Sixth Five-year Review Report for Better Brite Plating Co. Chrome and Zinc Shops Superfund Site Brown County Wisconsin


997103

SIXTH FIVE-YEAR REVIEW REPORT FOR
BETTER BRITE PLATING CO. CHROME AMD ZINC SHOPS SUPERFUND SITE
BROWN COUNTY, WISCONSIN

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Prepared by
U.S. Environmental Protection Agency
Region 5
Chicago, Illinois

11/6/2024

X Douglas Ballotti

Douglas Ballotti, Director

Superfund & Emergency Management Division

Signed by: DOUGLAS BALLOTTI

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Table of Contents

LIST OF ABBREVIATIONS & ACRONYMS	2

I.	INTRODUCTION	3

FIVE-YEAR REVIEW SUMMARY FORM	4

II.	RESPONSE ACTION SUMMARY	5

Basis forTaking Action	5

Response Actions	7

Status of Implementation	9

Institutional Controls	10

Systems Operations/Operation & Maintenance	14

III.	PROGRESS SINCE THE LAST REVIEW	15

IV.	FIVE-YEAR REVIEW PROCESS	18

Community Notification, Involvement & Site Interviews	18

Data Review	18

Site Inspection	21

V.	TECHNICAL ASSESSMENT	21

QUESTION A: Is the remedy functioning as intended by the decision documents?	21

QUESTION B: Are the exposure assumptions, toxicity data, cleanup levels, and remedial action

objectives (RAOs) used at the time of the remedy selection still valid?	22

QUESTION C: Has any other information come to light that could call into question the
protectiveness of the remedy?	23

VI.	ISSUES/RECOMMENDATIONS	23

OTHER FINDINGS	24

VII.	PROTECTIVENESS STATEMENT	25

VIII.	NEXT REVIEW	26

APPENDIX A-REFERENCE LIST	27

APPENDIX B- Site Maps

APPENDIX C- Site Photos

APPENDIX D - FYR Inspection Checklist

APPENDIX E - Press Times FYR Notification

APPENDIX F - 2021 Summary Groundwater Monitoring Report

APPENDIX G - 2022 Summary Groundwater Monitoring Report

APPENDIX H - 2023 PFAS Validated Data Report

Tables

Table 1: Chrome Shop Groundwater COCs Cleanup Standards

Table 2: Zinc Shop Groundwater COCs Cleanup Standards

Table 3 - Summary of Planned and/or Implemented ICs

Table 4 - Protectiveness Determinations/Statements from the 2019 FYR

Table 5 - Status of Recommendations from the 2019 FYR

Table 6 - Chrome Shop PFAS Sampling Results

Table 7 - Zinc Shop PFAS Sampling Results

1

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LIST OF ABBREVIATIONS & ACRONYMS

BRRTS

Bureau for Remediation and Redevelopment Tracking System

CERCLA

Comprehensive Environmental Response, Compensation, and Liability Act

CFR

Code of Federal Regulations

CO

Continuing Obligation

COC

Contaminant of Concern

CSF

Cancer slope factor

EPA

United States Environmental Protection Agency

ES

Enforcement Standard

FOTH

Foth Infrastructure and Environment

FYR

Five-Year Review

ICs

Institutional Controls

ICIAP

Institutional Control Implementation and Assurance Plan

LTS

Long-Term Stewardship

NCP

National Oil and Hazardous Substances Pollution Contingency Plan

NPL

National Priorities List

O&M

Operation and Maintenance

OU

Operable Unit

PAL

Preventive Action Limit

PCOR

Preliminary Close Out Report

PFAS

Per- and Polyfluoroalkyl Substances

PFHxS

Perfluorohexanesulfonic Acid

PFOA

Perfluorooctanoic acid

PFOS

Perfluorooctane sulfonate

ppb

parts per billion

ppt

parts per trillion

RAO

Remedial Action Objective

RfD

Reference Dose

ROD

Record of Decision

RPM

Remedial Project Manager

Site

Better Brite Plating Co. Chrome and Zinc Shops Superfund Site

UU/UE

Unlimited Use and Unrestricted Exposure

VOC

Volatile Organic Compound

WAC

Wisconsin Administrative Code

WDNR

Wisconsin Department of Natural Resources

2

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I. INTRODUCTION

The purpose of a Five-Year Review (FYR) is to evaluate the implementation and performance of a
remedy in order to determine if the remedy is and will continue to be protective of human health and
the environment. The methods, findings, and conclusions of reviews are documented in FYR reports
such as this one. In addition, FYR reports identify issues found during the review, if any, and document
recommendations to address them.

The United States Environmental Protection Agency (EPA) is preparing this FYR pursuant to the
Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Section 121,
consistent with the National Oil and Hazardous Substances Pollution Contingency Plan (NCP) (40 CFR
Section 300.430(f)(4)(ii)), and considering EPA policy.

This is the sixth FYR for the Better Brite Plating Co. Chrome and Zinc Shops Superfund Site (Site). The
triggering action for this statutory FYR is the completion date of the previous FYR on November 18,
2019. The FYR has been prepared due to the fact that hazardous substances, pollutants, or
contaminants remain at the site above levels that allow for unlimited use and unrestricted exposure
(UU/UE).

The Site consists of two Operable Units (OUs), both of which will be addressed in this FYR.
Implementation of the 1991 interim remedy Record of Decision (ROD) and the 1996 final remedy ROD,
signed on September 24,1996, were treated as separate OUs for administrative purposes. Therefore,
OU1 addresses the implementation of the 1991 interim remedy ROD, and OU2 addresses the
implementation of the 1996 final remedy ROD.

The Better Brite Plating Co. Chrome and Zinc Shops Superfund Site FYR was led by Sarah Friedman, EPA
Remedial Project Manager (RPM). Participants included Gwen Saliares, Wisconsin Department of
Natural Resources (WDNR) Project Manager; and Karen Chen, EPA Community Involvement
Coordinator. EPA and WDNR are the lead agencies for developing and implementing the remedy for
the Site. The review began on 11/15/2023.

Site Background

The Site is in the City of De Pere, Brown County, Wisconsin. The Site consists of two separate
properties: the Better Brite Zinc Shop and the Better Brite Chrome Shop. These two properties were
listed as one site on the National Priorities List (NPL) on August 30, 1990 (Federal Register 35502 -
35512 / Vol. 55, No. 169) due to similarities in contaminants, site history, and ownership.

The Better Brite Plating Company began operations at the Zinc Shop in the late 1960s and was
primarily engaged in plating 15-20-foot rollers for paper mills in the area. By 1978, chrome plating
operations began at the Chrome Shop, and operations at the Zinc Shop were converted to zinc plating
only. Vertical in-ground dip tanks were used for chromium plating operations. Known chemicals
include muriatic acid, sodium hypochlorite, degreasers containing volatile organic compounds (VOCs),
chromic acid, and sodium cyanide solutions.

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Operational practices were poor. Numerous complaints from neighbors and employees regarding spills
and dumping prompted initial investigations by WDNR in 1979. Limited site investigations and remedial
efforts were conducted during the 1980s. The Better Brite Plating Company filed for bankruptcy
protection and discontinued operations at the Chrome Shop in 1985, but operations continued at the
Zinc Shop until 1989. Investigations found that vertical tanks at the Chrome Shop had leaked between
20,000 and 60,000 gallons of chrome plating solution while the plant was in operation. Early
investigations discovered high concentrations of chromium, zinc, cadmium, and cyanide in stored
waste, surface water, and soil samples at the Site.

The Chrome Shop property comprises 3.7 acres and the Zinc Shop property comprises 0.61 acres. Both
the Zinc Shop and Chrome Shop properties are in a mixed residential/commercial area. Land use is
expected to remain the same in the foreseeable future. Several homes directly border both properties,
with the nearest residence located across the street to the south of the Zinc Shop property.
Approximately seven single-family residences are adjacent to the Chrome Shop property. Commercial
operations nearby include a foundry on South Sixth Street, a heating and air conditioning contractor,
and a resale shop adjacent to the Zinc Shop as depicted in the Site maps (Appendix B).

FIVE-YEAR REVIEW SUMMARY FORM

SITE IDENTIFICATION

Site Name: Better Brite Plating Co. Chrome and Zinc Shops

EPA ID:

WIT560010118

Region: 5

State: Wl

City/County: De Pere, Brown

NPL Status: Final

Multiple OUs?

Yes

Has the site achieved construction completion?

Yes

Lead agency: EPA

Author name (Federal or State Project Manager): Sarah Friedman

Author affiliation: EPA Region 5

Review period: 11/15/2023 - 7/19/2024

Date of site inspection: 4/10/2024

Type of review: Statutory

Review number: 6

Triggering action date: 11/18/2019

Due date (five years after triggering action date): 11/18/2024

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II. RESPONSE ACTION SUMMARY

Basis for Taking Action

Hazardous substances have been released at the Site. These substances include VOCs, cyanide, and
metals, especially chromium and hexavalent chromium as identified by the ROD. EPA and WDNR
addressed the Contaminants of Concern (COCs) in soil contaminated with cyanide, sodium, zinc,
chromium, and cadmium by removal and response actions in 1993. EPA and WDNR have determined
that chromium is the primary COC in groundwater at both the Zinc Shop and Chrome Shop properties
(EPA, 1996). A large percentage of the chromium was present in the form of hexavalent chromium, the
most mobile and toxic form of chromium. Other COCs in site groundwater include the following in
Table 1 and Table 2 below, along with their preventive action limits (PALs) which are WDNR's
groundwater quality standards.

Table 1: Chrome Shop Groundwater COCs Cleanup Standards

Groundwater COC

Preventive Action Limits (PALs)



in parts per billion (ppb)

Inorganics

Aluminum

NA

Antimony

1.2

Arsenic

5

Beryllium

0.4

Cadmium

0.5

Calcium

NA

Cobalt

NA

Chromium

10

Hexavalent Chromium

NA

Iron

150*

Magnesium

NA

Manganese

25*

Nickel

20

Potassium

NA

Silver

10

Sodium

NA

Thallium

0.4

Vanadium

NA

VOCs

Carbon Disulfide

NA

1,1-Dichloroethene

0.7

Tetrachloroethene

0.5

1,1,1-Trichloroethane

40

Trichloroethene

0.5

5

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Notes: *	=	Public Welfare Standard

NA =	Not Available

Ppb =	parts per billion

Table 2: Zinc Shop Groundwater COCs Cleanup Standards

Groundwater COCs

PALs (ppb)

Inorganics

Aluminum

NA

Antimony

1.2

Beryllium

0.4

Calcium

NA

Cobalt

NA

Chromium

10

Hexavalent Chromium

NA

Cyanide

40

Iron

150*

Lead

1.5

Magnesium

NA

Manganese

25*

Nickel

20

Potassium

NA

Sodium

NA

Thallium

0.4

Vanadium

NA

VOCs

Carbon Disulfide

NA

Carbon Tetrachloride

0.5

1,2-Dichloroethane

0.5

1,1,2-Trichloroethane

0.06

Notes: *	=	Public Welfare Standard

NA =	Not Available

Ppb =	parts per billion

Exposure through direct contact, inhalation and ingestion to soil and groundwater contaminated with
site COCs posed risks to human health and, therefore, needed to be addressed with response actions.
Contaminated groundwater at the site poses a possible future threat to human health and the
environment therefore a groundwater remedy was selected in the ROD (EPA, 1996). A quantitative risk
assessment was not completed because it was already addressed through the health based ARARs, and
it was determined that a qualitative risk assessment was sufficient (EPA, 1996). An ecological risk
assessment was not conducted because this is primarily a groundwater remedy (EPA, 1999) and soil
contamination as mentioned above was removed through removal actions or soil stabilized prior to
remedy selection process.

6

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Response Actions

Initial Response

The imminent public health threats at the Site were addressed between 1980 and 1995 through WDNR
enforcement actions and EPA removal actions. These actions resulted in the disposal of all
containerized waste, contaminated debris, and shallow contaminated soil; construction of fencing;
placement of clean soil over the remaining contaminated soil; and construction and operation of a
groundwater extraction and treatment system.

Chrome Shop

From 1979-1990, ongoing investigations and litigation by WDNR resulted in limited measures to
remove or contain contamination. EPA prepared a response plan in 1979, which the Better Brite
Plating Company implemented, including excavation of a groundwater collection trench, installation of
surface water controls and groundwater monitoring wells, and limited soil removal (EPA, 1991).
Groundwater from the collection trench was discharged to a City of De Pere sanitary sewer. Following
the 1985 bankruptcy by Better Brite Plating Company, the Chrome Shop building was demolished and
removed, the holding pond was excavated, and the former building area was capped with clay (EPA,
1991). In April 1986, EPA removed four subsurface plating tanks from the Chrome Shop property (EPA,
1991). In September 1986, EPA prepared a Site Assessment and Emergency Action Plan, which
concluded that the Chrome Shop property area posed an immediate threat to human health (EPA,
1991). From September 1986 to April 1987, EPA completed actions that removed 83 tons of
contaminated soil, 9,279 gallons of chromic acid, 3,600 gallons of caustic liquid, 550 gallons of cyanide
solution, 150 pounds of cyanide sludge, and 500 gallons of flammable liquid (EPA, 1991).

The Better Brite Plating Company discontinued pumping from the collection trench in 1986 (EPA,
1991). As a result, chromium contaminated surface water began collecting in nearby yards. As an
interim measure in March 1988, EPA started pumping from the collection trench and discharging waste
to the sanitary sewer (EPA, 1991). In 1990, EPA built a 2,000 gallon per day treatment system to treat
groundwater prior to discharging to the sanitary sewer, and initiated pumping from a recovery well in
addition to the collection trench (EPA, 1991). In 1993, as part of the removal activities, EPA replaced
the recovery well and groundwater collection trench with an engineered groundwater collection sump
(EPA, 1996).

As part of EPA's ongoing removal action, EPA excavated and removed approximately 10,000 tons of
contaminated soil, concrete, and debris in 1993 (EPA, 1996). Contaminated surface soil was excavated
from the Chrome Shop property, and from some adjacent properties (EPA, 1996). A smaller area
located adjacent to the southwest corner of the former location of the Chrome Shop building was
excavated to a depth of 20 feet, where sampling indicated that soils outside of and below the
excavated area were uncontaminated (EPA, 1996). The excavated area was subsequently filled with
clean soil (EPA, 1996).

Zinc Shop

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In October 1989, EPA performed a site assessment at the Zinc Shop. The assessment confirmed
WDNR's discovery of contamination and illegally stored hazardous substances. Based on the results of
the site assessment, EPA conducted a removal action from December 27,1989, to October 22, 1993,
that entailed sampling and sorting hazardous materials; securing, decontaminating, and heating the
building; removing waste; and compiling the analytical results from previous investigations (EPA,

1996).

In 1990, as part of the removal action, EPA constructed a groundwater recovery sump along the east
side of the building (EPA, 2000). Contaminated groundwater from the sump was trucked to the
Chrome Shop for pretreatment prior to discharge to the De Pere sanitary sewer (EPA, 2000).
Approximately 350 cubic yards of chromium contaminated soil was excavated during installation of the
sump (EPA, 2000). In 1991, EPA conducted additional decontamination of the building and investigated
beneath the concrete slab foundation (EPA, 2000). The original sump was replaced with a larger sump
following further excavation in 1993 (EPA, 2000). Until the fall of 1999, contaminated groundwater was
regularly extracted from the sump and trucked to the Chrome Shop for treatment (EPA, 2000).

The Zinc Shop burned down in September 1992 (EPA, 1996). From November 1992 to January 1993,
EPA removed the remains of the building, the slab foundation, and two 15-foot long vertical in-ground
dip tanks as part of the ongoing removal action (EPA, 1996). Contaminated soil was excavated from
beneath the slab foundation until uncontaminated soil was reached. Approximately 6,032 tons of
chromium contaminated soil, concrete, and building debris was removed from the Site (EPA, 1996).

Remedy Selection

On June 28, 1991, EPA issued an interim remedy ROD that required the following selected remedies:

• Expanding the operation of the treatment facility in order to meet the pretreatment standards
set by the City of De Pere's publicly owned treatment works.

• Improving surface water drainage by incorporating a surface water control system and
modifying the groundwater collection system to prevent contamination leaving the area and
instead allow the groundwater to be redirected to a holding pond located in the northwest
corner of the Chrome Property.

• Securing the Site with fencing and siding material to prevent contact with contaminated soil
and debris.

• Installing monitoring wells to serve as an early detection system for a nearby municipal well and
monitoring potential contamination within the deep aquifer.

Since soil from both the Zinc Shop and Chrome Shop properties was already excavated as part of EPA
removal or other actions before this ROD, soil excavation remedies were not included in this final ROD.
On September 24, 1996, EPA issued a final remedy ROD. This ROD added the following requirements as
selected remedies for the Site:

• Continue extraction and treatment of groundwater from the sump at the Zinc Shop with
discharge of treated water to the sanitary sewer.

• Relocate the existing groundwater pre-treatment plant from the Chrome Shop to the Zinc Shop.

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• Conduct in-situ stabilization and/or solidification treatment to stabilize hexavalent chromium in
soil and groundwater at the Chrome Shop to prevent further migration.

• Construct new exterior building foundation drains with collected water treated at the Zinc Shop
pretreatment facility. If necessary, any additional soil contamination found near the Zinc Shop
will be removed, treated and disposed of.

• Continue groundwater monitoring at the Chrome Shop and Zinc Shop to evaluate the
effectiveness of the remedial action.

• Implement Institutional Controls (ICs) and site access restrictions, such as deed restrictions
placed on the Zinc and Chrome Shop properties, to prevent activities that could affect the
remedy, including subsurface excavation and water well installation.

Remedial Action Objectives (RAOs) were developed for the Site remedy to address groundwater and
soil contamination. The RAOs listed in the ROD include:

• The initial groundwater objective is to protect the underlying bedrock aquifer and contain
and/or control the further migration of contaminants.

• The long-term remedial objective for the Site is to reduce the contaminant concentration in
groundwater to meet state and/or federal groundwater quality standards, whichever are more
stringent.

• Prevent human contact with the contaminated soil, dust, and groundwater at the residences
near the Zinc Shop.

The 1996 ROD Summary included an assessment of the remaining risks from groundwater
contamination. EPA and WDNR concluded that the Wisconsin Administrative Code (WAC) Chapter NR
140 Enforcement Standards (ESs) and Wisconsin Administrative Code (WAC) Chapter NR 140
Preventive Action Limits (PALs) provided sufficient protection of public health for the use of residential
groundwater (EPA, 1996). Per the ROD, the standard for determining groundwater COCs is the ES (EPA,
1996). The PAL is used to identify potential contamination problems and the remedy is intended to
achieve compliance with PALs for all COCs (EPA, 1996). The COCs identified in 1996 ROD are identified
in Tables 1 and 2 above for groundwater at the Chrome Shop and Zinc Shop properties.

Status of Implementation

Pursuant to the 1991 interim ROD, a fencing contractor was subcontracted to install the fence at the
Chrome Shop property, which enclosed the groundwater collection systems, the groundwater
treatment plant and monitoring wells that were installed there at that time (EPA, 1999). Other
remedial activities from the interim ROD (OU1) were concluded, and all components were
implemented prior to the 1996 final remedy ROD (OU2). The remedy selected in the 1996 ROD are still
operating and in effect specifically for groundwater monitoring (EPA, 1996). The remedial design,
construction and Operation and Maintenance (O&M) for the 1996 ROD selected remedies have been
conducted by WDNR under a cooperative agreement with EPA.

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Chrome Shop

Construction activities began at the Site on August 23,1999 (EPA, 2000). The area with groundwater
impacted by hexavalent chromium at the Chrome Shop was stabilized by adding a chemical reductant
to the soil to a depth of 20 feet (EPA, 2000). Approximately 15,000 cubic yards of soil were treated
(EPA, 2000). The treated soil was field tested and stockpiled after field tests indicated that treatment
was sufficient. After final treatment, all the chromium leaching results were less than the PAL (10 ppb)
(EPA, 2000). Soil stabilization at the Chrome Shop property was completed on October 29, 1999 (EPA,
2000).

The treated soils were deposited and compacted back into the excavated area (EPA, 2000). The
appearance of the Chrome Shop property was restored, and the treated soil was protected from
erosion and human contact by backfilling and grading in order to improve drainage, along with
placement of topsoil, seeding and mulching (EPA, 2000). Approximately 1,080 cubic yards of topsoil
were spread on the Chrome Shop property to provide a four-inch cover over the stabilized soil and
staging areas (EPA, 2000). The fence around the Chrome Shop was not replaced, and currently there is
no fence at the Chrome Shop. Access controls (fencing) at the Site are no longer necessary and have
been removed since the early 2000s because all potential routes of direct exposure to contaminated
soil have been eliminated. The area was then seeded and mulched, completing the soil stabilization at
the Chrome Shop property (EPA, 2000).

Zinc Shop

Relocation and restart of the groundwater recovery and treatment system from the Chrome Shop
property to the Zinc Shop property was completed by the end of 1999, as required in the 1996 OU2
ROD (EPA, 2000). This included pumping groundwater from new exterior foundation drains at two
nearby residences to the treatment system (EPA, 2000). Disturbed areas were restored and covered
with four inches of topsoil or four inches of crushed aggregate and asphalt paving (EPA, 2000).
Approximately 2,100 square feet were paved, and 45 cubic yards of topsoil were spread (EPA, 2000). A
fence was installed around the Zinc Shop sump, and groundwater treatment facilities were enclosed
within a locked building, but no fence was installed around the Zinc Shop property due to the exposure
pathways with direct soil had been addressed by removal activities (EPA, 2000). The removal of
hexavalent chromium contaminated groundwater and subsequent pretreatment prior to discharge to
the sanitary sewer is currently ongoing at the Zinc Shop property (EPA, 2000).

Institutional Controls

The site RODs require ICs and site access restrictions, such as deed restrictions and fencing, be placed
on the Zinc and Chrome Shop properties to prevent activities that could affect the remedy, or that
could result in unacceptable exposures, including subsurface excavation and water well installation. ICs
are non-engineered instruments such as administrative and/or legal controls, that help minimize the
potential for exposure to contamination and protect remedy integrity. Compliance with ICs is required
to assure long-term protectiveness for any areas which do not allow for UU/UE. Implemented ICs for
the Site are listed in Table 3 and are further discussed below. A map showing the areas to which the ICs
apply is included in Appendix B.

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Table 3: Summary of Planned and/or Implemented ICs

Media, engineered controls,
and areas that do not
support UU/UE based on
current conditions

ICs
Needed

ICs
Called
for in the
Decision
Docume
nts

Impacted
Parcel(s)

IC

Objective

Title of IC Instrument
Implemented and Date
(or planned)

Soil/Groundwater
(Chrome Shop Property)

Yes

Yes

Parcel WD-
145 Area of

soil
treatment
owned by
City of De
Pere

Restrict groundwater
use, soil excavation,
and disturbing the
cap.

•	Municipal
groundwater use
restrictions (De Pere
Municipal Code,
Chapter 26, August 7,
2001).

•	Well drilling
restrictions (De Pere
Municipal Code,
Chapter 26 & WAC
NR# 812, effective
February 1, 1991;
Renumbered NR#812
September 1994).

Soil/Groundwater
(Zinc Shop Property)

Yes

Yes

Parcel WD-
103-1 - Area
of

groundwater
contaminatio
n owned by
City of De
Pere

Requires connection
to sewer and water
system.

Prohibits cross
connections from the
city water system
and a private source.

Requires a permit for
private well
installation.

Requires
abandonment of
unused or previously
abandoned wells.

Requirements for
new well
construction and
pump installation.

•	Restrictive
covenants
filed with Brown
County, April 2010.

•	State of Wisconsin
Continuing
Obligation (CO)

April 2010 (Statute
292.12).

•	WDNR Bureau for
Remediation and
Redevelopment
Tracking System
(BRRTS) database,
April 2010 Wisconsin
Statute 292.12(2)(c)).

11

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Status of Access Restrictions and ICs:

The City of De Pere assumed ownership of the Better Brite Company properties in 2001. City
ownership and oversight by WDNR and EPA provide assurance that the remedial actions will be
properly maintained, and that the contaminated areas will not be improperly developed in the future.
The City has no plans to sell the properties currently. The fence around the Chrome Shop property was
never replaced after removal activities in 1999 and currently does not exist due to it no longer being
necessary as direct contact exposure had been addressed by removal actions. The Zinc shop property,
however, still does have a fence around the sump and is locked. The portion of the Zinc Shop property
that is paved with asphalt is being leased by the City for parking. Currently, the City has no other plans
for use of the two properties.

For the areas where the residual contamination that remains following a cleanup is above state
standards1, the State of Wisconsin, under the statutory authority of Wis. Stat. § 292.122, has placed a
continuing obligation (CO) on the property to ensure protection of human health and the environment.
A CO is a legal requirement that applies to a property even after ownership changes. Information on
COs can be found at: https://dnr.wi.gov/topic/brownfields/residual.html.

WDNR provides searchable online databases containing information on the investigation and cleanup
of potential and confirmed contamination of soil and groundwater in the state of Wisconsin. In
accordance with Wisconsin Statute § 292.12(2)(c), the approved COs are listed on a CO database,
known as the Bureau for Remediation and Redevelopment Tracking System (BRRTS) at
https://dnr.wi.gov/topic/Brownfields/botw.html. to provide public notice of residual contamination.
Additionally, relevant requirements, limitations, or conditions imposed at the property are listed in the
database. Sites can also be viewed on the Remediation and Redevelopment Sites Map, which is a map
view layer at the same web address. WDNR approval prior to well construction or reconstruction is
required for all sites with residual contamination shown on the CO database, in accordance with
Wisconsin Administrative Code Chapter NR 812.09(4)(w). This requirement applies to private drinking
water wells and high-capacity wells. The BRRTS on the Web database allows people to search
properties with the intent of purchasing land, for governments planning redevelopment, for businesses
planning expansion, and for well drillers.

Information on the Chrome Shop property, including the CO Packet, can be found at:
https://dnr.wi.gov/botw/GetActivityDetail.do?detailSeqNo=32842#co

Information on the Zinc Shop property and the CO Packet can be found at:
https://dnr.wi.gov/botw/GetActivityDetail.do?detailSeqNo=32846

Wisconsin Statute § 292.12 grants WDNR the authority to require, implement, and enforce compliance
with the requirements under Wisconsin Statute § 292.12 and the rules promulgated under the statute.

1 Chapter 160 of the Wisconsin Statutes authorizes WDNR to set numerical Groundwater Protection Standards, and WAC
Chapter NR 140 is the administrative rule that contains the standards themselves.

2 Wisconsin Statute 292.12(2)(c), regarding Sites with Residual Contamination states that the WDNR may "impose
limitations or other conditions related to property, in accordance with rules promulgated by the department, to ensure that
conditions at the site remain protective of public health, safety, and welfare and the environment, and, as applicable, to
promote economic development."

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The CO regulations required under Wisconsin Statute § 292.12 help ensure long-term protection of
public health and the environment in accordance with state laws, and the required restrictions on
groundwater use meet the objectives of the remedy.

The City of De Pere's drinking water wells are no longer in operation, as the City now uses Lake
Michigan water. The City of De Pere regulates all well construction, use, and abandonment within the
City limits. Chapter 26 of the municipal code of De Pere includes the following requirements: if the
building is adjacent to an installed water line, (1) the owner is required to connect to the City water
line, (2) cross connections between City and private water supplies are prohibited, (3) a permit is
required for any well, constructed, installed, or maintained (the permit can be revoked if the well
water is found to be contaminated), and (4) unused wells must be abandoned in accordance with
Wisconsin Administrative Code Chapter NR 812, which also prohibits installation of new wells within
1,200 feet of a hazardous waste treatment facility.

Environmental Protection Easement and Declaration of Restrictive Covenants (restrictive covenants)
were filed on April 14, 2010, on the affected properties owned by the City. The covenants provide
property use restrictions that run with the land for the purpose of protecting human health and the
environment until such time as EPA and WDNR determine that they are no longer necessary to ensure
protectiveness. The following conditions and restrictions apply to the use of the properties: 1) the
prohibition of groundwater use for consumptive or other uses without prior approval from WDNR and
EPA; 2) the prohibition to excavate soils or disturb the cap in the Chrome and Zinc Shop areas of the
Site; and 3) the prohibition of excavating or grading of the land surface, filling on the capped area,
plowing for agricultural cultivation, and construction or installation of a building or other structure with
a foundation that would sit on or be placed within the cap or cover in the Chrome and Zinc Shop areas.

EPA's review of the ICs determined that they are currently adequate to protect human health and the
environment. At this time, there are no plans to pursue restrictive covenants on affected properties
that are not owned by the City, because City and WDNR regulations should be effective in preventing
residential groundwater use, and an agreement between the City of De Pere and WDNR will ensure
notification to WDNR should construction permits be issued in the general area of the Site. The State of
Wisconsin's CO and listing on WDNR's BRRTS database provide an additional layer of protection for the
Site.

Current Compliance:

Based on inspections and discussions with WDNR, EPA is not aware of Site or media uses which are
inconsistent with the stated objectives to be achieved by the ICs. The remedy appears to be
functioning as intended. No Site uses that are inconsistent with the implemented ICs or remedy IC
objectives were noted during the April 10, 2024, FYR Site inspection. EPA conducted a review of the ICs
and has determined that they are currently adequate to protect human health and the environment.
As part of this FYR, EPA performed the following activities related to the IC evaluation:

•	A preliminary review of the Environmental Protection Easement and Declaration of Restrictive
Covenant dated April 14, 2010;

•	A Site inspection on April 10, 2024; and

13

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• An evaluation of the effectiveness of the ICs.

Each area where ICs are necessary to assure protectiveness is identified in Table 3, above. Both shops
or parcels are owned by the City of De Pere.

IC Follow up Actions Needed:

Since continued compliance with ICs is necessary to ensure the long-term protectiveness of the
remedy, planning for long-term stewardship (LTS) is required to ensure that the site ICs continue to be
maintained, monitored, and enforced so that the remedy continues to function as intended. EPA will
continue to evaluate the ICs and work with WDNR to develop an Institutional Control Implementation
Assurance Plan (ICIAP). The developed ICIAP will document IC evaluation activities and long-term
stewardship (LTS) procedures for the continued monitoring and maintenance of the ICs at the Site. The
IC evaluation activities will include, as needed, updating maps depicting current conditions in areas
that do not allow for UU/UE and conducting title work to ensure no prior encumbrances exist on the
Site that are inconsistent with the ICs. Further, the ICIAP will include LTS procedures, such as regular
inspection of the engineering controls/access controls at the Site, and routine review of the ICs at the
Site.

The ICIAP will also include a requirement that WDNR annually certifies to EPA that ICs are in place and
effective. Finally, development of a communications plan to provide routine remedy updates and use
of the State's "one-call" system to receive notifications of dig sites in the vicinity of the remedial
system/components should be explored by WDNR.

Systems Operations/Operation & Maintenance

WDNR is responsible for performing O&M at the Site. O&M at the Site includes O&M of the
groundwater treatment plant, groundwater sumps, disposal of treatment byproducts, annual
groundwater sampling and analysis, maintain the cap/cover areas at the Chrome Shop, and monitoring
of the IC remedy. There are currently no substantive problems with system operation or environmental
monitoring of site remedy components.

WDNR prepared a Quality Assurance Project Plan for Groundwater Monitoring, which was finalized on
September 28, 1998, and a Remedial Action Documentation Report, finalized on February 21, 2000
(EPA, 2000). An updated Quality Assurance Project Plan for Groundwater Monitoring is in progress and
is expected to be approved by EPA in 2025. Together these documents provide a plan for long-term
monitoring, sampling, analysis, validation, health and safety, maintaining the grounds, and the content
of monitoring reports. These documents function as an O&M plan for the remedies at the Site and
include the same procedures outlined in an O&M plan. Until March 31, 2009, the City of De Pere was
responsible for O&M of the Zinc Shop groundwater removal system under an agreement with WDNR.
O&M was performed by City of De Pere wastewater treatment staff. In April 2009, WDNR assumed
responsibility for O&M of site remedies and follows the procedures outlined in the previously
mentioned above O&M documents (WDNR, 2011). WDNR prepared a Better Brite Water Treatment
Procedures document on July 21, 2011, to record the water treatment process at the Zinc Shop
property (WDNR, 2011). Maps showing the location of the wells are provided in Appendix B.

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III. PROGRESS SINCE THE LAST REVIEW

This section includes the protectiveness determinations and statements from the last FYR as well as
the recommendations and other findings from the last FYR and the status of those recommendations.

Table 4: Protectiveness Determinations/Statements from the 2019 FYR

ou#

Protectiveness
Determination

Protectiveness Statement

OU1

Short-term Protective

The Better Brite Site remedy currently protects human
health and the environment. All immediate threats
to human health and the environment have been
controlled. Exposure pathways that could result in
unacceptable risks are being monitored and controlled
through the annual monitoring of groundwater
via the long-term monitoring network at the Site.
However, in order for the remedy to be protective in
the long term, the following actions need to be taken to
ensure protectiveness: develop and implement
long-term stewardship procedures for monitoring and
tracking compliance with existing ICs by
developing an ICIAP or equivalent document for the
Site; evaluate the effectiveness of the soil
stabilization and the potential for off-site migration of
hexavalent chromium contaminated groundwater
at the Chrome Shop; and, determine if PFOA/PFOS are
potential contaminants of concern and whether
further investigation is necessary to characterize these
contaminants.

OU2

Short-term Protective

The Better Brite Site remedy currently protects human
health and the environment. All immediate threats
to human health and the environment have been
controlled. Exposure pathways that could result in
unacceptable risks are being monitored and controlled
through the annual monitoring of groundwater
via the long-term monitoring network at the Site.
However, in order for the remedy to be protective in
the long term, the following actions need to be taken to
ensure protectiveness: develop and implement
long-term stewardship procedures for monitoring and
tracking compliance with existing ICs by
developing an ICIAP or equivalent document for the
Site; evaluate the effectiveness of the soil
stabilization and the potential for off-site migration of
hexavalent chromium contaminated groundwater
at the Chrome Shop; and, determine if PFOA/PFOS are
potential contaminants of concern and whether
further investigation is necessary to characterize these
contaminants.

15

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Sitewide

Short-term Protective

The Better Brite Site remedy currently protects human
health and the environment. All immediate threats
to human health and the environment have been
controlled. Exposure pathways that could result in
unacceptable risks are being monitored and controlled
through the annual monitoring of groundwater
via the long-term monitoring network at the Site.
However, in order for the remedy to be protective in
the long term, the following actions need to be taken to
ensure protectiveness: develop and implement
long-term stewardship procedures for monitoring and
tracking compliance with existing ICs by
developing an ICIAP or equivalent document for the
Site; evaluate the effectiveness of the soil
stabilization and the potential for off-site migration of
hexavalent chromium contaminated groundwater
at the Chrome Shop; and, determine if PFOA/PFOS are
potential contaminants of concern and whether
further investigation is necessary to characterize these
contaminants.

Table 5: Status of Recommendations from t

he 2019 FYR

OU#

Issue

Recommendations

Current
Status

Current Implementation Status
Description

Completion

Date (if
applicable)

OU1,
OU2

A review of the ICs
is needed to
ensure that the
remedy continues
to function as
intended and that
effective

procedures are in
place for long-term
stewardship of the
Better Brite Site.

Prepare and
implement an
ICIAP or equivalent
document to
ensure long-term
stewardship.

Ongoing

A draft of the plan is being
reviewed by the agencies and is
expected to be completed by
12/30/2024.

N/A

OU1,
OU2

Concern about
effectiveness of
stabilization
treatment and off-
site migration of
the hexavalent
chromium
contaminated
groundwater at
the Chrome Shop.

Further evaluate
the effectiveness of
the soil

stabilization and
the potential for
off-site migration
of hexavalent
chromium
contaminated
groundwater at the
Chrome Shop.

Completed

Hexavalent chromium in the
groundwater is above the WDNR
PAL. Nevertheless, contaminant
concentrations have been
significantly decreasing
compared to historical
groundwater concentrations
within the soil stabilization area.
Downgradient monitoring wells
continue to show no signs of
plume migration. As discussed in
the Data Review Section of this
FYR, concentrations have been

5/22/2024

16

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decreasing and the plume is not
migrating for Site COCs.

OU1,
OU2

PFOA/PFOS have
not been
evaluated as
potential
contaminants of
concern.

Determine if
PFOA/PFOS are
potential
contaminants of
concern and
whether further
investigation is
necessary to
characterize the
contaminants.

Addressed
in Next FYR

Perfluorooctanoic acid
(PFOA)/perfluorooctane
sulfonate (PFOS) have been
detected in groundwater by a
first round of sampling
conducted in 2023. It has been
confirmed that no residents in
the immediate surrounding area
of the Sites are drinking private
water. Everyone in the area is on
municipal water. The first round
of sampling did not collect a
background sample. The nature
and extent of the per- and
polyfluoroalkyl substance (PFAS)
plume and if the detections are
attributed to on-site activities is
still unknown. Additional work is
needed to delineate the
PFOA/PFOS plume for the Site.
This additional work should
include another round of
sampling along with a
background sample.

N/A

The following are Other Findings that were identified during the 2019 FYR and may accelerate Site
close out and improve O&M, but do not affect current or future protectiveness. A status update is
provided for each.

• In addition to the concerns about the effectiveness of the stabilization remedy and its

continuing impact to groundwater concentrations, the RAO "to remediate the groundwater to
protect human health and the environment and to meet state and federal standards" per the
ROD is likely to take an extended time frame. Evaluate newly developed technologies and
opportunities to improve remedy performance that may significantly shorten the time frame to
achieve the RAOs. EPA recommends completing a Site-wide Remedy Optimization Review of
the present remedy to determine what can be done, if anything, to address the goal of
achieving state and federal standards in a reasonable time frame.

o An optimization report was completed on May 2020, that recommended installing
additional wells around MW-116 at the Chrome Shop property and sample every other
year (EPA, 2020). The report also recommended further characterizing the area around
W-l, W-1A, MW-6, MW-10, and the sump to assist with further accelerating the
remediation of chromium at the Zinc Shop. The hexavalent chromium plume at the
Chrome Shop property is characterized by a single monitoring well, MW-116, and the
report recommended further delineating this data point with additional wells. As of this

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FYR, however, WDNR does not have any additional funding to implement the
recommendations.

• Update O&M and Monitoring plans with the decision to include a re-evaluation of whether to
collect groundwater samples using a low-flow sampling procedure once chromium levels are
decreased to levels close to the ESs.

o Foth Infrastructure and Environment (consultant to WDNR) (FOTH) has submitted an
updated Quality Assurance Project Plan to EPA on November 13, 2023. The document is
in its 4th review of the updated document for EPA approval.

IV. FIVE-YEAR REVIEW PROCESS

Community Notification. Involvement & Site Interviews

A public notice was made available by a newspaper posting in the Press Times on 11/17/2023, stating
that there was a FYR and inviting the public to submit any comments to EPA. The Press Times serves
greater Green Bay and Brown County, Wisconsin. No comments concerning the Site or the sixth FYR
process were received during this period, and no interviews were conducted by EPA. WDNR and EPA
discussed aspects of the Site during monthly meetings and the Site inspection. The results of the
review and the FYR report will be available online at the Site information repository located at the
Brown County Library, Kress Family Branch, 333 N. Broadway, De Pere, Wisconsin.

Data Review

This FYR consisted of a review of relevant documents including O&M records and monitoring data,
previous FYRs, remedial investigation reports, and decision documents. Monitoring data was compared
to groundwater cleanup standards, as identified in the September 24, 1996, ROD. In this FYR, sampling
of metals and VOCs were conducted in 2021 and 2022. 2023 results were not validated by the time of
this FYR and are not discussed. They will be included in the next FYR. Sampling was not conducted in
2020 due to the coronavirus pandemic. Since 2021, all the monitoring wells were sampled at the
Chrome Shop property and all the monitoring wells, and the sump were sampled at the Zinc Shop
property on an annual basis. Well PF-MW-2 was also sampled at the Zinc Shop in 2022.

The PAL for hexavalent chromium is 10 ppb and the ES is 100 ppb. These cleanup standards were
developed later after the 1996 ROD, but the determined PAL number has been used when evaluating
data for the Site. A decision document needs to reflect this number for administrative purposes.
Hexavalent chromium is the only COC exceeding groundwater PALs at both properties at the Site. As
discussed in the 1996 ROD, PAL is the cleanup standard for all COCs, and specifically for hexavalent
chromium the WAC NR 140 PAL is 10 ppb. This PAL has not been met yet in MW-116 at the Chrome
shop property or the sump, W-l, and W-1A at the Zinc shop property.

Chrome Shop Property

At the former Chrome Shop property (as of the most recent sampling in November 2022) the
groundwater cleanup standard for hexavalent chromium was exceeded for PALs in monitoring well
MW-116. The highest concentration detected during the review period (2021 to 2022) was 7100 ppb

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and occurred in October 2021. Since 2021, hexavalent chromium concentrations have decreased from
previous sampling events to 6400 ppb in November 2022 (down from a high of 54,000 ppb in May
2005). Groundwater samples were also analyzed for several VOCs at MW-116 to determine if vapor
intrusion could be an exposure pathway at the Site. MW-116 had PAL exceedances in 2022 for 1,1-
Dichloroethene (34 ppb). MW-116 had PAL exceedances for Iron (estimated to be 153 ppb),
Tetrachloroethene (1 ppb), Trichloroethene (2 ppb), and 1,1,1-Trichloroethane (116 ppb) in 2022.
WDNR investigated by following EPA's vapor intrusion guidance and the distances to the surrounding
buildings to screen for vapor intrusion concerns (EPA 2015). All the surrounding buildings were over
the 100 ft threshold for screening for vapor intrusion risk. It is important to note, the VOCs only
exceeded WDNR's screening values and did not exceed EPA's screening standards for vapor intrusion.
EPA and WDNR determined vapor intrusion was not an exposure pathway at the Site based on the
results and EPA's vapor intrusion guideline. In addition, monitoring well MW-115, located on the
westside of the parcel, had PAL exceedance for Iron. VOC groundwater monitoring results, including
historical concentrations, are included in Appendix G.

Although groundwater contamination above PALs is still present within the area of soil stabilization,
concentrations have been significantly reduced compared to historical groundwater concentrations.
Monitoring wells surrounding MW-116 continue to show no signs of plume migration for Site COCs. As
part of routine groundwater monitoring for the site, the effectiveness of soil stabilization remedy and
the potential for off-site migration of hexavalent chromium contaminated groundwater will continue
to be evaluated.

Zinc Shop Property

At the former Zinc Shop property, from October 2021 through November 2022, the groundwater
cleanup standard for hexavalent chromium was exceeded in monitoring wells:

• W-l (2000 ppb in November 2022, down from a high of 6100 ppb in October 2021),

• W-1A (790 ppb in November 2002 and 640 ppb in October 2021),

• MW-3/MW-3R (less than 73 ppb in November 2022 and less than 180 ppb in October 2021),

• MW-5 (less than 73 ppb in November 2022 and less than 51 ppb in October 2021),

• MW-6 (less than 1800 ppb in November 2022 and 1400 ppb in October 2021),

• The sump (4200 ppb in November 2022, down from a high of 6500 ppb in October 2022).

Groundwater samples were also analyzed for cyanide and VOCs exceedances in 2022. The zinc sump
analytical results detected PAL exceedances for Cyanide above the 40-ppb cleanup standard at
concentrations of 75 ppb. WDNR further investigated and determined nearby buildings were not in
proximity to the sample screening for vapor intrusion risk based on vapor intrusion screening level
calculations. The highest concentrations of cyanide detected during the review period was in
November 2022 in the sump.

The Zinc Shop sump and monitoring well data appear to indicate an overall decreasing trend in
hexavalent chromium, cyanide, and VOCs during the review period and over the long-term in the
source area, but concentrations of hexavalent chromium still far exceed the PALs. Reaching
concentrations below PALs per the ROD is likely to take a longer time frame than estimated in the ROD.

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The most recent summary of monitoring results, which includes historical results and a photographic
survey of the monitoring wells, is provided in Appendix G. Other COCs were either below PALs or not
analyzed due to previously being phased out of sampling. The data has consistently indicated that the
total chromium in groundwater is mostly, if not all, hexavalent chromium.

In 2023, WDNR received funding from EPA to investigate PFAS in groundwater at the former Chrome
and Zinc Shop properties due to the prevalence of PFAS contamination associated with plating
facilities. At the Chrome Shop property, MW-116 exceeded the Maximum Contaminant Level (MCL) of
4 parts per trillion (ppt) for PFOS and the 4 ppt for PFOA (Table 6). MW-113 also exceeded the MCL for
PFOSand PFOA (Table 6).

Table 6: Chrome Shop PFAS Sampling Results

Monitoring Well

Compound

Sampling Result (ppt)

MW-113

PFOS

PFOA

MW-116

PFOS

9.3

PFOA

5.7

More widespread exceedances of the PFAS MCLs were detected at the Zinc Shop property. At the Zinc
Shop property, W-1A exceeded the MCL for PFOA and the 10 ppt MCL for perfluorohexanesulfonic acid
(PFHxS). W-l exceeds the MCL for PFOS and PFOA. MW-2, MW-5, MW-10, MW-11, and MW-12 all
exceeded the MCLs for PFOS and PFOA. MW-9 exceeded the MCL for PFOS. The sump only exceeded
the MCL for PFOA. MW-6 had multiple exceedances with PFHxS, PFOS, and PFOA. These results can be
found in Table 7 below and in the Appendix H.

Table 7: Zinc Shop PFAS Sampling Results

Monitoring Well

Compound

Sampling Result (ppt)

W-1A

PFHxS

PFOA

W-l

PFOS

PFOA

5.6

MW-2

PFOS

PFOA

MW-5

PFOS

PFOA

MW-6

PFHxS

150

PFOS

PFOA

MW-9

PFOS

4.7

MW-10

PFOS

PFOA

MW-11

PFOS

5.1

PFOA

7.8

MW-12

PFOS

PFOA

SUMP

PFOA

7.2

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PFAS sampling was only conducted in on-site wells, so the extent of the PFAS in groundwater and if it is
site-related is currently unknown. Therefore, conducting additional sampling to determine the nature
and extent of PFAS in groundwater is needed and to determine if the presence of PFAS is due to site-
related sources.

Site Inspection

The inspection of the Site was conducted on 4/10/2024. In attendance were Sarah Friedman, EPA;
Gwen Saliares, WDNR; Emma Mikolic, WDNR; and Nick Glander, FOTH. The purpose of the inspection
was to assess the protectiveness of the remedy. The Site Inspection Checklist is included as Appendix
D, and the inspection photo log is included in Appendix C.

The inspection team examined the groundwater extraction and treatment system at 315 S. Sixth Street
and the overall condition of the Site. The groundwater extraction, collection, and treatment equipment
were all in good condition and functioning properly. The City does not require a discharge permit of
the treated water from the pump and treatment facility. The sump fencing and treatment facility
building appeared to be in good condition, and all the monitoring wells were properly secured/locked.
MW-106A, MW-12, MW-09, MW-10, and MW-02 had minor damages which WDNR's consultant will fix
during the next sampling event in November of 2024 (see Site photos and FYR inspection in Appendix C
and D). The Chrome Shop property is currently an open field maintained by the City of De Pere. No
erosion damage was observed. The De Pere Christian Thrift Store recently purchased additional land
near MW-7 and MW-7A for the purpose of converting it to a parking lot. These wells are beyond the
Site boundary; however, De Pere Christian Thrift Store is aware of the wells and has indicated that the
parking lot will not disturb the wells. The Store will also continue to work with WDNR and EPA to allow
the agencies to access the wells. An access agreement will be considered and sought if necessary. EPA
did not observe any significant issues impacting current or future protectiveness of the remedy during
the site inspection.

V. TECHNICAL ASSESSMENT

QUESTION A: Is the remedy functioning as intended by the decision documents?

Question A Summary:

Yes.

The Site inspection and current review of data, documents, Applicable or Relevant and Appropriate
Requirements, and risk assumptions, indicate that the remedy is functioning as intended by the ROD.
While some COCs concentrations are above PALs at both properties, the concentrations have been
significantly reduced compared to historical groundwater concentrations within the soil stabilization
area.

Cleanup standards are on the path to being achieved in groundwater. Groundwater monitoring is
ongoing and would indicate if a concern is present with the stabilization treatment remedy. Currently
the results are trending downward, and the contaminant plume is stable. As discussed in the Data

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Review section, the current remedy to reduce hexavalent chromium concentrations below the ROD
cleanup standard (PAL) will likely require an extended time frame. The ROD states the selected remedy
is expected to take a very extended period of time, but also references utilizing FYRs to assess whether
newly developed technologies exist to achieve NR140 WAC standards quicker. Additional actions such
as implementing the optimization report's finding such as delineating the hexavalent chromium in
MW-116 at the Chrome Shop and characterizing the area around monitoring wells at the Zinc Shop
once funding becomes available may be needed to address these concerns, and new opportunities or
technologies may exist to improve remedy performance and significantly shorten the time frame to
achieve cleanup standards. However, based on the lack of funding implementing the optimization
report cannot be conducted at this time.

System operations appear to be working in a manner that will continue to maintain the effectiveness
of the remedy. Access controls (fencing) at the Site are no longer necessary and have been removed
since the early 2000s because all potential routes of direct exposure to contaminated soil have been
eliminated. Additionally, restrictive covenants placed on Site property owned by the City of De Pere,
and State and local governmental controls on the installation of water supply wells, prevent risks from
residential groundwater use and on land use in areas that are not UU/UE. An ICIAP is being developed
for the Site to ensure that LTS procedures are developed and implemented so that ICs continue to be
properly maintained, monitored, and enforced.

QUESTION B: Are the exposure assumptions, toxicity data, cleanup levels, and remedial action
objectives (RAOs) used at the time of the remedy selection still valid?

Question B Summary:

No.

The exposure assumptions used to assess Site risks included both current exposures and potential
future exposures. There have been no changes in the toxicity factors for the COCs that were used in
the baseline risk assessment. The assumptions are conservative and reasonable in evaluating risk and
developing risk-based cleanup levels. WDNR investigated the vapor intrusion risk at the Site based on
the VOC data and followed EPA's vapor intrusion guidance. The investigation found that the vapor
intrusion pathway is not a concern based the distance between the monitoring well to the surrounding
buildings and the VOC results do not exceed EPA's screening levels for vapor intrusion (EPA, 2015). No
changes to these assumptions or the cleanup levels developed for them are warranted, and there has
been no change to the standardized risk assessment methodology that could affect the protectiveness
of the remedy.

The PAL for hexavalent chromium was determined after the 1996 ROD was implemented. The
hexavalent chromium PAL is 10 ppb, and this value has been used and is continued to be used when
analyzing the groundwater monitoring well data. This change was not administratively documented in
a decision document; however, the PAL was referenced in the data review and analysis of monitoring
data. This PAL number needs to be addressed in a decision document for administrative purposes and
to reflect the current cleanup criteria for the Site.

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Some changes related to exposure pathways and new contaminants exist. PFAS are a class of man-
made chemicals that have been widely used as a surfactant, wetting agent, and a mist suppressing
agent for chrome plating. PFAS use for second generation wetting agent fume suppressant was first
reported in the chromium plating industry in 1954. Numerous sites are known to have environmental
media with PFAS contamination from metal plating and finishing operations (Gaines, 2022).

A first round of sampling for PFAS in site groundwater was conducted in 2023. Based on those results,
PFOS, PFOA, and PFHxS were detected above their MCLs in groundwater at the Site. PFAS sampling
was only conducted in on-site wells, so the extent of the PFAS in groundwater and if it is site-related is
currently unknown. It is also unclear at this time whether these contaminants have migrated beyond
the Site boundaries via the groundwater pathway. Residents within the one-mile area of the Site are
on the municipal water supply though. EPA recommends that PFAS continue to be evaluated as
potential COCs and that further investigation/delineation be conducted to determine the nature and
extent of PFAS and if it is due to site-related sources.

QUESTION C: Has any other information come to light that could call into question the protectiveness
of the remedy?

No.

There are no impacts from natural disasters that would call into question the protectiveness of the
remedy. Currently, there are no Site issues related to climate change impacts not apparent during the
remedy selection, remedy implementation or O&M that would interfere with the protectiveness of the
remedy.

VI. ISSUES/RECOMMENDATIONS

Issues and Recommendations Identified in the Five-Year Review:

OU(s): 1, 2

Issue Category: Institutional Controls

Issue: A review of the ICs is needed to ensure that the remedy continues to
function as intended and that effective procedures are in place for long-term
stewardship of the Better Brite Site.

Recommendation: Prepare and implement an ICIAP or equivalent document to
ensure long-term stewardship.

Affect Current
Protectiveness

Affect Future
Protectiveness

Party Responsible

Oversight Party

Milestone Date

Yes

EPA/State

EPA

12/31/2024

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OU(s): 1, 2

Issue Category: Monitoring

Issue: PFAS have been detected in Site groundwater.

Recommendation: Complete analytical sampling to determine the nature and
extent of the PFAS in groundwater and if its presence is due to site-related
sources.

Affect Current
Protectiveness

Affect Future
Protectiveness

Party Responsible

Oversight Party

Milestone Date

No

Yes

State

EPA

11/18/2028

OU(s): 1, 2

Issue Category: Other

Issue: Cleanup Criteria administrative documentation

Recommendation: The PAL for hexavalent chromium was established to be 10
ppb after the 1996 ROD, yet there is no evidence of this change in the cleanup
criteria in current Site decision documents. Therefore, an ESD or technical
memoranda or ROD amendment is needed to officially document this decision.
Not having the current cleanup criteria for hexavalent chromium reflected in a
decision document could affect the long-term protectiveness of the remedy.

Affect Current
Protectiveness

Affect Future
Protectiveness

Party Responsible

Oversight Party

Milestone Date

No

Yes

EPA/State

EPA

11/18/2028

OTHER FINDINGS

In addition, the following are recommendations that were identified during the FYR and may improve
performance of the remedy and improve management of O&M, but do not affect current or future
protect iveness:

•	Implementation of the new Quality Assurance Project Plan with the decision to include a re-
evaluation of whether to collect groundwater samples using a low-flow sampling procedure
once chromium levels are decreased to levels close to the ESs.

•	Implementation of the Optimization Report by delineating the hexavalent chromium in the one
monitoring well, MW-116, at the Chrome Shop and further characterize the area around the
sump at the Zinc Shop. Then reduce sampling of the groundwater monitoring program and this
would accelerate remediation at the Site.

•	An access agreement will be considered and sought if necessary for MW-7 and MW-7A that are
beyond the Site boundary.

24

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VII. PROTECTIVENESS STATEMENT

Protectiveness Statement(s)

Operable Unit: Protectiveness Determination:

1 Short-term Protective

Protectiveness Statement:

The Site remedy currently protects human health and the environment. All immediate threats to
human health and the environment have been controlled. Exposure pathways that could result in
unacceptable risks are being monitored and controlled through the annual monitoring of
groundwater via the long-term monitoring network at the Site and through the implementation of
effective ICs. However, in order for the remedy to be protective in the long term, the following
actions need to be taken to ensure protectiveness:

-Prepare and implement an ICIAP or equivalent document to ensure long-term stewardship of ICs;
-Determine the nature and extent of the PFAS in groundwater and if its presence is due to site-
related sources.

- The PAL for hexavalent chromium was established to be 10 ppb after the 1996 ROD, yet there is no
evidence of this change in the cleanup criteria in current Site decision documents. Therefore, an ESD
or technical memoranda or ROD amendment is needed to officially document this decision. Not
having the current cleanup criteria for hexavalent chromium reflected in a decision document could
affect the long-term protectiveness of the remedy.

Protectiveness Statement(s)

Operable Unit: Protectiveness Determination:

2 Short-term Protective

Protectiveness Statement:

Sitewide Protectiveness Statement

^^mtectivenes^etenvinatio^

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Short-term Protective
Protectiveness Statement:

The Site remedy currently protects human health and the environment. All immediate threats to
human health and the environment have been controlled. Exposure pathways that could result in
unacceptable risks are being monitored and controlled through the annual monitoring of
groundwater via the long-term monitoring network at the Site and through implementation of
effective ICs. However, in order for the remedy to be protective in the long term, the following
actions need to be taken to ensure protectiveness:

-Prepare and implement an ICIAP or equivalent document to ensure long-term stewardship of ICs;
-Determine the nature and extent of the PFAS in groundwater and if its presence is due to site-
related sources.

- The PAL for hexavalent chromium was established to be 10 ppb after the 1996 ROD, yet there is no
evidence of this change in the cleanup criteria in current Site decision documents. Therefore, an ESD
or technical memoranda or ROD amendment is needed to officially document this decision. Not
having the current cleanup criteria for hexavalent chromium reflected in a decision document could
affect the long-term protectiveness of the remedy.

VIII. NEXT REVIEW

The next FYR report for the Better Brite Plating Co. Chrome and Zinc Shops Superfund Site is required
five years from the completion date of this review.

26

-------
APPENDIX A - REFERENCE LIST

Record of Decision, EPA, 6/28/1991. SEMS Document 180766

Superfund State Contract for an Interim Remedial Action at the Better Brite Plating Co. Chrome
and Zinc Shop Site between the State of Wisconsin and the U.S. Environmental Protection
Agency, EPA, 7/16/1991. SEMS Document 901365

Record of Decision, EPA, 9/24/1996. SEMS Document 180759

First Five-Year Review, EPA, 11/23/1999. SEMS Document 149716

Preliminary Closeout Report, EPA, 2/8/2000. SEMS Document 347869

Second Five-Year Review, EPA, 11/23/2004. SEMS Document 224718

Third Five-Year Review, EPA, 11/20/2009. SEMS Document 342705

Historical and current usage of per- and polyfluoroalkyl substances (PFAS): A literature review, Gaines,
Linda G.T., 4/25/2022.

Final Design Report, HIS GeoTrans, WDNR, 9/28/1998. SEMS Document 386123

Environmental Protection Easement and Declaration of Restrictive Covenants, City of De Pere,

WDNR, 4/14/2010. BRRTS #: 02-05-000030/02-05-000031

Better Brite Water Treatment Procedures, Foth Infrastructure & Environment, LLC, WDNR,

7/21/2011.

Fourth Five-Year Review, EPA, 11/18/2014. SEMS Document 482270

OSWER Technical Guide for Assessing and Mitigating the Vapor Intrusion Pathway from Subsurface
Vapor Sources to Indoor Air, EPA, June 2015.

Fifth Five-Year Review, EPA, 11/18/2019. SEMS Document 951667.

Optimization Review Report Remedial Process Optimization Study, EPA, 05/2020.

Summary of the October 14, 2021, groundwater sampling event at the former Better Brite Chrome
and Zinc Shops, Westwood Infrastructure, Inc., WDNR 12/14/2021.

Summary of the November 2022 Groundwater Sampling Event at the Former Better Brite
Chrome and Zinc Shops, Foth Infrastructure & Environment, LLC., WDNR 2/10/2023

DNR Response to EPA Optimization Review Report for Better Brite Plating Co. Chrome and Zinc Shops

-------
SuperfundSite, WDNR,05/23/2024.

BRRTS website for the Chrome Shop:

https://dnr.wi.gov/botw/GetActivityDetail.do?detailSeqNo=32842#co

BRRTS website for the Zinc Shop: https://dnr.wi.gov/botw/GetActivityDetail.do?detailSeqNo=32846

28

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APPENDIX B SITE MAPS

29

-------
OMwi

ASSSGIATt*

ONE SVSSUi 3Jf.r P*Kr«C f&K-. 715-6fiCC
H(W1.r-?W VM ShAt* FM 0H* fc»-OiK

W-^fc-E

FORMER BETTER BRITE

SITE LOCATION MAP

315 £ «Tm STREET «£ LANCE ST&EJ
~TV OF D^EftE. BftOWN COUNTY W&CQNSN

ft cj»d Mhcwgw	BCW

PrcfKS En^rm	6tW

Ofwrr. Efy	JCW

Ct*c**d =tf	BOW

viaaoM

SCALE.

1 ¦ - 2,030 reel

PROJECT NO

N1969A07

FIGURE MO.

1

-------
NOTES:

1. 2022 - 6" resolution airphoto from Brown
County Land Information Office.

V Foth

This drawing is neither a legalfy recorded map nor a survey and is
not intended to be used as one. This drawing is a compilation of
records, information and data used for reference purposes only.

50

100

Feet

BETTER BRITE SUPERFUND SITE

FIGURE 2 - BETTER BRITE - CHROME SHOP

BETTER BRITE SUPERFUND SITE
315 S. 6TH STREET, DE PERE, WI 54115

Date: MARCH 2023

Revision Date:

Drawn By: BJW1 Checked By: NMG1 Scope: 22W016

Di+h- ri-WAftpr/snffin	OfmiPirn ira "7 Rattar Rrvtc. rhrwio QKnn mvH n*aha-

-------
NOTES:

1.	2022 - 6" resolution air photo from Brown
County Land Information Office.

2.	Sump water elevation not used in
creation of groundwater contours.

V Foth

BETTER BRITE SUPERFUND SITE

FIGURE 3 ¦ BETTER BRITE - ZINC SHOP

BETTER BRITE SUPERFUND SITE
315 S. 6TH STREET, DE PERE, Wl 54115

-------
APPENDIX C SITE PHOTOS

30

-------
Photo 2: Chrome Shop: The city owns the
property and stores soccer goals on the
property.

Photo 3: Chrome Shop: Depicts a different
angle of the property.

-------
Photo 4: Chrome Shop: Depicts MW-113

Photo 5: Chrome Shop: Depicts old rusty soccer
goals stored on the property.

Photo 6: Chrome Shop: Depicts MW-107 (left)
and MW-107A (right)

-------
Photo 7: Chrome Shop: Depicts MW-115 (left)
and MW-115A (right).

Photo 8: Chrome Shop: Depicts MW-110 (Top)
and MW-110A (bottom).



Photo 9: Chrome Shop: Depicts MW-116.

-------
Photo 10: Chrome Shop: Depicts MW-101.

Photo 12: Chrome Shop: Depicts MW-106.

-------


Photo 13: Chrome Shop: Depicts MW-106A
which was missing bolts for the lid and the
peizometer was sticking out. This is spected to be
due frost jacking.

Photo 14: Chrome Shop: Depicts MW -112.

Photo 15: Chrome Shop: Depicts MW-111, MW-
108A, and MW-108 at a distance.

-------
Photo 16: Zinc Shop: Depicts pump arid treat
building on the Zinc Shop property.

Photo 17: Zinc Shop: Depicts the Sump for the
pump and treatment facility.

-------
Photo 19: Zinc Shop: Depicts MW-12 which was
also damaged due to the cold weather.

Photo 20: Zinc Shop: Depicts MW-09 which was
missing bolts for the cap.

Photo 21: Zinc Shop: Depicts MW-11.

-------
Photo 22: Zinc Shop: Depicts MW-06
(left) and MW-06A (right).

I SB#!

Photo 23: Zinc Shop: Depicts W-1A (left)
and W-l (right).

Photo 24: Zinc Shop: Depicts MW-3R.

-------


Photo 25: Zinc Shop: Depicts MW-10
which was missing one bolt.

Photo 26: Zinc Shop: Depicts MW-02
which was missing a lock.

Photo 27: Zinc Shop: Depicts MW-05
(left) and MW-05A (right).

-------
Photo 28: Zinc Shop: Depicts MW-07A
(top) and MW-07 (bottom).

Photo 29: Zinc Shop: Depicts MW-08
(left) and MW-08A (right).

Photo 30: Zinc Shop: Depicts multiple
mesh filters that the treated water flows
through before discharing inside of the
facility.

-------
Photo 31: Zinc Shop: Depicts one of the
two 5,000 gallon tank used for
treatment.

Photo 32: Zinc Shop: Depicts piping from
the sump, safety manual, and
procedures.

Photo 33: Zinc Shop: Depicts piping from
the 5,000 gallon tank.

-------
Photo 34: Zinc Shop: Depicts the
switches used to run the system plus the
pH level in one of the tanks.

Photo 35: Zinc Shop: Depicts some of
the compounds needed in the process.

-------
APPENDIX D FYR INSPECTION CHECKLIST

31

-------
Site Inspection Checklist

1. SI I I. INFORMATION

Site name:

Better Brite Plating Co. Chrome and Zinc
Shops

Date of inspection:
4/10/2024

Location and Region:

EPA ID:

De Pere, Wisconsin, Region 5

WIT5620010118

Agency, office, or company leading the FYR:

Weather/temperature:

USEPA

Sunny, 60 degrees F

Remedy Includes: (Check all that apply)

~ Landfill cover/containment

~ Monitored natural attenuation

IEI Access controls

~ Groundwater containment

El Institutional controls

~ Vertical barrier walls

IEI Groundwater pump and treatment

~ Other: Click or tap here to enter text.

~ Surface water collection and treatment



Attachments:

~ Inspection team roster attached

IEI Site map attached

1

-------
Site Inspection Checklist

II. INTKRVIKWS (Check all that apply)

,T. , ,	Consultant from	Click or tap to

1 O&M Site Manager	NickGlander,	FOTH

Interviewed: M at site ~ at office ~ by phone Phone Number: Click here to enter text.
Problems, suggestions:	~ Report attached

No issues with the site. In the future he would like to replace the treatment pipes due to build
up from the material.	

Click or tap to

2. O&M Staff

Interviewed: ~ at site ~ at office ~ by phone Phone Number: Click here to enter text.
Problems, suggestions:	~ Report attached

Click or tap here to enter text.	

3.	Local regulatory authorities and response agencies (i.e., State and Tribal offices, emergency
response office, police department, office of public health or environmental health, zoning office,
recorder of deeds, or other city and county offices, etc.) Fill in all that apply.

Agency: WDNR

Contact: Gwen Saliares, Project Manager, 4/10/2024, P: 9205104343
Problems, suggestions:	~ Report attached

No issues or problems
Agency: WDNR

Contact: Emma Mikolic, IC coordinator, 4/10/2024, P: Phone Number
Problems, suggestions:	~ Report attached

No issues or problems
Agency: Click or tap here to enter text.

Contact: Name , Title , Click or tap to enter a date., P: Phone Number
Problems, suggestions:	~ Report attached

Click or tap here to enter text.

Agency: Click or tap here to enter text.

Contact: Name , Title , Click or tap to enter a date., P: Phone Number
Problems, suggestions:

Click or tap here to enter text.

4.	Other Interviews (optional):	~ Report attached

Click or tap here to enter text.

2

-------
Site Inspection Checklist



III. OVSITi: DOCl Ml]NTS & RKCORDS VKRir

IKI) (Check all thai apply)

1.

O&M Documents







El O&M manual El Readily available

El Up to date

~ N/A



~ As-built drawings ~ Readily available

~ Up to date

~ N/A



IEI Maintenance logs IEI Readily available

El Up to date

~ N/A



Remarks: Click or tap here to enter text.





2.

Site-Specific Health and Safety Plan

~ Contingency Plan/Emergency Response Plan
Remarks: Click or tap here to enter text.

El Readily available
~ Readily available



3.

O&M and OSHA Training Records







El Readily available

El Up to date

~ N/A



Remarks: Click or tap here to enter text.





4.

Permits and Service Agreements







~ Air discharge permit ~ Readily available

~ Up to date

El N/A



~ Effluent discharge ~ Readily available

~ Up to date

El N/A



~ Waste disposal, POTW ~ Readily available

~ Up to date

El N/A



~ Other permits: Click or tap here to enter text.







Remarks: The city does not require a discharge permit for the water after pump and treatment

5.

Gas Generation Records







~ Readily available

~ Up to date

El N/A



Remarks: Click or tap here to enter text.





6.

Settlement Monument Records







~ Readily available

~ Up to date

El N/A



Remarks: Click or tap here to enter text.





7.

Groundwater Monitoring Records







El Readily available

El Up to date

~ N/A



Remarks: WDNR has all of the records





8.

Leachate Extraction Records







~ Readily available

~ Up to date

El N/A

3

-------
Site Inspection Checklist

Remarks: Click or tap here to enter text.

9.	Discharge Compliance Records

~	Air	~ Readily available	~ Up to date ~ N/A
K Water (effluent) M Readily available M Up to date D N/A
Remarks: WDNR and Foth has these readily available electronically

10.	Daily Access/Security Logs

~ Readily available	~ Up to date ~ N/A

Remarks: Click or tap here to enter text.

	IV. O&M COSTS	

1.	O&M Organization

~	State in-house	ISI Contractor for State

~	PRP in-house	~ Contractor for PRP

~	Federal Facility in-house	~ Contractor for Federal Facility
Remarks: FOTH is the current contractor

2.	O&M Cost Records

KlReadily available [X] Up to date	El Funding mechanism/agreement in place

Original O&M cost estimate $103,400	~ Breakdown attached

Total annual cost by year for review period if available

From

To

Total cost



Click or tap to enter a

or tap to

Click or tap here to

~ Breakdown attached

date.

enter a date.

enter text.



From

To

Total cost



Click or tap to enter a

or tap to

Click or tap here to

~ Breakdown attached

date.

enter a date.

enter text.



From

To

Total cost



Click or tap to enter a

or tap to

Click or tap here to

~ Breakdown attached

date.

enter a date.

enter text.



From

To

Total cost



Click or tap to enter a

or tap to

Click or tap here to

~ Breakdown attached

date.

enter a date.

enter text.



From

To

Total cost



Click or tap to enter a

or tap to

Click or tap here to

~ Breakdown attached

date.

enter a date.

enter text.



3. Unanticipated or Unusually High O&M Costs During Review Period

Describe costs and reasons:

4

-------
Site Inspection Checklist

Click or tap here to enter text.



V. ACCESS AM) INSTH I TIONAI. CON

I'UOI.S





IEI Applicable

~ N/A



1.

Fencing Damaged ~ Location shown on site map
Remarks: Click or tap here to enter text.

~ Gates secured

El N/A

2.

Other Access Restrictions ~ Location shown on site map
Remarks: Click or tap here to enter text.

~ Gates secured



3.

Institutional Controls (ICs)







A. Implementation and Enforcement







Site conditions imply ICs not properly implemented

~ Yes El No

~ N/A



Site conditions imply ICs not being fully enforced

~ Yes El No

~ N/A



Type of monitoring {e.g., self-reporting, drive by)

Click or tap here to ente

r text.



Frequency

Click or tap here to ente

r text.



Responsible party/agency

City of De Pere





Contact: Name , Title , Click or tap to enter a date., P: Ph<

:»ne Number





Reporting is up-to-date

~ Yes ~ No

~ N/A



Reports are verified by the lead agency

~ Yes ~ No

~ N/A



Specific requirements in deed or decision documents have been
met

~ Yes ~ No

~ N/A



Violations have been reported

~ Yes ~ No

~ N/A



Other problems or suggestions:

Click or tap here to enter text.







B. Adequacy ^ ICs are adequate ~ ICs are inadequate ~ N/A





Remarks: Click or tap here to enter text.





4.

General







A. Vandalism/Trespassing ~ Location shown on site map

IEI No vandalism evident



Remarks: Click or tap here to enter text.







B. Land use changes on site IEI N/A







Remarks: Click or tap here to enter text.





C. Land use changes off site ~ N/A

5

-------
Site Inspection Checklist

Remarks: The thrift store has plans of buying additional land and converting it to a parking lot. The
land they would like to purchase is where wells MW-7 and MW-7A are located. They mentioned going
around those wells and not disturbing them when adding the parking lot

vi. general site conditions

1. Roads IEI Applicable

~ N/A

A. Roads damaged IEI Location shown on site map

IEI Roads adequate ~ N/A

Remarks: Click or tap here to enter text.

B. Other Site Conditions

Remarks: Click or tap ' to enter text.

Ml. I.ANDEII.E COVERS

1. Landfill Surface ~ Applicable

El N/A

A. Settlement (Low Spots) ~ Location Shown on Site Map

~ Settlement Not Evident

Areal Extent: Click or tap here to enter text. Depth: Click or tap here to enter text.

Remarks: Click or tap here to enter text.

B. Cracks ~ Location Shown on Site Map

~ Cracking Not Evident

Lengths: Click or tap here ,,,. , ,

Widths: Click or tap here to enter text.

to enter text.

Depths: Click or tap here to enter
text.

Remarks: Click or tap here to enter text.

C. Erosion ~ Location Shown on Site Map

~ Erosion Not Evident

Areal Extent: Click or tap here to enter text. Depth: Click or tap here to enter text.

Remarks: Click or tap here to enter text.

D. Holes ~ Location Shown on Site Map

~ Holes Not Evident

Areal Extent: Click or tap here to enter text. Depth: Click or tap here to enter text.

Remarks: Click or tap here to enter text.

E. Vegetative Cover ~ Grass

~ Cover Properly Established

~ Tress/Shrubs (indicate size and locations on a diagram

~ No Signs of Stress

Remarks: Click or tap here to enter text.

F. Alternative Cover (armored rock, concrete, etc.)

~ N/A

Remarks: Click or tap here to enter text.

G. Bulges ~ Location Shown on Site Map

~ Bulges Not Evident

Areal Extent: Click or tap here to enter text. Height: Click or tap here to enter text.

-------
Site Inspection Checklist

Remarks: Click or tap here to enter text.

H. Wet Areas/Water Damage ~ Wet Areas/Water Damage Not Evident

~ Wet Areas

~ Location Shown on Site Map

Areal Extent: Click or tap here to enter
text.

~ Ponding

~ Location Shown on Site Map

Areal Extent: Click or tap here to enter
text.

~ Seeps

~ Location Shown on Site Map

Areal Extent: Click or tap here to enter
text.

~ Soft Subgrade

~ Location Shown on Site Map

Areal Extent: Click or tap here to enter
text.

Remarks: Click or ta

tp here to enter text.



I. Slope Instability

~ Location Shown on Site Map

~ Slope Instability Not Evident



~ Slides

Areal Extent: Click or tap here to enter
text.

Remarks: Click or ta

tp here to enter text.



2. Benches

~ Applicable

~ N/A

(Horizontally constructed mounds of earth placed across a steep landfill side slope to interrupt the slope in
order to slow down the velocity of surface runoff and intercept and convey the runoff to a lined channel.)

A. Flows Bypass Bench ~ Location Shown on Site Map

~ N/A or Okay

Remarks: Click or ta

tp here to enter text.



B. Bench Breached

~ Location Shown on Site Map

~ N/A or Okay

Remarks: Click or ta

tp here to enter text.



C. Bench Overtopped

~ Location Shown on Site Map

~ N/A or Okay

Remarks: Click or ta

tp here to enter text.



3. Letdown Channels

~ Applicable

~ N/A

(Channel lined with erosion control mats, riprap, grout bags, or gabions that descend down the steep side
slope of the cover and will allow the runoff water collected by the benches to move off of the landfill cover
without creating erosion gullies.)

A. Settlement

~ Location Shown on Site Map

~ Settlement Not Evident

Areal Extent: Click

;»r tap here to enter text.

Depth: Click or tap here to enter text.

Remarks: Click or ta

tp here to enter text.



B. Material Degradation ~ Location Shown on Site Map ~ Degradation Not Evident

Material Type: Clicl

or tap here to enter text.

Areal Extent: Click or tap here to enter
text.

7

-------
Site Inspection Checklist

Remarks: Click or tap here to enter text.

C.	Erosion	~ Location Shown on Site Map	~ Erosion Not Evident
Areal Extent: Click or tap here to enter text. Depth: Click or tap here to enter text.
Remarks: Click or tap here to enter text.

D.	Undercutting	~ Location Shown on Site Map	~ Undercutting Not Evident
Areal Extent: Click or tap here to enter text. Depth: Click or tap here to enter text.
Remarks: Click or tap here to enter text.

E.	Obstructions	~ Location Shown on Site Map	~ Undercutting Not Evident
Type: Click or tap here to enter text.

Areal Extent: Click or tap here to enter text.	Size: Click or tap here to enter text.

Remarks: Click or tap here to enter text.

F. Excessive Vegetative Growth ~ Location Shown on Site Map ~ Excessive Growth Not Evident
Areal Extent: Click or tap here to enter text.

Remarks: Click or tap here to enter text.

~ Vegetation in channels does not obstruct
flow

4. Cover Penetrations

~ Applicable

~ N/A

A. Gas Vents

~	Properly secured/locked

~	Good condition

~	Needs Maintenance
Remarks: Click or tap here to enter

~ Active

~ Passive

~	Functioning ~ Routinely sampled

~	Evidence of leakage at penetration

~	N/A

B. Gas Monitoring Probes

~	Properly secured/locked

~	Good condition

~	Needs Maintenance
Remarks: Click or tap here to enter

~	Functioning ~ Routinely sampled

~	Evidence of leakage at penetration

~	N/A

C. Monitoring Wells

~	Properly secured/locked

~	Good condition

~	Needs Maintenance

~	Functioning ~ Routinely sampled

~	Evidence of leakage at penetration

~	N/A

8

-------




Site Inspection Checklist





Remarks: Click or tap here to

enter text.





D. Leachate Extraction Wells

~	Properly secured/locked

~	Good condition

~	Needs Maintenance
Remarks: Click or tap here to

~	Functioning ~ Routinely sampled

~	Evidence of leakage at penetration

~	N/A

enter text.



E. Settlement Monuments

Remarks: Click or tap here to

~ Located ~ Routinely Surveyed ~ N/A
enter text.

5.

Gas Collection and Treatment

~ Applicable

~ N/A



A. Gas Treatment Facilities

~	Flaring

~	Good condition
Remarks: Click or tap here to

~	Thermal Destruction

~	Needs Maintenance
enter text.

~ Collection for Reuse



B. Gas Collection Wells, Manifolds, and Piping

~ Good condition ~ Needs Maintenance
Remarks: Click or tap here to enter text.

~ N/A

C. Gas Monitoring Facilities (e.g. gas monitoring of adjacent homes or buildings)

~ Good condition ~ Needs Maintenance ~ N/A
Remarks: Click or tap here to enter text.

6.

Cover Drainage Layer

~ Applicable

~ N/A



A. Outlet Pipes Inspected

Remarks: Click or tap here to

~ Functioning
enter text.

~ N/A



B. Outlet Rock Inspected

Remarks: Click or tap here to

~ Functioning
enter text.

~ N/A

7.

Detention/Sediment Ponds

~ Applicable

~ N/A



A. Siltation

Areal Extent: Click or tap her
Remarks: Click or tap here to

~ Siltation Not Evident
e to enter text. Depth: CIic
enter text.

~ N/A
< or tap here to enter text.



B. Erosion

Areal Extent: Click or tap her

~ Erosion Not Evident
e to enter text. Depth: CI ic

< or tap here to enter text.

-------
Site Inspection Checklist

C. Outlet Works

~ Functioning

~ N/A

Remarks: Click or tap here to em

er text.



D. Dam

~ Functioning

~ N/A

Remarks: Click or tap here to em

er text.



8. Retaining Walls

~ Applicable

~ N/A

Remarks: Click or tap here to enter text.

A. Deformations	~ Location Shown on Site Map

Horizontal Displacement: Click or tap here to enter text.

Vertical Displacement: Click or tap here to enter text.

Rotational Displacement: Click or tap here to enter text.

Remarks: Click or tap here to enter text.

~ Deformation Not Evident

B. Degradation	~ Location Shown on Site Map ~ Deformation Not Evident

Remarks: Click or tap here to enter text.

9. Perimeter Ditches/Off-Site Discharge

~ Applicable

~ N/A

A. Siltation	~ Location Shown on Site Map ~ Siltation Not Evident

Areal Extent: Click or tap here to enter text.	Depth: : or tap here to enter text.

Remarks: Click or tap here to enter text.

B. Vegetative Growth	~ Location Shown on Site Map ~ N/A

~ Vegetation Does Not Impede Flow

Areal Extent: Click or tap here to enter text.	Type: Click or tap here to enter text.

Remarks: Click or tap here to enter text.

C. Erosion	~ Location Shown on Site Map ~ Erosion Not Evident

Areal Extent: Click or tap here to enter text.	Depth: . or tap here to enter text.

Remarks: Click or tap here to enter text.

D. Discharge Structure	~ Functioning

Remarks: Click or tap here to enter text.

~ N/A

Mil. YKUTICAL BAKKIKK WALLS

~ Applicable

E N/A

1. Settlement

~ Location Shown on Site Map

Areal Extent: Click or tap here to enter text.

~ Settlement Not Evident
Depth: Click or tap here to enter text.

10

-------
Site Inspection Checklist

Remarks: Click or tap here to enter text

2. Performance Monitoring

Type of Monitoring: Click or tap here to enter text

~ Performance Not Monitored
Frequency: Click or tap here to enter text
Remarks: Click or tap ' to enter text.

~ Evidence of Breaching

Head Differential: Click or tap here to enter text

ix. (;uoiM)\\ \n u/si ui \( i: watku rk.mkdiks

Applicable

~ N/A

1. Groundwater Extraction Wells, Pumps, and Pipelines

Applicable

~ N/A

A. Pumps, Wellhead Plumbing, and Electrical ~ N/A

El Good Condition El All Required Wells Properly Operating ~ Needs Maintenance

Remarks: Click or tap here to enter text.

B. Extraction System Pipelines, Valves, Valve Boxes, and Other Appurtenances

IEI Good Condition ~ Needs Maintenance

Remarks: Click or tap here to enter text.

C. Spare Parts and Equipment

IEI Readily Available El Good Condition

Remarks: Click or tap here to enter text.

~ Needs to be Provided

~ Requires Upgrade

2. Surface Water Collection Structures, Pumps, and Pipelines

Applicable

~ N/A

A. Collection Structures, Pumps, and Electrical

El Good Condition ~ Needs Maintenance

Remarks: Click or tap here to enter text.

B. Surface Water Collection System Pipelines, Valves, Valve Boxes, and Other Appurtenances

El Good Condition ~ Needs Maintenance

Remarks: Click or tap here to enter text.

C. Spare Parts and Equipment

El Readily Available El Good Condition

Remarks: Click or tap here to enter text.

~ Needs to be Provided

~ Requires Upgrade

3. Treatment System

Applicable

~ N/A

A. Treatment Train (Check components that apply)

El Metals removal ~ Oil/Water Separation

~ Bioremediation

-------
Site Inspection Checklist



~ Air Stripping ~ Carbon Absorbers



El Filters on final discharge



El Additive (e.g. chelation agent, flocculent) Sulfuric acid, sodium bisulfite, sodium hydroxide,



polymer, and flocculation.



~ Others Click or tap here to enter text.



IEI Good Condition ~ Needs Maintenance



IEI Sampling ports properly marked and functional



El Sampling/maintenance log displayed and up to date



El Equipment properly identified



El Quantity of groundwater treated annually in October or November samples are taken



~ Quantity of surface water treated annually Click or tap here to enter text.



Remarks: The ports and pipes are all identified in the O&M plan and safety plan in the Zinc shop

B. Electrical Enclosures and Panels (properly rated and functional)



~ N/A El Good Condition ~ Needs Maintenance



Remarks: Click or tap here to enter text.

C.

Tanks, Vaults, Storage Vessels ~ N/A



El Proper Secondary Containment El Good Condition ~ Needs Maintenance



Remarks: Click or tap here to enter text.

D. Discharge Structure and Appurtenances



~ N/A El Good Condition ~ Needs Maintenance



Remarks: Click or tap here to enter text.

E.

Treatment Building(s)



~ N/A El Good condition (esp. roof and doorways)



~ Needs repair El Chemicals and equipment properly stored



Remarks No signs of vandalism and Nick has had no issues with breakins or issues from the



community

F.

Monitoring Wells (Pump and Treatment Remedy) ~ N/A



El Properly secured/locked El Functioning



El Routinely sampled El All required wells located



El Good condition El Needs Maintenance

12

-------
Site Inspection Checklist

Remarks MW-106A and MW-12 were popped open due to winter jacking from the cold temperatures.
The wells need to be adjusted. Someone drove into MW-12 knocking the lid off the well. Some of the
wells needed an additional bolt. This will be fixed by FOTH before the next sampling event in the fall.

4. Monitoring Data

A. Monitoring Data:

IEI Is Routinely Submitted on Time

~ Is of Acceptable Quality

B. Monitoring Data Suggests:

IEI Groundwater plume is effectively contained

El Contaminant concentrations are declining

5. Monitored Natural Attenuation

A. Monitoring Wells (natural attenuation remedy) IEI N/A

~ Properly secured/locked ~ Functioning ~ Routinely sampled

~ All required wells located ~ Needs Maintenance ~ Good condition

Remarks: Click or tap here to enter text.

X. QUI IK U I'M 1.1)1 IS

If there are remedies applied at the site which are not covered above, attach an inspection sheet
describing the physical nature and condition of any facility associated with the remedy. An example
would be soil vapor extraction.

XI. OVKKAM, OBSERVATIONS

1. Implementation of the Remedy

Describe issues and observations relating to whether the remedy is effective and functioning as designed.
Begin with a brief statement of what the remedy is to accomplish (i.e., to contain contaminant plume,
minimize infiltration and gas emission, etc.).

There are no issues with OU1 or OU2 involving groundwater pump and treatment. The goundwater
conitues to be monitored yearly.

2. Adequacy of O&M

Describe issues and observations related to the implementation and scope of O&M procedures. In
particular, discuss their relationship to the current and long-term protectiveness of the remedy.

The pump and treatment facility is properly maintained. MW-106A and MW-12 needs maintence, but the
other monitoring wells are in good condition. No signs of patches or holes on the chrome shop property.

3. Early Indicators of Potential Remedy Problems

Describe issues and observations such as unexpected changes in the cost or scope of O&M or a high
frequency of unscheduled repairs that suggest that the protectiveness of the remedy may be compromised
in the future.

Further investigation into Per- and Polyfluorinated Substances (PFAS) could increase the cost or scope of the O&M. No
issues with the current remedy.

4. Early Indicators of Potential Remedy Problems

-------
Site Inspection Checklist

Describe possible opportunities for optimization in monitoring tasks or the operation of the remedy.

Since the Site is in O&M, WDNR covers the cost of the monitoring and sampling. Due to WDNR lack of
funding, cost towards optimization and/or additional tests are not feasible.	

14

-------
APPENDIX E PRESS TIMES FYR NOTIFICATION

32

-------
PRESS TIMES, NOVEMBER 17, 2023 - PAGE 8

Allouez approves 2024 budget

BY JANELLE FISHER

CITY PAGES EDITOR

ALLOUEZ - The 2024
budget for the village of
Allouez was unanimously
approved by the village
board at its Tuesday, Nov.
7, meeting.

"Village staff have been
working extremely hard,
along with our commit-
tees, to come up with a
budget that is responsible
and yet provides the funds
we need to continue to
provide the services that
our residents have come
to expect in their village of
Allouez," said Allouez Vil-
lage President Jim Rafter.

"We've been providing
the same level of service

for this village for the past
20-plus years and with the
levy limits and other con-
straints we work under,
it's really a staff effort,"
said Allouez Village Fi-
nance Director Julie Beau-
champ

The approved budget
includes $7,664,383 in the
general village levy —
with $5,724,256 in the gen-
eral fund, $110,000 in the
public bus services fund,
$20,000 in the compensated
absences reserve fund,
$315,000 in the revolv-
ing loan fund, $1,470,127
in the debt service fund
and $25,000 in the parks
capital projects fund —and
$347,914 in the TID No.
1 levy for a total levy of

$8,012,297.

That total represents a
0.89% increase over last
year's total levy, which
came in at $7,941,749.

The 2024 tax rate
amounts to $6.48 per $1,000
of assessed value — a
0.73% increase over last
year's $6.43 rate.

"It is so nice to once
again have a budget that
people will be proud of,"
Rafter said "We are living
in the world of increased
cost — dramatically in-
creased costs — and for
us to be able to provide
the services that we pro-
vide on the budget that we
provide, I would like to for-
mally thank our staff for
that."

Local news online
www.GoPressTimes.com

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frompage 1
CEO Brad Toll.

"And there are all dif-
ferent displays and things.
People can look at Super
Bowl rings and they have
the Super Bowl trophy. I
mean, we know what that
looks like; we have four of
those," Toll joked.

"There are samples of
lockers from all the differ-
ent teams and it's all the
teams — all 32. So, it's kind
of like a fair almost, with all
kinds of exhibits and fun
activities, but for all of the
teams in the NFL.

"So you know, a lot of
times when we have a home
game, the other team has
a number of their fans vis-
iting us but in this case,
they will all be visiting. So
you see, we have some of
our fan fanatics that are
dressed up and every kind
of green and gold whatever
that you can come up with.
Well, we'll see those from
all the other teams that are
here — Eagles and the cra-
zy Raider fans with all their
spikes and whatnot. You
see them all here walking
around, and the cool thing
is there's no game; so you
know, everybody gets along
great and has a good time."

Toll said that during
the Kansas City-host NFL
Draft, they noticed that the
environment was very fam-
ily-friendly.

"There's are a lot of fami-
lies that are here; there's a
lot of kids that are here as
well. They do their Tlay
360' — the NFL's kind of
youth program — youth
sports and getting kids ac-
tive. So, there'll be a whole

area where they'll be prac-
ticing or showing off their
skills with kicking and
punting and passing. So,
there's some of those activi-
ties that are taking place.
It really is a great time and
you know, it's not a game
day, kind of atmosphere.
It's almost more like going
to the fair, only it's all foot-
ball-related," he said.

Toll said that after at-
tending the Kansas City
event, they were told that
not a single arrest was
made.

"125,000 people, not one
arrest," he added.

Toll said that he was ex-
cited to be a part of bring-
ing the three-day event to
Wisconsin for others to en-
joy.

*I'm really excited for
our community to be able
to experience. It's free, so
anyone and everyone can
go and what an awesome
opportunity for the people
in our community to be able
to go and see it —the thing
that we've watched on TV
every year — it's cool that
we're able to do that for the
community.

Toll said that organizers
are also working on devel-
oping a unique experience
for the players coming into
the area.

"One of the things that
we will work on is devel-
oping experiences. So as
the players come in, and
they have some free time
here and there, what are
some experiences unique to
our community? So, sport
fishing, perhaps, on Lake
Michigan; curling is one of
the things that we thought
would be kind of fun. You
know a lot of them prob-

ably haven't curled before
growing up in the southern
part of the country," he ex-
plained.

A three-day
commercial

"Then, from a tourism
perspective, we're really
excited that it's a three-day
commercial," Toll added.

This also gives the city an
opportunity to call itself a
"Draft City."

"A lot of times when say
a big sports tournament is
thinking about coming to
Green Bay, and we're being
considered against other
cities. It's like, 'Well, did
you know we're hosting the
draft in 2025; 'You are?' You
know, suddenly, 'Well, if
you can host that. You prob-
ably do a great job with my
tournament,' he explained.

"It really becomes a great
sales tool and draws atten-
tion to your destination.

"There are some brag-
ging rights that go with it
that really helps you sell
the community for other
business, so we're excited
about that."

In addition to those in at-
tendance, organizers proj-
ect that 70 million people
will be viewing the draft on
television that Thursday
night.

"Even with a massive
budget, you can't get that
kind of exposure. Certainly,
with a community our size
and the budget that we have
for sales and marketing, I
mean, there's just no possi-
ble way you'd get that kind
of exposure," Toll stated.

Next week: The nearly
three dozen committees that
will prepare

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\>EPA

EPA Begins Fifth Review of
Better Brite Plating Co. Chrome and Zinc Shops Superfund Site

De Pere, Wisconsin

U.S. Environmental Protection Agency is conducting a five-year review of the Better Brite
Plating Co. Chrome and Zinc Shops Superfund site, located at 519 Lande St. in De Pere,
Wisconsin. The site's operation and maintenance are led by the Wisconsin Department of
Natural Resources. The Superfund law requires regular checkups of sites that have been cleaned
up - with waste managed on-site - to make sure that the cleanup continues to protect people and
the environment. This is the sixth five-year review of this site and is expected to be completed
November 2024.

Metal plating operations were conducted at the Chrome Shop from 1978 to 1985 and at the Zinc
Shop from 1968 to 1989. Spilled plating solution and waste contaminated soil and groundwater
with high levels of heavy metals, including chromium, zinc, cadmium, and cyanide.

After several cleanup measures were conducted, the site's long-term remedy was selected in
1996. It included replacing the groundwater removal and treatment system at the Chrome Shop,
treating the soil and groundwater by stabilizing the chromium, continuing groundwater removal
and treatment at the Zinc Shop, and isolating the recharge of contaminated groundwater to
basement sumps in a nearby residence.

More information is available online at w'ww.epa.gov/superfund/better-brite-plating.

The five-year review is an opportunity for you to tell EPA about site conditions and any concerns
you have. Contact:

Karen Chen Sarah Friedman

Community Involvement Coordinator Remedial Project Manager

312-886-6009 312-886-6707

chen.karenO 1 @epa.gov friedman.sarah@epa.gov

You may also call EPA toll-free at 800-621-8431,8:30 a.m. to 4:30 p.m., weekdays.

-------
APPENDIX F 2021 SUMMARY GROUNDWATER MONITORING REPORT

33

-------
Westwood

1 Systems Drive
Appleton, Wl 54914

main {920)735-6900

December 14, 2021

Ms. Gwen Saliares
Hydrogeologist
DNR-Northeast Region RR
625 East County Road Y, Suite 700
Oshkosh, Wl 54901

Re: Summary of the October 14, 2021, groundwater sampling event at the former Better Brite Chrome
and Zinc Shops

Dear Ms. Saliares:

The purpose of this letter is to summarize the groundwater sampling event conducted on October
14, 2021, at the former Better Brite chrome and zinc shops. The former Better Brite facilities are
located at 500 Lande Street Blk (chrome shop, BRRTS # 02-05-000030) and 315 S. 6th Street (zinc
shop, BRRTS # 02-05-000031), De Pere, Wisconsin. (See Figure 1 - Site Location Map.) This report
includes:

• Figure 1 - Site Location Map

• Figure 2 - Monitoring Wells - Chrome Site

• Figure 3 - Monitoring Wells - Zinc Site

• Well Specific Field Sheets

• Table 1 - Groundwater Analytical Summary, Better Brite - Chrome Shop

• Table 2 - Groundwater Analytical Summary, Better Brite - Zinc Shop

• Monitoring Well Photograph Summary

• Laboratory Report

Groundwater elevations were only taken at the monitoring points that were sampled.
Groundwater elevations were recorded on the well specific field sheets. (See Well Specific Field
Sheets.)

Monitoring points W-l and W-1A would allow the water level meter probe to be placed down the
PVC pipe. However, a standard bailer would not freely go down the PVC pipe. A peristaltic pump
was used to collect the samples. FOTH purged these monitoring points leading up to OMNNI's
sampling.

Monitoring well covers were inspected at all monitoring points that could be located during the
sampling event. The conditions of the covers were noted on the well specific field sheets and
photographs of the covers were taken. (See Well Specific Field Sheets and Monitoring Well
Photograph Summary.)

westwoodps.com

(888) 937-5150

-------
December 14, 2021
Page 2 of 2

Color, odor, and turbidity observations were recorded on well specific field sheets. The well specific
field sheets also list the measured depth to water from the top of the PVC pipe, mean sea level
groundwater elevation, the length of time spent purging and the approximate gallons of
groundwater purged from each monitoring well/piezometer prior to taking the groundwater
sample. (See Well Specific Field Sheets.)

Purged groundwater from the monitoring wells and piezometers was collected in 5-gallon buckets.
The purged groundwater was placed into the sump in the treatment building located at the former
zinc shop site for treatment.

Unfiltered groundwater samples collected from the monitoring wells and zinc shop sump were
submitted for laboratory hexavalent chromium and volatile organic compounds (VOCs) analysis.
Unfiltered groundwater from the zinc shop sump was also analyzed for cyanide. Unfiltered
groundwater from monitoring well MW-115 and MW-116 were also analyzed for iron and sulfate.
Groundwater analytical methods are included with the laboratory report. (See Laboratory Report.)
The laboratory analysis has been summarized in Table 1 and Table 2. (See Table 1 - Groundwater
Analytical Summary, Better Brite - Chrome Shop and Table 2 - Groundwater Analytical Summary,
Better Brite - Zinc Shop.)

Monitoring wells MW-116, W-1A, MW-10 and the Zinc Sump had decreased hexavalent chromium
laboratory analysis results than recent events, while W-l and MW-6 increased. However, all but
MW-10 still exceeded the groundwater enforcement standard for hexavalent chromium. In
general, VOC results for the zinc shop sump and MW-116 were similar when compared to past
sampling events. The remaining VOC results were below the groundwater preventive action limits,
except for MW-3 which had one parameter above the preventive action limit. At the former
chrome shop site, MW-116 had groundwater enforcement standard exceedances in hexavalent
chromium and sulfate, and groundwater preventative action limit exceedance in iron. Groundwater
enforcement standard and preventive action limit exceedances of VOCs also remain in MW-116.
The iron enforcement standard exceedance remains in MW-115. At the former zinc shop site, the
sump had groundwater enforcement standard exceedance of hexavalent chromium and
groundwater preventive action limit exceedances of cyanide and VOCs.

If you have any questions on the enclosed information, please contact me at (920) 830-6174 or by
email at Kimberly.Kennedy@westwoodps.com.

Sincerely,

WESTWOOD INFRASTRUCTURE, INC.

Kimberly Kennedy
Environmental Technician

Attachments

-------
Zinc Shop Site
315 S, 6th Street

Athletic
FieSd ,

Chrome Shop Site
500 Lande Street Blk

Athletic
¦s-field

ONNMt

ASSOCIATES

ONE SYSTEMS DRIVE PHONE (920) 735-6900
APPLETON.WI 54914 FAX (920)830-6100

Project Manager: BDW SCALE:

Project Engineer: BDW 1 - 2,000 feet

Drawn By:	JCW	PROJECT NO.

Checked By BDW 3QQ1438.00

FIGURE NO.

1

FORMER BETTER BRITE

SITE LOCATION MAP

315 S. 6TH STREET AND 500 LANDE STREET BLK
CITY OF DEPERE, BROWN COUNTY, WISCONSIN

2,000

4,000
Feet

F:\ENVIRO\N1969A07 (Better Brite State Lead)\GIS\SiteLocationmap.mxd

-------
Tax Parcel

Monitoring Wells

® Active Well
K Abandoned Well

k itaH

MW-112

MW-113

&

MW-114

MW-106 A

m

MW-1
MW-106

06 B

LILAC ln

tn
x

I—

«>

05

MW-110A

J MW-110

rW-9

B-105B
MW-109A MW-109

MH-1

X

W-1

&

MW-104A

MW-101

MW-115

J.MW-115A

MW-109 B

MW-116 SUMP

EX-WELL

&

MW-111



FD-3

X

B-102

K w

^ MW-107B
MW-107A$ MW-107

FD-2

FD-1

X

W-5

MW-108 B^®® MW-108A
MW-108



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Q Q O D
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£

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SCALE:

1 " = 50 '

LU V-

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PROJECT NO.

N1969A07

FIGURE NO.

2

-------






u>

$
•s.
«/)

MW-7A
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SMW-7

MW-8 MW-8A

MW-4B

&

MW-4A}^

MW-4

«

£

-------
Well Specific Field Sheets

Facility Name:	Former Better Brite - Chrome Shop

Date:	October 14, 2021

Weather Conditions:	Sunny, 65F

Person(s) Sampling:	Kim Kennedy; Evan Dujardin

Sampling Equipment: Dedicated bailers, Solonist 101 water level meter.

Well Name

MW101

MW104A

MW106

MW106A

MW107

MW107A

MW108

MW108A

MW110

MW110A

MW111

MW112

MW113

MW115

MW115A

MW116

Top of PVC Casing Elevation (MSL)





606.21

606.36

608.41

608.33

604.22

604.44

603.05

603.31

600.76

600.61

611.08

601.04

601.01

604.28

Depth to Bottom of Well (ft)



18.30

14.58

32.09

15.39

39.33

15.82

33.27

14.76

23.80

14.38

15.86

15.08

14.48

23.45

18.88

Water Elevation (MSL)

_

_

602.69

_

605.38

_

_

_

_

_

_

_

_

599.08

590.89

602.68



































Measured Depth to Water (ft)

	

	

3.52

	

3.03

	

	

	

	

	

	

	

	

1.96

10.12

1.6

Time Purging Begun

	

	

15:30

	

14:50

	

	

	

	

	

	

	

	

13:43

14:13

13:33

Time Purging Completed

	

	

15:40

	

15:00

	

	

	

	

	

	

	

	

13:54

14:20

13:43

Amount Purged (gal)

_

_

7.25

_

8.25

_

_

_

_

_

_

_

_

8.5

8.5

11.5

Purged Dry? (Y/N)





N



N

















Y

Y

N



































Color (Y/N)

	

	

Brown

	

Brown

	

	

	

	

	

	

	

	

Brown

Brown

Yellow

Odor (Y/N)

	

	

N

	

N

	

	

	

	

	

	

	

	

N

Slight

N

Turbidity (Y/N)

	

	

Y

	

Y

	

	

	

	

	

	

	

	

Y

Y

N



































Time Sample Withdrawn

_

_

15:43

_

15:05

_

_

_

_

_

_

_

_

13:55

14:23

13:45

Well secured? (Y/N)

_

_

Y

_

Y

_

_

_

_

_

_

_

_

Y

Y

Y

Cover Condition

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Cover is flush when
bolted, but plug is raised
when cover is off. Both
bolts secure.

Cover in good condition.
Both bolts secure.

One bolt snapped off.
Cover in good condition.

Cover in good condition.
Only one bolt secure.

Concrete surround
slightly moves. Both
bolts secure.

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Concrete surround
slightly moves. Both
bolts secure.

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Purge 2" Well = (Depth to Bottom of Well - Measured Depth to Water) x 0.163 x 4

Page 1 of 2

-------
Well Specific Field Sheets

Facility Name:

Date:

Weather Conditions:
Person(s) Sampling:
Sampling Equipment:

Former Better Brite - Zinc Shop
October 14, 2021
Sunny, 65F

Kim Kennedy; Evan Dujardin

Dedicated bailers, Solonist 101 water level meter, perastaltic pump for W-1, W-1A.

Well Name

W-1

(1,2,4)

W-1 A

(1,2,4)

MW2

(4)

MW3R

MW5

MW5A

MW6

(4)

MW6A

(4)

MW7

MW7A

MW8

MW8A

MW9

MW10

(4)

MW11

MW12

Zinc
Sump

(3)

Top of PVC Casing Elevation (MSL)







602.88

600.81

600.81





600.60

600.51

598.18

598.59

601.66



602.41

599.65

603.99

Depth to Bottom of Well (ft)

19.9

31.52

17.65

16.72

15.53

29.67

18.43

18.48

15.86

26.73

11.41

21.73

16.30

15.00

15.62

10.04

20.40

Water Elevation (MSL)

	

	

	

596.10

592.98

590.31

	

	

	

	

	

	

594.80

	

	

	

	





































Measured Depth to Water (ft)

15.07

15.8

	

6.78

7.83

10.50

11.39

12.32

	

	

	

	

6.86

5.59

	

	

	

Time Purging Begun

Grab Sample (3)

Grab Sample (3)

Grab Sample (3)

9:43

11:40

12:40

10:40

11:30

	

	

	

	

8:40

8:45

	

	

	

Time Purging Completed

9:50

11:52

12:55

10:50

11:40

	

	

	

	

8:51

8:53

	

	

	

Amount Purged (gal)

6.5

5.0

8.5

4.75

4.25

	

	

	

	

6.25

6.25

	

	

	

Purged Dry? (Y/N)

N

Y

Y

N

N

	

	

	

	

N

Y

	

	

	





































Color (Y/N)

Yellow

N

	

Brown

Brown

Brown

Brown

Brown

	

	

	

	

Brown

Brown

	

	

Yellow

Odor (Y/N)

N

N

	

N

N

N

N

N

	

	

	

	

N

N

	

	

N

Turbidity (Y/N)

N

N

	

Y

Y

Y

Y

Y

	

	

	

	

Y

Y

	

	

N





































Time Sample Withdrawn

10:41

10:11

	

9:59

11:54

13:07

10:55

11:45

	

	

	

	

8:52

9:05

	

	



Well secured? (Y/N)

Y

Y

	

Y

Y

Y

Y

Y

	

	

	

	

Y

Y

	

	

Y

Cover Condition

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Pro-top in good condition
(some rust). Lock
secure.

One bolt snapped off.
Cover in good condition.

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Pro-top in good condition
(some rust). Lock
secure. Wasp Nest on
the inside wall.

Pro-top in good condition
(some rust). Lock
secure.

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Cover is flush when
bolted, but well and plug
are raised when cover is
off. Both bolts secure.

Cover in good condition.
Both bolts secure.

Cover in good condition.
Both bolts secure.

Gate overgrown with
vegetation. Cover in
good condition. Locks
secure.

1	Depth to bottom of the well is suspect. Felt like soft bottom (sediment).

2	A standard bailer would not fit down the monitoirng well.

3	Sump was not running at time of sample collection.

4	Well height modified. New elevation unknown.

Purge 2" Well = (Depth to Bottom of Well - Measured Depth to Water) x 0.163 x 4

Page 2 of 2

-------
Table 1 Groundwater Analytical Summary, Better Brite - Chrome Shop

500 Lande Street Blk, De Pere, Wl BRRTS # 02-05-000030





Detected Parameters (mq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,2-DCA

1,1-DCE

cis-1,2-
DCE

PCE

1,1,1-TCA

1,1,2-TCA

TCE

VC

NR140 Preventive Action Limi

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.5

0.7

7

0.5

40

0.5

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

5

7

70

5

200

5

5

0.2



Aug-94

620000

694000

NA

NA

NA



Chrome Sump

Oct-94

300200

297000

NA

NA

NA



(Abandoned)

Apr-98

195000

192000

NA

NA

NA





Jul-98

132000



NA

NA

NA





Aug-94

25800

22000

NA

NA

NA



French Drain

Oct-94

32000

31700

NA

NA

NA



Apr-98

1060

1010

NA

NA

NA





Jul-98

336

312

NA

NA

NA



B-101

Auq-94

<10

<3.4

NA

NA

NA



Oct-94

<10



NA

NA

NA





Auq-94

7

<2.8

NA

NA

NA





DUP.

<10

<2.8

NA

NA

NA





Oct-94

<10 J

<3.4 J

NA

NA

NA





DUP.

<10 J

<3.4 J

NA

NA

NA



MW-106

Apr-98

<10

<5

NA

NA

NA



DUP

<10

<5

NA

NA

NA





May-00

<4.2

4

NA

NA

NA





8/26/10

<3.9

5.4

NA

NA

NA





6/16/11

<3.9

NA

NA

NA

NA





10/14/21

<180

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17



Auq-94

<10

<2.8

NA

NA

NA





Oct-94

<10 J

<3.4 J

NA

NA

NA



MW-106A

Apr-98

<10

<5

NA

NA

NA



May-00

<4.2

9.4

NA

NA

NA





8/26/10

<3.9

1.1 "J"

NA

NA

NA





6/16/11

<3.9

NA

NA

NA

NA



MW-106B
(Abandoned)

Aug-94

<10

NA

NA

NA

NA





Auq-94

<10

4.1 BJ

NA

NA

NA





Oct-94

<10 J

<3.4

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





May-00

<4.2

4.2

NA

NA

NA





Jun-01

NA

NA

530

50

NA





Nov-01

<4.2

26

3900

NA

1800





May-02

7.8

1.2

230

NA

2300



MW-107

DUP

100

1.9

490

NA

2800





Nov-02

NA

NA

8200

140000

2300





May-03

<4.2

1.6

490

95000

1700





May-04

6.5

1.7

260

100000

NA





May-05

<5.0

0.89

380

97000

NA





8/26/10

<3.9

16.4

4010

16400

NA





6/16/11

<3.9

NA

3130

83600

NA





10/14/21

<180

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17



Auq-94

<10

<2.8

NA

NA

NA





Oct-94

<10 J

<3.4 J

NA

NA

NA



MW-107A

Apr-98

<10

<5

NA

NA

NA



May-00

<4.2

16

NA

NA

NA





8/26/10

<3.9

23.2

NA

NA

NA





6/16/11

<3.9

NA

NA

NA

NA



MW-107B
(Abandoned)

Aug-94

<10

NA

NA

NA

NA



NA - Compound not analyzed
Underlined - Concentration exceeds PAL
Bolded - Concentration exceeds ES

Page 1 of 13

-------
Table 1 Groundwater Analytical Summary, Better Brite - Chrome Shop

500 Lande Street Blk, De Pere, Wl BRRTS # 02-05-000030





Detected Parameters (mq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,2-DCA

1,1-DCE

cis-1,2-
DCE

PCE

1,1,1-TCA

1,1,2-TCA

TCE

VC

NR140 Preventive Action Limi

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.5

0.7

7

0.5

40

0.5

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

5

7

70

5

200

5

5

0.2



Auq-94

<10

<2.8

NA

NA

NA





Oct-94

<10

<3.4 J

NA

NA

NA





Apr-98

<10

NA

NA

NA

NA



MW-108

DUP

<10

<5

NA

NA

NA



Jul-09

NA

16.0

NA

NA

NA





8/26/10

<3.9

4.6"J"

NA

NA

NA





6/16/11

<3.9

NA

NA

NA

NA





12/5/13

<3.4

NA

NA

NA

NA





Auq-94

<10

3.0 BJ

NA

NA

NA





Oct-94

<10

<3.4 J

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA



MW-108A

May-00

<4.2

55

NA

NA

NA



Jul-09

NA

NA

NA

NA

NA





8/26/10

<3.9

1.3"J"

NA

NA

NA





6/16/11

<3.9

1.3"J"

NA

NA

NA





12/5/13

<8.6

NA

NA

NA

NA



MW-108B
(Abandoned)

Aug-94

<10

NA

NA

NA

NA





Aug-94

6780

9570

NA

NA

NA



MW-109
(Abandoned)

Oct-94

2400

1980

NA

NA

NA



DUP.

3100

1700

NA

NA

NA



Apr-98

16500

18600

NA

NA

NA





Jul-98

12200

11100

NA

NA

NA





Auq-94

<10

<2.8

NA

NA

NA



MW-109A

Oct-94

<10

1.3 B

NA

NA

NA



(Abandoned)

Apr-98

<10

<5

NA

NA

NA





Jul-98

<10

7

NA

NA

NA



MW-109B

Auq-94

<10

NA

NA

NA

NA



(Abandoned)

Oct-94

<10

NA

NA

NA

NA





Auq-94

<10

3.6 BJ

NA

NA

NA





Oct-94

<10

<3.4 J

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





May-00

<4.2

37

NA

NA

NA





May-04

<2.5

11

3400

230000

NA





May-05

<5.0

0.89

82

70000

NA



MW-110

Oct-06

<6.8

1.8

NA

NA

NA





8/21/07

NA

7.4

NA

NA

NA





7/21/09

NA

5.3

NA

NA

NA





8/26/10

<3.9

2.0 J

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.75

NA

<0.57

NA

<0.45

<0.9

NA

<0.48

<0.18



6/16/11

<3.9

NA

NA

NA

NA





10/24/12

<3.9

NA

NA

NA

NA





12/5/13

<3.4

NA

NA

NA

NA



NA - Compound not analyzed
Underlined - Concentration exceeds PAL
Bolded - Concentration exceeds ES

Page 2 of 13

-------
Table 1 Groundwater Analytical Summary, Better Brite - Chrome Shop

500 Lande Street Blk, De Pere, Wl BRRTS # 02-05-000030





Detected Parameters (mq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,2-DCA

1,1-DCE

cis-1,2-
DCE

PCE

1,1,1-TCA

1,1,2-TCA

TCE

VC

NR140 Preventive Action Limi

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.5

0.7

7

0.5

40

0.5

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

5

7

70

5

200

5

5

0.2



Auq-94

<10

<2.8

NA

NA

NA





Oct-94

<10

<3.4 J

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





May-00

<4.2

25

NA

NA

NA



MW-110A

Oct-06

<6.8

4.2

NA

NA

NA





8/21/07

NA

1.9

NA

NA

NA





7/21/09

NA

1.3

NA

NA

NA





8/26/10

<3.9

1.8 J

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.75

NA

<0.57

NA

<0.45

<0.9

NA

<0.48

<0.18



6/16/11

<3.9

NA

NA

NA

NA





Auq-94

<10

<3.4

NA

NA

NA





DUP.

<10

<3.4

NA

NA

NA





Oct-94

<10

<0.70

NA

NA

NA





Apr-98

226

<5

NA

NA

NA





Jul-98

22

27

NA

NA

NA





Nov-98

<0.5

<0.5

NA

NA

NA





May-00

<4.2

36

NA

NA

NA





Nov-02

<4.2

43

4400

130000

2600





DUP

<4.2

38

3400

100000

280





May-03

5.2

33

2700

98000

1400





May-04

50

150

5000

93000

NA





May-05

250

260

200

87000

NA



MW-111

Nov-05

<5.0

39

12000

98000

NA



DUP

<5.0

55

21000

96000

NA





Oct-06

<6.8

16

NA

NA

NA





8/21/07

NA

25

NA

NA

NA





7/21/09

NA

23.6

NA

NA

NA





8/26/10

<3.9

19.8

NA

NA

NA





6/16/11

<3.9

NA

NA

NA

NA





10/24/11

<3.9

NA

NA

NA

NA





10/24/12

<3.9

NA

NA

NA

NA





12/5/13

<3.4

NA

NA

NA

NA





10/22/15

<3.9

NA

NA

NA

NA





9/20/16

<51

NA

NA

NA

NA





6/13/18

<130

NA

NA

NA

NA





5/15/19

<130

NA

NA

NA

NA





Oct-94

<10

<0.70

NA

NA

NA





Nov-94

<10

<2.5

NA

NA

NA



MW-112

Apr-98

<10

<5

NA

NA

NA



May-00

<4.2

4.1

NA

NA

NA





8/26/10

<3.9

3.9

NA

NA

NA





6/16/11

<3.9

NA

NA

NA

NA





Aug-94

140

99.7

NA

NA

NA





Oct-94

<10 J

8.6 B

NA

NA

NA





May-95

43

20.3

NA

NA

NA



MW-113

Apr-98

<10

<5

NA

NA

NA



Jul-98

<10

12

NA

NA

NA





May-00

<4.2

22

NA

NA

NA





8/26/10

<3.9

24.3

NA

NA

NA





6/16/11

<3.9

NA

NA

NA

NA



NA - Compound not analyzed
Underlined - Concentration exceeds PAL
Bolded - Concentration exceeds ES

Page 3 of 13

-------
Table 1 Groundwater Analytical Summary, Better Brite - Chrome Shop

500 Lande Street Blk, De Pere, Wl BRRTS # 02-05-000030





Detected Parameters (mq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,2-DCA

1,1-DCE

cis-1,2-
DCE

PCE

1,1,1-TCA

1,1,2-TCA

TCE

VC

NR140 Preventive Action Limi

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.5

0.7

7

0.5

40

0.5

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

5

7

70

5

200

5

5

0.2



Mar-95

<10 J

<2.9

NA

NA

NA



MW-114
(Abandoned)

DUP.

<10 J

<2.9

NA

NA

NA



May-95

<10 J

<1.0

NA

NA

NA



DUP.

<10 J

<1.0

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





May-00

<4.2

6.0

NA

NA

NA





Jun-01

<4.2

<0.52

160

92

NA





Nov-01

<4.2

12

1100

NA

3000





DUP

<4.2

10

3300

NA

3300





May-02

<4.2

38

19000

NA

2800





Nov-02

<4.2

38

7000

130000

3100





May-03

<4.2

260

9700

90000

1400





DUP

<4.2

56

3600

89000

1400





May-04

<2.5

1.3

130

34000

NA





May-05

<5.0

1.1

320

44000

NA





Oct-06

<6.8

2.6

NA

NA

NA



MW-115

8/21/07

NA

10

NA

NA

NA



7/21/09

NA

5.8

NA

NA

NA





8/26/10

<3.9

1.6 J

3530

24800

NA





6/16/11

<3.9

NA

4460

10000

NA





10/24/11

<3.9

NA

NA

NA

NA





10/24/12

<3.9

NA

NA

NA

NA





12/5/13

<5.7

NA

NA

NA

NA





10/16/14

<3.9

NA

NA

NA

NA





10/22/15

<3.9

NA

NA

NA

NA





9/20/16

<26

NA

NA

NA

NA





6/13/18

<130

NA

NA

NA

NA





5/15/19

<51

NA

NA

NA

NA





10/14/21

<73

NA

11300

48700

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17



May-00

<4.2

12.0

NA

NA

NA





Oct-06

<6.8

4.6

NA

NA

NA





8/21/07

NA

2.7

NA

NA

NA





7/21/09

NA

2.9

NA

NA

NA





8/26/10

<3.9

1.4 J

NA

NA

NA





6/16/11

<3.9

NA

NA

NA

NA



MW-115A

10/24/12

<3.9

NA

NA

NA

NA



12/5/13

<8.6

NA

NA

NA

NA





10/16/14

<3.9

NA

NA

NA

NA





10/22/15

<3.9

NA

NA

NA

NA





9/20/16

<26

NA

NA

NA

NA





6/13/18

<130

NA

NA

NA

NA





5/15/19

<51

NA

NA

NA

NA





10/14/21

<370

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17

NA - Compound not analyzed
Underlined - Concentration exceeds PAL
Bolded - Concentration exceeds ES

Page 4 of 13

-------
Table 1 Groundwater Analytical Summary, Better Brite - Chrome Shop

500 Lande Street Blk, De Pere, Wl BRRTS # 02-05-000030

Sample Location

Date

Detected Parameters (mq/L)

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,2-DCA

1,1-DCE

cis-1,2-
DCE

PCE

1,1,1-TCA

1,1,2-TCA

TCE

VC

NR140 Preventive Action Limi

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.5

0.7

7

0.5

40

0.5

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

5

7

70

5

200

5

5

0.2

MW-116

May-00

1600

470

NA

NA

NA



DUP.

1500

460

NA

NA

NA

Nov-00

37

23

NA

NA

NA

DUP

46

24

NA

NA

NA

Jun-01

4400

2300

840

2100

NA

Nov-01

3300

2100

690

NA

2400

May-02

12000

7300

530

NA

2500

Nov-02

5100

3200

720

20000

2900

May-03

8900

6000

410

2700000

1700

May-04

28000

22000

43

19000

NA

DUP

28000

22000

280

24000

NA

May-05

52000

52000

950

1900000

NA

DUP

54000

53000

710

1800000

NA

Nov-05

50000

61000

840

1800000

NA

Oct-06

39000

36000

900

1800000

NA

DUP

42000

36000

NA

NA

NA

8/21/07

NA

39,000

NA

NA

NA

7/21/09

NA

25,500

NA

NA

NA

8/26/10

21,300

19,200

478

1330000

NA

162 I 2.4 J I 0.43 J | NA | 10.3 | <0.46 | <2.2 | NA | NA | 30.9 | NA | 22.1 | NA | 3.2 I 76.9 I NA | H | 0.21 J

1/26/10 LF

20,200

17,700

NA

NA

NA



4/25/11

34,600

NA

NA

1030000

NA

6/16/11

13,800

NA

240

1660000

NA

3.4 "J" | NA | NA | NA | NA | NA | NA | NA | NA | 28.1 | NA | 25.9 | NA | 1.2 I 84.1 I NA | 2J> | <0.18

10/24/11

18,300

NA

NA

NA

NA



10/24/12

22,300

NA

NA

NA

NA

12/5/13

17,600

NA

NA

NA

NA

DUP

17,500

NA

NA

NA

NA

10/16/14

13,300

NA

NA

NA

NA

10/22/15

16,500

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

43.5

0.32 J

40.6

1.5

1.7

145

0.46 J

1.6

0.27 J

9/20/16

16,100

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

34.8

<0.34

34.8

1.2 J

1.4 J

135

<0.39

1.5 J

<0.35

6/13/18

12,100

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

34.4

<0.34

37.4

0.93 J

1.1 J

125

<0.39

1.5 J

<0.35

5/15/19

9,800

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

38.9

<0.28

44.3

1.3

1.2

142

<0.55

2.1

<0.17

10/14/21

7100

NA

177

1020000

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

36.7

<0.29

28.9

0.92J

1.2

118

<0.34

2.2

0.22J

CSTW1

4/25/11

<3.9

NA

NA

1,180,000

NA



CSTW2

4/25/11

<3.9

NA

NA

2,840,000

NA

CSTW3

4/25/11

1,000

NA

NA

2,010,000

NA

CSTW4

4/25/11

<3.9

NA

NA

426,000

NA

CSTW5

4/25/11

4.9 "J"

NA

NA

592,000

NA

CSTW6

4/25/11

<3.9

NA

NA

608000

NA

NA - Compound not analyzed
Underlined - Concentration exceeds PAL
Bolded - Concentration exceeds ES

Page 5 of 13

-------
Table 2 Groundwater Analytical Summary, Better Brlte - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031

Sample Location Date

Hexavalent
Chromium

Antimony

Detected Parameters (pg/L)

Cyanide

Nickel

Silver

NR140 Preventive Action Limit

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

NO ES

10

200

10/22/15

10,300

NA

NA

NA

NA

9/19/16

9600

NA

NA

NA

NA

6/12/18

6600

NA

NA

NA

NA

5/14/19

4400

NA

NA

NA

NA

(Grab Sample, no purging)

(Grab Sample, previously purged)
(Grab Sample, previously purged)
(Grab Sample, previously purged)

10/14/21

6100

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

10/22/15

3,300

NA

NA

NA

NA

9/19/16

2800

NA

NA

NA

NA

6/12/18

2700

NA

NA

NA

NA

5/14/19

1800

NA

NA

NA

NA

(Grab Sample, no purging)

(Grab Sample, previously purged)
(Grab Sample, previously purged)
(Grab Sample, previously purged)

10/14/21

640

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.58

<0.41

4.5

<0.32 <0.17

May-00

NA

NA

NA

Jun-01

<4.2

7.1

NA

NA

NA

Nov-01

NA

NA

NA

PF-MW-2

May-02

<4.2

<0.52

NA

NA

NA

Nov-02

NA

NA

NA

May-03

<4.2

49

NA

NA

NA

10/22/15

NA

NA

NA

NA

9/19/16

<5.1

NA

NA

NA

NA

6/13/18

NA

NA

NA

NA

(Grab Sample, no purging)

(Grab Sample, previously purged)
(Grab Sample, previously purged)

May-00

230

330

NA

NA

NA

Nov-00

130

NA

NA

NA

Jun-01

3500

2200

NA

NA

NA

Nov-01

1700

NA

NA

NA

May-02

<4.2

220

NA

NA

NA

Nov-02

NA

NA

NA

May-03

110

55

NA

NA

NA

Pup

NA

NA

NA

May-04

190

NA

NA

NA

May-05

NA

NA

NA

MW-3/MW3R

7/21/09

NA

717

NA

NA

NA

8/24/10

660

552

NA

NA

NA

6/28/11

2800

NA

NA

NA

NA

10/24/11

2200

NA

NA

NA

NA

10/23/12

560

NA

NA

NA

NA

12/5/13

140

NA

NA

NA

NA

10/16/14

190

NA

NA

NA

NA

10/22/15

100

NA

NA

NA

NA

9/19/16

380

NA

NA

NA

NA

6/1 2/18

NA

NA

NA

NA

5/14/19

NA

NA

NA

NA

10/14/21

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

4.6

0.96J

<0.41

8.9

<0.32 <0.17

NA - Compound not analyzed

Underlined - Concentration exceeds preventive action limit
Bolded - Concentration exceeds enforcement standard

Page 6 of 13

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031





Detected Parameters (nq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,1-DCE

PCE

1,1,1-TCA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

7

5

200

5

0.2



Auq-94

<10

<3.4

NA

NA

NA





DUP

<10

<3.4

NA

NA

NA





Oct-94

<10 J

<3.4 J

NA

NA

NA





DUP

<10 J

<3.4 J

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





Mav-00

<4.2

4.6

NA

NA

NA



MW-4
(Abandoned)

Nov-00

<4.2

2.4

NA

NA

NA



Jun-01

<4.2

12

NA

NA

NA



Nov-01

<4.2

7.4

NA

NA

NA





Mav-02

<4.2

1.4

NA

NA

NA





Nov-02

<4.2

15

NA

NA

NA





Mav-03

<4.2

27

NA

NA

NA





Mav-04

<2.5

1.8

NA

NA

NA





Mav-05

<5.0

9

NA

NA

NA





Nov-05

<5.0

12

NA

NA

NA





Auq-94

<10

<3.4

NA

NA

NA





Oct-94

<10 J

6.0 B

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





Mav-00

<4.2

8.7

NA

NA

NA





Nov-00

<4.2

3.7

NA

NA

NA



MW-4A
(Abandoned)

Jun-01

<4.2

3.7

NA

NA

NA



Nov-01

<4.2

13

NA

NA

NA



Mav-02

<4.2

38

NA

NA

NA





Nov-02

<4.2

28

NA

NA

NA





Mav-03

<4.2

32

NA

NA

NA





Mav-04

<2.5

0.75

NA

NA

NA





Mav-05

<5.0

2

NA

NA

NA





Nov-05

<5.0

2.8

NA

NA

NA



MW-4B

Oct-94

<10

<0.70

NA

NA

NA



(Abandoned)

Nov-94

<10

<2.5

NA

NA

NA



NA - Compound not analyzed

Underlined - Concentration exceeds preventive action limit
Bolded - Concentration exceeds enforcement standard

Page 7 of 13

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031





Detected Parameters (nq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,1-DCE

PCE

1,1,1-TCA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

7

5

200

5

0.2



Aug-94

1590

827

NA

NA

NA





Oct-94

460 J

299 J

NA

NA

NA





DUP

510 J

763 J

NA

NA

NA





Apr-98

212

631

NA

NA

NA





DUP

207

667

NA

NA

NA





Jul-98

1420

1230

NA

NA

NA





May-00

120

190

NA

NA

NA





Nov-00

<4.2

6.6

NA

NA

NA





Jun-01

590

450

NA

NA

NA





Nov-02

2200

2200

NA

NA

NA





DUP

2200

2200

NA

NA

NA





May-03

4900

3600

NA

NA

NA





May-04

4700

3100

NA

NA

NA



MW-5

May-05

4000

3200

NA

NA

NA





Oct-06

4900

4000

NA

NA

NA





8/21/07

NA

2,700

NA

NA

NA





7/21/09

NA

2,210

NA

NA

NA





8/24/10

1,300

1,180

NA

NA

NA





6/28/11

970

NA

NA

NA

NA





1 0/24/11

1,100

NA

NA

NA

NA





1 0/23/1 2

970

NA

NA

NA

NA





1 2/5/13

1000

NA

NA

NA

NA





1 0/22/1 5

330

NA

NA

NA

NA





9/19/16

460

NA

NA

NA

NA





6/1 2/18

180

NA

NA

NA

NA





5/14/19

<51

NA

NA

NA

NA





10/14/21

<73

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17



Auq-94

<10

<3.4

NA

NA

NA





Oct-94

<10

<3.4 J

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





Mav-00

<4.2

6.5

NA

NA

NA





Nov-00

340

380

NA

NA

NA





Jun-01

<4.2

3.9

NA

NA

NA



MW-5A

Nov-02

<4.2

34

NA

NA

NA



Mav-03

<4.2

22

NA

NA

NA





DUP

<4.2

49

NA

NA

NA





Mav-04

<2.5

2.7

NA

NA

NA





Mav-05

<5.0

7.6

NA

NA

NA





8/24/10

<3.9

2.5"J"

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA





10/14/21

<1800

NA

NA

NA

NA



MW-5B

Auq-94

NA

NA

NA

NA

NA



(Abandoned)

Oct-94

<10

<5

NA

NA

NA



NA - Compound not analyzed

Underlined - Concentration exceeds preventive action limit
Bolded - Concentration exceeds enforcement standard

Page 8 of 13

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031





Detected Parameters (nq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,1-DCE

PCE

1,1,1-TCA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

7

5

200

5

0.2



Aug-94

15900

39200

NA

NA

NA





Oct-94

47000

41,900 J

NA

NA

NA





Apr-98

7650

4560

NA

NA

NA





May-00

23000

26000

NA

NA

NA





Nov-00

26000

23000

NA

NA

NA





Jun-01

14000

15000

NA

NA

NA





Nov-01

25000

29000

NA

NA

NA





May-02

13000

13000

NA

NA

NA





Nov-02

21000

22000

NA

NA

NA





May-03

11000

9300

NA

NA

NA





May-04

13000

15000

NA

NA

NA





May-05

12000

11000

NA

NA

NA





DUP

12000

11000

NA

NA

NA



MW-6

Oct-06

12000

12000

NA

NA

NA



DUP

14000

12000

NA

NA

NA





8/21/07

NA

8,900

NA

NA

NA





7/21/09

NA

10,400

NA

NA

NA





8/24/10

8400

7,540

NA

NA

NA





6/28/11

5200

NA

NA

NA

NA





1 0/24/11

6,500

NA

NA

NA

NA





1 0/23/1 2

7,300

NA

NA

NA

NA





1 2/5/13

6,100

NA

NA

NA

NA





1 0/16/14

3,300

NA

NA

NA

NA





1 0/22/1 5

360

NA

NA

NA

NA





9/20/16

3500

NA

NA

NA

NA





6/13/18

1400

NA

NA

NA

NA





5/14/19

1200

NA

NA

NA

NA





10/14/21

1400

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17



Auq-94

<10

4.9 B

NA

NA

NA





Oct-94

<10

<3.4 J

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





Mav-00

6.6

22

NA

NA

NA





Nov-00

<4.2

13

NA

NA

NA





6/01

<4.2

11

NA

NA

NA





Nov-01

<4.2

7.1

NA

NA

NA



MW-6A

Mav-02

<4.2

51

NA

NA

NA





Nov-02

<4.2

83

NA

NA

NA





Mav-03

<4.2

59

NA

NA

NA





Mav-04

<2.5

3.4

NA

NA

NA





Mav-05

<5.0

12

NA

NA

NA





8/24/10

<3.9

1.7"J"

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA





10/14/21

<73

NA

NA

NA

NA



MW-6B
(Abandoned)

Aug-94

<10

NA

NA

NA

NA



NA - Compound not analyzed

Underlined - Concentration exceeds preventive action limit
Bolded - Concentration exceeds enforcement standard

Page 9 of 13

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031





Detected Parameters (nq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,1-DCE

PCE

1,1,1-TCA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

7

5

200

5

0.2



Auq-94

<10

6.6 BJ

NA

NA

NA





DUP.

<10

<2.8

NA

NA

NA





Oct-94

<10 J

36.4 J

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





DUP

<10

<5

NA

NA

NA





Mav-00

<4.2

3.9

NA

NA

NA





Nov-00

<4.2

1.1

NA

NA

NA





Jun-01

<4.2

2.7

NA

NA

NA



MW-7

Nov-01

<4.2

9.7

NA

NA

NA



Mav-02

<4.2

3.2

NA

NA

NA





Nov-02

<4.2

1.9

NA

NA

NA





Mav-03

<4.2

0.91

NA

NA

NA





Mav-04

<2.5

0.88

NA

NA

NA





Mav-05

<5.0

32

NA

NA

NA





8/21/07

NA

4.4

NA

NA

NA





7/21/09

NA

9

NA

NA

NA





8/24/10

<3.9

3.7"J"

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA





Auq-94

<10

<2.8

NA

NA

NA





Oct-94

<10 J

<3.4 J

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





Mav-00

<4.2

4.7

NA

NA

NA





Nov-00

7.9

5

NA

NA

NA





Jun-01

<4.2

2.5

NA

NA

NA



MW-7A

Nov-01

<4.2

<.52

NA

NA

NA



Mav-02

<4.2

1.4

NA

NA

NA





Nov-02

<4.2

0.98

NA

NA

NA





Mav-03

<4.2

0.85

NA

NA

NA





Mav-04

3.9

2.2

NA

NA

NA





Mav-05

<5.0

0,65

NA

NA

NA





8/24/10

<3.9

1.6"J"

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA





Oct-94

<10

<0.70

NA

NA

NA





Nov-94

<10

<2.5

NA

NA

NA





DUP.

<10

<2.5

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





Mav-00

<4.2

15

NA

NA

NA





Nov-00

13

13

NA

NA

NA





Jun-01

5.3

2

NA

NA

NA





Nov-01

<4.2

2.3

NA

NA

NA



MW-8

DUP

<4.2

6.7

NA

NA

NA





Mav-02

<4.2

4

NA

NA

NA





Nov-02

<4.2

23

NA

NA

NA





Mav-03

<4.2

2.2

NA

NA

NA





Mav-04

<2.5

1.7

NA

NA

NA





Mav-05

<5.0

1.1

NA

NA

NA





8/21/07

NA

2.3

NA

NA

NA





8/24/10

<3.9

96

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA



NA - Compound not analyzed

Underlined - Concentration exceeds preventive action limit
Bolded - Concentration exceeds enforcement standard

Page 10 of 13

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031





Detected Parameters (nq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,1-DCE

PCE

1,1,1-TCA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

7

5

200

5

0.2



Oct-94

<10

<0.70

NA

NA

NA





Nov-94

<10

<2.5

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





Mav-00

<4.2

16

NA

NA

NA





Nov-00

<4.2

34

NA

NA

NA





Jun-01

<4.2

3.7

NA

NA

NA





Nov-01

<4.2

14

NA

NA

NA



MW-8A

Mav-02

<4.2

2.5

NA

NA

NA



DUP

<4.2

11

NA

NA

NA





Nov-02

<4.2

20

NA

NA

NA





Mav-03

<4.2

13

NA

NA

NA





Mav-04

3.9

0.59

NA

NA

NA





Mav-05

<5.0

2.6

NA

NA

NA





8/21/07

NA

0.92

NA

NA

NA





8/24/10

<3.9

1.7"J"

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA





Aug-94

400

697

NA

NA

NA





Oct-94

470 J

442 J

NA

NA

NA





Apr-98

209

<5

NA

NA

NA





Jul-98

60

75

NA

NA

NA





Nov-00

13

15

NA

NA

NA





DUP

19

51

NA

NA

NA





Jun-01

28

180

NA

NA

NA





Nov-01

35

76

NA

NA

NA





Mav-02

75

72

NA

NA

NA





Nov-02

67

80

NA

NA

NA





Mav-03

32

53

NA

NA

NA





Mav-04

54

63

NA

NA

NA





Dup

50

46

NA

NA

NA



MW-9

Mav-05

28

41

NA

NA

NA





Oct-06

17

34

NA

NA

NA





8/21/07

NA

52

NA

NA

NA





7/21/09

NA

33.3

NA

NA

NA





8/24/10

27

30.3

NA

NA

NA





6/28/11

14

NA

NA

NA

NA





10/23/1 2

18 J

NA

NA

NA

NA





1 2/5/13

<3.4

NA

NA

NA

NA





10/16/14

<3.9

NA

NA

NA

NA





10/22/1 5

<3.9

NA

NA

NA

NA





9/19/16

<26

NA

NA

NA

NA





6/1 2/18

<130

NA

NA

NA

NA





5/14/19

<51

NA

NA

NA

NA





10/14/21

<730

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17

NA - Compound not analyzed

Underlined - Concentration exceeds preventive action limit
Bolded - Concentration exceeds enforcement standard

Page 11 of 13

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031





Detected Parameters (nq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,1-DCE

PCE

1,1,1-TCA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

7

5

200

5

0.2



Aug-94

60300

53100

NA

NA

NA





Oct-94

60800 J

43,500 J

NA

NA

NA





Nov-00

20000

18000

NA

NA

NA





Jun-01

<4.2

20

NA

NA

NA





Nov-02

35000

38000

NA

NA

NA





May-03

38000

37000

NA

NA

NA





May-04

25000

22000

NA

NA

NA



MW-10

Nov-05

13000

13000

NA

NA

NA





Oct-06

14000

13000

NA

NA

NA





8/21/07

NA

17,000

NA

NA

NA





10/22/15

10,300

NA

NA

NA

NA





9/19/16

9,800

NA

NA

NA

NA





6/1 2/18

3,200

NA

NA

NA

NA





5/14/19

1,500

NA

NA

NA

NA





10/14/21

<180

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17



Mav-95

<10

<1.0

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





Mav-00

<4.2

7.0

NA

NA

NA





Nov-00

<4.2

4.1

NA

NA

NA





Jun-01

<4.2

3.6

NA

NA

NA





Nov-01

<4.2

7.8

NA

NA

NA



MW-11

Mav-02

17

<20

NA

NA

NA





Nov-02

<4.2

27

NA

NA

NA





Mav-03

<4.2

12

NA

NA

NA





Mav-04

<2.5

2.3

NA

NA

NA





Mav-05

<5.0

2.8

NA

NA

NA





8/24/10

<3.9

8.9

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA





Mar-95

<10 J

<2.9

NA

NA

NA





Mav-95

<10

<1.0

NA

NA

NA





Apr-98

<10

<5

NA

NA

NA





Mav-00

<4.2

4.8

NA

NA

NA





Nov-00

<4.2

6

NA

NA

NA





jun-01

<4.2

6.4

NA

NA

NA



MW-12

Nov-01

<4.2

<0.52

NA

NA

NA



Mav-02

<4.2

4.8

NA

NA

NA





Nov-02

<4.2

1.3

NA

NA

NA





Mav-03

<4.2

1.3

NA

NA

NA





Mav-04

<2.5

1.8

NA

NA

NA





Mav-05

<5.0

8.1

NA

NA

NA





8/24/10

<3.9

6.5

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA



MW-13

Mar-95

<10 J

<2.9

NA

NA

NA



Mav-95

<10

<1.0

NA

NA

NA



NA - Compound not analyzed

Underlined - Concentration exceeds preventive action limit
Bolded - Concentration exceeds enforcement standard

Page 12 of 13

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031

Sample Location

Date

Detected Parameters (nq/L)

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,1-DCE

PCE

1,1,1-TCA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

7

5

200

5

0.2

Zinc Sump

Aug-94

89000

209000

NA

NA

NA



Oct-94

144900

277000

NA

NA

NA

Apr-98

66000

38300

NA

NA

NA

Jul-98

131000

131000

NA

NA

NA

May-00

1800

1700

NA

NA

NA

Nov-00

41000

27000

NA

NA

NA

Jun-01

40000

110000

NA

NA

NA

Nov-01

23000

56000

NA

NA

NA

May-02

43000

14000

NA

NA

NA

Nov-03

23000

30000

NA

NA

NA

May-03

8400

6800

NA

NA

NA

May-04

24000

6400

NA

NA

NA

May-05

15000

13000

NA

NA

NA

Oct-06

7500

5900

NA

NA

NA

8/21/07

NA

20,000

NA

NA

NA

7/21/09

NA

14,800

NA

NA

NA

8/24/10

12,100

11,300

NA

NA

NA

90.6

NA

NA

40

NA

NA

<2.2

2.5 J

4.7 J

<0.75

<0.57

<0.45

1.5

<0.48

<0.18

6/28/11

4100

NA

NA

NA

NA

6.6

NA

NA

250

NA

NA

<2.2

2.5 J

4.7 J

1.2

2.8

0,84

38.9

<0.48

<0.18

1 0/24/11

3,700

NA

NA

NA

NA

6.0 "J"

NA

NA

220

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

1 0/23/1 2

110

NA

NA

NA

NA

NA

NA

NA

40

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

1 2/5/13

5,100

NA

NA

NA

NA

NA

NA

NA

340

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

1 0/16/14

9,600

NA

NA

NA

NA

NA

NA

NA

190

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

1 0/22/1 5

10,200

NA

NA

NA

NA

NA

NA

NA

220

NA

NA

NA

NA

NA

2.9

2.5

1.2

49.0

<0.33

<0.18

9/19/16

14,000

NA

NA

NA

NA

<7.3

NA

NA

160

NA

NA

NA

NA

NA

1.4

1.2

0.79J

22.6

<0.33

<0.18

6/13/18

9900

NA

NA

NA

NA

NA

NA

NA

51

NA

NA

NA

NA

NA

<0.24

<0.41

<0.50

2.1

<0.33

<0.18

5/14/19

8100

NA

NA

NA

NA

NA

NA

NA

100

NA

NA

NA

NA

NA

0.68J

1.2

0.45J

14.1

<0.26

<0.17

10/14/21

6500

NA

NA

NA

NA

NA

NA

NA

89J

NA

NA

NA

NA

NA

1.5

0.81 J

0.75J

15.7

<0.32

<0.17

Private

Aug-94

<10

<10

NA

NA

NA



Municipal

Auq-94

<10

<10

NA

NA

NA

DUP.

<10

<10

NA

NA

NA

Oct-94

<10

<10

NA

NA

NA

DUP.

<10

<10

NA

NA

NA

USGS

Oct-94

<10

0.75 B

NA

NA

NA

USGS-A

Oct-94

<10

11.9

NA

NA

NA

NA - Compound not analyzed

Underlined - Concentration exceeds preventive action limit
Bolded - Concentration exceeds enforcement standard

Page 13 of 13

-------
-------
-------
-------
-------
-------
Pace Analytical Services, LLC

1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

October 29, 2021

Kim Kennedy
Westwood Infrastructure.
ONE SYSTEMS DRIVE
Appleton, Wl 54914

RE: Project: 3001438 BETTER BRITE
Pace Project No.: 40235181

Dear Kim Kennedy:

Enclosed are the analytical results for sample(s) received by the laboratory on October 14, 2021. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.

The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Green Bay

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

- p-fT'

u

Tod Noltemeyer
tod.noltemeyer@pacelabs.com
(920)469-2436
Project Manager

Enclosures

cc: Brian Wayner, Westwood Infrastructure

Face Analytical "

WHW.pceIabs.com



REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 1 of 43

-------
iceAnalytical

www.paceIibs.eom

CERTIFICATIONS

Project:	3001438 BETTER BRITE

Pace Project No.: 40235181

Pace Analytical Services Green Bay

1241 Bellevue Street, Green Bay, Wl 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky UST Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
New York Certification #: 12064
North Dakota Certification #: R-150

Virginia VELAP ID: 460263
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
Wisconsin Certification #: 405132750
Wisconsin DATCP Certification #: 105-444
USDASoil Permit#: P330-16-00157
Federal Fish & Wildlife Permit #: LE51774A-0

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 2 of 43

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

SAMPLE SUMMARY

Project:	3001438 BETTER BRITE

Pace Project No.: 40235181

Lab ID	Sample ID	Matrix	Date Collected Date Received

40235181001

MW-106

Water

10/14/21

15:43

10/14/21

16:46

40235181002

MW-107

Water

10/14/21

15:05

10/14/21

16:46

40235181003

MW-115

Water

10/14/21

13:55

10/14/21

16:46

40235181004

MW-115A

Water

10/14/21

14:23

10/14/21

16:46

40235181005

MW-116

Water

10/14/21

13:45

10/14/21

16:46

40235181006

W-1

Water

10/14/21

10:41

10/14/21

16:46

40235181007

W-1A

Water

10/14/21

10:11

10/14/21

16:46

40235181008

MW-3R

Water

10/14/21

09:59

10/14/21

16:46

40235181009

MW-5

Water

10/14/21

11:54

10/14/21

16:46

40235181010

MW-5A

Water

10/14/21

13:07

10/14/21

16:46

40235181011

MW-6

Water

10/14/21

10:55

10/14/21

16:46

40235181012

MW-6A

Water

10/14/21

09:05

10/14/21

16:46

40235181013

MW-9

Water

10/14/21

08:52

10/14/21

16:46

40235181014

MW-10

Water

10/14/21

10:05

10/14/21

16:46

40235181015

ZINC SUMP

Water

10/14/21

12:17

10/14/21

16:46

40235181016

TRIP BLANK

Water

10/14/21

00:00

10/14/21

16:46

^Analytical

www.paceIibs.eom

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 3 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

Project:

Pace Project No

3001438 BETTER BRITE
i.: 40235181

SAMPLE ANALYTE COUNT







Lab ID

Sample ID



Method

Analysts

Analytes
Reported

Laboratory

40235181001

MW-106



EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G

40235181002

MW-107



EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G

40235181003

MW-115



EPA 6010D

TXW

1

PASI-G







EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G







EPA 300.0

HMB

1

PASI-G

40235181004

MW-115A



EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G

40235181005

MW-116



EPA 6010D

TXW

1

PASI-G







EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G







EPA 300.0

HMB

1

PASI-G

40235181006

W-1



EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G

40235181007

W-1A



EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G

40235181008

MW-3R



EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G

40235181009

MW-5



EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G

40235181010

MW-5A

SM

3500-Cr B (Online)

EXM

1

PASI-G

40235181011

MW-6



EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G

40235181012

MW-6A

SM

3500-Cr B (Online)

EXM

1

PASI-G

40235181013

MW-9



EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G

40235181014

MW-10



EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G

40235181015

ZINC SUMP



EPA 8260

LAP

64

PASI-G





SM

3500-Cr B (Online)

EXM

1

PASI-G







EPA 335.4

DAW

1

PASI-G

40235181016

TRIP BLANK



EPA 8260

LAP

64

PASI-G

PASI-G = Pace Analytical Services - Green Bay

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 4 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-106

Lab ID:

40235181001

Collected:

10/14/21

15:43

Received:

10/14/2116:46 Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













Benzene

<0.30

ug/L

1.0

0.30

1



10/15/21

19:36

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36

1



10/15/21

19:36

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36

1



10/15/21

19:36

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42

1



10/15/21

19:36

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8

1



10/15/21

19:36

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2

1



10/15/21

19:36

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86

1



10/15/21

19:36

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42

1



10/15/21

19:36

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59

1



10/15/21

19:36

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37

1



10/15/21

19:36

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86

1



10/15/21

19:36

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4

1



10/15/21

19:36

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2

1



10/15/21

19:36

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6

1



10/15/21

19:36

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21

19:36

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21

19:36

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4

1



10/15/21

19:36

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6

1



10/15/21

19:36

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31

1



10/15/21

19:36

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99

1



10/15/21

19:36

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33

1



10/15/21

19:36

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35

1



10/15/21

19:36

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89

1



10/15/21

19:36

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46

1



10/15/21

19:36

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21

19:36

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29

1



10/15/21

19:36

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58

1



10/15/21

19:36

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47

1



10/15/21

19:36

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53

1



10/15/21

19:36

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45

1



10/15/21

19:36

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30

1



10/15/21

19:36

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2

1



10/15/21

19:36

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41

1



10/15/21

19:36

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36

1



10/15/21

19:36

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5

1



10/15/21

19:36

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21

19:36

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33

1



10/15/21

19:36

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7

1



10/15/21

19:36

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0

1



10/15/21

19:36

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0

1



10/15/21

19:36

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32

1



10/15/21

19:36

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21

19:36

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1

1



10/15/21

19:36

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35

1



10/15/21

19:36

103-65-1

Styrene

<0.36

ug/L

1.0

0.36

1



10/15/21

19:36

100-42-5

Qual

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 5 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-106

Lab ID:

40235181001

Collected:

10/14/21

15:43

Received:

10/14/2116:46 Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1



10/15/21 19:36

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

1



10/15/21 19:36

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41

1



10/15/21 19:36

127-18-4

Toluene

<0.29

ug/L

1.0

0.29

1



10/15/21 19:36

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1



10/15/21 19:36

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1



10/15/21 19:36

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21 19:36

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

1



10/15/21 19:36

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32

1



10/15/21 19:36

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1



10/15/21 19:36

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1



10/15/21 19:36

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1



10/15/21 19:36

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

1



10/15/21 19:36

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17

1



10/15/21 19:36

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70

1



10/15/21 19:36

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35

1



10/15/21 19:36

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

96

%

70-130



1



10/15/21 19:36

460-00-4

1,2-Dichlorobenzene-d4 (S)

99

%

70-130



1



10/15/21 19:36

2199-69-1

Toluene-d8 (S)

102

%

70-130



1



10/15/21 19:36

2037-26-5

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)











Pace Analytical Services -

Green Bay











Chromium, Hexavalent

<0.18

mg/L

0.61

0.18

25



10/15/21 07:38

D3

Sample: MW-107

Lab ID:

40235181002

Collected:

10/14/21

15:05

Received:

10/14/2116:46 Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

10/15/21 19:55

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

10/15/21 19:55

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

10/15/21 19:55

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

10/15/21 19:55

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

10/15/21 19:55

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

10/15/21 19:55

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

10/15/21 19:55

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

10/15/21 19:55

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

10/15/21 19:55

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

10/15/21 19:55

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

10/15/21 19:55

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

10/15/21 19:55

75-00-3

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 6 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-107

Lab ID:

40235181002

Collected:

10/14/21

15:05

Received:

10/14/2116:46 Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













Chloroform

<1.2

ug/L

5.0

1.2

1



10/15/21

19:55

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6

1



10/15/21

19:55

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21

19:55

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21

19:55

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4

1



10/15/21

19:55

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6

1



10/15/21

19:55

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31

1



10/15/21

19:55

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99

1



10/15/21

19:55

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33

1



10/15/21

19:55

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35

1



10/15/21

19:55

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89

1



10/15/21

19:55

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46

1



10/15/21

19:55

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21

19:55

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29

1



10/15/21

19:55

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58

1



10/15/21

19:55

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47

1



10/15/21

19:55

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53

1



10/15/21

19:55

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45

1



10/15/21

19:55

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30

1



10/15/21

19:55

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2

1



10/15/21

19:55

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41

1



10/15/21

19:55

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36

1



10/15/21

19:55

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5

1



10/15/21

19:55

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21

19:55

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33

1



10/15/21

19:55

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7

1



10/15/21

19:55

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0

1



10/15/21

19:55

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0

1



10/15/21

19:55

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32

1



10/15/21

19:55

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21

19:55

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1

1



10/15/21

19:55

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35

1



10/15/21

19:55

103-65-1

Styrene

<0.36

ug/L

1.0

0.36

1



10/15/21

19:55

100-42-5

1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1



10/15/21

19:55

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

1



10/15/21

19:55

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41

1



10/15/21

19:55

127-18-4

Toluene

<0.29

ug/L

1.0

0.29

1



10/15/21

19:55

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1



10/15/21

19:55

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1



10/15/21

19:55

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21

19:55

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

1



10/15/21

19:55

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32

1



10/15/21

19:55

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1



10/15/21

19:55

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1



10/15/21

19:55

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1



10/15/21

19:55

95-63-6

Qual

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 7 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-107

Lab ID:

40235181002

Collected: 10/14/21 15:05

Received:

10/14/2116:46 Matrix: Water



Parameters

Results

Units

LOQ LOD DF

Prepared

Analyzed

CAS No.

Qual

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,3,5-Trimethylbenzene

<0.36

ug/L

1.0 0.36 1



10/15/21

19:55

108-67-8



Vinyl chloride

<0.17

ug/L

1.0 0.17 1



10/15/21

19:55

75-01-4



m&p-Xylene

<0.70

ug/L

2.0 0.70 1



10/15/21

19:55

179601-23-1



o-Xylene

<0.35

ug/L

1.0 0.35 1



10/15/21

19:55

95-47-6



Surrogates

















4-Bromofluorobenzene (S)

96

%

70-130 1



10/15/21

19:55

460-00-4



1,2-Dichlorobenzene-d4 (S)

101

%

70-130 1



10/15/21

19:55

2199-69-1



Toluene-d8 (S)

103

%

70-130 1



10/15/21

19:55

2037-26-5



Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)













Pace Analytical Services -

Green Bay











Chromium, Hexavalent

<0.18

mg/L

0.61 0.18 25



10/15/21

07:38



D3,M0

Sample: MW-115

Parameters

Lab ID: 40235181003 Collected: 10/14/2113:55 Received: 10/14/2116:46 Matrix: Water

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

6010D MET ICP

Analytical Method: EPA 6010D Preparation Method: EPA 301 OA
Pace Analytical Services - Green Bay

Iron

11300

ug/L

100

56.7

1

10/20/21 07:29 10/20/21

23:06

7439-89-

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













Benzene

<0.30

ug/L

1.0

0.30

1

10/15/21

20

15

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36

1

10/15/21

20

15

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36

1

10/15/21

20

15

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42

1

10/15/21

20

15

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8

1

10/15/21

20

15

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2

1

10/15/21

20

15

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86

1

10/15/21

20

15

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42

1

10/15/21

20

15

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59

1

10/15/21

20

15

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37

1

10/15/21

20

15

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86

1

10/15/21

20

15

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4

1

10/15/21

20

15

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2

1

10/15/21

20

15

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6

1

10/15/21

20

15

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89

1

10/15/21

20

15

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89

1

10/15/21

20

15

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4

1

10/15/21

20

15

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6

1

10/15/21

20

15

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31

1

10/15/21

20

15

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99

1

10/15/21

20

15

74-95-3

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 8 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-115

Lab ID:

40235181003

Collected:

10/14/21

13:55

Received:

10/14/21 16:46

Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33

1



10/15/21 20

15

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35

1



10/15/21 20

15

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89

1



10/15/21 20

15

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46

1



10/15/21 20

15

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21 20

15

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29

1



10/15/21 20

15

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58

1



10/15/21 20

15

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47

1



10/15/21 20

15

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53

1



10/15/21 20

15

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45

1



10/15/21 20

15

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30

1



10/15/21 20

15

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2

1



10/15/21 20

15

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41

1



10/15/21 20

15

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36

1



10/15/21 20

15

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5

1



10/15/21 20

15

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21 20

15

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33

1



10/15/21 20

15

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7

1



10/15/21 20

15

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0

1



10/15/21 20

15

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0

1



10/15/21 20

15

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32

1



10/15/21 20

15

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21 20

15

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1

1



10/15/21 20

15

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35

1



10/15/21 20

15

103-65-1

Styrene

<0.36

ug/L

1.0

0.36

1



10/15/21 20

15

100-42-5

1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1



10/15/21 20

15

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

1



10/15/21 20

15

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41

1



10/15/21 20

15

127-18-4

Toluene

<0.29

ug/L

1.0

0.29

1



10/15/21 20

15

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1



10/15/21 20

15

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1



10/15/21 20

15

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21 20

15

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

1



10/15/21 20

15

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32

1



10/15/21 20

15

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1



10/15/21 20

15

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1



10/15/21 20

15

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1



10/15/21 20

15

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

1



10/15/21 20

15

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17

1



10/15/21 20

15

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70

1



10/15/21 20

15

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35

1



10/15/21 20

15

95-47-6

Surrogates



















4-Bromofluorobenzene (S)

97

%

70-130



1



10/15/21 20

15

460-00-4

1,2-Dichlorobenzene-d4 (S)

100

%

70-130



1



10/15/21 20

15

2199-69-1

Toluene-d8 (S)

103

%

70-130



1



10/15/21 20

15

2037-26-5

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 9 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	3001438 BETTER BRITE

Pace Project No.: 40235181

Sample: MW-115

Lab ID:

40235181003

Collected:

10/14/21

13:55

Received:

10/14/2116:46 Matrix: Water



Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)













Pace Analytical Services -

Green Bay













Chromium, Hexavalent

<0.073

mg/L

0.24

0.073

10



10/15/21 07:39



D3

300.0 IC Anions

Analytical Method: EPA 300.0















Pace Analytical Services -

Green Bay













Sulfate

48.7

mg/L

10.0

2.2

5



10/28/21 02:30

14808-79-8



Sample: MW-115A

Lab ID:

40235181004

Collected:

10/14/21

14:23

Received:

10/14/2116:46 Matrix: Water



Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













Benzene

<0.30

ug/L

1.0

0.30

1



10/15/21 20:34

71-43-2



Bromobenzene

<0.36

ug/L

1.0

0.36

1



10/15/21 20:34

108-86-1



Bromochloromethane

<0.36

ug/L

5.0

0.36

1



10/15/21 20:34

74-97-5



Bromodichloromethane

<0.42

ug/L

1.0

0.42

1



10/15/21 20:34

75-27-4



Bromoform

<3.8

ug/L

5.0

3.8

1



10/15/21 20:34

75-25-2



Bromomethane

<1.2

ug/L

5.0

1.2

1



10/15/21 20:34

74-83-9



n-Butylbenzene

<0.86

ug/L

1.0

0.86

1



10/15/21 20:34

104-51-8



sec-Butylbenzene

<0.42

ug/L

1.0

0.42

1



10/15/21 20:34

135-98-8



tert-Butylbenzene

<0.59

ug/L

1.0

0.59

1



10/15/21 20:34

98-06-6



Carbon tetrachloride

<0.37

ug/L

1.0

0.37

1



10/15/21 20:34

56-23-5



Chlorobenzene

<0.86

ug/L

1.0

0.86

1



10/15/21 20:34

108-90-7



Chloroethane

<1.4

ug/L

5.0

1.4

1



10/15/21 20:34

75-00-3



Chloroform

<1.2

ug/L

5.0

1.2

1



10/15/21 20:34

67-66-3



Chloromethane

<1.6

ug/L

5.0

1.6

1



10/15/21 20:34

74-87-3



2-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21 20:34

95-49-8



4-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21 20:34

106-43-4



1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4

1



10/15/21 20:34

96-12-8



Dibromochloromethane

<2.6

ug/L

5.0

2.6

1



10/15/21 20:34

124-48-1



1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31

1



10/15/21 20:34

106-93-4



Dibromomethane

<0.99

ug/L

5.0

0.99

1



10/15/21 20:34

74-95-3



1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33

1



10/15/21 20:34

95-50-1



1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35

1



10/15/21 20:34

541 -73-1



1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89

1



10/15/21 20:34

106-46-7



Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46

1



10/15/21 20:34

75-71-8



1,1-Dichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21 20:34

75-34-3



1,2-Dichloroethane

<0.29

ug/L

1.0

0.29

1



10/15/21 20:34

107-06-2



1,1-Dichloroethene

<0.58

ug/L

1.0

0.58

1



10/15/21 20:34

75-35-4



cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47

1



10/15/21 20:34

156-59-2



trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53

1



10/15/21 20:34

156-60-5



1,2-Dichloropropane

<0.45

ug/L

1.0

0.45

1



10/15/21 20:34

78-87-5



1,3-Dichloropropane

<0.30

ug/L

1.0

0.30

1



10/15/21 20:34

142-28-9



REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 10 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-115A

Lab ID:

40235181004

Collected:

10/14/21

14:23

Received:

10/14/2116:46 Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













2,2-Dichloropropane

<4.2

ug/L

5.0

4.2

1



10/15/21

20:34

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41

1



10/15/21

20:34

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36

1



10/15/21

20:34

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5

1



10/15/21

20:34

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21

20:34

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33

1



10/15/21

20:34

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7

1



10/15/21

20:34

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0

1



10/15/21

20:34

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0

1



10/15/21

20:34

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32

1



10/15/21

20:34

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21

20:34

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1

1



10/15/21

20:34

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35

1



10/15/21

20:34

103-65-1

Styrene

<0.36

ug/L

1.0

0.36

1



10/15/21

20:34

100-42-5

1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1



10/15/21

20:34

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

1



10/15/21

20:34

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41

1



10/15/21

20:34

127-18-4

Toluene

<0.29

ug/L

1.0

0.29

1



10/15/21

20:34

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1



10/15/21

20:34

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1



10/15/21

20:34

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21

20:34

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

1



10/15/21

20:34

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32

1



10/15/21

20:34

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1



10/15/21

20:34

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1



10/15/21

20:34

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1



10/15/21

20:34

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

1



10/15/21

20:34

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17

1



10/15/21

20:34

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70

1



10/15/21

20:34

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35

1



10/15/21

20:34

95-47-6

Surrogates



















4-Bromofluorobenzene (S)

96

%

70-130



1



10/15/21

20:34

460-00-4

1,2-Dichlorobenzene-d4 (S)

100

%

70-130



1



10/15/21

20:34

2199-69-1

Toluene-d8 (S)

103

%

70-130



1



10/15/21

20:34

2037-26-5

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)













Pace Analytical Services -

Green Bay













Chromium, Hexavalent

<0.37

mg/L

1.2

0.37

50



10/15/21

10:11

D3

Date: 10/29/2021 02:47 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.	Page 11 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-116

Lab ID:

40235181005 Collected:

10/14/21

13:45

Received: 10/14/2116:46 Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

6010D MET ICP

Analytical Method:

EPA 6010D Preparation Method: EPA 301 OA









Pace Analytical Services - Green Bay













Iron

177

ug/L

100

56.7

1

10/20/21 07:29

10/20/21

23:09

7439-89-6

8260 MSV

Analytical Method:

EPA 8260















Pace Analytical Services - Green Bay













Benzene

<0.30

ug/L

1.0

0.30

1



10/15/21

20:54

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36

1



10/15/21

20:54

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36

1



10/15/21

20:54

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42

1



10/15/21

20:54

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8

1



10/15/21

20:54

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2

1



10/15/21

20:54

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86

1



10/15/21

20:54

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42

1



10/15/21

20:54

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59

1



10/15/21

20:54

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37

1



10/15/21

20:54

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86

1



10/15/21

20:54

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4

1



10/15/21

20:54

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2

1



10/15/21

20:54

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6

1



10/15/21

20:54

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21

20:54

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21

20:54

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4

1



10/15/21

20:54

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6

1



10/15/21

20:54

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31

1



10/15/21

20:54

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99

1



10/15/21

20:54

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33

1



10/15/21

20:54

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35

1



10/15/21

20:54

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89

1



10/15/21

20:54

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46

1



10/15/21

20:54

75-71-8

1,1-Dichloroethane

36.7

ug/L

1.0

0.30

1



10/15/21

20:54

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29

1



10/15/21

20:54

107-06-2

1,1-Dichloroethene

28.9

ug/L

1.0

0.58

1



10/15/21

20:54

75-35-4

cis-1,2-Dichloroethene

0.92J

ug/L

1.0

0.47

1



10/15/21

20:54

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53

1



10/15/21

20:54

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45

1



10/15/21

20:54

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30

1



10/15/21

20:54

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2

1



10/15/21

20:54

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41

1



10/15/21

20:54

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36

1



10/15/21

20:54

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5

1



10/15/21

20:54

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21

20:54

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33

1



10/15/21

20:54

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7

1



10/15/21

20:54

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0

1



10/15/21

20:54

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0

1



10/15/21

20:54

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32

1



10/15/21

20:54

75-09-2

Qual

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 12 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-116

Lab ID:

40235181005 Collected:

10/14/21

13:45

Received:

10/14/2116:46 Matrix: Water

Parameters

Results

Units LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services - Green Bay













Methyl-tert-butyl ether

<1.1

ug/L 5.0

1.1

1



10/15/21

20:54

1634-04-4

Naphthalene

<1.1

ug/L 5.0

1.1

1



10/15/21

20:54

91-20-3

n-Propylbenzene

<0.35

ug/L 1.0

0.35

1



10/15/21

20:54

103-65-1

Styrene

<0.36

ug/L 1.0

0.36

1



10/15/21

20:54

100-42-5

1,1,1,2-Tetrachloroethane

<0.36

ug/L 1.0

0.36

1



10/15/21

20:54

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L 1.0

0.38

1



10/15/21

20:54

79-34-5

Tetrachloroethene

1.2

ug/L 1.0

0.41

1



10/15/21

20:54

127-18-4

Toluene

<0.29

ug/L 1.0

0.29

1



10/15/21

20:54

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L 5.0

1.0

1



10/15/21

20:54

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L 5.0

0.95

1



10/15/21

20:54

120-82-1

1,1,1-Trichloroethane

118

ug/L 1.0

0.30

1



10/15/21

20:54

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L 5.0

0.34

1



10/15/21

20:54

79-00-5

Trichloroethene

2.2

ug/L 1.0

0.32

1



10/15/21

20:54

79-01-6

Trichlorofluoromethane

<0.42

ug/L 1.0

0.42

1



10/15/21

20:54

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L 5.0

0.56

1



10/15/21

20:54

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L 1.0

0.45

1



10/15/21

20:54

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L 1.0

0.36

1



10/15/21

20:54

108-67-8

Vinyl chloride

0.22J

ug/L 1.0

0.17

1



10/15/21

20:54

75-01-4

m&p-Xylene

<0.70

ug/L 2.0

0.70

1



10/15/21

20:54

179601-23-1

o-Xylene

<0.35

ug/L 1.0

0.35

1



10/15/21

20:54

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

94

% 70-130



1



10/15/21

20:54

460-00-4

1,2-Dichlorobenzene-d4 (S)

99

% 70-130



1



10/15/21

20:54

2199-69-1

Toluene-d8 (S)

103

% 70-130



1



10/15/21

20:54

2037-26-5

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)













Pace Analytical Services - Green Bay













Chromium, Hexavalent

7.1

mg/L 1.2

0.37

50



10/15/21

07:40



300.0 IC Anions

Analytical Method: EPA 300.0















Pace Analytical Services - Green Bay













Sulfate

1020

mg/L 100

22.2

50



10/29/21

11:51

14808-79-8

Sample: W-1

Lab ID:

40235181006 Collected:

10/14/21

10:41

Received:

10/14/2116:46 Matrix: Water

Parameters

Results

Units LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services - Green Bay













Benzene

<0.30

ug/L 1.0

0.30

1



10/15/21

21:13

71-43-2

Bromobenzene

<0.36

ug/L 1.0

0.36

1



10/15/21

21:13

108-86-1

Bromochloromethane

<0.36

ug/L 5.0

0.36

1



10/15/21

21:13

74-97-5

Bromodichloromethane

<0.42

ug/L 1.0

0.42

1



10/15/21

21:13

75-27-4

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 13 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: W-1

Lab ID:

40235181006

Collected:

10/14/21

10:41

Received:

10/14/21 16:46

Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













Bromoform

<3.8

ug/L

5.0

3.8

1



10/15/21 21

13

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2

1



10/15/21 21

13

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86

1



10/15/21 21

13

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42

1



10/15/21 21

13

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59

1



10/15/21 21

13

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37

1



10/15/21 21

13

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86

1



10/15/21 21

13

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4

1



10/15/21 21

13

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2

1



10/15/21 21

13

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6

1



10/15/21 21

13

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21 21

13

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21 21

13

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4

1



10/15/21 21

13

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6

1



10/15/21 21

13

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31

1



10/15/21 21

13

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99

1



10/15/21 21

13

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33

1



10/15/21 21

13

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35

1



10/15/21 21

13

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89

1



10/15/21 21

13

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46

1



10/15/21 21

13

75-71-8

1,1-Dichloroethane

1.1

ug/L

1.0

0.30

1



10/15/21 21

13

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29

1



10/15/21 21

13

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58

1



10/15/21 21

13

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47

1



10/15/21 21

13

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53

1



10/15/21 21

13

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45

1



10/15/21 21

13

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30

1



10/15/21 21

13

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2

1



10/15/21 21

13

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41

1



10/15/21 21

13

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36

1



10/15/21 21

13

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5

1



10/15/21 21

13

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21 21

13

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33

1



10/15/21 21

13

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7

1



10/15/21 21

13

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0

1



10/15/21 21

13

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0

1



10/15/21 21

13

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32

1



10/15/21 21

13

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21 21

13

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1

1



10/15/21 21

13

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35

1



10/15/21 21

13

103-65-1

Styrene

<0.36

ug/L

1.0

0.36

1



10/15/21 21

13

100-42-5

1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1



10/15/21 21

13

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

1



10/15/21 21

13

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41

1



10/15/21 21

13

127-18-4

Toluene

<0.29

ug/L

1.0

0.29

1



10/15/21 21

13

108-88-3

Qual

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 14 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: W-1

Lab ID:

40235181006

Collected:

10/14/21

10:41

Received:

10/14/21 16:46

Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1



10/15/21 21

13

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1



10/15/21 21

13

120-82-1

1,1,1-Trichloroethane

9.7

ug/L

1.0

0.30

1



10/15/21 21

13

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

1



10/15/21 21

13

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32

1



10/15/21 21

13

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1



10/15/21 21

13

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1



10/15/21 21

13

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1



10/15/21 21

13

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

1



10/15/21 21

13

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17

1



10/15/21 21

13

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70

1



10/15/21 21

13

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35

1



10/15/21 21

13

95-47-6

Surrogates



















4-Bromofluorobenzene (S)

95

%

70-130



1



10/15/21 21

13

460-00-4

1,2-Dichlorobenzene-d4 (S)

100

%

70-130



1



10/15/21 21

13

2199-69-1

Toluene-d8 (S)

102

%

70-130



1



10/15/21 21

13

2037-26-5

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)













Pace Analytical Services -

Green Bay













Chromium, Hexavalent

6.1

mg/L

0.61

0.18

25



10/15/21 07:40



Sample: W-1A

Lab ID:

40235181007

Collected:

10/14/21

10:11

Received:

10/14/21 16:46

Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

10/15/21

21

32

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

10/15/21

21

32

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

10/15/21

21

32

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

10/15/21

21

32

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

10/15/21

21

32

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

10/15/21

21

32

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

10/15/21

21

32

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

10/15/21

21

32

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

10/15/21

21

32

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

10/15/21

21

32

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

10/15/21

21

32

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

10/15/21

21

32

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

10/15/21

21

32

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

10/15/21

21

32

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

10/15/21

21

32

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

10/15/21

21

32

106-43-4

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 15 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: W-1A

Lab ID:

40235181007

Collected:

10/14/21

10:11

Received:

10/14/21 16:46

Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4

1



10/15/21 21

32

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6

1



10/15/21 21

32

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31

1



10/15/21 21

32

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99

1



10/15/21 21

32

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33

1



10/15/21 21

32

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35

1



10/15/21 21

32

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89

1



10/15/21 21

32

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46

1



10/15/21 21

32

75-71-8

1,1-Dichloroethane

2.0

ug/L

1.0

0.30

1



10/15/21 21

32

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29

1



10/15/21 21

32

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58

1



10/15/21 21

32

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47

1



10/15/21 21

32

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53

1



10/15/21 21

32

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45

1



10/15/21 21

32

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30

1



10/15/21 21

32

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2

1



10/15/21 21

32

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41

1



10/15/21 21

32

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36

1



10/15/21 21

32

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5

1



10/15/21 21

32

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21 21

32

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33

1



10/15/21 21

32

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7

1



10/15/21 21

32

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0

1



10/15/21 21

32

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0

1



10/15/21 21

32

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32

1



10/15/21 21

32

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21 21

32

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1

1



10/15/21 21

32

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35

1



10/15/21 21

32

103-65-1

Styrene

<0.36

ug/L

1.0

0.36

1



10/15/21 21

32

100-42-5

1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1



10/15/21 21

32

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

1



10/15/21 21

32

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41

1



10/15/21 21

32

127-18-4

Toluene

<0.29

ug/L

1.0

0.29

1



10/15/21 21

32

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1



10/15/21 21

32

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1



10/15/21 21

32

120-82-1

1,1,1-Trichloroethane

4.5

ug/L

1.0

0.30

1



10/15/21 21

32

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

1



10/15/21 21

32

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32

1



10/15/21 21

32

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1



10/15/21 21

32

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1



10/15/21 21

32

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1



10/15/21 21

32

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

1



10/15/21 21

32

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17

1



10/15/21 21

32

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70

1



10/15/21 21

32

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35

1



10/15/21 21

32

95-47-6

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 16 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: W-1A

Lab ID: 40235181007 Collected: 10/14/2110:11 Received: 10/14/2116:46 Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

8260 MSV
Surrogates

4-Bromofluorobenzene (S)
1,2-Dichlorobenzene-d4 (S)
Toluene-d8 (S)

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: EPA 8260
Pace Analytical Services - Green Bay

95 %
99 %
103 %

70-130
70-130
70-130

1

Analytical Method: SM 3500-Cr B (Online)

Pace Analytical Services - Green Bay

0.64 mg/L	0.24 0.073 10

10/15/21 21:32 460-00-4
10/15/21 21:32 2199-69-1
10/15/21 21:32 2037-26-5

10/15/21 07:40

Sample: MW-3R

Parameters

Lab ID: 40235181008 Collected: 10/14/21 09:59 Received: 10/14/2116:46 Matrix: Water

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

8260 MSV

Analytical Method: EPA 8260
Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

10/15/21

21

52

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

10/15/21

21

52

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

10/15/21

21

52

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

10/15/21

21

52

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

10/15/21

21

52

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

10/15/21

21

52

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

10/15/21

21

52

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

10/15/21

21

52

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

10/15/21

21

52

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

10/15/21

21

52

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

10/15/21

21

52

108-90-7

Chloroethane

1.7J

ug/L

5.0

1.4 1

10/15/21

21

52

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

10/15/21

21

52

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

10/15/21

21

52

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

10/15/21

21

52

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

10/15/21

21

52

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

10/15/21

21

52

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

10/15/21

21

52

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

10/15/21

21

52

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

10/15/21

21

52

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

10/15/21

21

52

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

10/15/21

21

52

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

10/15/21

21

52

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

10/15/21

21

52

75-71-8

1,1-Dichloroethane

4.6

ug/L

1.0

0.30 1

10/15/21

21

52

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

10/15/21

21

52

107-06-2

1,1-Dichloroethene

0.96J

ug/L

1.0

0.58 1

10/15/21

21

52

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

10/15/21

21

52

156-59-2

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 17 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-3R

Lab ID:

40235181008

Collected:

10/14/21 09:59

Received:

10/14/21 16:46

Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



10/15/21

21

52

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



10/15/21

21

52

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



10/15/21

21

52

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



10/15/21

21

52

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



10/15/21

21

52

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



10/15/21

21

52

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



10/15/21

21

52

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



10/15/21

21

52

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



10/15/21

21

52

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



10/15/21

21

52

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



10/15/21

21

52

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



10/15/21

21

52

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



10/15/21

21

52

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1



10/15/21

21

52

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1



10/15/21

21

52

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1



10/15/21

21

52

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1



10/15/21

21

52

100-42-5

1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



10/15/21

21

52

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



10/15/21

21

52

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



10/15/21

21

52

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



10/15/21

21

52

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



10/15/21

21

52

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



10/15/21

21

52

120-82-1

1,1,1-Trichloroethane

8.9

ug/L

1.0

0.30 1



10/15/21

21

52

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



10/15/21

21

52

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



10/15/21

21

52

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



10/15/21

21

52

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



10/15/21

21

52

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



10/15/21

21

52

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



10/15/21

21

52

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



10/15/21

21

52

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



10/15/21

21

52

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



10/15/21

21

52

95-47-6

Surrogates



















4-Bromofluorobenzene (S)

95

%

70-130

1



10/15/21

21

52

460-00-4

1,2-Dichlorobenzene-d4 (S)

101

%

70-130

1



10/15/21

21

52

2199-69-1

Toluene-d8 (S)

102

%

70-130

1



10/15/21

21

52

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)
Pace Analytical Services - Green Bay

<0.18 mg/L	0.61	0.1

8 25

10/15/21 10:12

D3,H5

Date: 10/29/2021 02:47 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 18 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-5

Lab ID:

40235181009

Collected:

10/14/21

11:54

Received:

10/14/21 16:46

Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













Benzene

<0.30

ug/L

1.0

0.30

1



10/15/21 22

11

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36

1



10/15/21 22

11

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36

1



10/15/21 22

11

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42

1



10/15/21 22

11

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8

1



10/15/21 22

11

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2

1



10/15/21 22

11

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86

1



10/15/21 22

11

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42

1



10/15/21 22

11

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59

1



10/15/21 22

11

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37

1



10/15/21 22

11

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86

1



10/15/21 22

11

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4

1



10/15/21 22

11

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2

1



10/15/21 22

11

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6

1



10/15/21 22

11

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21 22

11

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21 22

11

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4

1



10/15/21 22

11

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6

1



10/15/21 22

11

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31

1



10/15/21 22

11

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99

1



10/15/21 22

11

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33

1



10/15/21 22

11

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35

1



10/15/21 22

11

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89

1



10/15/21 22

11

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46

1



10/15/21 22

11

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21 22

11

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29

1



10/15/21 22

11

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58

1



10/15/21 22

11

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47

1



10/15/21 22

11

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53

1



10/15/21 22

11

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45

1



10/15/21 22

11

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30

1



10/15/21 22

11

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2

1



10/15/21 22

11

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41

1



10/15/21 22

11

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36

1



10/15/21 22

11

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5

1



10/15/21 22

11

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21 22

11

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33

1



10/15/21 22

11

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7

1



10/15/21 22

11

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0

1



10/15/21 22

11

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0

1



10/15/21 22

11

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32

1



10/15/21 22

11

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21 22

11

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1

1



10/15/21 22

11

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35

1



10/15/21 22

11

103-65-1

Styrene

<0.36

ug/L

1.0

0.36

1



10/15/21 22

11

100-42-5

Qual

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 19 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-5

Lab ID:

40235181009

Collected:

10/14/21

11:54

Received:

10/14/21 16:46

Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1



10/15/21 22

11

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

1



10/15/21 22

11

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41

1



10/15/21 22

11

127-18-4

Toluene

<0.29

ug/L

1.0

0.29

1



10/15/21 22

11

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1



10/15/21 22

11

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1



10/15/21 22

11

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21 22

11

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

1



10/15/21 22

11

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32

1



10/15/21 22

11

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1



10/15/21 22

11

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1



10/15/21 22

11

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1



10/15/21 22

11

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

1



10/15/21 22

11

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17

1



10/15/21 22

11

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70

1



10/15/21 22

11

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35

1



10/15/21 22

11

95-47-6

Surrogates



















4-Bromofluorobenzene (S)

96

%

70-130



1



10/15/21 22

11

460-00-4

1,2-Dichlorobenzene-d4 (S)

100

%

70-130



1



10/15/21 22

11

2199-69-1

Toluene-d8 (S)

103

%

70-130



1



10/15/21 22

11

2037-26-5

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)













Pace Analytical Services -

Green Bay













Chromium, Hexavalent

<0.073

mg/L

0.24

0.073

10



10/15/21 07:40

D3

Sample: MW-5A

Lab ID:

40235181010

Collected:

10/14/21

13:07

Received:

10/14/21 16:46

Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)













Pace Analytical Services -

Green Bay













Chromium, Hexavalent

<1.8

mg/L

6.1

1.8

250



10/15/21 10:12

D3

Sample: MW-6

Lab ID:

40235181011

Collected:

10/14/21

10:55

Received:

10/14/21 16:46

Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













Benzene

<0.30

ug/L

1.0

0.30

1



10/15/21 22:31

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36

1



10/15/21 22:31

108-86-1

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 20 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-6

Lab ID:

40235181011

Collected:

10/14/21

10:55

Received:

10/14/2116:46 Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













Bromochloromethane

<0.36

ug/L

5.0

0.36

1



10/15/21

22:31

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42

1



10/15/21

22:31

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8

1



10/15/21

22:31

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2

1



10/15/21

22:31

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86

1



10/15/21

22:31

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42

1



10/15/21

22:31

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59

1



10/15/21

22:31

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37

1



10/15/21

22:31

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86

1



10/15/21

22:31

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4

1



10/15/21

22:31

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2

1



10/15/21

22:31

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6

1



10/15/21

22:31

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21

22:31

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21

22:31

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4

1



10/15/21

22:31

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6

1



10/15/21

22:31

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31

1



10/15/21

22:31

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99

1



10/15/21

22:31

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33

1



10/15/21

22:31

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35

1



10/15/21

22:31

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89

1



10/15/21

22:31

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46

1



10/15/21

22:31

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21

22:31

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29

1



10/15/21

22:31

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58

1



10/15/21

22:31

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47

1



10/15/21

22:31

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53

1



10/15/21

22:31

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45

1



10/15/21

22:31

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30

1



10/15/21

22:31

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2

1



10/15/21

22:31

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41

1



10/15/21

22:31

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36

1



10/15/21

22:31

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5

1



10/15/21

22:31

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21

22:31

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33

1



10/15/21

22:31

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7

1



10/15/21

22:31

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0

1



10/15/21

22:31

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0

1



10/15/21

22:31

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32

1



10/15/21

22:31

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21

22:31

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1

1



10/15/21

22:31

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35

1



10/15/21

22:31

103-65-1

Styrene

<0.36

ug/L

1.0

0.36

1



10/15/21

22:31

100-42-5

1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1



10/15/21

22:31

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

1



10/15/21

22:31

79-34-5

Qual

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.	Page 21 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-6

Lab ID:

40235181011

Collected:

10/14/21

10:55

Received:

10/14/2116:46 Matrix: Water



Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

8260 MSV

Analytical Method: EPA 8260

















Pace Analytical Services -

Green Bay















Tetrachloroethene

<0.41

ug/L

1.0

0.41

1



10/15/21

22:31

127-18-4



Toluene

<0.29

ug/L

1.0

0.29

1



10/15/21

22:31

108-88-3



1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1



10/15/21

22:31

87-61-6



1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1



10/15/21

22:31

120-82-1



1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21

22:31

71-55-6



1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

1



10/15/21

22:31

79-00-5



Trichloroethene

<0.32

ug/L

1.0

0.32

1



10/15/21

22:31

79-01-6



Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1



10/15/21

22:31

75-69-4



1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1



10/15/21

22:31

96-18-4



1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1



10/15/21

22:31

95-63-6



1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

1



10/15/21

22:31

108-67-8



Vinyl chloride

<0.17

ug/L

1.0

0.17

1



10/15/21

22:31

75-01-4



m&p-Xylene

<0.70

ug/L

2.0

0.70

1



10/15/21

22:31

179601-23-1



o-Xylene

<0.35

ug/L

1.0

0.35

1



10/15/21

22:31

95-47-6



Surrogates





















4-Bromofluorobenzene (S)

96

%

70-130



1



10/15/21

22:31

460-00-4



1,2-Dichlorobenzene-d4 (S)

101

%

70-130



1



10/15/21

22:31

2199-69-1



Toluene-d8 (S)

103

%

70-130



1



10/15/21

22:31

2037-26-5



Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)















Pace Analytical Services -

Green Bay















Chromium, Hexavalent

1.4

mg/L

0.24

0.073

10



10/15/21

07:40





Sample: MW-6A

Lab ID:

40235181012

Collected:

10/14/21 09:05

Received:

10/14/2116:46 Matrix: Water



Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)















Pace Analytical Services -

Green Bay















Chromium, Hexavalent

<0.073

mg/L

0.24

0.073

10



10/15/21 07:41



D3

Sample: MW-9

Lab ID:

40235181013

Collected:

10/14/21 08:52

Received:

10/14/2116:46 Matrix: Water



Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

8260 MSV

Analytical Method: EPA 8260

















Pace Analytical Services -

Green Bay















Benzene

<0.30

ug/L

1.0

0.30

1



10/15/21

22:50

71-43-2



Bromobenzene

<0.36

ug/L

1.0

0.36

1



10/15/21

22:50

108-86-1



Bromochloromethane

<0.36

ug/L

5.0

0.36

1



10/15/21

22:50

74-97-5



Bromodichloromethane

<0.42

ug/L

1.0

0.42

1



10/15/21

22:50

75-27-4



REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 22 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-9

Lab ID:

40235181013

Collected:

10/14/21 08:52

Received:

10/14/2116:46 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











Bromoform

<3.8

ug/L

5.0

3.8 1



10/15/21

22:50

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



10/15/21

22:50

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



10/15/21

22:50

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



10/15/21

22:50

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



10/15/21

22:50

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



10/15/21

22:50

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



10/15/21

22:50

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



10/15/21

22:50

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



10/15/21

22:50

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



10/15/21

22:50

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



10/15/21

22:50

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



10/15/21

22:50

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



10/15/21

22:50

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



10/15/21

22:50

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



10/15/21

22:50

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



10/15/21

22:50

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



10/15/21

22:50

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



10/15/21

22:50

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



10/15/21

22:50

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



10/15/21

22:50

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1



10/15/21

22:50

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



10/15/21

22:50

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1



10/15/21

22:50

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1



10/15/21

22:50

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



10/15/21

22:50

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



10/15/21

22:50

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



10/15/21

22:50

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



10/15/21

22:50

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



10/15/21

22:50

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



10/15/21

22:50

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



10/15/21

22:50

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



10/15/21

22:50

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



10/15/21

22:50

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



10/15/21

22:50

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



10/15/21

22:50

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



10/15/21

22:50

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



10/15/21

22:50

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1



10/15/21

22:50

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1



10/15/21

22:50

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1



10/15/21

22:50

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1



10/15/21

22:50

100-42-5

1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



10/15/21

22:50

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



10/15/21

22:50

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



10/15/21

22:50

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



10/15/21

22:50

108-88-3

Qual

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 23 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-9

Lab ID:

40235181013

Collected:

10/14/21 08:52

Received:

10/14/2116:46 Matrix: Water



Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

8260 MSV

Analytical Method: EPA 8260

















Pace Analytical Services -

Green Bay















1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1



10/15/21

22:50

87-61-6



1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1



10/15/21

22:50

120-82-1



1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21

22:50

71-55-6



1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

1



10/15/21

22:50

79-00-5



Trichloroethene

<0.32

ug/L

1.0

0.32

1



10/15/21

22:50

79-01-6



Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1



10/15/21

22:50

75-69-4



1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1



10/15/21

22:50

96-18-4



1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1



10/15/21

22:50

95-63-6



1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

1



10/15/21

22:50

108-67-8



Vinyl chloride

<0.17

ug/L

1.0

0.17

1



10/15/21

22:50

75-01-4



m&p-Xylene

<0.70

ug/L

2.0

0.70

1



10/15/21

22:50

179601-23-1



o-Xylene

<0.35

ug/L

1.0

0.35

1



10/15/21

22:50

95-47-6



Surrogates





















4-Bromofluorobenzene (S)

95

%

70-130



1



10/15/21

22:50

460-00-4



1,2-Dichlorobenzene-d4 (S)

100

%

70-130



1



10/15/21

22:50

2199-69-1



Toluene-d8 (S)

103

%

70-130



1



10/15/21

22:50

2037-26-5



Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)















Pace Analytical Services -

Green Bay















Chromium, Hexavalent

<0.73

mg/L

2.4

0.73

100



10/15/21

10:12



D3,H5

Sample: MW-10

Lab ID:

40235181014

Collected:

10/14/21

10:05

Received:

10/14/2116:46 Matrix: Water



Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

10/15/21

23

10

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

10/15/21

23

10

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

10/15/21

23

10

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

10/15/21

23

10

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

10/15/21

23

10

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

10/15/21

23

10

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

10/15/21

23

10

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

10/15/21

23

10

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

10/15/21

23

10

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

10/15/21

23

10

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

10/15/21

23

10

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

10/15/21

23

10

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

10/15/21

23

10

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

10/15/21

23

10

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

10/15/21

23

10

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

10/15/21

23

10

106-43-4

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 24 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-10

Lab ID:

40235181014

Collected:

10/14/21

10:05

Received:

10/14/21 16:46

Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4

1



10/15/21 23

10

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6

1



10/15/21 23

10

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31

1



10/15/21 23

10

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99

1



10/15/21 23

10

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33

1



10/15/21 23

10

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35

1



10/15/21 23

10

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89

1



10/15/21 23

10

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46

1



10/15/21 23

10

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21 23

10

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29

1



10/15/21 23

10

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58

1



10/15/21 23

10

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47

1



10/15/21 23

10

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53

1



10/15/21 23

10

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45

1



10/15/21 23

10

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30

1



10/15/21 23

10

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2

1



10/15/21 23

10

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41

1



10/15/21 23

10

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36

1



10/15/21 23

10

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5

1



10/15/21 23

10

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21 23

10

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33

1



10/15/21 23

10

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7

1



10/15/21 23

10

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0

1



10/15/21 23

10

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0

1



10/15/21 23

10

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32

1



10/15/21 23

10

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

1



10/15/21 23

10

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1

1



10/15/21 23

10

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35

1



10/15/21 23

10

103-65-1

Styrene

<0.36

ug/L

1.0

0.36

1



10/15/21 23

10

100-42-5

1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1



10/15/21 23

10

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

1



10/15/21 23

10

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41

1



10/15/21 23

10

127-18-4

Toluene

<0.29

ug/L

1.0

0.29

1



10/15/21 23

10

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1



10/15/21 23

10

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1



10/15/21 23

10

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30

1



10/15/21 23

10

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

1



10/15/21 23

10

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32

1



10/15/21 23

10

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1



10/15/21 23

10

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1



10/15/21 23

10

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1



10/15/21 23

10

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

1



10/15/21 23

10

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17

1



10/15/21 23

10

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70

1



10/15/21 23

10

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35

1



10/15/21 23

10

95-47-6

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 25 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: MW-10

Lab ID:

40235181014

Collected:

10/14/21

10:05

Received:

10/14/2116:46 Matrix: Water



Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













Surrogates



















4-Bromofluorobenzene (S)

97

%

70-130



1



10/15/21 23:10

460-00-4



1,2-Dichlorobenzene-d4 (S)

101

%

70-130



1



10/15/21 23:10

2199-69-1



Toluene-d8 (S)

102

%

70-130



1



10/15/21 23:10

2037-26-5



Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)













Pace Analytical Services -

Green Bay













Chromium, Hexavalent

<0.18

mg/L

0.61

0.18

25



10/15/21 07:41



D3

Sample: ZINC SUMP

Lab ID:

40235181015

Collected:

10/14/21

12:17

Received:

10/14/2116:46 Matrix: Water



Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

8260 MSV

Analytical Method: EPA 8260















Pace Analytical Services -

Green Bay













Benzene

<0.30

ug/L

1.0

0.30

1



10/15/21 23:29

71-43-2



Bromobenzene

<0.36

ug/L

1.0

0.36

1



10/15/21 23:29

108-86-1



Bromochloromethane

<0.36

ug/L

5.0

0.36

1



10/15/21 23:29

74-97-5



Bromodichloromethane

<0.42

ug/L

1.0

0.42

1



10/15/21 23:29

75-27-4



Bromoform

<3.8

ug/L

5.0

3.8

1



10/15/21 23:29

75-25-2



Bromomethane

<1.2

ug/L

5.0

1.2

1



10/15/21 23:29

74-83-9



n-Butylbenzene

<0.86

ug/L

1.0

0.86

1



10/15/21 23:29

104-51-8



sec-Butylbenzene

<0.42

ug/L

1.0

0.42

1



10/15/21 23:29

135-98-8



tert-Butylbenzene

<0.59

ug/L

1.0

0.59

1



10/15/21 23:29

98-06-6



Carbon tetrachloride

<0.37

ug/L

1.0

0.37

1



10/15/21 23:29

56-23-5



Chlorobenzene

<0.86

ug/L

1.0

0.86

1



10/15/21 23:29

108-90-7



Chloroethane

<1.4

ug/L

5.0

1.4

1



10/15/21 23:29

75-00-3



Chloroform

<1.2

ug/L

5.0

1.2

1



10/15/21 23:29

67-66-3



Chloromethane

<1.6

ug/L

5.0

1.6

1



10/15/21 23:29

74-87-3



2-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21 23:29

95-49-8



4-Chlorotoluene

<0.89

ug/L

5.0

0.89

1



10/15/21 23:29

106-43-4



1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4

1



10/15/21 23:29

96-12-8



Dibromochloromethane

<2.6

ug/L

5.0

2.6

1



10/15/21 23:29

124-48-1



1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31

1



10/15/21 23:29

106-93-4



Dibromomethane

<0.99

ug/L

5.0

0.99

1



10/15/21 23:29

74-95-3



1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33

1



10/15/21 23:29

95-50-1



1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35

1



10/15/21 23:29

541 -73-1



1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89

1



10/15/21 23:29

106-46-7



Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46

1



10/15/21 23:29

75-71-8



1,1-Dichloroethane

1.5

ug/L

1.0

0.30

1



10/15/21 23:29

75-34-3



1,2-Dichloroethane

<0.29

ug/L

1.0

0.29

1



10/15/21 23:29

107-06-2



1,1-Dichloroethene

0.81J

ug/L

1.0

0.58

1



10/15/21 23:29

75-35-4



cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47

1



10/15/21 23:29

156-59-2



REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 26 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: ZINC SUMP

Lab ID: 40235181015 Collected: 10/14/2112:17 Received: 10/14/2116:46 Matrix: Water

Parameters

Results

Units

LOQ

LOD

8260 MSV

Analytical Method: EPA 8260





Pace Analytical Services -

Green Bay



trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5

Diisopropyl ether

<1.1

ug/L

5.0

1.1

Ethylbenzene

<0.33

ug/L

1.0

0.33

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0

Methylene Chloride

<0.32

ug/L

5.0

0.32

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

Naphthalene

<1.1

ug/L

5.0

1.1

n-Propylbenzene

<0.35

ug/L

1.0

0.35

Styrene

<0.36

ug/L

1.0

0.36

1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

Tetrachloroethene

0.75J

ug/L

1.0

0.41

Toluene

<0.29

ug/L

1.0

0.29

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1,1,1-Trichloroethane

15.7

ug/L

1.0

0.30

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

Trichloroethene

<0.32

ug/L

1.0

0.32

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

Vinyl chloride

<0.17

ug/L

1.0

0.17

m&p-Xylene

<0.70

ug/L

2.0

0.70

o-Xylene

<0.35

ug/L

1.0

0.35

Surrogates









4-Bromofluorobenzene (S)

95

%

70-130



1,2-Dichlorobenzene-d4 (S)

101

%

70-130



Toluene-d8 (S)

103

%

70-130



Chromium, Hexavalent

Analytical Method: SM 3500-Cr B (Online)



Pace Analytical Services -

Green Bay



Chromium, Hexavalent

6.5

mg/L

1.2

0.37

DF

Prepared

Analyzed

CAS No.

