2016-2017

12 (N/R)

0.07

High

Chokwe and
Okonkwo
(2019)

ZA

Unknown/Not
Specified

2017

16 (0.88)

0.24

High

Choo et al.
(2018)

KR

General
Population
(Background)

2015

4(1.00)

0.01

High

Stachel et al.
(2005)

CZ,DE

Near Facility
(Highly '
Exposed)

2002

37 (N/R)

1.0

Medium

Ishikawa et
al. (1985)

JP

General
Population
(Background)

1980

6(0.83)

5.0

Medium

Wet

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Brandsma et
al. (2015)

NL

Near Facility
(Highly '
Exposed)

2008

3 (0.67)

0.2

High

Abbreviations: N/R, Not reported

1.25 Soil

1.25.1 Soil (ng/g) - Dry Fraction

Measured concentrations of TCEP in Soil with unit of ng/g, extracted from three sources, are
summarized in Figure 1-36 and supplemental information is provided in Table 1-36. Overall,
concentrations ranged from not detected to 23.48 ng/g from 18 samples collected between 2010 and
2014 in two countries, DE and TR. Location types were categorized as General Population
(Background). Reported detection frequency was not reported.

NonUS Drv

5017070 - Kurt-Karakus et al., 2018 - TR
1051336 - Mihajlovi et al., 2011 - DE

m General Population (Background)

1





2662833 - Mihajlovic and Fries, 2012 - DE







0.1

1 10
Concentration (ng/g)

100

Figure 1-36. Concentrations of TCEP (ng/g) in the Dry Fraction of Soil in General Population
(Background) Locations from 2010 to 2014

Table 1-36. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Dry
Fraction of Soil

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Kurt-Karakus
et al. (2018)

TR

General
Population
(Background)

2014

8 (N/R)

3.4

High

Mihailovic et
al. (2011)

DE

General
Population
(Background)

2011

6 (N/R)

0.2

Medium

Mihailovic
and Fries
(2012)

DE

General
Population
(Background)

2010-2011

4 (N/R)

0.2

High

Abbreviations: N/R, Not reported

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1.26 Surface Water

1.26.1 Surface Water (ng/L) - Not Specified Fraction

Measured concentrations of TCEP in Surface Water with unit of ng/L, extracted from 29 sources, are
summarized in Figure 1-37 and supplemental information is provided in Table 1-37. Overall,
concentrations ranged from not detected to 2,019.0 ng/L from 3,283 samples collected between 1980
and 2017 in 14 countries, AQ, AU, CA, DE, DK, ES, FR, GB, GL, JP, KR, PT, SE and US. Location
types were categorized as General Population (Background), Near Facility (Highly Exposed) and
Remote (Not Near Source). Reported detection frequency ranged from 0.0 to 1.0.

US Not Specified

Mix Not Specified
NonUS Not Specified

4182703 - Maruya ct al2016 - US
4181598 - Sengupta et al2014 - US
4253347 - Padhyc et al., 2014 - US
5469762 - Giorgino et al., 2007 - US
3353787 - Kolpin et al., 2002 - US

4530235 - Scott et al., 1996 - CA.US

5305891 - Gadelha et al., 2019 - PT
5428453 - Gao et al., 2019 - SE
5469295 - McDonough et al., 2018 - CA,GL
4829919 - Blum et al., 2018 - SE
5428638 - Blum et al., 2018 - SE
5469301 - Choo et al., 2018 - KR
3862723-Li et al.,2017-AQ
3860951 - Loos et al., 2017 - DE
5499542 - Gustavsson et al., 2018 - SE
5469274 - Scott et al., 2014 - AU
1788425 - Cristale et al., 2013 - GB
4330586 - Matamoros et al., 2012 - DK
2588430 - Regnery arid Piittmann, 2010 - DE
2919589 - Calderon-Preciado et al., 2011 - ES
5469263 - Regnery and Piittmann, 2010 - DE
5469315 - Gourmelon et al., 2010 - FR
1250860 - Rodil et al., 2012 - ES
2593950 - Quednow and Piittmann, 2009 - DE
1619118 - Andresen et al., 2007 - DE
4832200 - Andresen et al., 2004 - DE
5469313 - Fries and Puttmann, 2003 - DE
5469312 - Fries and Puttmann, 2001 - DE

10A-4

¦ General Population (Background)

¦HI Near Facility (Highly Exposed)

| Remote (Not Near Source)