Qual

50

10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21
10/15/21

23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29
23:29

156-60-5

78-87-5

142-28-9
594-20-7
563-58-6
10061 -01 -5
10061 -02-6
108-20-3
100-41-4
87-68-3

98-82-8

99-87-6
75-09-2

1634-04-4
91-20-3
103-65-1

100-42-5
630-20-6

79-34-5
127-18-4
108-88-3
87-61-6

120-82-1

71-55-6

79-00-5

79-01-6

75-69-4

96-18-4

95-63-6

108-67-8

75-01-4

179601-23-1

95-47-6

10/15/21 23:29 460-00-4
10/15/21 23:29 2199-69-1
10/15/21 23:29 2037-26-5

10/15/21 07:41

335.4 Cyanide, Total

Cyanide

Analytical Method: EPA 335.4 Preparation Method: EPA 335.4
Pace Analytical Services - Green Bay

0.089J mg/L	0.14 0.041 1 10/21/21 10:35 10/21/21 14:20 57-12-5

D3

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 27 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: TRIP BLANK

Lab ID:

40235181016

Collected:

10/14/21 00:00

Received:

10/14/2116:46 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











Benzene

<0.30

ug/L

1.0

0.30 1



10/15/21

17:20

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1



10/15/21

17:20

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1



10/15/21

17:20

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1



10/15/21

17:20

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1



10/15/21

17:20

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



10/15/21

17:20

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



10/15/21

17:20

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



10/15/21

17:20

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



10/15/21

17:20

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



10/15/21

17:20

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



10/15/21

17:20

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



10/15/21

17:20

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



10/15/21

17:20

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



10/15/21

17:20

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



10/15/21

17:20

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



10/15/21

17:20

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



10/15/21

17:20

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



10/15/21

17:20

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



10/15/21

17:20

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



10/15/21

17:20

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



10/15/21

17:20

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



10/15/21

17:20

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



10/15/21

17:20

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



10/15/21

17:20

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1



10/15/21

17:20

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



10/15/21

17:20

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1



10/15/21

17:20

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1



10/15/21

17:20

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



10/15/21

17:20

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



10/15/21

17:20

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



10/15/21

17:20

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



10/15/21

17:20

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



10/15/21

17:20

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



10/15/21

17:20

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



10/15/21

17:20

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



10/15/21

17:20

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



10/15/21

17:20

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



10/15/21

17:20

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



10/15/21

17:20

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



10/15/21

17:20

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



10/15/21

17:20

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1



10/15/21

17:20

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1



10/15/21

17:20

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1



10/15/21

17:20

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1



10/15/21

17:20

100-42-5

Qual

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 28 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Sample: TRIP BLANK

Lab ID:

40235181016

Collected:

10/14/21 00:00

Received:

10/14/2116:46 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



10/15/21

17:20

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



10/15/21

17:20

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



10/15/21

17:20

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



10/15/21

17:20

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



10/15/21

17:20

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



10/15/21

17:20

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



10/15/21

17:20

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



10/15/21

17:20

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



10/15/21

17:20

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



10/15/21

17:20

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



10/15/21

17:20

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



10/15/21

17:20

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



10/15/21

17:20

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



10/15/21

17:20

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



10/15/21

17:20

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



10/15/21

17:20

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

98

%

70-130

1



10/15/21

17:20

460-00-4

1,2-Dichlorobenzene-d4 (S)

100

%

70-130

1



10/15/21

17:20

2199-69-1

Toluene-d8 (S)

103

%

70-130

1



10/15/21

17:20

2037-26-5

Date: 10/29/2021 02:47 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 29 of 43

-------
ice Analytical'

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302

www.pacrtiln.cont	(920)469-2436

QUALITY CONTROL DATA

Project:	3001438 BETTER BRITE

Pace Project No.: 40235181

QC Batch:	399059

QC Batch Method: EPA 301 OA

Associated Lab Samples: 40235181003, 40235181005

Analysis Method:	EPA6010D

Analysis Description: 6010D MET

Laboratory:	Pace Analytical Services - Green Bay

METHOD BLANK: 2304150	Matrix: Water

Associated Lab Samples: 40235181003, 40235181005

Blank	Reporting

Parameter	Units	Result	Limit	Analyzed	Qualifiers

Iron	ug/L	<56.7	100 10/21/21 08:42

LABORATORY CONTROL SAMPLE: 2304151

Spike	LCS	LCS	% Rec

Parameter	Units	Cone.	Result	% Rec	Limits	Qualifiers

Iron	ug/L	10000	10100	101	80-120

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2304152

MS	MSD

40235264001 Spike	Spike

Parameter Units Result Cone.	Cone.

Iron ug/L 19800 10000	10000

2304153

MS	MSD	MS MSD	% Rec	Max

Result	Result	% Rec % Rec	Limits	RPD RPD Qual

29700	29400	99 97	75-125	1 20

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 30 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

QC Batch:	398659	Analysis Method:	EPA 8260

QC Batch Method: EPA 8260	Analysis Description: 8260 MSV

Laboratory:	Pace Analytical Services - Green Bay

40235181001, 40235181002, 40235181003, 40235181004, 40235181005, 40235181006, 40235181007,
40235181008, 40235181009, 40235181011, 40235181013, 40235181014, 40235181015, 40235181016

Associated Lab Samples:

METHOD BLANK: 2301599
Associated Lab Samples:

40235181001, 40235181002,
40235181008, 40235181009,

Matrix: Water

40235181003, 40235181004,
40235181011, 40235181013,

Blank

Reporting

Parameter

Units

Result

Limit

Analyzed

1,1,1,2-Tetrachloroethane

ug/L

<0.36

1.0

10/15/21 15:43

1,1,1-Trichloroethane

ug/L

<0.30

1.0

10/15/21 15:43

1,1,2,2-Tetrachloroethane

ug/L

<0.38

1.0

10/15/21 15:43

1,1,2-Trichloroethane

ug/L

<0.34

5.0

10/15/21 15:43

1,1-Dichloroethane

ug/L

<0.30

1.0

10/15/21 15:43

1,1-Dichloroethene

ug/L

<0.58

1.0

10/15/21 15:43

1,1-Dichloropropene

ug/L

<0.41

1.0

10/15/21 15:43

1,2,3-Trichlorobenzene

ug/L

<1.0

5.0

10/15/21 15:43

1,2,3-Trichloropropane

ug/L

<0.56

5.0

10/15/21 15:43

1,2,4-Trichlorobenzene

ug/L

<0.95

5.0

10/15/21 15:43

1,2,4-Trimethylbenzene

ug/L

<0.45

1.0

10/15/21 15:43

1,2-Dibromo-3-chloropropane

ug/L

<2.4

5.0

10/15/21 15:43

1,2-Dibromoethane (EDB)

ug/L

<0.31

1.0

10/15/21 15:43

1,2-Dichlorobenzene

ug/L

<0.33

1.0

10/15/21 15:43

1,2-Dichloroethane

ug/L

<0.29

1.0

10/15/21 15:43

1,2-Dichloropropane

ug/L

<0.45

1.0

10/15/21 15:43

1,3,5-Trimethylbenzene

ug/L

<0.36

1.0

10/15/21 15:43

1,3-Dichlorobenzene

ug/L

<0.35

1.0

10/15/21 15:43

1,3-Dichloropropane

ug/L

<0.30

1.0

10/15/21 15:43

1,4-Dichlorobenzene

ug/L

<0.89

1.0

10/15/21 15:43

2,2-Dichloropropane

ug/L

<4.2

5.0

10/15/21 15:43

2-Chlorotoluene

ug/L

<0.89

5.0

10/15/21 15:43

4-Chlorotoluene

ug/L

<0.89

5.0

10/15/21 15:43

Benzene

ug/L

<0.30

1.0

10/15/21 15:43

Bromobenzene

ug/L

<0.36

1.0

10/15/21 15:43

Bromochloromethane

ug/L

<0.36

5.0

10/15/21 15:43

Bromodichloromethane

ug/L

<0.42

1.0

10/15/21 15:43

Bromoform

ug/L

<3.8

5.0

10/15/21 15:43

Bromomethane

ug/L

<1.2

5.0

10/15/21 15:43

Carbon tetrachloride

ug/L

<0.37

1.0

10/15/21 15:43

Chlorobenzene

ug/L

<0.86

1.0

10/15/21 15:43

Chloroethane

ug/L

<1.4

5.0

10/15/21 15:43

Chloroform

ug/L

<1.2

5.0

10/15/21 15:43

Chloromethane

ug/L

<1.6

5.0

10/15/21 15:43

cis-1,2-Dichloroethene

ug/L

<0.47

1.0

10/15/21 15:43

cis-1,3-Dichloropropene

ug/L

<0.36

1.0

10/15/21 15:43

Dibromochloromethane

ug/L

<2.6

5.0

10/15/21 15:43

Dibromomethane

ug/L

<0.99

5.0

10/15/21 15:43

Dichlorodifluoromethane

ug/L

<0.46

5.0

10/15/21 15:43

40235181005, 40235181006, 40235181007,
40235181014, 40235181015, 40235181016

Qualifiers

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 31 of 43

-------
ice Analytical'

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302

www.pacrtiln.cont	(920)469-2436

QUALITY CONTROL DATA

Project:	3001438 BETTER BRITE

Pace Project No.: 40235181

METHOD BLANK: 2301599	Matrix: Water

Associated Lab Samples: 40235181001, 40235181002, 40235181003, 40235181004, 40235181005, 40235181006, 40235181007,
40235181008, 40235181009, 40235181011, 40235181013, 40235181014, 40235181015, 40235181016

Blank	Reporting

Parameter	Units	Result	Limit	Analyzed	Qualifiers

Diisopropyl ether

ug/L

<1.1

5.0

10/15/21 15:43

Ethylbenzene

ug/L

<0.33

1.0

10/15/21 15:43

Hexachloro-1,3-butadiene

ug/L

<2.7

5.0

10/15/21 15:43

Isopropylbenzene (Cumene)

ug/L

<1.0

5.0

10/15/21 15:43

m&p-Xylene

ug/L

<0.70

2.0

10/15/21 15:43

Methyl-tert-butyl ether

ug/L

<1.1

5.0

10/15/21 15:43

Methylene Chloride

ug/L

<0.32

5.0

10/15/21 15:43

n-Butylbenzene

ug/L

<0.86

1.0

10/15/21 15:43

n-Propylbenzene

ug/L

<0.35

1.0

10/15/21 15:43

Naphthalene

ug/L

<1.1

5.0

10/15/21 15:43

o-Xylene

ug/L

<0.35

1.0

10/15/21 15:43

p-lsopropyltoluene

ug/L

<1.0

5.0

10/15/21 15:43

sec-Butylbenzene

ug/L

<0.42

1.0

10/15/21 15:43

Styrene

ug/L

<0.36

1.0

10/15/21 15:43

tert-Butylbenzene

ug/L

<0.59

1.0

10/15/21 15:43

Tetrachloroethene

ug/L

<0.41

1.0

10/15/21 15:43

Toluene

ug/L

<0.29

1.0

10/15/21 15:43

trans-1,2-Dichloroethene

ug/L

<0.53

1.0

10/15/21 15:43

trans-1,3-Dichloropropene

ug/L

<3.5

5.0

10/15/21 15:43

Trichloroethene

ug/L

<0.32

1.0

10/15/21 15:43

Trichlorofluoromethane

ug/L

<0.42

1.0

10/15/21 15:43

Vinyl chloride

ug/L

<0.17

1.0

10/15/21 15:43

1,2-Dichlorobenzene-d4 (S)

%

98

70-130

10/15/21 15:43

4-Bromofluorobenzene (S)

%

97

70-130

10/15/21 15:43

Toluene-d8 (S)

%

103

70-130

10/15/21 15:43

LABORATORY CONTROL SAMPLE: 2301600

Spike

LCS

LCS

% Rec

Parameter

Units

Cone.

Result

% Rec

Limits

1,1,1-Trichloroethane

ug/L

50

52.2

104

70-130

1,1,2,2-Tetrachloroethane

ug/L

50

56.4

113

66-130

1,1,2-Trichloroethane

ug/L

50

56.9

114

70-130

1,1-Dichloroethane

ug/L

50

60.3

121

68-132

1,1-Dichloroethene

ug/L

50

50.7

101

85-126

1,2,4-Trichlorobenzene

ug/L

50

50.5

101

70-130

1,2-Dibromo-3-chloropropane

ug/L

50

47.6

95

51-126

1,2-Dibromoethane (EDB)

ug/L

50

55.3

111

70-130

1,2-Dichlorobenzene

ug/L

50

56.6

113

70-130

1,2-Dichloroethane

ug/L

50

53.2

106

70-130

1,2-Dichloropropane

ug/L

50

59.6

119

78-125

1,3-Dichlorobenzene

ug/L

50

56.4

113

70-130

1,4-Dichlorobenzene

ug/L

50

57.1

114

70-130

Benzene

ug/L

50

55.4

111

70-132

Qualifiers

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 32 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:	3001438 BETTER BRITE

Pace Project No.: 40235181

LABORATORY CONTROL SAMPLE:

2301600













Spike

LCS

LCS

% Rec

Parameter

Units

Cone.

Result

% Rec

Limits

Bromodichloromethane

ug/L

50

53.0

106

70-130

Bromoform

ug/L

50

43.8

88

65-130

Bromomethane

ug/L

50

29.3

59

44-128

Carbon tetrachloride

ug/L

50

53.2

106

70-130

Chlorobenzene

ug/L

50

58.6

117

70-130

Chloroethane

ug/L

50

57.9

116

73-137

Chloroform

ug/L

50

55.8

112

80-122

Chloromethane

ug/L

50

43.1

86

27-148

cis-1,2-Dichloroethene

ug/L

50

52.4

105

70-130

cis-1,3-Dichloropropene

ug/L

50

49.7

99

70-130

Dibromochloromethane

ug/L

50

51.8

104

70-130

Dichlorodifluoromethane

ug/L

50

31.3

63

22-151

Ethylbenzene

ug/L

50

57.3

115

80-123

Isopropylbenzene (Cumene)

ug/L

50

59.4

119

70-130

m&p-Xylene

ug/L

100

115

115

70-130

Methyl-tert-butyl ether

ug/L

50

47.7

95

66-130

Methylene Chloride

ug/L

50

48.8

98

70-130

o-Xylene

ug/L

50

57.8

116

70-130

Styrene

ug/L

50

59.5

119

70-130

Tetrachloroethene

ug/L

50

55.0

110

70-130

Toluene

ug/L

50

56.4

113

80-121

trans-1,2-Dichloroethene

ug/L

50

53.1

106

70-130

trans-1,3-Dichloropropene

ug/L

50

50.3

101

58-125

Trichloroethene

ug/L

50

53.8

108

70-130

Trichlorofluoromethane

ug/L

50

47.0

94

84-148

Vinyl chloride

ug/L

50

50.2

100

63-142

1,2-Dichlorobenzene-d4 (S)

%





97

70-130

4-Bromofluorobenzene (S)

%





98

70-130

Toluene-d8 (S)

%





104

70-130

Qualifiers

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2302607	2302608

Parameter

Units

40235139001
Result

MS
Spike
Cone.

MSD
Spike
Cone.

MS
Result

MSD
Result

MS
% Rec

MSD
% Rec

% Rec
Limits

RPD

Max
RPD

1,1,1-Trichloroethane

ug/L

<0.30

50

50

52.0

53.0

104

106

70-130

2

20

1,1,2,2-Tetrachloroethane

ug/L

<0.38

50

50

56.3

55.3

113

111

66-130

2

20

1,1,2-Trichloroethane

ug/L

<0.34

50

50

57.4

55.7

115

111

70-130

3

20

1,1-Dichloroethane

ug/L

8.5

50

50

68.5

68.6

120

120

68-132

0

20

1,1-Dichloroethene

ug/L

<0.58

50

50

49.9

49.7

100

99

76-132

0

20

1,2,4-Trichlorobenzene

ug/L

<0.95

50

50

52.7

52.4

105

105

70-130

1

20

1,2-Dibromo-3-

ug/L

<2.4

50

50

48.0

47.9

96

96

51-126

0

20

chloropropane





















1,2-Dibromoethane (EDB)

ug/L

<0.31

50

50

55.2

54.4

110

109

70-130

2

20

1,2-Dichlorobenzene

ug/L

<0.33

50

50

56.0

57.0

112

114

70-130

2

20

1,2-Dichloroethane

ug/L

<0.29

50

50

52.6

58.8

105

118

70-130

11

20

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 33 of 43

-------
ice Analytical'

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302

www.pacrtiln.cont	(920)469-2436

QUALITY CONTROL DATA

Project:	3001438 BETTER BRITE

Pace Project No.: 40235181

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2302607	2302608

Parameter

Units

40235139001
Result

MS
Spike
Cone.

MSD
Spike
Cone.

MS
Result

MSD
Result

MS
% Rec

MSD
% Rec

% Rec
Limits

RPD

Max
RPD

1,2-Dichloropropane

ug/L

<0.45

50

50

58.1

59.1

116

118

77-125

2

20

1,3-Dichlorobenzene

ug/L

<0.35

50

50

54.9

55.2

110

110

70-130

1

20

1,4-Dichlorobenzene

ug/L

<0.89

50

50

56.7

56.4

113

113

70-130

0

20

Benzene

ug/L

<0.30

50

50

55.3

55.6

111

111

70-132

1

20

Bromodichloromethane

ug/L

<0.42

50

50

53.3

52.6

107

105

70-130

1

20

Bromoform

ug/L

<3.8

50

50

43.9

43.8

88

88

65-130

0

20

Bromomethane

ug/L

<1.2

50

50

36.8

43.4

74

87

44-128

16

21

Carbon tetrachloride

ug/L

<0.37

50

50

53.3

54.3

107

109

70-132

2

20

Chlorobenzene

ug/L

<0.86

50

50

57.5

57.6

115

115

70-130

0

20

Chloroethane

ug/L

<1.4

50

50

57.9

58.7

116

117

70-137

1

20

Chloroform

ug/L

<1.2

50

50

55.5

55.5

111

111

80-122

0

20

Chloromethane

ug/L

<1.6

50

50

42.5

43.1

85

86

17-149

1

20

cis-1,2-Dichloroethene

ug/L

0.88J

50

50

53.2

54.1

105

106

70-130

2

20

cis-1,3-Dichloropropene

ug/L

<0.36

50

50

49.7

50.2

99

100

70-130

1

20

Dibromochloromethane

ug/L

<2.6

50

50

51.6

51.8

103

104

70-130

0

20

Dichlorodifluoromethane

ug/L

<0.46

50

50

29.7

30.1

59

60

22-158

1

20

Ethylbenzene

ug/L

<0.33

50

50

57.6

57.2

115

114

80-123

1

20

Isopropylbenzene

ug/L

<1.0

50

50

58.4

58.4

117

117

70-130

0

20

(Cumene)





















m&p-Xylene

ug/L

<0.70

100

100

114

115

114

115

70-130

1

20

Methyl-tert-butyl ether

ug/L

<1.1

50

50

44.5

47.8

89

96

66-130

7

20

Methylene Chloride

ug/L

<0.32

50

50

49.1

48.9

98

98

70-130

0

20

o-Xylene

ug/L

<0.35

50

50

56.8

56.7

114

113

70-130

0

20

Styrene

ug/L

<0.36

50

50

58.7

59.2

117

118

70-130

1

20

Tetrachloroethene

ug/L

<0.41

50

50

54.5

55.0

109

110

70-130

1

20

Toluene

ug/L

<0.29

50

50

56.5

56.1

113

112

80-121

1

20

trans-1,2-Dichloroethene

ug/L

<0.53

50

50

51.3

53.5

103

107

70-134

4

20

trans-1,3-Dichloropropene

ug/L

<3.5

50

50

51.4

50.2

103

100

58-130

2

20

Trichloroethene

ug/L

<0.32

50

50

53.1

53.9

106

108

70-130

1

20

Trichlorofluoromethane

ug/L

<0.42

50

50

46.4

46.5

93

93

82-151

0

20

Vinyl chloride

ug/L

3.7

50

50

53.1

53.5

99

100

61-143

1

20

1,2-Dichlorobenzene-d4 (S)

%











98

96

70-130





4-Bromofluorobenzene (S)

%











96

96

70-130





Toluene-d8 (S)

%











104

102

70-130





Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 34 of 43

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:	3001438 BETTER BRITE

Pace Project No.: 40235181

QC Batch:	398606	Analysis Method:	SM 3500-Cr B (Online)

QC Batch Method: SM 3500-Cr B (Online)	Analysis Description: Chromium, Hexavalent by 3500

Laboratory:	Pace Analytical Services - Green Bay

Associated Lab Samples: 40235181001, 40235181002, 40235181003, 40235181004, 40235181005, 40235181006, 40235181007,
40235181008, 40235181009, 40235181010, 40235181011, 40235181012, 40235181013, 40235181014,
40235181015

METHOD BLANK: 2301169	Matrix: Water

Associated Lab Samples: 40235181001, 40235181002, 40235181003, 40235181004, 40235181005, 40235181006, 40235181007,
40235181008, 40235181009, 40235181010, 40235181011, 40235181012, 40235181013, 40235181014,
40235181015

Blank	Reporting

Parameter	Units	Result	Limit	Analyzed	Qualifiers

Chromium, Hexavalent

mg/L

<0.0073

0.024

10/15/21 07:38











LABORATORY CONTROL SAMPLE: 2301170

Parameter Units

Spike
Cone.

LCS
Result

LCS
% Rec

% Rec

Limits Qualifiers







Chromium, Hexavalent

mg/L

0.3

0.29

98

90-110









MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2301171

MS

40235181001 Spike
Parameter Units Result Cone.

MSD
Spike
Cone.

2301172

MS
Result

MSD
Result

MS
% Rec

MSD
% Rec

% Rec
Limits

RPD

Max
RPD

Qual

Chromium, Hexavalent

mg/L <0.18

7.5

7.5

7.0

7.1

93

94

90-110

1

20



MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2301173

MS

40235181002 Spike
Parameter Units Result Cone.

MSD
Spike
Cone.

2301174

MS
Result

MSD
Result

MS
% Rec

MSD
% Rec

% Rec
Limits

RPD

Max
RPD

Qual

Chromium, Hexavalent

mg/L <0.18

7.5

7.5

6.6

6.7

89

89

90-110

0

20 M0

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result

REPORT OF LABORATORY ANALYSIS

uce Analytical

www.pacelabs.com

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 35 of 43

-------
ice Analytical'

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302

www.pacrtiln.cont	(920)469-2436

QUALITY CONTROL DATA

Project:	3001438 BETTER BRITE

Pace Project No.: 40235181

QC Batch:	399679

QC Batch Method: EPA 300.0

Associated Lab Samples: 40235181003, 40235181005

Analysis Method:	EPA 300.0

Analysis Description: 300.0 IC Anions

Laboratory:	Pace Analytical Services - Green Bay

METHOD BLANK: 2307718	Matrix: Water

Associated Lab Samples: 40235181003, 40235181005

Blank	Reporting

Parameter	Units	Result	Limit	Analyzed	Qualifiers

Sulfate	mg/L	<0.44	2.0 10/28/21 02:02

LABORATORY CONTROL SAMPLE: 2307719

Spike	LCS	LCS	% Rec

Parameter	Units	Cone.	Result	% Rec	Limits	Qualifiers

Sulfate	mg/L	20	20.8	104	90-110

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2307722	2307723

MS	MSD

40235181003 Spike	Spike MS MSD MS MSD % Rec	Max

Parameter	Units Result Cone.	Cone.	Result Result % Rec % Rec Limits RPD RPD Qual

Sulfate	mg/L	48.7 100 100 155 155 106 107 90-110 0 15

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2308304

MS	MSD

40235210003 Spike	Spike

Parameter Units Result Cone.	Cone.

Sulfate mg/L <222 10000	10000

2308305

MS	MSD	MS	MSD	% Rec	Max

Result	Result	% Rec	% Rec	Limits	RPD RPD Qual

10500	10400	105 104 90-110	1 15

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 36 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:	3001438 BETTER BRITE

Pace Project No.: 40235181

QC Batch:
QC Batch Method:

399213
EPA 335.4

Associated Lab Samples: 40235181015

Analysis Method:
Analysis Description:
Laboratory:

EPA 335.4

335.4 Cyanide, Total

Pace Analytical Services - Green Bay

METHOD BLANK: 2304936
Associated Lab Samples: 40235181015

Parameter

Matrix: Water

Units

Blank
Result

Reporting
Limit

Analyzed

Qualifiers

Cyanide

mg/L

<0.0069

0.023 10/21/21 14:16

LABORATORY CONTROL SAMPLE: 2304937

Spike	LCS	LCS % Rec

Parameter Units Cone.	Result	% Rec Limits	Qualifiers

Cyanide mg/L 0.1 0.092	92	90-110

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2304938	2304939

MS	MSD

10583110004 Spike	Spike MS MSD MS MSD % Rec	Max

Parameter	Units Result Cone.	Cone.	Result Result % Rec % Rec Limits RPD RPD Qual

Cyanide	mg/L	ND	0.2	0.2 0.19 0.20	96	98 90-110 2 20

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2304940	2304941

MS	MSD

40235402001 Spike	Spike	MS MSD MS MSD % Rec	Max

Parameter Units Result Cone.	Cone.	Result Result % Rec % Rec Limits RPD RPD Qual

Cyanide	mg/L	0.51	0.6	0.6	1.1	1.1	100 100 90-110 0 20

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 10/29/2021 02:47 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 37 of 43

-------
\ce Analytical9

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALIFIERS

Project:

3001438 BETTER BRITE

Pace Project No.: 40235181
DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.

ND - Not Detected at or above LOD.

J - Estimated concentration at or above the LOD and below the LOQ.

LOD - Limit of Detection adjusted for dilution factor, percent moisture, initial weight and final volume.

LOQ - Limit of Quantitation adjusted for dilution factor, percent moisture, initial weight and final volume.

S - Surrogate

1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.

Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.

LCS(D) - Laboratory Control Sample (Duplicate)

MS(D) - Matrix Spike (Duplicate)

DUP - Sample Duplicate

RPD - Relative Percent Difference

NC - Not Calculable.

SG - Silica Gel - Clean-Up

U - Indicates the compound was analyzed for, but not detected at or above the adjusted LOD.

N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.

Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.

TNI - The NELAC Institute.

ANALYTE QUALIFIERS

D3	Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.

H5	Reanalysis conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time.

M0	Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.

Date: 10/29/2021 02:47 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 38 of 43

-------
iceAnalytical

www.pacdiln.cani

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA CROSS REFERENCE TABLE

Project:

Pace Project No.

3001438 BETTER BRITE
40235181

Lab ID

Sample ID

QC Batch Method

QC Batch

40235181003

MW-115

EPA 301 OA

399059

40235181005

MW-116

EPA 301 OA

399059

40235181001

MW-106

EPA 8260

398659

40235181002

MW-107

EPA 8260

398659

40235181003

MW-115

EPA 8260

398659

40235181004

MW-115A

EPA 8260

398659

40235181005

MW-116

EPA 8260

398659

40235181006

W-1

EPA 8260

398659

40235181007

W-1A

EPA 8260

398659

40235181008

MW-3R

EPA 8260

398659

40235181009

MW-5

EPA 8260

398659

40235181011

MW-6

EPA 8260

398659

40235181013

MW-9

EPA 8260

398659

40235181014

MW-10

EPA 8260

398659

40235181015

ZINC SUMP

EPA 8260

398659

40235181016

TRIP BLANK

EPA 8260

398659

40235181001

MW-106

SM 3500-Cr B (Online)

398606

40235181002

MW-107

SM 3500-Cr B (Online)

398606

40235181003

MW-115

SM 3500-Cr B (Online)

398606

40235181004

MW-115A

SM 3500-Cr B (Online)

398606

40235181005

MW-116

SM 3500-Cr B (Online)

398606

40235181006

W-1

SM 3500-Cr B (Online)

398606

40235181007

W-1 A

SM 3500-Cr B (Online)

398606

40235181008

MW-3R

SM 3500-Cr B (Online)

398606

40235181009

MW-5

SM 3500-Cr B (Online)

398606

40235181010

MW-5A

SM 3500-Cr B (Online)

398606

40235181011

MW-6

SM 3500-Cr B (Online)

398606

40235181012

MW-6A

SM 3500-Cr B (Online)

398606

40235181013

MW-9

SM 3500-Cr B (Online)

398606

40235181014

MW-10

SM 3500-Cr B (Online)

398606

40235181015

ZINC SUMP

SM 3500-Cr B (Online)

398606

40235181003

MW-115

EPA 300.0

399679

40235181005

MW-116

EPA 300.0

399679

40235181015

ZINC SUMP

EPA 335.4

399213

Analytical Method

Analytical
Batch

EPA 6010D
EPA 6010D

399147
399147

EPA 335.4

399284

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

Date: 10/29/2021 02:47 PM	without the written consent of Pace Analytical Services, LLC.	Page 39 of 43

-------
^ace Analytical'

tvmv. paceiabs.com

CHAIN-OF-CUSTODYI Analytical Request Document

The Chain-of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.

Section A

Required Client Information:

Section B

Required Project Information:

Section C

Invoice Information:

Company:

Westwood Infrastructure

Report To: Kim Kennedy

Attention:

Kim Kennedy

Lj<^5l& I

Page:

Address: 1 N Systems Drive

Copy To: Brian Wayner

Company Name: Westwood Infrastructure

REGULATORY AGENCY

r NPDES r GROUNDWATER T DRINKING WATER
r UST r RCRA	r OTHER 	

Appleton, Wisocnsin 54914

Address: 1 n Systems Drive

Email To: kim.kennedy@westwoodps.com

Purchase Order No.:

Pace Quote
Reference:

e: (920)830-6174

Project Name: Better Brite

Pace Project
Manager:

Requested Due Date/TAT:

&P

Project Number: 3001438

Site Location
STATE:

Wi

s

iu

Section D

Required Client Information

SAMPLE ID

(A-Z, 0-9/,-)

Sample IDs MUST BE UNIQUE tissue

Valid Matrix Codes

MATRIX

CODE

DRINKING WATER

DW

WATER

WT

WASTE WATER

WW

PRODUCT

P

SOIUSOLID	

.SL .....

OIL

OL

WIPE

WP

AIR

AR

OTHER

OT

TISSUE

TS

COLLECTED

COMPOSITE
START

COMPOSITE
END/GRAB

TIME

Preservatives

Requested Analysis Filtered (Y/N)

Pace Project No./ Lab I.D.

10

11

12

MW-106

lO/tHfyl

WJ

MW-107

MW-115

w

MW-115A

MW-116

W-1

W-1A



t$&

mi

/JV*

10 HI

MW-3R

w

10 It

TK

MW-5

HW

MW-5A





rXrs

5m

MW-6

/OSS

MW-6A

w







ADDITIONAL COMMENTS

RELINQUISHED BY I AFFILIATION

TIME.



ACCEPTED BY / AFFILIATION

TIME

SAMPLE CONDITIONS



y



WBL



T

TT

5

SAMPLER NAME AND SIGNATURE

PRINT Name of SAMPLER:

:: Evan Dujardin

SIGNATURE of SAMPLER:

2L

¦o 2

?8

ra 2
0) 5
U) c.



•Important Note; By signing this form you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5% per month for any invoices not paid within 30 days.

Page 40 of 43
F-ALL-Q-020rev.08.12-0ct-2007

-------
-------
Sample Preservation Receipt Form
Client Name: LVAjvA'Tf&WWhtft. Project #	l/o

Pace Analytical Services, LLC
1241 Bellevue Street, Suite 9
Green Bay, Wl 54302

All containers needing preservation have been checked and noted below.^sjfes aNo nN/A

Lab Std #ID of preservation (if pH adjusted):

Initial when
completed

m

Date/
Time:

Pace
Lab#















VOA Vials (>6mm) *

H2S04 pH <2

NaOH+Zn Act pH 29

CN
AJ
X

Q.

X

o

CO

2

HN03 pH <2

pH after adjusted

Volume
(mL)



Glass





Plastic



Vials





Jars

General

AG1U
BG1U

AG1H
AG4S
AG4U
AG5U

AG2S
BG3U

BP1U

BP3U
BP3B
BP3N
BP3S

VG9A

DG9T
VG9U
VG9H
VG9M

VG9D

JGFU

JG9U

WGFU

WPFU

SP5T

ZPLC
GN

001



















I













%































2,5/5/10

002



















I













3































2.6/5/10

003



















X













3



























><



2.5/5/10

004



















\













3































2.5/5/10

005



















X



1









"3































2.5/5/10

006



















\













3



























r \ .



2.5/6/10

007



















\













*3































2.5/5/10

008



















M ¦













3































2.5/6/10

009



















i













3































2.5/5/10

010



















i













































2.5/5/10

011

































































2.5/5/10

012



















i













































2.5/6/10

013



















1













































2.5/5/10

014



















(













































2.5/6/10

015



















(

\











?>

























X





2.5/5/10

016

































m































2.5/5/10

0TT







































\r

V ill

\\r

v



















2.5/5/10

018







































\L

>l\l

Mo

A

n\

m















2.5/5/10

019













































LA K

J















2.5/5/10

020

































































-24./5/10

Exceptions to preservation check:WOVColiform, TOC, TOX, TOH, O&G, Wl DRO, Phenolics, Other:

Headspace in VOA Vials (>6mm): ~Yes'^o dN/A *lf yes look in headspace column

AG1U

1 liter amber glass

BP1U

1 liter plastic unpres

VG9A

40 mL clear ascorbic

JGFU

4 oz amber jar unpres

BG1U

1 liter clear glass

BP3U

250 mL plastic unpres

DG9T

40 mL amber Na Thio

JG9U

9 02 amber jar unpres

AG1H

1 liter amber glass HCL

BP3B

250 mL plastic NaOH

VG9U

40 mL clear vial unpres

WGFU

4 oz clear jar unpres

AG4S

125 mL amber glass H2S04

BP3N

250 mL plastic HN03

VG9H

40 mL clear vial HCL

WPFU

4 oz plastic jar unpres

AG4U
AG5U
AG2S
BG3U

120 mL amber glass unpres
100 mL amber glass unpres
500 mL amber glass H2S04
250 mL clear glass unpres

BP3S

250 mL plastic H2S04

VG9M
VG9D

40 mL clear vial MeOH
40 mL clear vial Dl

SP5T
ZPLC
GN

120 mL plastic Na Thiosulfate
ziploc bag

















F-GB-C-046-Rev.03 (11Feb2020) Sample Preservation Receipt Form

"Page"42 of 43

-------
/J^ace Analytical

1241 Bellevue Street, Green Bay, Wl 54302

Document Name:

Sample Condition Upon Receipt (SCUR)

Document Revised: 26Mar2020

Document No.:
ENV-FRM-GBAY-0014-Rev.00

Author:

Pace Green Bay Quality Office

Sample Condition Upon Receipt Form (SCUR)

Project #:T

Client Name:	pfeyWAuOL.

Courier: |~ CS Logistics Fed Ex ~ Speedee [~ UPS C Waltco
T^CIient	~ Pace Other:	

UO#:40235181

III

Tracking #: ¦ 	

Custody Seal on Cooler/Box Present: [j yes	Seals intact: ~ yes fj no

Custody Seal on Samples Present: Cj yes jfcS^no Seals intact: ~ yes Cj no
Packing Material: C	Bubble Bags O None [j Other

40235181

n eub&4i
Thermometer Used SR

Cooler Temperature Uncorr:	/Corr: \.^

Type of lce:^Wet) Blue Dry None

"5^—Samples on ice, cooling process has begun

Temp Blank Present: *\J^i.es fj no
Temp should be above freezing to 6°C.

Biological Tissue is Frozen: C yesHj no

Person examining contents:
Date	/Initials: i



Chain of Custody Present: '^Yes Dno Dn/a

1.



Chain of Custody Filled Out: "^lyes Dno Dn/a

2.



Chain of Custody Relinquished: "^^es Dno Dn/a

3.



Sampler Name & Signature on COC: "^yes Dno Dn/a

4.



Samples Arrived within Hold Time: Dno
- VOA Samples frozen upon receipt dYes Dno

5.

Date/Time:



Short Hold Time Analysis (<72hr): ^No

6.

Rush Turn Around Time Requested: dYes "^no

7.

Sufficient Volume:

For AnalysisQ^Ves Dno MS/MSD: DYes Dn/a

8.

Correct Containers Used: Dno

-Pace Containers Used: Dno Dn/a
-Pace IR Containers Used: DYes Dno £&i/a

9-

Containers Intact: Ji£(es Dno

10.

Filtered volume received for Dissolved tests '^Yes Dno Dn/a

11' ;

Sample Labels match COC: \^Y\S "MNo On/a
-Includes date/time/ID/Analysis Matrix: V—

i20\^'.'^.05^ W\HG\ AU

Trip Blank Present: Dno Dn/a
Trip Blank Custody Seals Present *^I'es aNo ^N/A
Pace Trip Blank Lot # (if purchased): M"7 \

13.

Person Contacted: _
Comments/ Resolution:

Date/Time:

PM Review is documented electronically in LIMs. By releasing the project, the PM acknowledges they have reviewed the sample logii

Page ^ of JX—

Page 43 of 43

-------
APPENDIX G 2022 SUMMARY GROUNDWATER MONITORING REPORT

34

-------
t Fbth

2121 Innovation Court, Suite 100
P.O. Box 5095
DePere.WI 54115-5095
(920) 497-2500
foth.com

February 10, 2023

Gwen Saliares

Wisconsin Department of Natural Resources
Northeast Region RR
625 East County Road Y, Suite 700
Oshkosh, Wl 54901

Re: Summary of the November 2022 Groundwater Sampling Event at the Former Better Brite
Chrome and Zinc Shops

Dear Gwen Saliares:

The purpose of this letter is to summarize the groundwater sampling event conducted on
November 9 and 10, 2022, at the former Better Brite Chrome and Zinc shop locations. The former
Better Brite chrome shop site is located at 500 Lande Street (BRRTS #02-05-000030) and the zinc
shop site is located at 315 6th Street (BRRTS #02-05-000031), De Pere, Wisconsin as illustrated on
Figure 1. This summary includes the following:

~	Figure 1 - Site Location Map

~	Figure 2 - Monitoring Wells - Chrome Shop

~	Figure 3 - Monitoring Wells - Zinc Shop

~	Well-Specific Field Forms

~	Table 1 - Groundwater Analytical Summary - Chrome Shop

~	Table 2 - Groundwater Analytical Summary - Zinc Shop

~	Monitoring Well Photograph Log

~	Laboratory Reports

Groundwater elevations were collected at all available monitoring well network locations at both
sites. The groundwater elevations were recorded on the well-specific field forms.

At the Zinc Shop site, monitoring locations W-1, W-1 A, and MW-2, were purged utilizing a
peristaltic pump as the well column integrity does not allow a standard bailer to pass through the
well column. The wells were purged dry and allowed to recover before the sample was collected.

Monitoring well covers were inspected at all locations during the sampling event. The conditions
of the monitoring well protective casing were noted on the field forms and photographs of the
covers were collected.

pw:\WI DNR\0022W016.00\4000 Regulatory Agency Correspondence\Annual Sampling Report\L-Better Brite GW Summary.docx

-------
Gwen Saliares

Wisconsin Department of Natural Resources
February 10, 2023
Page 2

Color, odor, and turbidity observations were recorded on the field form. The well-specific field
forms also provide the measured depth to water, mean sea level groundwater elevation, time
spent purging, and approximate volume of water removed prior to sample collection. The purged
groundwater was containerized in five-gallon buckets and disposed of in the sump located inside
the zinc shop treatment facility where it will be treated before being discharged to the NEW
Water.

The unfiltered groundwater samples collected from the monitoring well network were submitted
to Pace Laboratories for analysis. The sample analysis per monitoring location is summarized
below:

Better Brite Analysis per Monitoring Location

Chrome Shop Site

Zinc Shop Site

VOCs: MW-106, MW-106A, MW-107, MW-107A,
MW-108, MW-108A, MW-110, MW-110A, MW-111,
MW-112, MW-113, MW-115, MW-115A, MW-116

VOCs: \ \i.\ \i.\ ¦ \i.\ -, \i.\ ¦,

MW-7, MW-8, MW-9, MW-10, MW-11, MW-12, Zinc
Sump

Hexavalent Chrome: MW-106. MW-106A. MW-107.
MW-107A, MW-108, MW-108A, MW-110, MW-
110A, MW-111, MW-112, MW-113, MW-115, MW-
115A, MW-116

Hexavalent Chromium: W-1. W-1 A. MW-2. MW-3R.
MW-5, MW-5A, MW-6, MW-6A, MW-7, MW-7A, MW-
8, MW-8A, MW-9, MW-10, MW-11, MW-12, Zinc
Sump

Iron and Sulfate: MW-115. MW-116

Cvanide: Zinc Sump

VOC = volatile organic compound

The groundwater analytical methods are included in the analytical reports. The laboratory
analysis has been summarized in Table 1 and Table 2. Monitoring well MW-106 was unable to be
sampled due to not being able to open the protective well cover.

Monitoring wells MW-116, W-1, W-1 A, and the Zinc Sump have Hexavalent Chromium analytical
results above the NR 140 Enforcement Standard (ES); however, the results depict a decreasing
trend from previous years. MW-3R has a NR140 Preventive Action Limit (PAL) exceedance for
1,1-Dichloroethene. The zinc sump analytical results detected PAL exceedances for Cyanide,
1,1 -Dichloroethene, and Tetrachloroethene. Monitoring wells MW-115 had an ES exceedance for
Iron. Monitoring location MW-116 had ES exceedances for Sulfate, 1,1 -Dichloroethene, and Vinyl
Chloride and PAL exceedances for Iron, Tetrachloroethene, Trichloroethene, and
1,1,1 -Trichloroethane. The remaining VOC results were below groundwater PAL for all other
constituents and monitoring locations.

pw:\WI DNR\0022W016.00\4000 Regulatory Agency Correspondence\Annual Sampling Report\L-Better Brite GW Summary.docx

-------
Gwen Saliares

Wisconsin Department of Natural Resources
February 10, 2023
Page 3

If you have any questions regarding the enclosed information, please contact me at
(920) 496-6758 or by email at nick.glander@foth.com.

Sincerely,

. \	\\ C - \ »

Sharon V. Kozicki, PG, MBA, PMP®
Senior Project Manager
Licensed PG in Wl

Attachments:

Attachment 1
Attachment 2
Attachment 3
Attachment 4
Attachment 5
Attachment 6
Attachment 7
Attachment 8

Foth Infrastructure & Environment, LLC

Nicholas M. Glander
Lead Environmental Scientist

Figure 1 - Site Location Map
Figure 2 - Monitoring Well Locations - Chrome Shop
Figure 3 - Monitoring Well Locations - Zinc Shop
Well-Specific Field Forms

Table 1 - Groundwater Analytical Summary - Chrome Shop Site
Table 2 - Groundwater Analytical Summary - Zinc Shop Site
Monitoring Well Photographic Log
Laboratory Analytical Reports

pw:\WI DNR\0022W016.00\4000 Regulatory Agency Correspondence\Annual Sampling Report\L-Better Brite GW Summary.docx

-------
Attachment 1
Figure 1 - Site Location Map

pw:\WI DNR\0022W016.00\4000 Regulatory Agency Correspondence\Annual Sampling Report\L-Better Brite GW Summary.docx

-------
Stale
R»tormatOrY

Zinc Shop Site
315 S. 6th Street

Chrome Shop Site
500 Lande Street Blk

	Tjr*	

Athletic
FWd

ad

Path: Q:\Wisconsin DNR\22W016\GiS\mxd\QAPP\Figure 1 - Site Location Map.mxd Date: 7/28/2022

NOTES:

1. Basemap from esri.com, courtesy of the
Microsoft Corporation and its data suppliers.

* Foth

This drawing is neither a legally recorded map nor a survey and is
not intended to be used as one. This drawing is a compilation of
records, information and data used for reference purposes only.

BETTER BRITE SUPERFUND SITE

FIGURE 1 - SITE LOCATION MAP

BETTER BRITE SUPERFUND SITE
315 S. 6TH ST. & 500 LANDE ST. BLK
DE PERE. Wl 54115

Date: JULY 2022

Drawn By: TRN

Revision Date:

Checked By: NMG1 Scope: 22W016

-------
Attachment 2
Figure 2 - Monitoring Well Locations - Chrome Shop

pw:\WI DNR\0022W016.00\4000 Regulatory Agency Correspondence\Annual Sampling Report\L-Better Brite GW Summary.docx

-------
MW-106B

EX-WELL

MW-107B



LEGEND

MW1108B

Groundwater Monitoring Well

Abandoned Groundwater Monitoring Well

Groundwater Elevation Contour

Inferred Groundwater Elevation Contour

Site Boundary

Tax Parcel



Path: Q:\Wisconsin DNR\22W016\GIS\mxd\GAPP\March 2023\Figure 2 - Better Brite - Chrome Shop.mxd Date: 3/23/2023

NOTES:

1. 2022 - 6" resolution air photo from Brown
County Land Information Office.

* Foth

This drawing is neither a legally recorded map nor a survey and is
not intended to be used as one. This drawing is a compilation of
records, information and data used for reference purposes only.

BETTER BRITE SUPERFUND SITE

FIGURE 2 - BETTER BRITE - CHROME SHOP

BETTER BRITE SUPERFUND SITE
315 S. 6TH STREET, DE PERE. Wl 54115

Date: MARCH 2023

Revision Date:

Drawn By: BJW1 Checked By: NMG1 Scope: 22W016

-------
Attachment 3
Figure 3 - Monitoring Well Locations - Zinc Shop

pw:\WI DNR\0022W016.00\4000 Regulatory Agency Correspondence\Annual Sampling Report\L-Better Brite GW Summary.docx

-------
NOTES:

1.	2022 - 6" resolution air photo from Brown
County Land Information Office.

2.	Sump water elevation not used in
creation of groundwater contours.

* Foth

This drawing is neither a legally recorded map nor a survey and is
not intended to be used as one. This drawing is a compilation of
records, information and data used for reference purposes only.

50 100

Feet

BETTER BRITE SUPERFUND SITE

FIGURE 3 - BETTER BRITE - ZINC SHOP

BETTER BRITE SUPERFUND SITE
315 S. 6TH STREET, DE PERE, Wl 54115

Date: MARCH 2023

Revision Date:

Drawn By: BJW1 Checked By: NMG1 Scope: 22W016

Path: Q:\Wisconsin DNR\22W016\GIS\mxd\QAPP\March 2023\Figure 3 - Better Brite - Zinc Shop.mxd Date: 3/22/2023

-------
Attachment 4
Well-Specific Field Forms

pw:\WI DNR\0022W016.00\4000 Regulatory Agency Correspondence\Annual Sampling Report\L-Better Brite GW Summary.docx

-------
Well Specific Field Sheets

Facility Name:

Date:

Weather Conditions:
Person(s) Sampling:
Sampling Equipment:

Former Better Brite - Chrome Shop
November 10, 2022

Partly Cloudy, High of 71 F, Southwest winds 10-15mph.
Dale Chervenka

Dedicated bailers, Solonist 101 water level meter.

Well Name

MW101

MW104A

MW106

MW106A

MW107

MW107A

MW108

MW108A

MW110

MW110A

MW111

MW112

MW113

MW115

MW115A

MW116

Top of PVC Casing Elevation (MSL)





606.21

606.36

608.41

608.33

604.22

604.44

603.05

603.31

600.76

600.61

611.08

601.04

601.01

604.28

Depth to Bottom of Well (ft)



18.30

14.58

32.09

15.39

39.33

15.82

33.27

14.76

23.80

14.38

15.86

15.08

14.48

23.45

18.88

Water Elevation (MSL)

__

__

__

598.61

605.74

592.78

599.9

590.66

600.94

593.14

596.76

587.53

607.69

598.03

589.76

603.04



































Measured Depth to Water (ft)





Unable to sample as
well could not be
opened

7.8

2.67

15.6

4.3

13.8

2.1

10.2

4.0

13.1

3.4

3.01

11.25

1.24

Time Purging Begun





13:42

14:47

15:07

9:54

10:05

12:00

12:17

10:53

12:53

14:08

11:22

11:38

13:13

Time Purging Completed





14:04

15:00

15:29

10:03

10:37

12:13

12:29

11:00

13:00

14:19

11:34

11:58

13:28

Amount Purged (gal)





16.0

8.0

15.0

8.0

12.5

8.0

9.0

7.0

2.0

7.5

7.5

8.0

11.5

Purged Dry? (Y/N)





N

N

N

N

N

N

N

N

N

N

N

N

N



































Color (Y/N)







N

Y

Y

N

N

N

Y

N

Y

N

N

Y

Y

Odor (Y/N)







N

N

N

N

N

N

N

N

N

N

N

N

N

Turbidity (Y/N)







N

Y

Y

N

N

N

Y

N

Y

Y

N

Y

N



































Time Sample Withdrawn







14:05

15:01

15:30

10:04

10:38

12:14

12:30

11:01

13:01

14:20

11:35

11:59

13:29

Well secured? (Y/N)





Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Cover Condition

Well broke.

Cap stuck.

Cover has shifted over,
PVC well lower and lid
cannot open.

Well in good condition.
Bolts secure.

Well in good condition.
One bolt missing.

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Purge 2" Well = (Depth to Bottom of Well - Measured Depth to Water) x 0.163 x 4

Page 1 of 1

-------
Well Specific Field Sheets

Facility Name:	Former Better Brite - Zinc Shop

Date:	November 9, 2022

Weather Conditions:	Partly Cloudy, High of 65 F, South / Southwest winds 10-15mph.

Person(s) Sampling:	Dale Chervenka

Sampling Equipment:	Dedicated bailers, Solonist 101 water level meter, perastaltic pump for W-1, W-1A, MW2.

Well Name

W-1

(1,2,4)

W-1 A

(1,2,4)

MW2

(2)

MW3R

MW5

MW5A

MW6

(4)

MW6A

(4)

MW7

MW7A

MW8

MW8A

MW9

MW10

(4)

MW11

MW12

Zinc
Sump

(3)

Top of PVC Casing Elevation (MSL)







602.88

600.81

600.81





600.60

600.51

598.18

598.59

601.66



602.41

599.65

603.99

Depth to Bottom of Well (ft)

19.9

31.52

17.65

16.72

15.53

29.67

18.43

31.74

15.86

26.73

11.41

21.73

16.30

15.00

15.62

10.04

20.40

Water Elevation (MSL)

__

__

__

598.15

592.89

590.33

__

__

595.13

600.02

595.10

589.50

594.55

__

598.06

596.26

586.96





































Measured Depth to Water (ft)

13.05

15.60

10.10

4.73

7.92

10.48

11.81

12.55

5.47

0.49

3.08

9.09

7.11

5.63

4.35

3.39

17.03

Time Purging Begun

10:00

10:12

13:38

10:40

14:08

13:40

12:15

12:40

11:27

11:00

13:13

10:23

14:36

11:24

12:45

12:04

..

Time Purging Completed

10:12

10:38

13:59

10:54

14:19

14:03

12:25

13:00

11:35

11:14

13:24

10:36

14:44

11:35

12:56

12:11

..

Amount Purged (gal)

1.5

5.5

4.0

7.8

4.0

8.0

4.5

12.5

6.7

10.0

5.3

8.0

6.0

6.0

7.0

4.0

..

Purged Dry? (Y/N)

Y

Y

Y

N

N

Y

Y

N

N

N

N

N

N

N

N

Y

..





































Color (Y/N)

brown

N

brown

brown

brown

brown

brown

brown

brown

brown

brown

brown

brown

brown

brown

brown

yellow

Odor (Y/N)

N

N

N

N

N

N

N

N

N

N

N

N

N

N

N

N

N

Turbidity (Y/N)

N

N

N

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y





































Time Sample Withdrawn

11:50

11:45

14:00

10:55

14:21

14:04

12:26

13:10

11:36

11:15

11:25

10:37

14:47

11:36

12:57

12:13

10:20

Well secured? (Y/N)

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

N

Y

Y

Y

N

Y

Cover Condition

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Pro-top in good
condition. Lock in place.

Missing 1 bolt. Still
secure

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Pro-top in good
condition. Lock in place.

Pro-top in good
condition. Lock in place.

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Well in good condition.
Bolts secure.

Well in good condition.
One bolt does not
thread.

Well in good condition.
Bolts secure.

Cover is flush when
bolted. Both bolts
secure.

Well in good condition.
Bolts secure.

cap broke. Screws
broke in well, casing
broke.

Gate overgrown with
vegetation. Cover in
good condition. Locks
secure.

1	Depth to bottom of the well is suspect. Felt like soft bottom (sediment).

2	A standard bailer would not fit down the monitoirng well.

3	Sump was not running at time of sample collection.

4	Well height modified. New elevation unknown.

Purge 2" Well = (Depth to Bottom of Well - Measured Depth to Water) x 0.163 x 4	Page 1 of 1

-------
Attachment 5

Table 1 - Groundwater Analytical Summary - Chrome Shop Site

pw:\WI DNR\0022W016.00\4000 Regulatory Agency Correspondence\Annual Sampling Report\L-Better Brite GW Summary.docx

-------
Table 1 Groundwater Analytical Summary, Better Brite - Chrome Shop

519 Lande Street, DePere, Wl BRRTS # 02-05-000030





Detected Parameters (mq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,2-DCA

1,1-DCE

cis-1,2-
DCE

PCE

1,1,1-TCA

1,1,2-TCA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.5

0.7

7

0.5

40

0.5

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

5

7

70

5

200

5

5

0.2

Units

|ig/L

|ig/L

|ig/L

|ig/L

-

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L



8/1/94

620000

694000

NA

NA

NA

































Chrome Sump

10/1/94

300200

297000

NA

NA

NA

































(Abandoned)

4/1/98

195000

192000

NA

NA

NA



































7/1/98

132000



NA

NA

NA



































8/1/94

25800

22000

NA

NA

NA

































French Drain

10/1/94

32000

31700

NA

NA

NA

































4/1/98

1060

1010

NA

NA

NA



































7/1/98

336

312

NA

NA

NA

































B-101

8/1/94

<10

<3.4

NA

NA

NA

































10/1/94

<10



NA

NA

NA



































8/1/94

7

<2.8

NA

NA

NA



































DUP.

<10

<2.8

NA

NA

NA



































10/1/94

<10 J

<3.4 J

NA

NA

NA



































DUP.

<10 J

<3.4 J

NA

NA

NA



































4/1/98

<10

<5

NA

NA

NA

































MW-106

DUP

<10

<5

NA

NA

NA



































5/1/00

<4.2

4

NA

NA

NA



































8/26/10

<3.9

5.4

NA

NA

NA



































6/16/11

<3.9

NA

NA

NA

NA



































10/14/21

<0.18

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17



11/10/22

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS

NS



8/1/94

<10

<2.8

NA

NA

NA



































10/1/94

<10 J

<3.4 J

NA

NA

NA



































4/1/98

<10

<5

NA

NA

NA

































MW-106A

5/1/00

<4.2

9.4

NA

NA

NA



































8/26/10

<3.9

1.1"J"

NA

NA

NA



































6/16/11

<3.9

NA

NA

NA

NA



































11/10/22

<370 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17

MW-106B
(Abandoned)

8/1/94

<10

NA

NA

NA

NA



































8/1/94

<10

4.1 BJ

NA

NA

NA



































10/1/94

<10 J

<3.4

NA

NA

NA



































4/1/98

<10

<5

NA

NA

NA



































5/1/00

<4.2

4.2

NA

NA

NA



































6/1/01

NA

NA

530

50

NA



































11/28/01

<4.2

26

3900

NA

1800



































5/1/02

7.8

1.2

230

NA

2300

































MW-107

DUP

100

1.9

490

NA

2800

































11/2/02

NA

NA

8200

140000

2300



































5/3/03

<4.2

1.6

490

95000

1700



































5/4/04

6.5

1.7

260

100000

NA



































5/12/05

<5.0

0.89

380

97000

NA



































8/26/10

<3.9

16.4

4010

16400

NA



































6/16/11

<3.9

NA

3130

83600

NA



































10/14/21

<0.18

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17



11/10/22

<180 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17



8/1/94

<10

<2.8

NA

NA

NA



































10/1/94

<10 J

<3.4 J

NA

NA

NA



































4/1/98

<10

<5

NA

NA

NA

































MW-107A

5/1/00

<4.2

16

NA

NA

NA



































8/26/10

<3.9

23.2

NA

NA

NA



































6/16/11

<3.9

NA

NA

NA

NA



































11/10/22

<370 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17

MW-107B
(Abandoned)

8/1/94

<10

NA

NA

NA

NA



Page 1 of 5

-------
Table 1 Groundwater Analytical Summary, Better Brite - Chrome Shop

519 Lande Street, DePere, Wl BRRTS # 02-05-000030





Detected Parameters (mq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,2-DCA

1,1-DCE

cis-1,2-
DCE

PCE

1,1,1-TCA

1,1,2-TCA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.5

0.7

7

0.5

40

0.5

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

5

7

70

5

200

5

5

0.2

Units

|ig/L

|ig/L

|ig/L

|ig/L

-

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

IM-

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L



8/1/94

<10

<2.8

NA

NA

NA





10/1/94

<10

<3.4 J

NA

NA

NA





4/1/98

<10

NA

NA

NA

NA





DUP

<10

<5

NA

NA

NA



MW-108

7/21/09

NA

16.0

NA

NA

NA





8/26/10

<3.9

4.6"J"

NA

NA

NA





6/16/11

<3.9

NA

NA

NA

NA





12/5/13

<3.4

NA

NA

NA

NA





11/10/22

<370 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17



8/1/94

<10

3.0 BJ

NA

NA

NA





10/1/94

<10

<3.4 J

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA





5/1/00

<4.2

55

NA

NA

NA



MW-108A

7/9/09

NA

NA

NA

NA

NA





8/26/10

<3.9

1.3"J"

NA

NA

NA





6/16/11

<3.9

1.3"J"

NA

NA

NA





12/5/13

<8.6

NA

NA

NA

NA





11/10/22

<180 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17

MW-108B
(Abandoned)

8/1/94

<10

NA

NA

NA

NA





8/1/94

6780

9570

NA

NA

NA



MW-109
(Abandoned)

10/1/94

2400

1980

NA

NA

NA



DUP.

3100

1700

NA

NA

NA



4/1/98

16500

18600

NA

NA

NA





7/1/98

12200

11100

NA

NA

NA





8/1/94

<10

<2.8

NA

NA

NA



MW-109A

10/1/94

<10

1.3 B

NA

NA

NA



(Abandoned)

4/1/98

<10

<5

NA

NA

NA





7/1/98

<10

7

NA

NA

NA



MW-109B

8/1/94

<10

NA

NA

NA

NA



(Abandoned)

10/1/94

<10

NA

NA

NA

NA





8/1/94

<10

3.6 BJ

NA

NA

NA





10/1/94

<10

<3.4 J

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA





5/1/00

<4.2

37

NA

NA

NA





5/4/04

<2.5

11

3400

230000

NA





5/12/05

<5.0

0.89

82

70000

NA



MW-110

10/5/06

<6.8

1.8

NA

NA

NA



8/21/07

NA

7.4

NA

NA

NA





7/21/09

NA

5.3

NA

NA

NA





8/26/10

<3.9

2.0 J

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.75

NA

<0.57

NA

<0.45

<0.9

NA

<0.48

<0.18



6/16/11

<3.9

NA

NA

NA

NA





10/24/12

<3.9

NA

NA

NA

NA





12/5/13

<3.4

NA

NA

NA

NA





11/10/22

<180 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17

Page 2 of 5

-------
Table 1 Groundwater Analytical Summary, Better Brite - Chrome Shop

519 Lande Street, DePere, Wl BRRTS # 02-05-000030





Detected Parameters (mq/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,2-DCA

1,1-DCE

cis-1,2-
DCE

PCE

1,1,1-TCA

1,1,2-TCA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.5

0.7

7

0.5

40

0.5

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

5

7

70

5

200

5

5

0.2

Units

|ig/L

|ig/L

|ig/L

|ig/L

-

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

IM-

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L



8/1/94

<10

<2.8

NA

NA

NA





10/1/94

<10

<3.4 J

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA





5/1/00

<4.2

25

NA

NA

NA



MW-110A

10/5/06

<6.8

4.2

NA

NA

NA



8/21/07

NA

1.9

NA

NA

NA





7/21/09

NA

1.3

NA

NA

NA





8/26/10

<3.9

1.8 J

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.75

NA

<0.57

NA

<0.45

<0.9

NA

<0.48

<0.18



6/16/11

<3.9

NA

NA

NA

NA





11/10/22

<370 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17



8/1/94

<10

<3.4

NA

NA

NA





DUP.

<10

<3.4

NA

NA

NA





10/1/94

<10

<0.70

NA

NA

NA





4/1/98

226

<5

NA

NA

NA





7/1/98

22

27

NA

NA

NA





11/1/98

<0.5

<0.5

NA

NA

NA





5/1/00

<4.2

36

NA

NA

NA





11/2/02

<4.2

43

4400

130000

2600





DUP

<4.2

38

3400

100000

280





5/3/03

5.2

33

2700

98000

1400





5/4/04

50

150

5000

93000

NA





5/12/05

250

260

200

87000

NA





11/28/05

<5.0

39

12000

98000

NA



MW-111

DUP

<5.0

55

21000

96000

NA





10/5/06

<6.8

16

NA

NA

NA





8/21/07

NA

25

NA

NA

NA





7/21/09

NA

23.6

NA

NA

NA





8/26/10

<3.9

19.8

NA

NA

NA





6/16/11

<3.9

NA

NA

NA

NA





10/24/11

<3.9

NA

NA

NA

NA





10/24/12

<3.9

NA

NA

NA

NA





12/5/13

<3.4

NA

NA

NA

NA





10/22/15

<3.9

NA

NA

NA

NA





9/20/16

<51

NA

NA

NA

NA





6/13/18

<130

NA

NA

NA

NA





5/15/19

<130

NA

NA

NA

NA





11/10/22

<180 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17



10/1/94

<10

<0.70

NA

NA

NA





11/1/94

<10

<2.5

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA



MW-112

5/1/00

<4.2

4.1

NA

NA

NA





8/26/10

<3.9

3.9

NA

NA

NA





6/16/11

<3.9

NA

NA

NA

NA





11/10/22

<180 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17



8/1/94

140

99.7

NA

NA

NA





10/1/94

<10 J

8.6 B

NA

NA

NA





5/1/95

43

20.3

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA



MW-113

7/1/98

<10

12

NA

NA

NA





5/1/00

<4.2

22

NA

NA

NA





8/26/10

<3.9

24.3

NA

NA

NA





6/16/11

<3.9

NA

NA

NA

NA





11/10/22

<180 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17

Page 3 of 5

-------
Table 1 Groundwater Analytical Summary, Better Brite - Chrome Shop

519 Lande Street, DePere, Wl BRRTS # 02-05-000030

Sample Location

Date

Detected Parameters (mq/L)

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,2-DCA

1,1-DCE

cis-1,2-
DCE

PCE

1,1,1-TCA

1,1,2-TCA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.5

0.7

7

0.5

40

0.5

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

5

7

70

5

200

5

5

0.2

Units

|ig/L

|ig/L

|ig/L

|ig/L

-

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

MW-114
(Abandoned)

3/1/95

<10 J

<2.9

NA

NA

NA



DUP.

<10 J

<2.9

NA

NA

NA

5/1/95

<10 J

<1.0

NA

NA

NA

DUP.

<10 J

<1.0

NA

NA

NA

4/1/98

<10

<5

NA

NA

NA

MW-115

5/1/00

<4.2

6.0

NA

NA

NA

6/1/01

<4.2

<0.52

160

92

NA

11/28/01

<4.2

12

1100

NA

3000

DUP

<4.2

10

3300

NA

3300

5/1/02

<4.2

38

19000

NA

2800

11/2/02

<4.2

38

7000

130000

3100

5/3/03

<4.2

260

9700

90000

1400

DUP

<4.2

56

3600

89000

1400

5/4/04

<2.5

1.3

130

34000

NA

5/12/05

<5.0

1.1

320

44000

NA

10/5/06

<6.8

2.6

NA

NA

NA

8/21/07

NA

10

NA

NA

NA

7/21/09

NA

5.8

NA

NA

NA

8/26/10

<3.9

1.6 J

3530

24800

NA

6/16/11

<3.9

NA

4460

10000

NA

10/24/11

<3.9

NA

NA

NA

NA

10/24/12

<3.9

NA

NA

NA

NA

12/5/13

<5.7

NA

NA

NA

NA

10/16/14

<3.9

NA

NA

NA

NA

10/22/15

<3.9

NA

NA

NA

NA

9/20/16

<26

NA

NA

NA

NA

6/13/18

<130

NA

NA

NA

NA

5/15/19

<51

NA

NA

NA

NA

10/14/21

<0.073

NA

11300

48.7

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17

11/10/22

<180 D3

NA

21000

33200

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17

MW-115A

5/1/00

<4.2

12.0

NA

NA

NA



10/5/06

<6.8

4.6

NA

NA

NA

8/21/07

NA

2.7

NA

NA

NA

7/21/09

NA

2.9

NA

NA

NA

8/26/10

<3.9

1.4 J

NA

NA

NA

6/16/11

<3.9

NA

NA

NA

NA

10/24/12

<3.9

NA

NA

NA

NA

12/5/13

<8.6

NA

NA

NA

NA

10/16/14

<3.9

NA

NA

NA

NA

10/22/15

<3.9

NA

NA

NA

NA

9/20/16

<26

NA

NA

NA

NA

6/13/18

<130

NA

NA

NA

NA

5/15/19

<51

NA

NA

NA

NA

10/14/21

<0.37

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17

11/10/22

<180 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<0.30

<0.29

<0.58

<0.47

<0.41

<0.30

<0.34

<0.32

<0.17

Page 4 of 5

-------
Table 1 Groundwater Analytical Summary, Better Brite - Chrome Shop

519 Lande Street, DePere, Wl BRRTS # 02-05-000030

Sample Location

Date

Detected Parameters (mq/L)

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

1,1-DCA

1,2-DCA

1,1-DCE

cis-1,2-
DCE

PCE

1,1,1-TCA

1,1,2-TCA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

85

0.5

0.7

7

0.5

40

0.5

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

850

5

7

70

5

200

5

5

0.2

Units

|ig/L

|ig/L

|ig/L

|ig/L

-

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

|ig/L

MW-116

5/1/00

1600

470

NA

NA

NA



DUP.

1500

460

NA

NA

NA

11/1/00

37

23

NA

NA

NA

DUP

46

24

NA

NA

NA

6/1/01

4400

2300

840

2100

NA

11/28/01

3300

2100

690

NA

2400

5/1/02

12000

7300

530

NA

2500

11/2/02

5100

3200

720

20000

2900

5/3/03

8900

6000

410

2700000

1700

5/4/04

28000

22000

43

19000

NA

DUP

28000

22000

280

24000

NA

5/12/05

52000

52000

950

1900000

NA

DUP

54000

53000

710

1800000

NA

11/28/05

50000

61000

840

1800000

NA

10/5/06

39000

36000

900

1800000

NA

DUP

42000

36000

NA

NA

NA

8/21/07

NA

39,000

NA

NA

NA

7/21/09

NA

25,500

NA

NA

NA

8/26/10

21,300

19,200

478

1330000

NA

162 I 2.4 J I 0.43 J | NA | 10.3 | <0.46 | <2.2 | NA | NA | 30.9 | NA | 22.1 | NA | 3.2 I 76.9 I NA | 1J. | 0.21 J

8/26/10 LF

20,200

17,700

NA

NA

NA



4/25/11

34,600

NA

NA

1030000

NA

6/16/11

13,800

NA

240

1660000

NA

3.4 "J" | NA | NA | NA | NA | NA | NA | NA | NA | 28.1 | NA | 25.9 | NA | 1.2 I 84.1 I NA | Z2 I <0.18

10/24/11

18,300

NA

NA

NA

NA



10/24/12

22,300

NA

NA

NA

NA

12/5/13

17,600

NA

NA

NA

NA

DUP

17,500

NA

NA

NA

NA

10/16/14

13,300

NA

NA

NA

NA

10/22/15

16,500

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

43.5

0.32 J

40.6

1.5

1.7

145

0.46 J

1.6

0.27 J

9/20/16

16,100

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

34.8

<0.34

34.8

1.2 J

1.4 J

135

<0.39

1.5 J

<0.35

6/13/18

12,100

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

34.4

<0.34

37.4

0.93 J

1.1 J

125

<0.39

1.5 J

<0.35

5/15/19

9,800

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

38.9

<0.28

44.3

1.3

1.2

142

<0.55

2.1

<0.17

10/14/21

7.1

NA

177

1020

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

36.7

<0.29

28.9

0.92J

1.2

118

<0.34

2.2

0.22J

11/10/22

640

NA

153 J

945,000

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

39.7

<0.29

34

0.92J

1

116

<0.34

2

0.27 J

CSTW1

4/25/11

<3.9

NA

NA

1,180,000

NA



CSTW2

4/25/11

<3.9

NA

NA

2,840,000

NA

CSTW3

4/25/11

1,000

NA

NA

2,010,000

NA

CSTW4

4/25/11

<3.9

NA

NA

426,000

NA

CSTW5

4/25/11

4.9 "J"

NA

NA

592,000

NA

CSTW6

4/25/11

<3.9

NA

NA

608000

NA

Notes:

1,1-DCA = 1,1-Dichloroethane / 1,2-DCA = 1,2-Dichloroethane /1,1-DCE = 1,1-Dichloroethylene / cis-1,2-DCE = cis-1,2-dichloroethylene / PCE = Tetrachloroethylene /1,1,1-TCA = 1,1,1-Trichloroethane / 1,1,2-TCA = 1,1,2-Trichloroethane
TCE - Trichlorethylene / VC = Vinyl Chloride
[jg/L = microgram/Liter
NA - Compound not analyzed
NS - Not Sampled

Underlined - Concentration exceeds preventive action limit
Bolded - Concentration exceeds enforcement standard

D3 - Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.

J - Estimate concentration at or above the Limit of Detection and below the Limit of Quantitation

Page 5 of 5

-------
Attachment 6

Table 2 - Groundwater Analytical Summary - Zinc Shop Site

pw:\WI DNR\0022W016.00\4000 Regulatory Agency Correspondence\Annual Sampling Report\L-Better Brite GW Summary.docx

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031

Sample Location

Date

Detected Parameters (mq/L)

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

Chloroethane

1,1-DCA

1,1-DCE

PCE

1,1,1 -T CA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

80

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

400

850

7

5

200

5

0.2

Units

Hg/L

Hg/L

Hg/L

Hg/L



Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

ng/L

Hg/L

Hg/L

Hg/L

Hg/L

W-1

10/22/15

10,300

NA

NA

NA

NA

(Grab Sample, no purging)

(Grab Sample, previously purged)
(Grab Sample, previously purged)

9/19/16

9600

NA

NA

NA

NA

6/12/18

6600

NA

NA

NA

NA

5/14/19

4400

NA

NA

NA

NA

(Grab Sample, previously pur

ged)

10/14/21

6.1

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA



1.1

<0.58

<0.41

9.7

<0.32

<0.17

11/9/22

2000

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<1.4

<0.30

<0.58

<0.41

4.4

<0.32

<0.17

W-1A

10/22/15

3,300

NA

NA

NA

NA

(Grab Sample, no purging)

(Grab Sample, previously purged)
(Grab Sample, previously purged)

9/19/16

2800

NA

NA

NA

NA

6/12/18

2700

NA

NA

NA

NA

5/14/19

1800

NA

NA

NA

NA

(Grab Sample, previously pur

ged)

10/14/21

0.64

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA



2

<0.58

<0.41

4.5

<0.32

<0.17

11/9/22

790

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<1.4

1.4

<0.58

<0.41

5

<0.32

<0.17

PF-MW-2

May-00

<4.2

7.6

NA

NA

NA

(Grab Sample, no purging)

(Grab Sample, previously purged)
(Grab Sample, previously purged)

Jun-01

<4.2

7.1

NA

NA

NA

Nov-01

<4.2

10

NA

NA

NA

May-02

<4.2

<0.52

NA

NA

NA

Nov-02

<4.2

2.4

NA

NA

NA

May-03

<4.2

49

NA

NA

NA

10/22/15

<3.9

NA

NA

NA

NA

9/19/16

<5.1

NA

NA

NA

NA

6/13/18

<26

NA

NA

NA

NA

11/9/22

<7.3

NA

NA

NA

NA

NA | NA | NA | NA | NA | NA | NA | NA | NA | <1.4 | <0.30 | <0.58 | <0.41 | <0.30 | <0.32 | <0.17

MW-3/MW3R

5/1/00

230

330

NA

NA

NA



11/1/00

50

130

NA

NA

NA

6/1/01

3500

2200

NA

NA

NA

11/28/01

38

1700

NA

NA

NA

5/1/02

<4.2

220

NA

NA

NA

11/2/02

<4.2

18

NA

NA

NA

5/3/03

110

55

NA

NA

NA

Dup

83

49

NA

NA

NA

5/4/04

89

190

NA

NA

NA

5/12/05

<5.0

17

NA

NA

NA

7/21/09

NA

717

NA

NA

NA

8/24/10

660

552

NA

NA

NA

6/28/11

2800

NA

NA

NA

NA

10/24/11

2200

NA

NA

NA

NA

10/23/12

560

NA

NA

NA

NA

12/5/13

140

NA

NA

NA

NA

10/16/14

190

NA

NA

NA

NA

10/22/15

100

NA

NA

NA

NA

9/19/16

380

NA

NA

NA

NA

6/12/18

<130

NA

NA

NA

NA

5/14/19

88

NA

NA

NA

NA

10/14/21

<0.18

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

1.7 J

4.6

0.96J

<0.41

8.9

<0.32

<0.17

11/9/22

<73 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

1.5 J

3.6

1.1

<0.41

10.2

<0.32

<0.17

Page 1 of 9

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031

















Detected Parameters

(Mfl/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

Chloroethane

1,1-DCA

1,1-DCE

PCE

1,1,1 -T CA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

80

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

400

850

7

5

200

5

0.2

Units

Hg/L

Hg/L

Hg/L

Hg/L



Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

ng/L

Hg/L

Hg/L

Hg/L

Hg/L



8/1/94

<10

<3.4

NA

NA

NA





DUP

<10

<3.4

NA

NA

NA





10/1/94

<10 J

<3.4 J

NA

NA

NA





DUP

<10 J

<3.4 J

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA





5/1/00

<4.2

4.6

NA

NA

NA



MW-4
(Abandoned)

11/1/00

<4.2

2.4

NA

NA

NA



6/1/01

<4.2

12

NA

NA

NA



11/28/01

<4.2

7.4

NA

NA

NA





5/1/02

<4.2

1.4

NA

NA

NA





11/2/02

<4.2

15

NA

NA

NA





5/3/03

<4.2

27

NA

NA

NA





5/4/04

<2.5

1.8

NA

NA

NA





5/12/05

<5.0

9

NA

NA

NA





11/28/05

<5.0

12

NA

NA

NA





8/1/94

<10

<3.4

NA

NA

NA





10/1/94

<10 J

6.0 B

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA





5/1/00

<4.2

8.7

NA

NA

NA





11/1/00

<4.2

3.7

NA

NA

NA



MW-4 A
(Abandoned)

6/1/01

<4.2

3.7

NA

NA

NA



11/28/01

<4.2

13

NA

NA

NA



5/1/02

<4.2

38

NA

NA

NA





11/2/02

<4.2

28

NA

NA

NA





5/3/03

<4.2

32

NA

NA

NA





5/4/04

<2.5

0.75

NA

NA

NA





5/12/05

<5.0

2

NA

NA

NA





11/28/05

<5.0

2.8

NA

NA

NA



MW-4B

10/1/94

<10

<0.70

NA

NA

NA



(Abandoned)

11/1/94

<10

<2.5

NA

NA

NA



Page 2 of 9

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031

















Detected Parameters

(Mfl/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

Chloroethane

1,1-DCA

1,1-DCE

PCE

1,1,1 -T CA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

80

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

400

850

7

5

200

5

0.2

Units

Hg/L

Hg/L

Hg/L

Hg/L



Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

ng/L

Hg/L

Hg/L

Hg/L

Hg/L



8/1/94

1590

827

NA

NA

NA





10/1/94

460 J

299 J

NA

NA

NA





DUP

510 J

763 J

NA

NA

NA





4/1/98

212

631

NA

NA

NA





DUP

207

667

NA

NA

NA





7/1/98

1420

1230

NA

NA

NA





5/1/00

120

190

NA

NA

NA





11/1/00

<4.2

6.6

NA

NA

NA





6/1/01

590

450

NA

NA

NA





11/2/02

2200

2200

NA

NA

NA





DUP

2200

2200

NA

NA

NA





5/3/03

4900

3600

NA

NA

NA





5/4/04

4700

3100

NA

NA

NA



MW-5

5/12/05

4000

3200

NA

NA

NA



Oct-06

4900

4000

NA

NA

NA





8/21/07

NA

2,700

NA

NA

NA





7/21/09

NA

2,210

NA

NA

NA





8/24/10

1,300

1,180

NA

NA

NA





6/28/11

970

NA

NA

NA

NA





10/24/11

1,100

NA

NA

NA

NA





10/23/12

970

NA

NA

NA

NA





12/5/13

1000

NA

NA

NA

NA





10/22/15

330

NA

NA

NA

NA





9/19/16

460

NA

NA

NA

NA





6/12/18

180

NA

NA

NA

NA





5/14/19

<51

NA

NA

NA

NA





10/14/21

<0.073

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<1.4

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17



11/9/22

<370 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<1.4

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17



8/1/94

<10

<3.4

NA

NA

NA





10/1/94

<10

<3.4 J

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA





5/1/00

<4.2

6.5

NA

NA

NA





11/1/00

340

380

NA

NA

NA





6/1/01

<4.2

3.9

NA

NA

NA





11/2/02

<4.2

34

NA

NA

NA



MW-5A

5/3/03

<4.2

22

NA

NA

NA





DUP

<4.2

49

NA

NA

NA





5/4/04

<2.5

2.7

NA

NA

NA





5/12/05

<5.0

7.6

NA

NA

NA





8/24/10

<3.9

2.5"J"

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA





10/14/21

<1.8

NA

NA

NA

NA





11/9/22

<1800 D3

NA

NA

NA

NA



MW-5B

8/1/94

NA

NA

NA

NA

NA



(Abandoned)

10/1/94

<10

<5

NA

NA

NA



Page 3 of 9

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031

















Detected Parameters

(Mfl/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

Chloroethane

1,1-DCA

1,1-DCE

PCE

1,1,1 -T CA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

80

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

400

850

7

5

200

5

0.2

Units

Hg/L

Hg/L

Hg/L

Hg/L



Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

ng/L

Hg/L

Hg/L

Hg/L

Hg/L



8/1/94

15900

39200

NA

NA

NA





10/1/94

47000

41,900 J

NA

NA

NA





4/1/98

7650

4560

NA

NA

NA





5/1/00

23000

26000

NA

NA

NA





11/1/00

26000

23000

NA

NA

NA





6/1/01

14000

15000

NA

NA

NA





11/1/01

25000

29000

NA

NA

NA





5/1/02

13000

13000

NA

NA

NA





11/2/02

21000

22000

NA

NA

NA





5/3/03

11000

9300

NA

NA

NA





5/4/04

13000

15000

NA

NA

NA





5/12/05

12000

11000

NA

NA

NA





DUP

12000

11000

NA

NA

NA





10/5/06

12000

12000

NA

NA

NA



MW-6

DUP

14000

12000

NA

NA

NA





8/21/07

NA

8,900

NA

NA

NA





7/21/09

NA

10,400

NA

NA

NA





8/24/10

8400

7,540

NA

NA

NA





6/28/11

5200

NA

NA

NA

NA





10/24/11

6,500

NA

NA

NA

NA





10/23/12

7,300

NA

NA

NA

NA





12/5/13

6,100

NA

NA

NA

NA





10/16/14

3,300

NA

NA

NA

NA





10/22/15

360

NA

NA

NA

NA





9/20/16

3500

NA

NA

NA

NA





6/13/18

1400

NA

NA

NA

NA





5/14/19

1200

NA

NA

NA

NA





10/14/21

1.4

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<1.4

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17



11/9/22

<1800 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<1.4

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17



8/1/94

<10

4.9 B

NA

NA

NA





10/1/94

<10

<3.4 J

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA





5/1/00

6.6

22

NA

NA

NA





11/1/00

<4.2

13

NA

NA

NA





6/01

<4.2

11

NA

NA

NA





11/1/01

<4.2

7.1

NA

NA

NA



MW-6A

5/1/02

<4.2

51

NA

NA

NA



11/2/02

<4.2

83

NA

NA

NA





5/3/03

<4.2

59

NA

NA

NA





5/4/04

<2.5

3.4

NA

NA

NA





5/12/05

<5.0

12

NA

NA

NA





8/24/10

<3.9

1.7"J"

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA





10/14/21

<0.073

NA

NA

NA

NA





11/9/22

<370

NA

NA

NA

NA



Page 4 of 9

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031

















Detected Parameters

(Mfl/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

Chloroethane

1,1-DCA

1,1-DCE

PCE

1,1,1 -T CA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

80

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

400

850

7

5

200

5

0.2

Units

Hg/L

Hg/L

Hg/L

Hg/L



Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

ng/L

Hg/L

Hg/L

Hg/L

Hg/L

MW-6B
(Abandoned)

8/1/94

<10

NA

NA

NA

NA





8/1/94

<10

6.6 BJ

NA

NA

NA





DUP.

<10

<2.8

NA

NA

NA





10/1/94

<10 J

36.4 J

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA





DUP

<10

<5

NA

NA

NA





5/1/00

<4.2

3.9

NA

NA

NA





11/1/00

<4.2

1.1

NA

NA

NA





6/1/01

<4.2

2.7

NA

NA

NA





11/28/01

<4.2

9.7

NA

NA

NA



MW-7

5/1/02

<4.2

3.2

NA

NA

NA





11/2/02

<4.2

1.9

NA

NA

NA





5/3/03

<4.2

0.91

NA

NA

NA





5/4/04

<2.5

0.88

NA

NA

NA





5/12/05

<5.0

32

NA

NA

NA





8/21/07

NA

4.4

NA

NA

NA





7/21/09

NA

9

NA

NA

NA





8/24/10

<3.9

3.7"J"

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA





11/9/22

<370 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<1.4

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17



8/1/94

<10

<2.8

NA

NA

NA





10/1/94

<10 J

<3.4 J

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA





5/1/00

<4.2

4.7

NA

NA

NA





11/1/00

7.9

5

NA

NA

NA





6/1/01

<4.2

2.5

NA

NA

NA





11/28/01

<4.2

<.52

NA

NA

NA



MW-7A

5/1/02

<4.2

1.4

NA

NA

NA





11/2/02

<4.2

0.98

NA

NA

NA





5/3/03

<4.2

0.85

NA

NA

NA





5/4/04

3.9

2.2

NA

NA

NA





5/12/05

<5.0

0.65

NA

NA

NA





8/24/10

<3.9

1.6"J"

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA





11/9/22

<370 D3

NA

NA

NA

NA



Page 5 of 9

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031

















Detected Parameters

(Mfl/L)

Sample Location

Date

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

Chloroethane

1,1-DCA

1,1-DCE

PCE

1,1,1 -T CA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

80

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

400

850

7

5

200

5

0.2

Units

Hg/L

Hg/L

Hg/L

Hg/L



Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

ng/L

Hg/L

Hg/L

Hg/L

Hg/L



10/1/94

<10

<0.70

NA

NA

NA





11/1/94

<10

<2.5

NA

NA

NA





DUP.

<10

<2.5

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA





5/1/00

<4.2

15

NA

NA

NA





11/1/00

13

13

NA

NA

NA





6/1/01

5.3

2

NA

NA

NA





11/28/01

<4.2

2.3

NA

NA

NA



MW-8

DUP

<4.2

6.7

NA

NA

NA



5/1/02

<4.2

4

NA

NA

NA





11/3/02

<4.2

23

NA

NA

NA





5/3/03

<4.2

2.2

NA

NA

NA





5/6/04

<2.5

1.7

NA

NA

NA





5/12/05

<5.0

1.1

NA

NA

NA





8/21/07

NA

2.3

NA

NA

NA





8/24/10

<3.9

96

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA





11/9/22

<1800 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<1.4

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17



10/1/94

<10

<0.70

NA

NA

NA





11/1/94

<10

<2.5

NA

NA

NA





4/1/98

<10

<5

NA

NA

NA





5/1/00

<4.2

16

NA

NA

NA





11/1/00

<4.2

34

NA

NA

NA





6/1/01

<4.2

3.7

NA

NA

NA





11/28/01

<4.2

14

NA

NA

NA





5/1/02

<4.2

2.5

NA

NA

NA



MW-8A

DUP

<4.2

11

NA

NA

NA





11/2/02

<4.2

20

NA

NA

NA





5/3/03

<4.2

13

NA

NA

NA





5/4/04

3.9

0.59

NA

NA

NA





5/12/05

<5.0

2.6

NA

NA

NA





8/21/07

NA

0.92

NA

NA

NA





8/24/10

<3.9

1.7"J"

NA

NA

NA





6/28/11

<3.9

NA

NA

NA

NA





11/9/22

<370 D3

NA

NA

NA

NA



Page 6 of 9

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031

Sample Location

Date

Detected Parameters (mq/L)

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

Chloroethane

1,1-DCA

1,1-DCE

PCE

1,1,1 -T CA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

80

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

400

850

7

5

200

5

0.2

Units

Hg/L

Hg/L

Hg/L

Hg/L



Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

ng/L

Hg/L

Hg/L

Hg/L

Hg/L

MW-9

8/1/94

400

697

NA

NA

NA



10/1/94

470 J

442 J

NA

NA

NA

4/1/98

209

<5

NA

NA

NA

7/1/98

60

75

NA

NA

NA

11/1/00

13

15

NA

NA

NA

DUP

19

51

NA

NA

NA

6/1/01

28

180

NA

NA

NA

11/1/01

35

76

NA

NA

NA

5/1/02

75

72

NA

NA

NA

11/2/02

67

80

NA

NA

NA

5/3/03

32

53

NA

NA

NA

5/4/04

54

63

NA

NA

NA

Dup

50

46

NA

NA

NA

5/12/05

28

41

NA

NA

NA

10/5/06

17

34

NA

NA

NA

8/21/07

NA

52

NA

NA

NA

7/21/09

NA

33.3

NA

NA

NA

8/24/10

27

30.3

NA

NA

NA

6/28/11

14

NA

NA

NA

NA

10/23/12

18 J

NA

NA

NA

NA

12/5/13

<3.4

NA

NA

NA

NA

10/16/14

<3.9

NA

NA

NA

NA

10/22/15

<3.9

NA

NA

NA

NA

9/19/16

<26

NA

NA

NA

NA

6/12/18

<130

NA

NA

NA

NA

5/14/19

<51

NA

NA

NA

NA

10/14/21

<0.73

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<1.4

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17

11/9/22

<370 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<1.4

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17

MW-10

8/1/94

60300

53100

NA

NA

NA



10/1/94

60800 J

43,500 J

NA

NA

NA

11/1/00

20000

18000

NA

NA

NA

6/1/01

<4.2

20

NA

NA

NA

11/2/02

35000

38000

NA

NA

NA

5/3/03

38000

37000

NA

NA

NA

5/4/04

25000

22000

NA

NA

NA

11/28/05

13000

13000

NA

NA

NA

10/5/06

14000

13000

NA

NA

NA

8/21/07

NA

17,000

NA

NA

NA

10/22/15

10,300

NA

NA

NA

NA

9/19/16

9,800

NA

NA

NA

NA

6/12/18

3,200

NA

NA

NA

NA

5/14/19

1,500

NA

NA

NA

NA

10/14/21

<0.18

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<1.4

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17

11/9/22

<370 D3

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

<1.4

<0.30

<0.58

<0.41

<0.30

<0.32

<0.17

Page 7 of 9

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031

Sample Location Date

Hexavalent
Chromium

Antimony

Cyanide

Detected Parameters (pg/L)

Nickel

Silver

NR140 Preventive Action Limit

1.2

40

NR140 Enforcement Standard

11/1/00
jun-01

Page 8 of 9

-------
Table 2 Groundwater Analytical Summary, Better Brite - Zinc Shop

315 6th Street, De Pere, Wl BRRTS # 02-05-000031

Sample Location

Date

Detected Parameters (gq/L)

Hexavalent
Chromium

Chromium

Iron

Sulfate

Sulfide

Antimony

Arsenic

Cadmium

Cyanide

Nickel

Silver

Thallium

Cobalt

Vanadium

Chloroethane

1,1-DCA

1,1-DCE

PCE

1,1,1 -T CA

TCE

VC

NR140 Preventive Action Limit

10

10

150

125,000

NO PAL

1.2

1

0.5

40

20

10

0.4

8

6

80

85

0.7

0.5

40

0.5

0.02

NR140 Enforcement Standard

100

100

300

250,000

NO ES

6

10

5

200

100

50

2

40

30

400

850

7

5

200

5

0.2

Units

Hg/L

Hg/L

Hg/L

Hg/L



Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

Hg/L

ng/L

Hg/L

Hg/L

Hg/L

Hg/L

MW-13

3/1/95

<10 J

<2.9

NA

NA

NA



5/1/95

<10

<1.0

NA

NA

NA

Zinc Sump

8/1/94

89000

209000

NA

NA

NA

10/1/94

144900

277000

NA

NA

NA

4/1/98

66000

38300

NA

NA

NA

7/1/98

131000

131000

NA

NA

NA

5/1/00

1800

1700

NA

NA

NA

11/1/00

41000

27000

NA

NA

NA

6/1/01

40000

110000

NA

NA

NA

11/28/01

23000

56000

NA

NA

NA

5/1/02

43000

14000

NA

NA

NA

11/2/03

23000

30000

NA

NA

NA

5/3/03

8400

6800

NA

NA

NA

5/4/04

24000

6400

NA

NA

NA

5/12/05

15000

13000

NA

NA

NA

10/5/06

7500

5900

NA

NA

NA

8/21/07

NA

20,000

NA

NA

NA

7/21/09

NA

14,800

NA

NA

NA

8/24/10

12,100

11,300

NA

NA

NA

90.6

NA

NA

40

NA

NA

<2.2

2.5 J

4.7 J

<0.75

<0.57

<0.45

1.5

<0.48

<0.18

6/28/11

4100

NA

NA

NA

NA

6.6

NA

NA

250

NA

NA

<2.2

2.5 J

4.7 J

1.2

2.8

0.84

38.9

<0.48

<0.18

10/24/11

3,700

NA

NA

NA

NA

6.0 "J"

NA

NA

220

NA

NA

NA

NA

NA



NA

NA

NA

NA

NA

NA

10/23/12

110

NA

NA

NA

NA

NA

NA

NA

40

NA

NA

NA

NA

NA



NA

NA

NA

NA

NA

NA

12/5/13

5,100

NA

NA

NA

NA

NA

NA

NA

340

NA

NA

NA

NA

NA



NA

NA

NA

NA

NA

NA

10/16/14

9,600

NA

NA

NA

NA

NA

NA

NA

190

NA

NA

NA

NA

NA



NA

NA

NA

NA

NA

NA

10/22/15

10,200

NA

NA

NA

NA

NA

NA

NA

220

NA

NA

NA

NA

NA



2.9

2.5

1.2

49.0

<0.33

<0.18

9/19/16

14,000

NA

NA

NA

NA

<7.3

NA

NA

160

NA

NA

NA

NA

NA



1.4

1.2

0.79J

22.6

<0.33

<0.18

6/13/18

9900

NA

NA

NA

NA

NA

NA

NA

51

NA

NA

NA

NA

NA



<0.24

<0.41

<0.50

2.1

<0.33

<0.18

5/14/19

8100

NA

NA

NA

NA

NA

NA

NA

100

NA

NA

NA

NA

NA



0.68J

1.2

0.45J

14.1

<0.26

<0.17

10/14/21

6.5

NA

NA

NA

NA

NA

NA

NA

0.089J

NA

NA

NA

NA

NA



1.5

0.81 J

0.75J

15.7

<0.32

<0.17

11/9/22

420

NA

NA

NA

NA

NA

NA

NA

75 J

NA

NA

NA

NA

NA

<1.4

1.9

1.4

0.93J

20.2

<0.32

<0.17

Private

8/1/94

<10

<10

NA

NA

NA



Municipal

8/1/94

<10

<10

NA

NA

NA

DUP.

<10

<10

NA

NA

NA

10/1/94

<10

<10

NA

NA

NA

DUP.

<10

<10

NA

NA

NA

USGS

10/1/94

<10

0.75 B

NA

NA

NA

USGS-A

10/1/94

<10

11.9

NA

NA

NA

Notes:

1,1-DCA = 1,1-Dichloroethane /1,1-DCE = 1,1-Dichloroethylene / PCE = Tetrachloroethylene /1,1,1-TCA = 1,1,1-Trichloroethane / TCE - Trichloroethylene / VC = Vinyl Chloride
[jg/L = microgram/Liter
NA - Compound not analyzed
NS - Not Sampled

Underlined - Concentration exceeds preventive action limit
Bolded - Concentration exceeds enforcement standard

D3 - Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.

J - Estimate concentration at or above the Limit of Detection and below the Limit of Quantitation

Page 9 of 9

-------
Attachment 7
Monitoring Well Photographic Log

pw:\WI DNR\0022W016.00\4000 Regulatory Agency Correspondence\Annual Sampling Report\L-Better Brite GW Summary.docx

-------
¦W-Foth



Photographic Log

Client's Name:

Site Location:

Project No.

WDNR - Better Brite

De Pere, Wisconsin

22W016

Photo
No.

1

Date:

11/9/2022

Photo

No.

3

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Photo Taken By:

Dale C.

Description:

Zinc Shop Sump

Description:

W-1A Monitoring
Well

Photo

No.

2

Date:

11/9/2022

Photo

No.
4

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Photo Taken By:

Dale C.

Description:

W-1 Monitoring
Well

Description:

MW2 Monitoring
Well

pw:\W! DNR\0022W016.00\4000 Regulatory Agency CorrespondenceVAnnual Sampling Report\Photo Log of Monitoring Wells.docx

-------
¦W-Foth



Photographic Log

Client's Name:

Site Location:

Project No.

WDNR - Better Brite

De Pere, Wisconsin

22W016

Photo

No.

5

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW-3R Monitoring
Well

iSwdiifl&B

Photo

No.

6

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW-5A Monitoring
Well

Photo

No.

7

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW 5 Monitoring
Well

ry

Photo
No

8

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW-6 Monitoring
Well

pw:\W! DNR\0022W016.00\4000 Regulatory Agency CorrespondenceVAnnual Sampling Report\Photo Log of Monitoring Wells.docx

-------
¦W-Foth



Photographic Log

Client's Name:

Site Location:

Project No.

WDNR - Better Brite

De Pere, Wisconsin

22W016

Photo

No.

9

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW-6A Monitoring
Well

Photo
No.
10

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW-7A Monitoring
Well

Photo
No.
11

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW 7 Monitoring
Well

Photo
No.
12

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW-8 Monitoring
Well

pw:\W! DNR\0022W016.00\4000 Regulatory Agency CorrespondenceVAnnual Sampling Report\Photo Log of Monitoring Wells.docx

-------
¦W-Foth



Photographic Log

Client's Name:

Site Location:

Project No.

WDNR - Better Brite

De Pere, Wisconsin

22W016

Photo
No.
14

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW-10 Monitoring
Well

Photo
No.
13

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW-8A Monitoring
Well

Photo
No.
15

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW 9 Monitoring
Well

Photo
No.
16

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW-11

Monitoring Well

pw:\W! DNR\0022W016.00\4000 Regulatory Agency CorrespondenceVAnnual Sampling Report\Photo Log of Monitoring Wells.docx

-------
¦W-Foth



Photographic Log

Client's Name:

Site Location:

Project No.

WDNR - Better Brite

De Pere, Wisconsin

22W016

Photo
No.
17

Date:

11/9/2022

Photo Taken
Location:

Zinc Shop Site

Photo Taken By:

Dale C.

Description:

MW-12 Monitoring
Well

Photo
No.
18

Date:

11/10/2022

Photo Taken
Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW-106A
Monitoring Well

Photo
No.
19

Date:

11/10/2022

Photo Taken
Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW-106
Monitoring Well

Photo
No
20

Date:

11/10/2022

Photo Taken
Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW-107
Monitoring Well

pw:\W! DNR\0022W016.00\4000 Regulatory Agency CorrespondenceVAnnual Sampling Report\Photo Log of Monitoring Wells.docx

-------
¦W-Foth



Photographic Log

Client's Name:

Site Location:

Project No.

WDNR - Better Brite

De Pere, Wisconsin

22W016

Photo
No.
21

Date:

11/10/2022

Photo Taken
Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW-107A
Monitoring Well

^ Wf%'~ k-!

Photo

No.
22

Date:

11/10/2022

Photo Taken
Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW-108A
Monitoring Well

Photo

No.
23

Date:

11/10/2022

Photo Taken
Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW-108
Monitoring Well

Photo
No
24

Date:

11/10/2022

Photo Taken
Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW-110
Monitoring Well

pw:\W! DNR\0022W016.00\4000 Regulatory Agency CorrespondenceVAnnual Sampling Report\Photo Log of Monitoring Wells.docx

-------
¦W-Foth



Photographic Log

Client's Name:

Site Location:

Project No.

WDNR - Better Brite

De Pere, Wisconsin

22W016

Photo

No.
27

Date:

11/10/2022

Photo

"aken

Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW 111
Monitoring Well

Photo

No.
26

Date:

11/10/2022

Photo

"aken

Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW-112
Monitoring Well

Photo
No.
28

Date:

11/10/2022

Photo

faken

Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW 113
Monitoring Well

Photo

No.
25

Date:

11/10/2022

Photo

"aken

Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW-110A
Monitoring Well

pw:\W! DNR\0022W016.00\4000 Regulatory Agency CorrespondenceVAnnual Sampling Report\Photo Log of Monitoring Wells.docx

-------
¦W-Foth



Photographic Log

Client's Name:

Site Location:

Project No.

WDNR - Better Brite

De Pere, Wisconsin

22W016

Photo

No.
29

Date:

11/10/2022

Photo Taken
Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW-115
Monitoring Well

Photo
No.
31

Date:

11/10/2022

Photo Taken
Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW-115A
Monitoring Well

Photo

No.
30

Date:

11/10/2022

Photo

"aken

Location:

Chrome Shop Site

Photo Taken By:

Dale C.

Description:

MW-116
Monitoring Well

pw:\W! DNR\0022W016.00\4000 Regulatory Agency CorrespondenceVAnnual Sampling Report\Photo Log of Monitoring Wells.docx

-------
Attachment 8
Laboratory Analytical Reports

pw:\WI DNR\0022W016.00\4000 Regulatory Agency Correspondence\Annual Sampling Report\L-Better Brite GW Summary.docx

-------
Technical Practice Area: Data Science	

Technical Practice Leader: Stephen Lehrke	

SOP Owner: T. Scott Barton	

Page 1 of 4

Foth Infrastructure & Environment, LLC

Data Verification Checklist Form

Event: Better Brite Superfund Site Groundwater Monitoring

Sample Date(s): 11 /09/2022

Sample Matrix: Groundwater

Field Technician: Dale Chervenka

Prepared by: T. Scott Barton

Laboratory: Pace Analytical Services, Green Bay, Wl

Checked by: NickGlander

Laboratory Batch Number(s): 40254467

Date: 02/02/2023

The data review is to be performed in accordance with the procedures specified in the USEPA Functional
Guidelines for Inorganic, Organic, and High-Resolution Superfund Methods Data Review (USEPA 2020a,
2020b, and 2020c), and quality assurance and control parameters set by the project laboratories.

This checklist verifies that sampling and analytical activities followed relevant methods, procedures, and
project-specific documents (e.g., QAPPs and SAPs) for the following:

Sample documentation and chain-of-custody protocol;

Sample container requirements;

Quality control (QC) procedures; and

Quality assurance (QA) management including data management and data verification procedures.
Data Verification Overview

Sample results subjected to a data verification review include an evaluation of the following QC
parameters:

Sample preservation and temperature upon receipt;

Holding times;

Method blank detections;

Method duplicates and relative percent difference (RPD);

Laboratory control samples/laboratory control samples duplicate (LCS/LCSD) recovery and RPD;
Matrix spike/matrix spike duplicate (MS/MSD) recovery and RPD;

Surrogate recovery (for organic parameters);

Field QA/QC samples and RPD;

Simplified charge balance calculation (for ion balancing); and
Completeness summary.

ID#: 3108
Revision #:

SgrSE

C:\Users\NMG1\Desktop\Better Brite\2022 PM\Annual Sampling Event\Final Report\40254467 Data Verification Checklist
02022023.docx

-------
Technical Practice Area: Data Science	

Technical Practice Leader: Stephen Lehrke	

SOP Owner: T. Scott Barton	

Page 2 of 4

Foth Infrastructure & Environment, LLC

The following tables summarize data verification results:

Analytes and Methods

VOCs

EPA 8260

Chromium, Hexavalent

SM 3500-Cr B

Cyanide, Total

EPA 335.4

Sample Summary

Lab ID

Sample ID

40254467001

W-1_202211

40254467002

W-1 A_202211

40254467003

MW-2_202211

40254467004

MW-3R_202211

40254467005

MW-5_202211

40254467006

MW-5A_202211

40254467007

MW-6_202211

40254467008

MW-6A_202211

40254467009

MW-7_202211

40254467010

MW-7A_202211

40254467011

MW-8_202211

40254467012

MW-8A_202211

40254467013

MW-9_202211

40254467014

MW-10_202211

40254467015

MW-11_202211

40254467016

MW-12_202211

40254467017

ZINC SHOP_202211

40254467018

MW-3RD_202211

Quality Assurance Sample IDs

Lab ID

Sample ID

40254467019

TB1_202211

Data Verification Checklist

Data Verification Criteria

Yes

No

Not
Applicable

CHAIN OF CUSTODY (COC)

1. Are relinquish and receipt signatures present on the COC?



~

~

2. Do the analyte and analytical methods requested on the COC agree with
the project requirements (e.g., QAPP, SAP)?



~

~

SAMPLE PRESERVATION & HOLDING TIMES

3. Samples received by the project laboratory, intact, with correct

preservation, and at the correct temperature (less than or equal to [<] 6
degrees Celsius [°C] but not frozen)?

~



~

C:\Users\NMG1\Desktop\Better Brite\2022 PM\Annual Sampling Event\Final Report\40254467 Data Verification Checklist
02022023.docx

ID#: 3108
Revision #:

SgrSE

-------
Technical Practice Area: Data Science	

Technical Practice Leader: Stephen Lehrke	

SOP Owner: T. Scott Barton	

Page 3 of 4

Foth Infrastructure & Environment, LLC

Data Verification Criteria

Yes

No

Not
Applicable

Comments:

• Post-analysis pH measurement indicates insufficient VOA sample
preservation in MW-8_202211 (Lab ID# 40254467011). No
qualifier is assigned because the sample was analyzed within the
technical holding time of 7 days specified in the National
Functional Guidelines for Organic Superfund Methods Data Review
(USEPA 2020).







4. Samples extracted and analyzed within the holding time limits set by the
respective analytical method(s)?

Comments:

• Analyses for hexavalent chromium (SM 3500-Cr B) for all samples
were performed outside the recommended holding time of 24
hours. No qualifiers are assigned because samples were analyzed
within the technical holding time of 14 days specified in the
National Functional Guidelines for Inorganic Superfund Methods
Data Review (USEPA 2020).

~



~

ANALYTICAL METHOD REQUIREMENTS

5. Method blanks analyzed at the required frequencies?



~

~

6. Target compounds detected in the method blanks?
Compounds detected:

• None

~



~

7. Method duplicate samples performed at the required frequency?
Comments:

• No method duplicates were reported for this Sample Delivery
Group.

~

~



8. Were LCS/LCSD analyses performed at the required frequency?
Comments:



~

~

9. Are the percent recoveries and RPDs for the LCS/LCSD within acceptance
limits?

Comments:

• The LCS % Recovery for trans-1,2-Dichloroethene was outside
control limits for LCS# 2483116. Project samples associated with
this LCS are MW-3RD_202211 and TB1_202211. No qualification
of data required because associated results were non-detect.

~



~

10. Were MS/MSD analyses performed at the required frequency?

13

~

~

11. Are percent recoveries and RPDs for the MS/MSD within acceptable
limits?

Comments:

• The MS/MSD % Recoveries for Bromomethane were outside
control limits in MS/MSD# 2484281 and 2484282. This MS/MSD
analysis was not performed using a project sample, so no
qualification of data is required.

~



~

QUALITY ASSURANCE REQUIREMENTS

C:\Users\NMG1\Desktop\Better Brite\2022 PM\Annual Sampling Event\Final Report\40254467 Data Verification Checklist
02022023.docx

ID#: 3108
Revision #:

SgrSE

-------
Technical Practice Area: Data Science	

Technical Practice Leader: Stephen Lehrke	

SOP Owner: T. Scott Barton	

Page 4 of 4

Foth Infrastructure & Environment, LLC

Data Verification Criteria

Yes

No

Not
Applicable

12. Were the appropriate number of trip blanks collected?

Comments:

• One trip blank was collected and analyzed for this Sample Delivery
Group.

Kl

u

u

13. Were the appropriate number of field blanks collected?
Comments:

• None specified in the QAPP.

~

~

m

14. Were the appropriate number of duplicates collected?
Comments:

• None specified in the QAPP.

~

~

m

15. Were the appropriate number of equipment blanks collected?
Comments:

• None specified in the QAPP.

~

~

h

16. Were the appropriate number of mercury field blanks collected?
Comments:

• Mercury is not an analyte of interest for this project.

~

~

h

QUALITY CONTROL REQUIREMENTS

17. Is the charge balance error less than 10% or 1 milliequivalents per liter
(meq/L), whichever is greater?

Comments:

• None specified in the QAPP.

~

~



18. Were all samples analyzed as defined in the sampling plan?
Comments:



~

~

19. Is the completeness check greater than or equal to 90% of the plan?
Comments:



~

~

20. Do the analytical results meet the data quality objectives?
Comments:



~

~

21. Was a trend evaluation completed as part of the data verification?
Comments:

• None specified in the QAPP.

~



~

ID#: 3108
Revision #:

SgrSE

C:\Users\NMG1\Desktop\Better Brite\2022 PM\Annual Sampling Event\Final Report\40254467 Data Verification Checklist
02022023.docx

-------
mf f	Pace Analytical Services, LLC

/ ParpAnah/tiraf	1241 Be"evue street -suite 9

/ i^yr aiiGni laiy llual	Green Bay, Wl 54302

/ " WWW.pctIallS.com	(920)469-2436

November 18, 2022

Nick Glander

Foth Infrastructure & Environment, LLC
2121 Innovation Court
Suite 300
De Pere, Wl 54115

RE: Project: 22W016 BETTER BRITE
Pace Project No.: 40254467

Dear Nick Glander:

Enclosed are the analytical results for sample(s) received by the laboratory on November 09, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.

The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Green Bay

If you have any questions concerning this report, please feel free to contact me.

Tod Noltemeyer
tod.noltemeyer@pacelabs.com
(920)469-2436
Project Manager

Enclosures

Sincerely,



REPORT OF LABORATORY ANALYSIS

^ORAt0^

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 1 of 59

-------
iceAnalytical

www.pacaliki.coni

CERTIFICATIONS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Pace Analytical Services Green Bay

1241 Bellevue Street, Green Bay, Wl 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky UST Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
New York Certification #: 12064
North Dakota Certification #: R-150

South Carolina Certification #: 83006001
Texas Certification #: T104704529-21-8
Virginia VELAP Certification ID: 11873
Wisconsin Certification #: 405132750
Wisconsin DATCP Certification #: 105-444
USDASoil Permit#: P330-21-00008
Federal Fish & Wildlife Permit #: 51774A

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 2 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

SAMPLE SUMMARY

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Lab ID	Sample ID	Matrix	Date Collected Date Received

40254467001

W-1_202211

Water

11/09/22 11:50

11/09/22 15:43

40254467002

W-1A_202211

Water

11/09/22 11:45

11/09/22 15:43

40254467003

MW-2_202211

Water

11/09/22 14:00

11/09/22 15:43

40254467004

MW-3R_202211

Water

11/09/22 10:55

11/09/22 15:43

40254467005

MW-5_202211

Water

11/09/22 14:21

11/09/22 15:43

40254467006

MW-5A_202211

Water

11/09/22 14:04

11/09/22 15:43

40254467007

MW-6_202211

Water

11/09/22 12:26

11/09/22 15:43

40254467008

MW-6A_202211

Water

11/09/22 13:10

11/09/22 15:43

40254467009

MW-7_202211

Water

11/09/22 11:36

11/09/22 15:43

40254467010

MW-7A_202211

Water

11/09/22 11:15

11/09/22 15:43

40254467011

MW-8_202211

Water

11/09/22 11:25

11/09/22 15:43

40254467012

MW-8A_202211

Water

11/09/22 10:37

11/09/22 15:43

40254467013

MW-9_202211

Water

11/09/22 14:47

11/09/22 15:43

40254467014

MW-10_202211

Water

11/09/22 14:30

11/09/22 15:43

40254467015

MW-11_202211

Water

11/09/22 12:57

11/09/22 15:43

40254467016

MW-12_202211

Water

11/09/22 12:13

11/09/22 15:43

40254467017

ZINC SHOP_202211

Water

11/09/22 10:20

11/09/22 15:43

40254467018

MW-3RD_202211

Water

11/09/22 10:55

11/09/22 15:43

40254467019

TB1 202211

Water

11/09/22 00:00

11/09/22 15:43

ceAnalytical

www.pacaliki.coni

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 3 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436





SAMPLE ANALYTE COUNT





Project:

Pace Project No.

22W016 BETTER BRITE
40254467







Lab ID

Sample ID

Method

Analysts

Analytes
Reported

40254467001

W-1_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254467002

W-1A_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254467003

MW-2_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254467004

MW-3R_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254467005

MW-5_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254467006

MW-5A_202211

SM 3500-Cr B

EXM

1

40254467007

MW-6_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254467008

MW-6A_202211

SM 3500-Cr B

EXM

1

40254467009

MW-7_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254467010

MW-7A_202211

SM 3500-Cr B

EXM

1

40254467011

MW-8_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254467012

MW-8A_202211

SM 3500-Cr B

EXM

1

40254467013

MW-9_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254467014

MW-10_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254467015

MW-11_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254467016

MW-12_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254467017

ZINC SHOP_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1





EPA 335.4

DAW

1

40254467018

MW-3RD_202211

EPA 8260

JAV

64





SM 3500-Cr B

EXM

1

40254467019

TB1 202211

EPA 8260

JAV

64

PASI-G = Pace Analytical Services - Green Bay

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacelabs.com

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 4 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

PROJECT NARRATIVE

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Method: EPA 8260
Description: 8260 MSV

Client: FOTH INFRASTRUCTURE & ENVIRONMENT
Date:	November 18, 2022

General Information:

15 samples were analyzed for EPA 8260 by Pace Analytical Services Green Bay. All samples were received in acceptable condition
with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.

pH: Post-analysis pH measurement indicates insufficient VOA sample preservation.

•	MW-8_202211 (Lab ID: 40254467011)

Hold Time:

The samples were analyzed within the method required hold times with any exceptions noted below.

Initial Calibrations (including MS Tune as applicable):

All criteria were within method requirements with any exceptions noted below.

Continuing Calibration:

All criteria were within method requirements with any exceptions noted below.

QC Batch: 431217

v1: The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated
samples may have a high bias.

•	BLANK (Lab ID: 2483115)

•	Bromomethane

•	LCS (Lab ID: 2483116)

•	Bromomethane
•MS (Lab ID: 2484281)

•	Bromomethane

•	MSD (Lab ID: 2484282)

•	Bromomethane

•	MW-3RD_202211 (Lab ID: 40254467018)

•	Bromomethane

•	TB1_202211 (Lab ID: 40254467019)

•	Bromomethane

Internal Standards:

All internal standards were within QC limits with any exceptions noted below.

Surrogates:

All surrogates were within QC limits with any exceptions noted below.

Method Blank:

All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.

Laboratory Control Spike:

All laboratory control spike compounds were within QC limits with any exceptions noted below.

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacelabs.com

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 5 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

PROJECT NARRATIVE

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Method: EPA 8260
Description: 8260 MSV

Client: FOTH INFRASTRUCTURE & ENVIRONMENT
Date:	November 18, 2022

QC Batch: 431217

L1: Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results may be biased high.
• LCS (Lab ID: 2483116)

• trans-1,2-Dichloroethene

ceAnalytical

www.pacaliki.coni

Matrix Spikes:

All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 431217

A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 40254535001
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.

•MS (Lab ID: 2484281)

•	trans-1,2-Dichloroethene

•	MSD (Lab ID: 2484282)

•	trans-1,2-Dichloroethene

M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
•MS (Lab ID: 2484281)

•	Bromomethane

•	MSD (Lab ID: 2484282)

•	Bromomethane

R1: RPD value was outside control limits.

•	MSD (Lab ID: 2484282)

•	Methyl-tert-butyl ether

Additional Comments:

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 6 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

PROJECT NARRATIVE

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Method: SM 3500-Cr B

Description: Chromium, Hexavalent

Client: FOTH INFRASTRUCTURE & ENVIRONMENT

Date:	November 18, 2022

General Information:

18 samples were analyzed for SM 3500-Cr B by Pace Analytical Services Green Bay. All samples were received in acceptable
condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.

Hold Time:

The samples were analyzed within the method required hold times with any exceptions noted below.

Method Blank:

All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.

Laboratory Control Spike:

All laboratory control spike compounds were within QC limits with any exceptions noted below.

Matrix Spikes:

All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 431224

A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 40254467001
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.

•MS (Lab ID: 2483142)

•	Chromium, Hexavalent

•	MSD (Lab ID: 2483143)

•	Chromium, Hexavalent

Additional Comments:

Analyte Comments:

QC Batch: 431224

D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.

•	MW-10_202211 (Lab ID: 40254467014)

•	Chromium, Hexavalent

•	MW-11_202211 (Lab ID: 40254467015)

•	Chromium, Hexavalent

•	MW-12_202211 (Lab ID: 40254467016)

•	Chromium, Hexavalent

•	MW-3RD_202211 (Lab ID: 40254467018)

•	Chromium, Hexavalent

•	MW-3R_202211 (Lab ID: 40254467004)

•	Chromium, Hexavalent

•	MW-5A_202211 (Lab ID: 40254467006)

•	Chromium, Hexavalent

•	MW-5_202211 (Lab ID: 40254467005)

•	Chromium, Hexavalent

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacelabs.com

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 7 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

PROJECT NARRATIVE

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Method: SM 3500-Cr B

Description: Chromium, Hexavalent

Client: FOTH INFRASTRUCTURE & ENVIRONMENT

Date:	November 18, 2022

Analyte Comments:

QC Batch: 431224

D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.

•	MW-6A_202211 (Lab ID: 40254467008)

•	Chromium, Hexavalent

•	MW-6_202211 (Lab ID: 40254467007)

•	Chromium, Hexavalent

•	MW-7A_202211 (Lab ID: 40254467010)

•	Chromium, Hexavalent

•	MW-7_202211 (Lab ID: 40254467009)

•	Chromium, Hexavalent

•	MW-8A_202211 (Lab ID: 40254467012)

•	Chromium, Hexavalent

•	MW-8_202211 (Lab ID: 40254467011)

•	Chromium, Hexavalent

•	MW-9_202211 (Lab ID: 40254467013)

•	Chromium, Hexavalent

ceAnalytical

www.pacaliki.coni

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 8 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

PROJECT NARRATIVE

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Method: EPA 335.4
Description: 335.4 Cyanide, Total

Client: FOTH INFRASTRUCTURE & ENVIRONMENT
Date:	November 18, 2022

ceAnalytical

www.pacaliki.coni

General Information:

1 sample was analyzed for EPA 335.4 by Pace Analytical Services Green Bay. All samples were received in acceptable condition with
any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.

Hold Time:

The samples were analyzed within the method required hold times with any exceptions noted below.

Sample Preparation:

The samples were prepared in accordance with EPA 335.4 with any exceptions noted below.

Method Blank:

All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.

Laboratory Control Spike:

All laboratory control spike compounds were within QC limits with any exceptions noted below.

Matrix Spikes:

All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 431488

A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 40254224001,40254629001
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.

•MS (Lab ID: 2484904)

•	Cyanide

•MS (Lab ID: 2484906)

•	Cyanide

•	MSD (Lab ID: 2484905)

•	Cyanide

•	MSD (Lab ID: 2484907)

•	Cyanide

Additional Comments:

Analyte Comments:

QC Batch: 431488

D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.

•	ZINC SHOP_202211 (Lab ID: 40254467017)

•	Cyanide

This data package has been reviewed for quality and completeness and is approved for release.

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 9 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: W-1 202211	Lab ID: 40254467001 Collected: 11/09/22 11:50 Received: 11/09/22 15:43 Matrix: Water

Parameters	Results	Units	LOQ LOD DF Prepared	Analyzed CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

11/1

0/22

23:43

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/1

0/22

23:43

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/1

0/22

23:43

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/1

0/22

23:43

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/1

0/22

23:43

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/1

0/22

23:43

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/1

0/22

23:43

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/1

0/22

23:43

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/1

0/22

23:43

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/1

0/22

23:43

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/1

0/22

23:43

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/1

0/22

23:43

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/1

0/22

23:43

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/1

0/22

23:43

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/1

0/22

23:43

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/1

0/22

23:43

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/1

0/22

23:43

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/1

0/22

23:43

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/1

0/22

23:43

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/1

0/22

23:43

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/1

0/22

23:43

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/1

0/22

23:43

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/1

0/22

23:43

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/1

0/22

23:43

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/1

0/22

23:43

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/1

0/22

23:43

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/1

0/22

23:43

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/1

0/22

23:43

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/1

0/22

23:43

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/1

0/22

23:43

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/1

0/22

23:43

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/1

0/22

23:43

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/1

0/22

23:43

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/1

0/22

23:43

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/1

0/22

23:43

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/1

0/22

23:43

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/1

0/22

23:43

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/1

0/22

23:43

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/1

0/22

23:43

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/1

0/22

23:43

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/1

0/22

23:43

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/1

0/22

23:43

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/1

0/22

23:43

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/1

0/22

23:43

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/1

0/22

23:43

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 10 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: W-1_202211

Lab ID:

40254467001

Collected:

11/09/22 11:50

Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260









Pace Analytical Services -

Green Bay







1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1

11/10/22 23:43

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1

11/10/22 23:43

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1

11/10/22 23:43

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1

11/10/22 23:43

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1

11/10/22 23:43

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1

11/10/22 23:43

120-82-1

1,1,1-Trichloroethane

4.4

ug/L

1.0

0.30 1

11/10/22 23:43

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1

11/10/22 23:43

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1

11/10/22 23:43

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1

11/10/22 23:43

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1

11/10/22 23:43

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1

11/10/22 23:43

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1

11/10/22 23:43

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1

11/10/22 23:43

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1

11/10/22 23:43

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1

11/10/22 23:43

95-47-6

Surrogates













4-Bromofluorobenzene (S)

102

%

70-130

1

11/10/22 23:43

460-00-4

1,2-Dichlorobenzene-d4 (S)

103

%

70-130

1

11/10/22 23:43

2199-69-1

Toluene-d8 (S)

93

%

70-130

1

11/10/22 23:43

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

2.0 mg/L	0.24

0.073 10

11/11/22 13:55

M0

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.	Page 11 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: W-1A_202211

Lab ID:

40254467002

Collected:

11/09/22 11:45

Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260









Pace Analytical Services -

Green Bay







Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 00:03

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 00:03

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 00:03

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 00:03

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 00:03

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 00:03

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 00:03

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 00:03

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 00:03

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 00:03

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 00:03

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/11/22 00:03

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 00:03

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 00:03

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 00:03

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 00:03

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 00:03

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 00:03

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 00:03

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 00:03

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 00:03

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 00:03

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 00:03

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 00:03

75-71-8

1,1-Dichloroethane

1.4

ug/L

1.0

0.30 1

11/11/22 00:03

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 00:03

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/11/22 00:03

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 00:03

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 00:03

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 00:03

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 00:03

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 00:03

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 00:03

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 00:03

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 00:03

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 00:03

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 00:03

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 00:03

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 00:03

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 00:03

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 00:03

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 00:03

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 00:03

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 00:03

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 00:03

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 12 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: W-1A_202211

Lab ID: 40254467002 Collected: 11/09/22 11:45 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD

8260 MSV

Analytical Method: EPA 8260





Pace Analytical Services -

Green Bay



1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

Tetrachloroethene

<0.41

ug/L

1.0

0.41

Toluene

<0.29

ug/L

1.0

0.29

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1,1,1-Trichloroethane

5.0

ug/L

1.0

0.30

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

Trichloroethene

<0.32

ug/L

1.0

0.32

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

Vinyl chloride

<0.17

ug/L

1.0

0.17

m&p-Xylene

<0.70

ug/L

2.0

0.70

o-Xylene

<0.35

ug/L

1.0

0.35

Surrogates









4-Bromofluorobenzene (S)

99

%

70-130



1,2-Dichlorobenzene-d4 (S)

98

%

70-130



Toluene-d8 (S)

89

%

70-130



DF

Prepared

Analyzed

CAS No.

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

0.79 mg/L	0.061

1/11/22

00:03

630-20-6

1/11/22

00:03

79-34-5

1/11/22

00:03

127-18-4

1/11/22

00:03

108-88-3

1/11/22

00:03

87-61-6

1/11/22

00:03

120-82-1

1/11/22

00:03

71-55-6

1/11/22

00:03

79-00-5

1/11/22

00:03

79-01-6

1/11/22

00:03

75-69-4

1/11/22

00:03

96-18-4

1/11/22

00:03

95-63-6

1/11/22

00:03

108-67-8

1/11/22

00:03

75-01-4

1/11/22

00:03

179601-23-1

1/11/22

00:03

95-47-6

1/11/22

00:03

460-00-4

1/11/22

00:03

2199-69-1

1/11/22

00:03

2037-26-5

0.018 2.5

11/11/22 13:56

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 13 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-2_202211

Lab ID:

40254467003

Collected:

11/09/22 14:00

Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260









Pace Analytical Services -

Green Bay







Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 00:22

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 00:22

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 00:22

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 00:22

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 00:22

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 00:22

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 00:22

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 00:22

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 00:22

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 00:22

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 00:22

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/11/22 00:22

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 00:22

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 00:22

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 00:22

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 00:22

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 00:22

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 00:22

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 00:22

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 00:22

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 00:22

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 00:22

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 00:22

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 00:22

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/11/22 00:22

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 00:22

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/11/22 00:22

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 00:22

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 00:22

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 00:22

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 00:22

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 00:22

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 00:22

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 00:22

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 00:22

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 00:22

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 00:22

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 00:22

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 00:22

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 00:22

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 00:22

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 00:22

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 00:22

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 00:22

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 00:22

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 14 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: MW-2_202211

Lab ID: 40254467003 Collected: 11/09/22 14:00 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD

8260 MSV

Analytical Method: EPA 8260





Pace Analytical Services -

Green Bay



1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

Tetrachloroethene

<0.41

ug/L

1.0

0.41

Toluene

<0.29

ug/L

1.0

0.29

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

Trichloroethene

<0.32

ug/L

1.0

0.32

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

Vinyl chloride

<0.17

ug/L

1.0

0.17

m&p-Xylene

<0.70

ug/L

2.0

0.70

o-Xylene

<0.35

ug/L

1.0

0.35

Surrogates









4-Bromofluorobenzene (S)

101

%

70-130



1,2-Dichlorobenzene-d4 (S)

101

%

70-130



Toluene-d8 (S)

93

%

70-130



DF

Prepared

Analyzed

CAS No.

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.0073 mg/L	0.024 0.0073

1/11/22

00:22

630-20-6

1/11/22

00:22

79-34-5

1/11/22

00:22

127-18-4

1/11/22

00:22

108-88-3

1/11/22

00:22

87-61-6

1/11/22

00:22

120-82-1

1/11/22

00:22

71-55-6

1/11/22

00:22

79-00-5

1/11/22

00:22

79-01-6

1/11/22

00:22

75-69-4

1/11/22

00:22

96-18-4

1/11/22

00:22

95-63-6

1/11/22

00:22

108-67-8

1/11/22

00:22

75-01-4

1/11/22

00:22

179601-23-1

1/11/22

00:22

95-47-6

1/11/22

00:22

460-00-4

1/11/22

00:22

2199-69-1

1/11/22

00:22

2037-26-5

11/11/22 13:58

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 15 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-3R_202211

Lab ID:

40254467004

Collected:

11/09/22 10:55

Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260









Pace Analytical Services -

Green Bay







Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 00:42

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 00:42

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 00:42

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 00:42

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 00:42

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 00:42

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 00:42

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 00:42

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 00:42

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 00:42

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 00:42

108-90-7

Chloroethane

1.5J

ug/L

5.0

1.4 1

11/11/22 00:42

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 00:42

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 00:42

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 00:42

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 00:42

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 00:42

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 00:42

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 00:42

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 00:42

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 00:42

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 00:42

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 00:42

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 00:42

75-71-8

1,1-Dichloroethane

3.6

ug/L

1.0

0.30 1

11/11/22 00:42

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 00:42

107-06-2

1,1-Dichloroethene

1.1

ug/L

1.0

0.58 1

11/11/22 00:42

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 00:42

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 00:42

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 00:42

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 00:42

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 00:42

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 00:42

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 00:42

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 00:42

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 00:42

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 00:42

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 00:42

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 00:42

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 00:42

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 00:42

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 00:42

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 00:42

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 00:42

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 00:42

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 16 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: MW-3R_202211

Lab ID: 40254467004 Collected: 11/09/22 10:55 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD

8260 MSV

Analytical Method: EPA 8260





Pace Analytical Services -

Green Bay



1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

Tetrachloroethene

<0.41

ug/L

1.0

0.41

Toluene

<0.29

ug/L

1.0

0.29

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1,1,1-Trichloroethane

10.2

ug/L

1.0

0.30

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

Trichloroethene

<0.32

ug/L

1.0

0.32

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

Vinyl chloride

<0.17

ug/L

1.0

0.17

m&p-Xylene

<0.70

ug/L

2.0

0.70

o-Xylene

<0.35

ug/L

1.0

0.35

Surrogates









4-Bromofluorobenzene (S)

100

%

70-130



1,2-Dichlorobenzene-d4 (S)

102

%

70-130



Toluene-d8 (S)

89

%

70-130



DF

Prepared

Analyzed

CAS No.

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.073 mg/L	0.24

1/11/22

00:42

630-20-6

1/11/22

00:42

79-34-5

1/11/22

00:42

127-18-4

1/11/22

00:42

108-88-3

1/11/22

00:42

87-61-6

1/11/22

00:42

120-82-1

1/11/22

00:42

71-55-6

1/11/22

00:42

79-00-5

1/11/22

00:42

79-01-6

1/11/22

00:42

75-69-4

1/11/22

00:42

96-18-4

1/11/22

00:42

95-63-6

1/11/22

00:42

108-67-8

1/11/22

00:42

75-01-4

1/11/22

00:42

179601-23-1

1/11/22

00:42

95-47-6

1/11/22

00:42

460-00-4

1/11/22

00:42

2199-69-1

1/11/22

00:42

2037-26-5

0.073 10

11/11/22 13:58

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 17 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-5 202211	Lab ID: 40254467005 Collected: 11/09/22 14:21 Received: 11/09/22 15:43 Matrix: Water

Parameters	Results	Units	LOQ LOD DF Prepared	Analyzed CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 01

01

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 01

01

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 01

01

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 01

01

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 01

01

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 01

01

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 01

01

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 01

01

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 01

01

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 01

01

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 01

01

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/11/22 01

01

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 01

01

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 01

01

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 01

01

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 01

01

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 01

01

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 01

01

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 01

01

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 01

01

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 01

01

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 01

01

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 01

01

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 01

01

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/11/22 01

01

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 01

01

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/11/22 01

01

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 01

01

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 01

01

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 01

01

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 01

01

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 01

01

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 01

01

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 01

01

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 01

01

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 01

01

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 01

01

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 01

01

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 01

01

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 01

01

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 01

01

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 01

01

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 01

01

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 01

01

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 01

01

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 18 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: MW-5_202211

Lab ID: 40254467005 Collected: 11/09/22 14:21 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/11/22 01

01

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/11/22 01

01

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/11/22 01

01

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/11/22 01

01

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/11/22 01

01

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/11/22 01

01

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/11/22 01

01

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/11/22 01

01

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/11/22 01

01

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/11/22 01

01

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/11/22 01

01

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/11/22 01

01

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/11/22 01

01

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/11/22 01

01

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/11/22 01

01

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/11/22 01

01

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

102

%

70-130

1



11/11/22 01

01

460-00-4

1,2-Dichlorobenzene-d4 (S)

102

%

70-130

1



11/11/22 01

01

2199-69-1

Toluene-d8 (S)

92

%

70-130

1



11/11/22 01

01

2037-26-5

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.37 mg/L	1.2

0.37 50

11/11/22 13:58

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 19 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-5A_202211

Parameters

Lab ID: 40254467006 Collected: 11/09/22 14:04 Received: 11/09/22 15:43 Matrix: Water

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<1.8 mg/L	6.1

1.8 250

11/11/22 13:58

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 20 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-6 202211	Lab ID: 40254467007 Collected: 11/09/22 12:26 Received: 11/09/22 15:43 Matrix: Water

Parameters	Results	Units	LOQ LOD DF Prepared	Analyzed CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 01

21

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 01

21

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 01

21

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 01

21

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 01

21

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 01

21

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 01

21

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 01

21

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 01

21

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 01

21

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 01

21

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/11/22 01

21

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 01

21

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 01

21

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 01

21

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 01

21

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 01

21

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 01

21

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 01

21

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 01

21

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 01

21

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 01

21

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 01

21

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 01

21

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/11/22 01

21

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 01

21

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/11/22 01

21

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 01

21

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 01

21

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 01

21

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 01

21

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 01

21

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 01

21

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 01

21

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 01

21

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 01

21

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 01

21

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 01

21

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 01

21

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 01

21

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 01

21

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 01

21

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 01

21

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 01

21

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 01

21

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 21 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: MW-6_202211

Lab ID: 40254467007 Collected: 11/09/22 12:26 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/11/22 01

21

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/11/22 01

21

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/11/22 01

21

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/11/22 01

21

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/11/22 01

21

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/11/22 01

21

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/11/22 01

21

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/11/22 01

21

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/11/22 01

21

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/11/22 01

21

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/11/22 01

21

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/11/22 01

21

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/11/22 01

21

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/11/22 01

21

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/11/22 01

21

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/11/22 01

21

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

99

%

70-130

1



11/11/22 01

21

460-00-4

1,2-Dichlorobenzene-d4 (S)

100

%

70-130

1



11/11/22 01

21

2199-69-1

Toluene-d8 (S)

94

%

70-130

1



11/11/22 01

21

2037-26-5

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<1.8 mg/L	6.1

1.8 250

11/11/22 13:59

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 22 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-6A_202211

Parameters

Lab ID: 40254467008 Collected: 11/09/22 13:10 Received: 11/09/22 15:43 Matrix: Water

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.37 mg/L	1.2 0.37

50

11/11/22 13:59

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 23 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-7 202211	Lab ID: 40254467009 Collected: 11/09/22 11:36 Received: 11/09/22 15:43 Matrix: Water

Parameters	Results	Units	LOQ LOD DF Prepared	Analyzed CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 01

40

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 01

40

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 01

40

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 01

40

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 01

40

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 01

40

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 01

40

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 01

40

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 01

40

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 01

40

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 01

40

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/11/22 01

40

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 01

40

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 01

40

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 01

40

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 01

40

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 01

40

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 01

40

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 01

40

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 01

40

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 01

40

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 01

40

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 01

40

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 01

40

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/11/22 01

40

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 01

40

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/11/22 01

40

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 01

40

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 01

40

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 01

40

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 01

40

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 01

40

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 01

40

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 01

40

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 01

40

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 01

40

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 01

40

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 01

40

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 01

40

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 01

40

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 01

40

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 01

40

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 01

40

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 01

40

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 01

40

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 24 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: MW-7_202211

Lab ID: 40254467009 Collected: 11/09/22 11:36 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/11/22 01

40

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/11/22 01

40

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/11/22 01

40

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/11/22 01

40

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/11/22 01

40

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/11/22 01

40

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/11/22 01

40

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/11/22 01

40

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/11/22 01

40

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/11/22 01

40

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/11/22 01

40

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/11/22 01

40

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/11/22 01

40

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/11/22 01

40

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/11/22 01

40

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/11/22 01

40

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

99

%

70-130

1



11/11/22 01

40

460-00-4

1,2-Dichlorobenzene-d4 (S)

101

%

70-130

1



11/11/22 01

40

2199-69-1

Toluene-d8 (S)

93

%

70-130

1



11/11/22 01

40

2037-26-5

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.37 mg/L	1.2

0.37 50

11/11/22 13:59

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 25 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-7A_202211

Parameters

Lab ID: 40254467010 Collected: 11/09/22 11:15 Received: 11/09/22 15:43 Matrix: Water

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.37 mg/L	1.2 0.37

50

11/11/22 13:59

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 26 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-8_202211

Lab ID:

40254467011

Collected:

11/09/22 11:25

Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260









Pace Analytical Services -

Green Bay







Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 02:00

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 02:00

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 02:00

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 02:00

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 02:00

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 02:00

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 02:00

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 02:00

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 02:00

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 02:00

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 02:00

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/11/22 02:00

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 02:00

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 02:00

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 02:00

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 02:00

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 02:00

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 02:00

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 02:00

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 02:00

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 02:00

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 02:00

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 02:00

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 02:00

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/11/22 02:00

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 02:00

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/11/22 02:00

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 02:00

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 02:00

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 02:00

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 02:00

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 02:00

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 02:00

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 02:00

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 02:00

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 02:00

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 02:00

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 02:00

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 02:00

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 02:00

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 02:00

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 02:00

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 02:00

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 02:00

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 02:00

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 27 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: MW-8_202211

Lab ID: 40254467011 Collected: 11/09/22 11:25 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/11/22 02:00

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/11/22 02:00

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/11/22 02:00

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/11/22 02:00

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/11/22 02:00

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/11/22 02:00

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/11/22 02:00

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/11/22 02:00

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/11/22 02:00

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/11/22 02:00

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/11/22 02:00

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/11/22 02:00

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/11/22 02:00

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/11/22 02:00

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/11/22 02:00

179601-23

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/11/22 02:00

95-47-6

Surrogates















4-Bromofluorobenzene (S)

99

%

70-130

1



11/11/22 02:00

460-00-4

1,2-Dichlorobenzene-d4 (S)

101

%

70-130

1



11/11/22 02:00

2199-69-1

Toluene-d8 (S)

92

%

70-130

1



11/11/22 02:00

2037-26-5

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<1.8 mg/L	6.1

PH

1.8 250

11/11/22 14:00

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 28 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-8A_202211

Parameters

Lab ID: 40254467012 Collected: 11/09/22 10:37 Received: 11/09/22 15:43 Matrix: Water

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.37 mg/L	1.2 0.37

50

11/11/22 14:00

D3

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

Date: 11/18/2022 01:38 PM	without the written consent of Pace Analytical Services, LLC.	Page 29 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-9 202211	Lab ID: 40254467013 Collected: 11/09/22 14:47 Received: 11/09/22 15:43 Matrix: Water

Parameters	Results	Units	LOQ LOD DF Prepared	Analyzed CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 02

19

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 02

19

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 02

19

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 02

19

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 02

19

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 02

19

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 02

19

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 02

19

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 02

19

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 02

19

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 02

19

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/11/22 02

19

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 02

19

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 02

19

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 02

19

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 02

19

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 02

19

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 02

19

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 02

19

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 02

19

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 02

19

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 02

19

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 02

19

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 02

19

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/11/22 02

19

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 02

19

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/11/22 02

19

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 02

19

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 02

19

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 02

19

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 02

19

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 02

19

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 02

19

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 02

19

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 02

19

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 02

19

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 02

19

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 02

19

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 02

19

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 02

19

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 02

19

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 02

19

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 02

19

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 02

19

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 02

19

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 30 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: MW-9_202211

Lab ID: 40254467013 Collected: 11/09/22 14:47 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/11/22 02

19

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/11/22 02

19

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/11/22 02

19

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/11/22 02

19

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/11/22 02

19

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/11/22 02

19

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/11/22 02

19

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/11/22 02

19

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/11/22 02

19

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/11/22 02

19

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/11/22 02

19

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/11/22 02

19

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/11/22 02

19

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/11/22 02

19

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/11/22 02

19

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/11/22 02

19

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

95

%

70-130

1



11/11/22 02

19

460-00-4

1,2-Dichlorobenzene-d4 (S)

100

%

70-130

1



11/11/22 02

19

2199-69-1

Toluene-d8 (S)

93

%

70-130

1



11/11/22 02

19

2037-26-5

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.37 mg/L	1.2

0.37 50

11/11/22 14:00

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 31 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-10_202211

Lab ID:

40254467014

Collected:

11/09/22 14:30

Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260









Pace Analytical Services -

Green Bay







Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 02:38

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 02:38

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 02:38

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 02:38

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 02:38

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 02:38

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 02:38

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 02:38

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 02:38

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 02:38

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 02:38

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/11/22 02:38

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 02:38

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 02:38

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 02:38

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 02:38

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 02:38

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 02:38

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 02:38

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 02:38

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 02:38

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 02:38

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 02:38

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 02:38

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/11/22 02:38

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 02:38

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/11/22 02:38

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 02:38

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 02:38

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 02:38

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 02:38

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 02:38

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 02:38

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 02:38

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 02:38

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 02:38

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 02:38

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 02:38

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 02:38

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 02:38

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 02:38

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 02:38

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 02:38

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 02:38

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 02:38

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 32 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: MW-10_202211

Lab ID: 40254467014 Collected: 11/09/22 14:30 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD

8260 MSV

Analytical Method: EPA 8260





Pace Analytical Services -

Green Bay



1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

Tetrachloroethene

<0.41

ug/L

1.0

0.41

Toluene

<0.29

ug/L

1.0

0.29

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

Trichloroethene

<0.32

ug/L

1.0

0.32

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

Vinyl chloride

<0.17

ug/L

1.0

0.17

m&p-Xylene

<0.70

ug/L

2.0

0.70

o-Xylene

<0.35

ug/L

1.0

0.35

Surrogates









4-Bromofluorobenzene (S)

97

%

70-130



1,2-Dichlorobenzene-d4 (S)

101

%

70-130



Toluene-d8 (S)

90

%

70-130



DF

Prepared

Analyzed

CAS No.

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.37 mg/L	1.2

1/11/22

02:38

630-20-6

1/11/22

02:38

79-34-5

1/11/22

02:38

127-18-4

1/11/22

02:38

108-88-3

1/11/22

02:38

87-61-6

1/11/22

02:38

120-82-1

1/11/22

02:38

71-55-6

1/11/22

02:38

79-00-5

1/11/22

02:38

79-01-6

1/11/22

02:38

75-69-4

1/11/22

02:38

96-18-4

1/11/22

02:38

95-63-6

1/11/22

02:38

108-67-8

1/11/22

02:38

75-01-4

1/11/22

02:38

179601-23-1

1/11/22

02:38

95-47-6

1/11/22

02:38

460-00-4

1/11/22

02:38

2199-69-1

1/11/22

02:38

2037-26-5

0.37 50

11/11/22 14:00

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 33 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-11_202211

Lab ID:

40254467015

Collected:

11/09/22 12:57

Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260









Pace Analytical Services -

Green Bay







Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 02:58

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 02:58

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 02:58

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 02:58

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 02:58

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 02:58

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 02:58

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 02:58

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 02:58

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 02:58

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 02:58

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/11/22 02:58

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 02:58

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 02:58

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 02:58

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 02:58

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 02:58

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 02:58

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 02:58

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 02:58

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 02:58

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 02:58

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 02:58

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 02:58

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/11/22 02:58

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 02:58

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/11/22 02:58

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 02:58

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 02:58

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 02:58

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 02:58

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 02:58

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 02:58

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 02:58

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 02:58

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 02:58

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 02:58

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 02:58

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 02:58

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 02:58

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 02:58

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 02:58

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 02:58

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 02:58

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 02:58

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 34 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: MW-11_202211

Lab ID: 40254467015 Collected: 11/09/22 12:57 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD

8260 MSV

Analytical Method: EPA 8260





Pace Analytical Services -

Green Bay



1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

Tetrachloroethene

<0.41

ug/L

1.0

0.41

Toluene

<0.29

ug/L

1.0

0.29

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1,1,1-Trichloroethane

0.34J

ug/L

1.0

0.30

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

Trichloroethene

<0.32

ug/L

1.0

0.32

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

Vinyl chloride

<0.17

ug/L

1.0

0.17

m&p-Xylene

<0.70

ug/L

2.0

0.70

o-Xylene

<0.35

ug/L

1.0

0.35

Surrogates









4-Bromofluorobenzene (S)

100

%

70-130



1,2-Dichlorobenzene-d4 (S)

103

%

70-130



Toluene-d8 (S)

92

%

70-130



DF

Prepared

Analyzed

CAS No.

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.37 mg/L	1.2

1/11/22

02:58

630-20-6

1/11/22

02:58

79-34-5

1/11/22

02:58

127-18-4

1/11/22

02:58

108-88-3

1/11/22

02:58

87-61-6

1/11/22

02:58

120-82-1

1/11/22

02:58

71-55-6

1/11/22

02:58

79-00-5

1/11/22

02:58

79-01-6

1/11/22

02:58

75-69-4

1/11/22

02:58

96-18-4

1/11/22

02:58

95-63-6

1/11/22

02:58

108-67-8

1/11/22

02:58

75-01-4

1/11/22

02:58

179601-23-1

1/11/22

02:58

95-47-6

1/11/22

02:58

460-00-4

1/11/22

02:58

2199-69-1

1/11/22

02:58

2037-26-5

0.37 50

11/11/22 14:00

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 35 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-12 202211	Lab ID: 40254467016 Collected: 11/09/22 12:13 Received: 11/09/22 15:43 Matrix: Water

Parameters	Results	Units	LOQ LOD DF Prepared	Analyzed CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 03

18 71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 03

18 108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 03

18 74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 03

18 75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 03

18 75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 03

18 74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 03

18 104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 03

18 135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 03

18 98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 03

18 56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 03

18 108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/11/22 03

18 75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 03

18 67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 03

18 74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 03

18 95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 03

18 106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 03

18 96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 03

18 124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 03

18 106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 03

18 74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 03

18 95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 03

18 541-73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 03

18 106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 03

18 75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/11/22 03

18 75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 03

18 107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/11/22 03

18 75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 03

18 156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 03

18 156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 03

18 78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 03

18 142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 03

18 594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 03

18 563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 03

18 10061-01-5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 03

18 10061-02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 03

18 108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 03

18 100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 03

18 87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 03

18 98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 03

18 99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 03

18 75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 03

18 1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 03

18 91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 03

18 103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 03

18 100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 36 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: MW-12_202211

Lab ID: 40254467016 Collected: 11/09/22 12:13 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/11/22 03

18

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/11/22 03

18

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/11/22 03

18

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/11/22 03

18

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/11/22 03

18

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/11/22 03

18

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/11/22 03

18

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/11/22 03

18

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/11/22 03

18

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/11/22 03

18

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/11/22 03

18

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/11/22 03

18

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/11/22 03

18

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/11/22 03

18

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/11/22 03

18

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/11/22 03

18

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

95

%

70-130

1



11/11/22 03

18

460-00-4

1,2-Dichlorobenzene-d4 (S)

99

%

70-130

1



11/11/22 03

18

2199-69-1

Toluene-d8 (S)

91

%

70-130

1



11/11/22 03

18

2037-26-5

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.18 mg/L	0.61

0.18 25

11/11/22 14:00

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 37 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: ZINC SHOP_202211

Lab ID:

40254467017

Collected:

11/09/22 10:20

Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260









Pace Analytical Services -

Green Bay







Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 03:37

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 03:37

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 03:37

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 03:37

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 03:37

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 03:37

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 03:37

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 03:37

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 03:37

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 03:37

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 03:37

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/11/22 03:37

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 03:37

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 03:37

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 03:37

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 03:37

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 03:37

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 03:37

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 03:37

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 03:37

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 03:37

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 03:37

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 03:37

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 03:37

75-71-8

1,1-Dichloroethane

1.9

ug/L

1.0

0.30 1

11/11/22 03:37

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 03:37

107-06-2

1,1-Dichloroethene

1.4

ug/L

1.0

0.58 1

11/11/22 03:37

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 03:37

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 03:37

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 03:37

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 03:37

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 03:37

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 03:37

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 03:37

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 03:37

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 03:37

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 03:37

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 03:37

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 03:37

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 03:37

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 03:37

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 03:37

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 03:37

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 03:37

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 03:37

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 38 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: ZINC SHOP_202211

Lab ID: 40254467017 Collected: 11/09/22 10:20 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD

8260 MSV

Analytical Method: EPA 8260





Pace Analytical Services -

Green Bay



1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

Tetrachloroethene

0.93J

ug/L

1.0

0.41

Toluene

<0.29

ug/L

1.0

0.29

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1,1,1-Trichloroethane

20.2

ug/L

1.0

0.30

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

Trichloroethene

<0.32

ug/L

1.0

0.32

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

Vinyl chloride

<0.17

ug/L

1.0

0.17

m&p-Xylene

<0.70

ug/L

2.0

0.70

o-Xylene

<0.35

ug/L

1.0

0.35

Surrogates









4-Bromofluorobenzene (S)

99

%

70-130



1,2-Dichlorobenzene-d4 (S)

102

%

70-130



Toluene-d8 (S)

91

%

70-130



DF

Prepared

Analyzed

CAS No.

Qual

Chromium, Hexavalent

Chromium, Hexavalent
335.4 Cyanide, Total

Cyanide

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

4.2 mg/L	0.24

0.073 10

1/11/22

03:37

630-20-6

1/11/22

03:37

79-34-5

1/11/22

03:37

127-18-4

1/11/22

03:37

108-88-3

1/11/22

03:37

87-61-6

1/11/22

03:37

120-82-1

1/11/22

03:37

71-55-6

1/11/22

03:37

79-00-5

1/11/22

03:37

79-01-6

1/11/22

03:37

75-69-4

1/11/22

03:37

96-18-4

1/11/22

03:37

95-63-6

1/11/22

03:37

108-67-8

1/11/22

03:37

75-01-4

1/11/22

03:37

179601-23-1

1/11/22

03:37

95-47-6

1/11/22

03:37

460-00-4

1/11/22

03:37

2199-69-1

1/11/22

03:37

2037-26-5

11/11/22 14:02

Analytical Method: EPA 335.4 Preparation Method: EPA 335.4
Pace Analytical Services - Green Bay

0.075J mg/L	0.14 0.041 1 11/15/22 10:30 11/15/22 12:46 57-12-5

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 39 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

Sample: MW-3RD 202211	Lab ID: 40254467018 Collected: 11/09/22 10:55 Received: 11/09/22 15:43 Matrix: Water

Parameters	Results	Units	LOQ LOD DF Prepared	Analyzed CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

11/11/22 23

11

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/11/22 23

11

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/11/22 23

11

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/11/22 23

11

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/11/22 23

11

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/11/22 23

11

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 23

11

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/11/22 23

11

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/11/22 23

11

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/11/22 23

11

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/11/22 23

11

108-90-7

Chloroethane

1.5J

ug/L

5.0

1.4 1

11/11/22 23

11

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/11/22 23

11

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/11/22 23

11

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 23

11

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/11/22 23

11

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/11/22 23

11

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/11/22 23

11

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/11/22 23

11

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/11/22 23

11

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 23

11

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 23

11

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/11/22 23

11

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/11/22 23

11

75-71-8

1,1-Dichloroethane

3.8

ug/L

1.0

0.30 1

11/11/22 23

11

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/11/22 23

11

107-06-2

1,1-Dichloroethene

0.91J

ug/L

1.0

0.58 1

11/11/22 23

11

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/11/22 23

11

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/11/22 23

11

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/11/22 23

11

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/11/22 23

11

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/11/22 23

11

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/11/22 23

11

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/11/22 23

11

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/11/22 23

11

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 23

11

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/11/22 23

11

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/11/22 23

11

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/11/22 23

11

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/11/22 23

11

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/11/22 23

11

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/11/22 23

11

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/11/22 23

11

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/11/22 23

11

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/11/22 23

11

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 40 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: MW-3RD_202211

Lab ID: 40254467018 Collected: 11/09/22 10:55 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/11/22 23

11

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/11/22 23

11

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/11/22 23

11

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/11/22 23

11

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/11/22 23

11

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/11/22 23

11

120-82-1

1,1,1-Trichloroethane

9.5

ug/L

1.0

0.30 1



11/11/22 23

11

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/11/22 23

11

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/11/22 23

11

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/11/22 23

11

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/11/22 23

11

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/11/22 23

11

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/11/22 23

11

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/11/22 23

11

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/11/22 23

11

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/11/22 23

11

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

108

%

70-130

1



11/11/22 23

11

460-00-4

1,2-Dichlorobenzene-d4 (S)

101

%

70-130

1



11/11/22 23

11

2199-69-1

Toluene-d8 (S)

101

%

70-130

1



11/11/22 23

11

2037-26-5

Qual

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.18 mg/L	0.61

0.18 25

11/11/22 14:03

D3

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 41 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: TB1_202211

Lab ID:

40254467019

Collected:

11/09/2

Parameters

Results

Units

LOQ

LOD

8260 MSV

Analytical Method: EPA 8260





Pace Analytical Services -

Green Bay



Benzene

<0.30

ug/L

1.0

0.30

Bromobenzene

<0.36

ug/L

1.0

0.36

Bromochloromethane

<0.36

ug/L

5.0

0.36

Bromodichloromethane

<0.42

ug/L

1.0

0.42

Bromoform

<3.8

ug/L

5.0

3.8

Bromomethane

<1.2

ug/L

5.0

1.2

n-Butylbenzene

<0.86

ug/L

1.0

0.86

sec-Butylbenzene

<0.42

ug/L

1.0

0.42

tert-Butylbenzene

<0.59

ug/L

1.0

0.59

Carbon tetrachloride

<0.37

ug/L

1.0

0.37

Chlorobenzene

<0.86

ug/L

1.0

0.86

Chloroethane

<1.4

ug/L

5.0

1.4

Chloroform

<1.2

ug/L

5.0

1.2

Chloromethane

<1.6

ug/L

5.0

1.6

2-Chlorotoluene

<0.89

ug/L

5.0

0.89

4-Chlorotoluene

<0.89

ug/L

5.0

0.89

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4

Dibromochloromethane

<2.6

ug/L

5.0

2.6

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31

Dibromomethane

<0.99

ug/L

5.0

0.99

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5

Diisopropyl ether

<1.1

ug/L

5.0

1.1

Ethylbenzene

<0.33

ug/L

1.0

0.33

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0

Methylene Chloride

<0.32

ug/L

5.0

0.32

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

Naphthalene

<1.1

ug/L

5.0

1.1

n-Propylbenzene

<0.35

ug/L

1.0

0.35

Styrene

<0.36

ug/L

1.0

0.36

Received: 11/09/22 15:43 Matrix: Water

DF

Prepared

Analyzed

CAS No.

Qual

/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15
/11/22 15

:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33
:33

71-43-2
108-86-1

74-97-5

75-27-4
75-25-2

74-83-9

104-51-8
135-98-8
98-06-6
56-23-5
108-90-7

75-00-3
67-66-3
74-87-3

95-49-8

106-43-4

96-12-8

124-48-1
106-93-4

74-95-3
95-50-1
541 -73-1

106-46-7

75-71-8
75-34-3

107-06-2
75-35-4

156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061 -01 -5
10061 -02-6

108-20-3
100-41-4
87-68-3

98-82-8

99-87-6
75-09-2

1634-04-4
91-20-3
103-65-1

100-42-5

v1

L1

REPORT OF LABORATORY ANALYSIS

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 42 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Sample: TB1_202211

Lab ID: 40254467019 Collected: 11/09/22 00:00 Received: 11/09/22 15:43 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/11/22 18:33

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/11/22 18:33

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/11/22 18:33

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/11/22 18:33

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/11/22 18:33

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/11/22 18:33

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/11/22 18:33

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/11/22 18:33

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/11/22 18:33

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/11/22 18:33

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/11/22 18:33

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/11/22 18:33

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/11/22 18:33

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/11/22 18:33

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/11/22 18:33

179601-23

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/11/22 18:33

95-47-6

Surrogates















4-Bromofluorobenzene (S)

106

%

70-130

1



11/11/22 18:33

460-00-4

1,2-Dichlorobenzene-d4 (S)

99

%

70-130

1



11/11/22 18:33

2199-69-1

Toluene-d8 (S)

101

%

70-130

1



11/11/22 18:33

2037-26-5

Qual

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 43 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

QC Batch:	431146	Analysis Method:	EPA 8260

QC Batch Method: EPA 8260	Analysis Description: 8260 MSV

Laboratory:	Pace Analytical Services - Green Bay

40254467001, 40254467002, 40254467003, 40254467004, 40254467005, 40254467007, 40254467009,
40254467011, 40254467013, 40254467014, 40254467015, 40254467016, 40254467017

Associated Lab Samples:

METHOD BLANK: 2482694
Associated Lab Samples:

40254467001,
40254467011,

40254467002,
40254467013,

Matrix: Water

40254467003, 40254467004,
40254467014, 40254467015,

Blank

Reporting

Parameter

Units

Result

Limit

Analyzed

1,1,1,2-Tetrachloroethane

ug/L

<0.36

1.0

11/10/22 17:32

1,1,1-Trichloroethane

ug/L

<0.30

1.0

11/10/22 17:32

1,1,2,2-Tetrachloroethane

ug/L

<0.38

1.0

11/10/22 17:32

1,1,2-Trichloroethane

ug/L

<0.34

5.0

11/10/22 17:32

1,1-Dichloroethane

ug/L

<0.30

1.0

11/10/22 17:32

1,1-Dichloroethene

ug/L

<0.58

1.0

11/10/22 17:32

1,1-Dichloropropene

ug/L

<0.41

1.0

11/10/22 17:32

1,2,3-Trichlorobenzene

ug/L

<1.0

5.0

11/10/22 17:32

1,2,3-Trichloropropane

ug/L

<0.56

5.0

11/10/22 17:32

1,2,4-Trichlorobenzene

ug/L

<0.95

5.0

11/10/22 17:32

1,2,4-Trimethylbenzene

ug/L

<0.45

1.0

11/10/22 17:32

1,2-Dibromo-3-chloropropane

ug/L

<2.4

5.0

11/10/22 17:32

1,2-Dibromoethane (EDB)

ug/L

<0.31

1.0

11/10/22 17:32

1,2-Dichlorobenzene

ug/L

<0.33

1.0

11/10/22 17:32

1,2-Dichloroethane

ug/L

<0.29

1.0

11/10/22 17:32

1,2-Dichloropropane

ug/L

<0.45

1.0

11/10/22 17:32

1,3,5-Trimethylbenzene

ug/L

<0.36

1.0

11/10/22 17:32

1,3-Dichlorobenzene

ug/L

<0.35

1.0

11/10/22 17:32

1,3-Dichloropropane

ug/L

<0.30

1.0

11/10/22 17:32

1,4-Dichlorobenzene

ug/L

<0.89

1.0

11/10/22 17:32

2,2-Dichloropropane

ug/L

<4.2

5.0

11/10/22 17:32

2-Chlorotoluene

ug/L

<0.89

5.0

11/10/22 17:32

4-Chlorotoluene

ug/L

<0.89

5.0

11/10/22 17:32

Benzene

ug/L

<0.30

1.0

11/10/22 17:32

Bromobenzene

ug/L

<0.36

1.0

11/10/22 17:32

Bromochloromethane

ug/L

<0.36

5.0

11/10/22 17:32

Bromodichloromethane

ug/L

<0.42

1.0

11/10/22 17:32

Bromoform

ug/L

<3.8

5.0

11/10/22 17:32

Bromomethane

ug/L

<1.2

5.0

11/10/22 17:32

Carbon tetrachloride

ug/L

<0.37

1.0

11/10/22 17:32

Chlorobenzene

ug/L

<0.86

1.0

11/10/22 17:32

Chloroethane

ug/L

<1.4

5.0

11/10/22 17:32

Chloroform

ug/L

<1.2

5.0

11/10/22 17:32

Chloromethane

ug/L

<1.6

5.0

11/10/22 17:32

cis-1,2-Dichloroethene

ug/L

<0.47

1.0

11/10/22 17:32

cis-1,3-Dichloropropene

ug/L

<0.36

1.0

11/10/22 17:32

Dibromochloromethane

ug/L

<2.6

5.0

11/10/22 17:32

Dibromomethane

ug/L

<0.99

5.0

11/10/22 17:32

Dichlorodifluoromethane

ug/L

<0.46

5.0

11/10/22 17:32

40254467005, 40254467007, 40254467009,
40254467016, 40254467017

Qualifiers

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 44 of 59

-------
Pace Analytical Services, LLC

irpAnah/tiral*	1241 Bellevue street"Suite 9

1UG ni laiy llual	Green Bay, Wl 54302

WWW.pctIallS.com	(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

METHOD BLANK: 2482694	Matrix: Water

Associated Lab Samples: 40254467001, 40254467002, 40254467003, 40254467004, 40254467005, 40254467007, 40254467009,
40254467011, 40254467013, 40254467014, 40254467015, 40254467016, 40254467017

Blank	Reporting

Parameter	Units	Result	Limit	Analyzed	Qualifiers

Diisopropyl ether

ug/L

<1.1

5.0

11/1

0/22

17:32

Ethylbenzene

ug/L

<0.33

1.0

11/1

0/22

17:32

Hexachloro-1,3-butadiene

ug/L

<2.7

5.0

11/1

0/22

17:32

Isopropylbenzene (Cumene)

ug/L

<1.0

5.0

11/1

0/22

17:32

m&p-Xylene

ug/L

<0.70

2.0

11/1

0/22

17:32

Methyl-tert-butyl ether

ug/L

<1.1

5.0

11/1

0/22

17:32

Methylene Chloride

ug/L

<0.32

5.0

11/1

0/22

17:32

n-Butylbenzene

ug/L

<0.86

1.0

11/1

0/22

17:32

n-Propylbenzene

ug/L

<0.35

1.0

11/1

0/22

17:32

Naphthalene

ug/L

<1.1

5.0

11/1

0/22

17:32

o-Xylene

ug/L

<0.35

1.0

11/1

0/22

17:32

p-lsopropyltoluene

ug/L

<1.0

5.0

11/1

0/22

17:32

sec-Butylbenzene

ug/L

<0.42

1.0

11/1

0/22

17:32

Styrene

ug/L

<0.36

1.0

11/1

0/22

17:32

tert-Butylbenzene

ug/L

<0.59

1.0

11/1

0/22

17:32

Tetrachloroethene

ug/L

<0.41

1.0

11/1

0/22

17:32

Toluene

ug/L

<0.29

1.0

11/1

0/22

17:32

trans-1,2-Dichloroethene

ug/L

<0.53

1.0

11/1

0/22

17:32

trans-1,3-Dichloropropene

ug/L

<3.5

5.0

11/1

0/22

17:32

Trichloroethene

ug/L

<0.32

1.0

11/1

0/22

17:32

Trichlorofluoromethane

ug/L

<0.42

1.0

11/1

0/22

17:32

Vinyl chloride

ug/L

<0.17

1.0

11/1

0/22

17:32

1,2-Dichlorobenzene-d4 (S)

%

100

70-130

11/1

0/22

17:32

4-Bromofluorobenzene (S)

%

101

70-130

11/1

0/22

17:32

Toluene-d8 (S)

%

95

70-130

11/1

0/22

17:32

LABORATORY CONTROL SAMPLE: 2482695

Spike

LCS

LCS

% Rec

Parameter

Units

Cone.

Result

% Rec

Limits

1,1,1-Trichloroethane

ug/L

50

52.7

105

70-134

1,1,2,2-Tetrachloroethane

ug/L

50

42.8

86

69-130

1,1,2-Trichloroethane

ug/L

50

45.4

91

70-130

1,1-Dichloroethane

ug/L

50

53.9

108

70-130

1,1-Dichloroethene

ug/L

50

59.9

120

74-131

1,2,4-Trichlorobenzene

ug/L

50

43.9

88

68-130

1,2-Dibromo-3-chloropropane

ug/L

50

35.2

70

64-137

1,2-Dibromoethane (EDB)

ug/L

50

47.0

94

70-130

1,2-Dichlorobenzene

ug/L

50

45.1

90

70-130

1,2-Dichloroethane

ug/L

50

56.1

112

70-137

1,2-Dichloropropane

ug/L

50

51.2

102

80-121

1,3-Dichlorobenzene

ug/L

50

48.4

97

70-130

1,4-Dichlorobenzene

ug/L

50

43.9

88

70-130

Benzene

ug/L

50

54.8

110

70-130

Qualifiers

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 45 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

LABORATORY CONTROL SAMPLE:

2482695





















Spike

LCS

LCS

% Rec







Parameter



Units

Cone. Result

% Rec

Limits Qualifiers





Bromodichloromethane



ug/L

50

49.1

98

70-130







Bromoform



ug/L

50

51.5

103

70-130







Bromomethane



ug/L

50

38.2

76

21-147







Carbon tetrachloride



ug/L

50

58.2

116

80-146







Chlorobenzene



ug/L

50

47.8

96

70-130







Chloroethane



ug/L

50

50.5

101

52-165







Chloroform



ug/L

50

51.8

104

80-123







Chloromethane



ug/L

50

42.1

84

51-122







cis-1,2-Dichloroethene



ug/L

50

53.2

106

70-130







cis-1,3-Dichloropropene



ug/L

50

49.5

99

70-130







Dibromochloromethane



ug/L

50

46.0

92

70-130







Dichlorodifluoromethane



ug/L

50

27.7

55

25-121







Ethylbenzene



ug/L

50

48.0

96

80-120







Isopropylbenzene (Cumene)



ug/L

50

48.1

96

70-130







m&p-Xylene



ug/L

100

95.9

96

70-130







Methyl-tert-butyl ether



ug/L

50

53.9

108

70-130







Methylene Chloride



ug/L

50

52.7

105

70-130







o-Xylene



ug/L

50

47.7

95

70-130







Styrene



ug/L

50

47.2

94

70-130







Tetrachloroethene



ug/L

50

52.2

104

70-130







Toluene



ug/L

50

47.3

95

80-120







trans-1,2-Dichloroethene



ug/L

50

55.8

112

70-130







trans-1,3-Dichloropropene



ug/L

50

44.4

89

70-130







Trichloroethene



ug/L

50

55.8

112

70-130







Trichlorofluoromethane



ug/L

50

61.6

123

65-160







Vinyl chloride



ug/L

50

46.3

93

63-134







1,2-Dichlorobenzene-d4 (S)



%





100

70-130







4-Bromofluorobenzene (S)



%





97

70-130







Toluene-d8 (S)



%





91

70-130







MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2483004

2483005

















MS MSD

















40254459014

Spike Spike

MS

MSD

MS MSD

% Rec



Max

Parameter

Units

Result

Cone. Cone.

Result

Result

% Rec % Rec

Limits

RPD

RPD Qual

1,1,1-Trichloroethane

ug/L

<0.30

50

50 53.4

53.9

107 108

70-134

1

20

1,1,2,2-Tetrachloroethane

ug/L

<0.38

50

50 45.0

45.6

90 91

61-135

1

20

1,1,2-Trichloroethane

ug/L

<0.34

50

50 46.3

47.8

93 96

70-130

3

20

1,1-Dichloroethane

ug/L

0.59J

50

50 55.4

55.3

110 110

70-130

0

20

1,1-Dichloroethene

ug/L

<0.58

50

50 59.9

58.0

120 116

71-130

3

20

1,2,4-Trichlorobenzene

ug/L

<0.95

50

50 47.8

48.8

96 98

68-131

2

20

1,2-Dibromo-3-

ug/L

<2.4

50

50 36.6

39.2

73 78

51-141

7

20

chloropropane

















1,2-Dibromoethane (EDB)

ug/L

<0.31

50

50 48.0

48.7

96 97

70-130

1

20

1,2-Dichlorobenzene

ug/L

<0.33

50

50 46.7

48.1

93 96

70-130

3

20

1,2-Dichloroethane

ug/L

<0.29

50

50 55.6

58.2

111 116

70-137

4

20

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 46 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2483004	2483005

Parameter

Units

40254459014
Result

MS
Spike
Cone.

MSD
Spike
Cone.

MS
Result

MSD
Result

MS
% Rec

MSD
% Rec

% Rec
Limits

RPD

Max
RPD

1,2-Dichloropropane

ug/L

0.48 J

50

50

54.0

53.4

107

106

80-121

1

20

1,3-Dichlorobenzene

ug/L

<0.35

50

50

50.8

51.0

102

102

70-130

0

20

1,4-Dichlorobenzene

ug/L

<0.89

50

50

45.8

46.2

92

92

70-130

1

20

Benzene

ug/L

<0.30

50

50

55.7

55.0

111

110

70-130

1

20

Bromodichloromethane

ug/L

<0.42

50

50

51.4

51.4

103

103

70-130

0

20

Bromoform

ug/L

<3.8

50

50

52.6

53.8

105

108

70-133

2

20

Bromomethane

ug/L

<1.2

50

50

45.0

45.1

90

90

21-149

0

22

Carbon tetrachloride

ug/L

<0.37

50

50

59.0

58.9

118

118

80-146

0

20

Chlorobenzene

ug/L

<0.86

50

50

49.3

49.8

99

100

70-130

1

20

Chloroethane

ug/L

2.1 J

50

50

53.9

53.0

104

102

52-165

2

20

Chloroform

ug/L

<1.2

50

50

54.7

54.2

109

108

80-123

1

20

Chloromethane

ug/L

<1.6

50

50

41.6

42.2

83

84

42-125

1

20

cis-1,2-Dichloroethene

ug/L

1.1

50

50

56.9

56.6

112

111

70-130

1

20

cis-1,3-Dichloropropene

ug/L

<0.36

50

50

51.8

52.0

104

104

70-130

0

20

Dibromochloromethane

ug/L

<2.6

50

50

48.2

49.6

96

99

70-130

3

20

Dichlorodifluoromethane

ug/L

<0.46

50

50

28.8

28.3

58

57

25-121

2

20

Ethylbenzene

ug/L

<0.33

50

50

48.9

49.9

98

100

80-121

2

20

Isopropylbenzene

ug/L

<1.0

50

50

49.4

49.2

99

98

70-130

0

20

(Cumene)





















m&p-Xylene

ug/L

<0.70

100

100

99.3

98.1

99

98

70-130

1

20

Methyl-tert-butyl ether

ug/L

<1.1

50

50

56.6

55.6

113

111

70-130

2

20

Methylene Chloride

ug/L

<0.32

50

50

55.8

54.0

112

108

70-130

3

20

o-Xylene

ug/L

<0.35

50

50

49.3

48.2

99

96

70-130

2

20

Styrene

ug/L

<0.36

50

50

49.4

49.4

99

99

70-132

0

20

Tetrachloroethene

ug/L

<0.41

50

50

54.2

52.1

108

104

70-130

4

20

Toluene

ug/L

<0.29

50

50

49.8

49.9

100

100

80-120

0

20

trans-1,2-Dichloroethene

ug/L

<0.53

50

50

57.4

56.9

115

114

70-130

1

20

trans-1,3-Dichloropropene

ug/L

<3.5

50

50

46.3

47.0

93

94

70-130

1

20

Trichloroethene

ug/L

<0.32

50

50

56.1

55.5

112

111

70-130

1

20

Trichlorofluoromethane

ug/L

<0.42

50

50

61.1

61.0

122

122

65-160

0

20

Vinyl chloride

ug/L

0.48 J

50

50

47.4

47.5

94

94

60-137

0

20

1,2-Dichlorobenzene-d4 (S)

%











100

100

70-130





4-Bromofluorobenzene (S)

%











99

100

70-130





Toluene-d8 (S)

%











93

92

70-130





ceAnalytical

www.pacaliki.coni

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
Date: 11/18/2022 01:38 PM	without the written consent of Pace Analytical Services, LLC.

Page 47 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

QC Batch:
QC Batch Method:

431217
EPA 8260

Analysis Method:
Analysis Description:
Laboratory:

EPA 8260
8260 MSV

Pace Analytical Services - Green Bay

Associated Lab Samples: 40254467018, 40254467019

METHOD BLANK: 2483115

Associated Lab Samples: 40254467018, 40254467019

Matrix: Water

Blank

Reporting

Parameter

Units

Result

Limit

Analyzed

1,1,1,2-Tetrachloroethane

ug/L

<0.36

1.0

1/11/22 15:23

1,1,1-Trichloroethane

ug/L

<0.30

1.0

1/11/22 15:23

1,1,2,2-Tetrachloroethane

ug/L

<0.38

1.0

1/11/22 15:23

1,1,2-Trichloroethane

ug/L

<0.34

5.0

1/11/22 15:23

1,1-Dichloroethane

ug/L

<0.30

1.0

1/11/22 15:23

1,1-Dichloroethene

ug/L

<0.58

1.0

1/11/22 15:23

1,1-Dichloropropene

ug/L

<0.41

1.0

1/11/22 15:23

1,2,3-Trichlorobenzene

ug/L

<1.0

5.0

1/11/22 15:23

1,2,3-Trichloropropane

ug/L

<0.56

5.0

1/11/22 15:23

1,2,4-Trichlorobenzene

ug/L

<0.95

5.0

1/11/22 15:23

1,2,4-Trimethylbenzene

ug/L

<0.45

1.0

1/11/22 15:23

1,2-Dibromo-3-chloropropane

ug/L

<2.4

5.0

1/11/22 15:23

1,2-Dibromoethane (EDB)

ug/L

<0.31

1.0

1/11/22 15:23

1,2-Dichlorobenzene

ug/L

<0.33

1.0

1/11/22 15:23

1,2-Dichloroethane

ug/L

<0.29

1.0

1/11/22 15:23

1,2-Dichloropropane

ug/L

<0.45

1.0

1/11/22 15:23

1,3,5-Trimethylbenzene

ug/L

<0.36

1.0

1/11/22 15:23

1,3-Dichlorobenzene

ug/L

<0.35

1.0

1/11/22 15:23

1,3-Dichloropropane

ug/L

<0.30

1.0

1/11/22 15:23

1,4-Dichlorobenzene

ug/L

<0.89

1.0

1/11/22 15:23

2,2-Dichloropropane

ug/L

<4.2

5.0

1/11/22 15:23

2-Chlorotoluene

ug/L

<0.89

5.0

1/11/22 15:23

4-Chlorotoluene

ug/L

<0.89

5.0

1/11/22 15:23

Benzene

ug/L

<0.30

1.0

1/11/22 15:23

Bromobenzene

ug/L

<0.36

1.0

1/11/22 15:23

Bromochloromethane

ug/L

<0.36

5.0

1/11/22 15:23

Bromodichloromethane

ug/L

<0.42

1.0

1/11/22 15:23

Bromoform

ug/L

<3.8

5.0

1/11/22 15:23

Bromomethane

ug/L

<1.2

5.0

1/11/22 15:23 v1

Carbon tetrachloride

ug/L

<0.37

1.0

1/11/22 15:23

Chlorobenzene

ug/L

<0.86

1.0

1/11/22 15:23

Chloroethane

ug/L

<1.4

5.0

1/11/22 15:23

Chloroform

ug/L

<1.2

5.0

1/11/22 15:23

Chloromethane

ug/L

<1.6

5.0

1/11/22 15:23

cis-1,2-Dichloroethene

ug/L

<0.47

1.0

1/11/22 15:23

cis-1,3-Dichloropropene

ug/L

<0.36

1.0

1/11/22 15:23

Dibromochloromethane

ug/L

<2.6

5.0

1/11/22 15:23

Dibromomethane

ug/L

<0.99

5.0

1/11/22 15:23

Dichlorodifluoromethane

ug/L

<0.46

5.0

1/11/22 15:23

Diisopropyl ether

ug/L

<1.1

5.0

1/11/22 15:23

Qualifiers

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 48 of 59

-------
Pace Analytical Services, LLC

irpAnah/tiral*	1241 Bellevue street"Suite 9

1UG ni laiy llual	Green Bay, Wl 54302

WWW.pctIallS.com	(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

METHOD BLANK: 2483115

Associated Lab Samples: 40254467018, 40254467019

Parameter

Units

Ethylbenzene

ug/L

Hexachloro-1,3-butadiene

ug/L

Isopropylbenzene (Cumene)

ug/L

m&p-Xylene

ug/L

Methyl-tert-butyl ether

ug/L

Methylene Chloride

ug/L

n-Butylbenzene

ug/L

n-Propylbenzene

ug/L

Naphthalene

ug/L

o-Xylene

ug/L

p-lsopropyltoluene

ug/L

sec-Butylbenzene

ug/L

Styrene

ug/L

tert-Butylbenzene

ug/L

Tetrachloroethene

ug/L

Toluene

ug/L

trans-1,2-Dichloroethene

ug/L

trans-1,3-Dichloropropene

ug/L

Trichloroethene

ug/L

Trichlorofluoromethane

ug/L

Vinyl chloride

ug/L

1,2-Dichlorobenzene-d4 (S)

%

4-Bromofluorobenzene (S)

%

Toluene-d8 (S)

%

Matrix: Water

Blank	Reporting

Result	Limit Analyzed	Qualifiers

<0.33	1.0	11/11/22 15:23

<2.7	5.0	11/11/22 15:23

<1.0	5.0	11/11/22 15:23

<0.70	2.0	11/11/22 15:23

<1.1	5.0	11/11/22 15:23

<0.32	5.0	11/11/22 15:23

<0.86	1.0	11/11/22 15:23

<0.35	1.0	11/11/22 15:23

<1.1	5.0	11/11/22 15:23

<0.35	1.0	11/11/22 15:23

<1.0	5.0	11/11/22 15:23

<0.42	1.0	11/11/22 15:23

<0.36	1.0	11/11/22 15:23

<0.59	1.0	11/11/22 15:23

<0.41	1.0	11/11/22 15:23

<0.29	1.0	11/11/22 15:23

<0.53	1.0	11/11/22 15:23

<3.5	5.0	11/11/22 15:23

<0.32	1.0	11/11/22 15:23

<0.42	1.0	11/11/22 15:23

<0.17	1.0	11/11/22 15:23

101	70-130	11/11/22 15:23

108	70-130	11/11/22 15:23

102	70-130	11/11/22 15:23

LABORATORY CONTROL SAMPLE: 2483116

Spike

LCS

LCS

% Rec

Parameter

Units

Cone.

Result

% Rec

Limits

1,1,1-Trichloroethane

ug/L

50

47.6

95

70-134

1,1,2,2-Tetrachloroethane

ug/L

50

56.5

113

69-130

1,1,2-Trichloroethane

ug/L

50

54.6

109

70-130

1,1-Dichloroethane

ug/L

50

52.3

105

70-130

1,1-Dichloroethene

ug/L

50

52.0

104

74-131

1,2,4-Trichlorobenzene

ug/L

50

41.5

83

68-130

1,2-Dibromo-3-chloropropane

ug/L

50

49.1

98

64-137

1,2-Dibromoethane (EDB)

ug/L

50

49.7

99

70-130

1,2-Dichlorobenzene

ug/L

50

50.8

102

70-130

1,2-Dichloroethane

ug/L

50

54.5

109

70-137

1,2-Dichloropropane

ug/L

50

55.4

111

80-121

1,3-Dichlorobenzene

ug/L

50

50.2

100

70-130

1,4-Dichlorobenzene

ug/L

50

49.7

99

70-130

Benzene

ug/L

50

52.6

105

70-130

Bromodichloromethane

ug/L

50

50.0

100

70-130

Bromoform

ug/L

50

43.8

88

70-130

Qualifiers

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 49 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

LABORATORY CONTROL SAMPLE:

2483116













Spike

LCS

LCS

% Rec

Parameter

Units

Cone.

Result

% Rec

Limits

Bromomethane

ug/L

50

64.9

130

21-147 v1

Carbon tetrachloride

ug/L

50

47.9

96

80-146

Chlorobenzene

ug/L

50

50.4

101

70-130

Chloroethane

ug/L

50

51.8

104

52-165

Chloroform

ug/L

50

52.2

104

80-123

Chloromethane

ug/L

50

42.7

85

51-122

cis-1,2-Dichloroethene

ug/L

50

46.4

93

70-130

cis-1,3-Dichloropropene

ug/L

50

45.6

91

70-130

Dibromochloromethane

ug/L

50

46.4

93

70-130

Dichlorodifluoromethane

ug/L

50

23.7

47

25-121

Ethylbenzene

ug/L

50

54.7

109

80-120

Isopropylbenzene (Cumene)

ug/L

50

53.0

106

70-130

m&p-Xylene

ug/L

100

105

105

70-130

Methyl-tert-butyl ether

ug/L

50

64.6

129

70-130

Methylene Chloride

ug/L

50

57.1

114

70-130

o-Xylene

ug/L

50

51.5

103

70-130

Styrene

ug/L

50

54.7

109

70-130

Tetrachloroethene

ug/L

50

45.1

90

70-130

Toluene

ug/L

50

53.0

106

80-120

trans-1,2-Dichloroethene

ug/L

50

66.8

134

70-130 L1

trans-1,3-Dichloropropene

ug/L

50

47.5

95

70-130

Trichloroethene

ug/L

50

49.8

100

70-130

Trichlorofluoromethane

ug/L

50

50.7

101

65-160

Vinyl chloride

ug/L

50

42.8

86

63-134

1,2-Dichlorobenzene-d4 (S)

%





97

70-130

4-Bromofluorobenzene (S)

%





108

70-130

Toluene-d8 (S)

%





101

70-130

Qualifiers

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2484281	2484282

Parameter

Units

40254535001
Result

MS
Spike
Cone.

MSD
Spike
Cone.

MS
Result

MSD
Result

MS
% Rec

MSD
% Rec

% Rec
Limits

RPD

Max
RPD

1,1,1-Trichloroethane

ug/L

<0.30

50

50

50.1

51.0

100

102

70-134

2

20

1,1,2,2-Tetrachloroethane

ug/L

<0.38

50

50

60.0

58.6

120

117

61-135

2

20

1,1,2-Trichloroethane

ug/L

<0.34

50

50

59.2

55.6

118

111

70-130

6

20

1,1-Dichloroethane

ug/L

<0.30

50

50

55.6

55.1

111

110

70-130

1

20

1,1-Dichloroethene

ug/L

<0.58

50

50

57.3

56.9

115

114

71-130

1

20

1,2,4-Trichlorobenzene

ug/L

<0.95

50

50

44.8

43.3

90

87

68-131

3

20

1,2-Dibromo-3-

ug/L

<2.4

50

50

51.6

50.8

103

102

51-141

2

20

chloropropane





















1,2-Dibromoethane (EDB)

ug/L

<0.31

50

50

53.0

51.2

106

102

70-130

3

20

1,2-Dichlorobenzene

ug/L

<0.33

50

50

54.2

51.9

108

104

70-130

4

20

1,2-Dichloroethane

ug/L

<0.29

50

50

58.2

55.1

116

110

70-137

5

20

1,2-Dichloropropane

ug/L

<0.45

50

50

57.2

55.1

114

110

80-121

4

20

1,3-Dichlorobenzene

ug/L

<0.35

50

50

52.6

50.4

105

101

70-130

4

20

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 50 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2484281	2484282

Parameter

Units

40254535001
Result

MS
Spike
Cone.

MSD
Spike
Cone.

MS
Result

MSD
Result

MS
% Rec

MSD
% Rec

% Rec
Limits

RPD

Max

RPD Qual

1,4-Dichlorobenzene

ug/L

<0.89

50

50

52.0

50.3

104

101

70-130

3

20

Benzene

ug/L

<0.30

50

50

55.1

54.6

110

109

70-130

1

20

Bromodichloromethane

ug/L

<0.42

50

50

53.8

51.1

108

102

70-130

5

20

Bromoform

ug/L

<3.8

50

50

46.7

44.9

93

90

70-133

4

20

Bromomethane

ug/L

<1.2

50

50

86.9

90.5

174

181

21-149

4

22 M1,v1

Carbon tetrachloride

ug/L

<0.37

50

50

51.9

51.9

104

104

80-146

0

20

Chlorobenzene

ug/L

<0.86

50

50

53.2

51.8

106

104

70-130

3

20

Chloroethane

ug/L

<1.4

50

50

58.3

59.4

117

119

52-165

2

20

Chloroform

ug/L

<1.2

50

50

55.1

53.4

110

107

80-123

3

20

Chloromethane

ug/L

<1.6

50

50

56.6

57.7

113

115

42-125

2

20

cis-1,2-Dichloroethene

ug/L

2.1

50

50

52.0

51.2

100

98

70-130

2

20

cis-1,3-Dichloropropene

ug/L

<0.36

50

50

48.4

46.7

97

93

70-130

4

20

Dibromochloromethane

ug/L

<2.6

50

50

50.0

47.1

100

94

70-130

6

20

Dichlorodifluoromethane

ug/L

<0.46

50

50

39.8

40.3

80

81

25-121

1

20

Ethylbenzene

ug/L

<0.33

50

50

56.9

55.6

114

111

80-121

2

20

Isopropylbenzene

ug/L

<1.0

50

50

56.6

54.6

113

109

70-130

4

20

(Cumene)





















m&p-Xylene

ug/L

<0.70

100

100

110

107

110

107

70-130

3

20

Methyl-tert-butyl ether

ug/L

<1.1

50

50

48.9

60.3

98

121

70-130

21

20 R1

Methylene Chloride

ug/L

<0.32

50

50

60.0

58.1

120

116

70-130

3

20

o-Xylene

ug/L

<0.35

50

50

54.2

53.0

108

106

70-130

2

20

Styrene

ug/L

<0.36

50

50

58.5

56.1

117

112

70-132

4

20

Tetrachloroethene

ug/L

1.4

50

50

49.1

48.8

95

95

70-130

1

20

Toluene

ug/L

<0.29

50

50

55.8

55.2

112

110

80-120

1

20

trans-1,2-Dichloroethene

ug/L

<0.53

50

50

69.8

69.8

140

140

70-130

0

20 M0

trans-1,3-Dichloropropene

ug/L

<3.5

50

50

52.2

50.4

104

101

70-130

4

20

Trichloroethene

ug/L

0.52J

50

50

53.8

52.1

107

103

70-130

3

20

Trichlorofluoromethane

ug/L

<0.42

50

50

57.0

55.4

114

111

65-160

3

20

Vinyl chloride

ug/L

<0.17

50

50

52.5

52.9

105

106

60-137

1

20

1,2-Dichlorobenzene-d4 (S)

%











98

98

70-130





4-Bromofluorobenzene (S)

%











108

111

70-130





Toluene-d8 (S)

%











101

100

70-130





ceAnalytical

www.pacaliki.coni

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 51 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

QC Batch:	431224	Analysis Method:	SM 3500-Cr B

QC Batch Method: SM 3500-Cr B	Analysis Description: Chromium, Hexavalent by 3500

Laboratory:	Pace Analytical Services - Green Bay

Associated Lab Samples: 40254467001, 40254467002, 40254467003, 40254467004, 40254467005, 40254467006, 40254467007,
40254467008, 40254467009, 40254467010, 40254467011, 40254467012, 40254467013, 40254467014,
40254467015, 40254467016, 40254467017, 40254467018

ceAnalytical

www.pacaliki.coni

METHOD BLANK: 2483140

Matrix: Water

Associated Lab Samples:

Parameter

40254467001, 40254467002, 40254467003, 40254467004, 40254467005, 40254467006, 40254467007,
40254467008, 40254467009, 40254467010, 40254467011, 40254467012, 40254467013, 40254467014,
40254467015, 40254467016, 40254467017, 40254467018

Blank	Reporting

Units	Result	Limit	Analyzed	Qualifiers

Chromium, Hexavalent

mg/L

<0.0073

0.024 11/11/22 13:55

LABORATORY CONTROL SAMPLE: 2483141

Spike	LCS LCS % Rec

Parameter Units Cone.	Result % Rec Limits	Qualifiers

Chromium, Hexavalent mg/L 0.3	0.30 101 90-110

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2483142

MS	MSD

40254467001 Spike	Spike
Parameter Units Result Cone. Cone.

Chromium, Hexavalent	mg/L	2.0	3

2483143

MS	MSD	MS MSD	% Rec	Max

Result	Result	% Rec % Rec	Limits	RPD RPD Qual

3 4.6 4.5	87	86	90-110	1 20 M0

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 52 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

QC Batch:
QC Batch Method:

431488
EPA 335.4

Associated Lab Samples: 40254467017

Analysis Method:
Analysis Description:
Laboratory:

EPA 335.4

335.4 Cyanide, Total

Pace Analytical Services - Green Bay

METHOD BLANK: 2484902
Associated Lab Samples: 40254467017

Parameter

Matrix: Water

Units

Blank
Result

Reporting
Limit

Analyzed

Qualifiers

Cyanide

mg/L

<0.0069

0.023 11/15/22 12:35

LABORATORY CONTROL SAMPLE: 2484903

Spike	LCS	LCS % Rec

Parameter Units Cone.	Result	% Rec Limits	Qualifiers

Cyanide mg/L 0.1 0.094	94	90-110

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2484904	2484905

MS	MSD

40254224001 Spike	Spike	MS MSD MS MSD % Rec	Max

Parameter	Units Result Cone.	Cone.	Result Result % Rec % Rec Limits RPD RPD Qual

Cyanide	mg/L	<0.0069	0.1	0.1 0.054 0.059	54	59 90-110 9 20 M0

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2484906	2484907

MS	MSD

40254629001 Spike	Spike	MS MSD MS MSD % Rec	Max

Parameter	Units Result Cone.	Cone.	Result Result % Rec % Rec Limits RPD RPD Qual

Cyanide	mg/L	<0.041	0.6	0.6 0.70 0.70	115	116 90-110 1 20 M0

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 11/18/2022 01:38 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 53 of 59

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALIFIERS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254467

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.

ND - Not Detected at or above LOD.

J - Estimated concentration at or above the LOD and below the LOQ.

LOD - Limit of Detection adjusted for dilution factor, percent moisture, initial weight and final volume.

LOQ - Limit of Quantitation adjusted for dilution factor, percent moisture, initial weight and final volume.

S - Surrogate

1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.

Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.

LCS(D) - Laboratory Control Sample (Duplicate)

MS(D) - Matrix Spike (Duplicate)

DUP - Sample Duplicate

RPD - Relative Percent Difference

NC - Not Calculable.

SG - Silica Gel - Clean-Up

U - Indicates the compound was analyzed for, but not detected at or above the adjusted LOD.

N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.

Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.

TNI - The NELAC Institute.

ANALYTE QUALIFIERS

D3	Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.

L1	Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results may be biased high.

M0	Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.

M1	Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.

R1	RPD value was outside control limits.

pH	Post-analysis pH measurement indicates insufficient VOA sample preservation.

vi	The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.

ceAnalytical

www.pacaliki.coni

Date: 11/18/2022 01:38 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 54 of 59

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA CROSS REFERENCE TABLE

Project:

Pace Project No.

22W016 BETTER BRITE
40254467

Lab ID

Sample ID

QC Batch Method

QC Batch

40254467001

W-1_202211

EPA 8260

431146

40254467002

W-1A_202211

EPA 8260

431146

40254467003

MW-2_202211

EPA 8260

431146

40254467004

MW-3R_202211

EPA 8260

431146

40254467005

MW-5_202211

EPA 8260

431146

40254467007

MW-6_202211

EPA 8260

431146

40254467009

MW-7_202211

EPA 8260

431146

40254467011

MW-8_202211

EPA 8260

431146

40254467013

MW-9_202211

EPA 8260

431146

40254467014

MW-10_202211

EPA 8260

431146

40254467015

MW-11_202211

EPA 8260

431146

40254467016

MW-12_202211

EPA 8260

431146

40254467017

ZINC SHOP_202211

EPA 8260

431146

40254467018

MW-3RD_202211

EPA 8260

431217

40254467019

TB1_202211

EPA 8260

431217

40254467001

W-1_202211

SM

3500-Cr B

431224

40254467002

W-1A_202211

SM

3500-Cr B

431224

40254467003

MW-2_202211

SM

3500-Cr B

431224

40254467004

MW-3R_202211

SM

3500-Cr B

431224

40254467005

MW-5_202211

SM

3500-Cr B

431224

40254467006

MW-5A_202211

SM

3500-Cr B

431224

40254467007

MW-6_202211

SM

3500-Cr B

431224

40254467008

MW-6A_202211

SM

3500-Cr B

431224

40254467009

MW-7_202211

SM

3500-Cr B

431224

40254467010

MW-7A_202211

SM

3500-Cr B

431224

40254467011

MW-8_202211

SM

3500-Cr B

431224

40254467012

MW-8A_202211

SM

3500-Cr B

431224

40254467013

MW-9_202211

SM

3500-Cr B

431224

40254467014

MW-10_202211

SM

3500-Cr B

431224

40254467015

MW-11_202211

SM

3500-Cr B

431224

40254467016

MW-12_202211

SM

3500-Cr B

431224

40254467017

ZINC SHOP_202211

SM

3500-Cr B

431224

40254467018

MW-3RD_202211

SM

3500-Cr B

431224

40254467017

ZINC SHOP 202211

EPA 335.4

431488

Analytical Method

Analytical
Batch

EPA 335.4

431537

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

Date: 11/18/2022 01:38 PM	without the written consent of Pace Analytical Services, LLC.	Page 55 of 59

-------
Company Name:

(Please Print Clearly)

Branch/Location:

Project Contact:
Phone:



/^Pace Analytical *

/	MMvpaceteteoom

CHAIN OF CUSTODY

UPPER MIDWEST REGION

MN: 612-607-1700 Wl: 920-469-2436

Page 1 of

lAm&uuwi

C019a(27Jun2006)

Version 6 0 06/14/06

ORIGINAL

-------
(Please Print Clearly)

Company Name:

Branch/Location:

Project Contact:

Phone:

Project Number:

Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO #:

5



iTo/

¦SOVOlfn

-7&%r HZ,7$.



Data Package Options

(billable)

~	EPA Level III

~	EPA Level IV

PACE LAB #

MS/MSD

~ On your sample

(billable)
I | NOT needed on
your sample

Regulatory
Program:

(ceAnafytical*

/	wwwpac0tabs.com

CHAIN OF CUSTODY

'Preservation Codes

A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol
H=Sodium Bisulfate Solution	l=Sodium Thiosulfate J=Other

UPPER MIDWEST REGION

MN: 612-607-1700 Wl: 920-469-2436

Page

of 7



Quote #:

FILTERED?
(YES/NO)

PRESERVATION
(CODE)*

Matrix Codes

A = Air
B = Biota
C ~ Charcoal
0 = 0il
S = Soil
SI = Sludge

W = Water
DW = Drinking Water
GW = Ground Water
SW = Surface Water
WW = Waste Water
WP — Wipe

CLIENT FIELD ID

COLLECTION

MATRIX

	¦ — ' » ¦ '	w	DATE	TIME 	

MGh lf?Z{j	fvi





P//7r. 7o&-\{

X



iUk.

Ma.

2<



70

IqZZj,

Qv

-mi 7&7.I

Rush Turnaround Time Requested - Prelims
(Rush TAT subject to approval/surcharge)
Date Needed:

Transmit Prelim Rush Results by (complete what you want):

Email #1:

Email #2:

Telephone:

Fax:

Samples on HOLD are subject to
special pricing and release of liability

-/

elinc

Relinquished By



Uff^sUUCl

Receipt Temp = '	°C

Sample Receipt pH

OK/Adjusted

Cooler Custody Seal
Present / Not Present
Intact ffidftS&ef 59

C019a(27Jun2006)

Version 6 0 06/14/06

ORIGINAL

-------
DC#_Title: ENV-FRM-GBAY-0035 v03_Sample Preservation Receipt Form
Effective Date: 8/16/2022

Client Name:



All containers needing preservation have been checked and noted below.

Lab Lot# of pH paper.



Sample Preservation,Ret]

Project #

"SSlYes DNo DN/A

Lab Std #ID of preservation (if pH adjusted)'

Initial when,
completed.

Date/
Time.

Pace
Lab #









BP2Z







*

?
E


§

H2S04 pH <2

MaOH+Zn Act pH 25

NaOH pH >12

OJ
VI
X
a

CO

O
z
X

pH after adjusted

Volume
(mL)



Glass





Plastic



Vials





Jars

General



AG1U
BG1U

AG1H
AG4S
AG5U

AG2S
BG3U

BP1U

BP3U
BP3B
BP3N
BP3S

VG9C

DG9T
VG9U
VG9H
VG9M

VG9D

JGFU

f

JG9U

WGFU

WPFU

SP5T
ZPLC
GN 1

GN 2

001

















t















*3

































2.5/5

s002

















I















h

° 1s



' lli..

' X '











:c,

1











2.5/5

003

















V















*?

































2.5/5

1004

















\















%



















. P4













2.5/5

005

















\















'6

































2.5/5

?006











































: ,ff

•i i»





















2.5/5

007



































































2.5/5

008

















r



































¦ft

4'











2.5/5

009

















i

















































2.5/5

010









>

























































2.5/5

011



































!?

































2.5/5

012



































f





















V











2.5/5

013

































*>

































2.5/5

014

















t















%

































2.5/5

015



































































2.5/5

1016













¦-K



\















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m































2.5/5

017

















\

I









































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2.5/5

018

















\















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2.5/5

019
•62#-











" ^





















a*

: y







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Ti















* •-



&

.2.5 /,5„,

Exceptions to preservation check VOA, Coliform, TOC, TOX, TOH, O&G, Wl DRO, Phenolics, OtheL.

Headspace in VOA Vials (>6mm). BYes DNo DN/A "If yes look in headspace-colugjn^

AG1U

1 liter amber glass

BP1U

1 liter plastic unpres

VG9C

40 mL clear ascorbic w/ HCI

JGFU

4 oz amber jar unpres

BG1U

1 liter clear glass

BP3U

250 mL plastic unpres

DG9T

40 mL amber Na Thio

JG9U

9 oz amber jar unpres

AG1H

1 liter amber glass HCL

BP3B

250 mL plastic NaOH

VG9U

40 mL clear vial unpres

WGFU

4 oz clear jar unpres

AG4S

125 mL amber glass H2S04

BP3N

250 mL plastic HN03

VG9H

40 mL clear vial HCL

WPFU

4 oz plastic jar unpres

AG5U

100 mL amber glass unpres

BP3S

250 mL plastic H2S04

VG9M

40 mL clear vial MeOH

SP5T

120 mL plastic Na Thiosulfate

AG2S

500 mL amber glass H2S04

BP2Z

500 mL plastic NaOH + Zn

VG9D

40 mL clear vial Dl

ZPLC

ziploc bag

BG3U

250 mL dear glass unpres









GN 1















GN 2



Page _1_ of

<1^

Qualtrax ID: 41307

Pace® Analytical Services, LLC

Page 1 of 3
PageT>8 of 59

-------
DC#_Title: ENV-FRM-GBAY-0014 v03_SCUR
Effective Date: 8/17/2022

Client Name:



Sample Condition Upon Receipt Form (SCUR)

Project #:|

Courier: ~ CS Logistics ~ Fed Ex O Speedee O UPS ~ Waltco
$ Client	other:

;ent: [H ye

Tracking #:	

Custody Seal on Cooler/Box Present: [H yes no Seals intact: O yes [[] no
Custody Seal on Samples Present: O yes I®" no Seals intact: fj yes O no
Packing Material: O Bubble Wrap f$$/Bubble Bags	O Other

Thermometer Used SR- \	Type of Wet/Blue Dry None

Cooler Temperature Uncorr: Q /Corr .

Temp Blank Present: jfeyes O no
Temp should be above freezing to 6°C.

WO#:40254467

40254467

O Meltwater Only

Biological Tissue is Frozen: O yesO no

~ate:

Person examining contents:
nitials:

nitia

Chain of Custody Present:



ISYes

~ No

~n/a

1.

Chain of Custody Filled Out:



S?Yes Ono

~n/a

2.

Chain of Custody Relinquished:



S/A'es

~ No

~n/a

3.

Sampler Name & Signature on COC:



t^Yes

~ No

~n/a

4.

Samples Arrived within Hold Time:



C?Yes

~ No



5.



- Dl VOA Samples frozen upon receipt



~ Yes

~ No



Date/Time:



Short Hold Time Analysis (<72hr):



(5Yes

~ No



6.

Rush Turn Around Time Requested:



~ Yes

®No



7.

Sufficient Volume:









8.



For Analysis: fefYes Dno MS/MSD:

~Yes

biwo

~n/a





Correct Containersjjgod



ISiVes

~ No



9.



Correct T^jS^-Pace GreenjJaTr Pace IR, Non-Pace











Containers intact:



SlVes

~ No



10.

Filtered volume received for Dissolved tests



~ Yes

Vpfio

~n/a

11.

Sample Labels match COC:

&Yes

~ No

~n/a

12.



-Includes date/time/ID/Analysis Matrix:









Trip Blank Present:



SHyes

~ No

~n/a

13.



Trip Blank Custody Seals Present

Pace Trip Blank Lot # (if purchased): I " L^"

fS/Ves

~ No

~ n/a















Client Notification/ Resolution:

Person Contacted.	

Comments/ Resolution:

If checked, see attached form for additional comments ~

Date/Time:

PM Review is documented electronically in LIMs. By releasing the project, the PM acknowledges they have reviewed the sample logii

Pag e of*^—"

Qualtrax ID: 41292

Pace® Analytical Services, LLC

Page 1 of 2

Page 59 of 59

-------
Technical Practice Area: Data Science	

Technical Practice Leader: Stephen Lehrke	

SOP Owner: T. Scott Barton	

Page 1 of 4

Foth Infrastructure & Environment, LLC

Data Verification Checklist Form

Event: Better Brite Superfund Site Groundwater Monitoring

Sample Date(s): 11 /10/2022

Sample Matrix: Groundwater

Field Technician: Dale Chervenka

Prepared by: T. Scott Barton

Laboratory: Pace Analytical Services, Green Bay, Wl

Checked by: Nick Glander

Laboratory Batch Number(s): 40254542

Date: 02/02/2023

The data review is to be performed in accordance with the procedures specified in the USEPA Functional
Guidelines for Inorganic, Organic, and High-Resolution Superfund Methods Data Review (USEPA 2020a,
2020b, and 2020c), and quality assurance and control parameters set by the project laboratories.

This checklist verifies that sampling and analytical activities followed relevant methods, procedures, and
project-specific documents (e.g., QAPPs and SAPs) for the following:

Sample documentation and chain-of-custody protocol;

Sample container requirements;

Quality control (QC) procedures; and

Quality assurance (QA) management including data management and data verification procedures.
Data Verification Overview

Sample results subjected to a data verification review include an evaluation of the following QC
parameters:

Sample preservation and temperature upon receipt;

Holding times;

Method blank detections;

Method duplicates and relative percent difference (RPD);

Laboratory control samples/laboratory control samples duplicate (LCS/LCSD) recovery and RPD;
Matrix spike/matrix spike duplicate (MS/MSD) recovery and RPD;

Surrogate recovery (for organic parameters);

Field QA/QC samples and RPD;

Simplified charge balance calculation (for ion balancing); and
Completeness summary.

ID#: 3108
Revision #:

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02022023.docx

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Technical Practice Area: Data Science	

Technical Practice Leader: Stephen Lehrke	

SOP Owner: T. Scott Barton	

Page 2 of 4

Foth Infrastructure & Environment, LLC

The following tables summarize data verification results:

Analytes and Methods

VOCs

EPA 8260

Chromium, Hexavalent

SM 3500-Cr B

Cyanide, Total

EPA 335.4

Iron

EPA 6010D

Sulfate

EPA 300.0

Sample Summary

Lab ID

Sample ID

40254542001

MW-106A_202211

40254542002

MW-107_202211

40254542003

MW-107A_202211

40254542004

MW-108_202211

40254542005

MW-108A_202211

40254542006

MW-110_202211

40254542007

MW-110A_202211

40254542008

MW-111_202211

40254542009

MW-112_202211

40254542010

MW-113_202211

40254542011

MW-115_202211

40254542012

MW-115A_202211

40254542013

MW-116_202211

40254542015

MW-116D_202211

Quality Assurance Sample IDs

Lab ID

Sample ID

40254542014

TB-202211

Data Verification Checklist

Data Verification Criteria

Yes

No

Not
Applicable

CHAIN OF CUSTODY (COC)

1. Are relinquish and receipt signatures present on the COC?

13

~

~

2. Do the analyte and analytical methods requested on the COC agree with
the project requirements (e.g., QAPP, SAP)?

13

~

~

SAMPLE PRESERVATION & HOLDING TIMES

3. Samples received by the project laboratory, intact, with correct

preservation, and at the correct temperature (less than or equal to [<] 6

degrees Celsius [°C] but not frozen)?

Comments:



~

~

ID#: 3108
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Technical Practice Area: Data Science	

Technical Practice Leader: Stephen Lehrke	

SOP Owner: T. Scott Barton	

Page 3 of 4

Foth Infrastructure & Environment, LLC

Data Verification Criteria

Yes

No

Not
Applicable

4. Samples extracted and analyzed within the holding time limits set by the
respective analytical method(s)?

Comments:

• Analyses for hexavalent chromium (SM 3500-Cr B) for all samples
were performed outside the recommended holding time of 24
hours. No qualifiers are assigned because samples were analyzed
within the technical holding time of 14 days specified in the
National Functional Guidelines for Inorganic Superfund Methods
Data Review (USEPA 2020).

u

M

u

ANALYTICAL METHOD REQUIREMENTS

5. Method blanks analyzed at the required frequencies?



~

~

6. Target compounds detected in the method blanks?
Compounds detected:

• None

~



~

7. Method duplicate samples performed at the required frequency?
Comments:

• No method duplicates were reported for this Sample Delivery
Group.

~

~



8. Were LCS/LCSD analyses performed at the required frequency?
Comments:

El

~

~

9. Are the percent recoveries and RPDs for the LCS/LCSD within acceptance
limits?

Comments:

•	The LCS % Recovery for 1,2-Dichloropropane was outside control
limits for LCS# 2483776. No qualification of data is required
because associated results were non-detect.

•	The LCS % Recoveries for Chloromethane and
Dichlorodifluoromethane were outside control limits for LCS#
2485523. No qualification of data is required because associated
results were non-detect.

~



~

10. Were MS/MSD analyses performed at the required frequency?



~

~

11. Are percent recoveries and RPDs for the MS/MSD within acceptable
limits?

Comments:

• The MS and/or MSD % Recoveries for 1,2-Dichloropropane and
Dichlorodifluoromethane were outside control limits in MS#
2484500 and/or MSD# 2484501. The Dichlorodifluoromethane
result for the parent sample used for the MS/MSD analysis (MW-
116_202211) is assigned a "UJ" qualifier due to recoveries less
than the control limit.

~



~

QUALITY ASSURANCE REQUIREMENTS

ID#: 3108
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-------
Technical Practice Area: Data Science	

Technical Practice Leader: Stephen Lehrke	

SOP Owner: T. Scott Barton	

Page 4 of 4

Foth Infrastructure & Environment, LLC

Data Verification Criteria

Yes

No

Not
Applicable

12. Were the appropriate number of trip blanks collected?

Comments:

• One trip blank was collected and analyzed for this Sample Delivery
Group. No analytes were detected.

Kl

u

u

13. Were the appropriate number of field blanks collected?
Comments:

• None specified in the QAPP.

~

~

m

14. Were the appropriate number of duplicates collected?
Comments:

• None specified in the QAPP.

~

~

m

15. Were the appropriate number of equipment blanks collected?
Comments:

• None specified in the QAPP.

~

~

h

16. Were the appropriate number of mercury field blanks collected?
Comments:

• Mercury is not an analyte of interest for this project.

~

~

h

QUALITY CONTROL REQUIREMENTS

17. Is the charge balance error less than 10% or 1 milliequivalents per liter
(meq/L), whichever is greater?

Comments:

• None specified in the QAPP.

~

~



18. Were all samples analyzed as defined in the sampling plan?
Comments:



~

~

19. Is the completeness check greater than or equal to 90% of the plan?
Comments:



~

~

20. Do the analytical results meet the data quality objectives?
Comments:



~

~

21. Was a trend evaluation completed as part of the data verification?
Comments:

• None specified in the QAPP.

~



~

ID#: 3108
Revision #:

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mf f	Pace Analytical Services, LLC

/ ParpAnah/tiraf	1241 Be"evue street -suite 9

/ i^yr aiiGni laiy llual	Green Bay, Wl 54302

/ " WWW.pctIallS.com	(920)469-2436

January 04, 2023

Nick Glander

Foth Infrastructure & Environment, LLC
2121 Innovation Court
Suite 300
De Pere, Wl 54115

RE: Project: 22W016 BETTER BRITE
Pace Project No.: 40254542

Dear Nick Glander:

Enclosed are the analytical results for sample(s) received by the laboratory on November 10, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.

The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Green Bay

Report revised to present Iron analysis.

If you have any questions concerning this report, please feel free to contact me.

Tod Noltemeyer
tod.noltemeyer@pacelabs.com
(920)469-2436
Project Manager

Enclosures

Sincerely,

REPORT OF LABORATORY ANALYSIS

^ORAt0^

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 1 of 60

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CERTIFICATIONS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Pace Analytical Services Green Bay

1241 Bellevue Street, Green Bay, Wl 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky UST Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
New York Certification #: 12064
North Dakota Certification #: R-150

South Carolina Certification #: 83006001
Texas Certification #: T104704529-21-8
Virginia VELAP Certification ID: 11873
Wisconsin Certification #: 405132750
Wisconsin DATCP Certification #: 105-444
USDASoil Permit#: P330-21-00008
Federal Fish & Wildlife Permit #: 51774A

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

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Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

SAMPLE SUMMARY

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Lab ID

Sample ID

Matrix

Date Collected

Date Received

40254542001

MW-106A_202211

Water

11/10/22

14:05

11/10/22 16:20

40254542002

MW-107_202211

Water

11/10/22

15:01

11/10/22 16:20

40254542003

MW-107A_202211

Water

11/10/22

15:30

11/10/22 16:20

40254542004

MW-108_202211

Water

11/10/22

10:04

11/10/22 16:20

40254542005

MW-108A_202211

Water

11/10/22

10:38

11/10/22 16:20

40254542006

MW-110_202211

Water

11/10/22

12:14

11/10/22 16:20

40254542007

MW-110A_202211

Water

11/10/22

12:30

11/10/22 16:20

40254542008

MW-111_202211

Water

11/10/22

11:01

11/10/22 16:20

40254542009

MW-112_202211

Water

11/10/22

13:01

11/10/22 16:20

40254542010

MW-113_202211

Water

11/10/22

14:20

11/10/22 16:20

40254542011

MW-115_202211

Water

11/10/22

11:35

11/10/22 16:20

40254542012

MW-115A_202211

Water

11/10/22

11:59

11/10/22 16:20

40254542013

MW-116_202211

Water

11/10/22

13:29

11/10/22 16:20

40254542014

TB-202211

Water

11/10/22

15:35

11/10/22 16:20

40254542015

MW-116D 202211

Water

11/10/22

13:29

11/10/22 16:20

ceAnalytical

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REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 3 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

SAMPLE ANALYTE COUNT

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Lab ID

Sample ID

Method

Analysts

Analytes
Reported

40254542001

MW-106A_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254542002

MW-107_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254542003

MW-107A_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254542004

MW-108_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254542005

MW-108A_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254542006

MW-110_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254542007

MW-110A_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254542008

MW-111_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254542009

MW-112_202211

EPA 8260

JAV

64





SM 3500-Cr B

EXM

1

40254542010

MW-113_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254542011

MW-115_202211

EPA 6010D

TXW

1





EPA 8260

EIB

64





SM 3500-Cr B

EXM

1





EPA 300.0

HMB

1

40254542012

MW-115A_202211

EPA 8260

EIB

64





SM 3500-Cr B

EXM

1

40254542013

MW-116_202211

EPA 6010D

TXW

1





EPA 8260

EIB

64





SM 3500-Cr B

EXM

1





EPA 300.0

HMB

1

40254542014

TB-202211

EPA 8260

EIB

64

40254542015

MW-116D_202211

EPA 8260

JAV

64





SM 3500-Cr B

EXM

1

PASI-G = Pace Analytical Services - Green Bay

ceAnalytical

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REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 4 of 60

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PROJECT NARRATIVE

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Method: EPA6010D
Description: 6010D MET ICP

Client: FOTH INFRASTRUCTURE & ENVIRONMENT
Date:	January 04, 2023

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

General Information:

2 samples were analyzed for EPA 6010D by Pace Analytical Services Green Bay. All samples were received in acceptable condition
with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.

Hold Time:

The samples were analyzed within the method required hold times with any exceptions noted below.

Sample Preparation:

The samples were prepared in accordance with EPA 301 OA with any exceptions noted below.

Initial Calibrations (including MS Tune as applicable):

All criteria were within method requirements with any exceptions noted below.

Continuing Calibration:

All criteria were within method requirements with any exceptions noted below.

Method Blank:

All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.

Laboratory Control Spike:

All laboratory control spike compounds were within QC limits with any exceptions noted below.

Matrix Spikes:

All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.

Additional Comments:

Analyte Comments:

QC Batch: 431728

D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• MW-116_202211 (Lab ID: 40254542013)

• Iron

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 5 of 60

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PROJECT NARRATIVE

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Method: EPA 8260
Description: 8260 MSV

Client: FOTH INFRASTRUCTURE & ENVIRONMENT
Date:	January 04, 2023

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

General Information:

15 samples were analyzed for EPA 8260 by Pace Analytical Services Green Bay. All samples were received in acceptable condition
with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.

Hold Time:

The samples were analyzed within the method required hold times with any exceptions noted below.

Initial Calibrations (including MS Tune as applicable):

All criteria were within method requirements with any exceptions noted below.

Continuing Calibration:

All criteria were within method requirements with any exceptions noted below.

Internal Standards:

All internal standards were within QC limits with any exceptions noted below.

Surrogates:

All surrogates were within QC limits with any exceptions noted below.

Method Blank:

All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:

All laboratory control spike compounds were within QC limits with any exceptions noted below.

QC Batch: 431290

L1: Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results may be biased high.
• LCS (Lab ID: 2483776)

•	1,2-Dichloropropane

QC Batch: 431626

L1: Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results may be biased high.
•LCS (Lab ID: 2485523)

•	Chloromethane

•	Dichlorodifluoromethane

Matrix Spikes:

All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 431290

A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 40254542013
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.

•MS (Lab ID: 2484500)

• 1,2-Dichloropropane

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 6 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

PROJECT NARRATIVE

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Method: EPA 8260
Description: 8260 MSV

Client: FOTH INFRASTRUCTURE & ENVIRONMENT
Date:	January 04, 2023

QC Batch: 431290

A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 40254542013
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.

• MSD (Lab ID: 2484501)

•	1,2-Dichloropropane

M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
•MS (Lab ID: 2484500)

•	Dichlorodifluoromethane
•MSD (Lab ID: 2484501)

•	Dichlorodifluoromethane

Additional Comments:

ceAnalytical

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REPORT OF LABORATORY ANALYSIS

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without the written consent of Pace Analytical Services, LLC.

Page 7 of 60

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Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

PROJECT NARRATIVE

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Method: SM 3500-Cr B

Description: Chromium, Hexavalent

Client: FOTH INFRASTRUCTURE & ENVIRONMENT

Date:	January 04, 2023

ceAnalytical

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General Information:

14 samples were analyzed for SM 3500-Cr B by Pace Analytical Services Green Bay. All samples were received in acceptable
condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.

Hold Time:

The samples were analyzed within the method required hold times with any exceptions noted below.

Method Blank:

All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.

Laboratory Control Spike:

All laboratory control spike compounds were within QC limits with any exceptions noted below.

Matrix Spikes:

All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.

Additional Comments:

Analyte Comments:

QC Batch: 432022

D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.

•	MW-106A_202211 (Lab ID: 40254542001)

•	Chromium, Hexavalent

•	MW-107A_202211 (Lab ID: 40254542003)

•	Chromium, Hexavalent

•	MW-107_202211 (Lab ID: 40254542002)

•	Chromium, Hexavalent

•	MW-108A_202211 (Lab ID: 40254542005)

•	Chromium, Hexavalent

•	MW-108_202211 (Lab ID: 40254542004)

•	Chromium, Hexavalent

•	MW-110A_202211 (Lab ID: 40254542007)

•	Chromium, Hexavalent

•	MW-110_202211 (Lab ID: 40254542006)

•	Chromium, Hexavalent

•	MW-111_202211 (Lab ID: 40254542008)

•	Chromium, Hexavalent

•	MW-112_202211 (Lab ID: 40254542009)

•	Chromium, Hexavalent

•	MW-113_202211 (Lab ID: 40254542010)

•	Chromium, Hexavalent

•	MW-115A_202211 (Lab ID: 40254542012)

•	Chromium, Hexavalent

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 8 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

PROJECT NARRATIVE

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Method: SM 3500-Cr B

Description: Chromium, Hexavalent

Client: FOTH INFRASTRUCTURE & ENVIRONMENT

Date:	January 04, 2023

Analyte Comments:

QC Batch: 432022

D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• MW-115_202211 (Lab ID: 40254542011)

• Chromium, Hexavalent

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REPORT OF LABORATORY ANALYSIS

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without the written consent of Pace Analytical Services, LLC.

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PROJECT NARRATIVE

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Method: EPA 300.0
Description: 300.0 IC Anions

Client: FOTH INFRASTRUCTURE & ENVIRONMENT
Date:	January 04, 2023

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

General Information:

2 samples were analyzed for EPA 300.0 by Pace Analytical Services Green Bay. All samples were received in acceptable condition with
any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.

Hold Time:

The samples were analyzed within the method required hold times with any exceptions noted below.

Method Blank:

All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.

Laboratory Control Spike:

All laboratory control spike compounds were within QC limits with any exceptions noted below.

Matrix Spikes:

All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 432219

A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 40254553001,40254841002
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.

•MS (Lab ID: 2488997)

• Sulfate

Additional Comments:

This data package has been reviewed for quality and completeness and is approved for release.

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 10 of 60

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Pace Analytical Services, LLC
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Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: MW-106A_202211

Lab ID:

40254542001

Collected:

11/10/22 14:05

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









Benzene

<0.30

ug/L

1.0

0.30 1



11/14/22 15:30

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 15:30

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1



11/14/22 15:30

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 15:30

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1



11/14/22 15:30

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



11/14/22 15:30

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 15:30

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



11/14/22 15:30

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



11/14/22 15:30

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



11/14/22 15:30

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 15:30

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



11/14/22 15:30

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



11/14/22 15:30

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



11/14/22 15:30

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 15:30

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 15:30

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



11/14/22 15:30

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



11/14/22 15:30

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



11/14/22 15:30

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



11/14/22 15:30

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 15:30

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 15:30

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



11/14/22 15:30

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



11/14/22 15:30

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 15:30

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



11/14/22 15:30

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1



11/14/22 15:30

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1



11/14/22 15:30

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



11/14/22 15:30

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



11/14/22 15:30

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



11/14/22 15:30

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



11/14/22 15:30

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



11/14/22 15:30

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



11/14/22 15:30

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



11/14/22 15:30

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 15:30

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 15:30

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



11/14/22 15:30

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



11/14/22 15:30

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



11/14/22 15:30

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



11/14/22 15:30

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 15:30

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1



11/14/22 15:30

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 15:30

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1



11/14/22 15:30

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 11 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-106A_202211

Lab ID:

40254542001

Collected:

11/10/22 14:05

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/14/22 15:30

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/14/22 15:30

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/14/22 15:30

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/14/22 15:30

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/14/22 15:30

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/14/22 15:30

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 15:30

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/14/22 15:30

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/14/22 15:30

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 15:30

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/14/22 15:30

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/14/22 15:30

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 15:30

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/14/22 15:30

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/14/22 15:30

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/14/22 15:30

95-47-6

Surrogates















4-Bromofluorobenzene (S)

109

%

70-130

1



11/14/22 15:30

460-00-4

1,2-Dichlorobenzene-d4 (S)

104

%

70-130

1



11/14/22 15:30

2199-69-1

Toluene-d8 (S)

106

%

70-130

1



11/14/22 15:30

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.37 mg/L	1.2

0.37 50

11/21/22 13:25

D3

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 12 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: MW-107_202211

Lab ID:

40254542002

Collected:

11/10/22 15:01

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









Benzene

<0.30

ug/L

1.0

0.30 1



11/14/22 12:24

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 12:24

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1



11/14/22 12:24

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 12:24

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1



11/14/22 12:24

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



11/14/22 12:24

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 12:24

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



11/14/22 12:24

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



11/14/22 12:24

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



11/14/22 12:24

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 12:24

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



11/14/22 12:24

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



11/14/22 12:24

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



11/14/22 12:24

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 12:24

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 12:24

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



11/14/22 12:24

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



11/14/22 12:24

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



11/14/22 12:24

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



11/14/22 12:24

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 12:24

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 12:24

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



11/14/22 12:24

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



11/14/22 12:24

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 12:24

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



11/14/22 12:24

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1



11/14/22 12:24

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1



11/14/22 12:24

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



11/14/22 12:24

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



11/14/22 12:24

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



11/14/22 12:24

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



11/14/22 12:24

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



11/14/22 12:24

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



11/14/22 12:24

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



11/14/22 12:24

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 12:24

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 12:24

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



11/14/22 12:24

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



11/14/22 12:24

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



11/14/22 12:24

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



11/14/22 12:24

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 12:24

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1



11/14/22 12:24

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 12:24

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1



11/14/22 12:24

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 13 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-107_202211

Lab ID:

40254542002

Collected:

11/10/22 15:01

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/14/22 12:24

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/14/22 12:24

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/14/22 12:24

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/14/22 12:24

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/14/22 12:24

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/14/22 12:24

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 12:24

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/14/22 12:24

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/14/22 12:24

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 12:24

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/14/22 12:24

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/14/22 12:24

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 12:24

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/14/22 12:24

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/14/22 12:24

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/14/22 12:24

95-47-6

Surrogates















4-Bromofluorobenzene (S)

112

%

70-130

1



11/14/22 12:24

460-00-4

1,2-Dichlorobenzene-d4 (S)

102

%

70-130

1



11/14/22 12:24

2199-69-1

Toluene-d8 (S)

102

%

70-130

1



11/14/22 12:24

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<1.8 mg/L	6.1

1.8 250

11/21/22 13:25

D3

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 14 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: MW-107A_202211

Lab ID:

40254542003

Collected:

11/10/22 15:30

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









Benzene

<0.30

ug/L

1.0

0.30 1



11/14/22 15:51

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 15:51

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1



11/14/22 15:51

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 15:51

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1



11/14/22 15:51

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



11/14/22 15:51

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 15:51

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



11/14/22 15:51

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



11/14/22 15:51

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



11/14/22 15:51

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 15:51

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



11/14/22 15:51

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



11/14/22 15:51

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



11/14/22 15:51

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 15:51

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 15:51

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



11/14/22 15:51

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



11/14/22 15:51

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



11/14/22 15:51

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



11/14/22 15:51

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 15:51

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 15:51

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



11/14/22 15:51

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



11/14/22 15:51

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 15:51

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



11/14/22 15:51

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1



11/14/22 15:51

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1



11/14/22 15:51

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



11/14/22 15:51

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



11/14/22 15:51

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



11/14/22 15:51

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



11/14/22 15:51

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



11/14/22 15:51

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



11/14/22 15:51

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



11/14/22 15:51

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 15:51

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 15:51

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



11/14/22 15:51

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



11/14/22 15:51

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



11/14/22 15:51

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



11/14/22 15:51

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 15:51

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1



11/14/22 15:51

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 15:51

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1



11/14/22 15:51

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 15 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-107A_202211

Lab ID:

40254542003

Collected:

11/10/22 15:30

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/14/22 15:51

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/14/22 15:51

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/14/22 15:51

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/14/22 15:51

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/14/22 15:51

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/14/22 15:51

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 15:51

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/14/22 15:51

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/14/22 15:51

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 15:51

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/14/22 15:51

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/14/22 15:51

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 15:51

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/14/22 15:51

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/14/22 15:51

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/14/22 15:51

95-47-6

Surrogates















4-Bromofluorobenzene (S)

110

%

70-130

1



11/14/22 15:51

460-00-4

1,2-Dichlorobenzene-d4 (S)

101

%

70-130

1



11/14/22 15:51

2199-69-1

Toluene-d8 (S)

106

%

70-130

1



11/14/22 15:51

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.37 mg/L	1.2

0.37 50

11/21/22 13:26

D3

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 16 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: MW-108 202211	Lab ID: 40254542004 Collected: 11/10/22 10:04 Received: 11/10/22 16:20 Matrix: Water

Parameters	Results	Units	LOQ LOD DF Prepared	Analyzed CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

11/14/22 16

11

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/14/22 16

11

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/14/22 16

11

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/14/22 16

11

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/14/22 16

11

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/14/22 16

11

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/14/22 16

11

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/14/22 16

11

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/14/22 16

11

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/14/22 16

11

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/14/22 16

11

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/14/22 16

11

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/14/22 16

11

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/14/22 16

11

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/14/22 16

11

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/14/22 16

11

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/14/22 16

11

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/14/22 16

11

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/14/22 16

11

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/14/22 16

11

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/14/22 16

11

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/14/22 16

11

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/14/22 16

11

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/14/22 16

11

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/14/22 16

11

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/14/22 16

11

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/14/22 16

11

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/14/22 16

11

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/14/22 16

11

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/14/22 16

11

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/14/22 16

11

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/14/22 16

11

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/14/22 16

11

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/14/22 16

11

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/14/22 16

11

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/14/22 16

11

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/14/22 16

11

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/14/22 16

11

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/14/22 16

11

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/14/22 16

11

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/14/22 16

11

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/14/22 16

11

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/14/22 16

11

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/14/22 16

11

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/14/22 16

11

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 17 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-108_202211

Lab ID:

40254542004

Collected:

11/10/22 10:04

Received:

11/10/22 16:20

Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/14/22 16

11

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/14/22 16

11

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/14/22 16

11

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/14/22 16

11

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/14/22 16

11

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/14/22 16

11

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 16

11

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/14/22 16

11

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/14/22 16

11

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 16

11

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/14/22 16

11

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/14/22 16

11

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 16

11

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/14/22 16

11

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/14/22 16

11

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/14/22 16

11

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

109

%

70-130

1



11/14/22 16

11

460-00-4

1,2-Dichlorobenzene-d4 (S)

102

%

70-130

1



11/14/22 16

11

2199-69-1

Toluene-d8 (S)

106

%

70-130

1



11/14/22 16

11

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.37 mg/L	1.2

0.37 50

11/21/22 13:26

D3

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 18 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: MW-108A_202211

Lab ID:

40254542005

Collected:

11/10/22 10:38

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









Benzene

<0.30

ug/L

1.0

0.30 1



11/14/22 17:55

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 17:55

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1



11/14/22 17:55

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 17:55

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1



11/14/22 17:55

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



11/14/22 17:55

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 17:55

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



11/14/22 17:55

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



11/14/22 17:55

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



11/14/22 17:55

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 17:55

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



11/14/22 17:55

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



11/14/22 17:55

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



11/14/22 17:55

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 17:55

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 17:55

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



11/14/22 17:55

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



11/14/22 17:55

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



11/14/22 17:55

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



11/14/22 17:55

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 17:55

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 17:55

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



11/14/22 17:55

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



11/14/22 17:55

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 17:55

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



11/14/22 17:55

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1



11/14/22 17:55

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1



11/14/22 17:55

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



11/14/22 17:55

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



11/14/22 17:55

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



11/14/22 17:55

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



11/14/22 17:55

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



11/14/22 17:55

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



11/14/22 17:55

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



11/14/22 17:55

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 17:55

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 17:55

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



11/14/22 17:55

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



11/14/22 17:55

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



11/14/22 17:55

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



11/14/22 17:55

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 17:55

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1



11/14/22 17:55

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 17:55

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1



11/14/22 17:55

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 19 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-108A_202211

Lab ID:

40254542005

Collected:

11/10/22 10:38

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/14/22 17:55

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/14/22 17:55

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/14/22 17:55

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/14/22 17:55

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/14/22 17:55

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/14/22 17:55

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 17:55

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/14/22 17:55

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/14/22 17:55

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 17:55

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/14/22 17:55

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/14/22 17:55

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 17:55

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/14/22 17:55

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/14/22 17:55

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/14/22 17:55

95-47-6

Surrogates















4-Bromofluorobenzene (S)

109

%

70-130

1



11/14/22 17:55

460-00-4

1,2-Dichlorobenzene-d4 (S)

100

%

70-130

1



11/14/22 17:55

2199-69-1

Toluene-d8 (S)

105

%

70-130

1



11/14/22 17:55

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.18 mg/L	0.61

0.18 25

11/21/22 13:26

D3

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 20 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: MW-110_202211

Lab ID:

40254542006

Collected:

11/10/22 12:14

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









Benzene

<0.30

ug/L

1.0

0.30 1



11/14/22 16:32

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 16:32

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1



11/14/22 16:32

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 16:32

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1



11/14/22 16:32

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



11/14/22 16:32

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 16:32

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



11/14/22 16:32

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



11/14/22 16:32

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



11/14/22 16:32

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 16:32

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



11/14/22 16:32

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



11/14/22 16:32

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



11/14/22 16:32

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 16:32

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 16:32

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



11/14/22 16:32

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



11/14/22 16:32

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



11/14/22 16:32

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



11/14/22 16:32

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 16:32

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 16:32

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



11/14/22 16:32

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



11/14/22 16:32

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 16:32

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



11/14/22 16:32

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1



11/14/22 16:32

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1



11/14/22 16:32

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



11/14/22 16:32

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



11/14/22 16:32

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



11/14/22 16:32

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



11/14/22 16:32

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



11/14/22 16:32

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



11/14/22 16:32

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



11/14/22 16:32

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 16:32

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 16:32

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



11/14/22 16:32

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



11/14/22 16:32

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



11/14/22 16:32

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



11/14/22 16:32

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 16:32

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1



11/14/22 16:32

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 16:32

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1



11/14/22 16:32

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 21 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-110_202211

Lab ID:

40254542006

Collected:

11/10/22 12:14

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/14/22 16:32

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/14/22 16:32

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/14/22 16:32

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/14/22 16:32

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/14/22 16:32

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/14/22 16:32

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 16:32

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/14/22 16:32

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/14/22 16:32

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 16:32

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/14/22 16:32

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/14/22 16:32

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 16:32

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/14/22 16:32

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/14/22 16:32

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/14/22 16:32

95-47-6

Surrogates















4-Bromofluorobenzene (S)

108

%

70-130

1



11/14/22 16:32

460-00-4

1,2-Dichlorobenzene-d4 (S)

102

%

70-130

1



11/14/22 16:32

2199-69-1

Toluene-d8 (S)

107

%

70-130

1



11/14/22 16:32

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.18 mg/L	0.61

0.18 25

11/21/22 13:26

D3

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 22 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: MW-110A_202211

Lab ID:

40254542007

Collected:

11/10/22 12:30

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









Benzene

<0.30

ug/L

1.0

0.30 1



11/14/22 16:53

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 16:53

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1



11/14/22 16:53

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 16:53

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1



11/14/22 16:53

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



11/14/22 16:53

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 16:53

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



11/14/22 16:53

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



11/14/22 16:53

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



11/14/22 16:53

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 16:53

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



11/14/22 16:53

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



11/14/22 16:53

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



11/14/22 16:53

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 16:53

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 16:53

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



11/14/22 16:53

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



11/14/22 16:53

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



11/14/22 16:53

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



11/14/22 16:53

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 16:53

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 16:53

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



11/14/22 16:53

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



11/14/22 16:53

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 16:53

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



11/14/22 16:53

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1



11/14/22 16:53

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1



11/14/22 16:53

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



11/14/22 16:53

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



11/14/22 16:53

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



11/14/22 16:53

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



11/14/22 16:53

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



11/14/22 16:53

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



11/14/22 16:53

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



11/14/22 16:53

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 16:53

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 16:53

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



11/14/22 16:53

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



11/14/22 16:53

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



11/14/22 16:53

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



11/14/22 16:53

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 16:53

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1



11/14/22 16:53

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 16:53

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1



11/14/22 16:53

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 23 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-110A_202211

Lab ID:

40254542007

Collected:

11/10/22 12:30

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/14/22 16:53

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/14/22 16:53

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/14/22 16:53

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/14/22 16:53

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/14/22 16:53

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/14/22 16:53

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 16:53

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/14/22 16:53

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/14/22 16:53

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 16:53

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/14/22 16:53

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/14/22 16:53

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 16:53

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/14/22 16:53

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/14/22 16:53

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/14/22 16:53

95-47-6

Surrogates















4-Bromofluorobenzene (S)

111

%

70-130

1



11/14/22 16:53

460-00-4

1,2-Dichlorobenzene-d4 (S)

105

%

70-130

1



11/14/22 16:53

2199-69-1

Toluene-d8 (S)

106

%

70-130

1



11/14/22 16:53

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.37 mg/L	1.2

0.37 50

11/21/22 13:27

D3

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 24 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: MW-111 202211	Lab ID: 40254542008 Collected: 11/10/22 11:01 Received: 11/10/22 16:20 Matrix: Water

Parameters	Results	Units	LOQ LOD DF Prepared	Analyzed CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

11/14/22 17

13

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/14/22 17

13

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/14/22 17

13

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/14/22 17

13

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/14/22 17

13

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/14/22 17

13

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/14/22 17

13

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/14/22 17

13

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/14/22 17

13

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/14/22 17

13

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/14/22 17

13

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/14/22 17

13

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/14/22 17

13

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/14/22 17

13

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/14/22 17

13

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/14/22 17

13

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/14/22 17

13

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/14/22 17

13

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/14/22 17

13

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/14/22 17

13

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/14/22 17

13

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/14/22 17

13

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/14/22 17

13

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/14/22 17

13

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/14/22 17

13

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/14/22 17

13

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/14/22 17

13

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/14/22 17

13

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/14/22 17

13

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/14/22 17

13

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/14/22 17

13

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/14/22 17

13

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/14/22 17

13

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/14/22 17

13

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/14/22 17

13

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/14/22 17

13

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/14/22 17

13

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/14/22 17

13

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/14/22 17

13

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/14/22 17

13

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/14/22 17

13

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/14/22 17

13

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/14/22 17

13

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/14/22 17

13

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/14/22 17

13

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 25 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-111_202211

Lab ID:

40254542008

Collected:

11/10/22 11:01

Received:

11/10/22 16:20

Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/14/22 17

13

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/14/22 17

13

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/14/22 17

13

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/14/22 17

13

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/14/22 17

13

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/14/22 17

13

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 17

13

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/14/22 17

13

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/14/22 17

13

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 17

13

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/14/22 17

13

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/14/22 17

13

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 17

13

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/14/22 17

13

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/14/22 17

13

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/14/22 17

13

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

109

%

70-130

1



11/14/22 17

13

460-00-4

1,2-Dichlorobenzene-d4 (S)

103

%

70-130

1



11/14/22 17

13

2199-69-1

Toluene-d8 (S)

103

%

70-130

1



11/14/22 17

13

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<1.8 mg/L	6.1

1.8 250

11/21/22 13:27

D3

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 26 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: MW-112 202211	Lab ID: 40254542009 Collected: 11/10/22 13:01 Received: 11/10/22 16:20 Matrix: Water

Parameters	Results	Units	LOQ LOD DF Prepared	Analyzed CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

11/16/22 14

11

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/16/22 14

11

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/16/22 14

11

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/16/22 14

11

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/16/22 14

11

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/16/22 14

11

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/16/22 14

11

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/16/22 14

11

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/16/22 14

11

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/16/22 14

11

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/16/22 14

11

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/16/22 14

11

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/16/22 14

11

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/16/22 14

11

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/16/22 14

11

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/16/22 14

11

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/16/22 14

11

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/16/22 14

11

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/16/22 14

11

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/16/22 14

11

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/16/22 14

11

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/16/22 14

11

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/16/22 14

11

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/16/22 14

11

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/16/22 14

11

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/16/22 14

11

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/16/22 14

11

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/16/22 14

11

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/16/22 14

11

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/16/22 14

11

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/16/22 14

11

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/16/22 14

11

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/16/22 14

11

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/16/22 14

11

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/16/22 14

11

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/16/22 14

11

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/16/22 14

11

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/16/22 14

11

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/16/22 14

11

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/16/22 14

11

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/16/22 14

11

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/16/22 14

11

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/16/22 14

11

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/16/22 14

11

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/16/22 14

11

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 27 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-112_202211

Lab ID:

40254542009

Collected:

11/10/22 13:01

Received:

11/10/22 16:20

Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/16/22 14

11

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/16/22 14

11

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/16/22 14

11

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/16/22 14

11

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/16/22 14

11

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/16/22 14

11

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/16/22 14

11

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/16/22 14

11

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/16/22 14

11

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/16/22 14

11

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/16/22 14

11

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/16/22 14

11

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/16/22 14

11

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/16/22 14

11

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/16/22 14

11

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/16/22 14

11

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

100

%

70-130

1



11/16/22 14

11

460-00-4

1,2-Dichlorobenzene-d4 (S)

102

%

70-130

1



11/16/22 14

11

2199-69-1

Toluene-d8 (S)

96

%

70-130

1



11/16/22 14

11

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.18 mg/L	0.61

0.18 25

11/21/22 13:27

D3

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 28 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: MW-113_202211

Lab ID:

40254542010

Collected:

11/10/22 14:20

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









Benzene

<0.30

ug/L

1.0

0.30 1



11/14/22 17:34

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 17:34

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1



11/14/22 17:34

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 17:34

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1



11/14/22 17:34

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



11/14/22 17:34

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 17:34

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



11/14/22 17:34

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



11/14/22 17:34

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



11/14/22 17:34

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 17:34

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



11/14/22 17:34

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



11/14/22 17:34

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



11/14/22 17:34

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 17:34

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 17:34

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



11/14/22 17:34

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



11/14/22 17:34

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



11/14/22 17:34

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



11/14/22 17:34

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 17:34

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 17:34

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



11/14/22 17:34

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



11/14/22 17:34

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 17:34

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



11/14/22 17:34

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1



11/14/22 17:34

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1



11/14/22 17:34

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



11/14/22 17:34

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



11/14/22 17:34

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



11/14/22 17:34

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



11/14/22 17:34

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



11/14/22 17:34

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



11/14/22 17:34

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



11/14/22 17:34

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 17:34

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 17:34

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



11/14/22 17:34

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



11/14/22 17:34

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



11/14/22 17:34

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



11/14/22 17:34

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 17:34

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1



11/14/22 17:34

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 17:34

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1



11/14/22 17:34

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 29 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-113_202211

Lab ID:

40254542010

Collected:

11/10/22 14:20

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/14/22 17:34

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/14/22 17:34

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/14/22 17:34

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/14/22 17:34

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/14/22 17:34

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/14/22 17:34

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 17:34

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/14/22 17:34

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/14/22 17:34

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 17:34

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/14/22 17:34

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/14/22 17:34

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 17:34

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/14/22 17:34

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/14/22 17:34

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/14/22 17:34

95-47-6

Surrogates















4-Bromofluorobenzene (S)

107

%

70-130

1



11/14/22 17:34

460-00-4

1,2-Dichlorobenzene-d4 (S)

102

%

70-130

1



11/14/22 17:34

2199-69-1

Toluene-d8 (S)

104

%

70-130

1



11/14/22 17:34

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<0.18 mg/L	0.61

0.18 25

11/21/22 13:29

D3

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 30 of 60

-------
^ace Analytical

www.pacelabs.com

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-115_202211

Lab ID:

40254542011 Collected:

11/10/22 11:35

Received: 11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

6010D MET ICP

Analytical Method:

EPA 6010D Preparation Method: EPA 301 OA









Pace Analytical Services - Green Bay











Iron

21000

ug/L

100

56.7 1

11/17/22 05:54

11/18/22 00:47

7439-89-6

8260 MSV

Analytical Method:

EPA 8260













Pace Analytical Services - Green Bay











Benzene

<0.30

ug/L

1.0

0.30 1



11/14/22

12:44

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1



11/14/22

12:44

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1



11/14/22

12:44

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1



11/14/22

12:44

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1



11/14/22

12:44

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



11/14/22

12:44

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



11/14/22

12:44

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



11/14/22

12:44

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



11/14/22

12:44

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



11/14/22

12:44

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



11/14/22

12:44

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



11/14/22

12:44

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



11/14/22

12:44

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



11/14/22

12:44

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22

12:44

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22

12:44

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



11/14/22

12:44

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



11/14/22

12:44

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



11/14/22

12:44

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



11/14/22

12:44

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



11/14/22

12:44

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



11/14/22

12:44

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



11/14/22

12:44

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



11/14/22

12:44

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22

12:44

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



11/14/22

12:44

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1



11/14/22

12:44

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1



11/14/22

12:44

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



11/14/22

12:44

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



11/14/22

12:44

78-87-5 L1

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



11/14/22

12:44

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



11/14/22

12:44

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



11/14/22

12:44

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



11/14/22

12:44

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



11/14/22

12:44

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22

12:44

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



11/14/22

12:44

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



11/14/22

12:44

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



11/14/22

12:44

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



11/14/22

12:44

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



11/14/22

12:44

75-09-2

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 31 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-115_202211

Lab ID:

40254542011

Collected:

11/10/22 11:35

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

1



11/14/22 12:44

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1

1



11/14/22 12:44

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35

1



11/14/22 12:44

103-65-1

Styrene

<0.36

ug/L

1.0

0.36

1



11/14/22 12:44

100-42-5

1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1



11/14/22 12:44

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

1



11/14/22 12:44

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41

1



11/14/22 12:44

127-18-4

Toluene

<0.29

ug/L

1.0

0.29

1



11/14/22 12:44

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1



11/14/22 12:44

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1



11/14/22 12:44

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30

1



11/14/22 12:44

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

1



11/14/22 12:44

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32

1



11/14/22 12:44

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1



11/14/22 12:44

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1



11/14/22 12:44

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1



11/14/22 12:44

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

1



11/14/22 12:44

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17

1



11/14/22 12:44

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70

1



11/14/22 12:44

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35

1



11/14/22 12:44

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

109

%

70-130



1



11/14/22 12:44

460-00-4

1,2-Dichlorobenzene-d4 (S)

103

%

70-130



1



11/14/22 12:44

2199-69-1

Toluene-d8 (S)

107

%

70-130



1



11/14/22 12:44

2037-26-5

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B













Pace Analytical Services -

Green Bay











Chromium, Hexavalent

<1.8

mg/L

6.1

1.8

250



11/21/22 13:29

D3

300.0 IC Anions

Sulfate

Analytical Method: EPA 300.0
Pace Analytical Services - Green Bay

33.2 mg/L	10.0

2.2

11/27/22 15:50 14808-79-8

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 32 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: MW-115A_202211

Lab ID:

40254542012

Collected:

11/10/22 11:59

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









Benzene

<0.30

ug/L

1.0

0.30 1



11/14/22 13:05

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 13:05

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1



11/14/22 13:05

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 13:05

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1



11/14/22 13:05

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



11/14/22 13:05

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 13:05

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



11/14/22 13:05

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



11/14/22 13:05

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



11/14/22 13:05

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



11/14/22 13:05

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



11/14/22 13:05

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



11/14/22 13:05

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



11/14/22 13:05

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 13:05

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22 13:05

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



11/14/22 13:05

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



11/14/22 13:05

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



11/14/22 13:05

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



11/14/22 13:05

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 13:05

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 13:05

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



11/14/22 13:05

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



11/14/22 13:05

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 13:05

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



11/14/22 13:05

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1



11/14/22 13:05

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1



11/14/22 13:05

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



11/14/22 13:05

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



11/14/22 13:05

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



11/14/22 13:05

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



11/14/22 13:05

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



11/14/22 13:05

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



11/14/22 13:05

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



11/14/22 13:05

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 13:05

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



11/14/22 13:05

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



11/14/22 13:05

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



11/14/22 13:05

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



11/14/22 13:05

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



11/14/22 13:05

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22 13:05

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1



11/14/22 13:05

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1



11/14/22 13:05

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1



11/14/22 13:05

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 33 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-115A_202211

Lab ID:

40254542012

Collected:

11/10/22 11:59

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/14/22 13:05

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/14/22 13:05

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/14/22 13:05

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/14/22 13:05

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/14/22 13:05

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/14/22 13:05

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 13:05

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/14/22 13:05

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/14/22 13:05

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 13:05

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/14/22 13:05

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/14/22 13:05

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 13:05

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/14/22 13:05

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/14/22 13:05

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/14/22 13:05

95-47-6

Surrogates















4-Bromofluorobenzene (S)

113

%

70-130

1



11/14/22 13:05

460-00-4

1,2-Dichlorobenzene-d4 (S)

103

%

70-130

1



11/14/22 13:05

2199-69-1

Toluene-d8 (S)

103

%

70-130

1



11/14/22 13:05

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

<1.8 mg/L	6.1

1.8 250

11/21/22 13:29

D3

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 34 of 60

-------
^ace Analytical

www.pacelabs.com

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-116_202211

Lab ID:

40254542013 Collected:

11/10/22 13:29

Received: 11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

6010D MET ICP

Analytical Method:

EPA 6010D Preparation Method: EPA 301 OA









Pace Analytical Services - Green Bay











Iron

153J

ug/L

200

113 2

11/17/22 05:54

11/18/22

14:44

7439-89-6

8260 MSV

Analytical Method:

EPA 8260













Pace Analytical Services - Green Bay











Benzene

<0.30

ug/L

1.0

0.30 1



11/14/22

12:03

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1



11/14/22

12:03

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1



11/14/22

12:03

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1



11/14/22

12:03

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1



11/14/22

12:03

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



11/14/22

12:03

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



11/14/22

12:03

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



11/14/22

12:03

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



11/14/22

12:03

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



11/14/22

12:03

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



11/14/22

12:03

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



11/14/22

12:03

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



11/14/22

12:03

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



11/14/22

12:03

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22

12:03

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/14/22

12:03

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



11/14/22

12:03

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



11/14/22

12:03

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



11/14/22

12:03

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



11/14/22

12:03

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



11/14/22

12:03

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



11/14/22

12:03

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



11/14/22

12:03

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



11/14/22

12:03

75-71-8

1,1-Dichloroethane

39.7

ug/L

1.0

0.30 1



11/14/22

12:03

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



11/14/22

12:03

107-06-2

1,1-Dichloroethene

34.0

ug/L

1.0

0.58 1



11/14/22

12:03

75-35-4

cis-1,2-Dichloroethene

0.92J

ug/L

1.0

0.47 1



11/14/22

12:03

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



11/14/22

12:03

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



11/14/22

12:03

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



11/14/22

12:03

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



11/14/22

12:03

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



11/14/22

12:03

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



11/14/22

12:03

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



11/14/22

12:03

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



11/14/22

12:03

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



11/14/22

12:03

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



11/14/22

12:03

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



11/14/22

12:03

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



11/14/22

12:03

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



11/14/22

12:03

75-09-2

Qual

D3

M1

L1.M0

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 35 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-116_202211

Lab ID:

40254542013

Collected:

11/10/22 13:29

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1

1



11/14/22 12:03

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1

1



11/14/22 12:03

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35

1



11/14/22 12:03

103-65-1

Styrene

<0.36

ug/L

1.0

0.36

1



11/14/22 12:03

100-42-5

1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36

1



11/14/22 12:03

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38

1



11/14/22 12:03

79-34-5

Tetrachloroethene

1.0

ug/L

1.0

0.41

1



11/14/22 12:03

127-18-4

Toluene

<0.29

ug/L

1.0

0.29

1



11/14/22 12:03

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0

1



11/14/22 12:03

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95

1



11/14/22 12:03

120-82-1

1,1,1-Trichloroethane

116

ug/L

1.0

0.30

1



11/14/22 12:03

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34

1



11/14/22 12:03

79-00-5

Trichloroethene

2.0

ug/L

1.0

0.32

1



11/14/22 12:03

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42

1



11/14/22 12:03

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56

1



11/14/22 12:03

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45

1



11/14/22 12:03

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36

1



11/14/22 12:03

108-67-8

Vinyl chloride

0.27J

ug/L

1.0

0.17

1



11/14/22 12:03

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70

1



11/14/22 12:03

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35

1



11/14/22 12:03

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

110

%

70-130



1



11/14/22 12:03

460-00-4

1,2-Dichlorobenzene-d4 (S)

99

%

70-130



1



11/14/22 12:03

2199-69-1

Toluene-d8 (S)

106

%

70-130



1



11/14/22 12:03

2037-26-5

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B













Pace Analytical Services -

Green Bay











Chromium, Hexavalent

6.4

mg/L

0.61

0.18

25



11/21/22 13:29



300.0 IC Anions

Sulfate

Analytical Method: EPA 300.0
Pace Analytical Services - Green Bay

946 mg/L	100

22.2 50

11/28/22 11:54 14808-79-8

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 36 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: TB-202211	Lab ID: 40254542014 Collected: 11/10/22 15:35 Received: 11/10/22 16:20 Matrix: Water

Parameters	Results	Units	LOQ LOD DF Prepared	Analyzed CAS No. Qual

8260 MSV	Analytical Method: EPA 8260

Pace Analytical Services - Green Bay

Benzene

<0.30

ug/L

1.0

0.30 1

11/1

4/22

11

42

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1

11/1

4/22

11

42

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1

11/1

4/22

11

42

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1

11/1

4/22

11

42

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1

11/1

4/22

11

42

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1

11/1

4/22

11

42

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1

11/1

4/22

11

42

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1

11/1

4/22

11

42

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1

11/1

4/22

11

42

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1

11/1

4/22

11

42

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1

11/1

4/22

11

42

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1

11/1

4/22

11

42

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1

11/1

4/22

11

42

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1

11/1

4/22

11

42

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/1

4/22

11

42

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1

11/1

4/22

11

42

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1

11/1

4/22

11

42

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1

11/1

4/22

11

42

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1

11/1

4/22

11

42

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1

11/1

4/22

11

42

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1

11/1

4/22

11

42

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1

11/1

4/22

11

42

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1

11/1

4/22

11

42

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1

11/1

4/22

11

42

75-71-8

1,1-Dichloroethane

<0.30

ug/L

1.0

0.30 1

11/1

4/22

11

42

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1

11/1

4/22

11

42

107-06-2

1,1-Dichloroethene

<0.58

ug/L

1.0

0.58 1

11/1

4/22

11

42

75-35-4

cis-1,2-Dichloroethene

<0.47

ug/L

1.0

0.47 1

11/1

4/22

11

42

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1

11/1

4/22

11

42

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1

11/1

4/22

11

42

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1

11/1

4/22

11

42

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1

11/1

4/22

11

42

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1

11/1

4/22

11

42

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1

11/1

4/22

11

42

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1

11/1

4/22

11

42

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1

11/1

4/22

11

42

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1

11/1

4/22

11

42

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1

11/1

4/22

11

42

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1

11/1

4/22

11

42

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1

11/1

4/22

11

42

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1

11/1

4/22

11

42

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1

11/1

4/22

11

42

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1

11/1

4/22

11

42

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1

11/1

4/22

11

42

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1

11/1

4/22

11

42

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 37 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: TB-202211

Lab ID:

40254542014

Collected:

11/10/22 15:35

Received:

11/10/22 16:20

Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260













Pace Analytical Services -

Green Bay











1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/14/22 11

42

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/14/22 11

42

79-34-5

Tetrachloroethene

<0.41

ug/L

1.0

0.41 1



11/14/22 11

42

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/14/22 11

42

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/14/22 11

42

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/14/22 11

42

120-82-1

1,1,1-Trichloroethane

<0.30

ug/L

1.0

0.30 1



11/14/22 11

42

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/14/22 11

42

79-00-5

Trichloroethene

<0.32

ug/L

1.0

0.32 1



11/14/22 11

42

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/14/22 11

42

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/14/22 11

42

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/14/22 11

42

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/14/22 11

42

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/14/22 11

42

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/14/22 11

42

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/14/22 11

42

95-47-6

Surrogates

















4-Bromofluorobenzene (S)

108

%

70-130

1



11/14/22 11

42

460-00-4

1,2-Dichlorobenzene-d4 (S)

101

%

70-130

1



11/14/22 11

42

2199-69-1

Toluene-d8 (S)

109

%

70-130

1



11/14/22 11

42

2037-26-5

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 38 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

Sample: MW-116D_202211

Lab ID:

40254542015

Collected:

11/10/22 13:29

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No.

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









Benzene

<0.30

ug/L

1.0

0.30 1



11/15/22 14:33

71-43-2

Bromobenzene

<0.36

ug/L

1.0

0.36 1



11/15/22 14:33

108-86-1

Bromochloromethane

<0.36

ug/L

5.0

0.36 1



11/15/22 14:33

74-97-5

Bromodichloromethane

<0.42

ug/L

1.0

0.42 1



11/15/22 14:33

75-27-4

Bromoform

<3.8

ug/L

5.0

3.8 1



11/15/22 14:33

75-25-2

Bromomethane

<1.2

ug/L

5.0

1.2 1



11/15/22 14:33

74-83-9

n-Butylbenzene

<0.86

ug/L

1.0

0.86 1



11/15/22 14:33

104-51-8

sec-Butylbenzene

<0.42

ug/L

1.0

0.42 1



11/15/22 14:33

135-98-8

tert-Butylbenzene

<0.59

ug/L

1.0

0.59 1



11/15/22 14:33

98-06-6

Carbon tetrachloride

<0.37

ug/L

1.0

0.37 1



11/15/22 14:33

56-23-5

Chlorobenzene

<0.86

ug/L

1.0

0.86 1



11/15/22 14:33

108-90-7

Chloroethane

<1.4

ug/L

5.0

1.4 1



11/15/22 14:33

75-00-3

Chloroform

<1.2

ug/L

5.0

1.2 1



11/15/22 14:33

67-66-3

Chloromethane

<1.6

ug/L

5.0

1.6 1



11/15/22 14:33

74-87-3

2-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/15/22 14:33

95-49-8

4-Chlorotoluene

<0.89

ug/L

5.0

0.89 1



11/15/22 14:33

106-43-4

1,2-Dibromo-3-chloropropane

<2.4

ug/L

5.0

2.4 1



11/15/22 14:33

96-12-8

Dibromochloromethane

<2.6

ug/L

5.0

2.6 1



11/15/22 14:33

124-48-1

1,2-Dibromoethane (EDB)

<0.31

ug/L

1.0

0.31 1



11/15/22 14:33

106-93-4

Dibromomethane

<0.99

ug/L

5.0

0.99 1



11/15/22 14:33

74-95-3

1,2-Dichlorobenzene

<0.33

ug/L

1.0

0.33 1



11/15/22 14:33

95-50-1

1,3-Dichlorobenzene

<0.35

ug/L

1.0

0.35 1



11/15/22 14:33

541 -73-1

1,4-Dichlorobenzene

<0.89

ug/L

1.0

0.89 1



11/15/22 14:33

106-46-7

Dichlorodifluoromethane

<0.46

ug/L

5.0

0.46 1



11/15/22 14:33

75-71-8

1,1-Dichloroethane

35.1

ug/L

1.0

0.30 1



11/15/22 14:33

75-34-3

1,2-Dichloroethane

<0.29

ug/L

1.0

0.29 1



11/15/22 14:33

107-06-2

1,1-Dichloroethene

30.7

ug/L

1.0

0.58 1



11/15/22 14:33

75-35-4

cis-1,2-Dichloroethene

1.0

ug/L

1.0

0.47 1



11/15/22 14:33

156-59-2

trans-1,2-Dichloroethene

<0.53

ug/L

1.0

0.53 1



11/15/22 14:33

156-60-5

1,2-Dichloropropane

<0.45

ug/L

1.0

0.45 1



11/15/22 14:33

78-87-5

1,3-Dichloropropane

<0.30

ug/L

1.0

0.30 1



11/15/22 14:33

142-28-9

2,2-Dichloropropane

<4.2

ug/L

5.0

4.2 1



11/15/22 14:33

594-20-7

1,1-Dichloropropene

<0.41

ug/L

1.0

0.41 1



11/15/22 14:33

563-58-6

cis-1,3-Dichloropropene

<0.36

ug/L

1.0

0.36 1



11/15/22 14:33

10061 -01 -5

trans-1,3-Dichloropropene

<3.5

ug/L

5.0

3.5 1



11/15/22 14:33

10061 -02-6

Diisopropyl ether

<1.1

ug/L

5.0

1.1 1



11/15/22 14:33

108-20-3

Ethylbenzene

<0.33

ug/L

1.0

0.33 1



11/15/22 14:33

100-41-4

Hexachloro-1,3-butadiene

<2.7

ug/L

5.0

2.7 1



11/15/22 14:33

87-68-3

Isopropylbenzene (Cumene)

<1.0

ug/L

5.0

1.0 1



11/15/22 14:33

98-82-8

p-lsopropyltoluene

<1.0

ug/L

5.0

1.0 1



11/15/22 14:33

99-87-6

Methylene Chloride

<0.32

ug/L

5.0

0.32 1



11/15/22 14:33

75-09-2

Methyl-tert-butyl ether

<1.1

ug/L

5.0

1.1 1



11/15/22 14:33

1634-04-4

Naphthalene

<1.1

ug/L

5.0

1.1 1



11/15/22 14:33

91-20-3

n-Propylbenzene

<0.35

ug/L

1.0

0.35 1



11/15/22 14:33

103-65-1

Styrene

<0.36

ug/L

1.0

0.36 1



11/15/22 14:33

100-42-5

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 39 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

ANALYTICAL RESULTS

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

Sample: MW-116D_202211

Lab ID:

40254542015

Collected:

11/10/22 13:29

Received:

11/10/22 16:20 Matrix: Water

Parameters

Results

Units

LOQ

LOD DF

Prepared

Analyzed

CAS No. Qual

8260 MSV

Analytical Method: EPA 8260











Pace Analytical Services -

Green Bay









1,1,1,2-Tetrachloroethane

<0.36

ug/L

1.0

0.36 1



11/15/22 14:33

630-20-6

1,1,2,2-Tetrachloroethane

<0.38

ug/L

1.0

0.38 1



11/15/22 14:33

79-34-5

Tetrachloroethene

1.0

ug/L

1.0

0.41 1



11/15/22 14:33

127-18-4

Toluene

<0.29

ug/L

1.0

0.29 1



11/15/22 14:33

108-88-3

1,2,3-Trichlorobenzene

<1.0

ug/L

5.0

1.0 1



11/15/22 14:33

87-61-6

1,2,4-Trichlorobenzene

<0.95

ug/L

5.0

0.95 1



11/15/22 14:33

120-82-1

1,1,1-Trichloroethane

114

ug/L

1.0

0.30 1



11/15/22 14:33

71-55-6

1,1,2-Trichloroethane

<0.34

ug/L

5.0

0.34 1



11/15/22 14:33

79-00-5

Trichloroethene

2.1

ug/L

1.0

0.32 1



11/15/22 14:33

79-01-6

Trichlorofluoromethane

<0.42

ug/L

1.0

0.42 1



11/15/22 14:33

75-69-4

1,2,3-Trichloropropane

<0.56

ug/L

5.0

0.56 1



11/15/22 14:33

96-18-4

1,2,4-Trimethylbenzene

<0.45

ug/L

1.0

0.45 1



11/15/22 14:33

95-63-6

1,3,5-Trimethylbenzene

<0.36

ug/L

1.0

0.36 1



11/15/22 14:33

108-67-8

Vinyl chloride

<0.17

ug/L

1.0

0.17 1



11/15/22 14:33

75-01-4

m&p-Xylene

<0.70

ug/L

2.0

0.70 1



11/15/22 14:33

179601-23-1

o-Xylene

<0.35

ug/L

1.0

0.35 1



11/15/22 14:33

95-47-6

Surrogates















4-Bromofluorobenzene (S)

100

%

70-130

1



11/15/22 14:33

460-00-4

1,2-Dichlorobenzene-d4 (S)

100

%

70-130

1



11/15/22 14:33

2199-69-1

Toluene-d8 (S)

101

%

70-130

1



11/15/22 14:33

2037-26-5

Chromium, Hexavalent

Chromium, Hexavalent

Analytical Method: SM 3500-Cr B
Pace Analytical Services - Green Bay

6.5 mg/L	0.61

0.18 25

11/21/22 13:30

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 40 of 60

-------
Pace Analytical Services, LLC

irpAnah/tiral*	1241 Bellevue street"Suite 9

1UG ni laiy llual	Green Bay, Wl 54302

WWW.pctIallS.com	(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

QC Batch:	431728

QC Batch Method: EPA 301 OA

Associated Lab Samples: 40254542011, 40254542013

Analysis Method:	EPA6010D

Analysis Description: 6010D MET

Laboratory:	Pace Analytical Services - Green Bay

METHOD BLANK: 2486246	Matrix: Water

Associated Lab Samples: 40254542011, 40254542013

Blank	Reporting

Parameter	Units	Result	Limit	Analyzed	Qualifiers

Iron	ug/L	<56.7	100 11/18/22 00:07

LABORATORY CONTROL SAMPLE: 2486247

Spike	LCS	LCS % Rec

Parameter Units Cone.	Result	% Rec Limits	Qualifiers

Iron ug/L 10000 10300	103	80-120

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2486248	2486249

MS	MSD

40254693037 Spike	Spike MS MSD MS MSD % Rec	Max

Parameter	Units Result Cone.	Cone.	Result Result % Rec % Rec Limits RPD RPD Qual

Iron	ug/L	5360 10000 10000 15500 15300 102	99 75-125 1 20

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 41 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

QC Batch:	431290	Analysis Method:	EPA 8260

QC Batch Method: EPA 8260	Analysis Description: 8260 MSV

Laboratory:	Pace Analytical Services - Green Bay

40254542001, 40254542002, 40254542003, 40254542004, 40254542005, 40254542006, 40254542007,
40254542008, 40254542010, 40254542011, 40254542012, 40254542013, 40254542014

Associated Lab Samples:

METHOD BLANK: 2483775
Associated Lab Samples:

40254542001, 40254542002,
40254542008, 40254542010,

Matrix: Water

40254542003, 40254542004,
40254542011, 40254542012,

Blank

Reporting

Parameter

Units

Result

Limit

Analyzed

1,1,1,2-Tetrachloroethane

ug/L

<0.36

1.0

11/14/22 07:53

1,1,1-Trichloroethane

ug/L

<0.30

1.0

11/14/22 07:53

1,1,2,2-Tetrachloroethane

ug/L

<0.38

1.0

11/14/22 07:53

1,1,2-Trichloroethane

ug/L

<0.34

5.0

11/14/22 07:53

1,1-Dichloroethane

ug/L

<0.30

1.0

11/14/22 07:53

1,1-Dichloroethene

ug/L

<0.58

1.0

11/14/22 07:53

1,1-Dichloropropene

ug/L

<0.41

1.0

11/14/22 07:53

1,2,3-Trichlorobenzene

ug/L

<1.0

5.0

11/14/22 07:53

1,2,3-Trichloropropane

ug/L

<0.56

5.0

11/14/22 07:53

1,2,4-Trichlorobenzene

ug/L

<0.95

5.0

11/14/22 07:53

1,2,4-Trimethylbenzene

ug/L

<0.45

1.0

11/14/22 07:53

1,2-Dibromo-3-chloropropane

ug/L

<2.4

5.0

11/14/22 07:53

1,2-Dibromoethane (EDB)

ug/L

<0.31

1.0

11/14/22 07:53

1,2-Dichlorobenzene

ug/L

<0.33

1.0

11/14/22 07:53

1,2-Dichloroethane

ug/L

<0.29

1.0

11/14/22 07:53

1,2-Dichloropropane

ug/L

<0.45

1.0

11/14/22 07:53

1,3,5-Trimethylbenzene

ug/L

<0.36

1.0

11/14/22 07:53

1,3-Dichlorobenzene

ug/L

<0.35

1.0

11/14/22 07:53

1,3-Dichloropropane

ug/L

<0.30

1.0

11/14/22 07:53

1,4-Dichlorobenzene

ug/L

<0.89

1.0

11/14/22 07:53

2,2-Dichloropropane

ug/L

<4.2

5.0

11/14/22 07:53

2-Chlorotoluene

ug/L

<0.89

5.0

11/14/22 07:53

4-Chlorotoluene

ug/L

<0.89

5.0

11/14/22 07:53

Benzene

ug/L

<0.30

1.0

11/14/22 07:53

Bromobenzene

ug/L

<0.36

1.0

11/14/22 07:53

Bromochloromethane

ug/L

<0.36

5.0

11/14/22 07:53

Bromodichloromethane

ug/L

<0.42

1.0

11/14/22 07:53

Bromoform

ug/L

<3.8

5.0

11/14/22 07:53

Bromomethane

ug/L

<1.2

5.0

11/14/22 07:53

Carbon tetrachloride

ug/L

<0.37

1.0

11/14/22 07:53

Chlorobenzene

ug/L

<0.86

1.0

11/14/22 07:53

Chloroethane

ug/L

<1.4

5.0

11/14/22 07:53

Chloroform

ug/L

<1.2

5.0

11/14/22 07:53

Chloromethane

ug/L

<1.6

5.0

11/14/22 07:53

cis-1,2-Dichloroethene

ug/L

<0.47

1.0

11/14/22 07:53

cis-1,3-Dichloropropene

ug/L

<0.36

1.0

11/14/22 07:53

Dibromochloromethane

ug/L

<2.6

5.0

11/14/22 07:53

Dibromomethane

ug/L

<0.99

5.0

11/14/22 07:53

Dichlorodifluoromethane

ug/L

<0.46

5.0

11/14/22 07:53

40254542005, 40254542006, 40254542007,
40254542013, 40254542014

Qualifiers

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 42 of 60

-------
Pace Analytical Services, LLC

irpAnah/tiral*	1241 Bellevue street"Suite 9

1UG ni laiy llual	Green Bay, Wl 54302

WWW.pctIallS.com	(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

METHOD BLANK: 2483775	Matrix: Water

Associated Lab Samples: 40254542001, 40254542002, 40254542003, 40254542004, 40254542005, 40254542006, 40254542007,
40254542008, 40254542010, 40254542011, 40254542012, 40254542013, 40254542014

Blank	Reporting

Parameter	Units	Result	Limit	Analyzed	Qualifiers

Diisopropyl ether

ug/L

<1.1

5.0

11/14/22 07:53

Ethylbenzene

ug/L

<0.33

1.0

11/14/22 07:53

Hexachloro-1,3-butadiene

ug/L

<2.7

5.0

11/14/22 07:53

Isopropylbenzene (Cumene)

ug/L

<1.0

5.0

11/14/22 07:53

m&p-Xylene

ug/L

<0.70

2.0

11/14/22 07:53

Methyl-tert-butyl ether

ug/L

<1.1

5.0

11/14/22 07:53

Methylene Chloride

ug/L

<0.32

5.0

11/14/22 07:53

n-Butylbenzene

ug/L

<0.86

1.0

11/14/22 07:53

n-Propylbenzene

ug/L

<0.35

1.0

11/14/22 07:53

Naphthalene

ug/L

<1.1

5.0

11/14/22 07:53

o-Xylene

ug/L

<0.35

1.0

11/14/22 07:53

p-lsopropyltoluene

ug/L

<1.0

5.0

11/14/22 07:53

sec-Butylbenzene

ug/L

<0.42

1.0

11/14/22 07:53

Styrene

ug/L

<0.36

1.0

11/14/22 07:53

tert-Butylbenzene

ug/L

<0.59

1.0

11/14/22 07:53

Tetrachloroethene

ug/L

<0.41

1.0

11/14/22 07:53

Toluene

ug/L

<0.29

1.0

11/14/22 07:53

trans-1,2-Dichloroethene

ug/L

<0.53

1.0

11/14/22 07:53

trans-1,3-Dichloropropene

ug/L

<3.5

5.0

11/14/22 07:53

Trichloroethene

ug/L

<0.32

1.0

11/14/22 07:53

Trichlorofluoromethane

ug/L

<0.42

1.0

11/14/22 07:53

Vinyl chloride

ug/L

<0.17

1.0

11/14/22 07:53

1,2-Dichlorobenzene-d4 (S)

%

103

70-130

11/14/22 07:53

4-Bromofluorobenzene (S)

%

111

70-130

11/14/22 07:53

Toluene-d8 (S)

%

107

70-130

11/14/22 07:53

LABORATORY CONTROL SAMPLE: 2483776

Spike	LCS	LCS	% Rec

Parameter

Units

Cone.

Result

% Rec

Limits

1,1,1-Trichloroethane

ug/L

50

51.7

103

70-134

1,1,2,2-Tetrachloroethane

ug/L

50

58.3

117

69-130

1,1,2-Trichloroethane

ug/L

50

55.5

111

70-130

1,1-Dichloroethane

ug/L

50

60.3

121

70-130

1,1-Dichloroethene

ug/L

50

57.3

115

74-131

1,2,4-Trichlorobenzene

ug/L

50

45.8

92

68-130

1,2-Dibromo-3-chloropropane

ug/L

50

48.3

97

64-137

1,2-Dibromoethane (EDB)

ug/L

50

48.3

97

70-130

1,2-Dichlorobenzene

ug/L

50

52.0

104

70-130

1,2-Dichloroethane

ug/L

50

50.8

102

70-137

1,2-Dichloropropane

ug/L

50

62.9

126

80-121 L1

1,3-Dichlorobenzene

ug/L

50

53.0

106

70-130

1,4-Dichlorobenzene

ug/L

50

48.8

98

70-130

Benzene

ug/L

50

56.3

113

70-130

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 43 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

LABORATORY CONTROL SAMPLE:

2483776





















Spike

LCS

LCS

% Rec







Parameter



Units

Cone. Result

% Rec

Limits Qualifiers





Bromodichloromethane



ug/L

50

52.5

105

70-130







Bromoform



ug/L

50

43.7

87

70-130







Bromomethane



ug/L

50

44.5

89

21-147







Carbon tetrachloride



ug/L

50

48.2

96

80-146







Chlorobenzene



ug/L

50

52.7

105

70-130







Chloroethane



ug/L

50

65.1

130

52-165







Chloroform



ug/L

50

54.7

109

80-123







Chloromethane



ug/L

50

57.9

116

51-122







cis-1,2-Dichloroethene



ug/L

50

52.6

105

70-130







cis-1,3-Dichloropropene



ug/L

50

56.6

113

70-130







Dibromochloromethane



ug/L

50

49.7

99

70-130







Dichlorodifluoromethane



ug/L

50

35.2

70

25-121







Ethylbenzene



ug/L

50

57.8

116

80-120







Isopropylbenzene (Cumene)



ug/L

50

54.7

109

70-130







m&p-Xylene



ug/L

100

109

109

70-130







Methyl-tert-butyl ether



ug/L

50

51.0

102

70-130







Methylene Chloride



ug/L

50

56.1

112

70-130







o-Xylene



ug/L

50

56.4

113

70-130







Styrene



ug/L

50

56.9

114

70-130







Tetrachloroethene



ug/L

50

47.5

95

70-130







Toluene



ug/L

50

58.1

116

80-120







trans-1,2-Dichloroethene



ug/L

50

56.9

114

70-130







trans-1,3-Dichloropropene



ug/L

50

51.0

102

70-130







Trichloroethene



ug/L

50

52.4

105

70-130







Trichlorofluoromethane



ug/L

50

52.4

105

65-160







Vinyl chloride



ug/L

50

54.0

108

63-134







1,2-Dichlorobenzene-d4 (S)



%





100

70-130







4-Bromofluorobenzene (S)



%





111

70-130







Toluene-d8 (S)



%





107

70-130







MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2484500

2484501

















MS MSD

















40254542013

Spike Spike

MS

MSD

MS MSD

% Rec



Max

Parameter

Units

Result

Cone. Cone.

Result

Result

% Rec % Rec

Limits

RPD

RPD Qual

1,1,1-Trichloroethane

ug/L

116

50

50 152

154

71 76

70-134

1

20

1,1,2,2-Tetrachloroethane

ug/L

<0.38

50

50 62.7

62.1

125 124

61-135

1

20

1,1,2-Trichloroethane

ug/L

<0.34

50

50 56.9

58.5

114 117

70-130

3

20

1,1-Dichloroethane

ug/L

39.7

50

50 91.8

94.0

104 109

70-130

2

20

1,1-Dichloroethene

ug/L

34.0

50

50 80.2

82.0

92 96

71-130

2

20

1,2,4-Trichlorobenzene

ug/L

<0.95

50

50 46.2

46.6

92 93

68-131

1

20

1,2-Dibromo-3-

ug/L

<2.4

50

50 54.8

53.0

110 106

51-141

3

20

chloropropane

















1,2-Dibromoethane (EDB)

ug/L

<0.31

50

50 49.9

50.5

100 101

70-130

1

20

1,2-Dichlorobenzene

ug/L

<0.33

50

50 52.7

53.6

105 107

70-130

2

20

1,2-Dichloroethane

ug/L

<0.29

50

50 51.3

52.8

103 106

70-137

3

20

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 44 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2484500



2484501



















MS

MSD



















40254542013

Spike

Spike

MS

MSD

MS

MSD

% Rec



Max

Parameter

Units

Result

Cone.

Cone.

Result

Result

% Rec

% Rec

Limits

RPD

RPD Qual

1,2-Dichloropropane

ug/L

<0.45

50

50

61.7

63.3

123

127

80-121

3

20 M0

1,3-Dichlorobenzene

ug/L

<0.35

50

50

53.5

52.8

107

106

70-130

1

20

1,4-Dichlorobenzene

ug/L

<0.89

50

50

49.1

50.2

98

100

70-130

2

20

Benzene

ug/L

<0.30

50

50

55.9

56.4

112

113

70-130

1

20

Bromodichloromethane

ug/L

<0.42

50

50

52.9

53.9

106

108

70-130

2

20

Bromoform

ug/L

<3.8

50

50

46.1

46.4

92

93

70-133

1

20

Bromomethane

ug/L

<1.2

50

50

36.1

37.1

72

74

21-149

3

22

Carbon tetrachloride

ug/L

<0.37

50

50

47.4

48.1

95

96

80-146

2

20

Chlorobenzene

ug/L

<0.86

50

50

52.8

54.3

106

109

70-130

3

20

Chloroethane

ug/L

<1.4

50

50

47.1

47.8

94

96

52-165

2

20

Chloroform

ug/L

<1.2

50

50

53.9

54.4

108

109

80-123

1

20

Chloromethane

ug/L

<1.6

50

50

31.2

30.9

62

62

42-125

1

20

cis-1,2-Dichloroethene

ug/L

0.92J

50

50

53.2

53.8

105

106

70-130

1

20

cis-1,3-Dichloropropene

ug/L

<0.36

50

50

56.3

57.0

113

114

70-130

1

20

Dibromochloromethane

ug/L

<2.6

50

50

51.6

51.9

103

104

70-130

1

20

Dichlorodifluoromethane

ug/L

<0.46

50

50

10.5

9.4

21

19

25-121

11

20 M1

Ethylbenzene

ug/L

<0.33

50

50

58.6

60.1

117

120

80-121

2

20

Isopropylbenzene

ug/L

<1.0

50

50

54.1

55.2

108

110

70-130

2

20

(Cumene)





















m&p-Xylene

ug/L

<0.70

100

100

109

113

109

113

70-130

3

20

Methyl-tert-butyl ether

ug/L

<1.1

50

50

52.1

51.3

104

103

70-130

2

20

Methylene Chloride

ug/L

<0.32

50

50

52.2

53.1

104

106

70-130

2

20

o-Xylene

ug/L

<0.35

50

50

55.9

56.7

112

113

70-130

1

20

Styrene

ug/L

<0.36

50

50

56.4

56.6

113

113

70-132

0

20

Tetrachloroethene

ug/L

1.0

50

50

49.1

51.2

96

100

70-130

4

20

Toluene

ug/L

<0.29

50

50

57.2

58.1

114

116

80-120

2

20

trans-1,2-Dichloroethene

ug/L

<0.53

50

50

54.8

54.3

110

109

70-130

1

20

trans-1,3-Dichloropropene

ug/L

<3.5

50

50

50.9

52.3

102

105

70-130

3

20

Trichloroethene

ug/L

2.0

50

50

53.3

55.8

103

108

70-130

5

20

Trichlorofluoromethane

ug/L

<0.42

50

50

42.8

43.1

86

86

65-160

1

20

Vinyl chloride

ug/L

0.27J

50

50

34.7

35.0

69

69

60-137

1

20

1,2-Dichlorobenzene-d4 (S)

%











100

102

70-130





4-Bromofluorobenzene (S)

%











113

112

70-130





Toluene-d8 (S)

%











106

107

70-130





ceAnalytical

www.pacaliki.coni

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 45 of 60

-------
Pace Analytical Services, LLC

irpAnah/tiral*	1241 Bellevue street"Suite 9

1UG ni laiy llual	Green Bay, Wl 54302

WWW.pctIallS.com	(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

QC Batch:	431428	Analysis Method:	EPA 8260

QC Batch Method: EPA 8260	Analysis Description:	8260 MSV

Laboratory:	Pace Analytical Services - Green Bay

Associated Lab Samples: 40254542015

METHOD BLANK: 2484684
Associated Lab Samples: 40254542015

Parameter

Units

1,1,1,2-Tetrachloroethane

ug/L

1,1,1-Trichloroethane

ug/L

1,1,2,2-Tetrachloroethane

ug/L

1,1,2-Trichloroethane

ug/L

1,1-Dichloroethane

ug/L

1,1-Dichloroethene

ug/L

1,1-Dichloropropene

ug/L

1,2,3-Trichlorobenzene

ug/L

1,2,3-Trichloropropane

ug/L

1,2,4-Trichlorobenzene

ug/L

1,2,4-Trimethylbenzene

ug/L

1,2-Dibromo-3-chloropropane

ug/L

1,2-Dibromoethane (EDB)

ug/L

1,2-Dichlorobenzene

ug/L

1,2-Dichloroethane

ug/L

1,2-Dichloropropane

ug/L

1,3,5-Trimethylbenzene

ug/L

1,3-Dichlorobenzene

ug/L

1,3-Dichloropropane

ug/L

1,4-Dichlorobenzene

ug/L

2,2-Dichloropropane

ug/L

2-Chlorotoluene

ug/L

4-Chlorotoluene

ug/L

Benzene

ug/L

Bromobenzene

ug/L

Bromochloromethane

ug/L

Bromodichloromethane

ug/L

Bromoform

ug/L

Bromomethane

ug/L

Carbon tetrachloride

ug/L

Chlorobenzene

ug/L

Chloroethane

ug/L

Chloroform

ug/L

Chloromethane

ug/L

cis-1,2-Dichloroethene

ug/L

cis-1,3-Dichloropropene

ug/L

Dibromochloromethane

ug/L

Dibromomethane

ug/L

Dichlorodifluoromethane

ug/L

Diisopropyl ether

ug/L

Matrix: Water
Blank	Reporting

Result	Limit	Analyzed	Qualifiers

<0.36

1.0

11/15/22 07:55

<0.30

1.0

11/15/22 07:55

<0.38

1.0

11/15/22 07:55

<0.34

5.0

11/15/22 07:55

<0.30

1.0

11/15/22 07:55

<0.58

1.0

11/15/22 07:55

<0.41

1.0

11/15/22 07:55

<1.0

5.0

11/15/22 07:55

<0.56

5.0

11/15/22 07:55

<0.95

5.0

11/15/22 07:55

<0.45

1.0

11/15/22 07:55

<2.4

5.0

11/15/22 07:55

<0.31

1.0

11/15/22 07:55

<0.33

1.0

11/15/22 07:55

<0.29

1.0

11/15/22 07:55

<0.45

1.0

11/15/22 07:55

<0.36

1.0

11/15/22 07:55

<0.35

1.0

11/15/22 07:55

<0.30

1.0

11/15/22 07:55

<0.89

1.0

11/15/22 07:55

<4.2

5.0

11/15/22 07:55

<0.89

5.0

11/15/22 07:55

<0.89

5.0

11/15/22 07:55

<0.30

1.0

11/15/22 07:55

<0.36

1.0

11/15/22 07:55

<0.36

5.0

11/15/22 07:55

<0.42

1.0

11/15/22 07:55

<3.8

5.0

11/15/22 07:55

<1.2

5.0

11/15/22 07:55

<0.37

1.0

11/15/22 07:55

<0.86

1.0

11/15/22 07:55

<1.4

5.0

11/15/22 07:55

<1.2

5.0

11/15/22 07:55

<1.6

5.0

11/15/22 07:55

<0.47

1.0

11/15/22 07:55

<0.36

1.0

11/15/22 07:55

<2.6

5.0

11/15/22 07:55

<0.99

5.0

11/15/22 07:55

<0.46

5.0

11/15/22 07:55

<1.1

5.0

11/15/22 07:55

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 46 of 60

-------
Pace Analytical Services, LLC

irpAnah/tiral*	1241 Bellevue street"Suite 9

1UG ni laiy llual	Green Bay, Wl 54302

WWW.pctIallS.com	(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

METHOD BLANK: 2484684
Associated Lab Samples: 40254542015

Parameter

Units

Ethylbenzene

ug/L

Hexachloro-1,3-butadiene

ug/L

Isopropylbenzene (Cumene)

ug/L

m&p-Xylene

ug/L

Methyl-tert-butyl ether

ug/L

Methylene Chloride

ug/L

n-Butylbenzene

ug/L

n-Propylbenzene

ug/L

Naphthalene

ug/L

o-Xylene

ug/L

p-lsopropyltoluene

ug/L

sec-Butylbenzene

ug/L

Styrene

ug/L

tert-Butylbenzene

ug/L

Tetrachloroethene

ug/L

Toluene

ug/L

trans-1,2-Dichloroethene

ug/L

trans-1,3-Dichloropropene

ug/L

Trichloroethene

ug/L

Trichlorofluoromethane

ug/L

Vinyl chloride

ug/L

1,2-Dichlorobenzene-d4 (S)

%

4-Bromofluorobenzene (S)

%

Toluene-d8 (S)

%

Matrix: Water
Blank	Reporting

Result	Limit	Analyzed	Qualifiers

<0.33

1.0

11/15/22 07:55

<2.7

5.0

11/15/22 07:55

<1.0

5.0

11/15/22 07:55

<0.70

2.0

11/15/22 07:55

<1.1

5.0

11/15/22 07:55

<0.32

5.0

11/15/22 07:55

<0.86

1.0

11/15/22 07:55

<0.35

1.0

11/15/22 07:55

<1.1

5.0

11/15/22 07:55

<0.35

1.0

11/15/22 07:55

<1.0

5.0

11/15/22 07:55

<0.42

1.0

11/15/22 07:55

<0.36

1.0

11/15/22 07:55

<0.59

1.0

11/15/22 07:55

<0.41

1.0

11/15/22 07:55

<0.29

1.0

11/15/22 07:55

<0.53

1.0

11/15/22 07:55

<3.5

5.0

11/15/22 07:55

<0.32

1.0

11/15/22 07:55

<0.42

1.0

11/15/22 07:55

<0.17

1.0

11/15/22 07:55

99

70-130

11/15/22 07:55

100

70-130

11/15/22 07:55

102

70-130

11/15/22 07:55

LABORATORY CONTROL SAMPLE: 2484685

Spike

LCS

LCS

% Rec

Parameter

Units

Cone.

Result

% Rec

Limits

1,1,1-Trichloroethane

ug/L

50

55.2

110

70-134

1,1,2,2-Tetrachloroethane

ug/L

50

50.3

101

69-130

1,1,2-Trichloroethane

ug/L

50

53.4

107

70-130

1,1-Dichloroethane

ug/L

50

55.9

112

70-130

1,1-Dichloroethene

ug/L

50

54.6

109

74-131

1,2,4-Trichlorobenzene

ug/L

50

49.2

98

68-130

1,2-Dibromo-3-chloropropane

ug/L

50

46.6

93

64-137

1,2-Dibromoethane (EDB)

ug/L

50

50.2

100

70-130

1,2-Dichlorobenzene

ug/L

50

50.8

102

70-130

1,2-Dichloroethane

ug/L

50

51.6

103

70-137

1,2-Dichloropropane

ug/L

50

54.8

110

80-121

1,3-Dichlorobenzene

ug/L

50

52.0

104

70-130

1,4-Dichlorobenzene

ug/L

50

48.8

98

70-130

Benzene

ug/L

50

55.6

111

70-130

Bromodichloromethane

ug/L

50

53.6

107

70-130

Bromoform

ug/L

50

51.4

103

70-130

Qualifiers

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 47 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

LABORATORY CONTROL SAMPLE:

2484685













Spike

LCS

LCS

% Rec

Parameter

Units

Cone.

Result

% Rec

Limits

Bromomethane

ug/L

50

48.3

97

21-147

Carbon tetrachloride

ug/L

50

56.2

112

80-146

Chlorobenzene

ug/L

50

54.0

108

70-130

Chloroethane

ug/L

50

51.9

104

52-165

Chloroform

ug/L

50

55.6

111

80-123

Chloromethane

ug/L

50

50.4

101

51-122

cis-1,2-Dichloroethene

ug/L

50

52.2

104

70-130

cis-1,3-Dichloropropene

ug/L

50

54.4

109

70-130

Dibromochloromethane

ug/L

50

51.6

103

70-130

Dichlorodifluoromethane

ug/L

50

38.8

78

25-121

Ethylbenzene

ug/L

50

57.6

115

80-120

Isopropylbenzene (Cumene)

ug/L

50

58.5

117

70-130

m&p-Xylene

ug/L

100

115

115

70-130

Methyl-tert-butyl ether

ug/L

50

52.0

104

70-130

Methylene Chloride

ug/L

50

54.8

110

70-130

o-Xylene

ug/L

50

55.2

110

70-130

Styrene

ug/L

50

56.6

113

70-130

Tetrachloroethene

ug/L

50

49.5

99

70-130

Toluene

ug/L

50

54.3

109

80-120

trans-1,2-Dichloroethene

ug/L

50

53.8

108

70-130

trans-1,3-Dichloropropene

ug/L

50

53.9

108

70-130

Trichloroethene

ug/L

50

52.7

105

70-130

Trichlorofluoromethane

ug/L

50

53.5

107

65-160

Vinyl chloride

ug/L

50

48.1

96

63-134

1,2-Dichlorobenzene-d4 (S)

%





96

70-130

4-Bromofluorobenzene (S)

%





101

70-130

Toluene-d8 (S)

%





100

70-130

Qualifiers

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 48 of 60

-------
Pace Analytical Services, LLC

irpAnah/tiral*	1241 Bellevue street"Suite 9

1UG ni laiy llual	Green Bay, Wl 54302

WWW.pctIallS.com	(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

QC Batch:	431626	Analysis Method:	EPA 8260

QC Batch Method: EPA 8260	Analysis Description:	8260 MSV

Laboratory:	Pace Analytical Services - Green Bay

Associated Lab Samples: 40254542009

METHOD BLANK: 2485522
Associated Lab Samples: 40254542009

Parameter

Units

1,1,1,2-Tetrachloroethane

ug/L

1,1,1-Trichloroethane

ug/L

1,1,2,2-Tetrachloroethane

ug/L

1,1,2-Trichloroethane

ug/L

1,1-Dichloroethane

ug/L

1,1-Dichloroethene

ug/L

1,1-Dichloropropene

ug/L

1,2,3-Trichlorobenzene

ug/L

1,2,3-Trichloropropane

ug/L

1,2,4-Trichlorobenzene

ug/L

1,2,4-Trimethylbenzene

ug/L

1,2-Dibromo-3-chloropropane

ug/L

1,2-Dibromoethane (EDB)

ug/L

1,2-Dichlorobenzene

ug/L

1,2-Dichloroethane

ug/L

1,2-Dichloropropane

ug/L

1,3,5-Trimethylbenzene

ug/L

1,3-Dichlorobenzene

ug/L

1,3-Dichloropropane

ug/L

1,4-Dichlorobenzene

ug/L

2,2-Dichloropropane

ug/L

2-Chlorotoluene

ug/L

4-Chlorotoluene

ug/L

Benzene

ug/L

Bromobenzene

ug/L

Bromochloromethane

ug/L

Bromodichloromethane

ug/L

Bromoform

ug/L

Bromomethane

ug/L

Carbon tetrachloride

ug/L

Chlorobenzene

ug/L

Chloroethane

ug/L

Chloroform

ug/L

Chloromethane

ug/L

cis-1,2-Dichloroethene

ug/L

cis-1,3-Dichloropropene

ug/L

Dibromochloromethane

ug/L

Dibromomethane

ug/L

Dichlorodifluoromethane

ug/L

Diisopropyl ether

ug/L

Matrix: Water
Blank	Reporting

Result	Limit	Analyzed	Qualifiers

<0.36

1.0

11/16/22 08:33

<0.30

1.0

11/16/22 08:33

<0.38

1.0

11/16/22 08:33

<0.34

5.0

11/16/22 08:33

<0.30

1.0

11/16/22 08:33

<0.58

1.0

11/16/22 08:33

<0.41

1.0

11/16/22 08:33

<1.0

5.0

11/16/22 08:33

<0.56

5.0

11/16/22 08:33

<0.95

5.0

11/16/22 08:33

<0.45

1.0

11/16/22 08:33

<2.4

5.0

11/16/22 08:33

<0.31

1.0

11/16/22 08:33

<0.33

1.0

11/16/22 08:33

<0.29

1.0

11/16/22 08:33

<0.45

1.0

11/16/22 08:33

<0.36

1.0

11/16/22 08:33

<0.35

1.0

11/16/22 08:33

<0.30

1.0

11/16/22 08:33

<0.89

1.0

11/16/22 08:33

<4.2

5.0

11/16/22 08:33

<0.89

5.0

11/16/22 08:33

<0.89

5.0

11/16/22 08:33

<0.30

1.0

11/16/22 08:33

<0.36

1.0

11/16/22 08:33

<0.36

5.0

11/16/22 08:33

<0.42

1.0

11/16/22 08:33

<3.8

5.0

11/16/22 08:33

<1.2

5.0

11/16/22 08:33

<0.37

1.0

11/16/22 08:33

<0.86

1.0

11/16/22 08:33

<1.4

5.0

11/16/22 08:33

<1.2

5.0

11/16/22 08:33

<1.6

5.0

11/16/22 08:33

<0.47

1.0

11/16/22 08:33

<0.36

1.0

11/16/22 08:33

<2.6

5.0

11/16/22 08:33

<0.99

5.0

11/16/22 08:33

<0.46

5.0

11/16/22 08:33

<1.1

5.0

11/16/22 08:33

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 49 of 60

-------
Pace Analytical Services, LLC

irpAnah/tiral*	1241 Bellevue street"Suite 9

1UG ni laiy llual	Green Bay, Wl 54302

WWW.pctIallS.com	(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

METHOD BLANK: 2485522
Associated Lab Samples: 40254542009

Parameter

Units

Ethylbenzene

ug/L

Hexachloro-1,3-butadiene

ug/L

Isopropylbenzene (Cumene)

ug/L

m&p-Xylene

ug/L

Methyl-tert-butyl ether

ug/L

Methylene Chloride

ug/L

n-Butylbenzene

ug/L

n-Propylbenzene

ug/L

Naphthalene

ug/L

o-Xylene

ug/L

p-lsopropyltoluene

ug/L

sec-Butylbenzene

ug/L

Styrene

ug/L

tert-Butylbenzene

ug/L

Tetrachloroethene

ug/L

Toluene

ug/L

trans-1,2-Dichloroethene

ug/L

trans-1,3-Dichloropropene

ug/L

Trichloroethene

ug/L

Trichlorofluoromethane

ug/L

Vinyl chloride

ug/L

1,2-Dichlorobenzene-d4 (S)

%

4-Bromofluorobenzene (S)

%

Toluene-d8 (S)

%

Matrix: Water
Blank	Reporting

Result	Limit	Analyzed	Qualifiers

<0.33

1.0

11/16/22 08:33

<2.7

5.0

11/16/22 08:33

<1.0

5.0

11/16/22 08:33

<0.70

2.0

11/16/22 08:33

<1.1

5.0

11/16/22 08:33

<0.32

5.0

11/16/22 08:33

<0.86

1.0

11/16/22 08:33

<0.35

1.0

11/16/22 08:33

<1.1

5.0

11/16/22 08:33

<0.35

1.0

11/16/22 08:33

<1.0

5.0

11/16/22 08:33

<0.42

1.0

11/16/22 08:33

<0.36

1.0

11/16/22 08:33

<0.59

1.0

11/16/22 08:33

<0.41

1.0

11/16/22 08:33

<0.29

1.0

11/16/22 08:33

<0.53

1.0

11/16/22 08:33

<3.5

5.0

11/16/22 08:33

<0.32

1.0

11/16/22 08:33

<0.42

1.0

11/16/22 08:33

<0.17

1.0

11/16/22 08:33

100

70-130

11/16/22 08:33

101

70-130

11/16/22 08:33

103

70-130

11/16/22 08:33

LABORATORY CONTROL SAMPLE: 2485523

Spike

LCS

LCS

% Rec

Parameter

Units

Cone.

Result

% Rec

Limits

1,1,1-Trichloroethane

ug/L

50

56.9

114

70-134

1,1,2,2-Tetrachloroethane

ug/L

50

51.3

103

69-130

1,1,2-Trichloroethane

ug/L

50

55.6

111

70-130

1,1-Dichloroethane

ug/L

50

57.3

115

70-130

1,1-Dichloroethene

ug/L

50

59.1

118

74-131

1,2,4-Trichlorobenzene

ug/L

50

50.0

100

68-130

1,2-Dibromo-3-chloropropane

ug/L

50

50.3

101

64-137

1,2-Dibromoethane (EDB)

ug/L

50

53.1

106

70-130

1,2-Dichlorobenzene

ug/L

50

53.5

107

70-130

1,2-Dichloroethane

ug/L

50

54.3

109

70-137

1,2-Dichloropropane

ug/L

50

55.2

110

80-121

1,3-Dichlorobenzene

ug/L

50

53.6

107

70-130

1,4-Dichlorobenzene

ug/L

50

50.7

101

70-130

Benzene

ug/L

50

57.2

114

70-130

Bromodichloromethane

ug/L

50

54.4

109

70-130

Bromoform

ug/L

50

53.7

107

70-130

Qualifiers

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 50 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:

Pace Project No.

22W016 BETTER BRITE
40254542

LABORATORY CONTROL SAMPLE:

2485523













Spike

LCS

LCS

% Rec

Parameter

Units

Cone.

Result

% Rec

Limits

Bromomethane

ug/L

50

55.2

110

21-147

Carbon tetrachloride

ug/L

50

57.3

115

80-146

Chlorobenzene

ug/L

50

56.2

112

70-130

Chloroethane

ug/L

50

56.2

112

52-165

Chloroform

ug/L

50

56.7

113

80-123

Chloromethane

ug/L

50

64.3

129

51-122 L1

cis-1,2-Dichloroethene

ug/L

50

53.5

107

70-130

cis-1,3-Dichloropropene

ug/L

50

56.0

112

70-130

Dibromochloromethane

ug/L

50

53.3

107

70-130

Dichlorodifluoromethane

ug/L

50

62.4

125

25-121 L1

Ethylbenzene

ug/L

50

59.9

120

80-120

Isopropylbenzene (Cumene)

ug/L

50

59.9

120

70-130

m&p-Xylene

ug/L

100

120

120

70-130

Methyl-tert-butyl ether

ug/L

50

53.1

106

70-130

Methylene Chloride

ug/L

50

57.8

116

70-130

o-Xylene

ug/L

50

57.9

116

70-130

Styrene

ug/L

50

59.4

119

70-130

Tetrachloroethene

ug/L

50

50.9

102

70-130

Toluene

ug/L

50

56.8

114

80-120

trans-1,2-Dichloroethene

ug/L

50

56.2

112

70-130

trans-1,3-Dichloropropene

ug/L

50

55.4

111

70-130

Trichloroethene

ug/L

50

54.5

109

70-130

Trichlorofluoromethane

ug/L

50

56.9

114

65-160

Vinyl chloride

ug/L

50

58.9

118

63-134

1,2-Dichlorobenzene-d4 (S)

%





97

70-130

4-Bromofluorobenzene (S)

%





101

70-130

Toluene-d8 (S)

%





102

70-130

Qualifiers

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2485524	2485525

Parameter

Units

40254739002
Result

MS
Spike
Cone.

MSD
Spike
Cone.

MS
Result

MSD
Result

MS
% Rec

MSD
% Rec

% Rec
Limits

RPD

Max
RPD

1,1,1-Trichloroethane

ug/L

<0.30

50

50

53.1

54.4

106

109

70-134

2

20

1,1,2,2-Tetrachloroethane

ug/L

<0.38

50

50

50.1

52.4

100

105

61-135

4

20

1,1,2-Trichloroethane

ug/L

<0.34

50

50

52.5

54.2

105

108

70-130

3

20

1,1-Dichloroethane

ug/L

<0.30

50

50

54.6

56.1

109

112

70-130

3

20

1,1-Dichloroethene

ug/L

<0.58

50

50

55.4

57.4

111

115

71-130

4

20

1,2,4-Trichlorobenzene

ug/L

<0.95

50

50

47.0

49.7

94

99

68-131

6

20

1,2-Dibromo-3-

ug/L

<2.4

50

50

47.3

48.3

95

97

51-141

2

20

chloropropane





















1,2-Dibromoethane (EDB)

ug/L

<0.31

50

50

50.3

50.9

101

102

70-130

1

20

1,2-Dichlorobenzene

ug/L

<0.33

50

50

50.2

52.7

100

105

70-130

5

20

1,2-Dichloroethane

ug/L

<0.29

50

50

50.4

51.9

101

104

70-137

3

20

1,2-Dichloropropane

ug/L

<0.45

50

50

53.1

52.9

106

106

80-121

0

20

1,3-Dichlorobenzene

ug/L

<0.35

50

50

50.4

53.1

101

106

70-130

5

20

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 51 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2485524	2485525

Parameter

Units

40254739002
Result

MS
Spike
Cone.

MSD
Spike
Cone.

MS
Result

MSD
Result

MS
% Rec

MSD
% Rec

% Rec
Limits

RPD

Max
RPD

1,4-Dichlorobenzene

ug/L

<0.89

50

50

47.7

50.4

95

101

70-130

5

20

Benzene

ug/L

<0.30

50

50

54.7

56.1

109

112

70-130

2

20

Bromodichloromethane

ug/L

<0.42

50

50

52.2

53.7

104

107

70-130

3

20

Bromoform

ug/L

<3.8

50

50

49.8

50.8

100

102

70-133

2

20

Bromomethane

ug/L

<1.2

50

50

57.0

61.0

114

122

21-149

7

22

Carbon tetrachloride

ug/L

<0.37

50

50

54.5

55.7

109

111

80-146

2

20

Chlorobenzene

ug/L

<0.86

50

50

52.2

53.7

104

107

70-130

3

20

Chloroethane

ug/L

<1.4

50

50

52.3

56.7

105

113

52-165

8

20

Chloroform

ug/L

<1.2

50

50

54.0

55.2

108

110

80-123

2

20

Chloromethane

ug/L

<1.6

50

50

60.0

61.4

119

122

42-125

2

20

cis-1,2-Dichloroethene

ug/L

<0.47

50

50

51.1

52.6

102

105

70-130

3

20

cis-1,3-Dichloropropene

ug/L

<0.36

50

50

51.6

53.2

103

106

70-130

3

20

Dibromochloromethane

ug/L

<2.6

50

50

49.8

51.7

100

103

70-130

4

20

Dichlorodifluoromethane

ug/L

<0.46

50

50

55.3

57.5

111

115

25-121

4

20

Ethylbenzene

ug/L

<0.33

50

50

55.5

57.1

111

114

80-121

3

20

Isopropylbenzene

ug/L

<1.0

50

50

55.2

57.0

110

114

70-130

3

20

(Cumene)





















m&p-Xylene

ug/L

<0.70

100

100

107

112

107

112

70-130

4

20

Methyl-tert-butyl ether

ug/L

<1.1

50

50

51.4

51.7

103

103

70-130

1

20

Methylene Chloride

ug/L

<0.32

50

50

55.5

55.6

111

111

70-130

0

20

o-Xylene

ug/L

<0.35

50

50

52.4

54.6

105

109

70-130

4

20

Styrene

ug/L

<0.36

50

50

47.3

50.0

95

100

70-132

6

20

Tetrachloroethene

ug/L

<0.41

50

50

47.7

49.0

95

98

70-130

3

20

Toluene

ug/L

<0.29

50

50

52.5

54.4

105

109

80-120

4

20

trans-1,2-Dichloroethene

ug/L

<0.53

50

50

53.5

54.8

107

110

70-130

2

20

trans-1,3-Dichloropropene

ug/L

<3.5

50

50

51.2

52.6

102

105

70-130

3

20

Trichloroethene

ug/L

<0.32

50

50

51.4

52.7

103

105

70-130

2

20

Trichlorofluoromethane

ug/L

<0.42

50

50

54.5

55.9

109

112

65-160

2

20

Vinyl chloride

ug/L

<0.17

50

50

54.2

55.2

108

110

60-137

2

20

1,2-Dichlorobenzene-d4 (S)

%











98

101

70-130





4-Bromofluorobenzene (S)

%











101

103

70-130





Toluene-d8 (S)

%











101

101

70-130





ceAnalytical

www.pacaliki.coni

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 52 of 60

-------
Pace Analytical Services, LLC

irpAnah/tiral*	1241 Bellevue street"Suite 9

1UG ni laiy llual	Green Bay, Wl 54302

WWW.pctIallS.com	(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

QC Batch:	432022	Analysis Method:	SM 3500-Cr B

QC Batch Method: SM 3500-Cr B	Analysis Description: Chromium, Hexavalent by 3500

Laboratory:	Pace Analytical Services - Green Bay

Associated Lab Samples: 40254542001, 40254542002, 40254542003, 40254542004, 40254542005, 40254542006, 40254542007,
40254542008, 40254542009, 40254542010, 40254542011, 40254542012, 40254542013, 40254542015

METHOD BLANK: 2488278	Matrix: Water

Associated Lab Samples: 40254542001, 40254542002, 40254542003, 40254542004, 40254542005, 40254542006, 40254542007,
40254542008, 40254542009, 40254542010, 40254542011, 40254542012, 40254542013, 40254542015

Blank	Reporting

Parameter	Units	Result	Limit	Analyzed	Qualifiers

Chromium, Hexavalent	mg/L	<0.0073	0.024 11/21/22 13:24

LABORATORY CONTROL SAMPLE: 2488279

Spike	LCS LCS % Rec

Parameter Units Cone.	Result % Rec Limits	Qualifiers

Chromium, Hexavalent mg/L 0.3	0.30 101 90-110

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2488280	2488281

MS	MSD

40254542001 Spike	Spike	MS MSD MS MSD % Rec	Max

Parameter Units Result Cone.	Cone.	Result Result % Rec % Rec Limits RPD RPD Qual

Chromium, Hexavalent	mg/L	<0.37	15	15 16.1 15.6 107 104 90-110 3 20

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 53 of 60

-------
Pace Analytical Services, LLC

irpAnah/tiral*	1241 Bellevue street"Suite 9

1UG ni laiy llual	Green Bay, Wl 54302

WWW.pctIallS.com	(920)469-2436

QUALITY CONTROL DATA

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

QC Batch:	432219

QC Batch Method: EPA 300.0

Associated Lab Samples: 40254542011, 40254542013

Analysis Method:	EPA 300.0

Analysis Description: 300.0 IC Anions

Laboratory:	Pace Analytical Services - Green Bay

METHOD BLANK: 2488995	Matrix: Water

Associated Lab Samples: 40254542011, 40254542013

Blank	Reporting

Parameter	Units	Result	Limit	Analyzed	Qualifiers

Sulfate	mg/L	<0.44	2.0 11/27/22 11:53

LABORATORY CONTROL SAMPLE: 2488996

Spike	LCS	LCS	% Rec

Parameter	Units	Cone.	Result	% Rec	Limits	Qualifiers

Sulfate	mg/L	20	18.5	93	90-110

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2488997	2488998

MS	MSD

40254841002 Spike	Spike MS MSD MS MSD % Rec	Max

Parameter	Units Result Cone.	Cone.	Result Result % Rec % Rec Limits RPD RPD Qual

Sulfate	mg/L	<2.2 100 100	112 109	111	108 90-110 3 15 M0

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2488999	2489000

MS	MSD

40254553001 Spike	Spike	MS MSD MS MSD % Rec	Max

Parameter Units Result Cone.	Cone.	Result Result % Rec % Rec Limits RPD RPD Qual

Sulfate	mg/L	56.1 400 400 458 458 101	100 90-110 0 15

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

REPORT OF LABORATORY ANALYSIS

Date: 01/04/2023 03:51 PM

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 54 of 60

-------
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALIFIERS

Project:	22W016 BETTER BRITE

Pace Project No.: 40254542

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.

ND - Not Detected at or above LOD.

J - Estimated concentration at or above the LOD and below the LOQ.

LOD - Limit of Detection adjusted for dilution factor, percent moisture, initial weight and final volume.

LOQ - Limit of Quantitation adjusted for dilution factor, percent moisture, initial weight and final volume.

S - Surrogate

1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.

Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.

LCS(D) - Laboratory Control Sample (Duplicate)

MS(D) - Matrix Spike (Duplicate)

DUP - Sample Duplicate

RPD - Relative Percent Difference

NC - Not Calculable.

SG - Silica Gel - Clean-Up

U - Indicates the compound was analyzed for, but not detected at or above the adjusted LOD.

N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.

Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.

TNI - The NELAC Institute.

ANALYTE QUALIFIERS

D3	Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.

L1	Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results may be biased high.

M0	Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.

M1	Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.

ceAnalytical

www.pacaliki.coni

Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 55 of 60

-------
iceAnalytical

www.pacaliki.coni

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, Wl 54302
(920)469-2436

QUALITY CONTROL DATA CROSS REFERENCE TABLE

Project:

22W016 BETTER BRITE









Pace Project No.:

40254542



















Analytical

Lab ID

Sample ID

QC Batch Method

QC Batch

Analytical Method

Batch

40254542011

MW-115_202211

EPA 301 OA

431728

EPA 6010D

431859

40254542013

MW-116_202211

EPA 301 OA

431728

EPA 6010D

431859

40254542001

MW-106A_202211

EPA 8260

431290





40254542002

MW-107_202211

EPA 8260

431290





40254542003

MW-107A_202211

EPA 8260

431290





40254542004

MW-108_202211

EPA 8260

431290





40254542005

MW-108A_202211

EPA 8260

431290





40254542006

MW-110_202211

EPA 8260

431290





40254542007

MW-110A_202211

EPA 8260

431290





40254542008

MW-111_202211

EPA 8260

431290





40254542009

MW-112_202211

EPA 8260

431626





40254542010

MW-113_202211

EPA 8260

431290





40254542011

MW-115_202211

EPA 8260

431290





40254542012

MW-115A_202211

EPA 8260

431290





40254542013

MW-116_202211

EPA 8260

431290





40254542014

TB-202211

EPA 8260

431290





40254542015

MW-116D_202211

EPA 8260

431428





40254542001

MW-106A_202211

SM 3500-Cr B

432022





40254542002

MW-107_202211

SM 3500-Cr B

432022





40254542003

MW-107A_202211

SM 3500-Cr B

432022





40254542004

MW-108_202211

SM 3500-Cr B

432022





40254542005

MW-108A_202211

SM 3500-Cr B

432022





40254542006

MW-110_202211

SM 3500-Cr B

432022





40254542007

MW-110A_202211

SM 3500-Cr B

432022





40254542008

MW-111_202211

SM 3500-Cr B

432022





40254542009

MW-112_202211

SM 3500-Cr B

432022





40254542010

MW-113_202211

SM 3500-Cr B

432022





40254542011

MW-115_202211

SM 3500-Cr B

432022





40254542012

MW-115A_202211

SM 3500-Cr B

432022





40254542013

MW-116_202211

SM 3500-Cr B

432022





40254542015

MW-116D_202211

SM 3500-Cr B

432022





40254542011

MW-115_202211

EPA 300.0

432219





40254542013

MW-116 202211

EPA 300.0

432219





Date: 01/04/2023 03:51 PM

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

Page 56 of 60

-------
(Please Print Clearly)

Company Name:

Branch/Location:

Project Contact:

Phone:

Project Number:

Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#:

f&r-H

/gee



f&TQr'

{aZT

Data Package Potions

(billable)

~	EPA Level III

~	EPA Level IV

PACE LAB #

MS/MSD

I | On your sample

(billable)
I | NOT needed on
your sample

Regulatory
Program:

/^Pace Analytical*

f	mmpacetabs.com

CHAIN OF CUSTODY

"Preservation Codes

A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH
H=Sodium Bisulfate Solution	l=Sodium Thiosulfate J=Other

UPPER MIDWEST REGION

MN: 612-607-1700 Wl: 920-469-2436

Page

1 of



Quote #:

Mall To Contact:

PRESERVATION
(CODE)*

Matrix Codes

As Air
B = Biota
C = Charcoal
0»0il
S = Soil
SI = Sludge

CLIENT FIELD ID

tMJ-W6A.7ffZ.Zir

DATE

W = Water
DW = Drinking Water
GW « Ground Water
SW = Surface Water
WW = Waste Water
WP = Wipe

TIME

CLIENT
COMMENTS

LAB COMMENTS
(Lab Use Only)

Profile#

CP\

"Jle/VL

M.



y

X



Si

X"

X

deer

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Rush Turnaround Time Requested - Prelims
(Rush TAT subject to approval/surcharge)
Date Needed:

Transmit Prelim Rush Results by (complete what you want):

Email #1:

Email #2:

Telephone:

Fax:

Samples on HOLD are subject to
special pricing and release of liability

Mb W»/m m



Relinquished By.

Date/Time

'ate^ime >

Received By*

Relinquished By.

Received By:

Date/Time.

Relinquished 8y:

Date/Time:

Received By.

Relinquished By

Date/Time:

Received By.

PACE Project No.

mbspsuf*

Receipt Temp *

3.S-

Sample Receipt pH
(\OK / Adjusted

Cool^rCustodySear
Present /LNotlPresent
Intact

C019a(27Jun2006)

Version 6 0 06/14/06

ORIGINAL

-------
Company Name:

(Please Print Clearly)

7Zril~~

Branch/Location:

Project Contact:

Phone:

Project Number:

Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#:

/Jet? 6t{fin£e/C



7SL/O/0

£p/Cr.

t/JZ

Data Package Options

(billable)

~	EPA Level III

~	EPA Level IV

PACE LAB #

MS/MSP

~ On your sample

(billable)
| | NOT needed on
your sample

Regulatory
Program:

/^J*aceAnalytical9

f	mm.pacelabs.com

CHAIN OF CUSTODY

UPPER MIDWEST REGION

MN: 612-607-1700 Wl: 920-469-2436

'Preservation Codes

A-None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol
H=Sodium Bisulfate Solution	l=Sodium Thtosulfate J=Other

FILTERED?
(YES/NO)

PRESERVATION
(CODE)*

Matrix Codes

A = Air
B = Biota
C = Charcoal
0 = 0il
S = Soil
SI = Sludge

CLIENT FIELD ID

W = Water
DW = Drinking Water
GW = Ground Water
SW = Surface Water
WW - Waste Water
WP = Wipe

COLLECTION

yiu

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Latter

*o

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5

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Mail To Contact:

Mali To Company:

Mail To Address:^,

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Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT
COMMENTS

Page ^ °l 2.



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LAB COMMENTS
(Lab Use Only)

Profile #



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Rush Turnaround Time Requested - Prelims
(Rush TAT subject to approval/surcharge)
Date Needed:

Transmit Prelim Rush Results by (complete what you want):

Email #1:

Email #2:

Telephone:

Fax:

Samples on HOLD are subject to
special pricing and release of liability

TX? fifh Whhz

Receivpd'By:

Relinquished By:

Receivi

Relinquished By

Date/Time:

Received By.

Relinquished By.

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Relinquished By

Date/Time'

Received By*

PACE Project No.



Receipt Temp >

3**0

Sample Receipt pH
(T^OK/Adjusted

CooTerfcustodvSeal
PresenVffiot Present"
IntactPtigc IBtaofgC

Version 6 0 06/14/06

C019a(27Jun2006)

ORIGINAL

-------
DC#_Title: ENV-FRM-GBAY-0035 v03_Sample Preservation Receipt Form
Effective Date: 8/16/2022

Client Name



All containers needing preservation have been checked and noted below.
		Lab Lot# of pH paper

Sample Preservation RaeeipL£prn>—t . >.

^Project#	CJJ^

JGYes DNo r~""'A	^

LdZm



~ N/A

Lab Std #ID of preservation (if pH adjusted):

Initial whenf VO Date/
completedTime'

Glass

Pace
Lab #

Z> Z> X CO 3 W D
i- t- T- -tt in n m

o o o o o o o

	w

O	O O O	O	O

>	Q > >	>	>

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3 D
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2 £

o o.

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I-	o	T-	CN|

m	_i	JL	11

Q.	Q.	Z	Z

(0	N	O O

Volume
(mL)

001

Jh/lZSLi

2.5/5

002

2.5/5

003

2.5/5

004

£

2.5/5

005

2.5/5

006

j:

2.5/5

007

2.5/5

008

2.5/5

009

2.5/5

010

2.5/5

011



2.5/5

012

12

2.5/5

013

014

3

3



2.5/5

2.5/5

015

2.5/5

2.5/5

017

018



2.5/5



2.5/5

019

2.5/5

020

Exceptions to preservation chefk VO&, doliformTTOC^^OX/TOH, O&G, Wl DRO, Phenolics, OthfiL

2.5/5

Headspace in VOA Vials (>6mm). IHYeSy2ffto DN/A *lf yes look in headspace column

AG1U

1 liter amber glass

BP1U

1 liter plastic unpres

VG9C

40 mL clear ascorbic w/ HCI

JGFU

4 oz amber jar unpres

BG1U

1 liter clear glass

BP3U

250 mL plastic unpres

DG9T

40 mL amber Na Thio

JG9U

9 oz amber jar unpres

AG1H

1 liter amber glass HCL

BP3B

250 mL plastic NaOH

VG9U

40 mL clear vial unpres

WGFU

4 oz clear jar unpres

AG4S

125 mL amber glass H2S04

BP3N

250 mL plastic HN03

VG9H

40 mL clear vial HCL

WPFU

4 oz plastic jar unpres

AG5U

100 mL amber glass unpres

BP3S

250 mL plastic H2S04

VG9M

40 mL clear vial MeOH

SP5T

120 mL plastic Na Thiosulfate

AG2S

500 mL amber glass H2S04

BP2Z

500 mL plastic NlaOH + Zn

VG9D

40 mL clear vial Dl

ZRLC

ziploc bag

BG3U

250 mL clear glass unpres









GN 1















GN 2



Page _1_ of rvP

Quaitrax ID: 41307

Pace® Analytical Services, LLC

Pa^W

-------
DC#_Title: ENV-FRM-GBAY-0014 v03_SCUR
Effective Date: 8/17/2022

Client Name:



Sample Condition Upon Receipt Form (SCUR)

Project #:

Courier: ~ CS Logistics ~ Fed Ex ~ Speedee ~ UPS ~ Waltco
Client	[j Pace Other:

IaIO# : 40254542

Tracking#:		40254542

Custody Seal on Cooler/Box Present: yes T/ffio Seals intact: O yes O no
Custody Seal on Samples Present: [j yes J?"j no Seals intact: d yes [j no
Packing Material: £j Bubble Wrap Pf Bubble Bags O	IZj Other

Thermometer Used SR- ^	Type of Ice/WeT^lue Dry None

Cooler Temperature Uncorr: ^ /Corr: 3,,-gr v-^

Temp Blank Present: pf yes ~ no	Biological Tissue is Frozen: F- yesfj no

Temp should be above freezing to 6°C.

O Meltwater Only

Date:

Person examining contents:

'to/t

Initials:



Chain of Custody Present: /ztves Dno Dn/a

1.

Chain of Custody Filled Out: ^v_es Dno Dn/a

2.

Chain of Custody Relinquished: j^Yes Dno Dn/a

3.

Sampler Name & Signature on COC: DYes ^Ino IHn/a

4.

Samples Arrived within Hold Time: ^Yes Dno
- Dl VOA Samples frozen upon receipt DYes Dno

5.

Date/Time

Short Hold Time Analysis (<72hr): J^Yes Dno

6.

/ /

Rush Turn Around Time Requested: DYes ^No

7.

Sufficient Volume: '

For Analysis- ^Yes Dno MS/MSD: DYes fiua Dn/a

8.

Correct Containere^Use^f Jj^Yes Dno
Correct Typs^Pace Green B^y, Pace IR, Non-Pace

9.

Containers Irrtacl. ^Yes Dno

10.

Filtered volume received for Dissolved tests DYes Dno pin/a

11.

Sample Labels match COC: ^pfYes Dno Dn/a
-Includes date/time/ID/Analysis Matrix: IsJ

12.

Trip Blank Present: Dno—

Trip Blank Custody Seals Present lAYes Dno Dn/a
Pace Trip Blank Lot # (if purchased): V1^^



Client Notification/ Resolution:

Person Contacted:	

Comments/ Resolution:

If checked, see attached form for additional comments ~

Date/Time:

PM Review is documented electronically in LIMs. By releasing the project, the PM acknowledges they have reviewed the sample logii

Page of -J&2-

Qualtrax ID: 41292

Pace® Analytical Services, LLC

Page 1 of 2
Page 60 of 60

-------
APPENDIX H 2023 PFAS VALIDATED DATA REPORT

35

-------
% ^ /
ICF

Better Brite Plating and Zinc Superfund Site
PFAS Data Validation Package

ICF Region 5 ESAT
ICF DCN: 01338

Contract Number: 68HE0521F0046
TDF 1338

-------
Table of Contents

Better Brite Plating Company and Zinc Shop Superfund Site (SSID 055L)

Validation Memo	 1

Sample Receipt and Hold Time Summary	 12

Continuing Calibration Standard Summary	 14

EIS (Extracted Internal Standard (surrogate)) Recoveries	 17

EIS Area Response Summaries:

4/26/2023 	 21

4/28/2023 	 23

5/4/2023 	 25

Laboratory Reagent Blank Summaries:

MBLK-214976-214976a	 27

MBLK-215208-215208a	 28

MBLK-215053-215053a	 29

MBLK-215318-215318a	 30

LFB (Lab Fortified Blank (LCS)) Summaries:

LCS-WI-214976 	31

LCS-WI-215053 	 32

LCS-WI-215208	 33

LCS-WI-215318	 34

Matrix Spike Recovery Summaries:

23041906-09 MS (MW-7-230419)	 35

23041906-14A MS (MW-10-230420)	 36

23041906-21A MS (MW-108-230420)	 37

Matrix Spike Duplicate (LFSMD) Summaries:

23041906-09 MSD (MW-7-230419)	 38

23041906-14A MSD (MW-10-230420)	 39

23041906-21A MSD (MW-108-230420)	 40

-------
Appendix A: Laboratory Supplied Missing Data

Updated Instrument Batch Run Sheet LCMS1_230325 	 41

Updated Instrument Batch Run Sheet LCMS1_230426	 44

Missing CCV instrument data from LCMS1-230426A	47

Updated Instrument Batch Run Sheet LCMS1-230428A	 131

Missing CCV/ICV instrument data from LCMS1-230428A	 126

Updated Instrument Batch Run Sheet LCMS1-230428B	 238

Missing CCV/ICV instrument data from LCMS1-230428B	 242

Updated Instrument Batch Run Sheet LCMS1-230504B 	 296

Missing CCV/ICV instrument data from LCMS1-230504B	 299

-------
Region 5 ICF-ESAT Document Control Number:

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION 5

SUPERFUND AND EMERGENCY MANAGEMENT DIVISION

SUBJECT: Review of Data: 10/2/2023

Received for review on: 6/16/2023

FROM: Bruce Gallant, ICF Incorporated.

Contractor, Environmental Services Assistance Team (ESAT)

TO: Jennifer Knoepfle: USEPA Superfund Division

Contact email address: Knoepfle.jennifer@epa.gov
Gwen Saliares: Wisconsin Department of Natrural Resources
Contact email address: gwen.saliares@WDNR.gov

All sample results in the attached sample delivery group (SDG) have the following label:

Stage_2B_Validation_Electronic_and_Manual (S2BVEM)

SITE NAME: Better Brite Plating Company and Zinc Shop Superfund Site (055L)

SDG NUMBER (Lab Work Order): 23041906

Number and Type of Samples: 37 Water samples

Sample Numbers: 23041906-01 to 23041906-37

Laboratory: ALS Environmental Laboratory, Holland MI.

The following are our findings:

1

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Case: Better Brite
Site: Better Brite

Page 2 of 11
SDG: 23041906
Laboratory: ALS-Holland

Below is a summary of the out-of-control audits and the possible effects on the data for this
case:

Thirty-seven (37) samples, identified in the table below were collected between 4/18/2023-4/20/2023 The
samples were submitted to ALS Laboratory located in Holland, MI. The samples were received on 4/24/2023
intact and in good condition.

Sample Identifier (from COC)

Lab ID Number

Collection
Date/Time

Receipt
Temp.

Analysis
Requested

W-l-230418

23041906-01

4/18/2023 19:20

3.7°C

537

W-1A-230418

23041906-02

4/18/2023 13:18

3.7°C

537

MW-2-230418

23041906-03

4/18/2023 14:54

3.7°C

537

MW-3R-230418

23041906-04

4/18/2023 15:54

3.7°C

537

MW-5-230419

23041906-05

4/19/2023 19:58

3.7°C

537

MW-5A-230420

23041906-06

4/20/2023 17:00

3.7°C

537

MW-6-230418

23041906-07

4/18/2023 18:43

3.7°C

537

MW-6A-230418

23041906-08

4/18/2023 17:20

3.7°C

537

MW-7-230419

23041906-09

4/19/2023 09:13

3.7°C

537

MW-7A-230419

23041906-10

4/19/2023 11:17

3.7°C

537

MW-8-230420

23041906-11

4/20/2023 09:05

4.7°C

537

MW-8A-230420

23041906-12

4/20/2023 08:40

4.7°C

537

MW-9-230419

23041906-13

4/19/2023 08:45

4.7°C

537

MW-10-230420

23041906-14

4/20/2023 09:31

4.7°C

537

MW-11-230419

23041906-15

4/19/2023 13:30

4.7°C

537

MW-12-230419

23041906-16

4/19/2023 11:00

4.7°C

537

MW-106-230420

23041906-17

4/20/2023 11:45

4.7°C

537

MW-106A-230420

23041906-18

4/20/2023 17:25

4.7°C

537

MW-107-230419

23041906-19

4/19/2023 16:01

4.7°C

537

MW-107A-230419

23041906-20

4/19/2023 14:28

4.7°C

537

MW-108-230420

23041906-21

4/20/2023 12:06

3.2°C

537

MW-108A-230420

23041906-22

4/20/2023 12:45

3.2°C

537

MW-110-230420

23041906-23

4/20/2023 16:05

3.2°C

537

MW -110A-230420

23041906-24

4/20/2023 16:30

3.2°C

537

MW-112-230420

23041906-25

4/20/2023 15:46

3.2°C

537

MW-113-230419

23041906-26

4/19/2023 17:22

3.2°C

537

MW-115-230419

23041906-27

4/19/2023 19:09

3.2°C

537

MW-115A-230419

23041906-28

4/19/2023 18:49

3.2°C

537

MW-116-230419

23041906-29

4/19/2023 14:27

3.2°C

537

DUP-01-230418

23041906-30

4/18/2023

3.2°C

537

DUP-02-230418

23041906-31

4/18/2023

4.2°C

537

FB-01-230420

23041906-32

4/20/2023 17:45

4.2°C

537

FB-02-230420

23041906-33

4/20/2023 17:49

4.2°C

537

EB-01-230420

23041906-34

4/20/2023 17:55

4.2°C

537

MW-099-230420

23041906-35

4/20/2023 18:12

4.2°C

537

SUMP-230418

23041906-36

4/18/2023 12:54

4.2°C

537

DUO-03-230419

23041906-37

4/19/2023

4.2°C

537

All samples were analyzed for PFAS Compounds using EPA Method 537 MOD. All samples were reviewed
according to the PFAS Sampling at Better Brite Plating Co. Chrome and Zinc Shops Superfund Site De Pere,

Assembled by: Bruce Gallant, contractor ICF Int. LLC
Date: 10/2-11/09//23

2

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Case: Better Brite
Site: Better Brite

Page 3 of 11
SDG: 23041906
Laboratory: ALS-Holland

Wisconsin Rev 0. QAPP (Quality Assurance Project Plan), and EPA Method 537 QA/QC criteria. Data
generated is from a contracted laboratory outside of the Contract Laboratory Program and evaluated using
the laboratory supplied Electronic Data Deliverable (EDD) cross referencing the Level-IV pdf report. The
data validation generated forms are provided as a review reference and documentation of conformity.

Three samples were designated by, proxy (submission of 6 sample bottles), by the samplers to be used for
laboratory QC (Quality Control), i.e., MS/MSD analyses. The laboratory performed Matrix Spike/Matrix
Spike Duplicate analysis on samples 23041906-09A (MW-7-230419), 23041906-14A (MW-10-230420) and
23041906-21A (MW-108-230420).

Three field samples were designated as field duplicates by the samplers, source samples for these duplicates
were not identified. The Field duplicate samples were identified as: Dup-01-230418, DUP-02-230418 and
DUP-03-230419.

Each sampling point was sampled in duplicate unpreserved sample containers, at minimum, with the
exception of sample MW-5A-230420 for which the laboratory received only one sample container and MW-
099-230420 which was sampled into three containers.

The sample results have been reviewed for compliance with the QAPP worksheets and all non-compliances
are described in Section 12. - QAPP Compliance

Assembled by: Bruce Gallant, contractor ICF Int. LLC
Date: 10/2-11/09//23

3

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Case: Better Brite
Site: Better Brite

Page 4 of 11
SDG: 23041906
Laboratory: ALS-Holland

1.	HOLDING TIMES AND PRESERVATION:

All samples were extracted within 28 days of sampling and analyzed within 28 days of extraction.

2.	TUNE AND SYSTEM PERFORMANCE:

NOT APPLICABLE.

3.	CALIBRATION:

Initial calibrations were performed on 4/25/2023, 4/28/2023, and 5/4/2023. Quality Check Standards and
Continuing calibration standards were performed at the method required frequency and levels.

Continuing Calibration Standards: The laboratory injected a low level CCV prior to each of the reported
Mid-Level CCVs however data is not reported in the data package. Additional CCV's were injected at the
point of continuing calibration, these standards were also not reported in the data package. Missing standards
reports have been received from the laboratory. Data has been validated such as any one of the injected
standards recoveries applied to the samples.

The opening bracketing CCV (CCV1-230426 file ID 230426005) had recoveries greater than the QAPP
acceptable levels, reported values are flagged "J" (estimated), non-detects were not flagged:

No sample detects identified
8:2 FtS

The bracketing CCV (L0.1ppb_230323 and CCV4-230426, file ID's 230426045, 230426046) had recoveries
greater than the QAPP acceptable levels, reported values are flagged "J" (estimated), non-detects were not
flagged:

No sample detects identified
PFTriA, PFTeA

The ICCV (ICV1-230428, Files 230428212 and 230428213) had recoveries greater than the QAPP
acceptable levels, reported values are flagged "J" (estimated), non-detects were not flagged:

No sample detects identified

NMeFOSE, PFTrDA, PFTeDA

The bracketing CCV (L0.1ppb_230323 and CCV4-230504, Files 230428253 and 230428254) had recoveries
greater than the QAPP acceptable levels, reported values are flagged "J" (estimated), non-detects were not
flagged:

No sample detects identified
PFTrDA, PFTeDA

Assembled by: Bruce Gallant, contractor ICF Int. LLC
Date: 10/2-11/09//23

4

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Case: Better Brite
Site: Better Brite

Page 5 of 11
SDG: 23041906
Laboratory: ALS-Holland

The bracketing CCV (CCV5-230504, File 230504133) had recoveries lower than the QAPP acceptable
levels, reported values are flagged "J" (estimated), non detects are flagged "UJ".

MW-108-230420MS, MW-108-230420MSD, 2MW-108-230420
PFTrDA, PFTeDA

The bracketing CCV (CCV6-230504, File 230504139) had recoveries lower than the QAPP acceptable
levels, reported values are flagged "J" (estimated), non detects are flagged "UJ".

MW-108-230420MS, MW-108-230420MSD, 2MW-108-230420
PFTrDA, PFTeDA

4.	LABORATORY REAGENT BLANKS

Analysis of Laboratory Reagent Blank (LRB) was found to be free of contamination above the required 'A
of LOQ (Level of quantitation).

5.	Extracted Internal STANDARDS (EIS)

Extracted Internal Standards (EIS) Responses:

The responses of the Isotope Performance Compounds were found to be acceptable with responses between
25-150% of the average responses from the initial calibration standards with the following exceptions.

Samples exhibiting EIS responses greater than 150 % the preceding CCV are flagged "J-" for analytes found
in the sample and "UJ" for non-detects:

MW-10-230420, MW-10-230420RI, MW-2-230418, MW-10-230420MS, MW-10-230420MSD
4:2 FTS

23041906-14MS( MW-10-230420MS), 23041906-14MSD( MW-10-230420MSD)

6:2-FTS

Samples exhibiting IES responses lower than required limits are flagged "J+", non-detects are not flagged.

MW-10-230420, MW-10-230420RI, 23041906-21AMSD, 23041906-21AMSDR1
NMeFOSE, PFTeDA

6. LABORATORY FORTIFIED SAMPLE MATRIX (LFSM)

Sample 23041906-09A (MW-7-230419) was used as a matrix spike/spike duplicate with all recoveries and
RPDs within QA Limits.

Sample 23041906-14A ( MW-10-230420) was used as a matrix spike/spike duplicate. All RPDs were within
QA Limits. The % recovery was lower than QA limits for:

Assembled by: Bruce Gallant, contractor ICF Int. LLC
Date: 10/2-11/09//23

5

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Case: Better Brite
Site: Better Brite

Page 6 of 11
SDG: 23041906
Laboratory: ALS-Holland

23041906-14A
DONA

Sample 23041906-21A (MW-108-230420) was used as a matrix spike/spike duplicate. Analysis of the
MS/MSD pair on 4/28 could not be used as batch QC as the lab neglected to extract the parent sample in the
batch. The sample and MS/MSD were re-extracted on 5/1/2023 and re-analyzed multiple times on the 5/4
analytical batch. From the analytical report provided the validator is unable to determine which reported
values came from which replicate of the 4 analyses performed that day. The EDD contains duplicate data
values for the MS and MSD for all analytes. The lab needs to decide which result is the valid result and
correct the EDD to contain one result for each compound for the MS and MSD sample. Note that results
from only one of the analytical injections was used for the sample

7. CLEANUP PROCEDURES

Not Applicable.

8 LABORATORY FORTIFIED BLANK (LFB):

The Laboratory fortified Blank recoveries were all found to be within QAPP requirements of 50-150%.
9. ISOTOPE DILUTION ANALOGUES STANDARD (IDS) RECOVERIES:

Extracted Internal Standards (EIS) Recoveries:

The recoveries of the Extracted Internal Standards were all within QAPP required limits of 25-150% (10-
150% for 13C5-FOSA, d3-N-MeFOSA, d5-N-EtFOSA, d7-N-MeFOSE and d9-N-EtFOSE) with the
following exceptions:

The following samples had the Extracted Internal Standard, 13C2-FtS 4:2, recoveries higher than QAPP
Limits, reported values should be considered as "J-" for associated reported analytes, non-detected analytes
are flagged "UJ":

MW-2-230418, MW-10-230420, MW-10-230420MS, MW-10-230420-MSD
4:2 FtS

The following samples had the Extracted Internal Standard, 13C2-FtS 6:2, recovered higher than QAPP
Limits, reported values should be considered as "J-" for associated reported analytes, non-detected analytes
are flagged "UJ":

MW-10-230420MS, MW-10-230420-MSD
6:2 FtS

The following samples had the Extracted Internal Standard, 13C2-PFTeA, recovered higher than QAPP
Limits, reported values should be considered as "J-" for associated reported analytes, non-detected analytes
are flagged "UJ":

Assembled by: Bruce Gallant, contractor ICF Int. LLC
Date: 10/2-11/09//23

6

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Case: Better Brite
Site: Better Brite

Page 7 of 11
SDG: 23041906
Laboratory: ALS-Holland

MW-10-230420
PFTeA

10. TARGET ANALYTE QUANTITATION AND SAMPLE ANALYSIS:

The following table lists samples with target analytes above volume adjusted MRL and their associated
method blank:

Assembled by: Bruce Gallant, contractor ICF Int. LLC
Date: 10/2-11/09//23

7

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Case: Better Brite
Site: Better Brite

Page 8 of 11
SDG: 23041906
Laboratory: ALS-Holland







Sample Result

Data



Associated

Lab Sample ID

Sample ID

Compound

(ng/L)

Flag

Batch

MB Value

23041906-01

W-1-230418

Perfluorooctanesulfonic Acid (PFOS)

6.0



214976a

ND





Perfluorooctanoic Acid (PFOA)

5.6



214976a

ND

23041906-02

W-1A-230418

Perfluorobutanoic Acid (PFBA)

8.8



214976a

ND





Perfluoroheptanoic Acid (PFHpA)

5.3



214976a

ND





Perfluorohexanesulfonic Acid (PFHxS)

25



214976a

ND





Perfluorohexanoic Acid (PFHxA)

13



214976a

ND





Perfluorooctanesulfonic Acid (PFOS)

3



214976a

ND





Perfluorooctanoic Acid (PFOA)

12



214976a

ND





Perfluoropentanoic Acid (PFPeA)

8.4



214976a

ND

23041906-03

MW-2-230418

Perfluorobutanoic Acid (PFBA)

15



215053a

ND





Perfluorooctanesulfonic Acid (PFOS)

54



215053a

ND





Perfluorooctanoic Acid (PFOA)

11



215053a

ND

23041906-04

MW-3R-230418

Perfluorooctanoic Acid (PFOA)

2.3



215053a

ND

23041906-05

MW-5-230419

Perfluorobutanoic Acid (PFBA)

11



215053a

ND





Perfluorohexanoic Acid (PFHxA)

5.8



215053a

ND





Perfluorooctanesulfonic Acid (PFOS)

13



215053a

ND





Perfluorooctanoic Acid (PFOA)

29



215053a

ND

23041906-07

MW-6-230418

Perfluorohexanesulfonic Acid (PFHxS)

150



215053a

ND





Perfluorohexanoic Acid (PFHxA)

6.0



215053a

ND





Perfluorooctanesulfonic Acid (PFOS)

43



215053a

ND





Perfluorooctanoic Acid (PFOA)

22



215053a

ND

23041906-11

MW-8-230420

Perfluorobutanoic Acid (PFBA)

9.0



215053a

ND

23041906-13

MW-9-230419

Perfluorooctanesulfonic Acid (PFOS)

4.7



215053a

ND

23041906-14

MW-10- 230420

Perfluorobutanesulfonic Acid (PFBS)

8.3



215053a

ND





Perfluorobutanoic Acid (PFBA)

19



215053a

ND





Perfluoroheptanoic Acid (PFHpA)

9.7



215053a

ND





Perfluorohexanoic Acid (PFHxA)

14



215053a

ND





Perfluorooctanesulfonic Acid (PFOS)

34



215053a

ND





Perfluorooctanoic Acid (PFOA)

31



215053a

ND





Perfluoropentanoic Acid (PFPeA)

16



215053a

ND

23041906-15

MW-11-230419

Perfluorooctanesulfonic Acid (PFOS)

5.1



215053a

ND





Perfluorooctanoic Acid (PFOA)

7.8



215053a

ND

23041906-16

MW-12-230419

Perfluorooctanesulfonic Acid (PFOS)

21



215053a

ND





Perfluorooctanoic Acid (PFOA)

9



215053a

ND

23041906-19

MW-10-230420

Perfluorooctanesulfonic Acid (PFOS)

2.1



215053a

ND

23041906-20

MW-107A-230419

Perfluorooctanesulfonic Acid (PFOS)

3.2



215208a

ND

23041906-21

MW-108-230420

Perfluorobutanoic Acid (PFBA)

6.1



215208a

ND

23041906-23

MW-110-230420

Perfluorooctanesulfonic Acid (PFOS)

2.8



215208a

ND

23041906-25

MW-112-230420

Perfluorobutanesulfonic Acid (PFBS)

0.36



215208a

ND





Perfluorooctanesulfonic Acid (PFOS)

0.91



215208a

ND

23041906-26

MW-113-230419

Perfluorobutanesulfonic Acid (PFBS)

5.7



215208a

ND





Perfluorobutanoic Acid (PFBA)

10



215208a

ND





Perfluoroheptanoic Acid (PFHpA)

7.9



215208a

ND





Perfluorohexanoic Acid (PFHxA)

15



215208a

ND





Perfluorooctanesulfonic Acid (PFOS)

36



215208a

ND





Perfluorooctanoic Acid (PFOA)

23



215208a

ND





Perfluoropentanoic Acid (PFPeA)

15



215208a

ND

23041906-29

MW-116-230419

Perfluorooctanesulfonic Acid (PFOS)

9.3



215208a

ND





Perfluorooctanoic Acid (PFOA)

5.7



215208a

ND

23041906-30

DUP-01-230418

Perfluorobutanoic Acid (PFBA)

10



215208a

ND





Perfluorooctanesulfonic Acid (PFOS)

4.2



215208a

ND





Perfluorooctanoic Acid (PFOA)

7.9

C

215208a

ND



AS

^TO^anS^e§fp#y$nt, contractor

IU±< l£t. LL

215208a

ND

-------
Case: Better Brite
Site: Better Brite

Page 9 of 11
SDG: 23041906
Laboratory: ALS-Holland







Sample Result

Data



Associated

Lab Sample ID

Sample ID

Compound

(ng/L)

Flag

Batch

MB Value

23041906-35

MW-099-230420

HCI-Pf30UdS

270



215208a

ND





4,8-Dioxa-3H-perfluorononanoic Acid (DONA)

230



215208a

ND





9CI-PF30NS

240



215208a

ND





Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

210



215208a

ND





Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

450



215208a

ND





Hexafluoropropylene oxide dimer acid (HFPO-DA)

190



215208a

ND





N-Ethylperfluorooctanesulfonamidoacetic Acid

470



215208a

ND





N-Methylperfluorooctanesulfonamidoacetic Acid

250



215208a

ND





Perfluorobutanesulfonic Acid (PFBS)

170



215208a

ND





Perfluorobutanoic Acid (PFBA)

180



215208a

ND





Pe rf 1 uo rode can esu If onic Acid (PFDS)

200



215208a

ND





PerfluorodecanoicAcid (PFDA)

250



215208a

ND





Perfluorododecanoic Acid (PFDoA)

380



215208a

ND





Perfluoroheptanesu If onic Acid (PFHpS)

440



215208a

ND





Perfluoroheptanoic Acid (PFHpA)

150



215208a

ND





Perfluorohexanesu If onic Acid (PFHxS)

400



215208a

ND





Pe rfluorononanesu If onic Acid (PFNS)

150



215208a

ND





Perfluorononanoic Acid (PFNA)

130



215208a

ND





Perfluorooctanesulfonamide (PFOSA)

210



215208a

ND





Perfluorooctanesulfonic Acid (PFOS)

180



215208a

ND





Perfluorooctanoic Acid (PFOA)

210



215208a

ND





Perfluoropentanoic Acid (PFPeA)

330



215208a

ND

23041906-36

SUMP-230418

Perfluorobutanoic Acid (PFBA)

10



215208a

ND





Perf luorooctanesulfonic Acid (PFOS)

3



215208a

ND





Perfluorooctanoic Acid (PFOA)

7.2



215208a

ND

23041906-37

DUP-03-230419

Perf luorooctanesulfonic Acid (PFOS)

8.7



215208a

ND





Perfluorooctanoic Acid (PFOA)

5.4



215208a

ND

11. FIELD QC SAMPLES:

No analytes were detected in the field QC samples above the MRL (adjusted for volume extracted). Parent
samples to the field duplicates were not transmitted and a comparison could not be performed.

Sample MW-099-230420 (23041906-35) was a blind QC sample provided by ERA. The laboratory detected
all analytes within the published ranges resulting in a 100% correct score:

Assembled by: Bruce Gallant, contractor ICF Int. LLC
Date: 10/2-11/09//23

9

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Case: Better Brite
Site: Better Brite

Page 10 of 11
SDG: 23041906
Laboratory: ALS-Holland

Analyte Name

Abbreviation

Certified
Value

Acceptance
Limits

Lab
Result



Acceptable
Y/N?

ll-Chloroicosafluoro-3-oxaundecane-l-sulfonic acid

11CI—PF30UdS

316

190-442

270

85.4%

Y

9-Chlorohexadecafluoro-3-oxanonane-l-sulfonic acid

9CI-PF30NS

270

162-378

240

88.9%

Y

4,8-Dioxa-3H-perfluorononanoic acid

ADONA

259

155-363

230

88.8%

Y

Hexafluoropropylene oxide dimeracid

HFPO-DA

200

120-280

190

95.0%

Y

Perfluorobutanoic acid

PFBA

185

111-259

180

97.3%

Y

Pe rfI u o ro b u ta n e s u I fo n i c a ci d

PFBS

177

106-248

170

96.0%

Y

lH,lH,2H,2H-Perfluorodecane sulfonic acid

8:2FTS

479

287-671

450

93.9%

Y

Perfluorodecanoic acid

PFDA

240

144-336

250

104.2%

Y

Perfluorododecanoic acid

PFDoA

400

240-560

380

95.0%

Y

Perfluoroheptanesulfonic acid

PFHpS

443

266-620

440

99.3%

Y

Perfluoroheptanoic acid

PFHpA

155

93.0-217

150

96.8%

Y

lH,lH,2H,2H-Perfluorohexane sulfonic acid

4:2FTS

229

137-321

210

91.7%

Y

Perfluorohexanesulfonic acid

PFHxS

410

246-574

400

97.6%

Y

Perfluorohexanoic acid

PFHxA

<60

-

<5.1



Y

Perfluorononanoic acid

PFNA

135

81.0-189

130

96.3%

Y

lH,lH,2H,2H-Perfluorooctane sulfonic acid

6:2FTS

<60

-

<5.1



Y

Perfluorooctanesulfonic acid

PFOS

200

120-280

180

90.0%

Y

Perfluorooctanoic acid

PFOA

230

138-322

210

91.3%

Y

Perfluoropentanoic acid

PFPe A

360

216-504

330

91.7%

Y

Perfluoropentanesulfonic acid

PFPeS

<60

64.8-151

0.97



Y

Perfluoroundecanoic acid

PFUnDA

<60

-

<5.1



Y

N-ethy perfl uroocta nesulfona midoacetic aci d

NEtFOSSA

480

288-672

470

97.9%

Y

N-methylperfluorooctanesulfonamidoacetic acid

NMeFOSAA

245

147-373

250

102.0%

Y

Perfl uo rode cane sulfonic acid

PFDS

227

136-318

200

88.1%

Y

Perfluorononane sulfonic acid

PFNS

173

104-242

150

86.7%

Y

Perfluoroctane sulfonamide

PFOSAm

225

135-315

210

93.3%

Y

Perfluorotetradecanoic acid

PFTe A

<60



<5.3



Y

Perfluorotridecanoic acid

PFTri A

<60

-

<5.1



Y

12. QAPP COMPLIANCE:

The analytical package fulfilled the component QC requirements of the QAPP and EPA Method 537.

13. DOCUMENTATION

The supplied Electronic Data Deliverable contains three additional compounds: Fluorotelomer Sulphonic
Acid 10:2 (FtS 10:2), Perfluorohexadecanoic Acid (PFHxDA) and Perfluorooctadecanoic Acid (PFODA).

The laboratory, on two of the three days during sample analysis, ran additional CCVs at the L0. lppb and at
the regular CCV level of 1.0 ppb. The data for these standards was not included in the data package and was
supplied by the lab upon request. Because this practice is not in the SOP, QAPP or standard practice, each of
the CCVs was evaluated separately and any data flagging generated by individual CCVs was applied to the
associated data. ICF strongly recommends that the customer (TRC) request an updated Level-IV package to
include the missing data and updated narrative for archive purposes.

Assembled by: Bruce Gallant, contractor ICF Int. LLC
Date: 10/2-11/09//23

10

-------
Page 11 of 11

Case: Better Brite	SDG: 23041906

Site: Better Brite	Laboratory: ALS-Holland

EXES SFAM01.1 Data Qualifier Sheet

Validation Data Qualifier Sheet
Qualifiers	Data Qualifier Definitions

U	The analyte was analyzed for but was not detected above the reported

sample quantitation limit.

J	The result is an estimated quantity. The associated numerical value is

the approximate concentration of the analyte in the sample.

J+	The result is an estimated quantity, but the results may be biased high.

J-	The result is an estimated quantity, but the results may be biased low.

NJ	The analyte has been "tentatively identified" or "presumptively" as

present and the associated numerical value is the estimated
concentration in the sample.

UJ	The analyte was analyzed for but was not detected. The reported

quantitation limit is approximate and may be inaccurate or imprecise.

R	The data is unusable. The sample results are rejected due to serious

deficiencies in meeting QC criteria. The analyte may or may not be
present in the sample.

Assembled by: Bruce Gallant, contractor ICF Int. LLC
Date: 10/2-11/09//23

11

-------
iCF international LLC
EPA Region 5 ESAT

SAMPLE RECEIPT/HOLD TIME SUMMARY

SDG/Lab Work Order Number:	23041906

Evaluation

SampleType

Criteria

Action

Detected

Non-Detected

Not Preserved with
Ammonium Acetate

Aqueous

Ratio of Ig/L maintained

J

R

Storge Temperature

Aqueous

If receipt >10C or Storage >

6C

J

UJ

Sample Extraction Hold
Time

Aqueous

<28 Davs

No Qualification

>28 Davs

J

UJ

Grossly exceeded

J

R

Analysis Time after
extraction

Aqueous

< 28 davs

No Qualification

> 28 davs

J

UJ

Grossly exceeded

J

R

Sample Id

Lab ID

COC Sampling Date

Shipping
Date

Lab Received
Date

Total Davs
Sampling to
Receipt

Extraction
Date

Total Davs
sampling

Analysis Date

Total Davs
extraction

Qua

Detect

ifier

Non Detect

23041906-09A MS

23041906-09A MS

4/19/2023



4/22/2023

3

4/25/2023

6

4/26/2023

1





23041906-09A MSD

23041906-09A MSD

4/19/2023



4/22/2023

3

4/25/2023

6

4/26/2023

1





MW-7-230419

23041906-09A

4/19/2023



4/22/2023

3

4/25/2023

6

4/26/2023

1





W-l-230418

23041906-01A

4/18/2023



4/22/2023

4

4/25/2023

7

4/27/2023

2





W-1A-230418

23041906-02A

4/18/2023



4/22/2023

4

4/25/2023

7

4/27/2023

2





MW-10-230420

23041906-14A

4/20/2023



4/22/2023

2

4/26/2023

6

4/27/2023

1





MW-2-230418

23041906-03A

4/18/2023



4/22/2023

4

4/26/2023

8

4/27/2023

1





MW-3R-230418

23041906-04A

4/18/2023



4/22/2023

4

4/26/2023

8

4/27/2023

1





MW-5-230419

23041906-05A

4/19/2023



4/22/2023

3

4/26/2023

7

4/27/2023

1





MW-5A-230420

23041906-06A

4/20/2023



4/22/2023

2

4/26/2023

6

4/27/2023

1





MW-6-230418

23041906-07A

4/18/2023



4/22/2023

4

4/26/2023

8

4/27/2023

1





MW-6A-230418

23041906-08A

4/18/2023



4/22/2023

4

4/26/2023

8

4/27/2023

1





MW-7A-230419

23041906-10A

4/19/2023



4/22/2023

3

4/26/2023

7

4/27/2023

1





MW-8-230420

23041906-11A

4/20/2023



4/22/2023

2

4/26/2023

6

4/27/2023

1





MW-8A-230420

23041906-12A

4/20/2023



4/22/2023

2

4/26/2023

6

4/27/2023

1





MW-9-230419

23041906-13A

4/19/2023



4/22/2023

3

4/26/2023

7

4/27/2023

1





MW-n-230419

23041906-15A

4/19/2023



4/22/2023

3

4/26/2023

7

4/27/2023

1





MW-12-230419

23041906-16A

4/19/2023



4/22/2023

3

4/26/2023

7

4/27/2023

1





MW-106-230420

23041906-17A

4/20/2023



4/22/2023

2

4/26/2023

6

4/27/2023

1





MW-106A-230420

23041906-18A

4/20/2023



4/22/2023

2

4/26/2023

6

4/27/2023

1





MW-107-230419

23041906-19A

4/19/2023



4/22/2023

3

4/26/2023

7

4/27/2023

1





MW-10-230420

23041906-14A

4/20/2023



4/22/2023

2

4/26/2023

6

4/27/2023

1





MW-108A-230420

23041906-22A

4/20/2023



4/22/2023

2

4/28/2023

8

4/30/2023

2





MW-110A-230420

23041906-24A

4/20/2023



4/22/2023

2

4/28/2023

8

4/30/2023

2





MW-112-230420

23041906-25A

4/20/2023



4/22/2023

2

4/28/2023

8

4/30/2023

2





MW-113-230419

23041906-26A

4/19/2023



4/22/2023

3

4/28/2023

9

4/30/2023

2





MW-115-230419

23041906-27A

4/19/2023



4/22/2023

3

4/28/2023

9

4/30/2023

2





MW-115A-230419

23041906-28A

4/19/2023



4/22/2023

3

4/28/2023

9

4/30/2023

2





MW-116-230419

23041906-29A

4/19/2023



4/22/2023

3

4/28/2023

9

4/30/2023

2





DUP-01-230418

23041906-30A

4/18/2023



4/22/2023

4

4/28/2023

10

4/30/2023

2





DUP-02-230418

23041906-31A

4/18/2023



4/22/2023

4

4/28/2023

10

4/30/2023

2





FB-01-230420

23041906-32A

4/20/2023



4/22/2023

2

4/28/2023

8

4/30/2023

2





FB-02-230420

23041906-33A

4/20/2023



4/22/2023

2

4/28/2023

8

4/30/2023

2





23041906-14A MS

23041906-14A MS

4/20/2023



4/22/2023

2

4/26/2023

6

5/4/2023

8





23041906-14A MSD

23041906-14A MSD

4/20/2023



4/22/2023

2

4/26/2023

6

5/4/2023

8





23041906-21A MS

23041906-21A MS

4/20/2023



4/22/2023

2

5/1/2023

11

5/4/2023

3





23041906-21A MSD

23041906-21A MSD

4/20/2023



4/22/2023

2

5/1/2023

11

5/4/2023

3





MW-107A-230419

23041906-20A

4/19/2023



4/22/2023

3

4/28/2023

9

5/5/2023

7





MW-108A-230420

23041906-22A

4/20/2023



4/22/2023

2

4/28/2023

8

5/5/2023

7





MW-110-230420

23041906-23A

4/20/2023



4/22/2023

2

4/28/2023

8

5/5/2023

7





_
'ICF

12

-------
iCF international LLC
EPA Region 5 ESAT

SAMPLE RECEIPT/HOLD TIME SUMMARY

SDG/Lab Work Order Number:	23041906

Evaluation

SampleType

Criteria

Action

Detected

Non-Detected

Not Preserved with
Ammonium Acetate

Aqueous

Ratio of Ig/L maintained

J

R

Storge Temperature

Aqueous

If receipt >10C or Storage >

6C

J

UJ

Sample Extraction Hold
Time

Aqueous

<28 Davs

No Qualification

>28 Davs

J

UJ

Grossly exceeded

J

R

Analysis Time after
extraction

Aqueous

< 28 davs

No Qualification

> 28 davs

J

UJ

Grossly exceeded

J

R

Sample Id

Lab ID

COC Sampling Date

Shipping
Date

Lab Received
Date

Total Davs
Samplingto
Receiot

Extraction
Date

Total Davs

Analysis Date

T>:
-------


LLCCV1-230426 File: 230426003
Injected 4/26 7:13:16 PM
REPORTED

CCV-1-230426-WI File: 230426004
Injected 4/26 ? w PM NOT
REPORTED

CCV1-230426 File: 230426005
Injected 4/26 7:40:50 PM NOT
REPORTED

L0.1ppb_230323 File: 230426018
Injected 4/26 10:39:41 PM NOT
REPORTED

CCV2-230426 File: 230426019
Injected 4/26 10:53:25 PM
REPORTED

CCV2-230426 File: 230426020
Injected 4/26 11:07:10 PM NOT
REPORTED

L0.1ppb_230323 File: 230426032
Injected 4/27 1:52:12 AM NOT
REPORTED

CCV3-230426 File: 230426033
Injected 4/27 2:05:56 AM
REPORTED

L0.1ppb_230323 File: 230426045
Injected 4/27 4:50:57 AM NOT
REPORTED

CCV4-230426 File: 230426046
Injected 4/27 5:04:41 AM NOT
REPORTED

CCV4-230426 File: 230426047
Injected 4/27 5:18:26 AM
REPORTED

L0.1ppb_230323 File: 230426059
Injected 4/27 8:03:33 AM NOT
REPORTED

CCV5-230426 File: 230426060
Injected 4/27 8:17:17 AM
REPORTED

CCV5-230426 File: 230426061
Injected 4/27 8:31:02 AM NOT
REPORTED

L0.1ppb_230323 File: 230426071
Injected 4/27 10:48:45 AM NOT
REPORTED

CCV6-230426 File: 230426072
Injected 4/27 11:02:28 AM
REPORTED

CCV6-230426 File: 230426073
Injected 4/27 11:16:14 AM NOT
REPORTED

L0.1ppb_230323 File: 230426081
Injected 4/27 1:06:19 PM NOT
REPORTED

CCV7-230426 File: 230426082
Injected 4/271:20:04 PM
REPORTED

Compound







































PFBA

107%

93%

110%

74%

97%

100%

97%

100%

79%

94%

99%

84%

99%

101%

97%

100%

100%

88%

96%

PFPeA

105%

99%

107%

97%

94%

93%

93%

93%

101%

94%

93%

94%

92%

92%

93%

92%

92%

90%

91%

PFBS

110%

98%

104%

81%

91%

91%

76%

88%

117%

102%

91%

92%

89%

88%

89%

88%

91%

94%

94%

HFPO_DA

68%

105%

110%

101%

95%

95%

78%

93%

118%

104%

93%

87%

93%

89%

92%

89%

93%

90%

98%

4-2-FtS

92%

99%

120%

97%

97%

98%

103%

98%

78%

95%

95%

97%

94%

97%

98%

99%

98%

92%

93%

PFHxA

106%

113%

117%

98%

99%

101%

106%

103%

90%

97%

101%

109%

99%

100%

103%

98%

100%

106%

99%

PFPeS

107%

91%

103%

93%

94%

96%

89%

93%

80%

98%

94%

87%

96%

95%

101%

93%

91%

86%

96%

PFHxS

118%

104%

101%

79%

84%

85%

98%

82%

102%

89%

87%

97%

83%

85%

90%

85%

89%

90%

87%

PFHpA

108%

97%

112%

102%

101%

102%

115%

103%

104%

100%

100%

108%

102%

102%

100%

101%

105%

105%

98%

PFHpS

101%

91%

105%

78%

91%

95%

94%

93%

86%

99%

96%

87%

96%

97%

88%

96%

95%

88%

99%

6-2-FTS

76%

104%

122%

90%

96%

97%

84%

107%

76%

100%

101%

91%

100%

103%

109%

100%

103%

105%

99%

PFOA

94%

90%

99%

87%

90%

89%

89%

87%

92%

89%

91%

98%

92%

90%

89%

93%

91%

91%

90%

PFOS

104%

109%

108%

87%

94%

93%

99%

95%

113%

94%

94%

81%

94%

88%

93%

96%

94%

86%

89%

PFNA

107%

100%

111%

98%

98%

96%

106%

99%

78%

83%

96%

99%

98%

105%

100%

103%

102%

92%

94%

PFNS

98%

95%

110%

107%

98%

96%

92%

99%

84%

101%

101%

82%

100%

99%

115%

101%

100%

91%

98%

8-2-FTS

123%

118%

135%

71%

105%

103%

105%

108%

77%

99%

109%

95%

117%

107%

111%

105%

108%

112%

109%

PFDA

107%

98%

112%

94%

97%

98%

100%

101%

104%

98%

99%

99%

98%

97%

104%

100%

99%

98%

95%

NMeFOSAA

108%

99%

103%

74%

89%

93%

93%

95%

72%

95%

92%

83%

92%

94%

100%

90%

88%

104%

94%

PFDS

86%

101%

110%

109%

101%

97%

82%

101%

86%

99%

99%

81%

98%

99%

80%

103%

99%

89%

97%

PFUnDA

97%

112%

117%

105%

104%

104%

109%

105%

89%

87%

104%

100%

105%

102%

104%

109%

106%

92%

93%

NEtFOSAA

99%

101%

108%

100%

96%

99%

107%

99%

98%

93%

99%

116%

105%

101%

107%

102%

102%

105%

99%

PFOSA

75%

93%

102%

89%

86%

88%

90%

94%

116%

103%

94%

94%

91%

90%

97%

97%

95%

102%

101%

PFDoA

102%

97%

104%

95%

90%

95%

96%

96%

120%

103%

98%

111%

100%

102%

100%

99%

101%

109%

101%

NMeFOSE

94%

88%

92%

99%

89%

88%

90%

86%

116%

106%

91%

91%

89%

90%

89%

90%

89%

100%

105%

NEtFOSE

98%

87%

95%

101%

98%

95%

90%

96%

102%

101%

103%

95%

98%

103%

104%

104%

104%

105%

106%

NMeFOSA

88%

104%

113%

95%

105%

102%

118%

101%

125%

108%

109%

96%

102%

104%

114%

106%

108%

107%

105%

NEtFOSA

111%

91%

104%

104%

97%

98%

91%

98%

88%

99%

102%

114%

101%

99%

93%

100%

102%

98%

99%

PFTrDA

117%

97%

104%

99%

93%

91%

92%

90%

292%

155%

100%

104%

94%

86%

89%

91%

94%

120%

117%

PFTeDA

111%

83%

93%

91%

82%

80%

81%

78%

326%

142%

91%

103%

88%

82%

90%

81%

86%

128%

114%

HCI-PF30UdS

89%

92%

113%

88%

99%

99%

106%

98%

94%

101%

95%

89%

96%

97%

96%

98%

93%

98%

97%

9CI-PF30NS

99%

99%

114%

100%

100%

101%

95%

99%

86%

95%

99%

106%

100%

97%

94%

99%

99%

100%

98%

L-PFDoS

81%

125%

120%

97%

103%

102%

109%

99%

104%

103%

101%

92%

102%

96%

107%

103%

96%

90%

99%

NaDONA

86%

85%

98%

82%

86%

88%

83%

86%

96%

100%

88%

93%

94%

94%

101%

98%

97%

105%

102%

14

-------


CCV7-230426 File: 230426083
Injected 4/27 1:33:49 PM NOT
REPORTED



ICV1-230428 File: 230428212
Injected 4/29 11:38:27 PM NOT
REPORTED

ICV1-230428 File: 230428213
Injected 4/29 11:52:15 PM NOT
REPORTED

LLCCV1-230428-WI File:
230428214 Injected 4/30 12:05:58
AM REPORTED

CCV1-230428-WI File: 230428215
Injected 4/30 12:19:42 AM NOT
REPORTED

L0.1ppb_230323 File: 230428227
Injected 4/30 3:04:38 AM NOT
REPORTED

CCV2_230428 File: 230428228
Injected 4/30 3:18:27 AM NOT
REPORTED

CCV2_230428 File: 230428229
Injected 4/30 3:32:29 AM
REPORTED

L0.1ppb_230323 File: 230428241
Injected 4/30 6:17:08 AM NOT
REPORTED

CCV3_230428 File: 230428242
Injected 4/30 6:30:52 AM NOT
REPORTED

CCV2_230428 File: 230428229
Injected 4/30 3:32:29 AM
REPORTED

L0,lppb_230323 File: 230428253
Injected 4/30 9:02:11 AM NOT
REPORTED

CCV4-2304283 File: 230428254
Injected 4/30 9:15:55 AM NOT
REPORTED

CCV4-2304283 File: 230428255
Injected 4/30 9:29:40 AM
REPORTED



ICV1-230504 File: 230504068
Injected 5/4 6:34:18 PM
REPORTED

ICV1-230504 File: 230504069
Injected 5/4 6:48:02 PM NOT
REPORTED

CCV2-230504 File: 230504081
Injected 5/4 9:33:10 PM
REPORTED

CCV2-230504 File: 230504082
Injected 5/4 9:46:54 PM NOT
REPORTED

Compound







































PFBA

99%



101%

108%

93%

94%

89%

98%

99%

84%

116%

99%

70%

96%

95%



115%

129%

100%

98%

PFPeA

91%



117%

118%

109%

97%

101%

105%

105%

109%

106%

105%

106%

107%

105%



106%

105%

99%

102%

PFBS

91%



129%

118%

100%

107%

88%

96%

97%

99%

98%

97%

99%

108%

107%



111%

108%

100%

101%

HFPO_DA

91%



119%

119%

107%

98%

86%

105%

105%

101%

99%

105%

94%

109%

110%



109%

112%

97%

102%

4-2-FtS

94%



115%

117%

121%

101%

89%

96%

101%

102%

102%

101%

109%

97%

97%



103%

99%

102%

98%

PFHxA

97%



108%

110%

116%

99%

100%

104%

103%

103%

104%

103%

111%

102%

102%



106%

104%

98%

101%

PFPeS

95%



116%

114%

109%

107%

94%

106%

102%

106%

104%

102%

114%

108%

113%



110%

107%

102%

105%

PFHxS

87%



110%

105%

112%

98%

90%

93%

93%

110%

88%

93%

111%

94%

97%



114%

115%

103%

111%

PFHpA

99%



110%

110%

118%

98%

102%

104%

104%

105%

103%

104%

99%

100%

103%



108%

104%

97%

99%

PFHpS

96%



113%

94%

91%

94%

84%

94%

89%

104%

90%

89%

105%

97%

94%



102%

102%

97%

101%

6-2-FTS

103%



130%

128%

92%

89%

70%

96%

101%

126%

97%

101%

131%

99%

103%



100%

92%

99%

95%

PFOA

93%



107%

110%

109%

100%

101%

96%

96%

97%

101%

96%

107%

99%

96%



100%

108%

93%

94%

PFOS

89%



116%

110%

113%

103%

85%

97%

104%

97%

102%

104%

103%

98%

97%



103%

104%

97%

99%

PFNA

91%



82%

91%

88%

80%

98%

91%

90%

89%

89%

90%

71%

81%

85%



97%

102%

99%

91%

PFNS

94%



120%

109%

120%

101%

94%

104%

106%

106%

101%

106%

88%

98%

100%



101%

104%

97%

94%

8-2-FTS

97%



89%

92%

119%

85%

105%

91%

96%

85%

95%

96%

81%

75%

87%



91%

92%

95%

82%

PFDA

97%



115%

115%

85%

97%

101%

95%

99%

91%

98%

99%

103%

101%

99%



101%

104%

100%

101%

NMeFOSAA

91%



105%

109%

106%

102%

90%

96%

97%

95%

98%

97%

82%

94%

93%



104%

110%

103%

100%

PFDS

98%



107%

104%

111%

95%

75%

95%

96%

91%

95%

96%

80%

93%

92%



100%

105%

94%

94%

PFUnDA

88%



82%

92%

90%

89%

95%

91%

93%

95%

93%

93%

80%

80%

82%



95%

102%

98%

93%

NEtFOSAA

103%



82%

82%

109%

87%

88%

86%

92%

101%

93%

92%

91%

84%

82%



105%

112%

103%

99%

PFOSA

97%



118%

108%

101%

85%

86%

90%

90%

80%

89%

90%

100%

94%

96%



101%

106%

105%

97%

PFDoA

105%



106%

97%

91%

99%

88%

84%

86%

95%

84%

86%

92%

89%

88%



90%

101%

102%

86%

NMeFOSE

103%



138%

118%

106%

94%

109%

101%

105%

104%

108%

105%

115%

113%

116%



104%

101%

96%

101%

NEtFOSE

107%



79%

85%

74%

88%

76%

83%

84%

83%

80%

84%

83%

81%

82%



80%

106%

101%

77%

NMeFOSA

103%



97%

106%

97%

92%

102%

97%

93%

94%

93%

93%

94%

94%

98%



109%

102%

97%

98%

NEtFOSA

103%



105%

106%

79%

88%

84%

101%

99%

114%

99%

99%

98%

98%

96%



107%

103%

99%

98%

PFTrDA

123%



276%

144%

113%

112%

105%

106%

99%

98%

104%

99%

154%

146%

130%



93%

96%

97%

88%

PFTeDA

121%



270%

134%

128%

114%

101%

97%

97%

93%

96%

97%

144%

138%

126%



93%

93%

96%

87%

HCI-PF30UdS

100%



127%

123%

115%

118%

110%

112%

117%

109%

108%

117%

128%

112%

113%



102%

101%

98%

100%

9CI-PF30NS

97%



95%

106%

93%

98%

101%

109%

112%

104%

109%

112%

87%

96%

99%



104%

106%

93%

95%

L-PFDoS

100%



115%

117%

142%

93%

93%

114%

113%

119%

113%

113%

105%

107%

109%



119%

112%

96%

104%

NaDONA

106%



122%

110%

102%

91%

95%

96%

95%

91%

95%

95%

104%

102%

103%



94%

102%

99%

88%

15

-------


CCV3-230504 File: 21
Injected 5/5 12:31:57
REPORTED

CCV3-230504 File: 21
Injected 5/5 12:45:45
REPORTED

CCV4-230504 File: 21
Injected 5/5 3:3045 fi
REPORTED

CCV4-230504 File: 21
Injected 5/5 3:44:30/
REPORTED

CCV5-230504 File: 21
Injected 5/5 6:29:32/
REPORTED

CCV5-230504 File: 21
Injected 5/5 6:43:16/
REPORTED

CCV6-230504 File: 21
Injected 5/5 7:52:06 fi
REPORTED

CCV6-230504 File: 21
Injected 5/5 8:05:51 fi
REPORTED

CCV6-230504 File: 21
Injected 5/5 9:01:30 fi
REPORTED

CCV7-230504 File: 21
Injected 5/5 11:05:18
REPORTED

CCV7-230504 File: 21
Injected 5/5 11:19:01
REPORTED



CCV8-230504 File: 230504.
Injected 5/5 1:22:43 PM
REPORTED

CCV8-230504 File: 230504.
Injected 5/5 1:36:27 PM
REPORTED



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1-4

No

Compound





























PFBA

101%

104%

97%

98%

107%

102%

103%



101%

92%







109%

PFPeA

98%

98%

99%

99%

97%

97%

97%



98%

96%

96%



94%

94%

PFBS

99%

99%

100%

98%

92%

97%

95%



98%

104%

105%



91%

88%

HFPO_DA

93%

94%

93%

99%

92%

92%

93%



93%

98%

101%



86%

82%

4-2-FtS

104%

102%

103%

102%

104%

105%

104%



104%

97%

101%



113%

108%

PFHxA

96%

97%

94%

97%

98%

97%

99%

Z
O

97%

94%

93%



98%

102%

PFPeS

95%

94%

94%

98%

96%

95%

94%

96%

98%

100%



89%

84%

PFHxS

102%

98%

100%

102%

101%

102%

97%

104%

102%

103%



94%

90%

PFHpA

95%

92%

94%

95%

96%

97%

95%

cz
in
>
CD

94%

94%

94%



95%

97%

PFHpS

93%

91%

96%

98%

96%

96%

96%

103%

99%

100%



97%

90%

6-2-FTS

101%

101%

98%

99%

94%

101%

100%

102%

93%

97%



98%

96%

PFOA

98%

106%

98%

103%

102%

97%

97%

1—

95%

95%

98%



110%

108%

PFOS

102%

103%

99%

103%

103%

106%

102%

m

104%

94%

95%



106%

105%

PFNA

107%

107%

97%

101%

111%

110%

112%

O

106%

94%

91%



119%

130%

PFNS

101%

105%

100%

102%

104%

104%

101%

>
H
>

96%

93%

96%



109%

107%

8-2-FTS

100%

106%

88%

99%

114%

96%

112%

109%

94%

81%



133%

143%

PFDA

97%

99%

100%

101%

95%

97%

97%

100%

99%

102%



90%

88%

NMeFOSAA

102%

104%

101%

101%

100%

102%

102%

O

105%

100%

102%



107%

112%

PFDS

100%

98%

99%

100%

100%

103%

104%

CZ

104%

95%

95%



106%

109%

PFUnDA

104%

107%

95%

97%

111%

108%

113%

1 1 1

H
O

104%

94%

86%



127%

138%

NEtFOSAA

103%

102%

94%

98%

110%

111%

115%

106%

100%

94%



118%

126%

PFOSA

106%

105%

107%

107%

102%

105%

100%

110%

97%

103%



116%

108%

PFDoA

104%

106%

107%

106%

99%

102%

98%

in

106%

101%

104%



94%

85%

NMeFOSE

92%

95%

102%

96%

87%

94%

87%

m

99%

88%

93%



87%

76%

NEtFOSE

107%

111%

112%

111%

109%

111%

111%

33

115%

108%

112%



131%

131%

NMeFOSA

102%

103%

100%

100%

100%

98%

98%

33

99%

95%

94%



108%

104%

NEtFOSA

104%

104%

99%

101%

104%

102%

106%

O

103%

97%

95%



103%

106%

PFTrDA

89%

91%

113%

106%

60%

75%

46%

33

100%

107%

122%



31%

23%

PFTeDA

89%

88%

111%

106%

60%

76%

45%



94%

107%

121%



28%

24%

HCI-PF30UdS

99%

96%

97%

98%

100%

99%

97%



93%

99%

105%



111%

129%

9CI-PF30NS

101%

105%

94%

97%

116%

111%

111%



101%

87%

89%



131%

147%

L-PFDoS

95%

96%

99%

100%

98%

103%

93%



95%

94%

96%



92%

90%

NaDONA

98%

99%

107%

104%

92%

98%

93%



101%

111%

117%



94%

91%

16

-------
3A

3

:£

.8

7

14

3

.6

3

54

:£

3

A

:£

A

A

.]_

A

A

.]_

•I

.6

A

:£

2

.]_

3

38

:£

.S_

A

3

A

3

£

ICF International LLC
EPA Region 5 ESAT

EXTRACTED INTERNAL STANDARD (EIS) PERCENT RECOVERY SUMMARY

SPG/Lab Work Order Number: 23041906

IDS
Abbreviation



IDS Name

13c4-pfba

Perfluoro-n-[l,2,3,4-13C4] butanoic acid

13Cc-PFPeA

Perfluoro-n-[l,2,3,4,5-13C5] pentanoic acid

13c3-pfbs

Sodium perfluoro-l-[2,3;4-13C3] butanesulfonate

13C,-4:2FTS

Sodium lH,lH,2H,2H-perfluoro-l-[l,2-13C2] hexane sulfonate

13C5-PFHxA

Perfluoro-n-[l,2,3,4,6-13C5] hexanoic acid

13c,-hfpo-da

2,3,3,3,-Tetrafluoro-2-(l,l,2,23,3,3-heptafluoropropoxy-13C3)-propanoic acid

13C4-PFHpA

Perfluoro-n-[l,23,4-13C4] heptanoic acid

13C,-PFHxS

Sodium perfluoro-l-[l,23-13C3] hexanesulfonate

13C3-6:2FTS

Sodium lH,lH,2H,2H-perfiuoro-l-[l,2-13C2]-octane sulfonate

13Cs-PFOA

Perfluoro-n[13C8] octanoic acid

13c9-pfna

Perfluoro-n-[13C9] nonanoicacid

13Cs-PFOS

Sodium perfluoro-[13C8] octanesulfonate

13C3-8:2FTS

Sodium lH,lH,2H,2H-perfiuoro-l-[l,2-13C2]-decane sulfonate

13Cc-PFDA

Perfluoro-n-[l,23,4,5,6-13C6] decanoic acid

13C7-PFUnA

Perfluoro-n[l,23,4,5,6,7-13C7] undecanoic acid

13C,-PFDoA

Perfluoro-n-[l,2-13C2] dodecanoic acid

13C2-RS 6:2 13C2-FtS 8:2 113C2-PFDA 13C2-PFDQA 13C2-PFHXA 13C2-PFHXDA 13C2-PFTeA 13C2-PFUnA 13C3-HFPO-DA 13C3-PFBS

T|me_|njected_

11:09:00 AM
11:23:00 AM

11:50:00 AM

10:10:00 AM

10:55:00 AM

10:41:00 AM

12:38:00 PM

10:07:00 AM
12:18:00 AM

' 23041906-09A MS
\ 23041906-09A MSP
23041906-14A MS
23041906-14A MSP
1123041906-21A MS ~
\ 23041906-21A MS
\ 23041906-21A MS

23041906-21A MSP
1123041906-21A MSP ~
\ 23041906-21A MSP
23041906-21A MSP

\ PUP-01-230418	

\ PUP-02-230418	

\ PUP-03-230419	

\ EB-01-230420	

\ FB-01-230420	

\ FB-02-230420	

\ LCS-Wi-214976-214976a
\ LCS-WI-215053-215053a
LCS-Wi-215208-2152 08a
\ LCS-WI-215318-215318a
\ MBLK-214976-214976a
\ MBLK-215053-215053a
M B LK-2152 08-2152 08a
l|MBLK-215318-215318a ~

\ MW-099-230420	

\ MW-10-230420	

MW-10-230420	

i|mW-106-23Q42Q ~
\ MW-106A-230420

MW-107-230419	

MW-107A-230419
i|mW-108-23Q42Q ~
\ MW-108A-230420
\ MW-108A-230420

\ MW-110-230420	

\ MW-110A-230420

\ MW-112-230420	

\ MW-11-230419	

\ MW-113-230419	

\ MW-115-230419	

\ MW-115A-230419

\ MW-116-230419	

I MW-12-230419

13C4-PFBA 13C4-PFHpA 13C4-PFQA

17

-------
\J/

^ICF

ICF International LLC
EPA Region 5 ESAT

25-150 10-150 25-50 10-150 10-150

Date Injected

Time Injected

Sample ID

03-N-MeF



05-N-EtFOSAA

07-N-MeFOSE

09-N-EtFOSE

4/26/2023

9:44:00 AM

23041906-09A MS

92.6

83.7

95.2

109

93.8

4/26/2023

9:58:00 AM

23041906-09A MSD

79.9

74.5

82.5

92.2

77.6

5/4/2023

11:09:00 AM

23041906-14A MS

71

66.8

74.7

72.8

75.5

5/4/2023

11:23:00 AM

23041906-14A MSD

67.5

68

74.2

71.9

81.8

5/4/2023

11:36:00 AM

23041906-21A MS

80.7

73.7

83.4

80.6

87.7

5/5/2023

5:07:00 AM

23041906-21A MS











5/5/2023

9:56:00 AM

23041906-21A MS

80.5

79.8

84.5

70.2

87.7

5/4/2023

11:50:00 AM

23041906-21A MSD

2.53

1.86

3.49

9

0

5/5/2023

4:25:00 AM

23041906-21A MSD











5/5/2023

5:20:00 AM

23041906-21A MSD











5/5/2023

10:10:00 AM

23041906-21A MSD

81.8

92.1

90.7

78.7

97.2

4/30/2023

5:22:00 AM

DUP-01-230418

86.1

79.9

88.6

102

112

4/30/2023

5:35:00 AM

DUP-02-230418

76.3

81.7

84.1

101

106

5/5/2023

2:22:00 AM

DUP-03-230419

68.6

80.1

74.5

89.1

90.7

5/5/2023

1:40:00 AM

EB-01-230420

85.6

78.9

92.6

91.6

94.3

4/30/2023

5:49:00 AM

FB-01-230420

79.2

66.1

88

92.5

95.7

4/30/2023

6:03:00 AM

FB-02-230420

85.3

68.1

93.2

104

104

4/26/2023

8:35:00 AM

LCS-WI-214976-214976a

85.6

66.4

89.1

90.9

77.2

4/26/2023

9:17:00 AM

LCS-WI-215053-215053a

63.2

60.5

68.8

69

60.3

5/4/2023

10:55:00 AM

LCS-WI-215208-215208a

87.6

87.3

98.1

90.2

99.9

5/5/2023

9:42:00 AM

LCS-WI-215318-215318a

88

88.8

94

81.3

102

4/26/2023

8:22:00 AM

MBLK-214976-214976a

89.8

69.7

97.8

98.3

84.4

4/26/2023

9:03:00 AM

MBLK-215053-215053a

65.9

60.2

72.2

68.6

59.7

5/4/2023

10:41:00 AM

MBLK-215208-215208a

77.3

63.1

85.7

77.8

86

5/5/2023

9:29:00 AM

MBLK-215318-215318a

85.8

87.3

94.7

84.7

96

5/5/2023

1:54:00 AM

MW-099-230420

78.5

78.9

82.9

80.7

87.2

4/27/2023

4:37:00 AM

MW-10-230420











4/27/2023

12:38:00 PM

MW-10-230420

84.4

91.2

89.2

74.6

78.7

4/27/2023

9:39:00 AM

MW-106-230420

72.5

74.2

77.3

86.9

72.5

4/27/2023

9:53:00 AM

MW-106A-230420

68.9

68.1

74.8

81.6

65.7

4/27/2023

10:07:00 AM

MW-107-230419

70.7

73.2

74.4

83.1

71.4

5/5/2023

12:18:00 AM

MW-107A-230419

87.4

89.8

89.9

92.9

103

5/5/2023

10:24:00 AM

MW-108-230420

82.3

71.3

87.3

59.4

76.6

4/30/2023

2:37:00 AM

MW-108A-230420











5/5/2023

1:13:00 AM

MW-108A-230420

87.8

91.2

91.4

93.6

104

5/5/2023

1:27:00 AM

MW-110-230420

83.6

83.1

91.1

90.6

91.9

4/30/2023

3:59:00 AM

MW-110A-230420

89.2

87.1

98.2

105

112

4/30/2023

4:13:00 AM

MW-112-230420

77.5

76.5

90

93.5

101

4/27/2023

9:12:00 AM

MW-11-230419

64.7

70.3

68.6

83.9

66.9

4/30/2023

4:27:00 AM

MW-113-230419

92.8

91

103

111

118

4/30/2023

4:40:00 AM

MW-115-230419

84.1

79.6

88.1

101

106

4/30/2023

4:54:00 AM

MW-115A-230419

91.6

84.6

95.7

105

109

4/30/2023

5:08:00 AM

MW-116-230419

82.9

80

92.6

103

110

4/27/2023

9:26:00 AM

MW-12-230419

66.5

70.3

72.6

80.9

63.7

18

-------
3A

.5

1

A

.8

.5

¦1

.2

3

¦1

.2

3

¦1

1

3

ICF International LLC
EPA Region 5 ESAT

EXTRACTED INTERNAL STANDARD (IES) PERCENT RECOVERY SUMMARY

SPG/Lab Work Order Number: 23041906

IDS

Abbreviation



IDS Name

13c„-pfba

Perfluoro-rt-[l,2,3,4-13C4] butartoic acid

"CrPFPeA

Perfluoro-rt-[l,2,3,4,5-13C5] perttartoic acid

13c3-pfbs

Sodium perfluoro-l-[2,3,4-13C3] butanesulfonate

13C,-4:2FTS

Sodium lH,lH,2H,2H-perfluoro-l-[l,2-13C2] hexane sulfonate

13C5-PFHxA

Perfluoro-rt-[l,2,3,4,6-13C5] hexartoic acid

13c,-hfpo-da

2333,-Tetrafluoro-2-(l,l,2,2333-heptafluoropropoxy-13C3)-propanoic acid

13C«-PFHpA

Perfluoro-n-[l,23,4-13C4] heptanoic acid

13C,-PFHxS

Sodium perfluoro-l-[l,23-13C3] hexartesulfortate

13C,-6:2FTS

Sodium lH,lH,2H,2H-perfluoro-l-[l,2-13C2]-octane sulfonate

13c5-pfoa

Perfluoro-n[13C8] octanoic acid

13c9-pfna

Perfluoro-n-[13C9] nonanoicacid

13c,-pfos

Sodium perfluoro-[13C8] octanesulfonate

13C,-8:2FTS

Sodium lH,lH,2H,2H-perfluoro-l-[l,2-13C2]-decane sulfonate

13c,-pfda

Perfluoro-n-[l,23,4,5,6-13C6] decanoic acid

13C7-PFUnA

Perfluoro-n[l,23,4,5,6,7-13C7] undecanoic acid



Perfluoro-n-[l,2-13C2] dodecanoic acid

Injectec^

>am|5le

13C2-FtS 6 2 13c I I:

3C2-PFHXDA 13C2-PFTeA 13C2-PFUnA

MW-2-230418

MW-3R-230418

MW-5-230419

MW-5A-230420

MW-6-230418

MW-6A-230418

10:12:00 PM

MW-7-230419

MW-7A-230419

MW-8-230420

MW-8A-230420

MW-9-230419

SUMP-230418

12:15:00 AM

W-1A-230418

19

-------
\J/

^ICF

ICF International LLC
EPA Region 5 ESAT

25-150 10-150 25-50 10-150 10-150

Date Injected

Time Injected

Sample ID

03-N-MeF



05-N-EtFOSAA

07-N-MeFOSE

09-N-EtFOSE

	4/22/2Q23

	5' SQ'OO AM

MW.-2.-.230.418..	

55.3

57.1

64.8

71.9

55.9

4/27/2023

6:13:00 AM

MW-3R-230418

67.6

65.3

72.7

75.1

64.8

4/27/2023

6:27:00 AM

MW-5-230419

63

60.6

67.2

79.2

61.9

4/27/2023

6:41:00 AM

MW-5A-230420

66.9

69.5

74.8

79.2

69.4

4/27/2023

6:54:00 AM

MW-6-230418

68.9

70.9

72.8

74.6

69.6

4/27/2023

7:08:00 AM

MW-6A-230418

75.7

68

80.3

65.4

70.7

4/26/2023

10:12:00 PM

MW-7-230419

84.2

73.5

89.6

101

87.1

4/27/2023

7:22:00 AM

MW-7A-230419

62.4

64.7

68.1

68.5

59.6

4/27/2023

7:36:00 AM

MW-8-230420

59.2

64.9

63.6

63.6

57.7

4/27/2023

7:49:00 AM

MW-8A-230420

65.9

72.3

69.5

76.4

70.6

4/27/2023

8:58:00 AM

MW-9-230419

67.9

69

74.5

87.3

65.9

5/5/2023

2:08:00 AM

SUMP-230418

70.7

73.3

74.9

86.2

81

4/27/2023

12:02:00 AM

W-l-230418

78.9

90.5

88.5

104

85.8

4/27/2023

12:15:00 AM

W-1A-230418

84.4

81.4

88.3

99.8

85.2

20

-------
_

'^iCF

EXTRACTED INTERNAL STANDARD (EIS) RESPONSE SUMMARY

ICAL Date:	4/25/2023

Instr. ID: LCMS1
Levels Calibrated:	7

ICF International LLC
EPA Region 5 ESAT

^Limits^^O^l^O^onCAl^Averag^

ICAL Ssoto

ie Performance Standard Responses

Lab Sample ID

Run ID

13C-PFBAJS



13C-PFPR4JS

Y/N?

13C-PFBSJ5

Y/N?

lSC.HFPO.DA



13C-4_2-
fTSJS



13C-FFH.--AJ5

Y/N?

lac-PFHpAJS



180-PFHKSJS



FTSJ5

Y/N?

13C-PFOAJS

Y/N?

HWFOSJS

Y/N?

ISC-PFNAJS



13C-8_3-
FT5J5

Passes
Y/N?

13C-PFDAJS

Passes
Y/N?

MeFOSMJS

Passes
Y/N?

L0.05DDb

230425003

873835

Y

14905



:4121

Y

326555

Y

247691

Y

2134032

Y

2116438

Y

598715

Y

429703

Y

2857096

Y

560552

Y

2976390

Y

309765

Y

3292458

Y

738044

Y

LO.lDDb

230425004

855112

Y

1414505

Y

540081

Y

299435

Y

244199

Y

2005035

Y

2036803

Y

537253

Y

445982

Y

2685970

Y

540130

Y

2849356

Y

305616

Y

3192644

Y

695456

Y

L0.5DDb

230425005

870846

Y

1496036

Y

574637

Y

311947

Y

262078

Y

2177077

Y

2232540

Y

590959

Y

499130

Y

2930182

Y

571729

Y

3030613

Y

350630

Y

3424270

Y

761926

Y



230425006

907511

Y

1492041

Y

576062

Y

307063

Y

263995

Y

2166414

Y

2218794

Y

595454

Y

501912

Y

2912692

Y

562748

Y

3069795

Y

373787

Y

3407788

Y

764811

Y



230425007

1004280

Y

1646270

Y

623801

Y

337955

Y

303078

Y

2344329

Y

2327056

Y

633315

Y

519280

Y

3048255

Y

647656

Y

3118434

Y

352957

Y

3594069

Y

825346

Y

LLOppb

230425008

859856

Y

1374262

Y

513071

Y

276111

Y

263141

Y

1974882

Y

1921482

Y

533859

Y

429657

Y

2452292

Y

538464

Y

2619849

Y

290132

Y

3057412

Y

704974

Y



230425009

890036

Y

1405191

Y

531419

Y

290728

Y

284230

Y

2020662

Y

1891182

Y

559166

Y

418495

Y

2446635

Y

550035

Y

2622832

Y

298605

Y

3019294

Y

721803

Y

































































































































Average of ICAL Standards
Low Limit of Response
High Limit of Response

894497



147411!>



56 SSI i



307113



266916



2117-1')()



2106328



578389



4634 SI



r 27611S/'>



567331



2898181



325'!.'/



3283991



744623



447248



737058



281!.'./



153557



133458



1058/V.



1053164



289194



2317A>



1381)') !/



283665



1449091



162')!.-1



1641995



372311



1341745



2211173



844970



460670



400374



3176235



3159492



867583



695177



4142812



850996



4347272



488891



4925986



1116934





LLCCV1-230426

230426003

857220

Y

1396796

Y

518289

Y

257107

Y

205915

Y

1920323

Y

1937229

Y

542970

Y

383164

Y

2709658

Y

533180

Y

2824112

Y

255030

Y

3213137

Y

712300

Y

MBLK-214976

230426008

856701

Y

1535199

Y

544844

Y

277709

Y

235269

Y

1893334

Y

2031888

Y

524330

Y

434479

Y

2689553

Y

511778

Y

2797256

Y

286838

Y

3012390

Y

616398

Y

MBLK- 215053

230426011

812633

Y

1296866

Y

467494

Y

230603

Y

197431

Y

1792315

Y

1716095

Y

516123

Y

361309

Y

2594698

Y

511183

Y

2719308

Y

255551

Y

2868014

Y

476349

Y

23041906-09A MS

230426014

839025

Y

1489221

Y

552977

Y

258451

Y

270608

Y

1854951

Y

1931261

Y

548553

Y

427993

Y

2583985

Y

539150

Y

2693238

Y

276104

Y

2851743

Y

595743

Y

23041906-09AMSD

230426015

834675

Y

1462943

Y

552086

Y

268935

Y

255741

Y

1863471

Y

1880620

Y

555476

Y

440970

Y

2555063

Y

536452

Y

2690117

Y

270699

Y

2882734

Y

557295

Y

23041906-09A

230426016

774413

Y

1565234

Y

568338

Y

284360

Y

275312

Y

1667221

Y

2064688

Y

498224

Y

449632

Y

2362872

Y

484271

Y

2509893

Y

285477

Y

2526335

Y

575311

Y

CCV2-230426

230426019

915826

Y

1426899

Y

568104

Y

279950

Y

224300

Y

1979773

Y

1940824

Y

586456

Y

389724

Y

2734601

Y

545828

Y

2917718

Y

264873

Y

3259388

Y

748115

Y

23041906-01A

230426024

739697

Y

1563433

Y

589060

Y

291569

Y

327509

Y

1628348

Y

1995786

Y

486448

Y

473085

Y

2312928

Y

443649

Y

2366184

Y

258709

Y

2286757

Y

518559

Y

23041906-02A

230426025

598873

Y

1504042

Y

542712

Y

266852

Y

285173

Y

1343404

Y

1934156

Y

402660

Y

437605

Y

1902697

Y

377602

Y

1996132

Y

263907

Y

2000462

Y

555294

Y

CCV3-230426

230426033

878239

Y

1398437

Y

564653

Y

296495

Y

220336

Y

1852535

Y

1839755

Y

574338

Y

353403

Y

2699564

Y

523836

Y

2852145

Y

267386

Y

3006829

Y

740356

Y

23041906-14A

230426044

651633

Y

1038247

Y

398521

Y

200749

Y

623/U0

N

1452919

Y

1441108

Y

446241

Y

473670

Y

2012059

Y

438242

Y

2310847

Y

200794

Y

2104760

Y

402361

Y

CCV4-230426

230426047

866145

Y

1389595

Y

544615

Y

281679

Y

220232

Y

1862631

Y

1877950

Y

573205

Y

341236

Y

2568583

Y

527885

Y

2797477

Y

240790

Y

2995528

Y

739912

Y

23041906-03A

230426050

617810

Y

1207937

Y

495039

Y

254718

Y

686897

N

1558343

Y

1629919

Y

455728

Y

635867

Y

2187227

Y

413807

Y

2404333

Y

232810

Y

2140470

Y

432941

Y

23041906-04A

230426051

707099

Y

1323558

Y

501307

Y

257822

Y

215643

Y

1561028

Y

1647922

Y

495516

Y

331320

Y

2376287

Y

444011

Y

2422644

Y

213100

Y

2384654

Y

535115

Y

23041906-05A

230426052

686679

Y

1320898

Y

495049

Y

263532

Y

256449

Y

1537124

Y

1689652

Y

462376

Y

365696

Y

2177653

Y

420511

Y

2244700

Y

214510

Y

2229448

Y

485817

Y

23041906-06A

230426053

678417

Y

1307997

Y

499291

Y

265776

Y

198184

Y

1506773

Y

1690013

Y

482171

Y

330536

Y

2167730

Y

430902

Y

2227732

Y

228490

Y

2362014

Y

519379

Y

23041906- 07A

230426054

664589

Y

1295537

Y

471929

Y

247040

Y

259573

Y

1510369

Y

1682014

Y

456033

Y

371345

Y

2034800

Y

413466

Y

2176976

Y

206391

Y

2207744

Y

493655

Y

23041906-08A

230426055

682727

Y

1194707

Y

442619

Y

235304

Y

181552

Y

1571463

Y

1577579

Y

472440

Y

302514

Y

2277266

Y

447929

Y

2268851

Y

207848

Y

2430158

Y

499847

Y

23041906-10A

230426056

674330

Y

1144145

Y

430168

Y

222537

Y

166860

Y

1456550

Y

1522043

Y

459422

Y

284866

Y

2105056

Y

421358

Y

2155602

Y

192425

Y

2222333

Y

439944

Y

23041906-11A

230426057

670614

Y

1210445

Y

456301

Y

238175

Y

259894

Y

1480245

Y

1577018

Y

443981

Y

348530

Y

2009152

Y

411214

Y

2121101

Y

190508

Y

2039389

Y

423646

Y

23041906-12A

230426058

580600

Y

1199410

Y

460516

Y

232072

Y

170282

Y

1264214

Y

1579487

Y

400552

Y

318286

Y

1852267

Y

387164

Y

1892111

Y

205147

Y

1950328

Y

442018

Y

CCV5-230426

230426060

813673

Y

1309626

Y

521824

Y

275074

Y

199173

Y

1758104

Y

1764006

Y

529566

Y

314450

Y

2389402

Y

500265

Y

2543600

Y

214990

Y

2896765

Y

675208

Y

23041906-13A

230426063

732928

Y

1330086

Y

475503

Y

245882

Y

232378

Y

1683055

Y

1748469

Y

491266

Y

349521

Y

2347563

Y

468961

Y

2364476

Y

214436

Y

2515054

Y

498083

Y

23041906-15A

230426064

772365

Y

1271538

Y

471235

Y

240811

Y

235013

Y

1763566

Y

1663883

Y

499253

Y

333534

Y

2406216

Y

467309

Y

2498071

Y

199423

Y

2470945

Y

456924

Y

23041906-16A

230426065

788795

Y

1343623

Y

489461

Y

251829

Y

231738

Y

1801668

Y

1710957

Y

505161

Y

382620

Y

2423121

Y

479588

Y

2433904

Y

217312

Y

2506400

Y

479471

Y

23041906-17A

230426066

766581

Y

1241590

Y

450605

Y

233229

Y

192275

Y

1711006

Y

1578884

Y

504326

Y

335308

Y

2376305

Y

489359

Y

2419054

Y

201674

Y

2587493

Y

489802

Y

23041906-18A

230426067

791711

Y

1280364

Y

459297

Y

239127



1')'X>11

Y

1806741

Y

1618774

Y

526857

Y

334663

Y

2559515

Y

530795

Y

2576082

Y

203004

Y

2869545

Y

495192

Y

23041906-19A

230426068

757757

Y

1284747

Y

452100

Y

241366



;>!>')(>/0

Y

1751531

Y

1676713

Y

480867

Y

350984

Y

2430387

Y

477935

Y

2316171

Y

201190

Y

2447519

Y

465740

Y

CCV6-230426

230426072

886068

Y

1442797

Y

585738

Y

297618



^11(>/8

Y

1946486

Y

1900410

Y

595236

Y

344636

Y

2537734

Y

532346

Y

2637427

Y

233597

Y

3156903

Y

759770

Y

23041906-14A

230426079

644669

Y

1035371

Y

393676

Y

193429



7

N

1456870

Y

1484741

Y

422072

Y

467425

Y

2082274

Y

455360

Y

2161104

Y

188369

Y

2039698

Y

416268

Y

CCV7-230426

230426082

872447

Y

1377313

Y

517896

Y

278731



207644

Y

1869401

Y

1883168

Y

548381

Y

311223

Y

2462726

Y

536527

Y

2579914

Y

206623

Y

2984094

Y

691466

Y

































































21

-------
'ICF

ICF International LLC
EPA Region 5 ESAT

EXTRACTED

ICALDate: 4/25/2023
Instr. ID: LCMS1

Levels Calibrated:

Limits = 50-150% c









Passes



Passes



Passes



Passes



Passes



Passes



Passes



Passes



Passes



Passes



Passes

Lab Sample ID

Run ID

13 G-
PFUnDAJS

Y/N?

d5-N-

EtFOSAAJS

Y/N?