A Normal Distribution (CT and 90th percentile)
V Lognormal Distribution (CT and 90th percentile)
5SJ Non-Detect

t A

VlV





























S7V







S7 V

ZJ3Z





V



V

CV

0.001

0.1	1	10

Concentration (ng/L) (pt 1)

100

1000

10A4

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NonUS Not Specified

2919504 - Ishikawa et al., 1985 - JP





General Population (Background)
\7 Lognormal Distribution (CT and 90th percentile)

vv



2919504 - Ishikawa et al, 1985 - JP





vv



10A-4

0.001

0.01

0.1 1 10 100 1000
Concentration (ng/L) (pt 2)

10A4

Figure 1-37. Concentrations of TCEP (ng/L) in the Not Specified Fraction of Surface Water from
1980 to 2017

Table 1-37. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Not
Specified Fraction of Surface Water					

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Maruva et al.
(2016)

US

General
Population
(Background)

2013

17 (0.65)

5.0

High

Sensupta et
al. (2014)

US

General
Population
(Background)

2011

30 (1.00)

N/R

Medium

Padhve et al.
(2014)

us

General
Population
(Background)

2009-2010

8 (N/R)

N/R

Medium

Gioraino et
al. (2007)

us

General
Population
(Background)

2002-2005

14 (0.36)

500.0

High

Kolpin et al.
(2002)

us

Near Facility
(Highly '
Exposed)

1999-2000

85 (0.58)

40.0

High

Scott et al.
(1996)

CA, US

General
Population
(Background)

1994

43 (1.00)

N/R

Low

Gadelha et
al. (2019)

PT

Near Facility
(Highly '
Exposed)

2016-2017

12 (N/R)

0.13

High

Gao et al.
(2019)

SE

General
Population
(Background)

2016-2017

8 (0.25)

7.2

High

McDonouah
et al. (2018)

CA,GL

Remote (Not
Near Source)

2014-2016

13 (0.46)

0.22

High

Blum et al.
(2018a)

SE

General
Population
(Background)

2014-2015

16 (0.88)

0.15

High

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Blum et al.
(2018b)

SE

Near Facility
(Highly '
Exposed)

2014-2015

20 (0.60)

N/R

High

Choo et al.
(2018)

KR

General
Population
(Background)

2015

4(1.00)

0.24

High

Li et al.
(2017)

AQ

Remote (Not
Near Source)

2014

25 (0.88)

0.21

High

Loos et al.
(2017)

DE

General
Population
(Background)

2013

71 (1.00)

0.29

High

Gustavsson
et al. (2018)

SE

General
Population
(Background)

2013

28 (0.57)

0.68

High

Scott et al.
(2014)

AU

General
Population
(Background)

2011-2012

285 (0.44)

10.0

High

Cristale et al.
(2013)

GB

General
Population
(Background)

2011

13 (1.00)

2.4

Medium

Matamoros
et al. (2012)

DK

Near Facility
(Highly '
Exposed)

2010

29 (1.00)

N/R

High

Reenerv and
Piittmann
(2010b)

DE

General
Population
(Background)

2008-2009

52 (1.00)

2.0

High

Calderon-
Preciado et
al. (2011)

ES

General
Population
(Background)

2008-2009

8 (0.00)

55.0

Medium

Reenerv and
Piittmann
(2010a)

DE

General
Population
(Background)

2007-2009

151 (N/R)

1.0

High

Gourmelon
et al. (2010)

FR

Near Facility
(Highly '
Exposed)

2009

20 (0.25)

40.0

Medium

Rodil et al.
(2012)

ES

General
Population
(Background)

2007-2008

28 (0.64)

0.004

Medium

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Ouednow

and
Puttmann
(2009)

DE

General
Population
(Background)

2003-2006

1,650(0.91)

5.0

High

Andresen et
al. (2007)

DE

General
Population
(Background)

2005

14 (N/R)

0.3

High

Andresen et
al. (2004)

DE

General
Population
(Background)

2002

44 (N/R)

N/R

Medium

Fries and
Puttmann
(2003)

DE

General
Population
(Background)

2000-2001

9(0.89)

1.0

Medium

Fries and
Puttmann
(2001)

DE

General
Population
(Background)

2000

561 (N/R)

1.0

Medium

Ishikawa et
al. (1985)

JP

General
Population
(Background)

1980

9(1.00)

10.0

Medium

Ishikawa et
al. (1985)

JP

General
Population
(Background)

1980

16 (0.88)