13CfOSAJS

Y/N?

13C-PFDOAJS

Y/N?

d5-NEtFOSAJS

Y/N?

dMtFOSEJS

Y/N?

NMtFOSAJS

Y/N?

MtfOSEJS

Y/N?

13C-PFTeDA_IS

Y/N?

13 C2-
PFHsDAJS

Y/N?

1SC7-
PFUnDAJS

Y/N?

L0.05ppb

230425003

3287520

Y

858735

Y

709980

Y

3257578

Y

625255

Y

249662

Y

591980

Y

369017

Y

2133576

Y

4053646

Y

3261105

Y

LO.lppb

230425004

3067585

Y

832568

Y

658015

Y

3028891

Y

620623

Y

242339

Y

559244

Y

334445

Y

1842775

Y

3871878

Y

2894088

Y

L0.5ppb

230425005

3347994

Y

871229

Y

689761

Y

3170944

Y

615936

Y

245267

Y

562101

Y

354309

Y

1894163

Y

4173049

Y

2874860

Y

Llppb

230425006

3332045

Y

878975

Y

687316

Y

3256005

Y

625273

Y

258027

Y

585970

Y

351741

Y

1977345

Y

4241679

Y

3102524

Y

L5ppb

230425007

3582653

Y

892304

Y

763734

Y

3460443

Y

707726

Y

276575

Y

648208

Y

366793

Y

1900407

Y

4629380

Y

3172124

Y

LLOppb

230425008

3006176

Y

763395

Y

623456

Y

2789031

Y

592692

Y

231799

Y

540200

Y

270298

Y

1307156

Y

3908993

Y

2451148

Y

LL5ppb

230425009

2938972

Y

766157

Y

647247

Y

2845322

Y

599597

Y

237915

Y

561194

Y

298237

Y

1444087

Y

4155400

Y

2394787

Y

































































































Average of ICAL Standards
Low Limit of Response
High Limit of Response

3223278



837623



682787



3115459



626729



248798



578414



334977



1785644



4147718



2878662



1611639



418812



341394



1557730



313364



124399



289207



167489



892822



2073859



1439331



4834917



1256435



1024181



4673189



940093



373197



867621



502466



2678466



6221577



4317993







LLCCV1-230426

230426003

3045742

Y

771274

Y

660026

Y

2846044

Y

547433

Y

216545

Y

527023

Y

347519

Y

1546666

Y

3781534

Y

2654357

Y

MBLK-214976

230426008

2801311

Y

753566

Y

599344

Y

2532514

Y

402472

Y

193380

Y

392881

Y

301306

Y

1644850

Y

3769929

Y

2630167

Y

MBLK-215053

230426011

2580800

Y

586178

Y

466130

Y

2418566

Y

366534

Y

144034

Y

363299

Y

221459

Y

1449719

Y

3137982

Y

2770533

Y

23041906-09A MS

230426014

2841367

Y

687106

Y

599403

Y

2609938

Y

453008

Y

201446

Y

440749

Y

312487

Y

1751680

Y

3778244

Y

2463737

Y

23041906-09A MSD

230426015

2694489

Y

645130

Y

561127

Y

2509775

Y

436890

Y

180511

Y

414305

Y

287051

Y

1653134

Y

3618697

Y

2670566

Y

23041906-09A

230426016

2454156

Y

686889

Y

626399

Y

2301993

Y

422584

Y

198642

Y

414877

Y

307100

Y

1834292

Y

3878943

Y

2618250

Y

CCV2-230426

230426019

3092779

Y

817485

Y

692103

Y

3037869

Y

552414

Y

223057

Y

522825

Y

353612

Y

1859297

Y

4077944

Y

3071986

Y

23041906-01A

230426024

2226137

Y

651860

Y

589877

Y

2127627

Y

500210

Y

188019

Y

482945

Y

303527

Y

1797793

Y

3790032

Y

2516088

Y

23041906-02A

230426025

1949655

Y

652102

Y

580800

Y

1827848

Y

450526

Y

187200

Y

445904

Y

293148

Y

1591824

Y

3522107

Y

2521331

Y

CCV3-230426

230426033

3107345

Y

840525

Y

668403

Y

3017404

Y

562530

Y

221746

Y

536049

Y

364778

Y

1944991

Y

3949550

Y

3126341

Y

23041906-14A

230426044

2206038

Y

470917

Y

417686

Y

1918080

Y

359115

Y

134671

Y

333889

Y

152162

N

539723

N

2621514

Y

2113515

Y

CCV4-230426

230426047

2966193

Y

803307

Y

675755

Y

2962630

Y

566965

Y

212824

Y

533151

Y

339837

Y

1665244

Y

4187854

Y

2809945

Y

23041906-03A

230426050

2039913

Y

569112

Y

450422

Y

1954796

Y

376103

Y

146008

Y

355151

Y

251405

Y

1613804

Y

3316977

Y

2998795

Y

23041906-04A

230426051

2380716

Y

645804

Y

537508

Y

2233163

Y

434732

Y

171095

Y

399774

Y

265473

Y

1659165

Y

3415690

Y

3031900

Y

23041906-05A

230426052

2221757

Y

581047

Y

506846

Y

2074646

Y

393118

Y

159403

Y

361568

Y

272732

Y

1494919

Y

3341505

Y

2953902

Y

23041906-06A

230426053

2304554

Y

651285

Y

561735

Y

2116176

Y

453671

Y

179777

Y

420528

Y

274482

Y

1618936

Y

3627749

Y

2973728

Y

23041906-07A

230426054

2179194

Y

584889

Y

489734

Y

2012714

Y

427394

Y

166506

Y

403004

Y

238584

Y

1412619

Y

3123032

Y

2744840

Y

23041906-08A

230426055

2424722

Y

594557

Y

463922

Y

2248328

Y

377794

Y

155715

Y

366803

Y

192870

Y

1094228

Y

3285706

Y

2529000

Y

23041906-10A

230426056

2143426

Y

538376

Y

464832

Y

2017177

Y

383661

Y

140255

Y

360651

Y

215456

Y

1164160

Y

3056021

Y

2699951

Y

23041906-11A

230426057

2060781

Y

509862

Y

427004

Y

1923297

Y

390442

Y

137807

Y

369092

Y

203121

Y

1196132

Y

3123650

Y

2739258

Y

23041906-12A

230426058

1911638

Y

523378

Y

478495

Y

1728562

Y

408002

Y

158035

Y

386495

Y

228738

Y

1226022

Y

3231744

Y

2569638

Y

CCV5-230426

230426060

2822759

Y

733840

Y

622824

Y

2772907

Y

534368

Y

203639

Y

506263

Y

333303

Y

1644924

Y

3823082

Y

2687153

Y

23041906-13A

230426063

2483014

Y

613168

Y

511028

Y

2233478

Y

426162

Y

161402

Y

403712

Y

285975

Y

1436726

Y

3339679

Y

2810553

Y

23041906-15A

230426064

2406896

Y

543650

Y

482937

Y

2289021

Y

417751

Y

157601

Y

387231

Y

264651

Y

1424059

Y

3109784

Y

2705607

Y

23041906-16A

230426065

2483106

Y

587334

Y

487242

Y

2290407

Y

426345

Y

153297

Y

405752

Y

260431

Y

1434888

Y

2987389

Y

2760670

Y

23041906-17A

230426066

2640239

Y

585667

Y

498883

Y

2390171

Y

421674

Y

163431

Y

401337

Y

262142

Y

1333796

Y

2775538

Y

2587662

Y

23041906-18A

230426067

2807455

Y

603464

Y

504414

Y

2596805

Y

411936

Y

157748

Y

387230

Y

262056

Y

1423112

Y

3089596

Y

2754190

Y

23041906-19A

230426068

2366772

Y

549575

Y

459205

Y

2228317

Y

405429

Y

156893

Y

377062

Y

244454

Y

1271876

Y

2789071

Y

2522718

Y

CCV6-230426

230426072

2953617

Y

829023

Y

675761

Y

2931043

Y

564202

Y

221814

Y

516692

Y

347487

Y

1909986

Y

4183910

Y

2980574

Y

23041906-14A

230426079

2109912

Y

493559

Y

405880

Y

1816774

Y

378309

Y

129581

Y

335024

Y

164319

N

477262

N

2566045

Y

1889260

Y

CCV7-230426

230426082

2952145

Y

778226

Y

627307

Y

2844881

Y

546174

Y

204219

Y

495768

Y

278863

Y

1237054

Y

4005656

Y

2411680

Y

















































22

-------
ICF International LLC
EPA Region 5 ESAT

^ICF

EXTRACTED INTERNAL STANDARD (EIS) RESPONSE SUMMARY

ICAL Date:	4/28/2023

Instr. ID: LCMS1
Levels Calibrated:	7



ICAL Isotope Performance Standard Responses

Lab Sample ID

Run ID

1SC-PFMJS

Y/N?

ISC-PFPeAJS

		

Y/N?

ISC-PFS^JS

		

Y/N?

1SCJ1FPOJ3A
JS

		

Y/N?

FTSJS

Y/N?

lS&PFHxAJS

Y/N?

lS&PFhpAJS

		

Y/N?

ISQ-PFMUUS

Y/N?

FTSJS

Y/N?

1SOPFOAJS

		

Y/N?

1SC-PFGSJS

Y/N?

1SOPFNAJS

Y/N?

FTSJS

		

Y/N?

1SC-PF0AJS

Y/N?

L0.05oob

230428021

798475

Y

1264308

Y

509409

Y

278368



227505



1757122



1762084



526615



255677



2097845



519473

Y

1890187



113475



2114113

Y

LO.loob

230428022

722548

Y

1175014

Y

477452

Y

262984



203402



1598692



1565470



478082



233427



1969740



493155

Y

1689182



99798



1910609

Y

L0.5oob

230428023

820783

Y

1305186

Y

536274

Y

296120



231512



1807780



1808784



556470



251320



2236386



561512

Y

1919119



120751



2167096

Y

Lloob

230428024

807428

Y

1327996

Y

542576

Y

283573



230481



1823790



1769802



555302



253038



2239184



572448

Y

1965925



116282



2195199

Y

L5oob

230428025

895354

Y

1437262

Y

586600

Y

303669



265939



1941600



1832133



595582



278552



2391167



598713

Y

2098677



135456



2397630

Y

LlOoob

230428026

772556

Y

1245937

Y

509890

Y

269883



240153



1647996



1582218



519709



238141



1953641



523629

Y

1807259



126917



2055834

Y

U5oob

230428027

808849

Y

1283861

Y

527496

Y

265909



258807



1702949



1597751



531108



253630



1946887



548641

Y

1814145



126886



2087812

Y







N



N



N



N



N



N



N



N



N



N



N



N



N



N







N



N



N



N



N



N



N



N



N



N



N



N



N



N

A verage of ICAL Standards

803713



1291366



527100



280072



236828



1754276



1702606



537553



251969



2119264



545367



1883499



119938



2132613



Low Limit of Response
Hiah Limit of Response

401857



645683



263550



140036



118414



877138



851303



268776



125985



1059632



272684



941750



59969



1066307



1205570



1337043



730643



420108



355243



2631413



2553303



806323



377354



3178836



818051



2825243



173307



3138320





LBLK

230428028

815102

Y

1327652

Y

566403

Y

293117

Y

233183

Y

1850971

Y

1815224

Y

561270

Y

238640

Y

2213201

Y

572127

Y

1952040

Y

110884

Y

2214952

Y

LLCCV1-230428-WI

230428214

787971

Y

1192552

Y

451267

Y

278877

Y

195163

Y

1618423

Y

1559387

Y

473928

Y

198966

Y

1925586

Y

433853

Y

1813979

Y

98543

Y

1930196

Y

23041906-22A

230428225

580212

Y

1080964

Y

389739

Y

246251

Y

226316

Y

1263356

Y

1320283

Y

364290

Y

229275

Y

1550807

Y

353246

Y

1464352

Y

93495

Y

1434859

Y

CCJ2- 230428

230428229

808372

Y

1219552

Y

486058

Y

292890

Y

208517

Y

1616759

Y

1564444

Y

490143

Y

195320

Y

1919696

Y

436764

Y

1798188

Y

101114

Y

1998144

Y

23041906-24A

230428231

659376

Y

1054218

Y

383116

Y

252299

Y

173180

Y

1313731

Y

1287077

Y

389991

Y

176399

Y

1669938

Y

377544

Y

1572350

Y

80548

Y

1697308

Y

23041906-25A

230428232

676150

Y

989849

Y

353385

Y

223325

Y

179624

Y

1394938

Y

1235853

Y

410266

Y

177225

Y

1701119

Y

373590

Y

1608577

Y

79035

Y

1633130

Y

23041906- 26A

230428233

672616

Y

1056566

Y

374293

Y

241633

Y

197382

Y

1405909

Y

1245020

Y

414493

Y

176798

Y

1732480

Y

374870

Y

1613820

Y

75002

Y

1624395

Y

23041906-27A

230428234

672515

Y

987296

Y

360812

Y

228520

Y

163897

Y

1349548

Y

1217059

Y

417421

Y

154379

Y

1662704

Y

378254

Y

1590161

Y

75665

Y

1573858

Y

23041906-28A

230428235

676047

Y

1015621

Y

368221

Y

239910

Y

177416

Y

1406142

Y

1263630

Y

428662

Y

178801

Y

1818974

Y

401146

Y

1641314

Y

78309

Y

1734101

Y

23041906- 29A

230428236

680933

Y

1112782

Y

412620

Y

248870

Y

199622

Y

1419468

Y

1303542

Y

430507

Y

191304

Y

1687749

Y

386079

Y

1660196

Y

85587

Y

1675155

Y

23041906-30A

230428237

650632

Y

1117919

Y

412699

Y

254640

Y

221008

Y

1374832

Y

1352244

Y

399938

Y

212289

Y

1672473

Y

381100

Y

1566825

Y

87818

Y

1659916

Y

23041906-31A

230428238

611240

Y

1084849

Y

400666

Y

254543

Y

217841

Y

1318903

Y

1305492

Y

389435

Y

210054

Y

1638818

Y

360039

Y

1535945

Y

87094

Y

1561448

Y

23041906-32A

230428239

621386

Y

1068152

Y

406786

Y

252051

Y

163109

Y

1297587

Y

1301064

Y

403930

Y

159698

Y

1567407

Y

360112

Y

1492090

Y

76887

Y

1510501

Y

23041906-33A

230428240

614179

Y

1016029

Y

388808

Y

232919

Y

155562

Y

1301344

Y

1244341

Y

402348

Y

161954

Y

1603553

Y

367012

Y

1502908

Y

73593

Y

1538958

Y

CCV3-230428

230428243

780522

Y

1183980

Y

469941

Y

290665

Y

205254

Y

1582296

Y

1499825

Y

482301

Y

189504

Y

1836741

Y

436195

Y

1800235

Y

95649

Y

1958627

Y

CCV4-230428

230428255

821114

Y

1191614

Y

432281

Y

288165

Y

207792

Y

1557202

Y

1515347

Y

442799

Y

186964

Y

1884380

Y

440653

Y

1695875

Y

88720

Y

1823162

Y





























































23

-------
ICF International LLC
EPA Region 5 ESAT

'ICF

EXTRACTED

4/28/2023
LCMS1

Limits - 50-150% <



Lab Sample ID

Run ID

dS-»-
MeFOSMJS

Y/N?

PFUn&AJB

		

Y/N?

dS-N-

EtFOSAAJS

		

Y/N?

ISC-FOSfcJS

		

Y/N?

ISG-PFOoAJS

Y/N?

NEtFOSfcJS

Y/N?

dS-EtFOSEJS

		

Y/N?

NMeFOS&JS

Y/N?

i!7-N-
MefQSEJS

Y/N?

PFTe&AJB

		

Y/N?

PFhxDAJS

Y/N?

lSC7-PFUnDAJ

Y/N?

L0.05oob

230428021

626505



1861969



663882



497439



1749619

Y

500434

Y

135530

Y

449380



253886



1061890

Y

3695661

Y

1425501

Y

LO.loob

230428022

554947



1690702



600197



483313



1591014

Y

514790

Y

141921

Y

456365



260887



1062419

Y

3407229

Y

1355910

Y

L0.5oob

230428023

641285



1926843



690851



507214



1862715

Y

515301

Y

145692

Y

451921



270014



1255944

Y

3956164

Y

1520071

Y

Lloob

230428024

616819



1951463



698492



511015



1894063

Y

506236

Y

148839

Y

461066



267286



1238521

Y

3926808

Y

1601557

Y

L5oob

230428025

669757



2111010



717840



552191



2083444

Y

551914

Y

163766

Y

523238



272378



1369133

Y

4195519

Y

1721205

Y

LlOoob

230428026

608157



1779906



634420



466616



1813294

Y

487367

Y

137270

Y

435193



232514



1237396

Y

3704953

Y

1479636

Y

U5oob

230428027

629914



1816805



631757



469184



1904673

Y

492041

Y

148120

Y

453479



251053



1261518

Y

3965949

Y

1516095

Y







N



N



N



N



N



N



N



N



N



N



N



N







N



N



N



N



N



N



N



N



N



N



N



N

A verage of ICAL Standards

621055



1876957



662491



498139



1842689



509726



145877



461520



258288



1212403



3836040



1517139



Low Limit of Response
Hiah Limit of Response

310527



938478



331246



249069



921344



254863



72938



230760



129144



606202



1918020



758570



S31582



2815435



S33737



747208



2764033



764583



218815



632280



387432



1818605



5754061



2275703







LBLK

230428028

625830

Y

2008552

Y

692846

Y

512925

Y

1953609

Y

506248

Y

149067

Y

457125

Y

263308

Y

1375028

Y

4018376

Y

1633473

Y

LLCCV1-230428-WI

230428214

663076

Y

1777312

Y

735321

Y

475293

Y

1814015

Y

494187

Y

188487

Y

455356

Y

294676

Y

771612

Y

3374444

Y

1360645

Y

23041906-22A

230428225

442655

Y

1320974

Y

542145

Y

349666

Y

1333674

Y

360311

Y

129795

Y

365793

Y

220439

Y

761380

Y

2457438

Y

1271390

Y

CCJ2- 230428

230428229

672031

Y

1806355

Y

734313

Y

473045

Y

1910775

Y

515580

Y

191588

Y

493713

Y

311513

Y

1050794

Y

3438309

Y

1556160

Y

23041906-24A

230428231

482383

Y

1498968

Y

566561

Y

367789

Y

1557984

Y

387313

Y

142078

Y

373157

Y

235790

Y

781081

Y

2672070

Y

1318718

Y

23041906-25A

230428232

418244

Y

1480288

Y

517695

Y

328451

Y

1580859

Y

339106

Y

127916

Y

327102

Y

210067

Y

761971

Y

2384887

Y

1314910

Y

23041906- 26A

230428233

458103

Y

1568184

Y

542879

Y

344539

Y

1589158

Y

369215

Y

136693

Y

350096

Y

228641

Y

724902

Y

2310158

Y

1203517

Y

23041906-27A

230428234

451713

Y

1456063

Y

504937

Y

343339

Y

1501329

Y

351729

Y

133091

Y

351022

Y

225633

Y

759094

Y

2347073

Y

1309770

Y

23041906-28A

230428235

485752

Y

1580335

Y

540960

Y

349730

Y

1681981

Y

368635

Y

136169

Y

360088

Y

232588

Y

821399

Y

2482759

Y

1292396

Y

23041906- 29A

230428236

460598

Y

1578765

Y

548545

Y

361531

Y

1624720

Y

365176

Y

143533

Y

354855

Y

238219

Y

843190

Y

2518909

Y

1354520

Y

23041906-30A

230428237

479201

Y

1503436

Y

525726

Y

381982

Y

1517135

Y

365363

Y

145932

Y

366483

Y

236163

Y

833071

Y

2493354

Y

1356604

Y

23041906-31A

230428238

424091

Y

1383773

Y

498332

Y

362874

Y

1440202

Y

373461

Y

138509

Y

375803

Y

233539

Y

821587

Y

2617399

Y

1355385

Y

23041906-32A

230428239

452276

Y

1377066

Y

535386

Y

347448

Y

1418486

Y

310324

Y

128295

Y

300472

Y

219843

Y

845378

Y

2574341

Y

1391588

Y

23041906-33A

230428240

449065

Y

1389286

Y

522844

Y

335919

Y

1486628

Y

294772

Y

128644

Y

282622

Y

227278

Y

821366

Y

2413745

Y

1282991

Y

CCV3-230428

230428243

660487

Y

1778454

Y

716542

Y

462205

Y

1899486

Y

500796

Y

198162

Y

469909

Y

302362

Y

1075845

Y

3466286

Y

1534423

Y

CCV4-230428

230428255

658886

Y

1713315

Y

730291

Y

424103

Y

1741320

Y

499371

Y

192638

Y

453743

Y

263182

Y

654926

Y

3174367

Y

1212845

Y





















































24

Ud m

Instr. ID
Levels Calibrated

-------
ICF International LLC
EPA Region 5 ESAT

^ICF

EXTRACTED INTERNAL STANDARD (EIS) RESPONSE SUMMARY

ICALDate
Instr. ID
Levels Calibrated



ICAL Isotope Performance Standard Responses

Lab Sample ID

Run ID

1SC-PFMJS

Y/N?

ISC-PFPeAJS

		

Y/N?

ISC-PFS^JS

		

Y/N?

1SCJ1FPOJ3A
JS

		

Y/N?

FTSJS

Y/N?

lS&PFHxAJS

Y/N?

lS&PFhpAJS

		

Y/N?

ISQ-PFMUUS

Y/N?

FTSJS

Y/N?

1SOPFOAJS

		

Y/N?

1SC-PFGSJS

Y/N?

1SOPFNAJS

Y/N?

FTSJS

		

Y/N?

1SC-PF0AJS

Y/N?

L0.05oob

230504058

1328594

Y

2295486

Y

863136

Y

623324

Y

331320

Y

3209898

Y

3208737

Y

897226

Y

362183

Y

3664529

Y

807677

Y

3556795

Y

147262

Y

3584597

Y

LO.loob

230504059

1339140

Y

2278427

Y

853401

Y

621930

Y

325676

Y

3141098

Y

3194949

Y

875034

Y

356166

Y

3737667

Y

823763

Y

3483595

Y

143427

Y

3542692

Y

L0.5oob

230504060

1333372

Y

2305878

Y

857244

Y

620690

Y

330992

Y

3165390

Y

3125647

Y

879736

Y

365626

Y

3603843

Y

813314

Y

3440245

Y

142871

Y

3530860

Y

Lloob

230504061

1329208

Y

2322826

Y

845165

Y

632398

Y

328264

Y

3138695

Y

3180874

Y

896209

Y

362629

Y

3668303

Y

818125

Y

3422046

Y

152158

Y

3530747

Y

L2.5oob

230504062

1225400

Y

2332447

Y

857313

Y

629265

Y

325920

Y

3140558

Y

3237814

Y

878220

Y

370764

Y

3426294

Y

783380

Y

3057156

Y

134109

Y

3338807

Y

L5oob

230504063

1312004

Y

2308241

Y

860060

Y

614678

Y

341127

Y

3135328

Y

3162710

Y

879881

Y

356443

Y

3222366

Y

793731

Y

3035632

Y

140042

Y

3463908

Y

LlOoob

230504064

1251350

Y

2293042

Y

835265

Y

608540

Y

349791

Y

2975593

Y

2991369

Y

844980

Y

344866

Y

3190170

Y

770314

Y

2873506

Y

142367

Y

3158603

Y

U5oob

230504065

1240975

Y

2171926

Y

819499

Y

593841

Y

372985

Y

2890170

Y

2793002

Y

802738

Y

353521

Y

3060926

Y

754437

Y

3004515

Y

152982

Y

3249169

Y







N



N



N



N



N



N



N



N



N



N



N



N



N



N

A verage of ICAL Standards

12S5005



2288534



848885



618083



338259



3099591



3111888



869253



359025



3446762



795593



3234186



144402



3424923



Low Limit of Response
Hiah Limit of Response

647503



1144267



424443



309042



169130



1549796



1555944



434627



179512



1723381



397796



1617093



72201



1712461



1S42508



3432801



1273328



S27125



507383



464S387



4667832



1303880



538537



5170143



11S338S



4851273



216603



5137384





LBLK

230504066

1285743

Y

2284494

Y

848975

Y

613901

Y

324332

Y

3107435

Y

3210926

Y

873161

Y

360936

Y

3347402

Y

793952

Y

3128879

Y

131884

Y

3392363

Y

CCJ2- 230504

230504081

1252701

Y

2206430

Y

850281

Y

630796

Y

356072

Y

2994154

Y

2982975

Y

867410

Y

348486

Y

3203345

Y

771609

Y

3154242

Y

145100

Y

3336878

Y

MB LK-215208

230504086

1034002

Y

2027804

Y

748206

Y

549700

Y

305579

Y

2440034

Y

2766072

Y

710149

Y

337847

Y

2870869

Y

670268

Y

2902336

Y

130132

Y

2803203

Y

23041906-14AMS

230504088

1039657

Y

1494915

Y

659153

Y

466337

Y

11841316

N

2661845

Y

2795254

Y

769784

Y

837281

N

3306026

Y

694153

Y

3409217

Y

134202

Y

2927252

Y

23041906-MAM 3>D

230504089

1101455

Y

1580897

Y

718889

Y

463858

Y

1276348

N

2834713

Y

2941399

Y

816718

Y

968230

N

3552688

Y

721861

Y

3624633

Y

157281

Y

2985393

Y

23041906-21AMS

230504090

1024267

Y

1714119

Y

648766

Y

462045

Y

286703

Y

2300747

Y

2356965

Y

686503

Y

288150

Y

2758809

Y

606943

Y

2622348

Y

104980

Y

2413181

Y

23041906-21AMSD

2310504091

6982

N

166

N

....

N



N



N

99

N

108

N



N



N

205

N

....

N



N



N

....

N

23041906-20A

230504093

1023346

Y

1747140

Y

636049

Y

485334

Y

315610

Y

2252166

Y

2417288

Y

664211

Y

332630

Y

2698170

Y

590759

Y

2414471

Y

97123

Y

2118603

Y

CCV3-230504

230504094

1271881

Y

2208283

Y

837259

Y

605282

Y

363637

Y

2941258

Y

2872842

Y

836998

Y

349626

Y

3374330

Y

799249

Y

3263032

Y

138454

Y

3201825

Y

23041906-22A

230504097

962017

Y

1769734

Y

687948

Y

500757

Y

370430

Y

2316831

Y

2556990

Y

665731

Y

393854

Y

2794066

Y

577762

Y

2541945

Y

118280

Y

2301964

Y

23041906- 23A

230504098

954863

Y

1809410

Y

659451

Y

487013

Y

290393

Y

2165080

Y

2454874

Y

633456

Y

302198

Y

2587840

Y

586194

Y

2335933

Y

107177

Y

2218738

Y

CCV4-230504

230504108

1246371

Y

2228310

Y

829416

Y

633247

Y

362710

Y

3021620

Y

3024248

Y

863025

Y

365133

Y

3477153

Y

817732

Y

3323512

Y

151119

Y

3440871

Y

23041906- 34A

230504112

1095858

Y

1907600

Y

697464

Y

519286

Y

290573

Y

2499240

Y

2610465

Y

738060

Y

307067

Y

2957731

Y

702218

Y

2834759

Y

113673

Y

2835068

Y

23041906-35A

230504113

1039842

Y

1825765

Y

674048

Y

517736

Y

293479

Y

2450905

Y

2351004

Y

675929

Y

291577

Y

2743111

Y

665046

Y

2736373

Y

135772

Y

2510943

Y

23041906-36A

230504114

1051308

Y

1862730

Y

748099

Y

544598

Y

386969

Y

2489936

Y

2650012

Y

732555

Y

384236

Y

3070840

Y

655851

Y

2759620

Y

127052

Y

2748903

Y

23041906- 37A

230504115

1066899

Y

1908542

Y

754341

Y

547688

Y

369868

Y

2506085

Y

2698751

Y

775660

Y

361065

Y

2961775

Y

680542

Y

2759973

Y

132920

Y

2702282

Y

23041906-21AMSD

2310504124

1918

N

149

N

95

N



N



N

277

N

167

N

214

N



N

393

N



N

180

N



N

731

N

23041906- 21A

230504127

999808

Y

1666916

Y

620488

Y

465489

Y

271629

Y

2386306

Y

2296315

Y

736236

Y

291860

Y

2758658

Y

662817

Y

2740783

Y

117298

Y

2691299

Y

23041906- 21A

230504128

1013384

Y

1698450

Y

624467

Y

457543

Y

276681

Y

2384491

Y

2326342

Y

712098

Y

284042

Y

2740841

Y

655654

Y

2805137

Y

118030

Y

2736895

Y

CCV5-230504

230504134

1319797

Y

2209222

Y

810970

Y

583673

Y

350144

Y

3075038

Y

3028759

Y

832887

Y

345299

Y

3400599

Y

834604

Y

3327220

Y

133369

Y

3271106

Y

CCV6-230504

230504142

1261939

Y

2226306

Y

820337

Y

593057

Y

354700

Y

3081424

Y

2981008

Y

850367

Y

367252

Y

3405638

Y

803188

Y

3398371

Y

157343

Y

3493518

Y

MB LK-215318

230504144

922914

Y

1804914

Y

651747

Y

486272

Y

264750

Y

2178645

Y

2425032

Y

638139

Y

296026

Y

2638966

Y

605824

Y

2539602

Y

114458

Y

2438336

Y

23041906- 21A

230504146

941727

Y

1633036

Y

650864

Y

450708

Y

263571

Y

2329180

Y

2184689

Y

693141

Y

283083

Y

2679758

Y

617606

Y

2693408

Y

113549

Y

2564458

Y

23041906- 21A

230504147

913228

Y

1615849

Y

652618

Y

463823

Y

259444

Y

2303533

Y

2201869

Y

705464

Y

288866

Y

2726740

Y

625520

Y

2634056

Y

112593

Y

2614628

Y

23041906- 21A

230504148

989449

Y

1832021

Y

753392

Y

509619

Y

289287

Y

2464789

Y

2446891

Y

773847

Y

291673

Y

2964117

Y

682852

Y

3004663

Y

123053

Y

2944651

Y

CCJ7- 230504

230504151

1147914

Y

2172635

Y

914728

Y

624323

Y

343667

Y

2941479

Y

2907736

Y

885147

Y

345803

Y

3244794

Y

749458

Y

3256318

Y

147943

Y

3264078

Y

CCV8- 2310504

230504161

1339802

Y

2144225

Y

747336

Y

534268

Y

370294

Y

3020953

Y

2949855

Y

774659

Y

339346

Y

3571560

Y

806597

Y

3264184

Y

135773

Y

2917912

Y





























































O/4/ZUZO

LCMS1

25

-------
ICF International LLC
EPA Region 5 ESAT

'ICF

EXTRACTED

ICALDate:	5/4/2023

Instr. ID: LCMS1
Levels Calibrated:	8

	Limits - 50-150% <



Lab Sample ID

Run ID

dS-»-
MeFOSMJS

Y/N?

PFUn&AJB

		

Y/N?

dS-N-EtFOSX

		

Y/N?

1SG-FOS&JS

		

Y/N?

ISC-PFDoAJS

Y/N?

NEtFOSfcJS

Y/N?

dS-EtFOSEJS

		

Y/N?

NMeFOS&JS

Y/N?

d7-N-
MefQSEJS

Y/N?

PFTe&AJB

		

Y/N?

PFhxDAJS

Y/N?

lSC7-PFUnDAJ

Y/N?

L0.05oob

230504058

1068988

Y

3439162

Y

1231832

Y

958425

Y

3110131

Y

1040037

Y

278068

Y

925511

Y

458175

Y

1481926

Y

6199670

Y

2759667

Y

LO.loob

230504059

1053476

Y

3334304

Y

1235626

Y

930011

Y

3137658

Y

1043547

Y

284829

Y

912857

Y

441873

Y

1469139

Y

6104781

Y

2749520

Y

L0.5oob

230504060

1107354

Y

3254794

Y

1225196

Y

941425

Y

3048697

Y

1038369

Y

262437

Y

933488

Y

449575

Y

1409361

Y

6170544

Y

2595479

Y

Lloob

230504061

1094283

Y

3205276

Y

1231120

Y

951613

Y

3043689

Y

1033931

Y

272603

Y

923183

Y

462803

Y

1407506

Y

6185336

Y

2634551

Y

L2.5oob

230504062

1089726

Y

3046008

Y

1193987

Y

921578

Y

2702537

Y

1038725

Y

227195

Y

917501

Y

447190

Y

1410935

Y

6216011

Y

2296906

Y

L5oob

230504063

1061074

Y

3013373

Y

1255411

Y

945124

Y

2727272

Y

1046828

Y

234483

Y

937564

Y

461236

Y

1382630

Y

6255193

Y

2291398

Y

LlOoob

230504064

1066795

Y

2885601

Y

1179909

Y

889765

Y

2555765

Y

1032367

Y

217284

Y

935574

Y

465751

Y

1305237

Y

6030627

Y

2065795

Y

U5oob

230504065

1036111

Y

3013426

Y

1151236

Y

875829

Y

2752301

Y

997253

Y

254874

Y

925782

Y

434942

Y

1378328

Y

5948029

Y

2324143

Y







N



N



N



N



N



N



N



N



N



N



N



N

A verage of ICAL Standards

1072226



3148993



1213040



926721



2884756



1033882



253972



926433



452693



1405633



6138774



2464682



Low Limit of Response
Hiah Limit of Response

536113



1574497



606520



463361



1442378



516941



126986



463216



226347



702816



3069387



1232341



160833S



4723430



181SSSS



13S0082



4327134



1550823



380357



138S64S



673040



2108449



S208161



3637024







LBLK

230504066

1080247

Y

3032524

Y

1197293

Y

931901

Y

2688325

Y

1017278

Y

230014

Y

912699

Y

442892

Y

1301517

Y

6000045

Y

2230220

Y

CCJ2- 230504

230504081

1031164

Y

3039592

Y

1220883

Y

929358

Y

2907580

Y

1038986

Y

256770

Y

930428

Y

440786

Y

1344734

Y

6079054

Y

2462765

Y

MB LK-215208

230504086

744010

Y

2464634

Y

931382

Y

739899

Y

2285538

Y

585428

Y

194334

Y

566499

Y

316288

Y

1205961

Y

4952486

Y

2191418

Y

23041906-14AMS

230504088

699034

Y

2615708

Y

831493

Y

712202

Y

2362704

Y

634564

Y

174607

Y

603183

Y

303086

Y

903812

Y

4141004

Y

2243607

Y

23041906-MAM 3>D

230504089

684834

Y

2754517

Y

850799

Y

715694

Y

2504020

Y

665693

Y

194996

Y

619274

Y

308266

Y

944693

Y

4176686

Y

2311413

Y

23041906-21AMS

230504090

649322

Y

2198508

Y

758235

Y

621766

Y

2046121

Y

571533

Y

165700

Y

534734

Y

274006

Y

830578

Y

4033798

Y

1832772

Y

23041906-21AMSD

2310504091

666

N

171

N

10319

N

49

N

....

N

472

N

....

N

215

N

1001

N

127

N

1396

N

59985

N

23041906-20A

230504093

646276

Y

1952670

Y

751377

Y

622437

Y

1778496

Y

640743

Y

179826

Y

583192

Y

290474

Y

535015

N

2635095

N

1684806

Y

CCV3-230504

230504094

1013018

Y

3031307

Y

1149706

Y

900516

Y

2936013

Y

1022858

Y

278468

Y

928454

Y

429938

Y

1099647

Y

5797918

Y

2380121

Y

23041906-22A

230504097

667906

Y

2141936

Y

785509

Y

681791

Y

1955215

Y

668870

Y

185787

Y

626631

Y

300821

Y

918962

Y

4179113

Y

1732381

Y

23041906- 23A

230504098

660565

Y

2105636

Y

813400

Y

640887

Y

1934608

Y

632823

Y

170503

Y

601092

Y

302468

Y

896237

Y

4100731

Y

1799788

Y

CCV4-230504

230504108

1071998

Y

3227904

Y

1202479

Y

950075

Y

3144975

Y

1042952

Y

291515

Y

950729

Y

464468

Y

1537995

Y

5949202

Y

2698452

Y

23041906-34A

230504112

735236

Y

2581599

Y

899280

Y

764530

Y

2417466

Y

654177

Y

190440

Y

624071

Y

332598

Y

1013327

Y

4384208

Y

1957265

Y

23041906- 35A

230504113

669937

Y

2311503

Y

799793

Y

661824

Y

2175423

Y

649286

Y

174787

Y

610367

Y

291073

Y

1068551

Y

4353842

Y

1943504

Y

23041906- 36A

230504114

703032

Y

2535616

Y

842114

Y

797186

Y

2460236

Y

703159

Y

189320

Y

681620

Y

362289

Y

1281295

Y

4513392

Y

2265131

Y

23041906- 37A

230504115

635444

Y

2591674

Y

779810

Y

777490

Y

2399123

Y

715403

Y

197493

Y

677209

Y

348899

Y

1149599

Y

4592530

Y

2110257

Y

23041906-21AMSD

2310504124

387

N

....

N

1087

N

208

N

58

N

462

N

....

N

198

N

1692

N

157

N

1486

N

48608

N

23041906-21A

230504127

712813

Y

2484602

Y

849866

Y

676809

Y

2448349

Y

672661

Y

174038

Y

633780

Y

305812

Y

1105170

Y

4072492

Y

2045768

Y

23041906-21A

230504128

725996

Y

2526178

Y

868775

Y

729099

Y

2460874

Y

745757

Y

193163

Y

708849

Y

340305

Y

1069938

Y

4191082

Y

1995517

Y

CCV5-230504

230504134

1056732

Y

3186976

Y

1208384

Y

918801

Y

2848761

Y

1033610

Y

285758

Y

914998

Y

440699

Y

901949

Y

5735425

Y

2324891

Y

CCV6-230504

230504142

1087516

Y

3280250

Y

1223999

Y

938426

Y

3044972

Y

1018836

Y

296558

Y

891806

Y

462614

Y

1271288

Y

5882074

Y

2622172

Y

MB LK-215318

230504144

712191

Y

2317233

Y

888785

Y

726249

Y

2194748

Y

699426

Y

187254

Y

656556

Y

297080

Y

918792

Y

4016880

Y

1891481

Y

23041906-21A

230504146

695971

Y

2327686

Y

825523

Y

621586

Y

2375208

Y

664929

Y

178063

Y

618541

Y

256372

Y

982684

Y

3986154

Y

1969042

Y

23041906-21A

230504147

689731

Y

2477363

Y

864723

Y

696303

Y

2397247

Y

749302

Y

192581

Y

695254

Y

280683

Y

1066780

Y

4189078

Y

1921322

Y

23041906-21A

230504148

796197

Y

2610146

Y

954448

Y

629955

Y

2698173

Y

665575

Y

174158

Y

600134

Y

242719

Y

1220966

Y

4810362

Y

2203844

Y

CCJ7- 230504

230504151

1088221

Y

3165853

Y

1244729

Y

919863

Y

3062485

Y

1068223

Y

281477

Y

913396

Y

417346

Y

1609056

Y

6325580

Y

2710521

Y

CCV8- 2310504

230504161

996473

Y

2832036

Y

1109930

Y

849584

Y

2383282

Y

986366

Y

329327

Y

879768

Y

387651

Y

226727

N

4765565

Y

1717201

Y





















































26

-------
iCF international LLC

| ^	EPA Region 5 ESAT

'ICF

LABORATORY REAGENT BLANK (LRB/MBLK) SUMMARY

SDG/Lab Work Order Number: 23041906

Blank ID: MBLK-214976-214976a	Date analyzed: 4/26/2023

Blank Data File: 2304260008	Date Prepared: 4/25/2023

LRB or FRB METHOD BLANK	Batch ID: 214976a

Analyte Name

Abbreviation

MRL ng/l.
(ppt)

Blank
Amount

_iept)

Flag

1 IC 1 !'i U)lIds '





0

II

A.i'. Picix.i '.!! jiciiliiiiiiiniin.iniiii Ai iii jhONAj

	



0

II

•X 1 !'! '.ONS



!).'j



U

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

5.0

0

u

Fluorotelomer Sulphonic Acid 4:2 (FtS4:2)

757124-72-4

5.0

0

u

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

5.0

0

u

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

5.0

0

u

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

5.0

0

u

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

5.0

0

u

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

5.0

0

u

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

5.0

1.299



N-methylperfluoro-l-octanesulfonamide

31506-32-8

5.0

0

u

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

5.0

0

u

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

5.0

0

u

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

5.0

0

u

Perfluorobutanoic Acid (PFBA)

375-22-4

5.0

0

u

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

5.0

0

u

PerfluorodecanoicAcid (PFDA)

335-76-2

5.0

0

u

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

5.0

0

u

PerfluorododecanoicAcid (PFDoA)

307-55-1

5.0

0

u

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

5.0

0

u

PerfluoroheptanoicAcid (PFHpA)

375-85-9

5.0

0

u

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

5.0

0

u

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

5.0

0

u

PerfluorohexanoicAcid (PFHxA)

307-24-4

5.0

0

u

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

5.0

0

u

Perfluorononanoic Acid (PFNA)

375-95-1

5.0

0

u

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

5.0

0

u

Perfluorooctanesulfonamide (PFOSA)

754-91-6

5.0

0

u

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

2.0

0

u

Perfluorooctanoic Acid (PFOA)

335-67-1

2.0

0

u

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

5.0

0

u

PerfluoropentanoicAcid (PFPeA)

2706-90-3

5.0

0

u

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

5.0

0

u

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

5.0

0

u

PerfluoroundecanoicAcid (PFUnA)

2058-94-8

5.0

0

u

Samples Associated with this Blank:

Client Sample !D

Lsb Sample ID

Analyzed

Lab File

MBLK-2149 76-214976a

MBLK-214976

4/26/2023



LCS-W1-214976-214976a

LCS-WI-214976

4/26/2023



23041906-09A MS

23041906-09A MS

4/26/2023



23041906-09A MSD

23041906-09A MSD

4/26/2023



MW-7-230419

23041906-09A

4/26/2023



W-l-230418

23041906-01A

4/27/2023



W-1A-230418

23041906-02A

4/27/2023



























































































































































































































27

-------
ICF International LLC
EPA Region 5 ESAT

'ICF LABORATORY REAGENT BLANK (LRB/MBLK) SUMMARY

SDG/Lab Work Order Number: 23041906

Blank ID: MBLK-215208-215208a	Date analyzed: 5/4/2023

Blank Data File: 230504086	Date Prepared: 4/28/2023
LRB or FRB METHOD BLANK Batch ID: 215208a

Analyte Name

Abbreviation

MRL ng/L
(PPt)

Biank
Amount
(PPt)

Flag

llCI-Pf30UdS

763051-92-9

5.0

0

u

4,8-Dioxa-3H-perfluorononanoic Acid (DONA)

919005-14-4

5.0

0

u

9CI-PF30NS

756426-58-1

5.0

0

u

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

5.0

0

u

Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

757124-72-4

5.0

0

u

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

5.0

0

u

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

5.0

0

u

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

5.0

0

u

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

5.0

0

u

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

5.0

0

u

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

5.0

0

u

N-methylperfluoro-l-octanesulfonamide

31506-32-8

5.0

0

u

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

5.0

0

u

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

5.0

0

u

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

5.0

0

u

Perfluorobutanoic Acid (PFBA)

375-22-4

5.0

0

u

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

5.0

0

u

Perfluorodecanoic Acid (PFDA)

335-76-2

5.0

0

u

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

5.0

0

u

Perfluorododecanoic Acid (PFDoA)

307-55-1

5.0

0

u

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

5.0

0

u

Perfluoroheptanoic Acid (PFHpA)

375-85-9

5.0

0

u

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

5.0

0

u

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

5.0

0

u

Perfluorohexanoic Acid (PFHxA)

307-24-4

5.0

0

u

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

5.0

0

u

Perfluorononanoic Acid (PFNA)

375-95-1

5.0

0

u

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

5.0

0

u

Perfluorooctanesulfonamide (PFOSA)

754-91-6

5.0

0

u

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

2.0

0

u

Perfluorooctanoic Acid (PFOA)

335-67-1

2.0

0

u

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

5.0

0

u

Perfluoropentanoic Acid (PFPeA)

2706-90-3

5.0

0

u

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

5.0

0

u

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

5.0

0

u

Perfluoroundecanoic Acid (PFUnA)

2058-94-8

5.0

0

u

Samples Associated with this Blank:

Client Sample ID

Lab Sample ID

Analyzed

Lab File

MW-108A-2 30420

23041906-22A

5/5/2023



MW-110 A-2 30420

23041906-24A

4/30/2023



MW-112-230420

23041906-25A

4/30/2023



MW-113-230419

23041906-26A

4/30/2023



MW-115-230419

23041906-27A

4/30/2023



MW-115 A-2 30419

23041906-28A

4/30/2023



MW-116-230419

23041906-29A

4/30/2023



DUP-01-230418

23041906-30A

4/30/2023



DUP-02-230418

23041906-31A

4/30/2023



FB-01-230420

23041906-32A

4/30/2023



FB-02-230420

23041906-33A

4/30/2023



MBLK-215208-215208 a

MBLK-215208

5/4/2023



LCS-WI-215208-215208 a

LCS-WI-215208

5/4/2023



MW-107 A-2 30419

23041906-20A

5/5/2023



28

-------
ICF International LLC
EPA Region 5 ESAT

'ICF LABORATORY REAGENT BLANK (LRB/MBLK) SUMMARY

SDG/Lab Work Order Number: 23041906

Blank ID: MBLK-215053-215053a	Date analyzed: 4/26/2023

Blank Data File: 230426011	Date Prepared: 4/26/2023
LRB or FRB METHOD BLANK Batch ID: 215053a

Analyte Name

Abbreviation

MRL ng/L
(PPt)

Biank
Amount
(PPt)

Flag

llCI-Pf30UdS

763051-92-9

5.0

0

u

4,8-Dioxa-3H-perfluorononanoic Acid (DONA)

919005-14-4

5.0

0

u

9CI-PF30NS

756426-58-1

5.0

0

u

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

5.0

0

u

Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

757124-72-4

5.0

0

u

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

5.0

0

u

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

5.0

0

u

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

5.0

0

u

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

5.0

0

u

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

5.0

0

u

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

5.0

1.254

J

N-methylperfluoro-l-octanesulfonamide

31506-32-8

5.0

0

u

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

5.0

0

u

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

5.0

0

u

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

5.0

0

u

Perfluorobutanoic Acid (PFBA)

375-22-4

5.0

0

u

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

5.0

0

u

Perfluorodecanoic Acid (PFDA)

335-76-2

5.0

0

u

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

5.0

0

u

Perfluorododecanoic Acid (PFDoA)

307-55-1

5.0

0

u

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

5.0

0

u

Perfluoroheptanoic Acid (PFHpA)

375-85-9

5.0

0

u

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

5.0

0

u

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

5.0

0

u

Perfluorohexanoic Acid (PFHxA)

307-24-4

5.0

0

u

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

5.0

0

u

Perfluorononanoic Acid (PFNA)

375-95-1

5.0

0

u

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

5.0

0

u

Perfluorooctanesulfonamide (PFOSA)

754-91-6

5.0

0

u

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

2.0

0

u

Perfluorooctanoic Acid (PFOA)

335-67-1

2.0

0

u

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

5.0

0

u

Perfluoropentanoic Acid (PFPeA)

2706-90-3

5.0

0

u

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

5.0

0

u

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

5.0

0

u

Perfluoroundecanoic Acid (PFUnA)

2058-94-8

5.0

0

u

Samples Associated with this Blank:

Client Sample ID

Lab Sample ID

Analyzed

Lab File

MBLK-215053-215053 a

M3LK-215053

4/2G/2023



LCS-WI-215053-215053 a

LCS-WI-215053

4/26/2023



MW-10-230420

23041906-14A

4/27/2023



MW-2-230418

23041906-03A

4/27/2023



MW-3R-230418

23041906-04A

4/27/2023



MW-5-230419

23041906-05A

4/27/2023



MW-5A-230420

23041906-06A

4/27/2023



MW-6-230418

23041906-07A

4/27/2023



MW-6A-230418

23041906-08A

4/27/2023



MW-7A-230419

23041906-10A

4/27/2023



MW-8-230420

23041906-11A

4/27/2023



MW-8A-230420

23041906-12A

4/27/2023



MW-9-230419

23041906-13A

4/27/2023



MW-11-230419

23041906-15A

4/27/2023



29

-------
ICF International LLC
EPA Region 5 ESAT

'ICF LABORATORY REAGENT BLANK (LRB/MBLK) SUMMARY

SDG/Lab Work Order Number: 23041906

Blank ID: MBLK-215318-215318a	Date analyzed: 5/5/2023

Blank Data File: 230504144	Date Prepared: 5/1/2023

LRB or FRB METHOD BLANK	Batch ID: 215318a

Analyte Name

Abbreviation

MRL ng/L
(PPt)

Biank
Amount
(ppt)

Flag

llCI-Pf30UdS

763051-92-9

0.0

0

u

4,8-Dioxa-3H-perfluorononanoic Acid (DONA)

919005-14-4

0.0

0

u

9CI-PF30NS

756426-58-1

0.0

0

u

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

0.0

0

u

Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

757124-72-4

0.0

0

u

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

0.0

0

u

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

0.0

0

u

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

0.0

0

u

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

0.0

0

u

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

0.0

0

u

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

0.0

0

u

N-methylperfluoro-l-octanesulfonamide

31506-32-8

0.0

0

u

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

0.0

0

u

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

0.0

0

u

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

0.0

0

u

Perfluorobutanoic Acid (PFBA)

375-22-4

0.0

0

u

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

0.0

0

u

Perfluorodecanoic Acid (PFDA)

335-76-2

0.0

0

u

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

0.0

0

u

Perfluorododecanoic Acid (PFDoA)

307-55-1

0.0

0

u

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

0.0

0

u

Perfluoroheptanoic Acid (PFHpA)

375-85-9

0.0

0

u

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

0.0

0

u

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

0.0

0

u

Perfluorohexanoic Acid (PFHxA)

307-24-4

0.0

0

u

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

0.0

0

u

Perfluorononanoic Acid (PFNA)

375-95-1

0.0

0

u

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

0.0

0

u

Perfluorooctanesulfonamide (PFOSA)

754-91-6

0.0

0

u

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

0.0

0

u

Perfluorooctanoic Acid (PFOA)

335-67-1

0.0

0

u

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

0.0

0

u

Perfluoropentanoic Acid (PFPeA)

2706-90-3

0.0

0

u

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

0.0

0

u

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

0.0

0

u

Perfluoroundecanoic Acid (PFUnA)

2058-94-8

0.0

0

u

Samples Associated with this Blank:

Client Sample ID

Lab Sample ID

Analyzed

Lab File

23041906-21A MS

23041906-21A MS

5/5/2023



23041906-21A MSD

23041906-21A MSD

5/5/2023



MBLK-215318-215318 a

MBLK-215318

5/5/2023



LCS-WI-215318-215318 a

LCS-WI-215318

5/5/2023



MW-108-2 30420

23041906-21A

5/5/2023











































































30

-------
ICF International LLC

xl/	EPA Region 5 ESAT

''ICF

LABORATORY CONTROL SPIKE SUMMARY

SDG/Lab work Order Number: 23041906

LCSID: LCS-WI-214976	Date analyzed: 4/26/2023

LCS DATA FILE: 2304260009	Date Prepared: 4/25/2023

Batch ID: 214976a





Spike

Blank

Amt



Analyte Name

Abbreviation

Amount

Amount

Found

.0



(ppt)

(ppt)

(ppt)

Recovery

llCI-Pf30UdS

763051-92-9

3.762

0

3.539

94.1%

4,8-Dioxa-3H-perfluorononanoic Acid (DONA)

919005-14-4

3.762

0

3.357

89.2%

9CI-PF30NS

756426-58-1

3.725

0

3.61

96.9%

Fluorotelomer Sulphortic Acid 10:2 (FtS 10:2)

120226-60-0

3.85

0

4.016

104.3%

FluorotelomerSulphorticAcid 4:2 (FtS4:2)

757124-72-4

3.738

0

4.387

117.4%

Fluorotelomer Sulphortic Acid 6:2 (FtS 6:2)

27619-97-2

3.788

0

3.76

99.3%

FluorotelomerSulphorticAcid 8:2 (FtS8:2)

39108-34-4

3.838

0

3.622

94.4%

Hexafluoropropylerte oxide dimer acid (HFPO-DA)

13252-13-6

4

0

3.661

91.5%

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

4

0

3.619

90.5%

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

4

0

3.882

97.1%

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

4

1.299

3.635

58.4%

N-methylperfluoro-l-octanesulfonamide

31506-32-8

4

0

4.067

101.7%

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

4

0

3.958

99.0%

N-Methylperfluorooctartesulfortamidoethartol

24448-09-7

4

0

3.571

89.3%

Perfluorobutartesulfortic Acid (PFBS)

375-73-5

3.538

0

3.35

94.7%

Perfluorobutanoic Acid (PFBA)

375-22-4

4

0

3.824

95.6%

Perfluorodecartesulfortic Acid (PFDS)

335-77-3

3.85

0

3.382

87.8%

Perfluorodecartoic Acid (PFDA)

335-76-2

4

0

4.525

113.1%

Perfluorododecanesulfortic Acid (PFDoS)

79780-39-5

3.875

0

3.6

92.9%

Perfluorododecartoic Acid (PFDoA)

307-55-1

4

0

4.342

108.6%

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

3.812

0

3.702

97.1%

Perfluoroheptanoic Acid (PFHpA)

375-85-9

4

0

4.093

102.3%

Perfluorohexadecartoic Acid (PFHxDA)

67905-19-5

4

0

3.245

81.1%

Perfluorohexartesulfortic Acid (PFHxS)

355-46-4

3.638

0

3.587

98.6%

Perfluorohexartoic Acid (PFHxA)

307-24-4

4

0

4.634

115.9%

Perf 1 uorortortartesulfortic Acid (PFNS)

68259-12-1

3.838

0

3.533

92.1%

Perfluoronortanoic Acid (PFNA)

375-95-1

4

0

4.07

101.8%

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

4

0

4.877

121.9%

Perfluorooctartesulfortamide (PFOSA)

754-91-6

4

0

3.68

92.0%

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

3.712

0

4.163

112.1%

Perfluorooctartoic Acid (PFOA)

335-67-1

4

0

3.683

92.1%

Perfluoropenta rtesulfort ic Acid (PFPeS)

2706-91-4

3.75

0

3.549

94.6%

Perfluoropentanoic Acid (PFPeA)

2706-90-3

4

0

3.773

94.3%

Perfluorotetradecartoic Acid (PFTeA)

376-06-7

4

0

3.773

94.3%

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

4

0

3.677

91.9%

Perfluorourtdecartoic Acid (PFUrtA)

2058-94-8

4

0

4.582

114.6%

sampler* Associated with thir> (Lh.-M):

Client Sample ID

Lab Sample ID



MBLK-214976-214976a

MBLK-214976

4/26/2023

214976a

LCS-WI-214976-214976a

LCS-WI-214976

4/26/2023

214976a

23041906-09A MS

23041906-09A MS

4/26/2023

214976a

23041906-09A MSD

23041906-09A MSD

4/26/2023

214976a

MW-7-230419

23041906-09A

4/26/2023

214976a

W-1-230418

23041906-01A

4/27/2023

214976a

W-1A-230418

23041906-02A

4/27/2023

214976a

























































































































































31

-------
ICF International LLC
EPA Region 5 ESAT

'ICF

LABORATORY CONTROL SPIKE SUMMARY

SDG/Lab work Order Number
LCS ID
LCS DATA FILE

23041906

LCS-WI-215053	Date analyzed: 4/26/2023

2304260012	Date Prepared: 4/26/2023

Batch ID: 215053a

Anaiyte Name

Abbreviation

Spike
Amount
. (ppt)

Blank
Amount
(ppt!

Amt
Found
. (PPt)

%

Recovery

HCI-Pf30UdS

763051-92-9

3.762

0

4.054

107.8%

4,8-Dioxa-3H-perfluorononanoic Acid (DONA)

919005-14-4

3.762

0

3.594

95.5%

9CI-PF30NS

756426-58-1

3.725

0

3.789

101.7%

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

3.85

0

4.173

108.4%

Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

757124-72-4

3.738

0

4.544

121.6%

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

3.788

0

5.187

136.9%

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

3.838

0

4.73

123.2%

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

4

0

4.746

118.7%

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

4

0

5.357

133.9%

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

4

0

4.832

120.8%

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

4

1.254

4.506

81.3%

N-methylperfluoro-l-octanesulfonamide

31506-32-8

4

0

4.739

118.5%

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

4

0

4.842

121.1%

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

4

0

4.413

110.3%

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

3.538

0

4.166

117.8%

Perfluorobutanoic Acid (PFBA)

375-22-4

4

0

4.061

101.5%

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

3.85

0

3.389

88.0%

Perfluorodecanoic Acid (PFDA)

335-76-2

4

0

3.952

98.8%

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

3.875

0

4.275

110.3%

Perfluorododecanoic Acid (PFDoA)

307-55-1

4

0

3.885

97.1%

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

3.812

0

3.469

91.0%

Perfluoroheptanoic Acid (PFHpA)

375-85-9

4

0

5.126

128.2%

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

4

0

4.102

102.6%

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

3.638

0

3.466

95.3%

Perfluorohexanoic Acid (PFHxA)

307-24-4

4

0

4.486

112.2%

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

3.838

0

4

104.2%

Perfluorononanoic Acid (PFNA)

375-95-1

4

0

4.17

104.3%

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

4

0

5.418

135.5%

Perfluorooctanesulfonamide (PFOSA)

754-91-6

4

0

4.333

108.3%

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

3.712

0

3.405

91.7%

Perfluorooctanoic Acid (PFOA)

335-67-1

4

0

4

100.0%

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

3.75

0

3.654

97.4%

Perfluoropentanoic Acid (PFPeA)

2706-90-3

4

0

4.224

105.6%

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

4

0

4.278

107.0%

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

4

0

4.314

107.9%

Perfluoroundecanoic Acid (PFUnA)

2058-94-8

4

0

4.781

119.5%

Samples Associated with this LCS (LFSM):

Client Sample ID

Lab Sample ID

Analyzed

Lab Fsle

MBLK-215053-215053a

MBLK-215053

4/26/2023

215053a

LCS-WI-215053-21505 3a

LCS-WI-215053

4/26/2023

215053a

MW-10-230420

23041906-14A

4/27/2023

215053a

MW-2-230418

23041906-03A

4/27/2023

215053a

MW-3R-230418

23041906-04A

4/27/2023

215053a

MW-5-230419

23041906-05A

4/27/2023

215053a

MW-5A-230420

23041906-06A

4/27/2023

215053a

MW-6-230418

23041906-07A

4/27/2023

215053a

MW-6A-230418

23041906-08A

4/27/2023

215053a

MW-7A-230419

23041906-10A

4/27/2023

215053a

MW-8-230420

23041906-11A

4/27/2023

215053a

MW-8A-230420

23041906-12A

4/27/2023

215053a

MW-9-230419

23041906-13A

4/27/2023

215053a

MW-11-230419

23041906-15A

4/27/2023

215053a

MW-12-230419

23041906-16A

4/27/2023

215053a

MW-106-230420

23041906-17A

4/27/2023

215053a

32

-------
ICF International LLC
EPA Region 5 ESAT

'ICF

LABORATORY CONTROL SPIKE SUMMARY

SDG/Lab work Order Number
LCS ID
LCS DATA FILE

23041906

LCS-WI-215208	Date analyzed: 5/4/2023

230504087	Date Prepared: 4/28/2023

Batch ID: 215208a





Spike

Blank

Amt

%

Recovery

Anaiyte Name

Abbreviation

Amount
. (ppt)

Amount
(ppt!

Found
. (PPt)

HCI-Pf30UdS

763051-92-9

3.762

0

3.558

94.6%

4,8-Dioxa-3H-perfluorononanoic Acid (DONA)

919005-14-4

3.762

0

3.59

95.4%

9CI-PF30NS

756426-58-1

3.725

0

3.786

101.6%

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

3.85

0

4.106

106.6%

Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

757124-72-4

3.738

0

3.338

89.3%

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

3.788

0

3.61

95.3%

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

3.838

0

3.674

95.7%

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

4

0

3.738

93.5%

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

4

0

4.579

114.5%

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

4

0

3.952

98.8%

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

4

0

4.115

102.9%

N-methylperfluoro-l-octanesulfonamide

31506-32-8

4

0

3.587

89.7%

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

4

0

3.827

95.7%

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

4

0

4.96

124.0%

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

3.538

0

3.488

98.6%

Perfluorobutanoic Acid (PFBA)

375-22-4

4

0

5.469

136.7%

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

3.85

0

3.562

92.5%

Perfluorodecanoic Acid (PFDA)

335-76-2

4

0

4.435

110.9%

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

3.875

0

3.613

93.2%

Perfluorododecanoic Acid (PFDoA)

307-55-1

4

0

4.17

104.3%

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

3.812

0

4.013

105.3%

Perfluoroheptanoic Acid (PFHpA)

375-85-9

4

0

4.48

112.0%

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

4

0

3.078

77.0%

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

3.638

0

3.802

104.5%

Perfluorohexanoic Acid (PFHxA)

307-24-4

4

0

4.502

112.6%

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

3.838

0

3.491

91.0%

Perfluorononanoic Acid (PFNA)

375-95-1

4

0

4.131

103.3%

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

4

0

4.73

118.3%

Perfluorooctanesulfonamide (PFOSA)

754-91-6

4

0

3.997

99.9%

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

3.712

0

4.25

114.5%

Perfluorooctanoic Acid (PFOA)

335-67-1

4

0

4.39

109.8%

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

3.75

0

3.597

95.9%

Perfluoropentanoic Acid (PFPeA)

2706-90-3

4

0

3.907

97.7%

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

4

0

4.067

101.7%

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

4

0

4.272

106.8%

Perfluoroundecanoic Acid (PFUnA)

2058-94-8

4

0

4.621

115.5%

Samples Associated with this LCS (LFSM):

Client Sample ID

Lab Sample ID

Analyzed

Lab Fsle

MW-108A-230420

23041906-22A

5/5/2023

215208a

MW-110A-230420

23041906-24A

4/30/2023

215208a

MW-112-230420

23041906-25A

4/30/2023

215208a

MW-113-230419

23041906-26A

4/30/2023

215208a

MW-115-230419

23041906-27A

4/30/2023

215208a

MW-115A-230419

23041906-28A

4/30/2023

215208a

MW-116-230419

23041906-29A

4/30/2023

215208a

DUP-01-230418

23041906-30A

4/30/2023

215208a

DUP-02-230418

23041906-31A

4/30/2023

215208a

FB-01-230420

23041906-32A

4/30/2023

215208a

FB-02-230420

23041906-33A

4/30/2023

215208a

MBLK-215208-215208a

MBLK-215208

5/4/2023

215208a

LCS-WI-215208-215208a

LCS-WI-215208

5/4/2023

215208a

MW-107A-230419

23041906-20A

5/5/2023

215208a

MW-110-230420

23041906-23A

5/5/2023

215208a

EB-01-230420

23041906-34A

5/5/2023

215208a

33

-------
ICF International LLC
EPA Region 5 ESAT

'ICF

LABORATORY CONTROL SPIKE SUMMARY

SDG/Lab work Order Number
LCS ID
LCS DATA FILE

23041906

LCS-WI-215318	Date analyzed: 1/0/1900

230404145	Date Prepared: 5/1/2023

Batch ID: 215318a





Spike

Blank

Amt

%

Recovery

Anaiyte Name

Abbreviation

Amount
. (ppt)

Amount
(ppt!

Found
. (PPt)

HCI-Pf30UdS

763051-92-9

3.762

0

3.859

102.6%

4,8-Dioxa-3H-perfluorononanoic Acid (DONA)

919005-14-4

3.762

0

3.824

101.6%

9CI-PF30NS

756426-58-1

3.725

0

3.693

99.1%

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

3.85

0

5.024

130.5%

Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

757124-72-4

3.738

0

3.946

105.6%

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

3.788

0

3.562

94.0%

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

3.838

0

3.814

99.4%

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

4

0

4.563

114.1%

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

4

0

4.954

123.9%

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

4

0

4.019

100.5%

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

4

0

3.843

96.1%

N-methylperfluoro-l-octanesulfonamide

31506-32-8

4

0

3.782

94.6%

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

4

0

3.994

99.9%

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

4

0

5.901

147.5%

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

3.538

0

3.699

104.6%

Perfluorobutanoic Acid (PFBA)

375-22-4

4

0

4.797

119.9%

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

3.85

0

3.075

79.9%

Perfluorodecanoic Acid (PFDA)

335-76-2

4

0

4.547

113.7%

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

3.875

0

3.235

83.5%

Perfluorododecanoic Acid (PFDoA)

307-55-1

4

0

4.214

105.4%

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

3.812

0

4.56

119.6%

Perfluoroheptanoic Acid (PFHpA)

375-85-9

4

0

4.614

115.4%

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

4

0

2.413

60.3%

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

3.638

0

4.246

116.7%

Perfluorohexanoic Acid (PFHxA)

307-24-4

4

0

5.219

130.5%

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

3.838

0

3.149

82.0%

Perfluorononanoic Acid (PFNA)

375-95-1

4

0

4.166

104.2%

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

4

0

3.418

85.5%

Perfluorooctanesulfonamide (PFOSA)

754-91-6

4

0

3.856

96.4%

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

3.712

0

4

107.8%

Perfluorooctanoic Acid (PFOA)

335-67-1

4

0

4.659

116.5%

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

3.75

0

4.138

110.3%

Perfluoropentanoic Acid (PFPeA)

2706-90-3

4

0

4.067

101.7%

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

4

0

4.144

103.6%

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

4

0

4.042

101.1%

Perfluoroundecanoic Acid (PFUnA)

2058-94-8

4

0

4.797

119.9%

Samples Associated with this LCS (LFSM):

Client Sample ID

Lab Sample ID

Analyzed

Lab Fsle

23041906-21A MS

23041906-21A MS

5/5/2023

215318a

23041906-21A MSD

23041906-21A MSD

5/5/2023

215318a

MBLK-215318-215318a

MBLK-215318

5/5/2023

215318a

LCS-WI-215318-215318a

LCS-WI-215318

5/5/2023

215318a

MW-108-230420

23041906-21A

5/5/2023

215318a

























































































34

-------
_
'ICF

ICF International LLC
EPA Region 5 ESAT

MATRIX SPIKE (LFSM) SUMMARY

SDG/Lab work Order Number: 23041906

Matrix Spike ID: 23041906-09A MS	Date analyzed: 4/26/2023

Parent Sample: MW-7-230419	Date Prepared: 4/25/2023

Batch ID: 214976a

Analyte Name

Abbreviation

Spike
Amount
(ppt)

Sample
Amount
(ppt)

Amt
Found
(ppt)

%

Recovery

HCI-Pf30UdS

763051-92-9

33.09

0

30.47

92.1%

4,8-Dioxa-3H-perfluorononanoic Acid (DONA)

919005-14-4

33.09

0

30.86

93.3%

9CI-PF30NS

756426-58-1

32.76

0

31.48

96.1%

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

33.86

0

39.19

115.7%

Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

757124-72-4

32.87

0

32.4

98.6%

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

33.31

0

34.92

104.8%

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

33.75

0

35.22

104.4%

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

35.18

0

34.64

98.5%

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

35.18

0

33.5

95.2%

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

35.18

0

36.66

104.2%

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

35.18

0

32.16

91.4%

N-methylperfluoro-l-octanesulfonamide

31506-32-8

35.18

0

34.47

98.0%

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

35.18

0

33.81

96.1%

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

35.18

0

33.97

96.6%

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

31.11

0

28.73

92.3%

Perfluorobutanoic Acid (PFBA)

375-22-4

35.18

0

34.3

97.5%

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

33.86

0

31.25

92.3%

Perfluorodecanoic Acid (PFDA)

335-76-2

35.18

0

34.81

98.9%

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

34.08

0

30.5

89.5%

Perfluorododecanoic Acid (PFDoA)

307-55-1

35.18

0

34.57

98.3%

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

33.53

0

31.83

94.9%

Perfluoroheptanoic Acid (PFHpA)

375-85-9

35.18

0

36.6

104.0%

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

35.18

0

45.09

128.2%

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

31.99

0

29.55

92.4%

Perfluorohexanoic Acid (PFHxA)

307-24-4

35.18

0

36.51

103.8%

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

33.75

0

32.53

96.4%

Perfluorononanoic Acid (PFNA)

375-95-1

35.18

0

34.7

98.6%

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

35.18

0

42.8

121.7%

Perfluorooctanesulfonamide (PFOSA)

754-91-6

35.18

0

31.47

89.5%

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

32.65

2.3

31.51

89.5%

Perfluorooctanoic Acid (PFOA)

335-67-1

35.18

0

32.19

91.5%

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

32.98

0

32.09

97.3%

Perfluoropentanoic Acid (PFPeA)

2706-90-3

35.18

0

31.25

88.8%

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

35.18

0

29.54

84.0%

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

35.18

0

31.69

90.1%

Perfluoroundecanoic Acid (PFUnA)

2058-94-8

35.18

0

37.15

105.6%

Samples Associated with this LCS (LFSM):

Client Sample ID

Lab Sample ID

Analyzed

Lab File

MBLK-214976-214976a

MBLK-214976

4/26/2023

214976a

LCS-WI-214976-214976a

LCS-WI-214976

4/26/2023

214976a

23041906-09A MS

23041906-09A MS

4/26/2023

214976a

23041906-09A MSD

23041906-09A MSD

4/26/2023

214976a

MW-7-230419

23041906-09A

4/26/2023

214976a

W-l-230418

23041906-01A

4/27/2023

214976a

W-1A-230418

23041906-02A

4/27/2023

214976a

























































35

-------
_
'ICF

ICF International LLC
EPA Region 5 ESAT

MATRIX SPIKE (LFSM) SUMMARY

SDG/Lab work Order Number: 23041906

LCS ID: 23041906-14A MS	Date analyzed: 5/4/2023

Parent Sample: MW-10-230420	Date Prepared: 4/26/2023

Batch ID: 215053a

Analyte Name

Abbreviation

Spike
Amount
(ppt)

Sample
Amount
(ppt)

215053a

%

Recovery

HCI-Pf30UdS

763051-92-9

32.84

0

29.99

91.3%

4,8-Dioxa-3H-perfluorononanoic Acid (DONA)

919005-14-4

32.84

0

21.98

66.9%

9CI-PF30NS

756426-58-1

32.51

0

30.83

94.8%

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

33.6

0

32.71

97.4%

Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

757124-72-4

32.62

0

30.11

92.3%

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

33.05

0

32.89

99.5%

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

33.49

0

39

116.5%

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

34.91

0

39.14

112.1%

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

34.91

0

35.88

102.8%

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

34.91

0

35.06

100.4%

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

34.91

0

34.49

98.8%

N-methylperfluoro-l-octanesulfonamide

31506-32-8

34.91

0

35.62

102.0%

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

34.91

0

36.63

104.9%

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

34.91

0

39.73

113.8%

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

30.87

8.3

37.17

93.5%

Perfluorobutanoic Acid (PFBA)

375-22-4

34.91

19

40.64

62.0%

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

33.6

0

30.29

90.1%

Perfluorodecanoic Acid (PFDA)

335-76-2

34.91

0

36.03

103.2%

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

33.82

0

26.41

78.1%

Perfluorododecanoic Acid (PFDoA)

307-55-1

34.91

0

31.94

91.5%

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

33.27

0.64

29.33

86.2%

Perfluoroheptanoic Acid (PFHpA)

375-85-9

34.91

9.7

43.26

96.1%

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

34.91

0

34.31

98.3%

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

31.74

2.2

30.74

89.9%

Perfluorohexanoic Acid (PFHxA)

307-24-4

34.91

14

46.45

93.0%

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

33.49

0

30.92

92.3%

Perfluorononanoic Acid (PFNA)

375-95-1

34.91

0

29.42

84.3%

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

34.91

0

36.8

105.4%

Perfluorooctanesulfonamide (PFOSA)

754-91-6

34.91

0

33.51

96.0%

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

32.4

34

63.59

91.3%

Perfluorooctanoic Acid (PFOA)

335-67-1

34.91

31

61.52

87.4%

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

32.73

1.3

33.4

98.1%

Perfluoropentanoic Acid (PFPeA)

2706-90-3

34.91

16

51.79

102.5%

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

34.91

0

35.57

101.9%

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

34.91

0

39

111.7%

Perfluoroundecanoic Acid (PFUnA)

2058-94-8

34.91

0

34.19

97.9%

Samples Associated with this LCS (LFSM):

Client Sample ID

Lab Sample ID

Analyzed

QC Batch

MBLK-215053-215053a

MBLK-215053

4/26/2023

215053a

LCS-WI-215053-215053a

LCS-WI-215053

4/26/2023

215053a

MW-10-230420

23041906-14A

4/27/2023

215053a

MW-2-230418

23041906-03A

4/27/2023

215053a

MW-3R-230418

23041906-04A

4/27/2023

215053a

MW-5-230419

23041906-05A

4/27/2023

215053a

MW-5A-230420

23041906-06A

4/27/2023

215053a

MW-6-230418

23041906-07A

4/27/2023

215053a

MW-6A-230418

23041906-08A

4/27/2023

215053a

MW-7A-230419

23041906-10A

4/27/2023

215053a

MW-8-230420

23041906-11A

4/27/2023

215053a

MW-8A-230420

23041906-12A

4/27/2023

215053a

MW-9-230419

23041906-13A

4/27/2023

215053a

MW-11-230419

23041906-15A

4/27/2023

215053a

36

-------
_
'ICF

ICF International LLC
EPA Region 5 ESAT

MATRIX SPIKE (LFSM) SUMMARY

SDG/Lab work Order Number: 23041906

LCS ID: 23041906-21A MS
Parent Sample: MW-108-230420

Date analyzed: 5/4-5/5/2023
Date Prepared: 5/1/2023
Batch ID: 215318a

Analyte Name

Abbreviation

Spike
Amount
(ppt)

Sample
Amount
(ppt)

215318a

%

Recovery

HCI-Pf30UdS

763051-92-9

29.2

0

28.18

96.5%

4,8-Dioxa-3H-perfluorononanoic Acid (DONA)

919005-14-4

29.2

0

25.97

88.9%

9CI-PF30NS

756426-58-1

28.91

0

29.76

102.9%

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

29.88

0

64.5

215.9%

Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

757124-72-4

29.01

0

31.85

109.8%

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

29.4

0

34.6

117.7%

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

29.78

0

33.5

112.5%

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

31.05

0

34.26

110.3%

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

31.05

0

36.51

117.6%

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

31.05

0

32.95

106.1%

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

31.05

0

33.13

106.7%

N-methylperfluoro-l-octanesulfonamide

31506-32-8

31.05

0

34.38

110.7%

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

31.05

0

35.28

113.6%

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

31.05

0

43.67

140.6%

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

27.46

0.53

29.48

105.4%

Perfluorobutanoic Acid (PFBA)

375-22-4

31.05

6.1

36.16

96.8%

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

29.88

0

27.87

93.3%

Perfluorodecanoic Acid (PFDA)

335-76-2

31.05

0

32.14

103.5%

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

30.07

0

26.65

88.6%

Perfluorododecanoic Acid (PFDoA)

307-55-1

31.05

0

31.44

101.3%

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

29.59

0

28.87

97.6%

Perfluoroheptanoic Acid (PFHpA)

375-85-9

31.05

0

36.32

117.0%

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

31.05

0

37.72

121.5%

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

28.23

0

28.8

102.0%

Perfluorohexanoic Acid (PFHxA)

307-24-4

31.05

0

33.54

108.0%

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

29.78

0

29.52

99.1%

Perfluorononanoic Acid (PFNA)

375-95-1

31.05

0

30.49

98.2%

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

31.05

0

35.36

113.9%

Perfluorooctanesulfonamide (PFOSA)

754-91-6

31.05

0

32.82

105.7%

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

28.81

0

29.17

101.2%

Perfluorooctanoic Acid (PFOA)

335-67-1

31.05

0

30.69

98.8%

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

29.1

0

29.69

102.0%

Perfluoropentanoic Acid (PFPeA)

2706-90-3

31.05

0

32.89

105.9%

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

31.05

0

33.06

106.5%

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

31.05

0

32.25

103.9%

Perfluoroundecanoic Acid (PFUnA)

2058-94-8

31.05

0

33.11

106.6%

Samples Associated with this LCS (LFSM):

Client Sample ID

Lab Sample ID

Analyzed

Lab File

23041906-21A MS

23041906-21A MS

5/5/2023

215318a

23041906-21A MSD

23041906-21A MSD

5/5/2023

215318a

MBLK-215318-215318a

MBLK-215318

5/5/2023

215318a

LCS-WI-215318-215318a

LCS-WI-215318

5/5/2023

215318a

MW-108-230420

23041906-21A

5/5/2023

215318a









































































37

-------


ICF International LLC
EPA Region 5 ESAT

^1C F	MATRIX SPIKE DUPLICATE! LFSMD) SUMMARY

SDG/Lab Work Order Number: 23041906

Parent Sample 23041906-09A MS	Date analyzed: 4/26/2023

Parent Sample: MW-7-230419	Date Prepared: 4/25/2023
MSD or LCSD MSD Batch ID: 214976a

Ansiyte Name

Abbreviation

Sampie
Amount
(ppt)

Spike %
Rec

MSD %
Rec

RPD

llCl-Pf30UdS

763051-92-9

0

92%

85%

8.23

4,8-Dioxa-BH-perfluorononanoic Acid (DONA)

919005-14-4

0

93%

92%

1.69

9CI-PF30NS

756426-58-1

0

96%

95%

0.83

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

0

116%

111%

4.18

Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

757124-72-4

0

99%

101%

2.44

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

0

105%

103%

1.76

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

0

104%

113%

7.95

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

0

98%

90%

9.54

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

0

95%

95%

0.76

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

0

104%

102%

2.14

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

0

91%

96%

4.79

N-methylperfluoro-l-octanesulfonamide

31506-32-8

0

98%

105%

6.92

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

0

96%

100%

3.77

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

0

97%

98%

0.97

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

0

92%

89%

3.47

Perfluorobutanoic Acid (PFBA)

375-22-4

0

97%

96%

1.86

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

0

92%

87%

6.25

Perfluorodecanoic Acid (PFDA)

335-76-2

0

99%

103%

4.01

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

0

89%

88%

2.25

Perfluorododecanoic Acid (PFDoA)

307-55-1

0

98%

100%

1.25

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

0

95%

86%

9.87

Perfluoroheptanoic Acid (PFHpA)

375-85-9

0

104%

103%

1.00

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

0

128%

130%

1.42

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

0

92%

86%

6.80

Perfluorohexanoic Acid (PFHxA)

307-24-4

0

104%

103%

0.75

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

0

96%

90%

7.30

Perfluorononanoic Acid (PFNA)

375-95-1

0

99%

97%

1.36

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

0

122%

124%

1.91

Perfluorooctanesulfonamide (PFOSA)

754-91-6

0

89%

92%

2.59

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

2.3

89%

90%

0.04

Perfluorooctanoic Acid (PFOA)

335-67-1

0

92%

90%

1.21

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

0

97%

85%

13.97

Perfluoropentanoic Acid (PFPeA)

2706-90-3

0

89%

91%

2.08

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

0

84%

85%

0.75

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

0

90%

91%

1.46

Perfluoroundecanoic Acid (PFUnA)

2058-94-8

0

106%

110%

4.08

Samples Associated with this Duplicate:

Client Sample ID

Lab Sample ID

Analyzed

QA Batch

MBLK-214976-214976a

MBLK-214976

4/26/2023

214976a

LCS-WI-214976-214976a

LCS-WI-214976

4/26/2023

214976a

23041906-09A MS

23041906-09A MS

4/26/2023

214976a

23041906-09A MSD

23041906-09A MSD

4/26/2023

214976a

MW-7-230419

23041906-09A

4/26/2023

214976a

W-l-230418

23041906-01A

4/27/2023

214976a

W-1A-230418

23041906-02A

4/27/2023

214976a

















38

-------


ICF International LLC
EPA Region 5 ESAT

^1C F	MATRIX SPIKE DUPLICATE! LFSMD) SUMMARY

SDG/Lab Work Order Number: 23041906

Parent Sample 23041906-14A MS	Date analyzed: 5/4/2023

Parent Sample ID: MW-10-230420	Date Prepared: 4/26/2023
MSD or LCSD MSD Batch ID: 215053a

Anaiyte Name

Abbreviation

Sampie
Amount
(ppt)

Spike
Recovery

Spike DUP
Recovery

RPD

llCl-Pf30UdS

763051-92-9

0

91%

85%

6.82

4,8-Dioxa-BH-perfluorononanoic Acid (DONA)

919005-14-4

0

67%

62%

8.46

9CI-PF30NS

756426-58-1

0

95%

89%

6.91

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

0

97%

91%

6.63

Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

757124-72-4

0

92%

87%

6.49

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

0

100%

89%

11.16

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

0

116%

94%

20.92

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

0

112%

107%

4.67

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

0

103%

96%

7.34

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

0

100%

96%

4.09

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

0

99%

86%

13.62

N-methylperfluoro-l-octanesulfonamide

31506-32-8

0

102%

101%

1.02

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

0

105%

106%

1.02

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

0

114%

110%

3.40

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

8.3

94%

84%

11.32

Perfluorobutanoic Acid (PFBA)

375-22-4

19

62%

74%

18.20

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

0

90%

78%

14.83

Perfluorodecanoic Acid (PFDA)

335-76-2

0

103%

96%

7.24

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

0

78%

78%

0.40

Perfluorododecanoic Acid (PFDoA)

307-55-1

0

91%

85%

7.12

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

0.64

86%

79%

8.25

Perfluoroheptanoic Acid (PFHpA)

375-85-9

9.7

96%

89%

7.71

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

0

98%

91%

7.91

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

2.2

90%

97%

7.16

Perfluorohexanoic Acid (PFHxA)

307-24-4

14

93%

81%

13.99

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

0

92%

81%

13.44

Perfluorononanoic Acid (PFNA)

375-95-1

0

84%

79%

6.08

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

0

105%

96%

8.93

Perfluorooctanesulfonamide (PFOSA)

754-91-6

0

96%

85%

12.38

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

34

91%

79%

14.47

Perfluorooctanoic Acid (PFOA)

335-67-1

31

87%

70%

21.86

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

1.3

98%

87%

11.97

Perfluoropentanoic Acid (PFPeA)

2706-90-3

16

103%

90%

12.57

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

0

102%

99%

2.88

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

0

112%

101%

10.08

Perfluoroundecanoic Acid (PFUnA)

2058-94-8

0

97.9%

90.6%

7.78

Samples Associated with this Duplicate:

Client Sample ID

Lab Sample ID

Analyzed

QA Batch

MBLK-215053-215053a

MBLK-215053

4/26/2023

215053a

LCS-WI-215053-215053a

LCS-WI-215053

4/26/2023

215053a

MW-10-230420

23041906-14A

4/27/2023

215053a

MW-2-230418

23041906-03A

4/27/2023

215053a

MW-3R-230418

23041906-04A

4/27/2023

215053a

MW-5-230419

23041906-05A

4/27/2023

215053a

MW-5A-230420

23041906-06A

4/27/2023

215053a

MW-6-230418

23041906-07A

4/27/2023

215053a

MW-6A-230418

23041906-08A

4/27/2023

215053a

39

-------


ICF International LLC
EPA Region 5 ESAT

^1C F	MATRIX SPIKE DUPLICATE! LFSMD) SUMMARY

SDG/Lab Work Order Number: 23041906

Parent Sample 23041906-21A MS	Date analyzed: 5/4-5/5/2023

Parent Samlpe ID: MW-108-230420	Date Prepared: 5/1/2023
MSD or LCSD MSD Batch ID: 215318a

Anaiyte Name

Abbreviation

Sampie
Amount
(ppt)

Spike
Recovery

Spike DUP
Recovery

RPD

llCl-Pf30UdS

763051-92-9

0

97%

93%

3.70

4,8-Dioxa-BH-perfluorononanoic Acid (DONA)

919005-14-4

0

89%

87%

2.20

9CI-PF30NS

756426-58-1

0

103%

102%

0.92

Fluorotelomer Sulphonic Acid 10:2 (FtS 10:2)

120226-60-0

0

216%

148%

37.30

Fluorotelomer Sulphonic Acid 4:2 (FtS 4:2)

757124-72-4

0

110%

113%

2.88

Fluorotelomer Sulphonic Acid 6:2 (FtS 6:2)

27619-97-2

0

118%

106%

10.45

Fluorotelomer Sulphonic Acid 8:2 (FtS 8:2)

39108-34-4

0

112%

109%

3.15

Hexafluoropropylene oxide dimer acid (HFPO-DA)

13252-13-6

0

110%

108%

2.14

N-ethylperfluoro-l-octanesulfonamide

4151-50-2

0

118%

113%

3.98

N-Ethylperfluorooctanesulfonamidoacetic Acid

2991-50-6

0

106%

103%

2.98

N-Ethylperfluorooctanesulfonamidoethanol

1691-99-2

0

107%

103%

3.53

N-methylperfluoro-l-octanesulfonamide

31506-32-8

0

111%

106%

4.36

N-Methylperfluorooctanesulfonamidoacetic Acid

2355-31-9

0

114%

109%

4.15

N-Methylperfluorooctanesulfonamidoethanol

24448-09-7

0

141%

106%

28.09

Perfluorobutanesulfonic Acid (PFBS)

375-73-5

0.53

105%

132%

22.39

Perfluorobutanoic Acid (PFBA)

375-22-4

6.1

97%

104%

7.16

Perfluorodecanesulfonic Acid (PFDS)

335-77-3

0

93%

86%

8.23

Perfluorodecanoic Acid (PFDA)

335-76-2

0

104%

100%

3.45

Perfluorododecanesulfonic Acid (PFDoS)

79780-39-5

0

89%

86%

2.89

Perfluorododecanoic Acid (PFDoA)

307-55-1

0

101%

98%

2.86

Perfluoroheptanesulfonic Acid (PFHpS)

375-92-8

0

98%

97%

1.10

Perfluoroheptanoic Acid (PFHpA)

375-85-9

0

117%

113%

3.45

Perfluorohexadecanoic Acid (PFHxDA)

67905-19-5

0

121%

132%

8.30

Perfluorohexanesulfonic Acid (PFHxS)

355-46-4

0

102%

91%

11.09

Perfluorohexanoic Acid (PFHxA)

307-24-4

0

108%

105%

2.83

Perfluorononanesulfonic Acid (PFNS)

68259-12-1

0

99%

96%

3.73

Perfluorononanoic Acid (PFNA)

375-95-1

0

98%

102%

3.80

Perfluorooctadecanoic Acid (PFODA)

16517-11-6

0

114%

116%

1.84

Perfluorooctanesulfonamide (PFOSA)

754-91-6

0

106%

95%

11.08

Perfluorooctanesulfonic Acid (PFOS)

1763-23-1

0

101%

100%

1.24

Perfluorooctanoic Acid (PFOA)

335-67-1

0

99%

96%

2.81

Perfluoropentanesulfonic Acid (PFPeS)

2706-91-4

0

102%

99%

2.91

Perfluoropentanoic Acid (PFPeA)

2706-90-3

0

106%

103%

2.80

Perfluorotetradecanoic Acid (PFTeA)

376-06-7

0

106%

128%

18.36

Perfluorotridecanoic Acid (PFTriA)

72629-94-8

0

104%

100%

3.89

Perfluoroundecanoic Acid (PFUnA)

2058-94-8

0

107%

105%

1.54

Samples Associated with this Duplicate:

Client Sample ID

Lab Sample ID

Analyzed

Lab File

23041906-21A MS

23041906-21A MS

5/5/2023

215318a

23041906-21A MSD

23041906-21A MSD

5/5/2023

215318a

MBLK-215318-215318a

MBLK-215318

5/5/2023

215318a

LCS-WI-215318-215318a

LCS-WI-215318

5/5/2023

215318a

MW-108-230420

23041906-21A

5/5/2023

215318a

































40

-------
10/24/2023 2:01:18 PM Page 1 / 3

==== Shimadzu LabSolutions Batch Table====

[General]

Start from Continuing Row
[Folder]

Use Current Folder
[Data Filename]

Not Create filename
[ASCII Conversion]

Not Output ASCII Files
[File Conversion]

Not Convert
[QA/QC]

Not Execute QA/QC
[Option Item]

Option 1 Title:

Option 2 Title:

Option 3 Title:

Option 4 Title:

Option 5 Title:

Option 6 Title:

Option 7 Title:

Option 8 Title:

Option 9 Title:

Option 10 Title:

[Bracket]

None
[Startup]

Startup Off
[Shutdown]

Shutdown On
Cool down Time:0min
Degassing Unit Off
LC Pump Off
Column Oven Off
[Comment]

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230425001.led

0

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230425002.led

0

5\System\DEFAULT.Isr

3

L0.05ppb_230323

L0.05ppb_230323

1:Standard:(l)

CMS1 230328 537M.lcm

230425003.led

1

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

1:Standard

CMS1 230328 537M.lcm

230425004.led

2

5\System\DEFAULT.Isr

5

L0.5ppb_230323

L0.5ppb_230323

1:Standard

CMS1 230328 537M.lcm

230425005.led

3

5\System\DEFAULT.Isr

6

L1ppb_230323

L1ppb_230323

1:Standard

CMS1 230328 537M.lcm

230425006.led

4

5\System\DEFAULT.Isr

7

L5ppb_230323

L5ppb_230323

1:Standard

CMS1 230328 537M.lcm

230425007.led

5

5\System\DEFAULT.Isr

8

L10ppb_230323

L10ppb_230323

1:Standard

CMS1 230328 537M.lcm

230425008.led

6

5\System\DEFAULT.Isr

9

L15ppb_230323

L15ppb_230323

1:Standard

CMS1 230328 537M.lcm

230425009.led

7

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230425010.lcd

0

5\System\DEFAULT.Isr

41

Z:\LabSolutions\Data\LCMS1-230425\LCMS1-230425A-537MOD.Icb

-------
10/24/2023 2:01:18 PM Page 2 / 3

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

10

Branched Mix 230117

Branched Mix 230117

3:Unspiked

CMS1 230328 537M.lcm

230425011.led

0

5\System\DEFAULT.Isr

11

ICV1-230425

ICV1-230425

2:Control

CMS1 230328 537M.lcm

230425012.led

4

5\System\DEFAULT.Isr

1

MBLK-214898

MBLK-214898

0:Unknown

CMS1 230328 537M.lcm

230425013.lcd

0

5\System\DEFAULT.Isr

2

LCS-214898

LCS-214898

0:Unknown

CMS1 230328 537M.lcm

230425014.led

0

5\System\DEFAULT.Isr

26

MBLK-214898

MBLK-214898

0:Unknown

CMS1 230328 537M.lcm

230425015.lcd

0

5\System\DEFAULT.Isr

27

LCS-214898

LCS-214898

0:Unknown

CMS1 230328 537M.lcm

230425016.led

0

5\System\DEFAULT.Isr

45

23041621-01G

23041621-01G

0:Unknown

CMS1 230328 537M.lcm

230425017.led

0

5\System\DEFAULT.Isr

3

23041195-09A MS

23041195-09A MS

0:Unknown

CMS1 230328 537M.lcm

230425018.lcd

0

5\System\DEFAULT.Isr

4

23041195-09AMSD

23041195-09AMSD

0:Unknown

CMS1 230328 537M.lcm

230425019.lcd

0

5\System\DEFAULT.Isr

5

23041624-26A

23041624-26A

0:Unknown

CMS1 230328 537M.lcm

230425020.led

0

5\System\DEFAULT.Isr

6

23041624-29A

23041624-29A

0:Unknown

CMS1 230328 537M.lcm

230425021.led

0

5\System\DEFAULT.Isr

7

23041624-30A

23041624-30A

0:Unknown

CMS1 230328 537M.lcm

230425022.led

0

5\System\DEFAULT.Isr

16

CCV2-230425

CCV2-230425

2:Control

CMS1 230328 537M.lcm

230425023.led

5

5\System\DEFAULT.Isr

10

23041844-03A

23041844-03A

0:Unknown

CMS1 230328 537M.lcm

230425024.led

0

5\System\DEFAULT.Isr

11

23041844-04A

23041844-04A

0:Unknown

CMS1 230328 537M.lcm

230425025.led

0

5\System\DEFAULT.Isr

12

23041844-05A

23041844-05A

0:Unknown

CMS1 230328 537M.lcm

230425026.led

0

5\System\DEFAULT.Isr

13

23041844-06A

23041844-06A

0:Unknown

CMS1 230328 537M.lcm

230425027.led

0

5\System\DEFAULT.Isr

14

23041844-07A

23041844-07A

0:Unknown

CMS1 230328 537M.lcm

230425028.led

0

5\System\DEFAULT.Isr

15

23041844-11A

23041844-11A

0:Unknown

CMS1 230328 537M.lcm

230425029.led

0

5\System\DEFAULT.Isr

16

23041844-12A

23041844-12A

0:Unknown

CMS1 230328 537M.lcm

230425030.led

0

5\System\DEFAULT.Isr

17

23041844-13A

23041844-13A

0:Unknown

CMS1 230328 537M.lcm

230425031.led

0

5\System\DEFAULT.Isr

18

23041844-14A

23041844-14A

0:Unknown

CMS1 230328 537M.lcm

230425032.led

0

5\System\DEFAULT.Isr

19

23041844-15A

23041844-15A

0:Unknown

CMS1 230328 537M.lcm

230425033.led

0

5\System\DEFAULT.Isr

16

CCV3-230425

CCV3-230425

2:Control

CMS1 230328 537M.lcm

230425034.led

5

5\System\DEFAULT.Isr

20

23041844-16A

23041844-16A

0:Unknown

CMS1 230328 537M.lcm

230425035.led

0

5\System\DEFAULT.Isr

21

23041844-17A

23041844-17A

0:Unknown

CMS1 230328 537M.lcm

230425036.led

0

5\System\DEFAULT.Isr

22

23041844-18A

23041844-18A

0:Unknown

CMS1 230328 537M.lcm

230425037.led

0

5\System\DEFAULT.Isr

23

23041844-19A

23041844-19A

0:Unknown

CMS1 230328 537M.lcm

230425038.led

0

5\System\DEFAULT.Isr

24

23041844-20A

23041844-20A

0:Unknown

CMS1 230328 537M.lcm

230425039.led

0

5\System\DEFAULT.Isr

30

23041183-03A MS

23041183-03A MS

0:Unknown

CMS1 230328 537M.lcm

230425040.led

0

5\System\DEFAULT.Isr

31

23041183-03AMSD

23041183-03AMSD

0:Unknown

CMS1 230328 537M.lcm

230425041.led

0

5\System\DEFAULT.Isr

32

23041623-14A

23041623-14A

0:Unknown

CMS1 230328 537M.lcm

230425042.led

0

5\System\DEFAULT.Isr

33

23041623-15A

23041623-15A

0:Unknown

CMS1 230328 537M.lcm

230425043.led

0

5\System\DEFAULT.Isr

34

23041623-16A

23041623-16A

0:Unknown

CMS1 230328 537M.lcm

230425044.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230425045.led

2

5\System\DEFAULT.Isr

16

CCV4-230425

CCV4-230425

2:Control

CMS1 230328 537M.lcm

230425046.led

5

5\System\DEFAULT.Isr

16

CCV4-230425

CCV4-230425

2:Control

CMS1 230328 537M.lcm

230425047.led

5

5\System\DEFAULT.Isr

35

23041623-17A

23041623-17A

0:Unknown

CMS1 230328 537M.lcm

230425048.led

0

5\System\DEFAULT.Isr

36

23041623-18A

23041623-18A

0:Unknown

CMS1 230328 537M.lcm

230425049.led

0

5\System\DEFAULT.Isr

37

23041623-19A

23041623-19A

0:Unknown

CMS1 230328 537M.lcm

230425050.led

0

5\System\DEFAULT.Isr

38

23041623-20A

23041623-20A

0:Unknown

CMS1 230328 537M.lcm

230425051.led

0

5\System\DEFAULT.Isr

42

Z:\LabSolutions\Data\LCMS1-230425\LCMS1-230425A-537MOD.Icb

-------
10/24/2023 2:01:18 PM Page 3 / 3

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

39

23041623-21A

23041623-21A

0:Unknown

CMS1 230328 537M.lcm

230425052.led

0

5\System\DEFAULT.Isr

40

23041623-22A

23041623-22A

0:Unknown

CMS1 230328 537M.lcm

230425053.led

0

5\System\DEFAULT.Isr

41

23041623-23A

23041623-23A

0:Unknown

CMS1 230328 537M.lcm

230425054.led

0

5\System\DEFAULT.Isr

42

23041623-24A

23041623-24A

0:Unknown

CMS1 230328 537M.lcm

230425055.led

0

5\System\DEFAULT.Isr

43

23041624-02E

23041624-02E

0:Unknown

CMS1 230328 537M.lcm

230425056.led

0

5\System\DEFAULT.Isr

44

23041624-06E

23041624-06E

0:Unknown

CMS1 230328 537M.lcm

230425057.led

0

5\System\DEFAULT.Isr

45

23041624-08E

23041624-08E

0:Unknown

CMS1 230328 537M.lcm

230425058.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230425059.led

2

5\System\DEFAULT.Isr

16

CCV5-230425

CCV5-230425

2:Control

CMS1 230328 537M.lcm

230425060.led

5

5\System\DEFAULT.Isr

16

CCV5-230425

CCV5-230425

2:Control

CMS1 230328 537M.lcm

230425061.led

5

5\System\DEFAULT.Isr

46

23041624-09E

23041624-09E

0:Unknown

CMS1 230328 537M.lcm

230425062.led

0

5\System\DEFAULT.Isr

47

23041624-11E

23041624-11E

0:Unknown

CMS1 230328 537M.lcm

230425063.led

0

5\System\DEFAULT.Isr

48

23041624-13A

23041624-13A

2:Control

CMS1 230328 537M.lcm

230425064.led

5

5\System\DEFAULT.Isr

49

23041624-17A

23041624-17A

2:Control

CMS1 230328 537M.lcm

230425065.led

5

5\System\DEFAULT.Isr

50

23041624-21A

23041624-21A

2:Control

CMS1 230328 537M.lcm

230425066.led

5

5\System\DEFAULT.Isr

51

23041817-03A

23041817-03A

2:Control

CMS1 230328 537M.lcm

230425067.led

5

5\System\DEFAULT.Isr

26

MBLK-214898

MBLK-214898

0:Unknown

CMS1 230328 537M.lcm

230425068.led

0

5\System\DEFAULT.Isr

27

LCS-214898

LCS-214898

0:Unknown

CMS1 230328 537M.lcm

230425069.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230425070.led

2

5\System\DEFAULT.Isr

16

CCV6-230425

CCV6-230425

2:Control

CMS1 230328 537M.lcm

230425071.led

5

5\System\DEFAULT.Isr

16

CCV6-230425

CCV6-230425

2:Control

CMS1 230328 537M.lcm

230425072.led

5

5\System\DEFAULT.Isr

1

MEOH

MEOH

0:Unknown

CMS1 230328 537M.lcm

230425073.led

0

5\System\DEFAULT.Isr

1

MEOH

MEOH

0:Unknown

CMS1 230328 537M.lcm

230425074.led

0

5\System\DEFAULT.Isr

43

Z:\LabSolutions\Data\LCMS1-230425\LCMS1-230425A-537MOD.Icb

-------
10/24/2023 2:44:39 PM Page 1 / 3

==== Shimadzu LabSolutions Batch Table====

[General]

Start from Continuing Row
[Folder]

Use Current Folder
[Data Filename]

Not Create filename
[ASCII Conversion]

Not Output ASCII Files
[File Conversion]

Not Convert
[QA/QC]

Not Execute QA/QC
[Option Item]

Option 1 Title:

Option 2 Title:

Option 3 Title:

Option 4 Title:

Option 5 Title:

Option 6 Title:

Option 7 Title:

Option 8 Title:

Option 9 Title:

Option 10 Title:

[Bracket]

None
[Startup]

Startup Off
[Shutdown]

Shutdown On
Cool down Time:0min
Degassing Unit Off
LC Pump Off
Column Oven Off
[Comment]

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230426001.led

0

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230426002.led

0

5\System\DEFAULT.Isr

3

LLCCV1-230426

LLCCV1-230426

1:Standard:(l)

CMS1 230328 537M.lcm

230426003.led

1

5\System\DEFAULT.Isr

4

CCV1-230426-WI

CCV1-230426-WI

1:Standard

CMS1 230328 537M.lcm

230426004.led

2

5\System\DEFAULT.Isr

11

CCV1-230426

CCV1-230426

2:Control

CMS1 230328 537M.lcm

230426005.led

4

5\System\DEFAULT.Isr

11

CCV1-230426

CCV1-230426

2:Control

CMS1 230328 537M.lcm

230426006.led

4

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230426007.led

0

5\System\DEFAULT.Isr

28

MBLK-214976

MBLK-214976

0:Unknown

CMS1 230328 537M.lcm

230426008.led

0

5\System\DEFAULT.Isr

29

LCS-WI-214976

LCS-WI-214976

0:Unknown

CMS1 230328 537M.lcm

230426009.led

0

5\System\DEFAULT.Isr

30

LCS-214976

LCS-214976

0:Unknown

CMS1 230328 537M.lcm

230426010.lcd

0

5\System\DEFAULT.Isr

44

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD.Icb

-------
10/24/2023 2:44:39 PM Page 2 / 3

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

1

MBLK-215053

MBLK-215053

0:Unknown

CMS1 230328 537M.lcm

230426011.led

0

5\System\DEFAULT.Isr

2

LCS-WI-215053

LCS-WI-215053

0:Unknown

CMS1 230328 537M.lcm

230426012.led

0

5\System\DEFAULT.Isr

3

LCS-215053

LCS-215053

0:Unknown

CMS1 230328 537M.lcm

230426013.lcd

0

5\System\DEFAULT.Isr

31

23041906-09A MS

23041906-09A MS

0:Unknown

CMS1 230328 537M.lcm

230426014.led

0

5\System\DEFAULT.Isr

32

23041906-09AMSD

23041906-09AMSD

0:Unknown

CMS1 230328 537M.lcm

230426015.lcd

0

5\System\DEFAULT.Isr

33

23041906-09A

23041906-09A

0:Unknown

CMS1 230328 537M.lcm

230426016.led

0

5\System\DEFAULT.Isr

34

23041844-08A

23041844-08A

0:Unknown

CMS1 230328 537M.lcm

230426017.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230426018.lcd

2

5\System\DEFAULT.Isr

16

CCV2-230426

CCV2-230426

2:Control

CMS1 230328 537M.lcm

230426019.lcd

5

5\System\DEFAULT.Isr

16

CCV2-230426

CCV2-230426

2:Control

CMS1 230328 537M.lcm

230426020.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230426021.led

0

5\System\DEFAULT.Isr

35

23041844-09A

23041844-09A

0:Unknown

CMS1 230328 537M.lcm

230426022.led

0

5\System\DEFAULT.Isr

36

23041844-1 OA

23041844-1 OA

0:Unknown

CMS1 230328 537M.lcm

230426023.led

0

5\System\DEFAULT.Isr

37

23041906-01A

23041906-01A

0:Unknown

CMS1 230328 537M.lcm

230426024.led

0

5\System\DEFAULT.Isr

38

23041906-02A

23041906-02A

0:Unknown

CMS1 230328 537M.lcm

230426025.led

0

5\System\DEFAULT.Isr

39

23041929-01A

23041929-01A

0:Unknown

CMS1 230328 537M.lcm

230426026.led

0

5\System\DEFAULT.Isr

40

23041930-02D

23041930-02D

0:Unknown

CMS1 230328 537M.lcm

230426027.led

0

5\System\DEFAULT.Isr

41

23041931-02D

23041931-02D

0:Unknown

CMS1 230328 537M.lcm

230426028.led

0

5\System\DEFAULT.Isr

42

23041933-02A

23041933-02A

0:Unknown

CMS1 230328 537M.lcm

230426029.led

0

5\System\DEFAULT.Isr

43

23041934-02D

23041934-02D

0:Unknown

CMS1 230328 537M.lcm

230426030.led

0

5\System\DEFAULT.Isr

44

23041944-01F

23041944-01F

0:Unknown

CMS1 230328 537M.lcm

230426031.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230426032.led

2

5\System\DEFAULT.Isr

16

CCV3-230426

CCV3-230426

2:Control

CMS1 230328 537M.lcm

230426033.led

5

5\System\DEFAULT.Isr

16

CCV3-230426

CCV3-230426

2:Control

CMS1 230328 537M.lcm

230426034.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230426035.led

0

5\System\DEFAULT.Isr

45

23041944-02F

23041944-02F

0:Unknown

CMS1 230328 537M.lcm

230426036.led

0

5\System\DEFAULT.Isr

46

23041959-01A

23041959-01A

0:Unknown

CMS1 230328 537M.lcm

230426037.led

0

5\System\DEFAULT.Isr

47

23041959-02A

23041959-02A

0:Unknown

CMS1 230328 537M.lcm

230426038.led

0

5\System\DEFAULT.Isr

48

23041959-04A

23041959-04A

0:Unknown

CMS1 230328 537M.lcm

230426039.led

0

5\System\DEFAULT.Isr

49

23041959-05A

23041959-05A

0:Unknown

CMS1 230328 537M.lcm

230426040.led

0

5\System\DEFAULT.Isr

50

23041959-06A

23041959-06A

0:Unknown

CMS1 230328 537M.lcm

230426041.led

0

5\System\DEFAULT.Isr

4

23041906-14AMS

23041906-14AMS

0:Unknown

CMS1 230328 537M.lcm

230426042.led

0

5\System\DEFAULT.Isr

5

23041906-14AMSD

23041906-14AMSD

0:Unknown

CMS1 230328 537M.lcm

230426043.led

0

5\System\DEFAULT.Isr

6

23041906-14A

23041906-14A

0:Unknown

CMS1 230328 537M.lcm

230426044.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230426045.led

2

5\System\DEFAULT.Isr

16

CCV4-230426

CCV4-230426

2:Control

CMS1 230328 537M.lcm

230426046.led

5

5\System\DEFAULT.Isr

16

CCV4-230426

CCV4-230426

2:Control

CMS1 230328 537M.lcm

230426047.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230426048.led

0

5\System\DEFAULT.Isr

7

23042004-01A

23042004-01A

0:Unknown

CMS1 230328 537M.lcm

230426049.led

0

5\System\DEFAULT.Isr

8

23041906-03A

23041906-03A

0:Unknown

CMS1 230328 537M.lcm

230426050.led

0

5\System\DEFAULT.Isr

9

23041906-04A

23041906-04A

0:Unknown

CMS1 230328 537M.lcm

230426051.led

0

5\System\DEFAULT.Isr

45

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD.Icb

-------
10/24/2023 2:44:39 PM Page 3 / 3

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

10

23041906-05A

23041906-05A

0:Unknown

CMS1 230328 537M.lcm

230426052.led

0

5\System\DEFAULT.Isr

11

23041906-06A

23041906-06A

0:Unknown

CMS1 230328 537M.lcm

230426053.led

0

5\System\DEFAULT.Isr

12

23041906-07A

23041906-07A

0:Unknown

CMS1 230328 537M.lcm

230426054.led

0

5\System\DEFAULT.Isr

13

23041906-08A

23041906-08A

0:Unknown

CMS1 230328 537M.lcm

230426055.led

0

5\System\DEFAULT.Isr

14

23041906-1 OA

23041906-1 OA

0:Unknown

CMS1 230328 537M.lcm

230426056.led

0

5\System\DEFAULT.Isr

15

23041906-11A

23041906-11A

0:Unknown

CMS1 230328 537M.lcm

230426057.led

0

5\System\DEFAULT.Isr

16

23041906-12A

23041906-12A

0:Unknown

CMS1 230328 537M.lcm

230426058.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230426059.led

2

5\System\DEFAULT.Isr

16

CCV5-230426

CCV5-230426

2:Control

CMS1 230328 537M.lcm

230426060.led

5

5\System\DEFAULT.Isr

16

CCV5-230426

CCV5-230426

2:Control

CMS1 230328 537M.lcm

230426061.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230426062.led

0

5\System\DEFAULT.Isr

17

23041906-13A

23041906-13A

0:Unknown

CMS1 230328 537M.lcm

230426063.led

0

5\System\DEFAULT.Isr

18

23041906-15A

23041906-15A

0:Unknown

CMS1 230328 537M.lcm

230426064.led

0

5\System\DEFAULT.Isr

19

23041906-16A

23041906-16A

0:Unknown

CMS1 230328 537M.lcm

230426065.led

0

5\System\DEFAULT.Isr

20

23041906-17A

23041906-17A

0:Unknown

CMS1 230328 537M.lcm

230426066.led

0

5\System\DEFAULT.Isr

21

23041906-18A

23041906-18A

0:Unknown

CMS1 230328 537M.lcm

230426067.led

0

5\System\DEFAULT.Isr

22

23041906-19A

23041906-19A

0:Unknown

CMS1 230328 537M.lcm

230426068.led

0

5\System\DEFAULT.Isr

23

23041959-03A

23041959-03A

0:Unknown

CMS1 230328 537M.lcm

230426069.led

0

5\System\DEFAULT.Isr

24

23041240-43A

23041240-43A

0:Unknown

CMS1 230328 537M.lcm

230426070.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230426071.led

2

5\System\DEFAULT.Isr

16

CCV6-230426

CCV6-230426

2:Control

CMS1 230328 537M.lcm

230426072.led

5

5\System\DEFAULT.Isr

16

CCV6-230426

CCV6-230426

2:Control

CMS1 230328 537M.lcm

230426073.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230426074.led

0

5\System\DEFAULT.Isr

25

23041240-43ADF10

23041240-43ADF10

0:Unknown

CMS1 230328 537M.lcm

230426075.led

0

5\System\DEFAULT.Isr

3

LCS-215053

LCS-215053

0:Unknown

CMS1 230328 537M.lcm

230426076.led

0

5\System\DEFAULT.Isr

4

23041906-14AMS

23041906-14AMS

0:Unknown

CMS1 230328 537M.lcm

230426077.led

0

5\System\DEFAULT.Isr

5

23041906-14AMSD

23041906-14AMSD

0:Unknown

CMS1 230328 537M.lcm

230426078.led

0

5\System\DEFAULT.Isr

6

23041906-14A

23041906-14A

0:Unknown

CMS1 230328 537M.lcm

230426079.led

0

5\System\DEFAULT.Isr

8

23041906-03A

23041906-03A

0:Unknown

CMS1 230328 537M.lcm

230426080.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230426081.led

2

5\System\DEFAULT.Isr

16

CCV7-230426

CCV7-230426

2:Control

CMS1 230328 537M.lcm

230426082.led

5

5\System\DEFAULT.Isr

16

CCV7-230426

CCV7-230426

2:Control

CMS1 230328 537M.lcm

230426083.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230426084.led

0

5\System\DEFAULT.Isr

46

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD.Icb

-------
Insight Report
Quantitation/lntegration
Printed 11/8/2023 12:21:56

CCV1 -230426-WI

Sample ID:CCV1-230426-WI

Date Acquired: 4/26/2023 7:27:04 PM

Acquired by: System Administrator

Data File: 230426004

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.206

850649

850649

—

5.0000

5.0000

nq/ml

13C-PFBA

Auto

4.206

850649

2772874

13C7-PFUnDA IS

5.0000

4.8852

nq/mL

PFBA

Auto

4.206

17974

850649

13C-PFBA IS

0.1000

0.0932

nq/ml

13C-PFPeA IS

Auto

5.372

1361516

1361516

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.372

1361516

2772874

13C7-PFUnDA IS

5.0000

4.7559

nq/ml

PFPeA

Auto

5.372

26270

1361516

13C-PFPeA IS

0.1000

0.0989

nq/mL

13C-PFBS IS

Auto

5.502

512690

512690

	

4.6500

4.6500

nq/ml

13C-PFBS

Auto

5.502

512690

2772874

13C7-PFUnDA IS

4.6500

4.3637

nq/mL

PFBS

Auto

5.502

7232

512690

13C-PFBS IS

0.0880

0.0859

nq/ml

13C HFPO DA IS

Auto

6.106

254456

254456

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.106

254456

2772874

13C7-PFUnDA IS

5.0000

4.2729

nq/ml

HFPO DA

Auto

6.104

4236

254456

13C HFPO DA IS

0.1000

0.1051

nq/mL

13C-4 2-FTS IS

Auto

5.906

196794

196794

	

4.6700

4.6700

nq/ml

13C-4 2-FTS

Auto

5.906

196794

2772874

13C7-PFUnDA IS

4.6700

3.5250

nq/mL

4-2-FtS

Auto

5.905

4521

196794

13C-4 2-FTS IS

0.0930

0.0920

nq/ml

PFHxA

Auto

5.961

54291

1833784

13C-PFHxA IS

0.1000

0.1130

nq/mL

13C-PFHxA IS

Auto

5.960

1833784

1833784

	

5.0000

5.0000

nq/ml

13C-PFHxA

Auto

5.960

1833784

2772874

13C7-PFUnDA IS

5.0000

4.4588

nq/mL

PFPeS

Auto

6.001

6764

531208

180-PFHxS IS

0.0940

0.0852

nq/ml

PFHxS

Auto

6.371

6657

531208

180-PFHxS IS

0.0910

0.0949

nq/mL

13C-PFHpA IS

Auto

6.367

1897920

1897920

	

5.0000

5.0000

nq/ml

13C-PFHpA

Auto

6.367

1897920

2772874

13C7-PFUnDA IS

5.0000

4.6501

nq/mL

180-PFHxS IS

Auto

6.374

531208

531208

	

4.7250

4.7250

nq/ml

180-PFHxS

Auto

6.374

531208

2772874

13C7-PFUnDA IS

4.7250

4.4695

nq/mL

PFHpA

Auto

6.368

54544

1897920

13C-PFHpA IS

0.1000

0.0966

nq/ml

13C2-6 2-FTS IS

Auto

6.669

371970

371970

	

4.7500

4.7500

nq/mL

13C2-6 2-FTS

Auto

6.669

371970

2772874

13C7-PFUnDA IS

4.7500

3.9298

nq/ml

PFHpS

Auto

6.677

6657

531208

180-PFHxS IS

0.0950

0.0862

nq/mL

6-2-FTS

Auto

6.668

7172

371970

13C2-6 2-FTS IS

0.0950

0.0988

nq/ml

PFOA

Auto

6.686

67204

2694692

13C-PFOA IS

0.1000

0.0903

nq/mL

13C-PFOA IS

Auto

6.686

2694692

2694692

	

5.0000

5.0000

nq/ml

13C-PFOA

Auto

6.686

2694692

2772874

13C7-PFUnDA IS

5.0000

5.0425

nq/mL

PFOS

Auto

6.974

5731

492278

13C-PFOS IS

0.0930

0.1011

nq/ml

13C-PFOS IS

Auto

6.975

492278

492278

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

6.975

492278

2772874

13C7-PFUnDA IS

4.7750

4.2620

nq/ml

PFNA

Auto

6.996

61758

2807017

13C-PFNA IS

0.1000

0.0997

nq/mL

13C-PFNA IS

Auto

6.996

2807017

2807017

	

5.0000

5.0000

nq/ml

13C-PFNA

Auto

6.996

2807017

2772874

13C7-PFUnDA IS

5.0000

4.9987

nq/mL

PFNS

Auto

7.305

11358

492278

13C-PFOS IS

0.0960

0.0912

nq/ml

8-2-FTS

Auto

7.331

5892

256651

13C-8 2-FTS IS

0.0960

0.1137

nq/mL

13C-8 2-FTS IS

Auto

7.329

256651

256651

	

4.7900

4.7900

nq/ml

13C-8 2-FTS

Auto

7.329

256651

2772874

13C7-PFUnDA IS

4.7900

3.8922

nq/mL

PFDA

Auto

7.335

55452

3002953

13C-PFDA IS

0.1000

0.0983

nq/ml

13C-PFDA IS

Auto

7.334

3002953

3002953

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.334

3002953

2772874

13C7-PFUnDA IS

5.0000

4.7124

nq/ml

d3-N-MeFOSAA IS

Auto

7.510

670872

670872

	

5.0000

5.0000

nq/mL

d3-N-MeFOSAA

Auto

7.510

670872

2772874

13C7-PFUnDA IS

5.0000

4.6340

nq/ml

NMeFOSAA

M

7.515

13321

670872

d3-N-MeFOSAA IS

0.1000

0.0991

nq/mL

PFDS

Auto

7.643

7985

492278

13C-PFOS IS

0.0960

0.0967

nq/ml

13C-PFUnDA IS

Auto

7.683

2963782

2963782

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.683

2963782

2772874

13C7-PFUnDA IS

5.0000

4.7416

nq/ml

PFUnDA

Auto

7.682

63164

2963782

13C-PFUnDA IS

0.1000

0.1115

nq/mL

d5-N-EtFOSAA IS

Auto

7.694

767773

767773

	

5.0000

5.0000

nq/ml

d5-N-EtFOSAA

Auto

7.694

767773

2772874

13C7-PFUnDA IS

5.0000

4.7273

nq/mL

NEtFOSAA

Auto

7.702

14164

767773

dS-N-EtFOSAA IS

0.1000

0.1014

nq/ml

PFOSA

Auto

7.755

12736

653737

13C-FOSA IS

0.1000

0.0932

nq/mL

13C-FOSA IS

Auto

7.754

653737

653737

	

5.0000

5.0000

nq/ml

13C-FOSA

Auto

7.754

653737

2772874

13C7-PFUnDA IS

5.0000

4.9354

nq/mL

PFDoA

Auto

8.026

51933

2837880

13C-PFDoA IS

0.1000

0.0965

nq/ml

13C-PFDoA IS

Auto

8.027

2837880

2837880

____

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

47

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Insight Report
Quantitation/lntegration
Printed 11/8/2023 12:21:56

CCV1 -230426-WI (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name



Std. Cone.

Cone.

Unit

13C-PFDoA

Auto

8.027

2837880

2772874

13C7-PFUnDA

IS

5.0000

4.7040

nq/mL

10-2-FtS

Auto

8.040

6184

256651

13C-8 2-FTS IS

0.0960

0.0955

ng/mL

d5-NEtFOSA IS

Auto

8.782

560494

560494

	



5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.782

560494

2772874

13C7-PFUnDA

IS

5.0000

4.6022

ng/mL

NMeFOSE

Auto

8.508

5694

355911

d7-N-MeFOSE

IS

0.1000

0.0882

nq/mL

NEtFOSE

Auto

8.757

15727

231929

d9-EtFOSE IS



0.1000

0.0865

ng/mL

d9-EtFOSE IS

Auto

8.738

231929

231929

	



5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.738

231929

2772874

13C7-PFUnDA

IS

5.0000

4.8001

ng/mL

NMeFOSA

Auto

8.532

4844

535099

d3-NMeFOSA

IS

0.1000

0.1043

nq/mL

d3-NMeFOSA IS

Auto

8.527

535099

535099

	



5.0000

5.0000

ng/mL

d3-NMeFOSA

Auto

8.527

535099

2772874

13C7-PFUnDA

IS

5.0000

4.7624

nq/mL

d7-N-MeFOSE IS

Auto

8.491

355911

355911

	



5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.491

355911

2772874

13C7-PFUnDA

IS

5.0000

5.5069

nq/mL

NEtFOSA

Auto

8.790

7462

560494

d5-NEtFOSA IS

0.1000

0.0913

ng/mL

PFTrDA

Auto

8.353

50715

1677262

13C-PFTeDA IS

0.1000

0.0968

nq/mL

PFTeDA

Auto

8.651

44956

1677262

13C-PFTeDA IS

0.1000

0.0825

ng/mL

13C-PFTeDA IS

Auto

8.651

1677262

1677262

	



5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.651

1677262

2772874

13C7-PFUnDA

IS

5.0000

4.8977

ng/mL

11CI-PF30UdS

Auto

7.835

9300

492278

13C-PFOS IS



0.0940

0.0865

nq/mL

9CI-PF30NS

Auto

7.157

22135

492278

13C-PFOS IS



0.0930

0.0925

ng/mL

L-PFDoS

Auto

8.304

4397

492278

13C-PFOS IS



0.0970

0.1212

nq/mL

NaDONA

Auto

6.412

35251

2807017

13C-PFNA IS



0.0940

0.0803

ng/mL

PFHxDA

Auto

9.178

49443

3675243

13C2-PFHxDA

IS

0.1000

0.1023

nq/mL

PFODA

Auto

9.727

22674

3675243

13C2-PFHxDA

IS

0.1000

0.1136

ng/mL

13C2-PFHxDA IS

Auto

9.178

3675243

3675243

	



5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.178

3675243

2772874

13C7-PFUnDA

IS

5.0000

4.5530

ng/mL

13C7-PFUnDA IS

Auto

7.682

2772874

2772874

	



5.0000

5.0000

nq/mL

PFecHS

Auto

6.637

40922

492278

13C-PFOS IS



0.0920

0.0876

ng/mL

PFBSA

Auto

6.146

30537

653737

13C-FOSA IS



0.1000

0.0953

nq/mL

PFHxSA

Auto

6.971

27697

2807017

13C-PFNA IS



0.1000

0.0940

ng/mL

CHARGE

ND(W/B)

	

	

2772874

13C7-PFUnDA

IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20> 172.30 (-)

13C-PFBA

Cone. 4.8852
Q217.20> 172.30 (-)

fA= 850649
RT=4.206

O.OeO

fA= 850649
RT=4.206

O.OeO

Q263.05>219.10 (-)
1.0e4 —i

1.00e4 ISTD 301.80>80.00 (-)

A= 26270
RT=5.372

A=512690
RT= 5.502

5.6

RT (min)

PFBA

Cone. 0.0932
Q213.20> 169.10 (-)

fA= 17974
RT=4.206

4.00 4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)

PFPeA	13C-PFBS IS

Cone. 0.0989	Cone. 4.6500

O.OeO-

4.00 4.25 4.50

RT (min)

13C-PFBS

Cone. 4.3637

1.99e5 Q 301.80>80.00 (-)

5.4 5.6 5.8
RT (min)

1 3C-PFPeA IS

Cone. 5.0000

ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.7559
Q 267.90>223.00 (-)

f A= 1361516
RT=5.372

O.OeO -

O.OeO -

A= 1361516
RT=5.372

5.2

5.2

5.4 5.6

RT (min)

PFBS

Cone. 0.0859
R#1 298.80>99.00 59.39 (72.97)

1.99e5 Q 299.00>80.00 (-)	2.89e3 ISTD 332.10>287.10 (-) 1.12e5

5.4 5.6

RT (min)

13C HFPO DA IS

Cone. 5.0000

I R1 59.39 (-

A=7232
|-$T= 5.502

A=254456
RT=6.106

5.4 5.6 5.8
RT (min)

5.6 5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

48

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A

Insight Report
Quantitation/lntegration
Printed 11/8/2023 12:21:56

CCV1 -230426-WI (continued)

13C HFPO DA

Cone. 4.2729

Q 332.10>287.10 (-)
1.0e5 -

5.0e4 -

HFPO DA

Cone. 0.1051

R#1 329.00 >285.10 58.63 (68.92)
1.12e5 Q 329.00> 169.00 (-)	2.00e3

y A=254456
RT=6.106

O.OeO -

¥A=4236
-R1 58.63 (-1-^7=6.104

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 0.1130

R#1 313.00> 119.10 2.16 (2.54)
Q 313.00>269.00 (-)	2.43e4

13C-PFHxA IS

Cone. 5.0000

R1 2.16 (—

f A=54291
i)RT= 5.961

ISTD 314.90>270.10 (-)
7.5e5

5.0e5 -
2.5e5 -
O.OeO -

A=1833784
RT=5.960

6.2
RT (min)

13C-PFHpA IS

Cone. 5.0000

13C-PFHpA

Cone. 4.6501

ISTD 366.90>322.10 (-) 8.52

^A= 1897920
RT= 6.367

Q366.90>322.10 (-)

f A= 1897920
RT= 6.367

13C2-6 2-FTS IS

Cone. 4.7500

13C2-6 2-FTS

Cone. 3.9298

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

13C-PFOA

Cone. 5.0425

1.17e6 Q 416.80>372.05 (-)

1 3C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 28.64 (27.58)

ISTD 329.00>309.15 (-) 8.63e4

1 3C-4 2-FTS

Cone. 3.5250

R#1 329.00>81.00 28.64 (27.58)
Q 329.00>309.15 (-)	8.63e4

4-2-FtS

Cone. 0.0920

R#1 327.00>81.10 9.10 (15.16)
Q 327.00>307.05 (-)	2.07e3

7.5e4
5.0e4
2.5e4
O.OeO

R1 28.64 (-

A=196794
f*T=5.906

6.2 6.4
RT (min)

13C-PFHxA

Cone. 4.4588

Q 314.90>270.10 (-)
7.5e5 -
5.0e5 -
2.5e5 -
O.OeO -

6.0 6.2
RT (min)

A=1833784
RT=5.960

2.0e3 H

Y A=4521

_R1 9.10 (— )rt=5.905

O.OeO -

6.0 6.2
RT (min)

PFPeS

Cone. 0.0852

R#1 349.00 >99.00 104.40 (80.87)
Q 349.00>79.95 (-)	2.65e3

f A=6764

]R1 10440 ^=6.001

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.0949

R#1 399.00>99.00 86.40 (92.02)
Q 399.00>80.00 (-)	2.53e3

O.OeO -

1

: R1 86.40 (-¦

' A=6657
i*T=6.371



I

6.2
RT (min)

6.2
RT (min)

6.2

RT (min)

6.2

6.4

180-PFHxS IS

Cone. 4.7250

180-PFHxS

Cone. 4.4695

8.52e5 ISTD 402.70>84.05 (-)

2.43e5 Q 402.70 >84.05 (-)

6.6
RT (min)

PFHpA

Cone. 0.0966

R#1 362.90> 169.00 21.36 (17.74)
Q 362.90>319.00 (-)	2.37e4

O.OeO

O.OeO

- R1 21.36 (-

i A= 54544
1*T=6.368

O.OeO -

6.6

RT (min)

6.2

6.4

6.2

6.6

RT (min)

PFHpS

Cone. 0.0862

R#1 449.00>99.20 56.13 (65.35)

Q 449.00>80.15 (-)	2.99e3 Q 427.00 >407.00 (-)

6.4

6.6
RT (min)

6-2-FTS

Cone. 0.0988

R#1 427.00>80.90 23.14 (27.82)

3.37e3

6.2

6.4

6.6
RT (min)

PFOA

Cone. 0.0903

R#1 413.00> 169.10 27.45 (27.71)
Q 413.00>369.00 (-)	3.09e4

O.OeO -



f A=6657

:R1 56.13 (-J

: I

\-kl=6.677

I .

RT (min)

6.6 6.8

RT (min)

PFOS

Cone. 0.1011
R#1 499.00>99.00 64.57 (96.24)

Q 499.00>80.00 (-)	1.82e3 ISTD 502.

1 3C-PFOS IS

Cone. 4.7750

105 (-)

1.0e6 -



'A=2694692
I RT= 6.686

1.0e6 -



fA=2694692
I RT= 6.686

1.5e3 ^

'

R1 64.57 (--

fA=5731
-kr= 6.974

5.0e5 -



I

5.0e5 -





1.0e3 ^









I





I

5.0e2 -



L

O.OeO -

i

V.

- O.OeO -

i

V,

- O.OeO -

Jv

2.0e5 1

f A=492278
RT= 6.975

Q 502.80>80.05 (-)
2.0e5 1

f A=492278
RT= 6.975

6.8 7.0
RT (min)

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

7.2

RT (min)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

49

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Insight Report
Quantitation/lntegration
Printed 11/8/2023 12:21:56

CCV1 -230426-WI (continued)

PFNA	13C-PFNA IS

Cone. 0.0997	Cone. 5.0000
R#1 463.00 >219.00 15.91 (20.94)

Q463.00>418.90 (-)	2.48e4	ISTD 467.80>423.00 (-)

1 3C-PFNA

Cone. 4.9987

1.15e6 Q 467.80>423.00 (-)

PFNS	8-2-FTS

Cone. 0.0912	Cone. 0.1137

R#1 549.00>99.00 72.15 (65.53)	R#1 527.20>487.00 2.70 (5.33)

1.15e6 Q 549.00>79.95 (-)	4.55e3	Q 527.10>506.90 (-)	1.99e3

A=61758

IR1 15.91 (¦ -r)t=6.996

f A=2807017
RT=6.996

O.OeO -

A=2807017
RT=6.996

O.OeO

- R1 2.70 (-

13C-8 2-FTSJS

Cone. 4.7900

ISTD 528.80> 509.00 (-)

13C-8 2-FTS

Cone. 3.8922

9.76e4 Q 528.80> 509.00 (-)

7.2	6.8 7.0 7.2

RT (min)	RT (min)

PFDA	13C-PFDAJS

Cone. 0.0983	Cone. 5.0000
R#1 512.90>219.00 21.69 (18.19)

9.76e4 Q 512.90>469.00 (-)	2.27e4 ISTD 514.80>469.95 (-)

7.4 7.6
RT (min)

7.4 7.6

RT (min)

1 3C-PFDA

Cone. 4.7124

1.21 e6 Q 514.80>469.95 (-)

i A=256651
RT= 7.329

O.OeO -

i A=256651
RT= 7.329

2.0e4-R121-69 <¦

7.2

7.4 7.6

RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

7.6
RT (min)

A=3002953
RT=7.334

d3-N-MeFOSAA

Cone. 4.6340

ISTD 572.80>419.05 (-)

f A=670872

th r	i RT=7.510

2.0e5 -	'

2.38e5 Q 572.80>419.05 (-)

O.OeO -

512.00 40.93 (35.78)
Q 570.20>419.00 (-)	4.10e3

4.0e3 -

f A=3002953
RT=7.334



II
<
•fc-

_R1 40.93 (-

RT=7.515

- wsJ

j

-- /

O.OeO

7.6
RT (min)

PFDS

Cone. 0.0967

R#1 599.00>99.00 72.02 (60.20)
Q 599.00>80.10 (-)	2.92e3

A=7985

I R1 72.02 -^=7.643

7.4 7.6

RT (min)

13C-PFUnDA_IS

Cone. 5.0000

7.4 7.6 7.8

RT (min)

13C-PFUnDA

Cone. 4.7416

Q 564.80>519.95 (-)

7.4 7.6 7.8

RT (min)

PFUnDA

Cone. 0.1115
R#1 563.00>219.00 11.60 (11.87)

1.13e6 Q563.00>518.90 (-)	2.21e4 ISTD 588.80>419.00 (-)

7.25 7.50 7.75

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 564.80>519.95 (-)
1.0e6-

5.0e5 -

fA= 2963782
RT=7.683

O.OeO -

7.6

RT (min)

d5-N-EtFOSAA

Cone. 4.7273

2.79e5 Q 588.80>419.00 (-)

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.1014

R#1 584.20>526.10 48.95 (55.50)
Q 584.20>418.95 (-)	4.23e3

i A=2963782
RT= 7.683

O.OeO -



f^A=63164





A=767773



{A=767773

1

A=14164

R1 11.60 j

¦fti= 7.682





RT=7.694



RT= 7.694 4.0e3-

R1 48.95 (-,

RT=7.702





2.0e5 -



2.0e5 -























2.0e3 -











1.0e5 -



1.0e5 -











1/

vVjt.	

O.OeO :

/

—	 O.OeO :

I

	 (1 Dpf) -

	rJ V.





7.6

7.8 8.0
RT (min)

PFOSA

Cone. 0.0932

R#1 498.20 >64.10 0.00 (0.15)
Q 498.20>78.00 (-)	5.20e3

7.8 8.0
RT (min)

7.8 8.0
RT (min)

13C-FOSA IS

Cone. 5.0000

1 3C-FOSA

Cone. 4.9354

ISTD 506.00>78.05 (-)

2.68e5 Q 506.00>78.05 (-)

- R1 0.00 (—

f A= 12736
l)RT= 7.755

A=653737
RT= 7.754

A=653737
RT= 7.754

7.6 7.8 8.0
RT (min)

PFDoA

Cone. 0.0965

R#1 613.05 >169.00 15.03 (15.47)
Q 613.05 >569.00 (-)	2.07e4

fA=51933

20e4:R115.( RT= 8.026

7.50 7.75 8.00

RT (min)

1 3C-PFDoA IS

Cone. 5.0000

7.6 7.8 8.0

RT (min)

7.8 8.0

RT (min)

7.8 8.0

RT (min)

ISTD 614.80>569.95 (-)
1.0e6-

1.10e6

A=2837880
RT= 8.027

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

50

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Quantitation/lntegration
Printed 11/8/2023 12:21:56

CCV1 -230426-WI (continued)

13C-PFDoA

Cone. 4.7040

Q 614.80> 569.95 (-)
1.0e6 -

A=2837880
RT=8.027

10-2-FtS

Cone. 0.0955

R#1 626.50 >81.05 53.88 (56.92)
Q 626.50>607.05 (-)	2.58e3

' A=6184

I RT= 8.040

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)
2.0e5 -

1.0e5 -

RT (min)

RT (min)

NEtFOSE

Cone. 0.0865

Q629.50> 59.10 (-)

6.0e3 ^

4.0e3 ^

2.0e3 ^

O.OeO -yT"

d9-EtFOSE_IS

Cone. 5.0000

d9-EtFOSE

Cone. 4.8001

7.31e3 ISTD 638.90> 59.10 (-)

f A= 15727
RT= 8.757

7.5e4-
5.0e4 -j
2.5e4^
O.OeO -

9.07e4 Q 638.90> 59.10 (-)

7.5e4^

5.0e4 -j
2.5e4^

— O.OeO 1 , , ,

d5-NEtFOSA

Cone. 4.6022

2.22e5 Q 531.10> 169.10 (-)

2.0e5 -

1.0e5 -

O.OeO

9.0

RT (min)

NMeFOSA

Cone. 0.1043

R#1 512.10>219.20 79.58 (86.99)
Q 512.10 > 169.20 (-)	1.79e3

NMeFOSE

Cone. 0.0882

2.22e5 Q 616.10>58.90 (-)

9.0

RT (min)

: R1 79.58
1.5e3 -

1.0e3 -
5.0e2 :
O.OeO

8.6 8.8 9.0

RT (min)

d3-NMeFOSA

Cone. 4.7624

9.0
RT (min)

9.0
RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 5.5069

Q 515.10> 169.00 (-)

^A=535099
I RT= 8.527

2.09e5 ISTD 623.00> 59.00 (-)

1.46e5 Q 623.00> 59.00 (-)

2.0e5 -

O.OeO -

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 0.0825

R#1 713.00 >169.30 12.08 (10.03)
Q 713.00>668.90 (-)	1.70e4

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

1 3C-PFTeDA

Cone. 4.8977

11CI-PF30UdS

Cone. 0.0865

ISTD 714.80>669.80 (-)

6.50e5 Q 714.80>669.80 (-)

6.50e5 Q 631.00>451.10 (-)

A= 1677262
RT= 8.651





fA= 1677262



t

A=9300

6.0e5 -

l

LD

CO
II

£

3.0e3 ^



RT= 7.835

4.0e5





2.0e3 ^





2.0e5 -J

I



1.0e3 ^





O.OeO :

i



- O.OeO -

/



9.0
RT (min)

L-PFDoS

Cone. 0.1212

R#1 698.80>98.80 49.26 (68.45)
Q 698.80>80.10 (-)	2.08e3

2.0e3 Hri 49 26

9.0
RT (min)

PFODA

Cone. 0.1136

f A=5694
RT=8.508

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-) 2.09e5
2.0e5 -

O.OeO

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0913

R#1 526.50>219.20 62.06 (64.74)
Q 526.50>169.10 (-)	2.96e3

f A=7462

IR1 62.06 (-Mt= 8.790

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.0968

R#1 663.10> 169.10 18.52 (18.77)
Q 663.10>618.90 (-)	2.14e4

2.0e4 - R1 18.52

9CI-PF30NS

Cone. 0.0925

3.61 e3 Q 531.00 >351.10 (-)

7.5e3 ^

5.0e3 :

2.5e3 ^

O.OeO 1 , , ,

A=22135
RT=7.157

RT (min)

7.4

RT (min)

1 3C2-PFHxDA IS

Cone. 5.0000

Q377.10>251.20 (-)
1.5e4-

A=35251
RT=6.412

Q 812.90>769.00 (-)
2.0e4 -

A=49443
RT=9.178

ISTD 815.00>770.00 (-)

A=3675243
RT=9.178

8.2 8.4 8.6

RT (min)

6.6

RT (min)

9.0 9.2 9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

51

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A

Insight Report
Quantitation/lntegration
Printed 11/8/2023 12:21:56

CCV1 -230426-WI (continued)

13C2-PFHxDA

Cone. 4.5530

Q 815.00>770.00 (-)
1.5e6 -
1.0e6-j
5.0e5 ^

O.OeO 4==

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 0.0953

PFecHS

Cone. 0.0876
R#1 461.00>99.10 36.96 (37.10)

1.59e6 ISTD 569.80>524.90 (-) 1.05e6 Q461.00>381.00 (-)	1.67e4 Q 298.00>78.00 (-)

PFHxSA

Cone. 0.0940

1.26e4 Q 397.90>78.00 (-)

A=3675243
RT=9.178

0.0 0.1

1.0e6

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)
Q 514.80>219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

RT (min)

f A=27697
RT= 6.971

7.2
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

52

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Insight Report
Quantitation/lntegration
Printed 11/8/2023 12:21:56

CCV1 -230426-WI

Sample ID:CCV1-230426-WI

Date Acquired: 4/26/2023 7:27:04 PM

Acquired by: System Administrator

Data File: 230426004

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.206

850649

850649

—

5.0000

5.0000

nq/ml

13C-PFBA

Auto

4.206

850649

2772874

13C7-PFUnDA IS

5.0000

4.8852

nq/mL

PFBA

Auto

4.206

17974

850649

13C-PFBA IS

0.1000

0.0932

nq/ml

13C-PFPeA IS

Auto

5.372

1361516

1361516

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.372

1361516

2772874

13C7-PFUnDA IS

5.0000

4.7559

nq/ml

PFPeA

Auto

5.372

26270

1361516

13C-PFPeA IS

0.1000

0.0989

nq/mL

13C-PFBS IS

Auto

5.502

512690

512690

	

4.6500

4.6500

nq/ml

13C-PFBS

Auto

5.502

512690

2772874

13C7-PFUnDA IS

4.6500

4.3637

nq/mL

PFBS

Auto

5.502

7232

512690

13C-PFBS IS

0.0880

0.0859

nq/ml

13C HFPO DA IS

Auto

6.106

254456

254456

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.106

254456

2772874

13C7-PFUnDA IS

5.0000

4.2729

nq/ml

HFPO DA

Auto

6.104

4236

254456

13C HFPO DA IS

0.1000

0.1051

nq/mL

13C-4 2-FTS IS

Auto

5.906

196794

196794

	

4.6700

4.6700

nq/ml

13C-4 2-FTS

Auto

5.906

196794

2772874

13C7-PFUnDA IS

4.6700

3.5250

nq/mL

4-2-FtS

Auto

5.905

4521

196794

13C-4 2-FTS IS

0.0930

0.0920

nq/ml

PFHxA

Auto

5.961

54291

1833784

13C-PFHxA IS

0.1000

0.1130

nq/mL

13C-PFHxA IS

Auto

5.960

1833784

1833784

	

5.0000

5.0000

nq/ml

13C-PFHxA

Auto

5.960

1833784

2772874

13C7-PFUnDA IS

5.0000

4.4588

nq/mL

PFPeS

Auto

6.001

6764

531208

180-PFHxS IS

0.0940

0.0852

nq/ml

PFHxS

Auto

6.371

6657

531208

180-PFHxS IS

0.0910

0.0949

nq/mL

13C-PFHpA IS

Auto

6.367

1897920

1897920

	

5.0000

5.0000

nq/ml

13C-PFHpA

Auto

6.367

1897920

2772874

13C7-PFUnDA IS

5.0000

4.6501

nq/mL

180-PFHxS IS

Auto

6.374

531208

531208

	

4.7250

4.7250

nq/ml

180-PFHxS

Auto

6.374

531208

2772874

13C7-PFUnDA IS

4.7250

4.4695

nq/mL

PFHpA

Auto

6.368

54544

1897920

13C-PFHpA IS

0.1000

0.0966

nq/ml

13C2-6 2-FTS IS

Auto

6.669

371970

371970

	

4.7500

4.7500

nq/mL

13C2-6 2-FTS

Auto

6.669

371970

2772874

13C7-PFUnDA IS

4.7500

3.9298

nq/ml

PFHpS

Auto

6.677

6657

531208

180-PFHxS IS

0.0950

0.0862

nq/mL

6-2-FTS

Auto

6.668

7172

371970

13C2-6 2-FTS IS

0.0950

0.0988

nq/ml

PFOA

Auto

6.686

67204

2694692

13C-PFOA IS

0.1000

0.0903

nq/mL

13C-PFOA IS

Auto

6.686

2694692

2694692

	

5.0000

5.0000

nq/ml

13C-PFOA

Auto

6.686

2694692

2772874

13C7-PFUnDA IS

5.0000

5.0425

nq/mL

PFOS

Auto

6.974

5731

492278

13C-PFOS IS

0.0930

0.1011

nq/ml

13C-PFOS IS

Auto

6.975

492278

492278

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

6.975

492278

2772874

13C7-PFUnDA IS

4.7750

4.2620

nq/ml

PFNA

Auto

6.996

61758

2807017

13C-PFNA IS

0.1000

0.0997

nq/mL

13C-PFNA IS

Auto

6.996

2807017

2807017

	

5.0000

5.0000

nq/ml

13C-PFNA

Auto

6.996

2807017

2772874

13C7-PFUnDA IS

5.0000

4.9987

nq/mL

PFNS

Auto

7.305

11358

492278

13C-PFOS IS

0.0960

0.0912

nq/ml

8-2-FTS

Auto

7.331

5892

256651

13C-8 2-FTS IS

0.0960

0.1137

nq/mL

13C-8 2-FTS IS

Auto

7.329

256651

256651

	

4.7900

4.7900

nq/ml

13C-8 2-FTS

Auto

7.329

256651

2772874

13C7-PFUnDA IS

4.7900

3.8922

nq/mL

PFDA

Auto

7.335

55452

3002953

13C-PFDA IS

0.1000

0.0983

nq/ml

13C-PFDA IS

Auto

7.334

3002953

3002953

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.334

3002953

2772874

13C7-PFUnDA IS

5.0000

4.7124

nq/ml

d3-N-MeFOSAA IS

Auto

7.510

670872

670872

	

5.0000

5.0000

nq/mL

d3-N-MeFOSAA

Auto

7.510

670872

2772874

13C7-PFUnDA IS

5.0000

4.6340

nq/ml

NMeFOSAA

M

7.515

13321

670872

d3-N-MeFOSAA IS

0.1000

0.0991

nq/mL

PFDS

Auto

7.643

7985

492278

13C-PFOS IS

0.0960

0.0967

nq/ml

13C-PFUnDA IS

Auto

7.683

2963782

2963782

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.683

2963782

2772874

13C7-PFUnDA IS

5.0000

4.7416

nq/ml

PFUnDA

Auto

7.682

63164

2963782

13C-PFUnDA IS

0.1000

0.1115

nq/mL

d5-N-EtFOSAA IS

Auto

7.694

767773

767773

	

5.0000

5.0000

nq/ml

d5-N-EtFOSAA

Auto

7.694

767773

2772874

13C7-PFUnDA IS

5.0000

4.7273

nq/mL

NEtFOSAA

Auto

7.702

14164

767773

dS-N-EtFOSAA IS

0.1000

0.1014

nq/ml

PFOSA

Auto

7.755

12736

653737

13C-FOSA IS

0.1000

0.0932

nq/mL

13C-FOSA IS

Auto

7.754

653737

653737

	

5.0000

5.0000

nq/ml

13C-FOSA

Auto

7.754

653737

2772874

13C7-PFUnDA IS

5.0000

4.9354

nq/mL

PFDoA

Auto

8.026

51933

2837880

13C-PFDoA IS

0.1000

0.0965

nq/ml

13C-PFDoA IS

Auto

8.027

2837880

2837880

____

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

53

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A

Insight Report
Quantitation/lntegration
Printed 11/8/2023 12:21:56

CCV1 -230426-WI (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name



Std. Cone.

Cone.

Unit

13C-PFDoA

Auto

8.027

2837880

2772874

13C7-PFUnDA

IS

5.0000

4.7040

nq/mL

10-2-FtS

Auto

8.040

6184

256651

13C-8 2-FTS IS

0.0960

0.0955

ng/mL

d5-NEtFOSA IS

Auto

8.782

560494

560494

	



5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.782

560494

2772874

13C7-PFUnDA

IS

5.0000

4.6022

ng/mL

NMeFOSE

Auto

8.508

5694

355911

d7-N-MeFOSE

IS

0.1000

0.0882

nq/mL

NEtFOSE

Auto

8.757

15727

231929

d9-EtFOSE IS



0.1000

0.0865

ng/mL

d9-EtFOSE IS

Auto

8.738

231929

231929

	



5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.738

231929

2772874

13C7-PFUnDA

IS

5.0000

4.8001

ng/mL

NMeFOSA

Auto

8.532

4844

535099

d3-NMeFOSA

IS

0.1000

0.1043

nq/mL

d3-NMeFOSA IS

Auto

8.527

535099

535099

	



5.0000

5.0000

ng/mL

d3-NMeFOSA

Auto

8.527

535099

2772874

13C7-PFUnDA

IS

5.0000

4.7624

nq/mL

d7-N-MeFOSE IS

Auto

8.491

355911

355911

	



5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.491

355911

2772874

13C7-PFUnDA

IS

5.0000

5.5069

nq/mL

NEtFOSA

Auto

8.790

7462

560494

d5-NEtFOSA IS

0.1000

0.0913

ng/mL

PFTrDA

Auto

8.353

50715

1677262

13C-PFTeDA IS

0.1000

0.0968

nq/mL

PFTeDA

Auto

8.651

44956

1677262

13C-PFTeDA IS

0.1000

0.0825

ng/mL

13C-PFTeDA IS

Auto

8.651

1677262

1677262

	



5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.651

1677262

2772874

13C7-PFUnDA

IS

5.0000

4.8977

ng/mL

11CI-PF30UdS

Auto

7.835

9300

492278

13C-PFOS IS



0.0940

0.0865

nq/mL

9CI-PF30NS

Auto

7.157

22135

492278

13C-PFOS IS



0.0930

0.0925

ng/mL

L-PFDoS

Auto

8.304

4397

492278

13C-PFOS IS



0.0970

0.1212

nq/mL

NaDONA

Auto

6.412

35251

2807017

13C-PFNA IS



0.0940

0.0803

ng/mL

PFHxDA

Auto

9.178

49443

3675243

13C2-PFHxDA

IS

0.1000

0.1023

nq/mL

PFODA

Auto

9.727

22674

3675243

13C2-PFHxDA

IS

0.1000

0.1136

ng/mL

13C2-PFHxDA IS

Auto

9.178

3675243

3675243

	



5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.178

3675243

2772874

13C7-PFUnDA

IS

5.0000

4.5530

ng/mL

13C7-PFUnDA IS

Auto

7.682

2772874

2772874

	



5.0000

5.0000

nq/mL

PFecHS

Auto

6.637

40922

492278

13C-PFOS IS



0.0920

0.0876

ng/mL

PFBSA

Auto

6.146

30537

653737

13C-FOSA IS



0.1000

0.0953

nq/mL

PFHxSA

Auto

6.971

27697

2807017

13C-PFNA IS



0.1000

0.0940

ng/mL

CHARGE

ND(W/B)

	

	

2772874

13C7-PFUnDA

IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20> 172.30 (-)

13C-PFBA

Cone. 4.8852
Q217.20> 172.30 (-)

fA= 850649
RT=4.206

O.OeO

fA= 850649
RT=4.206

O.OeO

Q263.05>219.10 (-)
1.0e4 —i

1.00e4 ISTD 301.80>80.00 (-)

A= 26270
RT=5.372

A=512690
RT= 5.502

5.6

RT (min)

PFBA

Cone. 0.0932
Q213.20> 169.10 (-)

fA= 17974
RT=4.206

4.00 4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)

PFPeA	13C-PFBS IS

Cone. 0.0989	Cone. 4.6500

O.OeO-

4.00 4.25 4.50

RT (min)

13C-PFBS

Cone. 4.3637

1.99e5 Q 301.80>80.00 (-)

5.4 5.6 5.8
RT (min)

1 3C-PFPeA IS

Cone. 5.0000

ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.7559
Q 267.90>223.00 (-)

f A= 1361516
RT=5.372

O.OeO -

O.OeO -

A= 1361516
RT=5.372

5.2

5.2

5.4 5.6

RT (min)

PFBS

Cone. 0.0859
R#1 298.80>99.00 59.39 (72.97)

1.99e5 Q 299.00>80.00 (-)	2.89e3 ISTD 332.10>287.10 (-) 1.12e5

5.4 5.6

RT (min)

13C HFPO DA IS

Cone. 5.0000

I R1 59.39 (-

A=7232
|-$T= 5.502

A=254456
RT=6.106

5.4 5.6 5.8
RT (min)

5.6 5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

54

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A

Insight Report
Quantitation/lntegration
Printed 11/8/2023 12:21:56

CCV1 -230426-WI (continued)

13C HFPO DA

Cone. 4.2729

Q 332.10>287.10 (-)
1.0e5 -

5.0e4 -

HFPO DA

Cone. 0.1051

R#1 329.00 >285.10 58.63 (68.92)
1.12e5 Q 329.00> 169.00 (-)	2.00e3

y A=254456
RT=6.106

O.OeO -

¥A=4236
-R1 58.63 (-1-^7=6.104

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 0.1130

R#1 313.00> 119.10 2.16 (2.54)
Q 313.00>269.00 (-)	2.43e4

13C-PFHxA IS

Cone. 5.0000

R1 2.16 (—

f A=54291
i)RT= 5.961

ISTD 314.90>270.10 (-)
7.5e5

5.0e5 -
2.5e5 -
O.OeO -

A=1833784
RT=5.960

6.2
RT (min)

13C-PFHpA IS

Cone. 5.0000

13C-PFHpA

Cone. 4.6501

ISTD 366.90>322.10 (-) 8.52

^A= 1897920
RT= 6.367

Q366.90>322.10 (-)

f A= 1897920
RT= 6.367

13C2-6 2-FTS IS

Cone. 4.7500

13C2-6 2-FTS

Cone. 3.9298

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

13C-PFOA

Cone. 5.0425

1.17e6 Q 416.80>372.05 (-)

1 3C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 28.64 (27.58)

ISTD 329.00>309.15 (-) 8.63e4

1 3C-4 2-FTS

Cone. 3.5250

R#1 329.00>81.00 28.64 (27.58)
Q 329.00>309.15 (-)	8.63e4

4-2-FtS

Cone. 0.0920

R#1 327.00>81.10 9.10 (15.16)
Q 327.00>307.05 (-)	2.07e3

7.5e4
5.0e4
2.5e4
O.OeO

R1 28.64 (-

A=196794
f*T=5.906

6.2 6.4
RT (min)

13C-PFHxA

Cone. 4.4588

Q 314.90>270.10 (-)
7.5e5 -
5.0e5 -
2.5e5 -
O.OeO -

6.0 6.2
RT (min)

A=1833784
RT=5.960

2.0e3 H

Y A=4521

_R1 9.10 (— )rt=5.905

O.OeO -

6.0 6.2
RT (min)

PFPeS

Cone. 0.0852

R#1 349.00 >99.00 104.40 (80.87)
Q 349.00>79.95 (-)	2.65e3

f A=6764

]R1 10440 ^=6.001

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.0949

R#1 399.00>99.00 86.40 (92.02)
Q 399.00>80.00 (-)	2.53e3

O.OeO -

1

: R1 86.40 (-¦

' A=6657
i*T=6.371



I

6.2
RT (min)

6.2
RT (min)

6.2

RT (min)

6.2

6.4

180-PFHxS IS

Cone. 4.7250

180-PFHxS

Cone. 4.4695

8.52e5 ISTD 402.70>84.05 (-)

2.43e5 Q 402.70 >84.05 (-)

6.6
RT (min)

PFHpA

Cone. 0.0966

R#1 362.90> 169.00 21.36 (17.74)
Q 362.90>319.00 (-)	2.37e4

O.OeO

O.OeO

- R1 21.36 (-

i A= 54544
1*T=6.368

O.OeO -

6.6

RT (min)

6.2

6.4

6.2

6.6

RT (min)

PFHpS

Cone. 0.0862

R#1 449.00>99.20 56.13 (65.35)

Q 449.00>80.15 (-)	2.99e3 Q 427.00 >407.00 (-)

6.4

6.6
RT (min)

6-2-FTS

Cone. 0.0988

R#1 427.00>80.90 23.14 (27.82)

3.37e3

6.2

6.4

6.6
RT (min)

PFOA

Cone. 0.0903

R#1 413.00> 169.10 27.45 (27.71)
Q 413.00>369.00 (-)	3.09e4

O.OeO -



f A=6657

:R1 56.13 (-J

: I

\-kl=6.677

I .

RT (min)

6.6 6.8

RT (min)

PFOS

Cone. 0.1011
R#1 499.00>99.00 64.57 (96.24)

Q 499.00>80.00 (-)	1.82e3 ISTD 502.

1 3C-PFOS IS

Cone. 4.7750

105 (-)

1.0e6 -



'A=2694692
I RT= 6.686

1.0e6 -



fA=2694692
I RT= 6.686

1.5e3 ^

'

R1 64.57 (--

fA=5731
-kr= 6.974

5.0e5 -



I

5.0e5 -





1.0e3 ^









I





I

5.0e2 -



L

O.OeO -

i

V.

- O.OeO -

i

V,

- O.OeO -

Jv

2.0e5 1

f A=492278
RT= 6.975

Q 502.80>80.05 (-)
2.0e5 1

f A=492278
RT= 6.975

6.8 7.0
RT (min)

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

7.2

RT (min)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

55

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A

Insight Report
Quantitation/lntegration
Printed 11/8/2023 12:21:56

CCV1 -230426-WI (continued)

PFNA	13C-PFNA IS

Cone. 0.0997	Cone. 5.0000
R#1 463.00 >219.00 15.91 (20.94)

Q463.00>418.90 (-)	2.48e4	ISTD 467.80>423.00 (-)

1 3C-PFNA

Cone. 4.9987

1.15e6 Q 467.80>423.00 (-)

PFNS	8-2-FTS

Cone. 0.0912	Cone. 0.1137

R#1 549.00>99.00 72.15 (65.53)	R#1 527.20>487.00 2.70 (5.33)

1.15e6 Q 549.00>79.95 (-)	4.55e3	Q 527.10>506.90 (-)	1.99e3

A=61758

IR1 15.91 (¦ -r)t=6.996

f A=2807017
RT=6.996

O.OeO -

A=2807017
RT=6.996

O.OeO

- R1 2.70 (-

13C-8 2-FTSJS

Cone. 4.7900

ISTD 528.80> 509.00 (-)

13C-8 2-FTS

Cone. 3.8922

9.76e4 Q 528.80> 509.00 (-)

7.2	6.8 7.0 7.2

RT (min)	RT (min)

PFDA	13C-PFDAJS

Cone. 0.0983	Cone. 5.0000
R#1 512.90>219.00 21.69 (18.19)

9.76e4 Q 512.90>469.00 (-)	2.27e4 ISTD 514.80>469.95 (-)

7.4 7.6
RT (min)

7.4 7.6

RT (min)

1 3C-PFDA

Cone. 4.7124

1.21 e6 Q 514.80>469.95 (-)

i A=256651
RT= 7.329

O.OeO -

i A=256651
RT= 7.329

2.0e4-R121-69 <¦

7.2

7.4 7.6

RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

7.6
RT (min)

A=3002953
RT=7.334

d3-N-MeFOSAA

Cone. 4.6340

ISTD 572.80>419.05 (-)

f A=670872

th r	i RT=7.510

2.0e5 -	'

2.38e5 Q 572.80>419.05 (-)

O.OeO -

512.00 40.93 (35.78)
Q 570.20>419.00 (-)	4.10e3

4.0e3 -

f A=3002953
RT=7.334



II
<
•fc-

_R1 40.93 (-

RT=7.515

- wsJ

j

-- /

O.OeO

7.6
RT (min)

PFDS

Cone. 0.0967

R#1 599.00>99.00 72.02 (60.20)
Q 599.00>80.10 (-)	2.92e3

A=7985

I R1 72.02 -^=7.643

7.4 7.6

RT (min)

13C-PFUnDA_IS

Cone. 5.0000

7.4 7.6 7.8

RT (min)

13C-PFUnDA

Cone. 4.7416

Q 564.80>519.95 (-)

7.4 7.6 7.8

RT (min)

PFUnDA

Cone. 0.1115
R#1 563.00>219.00 11.60 (11.87)

1.13e6 Q563.00>518.90 (-)	2.21e4 ISTD 588.80>419.00 (-)

7.25 7.50 7.75

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 564.80>519.95 (-)
1.0e6-

5.0e5 -

fA= 2963782
RT=7.683

O.OeO -

7.6

RT (min)

d5-N-EtFOSAA

Cone. 4.7273

2.79e5 Q 588.80>419.00 (-)

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.1014

R#1 584.20>526.10 48.95 (55.50)
Q 584.20>418.95 (-)	4.23e3

i A=2963782
RT= 7.683

O.OeO -



f^A=63164





A=767773



{A=767773

1

A=14164

R1 11.60 j

¦fti= 7.682





RT=7.694



RT= 7.694 4.0e3-

R1 48.95 (-,

RT=7.702





2.0e5 -



2.0e5 -























2.0e3 -











1.0e5 -



1.0e5 -











1/

vVjt.	

O.OeO :

/

—	 O.OeO :

I

	 (1 Dpf) -

	rJ V.





7.6

7.8 8.0
RT (min)

PFOSA

Cone. 0.0932

R#1 498.20 >64.10 0.00 (0.15)
Q 498.20>78.00 (-)	5.20e3

7.8 8.0
RT (min)

7.8 8.0
RT (min)

13C-FOSA IS

Cone. 5.0000

1 3C-FOSA

Cone. 4.9354

ISTD 506.00>78.05 (-)

2.68e5 Q 506.00>78.05 (-)

- R1 0.00 (—

f A= 12736
l)RT= 7.755

A=653737
RT= 7.754

A=653737
RT= 7.754

7.6 7.8 8.0
RT (min)

PFDoA

Cone. 0.0965

R#1 613.05 >169.00 15.03 (15.47)
Q 613.05 >569.00 (-)	2.07e4

fA=51933

20e4:R115.( RT= 8.026

7.50 7.75 8.00

RT (min)

1 3C-PFDoA IS

Cone. 5.0000

7.6 7.8 8.0

RT (min)

7.8 8.0

RT (min)

7.8 8.0

RT (min)

ISTD 614.80>569.95 (-)
1.0e6-

1.10e6

A=2837880
RT= 8.027

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

56

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A

Insight Report
Quantitation/lntegration
Printed 11/8/2023 12:21:56

CCV1 -230426-WI (continued)

13C-PFDoA

Cone. 4.7040

Q 614.80> 569.95 (-)
1.0e6 -

A=2837880
RT=8.027

10-2-FtS

Cone. 0.0955

R#1 626.50 >81.05 53.88 (56.92)
Q 626.50>607.05 (-)	2.58e3

' A=6184

I RT= 8.040

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)
2.0e5 -

1.0e5 -

RT (min)

RT (min)

NEtFOSE

Cone. 0.0865

Q629.50> 59.10 (-)

6.0e3 ^

4.0e3 ^

2.0e3 ^

O.OeO -yT"

d9-EtFOSE_IS

Cone. 5.0000

d9-EtFOSE

Cone. 4.8001

7.31e3 ISTD 638.90> 59.10 (-)

f A= 15727
RT= 8.757

7.5e4-
5.0e4 -j
2.5e4^
O.OeO -

9.07e4 Q 638.90> 59.10 (-)

7.5e4^

5.0e4 -j
2.5e4^

— O.OeO 1 , , ,

d5-NEtFOSA

Cone. 4.6022

2.22e5 Q 531.10> 169.10 (-)

2.0e5 -

1.0e5 -

O.OeO

9.0

RT (min)

NMeFOSA

Cone. 0.1043

R#1 512.10>219.20 79.58 (86.99)
Q 512.10 > 169.20 (-)	1.79e3

NMeFOSE

Cone. 0.0882

2.22e5 Q 616.10>58.90 (-)

9.0

RT (min)

: R1 79.58
1.5e3 -

1.0e3 -
5.0e2 :
O.OeO

8.6 8.8 9.0

RT (min)

d3-NMeFOSA

Cone. 4.7624

9.0
RT (min)

9.0
RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 5.5069

Q 515.10> 169.00 (-)

^A=535099
I RT= 8.527

2.09e5 ISTD 623.00> 59.00 (-)

1.46e5 Q 623.00> 59.00 (-)

2.0e5 -

O.OeO -

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 0.0825

R#1 713.00 >169.30 12.08 (10.03)
Q 713.00>668.90 (-)	1.70e4

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

1 3C-PFTeDA

Cone. 4.8977

11CI-PF30UdS

Cone. 0.0865

ISTD 714.80>669.80 (-)

6.50e5 Q 714.80>669.80 (-)

6.50e5 Q 631.00>451.10 (-)

A= 1677262
RT= 8.651





fA= 1677262



t

A=9300

6.0e5 -

l

LD

CO
II

£

3.0e3 ^



RT= 7.835

4.0e5





2.0e3 ^





2.0e5 -J

I



1.0e3 ^





O.OeO :

i



- O.OeO -

/



9.0
RT (min)

L-PFDoS

Cone. 0.1212

R#1 698.80>98.80 49.26 (68.45)
Q 698.80>80.10 (-)	2.08e3

2.0e3 Hri 49 26

9.0
RT (min)

PFODA

Cone. 0.1136

f A=5694
RT=8.508

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-) 2.09e5
2.0e5 -

O.OeO

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0913

R#1 526.50>219.20 62.06 (64.74)
Q 526.50>169.10 (-)	2.96e3

f A=7462

IR1 62.06 (-Mt= 8.790

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.0968

R#1 663.10> 169.10 18.52 (18.77)
Q 663.10>618.90 (-)	2.14e4

2.0e4 - R1 18.52

9CI-PF30NS

Cone. 0.0925

3.61 e3 Q 531.00 >351.10 (-)

7.5e3 ^

5.0e3 :

2.5e3 ^

O.OeO 1 , , ,

A=22135
RT=7.157

RT (min)

7.4

RT (min)

1 3C2-PFHxDA IS

Cone. 5.0000

Q377.10>251.20 (-)
1.5e4-

A=35251
RT=6.412

Q 812.90>769.00 (-)
2.0e4 -

A=49443
RT=9.178

ISTD 815.00>770.00 (-)

A=3675243
RT=9.178

8.2 8.4 8.6

RT (min)

6.6

RT (min)

9.0 9.2 9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

57

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A

Insight Report
Quantitation/lntegration
Printed 11/8/2023 12:21:56

CCV1 -230426-WI (continued)

13C2-PFHxDA

Cone. 4.5530

Q 815.00>770.00 (-)
1.5e6 -
1.0e6-j
5.0e5 ^

O.OeO 4==

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 0.0953

PFecHS

Cone. 0.0876
R#1 461.00>99.10 36.96 (37.10)

1.59e6 ISTD 569.80>524.90 (-) 1.05e6 Q461.00>381.00 (-)	1.67e4 Q 298.00>78.00 (-)

PFHxSA

Cone. 0.0940

1.26e4 Q 397.90>78.00 (-)

A=3675243
RT=9.178

0.0 0.1

1.0e6

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)
Q 514.80>219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

RT (min)

f A=27697
RT= 6.971

7.2
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

58

-------
1st /S/AO 10/24/23

2nd /S/AO 10/26/23

Insight Report
Quantitation/Integration
Printed 10/24/2023 15:05:00

CCV1-230426

Sample ID: CCV1-230426

Date Acquired: 4/26/2023 7:40:50 PM

Acquired by: System Administrator

Data File: 230426005

Vial: 11 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.203

801673

801673

	

5.0000

5.0000

nq/mL

13C-PFBA

Auto

4.203

801673

2817773

13C7-PFUnDA IS

1000

4.5306

ng/ml

PFBA

Auto

4.204

199749

801673

13C-PFBA IS

1.0000

1.0990

ng/mt

13C-PFPeA IS

Auto

5.365

1295675

1295675

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.36S

1295675

2817773

>A IS

5.0000

4.4538

ng/ml

PFPeA

Auto

5.367

270331

1295675

IS

1.0000

1.0698

ng/ml

13C-PFBS IS

Auto

5.497

500398

500398

	





1

13C-PFBS

Auto

497

500398

2817773

13C7-PFUnDA IS

4.6500

4.1912

ng/ml

PFBS

Auto

S.497

75565

500398

13C-PFBS IS

0.8840

0.9197

ng/mL

13C HFPO DA IS

Auto

6.100

246978

246978



5.0000

5.0000

ng/ml

FPO DA

Auto

6.100

246978

2817773

13C7-PFUriDA IS

5.0000

4.0813

ng/mL

HFPO DA

Auto

6.101

42859

246978

13C HFPO DA IS

1.0000

1.0958

ng/ml

13C-4 2-FTS IS

Auto

S.900

201591

591

	

4.6700

4.6700

ig/mL

13C-4 2-FTS

Auto

5.900

201591

2817773

13C7-PFUnDA IS

>700

3.5534

ig/ml

4-2-FtS

Auto

S.900

56225

201591

13C-4 2-FTS IS

0.9340

1.1168

ig/mL

PFHxA

Auto

354

540874

1761603

' IS

1.0000

1.1721

ig/ml

13C-PFHxA IS

Auto

S.954

1761603

1761603

	

5.0000

5.0000

ng/mL

13C-PFHxA

Auto

5.954

1761603

2817773

13C7-PFUnDA IS

5.0000

4.2150

ng/ml

PFPeS

Auto

S.995

74679

515071

180 IS

0.9380

0.9706

ng/mL

PFHxS

Auto

6.368

62593

071

180-PFHxS IS

0.9100

0.9206

ng/ml

13C-PFHpA IS

Auto

6.361

1840705

1840705

	

5.0000

5.0000

ng/mL

13C-PFHpA

Auto

6.361

1840705

2817773

'FUnDA IS

5.0000

4.4381

ng/ml

180-PFHxS IS

Auto

6.368

515071

515071

	

4.7250

4.7250

ig/mL

180-PFHxS

Auto

6.368

515071

2817773

13C7-PFUnDA IS

4.7250

4.2647

ig/ml

PFHpA

Auto

6.361

615081

1840705

:HpA

1.0000

1.1233

ig/mL

' 5 2-FTS IS

Auto

6.662

367046

367046

	

4.7500

4.7500

ig/ml

13C2-6 2-FTS

Auto

6.662

367046

2817773

13C7-PFUnDA IS

4.7500

3.8160

ig/mL

PFHpS

Auto

6.671

74848

071

180-PFHxS IS

0.9520

0.9995

ng/ml

6-2-FTS

Auto

6.662

82S2S

367046

13C2-6 2-FTS IS

0.9480

1 miq

na/mL

PFOA

Auto

6.680

!0

2619419

13C-PF

1.0000

0.9863

ng/ml

13C-PFOA IS

,<-»

6.680

2619419

2619419



5.0000

5.0000

ng/mL

13C-PFOA

Auto

6.680

2619419

2817773

13C7-PFUnDA IS

5.0000

4.8235

ng/ml

PFOS

Auto

6.969

i ri

900

13C-PFOS IS

•280

1.0017

ng/mL

' : FOS IS

Auto

6.968

477900

477900

	

750

4.7750

ng/ml

13C-PFOS

Auto

6.968

477900

2817773

13C7-PFlJnDA IS

4.7750

4.0716

ig/mL

PFNA

Auto

6.989

648480

2652843

13C-PFNA IS

1.0000

: 'I

ng/ml

13C-PFNA IS

Auto

6.989

2652843

2652843

	

5.0000

5.0000

ig/mL

13C-PFNA

Auto

6.989

2652843

2817773

13C7-PFUnDA IS

5.0000

4.6489

nq/mL

PFNS

Auto

7.296

127846

477900

13C-PFOS IS

0.9600

1.0574

ng/mL

8-2-FTS

Auto

7.323

61239

176

13C-8 2-FTS IS

0.9580

1.2953

ng/ml

13C-8 2-FTS IS

Auto

7.323

234176

234176

	

4.7900

4.7900

ng/mL

13C-8 2-FTS

Auto

7.323

234176

2817773

13C7-PFUnDA IS

'900

3.4948

ng/ml

PFDA

Auto

7.327

627751

2978112

13C-PF

1.0000

1.1221

ng/mL

13C-PFDA IS

Auto

7.327

2978112

112

	

5.0000

5.0000

ng/ml

13C-PFDA

Auto

7.327

2978112

2817773

13C7-PFUnDA IS

5.0000

4.5990

ig/mL

d3-N-MeFOSAA IS

Auto

7.503

633123

633123

	

5.0000

5.0000

ng/ml

d3-N-MeFOSAA

Auto

7.503

633123

2817773

13C7-PFUnDA IS

5.0000

4.3035

ig/mL

NMeFi

Auto

7.508

!3

633123

iSAA IS

1.0000

1.0252

ng/ml

PFDS

Auto

7.636

)4

477900

13C-PFOS IS

0.9640

1.0651

nq/mL

13C-PFUnDA IS

Auto

576

2841259

¦¦¦¦¦ 259

	

5.0000

5.0000

ng/ml

13
-------
1st /S/ AO 10/24/23
2nd IS/ AO 10/26/23



Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:00

CCV1-230426 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.019

2717987

2817773

13C7-PFUnDA IS

5.0000

4.4335

nq/mL

10-2-FtS

Auto

8.030

74347

234176

13C-8 2-FTS IS

0.9640

1.2583

nq/mL

d5-NEtFOSA IS

Auto

8.777

519296

519296

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.777

519296

2817773

13C7-PFUnDA IS

5.0000

4.1960

nq/mL

NMeFOSE

Auto

8.501

55771

335674

d7-N-MeFOSE IS

1.0000

0.9164

nq/mL

NEtFOSE

Auto

8.752

158866

214544

d9-EtFOSE IS

1.0000

0.9450

nq/mL

d9-EtFOSE IS

Auto

8.733

214544

214544

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.733

214544

2817773

13C7-PFUnDA IS

5.0000

4.3695

nq/mL

NMeFOSA

Auto

8.526

49235

500288

d3-NMeFOSA IS

1.0000

1.1337

nq/mL

dB-NMeFOSA IS

Auto

8.521

500288

500288

—

5.0000

5.0000

nq/mL

dB-NMeFOSA

Auto

8.521

500288

2817773

13C7-PFUnDA IS

5.0000

4.3816

nq/mL

d7-N-MeFOSE IS

Auto

8.486

335674

335674

—

5.0000

5.0000

nq/mL

d7-N-MeFOSE

Auto

8.486

335674

2817773

13C7-PFUnDA IS

5.0000

5.1110

nq/mL

NEtFOSA

Auto

8.788

78635

519296

d5-NEtFOSA IS

1.0000

1.0386

nq/mL

PFTrDA

Auto

8.346

544860

1682700

13C-PFTeDA IS

1.0000

1.0370

nq/mL

PFTeDA

Auto

8.646

507289

1682700

13C-PFTeDA IS

1.0000

0.9278

nq/mL

13C-PFTeDA IS

Auto

8.646

1682700

1682700

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.646

1682700

2817773

13C7-PFUnDA IS

5.0000

4.8353

nq/mL

11CI-PFBOUdS

Auto

7.829

110913

477900

13C-PFOS IS

0.9420

1.0622

nq/mL

9CI-PF30NS

Auto

7.151

247226

477900

13C-PFOS IS

0.9320

1.0647

nq/mL

L-PFDoS

Auto

8.296

40975

477900

13C-PFOS IS

0.9680

1.1638

nq/mL

NaDONA

Auto

6.406

381713

2652843

13C-PFNA IS

0.9420

0.9201

nq/mL

PFHxDA

Auto

9.175

365084

3582389

13C2-PFHxDA IS

1.0000

1.3941

nq/mL

PFODA

Auto

9.718

234798

3582389

13C2-PFHxDA IS

1.0000

1.2068

nq/mL

13C2-PFHxDA IS

Auto

9.175

3582389

3582389

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.175

3582389

2817773

13C7-PFUnDA IS

5.0000

4.3672

nq/mL

13C7-PFUnDA IS

Auto

7.675

2817773

2817773

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.630

365724

477900

13C-PFOS IS

0.9200

0.8067

nq/mL

PFBSA

Auto

6.140

310375

611162

13C-FOSA IS

1.0000

1.0357

nq/mL

PFHxSA

Auto

6.964

285076

2652843

13C-PFNA IS

1.0000

1.0232

nq/mL

CHARGE

ND(W/B)

	

	

2817773

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 4.5306
1.76e5 Q 217.20>172.30 (-)

PFBA

Cone. 1.0990
1.76e5 Q 213.20> 169.10 (-)

A=801673
RT=4.203

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 1.0698

Q263.05>219.10 (-)

9.46e4 ISTD 301.80>80.00 (-)

13C-PFPeA IS

Cone. 5.0000
4.42e4 ISTD 267.90>223.00 (-)

TA= 199749
RT=4.204

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

O.OeO

4.00 4.25 4.50

RT (min)

13C-PFBS

Cone. 4.1912

1.81e5 Q 301.80>80.00 (-)

13C-PFPeA

Cone. 4.4538
4.97e5 Q 267.90>223.00 (-)

O.OeO

A=1295675
RT= 5.365

O.OeO

5.6

RT (min)

PFBS

Cone. 0.9197
R#1 298.80>99.00 68.52 (72.97)

1.81e5 Q 299.00>80.00 (-)	2.76e4 ISTD 332.10>287.10 (-)

13C HFPO DA IS

Cone. 5.0000

I R1 68.52 (-

5.6 5.8
RT (min)

1.0e5-

A=246978
RT=6.100

L

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

60

-------
1st /S/ AO 10/24/23
2nd IS/ AO 10/26/23



Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:00

CCV1-230426 (continued)

13C HFPO DA

Cone. 4.0813

Q 332.10>287.10 (-)
1.0e5 -

|A=2

RT='

O.OeO -

246978
6.100

L

6.0

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)
7.5e5
5.0e5 :

2.5e5 :

O.OeO



¥A= 1840705



RT=6.361

:—i



13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)
1.5e5 -

| A=367046
RT=6.662

1.0e5 -
5.0e4 :
O.OeO :

L

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
1.0e6 -

5.0e5 -

HFPO DA

Cone. 1.0958

R#1 329.00>285.10 77.41 (68.92)
Q 329.00>169.00 (-)	1.78e4

|A=42859

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 26.42 (27.58)

ISTD 329.00>309.15 (-)	8.46e4

6.2 6.4
RT (min)

PFHxA

Cone. 1.1721

R#1 313.00> 119.10 2.62 (2.54)
Q 313.00>269.00 (-)	2.22e5

TA= 540874

2.0e5-R1 262 ("t)RT=5.954

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

7.12e5 Q 314.90>270.10 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

A=1761603
RT= 5.954

6.2
RT (min)

13C-PFHpA

Cone. 4.4381

Q 366.90>322.10 (-)
7.5e5 -
5.0e5 ^

2.5e5 ^

O.OeO 1 . .

A=1840705
RT=6.361

6.6

RT (min)

13C2-6 2-FTS

Cone. 3.8160

Q 428.90>409.00 (-)
1.5e5 -
1.0e5^

5.0e4 ^

O.OeO 1, i i

A=367046
RT=6.662

RT (min)

RT (min)

13C-PFOA

Cone. 4.8235

Q 416.80>372.05 (-)
1.0e6 -

5.0e5 -

6.8 7.0
RT (min)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

6.2
RT (min)

180-PFHxS IS

Cone. 4.7250

7.90e5 ISTD 402.70>84.05 (-)

|A=5
RT='

515071
6.368

O.OeO -



6.6

RT (min)

6.2

6.4

L

M

L

6.8 7.0
RT (min)

13C-4 2-FTS

Cone. 3.5534

R#1 329.00>81.00 26.42 (27.58)
Q 329.00>309.15 (-)	8.46e4

~ A=201591
7.5e4- R1 2642 (- ^=5-900

4-2-FtS

Cone. 1.1168

R#1 327.00>81.10 13.79 (15.16)
Q 327.00>307.05 (-)	2.33e4

]R1 13.79 (-

V.1

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 0.9706

R#1 349.00>99.00 80.64 (80.87)
Q 349.00>79.95 (-)	3.13e4

6.2
RT (min)

O.OeO

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.9206

R#1 399.00 >99.00 97.70 (92.02)
Q 399.00>80.00 (-)	2.17e4

f A=62593
2.0e4-|R1 97.70 (-1-^1=6.368

O.OeO -



6.2

6.4

180-PFHxS

Cone. 4.2647

2.26e5 Q 402.70>84.05 (-)

6.6
RT (min)

PFHpA

Cone. 1.1233

R#1 362.90>169.00 17.58 (17.74)
Q 362.90>319.00 (-)	2.65e5

O.OeO



>
ii

o



rA=615081

-

RT=6.368

R1 17.58 (-

mT=6.361

-

2.0e5 -





-

1.0e5-



I

: i

1 w

1-rVT	 0 OpO -

/

Vv

6.6
RT (min)

PFHpS

Cone. 0.9995

R#1 449.00>99.20 60.25 (65.35)
Q 449.00>80.15 (-)	3.24e4

~ A=74848

3.0e4-R1 60.25 (-|)l^T=6.671

2.0e4 :
1.0e4:
O.OeO :

6.2

6.4

6.6
RT (min)

6-2-FTS

Cone. 1.1519

R#1 427.00>80.90 29.28 (27.82)
Q 427.00>407.00 (-)	3.60e4

6.2

6.4

6.6
RT (min)

PFOA

Cone. 0.9863

R#1 413.00 > 169.10 27.66 (27.71)
Q 413.00>369.00 (-)	3.05e5

6.6 6.8

RT (min)

PFOS

Cone. 1.0017

R#1 499.00>99.00 90.99 (96.24)
Q 499.00>80.00 (-)	1.65e4

¥A=55127
1.5e4-|R1 90.99 (--4kT=6.969

1.0e4-
5.0e3 :
O.OeO :

3.0e4
2.0e4
1.0e4
O.OeO

fA=82525

R1 29-28 (4-^=6.662

3.0e5 :
2.0e5 :
1.0e5:
O.OeO -

A=713520

R1 27.66 (- =6

RT (min)

13C-PFOS IS

Cone. 4.7750

13C-PFOS

Cone. 4.0716

105 (-)

r4

RT=.

1.96e5 Q 502.80>80.05 (-)

477900
RT=6.968

6.75 7.00 7.25

RT (min)

L

6.8 7.0
RT (min)

A=477900
RT=6.968

6.8 7.0 7.2

RT (min)

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

61

-------
1st /S/ AO 10/24/23
2nd IS/ AO 10/26/23

A

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:00

CCV1-230426 (continued)

PFNA

Cone. 1.1079

R#1 463.00>219.00 19.56 (20.94)
Q 463.00>418.90 (-)	2.66e5

ITA=648480
-R1 19.56 ( U\=ec

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

A=234176
RT=7.323

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)

{A=633123
I RT=7.503

7.6 7.8
RT (min)

13C-PFUnDA

Cone. 4.4731

Q 564.80>519.95 (-)
1.0e6 -

O.OeO -

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)
1.0e6 -

13C-PFNA

Cone. 4.6489

Q 467.80>423.00 (-)
1.0e6 -

PFNS

Cone. 1.0574

R#1 549.00>99.00 68.32 (65.53)
1.08e6 Q 549.00>79.95 (-)

A= 127846

R1 68.32 (fl-Rt=7.296

13C-8 2-FTS

Cone. 3.4948

9.17e4 Q 528.80> 509.00 (-)

7.5e4 i
5.0e4 i
2.5e4 ~

O.OeO 1. . .

O.OeO

6.8 7.0 7.2

RT (min)

PFDA

Cone. 1.1221

R#1 512.90>219.00 17.77 (18.19)
Q 512.90>469.00 (-)	2.55e5

A=234176
RT=7.323

7.6
RT (min)

7.6
RT (min)

d3-N-MeFOSAA

Cone. 4.3035

2.33e5 Q 572.80>419.05 (-)

{A=633123
1 RT=7.503

4.0e4 -

O.OeO -

~ A= 130033

R1 37.64 (-4 ^j=7.508



7.4

7.25 7.50 7.75

7.6 7.8
RT (min)

PFUnDA

Cone. 1.1708
R#1 563.00>219.00 12.99 (11.87)

1.05e6 Q563.00>518.90 (-)	2.29e5 ISTD 588.80>419.00 (-)

d5-N-EtFOSAA IS

Cone. 5.0000

O.OeO

J ]

'A=635814



^ 7.675

I

iVT

7.6

7.6

7.8 8.0
RT (min)

PFOSA

Cone. 1.0222
R#1 498.20>64.10 0.34 (0.15)

Q 498.20>78.00 (-)	5.12e4 ISTD 506.00>78.05 (-)

7.8 8.0
RT (min)

13C-FOSA IS

Cone. 5.0000

13C-FOSA

Cone. 4.5405

2.42e5 Q 506.00>78.05 (-)

A= 130644

- R1 0.34 (—

7.8 8.0

RT (min)

8-2-FTS

Cone. 1.2953

R#1 527.20>487.00 6.06 (5.33)
5.09e4 Q 527.10>506.90 (-)	I

(A=61239

2.0e4HR1 6.06 HHt=7.323

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

O.OeO TJk".

7.2 7.4 7.6

RT (min)

NMeFOSAA

Cone. 1.0252

R#1 570.20>512.00 37.64(35.78)
Q 570.20>419.00 (-)	4.10e4

O.OeO -

7.2

7.4

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 4.4999

2.68e5 Q 588.80>419.00 (-)

7.8 8.0
RT (min)

2.0e5 -

A= 536176
R1 16.14 -rj)=8.018

7.6 7.8 8.0

RT (min)

7.4 7.6
RT (min)

7.6
RT (min)

13C-PFDA

Cone. 4.5990

1.19e6 Q 514.80>469.95 (-)

7.6
RT (min)

PFDS

Cone. 1.0651

R#1 599.00>99.00 59.21 (60.20)
Q 599.00>80.10 (-)	3.27e4

7.4 7.6

RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)
1.0e6-

O.OeO -

7.6

7.8 8.0
RT (min)

NEtFOSAA

Cone. 1.0786

R#1 584.20>526.10 52.21 (55.50)
Q 584.20>418.95 (-)	4.50e4

4.0e4-R1 5221 (-

A= 145732
"At=7.695

O.OeO -

7.8 8.0
RT (min)

PFDoA

Cone. 1.0405

R#1 613.05> 169.00 16.14(15.47)
Q 613.05>569.00 (-)	2.03e5

O.Oe01, ^rrrfi

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)
1.0e6H

1.03e6

A=2717987
RT=8.019

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

62

-------
1st /S/ AO 10/24/23
2nd IS/ AO 10/26/23



Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:00

CCV1-230426 (continued)

13C-PFDoA

Cone. 4.4335

Q614.80>569.95 (-)
1.0e6 H

10-2-FtS

Cone. 1.2583

R#1 626.50>81.05 57.31 (56.92)
Q 626.50>607.05 (-)	2.8

A=2717987
RT=8.019



fA=74347

- R1 57.31

mT)= 8.030

:

i

:	I

L

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)
2.0e51

RT (min)

RT (min)

NEtFOSE

Cone. 0.9450

d9-EtFOSE IS

Cone. 5.0000

d5-NEtFOSA

Cone. 4.1960

2.05e5 Q 531.10> 169.10 (-)
2.0e51

O.OeO -

NMeFOSE

Cone. 0.9164

2.05e5 Q 616.10> 58.90 (-)
2.0e4 -

9.0
RT (min)

NMeFOSA

Cone. 1.1337

R#1 512.10>219.20 78.96 (86.99)
Q 512.10> 169.20 (-)	1.86e4

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

d3-NMeFOSA

Cone. 4.3816

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

d7-N-MeFOSE IS

Cone. 5.0000

1.91e5 ISTD 623.00>59.00 (-)

d7-N-MeFOSE

Cone. 5.1110

1.36e5 Q 623.00> 59.00 (-)

8.4 8.6

RT (min)

NEtFOSA

Cone. 1.0386

R#1 526.50>219.20 64.27 (64.74)
Q 526.50>169.10 (-)	3.07e4

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 0.9278

R#1 713.00>169.30 10.25 (10.03)
Q 713.00>668.90 (-)	1.95e5

RT (min)

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 1.0370

R#1 663.10> 169.10 17.38 (18.77)
Q 663.10>618.90 (-)	2.16e5

f A =544860

2.0e5HR1 17.38 1-^=8.346

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 4.8353

Q 714.80>669.80 (-)

11CI-PF30UdS

Cone. 1.0622

Q 631.00>451.10 (-)

10913
7.829

9CI-PF30NS

Cone. 1.0647

Q 531.00>351.10 (-)

1.0e5 —I	TA=2

I RT=

247226
RT=7.151

O.OeO

9.0
RT (min)

L-PFDoS

Cone. 1.1638

R#1 698.80 >98.80 66.78 (68.45)
Q 698.80>80.10 (-)	1.74e4

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

8.09e4 ISTD 815.00>770.00 (-)
1.5e6H

A=3582389
RT=9.175

8.4 8.6
RT (min)

6.6

RT (min)

9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

63

-------
1st /S/ AO 10/24/23
2nd IS/ AO 10/26/23

(ALSJ

CCV1-230426 (continued)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:00

13C2-PFHxDA

Cone. 4.3672

Q 815.00>770.00 (-)
1.5e6-

1.0e6 ^

5.0e5 :

A=3582389
RT=9.175

13C7-PFUnDA IS

Cone. 5.0000

1.55e6 ISTD 569.80>524.90 (-)
1.0e6 -

O.OeO -



Vj

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	3.00e0

5.0e0 -

0.2
RT (min)

PFecHS	PFBSA

Cone. 0.8067	Cone. 1.0357
R#1 461.00>99.10 37.25 (37.10)

1.04e6 Q 461.00>381.00 (-)	1.45e5 Q 298.00>78.00 (-)

A=2817773	¥A=365724

RT=7.675	: R1 37 25 ("Mt=6.630	I

PFHxSA

Cone. 1.0232

1.26e5 Q 397.90>78.00 (-)

8.0
RT (min)

6.4 6.6 6.8

RT (min)

rA=285076
RT=6.964

6.4
RT (min)

7.2
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

64

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:05

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/26/2023 10:39:41 PM

Acquired by: System Administrator

Data File: 230426018

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.211

815267

815267

	 	

5.0000

nq/mL

1BC-PFBA

Auto

4.211

815267

2746360

13C7-PFUnDA IS

4.7272

nq/mL

PFBA

Auto

4.211

13706

815267

13C-PFBA IS

0.0742

nq/mL

13C-PFPeA IS

Auto

5.374

1239690

1239690

	 	

5.0000

nq/mL

13C-PFPeA

Auto

5.374

1239690

2746360

13C7-PFUnDA IS

4.3721

nq/mL

PFPeA

Auto

5.374

23524

1239690

13C-PFPeA IS

0.0973

nq/mL

13C-PFBS IS

Auto

5.504

498723

498723

	 	

4.6500

nq/mL

13C-PFBS

Auto

5.504

498723

2746360

13C7-PFUnDA IS

4.2858

nq/mL

PFBS

Auto

5.502

5813

498723

13C-PFBS IS

0.0710

nq/mL

13C HFPO DA IS

Auto

6.106

246800

246800

	 	

5.0000

nq/mL

13C HFPO DA

Auto

6.106

246800

2746360

13C7-PFUnDA IS

4.1844

nq/mL

HFPO DA

Auto

6.105

3965

246800

13C HFPO DA IS

0.1014

nq/mL

13C-4 2-FTS IS

Auto

5.907

185515

185515

	 	

4.6700

nq/mL

13C-4 2-FTS

Auto

5.907

185515

2746360

13C7-PFUnDA IS

3.3550

nq/mL

4-2-FtS

Auto

5.907

4495

185515

13C-4 2-FTS IS

0.0970

nq/mL

PFHxA

Auto

5.962

44672

1742045

13C-PFHxA IS

0.0979

nq/mL

13C-PFHxA IS

Auto

5.961

1742045

1742045

	 	

5.0000

nq/mL

13C-PFHxA

Auto

5.961

1742045

2746360

13C7-PFUnDA IS

4.2766

nq/mL

PFPeS

Auto

6.002

7008

506574

180-PFHxS IS

0.0926

nq/mL

PFHxS

Auto

6.375

5278

506574

180-PFHxS IS

0.0789

nq/mL

13C-PFHpA IS

Auto

6.369

1771834

1771834

	 	

5.0000

nq/mL

13C-PFHpA

Auto

6.369

1771834

2746360

13C7-PFUnDA IS

4.3831

nq/mL

180-PFHxS IS

Auto

6.374

506574

506574

	 	

4.7250

nq/mL

180-PFHxS

Auto

6.374

506574

2746360

13C7-PFUnDAJS

4.3034

ng/mL

PFHpA

Auto

6.369

53947

1771834

13C-PFHpA IS

0.1023

ng/mL

13C2-6 2-FTS IS

Auto

6.669

359155

359155

—-

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.669

359155

2746360

13C7-PFUnDA IS

3.8311

ng/mL

PFHpS

Auto

6.679

5739

506574

180-PFHxS IS

0.0779

nq/mL

6-2-FTS

Auto

6.668

6289

359155

13C2-6 2-FTS IS

0.0897

nq/mL

PFOA

Auto

6.687

62161

2586516

13C-PFOA IS

0.0870

nq/mL

13C-PFOA IS

Auto

6.687

2586516

2586516

	 	

5.0000

nq/mL

13C-PFOA

Auto

6.687

2586516

2746360

13C7-PFUnDA IS

4.8868

nq/mL

PFOS

Auto

6.976

4790

480777

13C-PFOS IS

0.0865

nq/mL

13C-PFOS IS

Auto

6.975

480777

480777

	 	

4.7750

nq/mL

13C-PFOS

Auto

6.975

480777

2746360

13C7-PFUnDA IS

4.2026

nq/mL

PFNA

Auto

6.996

58587

2715299

13C-PFNA IS

0.0978

nq/mL

13C-PFNA IS

Auto

6.996

2715299

2715299

	 	

5.0000

nq/mL

13C-PFNA

Auto

6.996

2715299

2746360

13C7-PFUnDA IS

4.8821

nq/mL

PFNS

Auto

7.303

13046

480777

13C-PFOS IS

0.1073

nq/mL

8-2-FTS

Auto

7.331

3518

244502

13C-8 2-FTS IS

0.0713

nq/mL

13C-8 2-FTS IS

Auto

7.330

244502

244502

	 	

4.7900

nq/mL

13C-8 2-FTS

Auto

7.330

244502

2746360

13C7-PFUnDA IS

3.7438

nq/mL

PFDA

Auto

7.335

50492

2868221

13C-PFDA IS

0.0937

r

13C-PFDA IS

Auto

7.334

2868221

2868221

	 	

5.0000

ng/mL

13C-PFDA

Auto

7.334

2868221

2746360

13C7-PFUnDA IS

4.5445

r

d3-N-MeFOSAA IS

Auto

7.511

639394

639394

	 	

5.0000

ng/mL

cB-N-MeFOSAA

Auto

7.511

639394

2746360

13C7-PFUnDA IS

4.4592

r

NMeFOSAA

Auto

7.514

9532

639394

d3-N-MeFOSAA IS

0.0744

nq/mL

PFDS

Auto

7.643

8820

480777

13C-PFOS IS

0.1093

r

13C-PFUnDA IS

Auto

7.683

2892551

2892551

	 	

5.0000

ng/mL

13C-PFUnDA

Auto

7.683

2892551

2746360

13C7-PFUnDA IS

4.6723

r

PFUnDA

Auto

7.683

57793

2892551

13C-PFUnDA IS

0.1045

ng/mL

d5-N-EtFOSAA IS

Auto

7.695

727072

727072

	 	

5.0000

r

d5-N-EtFOSAA

Auto

7.695

727072

2746360

13C7-PFUnDA IS

4.5199

ng/mL

NEtFOSAA

Auto

7.703

13261

727072

dS-N-EtFOSAA IS

0.1003

r

PFOSA

Auto

7.753

11506

618548

13C-FOSA IS

0.0889

ng/mL

13C-FOSA IS

Auto

7.753

618548

618548

	 	

5.0000

r

13C-FOSA

Auto

7.753

618548

2746360

13C7-PFUnDA IS

4.7148

nq/mL

PFDoA

Auto

8.028

48802

2698517

13C-PFDoA IS

0.0954

nq/mL

13C-PFDoA IS

Auto

8.027

2698517

2698517

	 	

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

65

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:05

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone. Cone.

Unit

1BC-PFDoA

Auto

8.027

2698517

2746360

13C7-PFUnDA IS

—- 4.5162

nq/mL

10-2-FtS

Auto

8.040

6471

244502

13C-8 2-FTS IS

—- 0.1049

ng/mL

d5-NEtFOSA IS

Auto

8.783

532278

532278

—

—- 5.0000

nq/mL

d5-NEtFOSA

Auto

8.783

532278

2746360

13C7-PFUnDA IS

—- 4.4127

ng/mL

NMeFOSE

Auto

8.506

5959

333787

d7-N-MeFOSE IS

—- 0.0985

nq/mL

NEtFOSE

Auto

8.757

17045

215986

d9-EtFOSE IS

—- 0.1007

ng/mL

d9-EtFOSE IS

Auto

8.739

215986

215986

—

—- 5.0000

nq/mL

d9-EtFOSE

Auto

8.739

215986

2746360

13C7-PFUnDA IS

—- 4.5133

ng/mL

NMeFOSA

Auto

8.531

4280

516720

d3-NMeFOSA IS

—- 0.0954

nq/mL

dB-NMeFOSA IS

Auto

8.526

516720

516720

	

—- 5.0000

ng/mL

dB-NMeFOSA

Auto

8.526

516720

2746360

13C7-PFUnDA IS

—- 4.6432

nq/mL

d7-N-MeFOSE IS

Auto

8.491

333787

333787

	

—- 5.0000

ng/mL

d7-N-MeFOSE

Auto

8.491

333787

2746360

13C7-PFUnDA IS

—- 5.2145

nq/mL

NEtFOSA

Auto

8.792

8077

532278

d5-NEtFOSA IS

—- 0.1041

ng/mL

PFTrDA

Auto

8.354

50459

1641074

13C-PFTeDA IS

—- 0.0985

nq/mL

PFTeDA

Auto

8.654

48653

1641074

13C-PFTeDA IS

—- 0.0912

ng/mL

13C-PFTeDA IS

Auto

8.654

1641074

1641074

—

—- 5.0000

nq/mL

13C-PFTeDA

Auto

8.654

1641074

2746360

13C7-PFUnDA IS

—- 4.8383

ng/mL

11CI-PFBOUdS

Auto

7.837

8650

480777

13C-PFOS IS

—- 0.0823

nq/mL

9CI-PF30NS

Auto

7.157

21916

480777

13C-PFOS IS

—- 0.0938

ng/mL

L-PFDoS

Auto

8.304

3310

480777

13C-PFOS IS

—- 0.0935

nq/mL

NaDONA

Auto

6.412

32747

2715299

13C-PFNA IS

—- 0.0771

ng/mL

PFHxDA

Auto

9.181

47655

3626218

13C2-PFHxDA IS

—- 0.0978

nq/mL

PFODA

Auto

9.726

20460

3626218

13C2-PFHxDA IS

—- 0.1039

ng/mL

13C2-PFHxDA IS

Auto

9.181

3626218

3626218

—

—- 5.0000

nq/mL

13C2-PFHxDA

Auto

9.181

3626218

2746360

13C7-PFUnDA IS

—- 4.5356

ng/mL

13C7-PFUnDA IS

Auto

7.683

2746360

2746360

—

—- 5.0000

nq/mL

PFecHS

Auto

6.638

40544

480777

13C-PFOS IS

—- 0.0889

ng/mL

PFBSA

Auto

6.146

27746

618548

13C-FOSA IS

—- 0.0915

nq/mL

PFHxSA

Auto

6.969

25683

2715299

13C-PFNA IS

—- 0.0901

ng/mL

CHARGE

ND(W/B)

	

	

2746360

13C7-PFUnDA IS

	 	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 4.7272
1.75e5 Q 217.20>172.30 (-)

1.5e5 -
1.0e5:
5.0e4 :

O.OeO -tj;

A=815267
RT=4.211

PFBA

Cone. 0.0742
1.75e5 Q 213.20> 169.10 (-)

4.0e3 -i

13C-PFPeA IS

Cone. 5.0000
4.03e3 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.3721
4.92e5 Q 267.90>223.00 (-)

TA= 13706
RT=4.211

fA= 1239690
I RT= 5.374

fA= 1239690
I RT= 5.374

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 0.0973

O.OeO -tj;

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

O.OeO -

O.OeO -

4.00 4.25 4.50

RT (min)

5.2

5.4

5.2

5.4

13C-PFBS

Cone. 4.2858

Q263.05>219.10 (-)

8.59e3 ISTD 301.80>80.00 (-)

1.75e5 Q 301.80>80.00 (-)

5.6

RT (min)

PFBS

Cone. 0.0710
R#1 298.80>99.00 71.00 (72.97)

1.75e5 Q 299.00>80.00 (-)	2.17e3 ISTD 332.10>287.10 (-)

5.6

RT (min)

13C HFPO DA IS

Cone. 5.0000

1.0e5-

6.2 6.4
RT (min)

A=498723
RT= 5.504

5.0e3 -
2.5e3 ^
O.OeO1

23524
= 5.374

A=498723

RT= 5.504	2.0e3-

TA=5813
R1 71.00 (4^1=5.502

1.0e5 -
5.0e4 :
O.OeO :

5.6 5.8
RT (min)

1.0e5 -
5.0e4 :
O.OeO :

5.6

RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

66

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:05

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 4.1844

Q 332.10>287.10 (-)
1.0e5 -

HFPO DA

Cone. 0.1014

R#1 329.00>285.10 65.89 (68.92)
Q 329.00>169.00 (-)	1.51e3

A=246800
RT=6.106

O.OeO -

1.5e3 -
1.0e3 -
5.0e2 ^
O.OeO -

: R1 65.89 (-

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 0.0979

R#1 313.00> 119.10 1.98 (2.54)
Q 313.00>269.00 (-)	1.86e4

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

7.55e5 Q 366.90>322.10 (-)

fA= 1771834
| RT=6.369

A=1771834
RT=6.369

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

6.6

RT (min)

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)
1.5e5 i

13C2-6 2-FTS

Cone. 3.8311

Q 428.90>409.00 (-)

A=359155
RT=6.669

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
1.0e6 -

13C-PFOA

Cone. 4.8868

A=2586516
RT=6.687

Q 416.80>372.05 (-)
1.0e6 -

A=2586516
RT=6.687

6.8 7.0
RT (min)

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 30.14 (27.58)

ISTD 329.00>309.15 (-)	7.20e4

13C-4 2-FTS

Cone. 3.3550

R#1 329.00>81.00 30.14 (27.58)
Q 329.00>309.15 (-)	7.20e4

4-2-FtS

Cone. 0.0970

R#1 327.00>81.10 9.87 (15.16)
Q 327.00>307.05 (-)	1.79e3

A=185515

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

:R1 30.14 (-

A=185515

6.0e4 -
4.0e4z_
2.0e4z_
O.OeO -

: R1 30.14 (-

6.2 6.4
RT (min)

6.0 6.2
RT (min)

13C-PFHxA

Cone. 4.2766

7.04e5 Q 314.90>270.10 (-)

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 0.0926

R#1 349.00>99.00 94.47 (80.87)
Q 349.00>79.95 (-)	2.92e3

f A=7008

I R1 94.47 (--| kT=6.002

6.0 6.2
RT (min)

PFHxS

Cone. 0.0789

R#1 399.00 >99.00 90.87 (92.02)
Q 399.00>80.00 (-)	2.01e3

6.2
RT (min)

6.2
RT (min)

2.0e3

A=5278

JR1 90.87 (- -kT=6.375

180-PFHxS IS

Cone. 4.7250

180-PFHxS

Cone. 4.3034

ISTD 402.70>84.05 (-)
2.0e5 -

O.OeO -

Q 402.70>84.05 (-)
2.0e5 -

O.OeO -

O.OeO

6.6
RT (min)

PFHpA

Cone. 0.1023

R#1 362.90 >169.00 19.41 (17.74)
Q 362.90>319.00 (-)	2.31e4

r a = 53947
2.0e4 -|R1 1941 ("jpT=6.369

O.OeO -

6.2

6.4

6.6
RT (min)

PFHpS

Cone. 0.0779

R#1 449.00>99.20 40.80 (65.35)

6.2

6.4

6.6
RT (min)

6-2-FTS

Cone. 0.0897

R#1 427.00>80.90 32.10 (27.82)

6.2

6.4

6.6
RT (min)

PFOA

Cone. 0.0870

R#1 413.00> 169.10 31.69 (27.71)

1.53e5 Q 449.00>80.15 (-)

2.56e3 Q 427.00>407.00 (-)

3.06e3 Q 413.00>369.00 (-)

2.72e4

A=62161
-kl=6.687

13C-PFOSJS

Cone. 4.7750

O.OeO

6.6 6.8

RT (min)

PFOS

Cone. 0.0865

R#1 499.00>99.00 126.38 (96.24)

Q 499.00> 80.00 (-)	1,23e3 I STD 502.80 > 80.05 (-)

A=4790	Y A=480777

1-5e3:Ri 126.3BM976	"	RT=6.975

1.0e3 -
5.0e2 ^

O.OeO :

1.95e5 Q 502.80>80.05 (-)

f A=480777
RT=6.975

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

67

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:05

L0.1ppb_230323 (continued)

13C-PFNA IS

Cone. 5.0000

PFNA

Cone. 0.0978
R#1 463.00>219.00 18.47 (20.94)

Q 463.00>418.90 (-)	2.36e4 ISTD 467.80>423.00 (-)

r A=2715299
RT=6.996

13C-PFNA

Cone. 4.8821

Q 467.80>423.00 (-)
1.0e6

5.0e5

O.OeO

PFNS

Cone. 0.1073

R#1 549.00>99.00 41.40 (65.53)
1.11e6 Q 549.00>79.95 (-)

A=2715299
RT=6.996

O.OeO -

8-2-FTS

Cone. 0.0713

R#1 527.20>487.00 7.74 (5.33)
5.41 e3 Q 527.10>506.90 (-)

fA=3518

1.5e3HR1 7.74 (-S-fcT=7.331

1.0e3-
5.0e2 :
O.OeO :

7.2

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 3.7438

9.54e4 Q 528.80> 509.00 (-)

7.2

RT (min)

PFDA

Cone. 0.0937
R#1 512.90>219.00 19.24(18.19)

Q 512.90>469.00 (-)	2.05e4 ISTD 514.80>469.95 (-)

13C-PFDAJS

Cone. 5.0000

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

A=244502
RT=7.330

7.2

7.4 7.6

RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

2.0e4 -

A= 50492

R1 19.24 (- -|^r=7.335

7.4 7.6

RT (min)

fA=2868221
RT=7.334

d3-N-MeFOSAA

Cone. 4.4592

ISTD 572.80>419.05 (-)

2.29e5 Q 572.80>419.05 (-)

O.OeO

7.6
RT (min)

NMeFOSAA

Cone. 0.0744

R#1 570.20>512.00 37.68 (35.78)
Q 570.20>419.00 (-)	3.84e3

fA=639394
RT=7.511

TA=639394
RT=7.511

O.OeO -

7.6 7.8
RT (min)

7.4

7.25 7.50 7.75

13C-PFUnDA

Cone. 4.6723

Q 564.80>519.95 (-)
1.0e6 -

d5-N-EtFOSAA IS

Cone. 5.0000

A=2892551
RT=7.683

7.6 7.8
RT (min)

PFUnDA

Cone. 0.1045
R#1 563.00>219.00 8.43 (11.87)

1,08e6 Q 563.00> 518.90 (-)	2.13e4 ISTD 588.80>419.00 (-)

jfA= 57793
2.0e4HR1 8.43 (- j£r=7.683

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 4.5199

2.65e5 Q 588.80>419.00 (-)

O.OeO -

O.OeO

7.6

13C-FOSA IS

Cone. 5.0000

7.8 8.0
RT (min)

PFOSA

Cone. 0.0889
R#1 498.20>64.10 1.24 (0.15)

Q 498.20>78.00 (-)	4.47e3 ISTD 506.00>78.05 (-)

r A=11506
4.0e3 ^R1 124 (—|RT=7.753

O.OeO -

7.8 8.0
RT (min)

7.6

13C-FOSA

Cone. 4.7148

2.43e5 Q 506.00>78.05 (-)

7.8 8.0

RT (min)

7.8 8.0

RT (min)

7.6 7.8 8.0

RT (min)



7.4 7.6
RT (min)

7.6
RT (min)

13C-PFDA

Cone. 4.5445

1.15e6 Q 514.80>469.95 (-)

t A=2868221
RT=7.334

O.OeO . 	

7.6
RT (min)

PFDS

Cone. 0.1093

R#1 599.00>99.00 43.13 (60.20)
Q 599.00>80.10 (-)	3.37e3

7.4 7.6

RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)	1.08e6

1.0e6-

O.OeO -

7.6

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.1003

R#1 584.20>526.10 47.68 (55.50)
Q 584.20>418.95 (-)	4.17e3

4,0e3 -

R1 47.68 (--

A= 13261

RT=7.703

O.OeO

7.8 8.0
RT (min)

PFDoA

Cone. 0.0954

R#1 613.05 > 169.00 15.21 (15.47)
Q 613.05>569.00 (-)	1.86e4

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)
1.0e6-|

1.02e6

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

68

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:05

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 4.5162

Q614.80>569.95 (-)
1.0e6 i

NEtFOSE

Cone. 0.1007

d5-NEtFOSA IS

Cone. 5.0000

10-2-FtS

Cone. 0.1049
R#1 626.50 >81.05 46.61 (56.92)

1,02e6 Q 626.50>607.05 (-)	2.50e3 ISTD 531.10> 169.10 (-)

RT (min)

d5-NEtFOSA

Cone. 4.4127

2.11e5 Q 531.10> 169.10 (-)

NMeFOSE

Cone. 0.0985

2.11e5 Q 616.10>58.90 (-)

Q 629.50>59.10 (-)

d3-NMeFOSA

Cone. 4.6432

Q 515.10> 169.00 (-)

O.OeO -

d7-N-MeFOSE IS

Cone. 5.0000

1,97e5 I STD 623.00 > 59.00 (-)

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 0.0912

R#1 713.00 >169.30 9.10 (10.03)
Q 713.00>668.90 (-)	1.83e4

13C-PFTeDA IS

Cone. 5.0000

I STD 714.80 >669.80 (-)

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

A=215986
RT=8.739



9.0
RT (min)

d7-N-MeFOSE

Cone. 5.2145

1.35e5 Q 623.00> 59.00 (-)

T A=4280

1.5e3HR1 79.72 (--|Ut=8.531

1.0e3-
5.0e2 :
O.OeO :



9.0
RT (min)

1.35e5 Q 526.50> 169.10 (-)

RT (min)

13C-PFTeDA

Cone. 4.8383

6.35e5 Q 714.80>669.80 (-)

RT (min)

6.35e5 Q 631.00>451.10 (-)

O.OeO -

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.1041

R#1 526.50>219.20 56.67 (64.74)

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.0985

R#1 663.10> 169.10 17.18 (18.77)

3.00e3 Q 663.10>618.90 (-)

2.09e4

3.78e3 Q 531.00>351.10 (-)

9.0
RT (min)

L-PFDoS

Cone. 0.0935

R#1 698.80 >98.80 82.39 (68.45)
Q 698.80>80.10 (-)	1.38e3

fA=3310

: R1 8239 (|Rt=8.304

Q 377.10>251.20 (-)

1.41e4 Q 812.90>769.00 (-)
2.0e4 H

2.07e4 Q 912.80>869.00 (-)

A=47655
RT=9.181

B.2 8.4 8.6

RT (min)

6.6

RT (min)

9.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

7.37e3 I STD 815.00 > 770.00 (-)
1.5e6-

9.4

RT (min)

O.OeO 1,1,7 Al'i VtT i | i i —r
8.6 8.8 9.0

RT (min)

d9-EtFOSE

Cone. 4.5133

Q 638.90> 59.10 (-)	8.42e4

O.OeO 4

8.6 8.8 9.0

RT (min)

NMeFOSA

Cone. 0.0954

R#1 512.10>219.20 79.72 (86.99)
Q 512.10> 169.20 (-)	1.63e3

d9-EtFOSE IS

Cone. 5.0000

iSTD 638.90>59.10 (-)

B.2

RT (min)

A=5959
RT=8.506

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)	1.97e5

3.0e3
2.0e3
1.0e3
O.OeO

2-0e4 i R1 17.18

9.0

RT (min)

11CI-PF30UdS

Cone. 0.0823

9CI-PF30NS

Cone. 0.0938

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

69

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A

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:05

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 4.5356

Q 815.00>770.00 (-)
1.5e6 -
1.0e6-j
5.0e5 ^

O.OeO 1. . . .

13C7-PFUnDA IS

Cone. 5.0000

1.57e6 ISTD 569.80>524.90 (-)
1.0e6 H

PFecHS	PFBSA

Conc. 0.0889	Conc. 0.0915
R#1 461.00>99.10 40.58 (37.10)

1.03e6 Q 461.00>381.00 (-)	1.57e4	Q 298.00>78.00 (-)

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

1.5e4-
1.0e4^
5.0e3 -
O.OeO:

R1 40.58 (-

A=40544
[kl=6.638

8.0
RT (min)

6.4 6.6 6.8

RT (min)

PFHxSA

Cone. 0.0901

1.11e4 Q 397.90>78.00 (-)
1.0e4-

6.4
RT (min)

7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

70

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:09

CCV2-230426

Sample ID: CCV2-230426

Date Acquired: 4/26/2023 11:07:10 PM

Acquired by: System Administrator

Data File: 230426020

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.208

905208

905208

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.208

905208

3039063

13C7-PFUnDA IS

5.0000

4.7432

nq/mL

PFBA

Auto

4.208

1026143

905208

13C-PFBA IS

5.0000

4.9998

nq/mL

13C-PFPeA IS

Auto

5.369

1456391

1456391

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.369

1456391

3039063

13C7-PFUnDA IS

5.0000

4.6417

nq/mL

PFPeA

Auto

5.370

1323928

1456391

13C-PFPeA IS

5.0000

4.6612

nq/mL

13C-PFBS IS

Auto

5.499

557967

557967

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.499

557967

3039063

13C7-PFUnDA IS

4.6500

4.3331

nq/mL

PFBS

Auto

5.499

370175

557967

13C-PFBS IS

4.4200

4.0404

nq/mL

13C HFPO DA IS

Auto

6.101

285241

285241

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.101

285241

3039063

13C7-PFUnDA IS

5.0000

4.3703

nq/mL

HFPO DA

Auto

6.102

213498

285241

13C HFPO DA IS

5.0000

4.7263

nq/mL

13C-4 2-FTS IS

Auto

5.902

227244

227244

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.902

227244

3039063

13C7-PFUnDA IS

4.6700

3.7139

nq/mL

4-2-FtS

Auto

5.902

259679

227244

13C-4 2-FTS IS

4.6700

4.5756

nq/mL

PFHxA

Auto

5.956

2608714

1968332

13C-PFHxA IS

5.0000

5.0594

nq/mL

13C-PFHxA IS

Auto

5.956

1968332

1968332

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

5.956

1968332

3039063

13C7-PFUnDA IS

5.0000

4.3667

nq/mL

PFPeS

Auto

5.997

387983

577415

180-PFHxS IS

4.6900

4.4982

nq/mL

PFHxS

Auto

6.369

294465

577415

180-PFHxS IS

4.5500

3.8633

nq/mL

13C-PFHpA IS

Auto

6.363

1949539

1949539

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.363

1949539

3039063

13C7-PFUnDA IS

5.0000

4.3582

nq/mL

180-PFHxS IS

Auto

6.369

577415

577415

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.369

577415

3039063

13C7-PFUnDAJS

4.7250

4.4328

ng/mL

PFHpA

Auto

6.363

2967494

1949539

1 3C-PFHpA IS

5.0000

5.1168

ng/mL

13C2-6 2-FTS IS

Auto

6.663

385496

385496

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.663

385496

3039063

1 3C7-PFUnDA IS

4.7500

3.7160

ng/mL

PFHpS

Auto

6.673

379951

577415

180-PFHxS IS

4.7600

4.5258

nq/mL

6-2-FTS

Auto

6.663

345990

385496

13C2-6 2-FTS IS

4.7400

4.5981

nq/mL

PFOA

Auto

6.682

3390570

2768577

13C-PFOA IS

5.0000

4.4342

nq/mL

13C-PFOA IS

Auto

6.681

2768577

2768577

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.681

2768577

3039063

13C7-PFUnDA IS

5.0000

4.7270

nq/mL

PFOS

Auto

6.971

269569

544540

13C-PFOS IS

4.6400

4.2990

nq/mL

13C-PFOS IS

Auto

6.971

544540

544540

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

6.971

544540

3039063

13C7-PFUnDA IS

4.7750

4.3016

nq/mL

PFNA

Auto

6.992

3081983

2898298

13C-PFNA IS

5.0000

4.8193

nq/mL

13C-PFNA IS

Auto

6.992

2898298

2898298

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.992

2898298

3039063

13C7-PFUnDA IS

5.0000

4.7092

nq/mL

PFNS

Auto

7.299

636990

544540

13C-PFOS IS

4.8000

4.6236

nq/mL

8-2-FTS

Auto

7.325

266182

266152

13C-8 2-FTS IS

4.7900

4.9536

nq/mL

13C-8 2-FTS IS

Auto

7.325

266152

266152

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.325

266152

3039063

13C7-PFUnDA IS

4.7900

3.6828

nq/mL

PFDA

Auto

7.330

2919914

3187344

13C-PFDA IS

5.0000

4.8766

r

13C-PFDA IS

Auto

7.330

3187344

3187344

	

5.0000

5.0000

ng/mL

13C-PFDA

Auto

7.330

3187344

3039063

13C7-PFUnDA IS

5.0000

4.5637

r

d3-N-MeFOSAA IS

Auto

7.506

756022

756022

	

5.0000

5.0000

ng/mL

cB-N-MeFOSAA

Auto

7.506

756022

3039063

13C7-PFUnDA IS

5.0000

4.7647

r

NMeFOSAA

Auto

7.510

707089

756022

d3-N-MeFOSAA IS

5.0000

4.6687

nq/mL

PFDS

Auto

7.638

425269

544540

13C-PFOS IS

4.8200

4.6546

r

13C-PFUnDA IS

Auto

7.679

3129335

3129335

	

5.0000

5.0000

ng/mL

13C-PFUnDA

Auto

7.679

3129335

3039063

13C7-PFUnDA IS

5.0000

4.5679

r

PFUnDA

Auto

7.679

3114008

3129335

13C-PFUnDA IS

5.0000

5.2062

ng/mL

d5-N-EtFOSAA IS

Auto

7.691

828909

828909

	

5.0000

5.0000

r

d5-N-EtFOSAA

Auto

7.691

828909

3039063

13C7-PFUnDA IS

5.0000

4.6567

ng/mL

NEtFOSAA

Auto

7.698

750102

828909

dS-N-EtFOSAA IS

5.0000

4.9742

r

PFOSA

Auto

7.748

631810

685976

13C-FOSA IS

5.0000

4.4042

ng/mL

13C-FOSA IS

Auto

7.748

685976

685976

	

5.0000

5.0000

r

13C-FOSA

Auto

7.748

685976

3039063

13C7-PFUnDA IS

5.0000

4.7252

nq/mL

PFDoA

Auto

8.023

2725012

3040593

13C-PFDoA IS

5.0000

4.7270

nq/mL

13C-PFDoA IS

Auto

8.023

3040593

3040593

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

71

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:09

CCV2-230426 (continued)













(Table continued from previous page)
Name Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.023

3040593

3039063

13C7-PFUnDA IS

5.0000

4.5986

nq/mL

10-2-FtS

Auto

8.035

362306

266152

13C-8 2-FTS IS

4.8200

5.3953

ng/mL

d5-NEtFOSA IS

Auto

8.774

558534

558534

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.774

558534

3039063

13C7-PFUnDA IS

5.0000

4.1844

ng/mL

NMeFOSE

Auto

8.499

291593

364023

d7-N-MeFOSE IS

5.0000

4.4182

nq/mL

NEtFOSE

Auto

8.748

866645

232919

d9-EtFOSE IS

5.0000

4.7486

ng/mL

d9-EtFOSE IS

Auto

8.730

232919

232919

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.730

232919

3039063

13C7-PFUnDA IS

5.0000

4.3984

ng/mL

NMeFOSA

Auto

8.523

237600

536803

d3-NMeFOSA IS

5.0000

5.0987

nq/mL

dB-NMeFOSA IS

Auto

8.519

536803

536803

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.519

536803

3039063

13C7-PFUnDA IS

5.0000

4.3591

nq/mL

d7-N-MeFOSE IS

Auto

8.484

364023

364023

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.484

364023

3039063

13C7-PFUnDA IS

5.0000

5.1391

nq/mL

NEtFOSA

Auto

8.784

398269

558534

d5-NEtFOSA IS

5.0000

4.8906

ng/mL

PFTrDA

Auto

8.348

2732723

1914804

13C-PFTeDA IS

5.0000

4.5705

nq/mL

PFTeDA

Auto

8.645

2485933

1914804

13C-PFTeDA IS

5.0000

3.9953

ng/mL

13C-PFTeDA IS

Auto

8.645

1914804

1914804

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.645

1914804

3039063

13C7-PFUnDA IS

5.0000

5.1016

ng/mL

11CI-PFBOUdS

Auto

7.832

556970

544540

13C-PFOS IS

4.7100

4.6812

nq/mL

9CI-PF30NS

Auto

7.154

1248893

544540

13C-PFOS IS

4.6600

4.7200

ng/mL

L-PFDoS

Auto

8.299

197836

544540

13C-PFOS IS

4.8400

4.9313

nq/mL

NaDONA

Auto

6.408

1877354

2898298

13C-PFNA IS

4.7100

4.1420

ng/mL

PFHxDA

Auto

9.176

1832929

4139306

13C2-PFHxDA IS

5.0000

6.7409

nq/mL

PFODA

Auto

9.724

1187543

4139306

13C2-PFHxDA IS

5.0000

5.2827

ng/mL

13C2-PFHxDA IS

Auto

9.176

4139306

4139306

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.176

4139306

3039063

13C7-PFUnDA IS

5.0000

4.6787

ng/mL

13C7-PFUnDA IS

Auto

7.678

3039063

3039063

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.632

2340364

544540

13C-PFOS IS

4.6100

4.5306

ng/mL

PFBSA

Auto

6.141

1461232

685976

13C-FOSA IS

5.0000

4.3441

nq/mL

PFHxSA

Auto

6.965

1388135

2898298

13C-PFNA IS

5.0000

4.5605

ng/mL

CHARGE

ND(W/B)

	

	

3039063

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

2.0e5

O.OeO -bge

13C-PFBA

Cone. 4.7432
2.00e5 Q 217.20>172.30 (-)

2.0e5

PFBA

Cone. 4.9998
2.00e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
2.27e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.6417
5.70e5 Q 267.90>223.00 (-)

O.OeO -tap

O.OeO

JA= 1456391
RT= 5.369

JA= 1456391
RT= 5.369

O.OeO -

O.OeO -

5.2

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 4.6612	Cone. 4.6500	Cone. 4.3331 Cone. 4.0404

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)

4.73e5 ISTD 301.80>80.00 (-)
2.0e5 -

A= 557967
RT= 5.499

2.11e5 Q 301.80>80.00 (-)
2.0e5 -

R#1 298.80>99.00 69.99 (72.97)

2.11e5 Q 299.00>80.00 (-)	1.39e5 ISTD 332.10>287.10 (-)	1.24e5

A= 557967
RT= 5.499

: R1 69.9!

5.6 5.8
RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

72

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:09

CCV2-230426 (continued)

13C HFPO DA

Cone. 4.3703

Q 332.10>287.10 (-)

HFPO DA

Cone. 4.7263

R#1 329.00>285.10 67.35 (68.92)
Q 329.00>169.00 (-)	9.56e4

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 26.75 (27.58)

ISTD 329.00>309.15 (-)	9.38e4

13C-4 2-FTS

Cone. 3.7139

R#1 329.00>81.00 26.75 (27.58)
Q 329.00>309.15 (-)	9.38e4

A=285241
RT=6.101

fA=213498

:R1 67.35 (-«t=6.102

f A=227244
= R1 26.75 (-Mt=5.902

f A=227244
= R1 26.75 (- 1-^7=5.902

4-2-FtS

Cone. 4.5756

R#1 327.00>81.10 14.24 (15.16)
Q 327.00>307.05 (-)	1.08e5

f A=259679

1.0e5-|R1 14.24 (-1-^7=5.902

O.OeO -

L,

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

7.5e4 -
5.0e4z_
2.5e4z_
O.OeO -

O.OeO -

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 5.0594

R#1 313.00> 119.10 2.29 (2.54)
Q 313.00>269.00 (-)	1.08e6

6.2 6.4
RT (min)

6.0 6.2
RT (min)

13C-PFHxA IS

Cone. 5.0000

13C-PFHxA

Cone. 4.3667



A=2608714

r_



I

I.

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 4.4982

R#1 349.00>99.00 77.27 (80.87)
Q 349.00>79.95 (-)	1.66e5

TA=387983
"&T= 5.997

6.2
RT (min)

13C-PFHpA_IS

Cone. 5.0000

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 3.8633

R#1 399.00 >99.00 96.23 (92.02)
Q 399.00>80.00 (-)	1.07e5

f A=294465
1.0e5 —IR1 96 Mt=6.369

O.OeO -

6.2

6.4

6.6
RT (min)

PFHpA

Cone. 5.1168

R#1 362.90 >169.00 16.81 (17.74)
Q 362.90>319.00 (-)	1.30e6

fA=2967494

I 1 16-81 (" RT=6.363

O.OeO -

13C2-6 2-FTS IS

Cone. 4.7500

13C2-6 2-FTS

Cone. 3.7160

6.6
RT (min)

PFHpS

Cone. 4.5258

R#1 449.00>99.20 62.43 (65.35)
Q 449.00>80.15 (-)	1.64e5

A=379951
6.673

6.6
RT (min)

6-2-FTS

Cone. 4.5981

R#1 427.00>80.90 29.95 (27.82)

6.2

6.4

6.6
RT (min)

PFOA

Cone. 4.4342

R#1 413.00 > 169.10 29.68 (27.71)

Q 427.00>407.00 (-)

1.45e5 Q 413.00>369.00 (-)

1.44e6

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

I STD 416.80 >372.05 (-)

13C-PFOA

Cone. 4.7270

1.16e6 Q 416.80>372.05 (-)

6.6 6.8

RT (min)

PFOS

Cone. 4.2990

R#1 499.00>99.00 92.91 (96.24)
Q 499.00>80.00 (-)	8.41 e4

13C-PFOS IS

Cone. 4.7750

105 (-)

2.25e5 Q 502.80>80.05 (-)

fA=2768577
RT=6.681

6.8 7.0
RT (min)

A= 544540
RT=6.971

6.75 7.00 7.25

RT (min)

A= 544540
RT=6.971

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

73

-------
)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:09

CCV2-230426 (continued)

13C-PFNA IS

Cone. 5.0000

PFNA

Cone. 4.8193
R#1 463.00>219.00 19.30 (20.94)

Q 463.00>418.90 (-)	1.26e6 ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 4.7092

1.17e6 Q 467.80>423.00 (-)

PFNS

Cone. 4.6236

R#1 549.00>99.00 65.57 (65.53)

1.17e6 Q 549.00>79.95 (-)



fA=3081983

IR1 19.30 (-

1"Fdr=6.992

I



A=2898298
RT=6.992

7.2

RT (min)

A=2898298
RT=6.992

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 3.6828

9.85e4 Q 528.80> 509.00 (-)

O.OeO i, , ,

7.2 7.4 7.6

RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

0-0e0

7.2
RT (min)

PFDA

Cone. 4.8766

R#1 512.90>219.00 17.62 (18.19)
Q 512.90>469.00 (-)	1.16e6

~ A=2919914

1n JR1 17.62 (itf=7.330

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

7.4 7.6

RT (min)

d3-N-MeFOSAA

Cone. 4.7647

ISTD 572.80>419.05 (-)

2.76e5 Q 572.80>419.05 (-)

O.OeO

7.4 7.6

RT (min)

NMeFOSAA

Cone. 4.6687

R#1 570.20>512.00 37.78 (35.78)
Q 570.20>419.00 (-)	2.12e5

O.OeO

O.OeO -

2.0e5 - R1 37.78 (-

A=707089
~&T=7.510

7.25 7.50 7.75

13C-PFUnDA

Cone. 4.5679

Q 564.80>519.95 (-)

7.6 7.8
RT (min)

PFUnDA

Cone. 5.2062
R#1 563.00>219.00 11.90 (11.87)

1.16e6 Q 563.00> 518.90 (-)	1.16e6 ISTD 588.80>419.00 (-)

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

d5-N-EtFOSAA

Cone. 4.6567

2.98e5 Q 588.80>419.00 (-)

O.OeO -

O.OeO



If A=3114008

:R1 11.90

1"R^= 7.679

I

L ~

7.6

13C-FOSA IS

Cone. 5.0000

8.0
RT (min)

PFOSA

Cone. 4.4042
R#1 498.20>64.10 0.15 (0.15)

Q 498.20>78.00 (-)	2.49e5 ISTD 506.00>78.05 (-)

JfA=631810

IR1 0.15 (—1)rt=7.748

7.8 8.0
RT (min)

7.8 8.0
RT (min)

13C-FOSA

Cone. 4.7252

2.70e5 Q 506.00>78.05 (-)

7.8 8.0

RT (min)

7.8 8.0

RT (min)

8-2-FTS

Cone. 4.9536

R#1 527.20>487.00 6.93 (5.33)

2.52e5 Q 527.10>506.90 (-)

f A=266182
- R1 6.93 (-Mt=7.325

7.4 7.6
RT (min)

7.6
RT (min)

13C-PFDA

Cone. 4.5637

1.26e6 Q 514.80>469.95 (-)



fA=3187344

:

RT=7.330

:



7.6
RT (min)

PFDS

Cone. 4.6546

R#1 599.00>99.00 69.63 (60.20)
Q 599.00>80.10 (-)	1.63e5

f A=425269

1.5e5^R1 69.63 fl-R-|)=7.638

7.4 7.6

RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

t A=3129335
RT=7.679

rir

7.6 7.8 8.0
RT (min)

PFDoA

Cone. 4.7270

R#1 613.05> 169.00 15.89 (15.47)
Q 613.05>569.00 (-)	1.05e6

rA=2725012
1.0e6- ri 15 89 fl-R^g.023

O.OeO

7.8 8.0
RT (min)

NEtFOSAA

Cone. 4.9742

R#1 584.20>526.10 49.53 (55.50)
Q 584.20>418.95 (-)	2.28e5

fA=750102
2.0e5 —I49-53 ("ll ^T=7.698

O.Oe01, A ffrr.

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

1.15e6

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

74

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:09

CCV2-230426 (continued)

13C-PFDoA

Cone. 4.5986

Q614.80>569.95 (-)

NEtFOSE

Cone. 4.7486

Q 629.50>59.10 (-)
3.0e5 ^

2.0e5 i
1.0e5 ^

O.OeO -I. . . .

d3-NMeFOSA

Cone. 4.3591

Q 515.10> 169.00 (-)
2.0e5

O.OeO -

10-2-FtS

Cone. 5.3953

R#1 626.50>81.05 57.00 (56.92)
Q 626.50>607.05 (-)	1.33e5

RT (min)

RT (min)

d9-EtFOSE IS

Cone. 5.0000

3.38e5 ISTD 638.90> 59.10 (-)

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

A=232919
RT=8.730

9.0
RT (min)

9.0
RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

2.10e5 I STD 623.00 > 59.00 (-)

~ A=364023
RT=8.484



8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 3.9953

R#1 713.00>169.30 10.57 (10.03)
Q 713.00>668.90 (-)	9.45e5

13C-PFTeDA IS

Cone. 5.0000

I STD 714.80 >669.80 (-)

A=1914804
RT=8.645

L

9.0
RT (min)

L-PFDoS

Cone. 4.9313

R#1 698.80 >98.80 72.38 (68.45)
Q 698.80>80.10 (-)	8.12e4

NaDONA

Cone. 4.1420

B.2 8.4 8.6

RT (min)

d5-NEtFOSA IS

Cone. 5.0000

I STD 531.10> 169.10 (-)
2.0e5

O.OeO



fA= 558534



RT=8.774



L.

d5-NEtFOSA

Cone. 4.1844

2.21 e5 Q 531.10> 169.10 (-)
2.0e5 -

8.6 8.8 9.0

RT (min)

d9-EtFOSE

Cone. 4.3984

9.22e4 Q 638.90> 59.10 (-)

7.5e4 i
5.0e4 ~

2.5e4 -

fA=232919
RT=8.730

0-0e0 I i i | i A' ,¦ ¦ ,~r i i i

8.6 8.8 9.0

RT (min)

d7-N-MeFOSE

Cone. 5.1391

Q 623.00> 59.00 (-)	1.46e5

^	| A=364023

RT=8.484



RT (min)

13C-PFTeDA

Cone. 5.1016

7.35e5 Q 714.80>669.80 (-)

6.0e5 -
4.0e5 -
2.0e5 -
O.OeO -

t A=1914804
I RT=8.645

9.0
RT (min)

PFHxDA

Cone. 6.7409

Q 812.90>769.00 (-)
7.5e5 -

NMeFOSE

Cone. 4.4182

2.21 e5 Q 616.10>58.90 (-)

O.OeO -

8.6

: R1 75.94 (-

7.5e4 -
5.0e4z_
2.5e4z_
O.OeO -

RT (min)

11CI-PF30UdS

Cone. 4.6812

Q 631.00>451.10 (-)
2.0e5 -

1.0e5-

A= 556970
RT=7.832

9.0
RT (min)

PFODA

Cone. 5.2827

Q 912.80>869.00 (-)
4.0e5 H

9.4

RT (min)

8.8 9.0

RT (min)
NMeFOSA

Cone. 5.0987

R#1 512.10>219.20 75.94(86.99)
9.22e4 Q 512.10> 169.20 (-)	9.46e4

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)	2.10e5

2.0e5 -

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 4.8906

R#1 526.50>219.20 64.96 (64.74)
Q 526.50> 169.10 (-)	1.59e5

If A=398269
1.5e5HR1 64.96 (-j]-frr=8.784

O.OeO-=

8.4 8.6

RT (min)

PFTrDA

Cone. 4.5705

R#1 663.10> 169.10 17.39 (18.77)
Q 663.10>618.90 (-)	1.10e6

{A=2732723

1.0e6HR1 17.39 i1-r=|)=8.348

O.OeO

3.2 8.4 8.6

RT (min)

9CI-PF30NS

Cone. 4.7200

2.23e5 Q 531.00>351.10 (-)

5.17e5

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

4.11 e5 I STD 815.00 > 770.00 (-)

9.6 9.8 10.0

RT (min)

1.5e6-
1.0e6:
5.0e5 :
O.OeO :

'A=4139306
RT=9.176

9.2 9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

75

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:09

CCV2-230426 (continued)

13C2-PFHxDA

Cone. 4.6787

Q 815.00>770.00 (-)

^.Se6z_

^.0e6z_

5.0e5 i
O.OeO 1. . .

13C7-PFUnDA IS

Cone. 5.0000

1,79e6 ISTD 569.80> 524.90 (-)
1.0e6 -

PFecHS	PFBSA

Cone. 4.5306	Cone. 4.3441
R#1 461.00>99.10 37.66 (37.10)

1.11e6 Q 461.00>381.00 (-)	9.50e5	Q 298.00>78.00 (-)

PFHxSA

Cone. 4.5605

6.04e5 Q 397.90>78.00 (-)

5.0e5 -

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

A=3039063
RT=7.678

fA=2340364

: R1 37.66 (- |Wt=6.632

6.0e5 -

8.0
RT (min)

RT (min)

fA=1461232
RT=6.141

A=1388135
RT=6.965

6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

76

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1st /S/AO 04/28/23
2nd /S/AO 05/01/23

Insight Report
Quantitation/Integration
Printed 4/28/2023 10:12:36

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/27/2023 1:52:12 AM

Acquired by: System Administrator

Data File: 230426032

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.207

776009

776009

	 	

5.0000

nq/ml

13C-PFBA

Auto

4.207

- >9

442

13C7-PFUnDA IS

4.5175

ng/mL

PFBA

M

4.207

17010

776009

13C-PFBA IS

0.0967

ng/mL

13C-PFPeA IS

Auto

5.367

1247627

627

	 	

: : :)

ng/mL

13C-PFPeA

Auto

5.367

1247627

442

13C7-PFllnDA IS

4.4177

ng/mL

PFPeA

Auto

5.367

22530

1247627

13C-PFPeA IS

0.0926

ng/mL

13C-PFBS IS

Auto

5.497

502286

502286



4.6500

ng/mL

13C-PFBS

Auto

497

502286

442

13C7-PFUnDA IS

4.3337

ng/mL

PFBS

Auto

5.496

CCD")

502286

13C-PFBS IS 	

0.0671

nq/mL

13C HFPO DA IS

Auto

6.098

267570

267570

	 	



ng/mL

13C HFPO DA

Auto

6.098

'0

2735442

13C7-PFUnDA IS

4.5546

ng/mL

HFPO DA

Auto

6.102

3304

267570

13C HI

0.0780

ng/mL

13C-4 2-FTS IS

Auto

5.899

191395

191395

	 	

4 67(10

ng/mL

13C-4 2-FTS

Auto

399

191395

2735442

13C7-PFUnDA IS

3.4752

ng/mL

4-2-FtS

Auto

5.898

4929

191395

13C-4 2-FTS IS

0.1031

ng/mL

PFHxA

Auto

5.954

47051

056

13C-PFHxA

0.1063

nq/mL

13C-PFHxA IS

Auto

5.954

1690056

1690056

	 	

5.0000

ng/mL

13C-PFHxA

Auto

5.954

1690056

2735442

>FUn[

4.1655

ng/mL

PFPeS

Auto

5.994

6757

511169

180-PFHxS IS

0.0885

nq/mL

PFHxS

Auto

6.365

)2

511169

180-PFHxS

0.0977

ng/mL

13C-PFHpA IS

Auto

6.360

1749132

1749132

	 	

5.0000

ng/mL

13C-PFHpA

Auto

6.360

1749132

442

>FUn[

.¦¦¦¦¦¦ >

ng/mL

180-PFHxS IS

Auto

6.366

511169

511169

	

4.7250

ng/mL

180-PFHxS

Auto

6.366

511169

2735442

13C7-PFUnDA IS

4.3598

ng/mL

PFHpA

Auto

6.360

59786

1749132

13C-PFHpA

0.1149

ng/mL

13C2-6 2-FTS IS

Auto

6.661

332934

934

	 	

a 7cnn

nq/mL

13C2-6 2-FTS

Auto

6.661

332934

442

13C7-PFUnDA IS



ng/mL

PFHpS

Auto

6.668

6969

169

180-PFHxS IS



ng/mL

6-2-FTS

Auto

6.661

5442

934

13C2-6 2-FTS IS



nq/mL

PFOA

Auto

6.678

62221

2523116

13C-PFOA IS

0.0893

ng/mL

13C-PFOA IS

Auto

6.678

2523116

2523116

	 	

5.0000

ng/mL

13C-PFOA

Auto

6.678

2!

2735442

13C7-PFUnDA IS

4.7860

ng/mL

PFOS

Auto

6.966

5406

475109

13C-PFOS IS

0.0988

ng/mL

13C-PFOS IS

Auto

6.967

>9

475109

	 	

4.7750

nq/mL

13C-PFOS

Auto

6.967

)9

2735442

'Flint

4.1697

ng/mL

PFNA

Auto

6.988

60686

2604033

1?

5

ng/mL

13C-PFNA IS

Auto

6.988

2604033

2604033

	 	

5.0000

ng/mL

13C-PFNA

Auto

6.988

2604033

2735442

13C7-PFUnDA IS

4.7007

ng/mL

PFNS

Auto

7.298

11024

109

13C-PFOS IS

0.091 7

ng/mL

8-2-FTS

Auto

7.322

5162

244671

13C-8 2-FTS IS

0.1045

nq/mL

13C-8 2-FTS IS

Auto

7.322

244671

244671

	 	

4.7900

ng/mL

13C-8 2-FTS

Auto

7.322

244671

442

13C7-PFUn[

3.7613

ng/mL

PFDA

Auto

7.327

52958

2814625

13C-PFDA IS

0.1002

ng/mL

13C-PFDA IS

Auto

7.327

!5

2814625

	 	

5.0000

ng/mL

13C-PFDA

Auto

7.327

IS

2735442

>FUn[

4.4773

ng/mL

d3-N-MeFOSAA IS

Auto

7.503

637048

637048

	 	

5.0000

ng/mL

d3-N-MeFOSAA

Auto

7.503

637048

442

13C7-PFUnDA IS

4.4605

ng/mL

NMeFC

M

7.508

11845

048

d.?-N-McFO-.AA IS

- i

ng/mL

PFDS

Auto

7.634

6527

109

13C-PFOS IS

0.0819

ng/mL

13C-PFUnDA IS

Auto

7.675

2777290

2777290

	 	

5.0000

nq/mL

13C-PFUnDA

Auto

7.675

2777290

2735442

13C7-PFUnDA IS

4.5040

L

PFUnDA

Auto

7.675

57853

2777290

13C-PFUnDA IS

0.1090

ng/mL

.b N ttFOSAA IS

Auto

7.686

738064

738064

	 	

5.0000

L

d5-N-EtFOSAA

Auto

7.686

738064

2735442

>FUn[

4.6065

ng/mL

NEIFOSAA

Auto

7.691

14417

738064

;tFOS

0.1074

nq/mL

PFOSA

Auto

743

11637

621811

13C-FOSA IS

0.0895

nq/ml.

I k FOSA IS

Auto

743

621811

621811

	 	

5.0000

I L

13C-FOSA

Auto

7.743

621811

2735442

13C7-PFUnDA IS



ng/mL

PFDoA

Auto

8.019

49369

2705405

13C-PFDoA IS

0.0962

i i	

13C-PFDoA IS

Auto

8.019

2705405

2705405

	 	

5.0000

ng/mL

I -sC-PFPoA

Auto

8.019

2705405







nq-mL

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCalJproc

77

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1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:12:36

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone. Cone. Unit

10-2-FtS

Auto

8.031

5906

244671

13C-8 2-FTS IS

—- 0.0957

nq/mL

d5-NEtFOSA IS

Auto

8.773

533533

533533

—

—- 5.0000

nq/mL

d5-NEtFOSA

Auto

8.773

533533

2735442

13C7-PFUnDA IS

—- 4.4408

nq/mL

NMeFOSE

Auto

8.495

5488

335804

d7-N-MeFOSE IS

—- 0.0901

nq/mL

NEtFOSE

Auto

8.747

14815

210072

d9-EtFOSE IS

—- 0.0900

nq/mL

d9-EtFOSE IS

Auto

8.728

210072

210072

—

—- 5.0000

nq/mL

d9-EtFOSE

Auto

8.728

210072

2735442

13C7-PFUnDA IS

—- 4.4072

nq/mL

NMeFOSA

Auto

8.521

5197

505882

d3-NMeFOSA IS

—- 0.1183

nq/mL

dB-NMeFOSA IS

Auto

8.516

505882

505882

—

—- 5.0000

nq/mL

dB-NMeFOSA

Auto

8.516

505882

2735442

13C7-PFUnDA IS

—- 4.5640

nq/mL

d7-N-MeFOSE IS

Auto

8.480

335804

335804

—

—- 5.0000

nq/mL

d7-N-MeFOSE

Auto

8.480

335804

2735442

13C7-PFUnDA IS

—- 5.2669

nq/mL

NEtFOSA

Auto

8.779

7111

533533

d5-NEtFOSA IS

—- 0.0914

nq/mL

PFTrDA

Auto

8.344

51720

1794832

13C-PFTeDA IS

—- 0.0923

nq/mL

PFTeDA

Auto

8.645

47411

1794832

13C-PFTeDA IS

—- 0.0813

nq/mL

13C-PFTeDA IS

Auto

8.646

1794832

1794832

—

—- 5.0000

nq/mL

1BC-PFTeDA

Auto

8.646

1794832

2735442

13C7-PFUnDA IS

—- 5.3128

nq/mL

11CI-PF30UdS

Auto

7.826

10303

475109

13C-PFOS IS

—- 0.0992

nq/mL

9CI-PFBONS

Auto

7.150

20586

475109

13C-PFOS IS

—- 0.0892

nq/mL

L-PFDoS

Auto

8.297

3671

475109

13C-PFOS IS

—- 0.1049

nq/mL

NaDONA

Auto

6.404

31943

2604033

13C-PFNA IS

—- 0.0784

nq/mL

PFHxDA

Auto

9.175

50267

3482718

13C2-PFHxDA IS

—- 0.1164

nq/mL

PFODA

Auto

9.725

19751

3482718

13C2-PFHxDA IS

—- 0.1044

nq/mL

13C2-PFHxDA IS

Auto

9.176

3482718

3482718

—

—- 5.0000

nq/mL

1BC2-PFHxDA

Auto

9.176

3482718

2735442

13C7-PFUnDA IS

—- 4.3735

nq/mL

13C7-PFUnDA IS

Auto

7.674

2735442

2735442

—

—- 5.0000

nq/mL

PFecHS

Auto

6.630

39325

475109

13C-PFOS IS

—- 0.0873

nq/mL

PFBSA

Auto

6.138

25727

621811

13C-FOSA IS

—- 0.0844

nq/mL

PFHxSA

Auto

6.961

26141

2604033

13C-PFNA IS

—- 0.0956

nq/mL

CHARGE

ND(W/B)

	

	

2735442

13C7-PFUnDA IS

	 	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 4.5175
1.69e5 Q 217.20>172.30 (-)

A=776009
RT=4.207

PFBA	13C-PFPeAJS

Cone. 0.0967	Cone. 5.0000

1.69e5 Q 213.20> 169.10 (-)	4.65e3	ISTD 267.90>223.00 (-)

fA=17010
RT=4.207

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 0.0926

Q263.05>219.10 (-)

8.80e3 I STD 301.80 > 80.00 (-)

13C-PFPeA

Cone. 4.4177
4.92e5 Q 267.90>223.00 (-)

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

4.0e3 -

O.OeO - ..................

4.00 4.25 4.50

RT (min)

13C-PFBS

Cone. 4.3337

4.0e5 -

A=1247627
RT= 5.367

O.OeO -

A=1247627
RT= 5.367

O.OeO

1.87e5 Q 301.80>80.00 (-)

5.6

RT (min)

PFBS

Cone. 0.0671
R#1 298.80>99.00 75.58 (72.97)

1.87e5 Q 299.00>80.00 (-)	2.26e3 ISTD 332.10>287.10 (-)

13C HFPO DA IS

Cone. 5.0000

A= 502286
RT= 5.497

?A=5532
2.0e3 - R1 75 58 (-fr^T= 5.496

5.6 5.8
RT (min)

rA=267570
I RT=6.C

5.6 5.8
RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

78

-------
1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:12:36

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 4.5546

Q 332.10>287.10 (-)

HFPO DA

Cone. 0.0780

R#1 329.00>285.10 70.08 (68.92)
Q 329.00>169.00 (-)	1.50e3

JA=267570
RT=6.098

1.5e3 -

f A=3304
R1 70.08 (--^1=6.102

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 27.59 (27.58)

ISTD 329.00>309.15 (-)	7.91 e4

f A=191395
7-5e4-Ri 27.59 Hrtfr=5.£

13C-4 2-FTS

Cone. 3.4752

R#1 329.00>81.00 27.59 (27.58)
Q 329.00>309.15 (-)	7.91e4

TA=191395

7.5e4:Rl 27.59 (---£1=5.8

4-2-FtS

Cone. 0.1031

R#1 327.00>81.10 14.32 (15.16)
Q 327.00>307.05 (-)	2.02e3

O.OeO -

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 0.1063

R#1 313.00> 119.10 2.40 (2.54)
Q 313.00>269.00 (-)	2.06e4

2.0e3 -

y A=4929

R1 14.32 (-jrtr=5.

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

5.8 6.0 6.2
RT (min)

13C-PFHxA

Cone. 4.1655

6.95e5 Q 314.90>270.10 (-)

6.95e5

2.0e4 -

J A=47051

R1 2 40 (---1)RT= 5.954

A=1690056
RT= 5.954

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

7.68e5 Q 366.90>322.10 (-)

A=1749132
RT=6.360

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)
2.0e5 -

1.0e5-

O.OeO -

6.6

RT (min)

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

13C2-6 2-FTS

Cone. 3.5655

1.40e5 Q 428.90>409.00 (-)

f A=332934
I RT=6.661

3.0e3 -

^A=6969

R1 45.44 (--|ftT=6.668

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
1.0e6 -

A=2523116
RT=6.678

13C-PFOA

Cone. 4.7860

Q 416.80>372.05 (-)
1.0e6 -

A=2523116
RT=6.678

6.8 7.0
RT (min)

6.0 6.2
RT (min)

PFPeS

Cone. 0.0885

R#1 349.00>99.00 69.41 (80.87)
Q 349.00>79.95 (-)	2.90e3

f A=6757

IR1 69.41 (-| ^j= 5994

O.OeO

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.0977

R#1 399.00 >99.00 91.60 (92.02)
Q 399.00>80.00 (-)	2.43e3

~ A=6592
-R1 91.60 (-#^7=6.365

6.6
RT (min)

PFHpS

Cone. 0.0938

R#1 449.00>99.20 45.44 (65.35)
Q 449.00>80.15 (-)	3.06e3

6.2
RT (min)

180-PFHxS

Cone. 4.3598

Q 402.70>84.05 (-)	2.23e5

2.0e5 -

1.0e5-

O.OeO -

6.2 6.4 6.6

RT (min)

6-2-FTS

Cone. 0.0837

R#1 427.00>80.90 27.09 (27.82)
Q 427.00>407.00 (-)	2.64e3

Jf A=544?
]R1 27.09 (-4^=6.661

O.OeO

6.2 6.4 6.6

RT (min)

PFHpA

Cone. 0.1149

R#1 362.90 >169.00 14.47 (17.74)
Q 362.90>319.00 (-)	2.54e4

~ A= 59786
IR1 1447 ("t^T=6.360

O.OeO

6.2 6.4 6.6

RT (min)

PFOA

Cone. 0.0893

R#1 413.00>169.10 35.21 (27.71)
Q 413.00>369.00 (-)	2.64e4

TA=62221

- R1 35.21 (-jt^T=6.678

6.6 6.8

RT (min)

PFOS

Cone. 0.0988

R#1 499.00>99.00 88.54 (96.24)
Q 499.00>80.00 (-)	1.58e3

~ A=5406

1.5e3-R1 88.54 (--rkT=6.966

13C-PFOS IS

Cone. 4.7750

105 (-)

1.98e5 Q 502.80>80.05 (-)

fA=475109
I RT=6.967

6.75 7.00 7.25

RT (min)

7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

79

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1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:12:36

L0.1ppb_230323 (continued)

PFNA	13C-PFNA IS

Cone. 0.1056	Cone. 5.0000
R#1 463.00>219.00 16.41 (20.94)

Q 463.00>418.90 (-)	2.42e4	ISTD 467.80>423.00 (-)

TA=60686
-R1 16-41 (|-rV=6.S

13C-PFNA

Cone. 4.7007

1.08e6 Q 467.80>423.00 (-)

7.2

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 3.7613

9.35e4 Q 528.80> 509.00 (-)

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

A=244671
RT=7.322

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

A=244671
RT=7.322

2.0e4

TA= 52958
_R1 17.44 (f"Rt=7.327

O.OeO -

V*

7.2

7.4 7.6

RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

7.4 7.6

RT (min)

7.2

7.4

d3-N-MeFOSAA

Cone. 4.4605

ISTD 572.80>419.05 (-)

2.34e5 Q 572.80>419.05 (-)

f A=637048
1 RT=7.503

tA=637048
] RT=7.503

=P=; O.OeO -

3.0e3 -
2.0e3 -
1.0e3-
O.OeO -

~ A= 11845

R1 55.49 (--(



"&T=7.508

7.6 7.8
RT (min)

7.4

7.25 7.50 7.75

13C-PFUnDA

Cone. 4.5040

Q 564.80>519.95 (-)

1.0e6 H	I

d5-N-EtFOSAA IS

Cone. 5.0000

A=2777290
RT=7.675

7.6 7.8
RT (min)

PFUnDA

Cone. 0.1090
R#1 563.00>219.00 10.72 (11.87)

1.03e6 Q563.00>518.90 (-)	2.22e4 ISTD 588.80>419.00 (-)

~ A= 57853
2.0e4-R1 10-72 (^-RT^ 7.675

O.OeO -

O.OeO -



7.6

7.6

13C-FOSA IS

Cone. 5.0000

.8 8.0
RT (min)

PFOSA

Cone. 0.0895
R#1 498.20>64.10 0.00 (0.15)

Q 498.20>78.00 (-)	4.68e3 ISTD 506.00>78.05 (-)

f A=11637

„n78.05 (-)

8.0
RT (min)

7.8 8.0

RT (min)

PFNS

Cone. 0.0917

R#1 549.00>99.00 57.03 (65.53)

8-2-FTS

Cone. 0.1045

R#1 527.20>487.00 0.52 (5.33)

1.08e6 Q 549.00>79.95 (-)

~ A= 11024

4.0e3HR1 57.03 (4Rt=7.298

O.OeO

7.2
RT (min)

PFDA

Cone. 0.1002

R#1 512.90>219.00 17.44(18.19)
Q 512.90>469.00 (-)	2.05e4

4.31e3 Q 527.10>506.90 (-)

tA=5162

2.0e3-R1 0.52 (- -^7=7.322



7.4 7.6
RT (min)

7.6
RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 4.4773

ISTD 514.80>469.95 (-)

1.13e6 Q 514.80>469.95 (-)

J A=2814625
1 RT=7.327

[A=2814625
I RT=7.327

O.OeO -

7.6
RT (min)

NMeFOSAA

Cone. 0.0928

R#1 570.20>512.00 55.49 (35.78)
Q 570.20>419.00 (-)	3.59e3

7.2

7.4

7.6
RT (min)

PFDS

Cone. 0.0819

R#1 599.00>99.00 77.94 (60.20)
Q 599.00>80.10 (-)	2.80e3

~ A=6527

I R1 77 94 l;1^=7.634

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)
1.0e6H

A=2777290
RT=7.675

O.OeO -

7.6

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 4.6065

2.74e5 Q 588.80>419.00 (-)

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.1074

R#1 584.20>526.10 48.25 (55.50)
Q 584.20>418.95 (-)	3.71e3

|A=14417

R1 48-25 (" t^T=7.691

7.8 8.0
RT (min)

O.OeO - _

7.8 8.0
RT (min)

PFDoA

Cone. 0.0962

R#1 613.05 > 169.00 15.31 (15.47)
Q 613.05>569.00 (-)	1.88e4

f A=49369
;R1 1^-31 (t-Rj)=8.019

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)
1.0e6H

1.03e6

7.6 7.8 8.0

RT (min)

RT (min)

RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

80

-------
1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:12:36

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 4.5458

Q614.80>569.95 (-)
1.0e6 H

10-2-FtS

Cone. 0.0957

R#1 626.50>81.05 45.59 (56.92)
Q 626.50>607.05 (-)	2.70e3

~ A=5906

IR1 45.59 -rt!=8.031

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)
2.0e5 -



d5-NEtFOSA

Cone. 4.4408

2.09e5 Q 531.10> 169.10 (-)
2.0e5 -

RT (min)

RT (min)

NEtFOSE

Cone. 0.0900

Q629.50>59.10 (-)

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 4.4072

O.OeO H , , , , , , I, , , , , , , , ,
8.6 8.8 9.0

RT (min)

d3-NMeFOSA

Cone. 4.5640

d7-N-MeFOSE IS

Cone. 5.0000

Q 515.10> 169.00 (-)

1,99e5 ISTD 623.00> 59.00 (-)

d7-N-MeFOSE

Cone. 5.2669

1.40e5 Q 623.00> 59.00 (-)

O.OeO -

A=335804
RT=8.480

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 0.0813

R#1 713.00 >169.30 8.81 (10.03)
Q 713.00>668.90 (-)	1.74e4

RT (min)

13C-PFTeDA IS

Cone. 5.0000

13C-PFTeDA

Cone. 5.3128

ISTD 714.80>669.80 (-)

1.5e4-
1.0e4-
5.0e3 -
O.OeO -

f A=47411

R1 8.81 (-H-^r=8.645

6.0e5 -
4.0e5 -
2.0e5 -
O.OeO -

A=1794832
RT=8.646

6.79e5 Q 714.80>669.80 (-)

6.0e5 -
4.0e5 -
2.0e5 -
O.OeO -

A=1794832
RT=8.646

8.6

.8 9.0
RT (min)

L-PFDoS

Cone. 0.1049

R#1 698.80 >98.80 43.72 (68.45)
Q 698.80>80.10 (-)	1.66e3

1.0e3 -
5.0e2 :
O.OeO :

9.0
RT (min)

NaDONA

Cone. 0.0784

Q377.10>251.20 (-)

PFHxDA

Cone. 0.1164

: R1 43.72

'-Rl)= 8.297

|

1

= l

Pw

IA=31943
RT=6.404

Q 812.90>769.00 (-)
2.0e4 -

L

8.4 8.6
RT (min)

6.6

RT (min)

O.OeO -

NMeFOSE

Cone. 0.0901

2.09e5 Q 616.10>58.90 (-)
2.0e3 -

1.0e3-

O.OeO -

9.0

RT (min)

8.6

.8 9.0

RT (min)

NMeFOSA

Cone. 0.1183
R#1 512.10>219.20 66.32 (86.99)

Q 512.10 > 169.20 (-)	2.07e3 I STD 515.10 > 169.00 (-)

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

2.0e3 -

f A=5197
R1 66.32 (--Ht=8.521

O.OeO -

9.0
RT (min)

RT (min)

11CI-PF30UdS

Cone. 0.0992

Q 631.00>451.10 (-)
4.0e3 -

9.0
RT (min)

PFODA

Cone. 0.1044

2.16e4 Q 912.80>869.00 (-)

6.0e3 ^

4.0e3 ^

2.0e3 ^
. . . . O.OeO -q=p

9.4

RT (min)

O.OeO -

A= 505882
RT=8.516

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0914

R#1 526.50>219.20 68.84(64.74)
Q 526.50>169.10 (-)	2.74e3

4.0e3 - A=

: RT=8/779

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.0923

R#1 663.10> 169.10 18.58 (18.77)
Q 663.10>618.90 (-)	2.12e4

V. A=51720

2.0e4-R1 18.58 (-^8.344

9CI-PF30NS

Cone. 0.0892

4.14e3 Q 531.00>351.10 (-)

7.5e3 i
5.0e3 ^

2.5e3 i
: r O.OeO 1 . 7"

A=20586
RT=7.150

RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

ISTD 815.00>770.00 (-)
1.5e6 —|

A=3482718
RT=9.176

9.6 9.8 10.0

RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

81

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1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:12:36

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 4.3735

Q 815.00>770.00 (-)
1.5e6 -

1.0e6-j

5.0e5 ^

O.OeO 1 . . ,

13C7-PFUnDA IS

Cone. 5.0000

1.51e6 ISTD 569.80>524.90 (-)

PFecHS	PFBSA

Cone. 0.0873	Cone. 0.0844
R#1 461.00>99.10 39.10 (37.10)

9.98e5 Q 461.00>381.00 (-)	1.60e4	Q 298.00>78.00 (-)

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	2.00e0

5.0e0 -

0.2
RT (min)

TA=2735442
RT=7.674

*A=39325
1.5e4-R1 39.10(^^=6.630

1.0e4

8.0
RT (min)

RT (min)

PFHxSA

Cone. 0.0956

1.02e4 Q 397.90>78.00 (-)
1.0e4-

7.0 7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

82

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:18

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/27/2023 4:50:57 AM

Acquired by: System Administrator

Data File: 230426045

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.207

808267

808267

	 	

5.0000

nq/mL

1BC-PFBA

Auto

4.207

808267

1682881

13C7-PFUnDA IS

7.6482

nq/mL

PFBA

Auto

4.207

14517

808267

13C-PFBA IS

0.0792

nq/mL

13C-PFPeA IS

Auto

5.367

1153927

1153927

	 	

5.0000

nq/mL

13C-PFPeA

Auto

5.367

1153927

881

13C7-PFUnDA IS

6.6414

nq/mL

PFPeA

Auto

5.368

22711

1153927

13C-PFPeA IS

0.1009

nq/mL

13C-PFBS IS

Auto

5.497

399939

399939

	 	

4.6500

nq/mL

13C-PFBS

Auto

5.497

399939

1682881

13C7-PFUnDA IS

5.6089

nq/mL

PFBS

Auto

5.498

6754

399939

13C-PFBS IS

0.1028

nq/mL

13C HFPO DA IS

Auto

6.099

218295

218295

	 	

5.0000

nq/mL

13C HFPO DA

Auto

6.099

218295

881

13C7-PFUnDA IS

6.0400

nq/mL

HFPO DA

Auto

6.097

4076

218295

13C HFPO DA IS

0.1179

nq/mL

13C-4 2-FTS IS

Auto

5.899

172422

172422

	 	

4.6700

nq/mL

13C-4 2-FTS

Auto

5.899

172422

1682881

13C7-PFUnDA IS

5.0888

nq/mL

4-2-FtS

Auto

5.900

3365

172422

13C-4 2-FTS IS

0.0781

nq/mL

PFHxA

Auto

5.955

38565

1630746

13C-PFHxA IS

0.0903

nq/mL

13C-PFHxA IS

Auto

5.954

1630746

1630746

	 	

5.0000

nq/mL

13C-PFHxA

Auto

5.954

1630746

1682881

13C7-PFUnDA IS

6.5332

nq/mL

PFPeS

Auto

5.994

5499

458715

180-PFHxS IS

0.0803

nq/mL

PFHxS

Auto

6.365

6159

458715

180-PFHxS IS

0.1017

nq/mL

13C-PFHpA IS

Auto

6.360

1678788

1678788

	 	

5.0000

nq/mL

13C-PFHpA

Auto

6.360

1678788

1682881

13C7-PFUnDA IS

6.7773

nq/mL

180-PFHxS IS

Auto

6.366

458715

458715

	 	

4.7250

nq/mL

180-PFHxS

Auto

6.366

458715

1682881

13C7-PFUnDAJS

6.3594

ng/mL

PFHpA

Auto

6.359

51992

1678788

13C-PFHpA IS

0.1041

ng/mL

13C2-6 2-FTS IS

Auto

6.661

288138

288138

—-

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.661

288138

1682881

13C7-PFUnDA IS

5.0158

ng/mL

PFHpS

Auto

6.670

5745

458715

180-PFHxS IS

0.0861

nq/mL

6-2-FTS

Auto

6.662

4299

288138

13C2-6 2-FTS IS

0.0764

nq/mL

PFOA

Auto

6.679

59248

2325424

13C-PFOA IS

0.0923

nq/mL

13C-PFOA IS

Auto

6.678

2325424

2325424

	 	

5.0000

nq/mL

13C-PFOA

Auto

6.678

2325424

1682881

13C7-PFUnDA IS

7.1699

nq/mL

PFOS

Auto

6.968

5950

458464

13C-PFOS IS

0.1127

nq/mL

13C-PFOS IS

Auto

6.967

458464

458464

	 	

4.7750

nq/mL

13C-PFOS

Auto

6.967

458464

881

13C7-PFUnDA IS

6.5402

nq/mL

PFNA

Auto

6.989

40436

2359580

13C-PFNA IS

0.0777

nq/mL

13C-PFNA IS

Auto

6.989

2359580

2359580

	 	

5.0000

nq/mL

13C-PFNA

Auto

6.989

2359580

1682881

13C7-PFUnDA IS

6.9235

nq/mL

PFNS

Auto

7.298

9765

458464

13C-PFOS IS

0.0842

nq/mL

8-2-FTS

Auto

7.325

3061

197884

13C-8 2-FTS IS

0.0766

nq/mL

13C-8 2-FTS IS

Auto

7.323

197884

197884

	 	

4.7900

nq/mL

13C-8 2-FTS

Auto

7.323

197884

1682881

13C7-PFUnDA IS

4.9447

nq/mL

PFDA

Auto

7.329

48661

2485350

13C-PFDA IS

0.1042

r

13C-PFDA IS

Auto

7.328

2485350

2485350

	 	

5.0000

ng/mL

13C-PFDA

Auto

7.328

2485350

881

13C7-PFUnDA IS

6.4263

r

d3-N-MeFOSAA IS

Auto

7.505

596744

596744

	 	

5.0000

ng/mL

cB-N-MeFOSAA

Auto

7.505

596744

881

13C7-PFUnDA IS

6.7917

r

NMeFOSAA

Auto

7.509

8629

596744

d3-N-MeFOSAA IS

0.0722

nq/mL

PFDS

Auto

7.636

6596

458464

13C-PFOS IS

0.0857

r

13C-PFUnDA IS

Auto

7.679

2408747

2408747

	 	

5.0000

ng/mL

13C-PFUnDA

Auto

7.679

2408747

881

13C7-PFUnDA IS

6.3496

r

PFUnDA

Auto

7.680

40951

2408747

13C-PFUnDA IS

0.0889

ng/mL

d5-N-EtFOSAA IS

Auto

7.690

652285

652285

	 	

5.0000

r

d5-N-EtFOSAA

Auto

7.690

652285

1682881

13C7-PFUnDA IS

6.6175

ng/mL

NEtFOSAA

Auto

7.699

11595

652285

dS-N-EtFOSAA IS

0.0977

r

PFOSA

Auto

7.747

13068

538782

13C-FOSA IS

0.1160

ng/mL

13C-FOSA IS

Auto

7.747

538782

538782

	 	

5.0000

r

13C-FOSA

Auto

7.747

538782

1682881

13C7-PFUnDA IS

6.7021

nq/mL

PFDoA

Auto

8.022

48167

2122361

13C-PFDoA IS

0.1197

nq/mL

13C-PFDoA IS

Auto

8.022

2122361

2122361

	 	

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

83

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:18

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone. Cone. Unit

1BC-PFD0A

Auto

8.022

2122361

1682881

13C7-PFUnDA IS

—- 5.7966

nq/mL

10-2-FtS

Auto

8.035

2713

197884

13C-8 2-FTS IS

—- 0.0543

ng/mL

d5-NEtFOSA IS

Auto

8.775

540396

540396

—

—- 5.0000

nq/mL

d5-NEtFOSA

Auto

8.775

540396

1682881

13C7-PFUnDA IS

—- 7.3111

ng/mL

NMeFOSE

Auto

8.498

4110

195948

d7-N-MeFOSE IS

—- 0.1157

nq/mL

NEtFOSE

Auto

8.750

15371

192803

d9-EtFOSE IS

—- 0.1017

ng/mL

d9-EtFOSE IS

Auto

8.730

192803

192803

—

—- 5.0000

nq/mL

d9-EtFOSE

Auto

8.730

192803

1682881

13C7-PFUnDA IS

—- 6.5748

ng/mL

NMeFOSA

Auto

8.522

5054

465703

d3-NMeFOSA IS

—- 0.1250

nq/mL

dB-NMeFOSA IS

Auto

8.519

465703

465703

	

—- 5.0000

ng/mL

dB-NMeFOSA

Auto

8.519

465703

1682881

13C7-PFUnDA IS

—- 6.8293

nq/mL

d7-N-MeFOSE IS

Auto

8.484

195948

195948

	

—- 5.0000

ng/mL

d7-N-MeFOSE

Auto

8.484

195948

1682881

13C7-PFUnDA IS

—- 4.9956

nq/mL

NEtFOSA

Auto

8.785

6963

540396

d5-NEtFOSA IS

—- 0.0884

ng/mL

PFTrDA

Auto

8.348

28672

314871

13C-PFTeDA IS

—- 0.2916

nq/mL

PFTeDA

Auto

8.649

33392

314871

13C-PFTeDA IS

—- 0.3264

ng/mL

13C-PFTeDA IS

Auto

8.649

314871

314871

—

—- 5.0000

nq/mL

13C-PFTeDA

Auto

8.649

314871

1682881

13C7-PFUnDA IS

—- 1.5150

ng/mL

11CI-PFBOUdS

Auto

7.832

8896

458464

13C-PFOS IS

—- 0.0888

nq/mL

9CI-PF30NS

Auto

7.150

18110

458464

13C-PFOS IS

—- 0.0813

ng/mL

L-PFDoS

Auto

8.298

3373

458464

13C-PFOS IS

—- 0.0999

nq/mL

NaDONA

Auto

6.404

33302

2359580

13C-PFNA IS

—- 0.0902

ng/mL

PFHxDA

Auto

9.176

5344

3116183

13C2-PFHxDA IS

—- -0.0665

nq/mL

PFODA

Auto

9.725

3660

3116183

13C2-PFHxDA IS

—- 0.0216

ng/mL

13C2-PFHxDA IS

Auto

9.177

3116183

3116183

—

—- 5.0000

nq/mL

13C2-PFHxDA

Auto

9.177

3116183

1682881

13C7-PFUnDA IS

—- 6.3607

ng/mL

13C7-PFUnDA IS

Auto

7.678

1682881

1682881

—

—- 5.0000

nq/mL

PFecHS

Auto

6.629

39426

458464

13C-PFOS IS

—- 0.0907

ng/mL

PFBSA

Auto

6.139

25613

538782

13C-FOSA IS

—- 0.0969

nq/mL

PFHxSA

Auto

6.960

24373

2359580

13C-PFNA IS

—- 0.0984

ng/mL

CHARGE

ND(W/B)

	

	

1682881

13C7-PFUnDA IS

	 	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 7.6482
Q 217.20> 172.30 (-)

A=808267
RT=4.207

PFBA

Cone. 0.0792
1.82e5 Q 213.20> 169.10 (-)

4.0e3 -

13C-PFPeA IS

Cone. 5.0000
4.26e3 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 6.6414
4.59e5 Q 267.90>223.00 (-)

r a=14517
RT=4.207

O.OeO

A= 1153927
RT= 5.367

O.OeO -

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 0.1009	Cone. 4.6500	Cone. 5.6089 Cone. 0.1028

r A= 1153927
RT= 5.367

O.OeO -

lL

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)

8.67e3 I STD 301.80 > 80.00 (-)

1.50e5 Q 301.80>80.00 (-)

R#1 298.80>99.00 61.23 (72.97)

1.50e5 Q 299.00>80.00 (-)	2.49e3 ISTD 332.10>287.10 (-)	9.58e4

5.6 5.8
RT (min)

f A=6754
IR1 61.23 (-1^1=5.498

A=218295
RT=6.099

5.6 5.8
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

84

-------


L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 6.0400

Q 332.10>287.10 (-)

rA=218295
RT=6.099

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :



1.5e4iR1 146 (-
1,0e4 ^

5.0e3 ^

O.OeO TTTT

A=38565
RT= 5.955

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

'A=1678788
RT=6.360

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

f A=288138
RT=6.661

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

A=2325424
RT=6.678

HFPO DA

Cone. 0.1179

R#1 329.00>285.10 96.84 (68.92)
Q 329.00>169.00 (-)	1.60e3

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 27.45 (27.58)

ISTD 329.00>309.15 (-)	7.23e4

6.0 6.2 6.4
RT (min)

PFHxA

Cone. 0.0903

R#1 313.00> 119.10 1.46 (2.54)
Q 313.00>269.00 (-)	1.67e4

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

6.80e5 Q 314.90>270.10 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

f A=1630746
RT= 5.954

6.2
RT (min)

13C-PFHpA

Cone. 6.7773

7.37e5 Q 366.90>322.10 (-)

~ A= 1678788

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

6.6

RT (min)

13C2-6 2-FTS

Cone. 5.0158

1.21e5 Q 428.90>409.00 (-)

Irt=2

288138
RT=6.661

Vjf

RT (min)

RT (min)

13C-PFOA

Cone. 7.1699

9.91 e5 Q416.80>372.05 (-)

A=2325424
RT=6.678

6.6 6.8 7.0
RT (min)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

6.2
RT (min)

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)
2.0e5 H

A=458715
RT=6.366

O.OeO -



6.6

RT (min)

6.2

IA=5745
"At=6.670

O.OeO -

/ , w

6.6 6.8 7.0
RT (min)

15e3:R1 80.56 (-
1.0e3 ^

5.0e2 ^

O.OeO 1. . . .

'A=5950
RT=6.968

13C-4 2-FTS

Cone. 5.0888

R#1 329.00>81.00 27.45 (27.58)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:18

4-2-FtS

Cone. 0.0781

R#1 327.00>81.10 6.58 (15.16)

Q 329.00>309.15 (-)

7.23e4 Q 327.00>307.05 (-)

fA= 172422

:R1 27.45 (-fj-^j= 5.899

IA=3365
)RT= 5.900

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 0.0803

R#1 349.00>99.00 116.60 (80.87)

6.80e5 Q 349.00>79.95 (-)

" R1 116.60 (^

r Ay 5499

:

[RT= 5.994

1 i



6.0 6.2
RT (min)

PFHxS

Cone. 0.1017

R#1 399.00 >99.00 98.18 (92.02)
2.16e3 Q 399.00>80.00 (-)	2.27e3

JTA=6159

2.0e3^R1 98"18 1^=6.365

O.OeO -

Ai

6.2
RT (min)

6.2

RT (min)

6.2

6.4

180-PFHxS

Cone. 6.3594

Q 402.70>84.05 (-)

2-0e51	Irt=4

6.6

RT (min)
PFHpA

Cone. 0.1041

R#1 362.90 >169.00 16.28 (17.74)
2.06e5 Q 362.90>319.00 (-)	2.31 e4

458715
RT=6.366

IR1 16.28 (

O.OeO -

L

6.4 6.6

RT (min)

PFHpS

Cone. 0.0861

R#1 449.00>99.20 91.25 (65.35)
Q 449.00>80.15 (-)	2.39e3

6.2

6.4

6.6
RT (min)

6-2-FTS

Cone. 0.0764

R#1 427.00>80.90 25.42 (27.82)

O.OeO

6.6
RT (min)

PFOA

Cone. 0.0923

R#1 413.00> 169.10 32.19 (27.71)

Q 427.00>407.00 (-)

1.97e3 Q 413.00>369.00 (-)

2.46e4

- R1 25.42 (-

Y A=4299
"At=6.662

- R1 32.19 (-

A= 59248
f^T=6.679

6.6 6.8

RT (min)

PFOS

Cone. 0.1127

R#1 499.00>99.00 80.56 (96.24)
Q 499.00>80.00 (-)	1.68e3

13C-PFOS IS

Cone. 4.7750

105 (-)

1.95e5 Q 502.80>80.05 (-)

fA=458464
| RT=6.967

6.75 7.00 7.25

RT (min)

6.8 7.0 7.2

RT (min)



A=458464

j1

RT=6.967





6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

85

-------
A

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0777

R#1 463.00>219.00 20.41 (20.94)
Q 463.00>418.90 (-)	1.69e4

f A=40436

1.5e4^R1 20 41 ( |1^r=6.9

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 6.9235

9.73e5 Q 467.80>423.00 (-)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 4.9447

7.46e4 Q 528.80> 509.00 (-)

d3-N-MeFOSAAJS

Cone. 5.0000

ISTD 572.80>419.05 (-)
2.0e5 -

1.0e5 -

d3-N-MeFOSAA

Cone. 6.7917

Q 572.80>419.05 (-)
2.0e5 -

1.0e5 -

O.OeO

13C-PFUnDA

Cone. 6.3496

Q 564.80>519.95 (-)

7.8 8.0
RT (min)

PFOSA

Cone. 0.1160

R#1 498.20>64.10 0.00 (0.15)
Q 498.20>78.00 (-)	5.84e3

fA= 13068
:	(— RT=7.747

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)
2.0e5 -

7.8 8.0

RT (min)

PFNS

Cone. 0.0842

R#1 549.00>99.00 62.13 (65.53)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:18

8-2-FTS

Cone. 0.0766

R#1 527.20>487.00 2.46 (5.33)

9.73e5 Q 549.00>79.95 (-)

3.81e3 Q 527.10>506.90 (-)

A=2359580
RT=6.989

O.OeO -

6.8

7.0

7.2

RT (min)

PFDA

Cone. 0.1042
R#1 512.90>219.00 14.72 (18.19)

Q 512.90>469.00 (-)	2.03e4 ISTD 514.80>469.95 (-)

13C-PFDAJS

Cone. 5.0000

2.0e4

~ A=48661

-R1 14.72 (| "Rt=7.329

O.OeO

7.6
RT (min)

- R1 42.03 (-

A=8629
1*T=7.509

7.6 7.8
RT (min)

PFUnDA

Cone. 0.0889

R#1 563.00>219.00 15.59 (11.87)
Q563.00>518.90 (-)	1.57e4

A=40951

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

13C-FOSA

Cone. 6.7021

Q 506.00>78.05 (-)
2.0e5 -

7.6 7.8 8.0

RT (min)

1.0e6-

fA=2485350
RT=7.328

1.02e6 Q 514.80>469.95 (-)
1.0e6 —|

A=2485350
RT=7.328

O.OeO -

7.6
RT (min)

NMeFOSAA

Cone. 0.0722

R#1 570.20>512.00 42.03 (35.78)
Q 570.20>419.00 (-)	2.88e3

7.2

7.4 7.6

RT (min)

PFDS

Cone. 0.0857

R#1 599.00>99.00 67.69 (60.20)
Q 599.00>80.10 (-)	2.67e3

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 6.6175

2.37e5 Q 588.80>419.00 (-)

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.0977

R#1 584.20>526.10 56.28 (55.50)
Q 584.20>418.95 (-)	3.60e3



7.8 8.0
RT (min)

O.OeO -

7.8 8.0
RT (min)

PFDoA

Cone. 0.1197

R#1 613.05> 169.00 14.18 (15.47)
Q 613.05>569.00 (-)	1.87e4

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

8.12e5

7.6 7.8 8.0

RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

86

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:18

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 5.7966

10-2-FtS

Cone. 0.0543

R#1 626.50>81.05 97.99 (56.92)
Q 626.50>607.05 (-)	1.08e3

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)
2.0e5 -

O.OeO -

d5-NEtFOSA

Cone. 7.3111

Q 531.10> 169.10 (-)
2.0e5 -

NMeFOSE

Cone. 0.1157

O.OeO -

A=4110
RT=8.498

RT (min)

RT (min)

NEtFOSE

Cone. 0.1017

Q 629.50>59.10 (-)

d9-EtFOSE IS

Cone. 5.0000

8.6 8.8 9.0

RT (min)

d9-EtFOSE

Cone. 6.5748

8.6

6.98e3 ISTD 638.90> 59.10 (-)

7.49e4 Q 638.90> 59.10 (-)

8.8 9.0

RT (min)

NMeFOSA

Cone. 0.1250
R#1 512.10>219.20 64.60 (86.99)

7.49e4 Q 512.10 > 169.20 (-)	1,92e3 I STD 515.10 > 169.00 (-)

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

9.0
RT (min)

d3-NMeFOSA

Cone. 6.8293

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

d7-N-MeFOSE IS

Cone. 5.0000

8.6 8.8 9.0

RT (min)

d7-N-MeFOSE

Cone. 4.9956

8.06e4

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 0.3264

R#1 713.00 >169.30 12.86 (10.03)
Q 713.00>668.90 (-)	1.19e4

A=33392

R1 12.86 ( ^=8.649

8.4 8.6

RT (min)

NEtFOSA

Cone. 0.0884

R#1 526.50>219.20 70.14(64.74)
Q 526.50>169.10 (-)	2.88e3

- R1 70.14 (-

A=6963
"&T=8.785

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.2916

R#1 663.10> 169.10 28.10 (18.77)
Q 663.10>618.90 (-)	1.19e4

~ A=28672
_ -R1 28.10 A-^=8.348

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 1.5150

1.19e5 Q714.80>669.80 (-)

11CI-PF30UdS

Cone. 0.0888

1.19e5 Q 631.00>451.10 (-)

O.OeO -

O.OeO -

9CI-PF30NS

Cone. 0.0813

Q 531.00>351.10 (-)

A= 18110
RT=7.150

8.6

8.6

NaDONA

Cone. 0.0902

.8 9.0
RT (min)

L-PFDoS

Cone. 0.0999
R#1 698.80>98.80 55.95 (68.45)

Q 698.80>80.10 (-)	1,40e3 Q 377.10>251.20 (-)

JT A=3373

: R1 55.95 (fl-Rf=8.298

9.0
RT (min)

8.6 8.8 9.0
RT (min)

PFHxDA

Cone. -0.0665

13C2-PFHxDA IS

Cone. 5.0000

1.42e4 Q 812.90>769.00 (-)

2.50e3 Q 912.80>869.00 (-)

1,29e3 I STD 815.00 > 770.00 (-)

A=33302
RT=6.404

A=5344
RT=9.176

8.4 8.6
RT (min)

6.6

RT (min)

9.0 9.2 9.4

RT (min)

A=3116183
RT=9.177



9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

87

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:18

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 6.3607

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 0.0969

Q 815.00>770.00 (-)

PFecHS

Cone. 0.0907
R#1 461.00>99.10 42.17 (37.10)

1.35e6 ISTD 569.80>524.90 (-)	6.32e5 Q461.00>381.00 (-)	1.48e4 Q 298.00>78.00 (-)

A=3116183
RT=9.177

O.OeO -

V.

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

A=39426

1R1 42.17 (- $j=6.629

7.6 7.8 8.0	6.4 6.6 6.

RT (min)

RT (min)

PFHxSA

Cone. 0.0984

9.96e3 Q 397.90>78.00 (-)
1.0e4 —|

6.0 6.2 6.4
RT (min)

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

88

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:22

CCV4-230426

Sample ID: CCV4-230426

Date Acquired: 4/27/2023 5:04:41 AM

Acquired by: System Administrator

Data File: 230426046

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name	Mode ID Found RT Area ISTDArea ISTD Name	Std. Cone. Cone. Unit

13C-PFBA IS

Auto

4.206

904156

904156

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.206

904156

2076412

13C7-PFUnDA IS

5.0000

6.9341

nq/mL

PFBA

Auto

4.207

967121

904156

13C-PFBA IS

5.0000

4.7177

nq/mL

13C-PFPeA IS

Auto

5.365

1355310

1355310

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.365

1355310

2076412

13C7-PFUnDA IS

5.0000

6.3221

nq/mL

PFPeA

Auto

5.366

1238444

1355310

13C-PFPeA IS

5.0000

4.6855

nq/mL

13C-PFBS IS

Auto

5.495

488832

488832

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.495

488832

2076412

13C7-PFUnDA IS

4.6500

5.5562

nq/mL

PFBS

Auto

5.494

362423

488832

13C-PFBS IS

4.4200

4.5152

nq/mL

13C HFPO DA IS

Auto

6.098

251023

251023

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.098

251023

2076412

13C7-PFUnDA IS

5.0000

5.6292

nq/mL

HFPO DA

Auto

6.098

206053

251023

13C HFPO DA IS

5.0000

5.1832

nq/mL

13C-4 2-FTS IS

Auto

5.899

212154

212154

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.899

212154

2076412

13C7-PFUnDA IS

4.6700

5.0747

nq/mL

4-2-FtS

Auto

5.898

234269

212154

13C-4 2-FTS IS

4.6700

4.4215

nq/mL

PFHxA

Auto

5.953

2361103

1863618

13C-PFHxA IS

5.0000

4.8364

nq/mL

13C-PFHxA IS

Auto

5.953

1863618

1863618

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

5.953

1863618

2076412

13C7-PFUnDA IS

5.0000

6.0512

nq/mL

PFPeS

Auto

5.994

371111

538772

180-PFHxS IS

4.6900

4.6112

nq/mL

PFHxS

Auto

6.365

287678

538772

180-PFHxS IS

4.5500

4.0450

nq/mL

13C-PFHpA IS

Auto

6.360

1865350

1865350

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.360

1865350

2076412

13C7-PFUnDA IS

5.0000

6.1033

nq/mL

180-PFHxS IS

Auto

6.366

538772

538772

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.366

538772

2076412

13C7-PFUnDAJS

4.7250

6.0537

ng/mL

PFHpA

Auto

6.360

2770482

1865350

1 3C-PFHpA IS

5.0000

4.9927

ng/mL

13C2-6 2-FTS IS

Auto

6.661

327262

327262

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.661

327262

2076412

1 3C7-PFUnDA IS

4.7500

4.6172

ng/mL

PFHpS

Auto

6.670

369535

538772

180-PFHxS IS

4.7600

4.7175

nq/mL

6-2-FTS

Auto

6.661

302593

327262

13C2-6 2-FTS IS

4.7400

4.7370

nq/mL

PFOA

Auto

6.679

3140580

2564692

13C-PFOA IS

5.0000

4.4338

nq/mL

13C-PFOA IS

Auto

6.679

2564692

2564692

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.679

2564692

2076412

13C7-PFUnDA IS

5.0000

6.4089

nq/mL

PFOS

Auto

6.968

260305

519085

13C-PFOS IS

4.6400

4.3548

nq/mL

13C-PFOS IS

Auto

6.968

519085

519085

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

6.968

519085

2076412

13C7-PFUnDA IS

4.7750

6.0015

nq/mL

PFNA

Auto

6.989

2431593

2653647

13C-PFNA IS

5.0000

4.1528

nq/mL

13C-PFNA IS

Auto

6.989

2653647

2653647

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.989

2653647

2076412

13C7-PFUnDA IS

5.0000

6.3107

nq/mL

PFNS

Auto

7.293

633898

519085

13C-PFOS IS

4.8000

4.8268

nq/mL

8-2-FTS

Auto

7.320

217759

226722

13C-8 2-FTS IS

4.7900

4.7573

nq/mL

13C-8 2-FTS IS

Auto

7.320

226722

226722

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.320

226722

2076412

13C7-PFUnDA IS

4.7900

4.5916

nq/mL

PFDA

Auto

7.324

2590954

2803841

13C-PFDA IS

5.0000

4.9190

r

13C-PFDA IS

Auto

7.324

2803841

2803841

	

5.0000

5.0000

ng/mL

13C-PFDA

Auto

7.324

2803841

2076412

13C7-PFUnDA IS

5.0000

5.8758

r

d3-N-MeFOSAA IS

Auto

7.500

688322

688322

	

5.0000

5.0000

ng/mL

cB-N-MeFOSAA

Auto

7.500

688322

2076412

13C7-PFUnDA IS

5.0000

6.3492

r

NMeFOSAA

Auto

7.504

656059

688322

d3-N-MeFOSAA IS

5.0000

4.7578

nq/mL

PFDS

Auto

7.633

413761

519085

13C-PFOS IS

4.8200

4.7507

r

13C-PFUnDA IS

Auto

7.673

2788924

2788924

	

5.0000

5.0000

ng/mL

13C-PFUnDA

Auto

7.673

2788924

2076412

13C7-PFUnDA IS

5.0000

5.9584

r

PFUnDA

Auto

7.673

2308971

2788924

13C-PFUnDA IS

5.0000

4.3315

ng/mL

d5-N-EtFOSAA IS

Auto

7.685

752677

752677

	

5.0000

5.0000

r

d5-N-EtFOSAA

Auto

7.685

752677

2076412

13C7-PFUnDA IS

5.0000

6.1887

ng/mL

NEtFOSAA

Auto

7.691

634685

752677

dS-N-EtFOSAA IS

5.0000

4.6351

r

PFOSA

Auto

7.742

659069

613878

13C-FOSA IS

5.0000

5.1338

ng/mL

13C-FOSA IS

Auto

7.741

613878

613878

	

5.0000

5.0000

r

13C-FOSA

Auto

7.741

613878

2076412

13C7-PFUnDA IS

5.0000

6.1890

nq/mL

PFDoA

Auto

8.018

2556120

2619707

13C-PFDoA IS

5.0000

5.1464

nq/mL

13C-PFDoA IS

Auto

8.017

2619707

2619707

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

89

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)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:22

CCV4-230426 (continued)













(Table continued from previous page)
Name Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.017

2619707

2076412

13C7-PFUnDA IS

5.0000

5.7989

nq/mL

10-2-FtS

Auto

8.029

223672

226722

13C-8 2-FTS IS

4.8200

3.9101

ng/mL

d5-NEtFOSA IS

Auto

8.769

565415

565415

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.769

565415

2076412

13C7-PFUnDA IS

5.0000

6.1998

ng/mL

NMeFOSE

Auto

8.494

263539

273982

d7-N-MeFOSE IS

5.0000

5.3054

nq/mL

NEtFOSE

Auto

8.744

853326

215167

d9-EtFOSE IS

5.0000

5.0613

ng/mL

d9-EtFOSE IS

Auto

8.725

215167

215167

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.725

215167

2076412

13C7-PFUnDA IS

5.0000

5.9469

ng/mL

NMeFOSA

Auto

8.519

237668

507918

d3-NMeFOSA IS

5.0000

5.3902

nq/mL

dB-NMeFOSA IS

Auto

8.514

507918

507918

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.514

507918

2076412

13C7-PFUnDA IS

5.0000

6.0367

nq/mL

d7-N-MeFOSE IS

Auto

8.479

273982

273982

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.479

273982

2076412

13C7-PFUnDA IS

5.0000

5.6612

nq/mL

NEtFOSA

Auto

8.779

406881

565415

d5-NEtFOSA IS

5.0000

4.9355

ng/mL

PFTrDA

Auto

8.344

2120929

878022

13C-PFTeDA IS

5.0000

7.7360

nq/mL

PFTeDA

Auto

8.644

2018746

878022

13C-PFTeDA IS

5.0000

7.0756

ng/mL

13C-PFTeDA IS

Auto

8.644

878022

878022

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.644

878022

2076412

13C7-PFUnDA IS

5.0000

3.4239

ng/mL

11CI-PFBOUdS

Auto

7.826

540677

519085

13C-PFOS IS

4.7100

4.7672

nq/mL

9CI-PF30NS

Auto

7.149

1113500

519085

13C-PFOS IS

4.6600

4.4147

ng/mL

L-PFDoS

Auto

8.294

190580

519085

13C-PFOS IS

4.8400

4.9834

nq/mL

NaDONA

Auto

6.405

1947680

2653647

13C-PFNA IS

4.7100

4.6933

ng/mL

PFHxDA

Auto

9.171

695962

3944295

13C2-PFHxDA IS

5.0000

2.5105

nq/mL

PFODA

Auto

9.721

593908

3944295

13C2-PFHxDA IS

5.0000

2.7726

ng/mL

13C2-PFHxDA IS

Auto

9.172

3944295

3944295

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.172

3944295

2076412

13C7-PFUnDA IS

5.0000

6.5252

ng/mL

13C7-PFUnDA IS

Auto

7.672

2076412

2076412

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.629

2124803

519085

13C-PFOS IS

4.6100

4.3150

ng/mL

PFBSA

Auto

6.138

1394095

613878

13C-FOSA IS

5.0000

4.6312

nq/mL

PFHxSA

Auto

6.961

1341139

2653647

13C-PFNA IS

5.0000

4.8123

ng/mL

CHARGE

ND(W/B)

	

	

2076412

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 6.9341
2.38e5 Q 217.20>172.30 (-)

PFBA

Cone. 4.7177
2.38e5 Q 213.20> 169.10 (-)

13C-PFPeA IS	13C-PFPeA

Cone. 5.0000	Cone. 6.3221

2.50e5 ISTD 267.90>223.00 (-)	6.30e5 Q 267.90>223.00 (-)

A=904156
RT=4.206

A=904156
RT=4.206

O.OeO -

O.OeO -

O.OeO -

~ A=1355310
RT= 5.365

Vj

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 4.6855	Cone. 4.6500	Cone. 5.5562 Cone. 4.5152

5.4 5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C_HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)

f A= 1238444
RT= 5.366

5.12e5 ISTD 301.80>80.00 (-)
2.0e5 -

A=488832
RT= 5.495

2.15e5 Q 301.80>80.00 (-)
2.0e5 -

R#1 298.80>99.00 71.77 (72.97)

2.15e5 Q 299.00>80.00 (-)	1.57e5 ISTD 332.10>287.10 (-)	1.17e5

A=362423

F^= 5.494	1fw::

5.4 5.6 5.8
RT (min)

5.4 5.6 5.

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

90

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:22

CCV4-230426 (continued)

13C HFPO DA

Cone. 5.6292

Q 332.10>287.10 (-)

A=251023
RT=6.098

L

Q 313.00>269.00 (-)



JA=2361103

-R1 2.59 (—

)RT= 5.953

<

I

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

TA= 1865350

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

r A=327262
RT=6.661

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
1.0e6 -

A=2564692
RT=6.679

HFPO DA

Cone. 5.1832

R#1 329.00>285.10 75.74 (68.92)
Q 329.00>169.00 (-)	9.81e4

TA=206053

-R1 75.74 (4^=6.098

O.OeO I, , , , jfp .........

6.0 6.2 6.4
RT (min)

PFHxA

Cone. 4.8364

R#1 313.00> 119.10 2.59 (2.54)

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 28.15 (27.58)

ISTD 329.00>309.15 (-)	9.68e4

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

13C-4 2-FTS

Cone. 5.0747

R#1 329.00>81.00 28.15 (27.58)
Q 329.00>309.15 (-)	9.68e4



l[A=212154



^ A=212154

:R1 28.15 (-

f^T= 5.899

R1 28.15 (-J

f^T= 5.899

-

7.5e4 -







S.0e4z_







^ 2.5e4z_







i. 	- 0OpO-

i



6.2 6.4
RT (min)

6.0 6.2
RT (min)

13C-PFHxA IS

Cone. 5.0000

13C-PFHxA

Cone. 6.0512

1.07e6

6.2

RT (min)

8.50e5 Q 366.90>322.10 (-)

~ A= 1865350

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)

1

180-PFHxS

Cone. 6.0537

2.51 e5 Q 402.70>84.05 (-)

O.OeO -

A= 538772
RT=6.366

Kt\5

538772
6.366

O.OeO -

L

6.6

RT (min)

6.6

RT (min)

6.2

6.4

13C2-6 2-FTS

Cone. 4.6172

1.39e5 Q 428.90>409.00 (-)

6.6
RT (min)

PFHpS

Cone. 4.7175

R#1 449.00>99.20 64.18 (65.35)
Q 449.00>80.15 (-)	1.64e5

6.2

6.4

Q 427.00>407.00 (-)

TA=327262
RT=6.661



f A=369535

- R1 64.18 (-

MT=6.670



V ~

TA=302593

:R1 29.18 (- £t=6.661

RT (min)

RT (min)

13C-PFOA

Cone. 6.4089

1.09e6 Q 416.80>372.05 (-)
1.0e6 -

6.6 6.8

RT (min)

PFOS

Cone. 4.3548

R#1 499.00>99.00 91.23 (96.24)
Q 499.00>80.00 (-)	8.11e4

13C-PFOS IS

Cone. 4.7750

6.8 7.0
RT (min)

4-2-FtS

Cone. 4.4215

R#1 327.00>81.10 15.23 (15.16)
Q 327.00>307.05 (-)	1.06e5

1.0e5-Ri 15.23 (-

A=234269
$T= 5.898

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 4.6112

R#1 349.00>99.00 83.43 (80.87)
Q 349.00>79.95 (-)	1.70e5

O.OeO -

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 4.0450

R#1 399.00 >99.00 94.13 (92.02)
Q 399.00>80.00 (-)	1.08e5

| A=287678

1.0e5-R1 94.13 (- rT=6.365

J^

O.OeO ,

6.2 6.4 6.6

RT (min)

PFHpA

Cone. 4.9927

R#1 362.90 >169.00 16.89 (17.74)
Q 362.90>319.00 (-)	1.25e6

TA=2770482

IR1 1689 (" }^T=6.360

O.OeO -

6.6
RT (min)

6-2-FTS

Cone. 4.7370

R#1 427.00>80.90 29.18 (27.82)

6.2

6.4

6.6
RT (min)

PFOA

Cone. 4.4338

R#1 413.00> 169.10 29.12 (27.71)

1.29e5 Q 413.00>369.00 (-)

1.34e6

f A=3140580

2 (" I RT=6.679

RT (min)

13C-PFOS

Cone. 6.0015

2.20e5 Q 502.80>80.05 (-)
2.0e5 -

6.8 7.0
RT (min)

A=519085
RT=6.968



6.8 7.0 7.2

RT (min)

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

91

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:22

CCV4-230426 (continued)

PFNA	13C-PFNA IS

Conc. 4.1528	Conc. 5.0000
R#1 463.00>219.00 22.59 (20.94)

Q 463.00>418.90 (-)	1.01e6	ISTD 467.80>423.00 (-)

1.0e6 -

A=2431593

R1 22.59 ( =6

13C-8 2-FTSJS

Cone. 4.7900

ISTD 528.80>509.00 (-)

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

A=226722
RT=7.320



7.2

ISTD 572.80>419.05 (-)

A=688322
RT=7.500

V,

13C-PFUnDA

Cone. 5.9584

Q 564.80>519.95 (-)
1.0e6	1

O.OeO



RT=7.673

-

L

7.6

- R1 0.20 (--

|A=659069
kT=7.742

13C-8 2-FTS

Cone. 4.5916

8.62e4 Q 528.80> 509.00 (-)

7.5e4 ^

5.0e4 ^

2.5e4 ^

O.OeO 1. . .

7.4 7.6

RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

d3-N-MeFOSAA

Cone. 6.3492

2.61 e5 Q 572.80>419.05 (-)

O.OeO -

7.6 7.8
RT (min)

7.4



rA=2308971

: R1 14.79

r

I

L

7.8 8.0
RT (min)

PFOSA

Cone. 5.1338

R#1 498.20>64.10 0.20 (0.15)
Q 498.20>78.00 (-)	2.62e5

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

rA=613878
| RT=7.741

7.8 8.0

RT (min)

13C-PFNA

Cone. 6.3107

Q 467.80>423.00 (-)
1.0e6 -

PFNS

Cone. 4.8268

R#1 549.00>99.00 66.28 (65.53)

1.10e6 Q 549.00>79.95 (-)

A=2653647
RT=6.989

O.OeO -

O.OeO -

A=633898

R1 66.28 (ff Rt=7.293

6.8

7.0

7.2

7.2

RT (min)

PFDA

Cone. 4.9190
R#1 512.90>219.00 19.34(18.19)

Q 512.90>469.00 (-)	1.04e6 ISTD 514.80>469.95 (-)

13C-PFDAJS

Cone. 5.0000

1.0e6

'A=2590954
iRI 19.34 jRt=7.324

7.4 7.6

RT (min)

O.OeO

7.6
RT (min)

NMeFOSAA

Cone. 4.7578

R#1 570.20>512.00 38.35 (35.78)
Q 570.20>419.00 (-)	2.03e5

2.0e5 -

~ A=656059
R1 38.35 (-Mt=7.504

jSl

7.6 7.8
RT (min)

PFUnDA

Cone. 4.3315

R#1 563.00>219.00 14.79 (11.87)
Q563.00>518.90 (-)	8.67e5

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

7.8 8.0
RT (min)

13C-FOSA

Cone. 6.1890

2.46e5 Q 506.00>78.05 (-)

7.6 7.8 8.0

RT (min)

O.OeO -

7.2

7.4

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 6.1887

2.76e5 Q 588.80>419.00 (-)

O.OeO -

7.8 8.0
RT (min)

A=613878
RT=7.741

7.6

7.6 7.8 8.0

RT (min)

8-2-FTS

Cone. 4.7573

R#1 527.20>487.00 7.69 (5.33)

2.60e5 Q 527.10>506.90 (-)

5.0e4 -
2.5e4 ^
O.OeO :



A=217759

- R1 7.69 (-

1^T=7.320

I

L

7.4 7.6
RT (min)

7.6
RT (min)

13C-PFDA

Cone. 5.8758

1.13e6 Q 514.80>469.95 (-)

7.6
RT (min)

PFDS

Cone. 4.7507

R#1 599.00>99.00 56.34 (60.20)
Q 599.00>80.10 (-)	1.63e5

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)
1.0e6H

A=2788924
RT=7.673

L

O.OeO , ,

7.6 7.8 8.0
RT (min)

NEtFOSAA

Cone. 4.6351

R#1 584.20>526.10 60.80 (55.50)
Q 584.20>418.95 (-)	1.94e5

1.5e5~
1.0e5:
5.0e4 4
O.OeO -



fA=634685

: R1 60.80 (-

fpT=7.691

/~J\J



7.8 8.0
RT (min)

PFDoA

Cone. 5.1464

R#1 613.05> 169.00 16.70 (15.47)
Q 613.05>569.00 (-)	9.87e5

rA=2556120
-R1 16.70 Jrt)=8.018

8.00
RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)
1.0e6i

A=2619707
RT=8.017

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

92

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:22

CCV4-230426 (continued)

13C-PFDoA

Cone. 5.7989

Q614.80>569.95 (-)
1.0e6 i

10-2-FtS

Cone. 3.9101

R#1 626.50>81.05 80.72 (56.92)
Q 626.50>607.05 (-)	8.37e4

fA=223672
7.5e4^R1 8072 i|"RT^8.029

5.0e4 :

2.5e4 :

O.OeO :

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 6.1998

2.24e5 Q 531.10>169.10 (-)

T

O.OeO -

NMeFOSE

Cone. 5.3054

2.24e5 Q 616.10> 58.90 (-)
1.0e5-

RT (min)

RT (min)

9.0

RT (min)

8.6

NEtFOSE

Cone. 5.0613

Q 629.50>59.10 (-)

3.0e5 ^

2.0e5 ^

1.0e5 ^

O.OeO -I. . . .

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 5.9469

3.39e5 ISTD 638.90> 59.10 (-)

7.5e4 ^

5.0e4 ^

2.5e4 ^

— O.OeO I,,,

8.49e4 Q 638.90> 59.10 (-)

7.5e4 ^

5.0e4 ^

2.5e4 ^
— O.OeO I,,,

.8 9.0

RT (min)

NMeFOSA

Cone. 5.3902

R#1 512.10>219.20 81.17 (86.99)
Q 512.10> 169.20 (-)	9.36e4

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

= R1 81.17 (-

7.5e4 -
5.0e4z_
2.5e4z_
O.OeO -

A=237668
1^T=8.519

ISTD 515.10> 169.00 (-)	2.01 e5

2.0e5 -

O.OeO -

9.0
RT (min)

9.0
RT (min)

9.0
RT (min)

d3-NMeFOSA

Cone. 6.0367

Q 515.10> 169.00 (-)
2.0e5

d7-N-MeFOSE IS

Cone. 5.0000

O.OeO -

ISTD 623.00>59.00 (-)
1.0e5 -

O.OeO -

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 7.0756
R#1 713.00 >169.30 11.63 (10.03)

Q 713.00 > 668.90 (-)	7.91 e5 I STD 714.80 > 669.80 (-)

d7-N-MeFOSE

Cone. 5.6612

Q 623.00>59.00 (-)
1.0e5 -

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 4.9355

R#1 526.50>219.20 65.67 (64.74)
Q 526.50> 169.10 (-)	1.63e5

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 7.7360

R#1 663.10> 169.10 23.30 (18.77)
Q 663.10>618.90 (-)	8.41 e5

~ A=2120929
8.344

RT (min)

RT (min)

8.6

RT (min)

13C-PFTeDA IS

Cone. 5.0000

13C-PFTeDA

Cone. 3.4239

3.43e5 Q 714.80>669.80 (-)



TA=2018746

:R1 11.63

|"RT-8.644

I



11CI-PF30UdS

Cone. 4.7672

Q 631.00>451.10 (-)

9CI-PF30NS

Cone. 4.4147

2.19e5 Q 531.00>351.10 (-)

8.6 8.8 9.0
RT (min)

L-PFDoS

Cone. 4.9834
R#1 698.80>98.80 65.91 (68.45)

Q 698.80>80.10 (-)	7.91e4 Q 377.10>251.20 (-)

fA= 190580

7.5e4-Ri 65.91 |1-rjL8.294

IA= 11
RT=7.

13500
=7.149

RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

f A=1947680

Q 812.90>769.00 (-)
3.0e5 n

A=695962
RT=9.171

Q 912.80>869.00 (-)
2.0e5 H

2.05e5 I STD 815.00 > 770.00 (-)

1.5e6^

1.0e6^

5.0e5 ^
T-. . . O.OeO 1. . .

8.4 8.6
RT (min)

9.4

RT (min)

10.0

RT (min)

9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

93

-------
A

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:22

CCV4-230426 (continued)

13C2-PFHxDA

Cone. 6.5252

Q 815.00>770.00 (-)

1.5e6 -j
^.0e61_

5.0e5 i
O.OeO 1 . .

13C7-PFUnDA IS

Cone. 5.0000

1.71 e6 ISTD 569.80> 524.90 (-)

PFecHS	PFBSA

Cone. 4.3150	Cone. 4.6312
R#1 461.00>99.10 40.30 (37.10)

7.74e5 Q 461.00>381.00 (-)	8.84e5	Q 298.00>78.00 (-)

PFHxSA

Cone. 4.8123

5.99e5 Q 397.90>78.00 (-)

A=3944295
RT=9.172

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

0.2
RT (min)

A=2076412
RT=7.672



7.5e5
5.0e5
2.5e5
O.OeO

fA=2124803
]R1 40.30 (-Mt=6.629

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO -

8.0
RT (min)

RT (min)

fA= 1394095
RT=6.138

7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

94

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1st /S/AO 04/28/23
2nd /S/AO 05/01/23

Insight Report
Quantitation/Integration
Printed 4/28/2023 10:14:04

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/27/2023 8:03:33 AM
Acquired by: System Administrator
Data File: 230426059
Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5













Name

Mode ID Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto





757446

	 	

5.0000

i ' '

13C-PFBA

Auto

4.209

757446

2313106

13C7-PFUnDA IS

5.2145

ng/ml

PFBA

Auto

4.210

14352

757446

13C-PFBA IS

0.0836

ng/mL

13C-PFPeA IS

Auto

5.369

1174595

1174595

	 	

5.0000

ng/ml

13C-PFPeA

Auto

5.369

1174595

2313106

13C7-PFUnDA IS

4.9185

ng/mL

PFPeA

Auto

5.368

21439

1174595

13C-PFPeA :



ng/ml

13C-PFBS IS

Auto

5.498

456612

456612

	 	

4.6500

g/mL

13C-PFBS

Auto

5.498

456612

2313106

13C7-PFUn[ .

4.6589

ng/ml

PFBS

Auto

5.498

6085

456612

13C-PFBS IS

0.0812

nci/mL

13C HFPO DA IS

Auto

6.100

241448

241448

	 	

5.0000

ng/ml

FPO DA

Auto

6.100

241448

2313106

>FUn[

4.3o04

ng/mL

HFPO DA

Auto

6.100

3341

241448

13C HFPO DA IS

0.0874

ng/ml

13C-4 2-FTS IS

Auto

5.901

170145

170145

	 	

4.6700

i L

13C-4 2-FTS

Auto

5.901

170145

2313106

13C7-PFUn[

3.6534

nq/ml

4-2-FtS

Auto

5.904

4129

170145

13C-4 2-FTS IS

0.0972

ng/mL

PFHxA

Auto

5.955

45744

1600895

13C-PFHxA

0.1091

ng/ml

13C-PFHxA IS

Auto

5.955

1600895

1600895

	 	

5.0000

ng/mL

13C-PFHxA

Auto

5.955

1600895

2313106

13C7-PFUnDA IS

'¦I

ng/ml

PFPeS

Auto

5.999

6361

492469

100-PFHxS

0.0865

nq/mL

PFHxS

Auto

6.367

6297

469

180-PFHxS

0.0969

ng/ml

13C-PFHpA IS

Auto

6.362

1638905

1638905

	 	

5.0000

ng/mL

13C-PFHpA

Auto

6.362

1638905

2313106

13C7-PFUn[



ng/ml

kV PI H\s IS

Auto

6.368

492469

492469

	

4.7250

ng/mL

180-PFHxS

Auto

6.368

492469

2313106

13C7-PFUn[

4.9672

ng/ml

PFHpA

Auto

6.363

52498

1638905

:HpA

0.1077

g/mL

5 2-FTS IS

Auto

6.664

;

283495

	 	

4

ng/ml

2- V

Auto

6.664

283495

2313106

'FLirti:

3.5904

g/mL



Auto

6.674

6193

492469

180-PFHxS

0.0865

ng/ml

6-2-FTS

Auto

6.667

5012

283495

13C2-6 2-FTS IS

4 > 4 (>¦•/» in

nq/mL

PFOA

Auto

6.681

59356

: 403

13C-PF

0.0976

ng/ml

13C-PFOA IS

Auto

6.682

2202403

2202403

	 	

5.0000

ng/mL

13C-PFOA

Auto

6.682

2202403

2313106

13C7-PFUn[

4.9404

ng/ml

PFOS

M

6.972

4317

460622

13C-PFOS IS

0.0814

ng/mL

FOS IS

Auto

6.971

460622

460622

	 	

4.7750

ng/ml

13C-PFOS

Auto

6.971

460622

2313106

13C7-PFUnDA IS

4.7806

ng/mL

PFNA

Auto

6.992

51159

¦'¦' 546

13C-PFNA IS

0.0985

ng/ml

13C-PFNA IS

Auto

6.992

2354546

2354546

	

5.0000

ng/mL

13C-PFNA

Auto

6.992

2354546

2313106

13C7-PFUn[

: :.4

ng/ml

PFNS

Auto

7.298

9541

460622

:OS IS



ng/mL

8-2-FTS

Auto

7.326

4107

214648

13C-8 2-FTS IS

0.0948

nq/ml

13C-8 2-FTS IS

Auto

7.325

214648

214648

	 	

4.7900

ng/mL

13C-8 2-FTS

Auto

7.325

214648

''106

13C7-PFUnDA IS

3.9022

ng/ml

PFDA

Auto

7.330

48475

2608885

13C-PFDA IS

0.0989

ng/mL

13C-PFDA IS

Auto

7.329

2608885

2608885

	 	

5.0000

ng/ml

13C-PFDA

Auto

7.329

2608885

2313106

13C7-PFU nt

4.9078

ng/mL

d3-N-MeFOSAA IS

Auto

7.507

595152

595152

	 	

5.0000

ng/ml

d3-N-MeFOSAA

Auto

7.507

595152

2313106

13C7-PFUnDA IS

4.9281

ng/mL

NMeFOSAA

Auto

7.512

9949

595152

d3-N-MeFOSAA IS

0.0834

ng/ml

PFDS

Auto

7.642

6248

460622

13C-PFOS IS

0.0808

ng/mL

13C-PFUnDA IS

Auto

7.681

2632533

2632533

	 	

5.0000

nq/ml

139

560699

13C-FC

0.0944

ng/ml

3SA IS

Auto

7.750

»

560699

	 	

5.0000

ng/mL

13C-FOSA

Auto

7.750

560699

¦" ¦ 106

13C7-PFUnDA IS

5.0744

ng/ml

PFDoA

Auto

8.025

56

2522896

13C-PFDoA IS

0.1108

ng/mL

13C-PFDoAJS

I -iC-PFDoA

Auto
Auto

8.026

2522896

2522896

	 	

5.0000

132

nq/ml

ng/mL

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCalJproc

95

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1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:14:04

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone. Cone. Unit

10-2-FtS

Auto

8.035

5163

214648

13C-8 2-FTS IS

—- 0.0953

nq/mL

d5-NEtFOSA IS

Auto

8.777

520860

520860

—

—- 5.0000

nq/mL

d5-NEtFOSA

Auto

8.777

520860

2313106

13C7-PFUnDA IS

—- 5.1268

nq/mL

NMeFOSE

Auto

8.501

4679

282755

d7-N-MeFOSE IS

—- 0.0913

nq/mL

NEtFOSE

Auto

8.751

13773

184807

d9-EtFOSE IS

—- 0.0951

nq/mL

d9-EtFOSE IS

Auto

8.732

184807

184807

—

—- 5.0000

nq/mL

d9-EtFOSE

Auto

8.732

184807

2313106

13C7-PFUnDA IS

—- 4.5851

nq/mL

NMeFOSA

Auto

8.529

4023

480651

d3-NMeFOSA IS

—- 0.0964

nq/mL

dB-NMeFOSA IS

Auto

8.520

480651

480651

—

—- 5.0000

nq/mL

dB-NMeFOSA

Auto

8.520

480651

2313106

13C7-PFUnDA IS

—- 5.1281

nq/mL

d7-N-MeFOSE IS

Auto

8.484

282755

282755

—

—- 5.0000

nq/mL

d7-N-MeFOSE

Auto

8.484

282755

2313106

13C7-PFUnDA IS

—- 5.2446

nq/mL

NEtFOSA

Auto

8.787

8682

520860

d5-NEtFOSA IS

—- 0.1143

nq/mL

PFTrDA

Auto

8.351

44530

1372349

13C-PFTeDA IS

—- 0.1039

nq/mL

PFTeDA

Auto

8.650

45762

1372349

13C-PFTeDA IS

—- 0.1026

nq/mL

13C-PFTeDA IS

Auto

8.650

1372349

1372349

—

—- 5.0000

nq/mL

1BC-PFTeDA

Auto

8.650

1372349

2313106

13C7-PFUnDA IS

—- 4.8039

nq/mL

11CI-PF30UdS

Auto

7.835

8369

460622

13C-PFOS IS

—- 0.0832

nq/mL

9CI-PFBONS

Auto

7.154

22375

460622

13C-PFOS IS

—- 0.1000

nq/mL

L-PFDoS

Auto

8.302

3003

460622

13C-PFOS IS

—- 0.0885

nq/mL

NaDONA

Auto

6.405

32239

2354546

13C-PFNA IS

—- 0.0876

nq/mL

PFHxDA

Auto

9.177

39192

3519326

13C2-PFHxDA IS

—- 0.0689

nq/mL

PFODA

Auto

9.728

18014

3519326

13C2-PFHxDA IS

—- 0.0943

nq/mL

13C2-PFHxDA IS

Auto

9.177

3519326

3519326

—

—- 5.0000

nq/mL

1BC2-PFHxDA

Auto

9.177

3519326

2313106

13C7-PFUnDA IS

—- 5.2264

nq/mL

13C7-PFUnDA IS

Auto

7.681

2313106

2313106

—

—- 5.0000

nq/mL

PFecHS

Auto

6.633

37382

460622

13C-PFOS IS

—- 0.0856

nq/mL

PFBSA

Auto

6.141

25751

560699

13C-FOSA IS

—- 0.0937

nq/mL

PFHxSA

Auto

6.965

21739

2354546

13C-PFNA IS

—- 0.0879

nq/mL

CHARGE

ND(W/B)

	

	

2313106

13C7-PFUnDA IS

	 	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 5.2145
Q 217.20> 172.30 (-)

PFBA

Cone. 0.0836
1.70e5 Q 213.20> 169.10 (-)

4.0e3 -

13C-PFPeA IS

Cone. 5.0000
4.16e3 I STD 267.90 > 223.00 (-)

13C-PFPeA

Cone. 4.9185
4.74e5 Q 267.90>223.00 (-)

fA= 14352
RT=4.210

O.OeO -

O.OeO -

5.2

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 0.0936	Cone. 4.6500	Cone. 4.6589 Cone. 0.0812

fA= 1174595
RT= 5.369

~ A= 1174595
RT= 5.369

7

!!!!,: O.OeO -I"]—, , £ -
5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)

8.07e3 I STD 301.80 > 80.00 (-)

1.67e5 Q 301.80>80.00 (-)

R#1 298.80>99.00 63.09 (72.97)

1.67e5 Q 299.00>80.00 (-)	2.20e3 ISTD 332.10>287.10 (-)	1.03e5

A=21439

RT= 5.368	1.5e5-

A=456612

RT= 5.498	1.5e5-

A=241448
RT=6.100

6.0 6.2 6.4
RT (min)

5.0e3 -
2.5e3 :

1.0e5 -
5.0e4 -

1.0e5 -
5.0e4 -

O.OeO :

A=456612

RT= 5.498	2.0e3-

5.6

RT (min)

O.OeO :

5.6 5.8
RT (min)

O.OeO :

5.6 5.8
RT (min)

f A=6085

R1 63.09 (-*-^1=5.498

5.6 5.8
RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

96

-------
1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:14:04

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 4.8604

Q 332.10>287.10 (-)
1.0e5 H

A=241448
RT=6.100

HFPO DA

Cone. 0.0874

R#1 329.00>285.10 51.97 (68.92)
Q 329.00>169.00 (-)	1.60e3

*A=3341
1.5e3 - R1 51.97 Hrtfr=6.100

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 27.54 (27.58)

ISTD 329.00>309.15 (-)	6.88e4

f A=170145

6.0e4-R1 27 54 ("#TiT=5.901

13C-4 2-FTS

Cone. 3.6534

R#1 329.00>81.00 27.54 (27.58)

4-2-FtS

Cone. 0.0972

R#1 327.00>81.10 10.28 (15.16)

Q 329.00>309.15 (-)

f A=170145

6.88e4 Q 327.00>307.05 (-)

f A=4129

:R1 10.28 (-1^=5.904

O.OeO -

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 0.1091

R#1 313.00> 119.10 1.77 (2.54)
Q 313.00>269.00 (-)	1.87e4

13C-PFHxA IS

Cone. 5.0000

13C-PFHxA

Cone. 4.6662

6.0 6.2
RT (min)

PFPeS

Cone. 0.0865

R#1 349.00>99.00 113.20 (80.87)

6.68e5 Q 349.00>79.95 (-)

" R1 113.20 (I A)"6361
1 RT= 5.999

6.2
RT (min)

6.2

RT (min)

13C-PFHpA IS

Cone. 5.0000

I STD 366.90 >322.10 (-)

7.19e5 Q 366.90>322.10 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

fA= 1638905
RT=6.362

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

fA= 1638905
RT=6.362

180-PFHxS IS

Cone. 4.7250

I STD 402.70>84.05 (-)
2.0e5 -

180-PFHxS

Cone. 4.9672

A=492469
RT=6.368

1.0e5 -

O.OeO -

6.6

RT (min)

6.6

RT (min)

6.2

13C2-6 2-FTS IS

Cone. 4.7500

13C2-6 2-FTS

Cone. 3.5904

6.4 6.6

RT (min)

PFHpS

Cone. 0.0865

R#1 449.00>99.20 66.77 (65.35)

ISTD 428.90>409.00 (-)

1.24e5 Q 428.90>409.00 (-)

1.24e5 Q 449.00>80.15 (-)

2.49e3 Q 427.00>407.00 (-)

A=283495
RT=6.664

A=283495
RT=6.664

IR1 66.77 (-

~ A=6193
;-^T=6.674

*A=5012

-R1 31.71 Hrfrr=6.667

O.OeO -

O.OeO -

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

13C-PFOA

Cone. 4.9404

9.34e5 Q 416.80>372.05 (-)

6.6 6.8

RT (min)

PFOS

Cone. 0.0814
R#1 499.00>99.00 83.53 (96.24)

Q 499.00> 80.00 (-)	1.19e3 I STD 502.80 > 80.05 (-)

13C-PFOS IS

Cone. 4.7750

2202403
=6.682

f A=4317
- R1 83.53 (—|)RT=6.972

f A=460622
I RT=6.971

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

6.0 6.2
RT (min)

PFHxS

Cone. 0.0969

R#1 399.00>99.00 65.41 (92.02)

2.54e3 Q 399.00>80.00 (-)

2.57e3

fA=6297
IR1 6541 ("1+1^7=6-367

O.OeO -

6.2

6.4

Q 402.70>84.05 (-)

2.0e5 -

1.0e5

O.OeO

6.4 6.6

RT (min)

6-2-FTS

Cone. 0.0906

R#1 427.00>80.90 31.71 (27.82)

6.6

RT (min)
PFHpA

Cone. 0.1077

R#1 362.90 >169.00 14.68 (17.74)
2.20e5 Q 362.90>319.00 (-)	2.34e4

f A= 52498

"R1 14.68 (-4-|^t=6.363

O.OeO -

6.2

6.4 6.6

RT (min)

PFOA

Cone. 0.0976

R#1 413.00 >169.10 26.91 (27.71)

1.98e3 Q 413.00>369.00 (-)

2.55e4

~ A= 59356
:R1 26.91 (--1-^1=6.681

RT (min)

6.6 6.8 7.0
RT (min)

13C-PFOS

Cone. 4.7806

1.96e5 Q 502.80>80.05 (-)

|f A=460622
| RT=6.971

6.8 7.0 7.2

RT (min)

6.8 7.0 7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

97

-------
1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:14:04

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0985

R#1 463.00>219.00 18.72 (20.94)
Q 463.00>418.90 (-)	2.14e4

^A=51159
2.0e4^R1 18.72 (-j-^r=6.992

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

7.5e4 i
5.0e4 ^

2.5e4 i
O.OeO 1. . .

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)
2.0e5 -

7.6 7.8
RT (min)

13C-PFUnDA

Cone. 5.0488

Q 564.80>519.95 (-)

O.OeO -

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 5.0264

9.65e5 Q 467.80>423.00 (-)

fA=2354546
| RT=6.992

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

A=2354546
RT=6.992

7.2

RT (min)

7.2

RT (min)

6.8

7.0

13C-8 2-FTS

Cone. 3.9022

8.55e4 Q 528.80> 509.00 (-)

7.5e4 i
5.0e4 ^

2.5e4 i
=== O.OeO I. . .

7.6
RT (min)

7.6
RT (min)

d3-N-MeFOSAA

Cone. 4.9281

Q 572.80>419.05 (-)
2.0e5 -

O.OeO -

3.0e3 -
2.0e3 -
1.0e3-
O.OeO -

f A=9949

R1 36.47 (--h^T=7.5i2

7.4

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

7.6 7.8
RT (min)

PFUnDA

Cone. 0.0996
R#1 563.00>219.00 9.65 (11.87)

9.84e5 Q563.00>518.90 (-)	1.91e4 ISTD 588.80>419.00 (-)

f A=50113
:R1 9.65 KtfT=7.681

7.6

.8 8.0
RT (min)

PFOSA

Cone. 0.0944
R#1 498.20>64.10 0.00 (0.15)

Q 498.20>78.00 (-)	4.53e3 ISTD 506.00>78.05 (-)

13C-FOSA IS

Cone. 5.0000

13C-FOSA

Cone. 5.0744

2.24e5 Q 506.00>78.05 (-)

~ A= 11069

4.0e3-R1 000 J)RT=7.751

fA= 560699
| RT=7.750

7.8 8.0

RT (min)

7.8 8.0

RT (min)

PFNS

Cone. 0.0819

R#1 549.00>99.00 70.97 (65.53)

8-2-FTS

Cone. 0.0948

R#1 527.20>487.00 5.43 (5.33)

Q 549.00>79.95 (-)
4.0e3

~ A=9541

R1 70.97 (fRt=7.298

7.2
RT (min)

PFDA

Cone. 0.0989

R#1 512.90>219.00 20.23 (18.19)
Q 512.90>469.00 (-)	1.86e4

~ A=48475

IR1 20.23 (^f-Rt=7.330

4.25e3 Q 527.10>506.90 (-)

fA=4107
1.5e3-R1 543	7.326

1.0e3-
5.0e2 :
O.OeO :

7.4 7.6
RT (min)

7.6
RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 4.9078

ISTD 514.80>469.95 (-)
1.0e6-

YA=2608885
RT=7.329

1.06e6 Q 514.80>469.95 (-)
1.0e6-

A=2608885
RT=7.329

O.OeO -

I

O.OeO -

7.6
RT (min)

NMeFOSAA

Cone. 0.0834

R#1 570.20>512.00 36.47 (35.78)
Q 570.20>419.00 (-)	3.20e3

7.2

7.4

7.2

7.4

13C-PFUnDA_IS

Cone. 5.0000

7.6
RT (min)

PFDS

Cone. 0.0808
R#1 599.00>99.00 67.39 (60.20)

Q 599.00>80.10 (-)	2.23e3 ISTD 564.80>519.95 (-)

fA=6248

2.0e3- R1 6739 (rRt=7.642

7.6
RT (min)

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 4.9448

2.39e5 Q 588.80>419.00 (-)

O.OeO -

O.OeO

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.1162

R#1 584.20>526.10 42.30 (55.50)
Q 584.20>418.95 (-)	4.00e3

4.0e3

O.OeO



rA=14157

- R1 42.30 (--

""&T=7.700





7.8 8.0
RT (min)

7.6

7.8 8.0
RT (min)

PFDoA

Cone. 0.1108

R#1 613.05> 169.00 16.47 (15.47)
Q 613.05>569.00 (-)	1.99e4

If A= 52986

- R1 16 47 (l~RT)= 8.025

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

7.6 7.8 8.0

RT (min)

ISTD 614.80>569.95 (-)

7.5e5 -
5.0e5 :
2.5e5 :
O.OeO :

9.66e5

RT (min)

RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

98

-------
1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:14:04

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 5.0132

Q614.80>569.95 (-)

7.5e5 -
5.0e5 :
2.5e5 :
O.OeO :

10-2-FtS

Cone. 0.0953

R#1 626.50>81.05 54.62 (56.92)
Q 626.50>607.05 (-)	2.20e3

fA=5163

2.0e3-R1 54.62 (--R-^=a.035

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)
2.0e51

d5-NEtFOSA

Cone. 5.1268

2.04e5 Q 531.10> 169.10(-)
2.0e51

NMeFOSE

Cone. 0.0913

2.04e5 Q 616.10> 58.90 (0

O.OeO -

1 A=4679
1 RT=8.501

RT (min)

RT (min)

9.0

RT (min)

8.6

NEtFOSE

Cone. 0.0951

Q 629.50>59.10 (0

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 4.5851

5.73e3 ISTD 638.90> 59.10 (0

7.20e4 Q 638.90> 59.10 (0

6.0e4 ~

4.0e4 ~

2.0e4 ~
— O.OeO 1 . .

.8 9.0

RT (min)

NMeFOSA

Cone. 0.0964

R#1 512.10>219.20 80.07 (86.99)
Q 512.10> 169.20 (0	1.64e3

Y A=4023
1.5e3- R1 80.07 ("1-^1=8.529

1.0e3~
5.0e2 :
O.OeO :

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (0

1.5e5-
1.0e5-
5.0e4-
O.OeO -

9.0
RT (min)

9.0
RT (min)

d3-NMeFOSA

Cone. 5.1281

Q 515.10> 169.00 (0

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

d7-N-MeFOSE IS

Cone. 5.0000

1,89e5 I STD 623.00 > 59.00 (0

d7-N-MeFOSE

Cone. 5.2446

1.15e5 Q 623.00> 59.00 (0

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 0.1026

R#1 713.00 >169.30 7.23 (10.03)
Q 713.00>668.90 (0	1.77e4

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.1143

R#1 526.50>219.20 63.61 (64.74)
Q 526.50>169.10 (0	3.02e3

* A=8682

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.1039

R#1 663.10> 169.10 17.48 (18.77)
Q 663.10>618.90(0	1.76e4

~ A=44530

: R1 17-48(1-^=8.351

RT (min)

RT (min)

8.6

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (0

13C-PFTeDA

Cone. 4.8039

11CI-PF30UdS

Cone. 0.0832

5.20e5 Q 714.80>669.80 (0

5.20e5 Q 631.00>451.10(0

9CI-PF30NS

Cone. 0.1000

3.42e3 Q 531.00>351.10(0

9.0
RT (min)

L-PFDoS

Cone. 0.0885

R#1 698.80 >98.80 48.07 (68.45)
Q 698.80>80.10 (0	1.52e3

13C2-PFHxDA IS

Cone. 5.0000

Q 377.10>251.20 (0

1.46e4 Q 812.90>769.00 (0

1.5e3 -

~ A=3003
R1 48.07 (|-r^=8.302

B.2 8.4 8.6

RT (min)

A=39192
RT=9.177

Q 912.80>869.00 (0
6.0e3 -

ISTD 815.00>770.00 (0
1.5e6-l

L

A=3519326
RT=9.177

9.4

RT (min)

9.4

RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

99

-------
1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:14:04

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 5.2264

Q 815.00>770.00 (-)
1.5e6

1.0e6 -

5.0e5 -



RT=9.177

I

L

O.OeO -

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

13C7-PFUnDA_IS

Cone. 5.0000

1.54e6 ISTD 569.80>524.90 (-)

7.5e5 ^

5.0e5 ^

2.5e5 i
O.OeO 4==

PFecHS	PFBSA

Cone. 0.0856	Cone. 0.0937
R#1 461.00>99.10 40.41 (37.10)

8.63e5 Q 461.00>381.00 (-)	1.54e4	Q 298.00>78.00 (-)

PFHxSA

Cone. 0.0879

1.03e4 Q 397.90>78.00 (-)

0.2
RT (min)

1.5e4~
1.0e4:
5.0e3 :
O.OeO -

~ A=37382

R1 4041 (---1^=6.633

1.0e4

8.0
RT (min)

6.4 6.6 6.8

RT (min)

A=21739
RT=6.965

7.2
RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCalJproc

100

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:26

CCV5-230426

Sample ID: CCV5-230426

Date Acquired: 4/27/2023 8:31:02 AM

Acquired by: System Administrator

Data File: 230426061

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name	Mode ID Found RT Area ISTDArea ISTD Name	Std. Cone. Cone. Unit

13C-PFBA IS

Auto

4.211

818284

818284

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.211

818284

2933951

13C7-PFUnDA IS

5.0000

4.4413

nq/mL

PFBA

Auto

4.212

934008

818284

13C-PFBA IS

5.0000

5.0343

nq/mL

13C-PFPeA IS

Auto

5.375

1342994

1342994

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.375

1342994

2933951

13C7-PFUnDA IS

5.0000

4.4336

nq/mL

PFPeA

Auto

5.375

1207223

1342994

13C-PFPeA IS

5.0000

4.6092

nq/mL

13C-PFBS IS

Auto

5.505

526909

526909

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.505

526909

2933951

13C7-PFUnDA IS

4.6500

4.2385

nq/mL

PFBS

Auto

5.504

335501

526909

13C-PFBS IS

4.4200

3.8778

nq/mL

13C HFPO DA IS

Auto

6.107

281340

281340

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.107

281340

2933951

13C7-PFUnDA IS

5.0000

4.4650

nq/mL

HFPO DA

Auto

6.107

198622

281340

13C HFPO DA IS

5.0000

4.4579

nq/mL

13C-4 2-FTS IS

Auto

5.908

203022

203022

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.908

203022

2933951

13C7-PFUnDA IS

4.6700

3.4369

nq/mL

4-2-FtS

Auto

5.908

230526

203022

13C-4 2-FTS IS

4.6700

4.5465

nq/mL

PFHxA

Auto

5.962

2340205

1783377

13C-PFHxA IS

5.0000

5.0093

nq/mL

13C-PFHxA IS

Auto

5.962

1783377

1783377

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

5.962

1783377

2933951

13C7-PFUnDA IS

5.0000

4.0981

nq/mL

PFPeS

Auto

6.003

357107

536364

180-PFHxS IS

4.6900

4.4571

nq/mL

PFHxS

Auto

6.375

273190

536364

180-PFHxS IS

4.5500

3.8585

nq/mL

13C-PFHpA IS

Auto

6.369

1773546

1773546

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.369

1773546

2933951

13C7-PFUnDA IS

5.0000

4.1068

nq/mL

180-PFHxS IS

Auto

6.375

536364

536364

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.375

536364

2933951

13C7-PFUnDAJS

4.7250

4.2652

ng/mL

PFHpA

Auto

6.369

2679473

1773546

1 3C-PFHpA IS

5.0000

5.0786

ng/mL

13C2-6 2-FTS IS

Auto

6.670

312093

312093

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.670

312093

2933951

1 3C7-PFUnDA IS

4.7500

3.1162

ng/mL

PFHpS

Auto

6.679

361489

536364

180-PFHxS IS

4.7600

4.6355

nq/mL

6-2-FTS

Auto

6.669

298767

312093

13C2-6 2-FTS IS

4.7400

4.9044

nq/mL

PFOA

Auto

6.688

3037204

2434881

13C-PFOA IS

5.0000

4.5165

nq/mL

13C-PFOA IS

Auto

6.688

2434881

2434881

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.688

2434881

2933951

13C7-PFUnDA IS

5.0000

4.3062

nq/mL

PFOS

Auto

6.978

241819

513225

13C-PFOS IS

4.6400

4.0917

nq/mL

13C-PFOS IS

Auto

6.977

513225

513225

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

6.977

- : !5

2933951

13C7-PFUnDA IS

4.7750

4.1994

nq/mL

PFNA

Auto

6.999

2950231

2544378

13C-PFNA IS

5.0000

5.2550

nq/mL

13C-PFNA IS

Auto

6.999

2544378

2544378

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.999

2544378

2933951

13C7-PFUnDA IS

5.0000

4.2823

nq/mL

PFNS

Auto

7.307

615148

513225

13C-PFOS IS

4.8000

4.7375

nq/mL

8-2-FTS

Auto

7.335

241075

233031

13C-8 2-FTS IS

4.7900

5.1241

nq/mL

13C-8 2-FTS IS

Auto

7.334

233031

233031

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.334

233031

2933951

13C7-PFUnDA IS

4.7900

3.3400

nq/mL

PFDA

Auto

7.339

2656836

2901172

13C-PFDA IS

5.0000

4.8749

r

13C-PFDA IS

Auto

7.339

2901172

2901172

	

5.0000

5.0000

ng/mL

13C-PFDA

Auto

7.339

2901172

2933951

13C7-PFUnDA IS

5.0000

4.3028

r

d3-N-MeFOSAA IS

Auto

7.516

686797

686797

	

5.0000

5.0000

ng/mL

cB-N-MeFOSAA

Auto

7.516

686797

2933951

13C7-PFUnDA IS

5.0000

4.4835

r

NMeFOSAA

Auto

7.520

647949

686797

d3-N-MeFOSAA IS

5.0000

4.7094

nq/mL

PFDS

Auto

7.648

411811

513225

13C-PFOS IS

4.8200

4.7823

r

13C-PFUnDA IS

Auto

7.688

2952662

2952662

	

5.0000

5.0000

ng/mL

13C-PFUnDA

Auto

7.688

2952662

2933951

13C7-PFUnDA IS

5.0000

4.4645

r

PFUnDA

Auto

7.689

2888463

2952662

13C-PFUnDA IS

5.0000

5.1181

ng/mL

d5-N-EtFOSAA IS

Auto

7.701

784042

784042

	

5.0000

5.0000

r

d5-N-EtFOSAA

Auto

7.701

784042

2933951

13C7-PFUnDA IS

5.0000

4.5624

ng/mL

NEtFOSAA

Auto

7.708

721496

784042

dS-N-EtFOSAA IS

5.0000

5.0583

r

PFOSA

Auto

7.757

596616

630824

13C-FOSA IS

5.0000

4.5225

ng/mL

13C-FOSA IS

Auto

7.756

630824

630824

	

5.0000

5.0000

r

13C-FOSA

Auto

7.756

630824

2933951

13C7-PFUnDA IS

5.0000

4.5010

nq/mL

PFDoA

Auto

8.032

2651198

2741665

13C-PFDoA IS

5.0000

5.1004

nq/mL

13C-PFDoA IS

Auto

8.032

2741665

2741665

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

101

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:26

CCV5-230426 (continued)













(Table continued from previous page)
Name Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.032

2741665

2933951

13C7-PFUnDA IS

5.0000

4.2951

nq/mL

10-2-FtS

Auto

8.044

334395

233031

13C-8 2-FTS IS

4.8200

5.6874

ng/mL

d5-NEtFOSA IS

Auto

8.782

548718

548718

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.782

548718

2933951

13C7-PFUnDA IS

5.0000

4.2581

ng/mL

NMeFOSE

Auto

8.505

268421

329438

d7-N-MeFOSE IS

5.0000

4.4941

nq/mL

NEtFOSE

Auto

8.756

807317

200308

d9-EtFOSE IS

5.0000

5.1437

ng/mL

d9-EtFOSE IS

Auto

8.738

200308

200308

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.738

200308

2933951

13C7-PFUnDA IS

5.0000

3.9180

ng/mL

NMeFOSA

Auto

8.531

237091

525166

d3-NMeFOSA IS

5.0000

5.2005

nq/mL

dB-NMeFOSA IS

Auto

8.526

525166

525166

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.526

525166

2933951

13C7-PFUnDA IS

5.0000

4.4174

nq/mL

d7-N-MeFOSE IS

Auto

8.490

329438

329438

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.490

329438

2933951

13C7-PFUnDA IS

5.0000

4.8175

nq/mL

NEtFOSA

Auto

8.792

396183

548718

d5-NEtFOSA IS

5.0000

4.9520

ng/mL

PFTrDA

Auto

8.356

2441168

1814715

13C-PFTeDA IS

5.0000

4.3081

nq/mL

PFTeDA

Auto

8.655

2412426

1814715

13C-PFTeDA IS

5.0000

4.0910

ng/mL

13C-PFTeDA IS

Auto

8.655

1814715

1814715

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.655

1814715

2933951

13C7-PFUnDA IS

5.0000

5.0082

ng/mL

11CI-PFBOUdS

Auto

7.841

514676

513225

13C-PFOS IS

4.7100

4.5897

nq/mL

9CI-PF30NS

Auto

7.161

1124902

513225

13C-PFOS IS

4.6600

4.5108

ng/mL

L-PFDoS

Auto

8.306

176126

513225

13C-PFOS IS

4.8400

4.6581

nq/mL

NaDONA

Auto

6.413

1761341

2544378

13C-PFNA IS

4.7100

4.4266

ng/mL

PFHxDA

Auto

9.182

1793094

3896116

13C2-PFHxDA IS

5.0000

7.0323

nq/mL

PFODA

Auto

9.734

1087777

3896116

13C2-PFHxDA IS

5.0000

5.1409

ng/mL

13C2-PFHxDA IS

Auto

9.182

3896116

3896116

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.182

3896116

2933951

13C7-PFUnDA IS

5.0000

4.5616

ng/mL

13C7-PFUnDA IS

Auto

7.688

2933951

2933951

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.638

2099644

513225

13C-PFOS IS

4.6100

4.3126

ng/mL

PFBSA

Auto

6.147

1348620

630824

13C-FOSA IS

5.0000

4.3598

nq/mL

PFHxSA

Auto

6.971

1265324

2544378

13C-PFNA IS

5.0000

4.7353

ng/mL

CHARGE

ND(W/B)

	

	

2933951

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 4.4413
1.83e5 Q 217.20>172.30 (-)

PFBA

Cone. 5.0343
1.83e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
2.07e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.4336
5.40e5 Q 267.90>223.00 (-)

A=934008
RT=4.212

O.OeO

O.OeO

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)
4.0e5 -

4.36e5 ISTD 301.80>80.00 (-)
2.0e5 -i

A= 526909
RT= 5.505

2.02e5 Q 301.80>80.00 (-)
2.0e5 -i

5.6

RT (min)

PFBS

Cone. 3.8778

R#1 298.80>99.00 69.47 (72.97)

2.02e5 Q 299.00>80.00 (-)	1.26e5 ISTD 332.10>287.10 (-)

A= 526909	TA=335501

RT= 5.505	I R1 6947 (" | 1*T= 5.504

5.6 5.8
RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

102

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:26

CCV5-230426 (continued)

13C HFPO DA

Cone. 4.4650

Q 332.10>287.10 (-)

f A=281340
I RT=6.107

O.OeO -

6.0

- R1 2.44 (--

A=2340205

L

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)
7.5e5 -

A=1773546
RT=6.369

5.0e5 :
2.5e5 :
O.OeO :

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
1.0e6 i

HFPO DA

Cone. 4.4579

R#1 329.00>285.10 71.86 (68.92)
Q 329.00>169.00 (-)	8.57e4

[A= 198622
7.5e4^R1 7186 C~"[pT=6.107

5.0e4 :

2.5e4 :

O.OeO :

6.2 6.4
RT (min)

PFHxA

Cone. 5.0093

R#1 313.00> 119.10 2.44 (2.54)
Q 313.00>269.00 (-)	9.78e5

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

6.0e5 i
4.0e5 ~

2.0e5 ~

O.OeO 1. . . ~T

6.2
RT (min)

13C-PFHpA

Cone. 4.1068

Q 366.90>322.10 (-)
7.5e5 -
5.0e5 ^

2.5e5 ^

O.OeO 1 . . .

A=1773546
RT=6.369

6.6

RT (min)

13C2-6 2-FTS

Cone. 3.1162

1.32e5 Q 428.90>409.00 (-)

RT (min)

13C-PFOA

Cone. 4.3062

1.02e6 Q 416.80>372.05 (-)
1.0e6 i

6.8 7.0
RT (min)

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 26.95 (27.58)

ISTD 329.00>309.15 (-)	8.52e4

{A=203022
"frT= 5.908

5.0e4 :
2.5e4 :
O.OeO :

6.2 6.4
RT (min)

13C-PFHxA

Cone. 4.0981

7.44e5 Q 314.90>270.10 (-)

6.0e5 i
4.0e5 ~

2.0e5 ~
j= O.OeO 1. . . t

6.2
RT (min)

180-PFHxS IS

Cone. 4.7250

7.81 e5 ISTD 402.70>84.05 (-)

O.OeO -

6.6

RT (min)

6.2

6.4

RT (min)

13C-4 2-FTS

Cone. 3.4369

R#1 329.00>81.00 26.95 (27.58)
Q 329.00>309.15 (-)	8.52e4

4-2-FtS

Cone. 4.5465

R#1 327.00>81.10 15.42 (15.16)
Q 327.00>307.05 (-)	9.65e4

6.0 6.2
RT (min)

6.0 6.2
RT (min)

PFPeS

Cone. 4.4571

R#1 349.00>99.00 78.44 (80.87)
Q 349.00>79.95 (-)	1.53e5

1.5e5-
1.0e5^
5.0e4 -j
O.OeO -

A=357107

R1 78.44 ("|-^T=6.003



6.2
RT (min)

180-PFHxS

Cone. 4.2652

2.41 e5 Q 402.70>84.05 (-)

O.OeO -

6.6
RT (min)

PFHpS

Cone. 4.6355

R#1 449.00>99.20 60.54 (65.35)
Q 449.00>80.15 (-)	1.60e5

A=361489
1.5e5 HR1 60.54 (--§-^1=6.679

6.2

6.4

Q 427.00>407.00 (-)

fA=298767
IR1 2750 ("TkT=6.669

6.6 6.8

RT (min)

PFOS

Cone. 4.0917

R#1 499.00>99.00 93.02 (96.24)
Q 499.00>80.00 (-)	7.43e4

13C-PFOS IS

Cone. 4.7750

105 (-)

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :



fA=241819



: R1 93.02 (—

•)RT=6.978

2.0e5 -





1.0e5-

i A

X ~

- O.OeO-:

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

6.0 6.2
RT (min)

PFHxS

Cone. 3.8585

R#1 399.00 >99.00 94.12 (92.02)
Q 399.00>80.00 (-)	1.00e5

1.0e5-

- R1 94.12 (-

A=273190
kT=6.375

O.OeO -

W'v

6.2

RT (min)

6.2

6.4

6.6
RT (min)

PFHpA

Cone. 5.0786

R#1 362.90 >169.00 17.23 (17.74)
Q 362.90>319.00 (-)	1.16e6

f A=2679473

1R1 17.23 (--|-kT=6.369

O.OeO -

6.6
RT (min)

6-2-FTS

Cone. 4.9044

R#1 427.00>80.90 27.50 (27.82)

6.2

6.4

6.6
RT (min)

PFOA

Cone. 4.5165

R#1 413.00 > 169.10 28.45 (27.71)

1.28e5 Q 413.00>369.00 (-)

1.28e6



'A=3037204

- R1 28.45 (--

I "^T=6.688

:

L,

RT (min)

6.8 7.0
RT (min)

13C-PFOS

Cone. 4.1994

2.12e5 Q 502.80>80.05 (-)
2.0e5 -

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

103

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)

CCV5-230426 (continued)

PFNA	13C-PFNAJS

Cone. 5.2550	Cone. 5.0000
R#1 463.00>219.00 18.43 (20.94)

Q 463.00>418.90 (-)	1.20e6	ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 4.2823

PFNS

Cone. 4.7375

R#1 549.00>99.00 64.27 (65.53)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:26

8-2-FTS

Cone. 5.1241

R#1 527.20>487.00 5.72 (5.33)

fA=2950231

-R1 18.43 (- i^J=6.999

1.0e6 -

A=2544378
RT=6.999

Q 467.80>423.00 (-)	1.04e6 Q 549.00>79.95 (-)	2.51e5 Q 527.10>506.90 (-)	9.02e4

tA=2544378

O.OeO -

6.8

f A=615148
-	™=7.307

O.OeO -

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 3.3400

9.04e4 Q 528.80> 509.00 (-)

7.2

RT (min)

PFDA

Cone. 4.8749
R#1 512.90>219.00 17.40 (18.19)

Q 512.90>469.00 (-)	1.07e6 ISTD 514.80>469.95 (-)

13C-PFDAJS

Cone. 5.0000

fA=2656836
1.0e6 -|R1 17.40 (-|-^i-=7 339

O.OeO

7.4 7.6

RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

7.4 7.6

RT (min)

d3-N-MeFOSAA

Cone. 4.4835

ISTD 572.80>419.05 (-)

2.50e5 Q 572.80>419.05 (-)

fA=686797
l RT=7.516

fA=686797
\ RT=7.516

O.OeO

2.0e5

''A=647949

9.86 (- i rt=7.520

7.25 7.50 7.75

13C-PFUnDA

Cone. 4.4645

Q 564.80>519.95 (-)
1.0e6 -

5.0e5 -

O.OeO -Uf=f

d5-N-EtFOSAA IS

Cone. 5.0000

7.6 7.8
RT (min)

PFUnDA

Cone. 5.1181
R#1 563.00>219.00 11.05 (11.87)

1.12e6 Q 563.00> 518.90 (-)	1.10e6 ISTD 588.80>419.00 (-)

A=2888463

1.0e6-|R1 "11-05 (|Rt=7.6

O.OeO

7.6

13C-FOSA IS

Cone. 5.0000

7.8 8.0
RT (min)

PFOSA

Cone. 4.5225
R#1 498.20>64.10 0.25 (0.15)

Q 498.20>78.00 (-)	2.41e5 ISTD 506.00>78.05 (-)

fA=596616

-R1 0.25 (— I RT=7.757

13C-FOSA

Cone. 4.5010

2.54e5 Q 506.00>78.05 (-)

V,

7.8 8.0

RT (min)

f A=2901172
RT=7.339

O.OeO - . 	

7.4 7.6

RT (min)

NMeFOSAA

Cone. 4.7094

R#1 570.20>512.00 39.86 (35.78)
Q 570.20>419.00 (-)	2.00e5

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 4.5624

2.91 e5 Q 588.80>419.00 (-)

f A=784042
| RT=7.701

7.8 8.0
RT (min)

A=630824
RT=7.756

1.0e6-

R1 16.05 (,

A=2651198
Rt=8.032

7.8 8.0

RT (min)

f A=241075

: R1 572 ("lkr=7.335

7.4 7.6
RT (min)

1.17e6 Q 514.80>469.95 (-)

f A=2901172
RT=7.339

O.OeO . 	

7.6
RT (min)

PFDS

Cone. 4.7823

R#1 599.00>99.00 63.45 (60.20)
Q 599.00>80.10 (-)	1.57e5

f A=411811

1.5e5 - ri 63.45 (1RT=7_648

7.4 7.6

RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)
1.0e6-

5.0e5 -

O.OeO

7.8 8.0
RT (min)

NEtFOSAA

Cone. 5.0583

R#1 584.20>526.10 50.64 (55.50)
Q 584.20>418.95 (-)	2.30e5

I A=721496
kl=7.708

O.OeO

7.8 8.0
RT (min)

PFDoA

Cone. 5.1004

R#1 613.05> 169.00 16.05 (15.47)
Q 613.05>569.00 (-)	1.01e6

O.OeO -



7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)	1.04e6

1.0e6H

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

104

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:26

CCV5-230426 (continued)

13C-PFDoA

Cone 4.2951

Q 614.80>569.95 (-)

d5-NEtFOSA IS

Cone. 5.0000

10-2-FtS

Cone. 5.6874

R#1 626.50>81.05 54.22 (56.92)

1.04e6 Q 626.50>607.05 (-)	1.23e5 ISTD 531.10> 169.10 (-)

fA=2741665	|A=334395

\ RT=8.032	-R1 5422 (IrT=8.044

d5-NEtFOSA

Cone. 4.2581

2.16e5 Q 531.10> 169.10 (-)

NMeFOSE

Cone. 4.4941

2.16e5 Q 616.10>58.90 (-)

NEtFOSE

Cone. 5.1437

Q629.50>59.10 (-)
3.0e5 ^

2.0e5 ^

1.0e5 ^

O.OeO -I. . . .

d3-NMeFOSA

Cone. 4.4174

Q 515.10> 169.00 (-)
2.0e5

O.OeO

O.OeO -

RT (min)

RT (min)

9.0

RT (min)

8.6

d9-EtFOSE IS

Cone. 5.0000

ISTD 638.90>59.10 (-)
7.5e4 -
5.0e4 ^

2.5e4 ^

O.OeO 1 . .

d9-EtFOSE

Cone. 3.9180

A=200308
RT=8.738

Q 638.90>59.10 (-)
7.5e4 -

9.0
RT (min)

NMeFOSA

Cone. 5.2005

R#1 512.10>219.20 70.96 (86.99)
Q 512.10> 169.20 (-)	9.15e4

A=237091

R1 70.96 (--|"kT=8.531

RT (min)

9.0
RT (min)

9.0
RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)
2.0e5

O.OeO -

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 4.8175

2.05e5 ISTD 623.00> 59.00 (-)

1.36e5 Q 623.00> 59.00 (-)

8.4 8.6

RT (min)

PFTeDA

Cone. 4.0910

R#1 713.00 >169.30 9.43 (10.03)
Q 713.00>668.90 (-)	9.22e5

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 4.9520

R#1 526.50>219.20 64.59 (64.74)
Q 526.50>169.10 (-)	1.54e5

A=396183

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 4.3081

R#1 663.10> 169.10 17.40 (18.77)
Q 663.10>618.90 (-)	9.83e5

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 5.0082

6.90e5 Q 714.80>669.80 (-)

9.0
RT (min)

L-PFDoS

Cone. 4.6581

R#1 698.80 >98.80 77.37 (68.45)
Q 698.80>80.10 (-)	7.20e4

f A= 176126
dR1 77.37 (|Rt=8.306

11CI-PF30UdS

Cone. 4.5897

Q 631.00>451.10 (-)
2.0e51

9CI-PF30NS

Cone. 4.5108

2.05e5 Q 531.00>351.10 (-)

f A= 1124902
\ RT=7.161

8.4 8.6
RT (min)

9.4

RT (min)

10.0

RT (min)

9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

105

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:26

CCV5-230426 (continued)

13C2-PFHxDA

Cone. 4.5616

13C7-PFUnDA IS

Cone. 5.0000

1,69e6 ISTD 569.80> 524.90 (-)

PFBSA

Cone. 4.3598

O.OeO

9.0 9.2

9.4
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

PFecHS

Cone. 4.3126
R#1 461.00>99.10 37.12 (37.10)

1.12e6 Q 461.00>381.00 (-)	8.62e5 Q 298.00>78.00 (-)

JfA=2099644

7.5e5^R1 37/12 C~~jpT=6.638

5.0e5 :

2.5e5 :

O.OeO :

PFHxSA

Cone. 4.7353

5.49e5 Q 397.90>78.00 (-)

8.0
RT (min)

6.4 6.6 6.8

RT (min)

f A=1348620
| RT=6.147

f A=1265324
RT=6.971

6.4
RT (min)

7.2
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

106

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1st /S/AO 04/28/23
2nd /S/AO 05/01/23

Insight Report
Quantitation/Integration
Printed 4/28/2023 10:14:45

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/27/2023 10:48:45 AM

Acquired by: System Administrator

Data File: 230426071

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.207

775556

775556

	 	

5.0000

nq/mL

13C-PFBA

Auto

4.207

>6

2624448

13C7-PFUn[

4.7058

ng/mL

PFBA

Auto

4.207

16963

775556

13C-PFBA IS

0.0965

ng/mL

13C-PFPeA IS

Auto

5.366

1300544

1300544

	 	

5.0000

ng/mL

13C-PFPeA

Auto

5.366

1300544

448

13C7-PFllnDA IS

4.7998

ng/mL

PFPeA

Auto

5.366

23455

1300544

13C-PFPeA :

0.0925

ng/mL

13C-PFBS IS

Auto

5.495

517466

517466

	 	

4.6500

ng/mL

13C-PFBS

Auto

495

517466

2624448

13C7-PFUnDA IS

4.6535

ng/mL

PFBS

Auto

5.496

6689

517466

13C-PFBS IS

0.0787

nu. mL

13C HFPO DA IS

Auto

6.098

266803

266803

	 	

5.0000

ng/mL

13C HFPO DA

Auto

6.098

266803

448

1; )A is

4.7336

ng/mL

HFPO DA

Auto

6.099

3879

803

13C HFPO DA IS

0.0918

ng/mL

13C-4 2-FTS IS

Auto

5.899

183342

183342

	 	

4.6700

ng/mL

13C-4 2-FTS

Auto

399

183342

2624448

13C7-PFUn[

3.4698

ng/mL

4-2-FtS

Auto

5.900

4481

183342

13C-4 2-FTS IS

0.0979

ng/mL

PFHxA

Auto

354

47163

956

: :HxA

- o

nq/mL

13C-PFHxA IS

Auto

5.953

1753956

1753956

	 	

5.0000

ng/mL

13C-PFHxA

Auto

5.953

1753956

2624448

13C7-PFUnDA IS

4.5058

ng/mL

PFPeS

Auto

5.992

8123

539376

180-PFHxS IS

0.1008

ng/mL

PFHxS

Auto

6.366

'8

539376

180-PFHxS

0.0896

ng/mL

13C-PFHpA IS

Auto

6.359

1798172

1798172

	 	

5.0000

ng/mL

13C-PFHpA

Auto

6.359

1798172

2624448

13C7-PFUnDA IS

4.6549

ng/mL

180-PFHxS IS

Auto

6.366

539376

539376

	 	

4.7250

ng/mL

180-PFHxS

Auto

6.366

539376

2624448

13C7-PFUnDA IS

4.7949

ng/mL

PFHpA

Auto

6.360

53289

1798172

13C-PFHpA

0.0996

ng/mL

13C2-6 2-FTS IS

Auto

6.661

312941

312941

	 	

¦¦.¦¦¦)

nq/mL

13C2-6 2-FTS

Auto

6.661

312941

448

'FLirti:

3.4932

ng/mL

PFHpS

Auto

6.669

6918

376

180-PFHxS IS

¦¦¦¦¦¦I

ng/mL

6-2-FTS

Auto

6.662

6678

941

13C2-6 2-FTS IS

0.1093

nq/mL

PFOA

Auto

6.678

60253

452

13C-PFOA IS

0.0894

ng/mL

13C-PFOA IS

Auto

6.678

2440452

2440452

	 	

5.0000

ng/mL

13C-PFOA

Auto

6.678

2440452

2624448

13C7-PFUnDA IS

4.8250

ng/mL

PFOS

M

6.969

5169

481140

13C-PFOS IS

0.0933

ng/mL

13C-PFOS IS

Auto

6.968

481140

481140

	 	

4.7750

nq/mL

13C-PFOS

Auto

6.968

481140

2624448

)A IS

4.4012

L

PFNA

Auto

6.989

53415

462

1?

0.1003

ng/mL

13C-PFNA IS

Auto

6.989

2414462

462

	 	

5.0000

L

13C-PFNA

Auto

6.989

>2

2624448

13C7-PFUnDA IS

j

ng/mL

PFNS

Auto

7.297

'9

481140

13C-PFOS IS

3

ng/mL

8-2-FTS

Auto

7.323

>3

223468

13C-8 2-FTS IS

0.1113

ng/mL

13C-8 2-FTS IS

Auto

7.324

223468

468

	 	

4.7900

ng/mL

13C-8 2-FTS

Auto

7.324

;

2624448

>FUn[

3.5806

ng/mL

PFDA

Auto

7.329

55657

2859446

13C-PFDA IS

0.1036

ng/mL

13C-PFDA IS

Auto

7.328

2859446

2859446

	 	

5.0000

ng/mL

13C-PFDA

Auto

7.328

2859446

2624448

13C7-PFUnDA IS

4.7410

nq/mL

d3-N-MeFOSAA IS

Auto

7.503

!7

647207

	 	

5.0000

ng/mL

d3-N-MeFOSAA

Auto

7.503

)7

2624448

IV.' PFUnDA IS

4.7233

ng/mL

NMeFC

Auto

7.506

12908

647207

d3-N-T :

0.0996

ng/mL

PFDS

Auto

7.637

6439

140

13C-PF

0.0798

ng/mL

13C-PFUnDA IS

Auto

577

2706328

2706328

	 	

5.0000

ng/mL

13FUn[

4.8711

ng/mL

NEIFOSAA

Auto

7.695

14561

748781

;tFOS

0.1069

nq/mL

PFOSA

Auto

7.744

12850

635693

13C-FOSA IS

0.0967

ng/mL

I k FOSA IS

Auto

745

635693

635693

	 	

5.0000

L

13C-FOSA

Auto

7.745

635693

448

13C7-PFUnDA IS

5.0706

ng/mL

PFDoA

Auto

8.018

)3

2624582

13C-PFDoA IS

0.0999

L

13C-PFDoAJS

Auto

8.018

2624582

2624582



5.0000

nq/mL

KC-PFPoA	Auto

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCalJproc

107

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1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:14:45

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone. Cone. Unit

10-2-FtS

Auto

8.028

7601

223468

13C-8 2-FTS IS

—- 0.1348

nq/mL

d5-NEtFOSA IS

Auto

8.771

543033

543033

—

—- 5.0000

nq/mL

d5-NEtFOSA

Auto

8.771

543033

2624448

13C7-PFUnDA IS

—- 4.7110

nq/mL

NMeFOSE

Auto

8.496

5375

335082

d7-N-MeFOSE IS

—- 0.0885

nq/mL

NEtFOSE

Auto

8.746

16090

197217

d9-EtFOSE IS

—- 0.1041

nq/mL

d9-EtFOSE IS

Auto

8.726

197217

197217

—

—- 5.0000

nq/mL

d9-EtFOSE

Auto

8.726

197217

2624448

13C7-PFUnDA IS

—- 4.3125

nq/mL

NMeFOSA

Auto

8.521

4828

489426

d3-NMeFOSA IS

—- 0.1136

nq/mL

dB-NMeFOSA IS

Auto

8.515

489426

489426

—

—- 5.0000

nq/mL

dB-NMeFOSA

Auto

8.515

489426

2624448

13C7-PFUnDA IS

—- 4.6023

nq/mL

d7-N-MeFOSE IS

Auto

8.479

335082

335082

—

—- 5.0000

nq/mL

d7-N-MeFOSE

Auto

8.479

335082

2624448

13C7-PFUnDA IS

—- 5.4779

nq/mL

NEtFOSA

Auto

8.783

7377

543033

d5-NEtFOSA IS

—- 0.0932

nq/mL

PFTrDA

Auto

8.345

48591

1744561

13C-PFTeDA IS

—- 0.0892

nq/mL

PFTeDA

Auto

8.645

50975

1744561

13C-PFTeDA IS

—- 0.0899

nq/mL

13C-PFTeDA IS

Auto

8.644

1744561

1744561

—

—- 5.0000

nq/mL

1BC-PFTeDA

Auto

8.644

1744561

2624448

13C7-PFUnDA IS

—- 5.3824

nq/mL

11CI-PF30UdS

Auto

7.830

9477

481140

13C-PFOS IS

—- 0.0901

nq/mL

9CI-PFBONS

Auto

7.149

20649

481140

13C-PFOS IS

—- 0.0883

nq/mL

L-PFDoS

Auto

8.292

3631

481140

13C-PFOS IS

—- 0.1024

nq/mL

NaDONA

Auto

6.404

35810

2414462

13C-PFNA IS

—- 0.0948

nq/mL

PFHxDA

Auto

9.173

49375

3568808

13C2-PFHxDA IS

—- 0.1078

nq/mL

PFODA

Auto

9.718

20896

3568808

13C2-PFHxDA IS

—- 0.1078

nq/mL

13C2-PFHxDA IS

Auto

9.173

3568808

3568808

—

—- 5.0000

nq/mL

1BC2-PFHxDA

Auto

9.173

3568808

2624448

13C7-PFUnDA IS

—- 4.6711

nq/mL

13C7-PFUnDA IS

Auto

7.676

2624448

2624448

—

—- 5.0000

nq/mL

PFecHS

Auto

6.628

37473

481140

13C-PFOS IS

—- 0.0821

nq/mL

PFBSA

Auto

6.139

26347

635693

13C-FOSA IS

—- 0.0845

nq/mL

PFHxSA

Auto

6.961

26131

2414462

13C-PFNA IS

—- 0.1031

nq/mL

CHARGE

ND(W/B)

	

	

2624448

13C7-PFUnDA IS

	 	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 4.7058
1.87e5 Q 217.20>172.30 (-)

PFBA

Cone. 0.0965
1.87e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
4.46e3 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.7998
5.47e5 Q 267.90>223.00 (-)

O.OeO -

L\1

1300544
RT= 5.366

O.OeO -

L

O.OeO -

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 0.0925

Q263.05>219.10 (-)

A=23455
RT= 5.366

5.2

5.4

5.6

RT (min)

5.2

5.4

4.00 4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)

13C-PFBS IS	13C-PFBS	PFBS

Cone. 4.6500	Cone. 4.6535	Cone. 0.0787

R#1 298.80>99.00 61.44 (72.97)

9.31e3 ISTD 301.80>80.00 (-)	2.03e5 Q 301.80>80.00 (-)	2.03e5 Q 299.00>80.00 (-)	2.47e3 ISTD 332.10>287.10 (-)

5.6

RT (min)

13C HFPO DA IS

Cone. 5.0000

2.0e5 -

f A=517466
RT= 5.495

2.0e5 -

f A=517466
I RT= 5.495

f A=6689

_R1 61.44 (-"^r= 5.496

5.6 5.8
RT (min)

5.6 5.8
RT (min)

f A=266803
RT=6.098

5.4 5.6 5.8
RT (min)

6.2 6.4
RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

108

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1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:14:45

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 4.7336

Q 332.10>287.10 (-)

HFPO DA

Cone. 0.0918

R#1 329.00>285.10 74.46 (68.92)
Q 329.00>169.00 (-)	1.90e3

A=266803
RT=6.098

f A=3879

:R1 74,46 (-^=6.099

O.OeO -

1.5e3 -
1.0e3-j
5.0e2 :
O.OeO :

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 0.1026

R#1 313.00>119.10 4.03 (2.54)
Q 313.00>269.00 (-)	2.08e4

~ A=47163

2-°e4-R14.03 (-s)Rr=5.954

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

A= 1753956
RT= 5.953

13C-PFHpA IS

Cone. 5.0000

13C-PFHpA

Cone. 4.6549

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

13C2-6 2-FTS

Cone. 3.4932

1.34e5 Q 428.90>409.00 (-)

J A=312941
RT=6.661

fA=312941
RT=6.661

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
1.0e6 H

13C-PFOA

Cone. 4.8250

A=2440452
RT=6.678

1.04e6 Q 416.80>372.05 (-)
1.0e6 H

6.8 7.0
RT (min)

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 29.80 (27.58)

ISTD 329.00>309.15 (-)	7.85e4

13C-4 2-FTS

Cone. 3.4698

R#1 329.00>81.00 29.80 (27.58)
Q 329.00>309.15 (-)	7.85e4

*A= 183342
7.5e4-Ri 29.80 (-+tfr=5.8

6.2 6.4
RT (min)

13C-PFHxA

Cone. 4.5058

7.54e5 Q 314.90>270.10 (-)

A= 1753956
RT= 5.953

6.2
RT (min)

180-PFHxS IS

Cone. 4.7250

8.01 e5 ISTD 402.70>84.05 (-)

180-PFHxS

Cone. 4.7949

2.45e5 Q 402.70>84.05 (-)

A= 539376
RT=6.366

JA= 539376
I RT=6.366

O.OeO -

!

O.OeO -

6.2

6.4

6.6
RT (min)

PFHpS

Cone. 0.0882

R#1 449.00>99.20 65.98 (65.35)
Q 449.00>80.15 (-)	3.05e3

6.2

6.4

Q 427.00>407.00 (-)

3.0e3 :
2.0e3 :
1.0e3 -

~ A=6918

R1 65.98 (-- $T=6.669

~ A=6678
I R1 24.49 (- y-|^T=6.662



O.OeO | | | ^ j p

6.6 6.8

RT (min)

PFOS

Cone. 0.0933

R#1 499.00>99.00 99.05 (96.24)
Q 499.00>80.00 (-)	1.58e3

13C-PFOS IS

Cone. 4.7750

1.5e3-Ri 99.05 (-
1.0e3 ^

5.0e2 ^

O.OeO 1. . ^

TA=5169
!-kf=6.969

ISTD 502.8
2.0e5 -i

105 (-)

A=481140
RT=6.968

L

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

4-2-FtS

Cone. 0.0979

R#1 327.00>81.10 10.55 (15.16)
Q 327.00>307.05 (-)	2.02e3

2.0e3

~ A=4481

O.OeO -

_ R1 10.55 (-

l$J= 5.900





6.0 6.2
RT (min)

PFPeS

Cone. 0.1008

R#1 349.00>99.00 55.65 (80.87)
Q 349.00>79.95 (-)	3.85e3

TA=8123

:R1 55.65 (-t't^T= 5.992

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.0896

R#1 399.00 >99.00 89.89 (92.02)
Q 399.00>80.00 (-)	2.42e3

f A=6378

-R1 89.89 {-I -^7=6.366

6.2

RT (min)

O.OeO _

6.6
RT (min)

PFHpA

Cone. 0.0996

R# 1 362.90 > 169.00 19.47 (17.74)
Q 362.90>319.00 (-)	2.35e4

~ A= 53289
,n„JR1 1947 ^T=6.360

O.OeO -

6.6
RT (min)

6-2-FTS

Cone. 0.1093

R#1 427.00>80.90 24.49 (27.82)

6.2

6.4

6.6
RT (min)

PFOA

Cone. 0.0894

R#1 413.00 > 169.10 32.38 (27.71)

2.93e3 Q 413.00>369.00 (-)

2.63e4

fA=60253

- R1 32.38 (-ts-^t=6.678

RT (min)

13C-PFOS

Cone. 4.4012

2.00e5 Q 502.80>80.05 (-)
2.0e5 -i

6.8 7.0
RT (min)

A=481140
RT=6.968

6.8 7.0 7.2

RT (min)

6.8 7.0 7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

109

-------
1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:14:45

L0.1ppb_230323 (continued)

PFNA	13C-PFNA IS

Cone. 0.1003	Cone. 5.0000
R#1 463.00>219.00 18.51 (20.94)

Q 463.00>418.90 (-) 2.15e4	ISTD 467.80>423.00 (-)

~ A=53415
2.0e4-R1 18.51 (|-^r=6c

13C-PFNA

Cone. 4.5428

9.87e5 Q 467.80>423.00 (-)

PFNS

Cone. 0.1148

R#1 549.00>99.00 59.69 (65.53)
9.87e5 Q 549.00>79.95 (-)

8-2-FTS

Cone. 0.1113

R#1 527.20>487.00 11.76 (5.33)
5.47e3 Q 527.10>506.90 (-)	2.

*A=2414462

RT=6.9

O.OeO -

6.8

F=Fr
7.0

O.OeO -

~ A= 13979

R1 59 69 (f Rt=7.297



7.2

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 3.5806

8.75e4 Q 528.80> 509.00 (-)

13C-PFDAJS

Cone. 5.0000

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

~ A=223468
RT=7.324

A=223468
RT=7.324

L

7.6
RT (min)

7.2

RT (min)

PFDA

Cone. 0.1036
R#1 512.90>219.00 15.68 (18.19)

Q 512.90>469.00 (-)	2.16e4 ISTD 514.80>469.95 (-)

fA= 55657
2.0e4 _ R1 15.68 (lf"Rt=7.329

O.OeO

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 4.7233

7.6
RT (min)

NMeFOSAA

Cone. 0.0996

R#1 570.20>512.00 36.13 (35.78)

2.37e5 Q 572.80>419.05 (-)

2.37e5 Q 570.20>419.00 (-)

4.21e3 Q 599.00>80.10 (-)

O.OeO

40e3HRi 3613 (..

rJ\J

A=12908
¦ftT=7.506

~ A=6439
I R1 67.89 (--R1)= 7 637

L

7.25 7.50 7.75

13C-PFUnDA

Cone. 4.5746

Q 564.80>519.95 (-)
1.0e6 -i

7.6 7.8	7.4 7.6 7.8

RT (min)	RT (min)

PFUnDA

Cone. 0.1042
R#1 563.00>219.00 8.65 (11.87)

1.01 e6 Q 563.00> 518.90 (-)	1,98e4 ISTD 588.80>419.00 (-)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

d5-N-EtFOSAA

Cone. 4.8711

2.76e5 Q 588.80>419.00 (-)

O.OeO -

8.0
RT (min)

PFOSA

Cone. 0.0967

R#1 498.20>64.10 0.15 (0.15)
Q 498.20>78.00 (-)	5.43e3

f A= 12850
IR1 0.15 (—|)RT=7.744

¥A=635693
RT=7.745



y A=49703

: R1 16 78 |RT)=8.018

8.0
RT (min)

8.0
RT (min)

8.0
RT (min)

A =5023
_R1 11.76 HRt=7.323

7.4 7.6
RT (min)

7.6
RT (min)

13C-PFDA

Cone. 4.7410

1.15e6 Q 514.80>469.95 (-)

O.OeO -

7.6
RT (min)

PFDS

Cone. 0.0798

R#1 599.00>99.00 67.89 (60.20)

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

2.74e3 ISTD 564.80>519.95 (-)
1.0e6 —1

A=2706328
RT=7.677

O.OeO -



7.6

RT (min)

7.8 8.0
RT (min)
NEtFOSAA

Cone. 0.1069

R#1 584.20>526.10 44.97 (55.50)
2.76e5 Q 584.20>418.95 (-)	4.63e3

TA=2624582
RT=8.018

RT (min)

RT (min)

7.6 7.8 8.0
RT (min)

PFDoA

Cone. 0.0999

R#1 613.05> 169.00 16.78 (15.47)
Q 613.05>569.00 (-)	1.94e4

*A= 53909

1.0e4

ISTD 506.00>78.05 (-)	2.55e5

Q 506.00>78.05 (-)	2.55e5

f A= 14561

40e3lR1 44-97 (" ^T=7-695

O.OeO

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)	1.01e6

8.0
RT (min)

7.8 8.0
RT (min)

13C-FOSA IS

Cone. 5.0000

: 7.689

13C-FOSA

Cone. 5.0706

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

110

-------
1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:14:45

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 4.5965

Q614.80>569.95 (-)
1.0e6 -|

10-2-FtS

Cone. 0.1348

R#1 626.50>81.05 44.12 (56.92)
Q 626.50>607.05 (-)	3.55e3

3.0e3
2.0e3
1.0e3
O.OeO

Y;A=7601

;R1 44-12 (HRT)=8.028

RT (min)

NEtFOSE

Cone. 0.1041

Q629.50>59.10 (-)
6.0e3
4.0e3
2.0e3
O.OeO

d9-EtFOSE IS

Cone. 5.0000



{A= 16090



RT=8.746

I

IV

A i

6.51 e3 ISTD 638.90>59.10 (-)

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

8.6

d3-NMeFOSA

Cone. 4.6023

Q 515.10> 169.00 (-)

9.0
RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

1,96e5 ISTD 623.00> 59.00 (-)

O.OeO -

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 0.0899
R#1 713.00 >169.30 8.74 (10.03)

Q 713.00 > 668.90 (-)	1,88e4 I STD 714.80 > 669.80 (-)

13C-PFTeDA IS

Cone. 5.0000





¥A= 50975



r A= 1744561

-

R1 8.74 (

jh$r=8.645 6.0e5 -



RT=8.644

1.5e4:



1





1.0e4:





4.0e5 :





5.0e3 :





2.0e5 :



Vt

O.OeO

/



V , .. . :

i



i i |A|

1 1 1 1 1 1 1 1 1 1 u.ucu

¦ 1 lA| 		

8.6 8.8 9.0
RT (min)

L-PFDoS

Cone. 0.1024

R#1 698.80 >98.80 71.28 (68.45)
Q 698.80>80.10 (-)	1.38e3



¥^=363]

:R1 71.28

r-RT)= 8.292

:	I

L

NaDONA

Cone. 0.0948

Q 377.10>251.20 (-)
1.5e4-

A=35810
RT=6.404

8.4 8.6
RT (min)

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)
2.0e5 -

d5-NEtFOSA

Cone. 4.7110

2.15e5 Q 531.10> 169.10 (-)
2.0e5 -

O.OeO -

NMeFOSE

Cone. 0.0885

2.15e5 Q 616.10>58.90 (-)
2.0e3 -

RT (min)

9.0

RT (min)

8.6

d9-EtFOSE

Cone. 4.3125

7.58e4 Q 638.90> 59.10 (-)

6.0e4 ~

4.0e4 ~

2.0e4 ~
== O.OeO 1 . . .

: R1 49.42 (-

j

'¦ftT=8.521



L.

9.0
RT (min)

9.0
RT (min)

d7-N-MeFOSE

Cone. 5.4779

1.34e5 Q 623.00> 59.00 (-)

RT (min)

RT (min)

13C-PFTeDA

Cone. 5.3824

11CI-PF30UdS

Cone. 0.0901

6.83e5 Q 714.80>669.80 (-)

6.83e5 Q 631.00>451.10 (-)

Q 812.90>769.00 (-)
2.0e4 -

2.19e4 Q 912.80>869.00 (-)

A=5375
RT=8.496

.8 9.0

RT (min)

NMeFOSA

Cone. 0.1136

R#1 512.10>219.20 49.42 (86.99)
Q 512.10> 169.20 (-)	1.93e3

1.5e3~
1.0e3-j
5.0e2 :
O.OeO :

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

O.OeO -

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0932

R#1 526.50>219.20 63.39 (64.74)
Q 526.50> 169.10 (-)	3.35e3

~ A=7377
"&T=8.783

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.0892

R#1 663.10> 169.10 18.61 (18.77)
Q 663.10>618.90 (-)	2.02e4

2.0e4 -

Y A=48591
R1 18.61 (--Rit 8.345

9CI-PF30NS

Cone. 0.0883

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

ISTD 815.00>770.00 (-)

A=3568808
RT=9.173

9.4

RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

111

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1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:14:45

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 4.6711

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 0.0845

Q 815.00>770.00 (-)
1.5e6 -

1.0e6 -

5.0e5 ^

O.OeO 1 . .

PFecHS

Cone. 0.0821
R#1 461.00>99.10 37.88 (37.10)

1.54e6 ISTD 569.80>524.90 (-)	9.75e5 Q461.00>381.00 (-)	1.50e4 Q 298.00>78.00 (-)

PFHxSA

Cone. 0.1031

1.14e4 Q 397.90>78.00 (-)

A=3568808
RT=9.173

L

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

fA=2624448
] RT=7.676

1,5e4 —i	TA=37473

:R1 37.88 ^7=6.628

1.0e4-
5.0e3 -

O.OeO -

8.0
RT (min)

6.4 6.6 6.8

RT (min)

A=26131
RT=6.961

6.0 6.2 6.4
RT (min)

6.8 7.0 7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCalJproc

112

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:31

CCV6-230426

Sample ID: CCV6-230426

Date Acquired: 4/27/2023 11:16:14 AM

Acquired by: System Administrator

Data File: 230426073

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name	Mode ID Found RT Area ISTDArea ISTD Name	Std. Cone. Cone. Unit

13C-PFBA IS

Auto

4.203

889190

889190

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.203

889190

2882903

13C7-PFUnDA IS

5.0000

4.9116

nq/mL

PFBA

Auto

4.203

1012564

889190

13C-PFBA IS

5.0000

5.0225

nq/mL

13C-PFPeA IS

Auto

5.361

1441273

1441273

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.361

1441273

2882903

13C7-PFUnDA IS

5.0000

4.8423

nq/mL

PFPeA

Auto

5.361

1291576

1441273

13C-PFPeA IS

5.0000

4.5950

nq/mL

13C-PFBS IS

Auto

5.491

562821

562821

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.491

562821

2882903

13C7-PFUnDA IS

4.6500

4.6076

nq/mL

PFBS

Auto

5.490

372121

562821

13C-PFBS IS

4.4200

4.0266

nq/mL

13C HFPO DA IS

Auto

6.096

300049

300049

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.096

300049

2882903

13C7-PFUnDA IS

5.0000

4.8462

nq/mL

HFPO DA

Auto

6.096

221263

300049

13C HFPO DA IS

5.0000

4.6564

nq/mL

13C-4 2-FTS IS

Auto

5.896

210924

210924

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.896

210924

2882903

13C7-PFUnDA IS

4.6700

3.6339

nq/mL

4-2-FtS

Auto

5.895

240225

210924

13C-4 2-FTS IS

4.6700

4.5603

nq/mL

PFHxA

Auto

5.950

2497958

1914225

13C-PFHxA IS

5.0000

4.9815

nq/mL

13C-PFHxA IS

Auto

5.950

1914225

1914225

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

5.950

1914225

2882903

13C7-PFUnDA IS

5.0000

4.4767

nq/mL

PFPeS

Auto

5.990

375159

589838

180-PFHxS IS

4.6900

4.2579

nq/mL

PFHxS

Auto

6.362

313880

589838

180-PFHxS IS

4.5500

4.0313

nq/mL

13C-PFHpA IS

Auto

6.356

1852135

1852135

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.356

1852135

2882903

13C7-PFUnDA IS

5.0000

4.3647

nq/mL

180-PFHxS IS

Auto

6.363

589838

589838

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.363

589838

2882903

13C7-PFUnDAJS

4.7250

4.7734

ng/mL

PFHpA

Auto

6.357

2880726

1852135

13C-PFHpA IS

5.0000

5.2284

ng/mL

13C2-6 2-FTS IS

Auto

6.658

318821

318821

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.658

318821

2882903

13C7-PFUnDA IS

4.7500

3.2398

ng/mL

PFHpS

Auto

6.667

389309

589838

180-PFHxS IS

4.7600

4.5396

nq/mL

6-2-FTS

Auto

6.658

304600

318821

13C2-6 2-FTS IS

4.7400

4.8946

nq/mL

PFOA

Auto

6.676

3293587

2630188

13C-PFOA IS

5.0000

4.5340

nq/mL

13C-PFOA IS

Auto

6.676

2630188

2630188

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.676

2630188

2882903

13C7-PFUnDA IS

5.0000

4.7339

nq/mL

PFOS

Auto

6.964

275907

548323

13C-PFOS IS

4.6400

4.3697

nq/mL

13C-PFOS IS

Auto

6.964

548323

548323

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

6.964

548323

2882903

13C7-PFUnDA IS

4.7750

4.5661

nq/mL

PFNA

Auto

6.985

3004659

2670679

13C-PFNA IS

5.0000

5.0988

nq/mL

13C-PFNA IS

Auto

6.985

2670679

2670679

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.985

2670679

2882903

13C7-PFUnDA IS

5.0000

4.5744

nq/mL

PFNS

Auto

7.291

666281

548323

13C-PFOS IS

4.8000

4.8029

nq/mL

8-2-FTS

Auto

7.317

244246

233365

13C-8 2-FTS IS

4.7900

5.1840

nq/mL

13C-8 2-FTS IS

Auto

7.318

233365

233365

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.318

233365

2882903

13C7-PFUnDA IS

4.7900

3.4040

nq/mL

PFDA

Auto

7.322

2937526

3174936

13C-PFDA IS

5.0000

4.9252

r

13C-PFDA IS

Auto

7.323

3174936

3174936

	

5.0000

5.0000

ng/mL

13C-PFDA

Auto

7.323

3174936

2882903

13C7-PFUnDA IS

5.0000

4.7922

r

d3-N-MeFOSAA IS

Auto

7.498

749351

749351

	

5.0000

5.0000

ng/mL

cB-N-MeFOSAA

Auto

7.498

749351

2882903

13C7-PFUnDA IS

5.0000

4.9785

r

NMeFOSAA

Auto

7.503

660631

749351

d3-N-MeFOSAA IS

5.0000

4.4008

nq/mL

PFDS

Auto

7.633

436809

548323

13C-PFOS IS

4.8200

4.7479

r

13C-PFUnDA IS

Auto

7.672

3053119

3053119

	

5.0000

5.0000

ng/mL

13C-PFUnDA

Auto

7.672

3053119

2882903

13C7-PFUnDA IS

5.0000

4.6981

r

PFUnDA

Auto

7.673

3081077

3053119

13C-PFUnDA IS

5.0000

5.2797

ng/mL

d5-N-EtFOSAA IS

Auto

7.684

829047

829047

	

5.0000

5.0000

r

d5-N-EtFOSAA

Auto

7.684

829047

2882903

13C7-PFUnDA IS

5.0000

4.9097

ng/mL

NEtFOSAA

Auto

7.692

769124

829047

dS-N-EtFOSAA IS

5.0000

5.0995

r

PFOSA

Auto

7.740

696132

698563

13C-FOSA IS

5.0000

4.7651

ng/mL

13C-FOSA IS

Auto

7.741

698563

698563

	

5.0000

5.0000

r

13C-FOSA

Auto

7.741

698563

2882903

13C7-PFUnDA IS

5.0000

5.0725

nq/mL

PFDoA

Auto

8.017

2800036

2921531

13C-PFDoA IS

5.0000

5.0551

nq/mL

13C-PFDoA IS

Auto

8.016

2921531

2921531

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

113

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A

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:31

CCV6-230426 (continued)













(Table continued from previous page)
Name Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.016

2921531

2882903

13C7-PFUnDA IS

5.0000

4.6579

nq/mL

10-2-FtS

Auto

8.029

341660

233365

13C-8 2-FTS IS

4.8200

5.8026

ng/mL

d5-NEtFOSA IS

Auto

8.768

567724

567724

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.768

567724

2882903

13C7-PFUnDA IS

5.0000

4.4837

ng/mL

NMeFOSE

Auto

8.493

285891

354343

d7-N-MeFOSE IS

5.0000

4.4501

nq/mL

NEtFOSE

Auto

8.743

908448

222530

d9-EtFOSE IS

5.0000

5.2100

ng/mL

d9-EtFOSE IS

Auto

8.724

222530

222530

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.724

222530

2882903

13C7-PFUnDA IS

5.0000

4.4298

ng/mL

NMeFOSA

Auto

8.519

240738

514139

d3-NMeFOSA IS

5.0000

5.3938

nq/mL

dB-NMeFOSA IS

Auto

8.513

514139

514139

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.513

514139

2882903

13C7-PFUnDA IS

5.0000

4.4012

nq/mL

d7-N-MeFOSE IS

Auto

8.478

354343

354343

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.478

354343

2882903

13C7-PFUnDA IS

5.0000

5.2734

nq/mL

NEtFOSA

Auto

8.778

421033

567724

d5-NEtFOSA IS

5.0000

5.0864

ng/mL

PFTrDA

Auto

8.343

2731040

1862367

13C-PFTeDA IS

5.0000

4.6963

nq/mL

PFTeDA

Auto

8.643

2598824

1862367

13C-PFTeDA IS

5.0000

4.2944

ng/mL

13C-PFTeDA IS

Auto

8.644

1862367

1862367

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.644

1862367

2882903

13C7-PFUnDA IS

5.0000

5.2307

ng/mL

11CI-PFBOUdS

Auto

7.826

523081

548323

13C-PFOS IS

4.7100

4.3661

nq/mL

9CI-PF30NS

Auto

7.146

1223935

548323

13C-PFOS IS

4.6600

4.5938

ng/mL

L-PFDoS

Auto

8.294

187428

548323

13C-PFOS IS

4.8400

4.6397

nq/mL

NaDONA

Auto

6.401

1905071

2670679

13C-PFNA IS

4.7100

4.5614

ng/mL

PFHxDA

Auto

9.171

1840658

4334445

13C2-PFHxDA IS

5.0000

6.4392

nq/mL

PFODA

Auto

9.720

1089958

4334445

13C2-PFHxDA IS

5.0000

4.6303

ng/mL

13C2-PFHxDA IS

Auto

9.172

4334445

4334445

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.172

4334445

2882903

13C7-PFUnDA IS

5.0000

5.1647

ng/mL

13C7-PFUnDA IS

Auto

7.672

2882903

2882903

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.626

2374998

548323

13C-PFOS IS

4.6100

4.5659

ng/mL

PFBSA

Auto

6.136

1439097

698563

13C-FOSA IS

5.0000

4.2012

nq/mL

PFHxSA

Auto

6.957

1351667

2670679

13C-PFNA IS

5.0000

4.8192

ng/mL

CHARGE

ND(W/B)

	

	

2882903

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 4.9116
2.34e5 Q 217.20>172.30 (-)

PFBA

Cone. 5.0225
2.34e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
2.58e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.8423
6.92e5 Q 267.90>223.00 (-)

A=889190
RT=4.203

J A=889190
RT=4.203

TA= 1012564
RT=4.203

O.OeO -

O.OeO -

O.OeO -

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

r.A= 1441273
RT= 5.361



A= 1441273
RT= 5.361

5.2

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 4.5950	Cone. 4.6500	Cone. 4.6076 Cone. 4.0266

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)

5.37e5 ISTD 301.80>80.00 (-)

2.48e5 Q 301.80>80.00 (-)

R#1 298.80>99.00 71.33 (72.97)

2.48e5 Q 299.00>80.00 (-)	1.63e5 ISTD 332.10>287.10 (-)	1.36e5

fA=372121
^"=5.490

'A=300049
I RT=6.096



6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

114

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:31

CCV6-230426 (continued)

13C HFPO DA

Cone. 4.8462

Q 332.10>287.10 (-)

>=300049
RT=6.096

HFPO DA

Cone. 4.6564

R#1 329.00>285.10 68.03 (68.92)
Q 329.00>169.00 (-)	1.03e5

1.0e5

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 26.20 (27.58)

ISTD 329.00>309.15 (-)	9.59e4

O.OeO -



[A=221263

R1 68.03 (-

:

rRft"=6.096

:	

Vv

*A=210924

:R1 26.20 (-ft ^"=5.896

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 4.9815

R#1 313.00> 119.10 2.53 (2.54)
Q 313.00>269.00 (-)	1.11e6

6.2 6.4
RT (min)



A=2497958

- R1 2.53 (—

)RT= 5.950

I

i.

13C-PFHxA IS

Cone. 5.0000

I STD 314.90 >270.10 (-)

13C-PFHxA

Cone. 4.4767

8.51 e5 Q 314.90>270.10 (-)

7.5e5
5.0e5
2.5e5
O.OeO

A=1914225
RT= 5.950

L

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

6.2
RT (min)

6.2
RT (min)

13C-PFHpA_IS

Cone. 5.0000

13C-PFHpA

Cone. 4.3647

180-PFHxS IS

Cone. 4.7250

8.27e5 I STD 402.70>84.05 (-)

A= 589838
RT=6.363

O.OeO -

L

6.2

6.4

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

13C2-6 2-FTS

Cone. 3.2398

1.42e5 Q 428.90>409.00 (-)

f A=318821
| RT=6.658

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)	1.14e6

TA=2630188

13C-PFOA

Cone. 4.7339

Q 416.80>372.05 (-)

1.0e6 -



RT=6.676

5.0e5 -





O.OeO -



L

A=2630188
RT=6.676



6.8 7.0
RT (min)

6.8 7.0
RT (min)

13C-4 2-FTS

Cone. 3.6339

R#1 329.00>81.00 26.20 (27.58)
Q 329.00>309.15 (-)	9.59e4

7.5e4 -
5.0e4z_
2.5e4z_
O.OeO -



PJA=210924

: R1 26.20 (-

m= 5.896

!