10.0

Medium

Abbreviations: N/R, Not reported

1.27 Terrestrial Organisms - Bird

1.27.1 Terrestrial Organisms - Bird (ng/g) - All Fractions

Measured concentrations of TCEP in Terrestrial Organisms - Bird with unit of ng/g, extracted from
seven sources, are summarized in Figure 1-38 and supplemental information is provided in Table 1-38.
More than one weight fraction was reported and summarized separately below:

Overall, concentrations for Wet ranged from not detected to 39.0 ng/g from 160 samples collected
between 2000 and 2012 in four countries, CA, NL, NO and US. Location types were categorized as
General Population (Background), Near Facility (Highly Exposed) and Remote (Not Near Source).
Reported detection frequency ranged from 0.0 to 1.0.

Overall, concentrations for Dry ranged from not detected to 3,000.0 ng/g from 40 samples collected
between 2008 and 2016 in three countries, ES, NL and NO. Location types were categorized as General
Population (Background), Near Facility (Highly Exposed) and Remote (Not Near Source). Reported
detection frequency ranged from 0.0 to 1.0.

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US Wet

5166846 - Guo et al., 2018 - US - Bloodg
5166846 - Guo et al., 2018 - US - Egg (whole)

NonUS Wet

2823276 - Huber et al., 2015 - NO - Egg (whole)
4181327 - Chen et al., 2012 - CA - Egg (whole)
4931691 - Greaves and Letcher, 2014 - CA - Blood
4931691 - Greaves and Letcher, 2014 - CA - Liver
4931691 - Greaves and Letcher, 2014 - CA - Other
4931691 - Greaves and Letcher, 2014 - CA - Adipose Tissue
4931691 - Greaves and Letcher, 2014 - CA - Egg (yolk)
4931691 - Greaves and Letcher, 2014 - CA - Muscle/Filet

NonUS Dry

5017003 - Monclus et al., 2018 - ES - Feathers
2542346 - Eulaers et al., 2014 - NO - Feathers
2935128 - Brandsma et al., 2015 - NL - Egg (whole)

10A-6

| General Population (Background)

¦ Remote (Not Near Source)

Near Facility (Highly Exposed)

B5 Non-Detect

V Lognormal Distribution (CT and 90th percentile)

Btv

S7

w



10A-4

0.01	1

Concentration (ng/g)

I vv

I0"4

Figure 1-38. Concentrations of TCEP (ng/g) in Terrestrial Organisms - Bird from 2000 to 2016

Table 1-38. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in
Terrestrial Organisms - Bird					

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Wet

Guo et al.
(2018)

US

General
Population
(Background)

2000-2012

24 (0.00)

N/R

High

Guo et al.
(2018)

US

General
Population
(Background)

2000-2012

22 (0.55)

1.74

High

Huber et al.
(2015)

NO

Remote (Not
Near Source)

2012

16 (1.00)

N/R

High

Chen et al.
(2012)

CA

Remote (Not
Near Source)

2010

13 (0.77)

0.1

Medium

Greaves and
Letcher
(2014)

CA

Remote (Not
Near Source)

2010

16 (0.00)

0.03

Medium

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Greaves and
Letcher
(2014)

CA

Remote (Not
Near Source)

2010

8 (0.00)

0.03

Medium

Greaves and
Letcher
(2014)

CA

Remote (Not
Near Source)

2010

24 (N/R)

0.03

Medium

Greaves and
Letcher
(2014)

CA

Remote (Not
Near Source)

2010

8 (N/R)

0.03

Medium

Greaves and
Letcher
(2014)

CA

Remote (Not
Near Source)

2010

16 (N/R)

0.03

Medium

Greaves and
Letcher
(2014)

CA

Remote (Not
Near Source)

2010

8 (0.38)

0.03

Medium

Brandsma et
al. (2015)

NL

Near Facility
(Highly '
Exposed)

2008

5 (N/R)

0.26

High

Dry

Monclus et
al. (2018)

ES

General
Population
(Background)

2016

14 (0.43)

1.0

High

Eulaers et al.
(2014)

NO

Remote (Not
Near Source)

2011

21 (1.00)

1.0

High

Brandsma et
al. (2015)

NL

Near Facility
(Highly '
Exposed)

2008

5 (0.00)

0.26

High

Abbreviations: N/R, Not reported

1.27.2 Terrestrial Organisms - Bird (ng/g) - Wet Fraction

Measured concentrations of BCEP in Terrestrial Organisms - Bird with unit of ng/g, extracted from one
source, are summarized in Figure 1-39 and supplemental information is provided in Table 1-39. Overall,
concentrations ranged from 0.38 to 26 ng/g from 21 samples collected between 2000 and 2012 in one
country, US. Location types were categorized as General Population (Background). Reported detection
frequency was 1.0.