I

6.0 6.2
RT (min)

1.5e5
1.0e5
5.0e4
O.OeO

; R1 85.42 (-

6.2
RT (min)

180-PFHxS

Cone. 4.7734

2.70e5 Q 402.70>84.05 (-)

f A= 589838
RT=6.363

O.OeO -

6.6
RT (min)

PFHpS

Cone. 4.5396

R#1 449.00>99.20 62.60 (65.35)
Q 449.00>80.15 (-)	1.71e5

A=389309
ffr=6.667

6.2

6.4

6.6 6.8

RT (min)

PFOS

Cone. 4.3697

R#1 499.00>99.00 93.22 (96.24)
Q 499.00>80.00 (-)	8.39e4

A=275907
kT=6.964

13C-PFOS IS

Cone. 4.7750

105 (-)

tA=S

flRT='

548323
6.964

L

6.75 7.00 7.25

RT (min)

4-2-FtS

Cone. 4.5603

R#1 327.00>81.10 15.29 (15.16)
Q 327.00>307.05 (-)	1.09e5

O.OeO



FJ A=240225

- R1 15.29 (-

™= 5.895

I

¦ V ~

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 4.2579

R#1 349.00>99.00 85.42 (80.87)
Q 349.00>79.95 (-)	1.72e5

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 4.0313

R#1 399.00 >99.00 93.04 (92.02)
Q 399.00>80.00 (-)	1.16e5

f A=313880

:R1 93.04 (-if $7=6.362

O.OeO -

AL

6.2

RT (min)

6.2

6.4

6.6
RT (min)

PFHpA

Cone. 5.2284

R#1 362.90 >169.00 17.29 (17.74)
Q 362.90>319.00 (-)	1.30e6

TA=2880726

-|R1 17.29 (-If $7=6.357

O.OeO -

6.6
RT (min)

6-2-FTS

Cone. 4.8946

R#1 427.00>80.90 29.58 (27.82)
Q 427.00>407.00 (-)	1.32e5

- R1 29.58 (-

6.2

6.4 6.6

RT (min)

PFOA

Cone. 4.5340

R#1 413.00 > 169.10 28.72 (27.71)
Q 413.00>369.00 (-)	1.41e6

f A=3293587

JR1 28.72 ("if$7=6.676

RT (min)

6.8 7.0
RT (min)

13C-PFOS

Cone. 4.5661

2.33e5 Q 502.80>80.05 (-)

f A=5

flRT='

548323
6.964



7.2

RT (min)

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

115

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:31

CCV6-230426 (continued)

13C-PFNA IS

Cone. 5.0000

PFNA

Cone. 5.0988
R#1 463.00>219.00 18.55 (20.94)

Q 463.00>418.90 (-)	1.23e6 ISTD 467.80>423.00 (-)

- R1 18.55 (

fA=2670679
RT=6.985

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

A=233365
RT=7.318

13C-8 2-FTS

Cone. 3.4040

8.58e4 Q 528.80> 509.00 (-)

7.5e4 ^

5.0e4 i
2.5e4 ^

O.OeO 4=

'A=233365
RT=7.318

7.6
RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 4.9785

2.73e5 Q 572.80>419.05 (-)

A=749351
RT=7.498

O.OeO -

V,

7.6 7.8
RT (min)

7.4

13C-PFUnDA

Cone. 4.6981

Q 564.80>519.95 (-)

O.OeO -

O.OeO -

7.6

7.6

.8 8.0
RT (min)

PFOSA

Cone. 4.7651
R#1 498.20>64.10 0.10 (0.15)

Q 498.20>78.00 (-)	2.76e5 ISTD 506.00>78.05 (-)

13C-FOSA IS

Cone. 5.0000

:R1 0.10 (—

A=696132
kT=7.740

A=698563
RT=7.741

8.0
RT (min)

13C-PFNA

Cone. 4.5744

Q 467.80>423.00 (-)
1.0e6 -

PFNS

Cone. 4.8029

R#1 549.00>99.00 67.96 (65.53)

8-2-FTS

Cone. 5.1840

R#1 527.20>487.00 7.94 (5.33)

A=2670679
RT=6.985

Q 549.00>79.95 (-)

I R1 67.96
2.0e5 -

2.72e5 Q 527.10>506.90 (-)

O.OeO -



A=244246
tfT=7.317

6.8

7.0

7.2
RT (min)

PFDA

Cone. 4.9252

R#1 512.90>219.00 17.36 (18.19)
Q 512.90>469.00 (-)	1.17e6

f A=2937526

"R1 17.36 (|W=7.322

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

1.28e6 Q 514.80>469.95 (-)

7.6
RT (min)

O.OeO -

7.6
RT (min)

NMeFOSAA

Cone. 4.4008

R#1 570.20>512.00 41.40 (35.78)
Q 570.20>419.00 (-)	2.08e5

2.0e5

O.OeO



tA=3174936

^ I

RT=7.323

^ I

L

7.2

7.4

7.6 7.8

RT (min)
PFUnDA

Cone. 5.2797

R#1 563.00>219.00 11.60 (11.87)
1.14e6 Q 563.00> 518.90 (-)	1.15e6

TA=3081077

1.0e6:R1 1l60f|RT=7.673

7.25 7.50 7.75

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)
3.0e5 -

2.0e5 -

1.0e5-

O.OeO -

d5-N-EtFOSAA

Cone. 4.9097

Q 588.80>419.00 (-)
3.0e5

2.0e5 :
1.0e5-j
O.OeO -

A=829047
RT=7.684

L

L

7.8 8.0
RT (min)

7.8 8.0
RT (min)

7.6

13C-FOSA

Cone. 5.0725

2.75e5 Q 506.00>78.05 (-)



t A=2800036

-R1 15.84

'

00
o



L

7.8 8.0

RT (min)

7.8 8.0

RT (min)

A=3174936
RT=7.323

V,

7.6
RT (min)

PFDS

Cone. 4.7479

R#1 599.00>99.00 63.26 (60.20)
Q 599.00>80.10 (-)	1.71e5

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

O.OeO

7.8 8.0
RT (min)

NEtFOSAA

Cone. 5.0995

R#1 584.20>526.10 51.48 (55.50)
Q 584.20>418.95 (-)	2.33e5

*A=769124

jR1 5148 ("Skl=7.692

O.OeO -



7.8 8.0
RT (min)

PFDoA

Cone. 5.0551

R#1 613.05> 169.00 15.84(15.47)
Q 613.05>569.00 (-)	1.07e6

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

; A=2921531
RT=8.016

ISTD 614.80>569.95 (-)	1.12e6

1.0e6-

5.0e5 -

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

116

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:31

CCV6-230426 (continued)

13C-PFDoA

Cone. 4.6579

Q 614.80>569.95 (-)

~ A=2921531
1.0e6-	| RT=8.016

NEtFOSE

Cone. 5.2100

Q 629.50>59.10 (-)

3.0e5 i
2.0e5 ~

^.0eSz_

O.OeO -I. . .

Q 515.10> 169.00 (-)
2.0e5

O.OeO -

TA=5

RT=.

514139
8.513

O.OeO -

8.6

10-2-FtS

Cone. 5.8026

R#1 626.50>81.05 51.86 (56.92)
Q 626.50>607.05 (-)	1.31e5



'A=341660

- R1 51.86

|RT=8.029



|

^ I



d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)
2.0e5 -

RT (min)

d9-EtFOSE IS

Cone. 5.0000

d5-NEtFOSA

Cone. 4.4837

2.25e5 Q 531.10> 169.10 (-)
2.0e5 -

1.0e5-

3.58e5 ISTD 638.90> 59.10 (-)

RT (min)

8.59e4 Q 638.90> 59.10 (-)

8.6 8.8 9.0

RT (min)

d3-NMeFOSA

Cone. 4.4012

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 5.2734

2.05e5 I STD 623.00 > 59.00 (-)

1.43e5 Q 623.00> 59.00 (-)

fA=354343
I RT=8.478

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 4.2944

R#1 713.00 >169.30 9.34 (10.03)
Q 713.00>668.90 (-)	9.94e5

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

6.0e5 -
4.0e5 -
2.0e5 -
O.OeO -

13C-PFTeDA

Cone. 5.2307

7.19e5 Q714.80>669.80 (-)

6.0e5 -
4.0e5 -
2.0e5 -
O.OeO -

'A=1862367
RT=8.644

8 9.0
RT (min)

L-PFDoS

Cone. 4.6397

R#1 698.80>98.80 74.75 (68.45)
Q 698.80>80.10 (-)	7.81e4

fA= 187428

7-5e4:R1 7475ALT=a2g4

9.0
RT (min)

NaDONA

Cone. 4.5614

Q 377.10>251.20 (-)

PFHxDA

Cone. 6.4392

A= 1905071
RT=6.401

Q 812.90>769.00 (-)
7.5e5 -

A=1840658
RT=9.171

B.2 8.4 8.6

RT (min)

NMeFOSE

Cone. 4.4501

2.25e5 Q 616.10>58.90 (-)

A= 567724
RT=8.768

O.OeO -

8.6

9.0
RT (min)

RT (min)

11CI-PF30UdS

Cone. 4.3661

Q 631.00>451.10 (-)
2.0e5 -

9.0
RT (min)

PFODA

Cone. 4.6303

7.97e5 Q 912.80>869.00 (-)

3.0e5 -
2.0e5 :
1.0e5:
O.OeO :

9.4

RT (min)

L

9.0
RT (min)

NMeFOSA

Cone. 5.3938

R#1 512.10>219.20 76.11 (86.99)
Q 512.10> 169.20 (-)	9.48e4

1A=240738

: 1 76.11 (-41 rT=8.519

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)
2.0e5

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 5.0864

R#1 526.50>219.20 66.91 (64.74)
Q 526.50> 169.10 (-)	1.66e5

A=421033
1.5e5^ 66.91 (-1 f^j=8.778

O.OeO

8.4 8.6

RT (min)

PFTrDA

Cone. 4.6963

R#1 663.10> 169.10 18.52 (18.77)
Q 663.10>618.90 (-)	1.09e6

fA=2731040
1.0e6 —I18.52 |-rt)= 8.343

O.OeO

3.2 8.4 8.6

RT (min)

9CI-PF30NS

Cone. 4.5938

2.10e5 Q 531.00>351.10 (-)	5.05e5

f!A= 1223935
RT=7.146

RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

9.6 9.8 10.0

RT (min)

3.81 e5 I STD 815.00 > 770.00 (-)

^.Se6z_

1.0e6~_

5.0e5 i
T-. . . O.OeO 1. . .

9.2 9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

117

-------
)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:31

CCV6-230426 (continued)

13C2-PFHxDA

Cone. 5.1647

Q 815.00>770.00 (-)

^.Se6z_

^.0e6z_

5.0e5 ~

O.OeO 1. . .

13C7-PFUnDA IS

Cone. 5.0000

1,87e6 ISTD 569.80> 524.90 (-)
1.0e6 -

PFecHS	PFBSA

Cone. 4.5659	Cone. 4.2012
R#1 461.00>99.10 37.25 (37.10)

1.08e6 Q 461.00>381.00 (-)	9.78e5 Q 298.00>78.00 (-)

PFHxSA

Cone. 4.8192

6.34e5 Q 397.90>78.00 (-)

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

A=2882903
RT=7.672

- R1 37.25 (-

L

A=2374998
$T=6.626

8.0
RT (min)

6.4 6.6 6.8

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

RT (min)

A=1439097
RT=6.136

A=1351667
RT=6.957

6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

118

-------
1st /S/AO 04/28/23
2nd /S/AO 05/01/23

Insight Report
Quantitation/Integration
Printed 4/28/2023 10:15:18

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/27/2023 1:06:19 PM

Acquired by: System Administrator

Data File: 230426081

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.206

775096

775096

	 	

5.0 C""

' '

13C-PFBA

Auto

4.206

775096

2078872

13C7-PFUnDA IS

5.9373

ng/ml

PFBA

Auto

4.208

15529

775096

13C-PFBA IS

0.0884

ng/ml

13C-PFPeA IS

Auto

5.365

1236231

1236231

	 	

5.0000

ng/ml

13C-PFPeA

Auto

5.36S

1236231

2078872

13C7-PFUnDA IS

5.7598

ng/ml

PFPeA

Auto

5.366

21731

1236231

13C-PFPeA IS

0.0901

nq/ml

13C-PFBS IS

Auto

5.496

462299

462299

	 	

4.6500

ng/ml

13C-PFBS

Auto

496

462299

2078872

13C7-PFUnDA IS

5.2484

ng/ml

PFBS

Auto

S.498

m

462299

13C-PFBS IS

0.0830

i			

13C HFPO DA IS

Auto

6.099

: )4

258294

	

5.0000

ng/ml

13C HFPO DA

Auto

6.099

258294

2

13C7-PFUriDA IS



ng/ml

HFPO DA

Auto

6.101

3699

258294

13C HFPO DA IS

: : 4

ng/ml

13C-4 2-FTS IS

Auto

S.899

!6

;6

	

4.6700

ng/ml

13C-4 2-FTS

Auto

399

167486

2078872

*FUn[

4.0015

na/ml

4-2-FtS

Auto

S.900

3838

167486

13C-4 2-FTS IS

0.0918

ng/ml

PFHxA

Auto

354

46969

1696957

13C-PFHxA

0.1057

ng/ml

13C-PFHxA IS

Auto

S.954

1696957

1696957

	 	

5.0000

ng/ml

13C-PFHxA

Auto

5.954

1696957

2078872

13C7-PFUn[

5.5035

ng/ml

PFPeS

Auto

S.996

6352

558

180-PFHxS

0.0855

ng/ml

PFHxS

Auto

6.367

!6

558

1?: '

V ¦:>

ng/ml

13C-PFHpA IS

Auto

6.361

19

1754739

	 	

5.0000

ng/ml

13C-PFHpA

Auto

6.361

1754739

- 872

13C7-PFUnDA IS



ng/ml

180-PFHxS IS

Auto

6.367

497558

497558

	 	

4.7250

ng/ml

180-PFHxS

Auto

6.367

497558

2078872

13C7-PFUnDA IS

5.5840

ng/ml

PFHpA

Auto

6.361

54917

1754739

:HpA

0.1052

ng/ml

13C2-6 2-FTS IS

Auto

6.663

275363

363

	 	

4.7500

nq/ml

13C2-6 2-FTS

Auto

6.663

275363

2078872

•Flint

3.8804

ng/ml

PFHpS

Auto

6.670

6370

558

180-PFHxS

0.0881

ng/ml

6-2-FTS

Auto

6.664

5655

275363

13C2-6 2-FTS IS

0.1052

ng/ml

PFOA

Auto

6.681

58975

2354175

13C-PF

0.0907

ng/ml

13C-PFOA IS

Auto

6.680

2354175

2354175

	 	

5.0000

ng/ml

13C-PFOA

Auto

6.680

2354175

2078872

13C7-PFUnDA IS

5.8759

ng/ml

PFOS

Auto

6.969

'5

481995

13C-PFOS IS

0.0860

ng/ml

13C-PFOS IS

Auto

6.968

481995

481995

	 	

4.7750

nq/ml

13C-PFOS

Auto

6.968

481995

2078872

'FUnDA IS

5.5661

ng/ml

PFNA

Auto

6.991

47165

2314450

13C-PFNA IS

0.0924

ng/ml

13C-PFNA IS

Auto

6.989

>0

2314450

	 	

5.0000

ng/ml

13C-PFNA

Auto

6.989

2314450

2078872

13C7-PFUnDA IS

5.4975

ng/ml

PFNS

Auto

7.297

B

481995

13C-PFOS IS

0.0910

ng/ml

8-2-FTS

Auto

7.327

4323

191507

13C-8

0.1118

nq/ml

13C-8 2-FTS IS

Auto

7.323

191507

191507

	 	

4.7900

ng/ml

13C-8 2-FTS

Auto

7.323

191507

- .872

13C7-PFUnDA IS

•••••J

ng/ml

PFDA

Auto

7.327

49444

2687252

13C-PFDA IS

0.0979

ng/ml

13C-PFDA IS

Auto

7.327

2687252

2687252

	 	

5.0000

ng/ml

13C-PFDA

Auto

7.327

>2

2078872

13C7-PFUnDA IS

5.6248

i

d3-N-MeFOSAA IS

Auto

7.503

627819

627819

	 	

5.0000

ng/ml

d3-N-MeFOSAA

Auto

7.503

627819

2078872

13C7-PFllnDA IS

5.7843

ng/ml

NMeFC

Auto

7.508

13080

627819

' : ISAA IS

0.1040

ng/ml

PFDS

Auto

7.635

7153

481995

13C-PFOS IS

0.0885

nq/ml

13C-PFUnDA IS

Auto

576

2730825

2730825

	 	

5.0000

nq/ml

13C-PFUnDA

Auto

7.676

2730825

2078872

13C7-PFUnDA IS

5.8274

L

PFUnDA

Auto

7.677

47883

2730825

13C-PFUnD/

0.0917

ng/ml

.b N ttFOSAA IS

Auto

7.688

714890

714890

	 	

)

L

d5-N-EtFOSAA

Auto

7.688

714890

2078872

13C7-PFUnDA IS

5.8711

ng/ml

NEIFOSAA

Auto

7.695

7

714890

d5-N-EtFOSAA IS

0.1047

nq/ml

PFOSA

Auto

7.743

12614

592350

13C-FC

- i

ng/ml

I k FOSA IS

Auto

746

592350

592350

	 	

5.0000

ng/ml

13C-FOSA

Auto

7.746

592350

- 872

13C7-PFUnDA IS

5.9649

ng/ml

PFDoA

Auto

8.022

50234

2423656

13C-PFDoA IS

0.1093

ng/ml

13C-PFDoAJS

Auto

8.022

2423656

2423656

—-

5.0000

ng/ml

I -sC-PFPoA

Auto

8.022

2423656

2078872

13C7-PFUnDA IS

5.3586

L

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCalJproc

119

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1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:15:18

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone. Cone. Unit

10-2-FtS

Auto

8.036

4764

191507

13C-8 2-FTS IS

—- 0.0986

nq/mL

d5-NEtFOSA IS

Auto

8.775

551451

551451

—

—- 5.0000

nq/mL

d5-NEtFOSA

Auto

8.775

551451

2078872

13C7-PFUnDA IS

—- 6.0395

nq/mL

NMeFOSE

Auto

8.499

5201

285766

d7-N-MeFOSE IS

—- 0.1004

nq/mL

NEtFOSE

Auto

8.749

15965

195064

d9-EtFOSE IS

—- 0.1045

nq/mL

d9-EtFOSE IS

Auto

8.730

195064

195064

—

—- 5.0000

nq/mL

d9-EtFOSE

Auto

8.730

195064

2078872

13C7-PFUnDA IS

—- 5.3849

nq/mL

NMeFOSA

Auto

8.521

4494

485116

d3-NMeFOSA IS

—- 0.1067

nq/mL

dB-NMeFOSA IS

Auto

8.518

485116

485116

—

—- 5.0000

nq/mL

dB-NMeFOSA

Auto

8.518

485116

2078872

13C7-PFUnDA IS

—- 5.7589

nq/mL

d7-N-MeFOSE IS

Auto

8.483

285766

285766

—

—- 5.0000

nq/mL

d7-N-MeFOSE

Auto

8.483

285766

2078872

13C7-PFUnDA IS

—- 5.8977

nq/mL

NEtFOSA

Auto

8.784

7889

551451

d5-NEtFOSA IS

—- 0.0981

nq/mL

PFTrDA

Auto

8.347

42406

1133725

13C-PFTeDA IS

—- 0.1198

nq/mL

PFTeDA

Auto

8.648

47043

1133725

13C-PFTeDA IS

—- 0.1277

nq/mL

13C-PFTeDA IS

Auto

8.648

1133725

1133725

—

—- 5.0000

nq/mL

1BC-PFTeDA

Auto

8.648

1133725

2078872

13C7-PFUnDA IS

—- 4.4158

nq/mL

11CI-PF30UdS

Auto

7.830

9717

481995

13C-PFOS IS

—- 0.0923

nq/mL

9CI-PFBONS

Auto

7.150

21972

481995

13C-PFOS IS

—- 0.0938

nq/mL

L-PFDoS

Auto

8.300

3062

481995

13C-PFOS IS

—- 0.0862

nq/mL

NaDONA

Auto

6.405

35831

2314450

13C-PFNA IS

—- 0.0990

nq/mL

PFHxDA

Auto

9.178

30819

3628024

13C2-PFHxDA IS

—- 0.0309

nq/mL

PFODA

Auto

9.724

14732

3628024

13C2-PFHxDA IS

—- 0.0748

nq/mL

13C2-PFHxDA IS

Auto

9.178

3628024

3628024

—

—- 5.0000

nq/mL

1BC2-PFHxDA

Auto

9.178

3628024

2078872

13C7-PFUnDA IS

—- 5.9949

nq/mL

13C7-PFUnDA IS

Auto

7.676

2078872

2078872

—

—- 5.0000

nq/mL

PFecHS

Auto

6.630

44041

481995

13C-PFOS IS

—- 0.0963

nq/mL

PFBSA

Auto

6.140

24994

592350

13C-FOSA IS

—- 0.0860

nq/mL

PFHxSA

Auto

6.961

25387

2314450

13C-PFNA IS

—- 0.1044

nq/mL

CHARGE

ND(W/B)

	

	

2078872

13C7-PFUnDA IS

	 	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 5.9373
1.75e5 Q 217.20>172.30 (-)

PFBA

Cone. 0.0884
1.75e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
4.42e3 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 5.7598
4.99e5 Q 267.90>223.00 (-)

A=775096
RT=4.206

fA= 15529
RT=4.208

O.OeO -

O.OeO -

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 0.0901	Cone. 4.6500	Cone. 5.2484 Cone. 0.0830

'A=1236231
RT= 5.365

O.OeO

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)	8.41e3 ISTD 301.80>80.00 (-)	1.74e5 Q 301.80>80.00 (-)

f A=21731	fA=462299	fA=462299

RT= 5.496

R#1 298.80>99.00 54.34 (72.97)

1.74e5 Q 299.00>80.00 (-)	2.52e3 ISTD 332.10>287.10 (-)	1.15e5

~ A=6298

: R1 54.34 (-f^r= 5.498
2.0e3 -

5.6 5.8
RT (min)

1.0e5-

f A=258294
RT=6.099

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

120

-------
1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:15:18

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 5.7854

Q 332.10>287.10 (-)

J A=258294
RT=6.099

HFPO DA

Cone. 0.0904

R#1 329.00>285.10 56.14 (68.92)
Q 329.00>169.00 (-)	1.73e3

?A=3699
1 5e3-R1 56-14(-"rtT=6.101

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 28.94 (27.58)

ISTD 329.00>309.15 (-)	7.06e4

f A= 167486

Cn„,JR1 28.94 (-"^1=5.899

0.0e0

6.2 6.4
RT (min)

PFHxA

Cone. 0.1057

R#1 313.00> 119.10 3.03 (2.54)
Q 313.00>269.00 (-)	1.91e4

^ A=46969

:R1 3.03 (—')rt=5.954

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

5.8 6.0 6.2
RT (min)

13C-PFHxA

Cone. 5.5035

7.15e5 Q 314.90>270.10 (-)

A=1696957
RT= 5.954

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)
7.5e5 -

A=1754739
RT=6.361

5.0e5 :
2.5e5 :
O.OeO :

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

Q 366.90>322.10 (-)
7.5e5 -

5.0e5 ^

2.5e5 ^

O.OeO 1 , , ,

A=1754739
RT=6.361

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)
2.0e5 -

A=497558
RT=6.367

1.0e5 -

O.OeO -

6.6

RT (min)

6.6

RT (min)

13C2-6 2-FTS

Cone. 3.8804

1.19e5 Q 428.90>409.00 (-)

fA=275363
RT=6.663

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
1.0e6 -i

13C-PFOA

Cone. 5.8759

1.01e6 Q 416.80>372.05 (-)

13C-4 2-FTS

Cone. 4.0015

R#1 329.00>81.00 28.94 (27.58)
Q 329.00>309.15 (-)	7.06e4

TA= 167486
I R1 28.94 (-|^T=5.

4-2-FtS

Cone. 0.0918

R#1 327.00>81.10 2.05 (15.16)
Q 327.00>307.05 (-)	1.80e3

~ A=3838
R1 2.05 (~f)RT= 5.900

O.OeO

5.8 6.0 6.2
RT (min)
PFPeS

Cone. 0.0855

R#1 349.00>99.00 86.67 (80.87)
7.15e5 Q 349.00>79.95 (-)	2.73e3

~ A=6352
I R1 86.67 (-41^7=5.996

O.OeO

5.8 6.0 6.2

RT (min)

180-PFHxS

Cone. 5.5840

Q 402.70>84.05 (-)
2.0e5 -

1.0e5-

f A=497558
RT=6.367

6.4 6.6

RT (min)

PFHpS

Cone. 0.0881

R#1 449.00>99.20 74.15 (65.35)
Q 449.00>80.15 (-)	2.41 e3

^A=6370

"R1 7415 H"&T=6.670
2.0e3 -	|

1.0e3 -	J|

O.OeO 1	i | i^, r, , , ¦

6.6 6.8

RT (min)

PFOS

Cone. 0.0860

R#1 499.00>99.00 90.66 (96.24)
Q 499.00>80.00 (-)	1.53e3

TA=4775

R1 90.66 (-4kT=6.969

13C-PFOS IS

Cone. 4.7750

ISTD 502.80>80.05 (-)
2.0e5 -i

A=481995
RT=6.968

6.75 7.00 7.25

RT (min)

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.0902

R#1 399.00 >99.00 97.93 (92.02)
Q 399.00>80.00 (-)	2.22e3

tA=5926

2.0e3-R1 9793 ("""$T=6.367

1.0e3-	j|

o.oeo 1 , , a i i ivfrrrrr^

6.2

6.4 6.6

RT (min)
PFHpA

Cone. 0.1052

R#1 362.90>169.00 18.25 (17.74)
2.21 e5 Q 362.90>319.00 (-)	2.33e4

~ A=54917

1R1 18.25 (-tL1^T=6.361

O.OeO -

6.4 6.6

RT (min)

6-2-FTS

Cone. 0.1052

R#1 427.00>80.90 17.75 (27.82)
Q 427.00>407.00 (-)	2.38e3

~ A=5655

-R1 17.75 (-4^t=6.664

^.ue4^	iji 	

1.0e4-	I

O.OeO 1 i i i A,,' i i 7, ,TTT~

6.2 6.4 6.6

RT (min)

PFOA

Cone. 0.0907

R#1 413.00 > 169.10 29.92 (27.71)
Q 413.00>369.00 (-)	2.61e4

^A= 58975
-R1 29.92 (4^=6.681
2.0e4 -	I

^.0e4-

O.OeO	, , -^=

RT (min)

6.8 7.0
RT (min)

13C-PFOS

Cone. 5.5661

Q 502.8
2.0e5 -

105 (-)

rA=481995
| RT=6.968

7.0 7.2

RT (min)

7.0 7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

121

-------
1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:15:18

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0924

R#1 463.00>219.00 23.86 (20.94)
Q 463.00>418.90 (-)	1.89e4

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 5.4975

9.47e5 Q 467.80>423.00 (-)

PFNS

Cone. 0.0910

R#1 549.00>99.00 61.43 (65.53)

9.47e5 Q 549.00>79.95 (-)

~ A=47165

= R1 23.86 (•

O.OeO -

f A= 11093
R1 61.43 (4Rt=7.297

7.2

RT (min)

7.2

13C-8 2-FTSJS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 3.8738

7.38e4 Q 528.80> 509.00 (-)

13C-PFDAJS

Cone. 5.0000

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

A= 191507
RT=7.323

7.6
RT (min)

7.2

RT (min)

PFDA

Cone. 0.0979
R#1 512.90>219.00 17.09 (18.19)

Q 512.90>469.00 (-)	1.95e4 ISTD 514.80>469.95 (-)

~ A=49444

-R1 17.09 (-;Rt=7.327

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 5.7843

2.30e5 Q 572.80>419.05 (-)

O.OeO

7.6
RT (min)

NMeFOSAA

Cone. 0.1040

R#1 570.20>512.00 36.06 (35.78)
Q 570.20>419.00 (-)	4.05e3

O.OeO -

4.0e3 -

~ A= 13080

R1 36.06 (—f-ftT=7.508



L

7.6 7.8
RT (min)

7.4

13C-PFUnDA

Cone. 5.8274

Q 564.80>519.95 (-)
1.0e6 i

7.6 7.8
RT (min)

PFUnDA

Cone. 0.0917

R#1 563.00>219.00 10.23 (11.87)
Q563.00>518.90 (-)	1.84e4

Y A=47883
R1 10.23 (--rt)= 7.677

7.25 7.50 7.75

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

d5-N-EtFOSAA

Cone. 5.8711

2.60e5 Q 588.80>419.00 (-)

O.OeO

7.8 8.0
RT (min)

PFOSA

Cone. 0.1018

R#1 498.20>64.10 0.85 (0.15)
Q 498.20>78.00 (-)	5.93e3

f A=12614

O.OeO -

7.8 8.0
RT (min)

7.6

13C-FOSA IS

Cone. 5.0000

13C-FOSA

Cone. 5.9649

ISTD 506.00>78.05 (-)	2.36e5 Q 506.00>78.05 (-)

\=592350

:R1 0.85

)rj=7.743

2.0e5 -



RT=7.746

2.0e5

:



1.0e5 -





1.0e5





— O.OeO -

y

u

— O.OeO

7.8 8.0

RT (min)

7.6 7.8 8.0

RT (min)

7.6 7.8 8.0

RT (min)

8-2-FTS

Cone. 0.1118

R#1 527.20>487.00 3.27 (5.33)

4.70e3 Q 527.10>506.90 (-)

1.5e3
1.0e3
5.0e2
O.OeO

f A=4323

; R1 3 27 Hi-frT=7.327

7.4 7.6
RT (min)

7.6
RT (min)

13C-PFDA

Cone. 5.6248

1.09e6 Q 514.80>469.95 (-)
1.0e6-

0-0e0 I, | | i a i11 |—i—i—i—i—|—i—|—
7.2 7.4 7.6

RT (min)

PFDS

Cone. 0.0885

R#1 599.00>99.00 62.64 (60.20)
Q 599.00>80.10 (-)	2.99e3

¥ A=7153

I R1 62.64 -j-Ri)= 7.635

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)
1.0e6i

A=2730825
RT=7.676

O.OeO -



7.6

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.1047

R#1 584.20>526.10 45.64 (55.50)
Q 584.20>418.95 (-)	4.18e3

4.0e3 - ri 45.64 H

~ A=13617
"&T=7.695

7.8 8.0
RT (min)

PFDoA

Cone. 0.1093

R#1 613.05> 169.00 16.20 (15.47)
Q 613.05>569.00 (-)	1.89e4

O.OeO ~7AiT^;	

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

9.21 e5

RT (min)

RT (min)

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

122

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1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:15:18

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 5.3586

Q614.80>569.95 (-)

7.5e5 i
5.0e5 ~

2.5e5 i
O.OeO ^h-;-

d5-NEtFOSA IS

Cone. 5.0000

10-2-FtS

Cone. 0.0986
R#1 626.50>81.05 62.67 (56.92)

9.21 e5 Q 626.50>607.05 (-)	1,82e3 ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 6.0395

2.16e5 Q 531.10> 169.10 (-)

NMeFOSE

Cone. 0.1004

2.16e5 Q 616.10>58.90 (-)

RT (min)

NEtFOSE

Cone. 0.1045

Q 629.50> 59.10 (-)	6.49e3

RT (min)

d3-NMeFOSA

Cone. 5.7589

Q 515.10> 169.00 (-)	1.95e5

RT (min)

PFTeDA

Cone. 0.1277

R#1 713.00 >169.30 9.41 (10.03)
Q 713.00>668.90 (0	1.76e4

RT (min)

L-PFDoS

Cone. 0.0862

R#1 698.80 >98.80 54.26 (68.45)
Q 698.80>80.10 (0	1.38e3

RT (min)

RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

I STD 623.00 >59.00 (0	1.16e5

RT (min)

13C-PFTeDA IS

Cone. 5.0000

I STD 714.80 >669.80 (0	4.37e5

RT (min)

NaDONA

Cone. 0.0990

Q 377.10>251.20(0	1.63e4

RT (min)

RT (min)

d7-N-MeFOSE

Cone. 5.8977

Q 623.00> 59.00 (0	1.16e5

RT (min)

13C-PFTeDA

Cone. 4.4158

Q 714.80>669.80 (0	4.37e5

RT (min)

PFHxDA

Cone. 0.0309

Q 812.90>769.00 (0	1.34e4

RT (min)

RT (min)

NEtFOSA

Cone. 0.0981

R#1 526.50>219.20 60.37 (64.74)
Q526.50> 169.10(0	3.11e3

RT (min)

11CI-PF30UdS

Cone. 0.0923

Q 631.00>451.10 (0	3.81e3

RT (min)

PFODA

Cone. 0.0748

Q 912.80>869.00 (0	5.35e3

RT (min)

RT (min)

PFTrDA

Cone. 0.1198

R#1 663.10> 169.10 19.19 (18.77)
Q 663.10>618.90(0	1.78e4

RT (min)

9CI-PF30NS

Cone. 0.0938

Q 531.00>351.10(0	8.86e3

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

I STD 815.00 >770.00 (0	1.57e6

RT (min)

d9-EtFOSE

Cone. 5.3849

9.0

RT (min)

Q 638.90>59.10 (0

O.OeO , , r"

8.6 8.8 9.0

RT (min)

NMeFOSA

Cone. 0.1067

R#1 512.10>219.20 81.67 (86.99)
Q 512.10> 169.20 (0	1.85e3

1.0e3-

O.OeO -bj:

8.4 8.6

1.5e3

1.0e3

5.0e2

O.OeO

8.0

d9-EtFOSE IS

Cone. 5.0000

I STD 638.90 >59.10 (0

RT (min)

A=551451
RT=8.775

I STD 515.10> 169.00 (0 1.95e5

8.8
RT (min)

d3-NMeFOSA IS

Cone. 5.0000

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

123

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1st /S/ AO 04/28/23
2nd IS/ AO 05/01/23

Insight Report
Quantitation/lntegration
Printed 4/28/2023 10:15:18

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 5.9949

Q 815.00>770.00 (-)
1.5e6 -
1.0e6-j
5.0e5 ^

O.OeO 1. . .

13C7-PFUnDA IS

Cone. 5.0000

A=3628024
RT=9.178

1.57e6 ISTD 569.80>524.90 (-)
7.5e5 -

PFecHS	PFBSA

Cone. 0.0963	Cone. 0.0860
R#1 461.00>99.10 36.77 (37.10)

7.83e5 Q 461.00>381.00 (-)	1.77e4	Q 298.00>78.00 (-)

9.0

9.2

5.0e5 :
2.5e5 :
O.OeO :

9.4
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

A=2078872
RT=7.676

1.5e4
1.0e4
5.0e3
O.OeO

f A=44041

;R1 36.77 (-111*7=6.630

1.0e4

8.0
RT (min)



RT (min)

A=24994
RT=6.140

PFHxSA

Cone. 0.1044

Q 397.90>78.00 (-)
1.0e4-

C:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_.iproc

124

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:35

CCV7-230426

Sample ID: CCV7-230426

Date Acquired: 4/27/2023 1:33:49 PM

Acquired by: System Administrator

Data File: 230426083

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.211

857930

857930

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.211

857930

2225544

13C7-PFUnDA IS

5.0000

6.1387

nq/mL

PFBA

Auto

4.211

962193

857930

13C-PFBA IS

5.0000

4.9466

nq/mL

13C-PFPeA IS

Auto

5.373

1384249

1384249

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.373

1384249

2225544

13C7-PFUnDA IS

5.0000

6.0244

nq/mL

PFPeA

Auto

5.373

1233811

1384249

13C-PFPeA IS

5.0000

4.5703

nq/mL

13C-PFBS IS

Auto

5.502

- : - i7

513557

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.502

513557

2225544

13C7-PFUnDA IS

4.6500

5.4461

nq/mL

PFBS

Auto

5.502

340341

513557

13C-PFBS IS

4.4200

4.0360

nq/mL

13C HFPO DA IS

Auto

6.106

294539

294539

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.106

294539

2225544

13C7-PFUnDA IS

5.0000

6.1624

nq/mL

HFPO DA

Auto

6.106

212393

294539

13C HFPO DA IS

5.0000

4.5534

nq/mL

13C-4 2-FTS IS

Auto

5.906

205122

205122

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.906

205122

2225544

13C7-PFUnDA IS

4.6700

4.5778

nq/mL

4-2-FtS

Auto

5.906

225557

205122

13C-4 2-FTS IS

4.6700

4.4030

nq/mL

PFHxA

Auto

5.961

2387825

1872131

13C-PFHxA IS

5.0000

4.8689

nq/mL

13C-PFHxA IS

Auto

5.961

1872131

1872131

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

5.961

1872131

2225544

13C7-PFUnDA IS

5.0000

5.6715

nq/mL

PFPeS

Auto

6.002

361806

544568

180-PFHxS IS

4.6900

4.4477

nq/mL

PFHxS

Auto

6.373

284362

544568

180-PFHxS IS

4.5500

3.9558

nq/mL

13C-PFHpA IS

Auto

6.368

1872498

1872498

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.368

1872498

2225544

13C7-PFUnDA IS

5.0000

5.7161

nq/mL

180-PFHxS IS

Auto

6.374

544568

544568

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.374

544568

2225544

13C7-PFUnDAJS

4.7250

5.7088

ng/mL

PFHpA

Auto

6.368

^746476

1872498

13C-PFHpA IS

5.0000

4.9306

ng/mL

13C2-6 2-FTS IS

Auto

6.669

302819

302819

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.669

302819

2225544

13C7-PFUnDA IS

4.7500

3.9860

ng/mL

PFHpS

Auto

6.678

362435

544568

180-PFHxS IS

4.7600

4.5776

nq/mL

6-2-FTS

Auto

6.669

288872

302819

13C2-6 2-FTS IS

4.7400

4.8872

nq/mL

PFOA

Auto

6.687

3157892

2467254

13C-PFOA IS

5.0000

4.6343

nq/mL

13C-PFOA IS

Auto

6.687

2467254

2467254

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.687

2467254

2225544

13C7-PFUnDA IS

5.0000

5.7523

nq/mL

PFOS

Auto

6.976

253715

534771

13C-PFOS IS

4.6400

4.1201

nq/mL

13C-PFOS IS

Auto

6.976

534771

534771

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

6.976

534771

2225544

13C7-PFUnDA IS

4.7750

5.7686

nq/mL

PFNA

Auto

6.997

2562987

2551995

13C-PFNA IS

5.0000

4.5516

nq/mL

13C-PFNA IS

Auto

6.997

2551995

2551995

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.997

2551995

2225544

13C7-PFUnDA IS

5.0000

5.6622

nq/mL

PFNS

Auto

7.304

613548

534771

13C-PFOS IS

4.8000

4.5348

nq/mL

8-2-FTS

Auto

7.332

201712

214420

13C-8 2-FTS IS

4.7900

4.6595

nq/mL

13C-8 2-FTS IS

Auto

7.332

214420

214420

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.332

214420

2225544

13C7-PFUnDA IS

4.7900

4.0515

nq/mL

PFDA

Auto

7.336

2661968

2907918

13C-PFDA IS

5.0000

4.8730

r

13C-PFDA IS

Auto

7.336

2907918

2907918

	

5.0000

5.0000

ng/mL

13C-PFDA

Auto

7.336

2907918

2225544

13C7-PFUnDA IS

5.0000

5.6856

r

d3-N-MeFOSAA IS

Auto

7.513

704847

704847

	

5.0000

5.0000

ng/mL

d3-N-MeFOSAA

Auto

7.513

704847

2225544

13C7-PFUnDA IS

5.0000

6.0660

r

NMeFOSAA

Auto

7.517

641896

704847

d3-N-MeFOSAA IS

5.0000

4.5460

nq/mL

PFDS

Auto

7.645

424903

534771

13C-PFOS IS

4.8200

4.7355

r

13C-PFUnDA IS

Auto

7.686

2929273

2929273

	

5.0000

5.0000

ng/mL

13C-PFUnDA

Auto

7.686

2929273

2225544

13C7-PFUnDA IS

5.0000

5.8389

r

PFUnDA

Auto

7.686

2451196

2929273

13C-PFUnDA IS

5.0000

4.3779

ng/mL

d5-N-EtFOSAA IS

Auto

7.698

754919

754919

	

5.0000

5.0000

r

d5-N-EtFOSAA

Auto

7.698

754919

2225544

13C7-PFUnDA IS

5.0000

5.7912

ng/mL

NEtFOSAA

Auto

7.705

705368

754919

dS-N-EtFOSAA IS

5.0000

5.1360

r

PFOSA

Auto

7.753

647997

635721

13C-FOSA IS

5.0000

4.8741

ng/mL

13C-FOSA IS

Auto

7.753

635721

635721

	

5.0000

5.0000

r

13C-FOSA

Auto

7.753

635721

2225544

13C7-PFUnDA IS

5.0000

5.9797

nq/mL

PFDoA

Auto

8.029

2731934

2752011

13C-PFDoA IS

5.0000

5.2359

nq/mL

13C-PFDoA IS

Auto

8.029

2752011

2752011

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

125

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:35

CCV7-230426 (continued)













(Table continued from previous page)
Name Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.029

2752011

2225544

13C7-PFUnDA IS

5.0000

5.6836

nq/mL

10-2-FtS

Auto

8.042

272272

214420

13C-8 2-FTS IS

4.8200

5.0327

ng/mL

d5-NEtFOSA IS

Auto

8.780

531906

531906

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.780

531906

2225544

13C7-PFUnDA IS

5.0000

5.4416

ng/mL

NMeFOSE

Auto

8.503

261317

279813

d7-N-MeFOSE IS

5.0000

5.1511

nq/mL

NEtFOSE

Auto

8.754

840881

200275

d9-EtFOSE IS

5.0000

5.3584

ng/mL

d9-EtFOSE IS

Auto

8.736

200275

200275

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.736

200275

2225544

13C7-PFUnDA IS

5.0000

5.1644

ng/mL

NMeFOSA

Auto

8.528

218343

488630

d3-NMeFOSA IS

5.0000

5.1474

nq/mL

dB-NMeFOSA IS

Auto

8.524

488630

488630

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.524

488630

2225544

13C7-PFUnDA IS

5.0000

5.4183

nq/mL

d7-N-MeFOSE IS

Auto

8.488

279813

279813

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.488

279813

2225544

13C7-PFUnDA IS

5.0000

5.3942

nq/mL

NEtFOSA

Auto

8.790

398656

531906

d5-NEtFOSA IS

5.0000

5.1404

ng/mL

PFTrDA

Auto

8.354

2154616

1118158

13C-PFTeDA IS

5.0000

6.1711

nq/mL

PFTeDA

Auto

8.653

2205160

1118158

13C-PFTeDA IS

5.0000

6.0691

ng/mL

13C-PFTeDA IS

Auto

8.653

1118158

1118158

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.653

1118158

2225544

13C7-PFUnDA IS

5.0000

4.0681

ng/mL

11CI-PFBOUdS

Auto

7.838

551792

534771

13C-PFOS IS

4.7100

4.7225

nq/mL

9CI-PF30NS

Auto

7.158

1179313

534771

13C-PFOS IS

4.6600

4.5385

ng/mL

L-PFDoS

Auto

8.304

191236

534771

13C-PFOS IS

4.8400

4.8539

nq/mL

NaDONA

Auto

6.412

1989327

2551995

13C-PFNA IS

4.7100

4.9846

ng/mL

PFHxDA

Auto

9.183

905576

3985196

13C2-PFHxDA IS

5.0000

3.2868

nq/mL

PFODA

Auto

9.733

636311

3985196

13C2-PFHxDA IS

5.0000

2.9400

ng/mL

13C2-PFHxDA IS

Auto

9.183

3985196

3985196

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.183

3985196

2225544

13C7-PFUnDA IS

5.0000

6.1511

ng/mL

13C7-PFUnDA IS

Auto

7.685

2225544

2225544

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.637

2214266

534771

13C-PFOS IS

4.6100

4.3648

ng/mL

PFBSA

Auto

6.146

1415000

635721

13C-FOSA IS

5.0000

4.5392

nq/mL

PFHxSA

Auto

6.969

1327106

2551995

13C-PFNA IS

5.0000

4.9517

ng/mL

CHARGE

ND(W/B)

	

	

2225544

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 6.1387
1.96e5 Q 217.20>172.30 (-)

O.OeO -

'A=857930
RT=4.211

O.OeO

PFBA

Cone. 4.9466
1.96e5 Q 213.20> 169.10 (-)

2.0e5

13C-PFPeA IS

Cone. 5.0000
2.15e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 6.0244
5.55e5 Q 267.90>223.00 (-)

O.OeO

O.OeO -

fA= 1384249
RT= 5.373

O.OeO -

5.2

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 4.5703	Cone. 4.6500	Cone. 5.4461 Cone. 4.0360

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)

4.51 e5 ISTD 301.80>80.00 (-)

1.95e5 Q 301.80>80.00 (-)

R#1 298.80>99.00 72.04 (72.97)

1.95e5 Q 299.00>80.00 (-)	1.29e5 ISTD 332.10>287.10 (-)	1.30e5

fA=340341
jR1 72.04 (-UT=5.502

fA=294539
I RT=6.106

5.6

RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1~230426A-537MOD_OldCal_Corrected.iproc

126

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:35

CCV7-230426 (continued)

13C HFPO DA

Cone 6.1624

Q332.10>287.10 (-)

HFPO DA

Cone. 4.5534

R#1 329.00>285.10 76.21 (68.92)
Q 329.00>169.00 (-)	9.18e4

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 27.23 (27.58)

ISTD 329.00>309.15 (-)	8.73e4

13C-4 2-FTS

Cone. 4.5778

R#1 329.00>81.00 27.23 (27.58)
Q 329.00>309.15 (-)	8.73e4

fA=294539
RT=6.106

O.OeO -

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 4.8689

R#1 313.00> 119.10 2.60 (2.54)
Q 313.00>269.00 (-)	1.02e6

4-2-FtS

Cone. 4.4030

R#1 327.00>81.10 16.20 (15.16)
Q 327.00>307.05 (-)	9.43e4

fA=225557

: 1 16.20 (-4 RT= 5.906

1.0e6-

T A=2387825
R1 2 60 (— RT= 5.961

13C-PFHxA IS

Cone. 5.0000

I STD 314.90 >270.10 (-)
7.5e5 -
5.0e5 ^

2.5e5 ^

O.OeO 1. . . .

6.2
RT (min)

13C-PFHpA_IS

Cone. 5.0000

13C-PFHpA

Cone. 5.7161

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

13C2-6 2-FTS

Cone. 3.9860

1.31e5 Q 428.90>409.00 (-)

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
1.0e6 -

13C-PFOA

Cone. 5.7523

1.05e6 Q416.80>372.05 (-)
1.0e6 -

6.8 7.0
RT (min)

Q 314.90>270.10 (-)
7.5e5 -
5.0e5 ^

2.5e5 ^

O.OeO 1. . . .

6.0 6.2
RT (min)

PFPeS

Cone. 4.4477

R#1 349.00>99.00 83.98 (80.87)
Q 349.00>79.95 (-)	1.56e5

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 3.9558

R#1 399.00 >99.00 98.08 (92.02)
Q 399.00>80.00 (-)	1.04e5

1.5e5-
1.0e5^
5.0e4 -j
O.OeO :

A=361806

R1 83.98 (--|-^T=6.002

1.0e5

'A=284362

]R1 98.08 (-1-^1=6.373

L

O.OeO -



6.2
RT (min)

6.2
RT (min)

6.2

RT (min)

6.2

6.4

180-PFHxS IS

Cone. 4.7250

180-PFHxS

Cone. 5.7088

8.24e5 ISTD 402.70>84.05 (-)

2.47e5 Q 402.70>84.05 (-)

O.OeO -

O.OeO -

6.6
RT (min)

PFHpA

Cone. 4.9306

R#1 362.90 >169.00 17.32 (17.74)
Q 362.90>319.00 (-)	1.20e6

- R1

6.6

RT (min)

6.2

6.4

6.6
RT (min)

PFHpS

Cone. 4.5776

R#1 449.00>99.20 66.18 (65.35)

6.2

6.4

6.6
RT (min)

6-2-FTS

Cone. 4.8872

R#1 427.00>80.90 28.69 (27.82)

Q 449.00>80.15 (-)	1.54e5 Q 427.00>407.00 (-)	1.25e5

fA=362435

1.5e5 -
1.0e5:
5.0e4 :
O.OeO -

R1 6618 (--Rt=6.678

=F

O.OeO

13C-PFOSJS

Cone. 4.7750

6.6 6.8

RT (min)

PFOS

Cone. 4.1201
R#1 499.00>99.00 93.33 (96.24)

Q 499.00> 80.00 (-)	7.92e4 I STD 502.80 > 80.05 (-)

fA=253715

7-5e4^Rl 93.33 (- | RT=6.976

5.0e4 :

2.5e4 ^

O.OeO :

2.26e5 Q 502.80>80.05 (-)

fA= 534771
RT=6.976

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

7.2

RT (min)

7.2

RT (min)

17.32 (-

O.OeO I , | | | _

6.2 6.4 6.6

RT (min)

PFOA

Cone. 4.6343

R#1 413.00> 169.10 29.25 (27.71)
Q 413.00>369.00 (-)	1.37e6

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

127

-------
A

CCV7-230426 (continued)

PFNA	13C-PFNA IS

Cone. 4.5516	Cone. 5.0000
R#1 463.00>219.00 21.66 (20.94)

Q 463.00>418.90 (-)	1.04e6	ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 5.6622

PFNS

Cone. 4.5348

R#1 549.00>99.00 67.67 (65.53)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:35

8-2-FTS

Cone. 4.6595

R#1 527.20>487.00 6.77 (5.33)

1.0e6

1.0e6

Q 467.80>423.00 (-)	1.02e6 Q 549.00>79.95 (-)	2.47e5 Q 527.10>506.90 (-)	7.92e4

r A=2551995	fA=613548	|A=201712

7.5e4:Rl 6.77 (4 rT=7.332

0.0e0

O.OeO

13C-8 2-FTSJS

Cone. 4.7900

ISTD 528.80>509.00 (-)
7.5e4 ^

5.0e4 ^

2.5e4 ^

O.OeO 1. . .

7.2 7.4 7.6

RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

13C-8 2-FTS

Cone. 4.0515

7.99e4 Q 528.80> 509.00 (-)
7.5e4 ^

5.0e4 ^

2.5e4 ^
. . r- O.OeO 1. . |

7.2

RT (min)

PFDA

Cone. 4.8730
R#1 512.90>219.00 17.72 (18.19)

Q 512.90>469.00 (-)	1.07e6 ISTD 514.80>469.95 (-)

13C-PFDAJS

Cone. 5.0000

1.16e6 Q 514.80>469.95 (-)

f A=2661968

1.0e6jR1 17.72 ( |-^r=7.336

O.OeO

7.4 7.6

RT (min)

fA=2907918
I RT=7.336

O.OeO

d3-N-MeFOSAA

Cone. 6.0660

ISTD 572.80>419.05 (-)

2.58e5 Q 572.80>419.05 (-)

7.6
RT (min)

NMeFOSAA

Cone. 4.5460

R#1 570.20>512.00 39.69 (35.78)
Q 570.20>419.00 (-)	1.97e5

O.OeO -

7.25 7.50 7.75

13C-PFUnDA

Cone. 5.8389

Q 564.80>519.95 (-)
1.0e6 -

5.0e5 -

O.OeO -Uf=F

7.6 7.8
RT (min)

PFUnDA

Cone. 4.3779
R#1 563.00>219.00 14.19 (11.87)

1.10e6 Q 563.00> 518.90 (-)	9.18e5 ISTD 588.80>419.00 (-)

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

d5-N-EtFOSAA

Cone. 5.7912

2.83e5 Q 588.80>419.00 (-)

7.6 7.8 8.0
RT (min)

PFOSA

Cone. 4.8741
R#1 498.20>64.10 0.11 (0.15)

Q 498.20> 78.00 (-)	2.61 e5 I STD 506.00 > 78.05 (-)

13C-FOSA IS

Cone. 5.0000

13C-FOSA

Cone. 5.9797

2.58e5 Q 506.00>78.05 (-)

- R1 0.11 (—

fA=635721
RT=7.753

7.8 8.0
RT (min)

fA=635721
RT=7.753

7.6 7.8 8.0

RT (min)

7.8 8.0

RT (min)

7.8 8.0

RT (min)

fA=2907918
I RT=7.336

7.6
RT (min)

PFDS

Cone. 4.7355

R#1 599.00>99.00 60.20 (60.20)
Q 599.00>80.10 (-)	1.65e5

O.OeO-

7.2 7.4 7.6

RT (min)

13C-PFUnDA IS

Cone. 5.0000

ISTD 564.80>519.95 (-)	1.10e6

1.0e6-

5.0e5 -

O.OeO

7.8 8.0
RT (min)

NEtFOSAA

Cone. 5.1360

R#1 584.20>526.10 56.82 (55.50)
Q 584.20>418.95 (-)	2.24e5

TA=705368

2.0e5-R1 5682 (~~f~k.T=7.705

O.OeO

7.8 8.0
RT (min)

PFDoA

Cone. 5.2359

R#1 613.05> 169.00 16.50 (15.47)
Q 613.05>569.00 (-)	1.04e6

1.0e6-

O.OeO -



7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

1.05e6

RT (min)

R1 16.50

8.2

RT (min)

1

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128

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:35

CCV7-230426 (continued)

13C-PFDoA

Cone. 5.6836

Q614.80>569.95 (-)
1.0e6 -

NEtFOSE

Cone. 5.3584

d5-NEtFOSA IS

Cone. 5.0000

10-2-FtS

Cone. 5.0327
R#1 626.50>81.05 64.51 (56.92)

1,05e6 Q 626.50>607.05 (-)	1.01 e5 ISTD 531.10> 169.10 (-)

RT (min)

d5-NEtFOSA

Cone. 5.4416

2.14e5 Q 531.10> 169.10 (-)

NMeFOSE

Cone. 5.1511

2.14e5 Q 616.10>58.90 (-)

A=200275
RT=8.736

9.0
RT (min)

d3-NMeFOSA

Cone. 5.4183

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

d7-N-MeFOSE IS

Cone. 5.0000

1,90e5 I STD 623.00 > 59.00 (-)

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 6.0691

R#1 713.00>169.30 10.95 (10.03)
Q 713.00>668.90 (-)	8.45e5

13C-PFTeDA IS

Cone. 5.0000

I STD 714.80 >669.80 (-)
4.0e5

9.0
RT (min)

L-PFDoS

Cone. 4.8539

R#1 698.80 >98.80 66.29 (68.45)
Q 698.80>80.10 (-)	7.73e4

NaDONA

Cone. 4.9846

Q 377.10>251.20 (-)

8.4 8.6
RT (min)

d7-N-MeFOSE

Cone. 5.3942

1.13e5 Q 623.00> 59.00 (-)

RT (min)

13C-PFTeDA

Cone. 4.0681

Q 714.80>669.80 (-)
4.0e5

9.0
RT (min)

PFHxDA

Cone. 3.2868

8.94e5 Q 812.90>769.00 (-)

T A=218343
7.5e4^R1 7914 pT=8.528

9.0
RT (min)

O.OeO

8.4 8.6

RT (min)

NEtFOSA

Cone. 5.1404

R#1 526.50>219.20 64.53 (64.74)
Q 526.50> 169.10 (-)	1.55e5

1.5e5-
1.0e5^
5.0e4^
O.OeO:

A=398656

R1 64.53 (- -[^7=8.790

RT (min)

11CI-PF30UdS

Cone. 4.7225

Q 631.00>451.10 (-)
2.0e5 -

1.0e5-

8.6 8.8 9.0
RT (min)

PFODA

Cone. 2.9400

3.93e5 Q 912.80>869.00 (-)

f A=636311
2.0e5H	|RT=9.733

9.4

RT (min)

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 6.1711

R#1 663.10> 169.10 20.71 (18.77)
Q 663.10>618.90 (-)	8.79e5

7.5e5 f

R1 20.71 (

|-Rt=8.354

5.0e5 ~





2.5e5 ~





0 0<=>0 -

	1

	

9.0

RT (min)

8.6

RT (min)

9CI-PF30NS

Cone. 4.5385

2.23e5 Q 531.00>351.10 (-)

r A= 1179313
I RT=7.158

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

2.21 e5 I STD 815.00 > 770.00 (-)

1.5e6^

1.0e6^

5.0e5 ^
7~. . . O.OeO 1. . . .

10.0

RT (min)

9.4

RT (min)

O-OeO	i '	i i i T

8.6 8.8 9.0

RT (min)

NMeFOSA

Cone. 5.1474

R#1 512.10>219.20 79.14(86.99)
Q 512.10> 169.20 (-)	8.55e4

d9-EtFOSE IS

Cone. 5.0000

iSTD 638.90>59.10 (-)

RT (min)

8.6 8.8 9.0

RT (min)

d9-EtFOSE

Cone. 5.1644

Q 638.90> 59.10 (-)	7.94e4

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)	1.90e5

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

129

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:05:35

CCV7-230426 (continued)

13C2-PFHxDA

Cone 6.1511

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

PFecHS	PFBSA

Cone. 4.3648	Cone. 4.5392
R#1 461.00>99.10 38.55 (37.10)

8.23e5 Q 461.00>381.00 (-)	9.05e5	Q 298.00>78.00 (-)

PFHxSA

Cone. 4.9517

5.90e5 Q 397.90>78.00 (-)

9.4
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

RT (min)

0.2
RT (min)

A= 1415000
RT=6.146

TA= 1327106
RT=6.969

7.2
RT (min)

Z:\LabSolutions\Data\LCMS1-230426\LCMS1-230426A-537MOD_OldCal_Corrected.iproc

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10/24/2023 3:16:28 PM Page 1 / 5

==== Shimadzu LabSolutions Batch Table====

[General]

Start from Continuing Row
[Folder]

Use Current Folder
[Data Filename]

Not Create filename
[ASCII Conversion]

Not Output ASCII Files
[File Conversion]

Not Convert
[QA/QC]

Not Execute QA/QC
[Option Item]

Option 1 Title:

Option 2 Title:

Option 3 Title:

Option 4 Title:

Option 5 Title:

Option 6 Title:

Option 7 Title:

Option 8 Title:

Option 9 Title:

Option 10 Title:

[Bracket]

None
[Startup]

Startup Off
[Shutdown]

Shutdown On
Cool down Time:0min
Degassing Unit Off
LC Pump Off
Column Oven Off
[Comment]

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

1

MEOH

MEOH

0:Unknown

CMS1 230328 537M.lcm

230428001.led

0

5\System\DEFAULT.Isr

1

MEOH

MEOH

0:Unknown

CMS1 230328 537M.lcm

230428002.led

0

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428003.led

0

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428004.led

0

5\System\DEFAULT.Isr

3

L0.05ppb_230323

L0.05ppb_230323

1:Standard:(l)

CMS1 230328 537M.lcm

230428005.led

1

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428006.led

2

5\System\DEFAULT.Isr

5

L0.5ppb_230323

L0.5ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428007.led

3

5\System\DEFAULT.Isr

6

L1ppb_230323

L1ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428008.led

4

5\System\DEFAULT.Isr

7

L5ppb_230323

L5ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428009.led

5

5\System\DEFAULT.Isr

8

L10ppb_230323

L10ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428010.lcd

6

5\System\DEFAULT.Isr

131

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD.Icb

-------
10/24/2023 3:16:28 PM Page 2 / 5

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

9

L15ppb_230323

L15ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428011.led

7

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428012.led

0

5\System\DEFAULT.Isr

10

Branched Mix 230117

Branched Mix 230117

3:Unspiked

CMS1 230328 537M.lcm

230428013.lcd

0

5\System\DEFAULT.Isr

11

ICV1-230428

ICV1-230428

2:Control

CMS1 230328 537M.lcm

230428014.led

4

5\System\DEFAULT.Isr

11

ICV1-230428

ICV1-230428

2:Control

CMS1 230328 537M.lcm

230428015.lcd

4

5\System\DEFAULT.Isr

28

MBLK-215157

MBLK-215157

0:Unknown

CMS1 230328 537M.lcm

230428016.led

0

5\System\DEFAULT.Isr

29

LCS-215157

LCS-215157

0:Unknown

CMS1 230328 537M.lcm

230428017.led

0

5\System\DEFAULT.Isr

16

CCV2-230428

CCV2-230428

2:Control

CMS1 230328 537M.lcm

230428018.lcd

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428019.lcd

0

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428020.led

0

5\System\DEFAULT.Isr

3

L0.05ppb_230323

L0.05ppb_230323

1:Standard:(l)

CMS1 230328 537M.lcm

230428021.led

1

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428022.led

2

5\System\DEFAULT.Isr

5

L0.5ppb_230323

L0.5ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428023.led

3

5\System\DEFAULT.Isr

6

L1ppb_230323

L1ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428024.led

4

5\System\DEFAULT.Isr

7

L5ppb_230323

L5ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428025.led

5

5\System\DEFAULT.Isr

8

L10ppb_230323

L10ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428026.led

6

5\System\DEFAULT.Isr

9

L15ppb_230323

L15ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428027.led

7

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428028.led

0

5\System\DEFAULT.Isr

10

Branched Mix 230117

Branched Mix 230117

3:Unspiked

CMS1 230328 537M.lcm

230428029.led

0

5\System\DEFAULT.Isr

11

ICV1-230428

ICV1-230428

2:Control

CMS1 230328 537M.lcm

230428030.led

4

5\System\DEFAULT.Isr

11

ICV1-230428

ICV1-230428

2:Control

CMS1 230328 537M.lcm

230428031.led

4

5\System\DEFAULT.Isr

28

MBLK-215211

MBLK-215211

0:Unknown

CMS1 230328 537M.lcm

230428032.led

0

5\System\DEFAULT.Isr

29

LCS-215211

LCS-215211

0:Unknown

CMS1 230328 537M.lcm

230428033.led

0

5\System\DEFAULT.Isr

1

MBLK-215251

MBLK-215251

0:Unknown

CMS1 230328 537M.lcm

230428034.led

0

5\System\DEFAULT.Isr

2

LCS-215251

LCS-215251

0:Unknown

CMS1 230328 537M.lcm

230428035.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230428036.led

2

5\System\DEFAULT.Isr

16

CCV2-230428

CCV2-230428

2:Control

CMS1 230328 537M.lcm

230428037.led

5

5\System\DEFAULT.Isr

16

CCV2-230428

CCV2-230428

2:Control

CMS1 230328 537M.lcm

230428038.led

5

5\System\DEFAULT.Isr

51

23041931-02D

23041931-02D

0:Unknown

CMS1 230328 537M.lcm

230428039.led

0

5\System\DEFAULT.Isr

52

23041944-01F

23041944-01F

0:Unknown

CMS1 230328 537M.lcm

230428040.led

0

5\System\DEFAULT.Isr

20

23042199-14A

23042199-14A

0:Unknown

CMS1 230328 537M.lcm

230428041.led

0

5\System\DEFAULT.Isr

21

23042199-15A

23042199-15A

0:Unknown

CMS1 230328 537M.lcm

230428042.led

0

5\System\DEFAULT.Isr

22

23042199-19A

23042199-19A

0:Unknown

CMS1 230328 537M.lcm

230428043.led

0

5\System\DEFAULT.Isr

23

23042199-22A

23042199-22A

0:Unknown

CMS1 230328 537M.lcm

230428044.led

0

5\System\DEFAULT.Isr

24

23042199-26A

23042199-26A

0:Unknown

CMS1 230328 537M.lcm

230428045.led

0

5\System\DEFAULT.Isr

30

23041906-04A MS

23041906-04A MS

0:Unknown

CMS1 230328 537M.lcm

230428046.led

0

5\System\DEFAULT.Isr

31

23041906-08ADUP

23041906-08ADUP

0:Unknown

CMS1 230328 537M.lcm

230428047.led

0

5\System\DEFAULT.Isr

32

23041811-01A

23041811-01A

0:Unknown

CMS1 230328 537M.lcm

230428048.led

0

5\System\DEFAULT.Isr

33

23041811-02A

23041811-02A

0:Unknown

CMS1 230328 537M.lcm

230428049.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230428050.led

2

5\System\DEFAULT.Isr

16

CCV3-230428

CCV3-230428

2:Control

CMS1 230328 537M.lcm

230428051.led

5

5\System\DEFAULT.Isr

132

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD.Icb

-------
10/24/2023 3:16:28 PM Page 3 / 5

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

16

CCV3-230428

CCV3-230428

2:Control

CMS1 230328 537M.lcm

230428052.led

5

5\System\DEFAULT.Isr

34

23042036-01G

23042036-01G

0:Unknown

CMS1 230328 537M.lcm

230428053.led

0

5\System\DEFAULT.Isr

35

23042036-05A

23042036-05A

0:Unknown

CMS1 230328 537M.lcm

230428054.led

0

5\System\DEFAULT.Isr

36

23042036-06A

23042036-06A

0:Unknown

CMS1 230328 537M.lcm

230428055.led

0

5\System\DEFAULT.Isr

37

23042152-01A

23042152-01A

0:Unknown

CMS1 230328 537M.lcm

230428056.led

0

5\System\DEFAULT.Isr

38

23042152-02A

23042152-02A

0:Unknown

CMS1 230328 537M.lcm

230428057.led

0

5\System\DEFAULT.Isr

39

23042199-30A

23042199-30A

0:Unknown

CMS1 230328 537M.lcm

230428058.led

0

5\System\DEFAULT.Isr

40

23042199-34A

23042199-34A

0:Unknown

CMS1 230328 537M.lcm

230428059.led

0

5\System\DEFAULT.Isr

41

23042199-38A

23042199-38A

0:Unknown

CMS1 230328 537M.lcm

230428060.led

0

5\System\DEFAULT.Isr

42

23042199-40A

23042199-40A

0:Unknown

CMS1 230328 537M.lcm

230428061.led

0

5\System\DEFAULT.Isr

43

23042199-41A

23042199-41A

0:Unknown

CMS1 230328 537M.lcm

230428062.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230428063.led

2

5\System\DEFAULT.Isr

16

CCV4-230428

CCV4-230428

2:Control

CMS1 230328 537M.lcm

230428064.led

5

5\System\DEFAULT.Isr

16

CCV4-230428

CCV4-230428

2:Control

CMS1 230328 537M.lcm

230428065.led

5

5\System\DEFAULT.Isr

44

23042199-42A

23042199-42A

0:Unknown

CMS1 230328 537M.lcm

230428066.led

0

5\System\DEFAULT.Isr

45

23042199-43A

23042199-43A

0:Unknown

CMS1 230328 537M.lcm

230428067.led

0

5\System\DEFAULT.Isr

46

23042199-44A

23042199-44A

0:Unknown

CMS1 230328 537M.lcm

230428068.led

0

5\System\DEFAULT.Isr

47

23042222-01A

23042222-01A

0:Unknown

CMS1 230328 537M.lcm

230428069.led

0

5\System\DEFAULT.Isr

48

23042232-01C

23042232-01C

0:Unknown

CMS1 230328 537M.lcm

230428070.led

0

5\System\DEFAULT.Isr

49

23042232-02A

23042232-02A

0:Unknown

CMS1 230328 537M.lcm

230428071.led

0

5\System\DEFAULT.Isr

50

23042243-01F

23042243-01F

0:Unknown

CMS1 230328 537M.lcm

230428072.led

0

5\System\DEFAULT.Isr

51

23042289-01A

23042289-01A

0:Unknown

CMS1 230328 537M.lcm

230428073.led

0

5\System\DEFAULT.Isr

30

23042199-07A MS

23042199-07A MS

0:Unknown

CMS1 230328 537M.lcm

230428074.led

0

5\System\DEFAULT.Isr

31

23042199-07AMSD

23042199-07AMSD

0:Unknown

CMS1 230328 537M.lcm

230428075.led

0

5\System\DEFAULT.Isr

32

23042199-07A

23042199-07A

0:Unknown

CMS1 230328 537M.lcm

230428076.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230428077.led

2

5\System\DEFAULT.Isr

16

CCV5-230428

CCV5-230428

2:Control

CMS1 230328 537M.lcm

230428078.led

5

5\System\DEFAULT.Isr

16

CCV5-230428

CCV5-230428

2:Control

CMS1 230328 537M.lcm

230428079.led

5

5\System\DEFAULT.Isr

33

23042040-23A

23042040-23A

0:Unknown

CMS1 230328 537M.lcm

230428080.led

0

5\System\DEFAULT.Isr

34

23042040-24A

23042040-24A

0:Unknown

CMS1 230328 537M.lcm

230428081.led

0

5\System\DEFAULT.Isr

35

23042040-25A

23042040-25A

0:Unknown

CMS1 230328 537M.lcm

230428082.led

0

5\System\DEFAULT.Isr

36

23042040-26A

23042040-26A

0:Unknown

CMS1 230328 537M.lcm

230428083.led

0

5\System\DEFAULT.Isr

37

23042040-29A

23042040-29A

0:Unknown

CMS1 230328 537M.lcm

230428084.led

0

5\System\DEFAULT.Isr

38

23042040-30A

23042040-30A

0:Unknown

CMS1 230328 537M.lcm

230428085.led

0

5\System\DEFAULT.Isr

39

23042199-02A

23042199-02A

0:Unknown

CMS1 230328 537M.lcm

230428086.led

0

5\System\DEFAULT.Isr

40

23042199-03A

23042199-03A

0:Unknown

CMS1 230328 537M.lcm

230428087.led

0

5\System\DEFAULT.Isr

41

23042199-04A

23042199-04A

0:Unknown

CMS1 230328 537M.lcm

230428088.led

0

5\System\DEFAULT.Isr

42

23042199-06A

23042199-06A

0:Unknown

CMS1 230328 537M.lcm

230428089.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230428090.led

2

5\System\DEFAULT.Isr

16

CCV6-230428

CCV6-230428

2:Control

CMS1 230328 537M.lcm

230428091.led

5

5\System\DEFAULT.Isr

16

CCV6-230428

CCV6-230428

2:Control

CMS1 230328 537M.lcm

230428092.led

5

5\System\DEFAULT.Isr

133

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD.Icb

-------
10/24/2023 3:16:28 PM Page 4 / 5

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

43

23042199-08A

23042199-08A

0:Unknown

CMS1 230328 537M.lcm

230428093.led

0

5\System\DEFAULT.Isr

44

23042199-1 OA

23042199-1 OA

0:Unknown

CMS1 230328 537M.lcm

230428094.led

0

5\System\DEFAULT.Isr

45

23042199-11A

23042199-11A

0:Unknown

CMS1 230328 537M.lcm

230428095.led

0

5\System\DEFAULT.Isr

46

23042199-12A

23042199-12A

0:Unknown

CMS1 230328 537M.lcm

230428096.led

0

5\System\DEFAULT.Isr

47

23042199-13A

23042199-13A

0:Unknown

CMS1 230328 537M.lcm

230428097.led

0

5\System\DEFAULT.Isr

48

23042199-16A

23042199-16A

0:Unknown

CMS1 230328 537M.lcm

230428098.led

0

5\System\DEFAULT.Isr

49

23042199-17A

23042199-17A

0:Unknown

CMS1 230328 537M.lcm

230428099.led

0

5\System\DEFAULT.Isr

50

23042199-18A

23042199-18A

0:Unknown

CMS1 230328 537M.lcm

2304281 OO.Icd

0

5\System\DEFAULT.Isr

51

23042199-20A

23042199-20A

0:Unknown

CMS1 230328 537M.lcm

230428101.led

0

5\System\DEFAULT.Isr

3

23042199-21A MS

23042199-21A MS

0:Unknown

CMS1 230328 537M.lcm

230428102.lcd

0

5\System\DEFAULT.Isr

4

23042199-21A MSD

23042199-21A MSD

0:Unknown

CMS1 230328 537M.lcm

230428103.lcd

0

5\System\DEFAULT.Isr

5

23042199-21A

23042199-21A

0:Unknown

CMS1 230328 537M.lcm

230428104.lcd

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230428105.lcd

2

5\System\DEFAULT.Isr

16

CCV7-230428

CCV7-230428

2:Control

CMS1 230328 537M.lcm

230428106.lcd

5

5\System\DEFAULT.Isr

16

CCV7-230428

CCV7-230428

2:Control

CMS1 230328 537M.lcm

230428107.lcd

5

5\System\DEFAULT.Isr

6

23042199-23A

23042199-23A

0:Unknown

CMS1 230328 537M.lcm

230428108.lcd

0

5\System\DEFAULT.Isr

7

23042199-24A

23042199-24A

0:Unknown

CMS1 230328 537M.lcm

230428109.lcd

0

5\System\DEFAULT.Isr

8

23042199-25A

23042199-25A

0:Unknown

CMS1 230328 537M.lcm

230428110.led

0

5\System\DEFAULT.Isr

9

23042199-27A

23042199-27A

0:Unknown

CMS1 230328 537M.lcm

230428111.led

0

5\System\DEFAULT.Isr

10

23042199-28A

23042199-28A

0:Unknown

CMS1 230328 537M.lcm

230428112.led

0

5\System\DEFAULT.Isr

11

23042199-29A

23042199-29A

0:Unknown

CMS1 230328 537M.lcm

230428113.led

0

5\System\DEFAULT.Isr

12

23042199-31A

23042199-31A

0:Unknown

CMS1 230328 537M.lcm

230428114.led

0

5\System\DEFAULT.Isr

13

23042199-32A

23042199-32A

0:Unknown

CMS1 230328 537M.lcm

230428115.led

0

5\System\DEFAULT.Isr

14

23042199-33A

23042199-33A

0:Unknown

CMS1 230328 537M.lcm

230428116.led

0

5\System\DEFAULT.Isr

15

23042199-35A

23042199-35A

0:Unknown

CMS1 230328 537M.lcm

230428117.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230428118.led

2

5\System\DEFAULT.Isr

16

CCV8-230428

CCV8-230428

2:Control

CMS1 230328 537M.lcm

230428119.led

5

5\System\DEFAULT.Isr

16

CCV8-230428

CCV8-230428

2:Control

CMS1 230328 537M.lcm

230428120.led

5

5\System\DEFAULT.Isr

25

23042199-05ADF10

23042199-05ADF10

0:Unknown

CMS1 230328 537M.lcm

230428121.led

0

5\System\DEFAULT.Isr

26

23042199-19ADF10

23042199-19ADF10

0:Unknown

CMS1 230328 537M.lcm

230428122.led

0

5\System\DEFAULT.Isr

27

23042199-22ADF10

23042199-22ADF10

0:Unknown

CMS1 230328 537M.lcm

230428123.led

0

5\System\DEFAULT.Isr

54

23042199-26ADF10

23042199-26ADF10

0:Unknown

CMS1 230328 537M.lcm

230428124.led

0

5\System\DEFAULT.Isr

16

23042199-36A

23042199-36A

0:Unknown

CMS1 230328 537M.lcm

230428125.led

0

5\System\DEFAULT.Isr

17

23042199-37A

23042199-37A

0:Unknown

CMS1 230328 537M.lcm

230428126.led

0

5\System\DEFAULT.Isr

18

23042199-39A

23042199-39A

0:Unknown

CMS1 230328 537M.lcm

230428127.led

0

5\System\DEFAULT.Isr

19

23042199-45A

23042199-45A

0:Unknown

CMS1 230328 537M.lcm

230428128.led

0

5\System\DEFAULT.Isr

20

23042329-01A

23042329-01A

0:Unknown

CMS1 230328 537M.lcm

230428129.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230428130.lcd

2

5\System\DEFAULT.Isr

16

CCV9-230428

CCV9-230428

2:Control

CMS1 230328 537M.lcm

230428131.led

5

5\System\DEFAULT.Isr

16

CCV9-230428

CCV9-230428

2:Control

CMS1 230328 537M.lcm

230428132.lcd

5

5\System\DEFAULT.Isr

1

MEOH

MEOH

0:Unknown

CMS1 230328 537M.lcm

230428133.lcd

0

5\System\DEFAULT.Isr

134

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD.Icb

-------
10/24/2023 3:16:28 PM Page 5 / 5

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

1

MEOH

MEOH

0:Unknown

CMS1 230328 537M.lcm

230428134.lcd

0

5\System\DEFAULT.Isr

135

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD.Icb

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:38

ICV1-230428

Sample ID: ICV1-230428

Date Acquired: 4/28/2023 9:15:10 PM

Acquired by: System Administrator

Data File: 230428031

Vial: 11 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.226

733593

733593

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.226

733593

1411986

13C7-PFUnDA IS

5.0000

4.8975

ng/mL

PFBA

Auto

4.226

182012

733593

13C-PFBA IS

1.0000

1.1097

nq/mL

13C-PFPeA IS

Auto

5.397

1201838

1201838

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.397

1201838

1411986

13C7-PFUnDA IS

5.0000

4.9941

nq/mL

PFPeA

Auto

5.398

238107

1201838

13C-PFPeA IS

1.0000

1.0760

ng/mL

13C-PFBS IS

Auto

5.526

485950

485950

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.526

485950

1411986

13C7-PFUnDA IS

4.6500

4.6017

ng/mL

PFBS

Auto

5.526

72046

485950

13C-PFBS IS

0.8840

0.9550

nq/mL

13C HFPO DA IS

Auto

6.134

254238

254238

	

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.134

254238

1411986

13C7-PFUnDA IS

5.0000

4.8652

nq/mL

HFPO DA

Auto

6.136

43476

254238

13C HFPO DA IS

1.0000

1.1691

nq/mL

13C-4 2-FTS IS

Auto

5.937

203147

203147

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.937

203147

1411986

13C7-PFUnDA IS

4.6700

4.3017

ng/mL

4-2-FtS

Auto

5.936

56077

203147

13C-4 2-FTS IS

0.9340

1.1634

nq/mL

PFHxA

Auto

5.990

469354

1617577

13C-PFHxA IS

1.0000

1.0920

ng/mL

13C-PFHxA IS

Auto

5.990

1617577

1617577

	

5.0000

5.0000

i

13C-PFHxA

Auto

5.990

1617577

1411986

13C7-PFUnDA IS

5.0000

4.9472

ng/mL

PFPeS

Auto

6.027

77007

492505

180-PFHxS IS

0.9380

1.1099

nq/mL

PFHxS

Auto

6.401

58963

492505

180-PFHxS IS

0.9100

0.9420

ng/mL

13C-PFHpA IS

Auto

6.398

1575204

1575204

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.398

1575204

1411986

13C7-PFUnDA IS

5.0000

4.9593

ng/mL

180-PFHxS IS

Auto

6.401

492505

492505

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.401

492505

1411986

13C7-PFUnDAJS

4.7250

4.6474

ng/mL

PFHpA

Auto

6.398

509688

1575204

13C-PFHpA IS

1.0000

1.0848

ng/mL

13C2-6 2-FTS IS

Auto

6.703

209779

209779

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.703

209779

1411986

13C7-PFUnDA IS

4.7500

4.2406

ng/mL

PFHpS

Auto

6.709

76576

492505

180-PFHxS IS

0.9520

1.0230

ng/mL

6-2-FTS

Auto

6.704

49544

209779

13C2-6 2-FTS IS

0.9480

1.1883

nq/mL

PFOA

Auto

6.720

603832

1931401

13C-PFOA IS

1.0000

1.1501

ng/mL

13C-PFOA IS

Auto

6.721

1931401

1931401

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.721

1931401

1411986

13C7-PFUnDA IS

5.0000

4.8915

ng/mL

PFOS

Auto

7.020

53975

495860

13C-PFOS IS

0.9280

1.0450

nq/mL

13C-PFOS IS

Auto

7.020

495860

495860

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

7.020

495860

1411986

13C7-PFUnDA IS

4.7750

4.6607

nq/mL

PFNA

Auto

7.046

473614

1680659

13C-PFNA IS

1.0000

1.1803

ng/mL

13C-PFNA IS

Auto

7.046

1680659

1680659

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.046

1680659

1411986

13C7-PFUnDA IS

5.0000

4.7890

ng/mL

PFNS

Auto

7.359

128594

495860

13C-PFOS IS

0.9600

1.0833

nq/mL

8-2-FTS

Auto

7.393

28977

103662

13C-8 2-FTS IS

0.9580

1.1561

ng/mL

13C-8 2-FTS IS

Auto

7.393

103662

103662

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.393

103662

1411986

13C7-PFUnDA IS

4.7900

4.4481

ng/mL

PFDA

Auto

7.395

413312

1977081

13C-PFDA IS

1.0000

1.1039

nq/mL

13C-PFDA IS

Auto

7.396

1977081

1977081

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.396

1977081

1411986

13C7-PFUnDA IS

5.0000

4.9764

nq/mL

d3-N-MeFOSAA IS

Auto

7.580

551513

551513

	

5.0000

5.0000

nq/mL

d3-N-MeFOSAA

Auto

7.580

551513

1411986

13C7-PFUnDA IS

5.0000

4.7610

nq/mL

NMeFOSAA

Auto

7.585

103110

551513

d3-N-MeFOSAA IS

1.0000

0.9420

nq/mL

PFDS

Auto

7.710

90886

495860

13C-PFOS IS

0.9640

1.0388

nq/mL

13C-PFUnDA IS

Auto

7.756

1721537

1721537

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.756

1721537

1411986

13C7-PFUnDA IS

5.0000

4.9237

nq/mL

PFUnDA

Auto

7.757

374552

1721537

13C-PFUnDA IS

1.0000

1.1114

nq/mL

d5-N-EtFOSAA IS

Auto

7.772

597156

597156

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.772

597156

1411986

13C7-PFUnDA IS

5.0000

4.8349

nq/mL

NEtFOSAA

Auto

7.779

121739

597156

dS-N-EtFOSAA IS

1.0000

1.0306

nq/mL

PFOSA

Auto

7.742

114203

440722

13C-FOSA IS

1.0000

1.2093

nq/mL

13C-FOSA IS

Auto

7.743

440722

440722

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.743

440722

1411986

13C7-PFUnDA IS

5.0000

4.7420

nq/mL

PFDoA

Auto

8.109

422917

1691282

13C-PFDoA IS

1.0000

1.1192

nq/mL

13C-PFDoA IS

Auto

8.109

1691282

1691282

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

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Printed 10/24/2023 15:25:38

ICV1 -230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.109

1691282

1411986

13C7-PFUnDA IS

5.0000

4.9315

nq/mL

10-2-FtS

Auto

8.123

30480

103662

13C-8 2-FTS IS

0.9640

1.1575

ng/mL

d5-NEtFOSA IS

Auto

8.778

451642

451642

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.778

451642

1411986

13C7-PFUnDA IS

5.0000

4.7429

ng/mL

NMeFOSE

Auto

8.501

39903

227255

d7-N-MeFOSE IS

1.0000

1.0753

nq/mL

NEtFOSE

Auto

8.753

131634

134548

d9-EtFOSE IS

1.0000

0.9862

ng/mL

d9-EtFOSE IS

Auto

8.734

134548

134548

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.734

134548

1411986

13C7-PFUnDA IS

5.0000

4.9473

ng/mL

NMeFOSA

Auto

8.524

35487

414462

d3-NMeFOSA IS

1.0000

0.9293

nq/mL

dB-NMeFOSA IS

Auto

8.519

414462

414462

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.519

414462

1411986

13C7-PFUnDA IS

5.0000

4.8137

nq/mL

d7-N-MeFOSE IS

Auto

8.485

227255

227255

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.485

227255

1411986

13C7-PFUnDA IS

5.0000

4.7099

nq/mL

NEtFOSA

Auto

8.788

69683

451642

d5-NEtFOSA IS

1.0000

1.0517

ng/mL

PFTrDA

Auto

8.440

365999

1167552

13C-PFTeDA IS

1.0000

1.0319

nq/mL

PFTeDA

Auto

8.745

435924

1167552

13C-PFTeDA IS

1.0000

1.0428

ng/mL

13C-PFTeDA IS

Auto

8.744

1167552

1167552

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.744

1167552

1411986

13C7-PFUnDA IS

5.0000

5.1756

ng/mL

11CI-PFBOUdS

Auto

7.906

113233

495860

13C-PFOS IS

0.9420

0.9966

nq/mL

9CI-PF30NS

Auto

7.208

260773

495860

13C-PFOS IS

0.9320

1.0653

ng/mL

L-PFDoS

Auto

8.382

36657

495860

13C-PFOS IS

0.9680

1.1095

nq/mL

NaDONA

Auto

6.441

386349

1680659

13C-PFNA IS

0.9420

1.0891

ng/mL

PFHxDA

Auto

9.278

306334

3447618

13C2-PFHxDA IS

1.0000

1.0995

nq/mL

PFODA

Auto

9.899

190659

3447618

13C2-PFHxDA IS

1.0000

1.0835

ng/mL

1BC2-PFHxDA IS

Auto

9.278

3447618

3447618

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.278

3447618

1411986

13C7-PFUnDA IS

5.0000

4.8235

ng/mL

13C7-PFUnDA IS

Auto

7.756

1411986

1411986

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.665

385237

495860

13C-PFOS IS

0.9200

0.8560

ng/mL

PFBSA

Auto

6.134

260261

440722

13C-FOSA IS

1.0000

1.1332

nq/mL

PFHxSA

Auto

6.957

234519

1680659

13C-PFNA IS

1.0000

1.1299

ng/mL

CHARGE

ND(W/B)

	

	

1411986

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

1.5e5-

O.OeO

13C-PFBA

Cone. 4.8975
Q 217.20> 172.30 (-)

1.5e5 -

O.OeO -tjf

PFBA

Cone. 1.1097
1.57e5 Q 213.20> 169.10 (-)

4.0e4 n

13C-PFPeA IS

Cone. 5.0000
4.00e4 ISTD 267.90>223.00 (-)

O.OeO

4.00 4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS

Cone. 1.0760	Cone. 4.6500	Cone. 4.6017

4.00 4.25 4.50

RT (min)

8.28e4 ISTD 301.80>80.00 (-)

1.71e5 Q 301.80>80.00 (-)

r A=485950
RT= 5.526

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

r A=485950
| RT= 5.526

5.6 5.8
RT (min)

13C-PFPeA

Cone. 4.9941
4.56e5 Q 267.90>223.00 (-)

A=1201838
RT= 5.397

O.OeO -

f A=1201838
RT= 5.397

O.OeO -

5.6	5.2 5.4 5.6

RT (min)	RT (min)

PFBS	13C HFPO DAJS

Cone. 0.9550	Cone. 5.0000
R#1 298.80>99.00 65.60 (65.16)

1.71e5 Q 299.00>80.00 (-) 2.56e4	ISTD 332.10>287.10 (-)	1.03e5

fA=72046

I R1 6560 (—I)RT= 5.526

1.0e5-

r A=254238
RT=6.134

5.6 5.8
RT (min)

5.6 5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

137

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A

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:38

ICV1 -230428 (continued)

13C HFPO DA

Cone. 4.8652

Q 332.10>287.10 (-)
1.0e5 H

HFPO DA

Cone. 1.1691

R#1 329.00>285.10 78.44 (80.83)
Q 329.00>169.00 (-)	1.71e4

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 27.10 (27.58)

ISTD 329.00>309.15 (-)	7.97e4

13C-4 2-FTS

Cone. 4.3017

R#1 329.00>81.00 27.10 (27.58)
Q 329.00>309.15 (-)	7.97e4

A=203147

7.5e4HRl 27.10 (—§rj= 5.937

4-2-FtS

Cone. 1.1634

R#1 327.00 >81.10 12.70 (16.09)
Q 327.00>307.05 (-)	2.18e4

[A= 56077

2.0e4HR1 12.70 (— | rj= 5.936

O.OeO

6.2 6.4
RT (min)

PFHxA

Cone. 1.0920

R#1 313.00> 119.10 1.93 (2.51)
Q 313.00>269.00 (-)	1.90e5

O.OeO

6.0 6.2
RT (min)

PFHxS

Cone. 0.9420

R#1 399.00>99.00 94.03 (85.33)
Q 399.00>80.00 (-)	2.10e4

fA= 58963

2.0e4-R1 94.03 (- RT=6.401

13C-PFHpA IS

Cone. 5.0000

I STD 366.90 >322.10 (-)

6.87e5 Q 366.90>322.10 (-)

TA= 1575204
RT=6.398

I STD 402.70>84.05 (-)
2.0e5 -

A=492505
RT=6.401

180-PFHxS

Cone. 4.6474

Q 402.70>84.05 (-)
2.0e5 -

A=492505
RT=6.401

O.OeO -

6.6

RT (min)

6.2

6.4

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

13C2-6 2-FTS

Cone. 4.2406

8.57e4 Q 428.90>409.00 (-)

6.6
RT (min)

PFHpS

Cone. 1.0230

R#1 449.00>99.20 61.48 (66.50)

O.OeO

6.6
RT (min)

PFHpA

Cone. 1.0848

R#1 362.90 >169.00 17.77 (17.91)
Q 362.90>319.00 (-)	2.17e5

[A= 509688
2.0e5 —IR1 17.77 (—| rj=6.398

O.OeO

6.6
RT (min)

6-2-FTS

Cone. 1.1883

R#1 427.00>80.90 26.35 (33.45)

O.OeO -

6.2

6.4

6.6
RT (min)

PFOA

Cone. 1.1501

R#1 413.00> 169.10 28.19 (27.85)

8.57e4 Q 449.00>80.15 (-)

3.36e4 Q 427.00>407.00 (-)

2.04e4 Q 413.00>369.00 (-)

2.57e5

r A=209779
RT=6.703

fA=76576

3.0e4^R1 6148 (—"J RT=6.709
2.0e4 :

1.0e4:

O.OeO :

O.OeO

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

13C-PFOA

Cone. 4.8915

6.6 6.8

RT (min)

PFOS

Cone. 1.0450
R#1 499.00>99.00 94.63 (86.07)

Q 499.00>80.00 (-)	1.60e4 ISTD 502.

13C-PFOS IS

Cone. 4.7750

A= 53975

1.5e4HR1 94.63 (-—J rj=7.020

105 (-)

2.0e5

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

2.05e5 Q 502.80>80.05 (-)
2.0e5 H

A=495860
RT=7.020

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

138

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)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:38

ICV1 -230428 (continued)

PFNA	13C-PFNA IS

Cone. 1.1803	Cone. 5.0000
R#1 463.00>219.00 19.39 (24.00)

Q 463.00>418.90 (-)	2.00e5	ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 4.7890

7.05e5 Q 467.80>423.00 (-)

2.0e5 -

- R1 19.39 (—-

A=473614
RT=7.046

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)
4.0e41

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)
2.0e5 -

A=551513
RT=7.580

13C-PFUnDA

Cone. 4.9237

A=1680659
RT=7.046

7.2

RT (min)

13C-8 2-FTS

Cone. 4.4481

4.10e4 Q 528.80> 509.00 (-)
4.0e41

d3-N-MeFOSAA

Cone. 4.7610

2.11e5 Q 572.80>419.05 (-)
2.0e5 -

fA=551513
I RT=7.580

O.OeO -

7.6 7.8
RT (min)

7.4

7.8 8.0
RT (min)

PFOSA

Cone. 1.2093

R#1 498.20>64.10 0.32 (0.09)
Q 498.20>78.00 (-)	4.59e4

r A= 114203
4.0e4-|R1 032 1^=7.742

7.6 7.8 8.0

RT (min)

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

1.5e5 ^

1.0e5 ^

5.0e4 ^

O.OeO 1. .

PFNS

Cone. 1.0833

R#1 549.00 >99.00 60.33 (71.23)
Q 549.00>79.95 (-)	5.22e4

8-2-FTS

Cone. 1.1561

R#1 527.20>487.00 7.09 (6.74)
Q 527.10>506.90 (-)	1.14e4



TA= 1680659



A= 128594

TA=28977

6.0e5 -

RT=7.046 ;

R1 60.33 (—-

RT=7.359 1.0e4-

)|rT=7.393





i 4.0e4 -





i

4.0e5 -







i

I





I "

2.0e4 -



5.0e3 -

1

2.0e5 -



1 :





It

O.OeO



~

J

Jk*

JMiL?



i 1 1 1 'A

i i i i i i i i i O.OeO

i i | i iAi

—i—i—i—i—i—|—i— u.ucu

i i 1 i i Ai | i i i i | i i

6.8

7.0

7.2
RT (min)

PFDA

Cone. 1.1039

R#1 512.90>219.00 19.13 (17.51)
Q 512.90>469.00 (-)	1.66e5

A=41331?

1.5e5 -3^1 19-13 (—"1 RT=7.395

7.2

7.4

3.0e4 -
2.0e4 -
1.0e4-
O.OeO -

A=103110

R1 41.78 ( H RT=7.585

A= 10801
RT=7.477



7.6 7.8
RT (min)

PFUnDA

Cone. 1.1114

R#1 563.00>219.00 11.89 (13.86)
Q563.00>518.90 (-)	1.47e5

f A=374552

IR1 11.89 (—-I rt=7.757

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

13C-FOSA

Cone. 4.7420

1.78e5 Q 506.00>78.05 (-)

1.5e5 ^

1.0e5 ^

5.0e4 ^
== O.OeO 1. .

7.8 8.0

RT (min)

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 4.9764

ISTD 514.80>469.95 (-)
7.5e5-

A= 1977081
RT=7.396

7.6
RT (min)

NMeFOSAA

Cone. 0.9420

R#1 570.20 > 512.00 41.78 (37.68)
Q 570.20>419.00 (-)	3.87e4

Q 514.80>469.95 (-)
7.5e5 -

rA= 1977081
i RT=7.396

7.6
RT (min)

PFDS

Cone. 1.0388

R#1 599.00>99.00 62.29 (65.43)
Q 599.00>80.10 (-)	3.60e4

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 4.8349

2.38e5 Q 588.80>419.00 (-)

O.OeO -

7.8 8.0
RT (min)

7.6

7.8 8.0
RT (min)

PFDoA

Cone. 1.1192

R#1 613.05> 169.00 15.92 (16.16)
Q 613.05>569.00 (-)	1.73e5

7.8 8.0
RT (min)

NEtFOSAA

Cone. 1.0306

R#1 584.20>526.10 57.69 (58.21)
Q 584.20>418.95 (-)	3.98e4

TA= 121739

- R1 57.69 (	Ml RT=7.779

O.OeO

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

6.89e5

A=1691282
RT=8.109

7.8 8.0

RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

139

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:38

ICV1-230428 (continued)

13C-PFDoA

Cone. 4.9315

Q614.80>569.95 (-)

6.0e5 i
4.0e5 ^

2.0e5 ^

O.OeO 1. i i

fA= 1691282
l RT=8.109

NEtFOSE

Cone. 0.9862

Q 629.50>59.10 (-)

d3-NMeFOSA

Cone. 4.8137

Q 515.10> 169.00 (-)
1.5e5-
1.0e5-
5.0e4 -
O.OeO -

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

A=435924

R1 9.08 (-—-) RT=8.745

8.6

d5-NEtFOSA IS

Cone. 5.0000

10-2-FtS

Cone. 1.1575
R#1 626.50>81.05 56.25 (76.13)

6.89e5 Q 626.50>607.05 (-)	1.18e4 ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 4.7429

1.80e5 Q 531.10> 169.10 (-)

[A=30480

-R1 56.25 (—-I rt=8.123

RT (min)

RT (min)

9.0

RT (min)

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 4.9473

5.19e4 ISTD 638.90>59.10 (-)

5.22e4 Q 638.90> 59.10 (-)

9.0
RT (min)

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 1.0428

R#1 713.00 >169.30 9.08 (11.66)
Q 713.00>668.90 (-)	1.72e5



'

'A= 134548



'A= 134548





RT=8.734



RT=8.734

4.0e4 -



i 4.0e4 -





2.0e4 -



2.0e4 -







i

L

— 		 n HoH —

/

V,

U.UcU

I I I I A I

—i—|—i—i—i—i—|—i—r u.ueu

i i i i ~ i

i i i i i i i i i



8.6

o

cri

CO
CO

8.6

o

cri

CO
CO





RT (min)



RT (min)

d7-N

MeFOSEJS d7-N-

MeFOSE



Cone. 5.0000

Cone. 4.7099



ISTD 623.00>59.00 (-) 9.29e4 Q 623.00>59.00 (-)

9.29e4





fA=227255



'A=227255





RT=8.485



RT=8.485

7.5e4 ~



7.5e4 -





5.0e4 ~



S.0e4z_





2.5e4 ~

n —

!

J 2.5e4 z

	 	 n r\^r\ —

J

L .

u.ueu

i i i <4,1

—i—|—|—|—|—|—|—|— u.ueu

i i i A1

11111111



8.4

CO

CO
CO

8.4

CO

CO
CO





RT (min)



RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 5.1756

4.59e5 Q 714.80>669.80 (-)

.8 9.0
RT (min)

L-PFDoS

Cone. 1.1095

R#1 698.80>98.80 68.26 (71.85)
Q 698.80>80.10 (-)	1.46e4

IR1 68.26 (—-;

9.0
RT (min)

NaDONA

Cone. 1.0891

PFHxDA

Cone. 1.0995

8.4 8.6
RT (min)

1.67e5 Q 812.90>769.00 (-)

I R1 88.91 (-

11CI-PF30UdS

Cone. 0.9966

Q 631.00>451.10 (-)
4.0e4 -

2.0e4 -

A= 113233
RT=7.906

9.0
RT (min)

PFODA

Cone. 1.0835

1.28e5 Q 912.80>869.00 (-)

NMeFOSE

Cone. 1.0753

Q 616.10>58.90 (-)
1.5e4-

9.0
RT (min)

NMeFOSA

Cone. 0.9293

R#1 512.10>219.20 88.91 (76.94)
Q 512.10> 169.20 (-)	1.38e4

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)
1.5e5

O.OeO -

8.4 8.6

RT (min)

NEtFOSA

Cone. 1.0517

R#1 526.50>219.20 58.86 (67.00)
Q 526.50>169.10 (-)	2.71e4

I R1 58.86 (-

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 1.0319

R#1 663.10> 169.10 19.19 (20.38)
Q 663.10>618.90 (-)	1.47e5

fA=365999

IR1 19.19 (—-) I RT=8.440

9.0

RT (min)

8.6

RT (min)

9CI-PF30NS

Cone. 1.0653

Q 531.00>351.10 (-)
1.0e5-

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

6.13e4 ISTD 815.00>770.00 (-)

A=3447618 '
: RT=9.278

10.0

RT (min)

9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

140

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:38

ICV1 -230428 (continued)

13C2-PFHxDA

Cone. 4.8235

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

1.46e6 ISTD 569.80>524.90 (-)

PFecHS	PFBSA

Cone. 0.8560	Cone. 1.1332
R#1 461.00>99.10 35.37 (38.14)

5.52e5 Q 461.00>381.00 (-)	1.55e5	Q 298.00>78.00 (-)

A=3447618 ~
RT=9.278

O.OeO -



9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

fA= 1411986
RT=7.756

A=385237

R1 35.37 (—| rj=6.665

8.0
RT (min)

1.0e5-

RT (min)

PFHxSA

Cone. 1.1299

1.03e5 Q 397.90>78.00 (-)

7.5e4 i
5.0e4 i
2.5e4z_
~ O.OeO 1. . . .

fA=234519
I RT=6.957

6.4
RT (min)

7.2
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

140

-------
1st /S/AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/Integration
Printed 5/2/2023 11:28:58

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/28/2023 10:23:55 PM

Acquired by: System Administrator

Data File: 230428036

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.229

798102

798102

	 	

5.0000

ng/ml

13C-PFBA

Auto

4.229

798102

158

13C7-PFUn[

8.8701

nq/mL

PFBA

M

4.229

15441

798102

13C-PFBA IS

0.0865

ng/ml

13C-PFPeA IS

Auto

5.403

1095822

1095822

	 	

5.0000

ng/ml

13C-PFPeA

Auto

5.403

1095822

848158

13C7-PFllnDA IS

7.5806

ng/ml

PFPeA

Auto

5.403

20445

: ¦ 822

13C-PFPeA

0.1013

ng/ml

13C-PFBS IS

Auto

5.532

40

740

	 	

4.6500

ng/ml

13C-PFBS

Auto

5.532

'• ¦ 40

848158

13C7-PFUnDA IS

6.1441

ng/ml

PFBS

M

5.532

6047

389740

I k PFBS IS

0.0999

nq/mL

13C HFPO DA IS

Auto

6.139

213302

213302

	 	

5.0000

ng/ml

FPO DA

Auto

6.139

213302

848158

'Flint.'

6.7953

ng/ml

HFPO DA

Auto

6.138

99

213302

13C HFPO DA IS

0.1154

ng/ml

13C-4 2-FTS IS

Auto

5.941

45

203645

	 	

4.6700

ng/ml

13C-4 2-FTS

Auto

5.941

45

158

13C7-PFUn[

7.1789

ng/ml

4-2-FtS

Auto

5.941

4398

203645

13C-4 2-FTS IS

0.0910

ng/ml

PFHxA

Auto

395

38338

1526290

: :HxA

0.0945

ng/ml

13C-PFHxA IS

Auto

5.994

1526290

1526290

	

5.0000

ng/ml

13C-PFHxA

Auto

5.994

1526290

848158

13C7-PFUnDA IS

7.7712

ng/ml

PFPeS

Auto

6.038

5172

449342

180-PFHxS IS

0.0817

nq/mL

PFHxS

Auto

6.406

5342

449342

180-PFHxS IS

0.0935

ng/ml

13C-PFHpA IS

Auto

6.404

1459453

1459453

	 	

5.0000

ng/ml

13C-PFHpA

Auto

6.404

1459453

848158

13C7-PFUnDA IS

7.6494

ng/ml

kV PI H\s IS

Auto

6.407

449342

342

	 	

4.7250

ng/ml

180-PFHxS

Auto

6.407

449342

848158

13C7-PFUnDA IS

7.0587

nq/mL

PFHpA

Auto

6.403

41947

1459453

13C-PFHpA

0 0964

ng/ml

5 2-FTS IS

Auto

6.710

189814

189814

	

4.7500

ng/mL

2- F"

Auto

6.710

189814

848158

13C7-PFUnDA IS

6.3877

ng/ml



Auto

6.715

15

449342

180-PFHxS IS

0.0954

ng/ml

6-2-FTS

M

709

26

189814

13C2-6 2-FTS IS

0.0749

nq/mL

PFOA

Auto

6.726

76

1854042

13C-PFOA IS

0.1004

ng/ml

13C-PFOA IS

Auto

6.727

1854042

1854042

	 	

5.0000

iL

13C-PFOA

Auto

6.727

1854042

848158

13C7-PFUn[ .

7.8170

ng/ml

PFOS

Auto

7.025

4513

477307

13C-PFOS IS

0.0908

iL

FOS IS

Auto

7.026

477307

477307

	 	

4.7750

ng/ml

13C-PFOS

Auto

7.026

477307

848158

>FUn[

586

nq/mL

PFNA

Auto

7.052

28752

1558310

13C-PFNA IS

0.0773

nq/mL

13C-PFNA IS

Auto

7.052

1558310

1558310

	 	

5.0000

"1L

13C-PFNA

Auto

7.052

1558310

848158

13C7-PFUnDA IS

321

ng/mL

PFNS

Auto

7.364

9903

307

13C-PFOS IS

0.0867



8-2-FTS

Auto

7.405

902

87008

13C-8 2-FTS IS

0.0620

nq/mL

13C-8 2-FTS IS

Auto

7.399

87008

87008

	 	

4.7900

ng/mL

13C-8 2-FTS

Auto

7.399

87008

848158

13C7-PFUnDA IS

6.2153

ng/ml

PFDA

Auto

7.403

31664

141

13C-PFDA IS

0.1070

ng/mL

13C-PFDA IS

Auto

7.402

1562141

141

	 	

5.0000

ng/ml

13C-PFDA

Auto

7.402

1

848158

)A IS

6.5458

ng/mL

d3-N-MeFOSAA IS

Auto

7.588

485277

485277

	 	

^0000

ng/mL

d3-N-MeFOSAA

Auto

7.588

485277

848158

13C7-PFUnDA IS

6.9740

ng/mL

NMeFOSAA

M

7.594

35

277

d3-N-MeFOSAA IS

0.1000

ng/ml

PFDS

Auto

7.717

7102

477307

13C-PFOS IS

0.0843

ng/mL

13C-PFUnDA IS

Auto

7.763

1471390

1471390

	 	

5.0000

nq/mL

13
-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:28:58

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone.

Cone. Unit

10-2-FtS

Auto

8.127

655

87008

13C-8 2-FTS IS

0.0296

nq/mL

d5-NEtFOSA IS

Auto

8.784

468170

468170

—

5.0000

nq/mL

d5-NEtFOSA

Auto

8.784

468170

848158

13C7-PFUnDA IS

8.1848

nq/mL

NMeFOSE

Auto

8.507

3304

204157

d7-N-MeFOSE IS

0.0991

nq/mL

NEtFOSE

Auto

8.759

13202

144414

d9-EtFOSE IS

0.0922

nq/mL

d9-EtFOSE IS

Auto

8.740

144414

144414

—

5.0000

nq/mL

d9-EtFOSE

Auto

8.740

144414

848158

13C7-PFUnDA IS

8.8400

nq/mL

NMeFOSA

Auto

8.529

3226

425855

d3-NMeFOSA IS

0.0822

nq/mL

dB-NMeFOSA IS

Auto

8.525

425855

425855

—

5.0000

nq/mL

dB-NMeFOSA

Auto

8.525

425855

848158

13C7-PFUnDA IS

8.2340

nq/mL

d7-N-MeFOSE IS

Auto

8.491

204157

204157

—

5.0000

nq/mL

d7-N-MeFOSE

Auto

8.491

204157

848158

13C7-PFUnDA IS

7.0440

nq/mL

NEtFOSA

Auto

8.795

7299

468170

d5-NEtFOSA IS

0.1063

nq/mL

PFTrDA

Auto

8.444

17982

340710

13C-PFTeDA IS

0.1737

nq/mL

PFTeDA

Auto

8.750

28875

340710

13C-PFTeDA IS

0.2367

nq/mL

13C-PFTeDA IS

Auto

8.748

340710

340710

—

5.0000

nq/mL

13C-PFTeDA

Auto

8.748

340710

848158

13C7-PFUnDA IS

2.5143

nq/mL

11CI-PFBOUdS

Auto

7.914

9523

477307

13C-PFOS IS

0.0871

nq/mL

9CI-PFBONS

Auto

7.214

17886

477307

13C-PFOS IS

0.0759

nq/mL

L-PFDoS

Auto

8.382

2918

477307

13C-PFOS IS

0.0918

nq/mL

NaDONA

Auto

6.447

34394

1558310

13C-PFNA IS

0.1046

nq/mL

PFHxDA

Auto

9.282

7784

2974663

13C2-PFHxDA IS

-0.0086

nq/mL

PFODA

Auto

9.891

5353

2974663

13C2-PFHxDA IS

0.0353

nq/mL

13C2-PFHxDA IS

Auto

9.281

2974663

2974663

—

5.0000

nq/mL

13C2-PFHxDA

Auto

9.281

2974663

848158

13C7-PFUnDA IS

6.9284

nq/mL

13C7-PFUnDA IS

Auto

7.762

848158

848158

—

5.0000

nq/mL

PFecHS

Auto

6.672

33345

477307

13C-PFOS IS

0.0770

nq/mL

PFBSA

Auto

6.146

23911

434150

13C-FOSA IS

0.1057

nq/mL

PFHxSA

Auto

6.966

22380

1558310

13C-PFNA IS

0.1163

nq/mL

CHARGE

ND(W/B)

	

	

848158

13C7-PFUnDA IS

— 	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 8.8701
1.77e5 Q 217.20>172.30 (-)

O.OeO ~I=SC

Q263.05>219.10 (-)

PFBA

Cone. 0.0865
1.77e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
3.74e3 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 7.5806
4.24e5 Q 267.90>223.00 (-)

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 0.1013

4.0e5

A=1095822
RT= 5.403

O.OeO

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

O.OeO

7.45e3 I STD 301.80 > 80.00 (-)

fA=389740
RT= 5.532

4.0e5

A=1095822
RT= 5.403

O.OeO

4.00 4.25 4.50	5.2 5.4 5.6

RT (min)	RT (min)

13C-PFBS	PFBS

Cone. 6.1441	Cone. 0.0999

R#1 298.80>99.00 72.44(65.16)

1.39e5 Q 299.00>80.00 (-)	2.10e3 ISTD 332.10>287.10 (-)

13C HFPO DA IS

Cone. 5.0000

1.39e5 Q 301.80>80.00 (-)

fA=389740
RT= 5.532

~ A=6047

2.0e3^Ri 72.44 ( -)RT = 5,532

V*

5.6 5.8
RT (min)

5.6 5.8
RT (min)

7.5e4 -
5.0e4 ^
2.5e4 ^
O.OeO -

f A=213302
| RT=6.139

5.6 5.8
RT (min)

6.2 6.4
RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MODJ\JewCal.iproc

14*6

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:28:58

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 6.7953

Q 332.10>287.10 (-)

HFPO DA

Cone. 0.1154

R#1 329.00>285.10 100.68 (80.83)
Q 329.00>169.00 (-)	1.39e3

"R1 100.68 (--'-^=3599
| RT=6.138

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 25.65 (27.58)

ISTD 329.00>309.15 (-)	8.20e4

fA=203645
7.5e4-R1 25.65 (—-| rt=5.941

6.2 6.4
RT (min)

PFHxA

Cone. 0.0945

R#1 313.00> 119.10 0.33 (2.51)
Q 313.00>269.00 (-)	1.61e4

fA=38338
1.5e4-R1 0.33 (—-)| rj= 5.995

6.2 6.4
RT (min)

13C-PFHxA IS

Cone. 5.0000

I STD 314.90 >270.10 (-)
6.0e5 H

13C-PFHxA

Cone. 7.7712

Q 314.90>270.10 (-)

*=1526290
RT= 5.994

6.6

RT (min)

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

13C2-6 2-FTS

Cone. 6.3877

7.58e4 Q 428.90>409.00 (-)

A=189814
RT=6.710

O.OeO -

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
7.5e5 -

13C-PFOA

Cone. 7.8170

Q 416.80>372.05 (-)

RT (min)

rA= 1854042
RT=6.727

AW

6.8 7.0
RT (min)

13C-4 2-FTS

Cone. 7.1789

R#1 329.00>81.00 25.65 (27.58)
Q 329.00>309.15 (-)	8.20e4

fA=203645
7.5e4- R1 25.65 (-H) rt= 5.941

4-2-FtS

Cone. 0.0910

R#1 327.00 >81.10 8.89 (16.09)
Q 327.00>307.05 (-)	1.94e3

f A=4398

-R1 8.89 (-—)!. rj= 5.941

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 0.0817

R#1 349.00>99.00 103.63 (77.24)
Q 349.00>79.95 (-)	2.09e3

n

CO

™ p
T- (X)

<^_	

: J

/\

O.OeO

6.0 6.2
RT (min)

PFHxS

Cone. 0.0935

R#1 399.00>99.00 100.80 (85.33)
Q 399.00>80.00 (-)	1.86e3

f A=5342

:R1 100.80 (-|rkr=6.406

6.2

RT (min)

180-PFHxS

Cone. 7.0587

Q 402.70>84.05 (-)

f A=449342
I RT=6.407

6.6
RT (min)

PFHpA

Cone. 0.0964

R#1 362.90 >169.00 15.89 (17.91)
Q 362.90>319.00 (-)	1.77e4

f A=41947

R1 15.89 (—¦4 rt=6.403

6.4 6.6

RT (min)

PFHpS

Cone. 0.0954

R#1 449.00>99.20 64.36 (66.50)
Q 449.00>80.15 (-)	2.74e3

i A=6515

IR1 64.36 (-—I rt=6.715

O.OeO

6.4 6.6

RT (min)

6-2-FTS

Cone. 0.0749

R#1 427.00>80.90 50.94 (33.45)
Q 427.00>407.00 (-)	1.27e3

i A=2826

: R1 50.94 (-—J rt=6.709

6.6
RT (min)

PFOA

Cone. 0.1004

R#1 413.00> 169.10 29.38 (27.85)
Q 413.00>369.00 (-)	2.11e4

*A= 50576

2.0e4-Rl 29.38 (--) rT=6.726

6.6 6.8

RT (min)

PFOS

Cone. 0.0908

R#1 499.00>99.00 82.68 (86.07)
Q 499.00>80.00 (-)	1.39e3

f A=4513

;R1 82.68 (—-) rj=7.025

RT (min)

13C-PFOS IS

Cone. 4.7750

13C-PFOS

Cone. 7.4686

105 (-)

1.98e5 Q 502.80>80.05 (-)

f A=477307
RT=7.026

6.8 7.0
RT (min)

A=477307
RT=7.026

6.75 7.00 7.25

RT (min)

7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

14®

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:28:58

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0773

R#1 463.00>219.00 22.51 (24.00)
Q 463.00>418.90 (-)	1.26e4

YA=28752

IR1 22.51 (-—-)¦ rt=7.052

13C-PFNA IS

Cone. 5.0000

13C-PFNA

Cone. 7.3921

PFNS

Cone. 0.0867

R#1 549.00 >99.00 57.94 (71.23)

8-2-FTS

Cone. 0.0620

R#1 527.20>487.00 1.29 (6.74)

6.66e5 Q 549.00>79.95 (-)

4.15e3 Q 527.10>506.90 (-)

*A=9903

R1 57.94 (—-| rj=7.364 4.0e2 - R1 129 <"") RT=7.405

7.2

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

3.0e4 i
2.0e4 i
1.0e4z_

O.OeO 4====

13C-8 2-FTS

Cone. 6.2153

3.60e4 Q 528.80> 509.00 (-)

7.2
RT (min)

PFDA

Cone. 0.1070

R#1 512.90>219.00 20.84(17.51)
Q 512.90>469.00 (-)	1.23e4

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 6.5458

ISTD 514.80>469.95 (-)

Q 514.80>469.95 (-)

f A= 1562141
I RT=7.402

d3-N-MeFOSAAJS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 6.9740

1.85e5 Q 572.80>419.05 (-)

A=485277
RT=7.588

O.OeO

7.2 7.4 7.6

RT (min)

NMeFOSAA

Cone. 0.1000

R#1 570.20>512.00 36.50 (37.68)
Q 570.20>419.00 (-)	2.98e3

fA=9635

IR1 36.50 (—-)| rj=7.594

2.°e3- |
1.0e3 - 1
O-OeO 1	-/y i, 'r*	

7.4 7.6

RT (min)

PFDS

Cone. 0.0843

R#1 599.00>99.00 55.08 (65.43)
Q 599.00>80.10 (-)	3.02e3

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

3.0e3 -

f A=7102

R1 55.08 (—-)] rt=7.717

7.6 7.

RT (min)

13C-PFUnDA

Cone. 7.0057

Q 564.80>519.95 (-)

7.6 7.8
RT (min)

PFUnDA

Cone. 0.0672

R#1 563.00>219.00 19.36 (13.86)
Q563.00>518.90 (-)	7.98e3

7.25 7.50 7.75

A=1471390
RT=7.763

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)
2.0e5

O.OeO

7.8 8.0
RT (min)

PFOSA

Cone. 0.0966

R#1 498.20>64.10 0.00 (0.09)
Q 498.20>78.00 (-)	3.23e3

f A=.

3.0e3-R1 0.00 (—-)rt=7.753

d5-N-EtFOSAA

Cone. 6.8684

Q 588.80>419.00 (-)
2.0e5

O.OeO

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.1189

R#1 584.20>526.10 60.96 (58.21)
Q 584.20>418.95 (-)	3.16e3

f A=11981
3 0e3 - R1 60.96 (—)f RT=7 783

O.OeO

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

13C-FOSA

Cone. 7.7765

1.71e5 Q 506.00>78.05 (-)

7.8 8.0
RT (min)

A=434150
RT=7.753

7.8 8.0
RT (min)

PFDoA

Cone. 0.1018

R#1 613.05> 169.00 16.80 (16.16)
Q 613.05>569.00 (-)	1.30e4

~ A=30370
-R1 16.80 (—-)| rj=8.112

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

7.8 8.0

RT (min)

7.8 8.0

RT (min)

7.8 8.0

RT (min)

5.47e5

A=1335817
RT=8.113

RT (min)

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

14©

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:28:58

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 6.4843

Q614.80>569.95 (-)

f A=1335817
I RT=8.113

10-2-FtS

Cone. 0.0296

R#1 626.50 >81.05 160.71 (76.13)
Q 626.50>607.05 (-)	3.73e2

6 0e2-R1 16071 ("i
QX)ed -	A=6f65

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 8.1848

1.87e5 Q 531.10> 169.10 (-)

NMeFOSE

Cone. 0.0991

1.87e5 Q 616.10> 58.90 (-)

468170
=8.784

RT (min)

NEtFOSE

Cone. 0.0922

Q 629.50>59.10 (-)

A=3304
RT=8.507

d9-EtFOSE IS

Cone. 5.0000

4.90e3 ISTD 638.90> 59.10 (-)

5.54e4 Q 638.90> 59.10 (-)

A= 13202
RT=8.759

9.0
RT (min)

NMeFOSA

Cone. 0.0822

R#1 512.10>219.20 87.92 (76.94)
Q 512.10> 169.20 (-)	1.34e3

f A=3226

) (-:-kT=8 529

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)
1.5e5:

d3-NMeFOSA

Cone. 8.2340

Q 515.10> 169.00 (-)
1.5e5

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 7.0440

A=204157
RT=8.491

O.OeO

8.4 8.6

RT (min)

NEtFOSA

Cone. 0.1063

R#1 526.50>219.20 60.00 (67.00)
Q 526.50> 169.10 (-)	2.95e3

~ A=7299

I R1 60.00 (-4-^7=8.795

8.4 8.6

RT (min)

PFTrDA

Cone. 0.1737

R#1 663.10> 169.10 26.02 (20.38)
Q 663.10>618.90 (-)	7.52e3

f A= 17982

: R1 26.02 (-—)| rt=8.444

8.4 8.6

RT (min)

PFTeDA

Cone. 0.2367

R#1 713.00> 169.30 10.71 (11.66)
Q 713.00>668.90 (-)	1.14e4

f A=28875

1.0e4^R1 1071 I RT=8.750

O.OeO

RT (min)

RT (min)

9.0

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 2.5143

11CI-PF30UdS

Cone. 0.0871

9CI-PF30NS

Cone. 0.0759

1.34e5 Q714.80>669.80 (-)

1.34e5 Q 631.00>451.10 (-)

3.75e3 Q 531.00>351.10 (-)

O.OeO -

fA=340710
I RT=8.748

rA=340710
I RT=8.748

3.0e3 :
2.0e3 :
1.0e3:
O.OeO :

f A=9523
I RT=7.914

8.6

NaDONA

Cone. 0.1046

9.0
RT (min)

L-PFDoS

Cone. 0.0918
R#1 698.80>98.80 46.17 (71.85)

Q 698.80>80.10 (-)	1,26e3 Q 377.10>251.20 (-)

TA=2918

IR1 46-17 (—1 RT=8.382	:

9.0
RT (min)

9.0
RT (min)

RT (min)

PFHxDA

Cone. -0.0086

PFODA

Cone. 0.0353

13C2-PFHxDA IS

Cone. 5.0000

1.45e4 Q 812.90>769.00 (-)

3.47e3 Q 912.80>869.00 (-)

1,86e3 I STD 815.00 > 770.00 (-)

A=5353
RT=9.891

8.4 8.6
RT (min)

A=2974663
RT=9.281

9.4

RT (min)

10.0

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

14B

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:28:58

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 6.9284

Q 815.00>770.00 (-)

A=2974663 '
RT=9.281

13C7-PFUnDA_IS

Cone. 5.0000

1,27e6 ISTD 569.80> 524.90 (-)
3.0e5 i
2.0e5 i
^.0eS1_
'tTT- O.OeO 1	

PFecHS	PFBSA

Cone. 0.0770	Cone. 0.1057
R#1 461.00>99.10 38.21 (38.14)

3.36e5 Q 461.00>381.00 (-)	1.29e4	Q 298.00>78.00 (-)

9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)
Q 514.80 > 219.10 (+)

5.0e0 -

0.2
RT (min)

A=848158
RT=7.762

?A=33345
-R1 38.21 (-—-) rt=6.672

L



7.5e3 :
5.0e3 :
2.5e3 :
O.OeO :

8.0
RT (min)

RT (min)

PFHxSA

Cone. 0.1163

9.45e3 Q 397.90>78.00 (-)

7.5e3 i
5.0e3 i
2.5e3 i
— O.OeO 1. . . . -

A=22380
RT=6.966

6.4
RT (min)

7.2
RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

m

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:42

CCV2-230428

Sample ID: CCV2-230428

Date Acquired: 4/28/2023 10:51:23 PM

Acquired by: System Administrator

Data File: 230428038

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.227

930047

930047

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.227

930047

1006333

13C7-PFUnDA IS

5.0000

8.7119

ng/mL

PFBA

Auto

4.228

934574

930047

13C-PFBA IS

5.0000

4.4944

nq/mL

13C-PFPeA IS

Auto

5.401

1234655

1234655

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.401

1234655

1006333

13C7-PFUnDA IS

5.0000

7.1985

nq/mL

PFPeA

Auto

5.401

1171428

1234655

13C-PFPeA IS

5.0000

5.1531

ng/mL

13C-PFBS IS

Auto

5.529

452195

452195

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.529

452195

1006333

13C7-PFUnDA IS

4.6500

6.0082

ng/mL

PFBS

Auto

5.529

343838

452195

13C-PFBS IS

4.4200

4.8981

nq/mL

13C HFPO DA IS

Auto

6.137

247788

247788

	

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.137

247788

1006333

13C7-PFUnDA IS

5.0000

6.6532

nq/mL

HFPO DA

Auto

6.137

203840

247788

13C HFPO DA IS

5.0000

5.6242

nq/mL

13C-4 2-FTS IS

Auto

5.938

238191

238191

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.938

238191

1006333

13C7-PFUnDA IS

4.6700

7.0769

ng/mL

4-2-FtS

Auto

5.938

249167

238191

13C-4 2-FTS IS

4.6700

4.4089

nq/mL

PFHxA

Auto

5.993

2148660

1724222

13C-PFHxA IS

5.0000

4.6900

ng/mL

13C-PFHxA IS

Auto

5.993

1724222

1724222

	

5.0000

5.0000

i

13C-PFHxA

Auto

5.993

1724222

1006333

13C7-PFUnDA IS

5.0000

7.3991

ng/mL

PFPeS

Auto

6.032

356411

496376

180-PFHxS IS

4.6900

5.0967

nq/mL

PFHxS

Auto

6.405

281366

496376

180-PFHxS IS

4.5500

4.4601

ng/mL

13C-PFHpA IS

Auto

6.402

1618946

1618946

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.402

1618946

1006333

13C7-PFUnDA IS

5.0000

7.1516

ng/mL

180-PFHxS IS

Auto

6.406

496376

496376

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.406

496376

1006333

13C7-PFUnDAJS

4.7250

6.5720

ng/mL

PFHpA

Auto

6.402

2357175

1613946

13C-PFHpA IS

5.0000

4.8816

ng/mL

13C2-6 2-FTS IS

Auto

6.709

209147

209147

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.709

209147

1006333

13C7-PFUnDA IS

4.7500

5.9321

ng/mL

PFHpS

Auto

6.715

364997

496376

180-PFHxS IS

4.7600

4.8381

ng/mL

6-2-FTS

Auto

6.709

202791

209147

13C2-6 2-FTS IS

4.7400

4.8785

nq/mL

PFOA

Auto

6.727

2704619

2045562

13C-PFOA IS

5.0000

4.8640

ng/mL

13C-PFOA IS

Auto

6.727

2045562

2045562

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.727

2045562

1006333

13C7-PFUnDA IS

5.0000

7.2689

ng/mL

PFOS

Auto

7.026

253556

553291

13C-PFOS IS

4.6400

4.3996

nq/mL

13C-PFOS IS

Auto

7.026

553291

553291

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

7.026

553291

1006333

13C7-PFUnDA IS

4.7750

7.2968

nq/mL

PFNA

Auto

7.053

1679629

1775205

13C-PFNA IS

5.0000

3.9628

ng/mL

13C-PFNA IS

Auto

7.052

1775205

1775205

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.052

1775205

1006333

13C7-PFUnDA IS

5.0000

7.0974

ng/mL

PFNS

Auto

7.366

622350

553291

13C-PFOS IS

4.8000

4.6984

nq/mL

8-2-FTS

Auto

7.399

94235

110314

13C-8 2-FTS IS

4.7900

3.5707

ng/mL

13C-8 2-FTS IS

Auto

7.399

110314

110314

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.399

110314

1006333

13C7-PFUnDA IS

4.7900

6.6416

ng/mL

PFDA

Auto

7.402

1851162

1757812

13C-PFDA IS

5.0000

5.5608

nq/mL

13C-PFDA IS

Auto

7.402

1757812

1757812

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.402

1757812

1006333

13C7-PFUnDA IS

5.0000

6.2080

nq/mL

d3-N-MeFOSAA IS

Auto

7.586

577648

577648

	

5.0000

5.0000

nq/mL

d3-N-MeFOSAA

Auto

7.586

577648

1006333

13C7-PFUnDA IS

5.0000

6.9967

nq/mL

NMeFOSAA

Auto

7.591

556857

577648

d3-N-MeFOSAA IS

5.0000

4.8570

nq/mL

PFDS

Auto

7.717

422854

553291

13C-PFOS IS

4.8200

4.3315

nq/mL

13C-PFUnDA IS

Auto

7.763

1658024

1658024

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.763

1658024

1006333

13C7-PFUnDA IS

5.0000

6.6535

nq/mL

PFUnDA

Auto

7.763

1255724

1658024

13C-PFUnDA IS

5.0000

3.8689

nq/mL

d5-N-EtFOSAA IS

Auto

7.778

605717

605717

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.778

605717

1006333

13C7-PFUnDA IS

5.0000

6.8811

nq/mL

NEtFOSAA

Auto

7.786

492166

605717

dS-N-EtFOSAA IS

5.0000

4.1075

nq/mL

PFOSA

Auto

7.756

508578

432901

13C-FOSA IS

5.0000

5.4829

nq/mL

13C-FOSA IS

Auto

7.756

432901

432901

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.756

432901

1006333

13C7-PFUnDA IS

5.0000

6.5354

nq/mL

PFDoA

Auto

8.114

1823282

1566586

13C-PFDoA IS

5.0000

5.2094

nq/mL

13C-PFDoA IS

Auto

8.114

1566586

1566586

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

14SB

-------
A

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:42

CCV2-230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.114

1566586

1006333

13C7-PFUnDA IS

5.0000

6.4092

nq/mL

10-2-FtS

Auto

8.128

54034

110314

13C-8 2-FTS IS

4.8200

1.9282

ng/mL

d5-NEtFOSA IS

Auto

8.787

503676

503676

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.787

503676

1006333

13C7-PFUnDA IS

5.0000

7.4215

ng/mL

NMeFOSE

Auto

8.509

198144

204706

d7-N-MeFOSE IS

5.0000

5.9279

nq/mL

NEtFOSE

Auto

8.761

693804

153085

d9-EtFOSE IS

5.0000

4.5686

ng/mL

d9-EtFOSE IS

Auto

8.741

153085

153085

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.741

153085

1006333

13C7-PFUnDA IS

5.0000

7.8978

ng/mL

NMeFOSA

Auto

8.533

198125

438755

d3-NMeFOSA IS

5.0000

4.9009

nq/mL

dB-NMeFOSA IS

Auto

8.529

438755

438755

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.529

438755

1006333

13C7-PFUnDA IS

5.0000

7.1500

nq/mL

d7-N-MeFOSE IS

Auto

8.494

204706

204706

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.494

204706

1006333

13C7-PFUnDA IS

5.0000

5.9528

nq/mL

NEtFOSA

Auto

8.796

358488

503676

d5-NEtFOSA IS

5.0000

4.8517

ng/mL

PFTrDA

Auto

8.445

1174062

391309

13C-PFTeDA IS

5.0000

9.8767

nq/mL

PFTeDA

Auto

8.749

1472226

391309

13C-PFTeDA IS

5.0000

10.5081

ng/mL

13C-PFTeDA IS

Auto

8.749

391309

391309

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.749

391309

1006333

13C7-PFUnDA IS

5.0000

2.4338

ng/mL

11CI-PF30UdS

Auto

7.913

633432

553291

13C-PFOS IS

4.7100

4.9965

nq/mL

9CI-PF30NS

Auto

7.215

1037529

553291

13C-PFOS IS

4.6600

3.7985

ng/mL

L-PFDoS

Auto

8.388

186187

553291

13C-PFOS IS

4.8400

5.0505

nq/mL

NaDONA

Auto

6.445

2084005

1775205

13C-PFNA IS

4.7100

5.5617

ng/mL

PFHxDA

Auto

9.283

263231

3513657

13C2-PFHxDA IS

5.0000

0.9204

nq/mL

PFODA

Auto

9.897

291111

3513657

13C2-PFHxDA IS

5.0000

1.6233

ng/mL

13C2-PFHxDA IS

Auto

9.284

3513657

3513657

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.284

3513657

1006333

13C7-PFUnDA IS

5.0000

6.8974

ng/mL

13C7-PFUnDA IS

Auto

7.763

1006333

1006333

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.672

2085218

553291

13C-PFOS IS

4.6100

4.1525

ng/mL

PFBSA

Auto

6.147

1278530

432901

13C-FOSA IS

5.0000

5.6674

nq/mL

PFHxSA

Auto

6.969

1147515

1775205

13C-PFNA IS

5.0000

5.2341

ng/mL

CHARGE

ND(W/B)

	

	

1006333

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

2.0e5 -

O.OeO -tjp

13C-PFBA

Cone. 8.7119
Q 217.20> 172.30 (-)

2.0e51

O.OeO -tjp

PFBA

Cone. 4.4944
Q 213.20> 169.10 (-)

2.0e5

13C-PFPeA IS

Cone. 5.0000
2.01 e5 ISTD 267.90>223.00 (-)

O.OeO

4.00 4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS

Cone. 5.1531	Cone. 4.6500	Cone. 6.0082

4.00 4.25 4.50

RT (min)

Q263.05>219.10 (-)	4.09e5 ISTD 301.80>80.00 (-)	1.65e5 Q 301.80>80.00 (-)

A=452195
RT= 5.529

13C-PFPeA

Cone. 7.1985
4.93e5 Q 267.90>223.00 (-)

O.OeO

O.OeO

5.6	5.2 5.4 5.6

RT (min)	RT (min)

PFBS	13C HFPO DAJS

Cone. 4.8981	Cone. 5.0000
R#1 298.80>99.00 69.61 (65.16)

1.65e5 Q 299.00>80.00 (-) 1.24e5	ISTD 332.10>287.10 (-)	1.02e5

A=343838
)RT= 5.529

5.6 5.8
RT (min)

1.0e5-

fA=247788
RT=6.137



6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

-------
A

(AL?)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:42

CCV2-230428 (continued)

13C HFPO DA

Cone. 6.6532

Q 332.10>287.10 (-)
1.0e5 i

HFPO DA

Cone. 5.6242

R#1 329.00>285.10 70.31 (80.83)
Q 329.00>169.00 (-)	8.64e4

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 22.21 (27.58)
ISTD 329.00>309.15 (-)

13C-4 2-FTS

Cone. 7.0769

R#1 329.00>81.00 22.21 (27.58)

4-2-FtS

Cone. 4.4089

R#1 327.00 >81.10 15.82 (16.09)

9.71e4 Q 329.00>309.15 (-)

9.71e4 Q 327.00>307.05 (-)

T A=238191

-R1 22.21 (— |rj=5.938

O.OeO

6.2 6.4
RT (min)

PFHxA

Cone. 4.6900

R#1 313.00> 119.10 2.67 (2.51)
Q 313.00>269.00 (-)	8.80e5

A=249167

RT= 5.938

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

O.OeO

6.0 6.2
RT (min)

PFPeS

Cone. 5.0967

R#1 349.00>99.00 79.96 (77.24)

O.OeO

7.07e5 Q 314.90>270.10 (-)

7.07e5 Q 349.00>79.95 (-)	1.52e5 Q 399.00>80.00 (-)

A=356411

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 4.4601

R#1 399.00>99.00 95.02 (85.33)

9.94e4

A=281366

R1 95.02 (— rj=6.405

O.OeO

6.2

RT (min)

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

6.94e5 Q 366.90>322.10 (-)

A=1618946
RT=6.402

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)
2.0e5 -

A=496376
RT=6.406

O.OeO

180-PFHxS

Cone. 6.5720

2.21 e5 Q 402.70>84.05 (-)
2.0e5 -

6.6

RT (min)
PFHpA

Cone. 4.8816

R#1 362.90>169.00 17.58 (17.91)
2.21 e5 Q 362.90>319.00 (-)	1,02e6

A=496376
RT=6.406

O.OeO

1.0e6-

f A=2357175

R1 17.58 (—¦| rj=6.402

O.OeO -

6.6

RT (min)

6.2

6.4

13C2-6 2-FTS IS

Cone. 4.7500

13C2-6 2-FTS

Cone. 5.9321

6.6
RT (min)

PFHpS

Cone. 4.8381

R#1 449.00>99.20 67.59 (66.50)
Q 449.00>80.15 (-)	1.58e5

A=364997

1-5e5 Hri 67.59 (____| RT=6 715

6.2

6.4

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

13C-PFOA

Cone. 7.2689

8.65e5 Q416.80>372.05 (-)

6.6 6.8

RT (min)

PFOS

Cone. 4.3996

R#1 499.00>99.00 95.52 (86.07)
Q 499.00>80.00 (-)	7.82e4

A=253556

7.5e4-^ 95.52 (-4 RT=7.026

6.6
RT (min)

6-2-FTS

Cone. 4.8785

R#1 427.00>80.90 29.03 (33.45)
Q 427.00>407.00 (-)	8.07e4

TA=202791

7.5e4^|R1 29.03 (----jj rj=6.709

5.0e4 -j
2.5e4 -j
O.OeO :

6.2 6.4 6.6

RT (min)

PFOA

Cone. 4.8640

R#1 413.00> 169.10 29.64 (27.85)
Q 413.00>369.00 (-)	1.14e6

[A=2704619

1.0e6^R1 29-64(—RT=6.727

RT (min)

6.6 6.8 7.0
RT (min)

13C-PFOS IS

Cone. 4.7750

13C-PFOS

Cone. 7.2968

105 (-)

2.28e5 Q 502.80>80.05 (-)

A= 553291
RT=7.026

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

fA= 553291
RT=7.026

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

WD

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:42

CCV2-230428 (continued)

PFNA	13C-PFNA IS

Cone. 3.9628	Cone. 5.0000
R#1 463.00>219.00 25.42 (24.00)

Q 463.00>418.90 (-)	7.26e5	ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 7.0974

7.63e5 Q 467.80>423.00 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

TA= 1679629

:R1 25.42 (—-1 rt=7.053

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)
4.0e4 -

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)
2.0e5 -

1.0e5 -

13C-PFUnDA

Cone. 6.6535

2.0e5

A= 508578

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

A=1775205
RT=7.052

TA= 1775205
RT=7.052



6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

7.2

RT (min)

7.2

RT (min)

6.8

7.0

13C-8 2-FTS

Cone. 6.6416

4.35e4 Q 528.80> 509.00 (-)
4.0e4 -

7.6
RT (min)

d3-N-MeFOSAA

Cone. 6.9967

2.22e5 Q 572.80>419.05 (-)
2.0e5 -

1.0e5 -

7.6 7.8
RT (min)

O.OeO

7.6 7.8
RT (min)

PFUnDA

Cone. 3.8689

R#1 563.00>219.00 16.75 (13.86)
Q563.00>518.90 (-)	4.90e5

fA= 1255724

-R1 16.75 (— 1 RT=7.763

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

7.8 8.0
RT (min)

PFOSA

Cone. 5.4829

R#1 498.20>64.10 0.14 (0.09)
Q 498.20>78.00 (-)	2.02e5

A=605717
RT=7.778

L

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

A=432901
RT=7.756

V,

13C-FOSA

Cone. 6.5354

1.72e5 Q 506.00>78.05 (-)

1.5e5 ^

1.0e5 ^

5.0e4 -

O.OeO -

7.8 8.0

RT (min)

7.8 8.0

RT (min)

PFNS

Cone. 4.6984

R#1 549.00>99.00 65.88 (71.23)
Q 549.00>79.95 (-)	2.52e5

8-2-FTS

Cone. 3.5707

R#1 527.20>487.00 8.71 (6.74)
Q 527.10>506.90 (-)	3.67e4

A=94235

7.2
RT (min)

PFDA

Cone. 5.5608

R#1 512.90>219.00 18.27 (17.51)
Q 512.90>469.00 (-)	7.43e5

7.4 7.6
RT (min)

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

fA=1757812
I RT=7.402

7.6
RT (min)

NMeFOSAA

Cone. 4.8570

R#1 570.20>512.00 36.53 (37.68)
Q 570.20>419.00 (-)	1.89e5

A= 556857

R1 36.53 (—-)| rt=7.591

S\]

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 6.8811

2.32e5 Q 588.80>419.00 (-)

O.OeO -

7.8 8.0
RT (min)

7.6

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

f A=1823282

]R1 17.43 (-—)J\ RT=8.114

7.8 8.0

RT (min)

7.4 7.6

RT (min)

13C-PFDA

Cone. 6.2080

6.94e5 Q 514.80>469.95 (-)

7.2 7.4 7.6

RT (min)

PFDS

Cone. 4.3315

R#1 599.00>99.00 58.27 (65.43)
Q 599.00>80.10 (-)	1.63e5

f A=422854

1.5e5^|R1 58.27 (-—| rj=7.717

1.0e5^

5.0e4 -j
O.OeO :

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

r A=1757812
RT=7.402

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

7.8 8.0
RT (min)

NEtFOSAA

Cone. 4.1075

R#1 584.20>526.10 62.58 (58.21)
Q 584.20>418.95 (-)	1.64e5

1.5e5- R1 62.58 (—-)
1.0e5-

5.0e4 -

A=492166
RT=7.786

O.OeO -



L

7.8 8.0
RT (min)

PFDoA

Cone. 5.2094

R#1 613.05> 169.00 17.43 (16.16)
Q 613.05>569.00 (-)	7.40e5

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)
6.0e5 ^

4.0e5 ^

2.0e5 ^

O.OeO 4====

6.39e5

A= 1566586
RT=8.114



RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

1321

-------
A

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:42

CCV2-230428 (continued)

13C-PFDoA

Cone. 6.4092

Q614.80>569.95 (-)
6.0e51

10-2-FtS

Cone. 1.9282

R#1 626.50>81.05 150.47 (76.13)
Q 626.50>607.05 (-)	2.09e4

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)	2.02e5

d5-NEtFOSA

Cone. 7.4215

Q 531.10> 169.10 (-)
2.0e5 -|

NMeFOSE

Cone. 5.9279

Q 616.10>58.90 (-)

A= 198144
RT=8.509

Q 629.50>59.10 (-)

2.74e5 ISTD 638.90>59.10 (-)

5.96e4 Q 638.90> 59.10 (-)

O.OeO

9.0
RT (min)

NMeFOSA

Cone. 4.9009

R#1 512.10>219.20 79.36 (76.94)
Q 512.10> 169.20 (-)	7.52e4

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

9.0
RT (min)

9.0
RT (min)

d3-NMeFOSA

Cone. 7.1500

Q 515.10> 169.00 (-)

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 5.9528

8.4 8.6

RT (min)

NEtFOSA

Cone. 4.8517

R#1 526.50>219.20 61.37 (67.00)
Q 526.50>169.10 (-)	1.40e5

f A=358488

- R1 61.37 (- rftr=8.796

8.4 8.6

RT (min)

PFTeDA

Cone. 10.5081

R#1 713.00 >169.30 14.28 (11.66)
Q 713.00>668.90 (-)	5.82e5

RT (min)

RT (min)

8.4 8.6

RT (min)

PFTrDA

Cone. 9.8767

R#1 663.10> 169.10 27.22 (20.38)
Q 663.10>618.90 (-)	4.81 e5

TA= 1174062

- R1 27.22 (—• RT=8.445

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)
1.5e5

13C-PFTeDA

Cone. 2.4338

Q 714.80>669.80 (-)

11CI-PF30UdS

Cone. 4.9965

1.54e5 Q 631.00>451.10 (-)

A=633432
RT=7.913

O.OeO

9.0
RT (min)

L-PFDoS

Cone. 5.0505

R#1 698.80>98.80 62.67 (71.85)
Q 698.80>80.10 (-)	7.66e4

NaDONA

Cone. 5.5617

Q 377.10>251.20 (-)

9CI-PF30NS

Cone. 3.7985

Q 531.00>351.10 (-)
4.0e5 H

A=1037529
RT=7.215

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

A=2084005
RT=6.445

Q 812.90>769.00 (-)
1.0e5 -

5.0e4 -

1.12e5 Q 912.80>869.00 (-)

9.45e4 ISTD 815.00>770.00 (-)

B.2 8.4 8.6

RT (min)

9.0 9.2 9.4

RT (min)

9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

-------
)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:42

CCV2-230428 (continued)

13C2-PFHxDA

Cone. 6.8974

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

1.49e6 ISTD 569.80>524.90 (-)

PFecHS	PFBSA

Cone. 4.1525	Cone. 5.6674
R#1 461.00>99.10 40.07 (38.14)

3.93e5 Q 461.00>381.00 (-)	8.36e5	Q 298.00>78.00 (-)

PFHxSA

Cone. 5.2341

5.13e5 Q 397.90>78.00 (-)

A=3513657 '
RT=9.284

1.0e6 -
5.0e5 ^
O.OeO -

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

A=1006333
RT=7.763

V

f A=2085218
7.5e5^R1 4007 | RT=6.672

5.0e5 :

2.5e5 :

O.OeO :

8.0
RT (min)

6.4 6.6 6.8

RT (min)

A=1278530
RT=6.147

A= 1147515
RT=6.969

L

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

1356

-------
1st /S/AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/Integration
Printed 5/2/2023 11:29:46

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/29/2023 1:36:23 AM

Acquired by: System Administrator

Data File: 230428050

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.217

759516

759516

	 	

5.0000

ng/ml

13C-PFBA

Auto

4.217

759516

877168

13C7-F

8.1621

nq/mL

PFBA

M

4.217

14555

759516

13C-PFBA IS

0.0857

ng/ml

13C-PFPeA IS

Auto

5.388

1049922

1049922

	 	

)00

ng/ml

13C-PFPeA

Auto

5.388

1049922

877168

13C7-PFUnDA IS

7.0229

ng/ml

PFPeA

Auto

5.389

20119

1049922

13C-PFPeA IS

- )41

ng/ml

13C-PFBS IS

Auto

5.516

382564

382564

	 	

4.6500

ng/ml

13C-PFBS

Auto

5.516

382564

877168

13C7-PFUnDA IS

5.8315

ng/ml

PFBS

Auto

5.516

5726

382564

I k PFBS IS

0.0964

nq/mL

13C HFPO DA IS

Auto

6.124

223789

223789

	 	

5.0000

ng/ml

FPO DA

Auto

6.124

223789

877168

13C7-PFUnDA IS

6.8936

ng/ml

HFPO DA

Auto

6.124

3101

223789

13C HFPO DA IS

0.0947

ng/ml

13C-4 2-FTS IS

Auto

5.924

180043

180043

	 	

4 f.;-m

ng/ml

13C-4 2-FTS

Auto

5.924

43

877168

13C7-PFUnDA IS

6.1370

nq/mL

4-2-FtS

Auto

5.924

"17

180043

13C-4 2-FTS IS

0.0917

iL

PFHxA

Auto

378

34199

1451372

: :HxA

0.0887

ng/mL

13C-PFHxA IS

Auto

5.978

1451372

1451372

	 	

5.0000

iL

13C-PFHxA

Auto

5.978

1451372

877168

13C7-PFUnDA IS

7.1453

ng/mL

PFPeS

Auto

6.016

98

408812

180-PFHxS IS

0.1146

ng/mL

PFHxS

Auto

6.390

5243

408812

¦ : :HxS

0.1009

ng/mL

13C-PFHpA IS

Auto

6.387

1374975

1374975

	 	

5.0000

g/mL

13C-PFHpA

Auto

6.387

1374975

877168

13C7-PFUn[ .

6.9683

ng/ml

kV PI H\s IS

Auto

6.391

408812

12

	 	

4.7250

g/mL

180-PFHxS

Auto

6.391

408812

877168

13C7-PFUnDA IS

6.2097

nq/mL

PFHpA

Auto

6.388

39976

1374975

13C-PFHpA IS

0.0975

ng/mL

5 2-FTS IS

Auto

6.692

175330

175330

	 	

4.7500

ng/ml

2- F

Auto

6.692

175330

877168

13C7-PFUnDA IS

5.7052

ng/mL



Auto

6.696

6437

408812

180-PFHxS IS

0.1036

ng/ml

6-2-FTS

Auto

6.694

3241

175330

13C2-6 2-FTS IS

0.0930

. iL

PFOA

Auto

6.710

41143

1599737

13C-PFOA IS

0.0946

ng/mL

13C-PFOA IS

Auto

6.709

1599737

1599737

	 	

5.0000

ng/mL

13C-PFOA

Auto

6.709

1599737

877168

13C7-PFUn[ .

6.5217

ng/mL

PFOS

Auto

7.009

4663

439698

13C-PFOS IS

0.1018

ng/mL

FOS IS

Auto

7.006

439698

439698

	 	

4.7750

ng/mL

13C-PFOS

Auto

7.006

439698

877168

13C7-PFUnDA IS

6.6526

ng/mL

PFNA

Auto

7.031

18

1528641

13C-PFNA IS

0.0795

ng/mL

13C-PFNA IS

Auto

7.031

41

1528641

	 	

5.0000

ng/mL

13C-PFNA

Auto

7.031

1528641

877168

13C7-PFUnDA IS

7.0116

ng/mL

PFNS

Auto

7.340

7764

439698

13C-PFOS IS

0.0738

ng/mL

8-2-FTS

Auto

7.367

14

85004

13C-8 2-FTS IS

0.0777

nq/mL

13C-8 2-FTS IS

Auto

7.373

85004

85004

	 	

4.7900

iL

13C-8 2-FTS

Auto

7.373

85004

877168

13C7-PFUnDA IS

5.8714

ng/mL

PFDA

Auto

7.377

32264

1554356

13C-PFDA IS

0.1096

iL

13C-PFDA IS

Auto

7.377

1554356

356

	 	

5.0000

ng/mL

13C-PFDA

Auto

7.377

56

877168

13C7-PFU nt

6.2978

nq/mL

d3-N-MeFOSAA IS

Auto

7.560

485899

485899

	 	

5.0000

ng/ml

d3-N-MeFOSAA

Auto

7.560

485899

877168

13C7-PFUnDA IS

6.7520

ng/mL

NMeFOSAA

Auto

7.563

9555

899

d? : ; :

0.0991

ng/mL

PFDS

Auto

7.693

6740

439698

13C-PFOS IS

0.0869

ng/mL

13C-PFUnDA IS

Auto

7.736

1437778

778

	 	

5.0000

ng/ml

13C-PFUnDA

Auto

7.736

1437778

877168

13C7-PFUnDA IS

6.6193

ng/mL

PFUnDA

Auto

7.734

20176

1437778

13C-PFUnDA IS

0.0717

ng/mL

(IS- N- EtFOSAA IS

Auto

7.750

525319

525319

	 	

5.0000

ng/mL

d5-N-EtFOSAA

Auto

7.750

525319

877168

13C7-PFUnDA IS

6.8466

ng/ml

NEtFOSAA

Auto

7.758

10046

525319

;tFOS

0.0967

nq/mL

PFOSA

Auto

750

8144

128

13C-FOSA IS

0.0945

ng/ml

3SA IS

Auto

7.750

4i VI28

402128

	 	

5.0000

ng/mL

13C-FOSA

Auto

7.750

402128

877168

13C7-PFUnDA IS

6.9647

ng/ml

PFDoA

Auto

8.085

31533

1322718

13C-PFDoA IS

0.1067

ng/mL

13C-PFDoAJS
I iv. PFl'On

Auto
Auto

8.087
8.087

1322718

L

718

____

13C7-PFUnPA IS	-—

5.0000
6.2084

ng/ml

ng/mL

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:29:46

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone.

Cone. Unit

10-2-FtS

Auto

8.108

705

85004

13C-8 2-FTS IS

0.0326

nq/mL

d5-NEtFOSA IS

Auto

8.775

477964

477964

—

5.0000

nq/mL

d5-NEtFOSA

Auto

8.775

477964

877168

13C7-PFUnDA IS

8.0797

nq/mL

NMeFOSE

Auto

8.498

3960

205715

d7-N-MeFOSE IS

0.1179

nq/mL

NEtFOSE

Auto

8.749

13382

151772

d9-EtFOSE IS

0.0889

nq/mL

d9-EtFOSE IS

Auto

8.731

151772

151772

—

5.0000

nq/mL

d9-EtFOSE

Auto

8.731

151772

877168

13C7-PFUnDA IS

8.9831

nq/mL

NMeFOSA

Auto

8.524

2835

420018

d3-NMeFOSA IS

0.0733

nq/mL

dB-NMeFOSA IS

Auto

8.519

420018

420018

—

5.0000

nq/mL

dB-NMeFOSA

Auto

8.519

420018

877168

13C7-PFUnDA IS

7.8526

nq/mL

d7-N-MeFOSE IS

Auto

8.482

205715

205715

—

5.0000

nq/mL

d7-N-MeFOSE

Auto

8.482

205715

877168

13C7-PFUnDA IS

6.8630

nq/mL

NEtFOSA

Auto

8.785

6576

477964

d5-NEtFOSA IS

0.0938

nq/mL

PFTrDA

Auto

8.416

22432

337492

13C-PFTeDA IS

0.2188

nq/mL

PFTeDA

Auto

8.720

27702

337492

13C-PFTeDA IS

0.2293

nq/mL

13C-PFTeDA IS

Auto

8.719

337492

337492

—

5.0000

nq/mL

1BC-PFTeDA

Auto

8.719

337492

877168

13C7-PFUnDA IS

2.4082

nq/mL

11CI-PF30UdS

Auto

7.885

11346

439698

13C-PFOS IS

0.1126

nq/mL

9CI-PFBONS

Auto

7.192

17294

439698

13C-PFOS IS

0.0797

nq/mL

L-PFDoS

Auto

8.363

2852

439698

13C-PFOS IS

0.0974

nq/mL

NaDONA

Auto

6.431

31482

1528641

13C-PFNA IS

0.0976

nq/mL

PFHxDA

Auto

9.247

6945

2929305

13C2-PFHxDA IS

-0.0118

nq/mL

PFODA

Auto

9.841

5036

2929305

13C2-PFHxDA IS

0.0337

nq/mL

13C2-PFHxDA IS

Auto

9.248

2929305

2929305

—

5.0000

nq/mL

1BC2-PFHxDA

Auto

9.248

2929305

877168

13C7-PFUnDA IS

6.5971

nq/mL

13C7-PFUnDA IS

Auto

7.736

877168

877168

—

5.0000

nq/mL

PFecHS

Auto

6.656

36008

439698

13C-PFOS IS

0.0902

nq/mL

PFBSA

Auto

6.146

22861

402128

13C-FOSA IS

0.1091

nq/mL

PFHxSA

Auto

6.965

19702

1528641

13C-PFNA IS

0.1044

nq/mL

CHARGE

ND(W/B)

	

	

877168

13C7-PFUnDA IS

— 	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 8.1621
1.70e5 Q 217.20>172.30 (-)

PFBA

Cone. 0.0857
1.70e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
3.66e3 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 7.0229
4.05e5 Q 267.90>223.00 (-)

A= 14555
RT=4.217

4.0e5 -

J A=1049922
I RT= 5.388

O.OeO -tqjf

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 0.1041

Q263.05>219.10 (-)

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

O.OeO -

4.0e5 -

fA= 1049922
RT= 5.388

O.OeO -

7.51 e3 ISTD 301.80>80.00 (-)

5.2

4.00 4.25 4.50

RT (min)

13C-PFBS	PFBS

Cone. 5.8315	Cone. 0.0964

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

1.33e5 Q 301.80>80.00 (-)

R#1 298.80>99.00 63.04(65.16)

1.33e5 Q 299.00>80.00 (-)	2.26e3 ISTD 332.10>287.10 (-)	9.19e4

A=382564
RT=5.516

~ A=5726
2.0e3 - R1 63 04 ( kT=5.516

A=223789
RT=6.124

6.2 6.4
RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

¦y l/f

COED

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:29:46

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 6.8936

Q 332.10>287.10 (-)

HFPO DA

Cone. 0.0947

R#1 329.00>285.10 67.74 (80.83)
Q 329.00>169.00 (-)	1.44e3

f A=3101

-R1 67.74 (—-)rT=6.124

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 25.31 (27.58)

ISTD 329.00>309.15 (-)	7.10e4

TA= 180043

= R1 25.31 (--)rt=5.924

13C-4 2-FTS

Cone. 6.1370

R#1 329.00>81.00 25.31 (27.58)
Q 329.00>309.15 (-)	7.10e4

TA= 180043
R1 25.31 (-|)rt= 5.924

6.2 6.4
RT (min)

PFHxA

Cone. 0.0887

R#1 313.00>119.10 4.39 (2.51)
Q 313.00>269.00 (-)	1.41e4

TA=34199

:R1 4.39 (—ij rt= 5.978

4-2-FtS

Cone. 0.0917

R#1 327.00>81.10 17.95 (16.09)
Q 327.00>307.05 (-)	1.68e3

TA=3917
1.5e3^R1 1795 ("|)RT=5.924

6.0 6.2
RT (min)

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

13C-PFHxA

Cone. 7.1453

5.81 e5 Q 314.90>270.10 (-)

f A=1451372
I RT= 5.978

6.2
RT (min)

6.0 6.2
RT (min)

PFPeS

Cone. 0.1146

R#1 349.00>99.00 84.87 (77.24)
Q 349.00>79.95 (-)	2.59e3

TA=6598
-R1 84.87 (--t')rT=6.016

6.0 6.2
RT (min)

PFHxS

Cone. 0.1009

R#1 399.00>99.00 87.52 (85.33)
Q 399.00>80.00 (-)	1.91e3

fA=5243

: R1 87.52 (—¦-}rt=6.390

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

13C-PFHpA

Cone. 6.9683

5.98e5 Q 366.90>322.10 (-)

180-PFHxS IS

Cone. 4.7250

5.98e5 ISTD 402.70>84.05 (-)

180-PFHxS

Cone. 6.2097

1.83e5 Q 402.70>84.05 (-)

A=1374975
RT=6.387

6.6
RT (min)

PFHpA

Cone. 0.0975

R#1 362.90 >169.00 14.94 (17.91)
Q 362.90>319.00 (-)	1.78e4

~ A=39976
= R1 14.94 ( jij) RT=6.3

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

13C2-6 2-FTS

Cone. 5.7052

7.26e4 Q 428.90>409.00 (-)

A= 175330
RT=6.692

6.6
RT (min)

PFHpS

Cone. 0.1036

R#1 449.00>99.20 51.74 (66.50)
Q 449.00>80.15 (-)	2.70e3

*A=6437
IR1 51.74 (---|)rt=6.696

O.OeO

6.4 6.6

RT (min)

6-2-FTS

Cone. 0.0930

R#1 427.00>80.90 30.97 (33.45)
Q 427.00>407.00 (-)	1.26e3

~ A=3241

I R1 30.97 (—rj rt=6.694

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

13C-PFOA

Cone. 6.5217

6.6 6.8

RT (min)

PFOS

Cone. 0.1018

R#1 499.00>99.00 75.28 (86.07)
Q 499.00>80.00 (-)	1.40e3

f A=4663

6.6
RT (min)

PFOA

Cone. 0.0946

R#1 413.00> 169.10 32.56 (27.85)
Q 413.00>369.00 (-)	1.73e4

~ A=41143
1 5e4- R1 32-56 (—3rT=6.710

RT (min)

13C-PFOS IS

Cone. 4.7750

105 (-)	1.76e5 Q 502.8

f. A=439698

105 (-)

1.76e5
f A=439698

6.8 7.0
RT (min)

- R1 75.28 (—-

RT=7-009 1.5e5 ^



RT=7'006 1.5e5-|



RT=7.006

:

1.0e5^



1.0e5^





-

A=86 5.0e4-



I 5.0e4 ^





A J

kRT=7.244



4







V T -,Y 	 n Don







lik-v

iii*iiii









' i i i i i i i i

6.75 7.00 7.25

CTi
CO

O

7.2

6.8 7.0 7.2



RT (min)



RT (min)



RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

1356

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:29:46

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0795

R#1 463.00>219.00 19.65 (24.00)
Q 463.00>418.90 (-)	1.19e4

f;A=29018

-R1 19.65 (—-1rt=7.031

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)
6.0e5 -
4.0e5 ^

2.0e51

A= 1528641
RT=7.031

O.OeO -

7.2

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)
3.0e4 -

13C-8 2-FTS

Cone. 5.8714

Q 528.80>509.00 (-)

'A=85004
RT=7.373

d3-N-MeFOSAA IS

Cone. 5.0000

d3-N-MeFOSAA

Cone. 6.7520

ISTD 572.80>419.05 (-)

^.SeSz_

^.0eSz_

5.0e4 i
O.OeO 1 . . .

1.82e5 Q 572.80>419.05 (-)

rA=485899
\RT=7.560

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

7 A=485899
lRT=7.560

7.6 7.8
RT (min)

7.4

13C-PFUnDA

Cone. 6.6193

Q 564.80>519.95 (-)

O.OeO

7.8 8.0
RT (min)

PFOSA

Cone. 0.0945

R#1 498.20>64.10 0.00 (0.09)
Q 498.20>78.00 (-)	3.32e3

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

13C-PFNA

Cone. 7.0116

Q 467.80>423.00 (-)
6.0e5 -
4.0e5 ^

2.0e5 ^

O.OeO 1 . . . .

PFNS

Cone. 0.0738

R#1 549.00 >99.00 76.06 (71.23)
Q 549.00>79.95 (-)	3.55e3

8-2-FTS

Cone. 0.0777

R#1 527.20>487.00 8.32 (6.74)
Q 527.10>506.90 (-)	6.03e2

'A=1528641
RT=7.031

3.0e3 -
2.0e3 -
1.0e3-
O.OeO -

y.A=7764

R1 76.06 (-"|1rt=7.340

7.2

RT (min)

6.8

7.0

7.2
RT (min)

PFDA

Cone. 0.1096

R#1 512.90>219.00 15.09 (17.51)
Q 512.90>469.00 (-)	1.26e4

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 6.2978

IR1 15.09 (--

~ A=32264
1>RT=7.377

O.OeO -



ISTD 514.80>469.95 (-)
6.0e5 -

Q 514.80>469.95 (-)

'A=1554356
RT=7.377



7.6
RT (min)

7.2

7.4

7.6
RT (min)

NMeFOSAA

Cone. 0.0991

R#1 570.20>512.00 40.42 (37.68)
Q 570.20>419.00 (-)	3.21e3

~ A=9555
IR1 40.42 (-4 RT=7.563

7.6
RT (min)

PFDS

Cone. 0.0869

R#1 599.00 >99.00 49.71 (65.43)
Q 599.00>80.10 (-)	2.87e3

^ A=6740

- R1 49.71 (—hi rt=7.693

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

O.OeO -

7.6 7.8
RT (min)

PFUnDA

Cone. 0.0717

R#1 563.00>219.00 14.61 (13.86)
Q563.00>518.90 (-)	8.09e3

~ A=20176
7.5e3 - R1 14.61 (—1)RT=7.734

7.25 7.50 7.75

7.6

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)
2.0e5

d5-N-EtFOSAA

Cone. 6.8466

Q 588.80>419.00 (-)
2.0e5

13C-FOSA

Cone. 6.9647

Q 506.00>78.05 (-)

7.8 8.0
RT (min)

A=402128
RT=7.750

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.0967

R#1 584.20>526.10 55.64 (58.21)
Q 584.20>418.95 (-)	2.93e3

~ A= 10046

I R1 55.64 (—-| rj=7.758

O.OeO -

7.8 8.0
RT (min)

PFDoA

Cone. 0.1067

R#1 613.05> 169.00 18.86 (16.16)
Q 613.05>569.00 (-)	1.27e4

f ,A=31533
I R1 18-86 (—"):RT=8.085

O.OeO -

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

5.26e5

7.8 8.0

RT (min)

7.8 8.0

RT (min)

7.8 8.0

RT (min)

1322718
=8.087

RT (min)

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

m

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:29:46

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 6.2084

Q614.80>569.95 (-)

10-2-FtS

Cone. 0.0326

R#1 626.50>81.05 102.27 (76.13)
Q 626.50>607.05 (-)	3.42e2

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 8.0797

1.87e5 Q 531.10> 169.10 (-)

1.5e5-
^.0eSz_
5.0e4z_
O.OeO -

RT (min)

RT (min)

NEtFOSE

Cone. 0.0889

Q 629.50>59.10 (-)

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 8.9831

5.39e3 ISTD 638.90> 59.10 (-)

5.72e4 Q 638.90> 59.10 (-)

9.0
RT (min)

9.0
RT (min)

d3-NMeFOSA

Cone. 7.8526

Q 515.10> 169.00 (-)
1.5e5

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 6.8630

8.4 8.6

RT (min)

PFTeDA

Cone. 0.2293

R#1 713.00> 169.30 11.67 (11.66)
Q 713.00>668.90 (-)	1.03e4

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 2.4082

1.31e5 Q714.80>669.80 (-)

1.0e4

f A=27702

_R1 11.67 (—• Rj=8.720

O.OeO -

8.6

.8 9.0
RT (min)

L-PFDoS

Cone. 0.0974

R#1 698.80>98.80 67.37 (71.85)
Q 698.80>80.10 (-)	1.41e3

8.6 8.8 9.0
RT (min)

NaDONA

Cone. 0.0976

Q377.10>251.20 (-)

PFHxDA

Cone. -0.0118

- R1 67.37 (—

TA=2852
||RT=8.363

A=31482
RT=6.431

Q 812.90>769.00 (-)
3.0e3 -i

NMeFOSE

Cone. 0.1179

A=3960
RT=8.498

9.0

RT (min)

8.6

.8 9.0

RT (min)

NMeFOSA

Cone. 0.0733

R#1 512.10>219.20 76.30 (76.94)
Q 512.10> 169.20 (-)	1.01e3

RT (min)

1.0e3-

f A=2835
R1 76.30 (--*-^1=8.524

O.OeO I i i |

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0938

R#1 526.50>219.20 77.17 (67.00)
Q 526.50>169.10 (-)	2.62e3

~ A=6576

-R1 77.17 (~*£r=8.785

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)
1.5e5-
1.0e5-
5.0e4-
O.OeO -

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.2188

R#1 663.10> 169.10 29.13 (20.38)
Q 663.10>618.90 (-)	8.94e3

~ A=22432
R1 29.13 (-—I !RT=8.416

RT (min)

8.6

RT (min)

11CI-PF30UdS

Cone. 0.1126

1.31e5 Q 631.00>451.10 (-)



=11346
7.885

Jr^rr

9CI-PF30NS

Cone. 0.0797

4.49e3 Q 531.00>351.10 (-)

6.0e3 :

4.0e3 :

2.0e3 :

O.OeO :



^A= 17294

;

RT=7.192

: /

.L	

9.0
RT (min)

RT (min)

7.4

RT (min)

PFODA

Cone. 0.0337

13C2-PFHxDA IS

Cone. 5.0000

3.05e3 Q 912.80>869.00 (-)

1,90e3 I STD 815.00 > 770.00 (-)

A=5036
RT=9.841

B.2 8.4 8.6

RT (min)

6.6

RT (min)

'A=2929305
\1=9.248

9.6 9.8 10.0

RT (min)

9.0 9.2 9.4

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

HSB

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:29:46

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 6.5971

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

1.25e6 ISTD 569.80>524.90 (-)

PFecHS	PFBSA

Cone. 0.0902	Cone. 0.1091
R#1 461.00>99.10 36.61 (38.14)

3.47e5 Q 461.00>381.00 (-)	1.43e4	Q 298.00>78.00 (-)

PFHxSA

Cone. 0.1044

fA=2929305
RT=9.248

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)
Q 514.80 > 219.10 (+)

5.0e0 -

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

9.4

RT (min)

0.2
RT (min)

A=877168
RT=7.736

?A=36008

- R1 36.61 ( if;) RT=6.656

8.0
RT (min)

RT (min)

A= 19702
RT=6.965

7.0 7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

168®

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:46

CCV3-230428

Sample ID: CCV3-230428

Date Acquired: 4/29/2023 1:50:08 AM

Acquired by: System Administrator

Data File: 230428051

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.218

893849

893849

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.218

893849

975788

13C7-PFUnDA IS

5.0000

8.6349

ng/mL

PFBA

Auto

4.219

922152

893849

13C-PFBA IS

5.0000

4.6143

nq/mL

13C-PFPeA IS

Auto

5.389

1230861

1230861

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.389

1230861

975788

13C7-PFUnDA IS

5.0000

7.4010

nq/mL

PFPeA

Auto

5.389

1156830

1230861

13C-PFPeA IS

5.0000

5.1046

ng/mL

13C-PFBS IS

Auto

5.517

429603

429603

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.517

429603

975788

13C7-PFUnDA IS

4.6500

5.8867

ng/mL

PFBS

Auto

5.517

343106

429603

13C-PFBS IS

4.4200

5.1447

nq/mL

13C HFPO DA IS

Auto

6.124

254105

254105

	

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.124

254105

975788

13C7-PFUnDA IS

5.0000

7.0364

nq/mL

HFPO DA

Auto

6.124

199878

254105

13C HFPO DA IS

5.0000

5.3778

nq/mL

13C-4 2-FTS IS

Auto

5.925

230662

230662

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.925

230662

975788

13C7-PFUnDA IS

4.6700

7.0677

ng/mL

4-2-FtS

Auto

5.925

244920

230662

13C-4 2-FTS IS

4.6700

4.4752

nq/mL

PFHxA

Auto

5.979

2081244

1650450

13C-PFHxA IS

5.0000

4.7459

ng/mL

13C-PFHxA IS

Auto

5.979

1650450

1650450

	

5.0000

5.0000

i

13C-PFHxA

Auto

5.979

1650450

975788

13C7-PFUnDA IS

5.0000

7.3042

ng/mL

PFPeS

Auto

6.018

337521

471734

180-PFHxS IS

4.6900

5.0787

nq/mL

PFHxS

Auto

6.391

263873

471734

180-PFHxS IS

4.5500

4.4013

ng/mL

13C-PFHpA IS

Auto

6.387

1565612

1565612

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.387

1565612

975788

13C7-PFUnDA IS

5.0000

7.1325

ng/mL

180-PFHxS IS

Auto

6.391

471734

471734

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.391

471734

975788

13C7-PFUnDAJS

4.7250

6.4412

ng/mL

PFHpA

Auto

6.387

2269041

1565612

13C-PFHpA IS

5.0000

4.8591

ng/mL

13C2-6 2-FTS IS

Auto

6.692

200280

200280

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.692

200280

975788

13C7-PFUnDA IS

4.7500

5.8584

ng/mL

PFHpS

Auto

6.699

344732

471734

180-PFHxS IS

4.7600

4.8081

ng/mL

6-2-FTS

Auto

6.692

197139

200280

13C2-6 2-FTS IS

4.7400

4.9525

nq/mL

PFOA

Auto

6.709

2431775

1897301

13C-PFOA IS

5.0000

4.7151

ng/mL

13C-PFOA IS

Auto

6.709

1897301

1897301

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.709

1897301

975788

13C7-PFUnDA IS

5.0000

6.9531

ng/mL

PFOS

Auto

7.007

232039

512604

13C-PFOS IS

4.6400

4.3459

nq/mL

13C-PFOS IS

Auto

7.007

512604

512604

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

7.007

512604

975788

13C7-PFUnDA IS

4.7750

6.9718

nq/mL

PFNA

Auto

7.032

1661923

1806941

13C-PFNA IS

5.0000

3.8521

ng/mL

13C-PFNA IS

Auto

7.031

1806941

1806941

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.031

1806941

975788

13C7-PFUnDA IS

5.0000

7.4504

ng/mL

PFNS

Auto

7.343

577655

512604

13C-PFOS IS

4.8000

4.7071

nq/mL

8-2-FTS

Auto

7.375

87369

104148

13C-8 2-FTS IS

4.7900

3.5047

ng/mL

13C-8 2-FTS IS

Auto

7.375

104148

104148

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.375

104148

975788

13C7-PFUnDA IS

4.7900

6.4666

ng/mL

PFDA

Auto

7.378

1831219

1763263

13C-PFDA IS

5.0000

5.4839

nq/mL

13C-PFDA IS

Auto

7.378

1763263

1763263

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.378

1763263

975788

13C7-PFUnDA IS

5.0000

6.4222

nq/mL

d3-N-MeFOSAA IS

Auto

7.561

576935

576935

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.561

576935

975788

13C7-PFUnDA IS

5.0000

7.2068

nq/mL

NMeFOSAA

Auto

7.565

556718

576935

d3-N-MeFOSAA IS

5.0000

4.8618

nq/mL

PFDS

Auto

7.692

413315

512604

13C-PFOS IS

4.8200

4.5698

nq/mL

13C-PFUnDA IS

Auto

7.737

1609970

1609970

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.737

1609970

975788

13C7-PFUnDA IS

5.0000

6.6629

nq/mL

PFUnDA

Auto

7.737

1210635

1609970

13C-PFUnDA IS

5.0000

3.8413

nq/mL

d5-N-EtFOSAA IS

Auto

7.751

582099

582099

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.751

582099

975788

13C7-PFUnDA IS

5.0000

6.8198

nq/mL

NEtFOSAA

Auto

7.759

473065

582099

dS-N-EtFOSAA IS

5.0000

4.1083

nq/mL

PFOSA

Auto

7.752

481916

415813

13C-FOSA IS

5.0000

5.4089

nq/mL

13C-FOSA IS

Auto

7.752

415813

415813

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.752

415813

975788

13C7-PFUnDA IS

5.0000

6.4739

nq/mL

PFDoA

Auto

8.087

1767286

1482024

13C-PFDoA IS

5.0000

5.3375

nq/mL

13C-PFDoA IS

Auto

8.087

1482024

1482024

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

1330

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:46

CCV3-230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.087

1482024

975788

13C7-PFUnDA IS

5.0000

6.2531

nq/mL

10-2-FtS

Auto

8.100

50854

104148

13C-8 2-FTS IS

4.8200

1.9222

ng/mL

d5-NEtFOSA IS

Auto

8.777

482361

482361

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.777

482361

975788

13C7-PFUnDA IS

5.0000

7.3299

ng/mL

NMeFOSE

Auto

8.500

196947

198784

d7-N-MeFOSE IS

5.0000

6.0676

nq/mL

NEtFOSE

Auto

8.751

724870

157325

d9-EtFOSE IS

5.0000

4.6445

ng/mL

d9-EtFOSE IS

Auto

8.732

157325

157325

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.732

157325

975788

13C7-PFUnDA IS

5.0000

8.3706

ng/mL

NMeFOSA

Auto

8.526

205852

433587

d3-NMeFOSA IS

5.0000

5.1528

nq/mL

dB-NMeFOSA IS

Auto

8.521

433587

433587

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.521

433587

975788

13C7-PFUnDA IS

5.0000

7.2870

nq/mL

d7-N-MeFOSE IS

Auto

8.485

198784

198784

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.485

198784

975788

13C7-PFUnDA IS

5.0000

5.9615

nq/mL

NEtFOSA

Auto

8.787

348903

482361

d5-NEtFOSA IS

5.0000

4.9306

ng/mL

PFTrDA

Auto

8.417

1149974

323188

13C-PFTeDA IS

5.0000

11.7132

nq/mL

PFTeDA

Auto

8.719

1322373

323188

13C-PFTeDA IS

5.0000

11.4279

ng/mL

13C-PFTeDA IS

Auto

8.720

323188

323188

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.720

323188

975788

13C7-PFUnDA IS

5.0000

2.0731

ng/mL

11CI-PF30UdS

Auto

7.887

600839

512604

13C-PFOS IS

4.7100

5.1156

nq/mL

9CI-PF30NS

Auto

7.193

982906

512604

13C-PFOS IS

4.6600

3.8841

ng/mL

L-PFDoS

Auto

8.361

173835

512604

13C-PFOS IS

4.8400

5.0897

nq/mL

NaDONA

Auto

6.431

2033101

1806941

13C-PFNA IS

4.7100

5.3306

ng/mL

PFHxDA

Auto

9.253

248007

3429654

13C2-PFHxDA IS

5.0000

0.8870

nq/mL

PFODA

Auto

9.848

291513

3429654

13C2-PFHxDA IS

5.0000

1.6653

ng/mL

13C2-PFHxDA IS

Auto

9.253

3429654

3429654

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.253

3429654

975788

13C7-PFUnDA IS

5.0000

6.9433

ng/mL

13C7-PFUnDA IS

Auto

7.736

975788

975788

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.657

2024050

512604

13C-PFOS IS

4.6100

4.3507

ng/mL

PFBSA

Auto

6.148

1281250

415813

13C-FOSA IS

5.0000

5.9129

nq/mL

PFHxSA

Auto

6.966

1108150

1806941

13C-PFNA IS

5.0000

4.9658

ng/mL

CHARGE

ND(W/B)

	

	

975788

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

2.0e5 -

13C-PFBA

Cone. 8.6349
2.03e5 Q 217.20>172.30 (-)

2.0e51

O.OeO -

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 5.1046

Q263.05>219.10 (-)
4.0e5 H

PFBA

Cone. 4.6143
2.03e5 Q 213.20> 169.10 (-)

2.0e51

13C-PFPeA IS

Cone. 5.0000
2.04e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 7.4010
4.86e5 Q 267.90>223.00 (-)

O.OeO -

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

A=922152
RT=4.219

f A= 1230861
RT= 5.389

A= 1230861
RT= 5.389

O.OeO -

4.00 4.25 4.50

RT (min)

5.2

5.4

O.OeO

13C-PFBS

Cone. 5.8867

5.6

RT (min)

PFBS

Cone. 5.1447
R#1 298.80>99.00 69.21 (65.16)

1.61e5 Q 299.00>80.00 (-)	1.30e5 ISTD 332.10>287.10 (-)

13C HFPO DA IS

Cone. 5.0000

F[A=343106
-R1 69.21 (--|kT=5.517

A=254105
RT=6.124

L

5.6 5.8
RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

1053

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:46

CCV3-230428 (continued)

13C HFPO DA

Cone. 7.0364

Q 332.10>287.10 (-)
1.0e5 -

O.OeO -

A=254105
RT=6.124

HFPO DA

Cone. 5.3778

R#1 329.00>285.10 76.24 (80.83)
Q 329.00>169.00 (-)	8.68e4

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :



A=199878

-R1 76.24 (--

RT=6.124

^	J

L

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 4.7459

R#1 313.00> 119.10 2.64 (2.51)
Q 313.00>269.00 (-)	8.88e5

t A=2081244

13C-PFHxA IS

Cone. 5.0000

7.5e5 ~

R1 2.64 (-—-l

RT=5-979 6.0e5 ^



RT= 5.979

5.0e5 i



I 4.0e5 f





2.5e5 ~



2.0e5 ~







J

	 n n©n —

/

Vv

U.UcU

	A i

-*1—|—|—|—|—|—|—|— u.ugu

i I i i A i

i i i i i i i i



5.8 6.0 6.2

5.8 6.0 6.2





RT (min)



RT (min)

13C-PFHpA_IS

13C-PFHpA



Cone. 5.0000

Cone. 7.1325



ISTD 366.90>322.10 (-) 7.02e5 Q 366.90>322.10 (-)

7.02e5





A= 1565612



j A= 1565612

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :



6.6

RT (min)

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)
7.5e4 ^

5.0e4 ^

2.5e4 ^

O.OeO 1, i i i

13C2-6 2-FTS

Cone. 5.8584

8.47e4 Q 428.90>409.00 (-)

A=200280
RT=6.692



7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
7.5e5 -
5.0e5 ^

2.5e5 ^

O.OeO 1 , , ,

A= 1897301
RT=6.709

13C-PFOA

Cone. 6.9531

Q 416.80>372.05 (-)
7.5e5 -
5.0e5 ^

2.5e5 ^

O.OeO 1 . . .

RT (min)

A= 1897301
RT=6.709

V,

6.8 7.0
RT (min)

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 23.99 (27.58)
ISTD 329.00>309.15 (-)



fA=230662

- R1 23.99 (—

I

')RT= 5.925

L

6.2 6.4
RT (min)

6.0 6.2
RT (min)

ISTD 314.90>270.10 (-)	6.94e5

A= 1650450

13C-PFHxA

Cone. 7.3042

Q 314.90>270.10 (-)

6.0e5 i
4.0e5 ^

2.0e5 i
O.OeO r . ~. .

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)
2.0e5 -

O.OeO -

6.6

RT (min)

6.2

IR1 66.32 (-

A=344732
RT=6.699

fA=232039

6.0e4 -
4.0e4 :
2.0e4 :
O.OeO :

:R1 95.81 (-—-

Ai

L

6.8 7.0
RT (min)

13C-4 2-FTS

Cone. 7.0677

R#1 329.00>81.00 23.99 (27.58)

4-2-FtS

Cone. 4.4752

R#1 327.00 >81.10 13.79 (16.09)

9.71e4 Q 329.00>309.15 (-)

9.71e4 Q 327.00>307.05 (-)

- R1 23.99 (—

,JA=230662
)RT= 5.925

A=244920

_R1 13.79 (— )rt= 5.925

O.OeO	£

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 5.0787

R#1 349.00>99.00 85.70 (77.24)

O.OeO

6.94e5 Q 349.00>79.95 (-)

6.0 6.2
RT (min)

PFHxS

Cone. 4.4013

R#1 399.00>99.00 94.65 (85.33)
1.47e5 Q 399.00>80.00 (-)	9.63e4

A=337521

:R1 85.70 (- )rt=6.018

A=263873
RT=6.391

6.2
RT (min)

180-PFHxS

Cone. 6.4412

2.12e5 Q 402.70>84.05 (-)
2.0e5 -

6.2	6.2 6.4 6.6

RT (min)	RT (min)

PFHpA

Cone. 4.8591

R#1 362.90>169.00 16.95 (17.91)
2.12e5 Q 362.90>319.00 (-)	1,00e6

O.OeO -

1.0e6-

O.OeO -

A=2269041

-R1 16.95 (—

RT=6.387

-

L

6.4 6.6

RT (min)

PFHpS

Cone. 4.8081

R#1 449.00>99.20 66.32 (66.50)
Q 449.00>80.15 (-)	1.47e5

6.2

6.4

6.6
RT (min)

6-2-FTS

Cone. 4.9525

R#1 427.00>80.90 31.63 (33.45)

6.2

6.4

6.6
RT (min)

PFOA

Cone. 4.7151

R#1 413.00> 169.10 29.85 (27.85)

Q 427.00>407.00 (-)

O.OeO

6.6 6.8

RT (min)

PFOS

Cone. 4.3459

R#1 499.00>99.00 95.81 (86.07)
Q 499.00>80.00 (-)	7.18e4

7.5e4 -

R1 31.63 (—

J RT=6.692

5.0e4 ^





2.5e4 ^



1

0 0<=>0 -

/

Ik

8.07e4 Q 413.00>369.00 (-)

_ R1 29.85 (—

1.02e6

L

RT (min)

6.8 7.0
RT (min)

13C-PFOS IS

Cone. 4.7750

13C-PFOS

Cone. 6.9718

ISTD 502.8
2.0e5 -

105 (-)

~ A=5

ftRT=

512604
7.007

2.16e5 Q 502.80>80.05 (-)
2.0e5 -

6.75 7.00 7.25

RT (min)

7.2

RT (min)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

1052

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A

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:46

CCV3-230428 (continued)

PFNA	13C-PFNA IS

Cone. 3.8521	Cone. 5.0000
R#1 463.00>219.00 23.89 (24.00)

Q 463.00>418.90 (-)	7.01e5	ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 7.4504

7.56e5 Q 467.80>423.00 (-)

6.0e5
4.0e5
2.0e5
O.OeO

- R1 23.89 (•

1

A=1661923

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)
4.0e4 n

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)
2.0e5 -

13C-PFUnDA

Cone. 6.6629

Q 564.80>519.95 (-)
6.0e5 -

7.8 8.0
RT (min)

PFOSA

Cone. 5.4089

R#1 498.20>64.10 0.14 (0.09)
Q 498.20>78.00 (-)	1.93e5

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

A= 1806941
RT=7.031

7.2

RT (min)

13C-8 2-FTS

Cone. 6.4666

4.00e4 Q 528.80> 509.00 (-)
4.0e4 n

7.6
RT (min)

d3-N-MeFOSAA

Cone. 7.2068

2.19e5 Q 572.80>419.05 (-)
2.0e5 -

7.6 7.8
RT (min)

A=1609970
RT=7.737

- R1 17.18 (—

A=1210635
RT=7.737

13C-FOSA IS

Cone. 5.0000

fA= 1806941
RT=7.031

PFNS

Cone. 4.7071

R#1 549.00 >99.00 71.09 (71.23)
Q 549.00>79.95 (-)	2.29e5

fA= 577655

R1 71.09 ( A! RT=7343

8-2-FTS

Cone. 3.5047

R#1 527.20>487.00 9.95 (6.74)
Q 527.10>506.90 (-)	3.48e4

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

f,A=87369

; R1 9.95 (—-;

L*

7.2

RT (min)

6.8

7.0

7.2
RT (min)

PFDA

Cone. 5.4839

R#1 512.90>219.00 18.43 (17.51)
Q 512.90>469.00 (-)	7.31 e5

7.4 7.6
RT (min)

13C-PFDA IS

Cone. 5.0000

3.0e4
2.0e4
1.0e4
O.OeO

13C-PFDA

Cone. 6.4222

7.4 7.6

RT (min)

ISTD 514.80>469.95 (-)

7.05e5 Q 514.80>469.95 (-)

A=1763263
RT=7.378

7.6
RT (min)

7.6
RT (min)

NMeFOSAA

Cone. 4.8618

R#1 570.20>512.00 38.09 (37.68)
Q 570.20>419.00 (-)	1.82e5

7.6
RT (min)

PFDS

Cone. 4.5698

R#1 599.00>99.00 54.52 (65.43)
Q 599.00>80.10 (-)	1.59e5

O.OeO

7.6 7.8
RT (min)

PFUnDA

Cone. 3.8413

R#1 563.00>219.00 17.18 (13.86)
Q563.00>518.90 (-)	4.77e5

A= 556718

R1 38.09 (—-



13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

L

7.25 7.50 7.75

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)
2.0e5 -

1.0e5-

O.OeO -

A= 582099
RT=7.751

d5-N-EtFOSAA

Cone. 6.8198

Q 588.80>419.00 (-)
2.0e5 -

1.0e5-



O.OeO -

^=582099
RT=7.751

v,

7.8 8.0
RT (min)

NEtFOSAA

Cone. 4.1083

R#1 584.20>526.10 65.14 (58.21)
Q 584.20>418.95 (-)	1.54e5

1.5e5
1.0e5
5.0e4
O.OeO



1 A=473065

- R1 65.14 (—-

RT=7.759

-

, V. ~

7.8 8.0
RT (min)

7.6 7.8 8.0
RT (min)

13C-FOSA

Cone. 6.4739

1.61e5

7.6

7.8 8.0
RT (min)

PFDoA

Cone. 5.3375

R#1 613.05> 169.00 16.79 (16.16)
Q 613.05>569.00 (-)	7.02e5

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

5.82e5



fA= 1482024

:



: /



7.8 8.0

RT (min)

7.8 8.0

RT (min)

7.6 7.8 8.0

RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

103©

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:46

CCV3-230428 (continued)

13C-PFDoA

Cone. 6.2531

Q 614.80> 569.95 (-)	5.82e5

RT (min)

NEtFOSE

Cone. 4.6445

Q 629.50> 59.10 (-)	2.85e5

RT (min)

d3-NMeFOSA

Cone. 7.2870

Q 515.10> 169.00 (-)	1.73e5

RT (min)

PFTeDA

Cone. 11.4279

R#1 713.00 >169.30 15.26 (11.66)
Q 713.00>668.90 (0	5.11e5





A=1322373



R1 15.26 (—¦i

RT=8.719

;







	Aii1	

8.6 8.8 9.0
RT (min)

L-PFDoS

Cone. 5.0897

R#1 698.80>98.80 64.15 (71.85)
Q 698.80>80.10 (0	7.20e4

RT (min)

10-2-FtS

Cone. 1.9222

R#1 626.50>81.05 136.48 (76.13)
Q 626.50>607.05 (0	2.12e4

RT (min)

d9-EtFOSE IS

Cone. 5.0000

ISTD 638.90> 59.10 (0	6.18e4

6.0e4 -

4.0e4 ^

2.0e4 ^

O.OeO

8.6 8.8 9.0

RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

I STD 623.00 > 59.00 (0	8.03e4

RT (min)

13C-PFTeDA IS

Cone. 5.0000

I STD 714.80 >669.80 (0	1.26e5

RT (min)

NaDONA

Cone. 5.3306

Q 377.10>251.20(0	9.14e5

RT (min)

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10(0 1.88e5

RT (min)

d9-EtFOSE

Cone. 8.3706

Q 638.90> 59.10 (0	6.18e4

RT (min)

d7-N-MeFOSE

Cone. 5.9615

Q 623.00> 59.00 (0	8.03e4

RT (min)

13C-PFTeDA

Cone. 2.0731

Q 714.80>669.80 (0	1.26e5

RT (min)

PFHxDA

Cone. 0.8870

Q 812.90>769.00 (0	1.06e5

RT (min)

d5-NEtFOSA

Cone. 7.3299

Q 531.10> 169.10 (0	1.88e5

RT (min)

NMeFOSA

Cone. 5.1528

R#1 512.10>219.20 81.57 (76.94)
Q 512.10> 169.20 (0	7.69e4

RT (min)

NEtFOSA

Cone. 4.9306

R#1 526.50>219.20 61.28 (67.00)
Q526.50> 169.10(0	1.41e5

RT (min)

11CI-PF30UdS

Cone. 5.1156

Q 631.00>451.10(0	2.39e5

RT (min)

PFODA

Cone. 1.6653

Q 912.80>869.00 (0	9.87e4

RT (min)

NMeFOSE

Cone. 6.0676

Q 616.10> 58.90 (0	7.85e4

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00(0 1.73e5

RT (min)

PFTrDA

Cone. 11.7132

R#1 663.10> 169.10 28.57 (20.38)
Q 663.10>618.90(0	4.57e5

RT (min)

9CI-PF30NS

Cone. 3.8841

Q 531.00>351.10 (0	3.96e5

2.0e5 -

O.OeO 4^

7.0 7.2 7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

I STD 815.00 >770.00 (0	1.47e6

RT (min)

JA= 157325
! RT=8.732

FA=982906
\ RT=7.193

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

10354

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:46

CCV3-230428 (continued)

13C2-PFHxDA

Cone. 6.9433

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

1.47e6 ISTD 569.80>524.90 (-)

PFecHS	PFBSA

Cone. 4.3507	Cone. 5.9129
R#1 461.00>99.10 42.26 (38.14)

3.78e5 Q 461.00>381.00 (-)	8.38e5	Q 298.00>78.00 (-)

PFHxSA

Cone. 4.9658

5.27e5 Q 397.90>78.00 (-)

A=3429654
RT=9.253

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)
Q 514.80 > 219.10 (+)

5.0e0 -

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

9.4

RT (min)

0.2
RT (min)

fA=975788
RT=7.736

^ A=2024050

7.5e5 - R1 42 26 (" RT=6.657

L

5.0e5 :
2.5e5 :
O.OeO :

L

8.0
RT (min)

6.4 6.6 6.8

RT (min)

A=1281250
RT=6.148

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

-V7?T~

OED

-------
1st /S/AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/Integration
Printed 5/2/2023 11:30:30

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/29/2023 4:35:09 AM

Acquired by: System Administrator

Data File: 230428063

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.222

759343

759343

	 	

5.0000

ng/mL

13C-PFBA

Auto

4.222

759343

825252

13C7-PFUnDA IS

8.6736

nq/mL

PFBA

Auto

4.223

12405

343

13C-PFBA IS

0.0731

ng/mL

13C-PFPeA IS

Auto

5.390

1'

1019646

	 	

5.0000

ng/mL

13C-PFPeA

Auto

5.390

1019646

825252

>FUn[

7.2494

ng/mL

PFPeA

Auto

5.391

19728

1019646

13C-PFPeA IS

0.1051

ng/mL

13C-PFBS IS

Auto

5.520

366921

366921

	 	

4.6500

ng/mL

13C-PFBS

Auto

5.520

21

825252

13C7-PFUnDA IS

5.9449

ng/mL

PFBS

Auto

5.520

5366

366921

13C-PFBS IS

0.0942

nq/mL

13C HFPO DA IS

Auto

6.125

: :87

087

	 	

5.0000

ng/mL

FPO DA

Auto

6.125

206087

825252

13C7-PFllnDA IS

Ml

ng/mL

HFPO DA

Auto

6.123

3139

087

13C HFPO DA IS

0.1041

ng/mL

13C-4 2-FTS IS

Auto

5.927

175492

492

	 	

4.6700

ng/mL

13C-4 2-FTS

Auto

5.927

92

252

13C7-PFUnDA IS

6.3581

nq/mL

4-2-FtS

Auto

5.923

3624

175492

13C-4 2-FTS IS

0.0870

ng/mL

PFHxA

Auto

381

37

1400810

13C-PFHxA IS

0.0874

ng/mL

13C-PFHxA IS

Auto

5.981

10

1400810

	 	

5.0000

ng/mL

13C-PFHxA

Auto

5.981

- '.10

825252

13C7-PFUn[ .

7.3302

ng/mL

PFPeS

Auto

6.019

66

231

180-PFHxS IS

0.0982

ng/mL

PFHxS

Auto

6.392

42

402231

180-PFHxS IS

0.1084

ng/mL

13C-PFHpA IS

Auto

6.388

31

1339531

	 	

5.0000

g/mL

13C-PFHpA

Auto

6.388

1339531

825252

13C7-PFUn[ .

7.2157

ng/mL

kV PI H\s IS

Auto

6.393

402231

402231

	 	

4.7250

g/mL

180-PFHxS

Auto

6.393

402231

825252

13C7-PFUnDA IS

6.4941

nq/mL

PFHpA

Auto

6.389

50

1339531

13C-PFHpA IS

0.0985

ng/mL

5 2-FTS IS

Auto

6.694

162331

162331

	 	

4.7500

ng/mL

2- F

Auto

6.694

162331

OOQQ

13C7-PFUnDA IS

5.6145

ng/mL



Auto

6.703

25

402231

IS

0.1035

ng/mL

6-2-FTS

M

591

3020

162331

13C2-6 2-FTS IS

0.0936

ng/mL

PFOA

Auto

6.710

42223

1578726

13C-PFOA IS

0.0984

ng/mL

13C-PFOA IS

Auto

6.710

1578726

1578726

	 	

5.0000

na/mt.

13C-PFOA

Auto

6.710

1578726

825252

, PFUnDA i'i

6.8410

ng/mL

PFOS

Auto

7.005

4280

424612

13C-PFOS IS

0.0968

ng/mL

FOS IS

Auto

7.006

424612

424612

	 	

4.7750

nq/mL

13C-PFOS

Auto

7.006

424612

825252

>FUn[

6.8285

iL

PFNA

Auto

7.028

29264

1510570

13C-PFNA IS

0.0811

ng/mL

13C-PFNA IS

Auto

7.029

1510570

1510570

	 	

5.0000

iL

13C-PFNA

Auto

7.029

1510570

'• "'¦¦252

13C7-PFUn[ .

7.3646

ng/mL

PFNS

Auto

7.342

9750

612

13C-PFOS IS

0.0959

ng/mL

8-2-FTS

Auto

7.368

08

398

13C-8 2-FTS IS

0.0696

nq/mL

13C-8 2-FTS IS

Auto

7.370

90398

90398

	 	

4.7900

iL

13C-8 2-FTS

Auto

7.370

90398

825252

13C7-PFUn[

567

ng/mL

PFDA

Auto

7.374

30833

1517349

13C-PFDA IS

0.1073

iL

13C-PFDA IS

Auto

7.375

1517349

1517349

	 	

5.0000

ng/mL

13C-PFDA

Auto

7.375

1517349

825252

>FlIn[

6.5346

ng/mL

d3-N-MeFOSAA IS

Auto

7.555

478263

478263

	 	

)00

ng/mL

d3-N-MeFOSAA

Auto

7.555

478263

825252

13C7-PFUnDA IS

540

"i i	

NMeFOSAA

Auto

7.561

7578

478263

d3-N-MeFOSAA IS

0.0798

ng/mL

PFDS

Auto

7.687

5789

424612

13C-PFOS IS

0.0773

iL

13C-PFUnDA IS

Auto

7.731

27

1397927

	 	

5.0000

nq/mL

13C-PFUnDA

Auto

7.731

1397927

825252

13C7-PFllnDA IS

6.8407

"i i	

PFUnDA

Auto

7.731

22433

1397927

13C-PFUnD/

0.0820

ng/mL

ch-N-tthOhAA IS

Auto

7.745

504715

504715

	 	

5.0000

iL

d5-N-EtFOSAA

Auto

7.745

¦ 15

825252

13C7-PFUnDA IS

6.9918

ng/mL

NEtFOSAA

Auto

7.753

8645

715

;tFOS

0.0866

nq/mL

PFOSA

Auto

764

9201

392

13C-FOSA IS

0.1070

ng/mL

3SA IS

Auto

7.765

401392

401392

	 	

5.0000

ng/mL

13C-FOSA

Auto

7.765

401392

825252

13C7-PFUnDA IS

7.3893

ng/mL

PFDoA

Auto

8.079

29533

1308956

130-PFDoA IS

0.1010

ng/mL

13C-PFDoA IS

Auto

8.079

1308956

956

	 	

5.0000

ng/mL

I -sC-PFPoA

Auto





825252

1307 PFUnDA IS

6.5303



C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

TO

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:30:30

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone.