US Wet

5167023 - Stubbings et al., 2018 - US _ Egg (whole)



General Population (Background)



0.01

0.1

1 10 100 1000
Concentration (ng/g)

10A4

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Figure 1-39. Concentrations of BCEP (ng/g) in the Wet Fraction of Terrestrial Organisms - Bird
in General Population (Background) Locations from 2000 to 2012

Table 1-39. Summary of Peer-Reviewed Literature that Measured BCEP (ng/g) Levels in the Wet
Fraction of Terrestrial Organisms - Bird 				

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Stubbinas et
al. (2018)

US

General
Population
(Background)

2000-2012

21 (1.00)

N/R

High

Abbreviations: N/R, Not reported

1.28 Terrestrial Organisms - Mammal

1.28.1 Terrestrial Organisms - Mammal (ng/g) - All Fractions

Measured concentrations of TCEP in Terrestrial Organisms - Mammal with unit of ng/g, extracted from
two sources, are summarized in Figure 1-40 and supplemental information is provided in Table 1-40.
More than one weight fraction was reported and summarized separately below:

Overall, concentrations for Lipid ranged from 1.91 to 52.5 ng/g from 20 samples collected between 2008
and 2010 in one country, NO. Location types were categorized as Remote (Not Near Source). Reported
detection frequency was 0.1.

Overall, concentrations for Wet ranged from not detected to 0.115 ng/g from 21 samples collected
between 2017 and 2018 in one country, NO. Location types were categorized as General Population
(Background). Reported detection frequency was 0.0.





| Remote (Not Near Source)







General Population (Background)



NonUS Lipid

5162922 - Hallanger et al., 2015 - NO - Blood

V Lognormal Distribution (CT and 90th percentile)



NonUS Wet

7002451 - Heimstad et al., 2019 - NO - Liver







0.01 0.1

1 10 100 1000
Concentration (ng/g)

10^4

Figure 1-40. Concentrations of TCEP (ng/g) in Terrestrial Organisms - Mammal from 2008 to
2018

Table 1-40. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in
Terrestrial Organisms - Mammal				

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Lipid

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Hallanser et
al. (2015)

NO

Remote (Not
Near Source)

2008-2010

20 (0.10)

N/R

High

Wet

Heimstad et
al. (2019)

NO

General
Population
(Background)

2017-2018

21 (0.00)

0.23

High

Abbreviations: N/R, Not reported

1.29 Terrestrial Organisms - Plant

1.29.1 Terrestrial Organisms - Plant (ng/g) - Wet Fraction

Measured concentrations of TCEP in Terrestrial Organisms - Plant with unit of ng/g, extracted from one
source, are summarized in Figure 1-41 and supplemental information is provided in Table 1-41. Overall,
concentrations ranged from 1.25 to 1950 ng/g from nine samples collected between 1993 and 1994 in
one country, US. Location types were categorized as Remote (Not Near Source). Reported detection
frequency was 0.67.

US Wet

5469881 - Aston et al., 1996 - US - Foliage



| Remote (Not Near Source)
y Lognormal Distribution (CT and 90th percentile)













0.01

0.1

1 10 100 1000
Concentration (ng/g)

10A4

Figure 1-41. Concentrations of TCEP (ng/g) in the Wet Fraction of Terrestrial Organisms - Plant
in Remote (Not Near Source) Locations from 1993 to 1994

Table 1-41. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Wet
Fraction of Terrestrial Organisms - Plant 				

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Aston et al.
(1996)

US

Remote (Not
Near Source)

1993-1994

9 (0.67)

2.5

Medium

1.30 Wastewater

1.30.1 Wastewater (ng/g) - Wet Fraction	

Measured concentrations of TCEP in Wastewater with unit of ng/g, extracted from three sources, are
summarized in Figure 1-42 and supplemental information is provided in Table 1-42. Overall,
concentrations ranged from 0.5 to 198.0 ng/g from 74 samples collected between 2013 and 2018 in three
countries, CA, NO and US. Location types were categorized as Raw Influent and Treated Effluent.
Reported detection frequency ranged from 0.5 to 1.0.