Cone. Unit

10-2-FtS

Auto

8.087

401

90398

13C-8 2-FTS IS

0.0175

nq/mL

d5-NEtFOSA IS

Auto

8.785

469428

469428

—

5.0000

nq/mL

d5-NEtFOSA

Auto

8.785

469428

825252

13C7-PFUnDA IS

8.4346

nq/mL

NMeFOSE

Auto

8.509

3884

200940

d7-N-MeFOSE IS

0.1184

nq/mL

NEtFOSE

Auto

8.759

14487

154499

d9-EtFOSE IS

0.0945

nq/mL

d9-EtFOSE IS

Auto

8.741

154499

154499

—

5.0000

nq/mL

d9-EtFOSE

Auto

8.741

154499

825252

13C7-PFUnDA IS

9.7198

nq/mL

NMeFOSA

Auto

8.534

4067

408990

d3-NMeFOSA IS

0.1079

nq/mL

dB-NMeFOSA IS

Auto

8.529

408990

408990

—

5.0000

nq/mL

dB-NMeFOSA

Auto

8.529

408990

825252

13C7-PFUnDA IS

8.1274

nq/mL

d7-N-MeFOSE IS

Auto

8.493

200940

200940

—

5.0000

nq/mL

d7-N-MeFOSE

Auto

8.493

200940

825252

13C7-PFUnDA IS

7.1254

nq/mL

NEtFOSA

Auto

8.798

6328

469428

d5-NEtFOSA IS

0.0919

nq/mL

PFTrDA

Auto

8.408

23255

296518

13C-PFTeDA IS

0.2582

nq/mL

PFTeDA

Auto

8.710

26274

296518

13C-PFTeDA IS

0.2475

nq/mL

13C-PFTeDA IS

Auto

8.710

296518

296518

—

5.0000

nq/mL

1BC-PFTeDA

Auto

8.710

296518

825252

13C7-PFUnDA IS

2.2489

nq/mL

11CI-PF30UdS

Auto

7.881

9378

424612

13C-PFOS IS

0.0964

nq/mL

9CI-PFBONS

Auto

7.191

18235

424612

13C-PFOS IS

0.0870

nq/mL

L-PFDoS

Auto

8.352

2775

424612

13C-PFOS IS

0.0981

nq/mL

NaDONA

Auto

6.432

33242

1510570

13C-PFNA IS

0.1043

nq/mL

PFHxDA

Auto

9.242

5553

2778332

13C2-PFHxDA IS

-0.0165

nq/mL

PFODA

Auto

9.828

4215

2778332

13C2-PFHxDA IS

0.0297

nq/mL

13C2-PFHxDA IS

Auto

9.243

2778332

2778332

—

5.0000

nq/mL

1BC2-PFHxDA

Auto

9.243

2778332

825252

13C7-PFUnDA IS

6.6507

nq/mL

13C7-PFUnDA IS

Auto

7.731

825252

825252

—

5.0000

nq/mL

PFecHS

Auto

6.658

32158

424612

13C-PFOS IS

0.0834

nq/mL

PFBSA

Auto

6.162

23607

401392

13C-FOSA IS

0.1129

nq/mL

PFHxSA

Auto

6.979

19607

1510570

13C-PFNA IS

0.1051

nq/mL

CHARGE

ND(W/B)

	

	

825252

13C7-PFUnDA IS

— 	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 8.6736
1.67e5 Q 217.20>172.30 (-)

1.5e5 -
1.0e5:
5.0e4 :

'A=759343
RT=4.222

O.OeO

Q263.05>219.10 (-)

A= 19728
RT= 5.391

PFBA

Cone. 0.0731
1.67e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
3.65e3 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 7.2494
4.04e5 Q 267.90>223.00 (-)

A= 12405
RT=4.223

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 0.1051

4.0e5 -

f A=1019646
RT= 5.390

O.OeO

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

O.OeO -

4.0e5 -

f A=1019646
RT= 5.390

O.OeO -

7.17e3 ISTD 301.80>80.00 (-)

5.2

5.4

13C HFPO DA IS

Cone. 5.0000

4.00 4.25 4.50	5.2 5.4 5.6

RT (min)	RT (min)

13C-PFBS	PFBS

Cone. 5.9449	Cone. 0.0942

R#1 298.80>99.00 78.44(65.16)

1.30e5 Q 299.00>80.00 (-)	2.11e3 ISTD 332.10>287.10 (-)

~ A=5366

2.0e3-Rl 78.44 (~ ^T=5.520

5.6

RT (min)

1.30e5 Q 301.80>80.00 (-)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

6.2 6.4
RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:30:30

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 6.7477

Q 332.10>287.10 (-)

7.5e4 ^

5.0e4 i
2.5e4 i
O.OeO 1, , ,

f A=206087
I RT=6.125

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

A= 1339531
RT=6.3

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

6.0e4 :

4.0e4 :

2.0e4 :

O.OeO :

A= 162331
RT=6.694

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
6.0e5
4.0e5 :

2.0e5 ^

O.OeO :



]fA= 1578726



RT=6.710



L

HFPO DA

Cone. 0.1041

R#1 329.00>285.10 59.80 (80.83)
Q 329.00>169.00 (-)	1.41e3

~ A=3139
:R1 59.80 Hl)rt=6.123

6.0 6.2 6.4
RT (min)

PFHxA

Cone. 0.0874

R#1 313.00> 119.10 1.90 (2.51)
Q 313.00>269.00 (-)	1.48e4

f A=32537

:R1 1.90 . RJ= 5.981

W	

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

{A= 1400810
I RT= 5.981

13C-PFHpA

Cone. 7.2157

5.94e5 Q 366.90>322.10 (-)

A= 1339531
RT=6.3

13C2-6 2-FTS

Cone. 5.6145

6.96e4 Q 428.90>409.00 (-)

A= 162331
RT=6.694

RT (min)

RT (min)

13C-PFOA

Cone. 6.8410

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 24.23 (27.58)

ISTD 329.00>309.15 (-)	7.27e4

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

f A= 175492

:R1 2423 (	)RT=5.927

L

6.2 6.4
RT (min)

13C-PFHxA

Cone. 7.3302

5.72e5 Q 314.90>270.10 (-)

FfA= 1400810
JRT= 5.981

6.2
RT (min)

180-PFHxS IS

Cone. 4.7250

5.94e5 ISTD 402.70>84.05 (-)

A=402231
1 RT=6.393

6.2

6.4

O.OeO -

13C-4 2-FTS

Cone. 6.3581

R#1 329.00>81.00 24.23 (27.58)
Q 329.00>309.15 (-)	7.27e4

6.0e4 -
4.0e4z_
2.0e4z_
O.OeO -

?A= 175492

:R1 24.23 (—.r)RT=5.927

4-2-FtS

Cone. 0.0870

R#1 327.00 >81.10 12.02 (16.09)
Q 327.00>307.05 (-)	1.55e3

~ A=3624

-R1 12.02 (-^1=5.923

1.0e3^

5.0e2 ^

O.OeO 1. . . .

6.0 6.2
RT (min)

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 0.0982

R#1 349.00>99.00 68.55 (77.24)
Q 349.00>79.95 (-)	2.49e3

~ A=5566

IR1 68.55 (—H)rt=6.019

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.1084

R#1 399.00>99.00 98.98 (85.33)
Q 399.00>80.00 (-)	1.78e3

If A= 5542

R1 98.98 (--vj)Frr=6 392

6.2
RT (min)

180-PFHxS

Cone. 6.4941

1.79e5 Q 402.70>84.05 (-)

1.5e5-
^.0eSz
5.0e4 ^
O.OeO -

¥ A=402231
RT=6.393

L

6.6
RT (min)

PFHpA

Cone. 0.0985

R#1 362.90> 169.00 18.19 (17.91)
Q 362.90>319.00 (-)	1.66e4

f A=39360
1.5e4^1 18.19 (—rj)RT=6.389

6.6
RT (min)

PFHpS

Cone. 0.1035

R#1 449.00>99.20 38.25 (66.50)
Q 449.00>80.15 (-)	2.99e3

~ A=6325

IR1 38.25 (—| rt=6.703

6.2

6.4

6.6
RT (min)

6-2-FTS

Cone. 0.0936

R#1 427.00>80.90 30.78 (33.45)
Q 427.00>407.00 (-)	1.29e3

- R1 30.78 (—

~ A=3020
l)RT=6.691

6.6
RT (min)

PFOA

Cone. 0.0984

R#1 413.00> 169.10 28.79 (27.85)
Q 413.00>369.00 (-)	1.60e4

^ A=42223

1.5e4-R1 28.79 (--)RT=6710

Ik

6.6 6.8

RT (min)

PFOS

Cone. 0.0968

R#1 499.00>99.00 105.90 (86.07)
Q 499.00>80.00 (-)	1.19e3

i	~ A=4280

1R1 105.90 (---^=7.005

A = 48

6.75 7.00 7.25

RT (min)

RT (min)

13C-PFOS IS

Cone. 4.7750

105 (-)

1.72e5 Q 502.80>80.05 (-)

1.5e5-
1.0e5^
5.0e4 ^
O.OeO -

^A=424612
RT=7.006

1.5e5-
1.0e5:
5.0e4:
O.OeO :

; A=424612
RT=7.006



7.2

RT (min)

7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:30:30

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0811

R#1 463.00>219.00 25.69 (24.00)
Q 463.00>418.90 (-)	1.18e4

~A=29264

25 69 (-;-)RT=7.028

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)
6.0e5 -

13C-PFNA

Cone. 7.3646

Q 467.80>423.00 (-)

'A= 1510570
RT=7.029

7.2

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 6.6367

3.49e4 Q 528.80> 509.00 (-)

A=90398
RT=7.370

7.6
RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 7.0640

1.76e5 Q 572.80>419.05 (-)

478263
T=7.555

7.6 7.

RT (min)

13C-PFUnDA

Cone. 6.8407

Q 564.80>519.95 (-)

7.6 7.8
RT (min)

PFUnDA

Cone. 0.0820

R#1 563.00>219.00 11.01 (13.86)
Q563.00>518.90 (-)	8.87e3

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

O.OeO

7.8 8.0
RT (min)

PFOSA

Cone. 0.1070

R#1 498.20>64.10 0.00 (0.09)
Q 498.20>78.00 (-)	3.64e3

13C-FOSA IS

Cone. 5.0000

13C-FOSA

Cone. 7.3893

7.8 8.0

RT (min)

7.8 8.0

RT (min)

PFNS

Cone. 0.0959

R#1 549.00 >99.00 63.19 (71.23)

8-2-FTS

Cone. 0.0696

R#1 527.20>487.00 17.17 (6.74)

6.33e5 Q 549.00>79.95 (-)

4.24e3 Q 527.10>506.90 (-)

fA=9750	~A=1108

4.0e3 H R1 63.19 (—|}rt=7.342	4.0e2- R1 17-17 (""")RT=7.368

O.OeO -

7.2
RT (min)

PFDA

Cone. 0.1073

R#1 512.90>219.00 19.02 (17.51)
Q 512.90>469.00 (-)	1.23e4

TA=30833
_R1 19.02 (—|;rt=7.374

7.2 7.4 7.6
RT (min)

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)	6.13e5

6.0e51

7.4 7.6

RT (min)

13C-PFDA

Cone. 6.5346

Q 514.80>469.95 (-)

i=1517349
T=7.375

O.OeO

7.4 7.6

RT (min)

NMeFOSAA

Cone. 0.0798

R#1 570.20>512.00 42.54 (37.68)
Q 570.20>419.00 (-)	2.62e3

TA=7578

-R1 42.54 (—i)|RT=7.561

O.OeO

7.2 7.4 7.6

RT (min)

PFDS

Cone. 0.0773

R#1 599.00>99.00 46.95 (65.43)
Q 599.00>80.10 (-)	2.35e3

~ A=5789

, n„, : R1 46 95 (---')RT=7.687

13C-PFUnDA IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

1397927
T=7.731

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 6.9918

1.90e5 Q 588.80>419.00 (-)

1.5e5-
1.0e5-
5.0e4-
O.OeO -

7.8 8.0
RT (min)

7.6

7.8 8.0
RT (min)

PFDoA

Cone. 0.1010

R#1 613.05> 169.00 15.53 (16.16)
Q 613.05>569.00 (-)	1.26e4

O.OeO

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.0866

R#1 584.20>526.10 76.81 (58.21)
Q 584.20>418.95 (-)	2.74e3

fA=8645
IR1 76.81 (—-||rt=7.753

O.OeO

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

5.28e5

7.8 8.0

RT (min)

8.2

RT (min)

1308956

~ A=29533
R1 15.53 (—;^L- 	

J	

i i i i i i

8.2

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

1HB

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:30:30

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 6.5303

Q614.80>569.95 (-)

10-2-FtS

Cone. 0.0175

R#1 626.50>81.05 171.22 (76.13)

d5-NEtFOSA IS

Cone. 5.0000

d5-NEtFOSA

Cone. 8.4346

NMeFOSE

Cone. 0.1184

5.28e5 Q 626.50>607.05 (-)

2.20e2 ISTD 531.10> 169.10 (-)

1.84e5 Q 531.10> 169.10 (-)	1.84e5 Q 616.10>58.90 (-)

A=3884
RT=8.509

Q 629.50>59.10 (-)

ISTD 638.90>59.10 (-)

Q 638.90>59.10 (-)

.6 8.8 9.0

RT (min)

NMeFOSA

Cone. 0.1079

R#1 512.10>219.20 47.56 (76.94)
Q 512.10> 169.20 (-)	1.77e3

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

A=408990
RT=8.529

9.0
RT (min)

9.0
RT (min)

d3-NMeFOSA

Cone. 8.1274

Q 515.10> 169.00 (-)
1.5e5

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 7.1254

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0919

R#1 526.50>219.20 65.49 (67.00)
Q 526.50>169.10 (-)	2.34e3

y A=6328

o - R1 6549 (")rkT=8.798

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.2582

R#1 663.10> 169.10 26.22 (20.38)
Q 663.10>618.90 (-)	9.40e3

fA=23255

: R1 26.22 (—i?)rt=8.408

8.4 8.6

RT (min)

PFTeDA

Cone. 0.2475

R#1 713.00> 169.30 13.21 (11.66)
Q 713.00>668.90 (-)	1.02e4

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 2.2489

O.OeO

8.6 8.8 9.0

RT (min)

11CI-PF30UdS

Cone. 0.0964

9CI-PF30NS

Cone. 0.0870

1.16e5 Q714.80>669.80 (-)

1.16e5 Q 631.00>451.10 (-)

3.88e3 Q 531.00>351.10 (-)

1.0e4

f A=26274
_R1 13.21 (—| RT=8.710

O.OeO

O.OeO -

A= 18235
RT=7.191

8.6 8.8 9.0
RT (min)

L-PFDoS	NaDONA

Cone. 0.0981	Cone. 0.1043
R#1 698.80>98.80 91.11 (71.85)

Q 698.80>80.10 (-)	1,06e3 Q 377.10>251.20 (-)

f A=2775
1.0e3-Rl 91.11 (---J)RT=8.352

8.6 8.8 9.0
RT (min)

8.6 8.8 9.0
RT (min)

PFHxDA

Cone. -0.0165

1.44e4 Q 812.90>769.00 (-)

8.4 8.6
RT (min)

Q 912.80>869.00 (-)

13C2-PFHxDA IS

Cone. 5.0000

1 58e3 ISTD 815.00>770.00 (-)

A=4215
RT=9.a

9.0 9.2 9.4

RT (min)

9.6 9.8 10.0

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

177TO

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:30:30

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 6.6507

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

A=2778332
'T=9.243

1.18e6 ISTD 569.80> 524.90 (-)

T A=825252

PFecHS	PFBSA

Cone. 0.0834	Cone. 0.1129
R#1 461.00>99.10 41.59 (38.14)

3.24e5 Q 461.00>381.00 (-)	1.30e4	Q 298.00>78.00 (-)

PFHxSA

Cone. 0.1051

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)
Q 514.80 > 219.10 (+)

5.0e0 -

0.2
RT (min)

~ A=32158

3.0e5 ^



RT=7.731

1.0e4-

R1 41.59 (—

j)RT=6.658

2.0e5 ^



|





1.0e5 ^



5.0e3 -



I

O.OeO

J

Lj n nQn

I





	A i

—\—|—I—I—I—I—|—I— U.UcU

		 i

i i i i i i i i



7.6

7.8 8.0 6.4 6.6

6.8





RT (min)



RT (min)

7.0 7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

17521

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:50

CCV4-230428

Sample ID: CCV4-230428

Date Acquired: 4/29/2023 4:48:54 AM

Acquired by: System Administrator

Data File: 230428064

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.218

870978

870978

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.218

870978

1033661

13C7-PFUnDA IS

5.0000

7.9428

ng/mL

PFBA

Auto

4.218

887696

870978

13C-PFBA IS

5.0000

4.5585

nq/mL

13C-PFPeA IS

Auto

5.386

1226657

1226657

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.386

1226657

1033661

13C7-PFUnDA IS

5.0000

6.9628

nq/mL

PFPeA

Auto

5.386

1139681

1226657

13C-PFPeA IS

5.0000

5.0461

ng/mL

13C-PFBS IS

Auto

5.515

433813

433813

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.515

433813

1033661

13C7-PFUnDA IS

4.6500

5.6116

ng/mL

PFBS

Auto

5.515

333894

433813

13C-PFBS IS

4.4200

4.9580

nq/mL

13C HFPO DA IS

Auto

6.120

248426

248426

	

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.120

248426

1033661

13C7-PFUnDA IS

5.0000

6.4940

nq/mL

HFPO DA

Auto

6.120

206101

248426

13C HFPO DA IS

5.0000

5.6720

nq/mL

13C-4 2-FTS IS

Auto

5.921

222054

222054

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.921

222054

1033661

13C7-PFUnDA IS

4.6700

6.4230

ng/mL

4-2-FtS

Auto

5.921

234432

222054

13C-4 2-FTS IS

4.6700

4.4496

nq/mL

PFHxA

Auto

5.975

2070523

1672938

13C-PFHxA IS

5.0000

4.6580

ng/mL

13C-PFHxA IS

Auto

5.975

1672938

1672938

	

5.0000

5.0000

i

13C-PFHxA

Auto

5.975

1672938

1033661

13C7-PFUnDA IS

5.0000

6.9892

ng/mL

PFPeS

Auto

6.015

332629

473070

180-PFHxS IS

4.6900

4.9909

nq/mL

PFHxS

Auto

6.388

259836

473070

180-PFHxS IS

4.5500

4.3218

ng/mL

13C-PFHpA IS

Auto

6.383

1542818

1542818

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.383

1542818

1033661

13C7-PFUnDA IS

5.0000

6.6351

ng/mL

180-PFHxS IS

Auto

6.389

473070

473070

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.389

473070

1033661

13C7-PFUnDAJS

4.7250

6.0978

ng/mL

PFHpA

Auto

6.384

2281829

1542818

13C-PFHpA IS

5.0000

4.9587

ng/mL

13C2-6 2-FTS IS

Auto

6.687

194657

194657

	

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.687

194657

1033661

13C7-PFUnDA IS

4.7500

5.3751

ng/mL

PFHpS

Auto

6.695

339676

473070

180-PFHxS IS

4.7600

4.7242

ng/mL

6-2-FTS

Auto

6.687

182612

194657

13C2-6 2-FTS IS

4.7400

4.7201

nq/mL

PFOA

Auto

6.705

2356537

1828531

13C-PFOA IS

5.0000

4.7410

ng/mL

13C-PFOA IS

Auto

6.705

1828531

1828531

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.705

1828531

1033661

13C7-PFUnDA IS

5.0000

6.3259

ng/mL

PFOS

Auto

7.000

223573

498153

13C-PFOS IS

4.6400

4.3088

nq/mL

13C-PFOS IS

Auto

6.999

498153

498153

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

6.999

498153

1033661

13C7-PFUnDA IS

4.7750

6.3959

nq/mL

PFNA

Auto

7.023

1687873

1795393

13C-PFNA IS

5.0000

3.9375

ng/mL

13C-PFNA IS

Auto

7.023

1795393

1795393

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.023

1795393

1033661

13C7-PFUnDA IS

5.0000

6.9883

ng/mL

PFNS

Auto

7.334

564449

498153

13C-PFOS IS

4.8000

4.7330

nq/mL

8-2-FTS

Auto

7.363

89625

109201

13C-8 2-FTS IS

4.7900

3.4268

ng/mL

13C-8 2-FTS IS

Auto

7.364

109201

109201

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.364

109201

1033661

13C7-PFUnDA IS

4.7900

6.4007

ng/mL

PFDA

Auto

7.367

1820770

1811789

13C-PFDA IS

5.0000

5.3066

nq/mL

13C-PFDA IS

Auto

7.367

1811789

1811789

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.367

1811789

1033661

13C7-PFUnDA IS

5.0000

6.2295

nq/mL

d3-N-MeFOSAA IS

Auto

7.548

615612

615612

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.548

615612

1033661

13C7-PFUnDA IS

5.0000

7.2594

nq/mL

NMeFOSAA

Auto

7.552

558949

615612

d3-N-MeFOSAA IS

5.0000

4.5746

nq/mL

PFDS

Auto

7.679

391158

498153

13C-PFOS IS

4.8200

4.4503

nq/mL

13C-PFUnDA IS

Auto

7.723

1691020

1691020

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.723

1691020

1033661

13C7-PFUnDA IS

5.0000

6.6065

nq/mL

PFUnDA

Auto

7.723

1292453

1691020

13C-PFUnDA IS

5.0000

3.9043

nq/mL

d5-N-EtFOSAA IS

Auto

7.737

605927

605927

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.737

605927

1033661

13C7-PFUnDA IS

5.0000

6.7015

nq/mL

NEtFOSAA

Auto

7.744

477608

605927

dS-N-EtFOSAA IS

5.0000

3.9846

nq/mL

PFOSA

Auto

7.759

478125

416858

13C-FOSA IS

5.0000

5.3529

nq/mL

13C-FOSA IS

Auto

7.759

416858

416858

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.759

416858

1033661

13C7-PFUnDA IS

5.0000

6.1268

nq/mL

PFDoA

Auto

8.073

1798762

1573101

13C-PFDoA IS

5.0000

5.1180

nq/mL

13C-PFDoA IS

Auto

8.073

1573101

1573101

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

1772

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)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:50

CCV4-230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.073

1573101

1033661

13C7-PFUnDA IS

5.0000

6.2657

nq/mL

10-2-FtS

Auto

8.085

57782

109201

13C-8 2-FTS IS

4.8200

2.0830

ng/mL

d5-NEtFOSA IS

Auto

8.781

493455

493455

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.781

493455

1033661

13C7-PFUnDA IS

5.0000

7.0787

ng/mL

NMeFOSE

Auto

8.505

208334

222703

d7-N-MeFOSE IS

5.0000

5.7291

nq/mL

NEtFOSE

Auto

8.755

737311

163065

d9-EtFOSE IS

5.0000

4.5579

ng/mL

d9-EtFOSE IS

Auto

8.736

163065

163065

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.736

163065

1033661

13C7-PFUnDA IS

5.0000

8.1903

ng/mL

NMeFOSA

Auto

8.530

200517

437046

d3-NMeFOSA IS

5.0000

4.9795

nq/mL

dB-NMeFOSA IS

Auto

8.525

437046

437046

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.525

437046

1033661

13C7-PFUnDA IS

5.0000

6.9339

nq/mL

d7-N-MeFOSE IS

Auto

8.490

222703

222703

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.490

222703

1033661

13C7-PFUnDA IS

5.0000

6.3049

nq/mL

NEtFOSA

Auto

8.791

356595

493455

d5-NEtFOSA IS

5.0000

4.9260

ng/mL

PFTrDA

Auto

8.402

1175791

383301

13C-PFTeDA IS

5.0000

10.0979

nq/mL

PFTeDA

Auto

8.702

1395113

383301

13C-PFTeDA IS

5.0000

10.1657

ng/mL

13C-PFTeDA IS

Auto

8.703

383301

383301

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.703

383301

1033661

13C7-PFUnDA IS

5.0000

2.3210

ng/mL

11CI-PFBOUdS

Auto

7.875

591395

498153

13C-PFOS IS

4.7100

5.1813

nq/mL

9CI-PF30NS

Auto

7.185

1009171

498153

13C-PFOS IS

4.6600

4.1036

ng/mL

L-PFDoS

Auto

8.348

178870

498153

13C-PFOS IS

4.8400

5.3891

nq/mL

NaDONA

Auto

6.428

1921199

1795393

13C-PFNA IS

4.7100

5.0696

ng/mL

PFHxDA

Auto

9.235

269303

3371116

13C2-PFHxDA IS

5.0000

0.9843

nq/mL

PFODA

Auto

9.818

344647

3371116

13C2-PFHxDA IS

5.0000

2.0030

ng/mL

13C2-PFHxDA IS

Auto

9.236

3371116

3371116

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.236

3371116

1033661

13C7-PFUnDA IS

5.0000

6.4427

ng/mL

13C7-PFUnDA IS

Auto

7.723

1033661

1033661

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.653

2009329

498153

13C-PFOS IS

4.6100

4.4443

ng/mL

PFBSA

Auto

6.156

1284602

416858

13C-FOSA IS

5.0000

5.9135

nq/mL

PFHxSA

Auto

6.974

1087172

1795393

13C-PFNA IS

5.0000

4.9031

ng/mL

CHARGE

ND(W/B)

	

	

1033661

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 7.9428
1.96e5 Q 217.20>172.30 (-)

PFBA

Cone. 4.5585
Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
1,93e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 6.9628
4.85e5 Q 267.90>223.00 (-)

O.OeO -t^p

A=887696
RT=4.218

O.OeO -t^p

r A= 1226657
RT= 5.386

A= 1226657
RT= 5.386

O.OeO -

O.OeO -

5.2

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 5.0461	Cone. 4.6500	Cone. 5.6116 Cone. 4.9580

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)

3.95e5 I STD 301.80 > 80.00 (-)
1.5e5 -

A=433813
RT=5.515

1.56e5 Q 301.80>80.00 (-)
1.5e5 -

R#1 298.80>99.00 72.47 (65.16)

1.56e5 Q 299.00>80.00 (-)	1.20e5 ISTD 332.10>287.10 (-)	1.05e5

:A=433813
RT=5.515

r A=333894
H R1 72.47 (--|[kT=5.515

1.0e5 -
5.0e4 ^
O.OeO :

5.6 5.8
RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

175*6

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:50

CCV4-230428 (continued)

13C HFPO DA

Cone. 6.4940

Q 332.10>287.10 (-)
1.0e5 -

A=248426
RT=6.120

HFPO DA

Cone. 5.6720

R#1 329.00>285.10 76.26 (80.83)
Q 329.00>169.00 (-)	8.58e4

rA=206101

7.5e4-|R1 7626 pT=6.120

O.OeO -





6.0

6.2 6.4
RT (min)

PFHxA

Cone. 4.6580

R#1 313.00> 119.10 2.70 (2.51)
Q 313.00>269.00 (-)	8.41 e5

f A=2070523

7.5e5^R1 270 (— RT=5.975

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 21.58 (27.58)

ISTD 329.00>309.15 (-)	8.96e4

A=222054

R1 21.58 ( i'll RT = 5.921

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

6.82e5 Q 314.90>270.10 (-)

A=1672938
RT= 5.975

13C-PFHpA_IS

Cone. 5.0000

13C-PFHpA

Cone. 6.6351

13C2-6 2-FTS IS

Cone. 4.7500

13C2-6 2-FTS

Cone. 5.3751

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

6.0e5 ^

4.0e5 i
2.0e5 ^

O.OeO 1 . . . .

13C-PFOA

Cone. 6.3259

7.38e5 Q 416.80>372.05 (-)

6.0e5 ^

4.0e5 i
2.0e5 ^

= O.OeO 1 , , ,

6.8 7.0
RT (min)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

fA= 1672938
RT= 5.975

6.2
RT (min)

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)
2.0e5 H

A=473070
RT=6.389

O.OeO -



6.6

RT (min)

6.2

6.4

O.OeO -

~z R1 94.26 (-—

RT=7.000

I A

V ~

6.8 7.0
RT (min)

13C-4 2-FTS

Cone. 6.4230

R#1 329.00>81.00 21.58 (27.58)
Q 329.00>309.15 (-)	8.96e4

4-2-FtS

Cone. 4.4496

R#1 327.00 >81.10 17.00 (16.09)
Q 327.00>307.05 (-)	9.44e4

A=234432
)RT= 5.921

6.0 6.2
RT (min)

6.0 6.2
RT (min)

PFPeS

Cone. 4.9909

R#1 349.00>99.00 84.83 (77.24)
Q 349.00>79.95 (-)	1.37e5

6.0 6.2
RT (min)

PFHxS

Cone. 4.3218

R#1 399.00>99.00 94.57 (85.33)
Q 399.00>80.00 (-)	9.26e4

180-PFHxS

Cone. 6.0978

Q 402.70>84.05 (-)
2.0e5 H

6.6
RT (min)

PFHpA

Cone. 4.9587

R#1 362.90>169.00 17.25 (17.91)
Q 362.90>319.00 (-)	9.96e5

O.OeO -

O.OeO



]T A=2281829

-R1 17.25 (—

|RT=6.384

: i

Vv

6.6
RT (min)

PFHpS

Cone. 4.7242

R#1 449.00>99.20 65.19 (66.50)
Q 449.00>80.15 (-)	1.42e5

TA=339676

-R1 65.19 (—Irt=6.695

6.2

6.4

6.6
RT (min)

6-2-FTS

Cone. 4.7201

R#1 427.00>80.90 29.46 (33.45)

6.2

6.4

6.6
RT (min)

PFOA

Cone. 4.7410

R#1 413.00> 169.10 29.57 (27.85)

Q 427.00>407.00 (-)

7.76e4 Q 413.00>369.00 (-)

9.68e5

fA= 182612

: R1 29.46 (—A rt=6.687

: R1 29.57 (—

6.0e4 -
4.0e4z_
2.0e4z_
O.OeO -

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

6.6 6.8

RT (min)

PFOS

Cone. 4.3088

R#1 499.00>99.00 94.26 (86.07)
Q 499.00>80.00 (-)	6.95e4

6.0e4
4.0e4
2.0e4
O.OeO

RT (min)

13C-PFOS IS

Cone. 4.7750

13C-PFOS

Cone. 6.3959

ISTD 502.8
2.0e5 H

105 (-)

fA=498153
RT=6.999

2.05e5 Q 502.80>80.05 (-)
2.0e5 H

6.8 7.0
RT (min)

'A=498153
i RT=6.999

6.75 7.00 7.25

RT (min)

/ V,



7.2

RT (min)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:50

CCV4-230428 (continued)

PFNA	13C-PFNA IS

Cone. 3.9375	Cone. 5.0000
R#1 463.00>219.00 24.05 (24.00)

Q 463.00>418.90 (-)	6.95e5	ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 6.9883

7.32e5 Q 467.80>423.00 (-)

PFNS

Cone. 4.7330

R#1 549.00 >99.00 68.69 (71.23)
Q 549.00>79.95 (-)	2.25e5

8-2-FTS

Cone. 3.4268

R#1 527.20>487.00 6.68 (6.74)
Q 527.10>506.90 (-)	3.61e4

=1795393
T=7.023

7.2

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)
4.0e4 H

=109201
:T=7.364

13C-8 2-FTS

Cone. 6.4007

4.15e4 Q 528.80> 509.00 (-)
4.0e4 H

7.2
RT (min)

PFDA

Cone. 5.3066

R#1 512.90>219.00 18.20 (17.51)
Q 512.90>469.00 (-)	7.31 e5

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 6.2295

ISTD 514.80>469.95 (-)

7.19e5 Q 514.80>469.95 (-)

1811789
=7.367

7.6
RT (min)

7.6
RT (min)

d3-N-MeFOSAAJS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 7.2594

2.27e5 Q 572.80>419.05 (-)

7.6
RT (min)

NMeFOSAA

Cone. 4.5746

R#1 570.20>512.00 37.91 (37.68)
Q 570.20>419.00 (-)	1.80e5

7.6
RT (min)

PFDS

Cone. 4.4503

R#1 599.00>99.00 55.94 (65.43)
Q 599.00>80.10 (-)	1.52e5

13C-PFUnDA_IS

Cone. 5.0000

O.OeO -

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

=558949

R1 37.91 (—fl)|RT=7.552



7.6 7.8
RT (min)

7.4

13C-PFUnDA

Cone. 6.6065

7.6 7.8
RT (min)

PFUnDA

Cone. 3.9043

R#1 563.00>219.00 15.39 (13.86)
Q563.00>518.90 (-)	4.99e5

IR1 15.39 (--

7.25 7.50 7.75

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

d5-N-EtFOSAA

Cone. 6.7015

2.36e5 Q 588.80>419.00 (-)

7.8 8.0
RT (min)

NEtFOSAA

Cone. 3.9846

R#1 584.20>526.10 63.93 (58.21)
Q 584.20>418.95 (-)	1.56e5

O.OeO

7.8 8.0
RT (min)

PFOSA

Cone. 5.3529

R#1 498.20>64.10 0.11 (0.09)
Q 498.20>78.00 (-)	1.90e5

O.OeO -

1.5e5-
1.0e5:
5.0e4^
O.OeO:

R1 63.93 (—

^=477608
|RT=7.744



7.8 8.0
RT (min)

7.6

13C-FOSA IS

Cone. 5.0000

13C-FOSA

Cone. 6.1268

7.8 8.0
RT (min)

PFDoA

Cone. 5.1180

R#1 613.05> 169.00 17.36 (16.16)
Q 613.05>569.00 (-)	7.12e5

A=1798762

: R1 17.36 (-- )rj=8.073

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)
6.0e5 H

6.19e5

A= 1573101

rr=8.073

4.0e5 :
2.0e5 ^
O.OeO :

7.8 8.0

RT (min)

7.8 8.0

RT (min)

7.8 8.0

RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

17E5

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:50

CCV4-230428 (continued)

13C-PFDoA

Cone. 6.2657

Q614.80>569.95 (-)
6.0e5 -

4.0e5 ^

2.0e5 ^

O.OeO I,,,,

A= 1573101
fl"=8.073

10-2-FtS

Cone. 2.0830

R#1 626.50 >81.05 125.31 (76.13)
Q 626.50>607.05 (-)	2.37e4

A= 57782

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 7.0787

1.93e5 Q 531.10> 169.10 (-)

3.0e4 -

R1 125.39TH

RT (min)

RT (min)

NEtFOSE

Cone. 4.5579

Q629.50>59.10 (-)

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 8.1903

9.0
RT (min)

d3-NMeFOSA

Cone. 6.9339

Q 515.10> 169.00 (-)
1.5e5-
1.0e5-
5.0e4 -
O.OeO -

d7-N-MeFOSEJS

Cone. 5.0000

1,65e5 ISTD 623.00> 59.00 (-)

7.5e4 i
5.0e4 i
2.5e4 i
— O.OeO 1, i i i

d7-N-MeFOSE

Cone. 6.3049

8.76e4 Q 623.00> 59.00 (-)

7.5e4 i
5.0e4 i
2.5e4 i
— O.OeO -I. r~. .

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 10.1657

R#1 713.00 >169.30 13.79 (11.66)
Q 713.00>668.90 (-)	5.37e5

R1 13.79 (--

RT (min)

13C-PFTeDA IS

Cone. 5.0000

13C-PFTeDA

Cone. 2.3210

ISTD 714.80>669.80 (-)

1.47e5 Q714.80>669.80 (-)

O.OeO -

f A=383301
TT=8.703

A=383301
T=8.703

8.6

.8 9.0
RT (min)

L-PFDoS

Cone. 5.3891

R#1 698.80>98.80 65.95 (71.85)
Q 698.80>80.10 (-)	7.40e4

9.0
RT (min)

6.0e4 -
4.0e4 :
2.0e4 :
O.OeO :

fA= 178870

: R1 65.95 (--Mt=8.348

B.2 8.4 8.6

RT (min)

NaDONA

Cone. 5.0696

Q377.10>251.20 (-)
7.5e5 ^

5.0e5 ^

2.5e5 ^

O.OeO 1 . . . r:

PFHxDA

Cone. 0.9843

8.32e5 Q 812.90>769.00 (-)

A= 1921199
RT=6.428

6.2

6.4

6.6

RT (min)

NMeFOSE

Cone. 5.7291

9.0

RT (min)

7.5e4-

9.0
RT (min)

NMeFOSA

Cone. 4.9795

R#1 512.10>219.20 75.68 (76.94)
Q 512.10> 169.20 (-)	7.80e4

R1 75.68 (- 3.53o

9.0
RT (min)

:R1 61.19 (-

RT (min)

11CI-PF30UdS

Cone. 5.1813

1.47e5 Q 631.00>451.10 (-)

9.0
RT (min)

PFODA

Cone. 2.0030

1.15e5 Q 912.80>869.00 (-)

9.4

RT (min)

RT (min)

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 4.9260

R#1 526.50>219.20 61.19 (67.00)
Q 526.50>169.10 (-)	1.40e5

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)
1.5e5-
1.0e5-
5.0e4-
O.OeO -

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 10.0979

R#1 663.10> 169.10 26.24 (20.38)
Q 663.10>618.90 (-)	4.61 e5

f A= 1175791

40esT1 2624 (" Ut=8.402

O.OeO -

^t=FF

8.2 8.4 8.6

RT (min)

9CI-PF30NS

Cone. 4.1036

Q 531.00>351.10 (-)
4.0e51

4.10e5

RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

1.18e5 I STD 815.00 > 770.00 (-)

A=3371116
T=9.236

9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

177B

-------
A

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:50

CCV4-230428 (continued)

13C2-PFHxDA

Cone. 6.4427

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

1.45e6 ISTD 569.80>524.90 (-)

PFBSA

Cone. 5.9135

=3371116
RT=9.236

9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)
Q 514.80 > 219.10 (+)

5.0e0 -

0.2
RT (min)

PFecHS

Cone. 4.4443
R#1 461.00>99.10 39.30 (38.14)

3.92e5 Q 461.00>381.00 (-)	8.12e5 Q 298.00>78.00 (-)

fA=2009329
7.5e5 - R1 39.30 (---||rt=6.653

5.0e5 :

2.5e5 :

O.OeO :

8.0
RT (min)

6.4 6.6 6.8

RT (min)

*A= 1284602
RT=6.156

PFHxSA

Cone. 4.9031

5.12e5 Q 397.90>78.00 (-)
4.0e5 -

2.0e5 -

~ A= 1087172
I RT=6.974

Vj

/ Vt

6.4
RT (min)

7.2
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

W?

-------
1st /S/AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/Integration
Printed 5/2/2023 11:31:18

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/29/2023 7:47:41 AM

Acquired by: System Administrator

Data File: 230428077

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 1

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.199

780199

780199

	 	

5.0000

nq/ml

13C-PFBA

Auto

4.199

780199

920414

13C7-PFUn[

7.9904

nc

l/ml

PFBA

Auto

4.152

243

780199

'BG-PF

0.0014

nt

j/mL

13C-PFPeA IS

Auto

5.373

1114956

1114956

	 	

5.0000

nc

j/mL

13C-PFPeA

Auto

5.373

1114956

920414

13C7-PFllnDA IS

7.1075

nt

j/mL

PFPeA

?B)

	

	

1114956

13C-PFPeA IS

	

nc

j/mL

13C-PFBS IS

Auto

5.503

355342

355342

	 	

4.6500

nc

j/mL

13C-PFBS

Auto

5.503

¦¦¦¦¦¦¦¦¦ 42

920414

13C7-PFUnDA IS

520

nc

j/mL

PFBS

Auto

5.541

54

342

13C-PFBS IS

0.0046

nc

mL

13C HFPO DA IS

Auto

6.109

204292

292

	 	

5.0000

nc

j/mL

FPO DA

Auto

6.109

204292

414

13C7-PFUnDA IS

5.9974

nc

j/mL

HFPO DA

'B>

	

	

204292

13C HFPO DA IS

	

nc

j/mL

13C-4 2-FTS IS

Auto

5.909

203818

203818

	 	

4.6700

nc

j/mL

13C-4 2-FTS

Auto

5.909

203818

920414

13C7-PFUn[

6.6209

nc

j/mL

4-2-FtS

N D( W/B)

	

	

203818

13C-4 2-FTS IS

	



j/mL

PFHxA

Auto

5.965

3119

•' ..910

13C-PFHxA

0.0080

nc

j/mL

13C-PFHxA IS

Auto

5.963

1464910

1464910

	 	

5.0000



j/mL

13C-PFHxA

Auto

5.963

1464910

920414

13C7-PFUnDA IS

6.8731

nc

j/mL

PFPeS

N

	

	

414171

180-PFHxS IS

	

nq/mL

PFHxS

IV

6.373

884

171

1?:

0.0168

ng/ml

13C-PFHpA IS

Auto

6.371

1387941

1387941

	 	

5.0000

ng/mL

13C-PFHpA

Auto

6.371

1387941

414

13C7-PFUnDA IS

6.7035

ng/ml

kV PI H\s IS

Auto

6.377

414171

171

	 	

4.7250

ng/mL

180-PFHxS

Auto

6.377

414171

414

13C7-PFUnDA IS

D55

nq/ml

PFHpA

Auto

6.373

1160

1387941

:HpA IS

0.0028

ng/mL

5 2-FTS IS

Auto

6.674

184763

763

	 	

4.7500

ng/ml

2- F

Auto

574

184763

920414

13C7-PFUnDA IS

5.7296

ng/mL



N



	

414171

180-PFHxS IS

	

ng/ml

6-2-FTS

Auto

6.565

102

184763

13C2-6 2-FTS IS

0.0028

nq/mL

PFOA

Auto

6.694

3048

1780326

13C-PFOA IS

0.0063

ng/ml

13C-PFOA IS

Auto

6.692

1780326

1780326

	 	

5.0000

ng/mL

13C-PFOA

Auto

6.692

1780326

920414

13C7-PFUnDA IS

6.9169

ng/ml

PFOS

Auto

6.987

1110

444929

nc-PFOS is

0.0239

ng/mL

FOS IS

Auto

6.984

444929

444929

— —

4.7750

ng/ml

13C-PFOS

Auto

6.984

444929

920414

13C7-PFUnDA IS

6.4154

iL

PFNA

Auto

7.009

1385

1660346

13C-PFNA IS

0.0035

ng/ml

13C-PFNA IS

Auto

7.005

1660346

1660346

	 	

5.0000

iL

13C-PFNA

Auto

7.005

1660346

920414

13C7-PFUnDA IS

7.2578

ng/ml

PFNS

'B)

	

	

929

13C-PFOS IS

	

nq/mL

8-2-FTS

NDCW/B)

	

	

84336

13C-8

	

ng/ml

13C-8 2-FTS IS

Auto

7.341

84336

84336

	 	

4.7900

ng/mL

13C-8 2-FTS

Auto

7.341

84336

920414

13C7-PFUnDA IS

5.5515

ng/ml

PFDA

Auto

7.351

598

1462714

13C-PFDA IS

0.0022

nc

j/mL

13C-PFDA IS

Auto

7.345

14

1462714

	 	

5.0000

ng/ml

13C-PFDA

Auto

7.345

14

920414

13C7-PFUnDA IS

5.6480

nq/mL

d3-N-MeFOSAA IS

Auto

7.523

438983

438983

	 	

5.0000

ng/ml

cB-N-MeFOSAA

Auto

7.523

438983

920414

)A IS

5.8135

nq/mL

NMeFOSAA

Auto

7.524

469

438983

d3-N-MeFOSAA IS

0.0054

ng/ml

PFDS

ND(W/B)

	

	

444929

13C-PFOS IS

	

ng/mL

13C-PFUnDA IS

Auto

7.697

1439422

1439422

	 	

5.0000

ng/ml

13C-PFUnDA

Auto

7.697

1439422

920414

13C7-PFUnDA IS

6.3155

nq/mL

PFUnDA

Auto

7.630

904

1439422

13C-PFUnDA IS

0.0032

ng/ml

(IS- N- EtFOSAA IS

Auto

7.710

525883

525883

	 	

5.0000

ng/mL

d5-N-EtFOSAA

Auto

7.710

525883

920414

13C7-PFUnDA IS

6.5319

ng/ml

NEtFOSAA

Auto

7.699

893

525883

s|*> N EtFOSAA IS

)86

nq/mL

PFOSA

Auto

764

39

544

13C-FOSA IS

0.0032

ng/ml

3SA IS

Auto

7.758

44

544

	 	

5.0000

nq/mL

13C-FOSA

Auto

7.758

352544

920414

13C7-PFUnDA IS

5.8191

ng/ml

PFDoA

Auto

8.112

1414

1313242

13C-PFDoA IS

0.0048

nq/mL

13C-PFDoA IS

Auto

8.045

1313242

1313242

	 	

5.0000

nq/mL

KC-PFPoA	Auto	j i j V 12 °20414 1SCPFUnDA.JS

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

17®

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:31:18

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone.

Cone. Unit

10-2-FtS

ND(W/B)

	

—

84336

13C-8 2-FTS IS

— —

nq/mL

d5-NEtFOSA IS

Auto

8.780

350770

350770

—

5.0000

nq/mL

d5-NEtFOSA

Auto

8.780

350770

920414

13C7-PFUnDA IS

5.6510

nq/mL

NMeFOSE

ND(W/B)

	

	

185217

d7-N-MeFOSE IS

— 	

nq/mL

NEtFOSE

Auto

8.766

327

138868

d9-EtFOSE IS

0.0024

nq/mL

d9-EtFOSE IS

Auto

8.735

138868

138868

—

5.0000

nq/mL

d9-EtFOSE

Auto

8.735

138868

920414

13C7-PFUnDA IS

7.8331

nq/mL

NMeFOSA

ND(W/B)

—

—

327783

d3-NMeFOSA IS

— —

nq/mL

dB-NMeFOSA IS

Auto

8.524

327783

327783

—

5.0000

nq/mL

dB-NMeFOSA

Auto

8.524

327783

920414

13C7-PFUnDA IS

5.8402

nq/mL

d7-N-MeFOSE IS

Auto

8.487

185217

185217

—

5.0000

nq/mL

d7-N-MeFOSE

Auto

8.487

185217

920414

13C7-PFUnDA IS

5.8888

nq/mL

NEtFOSA

Auto

9.048

199

350770

d5-NEtFOSA IS

0.0039

nq/mL

PFTrDA

Auto

8.209

630

284029

13C-PFTeDA IS

0.0073

nq/mL

PFTeDA

Auto

8.684

2500

284029

13C-PFTeDA IS

0.0246

nq/mL

13C-PFTeDA IS

Auto

8.674

284029

284029

—

5.0000

nq/mL

1BC-PFTeDA

Auto

8.674

284029

920414

13C7-PFUnDA IS

1.9315

nq/mL

11CI-PF30UdS

ND(W/B)

	

	

444929

13C-PFOS IS

— 	

nq/mL

9CI-PFBONS

ND(W/B)

—

—

444929

13C-PFOS IS

— —

nq/mL

L-PFDoS

ND(W/B)

—

—

444929

13C-PFOS IS

— —

nq/mL

NaDONA

Auto

6.676

176

1660346

13C-PFNA IS

0.0005

nq/mL

PFHxDA

Auto

9.202

985

2560063

13C2-PFHxDA IS

-0.0373

nq/mL

PFODA

ND(W/B)

—

—

2560063

13C2-PFHxDA IS

— —

nq/mL

13C2-PFHxDA IS

Auto

9.205

2560063

2560063

—

5.0000

nq/mL

1BC2-PFHxDA

Auto

9.205

2560063

920414

13C7-PFUnDA IS

5.4946

nq/mL

13C7-PFUnDA IS

Auto

7.697

920414

920414

—

5.0000

nq/mL

PFecHS

Auto

6.863

138

444929

13C-PFOS IS

0.0003

nq/mL

PFBSA

Auto

6.154

76

352544

13C-FOSA IS

0.0004

nq/mL

PFHxSA

Auto

6.983

319

1660346

13C-PFNA IS

0.0016

nq/mL

CHARGE

ND(W/B)

	

	

920414

13C7-PFUnDA IS

— 	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 7.9904
1.72e5 Q 217.20>172.30 (-)

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

~ A=780199
RT=4.199

4.00 4.25 4.50

RT (min)

PFPeA

Cone. —

Q263.05>219.10 (-)

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

A=780199
RT=4.199

PFBA

Cone. 0.0014
1.72e5 Q 213.20> 169.10 (-)
A=243
6.0e2 ~\A RT=^V 2

4.0e2 -

2.0e2 -

O.OeO -

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

9.71e2 ISTD 301.80>80.00 (-)

1.34e5 Q 301.80>80.00 (-)

=355342
i|RT= 5.503

13C-PFPeA IS

Cone. 5.0000
6.35e2 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 7.1075
4.45e5 Q 267.90>223.00 (-)

=1114956
T= 5.373

O.OeO

4.00 4.25 4.50

RT (min)

13C-PFBS

Cone. 5.1620

=1114956
T= 5.373

O.OeO

5.6

RT (min)

PFBS

Cone. 0.0046
R#1 298.80>99.00 0.00 (65.16)

1.34e5 Q 299.00>80.00 (-)	7.30e1 ISTD 332.10>287.10 (-)

13C HFPO DA IS

Cone. 5.0000

~ A=254

R1 0.00 (—-)J rt= 5.541

5.6 5.8
RT (min)

204292
|RT=6.109



6.2 6.4
RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MODJ\JewCaUproc

1S®

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:31:18

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 5.9974

Q 332.10>287.10 (-)

7.5e4 :

5.0e4 :

2.5e4 :

O.OeO :

=204292
|RT=6.109

HFPO DA

Cone. —

R#1 329.00 >285.10

Q 329.00>169.00 (-)

1.5e2 ^

1.0e2 "i
5.0e1 i /1j
O.OeO-

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 27.21 (27.58)

ISTD 329.00>309.15 (-)	8.52e4

fA=203818
7.5e4 - R1 2721 ("""fcr= 5.909

5.0e4 :
2.5e4 :
O.OeO :

13C-4 2-FTS

Cone. 6.6209

R#1 329.00>81.00 27.21 (27.58)
Q 329.00>309.15 (-)	8.52e4

Y A=203818
7.5e4:R1 2721 H ^=5.909

5.0e4 -
2.5e4 ^
O.OeO -

4-2-FtS

Cone. —

R#1 327.00>81.10 —- (16.09)
Q 327.00>307.05 (-)	I.IOel

1.5e2-
1.0e2-j
5.0e1 :
O.OeO :



6.0 6.2 6.4
RT (min)

PFHxA

Cone. 0.0080

R#1 313.00>119.10 1.55 (2.51)
Q 313.00>269.00 (-)	1.75e3

6.2 6.4
RT (min)

6.0 6.2
RT (min)

13C-PFHxA IS

Cone. 5.0000

13C-PFHxA

Cone. 6.8731

I STD 314.90 >270.10 (-)

Q 314.90>270.10 (-)

5.8 6.0 6.2
RT (min)

PFPeS

Cone. —

R#1 349.00>99.00 — - (77.24)
Q 349.00>79.95 (-)	1.30e1

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.0168

R#1 399.00>99.00 64.34 (85.33)
Q 399.00>80.00 (-)	3.76e2

~ A=

: R1 64.34 (~|



^T=6.373



6.2

RT (min)

6.2

6.4

13C-PFHpA IS

Cone. 5.0000

I STD 366.90 >322.10 (-)
6.0e5 -

Q 366.90>322.10 (-)
6.0e5 -

180-PFHxS IS

Cone. 4.7250

6.22e5 I STD 402.70>84.05 (-)

180-PFHxS

Cone. 5.9955

1.88e5 Q 402.70>84.05 (-)

=414171
T=6.377

6.6
RT (min)

PFHpA

Cone. 0.0028

R#1 362.90 >169.00 18.74 (17.91)
Q 362.90>319.00 (-)	9.32e2

f A=1160

= R1 18.74 (—-bT=6.373

13C2-6 2-FTS IS

Cone. 4.7500

I STD 428.90>409.00 (-)
7.5e4 :

5.0e4 :

2.5e4 :

O.OeO :

=184763
T=6.674

13C2-6 2-FTS

Cone. 5.7296

Q 428.90>409.00 (-)
7.5e4 -

6.6
RT (min)

PFHpS

Cone. —

R#1 449.00>99.20 — - (66.50)

4.30e1

6.2

6.4

6.6
RT (min)

6-2-FTS

Cone. 0.0028

R#1 427.00>80.90 0.00 (33.45)
Q 427.00>407.00 (-)	6.60e1

6.6
RT (min)

PFOA

Cone. 0.0063

R#1 413.00> 169.10 15.35 (27.85)
Q 413.00>369.00 (-)	1.54e3

f A=3048



RT (min)

13C-PFOA IS

Cone. 5.0000

iSTD 416.80>372.05 (-)

7.65e5 Q416.80>372.05 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

IF

1780326
6.692

~^~r
6.8 7.0
RT (min)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

=1780326
RT=6.692

6.6 6.8

RT (min)

PFOS

Cone. 0.0239

R#1 499.00>99.00 49.47 (86.07)
Q 499.00>80.00 (-)	2.68e2

~ A= 1110

105 (-)



R1 49.47 (—i

)|RT=6.987

2.0e2 -





1.0e2 -



I A=60

— O.OeO -



[uRT=7.305

1.5e5-
1.0e5^
5.0e4 ^
O.OeO -

A=444929
'T=6.984

L

1.82e5 Q 502.80>80.05 (-)

^.SeS1_

"{.OeS-
S.0e4z_

O.OeO 1. . . .

a=444929
RT=6.984

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

7.2

RT (min)

7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

ttO

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:31:18

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0035

R#1 463.00>219.00 21.88 (24.00)
Q 463.00>418.90 (-)	2.65e2

_i	ifA=1385

-R1 21.88 ("""-^7=7 009

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 7.2578

6.77e5 Q 467.80>423.00 (-)

A=1660346
'T=7.005

7.2

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

13C-8 2-FTS

Cone. 5.5515

7.6
RT (min)

7.2

7.4

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)
1.5e5 -

d3-N-MeFOSAA

Cone. 5.8135

Q 572.80>419.05 (-)

7.6 7.

RT (min)

13C-PFUnDA

Cone. 6.3155

Q 564.80>519.95 (-)

7.6 7.8
RT (min)

PFUnDA

Cone. 0.0032

R#1 563.00>219.00 0.00 (13.86)
Q563.00>518.90 (-)	5.31e2

*A=904

-R1 0.00.1^7

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

O.OeO

7.8 8.0
RT (min)

PFOSA

Cone. 0.0032

R#1 498.20>64.10 0.00 (0.09)
Q 498.20>78.00 (-)	1.55e2

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

13C-FOSA

Cone. 5.8191

1.42e5 Q 506.00>78.05 (-)

1.5e2 -

,f A=239

R1 0.00 (—|-| rj=7.764

A=352544
RT=7.758

7.8 8.0

RT (min)

7.8 8.0

RT (min)

PFNS

Cone. —

R#1 549.00 >99.00 — - (71.23)
Q 549.00>79.95 (-)	O.OOeO

8-2-FTS

Cone. —

R#1 527.20>487.00 — - (6.74)
Q 527.10>506.90 (-)	O.OOeO

5.0e0 n	i

7.2
RT (min)

PFDA

Cone. 0.0022

R#1 512.90>219.00 20.39 (17.51)
Q 512.90>469.00 (-)	5.00e2

~ A=598
IR1 20.39 (-f-#7=7.351

O.OeO

O.OeO -

7.2 7.4 7.6
RT (min)

13C-PFDA IS

Cone. 5.0000

7.4 7.6

RT (min)

13C-PFDA

Cone. 5.6480

7.6
RT (min)

NMeFOSAA

Cone. 0.0054

R#1 570.20>512.00 35.03 (37.68)
Q 570.20>419.00 (-)	1.93e2

f A=469
R1 35.03 (—)"kT=7.524

ISTD 514.80>469.95 (-)	5.89e5 Q 514.80>469.95 (-)

=1462714
7.345	-

O.OeO

7.2 7.4 7.6

RT (min)

PFDS

Cone. —

R#1 599.00>99.00 — - (65.43)
Q 599.00>80.10 (-)	O.OOeO

5.0e0 n	i

7.4 7.6

RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

rA= 1439422
RT=7.697

O.OeO -

7.6

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 6.5319

1.94e5 Q 588.80>419.00 (-)

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.0086

R#1 584.20>526.10 9.03 (58.21)
Q 584.20>418.95 (-)	1.66e2

O.OeO -

A-113 ¥ Ai=893
ws.«dr-)l=7_699

7.8 8.0
RT (min)

7.6 7.8 8.0
RT (min)

PFDoA

Cone. 0.0048

R#1 613.05> 169.00 0.00 (16.16)
Q 613.05>569.00 (-)	4.34e2

1414

R1 0.00 (H-) =8.112

1.5e2-

1.0e2-

5.0e1 -

O.OeO -

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

5.06e5

7.8 8.0

RT (min)

RT (min)

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:31:18

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 5.8743

Q614.80>569.95 (-)

10-2-FtS

Cone. —

R#1 626.50>81.05 —- (76.13)
5.06e5 Q 626.50>607.05 (-)

d5-NEtFOSA IS

Cone. 5.0000

O.OOeO ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 5.6510

1.39e5 Q 531.10> 169.10 (-)

RT (min)

NEtFOSE

Cone. 0.0024

Q 629.50>59.10 (-)

"	A=3^7

2.0e2 -	RT=8.766

0.0e0 ~L,—,—|

8.6 8.8 9.0

RT (min)

d3-NMeFOSA

Cone. 5.8402

d9-EtFOSE IS

Cone. 5.0000

4.56e2 ISTD 638.90> 59.10 (-)

RT (min)

5.56e4 Q 638.90> 59.10 (-)

A= 138868
RT=8.735

O.OeO

8.6 8.8 9.0

RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 5.8888

Q 515.10> 169.00 (-)

1,26e5 I STD 623.00 > 59.00 (-)

7.39e4 Q 623.00> 59.00 (-)

A=185217
RT=8.487

13C-PFTeDA IS

Cone. 5.0000

O.OeO -

8.4 8.6

RT (min)

PFTeDA

Cone. 0.0246
R#1 713.00 >169.30 17.60 (11.66)

Q 713.00 > 668.90 (-)	7.19e2 I STD 714.80 > 669.80 (-)

f A=2500
IR1 17.60 (--H-fcf=8.684

O.OeO

8.6 8.8 9.0
RT (min)

L-PFDoS

Cone. —

R#1 698.80>98.80 — - (71.85)

Q 698.80>80.10 (-)	O.OOeO Q 377.10>251.20 (-)

RT (min)

13C-PFTeDA

Cone. 1.9315

Q 714.80>669.80 (-)
1.0e5

8.6 8.8 9.0
RT (min)

NaDONA

Cone. 0.0005

5.0e0 -

PFHxDA

Cone. -0.0373

Q 812.90>769.00 (-)
4.0e2 -

'A=985
RTp 9.202

8.4 8.6
RT (min)

6.2 6.4 6.6

RT (min)

NMeFOSE

Cone. —

1.39e5 Q 616.10>58.90 (-)

O.OeO

9.0
RT (min)

NMeFOSA

Cone. —

R#1 512.10>219.20 —- (76.94)
Q 512.10> 169.20 (-)	O.OOeO

5.0e0 n	i

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)	1.26e5

-5.0e0 H , , , , , ,l , , , , , , , ,
8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0039

R#1 526.50>219.20 0.00 (67.00)
Q 526.50>169.10 (-)	7.80e1

4 0e2 - R1 0.00 (—¦-j)

O.OeO -

8.4 8.6

RT (min)

PFTrDA

Cone. 0.0073

R#1 663.10> 169.10 0.00 (20.38)
Q 663.10>618.90 (-)	3.30e2

f A=630

RT (min)

8.6

RT (min)

11CI-PF30UdS

Cone. —

Q 631.00>451.10 (-)
2.0e1 -

1.0e1

9CI-PF30NS

Cone. —

2.20e1 Q 531.00>351.10 (-)

8.6 8.8 9.0
RT (min)

RT (min)

PFODA

Cone. —

13C2-PFHxDA IS

Cone. 5.0000

4.33e2 Q 912.80>869.00 (-)

9.0 9.2 9.4

RT (min)

5.50e 1 I STD 815.00 > 770.00 (-)
1.0e6-

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:31:18

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 5.4946

Q 815.00>770.00 (-)
1.0e6 -

13C7-PFUnDA IS

Cone. 5.0000

1.10e6 ISTD 569.80> 524.90 (-)

PFecHS	PFBSA

Cone. 0.0003	Cone. 0.0004
R#1 461.00>99.10 0.00 (38.14)

3.44e5 Q 461.00>381.00 (-)	1.40e2	Q 298.00>78.00 (-)

- R1 0.00 (—-)

O.OeO

9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

= 138
T=6.863

RT (min)

A=76
RT=6.154

PFHxSA

Cone. 0.0016

4.70e1 Q 397.90>78.00 (-)
1.0e2-

5.0e1

6.2 6.4
RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

®6

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:54

CCV5-230428

Sample ID: CCV5-230428

Date Acquired: 4/29/2023 8:15:09 AM

Acquired by: System Administrator

Data File: 230428079

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.211

837927

837927

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.211

837927

1559187

13C7-PFUnDA IS

5.0000

5.0659

ng/mL

PFBA

Auto

4.212

909079

837927

13C-PFBA IS

5.0000

4.8524

nq/mL

13C-PFPeA IS

Auto

5.375

1317952

1317952

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.375

1317952

1559187

13C7-PFUnDA IS

5.0000

4.9595

nq/mL

PFPeA

Auto

5.376

1240218

1317952

13C-PFPeA IS

5.0000

5.1109

ng/mL

13C-PFBS IS

Auto

5.505

496931

496931

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.505

496931

1559187

13C7-PFUnDA IS

4.6500

4.2614

ng/mL

PFBS

Auto

5.505

343020

496931

13C-PFBS IS

4.4200

4.4465

nq/mL

13C HFPO DA IS

Auto

6.108

278654

278654

	

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.108

278654

1559187

13C7-PFUnDA IS

5.0000

4.8290

nq/mL

HFPO DA

Auto

6.109

220283

278654

13C HFPO DA IS

5.0000

5.4047

nq/mL

13C-4 2-FTS IS

Auto

5.908

238518

238518

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.908

238518

1559187

13C7-PFUnDA IS

4.6700

4.5739

ng/mL

4-2-FtS

Auto

5.908

258090

238518

13C-4 2-FTS IS

4.6700

4.5605

nq/mL

PFHxA

Auto

5.963

2332832

1709818

13C-PFHxA IS

5.0000

5.1349

ng/mL

13C-PFHxA IS

Auto

5.963

1709818

1709818

	

5.0000

5.0000

i

13C-PFHxA

Auto

5.963

1709818

1559187

13C7-PFUnDA IS

5.0000

4.7356

ng/mL

PFPeS

Auto

6.004

363843

512683

180-PFHxS IS

4.6900

5.0375

nq/mL

PFHxS

Auto

6.375

269459

512683

180-PFHxS IS

4.5500

4.1355

ng/mL

13C-PFHpA IS

Auto

6.370

1658334

1658334

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.370

1658334

1559187

13C7-PFUnDA IS

5.0000

4.7281

ng/mL

180-PFHxS IS

Auto

6.376

53

512683

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.376

512683

1559187

13C7-PFUnDAJS

4.7250

4.3811

ng/mL

PFHpA

Auto

6.370

2534996

1650334

13C-PFHpA IS

5.0000

5.1251

ng/mL

13C2-6 2-FTS IS

Auto

6.673

233582

233582

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.673

233582

1559187

13C7-PFUnDA IS

4.7500

4.2760

ng/mL

PFHpS

Auto

6.681

362433

512683

180-PFHxS IS

4.7600

4.6513

ng/mL

6-2-FTS

Auto

6.672

205265

233582

13C2-6 2-FTS IS

4.7400

4.4215

nq/mL

PFOA

Auto

6.691

2609895

2057921

13C-PFOA IS

5.0000

4.6655

ng/mL

13C-PFOA IS

Auto

6.690

2057921

2057921

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.690

2057921

1559187

13C7-PFUnDA IS

5.0000

4.7199

ng/mL

PFOS

Auto

6.982

235447

512398

13C-PFOS IS

4.6400

4.4115

nq/mL

13C-PFOS IS

Auto

6.983

512398

512398

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

6.983

512398

1559187

13C7-PFUnDA IS

4.7750

4.3614

nq/mL

PFNA

Auto

7.004

2063411

2010613

13C-PFNA IS

5.0000

4.2983

ng/mL

13C-PFNA IS

Auto

7.004

2010613

2010613

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.004

2010613

1559187

13C7-PFUnDA IS

5.0000

5.1883

ng/mL

PFNS

Auto

7.312

589040

512398

13C-PFOS IS

4.8000

4.8018

nq/mL

8-2-FTS

Auto

7.340

112135

117562

13C-8 2-FTS IS

4.7900

4.0008

ng/mL

13C-8 2-FTS IS

Auto

7.340

117562

117562

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.340

117562

1559187

13C7-PFUnDA IS

4.7900

4.5683

ng/mL

PFDA

Auto

7.344

1953021

2131343

13C-PFDA IS

5.0000

4.8386

nq/mL

13C-PFDA IS

Auto

7.344

2131343

2131343

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.344

2131343

1559187

13C7-PFUnDA IS

5.0000

4.8582

nq/mL

d3-N-MeFOSAA IS

Auto

7.522

680213

680213

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.522

680213

1559187

13C7-PFUnDA IS

5.0000

5.3176

nq/mL

NMeFOSAA

Auto

7.527

649294

680213

d3-N-MeFOSAA IS

5.0000

4.8093

nq/mL

PFDS

Auto

7.655

394910

512398

13C-PFOS IS

4.8200

4.3681

nq/mL

13C-PFUnDA IS

Auto

7.696

2039481

2039481

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.696

2039481

1559187

13C7-PFUnDA IS

5.0000

5.2823

nq/mL

PFUnDA

Auto

7.696

1686551

2039481

13C-PFUnDA IS

5.0000

4.2244

nq/mL

d5-N-EtFOSAA IS

Auto

7.709

764719

764719

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.709

764719

1559187

13C7-PFUnDA IS

5.0000

5.6071

nq/mL

NEtFOSAA

Auto

7.716

650684

764719

dS-N-EtFOSAA IS

5.0000

4.3014

nq/mL

PFOSA

Auto

7.760

495916

500746

13C-FOSA IS

5.0000

4.6220

nq/mL

13C-FOSA IS

Auto

7.760

500746

500746

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.760

500746

1559187

13C7-PFUnDA IS

5.0000

4.8791

nq/mL

PFDoA

Auto

8.042

2055691

2071271

13C-PFDoA IS

5.0000

4.4423

nq/mL

13C-PFDoA IS

Auto

8.042

2071271

2071271

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

ttR

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:54

CCV5-230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.042

2071271

1559187

13C7-PFUnDA IS

5.0000

5.4693

nq/mL

10-2-FtS

Auto

8.056

125372

117562

13C-8 2-FTS IS

4.8200

4.1981

ng/mL

d5-NEtFOSA IS

Auto

8.782

521152

521152

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.782

521152

1559187

13C7-PFUnDA IS

5.0000

4.9562

ng/mL

NMeFOSE

Auto

8.505

256194

295287

d7-N-MeFOSE IS

5.0000

5.3134

nq/mL

NEtFOSE

Auto

8.756

806488

199285

d9-EtFOSE IS

5.0000

4.0794

ng/mL

d9-EtFOSE IS

Auto

8.737

199285

199285

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.737

199285

1559187

13C7-PFUnDA IS

5.0000

6.6358

ng/mL

NMeFOSA

Auto

8.532

214393

481143

d3-NMeFOSA IS

5.0000

4.8361

nq/mL

dB-NMeFOSA IS

Auto

8.527

481143

481143

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.527

481143

1559187

13C7-PFUnDA IS

5.0000

5.0606

nq/mL

d7-N-MeFOSE IS

Auto

8.490

295287

295287

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.490

295287

1559187

13C7-PFUnDA IS

5.0000

5.5421

nq/mL

NEtFOSA

Auto

8.792

381034

521152

d5-NEtFOSA IS

5.0000

4.9839

ng/mL

PFTrDA

Auto

8.370

1593496

949716

13C-PFTeDA IS

5.0000

5.5233

nq/mL

PFTeDA

Auto

8.672

1893523

949716

13C-PFTeDA IS

5.0000

5.5686

ng/mL

13C-PFTeDA IS

Auto

8.672

949716

949716

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.672

949716

1559187

13C7-PFUnDA IS

5.0000

3.8125

ng/mL

11CI-PFBOUdS

Auto

7.848

636748

512398

13C-PFOS IS

4.7100

5.4235

nq/mL

9CI-PF30NS

Auto

7.165

1201305

512398

13C-PFOS IS

4.6600

4.7491

ng/mL

L-PFDoS

Auto

8.318

184117

512398

13C-PFOS IS

4.8400

5.3929

nq/mL

NaDONA

Auto

6.414

1939290

2010613

13C-PFNA IS

4.7100

4.5696

ng/mL

PFHxDA

Auto

9.204

937617

3662260

13C2-PFHxDA IS

5.0000

3.2476

nq/mL

PFODA

Auto

9.769

793985

3662260

13C2-PFHxDA IS

5.0000

4.2477

ng/mL

1BC2-PFHxDA IS

Auto

9.204

3662260

3662260

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.204

3662260

1559187

13C7-PFUnDA IS

5.0000

4.6400

ng/mL

13C7-PFUnDA IS

Auto

7.695

1559187

1559187

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.640

2152075

512398

13C-PFOS IS

4.6100

4.6277

ng/mL

PFBSA

Auto

6.153

1311924

500746

13C-FOSA IS

5.0000

5.0275

nq/mL

PFHxSA

Auto

6.974

1113189

2010613

13C-PFNA IS

5.0000

4.4831

ng/mL

CHARGE

ND(W/B)

	

	

1559187

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 5.0659
1.85e5 Q 217.20>172.30 (-)

PFBA

Cone. 4.8524
1.85e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
1,98e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.9595
5.06e5 Q 267.90>223.00 (-)

1.5e5 -
1.0e5:
5.0e4 :

A=837927
RT=4.211

O.OeO

L

~ A=909079
RT=4.212

f A= 1317952
RT= 5.375

O.OeO

O.OeO -tgf

O.OeO

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 5.1109	Cone. 4.6500	Cone. 4.2614 Cone. 4.4465

O.OeO

5.4 5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)
4.0e5 -

4.31 e5 ISTD 301.80>80.00 (-)

A=1240218
RT= 5.376

5.4 5.6 5.8
RT (min)

1.80e5 Q 301.80>80.00 (-)

1.5e5 ^

^.0eSz_

5.0e4 i
=== O.OeO 1. .

R#1 298.80>99.00 69.61 (65.16)

1.80e5 Q 299.00>80.00 (-)	1.26e5 ISTD 332.10>287.10 (-)	1.21e5

I R1 69.61 (-

A=343020
&T= 5.505

5.4 5.6 5.8
RT (min)



5.6 5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

188B5

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:54

CCV5-230428 (continued)

13C HFPO DA

Cone. 4.8290

Q 332.10>287.10 (-)

HFPO DA

Cone. 5.4047

R#1 329.00>285.10 86.19 (80.83)
Q 329.00>169.00 (-)	9.29e4

278654
tT=6.108

- R1 86.19 (-

O.OeO -



7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

=220283

|RT=6.109

L

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 5.1349

R#1 313.00> 119.10 2.62 (2.51)
Q 313.00>269.00 (-)	9.50e5

:R1 2.62 (—

=2332832
)|RT= 5.963

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

6.0e5 i
4.0e5 ^

2.0e5 i
O.OeO 1 i i i

6.2
RT (min)

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

13C-PFHpA

Cone. 4.7281

7.19e5 Q 366.90>322.10 (-)

=1658334
T=6.370

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)
1.0e5 -i

13C2-6 2-FTS

Cone. 4.2760

Q 428.90>409.00 (-)
1.0e5 -i

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

13C-PFOA

Cone. 4.7199

8.55e5 Q416.80>372.05 (-)

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

f A=2057921
RT=6.690

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

f A=2057921
RT=6.690

6.8 7.0
RT (min)

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 26.24 (27.58)

ISTD 329.00>309.15 (-)	9.61 e4

^=238518

:R1 26.24 (-¦l-br=5.908

7.5e4 -
5.0e4 :
2.5e4 :
O.OeO :

6.2 6.4
RT (min)

13C-PFHxA

Cone. 4.7356

6.94e5 Q 314.90>270.10 (-)

6.0e5 i
4.0e5 ^

2.0e5 i
= O.OeO 1 . . .

6.2
RT (min)

180-PFHxS IS

Cone. 4.7250

7.19e5 ISTD 402.70>84.05 (-)

^=512683
RT=6.376

O.OeO -

6.2

6.4

1.5e5 -
1.0e5 ¦;
5.0e4 -
O.OeO:

TA=362433

R1 63.72 (--

tT=6.681

6.0e4
4.0e4
2.0e4
O.OeO

- R1 97.32 (•

t^=2

RT='

=235447
=6.982

6.8 7.0
RT (min)

13C-4 2-FTS

Cone. 4.5739

R#1 329.00>81.00 26.24 (27.58)
Q 329.00>309.15 (-)	9.61e4

6.0 6.2
RT (min)



^ A=363843

I R1 77.22 (--

W=6.004

: i

L

6.2
RT (min)

180-PFHxS

Cone. 4.3811

2.28e5 Q 402.70>84.05 (-)

=512683
|RT=6.376

O.OeO -

6.6
RT (min)

PFHpS

Cone. 4.6513

R#1 449.00>99.20 63.72 (66.50)
Q 449.00>80.15 (-)	1.56e5

6.2

6.4

Q 427.00>407.00 (-)
7-JR1 28.49 (-

=205265
T=6.672

6.6 6.8

RT (min)

PFOS

Cone. 4.4115

R#1 499.00>99.00 97.32 (86.07)
Q 499.00>80.00 (-)	7.01e4

13C-PFOS IS

Cone. 4.7750

ISTD 502.8
2.0e5 -

105 (-)

6.75 7.00 7.25

RT (min)

A= 512398
'T=6.983

4-2-FtS

Cone. 4.5605

R#1 327.00 >81.10 16.22 (16.09)
Q 327.00>307.05 (-)	1.05e5

=258090
1.0e5-Ri 16.22 (« r=5 c

6.0 6.2
RT (min)

PFPeS

Cone. 5.0375

R#1 349.00>99.00 77.22 (77.24)
Q 349.00>79.95 (-)	1.50e5

1.5e5~

1.0e5-

5.0e4 7
O.OeO -

6.2

RT (min)

O.OeO

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 4.1355

R#1 399.00>99.00 93.68 (85.33)
Q 399.00>80.00 (-)	9.84e4

=269459

- R1 93.68 (-- T=6.375

O.OeO

6.2 6.4 6.6

RT (min)

PFHpA

Cone. 5.1251

R#1 362.90 >169.00 17.28 (17.91)
Q 362.90>319.00 (-)	1.11e6

=2534996

1.0e6-|R1 17-28 ("fl-kr=6.370

O.OeO -

6.6
RT (min)

6-2-FTS

Cone. 4.4215

R#1 427.00>80.90 28.49 (33.45)

6.2

6.4

6.6
RT (min)

PFOA

Cone. 4.6655

R#1 413.00> 169.10 29.26 (27.85)

8.62e4 Q 413.00>369.00 (-)

1.08e6

=2609895
1.0e6 —IR1 29.26 (--i-kr=6.691

RT (min)

13C-PFOS

Cone. 4.3614

2.14e5 Q 502.80>80.05 (-)
2.0e5 -

6.8 7.0
RT (min)

A= 512398
'T=6.983

7.2

RT (min)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

fE6

-------
)

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:54

CCV5-230428 (continued)

PFNA	13C-PFNA IS

Cone. 4.2983	Cone. 5.0000
R#1 463.00>219.00 19.91 (24.00)

Q 463.00>418.90 (-)	8.45e5	ISTD 467.80>423.00 (-)

f A=2063411
7.5e5 - R1 1991 ("Mt=7.004

5.0e5 :
2.5e5 :
O.OeO :

13C-PFNA

Cone. 5.1883

A=2010613
•1=7.004

7.2

RT (min)

PFNS	8-2-FTS

Cone. 4.8018	Cone. 4.0008

R#1 549.00>99.00 66.71 (71.23)	R#1 527.20>487.00 6.28 (6.74)

Q 549.00>79.95 (-)	2.38e5	Q 527.10>506.90 (-)	4.39e4

R1 66.71 (



589040
7.312

4,0e4~ R1 6.28 (-•

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 4.5683

4.53e4 Q 528.80> 509.00 (-)

7.2
RT (min)

PFDA

Cone. 4.8386

R#1 512.90>219.00 18.13 (17.51)
Q 512.90>469.00 (-)	7.78e5

7.4 7.6
RT (min)

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

8.67e5 Q 514.80>469.95 (-)

7.5e5 -
5.0e5 -
2.5e5 -
O.OeO -

R1 18.13 (-

*A= 1953021
W=7.344

A=2131343
RT=7.344

7.6
RT (min)

7.6
RT (min)

7.2

7.4

d3-N-MeFOSAAJS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 5.3176

2.46e5 Q 572.80>419.05 (-)

7.6
RT (min)

NMeFOSAA

Cone. 4.8093

R#1 570.20 > 512.00 40.28 (37.68)
Q 570.20>419.00 (-)	2.03e5

7.6
RT (min)

PFDS

Cone. 4.3681

R#1 599.00>99.00 58.57 (65.43)
Q 599.00>80.10 (-)	1.52e5

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)





TA=680213
M RT=7.522

2.0e5 -

R1 40.28 (--]

A=649294
kl=7.527

2.0e5 -



I

1.0e5 -



T

1.0e5 -





:







y

L

-



I .





—rH—i—i—i—i—i—





7.6 7.8
RT (min)

13C-PFUnDA

Cone. 5.2823

Q 564.80>519.95 (-)

7.4 7.6 7.8

RT (min)

PFUnDA

Cone. 4.2244

R#1 563.00>219.00 13.95 (13.86)
Q563.00>518.90 (-)	6.31 e5

7.25 7.50 7.75

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

d5-N-EtFOSAA

Cone. 5.6071

2.87e5 Q 588.80>419.00 (-)

7.8 8.0
RT (min)

NEtFOSAA

Cone. 4.3014

R#1 584.20>526.10 59.32 (58.21)
Q 584.20>418.95 (-)	2.07e5

7.8 8.0
RT (min)

PFOSA

Cone. 4.6220

R#1 498.20>64.10 0.12 (0.09)
Q 498.20>78.00 (-)	1.99e5

f A=495916

- R1 °-12 (—||RT=7.760

f A=764719
RT=7.709

2.0e5 -

A=650684
R1 59.32 (--|-«J=7.716

O.OeO -

J



O.OeO -

'A 1 1—1—1 i ' 1

7.8 8.0
RT (min)

7.6

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

13C-FOSA

Cone. 4.8791

1.98e5 Q 506.00>78.05 (-)

A= 500746
RT=7.760

7.6 7.8 8.0

RT (min)

7.6 7.8 8.0

RT (min)

7.8 8.0
RT (min)

PFDoA

Cone. 4.4423

R#1 613.05> 169.00 16.65 (16.16)
Q 613.05>569.00 (-)	7.84e5

A=2055691
7-5e5- ri 16.65 (|-R)f=8.042

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)
7.5e5 -

7.80e5

7.8 8.0

RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

m

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:54

CCV5-230428 (continued)

13C-PFDoA

Cone. 5.4693

Q614.80>569.95 (-)
7.5e5 -

*A=2071271
RT=8.042

5.0e5 :
2.5e5 :
O.OeO :

L

NEtFOSE

Cone. 4.0794

Q629.50>59.10 (-)
3.0e5 -
2.0e5 ^

1.0e5:

O.OeO 1. . . .

d3-NMeFOSA

Cone. 5.0606

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

10-2-FtS

Cone. 4.1981

R#1 626.50>81.05 71.40 (76.13)
Q 626.50>607.05 (-)	4.71e4

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

RT (min)

d5-NEtFOSA

Cone. 4.9562

2.04e5 Q 531.10> 169.10(-)
2.0e51

d9-EtFOSE IS

Cone. 5.0000

ISTD 638.90>59.10 (0
7.5e4 -
5.0e4 ^

2.5e4 ^

O.OeO 1 . . .

A= 199285
RT=8.737

9.0
RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

1.84e5 ISTD 623.00>59.00 (0

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 5.5686

R#1 713.00> 169.30 11.46 (11.66)
Q 713.00>668.90 (0	7.18e5

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (0

A=949716
RT=8.672

vL

9.0
RT (min)

L-PFDoS

Cone. 5.3929

R#1 698.80>98.80 71.35 (71.85)
Q 698.80>80.10 (0	7.46e4

NaDONA

Cone. 4.5696

Q 377.10>251.20 (0

1939290
=6.414

B.2 8.4 8.6

RT (min)

Q 638.90>59.10 (0
7.5e4 -

9.0
RT (min)

d7-N-MeFOSE

Cone. 5.5421

1.18e5 Q 623.00> 59.00 (0

RT (min)

13C-PFTeDA

Cone. 3.8125

3.57e5 Q 714.80>669.80 (0

3.0e5 -
2.0e5 -
1.0e5-
O.OeO -

9.0
RT (min)

PFHxDA

Cone. 3.2476

Q 812.90>769.00 (0
4.0e5 -i

~ A=937617
RT 1=9.204



NMeFOSE

Cone. 5.3134

2.04e5 Q 616.10> 58.90 (0
1.0e5 —|

O.OeO

9.0
RT (min)

NMeFOSA

Cone. 4.8361

R#1 512.10>219.20 77.18 (76.94)
Q 512.10> 169.20 (0	8.23e4

A=?14393
7.5e4HR1 77.18 (- hT=8.532

RT (min)

O.OeO -

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4-
O.OeO -

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 4.9839

R#1 526.50>219.20 62.07 (67.00)
Q526.50> 169.10(0	1.50e5

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 5.5233

R#1 663.10> 169.10 20.70 (20.38)
Q 663.10>618.90(0	6.17e5

1.5e5

I R1 62.07 (--

RT (min)

11CI-PF30UdS

Cone. 5.4235

3.57e5 Q631.00>451.10 (0

9CI-PF30NS

Cone. 4.7491

2.54e5 Q 531.00>351.10(0

A=636748
RT=7.848

L

9.0
RT (min)

RT (min)

7.4

RT (min)

PFODA

Cone. 4.2477

13C2-PFHxDA IS

Cone. 5.0000

4.02e5 Q 912.80>869.00 (0



9.0 9.2 9.4

RT (min)

2.69e5 ISTD 815.00>770.00 (0

;	t a=

1.5e6-

1.0e6-j

5.0e5 ^

O.OeO 1. . . .



9.6 9.8 10.0

RT (min)

9.2 9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

18eSB

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:25:54

CCV5-230428 (continued)

13C2-PFHxDA

Cone. 4.6400

Q 815.00>770.00 (-)
1.5e6 -
1.0e6^

5.0e5 ^

O.OeO 1. . . .

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 5.0275

PFecHS

Cone. 4.6277
R#1 461.00>99.10 38.61 (38.14)

1.57e6 ISTD 569.80>524.90 (-)	5.91e5 Q461.00>381.00 (-)	8.75e5 Q 298.00>78.00 (-)

A=3662260
RTp 9.204



9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

^2152075

7.5e5 f

R1 38.61 (--

p.T= 6.640

5.0e5 i





2.5e5 ~





0 0<=>0 -

	J-

L

8.0
RT (min)

6.4 6.6 6.8

RT (min)

rA=1311924
RT=6.153

PFHxSA

Cone. 4.4831

5.23e5 Q 397.90>78.00 (-)
4.0e5 -

2.0e5 -

6.2 6.4
RT (min)

7.2
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

1SSB

-------
Insight Report
Quantitation/lntegration
Printed 10/30/2023 14:07:04

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/29/2023 10:46:27 AM

Acquired by: System Administrator

Data File: 230428090

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 1

Name	Mode ID Found RT Area ISTDArea ISTD Name	Std. Cone. Cone. Unit

13C-PFBA IS

Auto

4.189

643194

643194

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.189

643194

1536055

13C7-PFUnDA IS

5.0000

3.9471

nq/mL

PFBA

M

4.190

1329

643194

13C-PFBA IS

0.1000

0.0092

nq/mL

13C-PFPeA IS

Auto

5.351

1090546

1090546

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.351

1090546

1536055

13C7-PFUnDA IS

5.0000

4.1656

nq/mL

PFPeA

M

5.355

1684

1090546

13C-PFPeA IS

0.1000

0.0084

nq/mL

13C-PFBS IS

Auto

5.483

425834

425834

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.483

425834

1536055

13C7-PFUnDA IS

4.6500

3.7067

nq/mL

PFBS

M

5.497

168

425834

13C-PFBS IS

0.0880

0.0025

nq/mL

13C HFPO DA IS

Auto

6.083

244123

244123

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.083

244123

1536055

13C7-PFUnDA IS

5.0000

4.2943

nq/mL

HFPO DA

Auto

6.084

60

244123

13C HFPO DA IS

0.1000

0.0017

nq/mL

13C-4 2-FTS IS

Auto

5.885

185174

185174

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.885

185174

1536055

13C7-PFUnDA IS

4.6700

3.6044

nq/mL

4-2-FtS

Auto

5.882

162

185174

13C-4 2-FTS IS

0.0930

0.0037

nq/mL

PFHxA

Auto

5.936

3151

1384885

13C-PFHxA IS

0.1000

0.0086

nq/mL

13C-PFHxA IS

Auto

5.938

1384885

1384885

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

5.938

1384885

1536055

13C7-PFUnDA IS

5.0000

3.8934

ng/mL

PFPeS

NDfW, "

	

	

450130

180-PFHxS IS

0.0940

	

iq/mL

PFHxS

Auto

6.355

800

450130

180-PFHxS IS

0.0910

0.0140

ng/mL

13C-PFHpA IS

Auto

6.345

1324413

1324413

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.345

1324413

1536055

13C7-PFUnDA IS

5.0000

3.8329

nq/mL

180-PFHxS IS

Auto

6.352

450130

450130

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.352

450130

1536055

13C7-PFUnDAJS

4.7250

3.9044

ng/mL

PFHpA

Auto

6.348

1626

1324413

13C-PFHpA IS

0.1000

0.0041

ng/mL

13C2-6 2-FTS IS

Auto

6.646

195035

195035

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.646

195035

1536055

13C7-PFUnDA IS

4.7500

3.6241

ng/mL

PFHpS

ND(W/B)

	

	

450130

180-PFHxS IS

0.0950

	

nq/mL

6-2-FTS

Auto

6.719

70

195035

13C2-6 2-FTS IS

0.0950

0.0018

nq/mL

PFOA

Auto

6.665

2067

1753279

13C-PFOA IS

0.1000

0.0043

nq/mL

13C-PFOA IS

Auto

6.663

1753279

1753279

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.663

1753279

1536055

13C7-PFUnDA IS

5.0000

4.0817

nq/mL

PFOS

Auto

6.951

890

408508

13C-PFOS IS

0.0930

0.0209

nq/mL

13C-PFOS IS

Auto

6.950

408508

408508

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

6.950

408508

1536055

13C7-PFUnDA IS

4.7750

3.5295

nq/mL

PFNA

Auto

6.923

1483

1580587

13C-PFNA IS

0.1000

0.0039

nq/mL

13C-PFNA IS

Auto

6.970

1580587

1580587

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.970

1580587

1536055

13C7-PFUnDA IS

5.0000

4.1400

nq/mL

PFNS

Auto

7.255

55

408508

13C-PFOS IS

0.0960

0.0006

nq/mL

8-2-FTS

ND(W/B)

	

	

89759

13C-8 2-FTS IS

0.0960

	

nq/mL

13C-8 2-FTS IS

Auto

7.299

89759

89759

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.299

89759

1536055

13C7-PFUnDA IS

4.7900

3.5404

nq/mL

PFDA

Auto

7.328

1036

1636255

13C-PFDA IS

0.1000

0.0033

r

13C-PFDA IS

Auto

7.303

1636255

1636255

	

5.0000

5.0000

ng/mL

13C-PFDA

Auto

7.303

1636255

1536055

13C7-PFUnDA IS

5.0000

3.7859

r

d3-N-MeFOSAA IS

Auto

7.477

496842

496842

	

5.0000

5.0000

ng/mL

d3-N-MeFOSAA

Auto

7.477

496842

1536055

13C7-PFUnDA IS

5.0000

3.9426

r

NMeFOSAA

Auto

7.476

483

496842

d3-N-MeFOSAA IS

0.1000

0.0049

nq/mL

PFDS

Auto

7.557

116

408508

13C-PFOS IS

0.0960

0.0016

r

13C-PFUnDA IS

Auto

7.649

1517779

1517779

	

5.0000

5.0000

ng/mL

13C-PFUnDA

Auto

7.649

1517779

1536055

13C7-PFUnDA IS

5.0000

3.9903

r

PFUnDA

Auto

7.660

1714

1517779

13C-PFUnDA IS

0.1000

0.0058

ng/mL

d5-N-EtFOSAA IS

Auto

7.660

609443

609443

	

5.0000

5.0000

r

d5-N-EtFOSAA

Auto

7.660

609443

1536055

13C7-PFUnDA IS

5.0000

4.5358

ng/mL

NEtFOSAA

Auto

7.767

2386

609443

dS-N-EtFOSAA IS

0.1000

0.0198

r

PFOSA

Auto

7.735

246

375522

13C-FOSA IS

0.1000

0.0031

ng/mL

13C-FOSA IS

Auto

7.734

375522

375522

	

5.0000

5.0000

r

13C-FOSA

Auto

7.734

375522

1536055

13C7-PFUnDA IS

5.0000

3.7141

nq/mL

PFDoA

Auto

7.987

2199

1591524

13C-PFDoA IS

0.1000

0.0062

nq/mL

13C-PFDoA IS

Auto

7.993

1591524

1591524

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

®0

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Insight Report
Quantitation/lntegration
Printed 10/30/2023 14:07:04

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT Area ISTDArea ISTD Name	Std. Cone. Cone. Unit

1BC-PFD0A

Auto

7.993

1591524

1536055

13C7-PFUnDA IS

5.0000

4.2658

nq/mL

10-2-FtS

ND(W/B)

	

	

89759

13C-8 2-FTS IS

0.0960

	

ng/mL

d5-NEtFOSA IS

Auto

8.765

374378

374378

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.765

374378

1536055

13C7-PFUnDA IS

5.0000

3.6140

ng/mL

NMeFOSE

ND(W/B)

—

—

239654

d7-N-MeFOSE IS

0.1000

—

nq/mL

NEtFOSE

M

8.684

447

133251

d9-EtFOSE IS

0.1000

0.0034

ng/mL

d9-EtFOSE IS

Auto

8.721

133251

133251

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.721

133251

1536055

13C7-PFUnDA IS

5.0000

4.5038

ng/mL

NMeFOSA

ND(W/B)

—

—

357946

d3-NMeFOSA IS

0.1000

—

nq/mL

dB-NMeFOSA IS

Auto

8.508

357946

357946

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.508

357946

1536055

13C7-PFUnDA IS

5.0000

3.8215

nq/mL

d7-N-MeFOSE IS

Auto

8.473

239654

239654

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.473

239654

1536055

13C7-PFUnDA IS

5.0000

4.5657

nq/mL

NEtFOSA

M

8.821

78

374378

d5-NEtFOSA IS

0.1000

0.0014

ng/mL

PFTrDA

M

8.508

3212

1058779

13C-PFTeDA IS

0.1000

0.0100

nq/mL

PFTeDA

Auto

8.619

3100

1058779

13C-PFTeDA IS

0.1000

0.0082

ng/mL

13C-PFTeDA IS

Auto

8.620

1058779

1058779

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.620

1058779

1536055

13C7-PFUnDA IS

5.0000

4.3143

ng/mL

11CI-PFBOUdS

ND(W/B)

	

	

408508

13C-PFOS IS

0.0940

	

nq/mL

9CI-PF30NS

Auto

7.240

193

408508

13C-PFOS IS

0.0930

0.0010

ng/mL

L-PFDoS

ND(W/B)

	

	

408508

13C-PFOS IS

0.0970

	

nq/mL

NaDONA

ND(W/B)

	

	

1580587

13C-PFNA IS

0.0940

	

ng/mL

PFHxDA

Auto

9.154

6655

2901446

13C2-PFHxDA IS

0.1000

-0.0127

nq/mL

PFODA

Auto

9.700

450

2901446

13C2-PFHxDA IS

0.1000

0.0030

ng/mL

1BC2-PFHxDA IS

Auto

9.154

2901446

2901446

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.154

2901446

1536055

13C7-PFUnDA IS

5.0000

3.7315

ng/mL

13C7-PFUnDA IS

Auto

7.649

1536055

1536055

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.563

329

408508

13C-PFOS IS

0.0920

0.0009

ng/mL

PFBSA

Auto

6.131

170

375522

13C-FOSA IS

0.1000

0.0009

nq/mL

PFHxSA

ND(W/B)

	

	

1580587

13C-PFNA IS

0.1000

	

ng/mL

CHARGE

ND(W/B)

	

	

1536055

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 3.9471
1.50e5 Q 217.20>172.30 (-)

PFBA

Cone. 0.0092
1.50e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
4.93e2 ISTD 267.90>223.00 (-)

TA=643194
RT=4.189

O.OeO

^1329
RT=Ah90

L

O.OeO -

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS

Cone. 0.0084	Cone. 4.6500	Cone. 3.7067

13C-PFPeA

Cone. 4.1656
4.73e5 Q 267.90>223.00 (-)

A=1090546
T= 5.351

1090546
= 5.351

O.OeO I, , , a'. ¦ pTT	

5.2 5.4 5.6

RT (min)

PFBS

Cone. 0.0025

R#1 298.80>99.00 0.00 (65.16)
Q 299.00>80.00 (-)	8.40e1

i | i A i i | i i i i | i i i

5.2 5.4 5.6

RT (min)

13C HFPO DA IS

Cone. 5.0000

I STD 332.10 > 287.10 (-)	1,08e5

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

m

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Insight Report
Quantitation/lntegration
Printed 10/30/2023 14:07:04

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 4.2943

Q 332.10>287.10 (-)	1.08e5

| A=244123
1-0e5H	RT=6.083

HFPO DA

Cone. 0.0017

R#1 329.00>285.10 454.05 (80.83)
Q 329.00>169.00 (-)	4.80e1



O.OeO , , ~\£=\

6.0 6.2 6.4
RT (min)

PFHxA

Cone. 0.0086

R#1 313.00>119.10 0.00 (2.51)

IR1 454.05

i"

-)

:

1 A=6C





RT=6

na

4

J

i



13C-PFHxA IS

Cone. 5.0000

Q 313.00>269.00 (-)

f A=3151

1.5e3HR1 0.00 (¦ nW=5.936

1.58e3 ISTD 314.90>270.10 (-)
6.0e5 -i

A=1384885
RT= 5.938

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

5.90e5 Q 366.90>322.10 (-)

=1324413
RT=6.345



=1324413
RT=6.345



6.6

RT (min)

13C2-6 2-FTS IS

Cone. 4.7500

13C2-6 2-FTS

Cone. 3.6241

ISTD 428.90>409.00 (-)
7.5e4 ^

5.0e4 ^

2.5e4 :

A= 195035
RT=6.646

O.OeO -

/

\y

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

13C-PFOA

Cone. 4.0817

7.54e5 Q 416.80>372.05 (-)

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

A=1753279
RT=6.663



6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

A=1753279
RT=6.663



6.8 7.0
RT (min)

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 28.53 (27.58)

ISTD 329.00>309.15 (-)	8.30e4

13C-4 2-FTS

Cone. 3.6044

R#1 329.00>81.00 28.53 (27.58)
Q 329.00>309.15 (-)	8.30e4

4-2-FtS

Cone. 0.0037

R#1 327.00 >81.10 0.00 (16.09)
Q 327.00>307.05 (-)	1.26e2

Q 314.90>270.10 (-)
6.0e5 -i

fA= 1384885
RT= 5.938

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)
2.0e5 -i

O.OeO -

L

6.0 6.2
RT (min)

PFPeS

Cone. —

R#1 349.00>99.00 — - (77.24)
Q 349.00>79.95 (-)	5.20e1

6.0e11
4.0e1 :
2.0e1 :
O.OeO :

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.0140

R#1 399.00>99.00 157.14 (85.33)
Q 399.00>80.00 (-)	2.75e2

4^e2>H57AlU -)
] RT=6. S5

6.2
RT (min)

6.2

RT (min)

A=450130
RT=6.352

180-PFHxS

Cone. 3.9044

Q 402.70>84.05 (-)
2.0e5 -i

O.OeO

6.6
RT (min)

PFHpA

Cone. 0.0041

R#1 362.90 >169.00 9.97 (17.91)
Q 362.90>319.00 (-)	8.35e2

6.6

RT (min)

O.OeO

6.2 6.4 6.6

RT (min)

PFHpS

Cone. —

R#1 449.00>99.20 — - (66.50)
Q 449.00>80.15 (-)	O.OOeO

O.OeO

6.6
RT (min)

6-2-FTS

Cone. 0.0018

R#1 427.00>80.90 0.00 (33.45)
Q 427.00>407.00 (-)	4.50e1

H T

A=70

-R1 0.00 (—-) A
/ '

RT=6.719

IH



6.6
RT (min)

PFOA

Cone. 0.0043

R#1 413.00> 169.10 24.83 (27.85)
Q 413.00>369.00 (-)	1.31e3

fA=2067

"Rt=6.665

6.6 6.8

RT (min)

PFOS

Cone. 0.0209

R#1 499.00>99.00 17.89 (86.07)
Q 499.00>80.00 (-)	3.12e2

3.0e2^R1 17 89 (-]|^T:6;951
2.0e2 :

RT (min)

6.8 7.0
RT (min)

13C-PFOS IS

Cone. 4.7750

13C-PFOS

Cone. 3.5295

105 (-)

1.73e5 Q 502.80>80.05 (-)

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

W2.

-------
A

Insight Report
Quantitation/lntegration
Printed 10/30/2023 14:07:04

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0039

R#1 463.00>219.00 0.00 (24.00)
Q 463.00>418.90 (-)	4.14e2

40e2^Ri Ia=1483

T=q.923

13C-PFNA IS

Cone. 5.0000

13C-PFNA

Cone. 4.1400

PFNS

Cone. 0.0006

R#1 549.00 >99.00 0.00 (71.23)
Q 549.00>79.95 (-)	4.00e1

R1 0.00 (—-)
A=55
RT=7.255 I

8-2-FTS

Cone. —

R#1 527.20>487.00 — - (6.74)
Q 527.10>506.90 (-)	O.OOeO

5.0e0 n	i

7.2

RT (min)

13C-8 2-FTSJS

Cone. 4.7900

ISTD 528.80>509.00 (-)

3.0e4 i
2.0e4 i
^.0e4z_

O.OeO 4==

13C-8 2-FTS

Cone. 3.5404

3.56e4 Q 528.80> 509.00 (-)

7.2
RT (min)

PFDA

Cone. 0.0033

R#1 512.90>219.00 1.74(17.51)
Q 512.90>469.00 (-)	3.98e2

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDAJS

Cone. 5.0000

13C-PFDA

Cone. 3.7859

7.6
RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 3.9426

1.84e5 Q 572.80>419.05 (-)

NMeFOSAA

Cone. 0.0049

R#1 570.20>512.00 28.99 (37.68)
Q 570.20>419.00 (-)	2.6

7.6
RT (min)

PFDS

Cone. 0.0016

R#1 599.00>99.00 0.00 (65.43)
Q 599.00>80.10 (-)	7.30e1

A=116

R1 K RT=7.$57

13C-PFUnDA IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

13C-PFUnDA

Cone. 3.9903

Q 564.80>519.95 (-)

7.6 7.8
RT (min)

PFUnDA

Cone. 0.0058

R#1 563.00>219.00 0.00 (13.86)
Q563.00>518.90 (-)	5.20e2

O.OeO -

A= 1517779
RT=7.649

j

7.25 7.50 7.75

7.6

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

O.OeO -

A=1517779
RT=7.649

v

7.6

7.8 8.0
RT (min)

PFOSA

Cone. 0.0031

R#1 498.20>64.10 0.00 (0.09)
Q 498.20>78.00 (-)	9.90e1

ISTD 588.80>419.00 (-)	2.20e5

2.0e5 -

1.0e5 -

d5-N-EtFOSAA

Cone. 4.5358

Q 588.80>419.00 (-)
2.0e5 -

1.0e5-

O.OeO -

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.0198

R#1 584.20>526.10 48.00 (58.21)
Q 584.20>418.95 (-)	1.98e2

TA=2386
RT=7.767

O.OeO -

8.0
RT (min)

7.6

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

13C-FOSA

Cone. 3.7141

1.44e5 Q 506.00>78.05 (-)

'.8 8.0
RT (min)

PFDoA

Cone. 0.0062
R#1 613.05> 169.00 7.64 (16.16)

1.44e5 Q 613.05>569.00 (-)	7.25e2 ISTD 614.80>569.95 (-)

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

6.20e5

- R1 0.00 H

A=246
"kT=7.735

f A=375522
RT=7.734

7.8 8.0

RT (min)

7.8 8.0

RT (min)

8.0
RT (min)

f A= 1591524
I RT=7.993

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

1996

-------


Insight Report
Quantitation/lntegration
Printed 10/30/2023 14:07:04

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 4.2658

Q614.80>569.95 (-)

6-0e5l Irt=1

4.0e5 :

2.0e5 :
O.OeO :

=1591524
7.993

j

d5-NEtFOSA IS

Cone. 5.0000

10-2-FtS

Cone. —

R#1 626.50>81.05 —- (76.13)

6.20e5 Q 626.50>607.05 (-)	O.OOeO ISTD 531.10> 169.10 (-)

5.0e01	|

d5-NEtFOSA

Cone. 3.6140

NMeFOSE

Cone. —

NEtFOSE

Cone. 0.0034

RT (min)

d9-EtFOSE IS

Cone. 5.0000

RT (min)

Q 629.50>59.10 (-)

1.13e3 I STD 638.90 >59.10 (-)

5.0e2 A=447
RT=8.

O.OeO -

Q 515.10> 169.00 (-)

O.OeO -

O.OeO -

8.6 8.8 9.0

RT (min)

d3-NMeFOSA

Cone. 3.8215

1.42e5 I STD 623.00 >59.00 (-)

7.5e4 -
5.0e4 :
2.5e4 :
O.OeO :

A=239654
RT=8.473



L

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 0.0082
R#1 713.00> 169.30 9.16 (11.66)

Q 713.00 > 668.90 (-)	1.31 e3 I STD 714.80 > 669.80 (-)

13C-PFTeDA IS

Cone. 5.0000

8.6 8.8 9.0

RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

9.0
RT (min)

d7-N-MeFOSE

Cone. 4.5657

9.61e4 Q 623.00> 59.00 (-)

7.5e4 ~

5.0e4 ~

2.5e4 ~

O.OeO 1, i i i

A=239654
RT=8.473



RT (min)

13C-PFTeDA

Cone. 4.3143

O.OeO -

Q 714.80>669.80 (-)

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0014

R#1 526.50>219.20 0.00 (67.00)
Q 526.50>169.10 (-)	7.20e1

1.0e3-R1 0.00 (— )

RT (min)

11CI-PF30UdS

Cone. —

Q 631.00>451.10 (-)
2.0e1 -

8.6 8.8 9.0
RT (min)

L-PFDoS

Cone. —

R#1 698.80>98.80 — - (71.85)

Q 698.80>80.10 (-)	O.OOeO Q 377.10>251.20 (-)

5.0e0 n	i

RT (min)

Q 812.90>769.00 (-)
3.0e3 -i

3.02e3 Q 912.80>869.00 (-)

B.2 8.4 8.6

RT (min)

6.2 6.4 6.6

RT (min)

O.OeO -

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.0100

R#1 663.10> 169.10 0.00 (20.38)
Q 663.10>618.90 (-)	5.40e2

9CI-PF30NS

Cone. 0.0010

2.00e1 Q 531.00>351.10 (-)

A=193
RT=7.240

13C2-PFHxDA IS

Cone. 5.0000

1.13e2 I STD 815.00 > 770.00 (-)

d9-EtFOSE

Cone. 4.5038

Q 638.90>59.10 (-)

1.46e5

O.OeO		

8.6 8.8 9.0

RT (min)

NMeFOSA

Cone. —

R#1 512.10>219.20 —- (76.94)
Q 512.10> 169.20 (-)	2.30e1

Q 616.10>58.90 (-)
3.0e1

2.0e1

1.0e1

O.OeO

3.00e1

I STD 515.10> 169.00 (-)	1.42e5

9.0

RT (min)

4.92e4

Q 531.10> 169.10 (-)

8.8
RT (min)

d3-NMeFOSA IS

Cone. 5.0000

5.0e1

O.OeO

9.6

10.0

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

WA

-------


Insight Report
Quantitation/lntegration
Printed 10/30/2023 14:07:04

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 3.7315

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 0.0009

Q 815.00>770.00 (-)

PFecHS

Cone. 0.0009
R#1 461.00>99.10 0.00 (38.14)

1,23e6 ISTD 569.80> 524.90 (-)	5.61 e5 Q 461.00>381.00 (-)	1,45e2 Q 298.00>78.00 (-)

PFHxSA

Cone. —

5.60e1 Q 397.90>78.00 (-)

A=2901446
RT=9154

O.OeO -

y

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

T A=329

-R1 aooJ-RTifc

363



JU

6.4 6.6 6.8

RT (min)

f A=170

Vt=6.131

6.0 6.2 6.4
RT (min)

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

-------
Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:26:03

CCV6-230428

Sample ID: CCV6-230428

Date Acquired: 4/29/2023 11:00:13 AM

Acquired by: System Administrator

Data File: 230428091

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.198

752128

752128

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.198

752128

1915252

13C7-PFUnDA IS

5.0000

3.7018

ng/mL

PFBA

Auto

4.198

889108

752128

13C-PFBA IS

5.0000

5.2872

nq/mL

13C-PFPeA IS

Auto

5.352

1273096

1273096

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.352

1273096

1915252

13C7-PFUnDA IS

5.0000

3.9001

nq/mL

PFPeA

Auto

5.352

1188049

1273096

13C-PFPeA IS

5.0000

5.0684

ng/mL

13C-PFBS IS

Auto

5.481

519190

519190

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.481

519190

1915252

13C7-PFUnDA IS

4.6500

3.6246

ng/mL

PFBS

Auto

5.481

343156

519190

13C-PFBS IS

4.4200

4.2576

nq/mL

13C HFPO DA IS

Auto

6.081

297259

297259

	

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.081

297259

1915252

13C7-PFUnDA IS

5.0000

4.1937

nq/mL

HFPO DA

Auto

6.081

215243

297259

13C HFPO DA IS

5.0000

4.9505

nq/mL

13C-4 2-FTS IS

Auto

5.882

227985

227985

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.882

227985

1915252

13C7-PFUnDA IS

4.6700

3.5591

ng/mL

4-2-FtS

Auto

5.882

260181

227985

13C-4 2-FTS IS

4.6700

4.8099

nq/mL

PFHxA

Auto

5.936

2262267

1669438

13C-PFHxA IS

5.0000

5.1000

ng/mL

13C-PFHxA IS

Auto

5.936

1669438

1669438

	

5.0000

5.0000

i

13C-PFHxA

Auto

5.936

1669438

1915252

13C7-PFUnDA IS

5.0000

3.7642

ng/mL

PFPeS

Auto

5.977

339023

532183

180-PFHxS IS

4.6900

4.5219

nq/mL

PFHxS

Auto

6.347

275854

532183

180-PFHxS IS

4.5500

4.0786

ng/mL

13C-PFHpA IS

Auto

6.341

1621892

1621892

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.341

1621892

1915252

13C7-PFUnDA IS

5.0000

3.7645

ng/mL

180-PFHxS IS

Auto

6.348

532183

532183

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.348

532183

1915252

13C7-PFUnDAJS

4.7250

3.7022

ng/mL

PFHpA

Auto

6.341

2435766

1621892

13C-PFHpA IS

5.0000

5.0352

ng/mL

13C2-6 2-FTS IS

Auto

6.642

209846

209846

	

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.642

209846

1915252

13C7-PFUnDA IS

4.7500

3.1273

ng/mL

PFHpS

Auto

6.652

355949

532183

180-PFHxS IS

4.7600

4.4007

ng/mL

6-2-FTS

Auto

6.643

208147

209846

13C2-6 2-FTS IS

4.7400

4.9907

nq/mL

PFOA

Auto

6.661

2602225

1901009

13C-PFOA IS

5.0000

5.0357

ng/mL

13C-PFOA IS

Auto

6.661

1901009

1901009

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.661

1901009

1915252

13C7-PFUnDA IS

5.0000

3.5494

ng/mL

PFOS

Auto

6.948

231889

475943

13C-PFOS IS

4.6400

4.6776

nq/mL

13C-PFOS IS

Auto

6.947

475943

475943

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

6.947

475943

1915252

13C7-PFUnDA IS

4.7750

3.2980

nq/mL

PFNA

Auto

6.968

2241543

1814454

13C-PFNA IS

5.0000

5.1741

ng/mL

13C-PFNA IS

Auto

6.968

1814454

1814454

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.968

1814454

1915252

13C7-PFUnDA IS

5.0000

3.8116

ng/mL

PFNS

Auto

7.273

610899

475943

13C-PFOS IS

4.8000

5.3615

nq/mL

8-2-FTS

Auto

7.299

133686

111862

13C-8 2-FTS IS

4.7900

5.0583

ng/mL

13C-8 2-FTS IS

Auto

7.299

111862

111862

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.299

111862

1915252

13C7-PFUnDA IS

4.7900

3.5386

ng/mL

PFDA

Auto

7.303

1953326

2122819

13C-PFDA IS

5.0000

4.8588

nq/mL

13C-PFDA IS

Auto

7.303

2122819

2122819

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.303

2122819

1915252

13C7-PFUnDA IS

5.0000

3.9392

nq/mL

d3-N-MeFOSAA IS

Auto

7.478

740573

740573

	

5.0000

5.0000

nq/mL

d3-N-MeFOSAA

Auto

7.478

740573

1915252

13C7-PFUnDA IS

5.0000

4.7132

nq/mL

NMeFOSAA

Auto

7.482

703085

740573

d3-N-MeFOSAA IS

5.0000

4.7833

nq/mL

PFDS

Auto

7.611

399879

475943

13C-PFOS IS

4.8200

4.7618

nq/mL

13C-PFUnDA IS

Auto

7.650

2024852

2024852

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.650

2024852

1915252

13C7-PFUnDA IS

5.0000

4.2694

nq/mL

PFUnDA

Auto

7.650

1997277

2024852

13C-PFUnDA IS

5.0000

5.0388

nq/mL

d5-N-EtFOSAA IS

Auto

7.661

828840

828840

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.661

828840

1915252

13C7-PFUnDA IS

5.0000

4.9474

nq/mL

NEtFOSAA

Auto

7.669

656938

828840

dS-N-EtFOSAA IS

5.0000

4.0067

nq/mL

PFOSA

Auto

7.733

567299

540400

13C-FOSA IS

5.0000

4.8993

nq/mL

13C-FOSA IS

Auto

7.733

540400

540400

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.733

540400

1915252

13C7-PFUnDA IS

5.0000

4.2866

nq/mL

PFDoA

Auto

7.993

2259570

2140198

13C-PFDoA IS

5.0000

4.7256

nq/mL

13C-PFDoA IS

Auto

7.993

2140198

2140198

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

Wo

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:26:03

CCV6-230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

7.993

2140198

1915252

13C7-PFUnDA IS

5.0000

4.6007

nq/mL

10-2-FtS

Auto

8.005

154429

111862

13C-8 2-FTS IS

4.8200

5.4346

ng/mL

d5-NEtFOSA IS

Auto

8.763

568089

568089

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.763

568089

1915252

13C7-PFUnDA IS

5.0000

4.3982

ng/mL

NMeFOSE

Auto

8.486

291892

338414

d7-N-MeFOSE IS

5.0000

5.2823

nq/mL

NEtFOSE

Auto

8.736

844836

194081

d9-EtFOSE IS

5.0000

4.3880

ng/mL

d9-EtFOSE IS

Auto

8.717

194081

194081

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.717

194081

1915252

13C7-PFUnDA IS

5.0000

5.2611

ng/mL

NMeFOSA

Auto

8.512

245405

507532

d3-NMeFOSA IS

5.0000

5.2479

nq/mL

dB-NMeFOSA IS

Auto

8.507

507532

507532

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.507

507532

1915252

13C7-PFUnDA IS

5.0000

4.3457

nq/mL

d7-N-MeFOSE IS

Auto

8.470

338414

338414

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.470

338414

1915252

13C7-PFUnDA IS

5.0000

5.1707

nq/mL

NEtFOSA

Auto

8.772

423088

568089

d5-NEtFOSA IS

5.0000

5.0767

ng/mL

PFTrDA

Auto

8.319

2088300

1557576

13C-PFTeDA IS

5.0000

4.4135

nq/mL

PFTeDA

Auto

8.621

2252398

1557576

13C-PFTeDA IS

5.0000

4.0389

ng/mL

13C-PFTeDA IS

Auto

8.621

1557576

1557576

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.621

1557576

1915252

13C7-PFUnDA IS

5.0000

5.0902

ng/mL

11CI-PFBOUdS

Auto

7.804

502970

475943

13C-PFOS IS

4.7100

4.6122

nq/mL

9CI-PF30NS

Auto

7.128

1152291

475943

13C-PFOS IS

4.6600

4.9042

ng/mL

L-PFDoS

Auto

8.270

171143

475943

13C-PFOS IS

4.8400

5.3969

nq/mL

NaDONA

Auto

6.386

1743562

1814454

13C-PFNA IS

4.7100

4.5525

ng/mL

PFHxDA

Auto

9.151

1712791

3880598

13C2-PFHxDA IS

5.0000

5.6293

nq/mL

PFODA

Auto

9.693

1069221

3880598

13C2-PFHxDA IS

5.0000

5.3983

ng/mL

13C2-PFHxDA IS

Auto

9.152

3880598

3880598

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.152

3880598

1915252

13C7-PFUnDA IS

5.0000

4.0026

ng/mL

13C7-PFUnDA IS

Auto

7.650

1915252

1915252

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.611

2173215

475943

13C-PFOS IS

4.6100

5.0311

ng/mL

PFBSA

Auto

6.123

1312492

540400

13C-FOSA IS

5.0000

4.6606

nq/mL

PFHxSA

Auto

6.948

1077305

1814454

13C-PFNA IS

5.0000

4.8076

ng/mL

CHARGE

ND(W/B)

	

	

1915252

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 3.7018
1.71e5 Q 217.20>172.30 (-)

PFBA

Cone. 5.2872
1.71e5 Q 213.20> 169.10 (-)

~ A=752128
RT=4.198

O.OeO

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 5.0684

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

Q263.05>219.10 (-)
4.0e5 -

4.24e5 ISTD 301.80>80.00 (-)

TA= 1188049
4t= 5.352

f A=519190
RT= 5.481

5.6

RT (min)

13C-PFPeA IS

Cone. 5.0000
1,96e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 3.9001
5.00e5 Q 267.90>223.00 (-)

O.OeO

A=1273096
T= 5.352

O.OeO

A=1273096
T= 5.352

O.OeO

4.00 4.25 4.50

RT (min)

13C-PFBS	PFBS

Cone. 3.6246	Cone. 4.2576

R#1 298.80>99.00 68.19 (65.16)

1.97e5 Q 301.80>80.00 (-)	1.97e5 Q 299.00>80.00 (-)	1.28e5 ISTD 332.10>287.10 (-)

13C HFPO DA IS

Cone. 5.0000

A=519190
T= 5.481

fA=343156

~ R1 68.1 fKT= 5.481

f A=297259
] Ff=6.081

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

m

-------


Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:26:03

CCV6-230428 (continued)

13C HFPO DA

Cone. 4.1937

Q 332.10>287.10 (-)

A=297259
RT=6.081

O.OeO -

6.0

f A=2262267

: R1 2.28 (-

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

w=

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

A=1621892
RT=6.341

44

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

'A=209846
RT=6.642

ir

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
7.5e5 H

5.0e5 :
2.5e5 ^
O.OeO :

A=1901009
RT=6.661



HFPO DA

Cone. 4.9505

R#1 329.00>285.10 77.35 (80.83)
Q 329.00>169.00 (-)	9.38e4

= R1 77.35 (

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

f A=215243
6.081

Xj

6.2 6.4
RT (min)

PFHxA

Cone. 5.1000

R#1 313.00> 119.10 2.28 (2.51)
Q 313.00>269.00 (-)	9.60e5

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

=1669438
RT= 5.936

Vi

6.2
RT (min)

13C-PFHpA

Cone. 3.7645

7.11e5 Q 366.90>322.10 (-)

6.0e5 i
4.0e5 i
2.0e5 i
O.OeO 1 . .

A=1621892
RT=6.341

6.6

RT (min)

13C2-6 2-FTS

Cone. 3.1273

8.81e4 Q 428.90>409.00 (-)

RT (min)

13C-PFOA

Cone. 3.5494

Q 416.80>372.05 (-)
7.5e5 H

5.0e5 :
2.5e5 ^
O.OeO :

f A=1901009
RT=6.661



6.8 7.0
RT (min)

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 25.75 (27.58)

ISTD 329.00>309.15 (-)	9.26e4

13C-4 2-FTS

Cone. 3.5591

R#1 329.00>81.00 25.75 (27.58)
Q 329.00>309.15 (-)	9.26e4

A=227985

6.2 6.4
RT (min)

O.OeO

5.8 6.0 6.2
RT (min)

13C-PFHxA

Cone. 3.7642

6.89e5 Q 314.90>270.10 (-)

6.89e5

6.2
RT (min)

180-PFHxS IS

Cone. 4.7250

7.11e5 ISTD 402.70>84.05 (-)

6.6

RT (min)

O.OeO -

RT (min)

6.0e4 .
4.0e4 :
2.0e4 :
O.OeO :

=231889

JR1 93.29 (- l| riT=6.948

If"

A

6.8 7.0
RT (min)

- R1 81.83 (

|f A=339023
TO= 5.977

L

6.2
RT (min)

180-PFHxS

Cone. 3.7022

2.33e5 Q 402.70>84.05 (-)

f A=532183
RT=6.348

O.OeO

6.6
RT (min)

PFHpS

Cone. 4.4007

R#1 449.00>99.20 60.44 (66.50)
Q 449.00>80.15 (-)	1.54e5

- R1 60.44 (-/V-RT=6.652

fA=208147

7.5e4
5.0e4:
2.5e4:
O.OeO :

: R1 27.76 (



6.6 6.8

RT (min)

PFOS

Cone. 4.6776

R#1 499.00>99.00 93.29 (86.07)
Q 499.00>80.00 (-)	7.18e4

13C-PFOS IS

Cone. 4.7750

ISTD 502.8
2.0e51

105 (-)

6.75 7.00 7.25

RT (min)

4-2-FtS

Cone. 4.8099

R#1 327.00 >81.10 15.87 (16.09)
Q 327.00>307.05 (-)	1.09e5

1.0e5-R1

~ A=2

15.87

260181
m= 5.882

O.OeO -

L

6.0 6.2
RT (min)

PFPeS

Cone. 4.5219

R#1 349.00>99.00 81.83 (77.24)
Q 349.00>79.95 (-)	1.43e5

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 4.0786

R#1 399.00>99.00 94.41 (85.33)
Q 399.00>80.00 (-)	9.83e4

- R1 94.41 (

=275854
6.347

O.OeO -

N

6.2

RT (min)

6.2

6.4

6.6
RT (min)

PFHpA

Cone. 5.0352

R#1 362.90 >169.00 17.37 (17.91)
Q 362.90>319.00 (-)	1.05e6

fA=2435766

1-0e6> 17.37 (Uk6341

O.OeO

6.6
RT (min)

6-2-FTS

Cone. 4.9907

R#1 427.00>80.90 27.76 (33.45)
Q 427.00>407.00 (-)	8.88e4

O.OeO

6.6
RT (min)

PFOA

Cone. 5.0357

R#1 413.00> 169.10 27.92 (27.85)
Q 413.00>369.00 (-)	1.08e6

f A=2602225
1.0e6 —IR1 27.92 (rRT=6.661

RT (min)

Q 502.8
2.0e5 -

105 (-)

A=475943
RT=6.947

6.8 7.0 7.2

RT (min)



7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

1SESB

-------
A

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:26:03

CCV6-230428 (continued)

PFNA	13C-PFNA IS

Cone. 5.1741	Cone. 5.0000
R#1 463.00>219.00 18.02 (24.00)

Q 463.00>418.90 (-)	9.28e5	ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 3.8116

7.28e5 Q 467.80>423.00 (-)

PFNS

Cone. 5.3615

R#1 549.00>99.00 61.54 (71.23)

8-2-FTS

Cone. 5.0583

R#1 527.20>487.00 7.49 (6.74)

7.28e5 Q 549.00>79.95 (-)

2.45e5 Q 527.10>506.90 (-)

~ A= 1814454
RTp 6.968

U:

7.2

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)
4.0e4 -

13C-8 2-FTS

Cone. 3.5386

4.40e4 Q 528.80>509.00 (-)
4.0e4 -

7.2
RT (min)

PFDA

Cone. 4.8588

R#1 512.90>219.00 17.24(17.51)
Q 512.90>469.00 (-)	7.87e5

fA= 133686
IR1 7-49 (|-Rti7.299

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 3.9392

ISTD 514.80>469.95 (-)

8.57e5 Q 514.80>469.95 (-)

7.6
RT (min)



rA=2122819



RT| 7.303



I

I I I ~ I I I 'l I I I I I I I

d3-N-MeFOSAAJS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 4.7132

2.81 e5 Q 572.80>419.05 (-)

O.OeO

7.6
RT (min)

NMeFOSAA

Cone. 4.7833

R#1 570.20>512.00 42.48 (37.68)
Q 570.20>419.00 (-)	2.22e5

f A=703085

R1 42.48 (-|"RI=7.482

J\1

7.4 7.6

RT (min)

PFDS

Cone. 4.7618

R#1 599.00>99.00 62.63 (65.43)
Q 599.00>80.10 (-)	1.57e5

TA=399879

1.5e5-
1.0e5:

5.0 e4 7
O.OeO :

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

: R1 62.63

"RT=

7.611 :

:



6.0e5 -

:



4.0e5 -j

:



2.0e5 -



V,

~	 0 OeO -

7.6 7.8
RT (min)

7.4

13C-PFUnDA

Cone. 4.2694

Q 564.80>519.95 (-)

7.6 7.8
RT (min)

PFUnDA

Cone. 5.0388

R#1 563.00>219.00 11.68 (13.86)
Q563.00>518.90 (-)	7.22e5

7.25 7.50 7.75

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

d5-N-EtFOSAA

Cone. 4.9474

2.94e5 Q 588.80>419.00 (-)

7.6 7.8 8.0
RT (min)

NEtFOSAA

Cone. 4.0067

R#1 584.20>526.10 51.28 (58.21)
Q 584.20>418.95 (-)	2.42e5

O.OeO

7.8 8.0
RT (min)

PFOSA

Cone. 4.8993

R#1 498.20>64.10 0.18 (0.09)
Q 498.20>78.00 (-)	2.20e5

TA= 567299
2.0e5 -|R1 0.18 (--J-kT=7.733

O.OeO -

- R1 51.28 (

A=656938

O.OeO

7.8 8.0
RT (min)

7.6

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)
2.0e5 H

13C-FOSA

Cone. 4.2866

Q 506.00>78.05 (-)
2.0e5 H

7.8 8.0
RT (min)

PFDoA

Cone. 4.7256

R#1 613.05> 169.00 15.28 (16.16)
Q 613.05>569.00 (-)	8.75e5

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

8.23e5

8.0
RT (min)

7.8 8.0

RT (min)

7.8 8.0

RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

100

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:26:03

CCV6-230428 (continued)

13C-PFDoA

Cone. 4.6007

NEtFOSE

Cone. 4.3880

Q629.50>59.10 (-)
3.0e5 ^

2.0e5 ^

1.0e5 ^

O.OeO 4-

^=844836
RT=8.736

8.6

d3-NMeFOSA

Cone. 4.3457

Q 515.10> 169.00 (-)

O.OeO -

TA=5
RT=.

507532
RT=8.507

8.6

6.0e4 -
4.0e4 :
2.0e4 :
O.OeO :

f A=171143

: R1 69-94(rt4.270

u

10-2-FtS

Cone. 5.4346

R#1 626.50>81.05 56.82 (76.13)
Q 626.50>607.05 (-)	5.60e4

RT (min)

d9-EtFOSE IS

Cone. 5.0000

3.29e5 ISTD 638.90> 59.10 (-)

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

9.0
RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

1,95e5 I STD 623.00 > 59.00 (-)

fA=338414
RT=8.470

Vj

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 4.0389

R#1 713.00 >169.30 9.24 (11.66)
Q 713.00>668.90 (-)	8.51 e5

7.5e5 -
5.0e5 -
2.5e5 -
O.OeO -

13C-PFTeDA IS

Cone. 5.0000

I STD 714.80 >669.80 (-)

.8 9.0
RT (min)

L-PFDoS

Cone. 5.3969

R#1 698.80>98.80 69.94 (71.85)
Q 698.80>80.10 (-)	7.24e4

NaDONA

Cone. 4.5525

Q377.10>251.20 (-)
7.5e5 -
5.0e5 ^

2.5e5 ^

O.OeO 1 . . .

A=1743562
RT=6.386



8.4 8.6
RT (min)

d5-NEtFOSA IS

Cone. 5.0000

I STD 531.10> 169.10 (-)
2.0e5 -

A= 568089
RT=8.763

1.0e5 -

d5-NEtFOSA

Cone. 4.3982

2.21 e5 Q 531.10> 169.10 (-)
2.0e5 -

1.0e5-

RT (min)

d9-EtFOSE

Cone. 5.2611

7.58e4 Q 638.90> 59.10 (-)

6.0e4 ~

4.0e4 ~

2.0e4 ~
== O.OeO 1 . . .

=194081
|RT=8.717

9.0
RT (min)

d7-N-MeFOSE

Cone. 5.1707

1.36e5 Q 623.00> 59.00 (-)

RT (min)

13C-PFTeDA

Cone. 5.0902

5.94e5 Q 714.80>669.80 (-)

9.0
RT (min)

PFHxDA

Cone. 5.6293

7.92e5 Q 812.90>769.00 (-)

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :



fA= 1712791

:

RT=9

151





6.6

RT (min)

NMeFOSE

Cone. 5.2823

2.21 e5 Q 616.10>58.90 (-)

^=568089
RT=8.763

O.OeO -h=

Vj

9.0

RT (min)

: R1 77.82 (-

7.5e4 -
5.0e4z_
2.5e4z_
O.OeO -

9.0
RT (min)

RT (min)

11CI-PF30UdS

Cone. 4.6122

Q 631.00>451.10 (-)
2.0e5



fA=5

02970

;

RT=

7.804



V

w

9.0
RT (min)

PFODA

Cone. 5.3983

7.20e5 Q 912.80>869.00 (-)

9.4

RT (min)

fA=291892
I RT=8.486



8.6 8.8 9.0

RT (min)

NMeFOSA

Cone. 5.2479

R#1 512.10>219.20 77.82 (76.94)
Q 512.10> 169.20 (-)	9.54e4

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

O.OeO -

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 5.0767

R#1 526.50>219.20 64.66 (67.00)
Q 526.50> 169.10 (-)	1.62e5

f A=423088
1.5e5HR1 64.66 (•|W=8.772

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 4.4135

R#1 663.10> 169.10 17.47 (20.38)
Q 663.10>618.90 (-)	8.18e5

A=2088300
7.5e5 —| R.1 17.4; i(rt^8.319

8.6

RT (min)

9CI-PF30NS

Cone. 4.9042

2.04e5 Q 531.00>351.10 (-)

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

3.72e5 I STD 815.00 > 770.00 (-)



9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

20ffi

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Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:26:03

CCV6-230428 (continued)

13C2-PFHxDA

Cone. 4.0026

13C7-PFUnDA IS

Cone. 5.0000

>524.90 (-)

PFBSA

Cone. 4.6606

PFecHS

Cone. 5.0311
R#1 461.00>99.10 37.75 (38.14)

6.97e5 Q 461.00>381.00 (-)	8.91 e5 Q 298.00>78.00 (-)

TA=2173215
jlw=6.611

9.4
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

RT (min)

0.2
RT (min)

PFHxSA

Cone. 4.8076

Q 397.90>78.00 (-)
4.0e5 -

6.4
RT (min)

7.2
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

202

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:23

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/29/2023 2:12:46 PM

Acquired by: System Administrator

Data File: 230428105

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 1

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.194

623451

623451

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.194

623451

1351715

13C7-PFUnDA IS

5.0000

4.3477

ng/mL

PFBA

M

4.141

2137

623451

13C-PFBA IS

0.1000

0.0153

nq/mL

13C-PFPeA IS

Auto

5.361

1076648

1076648

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.361

1076648

1351715

13C7-PFUnDA IS

5.0000

4.6734

nq/mL

PFPeA

Auto

5.362

1640

1076648

13C-PFPeA IS

0.1000

0.0083

ng/mL

13C-PFBS IS

Auto

5.491

410578

410578

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.491

410578

1351715

13C7-PFUnDA IS

4.6500

4.0613

ng/mL

PFBS

ND(W, "





410578

13C-PFBS IS

0.0880



ng/mL

13C HFPO DA IS

Auto

6.092

242247

242247

—-

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.092

242247

1351715

13C7-PFUnDA IS

5.0000

4.8425

nq/mL

HFPO DA

ND(W/B)

	

	

242247

13C HFPO DA IS

0.1000

	

nq/mL

13C-4 2-FTS IS

Auto

5.894

182582

182582

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.894

182582

1351715

13C7-PFUnDAJS

4.6700

4.0386

ng/mL

4-2-FtS

ND(W, ~





182582

13C-4 2-FTS IS

0.0930



ng/mL

PFHxA

Auto

5.948

3435

1389638

13C-PFHxA IS

0.1000

0.0093

ng/mL

13C-PFHxA IS

Auto

5.947

1389638

1389638



-

5.0000

ng/mL

13C-PFHxA

Auto

5.947

1389638

1351715

13C7-PFUnDA IS

5.0000

4.4396

ng/mL

PFPeS

Auto

5.838

141

430866

180-PFHxS IS

0.0940

0.0023

nq/mL

PFHxS

M

6.358

822

430866

180-PFHxS IS

0.0910

0.0150

ng/mL

13C-PFHpA IS

Auto

6.352

1353368

1353368

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.352

1353368

1351715

13C7-PFUnDA IS

5.0000

4.4508

ng/mL

180-PFHxS IS

Auto

6.359

430866

430866

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.359

430866

1351715

13C7-PFUnDAJS

4.7250

4.2470

ng/mL

PFHpA

Auto

6.365

1784

1353368

13C-PFHpA IS

0.1000

0.0044

ng/mL

13C2-6 2-FTS IS

Auto

6.653

181472

181472

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.653

181472

1351715

13C7-PFUnDA IS

4.7500

3.8320

ng/mL

PFHpS

Auto

6.694

153

430866

180-PFHxS IS

0.0950

0.0023

ng/mL

6-2-FTS

Auto

6.923

131

181472

13C2-6 2-FTS IS

0.0950

0.0036

nq/mL

PFOA

Auto

6.676

2768

1662598

13C-PFOA IS

0.1000

0.0061

ng/mL

13C-PFOA IS

Auto

6.670

1662598

1662598

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.670

1662598

1351715

13C7-PFUnDA IS

5.0000

4.3985

ng/mL

PFOS

Auto

6.948

1107

397805

13C-PFOS IS

0.0930

0.0267

nq/mL

13C-PFOS IS

Auto

6.956

397805

397805

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

6.956

397805

1351715

13C7-PFUnDA IS

4.7750

3.9057

nq/mL

PFNA

Auto

6.972

1010

1549627

13C-PFNA IS

0.1000

0.0027

ng/mL

13C-PFNA IS

Auto

6.976

1549627

1549627

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.976

1549627

1351715

13C7-PFUnDAJS

5.0000

4.6125

ng/mL

PFNS

NDfW, "

—-

—-

397805

13C-PFOSJS

0.0960

—-

ng/mL

8-2-FTS

ND(W/B)





82908

13C-8_2-FTSJS

0.0960



ng/mL

13C-8 2-FTS IS

Auto

7.304

82908

82908

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.304

82908

1351715

13C7-PFUnDA IS

4.7900

3.7161

ng/mL

PFDA

M

7.313

1370

1623306

13C-PFDA IS

0.1000

0.0045

nq/mL

13C-PFDA IS

Auto

7.309

1623306

1623306

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.309

1623306

1351715

13C7-PFUnDA IS

5.0000

4.2681

nq/mL

d3-N-MeFOSAA IS

Auto

7.483

500234

500234

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.483

500234

1351715

13C7-PFUnDA IS

5.0000

4.5109

nq/mL

NMeFOSAA

Auto

7.477

697

500234

d3-N-MeFOSAA IS

0.1000

0.0070

nq/mL

PFDS

ND(W/B)

	

	

397805

13C-PFOS IS

0.0960

	

nq/mL

13C-PFUnDA IS

Auto

7.653

1479965

1479965

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.653

1479965

1351715

13C7-PFUnDA IS

5.0000

4.4215

nq/mL

PFUnDA

Auto

7.708

3678

1479965

13C-PFUnDA IS

0.1000

0.0127

nq/mL

d5-N-EtFOSAA IS

Auto

7.664

601351

601351

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.664

601351

1351715

13C7-PFUnDA IS

5.0000

5.0860

nq/mL

NEtFOSAA

Auto

7.819

1058

601351

d5-N-EtFOSAA IS

0.1000

0.0089

nq/mL

PFOSA

ND(W/B)

	

	

364222

13C-FOSA IS

0.1000

	

nq/mL

13C-FOSA IS

Auto

7.742

364222

364222

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.742

364222

1351715

13C7-PFUnDA IS

5.0000

4.0936

nq/mL

PFDoA

Auto

7.997

1819

1454513

13C-PFDoA IS

0.1000

0.0056

nq/mL

13C-PFDoA IS

Auto

7.996

1454513

1454513

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

203

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:23

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone. Cone. Unit

1BC-PFD0A

Auto

7.996

1454513

1351715

13C7-PFUnDA IS

5.0000

4.4302

nq/mL

10-2-FtS

ND(W/B)

	

	

82908

13C-8 2-FTS IS

0.0960

	

ng/mL

d5-NEtFOSA IS

Auto

8.777

355878

355878

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.777

355878

1351715

13C7-PFUnDA IS

5.0000

3.9039

ng/mL

NMeFOSE

ND(W/B)

	

—

242821

d7-N-MeFOSE IS

0.1000

—

nq/mL

NEtFOSE

Auto

8.926

674

126007

d9-EtFOSE IS

0.1000

0.0054

ng/mL

d9-EtFOSE IS

Auto

8.734

126007

126007

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.734

126007

1351715

13C7-PFUnDA IS

5.0000

4.8398

ng/mL

NMeFOSA

ND(W/B)

—

—

347888

d3-NMeFOSA IS

0.1000

—

nq/mL

dB-NMeFOSA IS

Auto

8.521

347888

347888

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.521

347888

1351715

13C7-PFUnDA IS

5.0000

4.2207

nq/mL

d7-N-MeFOSE IS

Auto

8.487

242821

242821

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.487

242821

1351715

13C7-PFUnDA IS

5.0000

5.2569

nq/mL

NEtFOSA

Auto

8.790

158

355878

d5-NEtFOSA IS

0.1000

0.0030

ng/mL

PFTrDA

Auto

8.520

1051

908338

13C-PFTeDA IS

0.1000

0.0038

nq/mL

PFTeDA

Auto

8.612

2345

908338

13C-PFTeDA IS

0.1000

0.0072

ng/mL

13C-PFTeDA IS

Auto

8.617

908338

908338

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.617

908338

1351715

13C7-PFUnDA IS

5.0000

4.2061

ng/mL

11CI-PFBOUdS

ND(W/B)

	

	

397805

13C-PFOS IS

0.0940

	

nq/mL

9CI-PF30NS

ND(W/B)

	

	

397805

13C-PFOS IS

0.0930

	

ng/mL

L-PFDoS

ND(W/B)

	

	

397805

13C-PFOS IS

0.0970

	

nq/mL

NaDONA

M

6.506

39

1549627

13C-PFNA IS

0.0940

0.0001

ng/mL

PFHxDA

Auto

9.147

5824

2759870

13C2-PFHxDA IS

0.1000

-0.0151

nq/mL

PFODA

Auto

9.684

424

2759870

13C2-PFHxDA IS

0.1000

0.0030

ng/mL

13C2-PFHxDA IS

Auto

9.147

2759870

2759870

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.147

2759870

1351715

13C7-PFUnDA IS

5.0000

4.0334

ng/mL

13C7-PFUnDA IS

Auto

7.653

1351715

1351715

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.730

346

397805

13C-PFOS IS

0.0920

0.0010

ng/mL

PFBSA

ND(W/B)

	

	

364222

13C-FOSA IS

0.1000

	

nq/mL

PFHxSA

M

6.903

250

1549627

13C-PFNA IS

0.1000

0.0013

ng/mL

CHARGE

ND(W/B)

	

	

1351715

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 4.3477
1.49e5 Q 217.20>172.30 (-)

PFBA

Cone. 0.0153
1.49e5 Q 213.20> 169.10 (-)

f A=623451
RT=4.194

TA=623451
RT=4.194

O.OeO -

O.OeO -

O.OeO -

13C-PFPeA IS

Cone. 5.0000
4.95e2 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.6734
4.70e5 Q 267.90>223.00 (-)

O.OeO

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 0.0083	Cone. 4.6500	Cone. 4.0613 Cone.—

A=1076648
'T= 5.361

O.OeO -

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)

9.42e2 ISTD 301.80>80.00 (-)

A=410578
fl"= 5.491

I

1.71e5 Q 301.80>80.00 (-)

1.5e5 ^

1.0e5 ^

5.0e4 ^

O.OeO 1, , ,

R#1 298.80>99.00 — - (65.16)

1.71e5 Q 299.00>80.00 (-)	4.70e1 ISTD 332.10>287.10 (-)

1.13e5

A=410578
fl"= 5.491

5.6 5.8
RT (min)

5.6 5.8
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

203

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:23

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 4.8425

Q 332.10>287.10 (-)

O.OeO -

HFPO DA

Cone. —

R#1 329.00 >285.10

Q 329.00>169.00 (-)

1.5e2 -

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 27.47 (27.58)

ISTD 329.00>309.15 (-)	8.00e4

TA= 182582
5.894

13C-4 2-FTS

Cone. 4.0386

R#1 329.00>81.00 27.47 (27.58)

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 0.0093

R#1 313.00> 119.10 0.00 (2.51)
Q 313.00>269.00 (-)	1.66e3

~ A= 182582
5.894

6.0 6.2
RT (min)

13C-PFHxA IS

Cone. 5.0000

I STD 314.90 >270.10 (-)
6.0e5 H

A=1389638
'T= 5.947

13C-PFHpA IS

Cone. 5.0000

I STD 366.90 >322.10 (-)
6.0e51

4.0e5 :
2.0e5 :
O.OeO -

=1353368
lT=6.352



Q 366.90>322.10 (-)
6.0e5 -

4.0e5 -

2.0e5 ^

O.OeO 1 . . .

=1353368
lT=6.352

L

6.6

RT (min)

13C2-6 2-FTS IS

Cone. 4.7500

I STD 428.90>409.00 (-)

6.0e4 ~

4.0e4 ~

2.0e4 ~

O.OeO 1, i i

13C2-6 2-FTS

Cone. 3.8320

7.31e4 Q 428.90>409.00 (-)

6.0e4 ~

4.0e4 ~

2.0e4 ~

== O.OeO 1. . .

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

I STD 416.80 >372.05 (-)

13C-PFOA

Cone. 4.3985

7.10e5 Q416.80>372.05 (-)

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

A=1662598
RT=6.670

L

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

A=1662598
RT=6.670



6.8 7.0
RT (min)

Q 314.90>270.10 (-)
6.0e5 -

4.0e5 -

2.0e5 ^

O.OeO 1 . ~. .

6.17e5 Q 349.00>79.95 (-)

A= 1389638	JA=141

1T= 5.947	1 -0e21 R1 i#^5.-8^l

O.OeO

6.2
RT (min)

180-PFHxS IS

Cone. 4.7250

6.2	5.8 6.0 6.2

RT (min)	RT (min)

180-PFHxS

Cone. 4.2470

6.11e5 I STD 402.70>84.05 (-)

1.97e5 Q 402.70>84.05 (-)

ir

430866
tT=6.359

O.OeO -

O.OeO -

6.6

RT (min)

6.2

6.4

6.6
RT (min)

PFHpS

Cone. 0.0023

R#1 449.00>99.20 0.00 (66.50)
Q 449.00>80.15 (-)	6.70e1

6.2

6.4

7.5e1
5.0e1 :
2.5e1 :
O.OeO :

A=153
IR1 0 00 RT=6.6

= 131

: R1 0 00 (—") IrT=6.923

6.0e1:
4.0e1 :
2.0e1 :
O.OeO :

6.6 6.8

RT (min)

PFOS

Cone. 0.0267

R#1 499.00>99.00 68.57 (86.07)
Q 499.00>80.00 (-)	1.98e2

1107

- R1 68.57 (- =6.948

13C-PFOS IS

Cone. 4.7750

105 (-)

A=397805
RT=6.956

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

4-2-FtS

Cone. —

R#1 327.00>81.10 —- (16.09)

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 0.0023

R#1 349.00>99.00 0.00 (77.24)

8.00e4 Q 327.00>307.05 (-)
3.0e2 -
2.0e2 ^

1.0e2 7
O.OeO :

a A/a

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.0150

R#1 399.00>99.00 80.05 (85.33)

1.06e2 Q 399.00>80.00 (-)

- R1 80.05 (-

4.01e2

O.OeO

6.6

RT (min)
PFHpA

Cone. 0.0044

R#1 362.90 >169.00 0.00 (17.91)
1,97e5 Q 362.90>319.00 (-)	6.67e2

f A=1784
6.0e2^R1 °-00 (— bpT=6.365

6.6
RT (min)

6-2-FTS

Cone. 0.0036

R#1 427.00>80.90 0.00 (33.45)
Q 427.00>407.00 (-)	7.50e1

6.6
RT (min)

PFOA

Cone. 0.0061

R#1 413.00> 169.10 16.57 (27.85)
Q 413.00>369.00 (-)	1.26e3

fA=2768

IR1 16.57 (- |-RT=6.676

RT (min)

6.6 6.8 7.0
RT (min)

13C-PFOS

Cone. 3.9057

1.69e5 Q 502.80>80.05 (-)

1.5e5^

1.0e5^

5.0e4 -

A=397805
RT=6.956

O.OeO -

L

7.2

RT (min)

7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

20§

-------
Aw_sS

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:23

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0027

R#1 463.00>219.00 1.44 (24.00)

Q 463.00>418.90 (-)	5.72e2

TA=1010

:r'	RT=6.972

4.0e2 -	II,

13C-PFNAJS

Cone. 5.0000

13C-PFNA

Cone. 4.6125

7.2

RT (min)

13C-8_2-FTSJS

Cone. 4.7900

ISTD 528.80>509.00 (-;
3.0e4 -
2.0e4 ^

1.0e4 ^

O.OeO 4-------

d3-N-MeFOSAA_IS

Cone. 5.0000

ISTD 572.80>419.05 (-;

13C-PFUnDA

Cone. 4.4215

Q 564.80>519.95 (-)

FA= 1479965
I RT=b.653

13C-8_2-FTS

Cone. 3.7161

Q 528.80> 509.00 (-;
3.0e4 -

7.6
RT (min)

d3-N-MeFOSAA

Cone. 4.5109

Q 572.80>419.05 (-)

~ A= 500234
RT^7.483

7.4 7.6 7.8

RT (min)

PFUnDA

Cone. 0.0127

R#1 563.00>219.00 0.00 (13.86)

Q 563.00>518.90 (-)	4.59e2

7.25 7.50 7.75

d5-N-EtFOSAAJS

Cone. 5.0000

O.OeO -

7.8 8.0
RT (min)

PFOSA

Cone. —

R#1 498.20 >64.10 — - (0.09)
Q 498.20>78.00 (-)	3.10e1

3.0e1 -
2.0e1 :
I.Oel :
O.OeO :

ISTD 588.80>419.00 (-;
2.0e5

O.OeO -

A=601351
RT=(7.664

13C-FOSAJS

Cone. 5.0000

ISTD 506.00>78.05 (-)

7.6 7.8 8.0
RT (min)

13C-FOSA

Cone. 4.0936

1.46e5 Q 506.00>78.05 (-)

f A=364222
I RT=7.742

f A=364222

1 dt=7 742

7.8 8.0

RT (min)

7.8 8.0

RT (min)

PFNS

Cone. —

R#1 549.00 >99.00 — - (71.23)

Q 549.00>79.95 (-)

5.0e0 -

8-2-FTS

Cone. —

R#1 527.20>487.00 —- (6.74)

O.OOeO Q 527.10>506.90 (-)	(

5.0e0 n	i

7.2

RT (min)

PFDA

Cone. 0.0045

R#1 512.90>219.00 18.15 (17.51)

Q 512.90>469.00 (-)	3.24e2

13C-PFDAJS

Cone. 5.0000

ISTD 514.80>469.95 (-)	£

~ A= 1623306
RT^ 7.309

7.6
RT (min)

NMeFOSAA

Cone. 0.0070

R#1 570.20>512.00 7.99 (37.68)

Q 570.20>419.00 (-)	2.75e2

¥ A=697

5 i""[l"pd=7.477

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 5.0860

Q 588.80>419.00 (-;
2.0e5

O.OeO-

7.4 7.6
RT (min)

13C-PFDA

Cone. 4.2681

Q 514.80>469.95 (-;
6.0e5 ^

4.0e5 ^

2.0e5 ^

O.OeO :,

7.4 7.6

RT (min)

Y A=1623306
RT^ 7.309

7.2 7.4 7.6

RT (min)

PFDS

Cone. —

R#1 599.00>99.00 —- (65.43)

Q 599.00>80.10 (-)	7.90e1

7.5e1 -	|

5.0e1 ^	|

2.5e1 ^	|

O.OeO 		

7.6
RT (min)

13C-PFUnDAJS

Cone. 5.0000

ISTD 564.80>519.95 (-)

f A=1479965
I RT=|7.653

O.OeO -

-r:
7.6

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.0089

R#1 584.20>526.10 20.69 (58.21)

Q 584.20>418.95 (-)	2.07e2

2.0e2 H ol\>

A=1058
RT^7.819

1;

O.OeO -

7.6

7.8 8.0
RT (min)

PFDoA

Cone. 0.0056
R#1 613.05>169.00 3.87 (16.16)

1.46e5 Q 613.05>569.00 (-)	8.48e2 ISTD 614.80>569.95 (-;

7.50 7.75 8.00

RT (min)

13C-PFDoA_IS

Cone. 5.0000

5.61e5

7.5e2 -

5.0e2:
2.5e2:
O.OeO :

~ A=1819
i RT=k997

Y A=1454513
l] RT="f.996

7.6 7.8 8.0

RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

206

-------
A

(al^)

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:23

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 4.4302

Q614.80>569.95 (-)

10-2-FtS

Cone. —

R#1 626.50>81.05 —- (76.13)
Q 626.50>607.05 (-)	O.OOeO

5.0e0 n	i

d5-NEtFOSA IS

Cone. 5.0000

d5-NEtFOSA

Cone. 3.9039

ISTD 531.10> 169.10 (-)	1.38e5 Q 531.10> 169.10 (-)	1.38e5

RT (min)

RT (min)

NEtFOSE

Cone. 0.0054

Q 629.50>59.10 (-)

d9-EtFOSE IS

Cone. 5.0000

O.OeO

8.6 8.8 9.0

RT (min)

d9-EtFOSE

Cone. 4.8398

9.61e2 ISTD 638.90>59.10 (-)	4.87e4 Q 638.90>59.10 (-)

9.0
RT (min)

d3-NMeFOSA

Cone. 4.2207

Q 515.10> 169.00 (-)

d7-N-MeFOSE IS

Cone. 5.0000

1,35e5 ISTD 623.00> 59.00 (-)

d7-N-MeFOSE

Cone. 5.2569

9.44e4 Q 623.00> 59.00 (-)

A=242821
RT=8.487

O.OeO

8.4 8.6

RT (min)

PFTeDA

Cone. 0.0072

R#1 713.00 >169.30 3.45 (11.66)
Q 713.00>668.90 (-)	9.34e2

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 4.2061

3.41 e5 Q714.80>669.80 (-)

9.0
RT (min)

L-PFDoS

Cone. —

R#1 698.80>98.80 — - (71.85)
Q 698.80>80.10 (-)	O.OOeO

5.0e0 n	i

NaDONA

Cone. 0.0001

Q 377.10>251.20 (-)
7.5e1 ^

5.0e1 ^

2.5e1 ^

O.OeO 4==

PFHxDA

Cone. -0.0151

8.00e1 Q 812.90>769.00 (-)

A^39
R|"=6.506

B.2 8.4 8.6

RT (min)

6.2

6.4

6.6

RT (min)

O.OeO

NMeFOSE

Cone. —

Q 616.10>58.90 (-)
2.0e1 -

.6 8.8 9.0

RT (min)

NMeFOSA

Cone. —

R#1 512.10>219.20 —- (76.94)

4.87e4 Q 512.10 > 169.20 (-)	O.OOeO I STD 515.10 > 169.00 (-)

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0030

R#1 526.50>219.20 4.61 (67.00)
Q 526.50> 169.10 (-)	1.16e2

- R1 4.61 (—

O.OeO

8.4 8.6

RT (min)

PFTrDA

Cone. 0.0038

R#1 663.10> 169.10 0.00 (20.38)
Q 663.10>618.90 (-)	3.72e2

A=1051

RT (min)

8.6

RT (min)

11CI-PF30UdS

Cone. —

3.41 e5 Q 631.00>451.10 (-)

9CI-PF30NS

Cone. —

Q 531.00>351.10 (-)
1.5e1 ^

1.0e1 ^

5.0e0 ^

O.OeO 1	

RT (min)

PFODA

Cone. 0.0030

2.67e3 Q 912.80>869.00 (-)

7.0

13C2-PFHxDA IS

Cone. 5.0000

7.4

RT (min)

1,34e2 I STD 815.00 > 770.00 (-)

9.6 9.8 10.0

RT (min)

9.0 9.2 9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

20B

-------


Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:23

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 4.0334

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. —

PFecHS

Cone. 0.0010
R#1 461.00>99.10 0.00 (38.14)

1.17e6 ISTD 569.80>524.90 (-)	5.10e5 Q461.00>381.00 (-)	1.42e2 Q 298.00>78.00 (-)

PFHxSA

Cone. 0.0013

4.00e1 Q 397.90>78.00 (-)

O.OeO

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -



'A= 1351715



RT=7.653

J

~

¦ ¦ A ¦

i i i i i i i i i i

7.6

CO
CO

o



RT (min)

0.2
RT (min)

f A=346

: R1 0.00 (—-) I RT=6.730

4.0e1 -

6.4 6.6 6.8

RT (min)

6.0 6.2 6.4
RT (min)

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

208

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:27

CCV7-230428

Sample ID: CCV7-230428

Date Acquired: 4/29/2023 2:40:14 PM

Acquired by: System Administrator

Data File: 230428107

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.202

773761

773761

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.202

773761

1659175

13C7-PFUnDA IS

5.0000

4.3960

ng/mL

PFBA

Auto

4.202

893066

773761

13C-PFBA IS

5.0000

5.1623

nq/mL

13C-PFPeA IS

Auto

5.358

1253981

1253981

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.358

1253981

1659175

13C7-PFUnDA IS

5.0000

4.4344

nq/mL

PFPeA

Auto

5.359

1194773

1253981

13C-PFPeA IS

5.0000

5.1748

ng/mL

13C-PFBS IS

Auto

5.489

507141

507141

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.489

507141

1659175

13C7-PFUnDA IS

4.6500

4.0869

ng/mL

PFBS

Auto

5.489

342785

507141

13C-PFBS IS

4.4200

4.3540

nq/mL

13C HFPO DA IS

Auto

6.088

291644

291644

	

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.088

291644

1659175

13C7-PFUnDA IS

5.0000

4.7496

nq/mL

HFPO DA

Auto

6.089

220164

291644

13C HFPO DA IS

5.0000

5.1612

nq/mL

13C-4 2-FTS IS

Auto

5.890

222383

222383

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.890

222383

1659175

13C7-PFUnDA IS

4.6700

4.0075

ng/mL

4-2-FtS

Auto

5.890

254131

222383

13C-4 2-FTS IS

4.6700

4.8164

nq/mL

PFHxA

Auto

5.944

2258637

1684204

13C-PFHxA IS

5.0000

5.0472

ng/mL

13C-PFHxA IS

Auto

5.944

1684204

1684204

	

5.0000

5.0000

i

13C-PFHxA

Auto

5.944

1684204

1659175

13C7-PFUnDA IS

5.0000

4.3836

ng/mL

PFPeS

Auto

5.985

333436

521104

180-PFHxS IS

4.6900

4.5419

nq/mL

PFHxS

Auto

6.354

274723

521104

180-PFHxS IS

4.5500

4.1482

ng/mL

13C-PFHpA IS

Auto

6.348

1673364

1673364

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.348

1673364

1659175

13C7-PFUnDA IS

5.0000

4.4834

ng/mL

180-PFHxS IS

Auto

6.355

521104

521104

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.355

521104

1659175

13C7-PFUnDAJS

4.7250

4.1847

ng/mL

PFHpA

Auto

6.348

2481643

1673364

13C-PFHpA IS

5.0000

4.9722

ng/mL

13C2-6 2-FTS IS

Auto

6.648

210468

210468

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.648

210468

1659175

13C7-PFUnDA IS

4.7500

3.6207

ng/mL

PFHpS

Auto

6.658

347823

521104

180-PFHxS IS

4.7600

4.3916

ng/mL

6-2-FTS

Auto

6.648

208179

210468

13C2-6 2-FTS IS

4.7400

4.9767

nq/mL

PFOA

Auto

6.667

2658928

1966139

13C-PFOA IS

5.0000

4.9750

ng/mL

13C-PFOA IS

Auto

6.667

1966139

1966139

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.667

1966139

1659175

13C7-PFUnDA IS

5.0000

4.2376

ng/mL

PFOS

Auto

6.952

229514

476095

13C-PFOS IS

4.6400

4.6282

nq/mL

13C-PFOS IS

Auto

6.952

476095

476095

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

6.952

476095

1659175

13C7-PFUnDA IS

4.7750

3.8082

nq/mL

PFNA

Auto

6.972

2185495

1824186

13C-PFNA IS

5.0000

5.0178

ng/mL

13C-PFNA IS

Auto

6.972

1824186

1824186

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.972

1824186

1659175

13C7-PFUnDA IS

5.0000

4.4235

ng/mL

PFNS

Auto

7.275

565723

476095

13C-PFOS IS

4.8000

4.9634

nq/mL

8-2-FTS

Auto

7.300

124505

116847

13C-8 2-FTS IS

4.7900

4.4876

ng/mL

13C-8 2-FTS IS

Auto

7.301

116847

116847

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.301

116847

1659175

13C7-PFUnDA IS

4.7900

4.2668

ng/mL

PFDA

Auto

7.305

1933909

2094195

13C-PFDA IS

5.0000

4.8762

nq/mL

13C-PFDA IS

Auto

7.305

2094195

2094195

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.305

2094195

1659175

13C7-PFUnDA IS

5.0000

4.4859

nq/mL

d3-N-MeFOSAA IS

Auto

7.479

753127

753127

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.479

753127

1659175

13C7-PFUnDA IS

5.0000

5.5328

nq/mL

NMeFOSAA

Auto

7.483

709036

753127

d3-N-MeFOSAA IS

5.0000

4.7434

nq/mL

PFDS

Auto

7.613

372073

476095

13C-PFOS IS

4.8200

4.4293

nq/mL

13C-PFUnDA IS

Auto

7.651

1932790

1932790

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.651

1932790

1659175

13C7-PFUnDA IS

5.0000

4.7043

nq/mL

PFUnDA

Auto

7.650

1848739

1932790

13C-PFUnDA IS

5.0000

4.8862

nq/mL

d5-N-EtFOSAA IS

Auto

7.661

798536

798536

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.661

798536

1659175

13C7-PFUnDA IS

5.0000

5.5022

nq/mL

NEtFOSAA

M

7.668

765362

798536

dS-N-EtFOSAA IS

5.0000

4.8452

nq/mL

PFOSA

Auto

7.739

545647

499335

13C-FOSA IS

5.0000

5.0999

nq/mL

13C-FOSA IS

Auto

7.739

499335

499335

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.739

499335

1659175

13C7-PFUnDA IS

5.0000

4.5722

nq/mL

PFDoA

Auto

7.992

2023156

1992608

13C-PFDoA IS

5.0000

4.5446

nq/mL

13C-PFDoA IS

Auto

7.992

1992608

1992608

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

208

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A

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:27

CCV7-230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

7.992

1992608

1659175

13C7-PFUnDA IS

5.0000

4.9445

nq/mL

10-2-FtS

Auto

8.004

151356

116847

13C-8 2-FTS IS

4.8200

5.0993

ng/mL

d5-NEtFOSA IS

Auto

8.777

544053

544053

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.777

544053

1659175

13C7-PFUnDA IS

5.0000

4.8622

ng/mL

NMeFOSE

Auto

8.500

271892

339729

d7-N-MeFOSE IS

5.0000

4.9013

nq/mL

NEtFOSE

Auto

8.751

837747

179211

d9-EtFOSE IS

5.0000

4.7122

ng/mL

d9-EtFOSE IS

Auto

8.732

179211

179211

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.732

179211

1659175

13C7-PFUnDA IS

5.0000

5.6078

ng/mL

NMeFOSA

Auto

8.525

230982

518066

d3-NMeFOSA IS

5.0000

4.8390

nq/mL

dB-NMeFOSA IS

Auto

8.520

518066

518066

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.520

518066

1659175

13C7-PFUnDA IS

5.0000

5.1206

nq/mL

d7-N-MeFOSE IS

Auto

8.485

339729

339729

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.485

339729

1659175

13C7-PFUnDA IS

5.0000

5.9920

nq/mL

NEtFOSA

Auto

8.786

401269

544053

d5-NEtFOSA IS

5.0000

5.0276

ng/mL

PFTrDA

Auto

8.318

1873341

1248771

13C-PFTeDA IS

5.0000

4.9383

nq/mL

PFTeDA

Auto

8.617

1977969

1248771

13C-PFTeDA IS

5.0000

4.4239

ng/mL

13C-PFTeDA IS

Auto

8.617

1248771

1248771

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.617

1248771

1659175

13C7-PFUnDA IS

5.0000

4.7109

ng/mL

11CI-PFBOUdS

Auto

7.804

529086

476095

13C-PFOS IS

4.7100

4.8502

nq/mL

9CI-PF30NS

Auto

7.132

1144262

476095

13C-PFOS IS

4.6600

4.8685

ng/mL

L-PFDoS

Auto

8.270

167660

476095

13C-PFOS IS

4.8400

5.2853

nq/mL

NaDONA

Auto

6.393

1830095

1824186

13C-PFNA IS

4.7100

4.7530

ng/mL

PFHxDA

Auto

9.145

1479946

3699373

13C2-PFHxDA IS

5.0000

5.0983

nq/mL

PFODA

Auto

9.675

995772

3699373

13C2-PFHxDA IS

5.0000

5.2738

ng/mL

13C2-PFHxDA IS

Auto

9.145

3699373

3699373

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.145

3699373

1659175

13C7-PFUnDA IS

5.0000

4.4046

ng/mL

13C7-PFUnDA IS

Auto

7.650

1659175

1659175

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.618

2192017

476095

13C-PFOS IS

4.6100

5.0730

ng/mL

PFBSA

Auto

6.124

1272553

499335

13C-FOSA IS

5.0000

4.8904

nq/mL

PFHxSA

Auto

6.954

1076179

1824186

13C-PFNA IS

5.0000

4.7769

ng/mL

CHARGE

ND(W/B)

	

	

1659175

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 4.3960
1.73e5 Q 217.20>172.30 (-)

PFBA

Cone. 5.1623
1.73e5 Q 213.20> 169.10 (-)

A=773761
RT=4.202

O.OeO -tgf

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 5.1748

Q263.05>219.10 (-)
4.0e5 -

4.33e5 ISTD 301.80>80.00 (-)

13C-PFPeA IS

Cone. 5.0000
2.01 e5 ISTD 267.90>223.00 (-)

2.0e5 -

~A=893066
RT=4.202

O.OeO



4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

4.00 4.25 4.50

RT (min)

13C-PFBS

Cone. 4.0869

1.91e5 Q 301.80>80.00 (-)

A=507141
'T= 5.489

13C-PFPeA

Cone. 4.4344
5.05e5 Q 267.90>223.00 (-)

rA= 1253981
RT= 5.358

O.OeO

f A= 1253981
RT= 5.358

O.OeO

5.6

RT (min)

PFBS

Cone. 4.3540
R#1 298.80>99.00 68.03 (65.16)

1.91e5 Q 299.00>80.00 (-)	1.29e5 ISTD 332.10>287.10 (-)

13C HFPO DA IS

Cone. 5.0000

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

2(DQ

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:27

CCV7-230428 (continued)

13C HFPO DA

Cone. 4.7496

Q 332.10>287.10 (-)	1.27e5

A=291644
RT=6.088

O.OeO -

6.0

fA=2258637
:R1 2.36 (--1-^7=5.944

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

1673364
=6.348

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

7.5e4 ~



R

f=6.648

5.0e4 ~







2.5e4 ~
0 0<=>0 -





13C-PFOA IS

Cone. 5.0000

HFPO DA

Cone. 5.1612

R#1 329.00>285.10 74.34 (80.83)
Q 329.00>169.00 (-)	9.68e4

f A=220164
HR1 74.34 (4^=6.089

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :



6.2 6.4
RT (min)

PFHxA

Cone. 5.0472

R#1 313.00> 119.10 2.36 (2.51)
Q 313.00>269.00 (-)	9.57e5

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

\=1684204
Jt= 5.944

6.2
RT (min)

13C-PFHpA

Cone. 4.4834

7.33e5 Q 366.90>322.10 (-)

~ A= 1673364
Drr-6.348



13C2-6 2-FTS

Cone. 3.6207

8.76e4 Q 428.90>409.00 (-)

RT (min)

13C-PFOA

Cone. 4.2376

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 25.78 (27.58)

ISTD 329.00>309.15 (-)	9.32e4

A=222383

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

6.2 6.4
RT (min)

13C-PFHxA

Cone. 4.3836

7.14e5 Q 314.90>270.10 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

Vi

6.2
RT (min)

180-PFHxS IS

Cone. 4.7250

7.33e5 ISTD 402.70>84.05 (-)

A= 521104
RTT=6.355

O.OeO -

Vj

6.6

RT (min)

6.2

6.4

RT (min)

6.8 7.0
RT (min)

13C-4 2-FTS

Cone. 4.0075

R#1 329.00>81.00 25.78 (27.58)
Q 329.00>309.15 (-)	9.32e4

6.0 6.2
RT (min)

=1684204
lT= 5.944

4-2-FtS

Cone. 4.8164

R#1 327.00 >81.10 15.93 (16.09)
Q 327.00>307.05 (-)	1.07e5

Y A=254131
1.0e5 —|R1 15.93 (4-^=5.890

O.OeO -

6.0 6.2
RT (min)

PFPeS

Cone. 4.5419

R#1 349.00>99.00 84.74 (77.24)
Q 349.00>79.95 (-)	1.43e5

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 4.1482

R#1 399.00>99.00 95.24 (85.33)
Q 399.00>80.00 (-)	9.69e4

-i

A=333436

- R1 84.74 (-i

"KT= 5.985

:	J'



fA=274723
^R1 95.24 (-1-^=6.354

7.5e4 -
5.0e4z_
2.5e4z_
O.OeO -



6.2
RT (min)

6.2

RT (min)

6.2

6.4

180-PFHxS

Cone. 4.1847

2.31 e5 Q 402.70>84.05 (-)



521104
1T=6.355

O.OeO -



6.6
RT (min)

PFHpA

Cone. 4.9722

R#1 362.90 >169.00 16.66 (17.91)
Q 362.90>319.00 (-)	1.09e6

f A=2481643
1.0e6 —IR1 16.66 (- |-RpT=6.348

O.OeO

6.6
RT (min)

PFHpS

Cone. 4.3916

R#1 449.00>99.20 58.73 (66.50)
Q 449.00>80.15 (-)	1.52e5

fA=347823

: R1 58.73 (-|-|4r=6.658

O.OeO I, , , ,

6.6 6.8

RT (min)

PFOS

Cone. 4.6282

R#1 499.00>99.00 93.09 (86.07)
Q 499.00>80.00 (-)	7.00e4

6.2

6.4

6.6

RT (min)

6-2-FTS

Cone. 4.9767

R#1 427.00>80.90 30.08 (33.45)

Q 427.00>407.00 (-)	8.52e4 Q 413.00>369.00 (-)

A=208179

7.5e4^R1 30-08 ( "1^=6.648

6.6
RT (min)

PFOA

Cone. 4.9750

R#1 413.00> 169.10 27.90 (27.85)

1.10e6

A=2658928

1.0e6-|R1 27.90 (-^^=6.667

RT (min)

6.8 7.0
RT (min)

13C-PFOS IS

Cone. 4.7750

13C-PFOS

Cone. 3.8082

105 (-)



r|=6.952



K*

2.00e5 Q 502.80>80.05 (-)
2.0e5 n

6.75 7.00 7.25

RT (min)

6.8 7.0 7.2

RT (min)

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

21ffi

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:27

CCV7-230428 (continued)

PFNA	13C-PFNA IS

Cone. 5.0178	Cone. 5.0000
R#1 463.00>219.00 18.25 (24.00)

Q 463.00>418.90 (-)	9.02e5	ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 4.4235

7.46e5 Q 467.80>423.00 (-)

TA= 1824186

DT-C CiT)

VL

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 4.2668

4.57e4 Q 528.80> 509.00 (-)

TA=116847
Rli 7.301

u

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)

13C-PFUnDA

Cone. 4.7043

Q 564.80>519.95 (-)

6.0e5 i
4.0e5 i
2.0e5 i
O.OeO 4==

7.6
RT (min)

d3-N-MeFOSAA

Cone. 5.5328

2.85e5 Q 572.80>419.05 (-)

7.6 7.8 8.0
RT (min)

PFOSA

Cone. 5.0999

R#1 498.20>64.10 0.32 (0.09)
Q 498.20>78.00 (-)	2.15e5

fA= 545647
2.0e5 —|R1 0.32 (--4\hj=7.739



A= 1,848739

	

cyi

			XL

(rt^

7.650

" I



~

13C-FOSA IS

Cone. 5.0000

7.6 7.8 8.0

RT (min)

ISTD 506.00>78.05 (-)

1.5e5 -
1.0e5-j
5.0e4 :
O.OeO :

A= 1824186
RT=6.972

7.2

RT (min)

7-5e5 - R1 17.64
5.0e5 ^

2.5e5 ^

O.OeO ~n~TT

A=1933909
RT* 7.305

7.6
RT (min)

7.2

7.4

2.0e5 -

O.OeO

7.6 7.8
RT (min)

PFUnDA

Cone. 4.8862

R#1 563.00>219.00 11.69 (13.86)
Q563.00>518.90 (-)	6.88e5

4.0e5
2.0e5
O.OeO

R1 38.27 (-



"Rtf=7.483



7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

7.8 8.0
RT (min)

13C-FOSA

Cone. 4.5722

1.94e5 Q 506.00>78.05 (-)

^.SeSz_

^.0eSz_

5.0e4 i
== O.OeO 1. . 7-

7.8 8.0

RT (min)

PFNS

Cone. 4.9634

R#1 549.00 >99.00 67.99 (71.23)

7.46e5 Q 549.00>79.95 (-)

7.2
RT (min)

PFDA

Cone. 4.8762

R#1 512.90>219.00 17.64(17.51)
Q 512.90>469.00 (-)	7.82e5

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

7.6
RT (min)

NMeFOSAA

Cone. 4.7434

R#1 570.20>512.00 38.27 (37.68)
Q 570.20>419.00 (-)	2.21 e5

f A=709036

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 5.5022

2.77e5 Q 588.80>419.00 (-)

O.OeO -

7.8 8.0
RT (min)

7.6

:R1 17.1
6.0e5 i

4.0e5 i

2.0e5 i

O.OeO z^=F=d

A=2023156
(Rt4.992

7.8 8.0

RT (min)

8-2-FTS

Cone. 4.4876

R#1 527.20>487.00 6.62 (6.74)

2.32e5 Q 527.10>506.90 (-)

f A= 124505

- R1 6.62 (J-Rt 17.300

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA

Cone. 4.4859

8.46e5 Q 514.80>469.95 (-)

*A=2094195
Rll 7.305

vl

7.6
RT (min)

PFDS

Cone. 4.4293

R#1 599.00>99.00 63.45 (65.43)
Q 599.00>80.10 (-)	1.46e5

A=372073

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

6.0e5 i
4.0e5 i
2.0e5 i
O.OeO

7.6 7.8 8.0
RT (min)

NEtFOSAA

Cone. 4.8452

R#1 584.20>526.10 52.50 (58.21)
Q 584.20>418.95 (-)	2.37e5

~ A=765362

_ -R1 52.50 (4-^=7.668

O.OeO -



7.8 8.0
RT (min)

PFDoA

Cone. 4.5446

R#1 613.05> 169.00 17.13 (16.16)
Q 613.05>569.00 (-)	7.63e5

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

7.53e5

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

212

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:27

CCV7-230428 (continued)

13C-PFDoA

Cone. 4.9445

Q614.80>569.95 (-)

10-2-FtS

Cone. 5.0993

R#1 626.50>81.05 53.83 (76.13)
Q 626.50>607.05 (-)	5.53e4

d5-NEtFOSA IS

Cone. 5.0000



f A=1f

1356

	

OJ

(rt^

.004

: .



~

ISTD 531.10> 169.10 (-)
2.0e5 -

A= 544053
RT=8.777

d5-NEtFOSA

Cone. 4.8622

2.08e5 Q 531.10> 169.10 (-)
2.0e5 -

L

O.OeO -

A= 544053
RT=8.777

NMeFOSE

Cone. 4.9013

2.08e5 Q 616.10> 58.90 (-)
1.0e5-

RT (min)

RT (min)

9.0

RT (min)

8.6

NEtFOSE

Cone. 4.7122

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 5.6078

9.0
RT (min)

9.0
RT (min)

d3-NMeFOSA

Cone. 5.1206

Q 515.10> 169.00 (-)
2.0e5

d7-N-MeFOSE IS

Cone. 5.0000

2.03e5 ISTD 623.00> 59.00 (-)

d7-N-MeFOSE

Cone. 5.9920

1.37e5 Q 623.00> 59.00 (-)

O.OeO -

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 4.4239

R#1 713.00 >169.30 9.79 (11.66)
Q 713.00>668.90 (-)	7.49e5

6.0e5 -
4.0e5 -
2.0e5 -
O.OeO -

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 4.7109

11CI-PF30UdS

Cone. 4.8502

4.65e5 Q 714.80>669.80 (-)

Q 631.00>451.10 (-)
2.0e5 -

A= 529086
RT=7.804

8.6

.8 9.0
RT (min)

L-PFDoS

Cone. 5.2853

R#1 698.80>98.80 70.05 (71.85)
Q 698.80>80.10 (-)	7.00e4

6.0e4
4.0e4 :
2.0e4 :
O.OeO :

57660

R1 70.0E :S.270

8.4 8.6
RT (min)

9.4

RT (min)

9.0
RT (min)

NMeFOSA

Cone. 4.8390

R#1 512.10>219.20 79.06 (76.94)
Q 512.10> 169.20 (-)	8.85e4

A=230982

R1 79.06 (-4 rt=8.525

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)
2.0e5

O.OeO -

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 5.0276

R#1 526.50>219.20 64.32 (67.00)
Q 526.50> 169.10 (-)	1.58e5

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 4.9383

R#1 663.10> 169.10 18.90 (20.38)
Q 663.10>618.90 (-)	7.34e5



r A=if

73341

I R1 18.9C

RT=f

.318

i I

I

¥

8.6

RT (min)

9CI-PF30NS

Cone. 4.8685

2.15e5 Q 531.00>351.10 (-)

u

144262
7.132

y

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

3.51e5 ISTD 815.00>770.00 (-)

L

10.0

RT (min)

9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

212

-------
)

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:27

CCV7-230428 (continued)

13C2-PFHxDA

Cone. 4.4046

Q 815.00>770.00 (-)
1.5e6 -

1.0e6-j

5.0e5 ^

O.OeO 1. . .

13C7-PFUnDA IS

Cone. 5.0000

1.56e6 ISTD 569.80>524.90 (-)
6.0e51

PFBSA

Cone. 4.8904

PFecHS

Cone. 5.0730
R#1 461.00>99.10 37.32 (38.14)

6.11e5 Q 461.00>381.00 (-)	9.12e5 Q 298.00>78.00 (-)

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

RT (min)

PFHxSA

Cone. 4.7769

Q 397.90>78.00 (-)
4.0e5 -

'A=1076179
RT=6.954

6.4
RT (min)

7.2
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

218

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1st /S/AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/Integration
Printed 5/2/2023 11:33:31

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/29/2023 5:11:35 PM

Acquired by: System Administrator

Data File: 230428118

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 1

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.192

665132

665132

	 	

5.0000

n

' '

13C-PFBA

Auto

4.192

665132

724

13C7-PFUn[

345

nq/ml

PFBA

Auto

4.196

326

665132

1 3C-PF

0.0022

n

q/mL

13C-PFPeA IS

Auto

5.356

1032974

- 974

	 	

5.0000

nq/ml

13C-PFPeA

Auto

5.356

1032974

1122724

>FUn[

5.3983

n

q/mL

PFPeA

IV

5.357

1264

1032974

13C-PFPeA IS

0.0066

nq/ml

13C-PFBS IS

Auto

5.488

347503

347503

	 	

4.6500

n

q/mL

13C-PFBS

Auto

5.488

347503

1122724

13C7-PFUnDA IS

4.1385

nq/ml

PFBS

Auto

495

34

347503

13C-PFBS IS

0.0043

ng/mL

13C HFPO DA IS

Auto

6.088

212845

212845

	 	

5.0000

nq/ml

FPO DA

Auto

6.088

212845

1122724

13C7-PFUnDA IS

5 1225

n

q/mL

HFPO DA

Auto

6.096

152

845

13C HFPO DA IS

0.0049

nq/ml

13C-4 2-FTS IS

Auto

5.890

171381

171381

	 	

4.6700

n

q/mL

13C-4 2-FTS

Auto

390

81

1122724

, i'FUnDA I'i

4.5640

nq/ml

4-2-FtS

N D( W/B)

	

	

171381

13C-4 2-FTS IS

	

ng/mt

PFHxA

Auto

5.942

3107

219

13C-PFHxA IS

0.0086

nq/ml

13C-PFHxA IS

Auto

5.944

1359219

1359219

	 	

5.0000

ng/mL

13C-PFHxA

Auto

5.944

1359219

1122724

13C7-PFUnDA IS

5.2281

nq/ml

PFPeS

Auto

5.979

82

395412

180-PFHxS IS

0.0015

n

ci/mL

PFHxS

Auto

6.356

668

395412

180-PFHxS IS

0.0133

n

q/mL

13C-PFHpA IS

Auto

6.348

1316935

1316935

	 	

5.0000

n

g/mL

13C-PFHpA

Auto

6.348

1316935

1122724

13C7-PFUnDA IS

5.2144

n

q/ml

kV PI H\s IS

Auto

6.355

395412

412

	 	

4.7250

n

g/mL

180-PFHxS

Auto

6.355

395412

724

13C7-PFUnDA IS

G5

n

q/ml

PFHpA

Auto

6.351

1081

1316935

:HpA IS

0.0028

n

iL

5 2-FTS IS

Auto

6.649

189470

470

	 	

4.7500

n

q/ml

2- V

Auto

6.649

189470

1122724

13C7-PFUnDA IS

4.8169

n

iL



N



	

395412

180-PFHxS IS

	

n

q/ml

6-2-FTS

Auto

6.511

129

189470

13C2-6 2-FTS IS

0.0034

nq/ml

PFOA

Auto

6.668

1481

1654378

13C-PF

0.0033

nq/ml

13C-PFOA IS

Auto

6.667

1654378

1654378

	 	

5.0000

ng/mL

13C-PFOA

Auto

6.667

1654378

724

13C7-PFUnDA IS

594

nq/ml

PFOS

Auto

6.952

471

:m I

13C-PFOS IS

0.0115

ng/mL

FOS IS

Auto

6.953

392201

392201

	 	

4.7750

nq/ml

13C-PFOS

Auto

6.953

392201

1122724

'FUnDA IS

4.6361

iL

PFNA

Auto

6.969

759

1508898

13C-PFNA IS

0.0021

nq/ml

13C-PFNA IS

Auto

6.973

1508898

1508898

	 	

5.0000

iL

13C-PFNA

Auto

6.973

1508898

1122724

13C7-PFUnDA IS

)73

nq/ml

PFNS

Auto

7.473

63

392201

13C-PFOS IS

0.0007

ng/mL

8-2-FTS

NDCW/B)

	

	

77229

13C-8 2-FTS IS

	

nq/ml

13C-8 2-FTS IS

Auto

7.303

77229

77229

	 	

4.7900

ng/mL

13C-8 2-FTS

Auto

7.303

77229

1122724

13C7-PFUnDA IS

4.1676

nq/ml

PFDA

Auto

7.161

405

1532647

13C-PFDA IS

0.0014

ng/mL

13C-PFDA IS

Auto

7.308

1532647

1532647

	 	

5.0000

nq/ml

13C-PFDA

Auto

7.308

47

1122724

13C7-PFUnDA IS

4.8516

nq/mL

d3-N-MeFOSAA IS

Auto

7.482

, 44

044

	 	

5.0000

nq/ml

cB-N-MeFOSAA

Auto

7.482

456044

1122724

13C7-PFUnDA IS

4.9511

ng/mL

NMeFOSAA

Auto

7.495

697

456044

: tSAA IS

. ¦" )77

nq/ml

PFDS

Auto

7.984

104

392201

13C-PFOS IS

0.0015

ng/mL

13C-PFUnDA IS

Auto

554

1446545

1446545

	 	

5.0000

nq/ml

13
-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:33:31

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone.

Cone. Unit

10-2-FtS

ND(W/B)

	

—

77229

13C-8 2-FTS IS

— —

nq/mL

d5-NEtFOSA IS

Auto

8.778

346342

346342

—

5.0000

nq/mL

d5-NEtFOSA

Auto

8.778

346342

1122724

13C7-PFUnDA IS

4.5742

nq/mL

NMeFOSE

ND(W/B)

	

	

201219

d7-N-MeFOSE IS

	 	

nq/mL

NEtFOSE

Auto

8.928

504

128386

d9-EtFOSE IS

0.0040

nq/mL

d9-EtFOSE IS

Auto

8.734

128386

128386

—

5.0000

nq/mL

d9-EtFOSE

Auto

8.734

128386

1122724

13C7-PFUnDA IS

5.9369

nq/mL

NMeFOSA

ND(W/B)

—

—

327956

d3-NMeFOSA IS

— —

nq/mL

dB-NMeFOSA IS

Auto

8.521

327956

327956

—

5.0000

nq/mL

dB-NMeFOSA

Auto

8.521

327956

1122724

13C7-PFUnDA IS

4.7904

nq/mL

d7-N-MeFOSE IS

Auto

8.486

201219

201219

—

5.0000

nq/mL

d7-N-MeFOSE

Auto

8.486

201219

1122724

13C7-PFUnDA IS

5.2448

nq/mL

NEtFOSA

Auto

8.842

257

346342

d5-NEtFOSA IS

0.0051

nq/mL

PFTrDA

Auto

8.322

808

535848

13C-PFTeDA IS

0.0050

nq/mL

PFTeDA

Auto

8.628

1351

535848

13C-PFTeDA IS

0.0070

nq/mL

13C-PFTeDA IS

Auto

8.621

535848

535848

—

5.0000

nq/mL

1BC-PFTeDA

Auto

8.621

535848

1122724

13C7-PFUnDA IS

2.9873

nq/mL

11CI-PF30UdS

Auto

7.981

48

392201

13C-PFOS IS

0.0005

nq/mL

9CI-PFBONS

ND(W/B)

—

—

392201

13C-PFOS IS

— —

nq/mL

L-PFDoS

ND(W/B)

—

—

392201

13C-PFOS IS

— —

nq/mL

NaDONA

ND(W/B)

—

—

1508898

13C-PFNA IS

— —

nq/mL

PFHxDA

Auto

9.146

2335

2494641

13C2-PFHxDA IS

-0.0302

nq/mL

PFODA

Auto

9.684

204

2494641

13C2-PFHxDA IS

0.0016

nq/mL

13C2-PFHxDA IS

Auto

9.146

2494641

2494641

—

5.0000

nq/mL

1BC2-PFHxDA

Auto

9.146

2494641

1122724

13C7-PFUnDA IS

4.3894

nq/mL

13C7-PFUnDA IS

Auto

7.654

1122724

1122724

—

5.0000

nq/mL

PFecHS

Auto

6.766

458

392201

13C-PFOS IS

0.0013

nq/mL

PFBSA

Auto

6.124

142

339038

13C-FOSA IS

0.0008

nq/mL

PFHxSA

ND(W/B)

—

—

1508898

13C-PFNA IS

— —

nq/mL

CHARGE

ND(W/B)

	

	

1122724

13C7-PFUnDA IS

— 	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 5.5845
1.56e5 Q 217.20>172.30 (-)

PFBA

Cone. 0.0022
1.56e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
5.28e2 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 5.3983
4.29e5 Q 267.90>223.00 (-)

4.0e5

f A=1032974
RT= 5.356

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 0.0066

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

O.OeO -

4.00 4.25 4.50

RT (min)

13C-PFBS

Cone. 4.1385

O.OeO

4.0e5 -

O.OeO -

J

A=1032974
fl"= 5.356

5.2

5.4

8.38e2 I STD 301.80 > 80.00 (-)

1.36e5 Q 301.80>80.00 (-)

5.6

RT (min)

PFBS

Cone. 0.0043
R#1 298.80>99.00 70.15 (65.16)

1.36e5 Q 299.00>80.00 (-)	9.50e1 ISTD 332.10>287.10 (-)

5.6

RT (min)

13C HFPO DA IS

Cone. 5.0000

fA=347503
RT= 5.488

fA=347503
RT= 5.488

~ A=234

:R1 70.15 (-5-1

A=212845
T=6.C

5.6 5.8
RT (min)

5.6 5.8
RT (min)

5.6 5.
RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

216

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1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:33:31

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 5.1225

Q 332.10>287.10 (-)

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

k=212845
RT=6.088

HFPO DA

Cone. 0.0049

R#1 329.00>285.10 0.00 (80.83)
Q 329.00>169.00 (-)	1.

IR1 0.0

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 26.46 (27.58)

ISTD 329.00>309.15 (-)	7.41e4

~ A=171381

;R1 26.46 (—F&T=5.8

13C-4 2-FTS

Cone. 4.5640

R#1 329.00>81.00 26.46 (27.58)
Q 329.00>309.15 (-)	7.41 e4

If A= 171381

;R1 26.46 (-;--R)r=5.8

4-2-FtS

Cone. —

R#1 327.00>81.10 —- (16.09)
Q 327.00>307.05 (-)	I.IOel

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 0.0086

R#1 313.00> 119.10 0.32 (2.51)
Q 313.00>269.00 (-)	1.94e3

TA=3107

:R1 0.32 (~--fer=5.942

A

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

13C-PFHxA

Cone. 5.2281

5.91 e5 Q 314.90>270.10 (-)

*1=1359219
fJj= 5.944

6.0 6.2
RT (min)

=1359219
lT= 5.944

Vj

6.2
RT (min)

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

13C-PFHpA

Cone. 5.2144

5.86e5 Q 366.90>322.10 (-)

180-PFHxS IS

Cone. 4.7250

5.86e5 ISTD 402.70>84.05 (-)

^=1316935
=6.348

^=1316935
=6.348

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

A=395412
RjT=6.355

6.6

RT (min)

6.6

RT (min)

6.2

6.4

13C2-6 2-FTS IS

Cone. 4.7500

13C2-6 2-FTS

Cone. 4.8169

Q 428.90>409.00 (-)	8.09e4 Q 449.00>80.15 (-)

=6.649

3.10e1

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

13C-PFOA

Cone. 5.2694

6.96e5 Q 416.80>372.05 (-)



1654378
6.667



6.8 7.0
RT (min)

6.0 6.2
RT (min)
PFPeS

Cone. 0.0015

R#1 349.00>99.00 0.00 (77.24)
Q 349.00>79.95 (-)	7.50e1

= R1 0.0flX«-)

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.0133

R#1 399.00>99.00 123.49 (85.33)
Q 399.00>80.00 (-)	2.84e2

A=668

: R1 123^6:356

6.2
RT (min)

180-PFHxS

Cone. 4.6925

1.80e5 Q 402.70>84.05 (-)

^.SeSz_

"{.OeSz
S.0e4z_

O.OeO 1 . . t

6.6
RT (min)

PFHpA

Cone. 0.0028

R#1 362.90 >169.00 9.00 (17.91)
Q 362.90>319.00 (-)	6.14e2

395412
tT=6.355

6.0e2 -

V A=1081
R1 9.00 (-4-^=6.351

L

6.6
RT (min)

PFHpS

Cone. —

R#1 449.00>99.20 — - (66.50)

6.2

6.4

6.6 6.8

RT (min)

PFOS

Cone. 0.0115

R#1 499.00>99.00 32.48 (86.07)
Q 499.00>80.00 (-)	2.13e2

f A=471
2.0e2 - R1 32.48 (~rfcT=6.952

6.6
RT (min)

6-2-FTS

Cone. 0.0034

R#1 427.00>80.90 0.00 (33.45)
Q 427.00>407.00 (-)	8.70e1

~ A=129 ;

7.5e1 -R1 ? ^"6:5)ljl

5.0e1:
2.5e1:
O.OeO :

PFOA

Cone. 0.0033

R#1 413.00> 169.10 29.92 (27.85)
Q 413.00>369.00 (-)	9.75e2

¥A=1481

-R1 29.92 (M=6.6

RT (min)

13C-PFOS IS

Cone. 4.7750

105 (-)

1.67e5 Q 502.80>80.05 (-)

A=392201
RT=6.953



6.75 7.00 7.25

RT (min)

7.2

RT (min)

C:\LabSolutions\Data\LCMS1~230428\LCMS1~230428A-537MOD_NewCal.iproc

210

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1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:33:31

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0021

R#1 463.00>219.00 27.25 (24.00)
Q 463.00>418.90 (-)	4.62e2

TA=759

40e2-R1 27 25 |m|=6.969

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)
6.0e5 -

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 4.1676

2.95e4 Q 528.80> 509.00 (-)

7.6
RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 4.9511

1.72e5 Q 572.80>419.05 (-)

7.6 7.

RT (min)

13C-PFUnDA

Cone. 5.2031

Q 564.80>519.95 (-)

A= 1446545
RT=7.654

O.OeO -



3.0e2 -
2.0e2 -
1.0e2-
O.OeO -

A= 1590

R1 °-00F(T=7)8B9

7.6

7.8 8.0
RT (min)

PFOSA

Cone. 0.0021

R#1 498.20>64.10 0.00 (0.09)
Q 498.20>78.00 (-)	8.90e1

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

7.5e1
5.0e1 :
2.5e1 :
O.OeO :

t A=152

: R1 0.00 (—-frr=7.731

7.8 8.0

RT (min)

13C-PFNA

Cone. 5.4073

Q 467.80>423.00 (-)
6.0e5 -

~ A= 1508898
RT=6.973

4.0e5 :
2.0e5 :
O.OeO :

PFNS

Cone. 0.0007

R#1 549.00 >99.00 0.00 (71.23)
6.28e5 Q 549.00>79.95 (-)

A=63.