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US

3862000 - Kim et al., 2017 - US
3862000 - Kim et al., 2017 - US
3862000 - Kim et al., 2017 - US

Raw Influent
I Treated Effluent

V Lognormal Distribution (CT and 90th percentile)

^ vl V I





v ka

vlv



NonUS

7002475 - Norwegian Environment, 2019 - NO
3035593 - Woudneh et al, 2015 - CA
3035593 - Woudneh et al, 2015 - CA

1

1

1





0.01 0.1

1 10 100
Concentration (ng/g)

1000

Figure 1-42. Concentrations of TCEP (ng/g) in the Wet Fraction of Wastewater from 2013 to 2018

Table 1-42. Summary of Peer-Reviewed Literature that Measured TCEP (ng/g) Levels in the Wet
Fraction of Wastewater

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit

(ng/g)

Overall
Quality
Level

Kim et al.
(2017)

US

Raw Influent

2013-2015

16 (1.00)

1.0

High

Kim et al.
(2017)

US

Treated Effluent

2013-2015

38 (0.50)

1.0

High

Kim et al.
(2017)

us

Treated Effluent

2013-2015

16 (1.00)

1.0

High

Norwegian
Environment
(2019a)

NO

Treated Effluent

2018

2 (N/R)

N/R

Medium

Woudneh et
al. (2015)

CA

Raw Influent

2015

1 (1.00)

0.1

Medium

Woudneh et
al. (2015)

CA

Treated Effluent

2015

1 (1.00)

0.1

Medium

Abbreviations: N/R, Not reported

1.30.2 Wastewater (ng/L) - Wet Fraction	

Measured concentrations of TCEP in Wastewater with unit of ng/L, extracted from 16 sources, are
summarized in Figure 1-43 and supplemental information is provided in Table 1-43. Overall,
concentrations ranged from not detected to 42800.0 ng/L from 305 samples collected between 2001 and
2018 in eight countries, AU, BE, DE, ES, FR, NO, SE and US. Location types were categorized as
Untreated Combined Sewer Overflow, Raw Influent, Treated Effluent and Untreated Effluent at
Discharge Origin. Reported detection frequency ranged from 0.0 to 1.0.

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us

NonUS

3862000 Kim ct al., 2017-US
3862000 - Kim et al., 2017 - US
2528320 - Schreder and La Guardia, 2014 - US
2528320 - vSchredcr and La Guardia, 2014 - US
5469289 - Laws et al., 2011 - US
1408465 - Jackson and Sutton, 2008 - US
1408465 - Jackson and Sutton, 2008 - US
5743010 - Lorainc and Pettigrov, 2006 - US

7002475 - Norwegian Environment, 2019 - NO
5428453 - Gao et al., 2019 - SE
5428453 - Gao et al., 2019 - SE
4457234 - Been et al., 2017 - BE
5664394 - Launay et al., 2016 - DE
5664394 - Launay et al., 2016 - DE
4143122-Blum et al., 2017-SE
3035438 - O'Brien et al., 2015 - AU
5469315 - Gourmelon et al., 2010 - FR
1250860 - Rodil et al., 2012 - ES
1250860 - Rodil et al., 2012 - ES
5162720 - Meyer and Bester, 2004 - DE
5162720 - Meyer and Bester, 2004 - DE
8683710 - Marklund et al, 2005 - SE
8683710 - Marklund et al, 2005 - SE
8683710 - Marklund et al, 2005 - SE
8683710 - Marklund et al, 2005 - SE
8683710 - Marklund et al, 2005 - SE
8683710 - Marklund et al, 2005 - SE
5469313 - Fries and Puttmann, 2003 - DE
5469313 - Fries and Puttmann, 2003 - DE

0.01

¦¦I Raw Influent
¦ Treated Effluent

Untreated Effluent at Discharge Origin
Untreated Combined Sewer Overflow
V Lognorrnal Distribution (CT and 90th percentile)
A Normal Distribution (CT and 90th percentile)
S3 Non-Detect





Aa







AA

4A

*

¦v

K7V

w

w

33

KS?
W
EA-
&
£A

Ov

^7

^37

10	100

Concentration (ng/L)

Figure 1-43. Concentrations of TCEP (ng/L) in the Wet Fraction of Wastewater from 2001 to 2018

Table 1-43. Summary of Peer-Reviewed Literature that Measured TCEP (ng/L) Levels in the Wet
Fraction of Wastewater

Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Kim et al.
(2017)

US

Raw Influent

2013-2015

16 (1.00)

50.0

High

Page 63 of 83


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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

Kim et al.
(2017)

US

Treated Effluent

2013-2015

16 (1.00)

50.0

High

Schreder and
La Guardia
(2014)

US

Treated Effluent

2011-2012

2(1.00)

1.0

High

Schreder and
La Guardia
(2014)

us

Untreated
Effluent at
Discharge
Origin

2011-2012

21 (1.00)

1.0

High

Laws et al.
(2011)

us

Treated Effluent

2009

1 (1.00)

200.0

Medium

Jackson and
Sutton
(2008)

us

Raw Influent

2006

10 (0.20)

6250.0

Medium

Jackson and
Sutton
(2008)

us

Treated Effluent

2006

3 (0.67)

N/R

Medium

Loraine and
Pettiarov
(2006)

us

Treated Effluent

2001-2002

6(0.50)

760.0

Medium

Norwegian
Environment
(2019a)

NO

Treated Effluent

2018

2 (N/R)

N/R

Medium

Gao et al.
(2019)

SE

Raw Influent

2017

4(1.00)

7.2

High

Gao et al.
(2019)

SE

Treated Effluent

2016-2017

8 (0.88)

7.2

High

Been et al.
(2017)

BE

Raw Influent

2015-2016

8 (1.00)

1.1

Medium

Launav et al.
(2016)

DE

Untreated
Combined
Sewer Overflow

2014

9 (N/R)

50.0

High

Launav et al.
(2016)

DE

Untreated
Effluent at
Discharge
Origin

2014

7 (N/R)

50.0

High

Blum et al.
(2017)

SE

Treated Effluent

2013

10 (0.80)

N/R

Medium

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Citation

Country

Location Type

Sampling
Year

Sample Size
(Frequency
of Detection)

Detection
Limit
(ng/L)

Overall
Quality
Level

O'Brien et al.
(2015)

AU

Raw Influent

2011

15 (0.93)

200.0

High

Gourmelon
et al. (2010)

FR

Treated Effluent

2009

14 (1.00)

40.0

Medium

Rodil et al.
(2012)

ES

Raw Influent

2007-2008

11 (1.00)

10.0

Medium

Rodil et al.
(2012)

ES

Treated Effluent

2007-2008

11 (1.00)

10.0

Medium

Mever and
Bester (2004)

DE

Raw Influent

2003

0 (N/R)

6.1

Medium

Mever and
Bester (2004)

DE

Treated Effluent

2003

18 (0.00)

6.1

Medium

Marklund et
al. (2005a)

SE

Raw Influent

2002-2003

18 (N/R)

N/R

Medium

Marklund et
al. (2005a)

SE

Treated Effluent

2002-2003

17 (N/R)

N/R

Medium

Marklund et
al. (2005a)

SE

Raw Influent

2002-2003

9 (N/R)

N/R

Medium

Marklund et
al. (2005a)

SE

Treated Effluent

2002-2003

34 (N/R)

N/R

Medium

Marklund et
al. (2005a)

SE

Treated Effluent

2002-2003

18 (N/R)

N/R

Medium

Marklund et
al. (2005a)

SE

Treated Effluent

2002-2003

9 (N/R)

N/R

Medium

Fries and
Puttmann
(2003)

DE

Raw Influent

2001

4(1.00)

1.0

Medium

Fries and
Puttmann
(2003)

DE

Treated Effluent

2001

4(0.75)

1.0

Medium

Abbreviations: N/R, Not reported

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2 METHODS AND APPROACH

2.1 Data Integration Methods and Approach

Extracted study data required further processing to allow for the standardization and integration of
TCEP data across all studies. Where studies reported data values for metabolites of TCEP, including
BCEP (bis(2-chloroethyl) phosphate, CAS No. 4050-56-0, these values were extracted separately in
DistillerSR and data summaries are reported separately in this report for TCEP and its individual
metabolites.

To enable comparison of data across studies, all extracted environmental monitoring and biomonitoring
concentrations were converted to common unit by medium (i.e., ng/L for aqueous media, ng/g for solid
phase media, ng/m3 for air media). Study-reported summary statistics were used, as available, to
characterize the concentrations for all unique scenarios including minimums and maximum
concentrations, measures of central tendency, percentiles, measures of variance, frequencies of
detection, and reported limits of detection (LOD) and/or limits of quantitation (LOQ). In cases where
point data were available, summary statistics were calculated for each unique scenario depending on the
number of point values. If only one point value was reported per unique scenario, it was treated as an
arithmetic mean. For unique scenarios with 2-9 point values, arithmetic means, medians, standard
deviations, and minimum and maximums were calculated. For unique scenarios with 10 or more point
values, the 25th, 50th, and 90th percentiles also were calculated.

A left-censoring protocol was applied to impute the lower bound of concentration ranges in cases where
the reported frequency of detection (FOD) was less than 100 percent, meaning that TCEP, or metabolite,
was not detected in at least one sample. Specifically, a value of one-half the highest reported LOD or
LOQ (if no LOD available) was imputed as the minimum value for each unique scenario. In cases where
authors reported values as "not detected" (e.g., "ND", "
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Section Error! Reference source not found, of this supplement provides a data summary plot for each m
edia by unit. Each plot presents summary statistics for each study aggregated by pollution source
receptor type and setting or microenvironment {i.e., General Population (Background), Near Facility
(Highly Exposed), Remote (Not Near Point Source)). Because individual studies often present multiple
unique scenarios that can be grouped into a single representative aggregate for the study, available
statistics were combined and the ranges observations {e.g., minimum, maximum, and percentiles) and
central tendencies {e.g. arithmetic mean, geometric mean, and median), and overall FOD where possible
were calculated.

Within each plot, data are separated by unit basis of sampling fraction, then monitoring data from the
U.S. are presented first, followed by studies with data from mixed locations {i.e., U.S. and other
countries), finally by studies with data from non-U.S. sources. For each grouping, data are presented
from newest to oldest, based on latest year of sampling. Differentiation by tissue type for ecological
monitoring media is indicated in the tick label. The lighter region of each bar represents the overall
range of data and the darker region represents the range of central tendency reported in each study.
Triangles indicate the arithmetic mean and 90th percentile estimates are plotted over the bars for study
aggregates that reported enough statistical results to reconstruct a lognormal or normal distribution. The
statistical methods used to calculate the central and high-end estimates are described in the following
section. The tables that follow each plot provide summary information for each study aggregate such as
the sampling location and dates, sample size and FOD, maximum LOD or LOQ (if no LOD was
reported), and overall study quality judgement from data evaluation.

2.2 Statistical Approach of Exposure Estimates Derived from Measured
Concentrations

Following the aggregation and standardization of reported study data from DistillerSR, the statistical
methods described were applied to enhance the comparability and informative value of the available
information. All statistical calculations were performed with Python scripts included as steps within the
computational pipeline of the methodology.

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2.2,1 Aggregation of Statistical Estimates	

Studies were aggregated as described in the previous section. Based on this aggregation and study-
reported statistics, normal and lognormal distributions were estimated based on available data. In cases
where more than one statistic type {i.e., mean, median, minimum, maximum, percentile, and variability
measures) each type was handled as described in Table 2-1 below.

Table 2-1. Statistics ant

Methods for Data Aggregation

Statistic Type

Description of Calculation Method for Aggregate Estimate

Arithmetic means

l!j= \ WjXj, where Xj = */,;

Medians

Ylj=1 Wj ¦ medj, where medj is the median of dataset J

Percentiles

Ey=i wj ' percj, where percj is the percentile of dataset J

Minimums

minfmi,, mK}, where rrij = min {xj 1;..., xJ Nj}

Maximums

max {M1; —,Mn} , where My = max {xj 1; ...,XjNj]

Geometric means

exp (If=i wj • In (GMf)). where GMj = exp (xy ;))

Geometric standard
deviations

2

exP

•	Equation for estimating 90th percentile from lognormal distribution: e(P+er*1-282))

If arithmetic means and standard deviations (SDs) or variance were provided and no other statistics
indicate that the data are not normally distributed, then a normal distribution was derived using the
available statistics. If arithmetic means, medians, and SDs were provided and means and medians were
within 5 percent relative percent difference, then a normal distribution was assumed and derived using
the provided arithmetic mean and measure of variation. When a normal distribution was assumed the
arithmetic mean (assumed to be median) and 90th percentile was calculated using the equations below.

•	Equation for arithmetic mean for normal distribution: /1

•	Equation for 90th percentile from normal distribution: /1 + 1.282
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Table 2-2. Distri

jutions Preferred Depending on Available Reported Statistics

Case Type

Description of Available Statistics Per
Study Aggregate

Distribution Type
Preferred

Case OA

Geometric mean and GSD

lognormal

Case OB

Median and GSD

lognormal

Case 1A

(Mean == Median) and SD

normal

Case IB

Mean and SD (no Median provided)

normal

Case 2A

Median and (min or max or percentile)

lognormal

Case 2B

Median and (F0D<1 and LOD/LOQ)

lognormal

Case 3A

Mean only and (min or max or percentile)

lognormal

Case 3B

Mean only and (F0D<1 and LOD/LOQ)

lognormal

Case 4

Median and mean only

lognormal

All other cases

Not enough data to build distribution

n/a

GSD = geometric standard deviation; SD = standard deviation; FOD = frequency of detection; LOD =
limit of detection; LOQ = limit of quantitation

2.2.2 Fitting Lognormal Distributions

In cases where the study data provided median values, the average median was substituted for geometric
mean, and the remaining statistics were used to estimate the GSD by minimizing the sum of squared
errors for all provided statistical estimates. Sum of squared errors was calculated by comparing the mean
of the residual statistic to the estimated value produced by the fitted distribution, based on the
assumptions in Table 2-3 that defined the percentiles assumed for each statistic type.

Table 2-3. Assumed Percentile for Calculating Error by Statistical Estimate Type

Mean of Statistical Estimate by Type

Assumed Percentile for Calculating Error

Maximum

0.99

Minimum

0.01

nth percentile (eg. 25th percentile)

n/100 (e.g., 0.25)

Half limit of quantitation substituted minimum

0.005

Half limit of detection substituted minimum

0.0025

This methodology requires a central tendency estimate and at least one data point on the distribution in
order to fit a lognormal distribution. Thus, lognormal distributions were fitted for studies that provided
an arithmetic mean and at least one data point on the curve. In these cases, both the geometric mean and
the GSD were derived by minimizing the sum of the squared errors for all estimates.

2.2.3 Fitting Normal Distributions

Normal distributions also were constructed for all study aggregates using an approach similar to the
approach for geometric distributions described in Section 2.2.1. Study-reported means were assumed to
be medians, and standard deviations were calculated by minimizing the sum of squares error of all
available estimates.

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2.2.4	Quality Control of Derived Exposure Estimates	

As a quality control measure, the estimated medians and arithmetic means were evaluated to verify that
the estimated values fell within the range of the reported data. Estimates were not used if they fell
outside of the range of the reported data, typically an indicator of anomalous data. In addition, derived
GSDs were not used if they exceeded 10 for the lognormal distributions, mean estimates were not used
if they exceeded 100% relative percent difference from residual means. In these cases, the estimates
from the normal distributions were used when normal distributions could be derived.

2.2.5	Final Exposure Estimates by Media and Pollution Source Receptor Type

Central tendency exposure values that carried forward to risk evaluation after passing the QC process
were summarized for each media aggregate by taking the sample weighted mean of the arithmetic mean
estimates from the selected distribution (i.e., lognormal or normal). Similarly, the 90th percentile
estimates carried forward to risk evaluation were calculated as the sample weighted mean of 90th
percentile estimates.

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3 REFERENCES

Abdollahi. A; Eng. A; J an tun en. LM; Ahrens. L; Shoeib. M; Parnis. J.M; Hairier. T. (2017).

Characterization of polyurethane foam (PUF) and sorbent impregnated PUF (SIP) disk passive
air samplers for measuring organophosphate flame retardants. Chemosphere 167: 212-219.

http://dx.doi.org/10.1016/i .chemosphere..01 0° i i i
AitBamai. Y; Araki. A; Nomura. T; Kawai. T; Tsuboi. T; Kobavashi. S: Miyashita. C; Takeda. M;

Shimizu. H; Kishi. R (2018). Association of filaggrin gene mutations and childhood eczema and
wheeze with phthalates and phosphorus flame retardants in house dust: The Hokkaido study on
Environment and Children's Health. Environ Int 121: 102-110.
http://dx.doi.org/10.1016/i .envint.2018.08.046
AU x	U .H 1 Mi Eede. N: Goosey. E: Harrad. S: Neels. I \ 1' Mannetie \ i oakln i

Douwes. aci. A. (2012). Occurrence of alternative flame retardants in indoor dust from
New Zealand: Indoor sources and human exposure assessment. Chemosphere 88: 1276-1282.
http://dx.doi.off	.chemosphere.2012.03.100

Andreses < * H»idmann \ -'ster. K. (2004). Organophosphorus flame retardants and plasticisers in
surface waters. Sci Total Environ 332: 155-166.
http://dx.doi.org/10.1016/i .scitotenv.2004.04.021
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