4.0 e1 - R1 0.00 (rt_=)7!473



7.2

RT (min)

6.8

7.0

Q 512.90>469.00 (-)
A=405

O.OeO

7.6
RT (min)

7.2

7.4

7.6 7.8
RT (min)

PFUnDA

Cone. 0.0056

R#1 563.00>219.00 0.00 (13.86)
Q563.00>518.90 (-)	3.53e2

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

7.8 8.0
RT (min)

O.OeO

7.6 7.8 8.0
RT (min)

13C-FOSA

Cone. 4.5877

1.33e5 Q 506.00>78.05 (-)

7.8 8.0

RT (min)

8-2-FTS

Cone. —

R#1 527.20>487.00 — - (6.74)
4.30e1 Q 527.10>506.90 (-)	i

7.2
RT (min)

PFDA

Cone. 0.0014

R#1 512.90>219.00 0.00 (17.51)

7.4 7.6
RT (min)

13C-PFDA IS

Cone. 5.0000

1.95e2 ISTD 514.80>469.95 (-)
4.0e5

2.0e5 -

532647
7.308

O.OeO -

u

7.6
RT (min)

NMeFOSAA

Cone. 0.0077

R#1 570.20>512.00 0.00 (37.68)
Q 570.20>419.00 (-)	4.41 e2

4.0e2 —|R1 0.00^69^

RT=7.49|5

2.0e2 -

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 5.5082

1.98e5 Q 588.80>419.00 (-)

O.OeO -

7.6
RT (min)

13C-PFDA

Cone. 4.8516

Q 514.80>469.95 (-)
6.0e51

4.0e5 :
2.0e5 :
O.OeO -

A= 1532647
RT^ 7.308

u

7.2 7.4 7.6

RT (min)

PFDS

Cone. 0.0015

R#1 599.00>99.00 0.00 (65.43)
Q 599.00>80.10 (-)	6.90e1

, A=104
6.0e1 - R1 000 I RT=7.984

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

O.OeO -

7.6

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.0042

R#1 584.20>526.10 0.00 (58.21)
Q 584.20>418.95 (-)	1.37e2

A=445	A=74

:(fcW.Sti9-:f) I RT=8.061
1.0e2-

O.OeO -

7.6

7.8 8.0
RT (min)

PFDoA

Cone. 0.0042
R#1 613.05> 169.00 7.02 (16.16)

1.33e5 Q 613.05>569.00 (-)	7.45e2 ISTD 614.80>569.95 (-)

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

5.14e5

7.6 7.8 8.0

RT (min)

6.0e2 -
4.0e2 -
2.0e2 -
O.OeO -

f A=1272
R1 7.02 (rRT)= 7.994

RT (min)

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

218

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1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:33:31

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 4.9610

Q614.80>569.95 (-)

10-2-FtS

Cone. —

R#1 626.50>81.05 —- (76.13)
5.14e5 Q 626.50>607.05 (-)	O.OOeO

d5-NEtFOSA IS

Cone. 5.0000

d5-NEtFOSA

Cone. 4.5742

ISTD 531.10> 169.10 (-)	1.36e5 Q 531.10> 169.10 (-)

NMeFOSE

Cone. —

1.36e5 Q 616.10> 58.90 (-)

RT (min)

RT (min)

NEtFOSE

Cone. 0.0040

Q 629.50>59.10 (-)
1.0e3 H

d9-EtFOSE IS

Cone. 5.0000

O.OeO

3.6 8.8 9.0

RT (min)

d9-EtFOSE

Cone. 5.9369

1.03e3 ISTD 638.90>59.10 (-)

A =504

RT=8.928 I 2.0e4

O.OeO -

8.6 8.8 9.0

RT (min)

d3-NMeFOSA

Cone. 4.7904

9.0
RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

Q 515.10> 169.00 (-)

1,29e5 ISTD 623.00> 59.00 (-)

d7-N-MeFOSE

Cone. 5.2448

Q 623.00>59.00 (-)

'A=201219
RT=8.486

O.OeO -

8.4 8.6

RT (min)

PFTeDA

Cone. 0.0070

R#1 713.00 >169.30 0.34 (11.66)
Q 713.00>668.90 (-)	5.72e2

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)
2.0e5

13C-PFTeDA

Cone. 2.9873

O.OeO

8.6 8.8 9.0
RT (min)

L-PFDoS

Cone. —

R#1 698.80>98.80 — - (71.85)
Q 698.80>80.10 (-)	O.OOeO

5.0e0 n	i

Q 714.80>669.80 (-)
2.0e5

8.6 8.8 9.0
RT (min)

NaDONA

Cone. —

Q 377.10>251.20 (-)
2.0e1

4.82e4 Q 638.90> 59.10 (-)	4.82e4

O.OeO

8.6 8.8 9.0

RT (min)

NMeFOSA

Cone. —

R#1 512.10>219.20 —- (76.94)
Q 512.10> 169.20 (-)	O.OOeO

5.0e0 n	i

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

-5.0e0 H , , , , , ,l , , , , , , , ,
8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0051

R#1 526.50>219.20 0.00 (67.00)
Q 526.50>169.10 (-)	7.80e1

" R1 0.00 (—-)

O.OeO -

8.4 8.6

RT (min)

PFTrDA

Cone. 0.0050

R#1 663.10> 169.10 11.21 (20.38)
Q 663.10>618.90 (-)	3.41 e2

O.OeO

8.6 8.8 9.0

RT (min)

11CI-PF30UdS

Cone. 0.0005

9CI-PF30NS

Cone. —

2.00e5 Q 631.00>451.10 (-)

4.80e1 Q 531.00>351.10 (-)

8.6 8.8 9.0
RT (min)

PFHxDA

Cone. -0.0302

Q 812.90>769.00 (-)	1.14e3

1.0e3

Q 912.80>869.00 (-)

13C2-PFHxDA IS

Cone. 5.0000

ISTD 815.00>770.00 (-)
1.0e6-

B.2 8.4 8.6

RT (min)

6.2 6.4 6.6

RT (min)

9.0 9.2 9.4

RT (min)

9.6 9.8 10.0

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

218

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1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:33:31

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 4.3894

Q 815.00>770.00 (-)
1.0e6 -

~ A=2494641
RT=9146

13C7-PFUnDA IS

Cone. 5.0000

1,06e6 ISTD 569.80> 524.90 (-)
4.0e5 -

O.OeO -

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

PFecHS	PFBSA

Cone. 0.0013	Cone. 0.0008
R#1 461.00>99.10 0.00 (38.14)

4.14e5 Q 461.00>381.00 (-)	2.48e2 Q 298.00>78.00 (-)

A=458

- R1 °-00ftT=6).766

6.4 6.6 6.8

RT (min)

PFHxSA

Cone. —

6.30e1 Q 397.90>78.00 (-)
3.0e11

7.0 7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

220

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:31

CCV8-230428

Sample ID: CCV8-230428

Date Acquired: 4/29/2023 5:39:04 PM

Acquired by: System Administrator

Data File: 230428120

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.204

852127

852127

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.204

852127

1181324

13C7-PFUnDA IS

5.0000

6.7996

ng/mL

PFBA

Auto

4.205

877319

852127

13C-PFBA IS

5.0000

4.6049

nq/mL

13C-PFPeA IS

Auto

5.361

1209409

1209409

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.361

1209409

1181324

13C7-PFUnDA IS

5.0000

6.0068

nq/mL

PFPeA

Auto

5.361

1144991

1209409

13C-PFPeA IS

5.0000

5.1419

ng/mL

13C-PFBS IS

Auto

5.491

441129

441129

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.491

441129

1181324

13C7-PFUnDA IS

4.6500

4.9929

ng/mL

PFBS

Auto

5.491

324757

441129

13C-PFBS IS

4.4200

4.7423

nq/mL

13C HFPO DA IS

Auto

6.090

256072

256072

	

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.090

256072

1181324

13C7-PFUnDA IS

5.0000

5.8571

nq/mL

HFPO DA

Auto

6.091

213041

256072

13C HFPO DA IS

5.0000

5.6879

nq/mL

13C-4 2-FTS IS

Auto

5.892

217067

217067

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.892

217067

1181324

13C7-PFUnDA IS

4.6700

5.4940

ng/mL

4-2-FtS

Auto

5.892

237947

217067

13C-4 2-FTS IS

4.6700

4.6201

nq/mL

PFHxA

Auto

5.946

2149710

1627757

13C-PFHxA IS

5.0000

4.9703

ng/mL

13C-PFHxA IS

Auto

5.946

1627757

757

	

5.0000

5.0000

i

13C-PFHxA

Auto

5.946

1627757

1181324

13C7-PFUnDA IS

5.0000

5.9504

ng/mL

PFPeS

Auto

5.987

327709

473029

180-PFHxS IS

4.6900

4.9175

nq/mL

PFHxS

Auto

6.357

263094

473029

180-PFHxS IS

4.5500

4.3763

ng/mL

13C-PFHpA IS

Auto

6.351

1560339

1560339

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.351

1560339

1181324

13C7-PFUnDA IS

5.0000

5.8717

ng/mL

180-PFHxS IS

Auto

6.358

473029

473029

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.358

473029

1181324

13C7-PFUnDAJS

4.7250

5.3351

ng/mL

PFHpA

Auto

6.351

2396684

1560339

13C-PFHpA IS

5.0000

5.1498

ng/mL

13C2-6 2-FTS IS

Auto

6.650

199516

199516

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.650

199516

1181324

13C7-PFUnDA IS

4.7500

4.8207

ng/mL

PFHpS

Auto

6.661

329819

473029

180-PFHxS IS

4.7600

4.5875

ng/mL

6-2-FTS

Auto

6.650

199014

199516

13C2-6 2-FTS IS

4.7400

5.0187

nq/mL

PFOA

Auto

6.668

2536588

1941485

13C-PFOA IS

5.0000

4.8064

ng/mL

13C-PFOA IS

Auto

6.668

1941485

1941485

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.668

1941485

1181324

13C7-PFUnDA IS

5.0000

5.8771

ng/mL

PFOS

Auto

6.955

222521

474195

13C-PFOS IS

4.6400

4.5052

nq/mL

13C-PFOS IS

Auto

6.955

474195

474195

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

6.955

474195

1181324

13C7-PFUnDA IS

4.7750

5.3273

nq/mL

PFNA

Auto

6.975

1723812

1743471

13C-PFNA IS

5.0000

4.1411

ng/mL

13C-PFNA IS

Auto

6.975

1743471

1743471

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.975

1743471

1181324

13C7-PFUnDA IS

5.0000

5.9380

ng/mL

PFNS

Auto

7.279

544045

474195

13C-PFOS IS

4.8000

4.7924

nq/mL

8-2-FTS

Auto

7.304

90909

95979

13C-8 2-FTS IS

4.7900

3.9719

ng/mL

13C-8 2-FTS IS

Auto

7.304

95979

95979

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.304

95979

1181324

13C7-PFUnDA IS

4.7900

4.9226

ng/mL

PFDA

Auto

7.308

1798346

1857793

13C-PFDA IS

5.0000

5.1114

nq/mL

13C-PFDA IS

Auto

7.308

1857793

1857793

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.308

1857793

1181324

13C7-PFUnDA IS

5.0000

5.5892

nq/mL

d3-N-MeFOSAA IS

Auto

7.484

666017

666017

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.484

666017

1181324

13C7-PFUnDA IS

5.0000

6.8721

nq/mL

NMeFOSAA

Auto

7.488

623269

666017

d3-N-MeFOSAA IS

5.0000

4.7150

nq/mL

PFDS

Auto

7.618

365478

474195

13C-PFOS IS

4.8200

4.3682

nq/mL

13C-PFUnDA IS

Auto

7.656

1743466

1743466

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.656

1743466

1181324

13C7-PFUnDA IS

5.0000

5.9600

nq/mL

PFUnDA

Auto

7.656

1351604

1743466

13C-PFUnDA IS

5.0000

3.9602

nq/mL

d5-N-EtFOSAA IS

Auto

7.666

750282

750282

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.666

750282

1181324

13C7-PFUnDA IS

5.0000

7.2609

nq/mL

NEtFOSAA

M

7.673

614666

750282

dS-N-EtFOSAA IS

5.0000

4.1414

nq/mL

PFOSA

Auto

7.742

477878

460920

13C-FOSA IS

5.0000

4.8387

nq/mL

13C-FOSA IS

Auto

7.743

460920

460920

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.743

460920

1181324

13C7-PFUnDA IS

5.0000

5.9276

nq/mL

PFDoA

Auto

7.998

1818058

1693291

13C-PFDoA IS

5.0000

4.8057

nq/mL

13C-PFDoA IS

Auto

7.997

1693291

1693291

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

22®

-------


Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:31

CCV8-230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

7.997

1693291

1181324

13C7-PFUnDA IS

5.0000

5.9014

nq/mL

10-2-FtS

Auto

8.008

65387

95979

13C-8 2-FTS IS

4.8200

2.6819

ng/mL

d5-NEtFOSA IS

Auto

8.777

522883

522883

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.777

522883

1181324

13C7-PFUnDA IS

5.0000

6.5633

ng/mL

NMeFOSE

Auto

8.502

259163

286561

d7-N-MeFOSE IS

5.0000

5.5387

nq/mL

NEtFOSE

Auto

8.752

811334

183625

d9-EtFOSE IS

5.0000

4.4539

ng/mL

d9-EtFOSE IS

Auto

8.734

183625

183625

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.734

183625

1181324

13C7-PFUnDA IS

5.0000

8.0701

ng/mL

NMeFOSA

Auto

8.527

206519

488563

d3-NMeFOSA IS

5.0000

4.5878

nq/mL

dB-NMeFOSA IS

Auto

8.522

488563

488563

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.522

488563

1181324

13C7-PFUnDA IS

5.0000

6.7823

nq/mL

d7-N-MeFOSE IS

Auto

8.487

286561

286561

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.487

286561

1181324

13C7-PFUnDA IS

5.0000

7.0987

nq/mL

NEtFOSA

Auto

8.787

375410

522883

d5-NEtFOSA IS

5.0000

4.8940

ng/mL

PFTrDA

Auto

8.324

1277122

516038

13C-PFTeDA IS

5.0000

8.1469

nq/mL

PFTeDA

Auto

8.623

1428721

516038

13C-PFTeDA IS

5.0000

7.7327

ng/mL

13C-PFTeDA IS

Auto

8.623

516038

516038

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.623

516038

1181324

13C7-PFUnDA IS

5.0000

2.7342

ng/mL

11CI-PFBOUdS

Auto

7.809

565771

474195

13C-PFOS IS

4.7100

5.2072

nq/mL

9CI-PF30NS

Auto

7.135

986277

474195

13C-PFOS IS

4.6600

4.2131

ng/mL

L-PFDoS

Auto

8.274

159752

474195

13C-PFOS IS

4.8400

5.0562

nq/mL

NaDONA

Auto

6.396

1964916

1743471

13C-PFNA IS

4.7100

5.3394

ng/mL

PFHxDA

Auto

9.150

400457

3270818

13C2-PFHxDA IS

5.0000

1.5310

nq/mL

PFODA

Auto

9.687

400543

3270818

13C2-PFHxDA IS

5.0000

2.3993

ng/mL

1BC2-PFHxDA IS

Auto

9.150

3270818

3270818

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.150

3270818

1181324

13C7-PFUnDA IS

5.0000

5.4696

ng/mL

13C7-PFUnDA IS

Auto

7.655

1181324

1181324

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.620

1981809

474195

13C-PFOS IS

4.6100

4.6049

ng/mL

PFBSA

Auto

6.128

1214882

460920

13C-FOSA IS

5.0000

5.0579

nq/mL

PFHxSA

Auto

6.956

1041453

1743471

13C-PFNA IS

5.0000

4.8368

ng/mL

CHARGE

ND(W/B)

	

	

1181324

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 6.7996
Q 217.20> 172.30 (-)

PFBA

Cone. 4.6049
Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
1,89e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 6.0068
4.77e5 Q 267.90>223.00 (-)

~ A=877319
RT=4.205

O.OeO -bgf

O.OeO -tgp

fA= 1209409
(RT= 5.361

rA= 1209409
RT= 5.361

O.OeO -

O.OeO -

5.2

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 5.1419	Cone. 4.6500	Cone. 4.9929 Cone 4.7423

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q 263.05 > 219.10 (-)	3.98e5 I STD 301.80 > 80.00 (-)

1144991

TA=11
RT= 5.361

1

1.5e5 -
1.0e5-j
5.0e4 ^
O.OeO :

A=441129
fl"= 5.491

1.58e5 Q 301.80>80.00 (-)
1.5e5 -
1.0e5-j
5.0e4 ^
~r . . O.OeO 4=

R#1 298.80>99.00 69.01 (65.16)

1.58e5 Q 299.00>80.00 (-)	1.16e5 ISTD 332.10>287.10 (-)	1.09e5

A=441129
fl"= 5.491

fA=324757
jR1 69.01 (-A-|k=5.491

TA=2
il"=-

256072
!T=6.090

5.6

RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

222

-------


Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:31

CCV8-230428 (continued)

13C HFPO DA

Cone. 5.8571

Q 332.10>287.10 (-)

T

1.0e5-

HFPO DA

Cone. 5.6879

R#1 329.00>285.10 73.59 (80.83)
Q 329.00>169.00 (-)	9.11e4

A=256072
'T=6.090

O.OeO -

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

fA=213041

HR1 73.59 (- -^=6.091

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 4.9703

R#1 313.00> 119.10 2.30 (2.51)
Q 313.00>269.00 (-)	8.79e5

13C-PFHxA IS

Cone. 5.0000

A=2149710

7.5e5
5.0e5 :
2.5e5 :
O.OeO :

- R1 2.30 (--

ISTD 314.90>270.10 (-)

It1

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

1627757
[T= 5.946

6.2
RT (min)

13C-PFHpA_IS

Cone. 5.0000

13C-PFHpA

Cone. 5.8717

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

i T^=1

7.5e4 -	pfo=.

5.0e4 ^

2.5e4 ^

O.OeO 1 i i i j

199516

rI|"=6.650

13C2-6 2-FTS

Cone. 4.8207

Q 428.90>409.00 (-)
7.5e4^

5.0e4 ^

2.5e41

A=199516
RT=6.650

O.OeO -

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
7.5e5 ^

5.0e5 ^

2.5e5 ^

O.OeO 4==

A=1941485
RTF=6

tjr=6.6i

L

13C-PFOA

Cone. 5.8771

Q 416.80>372.05 (-)
7.5e5 ^

5.0e5 ^

2.5e5 ^

O.OeO 1 , , ,

A=1941485
RTF=6

:jr=6.6i

L

6.6

6.8 7.0
RT (min)

6.6

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 27.77 (27.58)

ISTD 329.00>309.15 (-)	8.49e4

~ A=217067

7.5e4-|R1 2777 W=5.892

5.0e4 :
2.5e4 :
O.OeO :

6.2 6.4
RT (min)

13C-PFHxA

Cone. 5.9504

Q 314.90>270.10 (-)
6.0e5 ^

4.0e5 ^

2.0e51

O.OeO -

J

6.2
RT (min)

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)
2.0e5 H

O.OeO -

A=473029
T=6.358

L

6.6

RT (min)

6.2

6.4

L

A

6.8 7.0
RT (min)

13C-4 2-FTS

Cone. 5.4940

R#1 329.00>81.00 27.77 (27.58)
Q 329.00>309.15 (-)	8.49e4

r A=217067
7.5e4~|R1 2777 rm= 5-892

5.0e4 -

2.5e4 ^

O.OeO -

6.0 6.2
RT (min)

A=1627757
T= 5.946

- R1 83.80 (-



=327709

O.OeO -

6.2
RT (min)

O.OeO -



6.6
RT (min)

PFHpS

Cone. 4.5875

R#1 449.00>99.20 66.42 (66.50)
Q 449.00>80.15 (-)	1.39e5

f A=329819

IR1 66-42 ("|"WT=6.661

6.2

6.4

O.OeO , ,

6.6 6.8

RT (min)

PFOS

Cone. 4.5052

R#1 499.00>99.00 89.91 (86.07)
Q 499.00>80.00 (-)	6.85e4

TA=222521

6.0e4:R1 89"91 ("S4t=6.955

4.0e4 :
2.0e4 :
O.OeO :

Q 427.00>407.00 (-)

A=199014
7.5e4^R1 29-31 (-|-pJT=6-650

5.0e4 -
2.5e4 ^
O.OeO -

4-2-FtS

Cone. 4.6201

R#1 327.00 >81.10 15.39 (16.09)
Q 327.00>307.05 (-)	9.61e4

:R1 15.39 (-

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 4.9175

R#1 349.00>99.00 83.80 (77.24)
Q 349.00>79.95 (-)	1.32e5

7.5e4 -
5.0e4z_
2.5e4z_
O.OeO -

A=237947
5.892

^r=

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 4.3763

R#1 399.00>99.00 94.21 (85.33)
Q 399.00>80.00 (-)	9.26e4

7.5e4 -
5.0e4z_
2.5e4z_
O.OeO -

: R1 94.21 (-



A=263094

5.8 6.0 6.2

RT (min)

180-PFHxS

Cone. 5.3351

6.2

6.4

Q 402.70>84.05 (-)	2.06e5

,no, ,	T A=473029

ZOe5i	RT=6.358

6.6
RT (min)

PFHpA

Cone. 5.1498

R#1 362.90 >169.00 16.61 (17.91)
Q 362.90>319.00 (-)	1.03e6

1.0e6-

A=2396684
R1 16.61 (-|-ppr=6.351

O.OeO -

L

6.6
RT (min)

6-2-FTS

Cone. 5.0187

R#1 427.00>80.90 29.31 (33.45)

6.2

6.4

6.6
RT (min)

PFOA

Cone. 4.8064

R#1 413.00> 169.10 29.37 (27.85)

8.33e4 Q 413.00>369.00 (-)

1.05e6

f A=2536588

1.0e6j^ 29.37 ( -rV=6.6

13C-PFOS IS

Cone. 4.7750

105 (-)

RT (min)

1.94e5 Q 502.80>80.05 (-)

6.75 7.00 7.25

RT (min)



A=474195
RT=6.955

6.8 7.0 7.2

RT (min)

vL

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

222

-------
A

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:31

CCV8-230428 (continued)

PFNA

Cone. 4.1411

R#1 463.00>219.00 23.11 (24.00)
Q 463.00>418.90 (-)	6.99e5

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 5.9380

6.99e5 Q 467.80>423.00 (-)

A= 1743471
RT=6.975



7.2

RT (min)

PFNS

Cone. 4.7924

R#1 549.00 >99.00 71.06 (71.23)
Q 549.00>79.95 (-)	2.17e5

~ A= 544045

" R1 71 06 ft" RTt 7.279

8-2-FTS

Cone. 3.9719

R#1 527.20>487.00 8.31 (6.74)
Q 527.10>506.90 (-)	3.38e4

VL

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 4.9226

3.71e4 Q 528.80> 509.00 (-)

7.2
RT (min)

PFDA

Cone. 5.1114

R#1 512.90>219.00 18.17 (17.51)
Q 512.90>469.00 (-)	7.16e5

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 5.5892

ISTD 514.80>469.95 (-)

7.45e5 Q 514.80>469.95 (-)

7.6
RT (min)

d3-N-MeFOSAAJS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 6.8721

2.43e5 Q 572.80>419.05 (-)

7.6
RT (min)

NMeFOSAA

Cone. 4.7150

R#1 570.20>512.00 36.27 (37.68)
Q 570.20>419.00 (-)	2.02e5

7.6
RT (min)

PFDS

Cone. 4.3682

R#1 599.00>99.00 59.60 (65.43)
Q 599.00>80.10 (-)	1.42e5

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

A=1857793
Rli 7.308

Mr

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

O.OeO -

2.0e5 -

A=623269
R1 36.27 (-1-^=7.488

j\J

7.6 7.8
RT (min)

7.4

13C-PFUnDA

Cone. 5.9600

7.6 7.8
RT (min)

PFUnDA

Cone. 3.9602

R#1 563.00>219.00 15.29 (13.86)
Q563.00>518.90 (-)	5.00e5

7.25 7.50 7.75

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

d5-N-EtFOSAA

Cone. 7.2609

2.74e5 Q 588.80>419.00 (-)



rA=i

351604

_R1 15.29

|-RT^7.656

I



-~

O.OeO -

7.8 8.0
RT (min)

NEtFOSAA

Cone. 4.1414

R#1 584.20>526.10 61.53 (58.21)
Q 584.20>418.95 (-)	1.87e5

1.5e5:
1.0e5:
5.0e4i
O.OeO :



A=

614666

- R1 61.53 (¦

"R^

=7.673





- ~

7.8 8.0
RT (min)

PFOSA

Cone. 4.8387

R#1 498.20>64.10 0.21 (0.09)
Q 498.20>78.00 (-)	1.90e5

7.8 8.0
RT (min)

7.8 8.0
RT (min)

7.6

13C-FOSA IS

Cone. 5.0000

13C-FOSA

Cone. 5.9276

ISTD 506.00>78.05 (-)

1.81e5 Q 506.00>78.05 (-)

1.5e5 ^

1.0e5 ^

5.0e4 ^
== O.OeO -4—-—

7.8 8.0
RT (min)

PFDoA

Cone. 4.8057

R#1 613.05> 169.00 16.95 (16.16)
Q 613.05>569.00 (-)	6.69e5

7.8 8.0

RT (min)

7.8 8.0

RT (min)

7.8 8.0

RT (min)

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)	6.38e5

6.0e5 -

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

228

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:31

CCV8-230428 (continued)

13C-PFDoA

Cone. 5.9014

10-2-FtS

Cone. 2.6819

R#1 626.50>81.05 111.08 (76.13)
Q 626.50>607.05 (-)	2.34e4



R1 111.(1

6^387

2.0e4 -



] RT=|.008

1.0e4-



1

O.OeO -



V7

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)
2.0e51

d5-NEtFOSA

Cone. 6.5633

2.04e5 Q 531.10>169.10 (-)
2.0e51

O.OeO -

NMeFOSE

Cone. 5.5387

2.04e5 Q 616.10> 58.90 (-)
1.0e5-|

RT (min)

RT (min)

9.0

RT (min)

8.6

NEtFOSE

Cone. 4.4539

Q 629.50>59.10 (-)
3.0e5 :

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 8.0701

3.20e5 ISTD 638.90> 59.10 (-)

7.14e4 Q 638.90> 59.10 (-)

9.0
RT (min)

9.0
RT (min)

d3-NMeFOSA

Cone. 6.7823

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

d7-N-MeFOSE IS

Cone. 5.0000

ISTD 623.00>59.00 (-)
1.0e5 -

5.0e4 -

d7-N-MeFOSE

Cone. 7.0987

Q 623.00>59.00 (-)
1.0e5 -

5.0e4 -

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 7.7327

R#1 713.00 >169.30 12.82 (11.66)
Q 713.00>668.90 (-)	5.37e5

A= 1428721

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 2.7342

11CI-PF30UdS

Cone. 5.2072

1.92e5 Q714.80>669.80 (-)

1.92e5 Q 631.00>451.10 (-)

O.OeO -

.623

8.6

.8 9.0
RT (min)

L-PFDoS

Cone. 5.0562

R#1 698.80>98.80 63.57 (71.85)
Q 698.80>80.10 (-)	6.61e4

Q 377.10>251.20 (-)

8.59e5 Q 812.90>769.00 (-)

1.71e5 Q 912.80>869.00 (-)

6.0e4 ^

R1 63.57

]RT=

3.274

4.0e4 ^







2.0e4 ^



I



O.OeO -



V

r

7.5e5 -
5.0e5 :
2.5e5 :
O.OeO :

F

1964916
6.396

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

A=400457
RT=9150



8.4 8.6
RT (min)

6.6

RT (min)

9.4

RT (min)

.8 9.0

RT (min)

NMeFOSA

Cone. 4.5878

R#1 512.10>219.20 85.01 (76.94)
Q 512.10> 169.20 (-)	7.77e4

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

8.4 8.6

RT (min)

NEtFOSA

Cone. 4.8940

R#1 526.50>219.20 65.60 (67.00)
Q 526.50>169.10 (-)	1.45e5

{ A=375410

-R1 6560 ("jm=8.787

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 8.1469

R#1 663.10> 169.10 26.30 (20.38)
Q 663.10>618.90 (-)	4.89e5

O.OeO



rA=i,

.77122

- R1 26.30

|"RT"^{

.324

I

I

~

9.0

RT (min)

8.2 8.4 8.6

RT (min)

9CI-PF30NS

Cone. 4.2131

Q 531.00>351.10 (-)
4.0e5 H

4.12e5

A=986277
RT=7.135

VI

RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

1.40e5 ISTD 815.00>770.00 (-)

A=3270818
RT=9150



10.0

RT (min)

9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

22§

-------


Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:31

CCV8-230428 (continued)

13C2-PFHxDA

Cone. 5.4696

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

1,37e6 ISTD 569.80> 524.90 (-)

PFBSA

Cone. 5.0579

PFecHS

Cone. 4.6049
R#1 461.00>99.10 40.14 (38.14)

4.35e5 Q 461.00>381.00 (-)	7.99e5 Q 298.00>78.00 (-)

O.OeO

I

'A=32.70818

I

RT=9

150

: I



9.0 9.2

9.4
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

f A=

_

RT=

7.655

7.5e5

-





5.0e5







2.5e5

~

V

~

O.OeO

i i * i

I I

i i i i i i i



7.6



CO
CO

o







RT (min)



A=1981809

RT (min)

t A=1214882
I RT=6.128

PFHxSA

Cone. 4.8368

4.84e5 Q 397.90>78.00 (-)
4.0e5 -

6.4
RT (min)

7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

226

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1st /S/AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/Integration
Printed 5/2/2023 11:34:12

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/29/2023 7:56:35 PM
Acquired by: System Administrator
Data File: 230428130
Vial: 4 | Inj. Volume: 10.0000uL | Tray: 1













Name

Mode ID Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.194

690665

690665

	 	

5.0000

ng/ml

13C-PFBA

Auto

4.194

690665

728229

, i'FUnDA I'i

8.9402

nq/mL

PFBA

Auto

4.107

140

690665

13C-PFBA IS

0.0009

ng/ml

13C-PFPeA IS

Auto

5.361

962041

962041

	 	

5.0000

ng/ml

13C-PFPeA

Auto

5.361

962041

728229

13C7-PFllnDA IS

7.7511

ng/ml

PFPeA

IV

5.367

1453

962041

13C-PFPeA IS

0.0082

ng/ml

13C-PFBS IS

Auto

5.492

315366

315366

	 	

4.6500

ng/ml

13C-PFBS

Auto

5.492

¦¦¦¦¦66

728229

13C7-PFUnDA IS

504

ng/ml

PFBS

Auto

5.472

114

315366

13C-PFBS IS

0.0023

nq/mL

13C HFPO DA IS

Auto

6.094

193015

193015

	 	

5.0000

ng/ml

FPO DA

Auto

6.094

193015

728229

'FUrif

7.1617

ng/ml

HFPO DA

Auto

6.257

95

193015

1?

0.0034

ng/ml

13C-4 2-FTS IS

Auto

5.894

174837

174837

	 	

4.6700

ng/ml

13C-4 2-FTS

Auto

5.894

174837

728229

13C7-PFUnDA IS

?83

ng/ml

4-2-FtS

N D( W/B)

	

	

174837

13C-4 2-FTS IS

	

ng/ml

PFHxA

Auto

5.946

1659

606

13C-PFHxA

0.0047

ng/ml

13C-PFHxA IS

Auto

5.948

1323606

1323606

	 	

5.0000

ng/ml

13C-PFHxA

Auto

5.948

1323606

728229

13C7-PFUnDA IS

7.8490

ng/ml

PFPeS

N

	

	

364959

180-PFHxS IS

	

nq/mL

PFHxS

Auto

6.362

766

364959

180-PFHxS

0.0165

ng/ml

13C-PFHpA IS

Auto

6.354

1209356

1209356

	 	

5.0000

ng/ml

13C-PFHpA

Auto

6.354

1209356

728229

¦FUn[

5.9597

ng/ml

PFDA

Auto

7.312

636

1251155

13C-PFDA IS

0.0027

ng/mL

13C-PFDA IS

Auto

7.309

1251155

1251155

	 	

5.0000

ng/ml

13C-PFDA

Auto

7.309

1251155

728229

13C7-PFllnDA IS

6.1061

ng/mL

d3-N-MeFOSAA IS

Auto

7.484

63

417663

	 	

5.0000

ng/ml

cB-N-MeFOSAA

Auto

7.484

417663

728229

130 T PFUnDA IS

6.9908

ng/mL

NMeFi

Auto

7.494

410

417663

d3-N-MeFOSAA IS

0.0049

ng/ml

PFDS

Auto

7.925

105

363286

13C-PFOS IS

0.0016

ng/mL

13C-PFUnDA IS

Auto

7.656

1203275

1203275

	 	

5.0000

nq/mL

13C-PFUnDA

Auto

7.656

1203275

728229

13C7-PFUnDA IS

6.6727

ng/mL

PFUnDA

Auto

7.669

30

1203275

13C-PFUnDA IS

0.0027

ng/mL

cIS-N-Hk^-v IS

Auto

7.666

512028

512028

	 	

5.0000

ng/mL

d5-N-EtFOSAA

Auto

7.666

512028

728229

13C7-PFUnDA IS

8.0382

ng/ml

NEtFOSAA

Auto

7.568

1321

512028

il5-N- EtFOS

0.0130

nq/mL

PFOSA

Auto

7.756

86

296742

13C-FOSA IS

0.0014

nci/ml.

13C-FOSA IS

Auto

7.744

296742

742

	 	

5.0000

1L

13C-FOSA

Auto

7.744

296742

229

13C7-PFUnDA IS

6.1906

ng/ml

PFDoA

Auto

7.999

1011

351

:DoA

0.0042

ng/mL

13C-PFDoA IS

Auto

7.997

1078351

351

	 	

5 OOOO

nn/rri[_

I iv. PFl'On

Auto

7.997









iL

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2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration

	Printed 5/2/2023 11:34:12

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name Std. Cone.

Cone.

Unit

10-2-FtS

ND(W/B)

—

—

71633

13C-8 2-FTS IS

—

nq/mL

d5-NEtFOSA IS

Auto

8.781

332109

332109

— 	

5.0000

nq/mL

d5-NEtFOSA

Auto

8.781

332109

728229

13C7-PFUnDA IS

6.7623

nq/mL

NMeFOSE

ND(W/B)

	

	

165730

d7-N-MeFOSE IS

	

nq/mL

NEtFOSE

Auto

8.926

489

129811

d9-EtFOSE IS

0.0038

nq/mL

d9-EtFOSE IS

Auto

8.736

129811

129811

— 	

5.0000

nq/mL

d9-EtFOSE

Auto

8.736

129811

728229

13C7-PFUnDA IS

9.2547

nq/mL

NMeFOSA

ND(W/B)

—

—

305491

d3-NMeFOSA IS

—

nq/mL

dB-NMeFOSA IS

Auto

8.524

305491

305491

— 	

5.0000

nq/mL

dB-NMeFOSA

Auto

8.524

305491

728229

13C7-PFUnDA IS

6.8795

nq/mL

d7-N-MeFOSE IS

Auto

8.490

165730

165730

— —

5.0000

nq/mL

d7-N-MeFOSE

Auto

8.490

165730

728229

13C7-PFUnDA IS

6.6598

nq/mL

NEtFOSA

Auto

8.840

281

332109

d5-NEtFOSA IS

0.0058

nq/mL

PFTrDA

Auto

8.221

262

138542

13C-PFTeDA IS

0.0062

nq/mL

PFTeDA

Auto

8.630

1217

138542

13C-PFTeDA IS

0.0245

nq/mL

13C-PFTeDA IS

Auto

8.625

138542

138542

— 	

5.0000

nq/mL

1BC-PFTeDA

Auto

8.625

138542

728229

13C7-PFUnDA IS

1.1908

nq/mL

11CI-PF30UdS

ND(W/B)

	

	

363286

13C-PFOS IS

	

nq/mL

9CI-PFBONS

ND(W/B)

	

	

363286

13C-PFOS IS

	

nq/mL

L-PFDoS

ND(W/B)

	

	

363286

13C-PFOS IS

	

nq/mL

NaDONA

ND(W/B)

—

—

1415256

13C-PFNA IS

—

nq/mL

PFHxDA

Auto

9.157

558

2139881

13C2-PFHxDA IS

-0.0389

nq/mL

PFODA

ND(W/B)

	

	

2139881

13C2-PFHxDA IS

—

nq/mL

13C2-PFHxDA IS

Auto

9.154

2139881

2139881

— 	

5.0000

nq/mL

1BC2-PFHxDA

Auto

9.154

2139881

728229

13C7-PFUnDA IS

5.8049

nq/mL

13C7-PFUnDA IS

Auto

7.655

728229

728229

— 	

5.0000

nq/mL

PFecHS

Auto

6.686

224

363286

13C-PFOS IS

0.0007

nq/mL

PFBSA

ND(W/B)

—

—

296742

13C-FOSA IS

—

nq/mL

PFHxSA

ND(W/B)

—

—

1415256

13C-PFNA IS

—

nq/mL

CHARGE

ND(W/B)

	

	

728229

13C7-PFUnDA IS

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 8.9402
1.53e5 Q 217.20>172.30 (-)

1.5e5 -
1.0e5-j
5.0e4 ^
O.OeO -

A=690665
RT=4.194

A=690665
RT=4.194

4.00 4.25 4.50

PFBA

Cone. 0.0009
1.53e5 Q 213.20> 169.10 (-)
A=140
RT=4.1

4.0e2-

13C-PFPeA IS

Cone. 5.0000
5.09e2 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 7.7511
3.84e5 Q 267.90>223.00 (-)

A=962041
fl"= 5.361

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

O.OeO -

4.00 4.25 4.50

RT (min)

13C-PFBS

Cone. 5.7904

5.6

RT (min)

PFBS

Cone. 0.0023
R#1 298.80>99.00 0.00 (65.16)

Q 299.00>80.00 (-)	5.30e 1 ISTD 332.10>287.10 (-)

13C HFPO DA IS

Cone. 5.0000

RT (min)

PFPeA

Cone. 0.0082

Q263.05>219.10 (-)	8.73e2

7.5e2
5.0e2
2.5e2

O.OeO A			

5.2 5.4 5.6

RT (min)

ISTD 301.80>80.00 (-)

f A=315366
RT= 5.492

5.6 5.8
RT (min)

4.0e1
2.0e1
O.OeO

7.5e4 -
5.0e4 -j
2.5e4 -j
O.OeO :

A= 193015
fl"=6.094

6.2 6.4
RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

228

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1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:34:12

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 7.1617

Q 332.10>287.10 (-)
7.5e4z_

5.0e4 ^

2.5e41

A= 193015
'T=6.094

O.OeO -

6.0

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

A=1209356
T=6.354

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :



13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
6.0e5 -

4.0e5 :
2.0e5 ^
O.OeO :

=1537108
6.672

HFPO DA

Cone. 0.0034

R#1 329.00>285.10 0.00 (80.83)
Q 329.00>169.00 (-)	5.80e1

: R1 o.oo (—-)

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 26.62 (27.58)

ISTD 329.00>309.15 (-)	7.40e4

~ A= 174837
:R1 26.62 (-h-|#r= 5.894

13C-4 2-FTS

Cone. 7.1783

R#1 329.00>81.00 26.62 (27.58)
Q 329.00>309.15 (-)	7.40e4

~ A= 174837

:R1 26.62 (-j-^r= 5.894

4-2-FtS

Cone. —

R#1 327.00>81.10 —- (16.09)
Q 327.00>307.05 (-)	O.OOeO

6.2 6.4
RT (min)

PFHxA

Cone. 0.0047

R#1 313.00> 119.10 0.30 (2.51)
Q 313.00>269.00 (-)	1.42e3

TA=1659

-R1 0.30 (--^-UT= 5.946

6.0 6.2
RT (min)

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

13C-PFHxA

Cone. 7.8490

5.62e5 Q 314.90>270.10 (-)

A=1323606
fl"= 5.948

fA= 1323606
RT= 5.948

O.OeO -

5.8 6.0 6.2

RT (min)

13C-PFHpA

Cone. 7.3824

180-PFHxS IS

Cone. 4.7250

fA= 1209356
RT=6.354

5.30e5 Q 366.90>322.10 (-)	5.30e5 ISTD 402.70>84.05 (-)

1.5e5 -j
1.0e5 -j
5.0e4 ^

O.OeO 1 . . .

A=364959
'T=6.361

6.6

RT (min)

6.6

RT (min)

6.2

6.4

13C2-6 2-FTS

Cone. 6.2276

6.48e4 Q 428.90>409.00 (-)
6.0e4 ^

4.0e4 ^

2.0e4 ^

== O.OeO 1. . .

RT (min)

RT (min)

13C-PFOA

Cone. 7.5480

6.34e5 Q 416.80>372.05 (-)
6.0e5 -

4.0e5 :
2.0e5 ^
O.OeO :

=1537108
6.672

L

6.8 7.0
RT (min)

6.8 7.0
RT (min)

6.0 6.2
RT (min)

PFPeS

Cone. —

R#1 349.00>99.00 — - (77.24)
Q 349.00>79.95 (-)	O.OOeO

O.OeO | ' | | , | '	

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.0165

R#1 399.00>99.00 81.49 (85.33)
Q 399.00>80.00 (-)	3.06e2

3.0e2 :
2.0e2 :
1.0e2:
O.OeO -

~ A=766

R1 81.49 (-1-

f^T=6.362

L



6.2
RT (min)

6.2

RT (min)

6.2

6.4

180-PFHxS

Cone. 6.6773

6.6
RT (min)

PFHpA

Cone. 0.0040

R#1 362.90>169.00 4.55 (17.91)
Q 362.90>319.00 (-)	7.59e2

~ A=1448

: R1 4.55 (--^^7=6.352

6.6
RT (min)

PFHpS

Cone. —

R#1 449.00>99.20 — - (66.50)
Q 449.00>80.15 (-)	O.OOeO

6.6
RT (min)

6-2-FTS

Cone. 0.0027

R#1 427.00>80.90 0.00 (33.45)
Q 427.00>407.00 (-)	5.40e1

A=85

6-0e1:Ri 0.00 (—-) RT=6.800

6.4 6.6

RT (min)

PFOA

Cone. 0.0034

R#1 413.00 > 169.10 13.81 (27.85)
Q 413.00>369.00 (-)	8.35e2

f A=1407

7.5e2IR1 13-81 (|-|4r=6.669

6.6 6.8

RT (min)

PFOS

Cone. 0.0171

R#1 499.00>99.00 80.19 (86.07)
Q 499.00>80.00 (-)	1.88e2

f A=647
= R1 80.19 (--"ir=6.954

6.75 7.00 7.25

RT (min)

7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

228

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1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:34:12

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0018

R#1 463.00>219.00 4.55 (24.00)
Q 463.00>418.90 (-)

3.0e2 - R1 4.55 (—-)
I A=593 |

13C-PFNAJS

Cone. 5.0000

3.24e2 ISTD 467.80>423.00 (-)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

TA=71633
RT^ 7.305

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)
1.5e5 -

?A=417663
RT= 7.484

1.0e5 -
5.0e4 :
O.OeO :

U

13C-PFUnDA

Cone. 6.6727

Q 564.80>519.95 (-)
4.0e5 -

6.0e1 :
4.0e1 -
2.0e1 -
O.OeO:

TA=

R1 0.00 (—;

)RT=7.756

13C-PFNA

Cone. 7.8191

5.83e5 Q 467.80>423.00 (-)

~ A=1
R~ll='

1415256
Rlj=6.977



13C-8 2-FTS

Cone. 5.9597

2.80e4 Q 528.80> 509.00 (-)

TA=71633
RTf 7.305



7.6
RT (min)

d3-N-MeFOSAA

Cone. 6.9908

Q 572.80>419.05 (-)
1.5e5 -

7.6 7.8
RT (min)

O.OeO

7.8 8.0
RT (min)

PFOSA

Cone. 0.0014

R#1 498.20>64.10 0.00 (0.09)
Q 498.20>78.00 (-)	6.20e1

PFNS

Cone. —

R#1 549.00 >99.00 — - (71.23)
5.83e5 Q 549.00>79.95 (-)

O.OeO -

7.2

RT (min)

4.0e2

T A=.636

O.OeO

7.4 7.6

RT (min)

7.2

7.4

A=410
RT=7.494



A=35
RT=7-636

7.6 7.8
RT (min)

PFUnDA

Cone. 0.0027

R#1 563.00>219.00 0.00 (13.86)
Q563.00>518.90 (-)	2.47e2

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

O.OeO

7.6 7.8 8.0
RT (min)

13C-FOSA IS

Cone. 5.0000

13C-FOSA

Cone. 6.1906

ISTD 506.00>78.05 (-)	1.18e5 Q 506.00>78.05 (-)

7.8 8.0

RT (min)

7.6 7.8 8.0

RT (min)

8-2-FTS

Cone. —

R#1 527.20>487.00 — - (6.74)
O.OOeO Q 527.10>506.90 (-)	i

6.8 7.0 7.2

RT (min)

PFDA

Cone. 0.0027

R#1 512.90>219.00 5.41 (17.51)
Q 512.90>469.00 (-)	4.08e2

7.4 7.6
RT (min)

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

r A= 1251155
I Rl> 7.309

O.OeO -

7.6
RT (min)

NMeFOSAA

Cone. 0.0049

R#1 570.20 > 512.00 48.00 (37.68)
Q 570.20>419.00 (-)	3.91e2

R1 48.00 (—-)

7.2

7.4

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 8.0382

1.89e5 Q 588.80>419.00 (-)

1.5e5-
1.0e5-
5.0e4-
O.OeO -

7.8 8.0
RT (min)

7.6

7.8 8.0

RT (min)

7.6
RT (min)

13C-PFDA

Cone. 6.1061

5.01 e5 Q 514.80>469.95 (-)

~ A= 1251155
Rli 7.309

VI

7.6
RT (min)

PFDS

Cone. 0.0016

R#1 599.00>99.00 24.36 (65.43)
Q 599.00>80.10 (-)	6.70e1

f=105

6.0e11 R1 2436 (—"feT=7.925

4.0e1 :
2.0e1 :
O.OeO :

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)
4.0e5 -

203275
7.656

O.OeO

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.0130

R#1 584.20>526.10 5.80 (58.21)
Q 584.20>418.95 (-)	1.35e2

1 A=1321

I R1 5.80 (p;T^t68

7.8 8.0
RT (min)

PFDoA

Cone. 0.0042

R#1 613.05> 169.00 24.94 (16.16)
Q 613.05>569.00 (-)	4.56e2

f A=1011
4 0e2 - R1 24-94f^"RT=^7.999

O.OeO -

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)
4.0e5 H

4.11e5

RT (min)

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

220

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1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:34:12

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 6.0966

Q614.80>569.95 (-)
4.0e5 1

10-2-FtS

Cone. —

R#1 626.50>81.05 —- (76.13)
Q 626.50>607.05 (-)	O.OOeO

2.0e1 -
1.0e1:

d5-NEtFOSA IS

Cone. 5.0000

d5-NEtFOSA

Cone. 6.7623

ISTD 531.10> 169.10 (-)	1.29e5 Q 531.10> 169.10 (-)

f A=332109
RT=8.781	I

NMeFOSE

Cone. —

1.29e5 Q 616.10> 58.90 (-)

RT (min)

NEtFOSE

Cone. 0.0038

O.OeO -

d9-EtFOSE IS

Cone. 5.0000

O.OeO I | . |

A=332109
RT=8.781

RT (min)

8.6 8.8 9.0

RT (min)

d9-EtFOSE

Cone. 9.2547

O.OeO

O.OeO

Q 629.50> 59.10 (-)	8.96e2 ISTD 638.90> 59.10 (-)

4.92e4 Q 638.90> 59.10 (-)	4.92e4

O.OeO

9.0

RT (min)

NMeFOSA

Cone. —

R#1 512.10>219.20 —- (76.94)

Q 512.10 > 169.20 (-)	O.OOeO I STD 515.10 > 169.00 (-)

5.0e0 n	i

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

d3-NMeFOSA

Cone. 6.8795

Q 515.10> 169.00 (-)

8.6 8.8 9.0

RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

O.OeO

8.6 8.8 9.0

RT (min)

d7-N-MeFOSE

Cone. 6.6598

6.58e4

-5.0e0 H , , , , , ,l , , , , , , , ,
8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0058

R#1 526.50>219.20 0.00 (67.00)
Q 526.50> 169.10 (-)	1.13e2

n R1 0.00 (—)	l\

O.OeO

8.4 8.6

RT (min)

PFTeDA

Cone. 0.0245

R#1 713.00 >169.30 2.66 (11.66)
Q 713.00>668.90 (-)	3.58e2

f A=1217

on 1 JR1 266 (""frt=$.630
3.062-1	' ' Y

2.0e2 -

1.0e2-

O.OeO -

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

13C-PFTeDA

Cone. 1.1908

iSTD 714.80>669.80 (-)	4.98e4 Q 714.80>669.80 (-)

rA

f\

11CI-PF30UdS

Cone. —

Q 631.00>451.10 (-)
7.5e0 ^

5.0e0 ^

2.5e0 ^

O.OeO 1	

8.6 8.8 9.0
RT (min)

L-PFDoS

Cone. —

R#1 698.80>98.80 — - (71.85)
Q 698.80>80.10 (-)	O.OOeO

5.0e0 n	i

B.6 8.8 9.0
RT (min)

B.6 8.8 9.0
RT (min)

NaDONA

Cone. —

PFHxDA

Cone. -0.0389

PFODA

Cone. —

Q 377.10>251.20 (-)	2.60e1 Q 812.90>769.00 (-)	2.24e2 Q 912.80>869.00 (-)

O.OeO

8.4 8.6

RT (min)

PFTrDA

Cone. 0.0062

R#1 663.10> 169.10 0.00 (20.38)
Q 663.10>618.90 (-)	1.98e2

8.6

RT (min)

9CI-PF30NS

Cone. —

8.00e0 Q 531.00>351.10 (-)

RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

2.90e 1 I STD 815.00 > 770.00 (-)

B.2 8.4 8.6

RT (min)

1.0e2

O.OeO

9.0

10.0

RT (min)

6.6

RT (min)

9.4

RT (min)

7.5e5 -
5.0e5 i
2.5e5 i
O.OeO "r

9.4

RT (min)

A=2139881
RT=9.154

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal.iproc

23ffi

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 11:34:12

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 5.8049

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

9.16e5 ISTD 569.80>524.90 (-)

PFecHS	PFBSA

Cone. 0.0007	Cone. —
R#1 461.00>99.10 0.00 (38.14)

2.70e5 Q 461.00>381.00 (-)	1.41e2 Q 298.00>78.00 (-)

PFHxSA

Cone. —

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

TA=2139881
RT=9154

L

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

fA=224

:R1 0.00 (—¦-);ft rt=6.68

4.0e1

6.4 6.6 6.8

RT (min)

7.0 7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal.iproc

232

-------
Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:35

CCV9-230428

Sample ID: CCV9-230428

Date Acquired: 4/29/2023 8:10:22 PM

Acquired by: System Administrator

Data File: 230428131

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.206

854837

854837

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.206

854837

974051

13C7-PFUnDA IS

5.0000

8.2727

ng/mL

PFBA

Auto

4.207

880279

854837

13C-PFBA IS

5.0000

4.6058

nq/mL

13C-PFPeA IS

Auto

5.365

1155204

1155204

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.365

1155204

974051

13C7-PFUnDA IS

5.0000

6.9585

nq/mL

PFPeA

Auto

5.365

1127293

1155204

13C-PFPeA IS

5.0000

5.3000

ng/mL

13C-PFBS IS

Auto

5.495

406586

406586

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.495

406586

974051

13C7-PFUnDA IS

4.6500

5.5812

ng/mL

PFBS

Auto

5.495

319599

406586

13C-PFBS IS

4.4200

5.0635

nq/mL

13C HFPO DA IS

Auto

6.095

244357

244357

	

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.095

244357

974051

13C7-PFUnDA IS

5.0000

6.7785

nq/mL

HFPO DA

Auto

6.095

206407

244357

13C HFPO DA IS

5.0000

5.7750

nq/mL

13C-4 2-FTS IS

Auto

5.896

216650

216650

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.896

216650

974051

13C7-PFUnDA IS

4.6700

6.6502

ng/mL

4-2-FtS

Auto

5.896

230406

216650

13C-4 2-FTS IS

4.6700

4.4823

nq/mL

PFHxA

Auto

5.950

2059847

1590347

13C-PFHxA IS

5.0000

4.8746

ng/mL

13C-PFHxA IS

Auto

5.950

1590347

1590347

	

5.0000

5.0000

i

13C-PFHxA

Auto

5.950

1590347

974051

13C7-PFUnDA IS

5.0000

7.0508

ng/mL

PFPeS

Auto

5.992

313197

440290

180-PFHxS IS

4.6900

5.0492

nq/mL

PFHxS

Auto

6.362

252551

440290

180-PFHxS IS

4.5500

4.5133

ng/mL

13C-PFHpA IS

Auto

6.355

1485115

1485115

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.355

1485115

974051

13C7-PFUnDA IS

5.0000

6.7778

ng/mL

180-PFHxS IS

Auto

6.362

440290

440290

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.362

440290

974051

13C7-PFUnDAJS

4.7250

6.0226

ng/mL

PFHpA

Auto

6.355

2268898

1485115

13C-PFHpA IS

5.0000

5.1222

ng/mL

13C2-6 2-FTS IS

Auto

6.655

194305

194305

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.655

194305

974051

13C7-PFUnDA IS

4.7500

5.6938

ng/mL

PFHpS

Auto

6.666

320518

440290

180-PFHxS IS

4.7600

4.7897

ng/mL

6-2-FTS

Auto

6.656

179139

194305

13C2-6 2-FTS IS

4.7400

4.6387

nq/mL

PFOA

Auto

6.674

2414577

1909272

13C-PFOA IS

5.0000

4.6524

ng/mL

13C-PFOA IS

Auto

6.673

1909272

1909272

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.673

1909272

974051

13C7-PFUnDA IS

5.0000

7.0094

ng/mL

PFOS

Auto

6.960

223566

445564

13C-PFOS IS

4.6400

4.8172

nq/mL

13C-PFOS IS

Auto

6.959

445564

445564

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

6.959

445564

974051

13C7-PFUnDA IS

4.7750

6.0708

nq/mL

PFNA

Auto

6.980

1517172

1729096

13C-PFNA IS

5.0000

3.6750

ng/mL

13C-PFNA IS

Auto

6.979

1729096

1729096

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.979

1729096

974051

13C7-PFUnDA IS

5.0000

7.1422

ng/mL

PFNS

Auto

7.284

520180

445564

13C-PFOS IS

4.8000

4.8766

nq/mL

8-2-FTS

Auto

7.310

78705

97389

13C-8 2-FTS IS

4.7900

3.3729

ng/mL

13C-8 2-FTS IS

Auto

7.309

97389

97389

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.309

97389

974051

13C7-PFUnDA IS

4.7900

6.0577

ng/mL

PFDA

Auto

7.313

1755156

1719999

13C-PFDA IS

5.0000

5.3883

nq/mL

13C-PFDA IS

Auto

7.314

1719999

1719999

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.314

1719999

974051

13C7-PFUnDA IS

5.0000

6.2758

nq/mL

d3-N-MeFOSAA IS

Auto

7.488

668466

668466

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.488

668466

974051

13C7-PFUnDA IS

5.0000

8.3651

nq/mL

NMeFOSAA

Auto

7.491

623472

668466

d3-N-MeFOSAA IS

5.0000

4.6992

nq/mL

PFDS

Auto

7.621

352223

445564

13C-PFOS IS

4.8200

4.4803

nq/mL

13C-PFUnDA IS

Auto

7.659

1628472

1628472

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.659

1628472

974051

13C7-PFUnDA IS

5.0000

6.7515

nq/mL

PFUnDA

Auto

7.659

1214999

1628472

13C-PFUnDA IS

5.0000

3.8113

nq/mL

d5-N-EtFOSAA IS

Auto

7.670

712382

712382

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.670

712382

974051

13C7-PFUnDA IS

5.0000

8.3611

nq/mL

NEtFOSAA

M

7.677

558246

712382

dS-N-EtFOSAA IS

5.0000

3.9614

nq/mL

PFOSA

Auto

7.745

465111

444187

13C-FOSA IS

5.0000

4.8868

nq/mL

13C-FOSA IS

Auto

7.746

444187

444187

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.746

444187

974051

13C7-PFUnDA IS

5.0000

6.9280

nq/mL

PFDoA

Auto

8.001

1689477

1503687

13C-PFDoA IS

5.0000

5.0290

nq/mL

13C-PFDoA IS

Auto

8.000

1503687

1503687

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

233

-------
)

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:35

CCV9-230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.000

1503687

974051

13C7-PFUnDA IS

5.0000

6.3558

nq/mL

10-2-FtS

Auto

8.012

38356

97389

13C-8 2-FTS IS

4.8200

1.5504

ng/mL

d5-NEtFOSA IS

Auto

8.781

512443

512443

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.781

512443

974051

13C7-PFUnDA IS

5.0000

7.8009

ng/mL

NMeFOSE

Auto

8.505

257310

245043

d7-N-MeFOSE IS

5.0000

6.4308

nq/mL

NEtFOSE

Auto

8.755

783188

191811

d9-EtFOSE IS

5.0000

4.1159

ng/mL

d9-EtFOSE IS

Auto

8.737

191811

191811

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.737

191811

974051

13C7-PFUnDA IS

5.0000

10.2237

ng/mL

NMeFOSA

Auto

8.530

215084

449434

d3-NMeFOSA IS

5.0000

5.1940

nq/mL

dB-NMeFOSA IS

Auto

8.524

449434

449434

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.524

449434

974051

13C7-PFUnDA IS

5.0000

7.5668

nq/mL

d7-N-MeFOSE IS

Auto

8.489

245043

245043

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.489

245043

974051

13C7-PFUnDA IS

5.0000

7.3619

nq/mL

NEtFOSA

Auto

8.791

366944

512443

d5-NEtFOSA IS

5.0000

4.8811

ng/mL

PFTrDA

Auto

8.326

1104737

241638

13C-PFTeDA IS

5.0000

15.0500

nq/mL

PFTeDA

Auto

8.625

1239608

241638

13C-PFTeDA IS

5.0000

14.3281

ng/mL

13C-PFTeDA IS

Auto

8.626

241638

241638

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.626

241638

974051

13C7-PFUnDA IS

5.0000

1.5527

ng/mL

11CI-PFBOUdS

Auto

7.812

510410

445564

13C-PFOS IS

4.7100

4.9996

nq/mL

9CI-PF30NS

Auto

7.140

864737

445564

13C-PFOS IS

4.6600

3.9313

ng/mL

L-PFDoS

Auto

8.277

163241

445564

13C-PFOS IS

4.8400

5.4987

nq/mL

NaDONA

Auto

6.400

1956935

1729096

13C-PFNA IS

4.7100

5.3619

ng/mL

PFHxDA

Auto

9.153

139548

2949631

13C2-PFHxDA IS

5.0000

0.5657

nq/mL

PFODA

Auto

9.680

153761

2949631

13C2-PFHxDA IS

5.0000

1.0213

ng/mL

13C2-PFHxDA IS

Auto

9.154

2949631

2949631

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.154

2949631

974051

13C7-PFUnDA IS

5.0000

5.9821

ng/mL

13C7-PFUnDA IS

Auto

7.659

974051

974051

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.625

1826508

445564

13C-PFOS IS

4.6100

4.5168

ng/mL

PFBSA

Auto

6.133

1229675

444187

13C-FOSA IS

5.0000

5.3123

nq/mL

PFHxSA

Auto

6.961

1032005

1729096

13C-PFNA IS

5.0000

4.8328

ng/mL

CHARGE

ND(W/B)

	

	

974051

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 8.2727
Q 217.20> 172.30 (-)

PFBA

Cone. 4.6058
Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
1,90e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 6.9585
4.43e5 Q 267.90>223.00 (-)

TA= 1155204
TT= 5.365

O.OeO -bjf

O.OeO

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 5.3000	Cone. 4.6500	Cone. 5.5812 Cone. 5.0635

1155204
= 5.365

O.OeO

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)

3.97e5 I STD 301.80 > 80.00 (-)
1.5e5 -i

1.50e5 Q 301.80>80.00 (-)
1.5e5 n

1.0e5 ^

5.0e4 ^

, , , O.OeO 4=

R#1 298.80>99.00 70.44 (65.16)

1.50e5 Q 299.00>80.00 (-)	1.15e5 ISTD 332.10>287.10 (-)	1.04e5

r A=319599

l0e51R1 70.44 (-1=5.495

5.6 5.8
RT (min)

5.6 5.8
RT (min)

IE

244357
!T=6.095

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

233

-------


Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:35

CCV9-230428 (continued)

13C HFPO DA

Cone. 6.7785

Q 332.10>287.10 (-)
1.0e5 -

HFPO DA

Cone. 5.7750

R#1 329.00>285.10 75.82 (80.83)
Q 329.00>169.00 (-)	8.92e4

O.OeO -

A=244357
'T=6.095

7.5e4
5.0e4
2.5e4
O.OeO

r A=206407

]R1 75.82 ("|"wT=6.095

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 22.17 (27.58)

ISTD 329.00>309.15 (-)	8.81 e4

~ A=216650

7.5e4
5.0e4
2.5e4
O.OeO -

- R1 22.17 (-

=5.a

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 4.8746

R#1 313.00> 119.10 2.67 (2.51)
Q 313.00>269.00 (-)	8.41 e5

TA=2059847
7.5e5 -|R1 267 ("Mt= 5.950

6.2 6.4
RT (min)

13C-PFHxA IS

Cone. 5.0000

13C-PFHxA

Cone. 7.0508

13C-PFHpA IS

Cone. 5.0000

I STD 366.90 >322.10 (-)
6.0e5 H

YA= 1485115
4t=6.355

4.0e5 :
2.0e5 :
O.OeO :

Q 366.90>322.10 (-)
6.0e5 H

180-PFHxS IS

Cone. 4.7250

6.23e5 I STD 402.70>84.05 (-)

YA= 1485115
RT=6.355

4.0e5 :
2.0e5 :
O.OeO :

A=440290
'T=6.362

O.OeO -

6.6

RT (min)

6.6

RT (min)

6.2

6.4

13C2-6 2-FTS IS

Cone. 4.7500

I STD 428.90>409.00 (-)	7.87e4

TA= 194305
7.5e4^	RJT=6.655

5.0e4 ^

2.5e4 :

O.OeO -

13C2-6 2-FTS

Cone. 5.6938

Q 428.90>409.00 (-)
7.5e4 -
5.0e4 ^

2.5e4 :

~ A= 194305
RT=6.655

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

I STD 416.80 >372.05 (-)
7.5e5 -
5.0e5 ^

2.5e5 ^

O.OeO 1 , , ,

13C-PFOA

Cone. 7.0094

Q 416.80>372.05 (-)
7.5e5 -
5.0e5 ^

2.5e5 ^

O.OeO 1 , , ,

6.0e4qR1 9184 ("

4.0e4 ^

2.0e4 ^

O.OeO -

Ai

A=223566
"RT=6.960

6.8 7.0
RT (min)

6.8 7.0
RT (min)

13C-4 2-FTS

Cone. 6.6502

R#1 329.00>81.00 22.17 (27.58)
Q 329.00>309.15 (-)	8.81e4

A=216650

7.5e4
5.0e4
2.5e4
O.OeO -

- R1 22.17 (-

6.0 6.2
RT (min)

- R1 82.73 (

Tf=3

RT=

=313197
= 5.992

O.OeO , , ,



T^=4

RT='

440290
!T=6.362

O.OeO -

6.6
RT (min)

PFHpS

Cone. 4.7897

R#1 449.00>99.20 66.65 (66.50)
Q 449.00>80.15 (-)	1.35e5

6.2

6.4

f A= 179139

3 R1 26-52 ("ffRT=6.656

6.6 6.8

RT (min)

PFOS

Cone. 4.8172

R#1 499.00>99.00 91.84 (86.07)
Q 499.00>80.00 (-)	6.74e4

6.0e4 -
4.0e4z_
2.0e4z_
O.OeO -

13C-PFOS IS

Cone. 4.7750

105 (-)

6.75 7.00 7.25

RT (min)

1.5e5-
We5z_
5.0e4 ^
O.OeO -

YA=445564
RT=6.959

|=6.9:

4-2-FtS

Cone. 4.4823

R#1 327.00 >81.10 16.39 (16.09)
Q 327.00>307.05 (-)	9.45e4

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 5.0492

R#1 349.00>99.00 82.73 (77.24)
Q 349.00>79.95 (-)	1.30e5

6.0 6.2
RT (min)

PFHxS

Cone. 4.5133

R#1 399.00>99.00 93.46 (85.33)
Q 399.00>80.00 (-)	9.11e4

5.8 6.0 6.2

RT (min)

180-PFHxS

Cone. 6.0226

1.94e5 Q 402.70>84.05 (-)	1.94e5

7.5e4 -
5.0e4 ^
2.5e4z_
O.OeO -

: R1 93.46 (-

Y ^=252551
=6.362

6.2

6.4

6.6
RT (min)

PFHpA

Cone. 5.1222

R#1 362.90 >169.00 17.81 (17.91)
Q 362.90>319.00 (-)	9.70e5

YA=2268898
jR1 17.81 (4^=6.355

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

J

6.6
RT (min)

6-2-FTS

Cone. 4.6387

R#1 427.00>80.90 26.52 (33.45)
Q 427.00>407.00 (-)	7.50e4

6.2

6.4

6.6
RT (min)

PFOA

Cone. 4.6524

R#1 413.00> 169.10 30.11 (27.85)
Q 413.00>369.00 (-)	9.99e5

1.0e6-

l11 (X|

A=2414577
m=6.674

RT (min)

6.8 7.0
RT (min)

13C-PFOS

Cone. 6.0708

1.80e5 Q 502.80>80.05 (-)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

233

-------


Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:35

CCV9-230428 (continued)

PFNA

Cone. 3.6750

R#1 463.00>219.00 25.51 (24.00)
Q 463.00>418.90 (-)	6.09e5

6.0e5

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 7.1422

7.00e5 Q 467.80>423.00 (-)

A=1729096
RT=6.979

7.2

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 6.0577

3.80e4 Q 528.80> 509.00 (-)

¥ A=97389
Rli 7.309

3.0e4 :
2.0e4 :
1.0e4:
O.OeO :

d3-N-MeFOSAAIS

Cone. 5.0000

ISTD 572.80>419.05 (-)

13C-PFUnDA

Cone. 6.7515

Q 564.80>519.95 (-)
6.0e5 -

4.0e5 -

2.0e5 ^

O.OeO 4==

1628472
= 7.659

7.6
RT (min)

d3-N-MeFOSAA

Cone. 8.3651

2.49e5 Q 572.80>419.05 (-)

O.OeO -

7.6 7.8
RT (min)

7.4

7.6 7.8
RT (min)

PFUnDA

Cone. 3.8113

R#1 563.00>219.00 18.03 (13.86)
Q563.00>518.90 (-)	4.54e5

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

4.0e5 -|R1 18-03|M

214999
7.659

7.6 7.8 8.0
RT (min)

PFOSA

Cone. 4.8868

R#1 498.20>64.10 0.12 (0.09)
Q 498.20>78.00 (-)	1.79e5

7.8 8.0
RT (min)

13C-FOSA IS

Cone. 5.0000

13C-FOSA

Cone. 6.9280

ISTD 506.00>78.05 (-)

rA=444187
| RT=7.746

L

1.75e5 Q 506.00>78.05 (-)

1.5e5 ^

1.0e5 ^

5.0e4 ^

O.OeO 1. . .

V

7.8 8.0

RT (min)

7.8 8.0

RT (min)

PFNS

Cone. 4.8766

R#1 549.00 >99.00 68.30 (71.23)
Q 549.00>79.95 (-)	2.09e5

2.0e5

8-2-FTS

Cone. 3.3729

R#1 527.20>487.00 7.74 (6.74)
Q 527.10>506.90 (-)	3.03e4

7.2
RT (min)

PFDA

Cone. 5.3883

R#1 512.90>219.00 18.16 (17.51)
Q 512.90>469.00 (-)	7.02e5



A=

78705

: R1 7.74 (¦

V^r

=7.310

'



~

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 6.2758

ISTD 514.80>469.95 (-)

6.93e5 Q 514.80>469.95 (-)

6.0e5 ^

4.0e5 i
2.0e5 i
== O.OeO 1. .

7.6
RT (min)

NMeFOSAA

Cone. 4.6992

R#1 570.20>512.00 36.35 (37.68)
Q 570.20>419.00 (-)	1.98e5

7.2

7.4

7.6
RT (min)

PFDS

Cone. 4.4803

R#1 599.00>99.00 54.50 (65.43)
Q 599.00>80.10 (-)	1.39e5

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

628472
7.659

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 8.3611

2.54e5 Q 588.80>419.00 (-)

7.8 8.0
RT (min)

rA=444187
RT=7.746

7.8 8.0
RT (min)

NEtFOSAA

Cone. 3.9614

R#1 584.20>526.10 64.92 (58.21)
Q 584.20>418.95 (-)	1.78e5

A= 558246

O.OeO

7.8 8.0
RT (min)

PFDoA

Cone. 5.0290

R#1 613.05> 169.00 17.88 (16.16)
Q 613.05>569.00 (-)	6.33e5

f A=1689477

6.0e5 HR1 17.8EWjb.001

^.SeSz

R1 64.92 (-

R1

=7.677

1.0e5^







5.0e4 ^







0 0<=>0 -



V

pJ	

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

5.63e5

7.8 8.0

RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

236

-------


Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:35

CCV9-230428 (continued)

13C-PFDoA

Cone. 6.3558

Q614.80>569.95 (-)

NEtFOSE

Cone. 4.1159

Q629.50>59.10 (-)
3.0e5 -

2.0e5 ^

1.0e5-j

O.OeO 1. |~. t

d3-NMeFOSA

Cone. 7.5668

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

O.OeO -

8.6

O.OeO -

10-2-FtS

Cone. 1.5504

R#1 626.50 >81.05 189.21 (76.13)
Q 626.50>607.05 (-)	1.44e4

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 7.8009

1.97e5 Q 531.10> 169.10 (-)

RT (min)

NMeFOSE

Cone. 6.4308

1.97e5 Q 616.10> 58.90 (-)
1.0e5 —|

d9-EtFOSE IS

Cone. 5.0000

3.02e5 ISTD 638.90> 59.10 (-)

6.0e4 i
4.0e4 ~

2.0e4 ~

— O.OeO 1 . . .

7.33e4 Q 638.90> 59.10 (-)

6.0e4 i
4.0e4 ~

2.0e4 ~
— O.OeO 1 . . .

O.OeO

9.0
RT (min)

NMeFOSA

Cone. 5.1940

R#1 512.10>219.20 76.98 (76.94)
Q 512.10> 169.20 (-)	8.00e4

fA=215084

7.5e4^R1 76.98 (--fl-fcr=8.530

5.0e4 -j
2.5e4 -

O.OeO -

9.0
RT (min)

9.0
RT (min)

9.0
RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 7.3619

1,72e5 I STD 623.00 > 59.00 (-)

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

9.63e4 Q 623.00> 59.00 (-)

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 14.3281

R#1 713.00 >169.30 16.42 (11.66)
Q 713.00>668.90 (-)	4.60e5

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 1.5527

8.98e4 Q 714.80>669.80 (-)

11CI-PF30UdS

Cone. 4.9996

Q 631.00>451.10 (-)

.8 9.0
RT (min)

L-PFDoS

Cone. 5.4987

R#1 698.80>98.80 61.28 (71.85)
Q 698.80>80.10 (-)	6.93e4

6.0e4 :
4.0e4 :
2.0e4 :

Q 377.10>251.20 (-)

7.5e5 ^

5.0e5 ^

2.5e51

8.66e5 Q 812.90>769.00 (-)

5.93e4 Q 912.80>869.00 (-)

A=1956935
T=6.400

1A= 139548
RT=9153

B.2 8.4 8.6

RT (min)

O.OeO -



6.6

RT (min)

9.4

RT (min)

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4-
O.OeO -

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 4.8811

R#1 526.50>219.20 61.87 (67.00)
Q 526.50>169.10 (-)	1.40e5

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 15.0500

R#1 663.10> 169.10 30.20 (20.38)
Q 663.10>618.90 (-)	4.35e5

f A= 1104737
4.0e5 H R1 30.20 326

O.OeO

3.2 8.4 8.6

RT (min)

9CI-PF30NS

Cone. 3.9313

2.07e5 Q 531.00>351.10 (-)

3.57e5

A=864737
RT=7.140

RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

5.40e4 ISTD 815.00>770.00 (-)

9.6 9.8 10.0

RT (min)

9.0 9.2 9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428A-537MOD_NewCal_Corrected.iproc

23E

-------
A

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:01:35

CCV9-230428 (continued)

13C2-PFHxDA

Cone 5.9821

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

1.25e6 ISTD 569.80>524.90 (-)

PFecHS	PFBSA

Cone. 4.5168	Cone. 5.3123
R#1 461.00>99.10 42.15 (38.14)

3.54e5 Q 461.00>381.00 (-)	7.37e5	Q 298.00>78.00 (-)

A=2949631
RT=9154

O.OeO -

vl

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

TA=974051
RT J 7.659

U,

8.0
RT (min)

RT (min)

A=1229675
RT=6.133

PFHxSA

Cone. 4.8328

Q 397.90>78.00 (-)
4.0e5 H

L

6.4
RT (min)

7.2
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428A-537MOD_NewCal_Corrected.iproc

238

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10/24/2023 3:17:00 PM Page 1 / 3

==== Shimadzu LabSolutions Batch Table====

[General]

Start from Continuing Row
[Folder]

Use Current Folder
[Data Filename]

Not Create filename
[ASCII Conversion]

Not Output ASCII Files
[File Conversion]

Not Convert
[QA/QC]

Not Execute QA/QC
[Option Item]

Option 1 Title:

Option 2 Title:

Option 3 Title:

Option 4 Title:

Option 5 Title:

Option 6 Title:

Option 7 Title:

Option 8 Title:

Option 9 Title:

Option 10 Title:

[Bracket]

None
[Startup]

Startup Off
[Shutdown]

Shutdown On
Cool down Time:0min
Degassing Unit Off
LC Pump Off
Column Oven Off
[Comment]

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428201.led

0

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428202.led

0

5\System\DEFAULT.Isr

3

L0.05ppb_230323

L0.05ppb_230323

1:Standard:(l)

CMS1 230328 537M.lcm

230428203.led

1

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428204.led

2

5\System\DEFAULT.Isr

5

L0.5ppb_230323

L0.5ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428205.led

3

5\System\DEFAULT.Isr

6

L1ppb_230323

L1ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428206.led

4

5\System\DEFAULT.Isr

7

L5ppb_230323

L5ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428207.led

5

5\System\DEFAULT.Isr

8

L10ppb_230323

L10ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428208.led

6

5\System\DEFAULT.Isr

9

L15ppb_230323

L15ppb_230323

1:Standard

CMS1 230328 537M.lcm

230428209.led

7

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428210.lcd

0

5\System\DEFAULT.Isr

238

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD.Icb

-------
10/24/2023 3:17:00 PM Page 2 / 3

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

10

Branched Mix 230117

Branched Mix 230117

3:Unspiked

CMS1 230328 537M.lcm

230428211.led

0

5\System\DEFAULT.Isr

11

ICV1-230428

ICV1-230428

2:Control

CMS1 230328 537M.lcm

230428212.led

4

5\System\DEFAULT.Isr

11

ICV1-230428

ICV1-230428

2:Control

CMS1 230328 537M.lcm

230428213.lcd

4

5\System\DEFAULT.Isr

3

LLCCV1 -230428-WI

LLCCV1-230428-WI

1:Standard:(l)

CMS1 230328 537M.lcm

230428214.led

1

5\System\DEFAULT.Isr

4

CCV1-230428-WI

CCV1-230428-WI

1:Standard

CMS1 230328 537M.lcm

230428215.lcd

2

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428216.led

0

5\System\DEFAULT.Isr

28

MBLK-215208

MBLK-215208

0:Unknown

CMS1 230328 537M.lcm

230428217.led

0

5\System\DEFAULT.Isr

29

LCS-WI-215208

LCS-WI-215208

0:Unknown

CMS1 230328 537M.lcm

230428218.lcd

0

5\System\DEFAULT.Isr

4

23041906-14AMS

23041906-14AMS

0:Unknown

CMS1 230328 537M.lcm

230428219.lcd

0

5\System\DEFAULT.Isr

5

23041906-14AMSD

23041906-14AMSD

0:Unknown

CMS1 230328 537M.lcm

230428220.led

0

5\System\DEFAULT.Isr

30

23041906-21AMS

23041906-21 AMS

0:Unknown

CMS1 230328 537M.lcm

230428221.led

0

5\System\DEFAULT.Isr

31

23041906-21AMSD

23041906-21 AMSD

0:Unknown

CMS1 230328 537M.lcm

230428222.led

0

5\System\DEFAULT.Isr

32

23041906-21A

23041906-21A

0:Unknown

CMS1 230328 537M.lcm

230428223.led

0

5\System\DEFAULT.Isr

33

23041906-20A

23041906-20A

0:Unknown

CMS1 230328 537M.lcm

230428224.led

0

5\System\DEFAULT.Isr

34

23041906-22A

23041906-22A

0:Unknown

CMS1 230328 537M.lcm

230428225.led

0

5\System\DEFAULT.Isr

35

23041906-23A

23041906-23A

0:Unknown

CMS1 230328 537M.lcm

230428226.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230428227.led

2

5\System\DEFAULT.Isr

16

CCV2-230428

CCV2-230428

2:Control

CMS1 230328 537M.lcm

230428228.led

5

5\System\DEFAULT.Isr

16

CCV2-230428

CCV2-230428

2:Control

CMS1 230328 537M.lcm

230428229.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428230.led

0

5\System\DEFAULT.Isr

36

23041906-24A

23041906-24A

0:Unknown

CMS1 230328 537M.lcm

230428231.led

0

5\System\DEFAULT.Isr

37

23041906-25A

23041906-25A

0:Unknown

CMS1 230328 537M.lcm

230428232.led

0

5\System\DEFAULT.Isr

38

23041906-26A

23041906-26A

0:Unknown

CMS1 230328 537M.lcm

230428233.led

0

5\System\DEFAULT.Isr

39

23041906-27A

23041906-27A

0:Unknown

CMS1 230328 537M.lcm

230428234.led

0

5\System\DEFAULT.Isr

40

23041906-28A

23041906-28A

0:Unknown

CMS1 230328 537M.lcm

230428235.led

0

5\System\DEFAULT.Isr

41

23041906-29A

23041906-29A

0:Unknown

CMS1 230328 537M.lcm

230428236.led

0

5\System\DEFAULT.Isr

42

23041906-30A

23041906-30A

0:Unknown

CMS1 230328 537M.lcm

230428237.led

0

5\System\DEFAULT.Isr

43

23041906-31A

23041906-31A

0:Unknown

CMS1 230328 537M.lcm

230428238.led

0

5\System\DEFAULT.Isr

44

23041906-32A

23041906-32A

0:Unknown

CMS1 230328 537M.lcm

230428239.led

0

5\System\DEFAULT.Isr

45

23041906-33A

23041906-33A

0:Unknown

CMS1 230328 537M.lcm

230428240.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230428241.led

2

5\System\DEFAULT.Isr

16

CCV3-230428

CCV3-230428

2:Control

CMS1 230328 537M.lcm

230428242.led

5

5\System\DEFAULT.Isr

16

CCV3-230428

CCV3-230428

2:Control

CMS1 230328 537M.lcm

230428243.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428244.led

0

5\System\DEFAULT.Isr

46

23041906-34A

23041906-34A

0:Unknown

CMS1 230328 537M.lcm

230428245.led

0

5\System\DEFAULT.Isr

47

23041906-35A

23041906-35A

0:Unknown

CMS1 230328 537M.lcm

230428246.led

0

5\System\DEFAULT.Isr

48

23041906-36A

23041906-36A

0:Unknown

CMS1 230328 537M.lcm

230428247.led

0

5\System\DEFAULT.Isr

49

23041906-37A

23041906-37A

0:Unknown

CMS1 230328 537M.lcm

230428248.led

0

5\System\DEFAULT.Isr

50

23042109-01G

23042109-01G

0:Unknown

CMS1 230328 537M.lcm

230428249.led

0

5\System\DEFAULT.Isr

51

23042374-01G

23042374-01G

0:Unknown

CMS1 230328 537M.lcm

230428250.led

0

5\System\DEFAULT.Isr

50

23042109-01G

23042109-01G

0:Unknown

CMS1 230328 537M.lcm

230428251.led

0

5\System\DEFAULT.Isr

230

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD.Icb

-------
10/24/2023 3:17:00 PM Page 3 / 3

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

51

23042374-01G

23042374-01G

0:Unknown

CMS1 230328 537M.lcm

230428252.led

0

5\System\DEFAULT.Isr

4

L0.1 ppb_230323

L0.1 ppb_230323

0:Unknown

CMS1 230328 537M.lcm

230428253.led

2

5\System\DEFAULT.Isr

16

CCV4-230428

CCV4-230428

2:Control

CMS1 230328 537M.lcm

230428254.led

5

5\System\DEFAULT.Isr

16

CCV4-230428

CCV4-230428

2:Control

CMS1 230328 537M.lcm

230428255.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230328 537M.lcm

230428256.led

0

5\System\DEFAULT.Isr

1

MEOH

MEOH

0:Unknown

CMS1 230328 537M.lcm

230428257.led

0

5\System\DEFAULT.Isr

1

MEOH

MEOH

0:Unknown

CMS1 230328 537M.lcm

230428258.led

0

5\System\DEFAULT.Isr

24®

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD.Icb

-------
Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:39

ICV1-230428

Sample ID: ICV1-230428

Date Acquired: 4/29/2023 11:38:27 PM

Acquired by: System Administrator

Data File: 230428212

Vial: 11 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.205

792843

792843

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.205

792843

960889

13C7-PFUnDA IS

5.0000

7.7779

ng/mL

PFBA

Auto

4.205

178184

792843

13C-PFBA IS

1.0000

1.0052

nq/mL

13C-PFPeA IS

Auto

5.362

1100593

1100593

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.362

1100593

960889

13C7-PFUnDA IS

5.0000

6.7204

nq/mL

PFPeA

Auto

5.361

236747

1100593

13C-PFPeA IS

1.0000

1.1683

ng/mL

13C-PFBS IS

Auto

5.492

393506

393506

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.492

393506

960889

13C7-PFUnDA IS

4.6500

5.4757

ng/mL

PFBS

Auto

5.491

69802

393506

13C-PFBS IS

0.8840

1.1427

nq/mL

13C HFPO DA IS

Auto

6.091

243083

243083

	

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.091

243083

960889

13C7-PFUnDA IS

5.0000

6.8356

nq/mL

HFPO DA

Auto

6.092

42409

243083

13C HFPO DA IS

1.0000

1.1928

nq/mL

13C-4 2-FTS IS

Auto

5.893

195400

195400

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.893

195400

960889

13C7-PFUnDA IS

4.6700

6.0801

ng/mL

4-2-FtS

Auto

5.892

49875

195400

13C-4 2-FTS IS

0.9340

1.0758

nq/mL

PFHxA

Auto

5.947

446950

1555791

13C-PFHxA IS

1.0000

1.0812

ng/mL

13C-PFHxA IS

Auto

5.947

1555791

1555791

	

5.0000

5.0000

i

13C-PFHxA

Auto

5.947

1555791

960889

13C7-PFUnDA IS

5.0000

6.9920

ng/mL

PFPeS

Auto

5.988

65000

425238

180-PFHxS IS

0.9380

1.0850

nq/mL

PFHxS

Auto

6.357

53970

425238

180-PFHxS IS

0.9100

0.9986

ng/mL

13C-PFHpA IS

Auto

6.351

1477508

1477508

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.351

1477508

960889

13C7-PFUnDA IS

5.0000

6.8355

ng/mL

180-PFHxS IS

Auto

6.358

425238

425238

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.358

425238

960889

13C7-PFUnDAJS

4.7250

5.8964

ng/mL

PFHpA

Auto

6.351

486788

1477508

13C-PFHpA IS

1.0000

1.1046

ng/mL

13C2-6 2-FTS IS

Auto

6.651

175721

175721

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.651

175721

960889

13C7-PFUnDA IS

4.7500

5.2197

ng/mL

PFHpS

Auto

6.661

69815

425238

180-PFHxS IS

0.9520

1.0802

ng/mL

6-2-FTS

Auto

6.651

42922

175721

13C2-6 2-FTS IS

0.9480

1.2290

nq/mL

PFOA

Auto

6.669

534573

1836774

13C-PFOA IS

1.0000

1.0707

ng/mL

13C-PFOA IS

Auto

6.669

1836774

1836774

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.669

1836774

960889

13C7-PFUnDA IS

5.0000

6.8357

ng/mL

PFOS

Auto

6.954

47325

420331

13C-PFOS IS

0.9280

1.0809

nq/mL

13C-PFOS IS

Auto

6.954

420331

420331

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

6.954

420331

960889

13C7-PFUnDA IS

4.7750

5.8055

nq/mL

PFNA

Auto

6.974

329070

1679799

13C-PFNA IS

1.0000

0.8205

ng/mL

13C-PFNA IS

Auto

6.973

1679799

1679799

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.973

1679799

960889

13C7-PFUnDA IS

5.0000

7.0336

ng/mL

PFNS

Auto

7.278

115680

420331

13C-PFOS IS

0.9600

1.1496

nq/mL

8-2-FTS

Auto

7.302

16838

81805

13C-8 2-FTS IS

0.9580

0.8543

ng/mL

13C-8 2-FTS IS

Auto

7.303

81805

81805

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.303

81805

960889

13C7-PFUnDA IS

4.7900

5.1581

ng/mL

PFDA

Auto

7.307

363732

837

13C-PFDA IS

1.0000

1.1543

nq/mL

13C-PFDA IS

Auto

7.307

1663837

1663837

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.307

1663837

960889

13C7-PFUnDA IS

5.0000

6.1540

nq/mL

d3-N-MeFOSAA IS

Auto

7.482

602444

602444

	

5.0000

5.0000

nq/mL

d3-N-MeFOSAA

Auto

7.482

602444

960889

13C7-PFUnDA IS

5.0000

7.6421

nq/mL

NMeFOSAA

Auto

7.488

125394

602444

d3-N-MeFOSAA IS

1.0000

1.0487

nq/mL

PFDS

Auto

7.615

76628

420331

13C-PFOS IS

0.9640

1.0332

nq/mL

13C-PFUnDA IS

Auto

7.654

1547180

1547180

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.654

1547180

960889

13C7-PFUnDA IS

5.0000

6.5023

nq/mL

PFUnDA

Auto

7.654

248086

1547180

13C-PFUnDA IS

1.0000

0.8191

nq/mL

d5-N-EtFOSAA IS

Auto

7.663

695225

695225

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.663

695225

960889

13C7-PFUnDA IS

5.0000

8.2715

nq/mL

NEtFOSAA

Auto

7.671

113180

695225

dS-N-EtFOSAA IS

1.0000

0.8230

nq/mL

PFOSA

Auto

7.739

105127

417273

13C-FOSA IS

1.0000

1.1758

nq/mL

13C-FOSA IS

Auto

7.739

417273

417273

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.739

417273

960889

13C7-PFUnDA IS

5.0000

6.5974

nq/mL

PFDoA

Auto

7.995

348973

1475481

13C-PFDoA IS

1.0000

1.0586

nq/mL

13C-PFDoA IS

Auto

7.995

1475481

1475481

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

242

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Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:39

ICV1 -230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

7.995

1475481

960889

13C7-PFUnDA IS

5.0000

6.3220

nq/mL

10-2-FtS

Auto

8.006

8430

81805

13C-8 2-FTS IS

0.9640

0.4057

ng/mL

d5-NEtFOSA IS

Auto

8.775

477367

477367

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.775

477367

960889

13C7-PFUnDA IS

5.0000

7.3665

ng/mL

NMeFOSE

Auto

8.499

54085

240456

d7-N-MeFOSE IS

1.0000

1.3775

nq/mL

NEtFOSE

Auto

8.749

151343

192149

d9-EtFOSE IS

1.0000

0.7940

ng/mL

d9-EtFOSE IS

Auto

8.731

192149

192149

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.731

192149

960889

13C7-PFUnDA IS

5.0000

10.3820

ng/mL

NMeFOSA

Auto

8.522

38920

436941

d3-NMeFOSA IS

1.0000

0.9667

nq/mL

dB-NMeFOSA IS

Auto

8.518

436941

436941

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.518

436941

960889

13C7-PFUnDA IS

5.0000

7.4572

nq/mL

d7-N-MeFOSE IS

Auto

8.483

240456

240456

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.483

240456

960889

13C7-PFUnDA IS

5.0000

7.3231

nq/mL

NEtFOSA

Auto

8.784

73620

477367

d5-NEtFOSA IS

1.0000

1.0513

ng/mL

PFTrDA

Auto

8.321

231992

276667

13C-PFTeDA IS

1.0000

2.7603

nq/mL

PFTeDA

Auto

8.620

267558

276667

13C-PFTeDA IS

1.0000

2.7010

ng/mL

13C-PFTeDA IS

Auto

8.619

276667

276667

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.619

276667

960889

13C7-PFUnDA IS

5.0000

1.8022

ng/mL

11CI-PFBOUdS

Auto

7.807

114842

420331

13C-PFOS IS

0.9420

1.1924

nq/mL

9CI-PF30NS

Auto

7.134

183261

420331

13C-PFOS IS

0.9320

0.8832

ng/mL

L-PFDoS

Auto

8.273

31262

420331

13C-PFOS IS

0.9680

1.1162

nq/mL

NaDONA

Auto

6.396

407577

1679799

13C-PFNA IS

0.9420

1.1495

ng/mL

PFHxDA

Auto

9.149

42249

2872414

13C2-PFHxDA IS

1.0000

0.1468

nq/mL

PFODA

Auto

9.678

49652

2872414

13C2-PFHxDA IS

1.0000

0.3387

ng/mL

13C2-PFHxDA IS

Auto

9.149

2872414

2872414

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.149

2872414

960889

13C7-PFUnDA IS

5.0000

5.9053

ng/mL

13C7-PFUnDA IS

Auto

7.652

960889

960889

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.620

320224

420331

13C-PFOS IS

0.9200

0.8394

ng/mL

PFBSA

Auto

6.129

254680

417273

13C-FOSA IS

1.0000

1.1712

nq/mL

PFHxSA

Auto

6.955

221028

1679799

13C-PFNA IS

1.0000

1.0654

ng/mL

CHARGE

ND(W/B)

	

	

960889

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 7.7779
Q 217.20> 172.30 (-)

PFBA

Cone. 1.0052
1.78e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
3.95e4 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 6.7204
4.34e5 Q 267.90>223.00 (-)

O.OeO

O.OeO

rA= 1100593
RT= 5.362

O.OeO -

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 1.1683	Cone. 4.6500	Cone. 5.4757 Cone 1.1427

rA= 1100593
RT= 5.362

O.OeO -

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

8.29e4 ISTD 301.80>80.00 (-)

1.40e5 Q 301.80>80.00 (-)

R#1 298.80>99.00 69.08 (68.21)

1.40e5 Q 299.00>80.00 (-)	2.49e4 ISTD 332.10>287.10 (-)	9.99e4

1

A=393506
RT= 5.492

A=393506
fl"= 5.492

I R1 69.08 (

5.6

RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

'A=243083
ir=6.091

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

242

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Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:39

ICV1 -230428 (continued)

13C HFPO DA

Cone. 6.8356

Q 332.10>287.10 (-)
1.0e5 -i	Y

A=243083
'T=6.091

O.OeO -

6.0

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

: R1 2.70 (--

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)
6.0e5 -

4.0e5 :
2.0e5 :
O.OeO :

=1477508
lT=6.351

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

Y A=175721
RT=6.651

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

HFPO DA

Cone. 1.1928

R#1 329.00>285.10 80.26 (71.09)
Q 329.00>169.00 (-)	1.77e4

1.5e4
1.0e4
5.0e3
O.OeO

r A=42409

R1 80-26 (-fl-^r=6.092

6.2 6.4
RT (min)

PFHxA

Cone. 1.0812

R#1 313.00> 119.10 2.70 (2.21)
Q 313.00>269.00 (-)	1.82e5

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

YA=1

6.0e5 H	H3t=;

4.0e5 ^

2.0e5 ^

O.OeO 1 i i i

=1555791
T= 5.947

6.2
RT (min)

13C-PFHpA

Cone. 6.8355

Q 366.90>322.10 (-)
6.0e5 -
4.0e5 ^

2.0e5 ^

O.OeO 1 . . ;

1=1477508
T=6.351

6.6

RT (min)

13C2-6 2-FTS

Cone. 5.2197

7.40e4 Q 428.90>409.00 (-)

6.0e4 ~

4.0e4 i
2.0e4 i
O.OeO 1, i i

A=175721
RT=6.651

Lb

RT (min)

RT (min)

13C-PFOA

Cone. 6.8357

7.65e5 Q416.80>372.05 (-)

Y A= 1836774
RT=6.669

L

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 25.14 (25.06)

ISTD 329.00>309.15 (-)	7.90e4

J-i

A= 195400

5.0e4 :
2.5e4 :
O.OeO :

13C-4 2-FTS

Cone. 6.0801

R#1 329.00>81.00 25.14 (25.06)
Q 329.00>309.15 (-)	7.90e4

~ A= 195400

7-5e4^Rl 25.14 (-ft ^=5.893

5.0e4 -
2.5e4 -j
O.OeO :

4-2-FtS

Cone. 1.0758

R#1 327.00>81.10 14.29 (17.01)
Q 327.00>307.05 (-)	1.96e4

6.2 6.4
RT (min)

6.0 6.2
RT (min)

13C-PFHxA

Cone. 6.9920

Q 314.90>270.10 (-)
6.0e5 -
4.0e5 ^

2.0e5 ^

O.OeO

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 1.0850

R#1 349.00>99.00 87.60 (89.24)
Q 349.00>79.95 (-)	2.59e4

TA= 1555791
rt=£;q47



rA=65000

- R1 87.60 (-

-m= 5.988

: J

I

O.OeO

6.0 6.2
RT (min)

PFHxS

Cone. 0.9986

R#1 399.00 >99.00 105.11 (92.93)
Q 399.00>80.00 (-)	1.89e4

53970
T= 6.357

6.2
RT (min)

6.2
RT (min)

6.2

RT (min)

180-PFHxS IS

Cone. 4.7250

180-PFHxS

Cone. 5.8964

6.30e5 ISTD 402.70>84.05 (-)

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

f A=425238
RT=6.358



1.84e5 Q 402.70>84.05 (-)

^.SeSz_

"{.OeSz
S.0e4z_

O.OeO

6.2 6.4 6.6

RT (min)

PFHpA

Cone. 1.1046

R#1 362.90>169.00 16.52 (16.60)
Q 362.90>319.00 (-)	2.08e5

Y4=4

RT='

O.OeO -

425238
tT=6.358

~ A=486788
2-0e5 _R1 16.52 (-fl-ppr=6.351

O.OeO -

L

6.6

RT (min)

6.2

6.4

6.6
RT (min)

PFHpS

Cone. 1.0802

R#1 449.00>99.20 62.41 (55.18)
Q 449.00>80.15 (-)	2.92e4

6.2

6.4

6.6
RT (min)

6-2-FTS

Cone. 1.2290

R#1 427.00>80.90 29.48 (29.85)
Q 427.00>407.00 (-)	1.79e4

6.2

6.4

6.6
RT (min)

PFOA

Cone. 1.0707

R#1 413.00 > 169.10 30.76 (28.84)
Q 413.00>369.00 (-)	2.22e5

A= 534573
2.0e5HR1 3076 (i-rar=6.669

O.OeO

6.6 6.8

RT (min)

PFOS

Cone. 1.0809

R#1 499.00>99.00 85.27 (93.90)
Q 499.00>80.00 (-)	1.49e4

13C-PFOS IS

Cone. 4.7750



A=47325

- R1 85.27 (-

"RT=6.954

J

.

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

ISTD 502.8
1.5e5^
1.0e5^
5.0e4 ^
O.OeO 4=

105 (-)

|A=420331
RT=6.954

v ^

Q 502.8
1.5e5^
1.0e5^
5.0e4 ^
O.OeO -

105 (-)

7.2

RT (min)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

243

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A

Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:39

ICV1 -230428 (continued)

PFNA

Cone. 0.8205

R#1 463.00>219.00 25.62 (19.07)
Q 463.00>418.90 (-)	1.32e5

- R1 25.62 I

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

6.0e5 ^

4.0e5 i
2.0e5 i
O.OeO 1 . .

7.2

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 5.1581

31805
7.303

d3-N-MeFOSAAJS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 7.6421

2.29e5 Q 572.80>419.05 (-)

13C-PFUnDA

Cone. 6.5023

Q 564.80>519.95 (-)

A= 1547180
RT=7.654

O.OeO -

il



'A=2

48086

: R1 17.90

RT=7.654







7.6

7.8 8.0
RT (min)

PFOSA

Cone. 1.1758

R#1 498.20>64.10 0.01 (0.11)
Q 498.20>78.00 (-)	3.99e4

4.0e4

13C-FOSA IS

Cone. 5.0000

13C-PFNA

Cone. 7.0336

Q 467.80>423.00 (-)

is

6.0e5
4.0e5
2.0e5
O.OeO

1679799
RTl= 6.973



7.2

RT (min)

6.8

7.0

O.OeO -

7.6
RT (min)

7.2

7.4

O.OeO

7.6 7.8
RT (min)

PFUnDA

Cone. 0.8191

R#1 563.00>219.00 17.90 (12.92)
Q563.00>518.90 (-)	9.21e4

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

TA= 125394

R1 39.54 (-



Rt

=7.488

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

7.8 8.0
RT (min)

13C-FOSA

Cone. 6.5974

7.8 8.0

RT (min)

7.8 8.0

RT (min)

PFNS

Cone. 1.1496

R#1 549.00>99.00 63.75 (69.83)
Q 549.00>79.95 (-)	4.55e4

8-2-FTS

Cone. 0.8543

R#1 527.20>487.00 5.18 (6.24)
Q 527.10>506.90 (-)	6.47e3

7.2
RT (min)

PFDA

Cone. 1.1543

R#1 512.90>219.00 18.54(17.97)
Q 512.90>469.00 (-)	1.45e5

fA=363732



7A=

16838

6.0e3 -

R1 5-18 (W

7.302

4.0e3 ^





2.0e3 ^





0 0<=>0 -



* -

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)
6.0e5 ^

4.0e5 ^

2.0e51

13C-PFDA

Cone. 6.1540

A=1663837
RTf 7.307

O.OeO -



7.6
RT (min)

NMeFOSAA

Cone. 1.0487

R#1 570.20>512.00 39.54(38.98)
Q 570.20>419.00 (-)	3.84e4

7.2

7.4

7.6
RT (min)

PFDS

Cone. 1.0332

R#1 599.00>99.00 56.21 (59.45)
Q 599.00>80.10 (-)	2.99e4

f A=76628

;R1 56.21 Y RT=7.615

13C-PFUnDA IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

O.OeO -

A= 1547180
RT=7.654

U

7.6

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 8.2715

2.43e5 Q 588.80>419.00 (-)

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.8230

R#1 584.20>526.10 63.69 (51.48)
Q 584.20>418.95 (-)	3.85e4

A=113180

7.8 8.0
RT (min)

O.OeO

7.8 8.0
RT (min)

PFDoA

Cone. 1.0586

R#1 613.05> 169.00 17.25 (17.39)
Q 613.05>569.00 (-)	1.32e5

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

5.57e5

- R1 17.25

i(RT^

7.995





-~

7.8 8.0

RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

24S

-------


Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:39

ICV1 -230428 (continued)

13C-PFDoA

Cone. 6.3220

Q614.80>569.95 (-)

A= 1475481
RT=7.995

NEtFOSE

Cone. 0.7940

Q 629.50>59.10 (-)

d3-NMeFOSA

Cone. 7.4572

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

1.0e5-

O.OeO -

A=267558

R1 14.8E RT=8.620

10-2-FtS

Cone. 0.4057

R#1 626.50>81.05 163.87 (57.89)
Q 626.50>607.05 (-)	3.23e3

:R1A=8430 f
4.0e3 - RT=8.006

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 7.3665

1.86e5 Q 531.10> 169.10 (-)

A=477367
RT=8.775

RT (min)

d9-EtFOSE IS

Cone. 5.0000

5.90e4 ISTD 638.90> 59.10 (-)

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

RT (min)

7.67e4 Q 638.90> 59.10 (-)

6.0e4 ~

4.0e4 ~

2.0e4 ~
— O.OeO 1 . . .

O.OeO -

9.0
RT (min)

9.0
RT (min)

9.0
RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 7.3231

1,72e5 I STD 623.00 > 59.00 (-)

7.5e4 :
5.0e4 :
2.5e4 :
O.OeO :

9.41 e4 Q 623.00> 59.00 (-)

7.5e4 i
5.0e4 i
2.5e4 i
— O.OeO 1, i i i

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 2.7010

R#1 713.00 >169.30 14.88 (10.00)
Q 713.00>668.90 (-)	1.00e5

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)
1.0e5

13C-PFTeDA

Cone. 1.8022

11CI-PF30UdS

Cone. 1.1924

Q 714.80>669.80 (-)

1.05e5 Q 631.00>451.10 (-)

8.6

.8 9.0
RT (min)

L-PFDoS

Cone. 1.1162
R#1 698.80>98.80 62.76 (75.26)

Q 698.80>80.10 (-)	1.26e4 Q 377.10>251.20 (-)

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

1.81e5 Q 812.90>769.00 (-)

1.81e4 Q 912.80>869.00 (-)

407577
tT=6.396

L

1.5e4-
1.0e4:
5.0e3 :
O.OeO :

A=42249
RT=9149

8.4 8.6
RT (min)

6.6

RT (min)

9.2 9.4

RT (min)

NMeFOSE

Cone. 1.3775

Q 616.10>58.90 (-)
2.0e4 -

9.0
RT (min)

NMeFOSA

Cone. 0.9667

R#1 512.10>219.20 89.44(76.68)
Q 512.10> 169.20 (-)	1.47e4

A=38920

I R1 89.44 (-¦)) rt=8.522

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4-
O.OeO -

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 1.0513

R#1 526.50>219.20 60.22 (65.87)
Q 526.50>169.10 (-)	2.92e4

I R1 60.22 (-

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 2.7603

R#1 663.10> 169.10 30.25 (18.12)
Q 663.10>618.90 (-)	8.88e4

7.5e4
5.0e4:
2.5e4:
O.OeO :

r A=231992

R1 30-2! I(rt4321

9.0

RT (min)

8.6

RT (min)

9CI-PF30NS

Cone. 0.8832

4.55e4 Q 531.00>351.10 (-)

RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

1,72e4 I STD 815.00 > 770.00 (-)

A=2872414
RT=9149



9.0 9.2 9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

246

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Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:39

ICV1 -230428 (continued)

13C2-PFHxDA

Cone. 5.9053

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

1,20e6 ISTD 569.80> 524.90 (-)

PFBSA

Cone. 1.1712

TA=2

RT='

2872414
9149

O.OeO -

L

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	1.00e0

5.0e0 -

0.2
RT (min)

PFecHS

Cone. 0.8394
R#1 461.00>99.10 40.81 (38.19)

3.55e5 Q 461.00>381.00 (-)	1.28e5 Q 298.00>78.00 (-)

fA=320224

;R1 40.81 ("TRfT=6.620

RT (min)

PFHxSA

Cone. 1.0654

9.87e4 Q 397.90>78.00 (-)

7.5e4 ^

S.0e4z_

2.5e4z_
— O.OeO 4~ 7- . ~r

6.2 6.4
RT (min)

7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

24B

-------
Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:48

CCV1 -230428-WI

Sample ID: CCV1-230428-WI

Date Acquired: 4/30/2023 12:19:42 AM

Acquired by: System Administrator

Data File: 230428215

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.203

716992

716992

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.203

716992

1212553

13C7-PFUnDA IS

5.0000

5.5739

ng/mL

PFBA

Auto

4.203

15064

716992

13C-PFBA IS

0.1000

0.0940

nq/mL

13C-PFPeA IS

Auto

5.357

1093873

1093873

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.357

1093873

1212553

13C7-PFUnDA IS

5.0000

5.2930

nq/mL

PFPeA

Auto

5.358

19511

1093873

13C-PFPeA IS

0.1000

0.0969

ng/mL

13C-PFBS IS

Auto

5.488

414271

414271

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.488

414271

1212553

13C7-PFUnDA IS

4.6500

4.5682

ng/mL

PFBS

Auto

5.490

6042

414271

13C-PFBS IS

0.0880

0.0940

nq/mL

13C HFPO DA IS

Auto

6.086

255465

255465

	

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.086

255465

1212553

13C7-PFUnDA IS

5.0000

5.6928

nq/mL

HFPO DA

Auto

6.087

3668

255465

13C HFPO DA IS

0.1000

0.0982

nq/mL

13C-4 2-FTS IS

Auto

5.887

184146

184146

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.887

184146

1212553

13C7-PFUnDA IS

4.6700

4.5407

ng/mL

4-2-FtS

Auto

5.887

4107

184146

13C-4 2-FTS IS

0.0930

0.0940

nq/mL

PFHxA

Auto

5.942

38423

1456638

13C-PFHxA IS

0.1000

0.0993

ng/mL

13C-PFHxA IS

Auto

5.941

1456638

1456638

	

5.0000

5.0000

i

13C-PFHxA

Auto

5.941

1456638

1212553

13C7-PFUnDA IS

5.0000

5.1877

ng/mL

PFPeS

M

5.985

6122

433645

180-PFHxS IS

0.0940

0.1002

nq/mL

PFHxS

Auto

6.353

4910

433645

180-PFHxS IS

0.0910

0.0891

ng/mL

13C-PFHpA IS

Auto

6.346

1444766

1444766

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.346

1444766

1212553

13C7-PFUnDA IS

5.0000

5.2967

ng/mL

180-PFHxS IS

Auto

6.353

433645

433645

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.353

433645

1212553

13C7-PFUnDAJS

4.7250

4.7650

ng/mL

PFHpA

Auto

6.346

42314

1444766

13C-PFHpA IS

0.1000

0.0982

ng/mL

13C2-6 2-FTS IS

Auto

6.646

177291

177291

	

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.646

177291

1212553

13C7-PFUnDA IS

4.7500

4.1733

ng/mL

PFHpS

Auto

6.657

5909

433645

180-PFHxS IS

0.0950

0.0896

ng/mL

6-2-FTS

M

6.647

2990

177291

13C2-6 2-FTS IS

0.0950

0.0849

nq/mL

PFOA

Auto

6.663

49592

1832339

13C-PFOA IS

0.1000

0.0996

ng/mL

13C-PFOA IS

Auto

D.DDD

1832339

1832339

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.663

1832339

1212553

13C7-PFUnDA IS

5.0000

5.4038

ng/mL

PFOS

Auto

6.953

4229

422355

13C-PFOS IS

0.0930

0.0961

nq/mL

13C-PFOS IS

Auto

6.950

422355

422355

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

6.950

422355

1212553

13C7-PFUnDA IS

4.7750

4.6227

nq/mL

PFNA

Auto

6.969

31933

1663198

13C-PFNA IS

0.1000

0.0804

ng/mL

13C-PFNA IS

Auto

6.970

1663198

1663198

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.970

1663198

1212553

13C7-PFUnDA IS

5.0000

5.5187

ng/mL

PFNS

Auto

7.276

9825

422355

13C-PFOS IS

0.0960

0.0972

nq/mL

8-2-FTS

Auto

7.294

1448

94529

13C-8 2-FTS IS

0.0960

0.0819

ng/mL

13C-8 2-FTS IS

Auto

7.301

94529

94529

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.301

94529

1212553

13C7-PFUnDA IS

4.7900

4.7233

ng/mL

PFDA

Auto

7.305

32230

1748150

13C-PFDA IS

0.1000

0.0974

nq/mL

13C-PFDA IS

Auto

7.304

1748150

1748150

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.304

1748150

1212553

13C7-PFUnDA IS

5.0000

5.1239

nq/mL

d3-N-MeFOSAA IS

Auto

7.478

587906

587906

	

5.0000

5.0000

nq/mL

d3-N-MeFOSAA

Auto

7.478

587906

1212553

13C7-PFUnDA IS

5.0000

5.9099

nq/mL

NMeFOSAA

M

7.484

11912

587906

d3-N-MeFOSAA IS

0.1000

0.1021

nq/mL

PFDS

M

7.613

6821

422355

13C-PFOS IS

0.0960

0.0915

nq/mL

13C-PFUnDA IS

Auto

7.649

1666243

1666243

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.649

1666243

1212553

13C7-PFUnDA IS

5.0000

5.5493

nq/mL

PFUnDA

Auto

7.651

29031

1666243

13C-PFUnDA IS

0.1000

0.0890

nq/mL

d5-N-EtFOSAA IS

Auto

7.660

674256

674256

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.660

674256

1212553

13C7-PFUnDA IS

5.0000

6.3571

nq/mL

NEtFOSAA

M

7.668

11613

674256

dS-N-EtFOSAA IS

0.1000

0.0871

nq/mL

PFOSA

Auto

7.736

8273

456325

13C-FOSA IS

0.1000

0.0846

nq/mL

13C-FOSA IS

Auto

7.736

456325

456325

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.736

456325

1212553

13C7-PFUnDA IS

5.0000

5.7174

nq/mL

PFDoA

Auto

7.991

37203

1679510

13C-PFDoA IS

0.1000

0.0991

nq/mL

13C-PFDoA IS

Auto

7.991

1679510

1679510

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

248

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Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:48

CCV1 -230428-WI (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

7.991

1679510

1212553

13C7-PFUnDA IS

5.0000

5.7026

nq/mL

10-2-FtS

Auto

7.993

1332

94529

13C-8 2-FTS IS

0.0960

0.0555

ng/mL

d5-NEtFOSA IS

Auto

8.770

505309

505309

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.770

505309

1212553

13C7-PFUnDA IS

5.0000

6.1793

ng/mL

NMeFOSE

Auto

8.493

4542

297480

d7-N-MeFOSE IS

0.1000

0.0935

nq/mL

NEtFOSE

Auto

8.745

17054

195977

d9-EtFOSE IS

0.1000

0.0877

ng/mL

d9-EtFOSE IS

Auto

8.726

195977

195977

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.726

195977

1212553

13C7-PFUnDA IS

5.0000

8.3912

ng/mL

NMeFOSA

Auto

8.519

4020

476024

d3-NMeFOSA IS

0.1000

0.0917

nq/mL

dB-NMeFOSA IS

Auto

8.513

476024

476024

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.513

476024

1212553

13C7-PFUnDA IS

5.0000

6.4380

nq/mL

d7-N-MeFOSE IS

Auto

8.479

297480

297480

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.479

297480

1212553

13C7-PFUnDA IS

5.0000

7.1794

nq/mL

NEtFOSA

Auto

8.780

6538

505309

d5-NEtFOSA IS

0.1000

0.0882

ng/mL

PFTrDA

Auto

8.317

24377

713906

13C-PFTeDA IS

0.1000

0.1124

nq/mL

PFTeDA

Auto

8.616

29095

713906

13C-PFTeDA IS

0.1000

0.1138

ng/mL

13C-PFTeDA IS

Auto

8.615

713906

713906

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.615

713906

1212553

13C7-PFUnDA IS

5.0000

3.6851

ng/mL

11CI-PFBOUdS

Auto

7.806

10745

422355

13C-PFOS IS

0.0940

0.1110

nq/mL

9CI-PF30NS

Auto

7.131

18905

422355

13C-PFOS IS

0.0930

0.0907

ng/mL

L-PFDoS

Auto

8.271

2536

422355

13C-PFOS IS

0.0970

0.0901

nq/mL

NaDONA

Auto

6.391

30011

1663198

13C-PFNA IS

0.0940

0.0855

ng/mL

PFHxDA

Auto

9.145

21739

3075134

13C2-PFHxDA IS

0.1000

0.0486

nq/mL

PFODA

Auto

9.677

11494

3075134

13C2-PFHxDA IS

0.1000

0.0732

ng/mL

13C2-PFHxDA IS

Auto

9.146

3075134

3075134

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.146

3075134

1212553

13C7-PFUnDA IS

5.0000

5.0100

ng/mL

13C7-PFUnDA IS

Auto

7.649

1212553

1212553

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.614

34071

422355

13C-PFOS IS

0.0920

0.0889

ng/mL

PFBSA

Auto

6.124

24364

456325

13C-FOSA IS

0.1000

0.1025

nq/mL

PFHxSA

Auto

6.951

20979

1663198

13C-PFNA IS

0.1000

0.1021

ng/mL

CHARGE

ND(W/B)

	

	

1212553

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 5.5739
1.56e5 Q 217.20>172.30 (-)

PFBA

Cone. 0.0940
1.56e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
3.68e3 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 5.2930
4.20e5 Q 267.90>223.00 (-)

4.0e5 -

fA= 1093873
RT= 5.357

O.OeO

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 0.0969

O.OeO -

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

4.0e5 -

~ A= 1093873
RT= 5.357

O.OeO -

1

5.2

5.4

Q263.05>219.10 (-)

7.15e3 ISTD 301.80>80.00 (-)

4.00 4.25 4.50

RT (min)

13C-PFBS	PFBS

Cone. 4.5682	Cone. 0.0940

R#1 298.80>99.00 46.35 (68.21)

1.46e5 Q 301.80>80.00 (-)	1.46e5 Q 299.00>80.00 (-)	2.22e3 ISTD 332.10>287.10 (-)

5.6

RT (min)

13C HFPO DA IS

Cone. 5.0000

6.0e3
4.0e3
2.0e3
O.OeO

|=255465
T=6.086

5.4 5.6

RT (min)

1.0e5 -
5.0e4 -j
O.OeO :

A=414271
fl"= 5.488

5.6 5.8
RT (min)

1"= 5.488

5.6 5.8
RT (min)

6.2 6.4
RT (min)

5.8
RT (min)

O.OeO

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

248

-------
*

Insight Report



Quantitation/lntegration

(AILS)

Printed 11/2/2023 08:36:48

CCV1 -230428-WI (continued)

13C HFPO DA

Cone. 5.6928

Q 332.10>287.10 (-)	1.05e5

f A=255465
1.°e5H	'|3r=6.086

O.OeO -

6.0

k:

1444766
6.346

4.0e5 -

2.0e5 ^
O.OeO -

13C2-6_2-FTSJS

Cone. 4.7500

ISTD 428.90>409.00 (-)

t A=177291
I r|=6.646

6.0e4 -
4.0e4
2.0o4 :
O.OeO :

13C-PFOAJS

Cone. 5.0000

ISTD 416.80>372.05 (-)

~ A= 1832339
'l r|=6.663

6.0e5 -
4.0e5 ^
2.0e5 ^
O.OeO --

HFPO_DA

Cone. 0.0982

R#1 329.00>285.10 86.78 (71.09)

Q 329.00 		1.48e3

TA=3668
pit=6.087

6.2 6.4

RT (min)

PFHxA

Cone. 0.0993

R#1 313.00>119.10 2.42 (2.21)
Q 313.00>269.00 (-)	1.65e4

~ A=38423

1.5e4-f	|| p{t=5 942

1.0e4 ^

5.0e3 ^

O.OeO 4= : ,

5.8 6.0 6.2

RT (min)

13C-PFHpA_IS

Cone. 5.0000

ISTD 366.90>322.10 (-)	6.03e5

6.0e5 i

13C-PFHxAJS

Cone. 5.0000

ISTD 314.90>270.10 (-)

~ A= 1456638
r}t=5.941

13C-PFHpA

Cone. 5.2967

fA= 1444766
I rIt=6.346

6.6

RT (min)

4.0e5 -

2.0e5 ^
O.OeO -

13C2-6_2-FTS

Cone. 4.1733

7.51e4 Q 428.90>409.00 (-)

6.0e4 i
4.0e4 i
2.0e4 i
O.OeO 4=

|T A= 177291
1 r|=6.646

RT (min)

13C-PFOA

Cone. 5.4038

7.62e5 Q 416.80>372.05 (-)

^A= 1832339
| r|=6.663

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO -

6.8 7.0
RT (min)

13C-4_2-FTSJS

Cone. 4.6700

R#1 329.00>81.00 27.88 (25.06)

ISTD 329 mm lc i-)	7.07e4 Q 329.0'

13C-4_2-FTS

Cone. 4.5407

R#1 329.00>81.00 27.88 (25.06)

39.15 f

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

~ ^=184146
= 5.887



6.2 6.4
RT (min)

6.2
RT (min)

Q 366.90>322.10 (-)	6.03e5

6.0e5 i

180-PFHxSJS

Cone. 4.7250

ISTD 402.70>84.05 (-)

1.5e5 i
1.0e5i
5.0e4 i
O.OeO 4=

f A=4.3.3645
1 Rh"=6.353

6.4 6.6

RT (min)

6.2

6.4

RT (min)

O.OeO -

A=ai

pfr=7.149

6.8 7.0
RT (min)

6.0e4-
4.0e4i
2.0e4i
O.OeO -

YA=184146
' Wt = 5.887

5.8 6.0 6.2
RT (min)
13C-PFHxA

Cone. 5.1877

Q 314.90>270.10 (-)	5.78e5

~ A= 1456638

T= 5.941

4.0e5 -

6.2
RT (min)

180-PFHxS

Cone. 4.7650

1.85e5 Q 402.70>84.05 (-)

1.5e5 i
1.0e5i
5.0e4i

O.OeO 4^

TA=433645

| RjT=6.353

6.6
RT (min)

PFHpS

Cone. 0.0896

R#1 449.00>99.20 52.76 (55.18)
Q 449.00>80.15 (-)	2.48e3

6.2

6.4

6.6 6.8

RT (min)
PFOS

Cone. 0.0961

R#1 499.00>99.00 87.32 (93.90)
Q 499.0C	1.10e3

TA=4229
1.0e3 -	fir=6.953

13C-PFOSJS

Cone. 4.7750

ISTD 502.80>80.05 (-)

6.75 7.00 7.25

RT (min)

1.5e5 -

1.0e5 ^
5.0e4^
O.OeO -

fA=422355

I RT=6.950

4-2-FtS

Cone. 0.0940

R#1 327.00>81.10 7.24 (17.01)

7.07e4 Q 327.0"

1.5e3i
1.0e3 i
5.0e2 i
O.OeO 4

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 0.1002

R#1 349.00>99.00 71.57 (89.24)
Q349.00>79.95 (-)	2.69e3

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.0891

R#1 399.00>99.00 91.79 (92.93)
Q 399.00>80.00 (-)	1.80e3

yA=4910
01 l\ f[t=6.353

6.6

RT (min)

PFHpA

Cone. 0.0982

R#1 362.90>169.00 15.51 (16.60)

Q 362.90>319.00 (-)	1.83e4

1.5e4-
1.0e4i
5.0e3 i
O.OeO -

~ ^=42314

"j R|r=6 346

6.6
RT (min)

6-2-FTS

Cone. 0.0849

R#1 427.00>80.90 22.69 (29.85)
Q427.00>407.00 M	1.12e3

6.2

6.4

6.6
RT (min)

PFOA

Cone. 0.0996

R#1 413.00>169.10 24.33 (28.84)

Q 413.00>369.00 (-)	2.06e4

2.0e4 -

Y A=49592
'"m Rt=6 663

RT (min)

6.8 7.0
RT (min)

13C-PFOS

Cone. 4.6227

1.70e5 Q 502.80>80.05 (-)

1.5e5 ^

1.0e5 ^

5.0e4 ^

O.OeO 4"—

7.2

RT (min)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

230

-------
)

Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:48

CCV1 -230428-WI (continued)

PFNA

Cone. 0.0804

R#1 463.00>219.00 19.94 (19.07)
Q 463.00>418.90 (-)	1.28e4

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 5.5187

6.79e5 Q 467.80>423.00 (-)

7.2

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 4.7233

3.70e4 Q 528.80> 509.00 (-)

d3-N-MeFOSAAJS

Cone. 5.0000

ISTD 572.80>419.05 (-)
2.0e5 -

1.0e5 -

13C-PFUnDA

Cone. 5.5493

Q 564.80>519.95 (-)
6.0e5 H

d3-N-MeFOSAA

Cone. 5.9099

Q 572.80>419.05 (-)

2.0e5

1.0e5

O.OeO

7.4 7.6 7.E

RT (min)

PFUnDA

Cone. 0.0890

R#1 563.00>219.00 11.33 (12.92)
Q563.00>518.90 (-)	1.10e4

fA=29031
1.0e4 —|R1 11-3. |(rt^.651

7.8 8.0
RT (min)

PFOSA

Cone. 0.0846

R#1 498.20>64.10 0.00 (0.11)
Q 498.20>78.00 (-)	3.45e3

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

7.8 8.0

RT (min)

R1 28.85 (-



p:

1912
=7.484

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

8.0
RT (min)

13C-FOSA

Cone. 5.7174

1.80e5 Q 506.00>78.05 (-)

7.8 8.0

RT (min)

PFNS

Cone. 0.0972

R#1 549.00 >99.00 59.97 (69.83)
Q 549.00>79.95 (-)	3.75e3

= R1 59.97

•RTj= 7.276

6.0e2

-

|

4.0e2



I 1

2.0e2





— O.OeO

8-2-FTS

Cone. 0.0819

R#1 527.20>487.00 11.27 (6.24)
Q 527.10>506.90 (-)	6.73e2

'448
7.294

7.2
RT (min)

PFDA

Cone. 0.0974

R#1 512.90>219.00 17.21 (17.97)
Q 512.90>469.00 (-)	1.33e4

fA=32230
-R1 17.21 i-RT47.305

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 5.1239

ISTD 514.80>469.95 (-)

6.94e5 Q 514.80>469.95 (-)

f A= 1748150
RT^ 7.304

O.OeO

7.6
RT (min)

NMeFOSAA

Cone. 0.1021

R#1 570.20>512.00 28.85 (38.98)
Q 570.20>419.00 (-)	3.75e3



7.2

7.4

7.6
RT (min)

PFDS

Cone. 0.0915

R#1 599.00>99.00 56.62 (59.45)
Q 599.00>80.10 (-)	2.48e3

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 6.3571

2.48e5 Q 588.80>419.00 (-)

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.0871

R#1 584.20>526.10 51.14 (51.48)
Q 584.20>418.95 (-)	3.39e3

O.OeO -

7.6

7.8 8.0
RT (min)
PFDoA

Cone. 0.0991

R#1 613.05> 169.00 16.02 (17.39)
1.80e5 Q 613.05>569.00 (-)	1.43e4

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

8.0
RT (min)

ISTD 614.80>569.95 (-)
6.0e5 -

6.30e5

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

25ffi

-------


Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:48

CCV1 -230428-WI (continued)

13C-PFDoA

Cone. 5.7026

Q614.80>569.95 (-)
6.0e5 -

10-2-FtS

Cone. 0.0555

R#1 626.50>81.05 49.10 (57.89)
Q 626.50>607.05 (-)	6.08e2

RT (min)

NEtFOSE

Cone. 0.0877

d3-NMeFOSA

Cone. 6.4380

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

O.OeO -



fA=29095



"RT^8 616

I

L

	-	

V

d9-EtFOSE IS

Cone. 5.0000

6.46e3 ISTD 638.90> 59.10 (-)

d7-N-MeFOSE IS

Cone. 5.0000

1,86e5 I STD 623.00 > 59.00 (-)

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 0.1138

R#1 713.00>169.30 8.55 (10.00)
Q 713.00>668.90 (-)	1.08e4

13C-PFTeDA IS

Cone. 5.0000

I STD 714.80 >669.80 (-)

8.6 8.8 9.0
RT (min)

L-PFDoS

Cone. 0.0901

R#1 698.80>98.80 102.69 (75.26)
Q 698.80>80.10 (-)	1.02e3

I.0e3 Hri io;

NaDONA

Cone. 0.0855

Q 377.10>251.20 (-)

A=30011
RT=6.391



B.2 8.4 8.6

RT (min)

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 6.1793

1.96e5 Q 531.10> 169.10 (-)

A= 505309
RT=8.770



O.OeO

NMeFOSE

Cone. 0.0935

1.96e5 Q 616.10>58.90 (-)
2.0e3 H

O.OeO

RT (min)

d9-EtFOSE

Cone. 8.3912

7.42e4 Q 638.90> 59.10 (-)

6.0e4 i
4.0e4 ~

2.0e4 ~
— O.OeO I,,,

9.0	8.6 8.8 9.0

RT (min)	RT (min)

NMeFOSA

Cone. 0.0917
R#1 512.10>219.20 64.85 (76.68)

7.42e4 Q 512.10 > 169.20 (-)	1,72e3 I STD 515.10 > 169.00 (-)

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

9.0
RT (min)

d7-N-MeFOSE

Cone. 7.1794

1.19e5 Q 623.00> 59.00 (-)

RT (min)

13C-PFTeDA

Cone. 3.6851

2.66e5 Q 714.80>669.80 (-)

A=713906
RT=8 615

9.0
RT (min)

PFHxDA

Cone. 0.0486

6.2 6.4 6.6

RT (min)

1.31e4 Q 812.90>769.00 (-)

7.5e3 ^

5.0e3 ^

2.5e3 i
: O.OeO 4=

V,

1.0e3-
5.0e2 :
O.OeO :



| A=4020

: R1 64.85 (-



: ^ /

L

9.0
RT (min)

1.19e5 Q 526.50> 169.10 (-)

RT (min)

2.66e5 Q 631.00>451.10 (-)
RTH

3.0e3 :

2.0e3 :

1.0e3:

O.OeO :

0745
7.806

9.0
RT (min)

PFODA

Cone. 0.0732

9.27e3 Q 912.80>869.00 (-)

'A= 11494
RT=9.677

9.4

RT (min)

1.5e5-
1.0e5-
5.0e4-
O.OeO -

A=476024
RT=8.513

L

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0882

R#1 526.50>219.20 74.20 (65.87)

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.1124

R#1 663.10> 169.10 26.67 (18.12)

2.32e3 Q 663.10>618.90 (-)

8.77e3

3.88e3 Q 531.00>351.10 (-)

7.5e3 :
5.0e3 :
2.5e3 :
O.OeO :

~ A= 18905
Rl>7.131

RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

4.25e3 I STD 815.00 > 770.00 (-)

A=3075134
RT=9146

u

9.4

RT (min)

O.OeO

8.6

7.5e3
5.0e3
2.5e3
O.OeO

9.0

RT (min)

8.6

RT (min)

11CI-PF30UdS

Cone. 0.1110

9CI-PF30NS

Cone. 0.0907

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

252

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Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:48

CCV1 -230428-WI (continued)

13C2-PFHxDA

Cone. 5.0100

Q 815.00>770.00 (-)

O.OeO



^A=3075134



RT=9

146

:	L



13C7-PFUnDA_IS

Cone. 5.0000

1,29e6 ISTD 569.80> 524.90 (-)
4.0e5 -

2.0e5 -

9.0 9.2

9.4
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

PFecHS	PFBSA

Cone. 0.0889	Cone. 0.1025
R#1 461.00>99.10 35.34 (38.19)

4.44e5 Q 461.00>381.00 (-)	1.39e4	Q 298.00>78.00 (-)

fA=34071

IR1 35.34 (4#=6.614	=

PFHxSA

Cone. 0.1021

6.4 6.6 6.8

RT (min)

7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

252

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Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:44

ICV1-230428

Sample ID: ICV1-230428

Date Acquired: 4/29/2023 11:52:15 PM

Acquired by: System Administrator

Data File: 230428213

Vial: 11 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.205

763628

763628

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.205

763628

1232352

13C7-PFUnDA IS

5.0000

5.8411

ng/mL

PFBA

Auto

4.205

184127

763628

13C-PFBA IS

1.0000

1.0785

nq/mL

13C-PFPeA IS

Auto

5.361

1134096

1134096

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.361

1134096

1232352

13C7-PFUnDA IS

5.0000

5.3995

nq/mL

PFPeA

Auto

5.361

247203

1134096

13C-PFPeA IS

1.0000

1.1839

ng/mL

13C-PFBS IS

Auto

5.492

429733

429733

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.492

429733

1232352

13C7-PFUnDA IS

4.6500

4.6625

ng/mL

PFBS

Auto

5.492

69858

429733

13C-PFBS IS

0.8840

1.0472

nq/mL

13C HFPO DA IS

Auto

6.092

257247

257247

	

5.0000

5.0000

ng/mL

13C HFPO DA

Auto

6.092

257247

1232352

13C7-PFUnDA IS

5.0000

5.6404

nq/mL

HFPO DA

Auto

6.092

44663

257247

13C HFPO DA IS

1.0000

1.1870

nq/mL

13C-4 2-FTS IS

Auto

5.893

189599

189599

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.893

189599

1232352

13C7-PFUnDA IS

4.6700

4.6000

ng/mL

4-2-FtS

Auto

5.892

49044

189599

13C-4 2-FTS IS

0.9340

1.0902

nq/mL

PFHxA

Auto

5.948

454716

1554827

13C-PFHxA IS

1.0000

1.1007

ng/mL

13C-PFHxA IS

Auto

5.947

1554827

1554827

	

5.0000

5.0000

i

13C-PFHxA

Auto

5.947

1554827

1232352

13C7-PFUnDA IS

5.0000

5.4484

ng/mL

PFPeS

Auto

5.989

68616

456492

180-PFHxS IS

0.9380

1.0669

nq/mL

PFHxS

Auto

6.359

55224

456492

180-PFHxS IS

0.9100

0.9519

ng/mL

13C-PFHpA IS

Auto

6.352

1528640

1528640

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.352

1528640

1232352

13C7-PFUnDA IS

5.0000

5.5142

ng/mL

180-PFHxS IS

Auto

6.359

456492

456492

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.359

456492

1232352

13C7-PFUnDAJS

4.7250

4.9354

ng/mL

PFHpA

Auto

6.353

502631

1528640

13C-PFHpA IS

1.0000

1.1024

ng/mL

13C2-6 2-FTS IS

Auto

6.652

183289

183289

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.652

183289

1232352

13C7-PFUnDA IS

4.7500

4.2452

ng/mL

PFHpS

Auto

6.662

62150

456492

180-PFHxS IS

0.9520

0.8958

ng/mL

6-2-FTS

Auto

6.652

44084

183289

13C2-6 2-FTS IS

0.9480

1.2102

nq/mL

PFOA

Auto

6.670

542493

1821960

13C-PFOA IS

1.0000

1.0954

ng/mL

13C-PFOA IS

Auto

6.670

1821960

1821960

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.670

1821960

1232352

13C7-PFUnDA IS

5.0000

5.2869

ng/mL

PFOS

Auto

6.957

46808

441681

13C-PFOS IS

0.9280

1.0174

nq/mL

13C-PFOS IS

Auto

6.957

441681

441681

	

4.7750

4.7750

ng/mL

13C-PFOS

Auto

6.957

441681

1232352

13C7-PFUnDA IS

4.7750

4.7566

nq/mL

PFNA

Auto

6.976

377999

1748301

13C-PFNA IS

1.0000

0.9055

ng/mL

13C-PFNA IS

Auto

6.976

1748301

1748301

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.976

1748301

1232352

13C7-PFUnDA IS

5.0000

5.7079

ng/mL

PFNS

Auto

7.280

110964

441681

13C-PFOS IS

0.9600

1.0494

nq/mL

8-2-FTS

Auto

7.305

19953

93733

13C-8 2-FTS IS

0.9580

0.8831

ng/mL

13C-8 2-FTS IS

Auto

7.304

93733

93733

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.304

93733

1232352

13C7-PFUnDA IS

4.7900

4.6083

ng/mL

PFDA

Auto

7.309

387489

1780473

13C-PFDA IS

1.0000

1.1492

nq/mL

13C-PFDA IS

Auto

7.309

1780473

1780473

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.309

1780473

1232352

13C7-PFUnDA IS

5.0000

5.1348

nq/mL

d3-N-MeFOSAA IS

Auto

7.484

613316

613316

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.484

613316

1232352

13C7-PFUnDA IS

5.0000

6.0663

nq/mL

NMeFOSAA

Auto

7.488

132814

613316

d3-N-MeFOSAA IS

1.0000

1.0911

nq/mL

PFDS

Auto

7.616

78479

441681

13C-PFOS IS

0.9640

1.0070

nq/mL

13C-PFUnDA IS

Auto

7.655

1679883

1679883

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.655

1679883

1232352

13C7-PFUnDA IS

5.0000

5.5049

nq/mL

PFUnDA

Auto

7.655

302510

1679883

13C-PFUnDA IS

1.0000

0.9199

nq/mL

d5-N-EtFOSAA IS

Auto

7.666

702058

702058

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.666

702058

1232352

13C7-PFUnDA IS

5.0000

6.5128

nq/mL

NEtFOSAA

Auto

7.673

114491

702058

dS-N-EtFOSAA IS

1.0000

0.8244

nq/mL

PFOSA

Auto

7.741

102715

442011

13C-FOSA IS

1.0000

1.0845

nq/mL

13C-FOSA IS

Auto

7.741

442011

442011

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.741

442011

1232352

13C7-PFUnDA IS

5.0000

5.4491

nq/mL

PFDoA

Auto

7.997

367475

1693753

13C-PFDoA IS

1.0000

0.9711

nq/mL

13C-PFDoA IS

Auto

7.997

1693753

1693753

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

258

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)

Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:44

ICV1 -230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

7.997

1693753

1232352

13C7-PFUnDA IS

5.0000

5.6586

nq/mL

10-2-FtS

Auto

8.010

18586

93733

13C-8 2-FTS IS

0.9640

0.7806

ng/mL

d5-NEtFOSA IS

Auto

8.777

484837

484837

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.777

484837

1232352

13C7-PFUnDA IS

5.0000

5.8337

ng/mL

NMeFOSE

Auto

8.501

53392

275965

d7-N-MeFOSE IS

1.0000

1.1849

nq/mL

NEtFOSE

Auto

8.751

153609

181817

d9-EtFOSE IS

1.0000

0.8516

ng/mL

d9-EtFOSE IS

Auto

8.733

181817

181817

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.733

181817

1232352

13C7-PFUnDA IS

5.0000

7.6598

ng/mL

NMeFOSA

Auto

8.525

42684

435717

d3-NMeFOSA IS

1.0000

1.0632

nq/mL

dB-NMeFOSA IS

Auto

8.520

435717

435717

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.520

435717

1232352

13C7-PFUnDA IS

5.0000

5.7982

nq/mL

d7-N-MeFOSE IS

Auto

8.486

275965

275965

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.486

275965

1232352

13C7-PFUnDA IS

5.0000

6.5531

nq/mL

NEtFOSA

Auto

8.787

75453

484837

d5-NEtFOSA IS

1.0000

1.0608

ng/mL

PFTrDA

Auto

8.323

295666

677142

13C-PFTeDA IS

1.0000

1.4374

nq/mL

PFTeDA

Auto

8.622

324037

677142

13C-PFTeDA IS

1.0000

1.3365

ng/mL

13C-PFTeDA IS

Auto

8.623

677142

677142

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.623

677142

1232352

13C7-PFUnDA IS

5.0000

3.4392

ng/mL

11CI-PFBOUdS

Auto

7.809

117401

441681

13C-PFOS IS

0.9420

1.1601

nq/mL

9CI-PF30NS

Auto

7.136

215011

441681

13C-PFOS IS

0.9320

0.9861

ng/mL

L-PFDoS

Auto

8.276

33222

441681

13C-PFOS IS

0.9680

1.1289

nq/mL

NaDONA

Auto

6.397

382341

1748301

13C-PFNA IS

0.9420

1.0361

ng/mL

PFHxDA

Auto

9.149

145170

3156554

13C2-PFHxDA IS

1.0000

0.5487

nq/mL

PFODA

Auto

9.680

118282

3156554

13C2-PFHxDA IS

1.0000

0.7342

ng/mL

13C2-PFHxDA IS

Auto

9.150

3156554

3156554

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.150

3156554

1232352

13C7-PFUnDA IS

5.0000

5.0600

ng/mL

13C7-PFUnDA IS

Auto

7.655

1232352

1232352

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.621

337066

441681

13C-PFOS IS

0.9200

0.8409

ng/mL

PFBSA

Auto

6.130

252810

442011

13C-FOSA IS

1.0000

1.0975

nq/mL

PFHxSA

Auto

6.958

219469

1748301

13C-PFNA IS

1.0000

1.0165

ng/mL

CHARGE

ND(W/B)

	

	

1232352

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

1.5e5 -

1.0e5 -
5.0e4 :

O.OeO -q^

13C-PFBA

Cone. 5.8411
Q 217.20> 172.30 (-)

1.5e5 -

1.0e5 -
5.0e4 :

O.OeO -q^

PFBA

Cone. 1.0785
1.64e5 Q 213.20> 169.10 (-)

4.0e41

13C-PFPeA IS

Cone. 5.0000
4.06e4 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 5.3995
4.50e5 Q 267.90>223.00 (-)

O.OeO -qjf

O.OeO -

A= 1134096
'T= 5.361

f A= 1134096
(RT= 5.361

O.OeO -

5.2

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 1.1839	Cone. 4.6500	Cone. 4.6625 Cone 1.0472

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)

7.5e4 -
5.0e4 :
2.5e4 :
O.OeO :

TA=247203
TT= 5.361

8.68e4 ISTD 301.80>80.00 (-)
1.5e5 H

1.0e5 -
5.0e4 ^
O.OeO :

A=429733
fl"= 5.492

1.55e5 Q 301.80>80.00 (-)
1.5e5 -

1.0e5-j

5.0e4 ^

O.OeO 4==

R#1 298.80>99.00 67.88 (68.21)

1.55e5 Q 299.00>80.00 (-)	2.49e4 ISTD 332.10>287.10 (-)	1.04e5

A=429733
fl"= 5.492

I R1 67.88 (-

fA=257247
RT=6.092

5.6

RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

253

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Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:44

ICV1 -230428 (continued)

13C HFPO DA

Cone. 5.6404

Q 332.10>287.10 (-)
1.0e5

HFPO DA

Cone. 1.1870

R#1 329.00>285.10 82.18 (71.09)
Q 329.00>169.00 (-)	1.87e4

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 28.72 (25.06)

ISTD 329.00>309.15 (-)	7.64e4



Y A=257247

:

ft RT=6.092

i



13C-4 2-FTS

Cone. 4.6000

R#1 329.00>81.00 28.72 (25.06)
Q 329.00>309.15 (-)	7.64e4

4-2-FtS

Cone. 1.0902

R#1 327.00>81.10 14.55 (17.01)
Q 327.00>307.05 (-)	1.94e4

O.OeO

6.2 6.4
RT (min)

PFHxA

Cone. 1.1007

R#1 313.00> 119.10 2.52 (2.21)
Q 313.00>269.00 (-)	1.86e5

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)
7.5e4
5.0e4 :

2.5e4 :

O.OeO :

13C2-6 2-FTS

Cone. 4.2452



rA

=183289



R

f=6.652

i I

-L

Q 428.90>409.00 (-)
7.5e4 -

TA= 183289
D^"-6.652

5.0e4 :
2.5e4 :
O.OeO :



RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

13C-PFOA

Cone. 5.2869

7.63e5 Q 416.80>372.05 (-)

6.4 6.6

RT (min)

PFHpS

Cone. 0.8958

R#1 449.00>99.20 69.45 (55.18)
Q 449.00>80.15 (-)	2.72e4

fA=62150

IR1 69.45 (- |-rV=6.662

O.OeO

6.6 6.8

RT (min)

PFOS

Cone. 1.0174

R#1 499.00>99.00 93.49 (93.90)
Q 499.00>80.00 (-)	1.43e4

6.6
RT (min)

6-2-FTS

Cone. 1.2102

R#1 427.00>80.90 30.19 (29.85)
Q 427.00>407.00 (-)	1.90e4

:R1 30.19 (

it4

44084
6.652

6.2 6.4 6.6

RT (min)

PFOA

Cone. 1.0954

R#1 413.00 > 169.10 30.30 (28.84)
Q 413.00>369.00 (-)	2.31 e5

~ A= 542493
2.0e5- R1 3030 (TTRn=6.670

L

RT (min)

6.6 6.8 7.0
RT (min)

13C-PFOS IS

Cone. 4.7750

13C-PFOS

Cone. 4.7566

105 (-)

1.85e5 Q 502.80>80.05 (-)

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

A=1821960
RT=6.670

L

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

A=1821960
RT=6.670

- R1 93.49 (•

~ A=46808
--'-®T=6.957

L

A

6.8 7.0
RT (min)

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

1.5e5-
1.0e5^
5.0e4 ^
O.OeO -

1.5e5-
1.0e5^
5.0e4 ^
O.OeO -

TAf4
rI='

441681
RT=6.957



7.2

RT (min)

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

256

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Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:44

ICV1 -230428 (continued)

PFNA

Cone. 0.9055

R#1 463.00>219.00 21.51 (19.07)
Q 463.00>418.90 (-)	1.55e5

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 5.7079

7.08e5 Q 467.80>423.00 (-)

R1 21.51 (

1.5e5 -
1.0e5 ¦;
5.0e4 -
O.OeO -

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

A=377999

7.2

RT (min)

PFNS

Cone. 1.0494

R#1 549.00 >99.00 64.87 (69.83)
Q 549.00>79.95 (-)	4.49e4

fA=110964

R1 64.87 RTi 7280

8-2-FTS

Cone. 0.8831

R#1 527.20>487.00 3.98 (6.24)
Q 527.10>506.90 (-)	7.02e3

13C-8 2-FTS

Cone. 4.6083

3.58e4 Q 528.80> 509.00 (-)

d3-N-MeFOSAAJS

Cone. 5.0000

ISTD 572.80>419.05 (-)
2.0e5 -

1.0e5 -

d3-N-MeFOSAA

Cone. 6.0663

Q 572.80>419.05 (-)
2.0e5 -

1.0e5 -

O.OeO 4=

7.6 7.8
RT (min)

7.4

13C-PFUnDA

Cone. 5.5049

Q 564.80>519.95 (-)
6.0e51

7.8 8.0
RT (min)

PFOSA

Cone. 1.0845

R#1 498.20>64.10 0.00 (0.11)
Q 498.20>78.00 (-)	4.00e4

4.0e4

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

7.6 7.8 8.0

RT (min)

7.2
RT (min)

PFDA

Cone. 1.1492

R#1 512.90>219.00 17.92 (17.97)
Q 512.90>469.00 (-)	1.55e5

:R1 17.92 7.309

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 5.1348

ISTD 514.80>469.95 (-)

7.13e5 Q 514.80>469.95 (-)

7.6
RT (min)

7.2

7.4

7.6
RT (min)

NMeFOSAA

Cone. 1.0911

R#1 570.20>512.00 38.44(38.98)
Q 570.20>419.00 (-)	4.19e4

4.0e4



fA=

1780473

-

RT

=7.309

I

V

¥

	

i i i i I i i

7.6
RT (min)

PFDS

Cone. 1.0070

R#1 599.00>99.00 53.28 (59.45)
Q 599.00>80.10 (-)	3.05e4

7.6
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

7.6 7.8
RT (min)

PFUnDA

Cone. 0.9199

R#1 563.00>219.00 13.97 (12.92)
Q563.00>518.90 (-)	1.11e5

1.0e5-R1 13-97|-RT^

7.25 7.50 7.75

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

d5-N-EtFOSAA

Cone. 6.5128

2.53e5 Q 588.80>419.00 (-)

7.8 8.0
RT (min)

O.OeO -

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.8244

R#1 584.20>526.10 54.33 (51.48)
Q 584.20>418.95 (-)	4.17e4

TA=114491
1^=7.673

O.OeO

7.8 8.0
RT (min)

7.6

13C-FOSA

Cone. 5.4491

1.71e5 Q 506.00>78.05 (-)

1.5e5 ^

1.0e5 ^

5.0e4 ^
== O.OeO 1. . .

7.8 8.0
RT (min)

PFDoA

Cone. 0.9711

R#1 613.05> 169.00 16.77 (17.39)
Q 613.05>569.00 (-)	1.41e5

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

6.39e5

- R1 16.77

| RT=

7.997 6.0e5

:



4.0e5 -j

:



2.0e5 -j

: /



-

i i Ai I i i

—i—|—|—|—|—|—|- O.OeO L

7.8 8.0

RT (min)

7.8 8.0

RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

25E

-------


Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:44

ICV1 -230428 (continued)

13C-PFDoA

Cone. 5.6586

10-2-FtS

Cone. 0.7806

R#1 626.50>81.05 79.61 (57.89)
Q 626.50>607.05 (-)	6.90e3

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 5.8337

1.89e5 Q 531.10> 169.10 (-)

^.SeSz_

^.0eSz_

5.0e4 i
— O.OeO ~h~TT

A=484837
RT=8.777

V:

RT (min)

RT (min)

9.0

RT (min)

NEtFOSE

Cone. 0.8516

Q 629.50>59.10 (-)

4.0e4 -
2.0e4 -

O.OeO -I. . . .

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 7.6598

5.96e4 ISTD 638.90> 59.10 (-)

6.0e4 i
4.0e4 ^

2.0e4 i
=rr O.OeO 1 . . .

6.84e4 Q 638.90> 59.10 (-)

6.0e4 :

4.0e4 :

2.0e4 :

O.OeO:



>
II

05
05

~

RT=8.733

I



9.0
RT (min)

9.0
RT (min)

9.0
RT (min)

d3-NMeFOSA

Cone. 5.7982

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 6.5531

ISTD 623.00>59.00 (-)
1.0e5 -

Q 623.00>59.00 (-)
1.0e5 -

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 1.3365

R#1 713.00> 169.30 11.31 (10.00)
Q 713.00>668.90 (-)	1.23e5

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 3.4392

11CI-PF30UdS

Cone. 1.1601

2.53e5 Q 714.80>669.80 (-)

2.53e5 Q 631.00>451.10 (-)

O.OeO

9.0
RT (min)

L-PFDoS

Cone. 1.1289
R#1 698.80>98.80 72.27 (75.26)

Q 698.80>80.10 (-)	1.35e4 Q 377.10>251.20 (-)

Q 812.90>769.00 (-)

Q 912.80>869.00 (-)
4.0 e4 H

8.4 8.6
RT (min)

NMeFOSE

Cone. 1.1849

Q 616.10>58.90 (-)
2.0e4 -

8.6 8.8 9.0

RT (min)

NMeFOSA

Cone. 1.0632

R#1 512.10>219.20 70.77 (76.68)
Q 512.10> 169.20 (-)	1.68e4

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

8.4 8.6

RT (min)

NEtFOSA

Cone. 1.0608

R#1 526.50>219.20 64.40 (65.87)
Q 526.50>169.10 (-)	2.86e4

(A=75453

- R1 64.40 (-Mt=8.787

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 1.4374

R#1 663.10> 169.10 21.42 (18.12)
Q 663.10>618.90 (-)	1.16e5

rA=295666

1.0e5-

R1 21.42

|"RT^f

.323

5.0e4 -







OOpO-

r



~

9.0

RT (min)

8.2 8.4 8.6

RT (min)

9CI-PF30NS

Cone. 0.9861

4.75e4 Q 531.00>351.10 (-)

9.04e4

A=215011
RT=7.136

VI

RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

4.11 e4 I STD 815.00 > 770.00 (-)

~ A=3156554
RT=9150



10.0

RT (min)

9.2 9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

258

-------
A

Insight Report
Quantitation/lntegration
Printed 11/2/2023 08:36:44

ICV1 -230428 (continued)

13C2-PFHxDA

Cone. 5.0600

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

1.34e6 ISTD 569.80>524.90 (-)

PFecHS	PFBSA

Cone. 0.8409	Cone. 1.0975
R#1 461.00>99.10 38.05 (38.19)

4.48e5 Q 461.00>381.00 (-)	1.39e5	Q 298.00>78.00 (-)

O.OeO

;

RT=9

150

4.0e5 -







2.0e5 -

I

u

	 0 OpO -

9.0 9.2

9.4
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

232352
7.655

fA=337066
IR1 3805 (-™=6.621

1.0e5-

6.4 6.6 6.8

RT (min)

PFHxSA

Cone. 1.0165

1.01e5 Q 397.90>78.00 (-)

7.5e4 ^

S.0e4z_

2.5e4z_
— O.OeO 1. . r

A=219469
RT=6.958

L

6.4
RT (min)

7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

258

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1st /S/AO 10/26/23

2nd /S/AO 10/26/23

Insight Report
Quantitation/Integration
Printed 10/24/2023 15:45:02

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/30/2023 3:04:38 AM

Acquired by: System Administrator

Data File: 230428227

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone. Cone.

Unit

13C-PFBA IS

Auto

4.202

549035

549035

	

—- 5.0000

ng/mL

13C-PFBA

Auto

4.202

549035

575

13C7-PFUnDA IS

—- 3.8292

nq/mL

PFBA

Auto

4.203

10859

549035

13C-PFBA IS

—- 0.0885

ng/mL

13C-PFPeA IS

Auto

5.357

1070213

1070213

	

—- 5.0000

ng/mL

13C-PFPeA

Auto

5.357

1070213

1351575

1; )A is

—- 4.6459

ng/mL

PFPeA

Auto

5.357

19935

- -213

13C-PFPeA IS

. 1:12

ng/mL

13C-PFBS IS

Auto

5.487

4.' 5 7 HI

425710

	

30

ng/mL

13C-PFBS

Auto

487

425710

1351575

13C7-PFUnDA IS

—- 4.2115

ng/mL

PFBS

Auto

c/iaa

5145

425710

13C-PFBS IS

	 0.0778

g/mL

13C HFPO DA IS

Auto

6.086

272033

272033

	

—- 5.0000

ng/mL

13C HFPO DA

Auto

6.086

272033

1351575

13C7-PFlJnDA IS

34

ng/mL

HFPO DA

Auto

6.082

3427

033

13C HFPO DA IS

—- 0.0861

ng/mL

13C-4 2-FTS IS

Auto

5.888

175952

175952

	

—- 4.6700

ng/mL

13C-4 2-FTS

Auto

5.888



1351575

13C7-PFUnDA IS

3.8924

ng/mL

4-2-FtS

Auto

5.889

'/I

175952

13C-4 2-FTS IS

—- 0.0891

ng/mL

PFHxA

Auto

5.942

37475

1418046

13C-PFHxA IS

v- 35

ng/mL

13C-PFHxA IS

Auto

5.941

1418046

14180-16

	

)0

g/mL

13C-PFHxA

Auto

5.941

1418046

1351575

13C7-PFUnDA IS

—- 4.5308

nq/mL

PFPeS

Auto

5.983

(6

433154

180-PFHxS IS

—- 0.0942

ng/mL

PFHxS

Auto

6.354

4954

433154

180-PFHxS IS

—- 0.0900

ng/mL

13C-PFHpA IS

Auto

6.346

1403206

1403206

	

—- 5.0000

ng/mL

13C-PFHpA

Auto

6.346

1403206

1351575

13C7-PFUnDA IS

—- 4.6152

ng/mL

IS

Auto

6.353

433154

433154

	

—- 4.7250

nq/mL

180-PFHxS

Auto

6.353

433154

575

13C7-PFUnDA IS

-— 4.2700

ng/mL

PFHpA

Auto

6.346

56

1403206

:HpA IS

—- 0.1018

ng/mL

13C2-6 2-FTS IS

Auto

6.646

174338

174338

	

. "'00

ng/mL

13C2-6 2-FTS

Auto

546

174338

1351575

13C7-PFUnDA IS

—- 3.6817

ng/mL

PFHpS

Auto

6.655

5502

433154

180-PFHxS

—- 0.0836

nq/mL

6-2-FTS

Auto

6.646

2413

174338

13C2-6 2-FTS IS

—- 0.0697

ng/mL



Auto

6.663

•• 10

1686433

13C-PFOA IS

—- 0.1013

ng/mL

13C-PFOA IS

Auto

6.664

1686433

1686433

	

—- 5.0000

g/mL

13C-PFOA

Auto

6.664

1686433

575

1;

20

ng/mL

PFOS

Auto

6.952

3532

204

13C-PFOS IS

—- 0.0849

ng/mL

13C-PFOS IS

Auto

6.950

399204

204

	

—- 4.7750

ng/mL

13C-PFOS

Auto

6.950

399204

1351575

)A IS

—- 3.9199

g/mL

PFNA

Auto

6.971

38238

1634251

13C-PFNA IS

—- 0.0980

ng/mL

13C-PFNA IS

Auto

6.969

1634251

1634251

	

)0

g/mL

13C-PFNA

Auto

6.969

1634251

1351575

13C7-PFUnDA IS

—- 4.8649

ng/mL

PFNS

Auto

7.271

8978

399204

13C-PFOS IS

—- 0.0939

g/mL

8-2-FTS

Auto

7.298

1892

89540

13C-8 2-FTS IS

—- 0.1053

ng/mL

13C-8 2-FTS IS

Auto

7.299

89540

89540

	

—- 4.7900

g/mL

13C-8 2-FTS

Auto

7.299

89540

1351575

13C7-PFUnDA IS

—- 4.0138

ng/mL

PFDA

Auto

7.304

34202

1787106

13C-PFDA IS

11

ng/mL

13C-PFDA IS

Auto

7.303

' ;!6

1787106

	

30

ng/mL

13C-PFDA

Auto

7.303

1787106

1351575

1; )a is

93

ng/mL

d3-N-MeFOSAA IS

Auto

7.478

583633

633

—

30

ng/mL

d3-N-MeFOSAA

Auto

7.478

13

1351575

1; )A is

35

ng/mL

NMeFC

Auto

7.484

13

583633

vleFOSAA IS

—- 0.0896

ng/mL

PFDS

Auto

7.610

)8

399204

13C-PFOS IS

—- 0.0752

nq/mL

13C-PFUnDA IS

Auto

7.648

1654770

1654770

	

30

ng/mL

13C-PFUnDA

Auto

7.648

1654770

1351575

13C7-PFUnDA IS

42

ng/mL

PFUnDA

Auto

7.649

30819

1654770

13C-PFUnDA IS

• 51

ng/mL

.b N ttFOSAA IS

Auto

7.659

674533

674533

	

)0

ng/mL

d5-N-EtFOSAA

Auto

7.659

674533

1351575

13C7-PFUnDA IS

55

ng/mL

NEIFOSAA

Auto

7.666

11729

674533

(IS- N- ttFOSAA IS

79

ng/mL

PFOSA

Auto

7.737

>8

157

13C-FOSA IS

—- 0.0856

ng/mL

I k FOSA IS

Auto

7.735

456157

456157

	

—- 5.0000

ng/mL

13C-FOSA

Auto

7.735

456157

1351575

'FUnDA IS

—- 5.1274

ng/mL

PFDoA

Auto

7.991

33607

1709242

:DoA IS

—- 0.0880

ng/mL

13C-PFDoA IS

Auto

7.991

1709242

242





ng/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCaLCorrected.iproc

260

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1st /S/AO 10/26/23

2nd /S/AO 10/26/23



Insight Report
Quantitation/Integration
Printed 10/24/2023 15:45:02

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone. Cone. Unit

13C-PFDoA

Auto

7.991

1709242

1351575

13C7-PFUnDA IS

—- 5.2066

nq/mt

:tS

Auto

8.009

1602

89540

13C-8

0.0705

nc

j/mL

tFOSA IS

Auto

8.770

506304

506304

	

—- 5.0000

nt

j/ml

d5-NEtFOSA

Auto

8.770

506304

¦¦¦¦¦¦ :J5

13C7-PFUnDA IS

5.5546

nc

j/mL

NMeFObE

Auto

8.493

5631

317280

vleFOSE IS

—- 0.1087

nc

j/mL

NEtFOSE

Auto

8.744

14764

194792

d9-EtFOSE IS

—- 0.0764

nc

3/mL

d9-EtFOSE IS

Auto

8.726

194792

194792

	

X)

nc

j/mL

d9-EtFOSE

Auto

8.726

194792

1351575

1?

7.4825

nc

j/mL

NMeFOSA

Auto

8.519



456794

dB-NMeFOSA IS

—- 0.1019

nc

j/mL

d3-NMeFOSA IS

Auto

8.513

456794

456794

	

- 30

nc

j/mL

dB-NMeFOSA

Auto



i

1

1;

---- 5.5425

nq/ml

d7-N-MeFOSEJS

dy-N-MerOSE

NEtFOSA

PFTrDA

Auto

Auto

Auto

AUtO

PFTeDA

Auto

13C-PFTeDA IS

Auto

13C-PFTeDA

Auto

8.478

8.478
J3.780

8.315
8.616
8.613

317280

6224
29488

33745

929156

317280

506304

929156
929156

929156

i JCT-PFUnDA IS

d5	JS

13C~PFTePA IS
13C-PFTeDA IS

8.613 929156 1351575 13C7-PFUnDA IS

11C!-PF30UdS

Auto

7.802

9457

399204

130PFOS

IS



Auto

7.129

18715

¦ ¦ '34

13C-PFOS

IS

L-PFDoS

Auto

8.267

2368

399204

13C-PFOS

;

	 5.0000

ng/ml

njg/m.L

ng/mL.

.ng/mL...
rig/ml
5.0000 ng/mL

6.8696

0.0838

J3JQ45.

0.1014

4.3029
0.1034
0.0950
0.0890

ng/mL...
g/m.L.
ng/mL...

NaDONA

Auto

6.391

30666

1634251

13C-PFNA IS

0.0889

ng/mL

PFHxDA

Auto

9.143

31141

3060991

13C2-PFHxDA IS

—- 0.0885

g/mL

PFODA

Auto

9.669

IS

191

13C2-PFHxDA IS

0.0962

ng/mL

13C2-PFHxDA IS

Auto

9.144

3060991

•91

	

—- 5.0000

g/mL

3FHxDA

Auto

9.144

3060991

¦¦¦¦¦¦ ,75

1?

—- 4.4740

ng/mL

13C7~PFUnDA IS

Auto

7.648

1351575

'5

	

—- 5.0000

nq/mL

PFecHS

Auto

6.615

30764

399204

V: '

0.0849

ng/mL

PFBSA

Auto

6.124

24027

456157

130FOSA IS

—- 0.1011

ng/mL

PFHxSA

Auto

6.951

19260

1634251

13C-PFNA IS

0.0954

ng/mL

CHARGE

ND(W/B)

	

	

1351575

13C7-PFUnDA IS

	

ng/mL

13C-PFBAJS

Cone. 5.0000

ISTD 217.20> 172.30 (-)

13C-PFBA

Cone. 3.8292
1.45e5 Q 217.20> 172.30 (-)

VA=549035

2

PFBA

Cone. 0.0885
1.45e5 Q 213.20> 169.10 (-)

F.A=549035
RT=4.202

13C-PFPeA_IS

Cone. 5.0000

3.52e3 ISTD 267.90>223.00 (-)

3.0e3 :
2.0e3 :
1.0e3:

=10859
1=4.203

f A=1070213
I RT= 5.357

13C-PFPeA

Cone. 4.6459

3.99e5 Q 267.90>223.00 (-)	3.99e5

fA=1070213
I FkT= 5.357

4.00 4.25 4.50	4.00

RT (min)

PFPeA	13C-PFBSJS

Cone. 0.1012	Cone. 4.6500

Q 263.05>219.10 (-)

7.71e3 ISTD 301.80>80.00 (-)
1.5e5 -i

lOeO -

5.2

4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)

13C-PFBS	PFBS

Cone. 4.2115	Cone. 0.0778

5.4

~ A=425710
IT = 5.487

1.0e5 -

!,50e5 Q 301.80>80.00 (-)
1.5e5 n

1.0e5 -

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13CHFPODAJS

Cone. 5.0000
R#1 298.80>99.00 67.22 (68.21)

,50e5 Q 299.00>80.00 (-)	2.16e3 ISTD 332.10>287.10 (-)	1.14e5

A=425710
FkT= 5.487

f A=5145

- W'|''ikt = 5.489

f A=272033
RT=6.086

5.6 5.8

RT (min)

5.6 5.8

RT (min)

5.6 5.8

RT (min)

6.2 6.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCaLCorrected.iproc

16®

-------
1st /S/ AO 10/26/23
2nd IS/ AO 10/26/23



Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:45:02

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 5.4384

Q 332.10>287.10 (-)

.=272033
T=6.086

O.OeO -

J

_L

6.0

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

!A= 1403206
RT=6.346

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

6.0e4 i
4.0e4 i
2.0e4 i
O.OeO 1, i i

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

'A=1686433
RT=6.664

HFPO DA

Cone. 0.0861

R#1 329.00>285.10 85.07 (71.09)
Q 329.00>169.00 (-)	1.50e3

IR1 85.07 (

6.2 6.4
RT (min)

PFHxA

Cone. 0.0995

R#1 313.00> 119.10 2.30 (2.21)
Q 313.00>269.00 (-)	1.59e4

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 29.11 (25.06)

ISTD 329.00>309.15 (-)	6.84e4

175952

6.0e4^R1 29-11(M=5.8

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

5.66e5 Q 314.90>270.10 (-)

f A=1418046
Rn"= 5.941

13C-PFHpA

Cone. 4.6152

5.93e5 Q 366.90>322.10 (-)

fA= 1403206
[¥=6.346

6.6

RT (min)

6.6

RT (min)

13C2-6 2-FTS

Cone. 3.6817

7.16e4 Q 428.90>409.00 (-)

6.0e4 i
4.0e4 i
2.0e4 i
=== O.OeO 1. . .

RT (min)

RT (min)

13C-PFOA

Cone. 4.4620

6.99e5 Q 416.80>372.05 (-)

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

A=1686433
RT=6.664

vj

6.8 7.0
RT (min)

fA= 1418046
Rn"= 5.941

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)

^ It

1.5e5 -
1.0e5-j
5.0e4 :

433154
6.353



O.OeO -

"R1 107.86 (-I%3532
1.0e3 -	ftT=6-952



w

6.8 7.0
RT (min)

13C-4 2-FTS

Cone. 3.8924

R#1 329.00>81.00 29.11 (25.06)
Q 329.00>309.15 (-)	6.84e4

6.0 6.2
RT (min)

4-2-FtS

Cone. 0.0891

R#1 327.00>81.10 23.16 (17.01)
Q 327.00>307.05 (-)	1.64e3

~ A=3721
1.5e3>1 23.16(1^=5.889

O.OeO

6.0 6.2
RT (min)

PFPeS

Cone. 0.0942

R#1 349.00>99.00 70.68 (89.24)
Q 349.00>79.95 (-)	2.81e3

T A =5746

: R1 70.68 (-|-ror= 5.983

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.0900

R#1 399.00 >99.00 111.71 (92.93)
Q 399.00>80.00 (-)	1.70e3

4

6.2

RT (min)

1.5e3~
1.0e3-j
5.0e2 :
O.OeO :

: R1 111.71'

••4^4954



RT=6.354



A=267

= /kP

1\ RT=6.526

-

Vy	.~

| Ai i i

i I A	

6.2

6.4

180-PFHxS

Cone. 4.2700

1.87e5 Q 402.70>84.05 (-)

6.6
RT (min)

PFHpA

Cone. 0.1018

R#1 362.90 >169.00 14.41 (16.60)
Q 362.90>319.00 (-)	1.78e4

O.OeO i | | |

6.2 6.4 6.6

RT (min)

PFHpS

Cone. 0.0836

R#1 449.00>99.20 62.04 (55.18)
Q 449.00>80.15 (-)	2.38e3

fA=5502

- R1 62.04 (4m=6.655

6.6
RT (min)

6-2-FTS

Cone. 0.0697

R#1 427.00>80.90 25.96 (29.85)
Q 427.00>407.00 (-)	1.15e3

TA,=2413

I R1 25.96 (

6.6
RT (min)

PFOA

Cone. 0.1013

R#1 413.00> 169.10 25.73 (28.84)
Q 413.00>369.00 (-)	1.95e4

~ A=46440

6.6 6.8

RT (min)

PFOS

Cone. 0.0849

R#1 499.00>99.00 107.86 (93.90)
Q 499.00>80.00 (-)	1.17e3

6.75 7.00 7.25

RT (min)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

262

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1st /S/ AO 10/26/23
2nd IS/ AO 10/26/23



Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:45:02

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0980

R#1 463.00>219.00 19.07 (19.07)
Q 463.00>418.90 (-)	1.52e4

13C-PFNAJS

Cone. 5.0000

13C-PFNA

Cone. 4.8649

PFNS

Cone. 0.0939

R#1 549.00 >99.00 59.01 (69.83)
Q 549.00>79.95 (-)	3.66e3

A=j8978
R1 59.01 -RT-i 7.271

7.2

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

3.0e4 ^

2.0e4 i
1.0e4^

O.OeO 4=

13C-8 2-FTS

Cone. 4.0138

3.43e4 Q 528.80> 509.00 (-)

3.0e4 ^

2.0e4 i
1.0e4^
. . . . O.OeO "I—r-

7.6
RT (min)

d3-N-MeFOSAAJS

Cone. 5.0000

ISTD 572.80>419.05 (-)
2.0e5 -

1.0e5 -

13C-PFUnDA

Cone. 4.9442

Q 564.80>519.95 (-)

6.0e5 i TA= 1654770
RT=17.648

4.0e5 :

2.0e5 :

O.OeO -

V

7.6

7.8 8.0
RT (min)

PFOSA

Cone. 0.0856

R#1 498.20>64.10 0.00 (0.11)
Q 498.20>78.00 (-)	3.41 e3

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

7.8 8.0

RT (min)

7.2
RT (min)

PFDA

Cone. 0.1011

R#1 512.90>219.00 13.91 (17.97)
Q 512.90>469.00 (-)	1.30e4

8-2-FTS

Cone. 0.1053

R#1 527.20>487.00 0.00 (6.24)
Q 527.10>506.90 (-)	9.65e2

7.5e2 :
5.0e2 :
2.5e2 :
O.OeO :

o
o

0

5

1	I I I I I I I I I

Rt=

7.298







	



7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 4.6993

ISTD 514.80>469.95 (-)

7.24e5 Q 514.80>469.95 (-)

7.2 7.4 7.6

RT (min)

d3-N-MeFOSAA

Cone. 5.2635

Q 572.80>419.05 (-)	2.20e5

2.0e5

1.0e5

O.OeO

7.6 7.8
RT (min)

PFUnDA

Cone. 0.0951

R#1 563.00>219.00 13.95 (12.92)
Q563.00>518.90 (-)	1.22e4

fA=30819

-R1 13.9 S|( ^1=^7 649

O.OeO 	

7.6
RT (min)

NMeFOSAA

Cone. 0.0896

R#1 570.20>512.00 23.91 (38.98)
Q 570.20>419.00 (-)	3.46e3

f A= 10383

7.6
RT (min)

PFDS

Cone. 0.0752

R#1 599.00>99.00 82.05 (59.45)
Q 599.00>80.10 (-)	1.91e3

R1 23.91 (-

¦ >S\)

-R»=7.484

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)



7.25 7.50 7.75

RT (min)

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

d5-N-EtFOSAA

Cone. 5.7055

2.45e5 Q 588.80>419.00 (-)

f A=674533
RT=F.659

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.0879

R#1 584.20>526.10 61.49 (51.48)
Q 584.20>418.95 (-)	3.27e3

VA= 11729
'¦®"Kn= 7.666

O.OeO -

U

8.0
RT (min)

7.6

13C-FOSA

Cone. 5.1274

1.75e5 Q 506.00>78.05 (-)

7.8 8.0
RT (min)
PFDoA

Cone. 0.0880

R#1 613.05> 169.00 14.89 (17.39)
1.75e5 Q 613.05>569.00 (-)	1.25e4

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

6.48e5

7.8 8.0

RT (min)

8.0
RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

263

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1st /S/ AO 10/26/23
2nd IS/ AO 10/26/23



Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:45:02

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 5.2066

10-2-FtS

Cone. 0.0705

R#1 626.50>81.05 33.33 (57.89)
Q 626.50>607.05 (-)	5.85e2

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 5.5546

1.95e5 Q 531.10> 169.10 (-)

RT=^8.009

A=1

602





RT (min)

RT (min)

NEtFOSE

Cone. 0.0764

Q 629.50>59.10 (-)
6.0e3 -i

d9-EtFOSE IS

Cone. 5.0000

O.OeO

NMeFOSE

Cone. 0.1087

1.95e5 Q 616.10>58.90 (-)
2.0e3 -

1.0e3-

A=5631
RT=8.493

O.OeO -

8.4

6.05e3 ISTD 638.90> 59.10 (-)

A= 194792
RT=8.726

k

7.32e4 Q 638.90> 59.10 (-)

6.0e4 ~

4.0e4 ~

2.0e4 ~

O.OeO I,,,

9.0

RT (min)

NMeFOSA

Cone. 0.1019
R#1 512.10>219.20 80.12 (76.68)

7.32e4 Q 512.10 > 169.20 (-)	1,63e3 I STD 515.10 > 169.00 (-)

RT (min)

d3-NMeFOSA IS

Cone. 5.0000





A=4290

1.5e3-

R1 80.12 (-

kr=8.519

1.0e3^





5.0e2 ^





OOpO-

/

"jUfcar

9.0
RT (min)

9.0
RT (min)

d3-NMeFOSA

Cone. 5.5425

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 6.8696

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 0.0838

R#1 526.50>219.20 61.50 (65.87)

1,78e5 I STD 623.00 > 59.00 (-)

1.25e5 Q 623.00> 59.00 (-)

A=317280
RT=8.478

L

1.25e5 Q 526.50> 169.10 (-)

- R1 61.50 (-
2.0e3 -

A=6224
ffr=8.780

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 0.1014

R#1 713.00 >169.30 9.84 (10.00)
Q 713.00>668.90 (-)	1.22e4

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 4.3029

11CI-PF30UdS

Cone. 0.1034

3.45e5 Q 714.80>669.80 (-)

3.45e5 Q 631.00>451.10 (-)

O.OeO

9.0
RT (min)

L-PFDoS

Cone. 0.0890

R#1 698.80>98.80 94.26 (75.26)
Q 698.80>80.10 (-)	9.66e2

Q 377.10>251.20 (-)

1.32e4 Q 812.90>769.00 (-)

1.32e4 Q 912.80>869.00 (-)

A=30666
RT=6.391

V

8.4 8.6
RT (min)

6.2 6.4 6.6

RT (min)



rA=3i

41

_

RT=9.

143



.





^A= 15025
RT=9.669



9.4

RT (min)

1.5e5-
1.0e5-
5.0e4-
O.OeO -

A=456794
RT=8.513

L

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.1045

R#1 663.10> 169.10 25.50 (18.12)

2.40e3 Q 663.10>618.90 (-)

1.09e4

1.0e4- R1 25.5(

9.0

RT (min)

9CI-PF30NS

Cone. 0.0950

3.89e3 Q 531.00>351.10 (-)

~ A=18715
Rl>7.129



RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

5.41 e3 ISTD 815.00>770.00 (-)

TA=3(
RT=?



10.0

RT (min)

9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

263

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1st /S/ AO 10/26/23
2nd IS/ AO 10/26/23

A

Insight Report
Quantitation/lntegration
Printed 10/24/2023 15:45:02

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 4.4740

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 0.1011

PFecHS

Cone. 0.0849
R#1 461.00>99.10 45.40 (38.19)

1,30e6 ISTD 569.80> 524.90 (-)	4.97e5 Q 461.00>381.00 (-)	1,22e4 Q 298.00>78.00 (-)

PFHxSA

Cone. 0.0954

9.94e3 Q 397.90>78.00 (-)

50991
144

O.OeO

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

- R1 45.40 (-

'A=30764
W=6.615

8.0
RT (min)

6.4 6.6 6.8

RT (min)

6.0 6.2 6.4
RT (min)

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

263

-------
Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:08

CCV2-230428

Sample ID: CCV2-230428

Date Acquired: 4/30/2023 3:18:27 AM

Acquired by: System Administrator

Data File: 230428228

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.204

792524

792524

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.204

792524

1505933

13C7-PFUnDA IS

5.0000

4.9608

nq/mL

PFBA

Auto

4.204

864777

792524

13C-PFBA IS

5.0000

4.8804

nq/mL

13C-PFPeA IS

Auto

5.360

1195902

1195902

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.360

1195902

1505933

13C7-PFUnDA IS

5.0000

4.6594

nq/mL

PFPeA

Auto

5.360

1152745

1195902

13C-PFPeA IS

5.0000

5.2352

nq/mL

13C-PFBS IS

Auto

5.490

486817

486817

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.490

486817

1505933

13C7-PFUnDA IS

4.6500

4.3223

nq/mL

PFBS

Auto

5.490

322291

486817

13C-PFBS IS

4.4200

4.2646

nq/mL

13C HFPO DA IS

Auto

6.090

293902

293902

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.090

293902

1505933

13C7-PFUnDA IS

5.0000

5.2734

nq/mL

HFPO DA

Auto

6.089

225489

293902

13C HFPO DA IS

5.0000

5.2454

nq/mL

13C-4 2-FTS IS

Auto

5.890

209704

209704

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.890

209704

1505933

13C7-PFUnDA IS

4.6700

4.1635

nq/mL

4-2-FtS

Auto

5.891

224037

209704

13C-4 2-FTS IS

4.6700

4.5027

nq/mL

PFHxA

Auto

5.945

2187377

1582688

13C-PFHxA IS

5.0000

5.2015

nq/mL

13C-PFHxA IS

Auto

5.945

1582688

1582688

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

5.945

1582688

1505933

13C7-PFUnDA IS

5.0000

4.5385

nq/mL

PFPeS

Auto

5.986

333435

475401

180-PFHxS IS

4.6900

4.9785

nq/mL

PFHxS

Auto

6.355

254401

475401

180-PFHxS IS

4.5500

4.2106

nq/mL

13C-PFHpA IS

Auto

6.349

1532867

1532867

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.349

1532867

1505933

13C7-PFUnDA IS

5.0000

4.5249

nq/mL

180-PFHxS IS

Auto

6.356

475401

475401

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.356

475401

1505933

13C7-PFUnDA IS

4.7250

4.2061

ng/mL

PFHpA

Auto

6.349

2371435

1532867

13C-PFHpA IS

5.0000

5.1869

ng/mL

13C2-6 2-FTS IS

Auto

6.650

207920

207920

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.650

207920

1505933

13C7-PFUnDA IS

4.7500

3.9408

ng/mL

PFHpS

Auto

6.660

322843

475401

180-PFHxS IS

4.7600

4.4681

nq/mL

6-2-FTS

Auto

6.650

187529

207920

13C2-6 2-FTS IS

4.7400

4.5380

nq/mL

PFOA

Auto

6.668

2537943

1936110

13C-PFOA IS

5.0000

4.8223

nq/mL

13C-PFOA IS

Auto

6.668

1936110

1936110

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.668

1936110

1505933

13C7-PFUnDA IS

5.0000

4.5975

nq/mL

PFOS

Auto

6.954

207981

444010

13C-PFOS IS

4.6400

4.4971

nq/mL

13C-PFOS IS

Auto

6.955

444010

444010

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

6.955

444010

1505933

13C7-PFUnDA IS

4.7750

3.9130

nq/mL

PFNA

Auto

6.975

1908269

1757290

13C-PFNA IS

5.0000

4.5481

nq/mL

13C-PFNA IS

Auto

6.975

1757290

1757290

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.975

1757290

1505933

13C7-PFUnDA IS

5.0000

4.6949

nq/mL

PFNS

Auto

7.278

530980

444010

13C-PFOS IS

4.8000

4.9952

nq/mL

8-2-FTS

Auto

7.303

102216

98248

13C-8 2-FTS IS

4.7900

4.3776

nq/mL

13C-8 2-FTS IS

Auto

7.304

98248

98248

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.304

98248

1505933

13C7-PFUnDA IS

4.7900

3.9528

nq/mL

PFDA

Auto

7.308

1808529

2007055

13C-PFDA IS

5.0000

4.7581

m

13C-PFDA IS

Auto

7.307

2007055

2007055

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.307

2007055

1505933

13C7-PFUnDA IS

5.0000

4.7367

m

d3-N-MeFOSAA IS

Auto

7.482

655086

655086

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.482

655086

1505933

13C7-PFUnDA IS

5.0000

5.3023

m

NMeFOSAA

Auto

7.487

621264

655086

d3-N-MeFOSAA IS

5.0000

4.7782

nq/mL

PFDS

Auto

7.615

359531

444010

13C-PFOS IS

4.8200

4.5893

m

13C-PFUnDA IS

Auto

7.653

1835135

1835135

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.653

1835135

1505933

13C7-PFUnDA IS

5.0000

4.9211

m

PFUnDA

Auto

7.653

1643463

1835135

13C-PFUnDA IS

5.0000

4.5748

nq/mL

d5-N-EtFOSAA IS

Auto

7.664

736966

736966

	

5.0000

5.0000

m

d5-N-EtFOSAA

Auto

7.664

736966

1505933

13C7-PFUnDA IS

5.0000

5.5947

nq/mL

NEtFOSAA

M

7.671

623584

736966

dS-N-EtFOSAA IS

5.0000

4.2774

m

PFOSA

Auto

7.738

450836

465126

13C-FOSA IS

5.0000

4.5236

nq/mL

13C-FOSA IS

Auto

7.739

465126

465126

	

5.0000

5.0000

m

13C-FOSA

Auto

7.739

465126

1505933

13C7-PFUnDA IS

5.0000

4.6923

nq/mL

PFDoA

Auto

7.994

1821017

1934664

13C-PFDoA IS

5.0000

4.2130

nq/mL

13C-PFDoA IS

Auto

7.994

1934664

1934664

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

266

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:08

CCV2-230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

7.994

1934664

1505933

13C7-PFUnDA IS

5.0000

5.2893

nq/mL

10-2-FtS

Auto

8.005

122728

98248

13C-8 2-FTS IS

4.8200

4.9175

ng/mL

d5-NEtFOSA IS

Auto

8.773

501868

501868

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.773

501868

1505933

13C7-PFUnDA IS

5.0000

4.9416

ng/mL

NMeFOSE

Auto

8.496

263214

317841

d7-N-MeFOSE IS

5.0000

5.0716

nq/mL

NEtFOSE

Auto

8.747

793034

192700

d9-EtFOSE IS

5.0000

4.1485

ng/mL

d9-EtFOSE IS

Auto

8.729

192700

192700

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.729

192700

1505933

13C7-PFUnDA IS

5.0000

6.6435

ng/mL

NMeFOSA

Auto

8.521

208915

469173

d3-NMeFOSA IS

5.0000

4.8328

nq/mL

dB-NMeFOSA IS

Auto

8.516

469173

469173

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.516

469173

1505933

13C7-PFUnDA IS

5.0000

5.1092

nq/mL

d7-N-MeFOSE IS

Auto

8.481

317841

317841

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.481

317841

1505933

13C7-PFUnDA IS

5.0000

6.1764

nq/mL

NEtFOSA

Auto

8.783

371240

501868

d5-NEtFOSA IS

5.0000

5.0423

ng/mL

PFTrDA

Auto

8.320

1628539

1007758

13C-PFTeDA IS

5.0000

5.3197

nq/mL

PFTeDA

Auto

8.617

1754315

1007758

13C-PFTeDA IS

5.0000

4.8620

ng/mL

13C-PFTeDA IS

Auto

8.617

1007758

1007758

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.617

1007758

1505933

13C7-PFUnDA IS

5.0000

4.1885

ng/mL

11CI-PFBOUdS

Auto

7.806

534806

444010

13C-PFOS IS

4.7100

5.2569

nq/mL

9CI-PF30NS

Auto

7.134

1117643

444010

13C-PFOS IS

4.6600

5.0989

ng/mL

L-PFDoS

Auto

8.271

163919

444010

13C-PFOS IS

4.8400

5.5408

nq/mL

NaDONA

Auto

6.395

1680677

1757290

13C-PFNA IS

4.7100

4.5311

ng/mL

PFHxDA

Auto

9.146

1159457

3444918

13C2-PFHxDA IS

5.0000

4.2826

nq/mL

PFODA

Auto

9.677

845948

3444918

13C2-PFHxDA IS

5.0000

4.8112

ng/mL

13C2-PFHxDA IS

Auto

9.146

3444918

3444918

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.146

3444918

1505933

13C7-PFUnDA IS

5.0000

4.5190

ng/mL

13C7-PFUnDA IS

Auto

7.653

1505933

1505933

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.619

1980153

444010

13C-PFOS IS

4.6100

4.9139

ng/mL

PFBSA

Auto

6.127

1209712

465126

13C-FOSA IS

5.0000

4.9908

nq/mL

PFHxSA

Auto

6.956

1014526

1757290

13C-PFNA IS

5.0000

4.6747

ng/mL

CHARGE

ND(W/B)

	

	

1505933

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 4.9608
1.73e5 Q 217.20>172.30 (-)

PFBA

Cone. 4.8804
1.73e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
1,88e5 ISTD 267.90>223.00 (-)

A=864777
RT=4.204

O.OeO -bgf

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 5.2352

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

4.00 4.25 4.50

RT (min)

13C-PFBS

Cone. 4.3223

Q263.05>219.10 (-)

3.97e5 I STD 301.80 > 80.00 (-)

1.73e5 Q 301.80>80.00 (-)

A= 1152745
fl"= 5.360

5.6

RT (min)

13C-PFPeA

Cone. 4.6594
4.67e5 Q 267.90>223.00 (-)

f A=1195902
RT= 5.360

O.OeO -

f A=1195902
RT= 5.360

O.OeO

5.6

RT (min)

PFBS

Cone. 4.2646
R#1 298.80>99.00 74.27 (68.21)

1.73e5 Q 299.00>80.00 (-)	1.14e5 ISTD 332.10>287.10 (-)

13C HFPO DA IS

Cone. 5.0000

f A=322291
1.0e5 —I7427 (TF= 5-490

A=293902
'T=6.090

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

im

-------


Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:08

CCV2-230428 (continued)

13C HFPO DA

Cone. 5.2734

Q332.10>287.10 (-)

HFPO DA

Cone. 5.2454

R#1 329.00>285.10 76.00 (71.09)
Q 329.00>169.00 (-)	9.57e4

f A=293902
RT=6.090

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 26.32 (25.06)

ISTD 329.00>309.15 (-)	8.36e4

A=209704
5.8

O.OeO -

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 5.2015

R#1 313.00> 119.10 2.43 (2.21)
Q 313.00>269.00 (-)	8.92e5

7.5e5
5.0e5 :
2.5e5 :
O.OeO :

'A=2187377

R1 2-43 (-- |-RT= 5.945

6.2
RT (min)

13C-PFHpA_IS

Cone. 5.0000

A= 1532867
RT=6.349

13C-4 2-FTS

Cone. 4.1635

R#1 329.00>81.00 26.32 (25.06)
Q 329.00>309.15 (-)	8.36e4

TA=209704

7.5e4^R1 2632 ("Sm=5.890

5.0e4 -
2.5e4 ^
O.OeO -

180-PFHxS

Cone. 4.2061

Q 402.70>84.05 (-)
2.0e5 -i

~ a=475401
RT=6.356

O.OeO -

L

13C2-6 2-FTS IS

Cone. 4.7500

13C2-6 2-FTS

Cone. 3.9408

6.4 6.6

RT (min)

PFHpS

Cone. 4.4681

R#1 449.00>99.20 65.00 (55.18)
Q 449.00>80.15 (-)	1.36e5

r A=322843
IR1 65.00 |-rar=6.660

6.2

6.4

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

I STD 416.80 >372.05 (-)
7.5e5 -
5.0e5 ^

2.5e5 ^

O.OeO 1 , , ,

13C-PFOA

Cone. 4.5975

Q 416.80>372.05 (-)
7.5e5 -

¥A= 1936110
RT=6.668

O.OeO

6.6 6.8

RT (min)

PFOS

Cone. 4.4971

R#1 499.00>99.00 92.37 (93.90)
Q 499.00>80.00 (-)	6.66e4

=207981

13C-PFOS IS

Cone. 4.7750

5.0e5 :
2.5e5 :
O.OeO :



6.0e4 ^

R1 92.37 (--

-h=6.954

4.0e4 ^







2.0e41







O.OeO1

A

I

r

105 (-)

6.8 7.0
RT (min)

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

1.5e5-
1.0e5i
5.0e4 ^
O.OeO -

A-=444010
RT=6.955

1

4-2-FtS

Cone. 4.5027

R#1 327.00>81.10 15.77 (17.01)
Q 327.00>307.05 (-)	9.16e4

7.5e4 -
5.0e4z_
2.5e4z_
O.OeO -

IR1 15.77 (

~ A=224037
¦^"Wr= 5.891

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 4.9785

R#1 349.00>99.00 80.60 (89.24)
Q 349.00>79.95 (-)	1.37e5

TA=333435
]R1 80.60 (-1-^=5.986

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 4.2106

R#1 399.00 >99.00 96.81 (92.93)
Q 399.00>80.00 (-)	8.95e4

fA=254401

JR1 96.81 (• -1=6.355

6.2

RT (min)

6.6
RT (min)

PFHpA

Cone. 5.1869

R#1 362.90 >169.00 16.84 (16.60)
Q 362.90>319.00 (-)	1.01e6

1.0e6

O.OeO



A=2371435

_ R1 16.84(-

-M=6.349

/

'l\. ~

6.6
RT (min)

6-2-FTS

Cone. 4.5380

R#1 427.00>80.90 27.37 (29.85)
Q 427.00>407.00 (-)	7.90e4

fA= 187529

7.5e4qR-| 27.37 RT=6.650

6.2 6.4 6.6

RT (min)

PFOA

Cone. 4.8223

R#1 413.00 >169.10 27.91 (28.84)
Q 413.00>369.00 (-)	1.04e6

1.0e6

'A.=2537943

1R1 27.91 ( | -Rjf=6.6

RT (min)

6.6 6.8 7.0
RT (min)

13C-PFOS

Cone. 3.9130

1.83e5 Q 502.80>80.05 (-)

^.SeS1_

"{.OeSz
S.0e4z_

O.OeO 4==

A-=444010
RT=6.955

1

7.2

RT (min)

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

268

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*

Insight Report



Quantitation/lntegration

Ok ls5

Printed 10/26/2023 11:05:08

CCV2-230428 (continued)

PFNA

Cone 4.5481

R#1 463.00>219.00 20.74 (19.07)

Q 463.00 		7.60e5

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

A=1908269
RTj= 6.975

13C-8_2-FTSJS

Cone. 4.7900

ISTD 528.80> 509.00 (-)

y A=98248
\\ RtI7.304

3.0e4 -
2.0e4 :
1.0e4:
O.OeO -

d3-N-MeFOSAA_IS

Cone. 5.0000

ISTD 572.80>419.05 (-)

f A=655086
I RT^7.482

13C-PFUnDA

Cone. 4.9211

Q 564.80>519.95 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

FA=1835135
| RT=b.653

7.6

13C-PFNAJS

Cone. 5.0000

ISTD 467.80>423.00 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

f A=1757290
I Rli=6.975

13C-PFNA

Cone. 4.6949

7.11e5 Q 467.80>423.00 (-)

6.0e5 i
4.0e5 i
2.0e5 i
O.OeO

7.2

RT (min)

6.8 7.0 7.2

RT (min)

13C-82-FTS

Cone. 3.9528

3.87e4 Q 528.80> 509.00 (-)

f A=98248
M RtI 7.304

3.0e4 -
2.0e4 :
1.0e4:
O.OeO -

7.6
RT (min)

2.44e5 Q 572.80>419.05 (-)

f A=655086
1 RT^7.482

7.8
RT (min)

O.OeO -

7.4

7.8 8.0
RT (min)

PFOSA

Cone. 4.5236

R#1 498.20 >64.10 0.18 (0.11)

Q 498.20>78.00 (-)	1.81e5

13C-FOSAJS

Cone. 5.0000

ISTD 506.00>78.05 (-;

f A=1757290
I Rli=6.975

6.8

7.0

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

~ A= 1808529
V RT 4 7.308

-JW

7.2 7.4 7.6

RT (min)

d3-N-MeFOSAA

Cone. 5.3023

7.2

7.4

2.44e5

7.6 7.8
RT (min)

PFUnDA

Cone. 4.5748

R#1 563.00>219.00 13.10 (12.92)

Q 563.00>518.90 (-)	6.10e5

6.0e5 -
4.0e5 ^
2.0e5 :
O.OeO -

7.25 7.50 7.75

d5-N-EtFOSAAJS

Cone. 5.0000

ISTD 588.80>419.00 (-)

f A=736966
I RT=b.664

7.8 8.0
RT (min)

13C-FOSA

Cone. 4.6923

RT (min)

RT (min)

PFNS

Cone. 4.9952

R#1 549.00>99.00 62.76 (69.83)

8-2-FTS

Cone. 4.3776

R#1 527.20>487.00 6.73 (6.24)

Q 549.0'		2.12e5 Q 527.10>506.90 (-]

f A=,530980

|"RTj= 7.278

7.2

RT (min)
PFDA

Cone. 4.7581

R#1 512.90>219.00 17.91 (17.97)
3.87e4 Q 512.90>469.00 (-)	7.21e5

13C-PFDAJS

Cone. 5.0000

ISTD 514.80>469.95 (-;
7.5e5 -

~ A=2007055
RT^ 7.307

5.0e5 -
2.5e5:
O.OeO :

7.6
RT (min)

NMeFOSAA

Cone. 4.7782

R#1 570.20>512.00 41.36 (38.98)
Q 570.20>419.00 (-)	1.97e5

# A=621264
;t'^Rt[=7.487

7.2

7.4

359531
RT=7.615

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 5.5947

2.58e5 Q 588.80>419.00 (-)

O.OeO-

f A=736966
I RT=[7.664

7.8 8.0
RT (min)

7.6

7.8 8.0

RT (min)

A=102216
b /3 RT=7.303

7.4 7.6
RT (min)

7.6
RT (min)

13C-PFDA

Cone. 4.7367

Q 514.80>469.95 (-;
7.5e5 -

Y A=2007055
II RT^7.307

7.6
RT (min)

PFDS

Cone. 4.5893

R#1 599.00>99.00 64.42 (59.45)
Q 599.00>80.10 (-)	1.38e5

f A=.

5.0e5 -
2.5e5:
O.OeO :

13C-PFUnDAJS

Cone. 5.0000

7.6
RT (min)

ISTD 564.80>519.95 (-)

6.0e5 -
4.0e5 :
2.0e5:
O.OeO :

f A=1.835135
I RT=|7.653

7.6

7.8 8.0
RT (min)

NEtFOSAA

Cone. 4.2774

R#1 584.20>526.10 56.08 (51.48)

Q 584.20>418.95 (-)	1.91e5

1.5e5 -

1.0e5:
5.0e4:
O.OeO -

~ A=623584

|'| RT]=7 671

7.8 8.0
RT (min)

PFDoA

Cone. 4.2130

R#1 613.05>169.00 16.71 (17.39)

Q 613.0	6.88e5

7.50 7.75 8.00

RT (min)

13C-PFDoA_IS

Cone. 5.0000

ISTD 614.80> 569.95 (-)

7.30e5

6.0e5 -
4.0e5 ^
2.0e5 ^
O.OeO - .

f/\= 1934664
I RT=}.994

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

268

-------
A

(al^)

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:08

CCV2-230428 (continued)

13C-PFDoA

Cone. 5.2893

Q614.80>569.95 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

fA= 1934664
I RT=7.994

NEtFOSE

Cone. 4.1485

Q 629.50>59.10 (-)
3.0e5 -

2.0e5 ^

1.0e5-j

O.OeO r; . r~

A=793034
RT=8.747

d3-NMeFOSA

Cone. 5.1092

Q 515.10> 169.00 (-)

6.0e5 -
4.0e5 -
2.0e5 -
O.OeO -

A= 1754315
R1 10.3 rt^8 617

8.6

10-2-FtS

Cone. 4.9175

R#1 626.50>81.05 64.26 (57.89)
Q 626.50>607.05 (-)	4.31e4

4.0e4HR1 64.2dW4oo5

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 4.9416

1.92e5 Q 531.10> 169.10 (-)

RT (min)

RT (min)

d9-EtFOSE IS

Cone. 5.0000

3.08e5 ISTD 638.90> 59.10 (-)

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

9.0
RT (min)

1,82e5 I STD 623.00 > 59.00 (-)

8.4 8.6

RT (min)

PFTeDA

Cone. 4.8620

R#1 713.00 >169.30 10.31 (10.00)
Q 713.00>668.90 (-)	6.54e5

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

3.0e5 -
2.0e5 -
1.0e5-
O.OeO -

fA= 1007758
RT=8 617

.8 9.0
RT (min)

L-PFDoS

Cone. 5.5408

R#1 698.80>98.80 67.14 (75.26)
Q 698.80>80.10 (-)	6.64e4

NaDONA

Cone. 4.5311

Q 377.10>251.20 (-)

1680677
=6.395

8.4 8.6
RT (min)

.8 9.0

RT (min)

d9-EtFOSE

Cone. 6.6435

7.18e4 Q 638.90> 59.10 (-)

8.6 8.8 9.0

RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

8.6 8.8 9.0

RT (min)

d7-N-MeFOSE

Cone. 6.1764

1.28e5 Q 623.00> 59.00 (-)

RT (min)

RT (min)

13C-PFTeDA

Cone. 4.1885

3.80e5 Q 714.80>669.80 (-)

fA= 1007758
I RT=8 617

8.6 8.8 9.0
RT (min)

11CI-PF30UdS

Cone. 5.2569

Q 631.00>451.10 (-)
2.0e5 -

8.6 8.8 9.0
RT (min)

PFHxDA

Cone. 4.2826

PFODA

Cone. 4.8112

7.41 e5 Q 812.90>769.00 (-)

4.84e5 Q 912.80>869.00 (-)

6.2 6.4 6.6

RT (min)

9.0 9.2 9.4

RT (min)

NMeFOSE

Cone. 5.0716

Q 616.10>58.90 (-)
1.0e5H

9.0
RT (min)

NMeFOSA

Cone. 4.8328

R#1 512.10>219.20 77.13 (76.68)
Q 512.10> 169.20 (-)	8.10e4

A=208915
7.5e4HR1 77.13 (-f ^T=8.521

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

8.4 8.6 8.8
RT (min)
NEtFOSA

Cone. 5.0423

R#1 526.50>219.20 61.25 (65.87)
1.28e5 Q 526.50> 169.10 (-)	1.46e5

{A=371240

I R1 61.25 i | £j=8.783

8.4 8.6

RT (min)

PFTrDA

Cone. 5.3197

R#1 663.10> 169.10 18.60 (18.12)
Q 663.10>618.90 (-)	6.38e5

~ A=1(

28539

-R1 18.60|(RT^

.320

JL

r

8.6

RT (min)

9CI-PF30NS

Cone. 5.0989

2.16e5 Q 531.00>351.10 (-)

RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

2.98e5 I STD 815.00 > 770.00 (-)

f A=3444918
RT=9146

9.6 9.8 10.0

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

2 m

-------


Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:08

CCV2-230428 (continued)

13C2-PFHxDA

Cone 4.5190

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

1.43e6 ISTD 569.80>524.90 (-)

PFBSA

Cone. 4.9908

O.OeO

9.4
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	3.00e0

5.0e0 -

0.2
RT (min)

PFecHS

Cone. 4.9139
R#1 461.00>99.10 38.10 (38.19)

5.56e5 Q 461.00>381.00 (-)	7.97e5 Q 298.00>78.00 (-)

f A= 1980153
7.5e5 HR1 38.10 (-|-m"=6.619

RT (min)

PFHxSA

Cone. 4.6747

Q 397.90>78.00 (-)
4.0e5 -i

6.4
RT (min)

7.2
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

27®

-------
Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:12

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/30/2023 6:17:08 AM

Acquired by: System Administrator

Data File: 230428241

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.207

677857

677857

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.207

677857

1362001

13C7-PFUnDA IS

5.0000

4.6915

nq/mL

PFBA

Auto

4.208

12733

677857

13C-PFBA IS

0.1000

0.0840

nq/mL

13C-PFPeA IS

Auto

5.366

1026645

1026645

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.366

1026645

1362001

13C7-PFUnDA IS

5.0000

4.4227

nq/mL

PFPeA

Auto

5.367

20527

1026645

13C-PFPeA IS

0.1000

0.1086

nq/mL

13C-PFBS IS

Auto

5.496

416272

416272

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.496

416272

1362001

13C7-PFUnDA IS

4.6500

4.0866

nq/mL

PFBS

Auto

5.497

5601

416272

13C-PFBS IS

0.0880

0.0867

nq/mL

13C HFPO DA IS

Auto

6.096

252960

252960

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.096

252960

1362001

13C7-PFUnDA IS

5.0000

5.0184

nq/mL

HFPO DA

Auto

6.097

3718

252960

13C HFPO DA IS

0.1000

0.1005

nq/mL

13C-4 2-FTS IS

Auto

5.897

167768

167768

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.897

167768

1362001

13C7-PFUnDA IS

4.6700

3.6829

nq/mL

4-2-FtS

Auto

5.900

3777

167768

13C-4 2-FTS IS

0.0930

0.0949

nq/mL

PFHxA

Auto

5.951

37640

1372622

13C-PFHxA IS

0.1000

0.1032

nq/mL

13C-PFHxA IS

Auto

5.951

1372622

1372622

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

5.951

1372622

1362001

13C7-PFUnDA IS

5.0000

4.3521

nq/mL

PFPeS

Auto

5.991

6025

427429

180-PFHxS IS

0.0940

0.1000

nq/mL

PFHxS

Auto

6.362

5443

427429

180-PFHxS IS

0.0910

0.1002

nq/mL

13C-PFHpA IS

Auto

6.356

1353437

1353437

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.356

1353437

1362001

13C7-PFUnDA IS

5.0000

4.4175

nq/mL

180-PFHxS IS

Auto

6.363

427429

427429

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.363

427429

1362001

13C7-PFUnDA IS

4.7250

4.1813

ng/mL

PFHpA

Auto

6.357

42333

1353437

13C-PFHpA IS

0.1000

0.1049

ng/mL

13C2-6 2-FTS IS

Auto

6.657

175501

175501

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.657

175501

1362001

13C7-PFUnDA IS

4.7500

3.6779

ng/mL

PFHpS

Auto

6.663

6415

427429

180-PFHxS IS

0.0950

0.0988

nq/mL

6-2-FTS

Auto

6.654

4187

175501

13C2-6 2-FTS IS

0.0950

0.1200

nq/mL

PFOA

Auto

6.674

44991

1707734

13C-PFOA IS

0.1000

0.0969

nq/mL

13C-PFOA IS

Auto

6.673

1707734

1707734

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.673

1707734

1362001

13C7-PFUnDA IS

5.0000

4.4837

nq/mL

PFOS

Auto

6.960

3728

395663

13C-PFOS IS

0.0930

0.0905

nq/mL

13C-PFOS IS

Auto

6.959

395663

395663

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

6.959

395663

1362001

13C7-PFUnDA IS

4.7750

3.8554

nq/mL

PFNA

Auto

6.978

34302

1622638

13C-PFNA IS

0.1000

0.0885

nq/mL

13C-PFNA IS

Auto

6.978

1622638

1622638

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.978

1622638

1362001

13C7-PFUnDA IS

5.0000

4.7933

nq/mL

PFNS

Auto

7.282

9595

395663

13C-PFOS IS

0.0960

0.1013

nq/mL

8-2-FTS

Auto

7.305

1226

80588

13C-8 2-FTS IS

0.0960

0.0815

nq/mL

13C-8 2-FTS IS

Auto

7.308

80588

80588

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.308

80588

1362001

13C7-PFUnDA IS

4.7900

3.5849

nq/mL

PFDA

Auto

7.314

29845

1727182

13C-PFDA IS

0.1000

0.0912

m

13C-PFDA IS

Auto

7.313

1727182

1727182

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.313

1727182

1362001

13C7-PFUnDA IS

5.0000

4.5069

m

d3-N-MeFOSAA IS

Auto

7.487

591384

591384

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.487

591384

1362001

13C7-PFUnDA IS

5.0000

5.2925

m

NMeFOSAA

Auto

7.493

11167

591384

d3-N-MeFOSAA IS

0.1000

0.0951

nq/mL

PFDS

Auto

7.624

6103

395663

13C-PFOS IS

0.0960

0.0874

m

13C-PFUnDA IS

Auto

7.658

1626678

1626678

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.658

1626678

1362001

13C7-PFUnDA IS

5.0000

4.8231

m

PFUnDA

Auto

7.658

30219

1626678

13C-PFUnDA IS

0.1000

0.0949

nq/mL

d5-N-EtFOSAA IS

Auto

7.669

643438

643438

	

5.0000

5.0000

m

d5-N-EtFOSAA

Auto

7.669

643438

1362001

13C7-PFUnDA IS

5.0000

5.4008

nq/mL

NEtFOSAA

M

7.677

12866

643438

dS-N-EtFOSAA IS

0.1000

0.1011

m

PFOSA

Auto

7.741

7563

441101

13C-FOSA IS

0.1000

0.0800

nq/mL

13C-FOSA IS

Auto

7.745

441101

441101

	

5.0000

5.0000

m

13C-FOSA

Auto

7.745

441101

1362001

13C7-PFUnDA IS

5.0000

4.9202

nq/mL

PFDoA

Auto

7.999

36326

1717685

13C-PFDoA IS

0.1000

0.0947

nq/mL

13C-PFDoA IS

Auto

8.000

1717685

1717685

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

272

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A

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:12

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.000

1717685

1362001

13C7-PFUnDA IS

5.0000

5.1923

nq/mL

10-2-FtS

Auto

8.007

1838

80588

13C-8 2-FTS IS

0.0960

0.0898

ng/mL

d5-NEtFOSA IS

Auto

8.781

474251

474251

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.781

474251

1362001

13C7-PFUnDA IS

5.0000

5.1631

ng/mL

NMeFOSE

Auto

8.506

5193

307214

d7-N-MeFOSE IS

0.1000

0.1035

nq/mL

NEtFOSE

Auto

8.756

15353

187660

d9-EtFOSE IS

0.1000

0.0825

ng/mL

d9-EtFOSE IS

Auto

8.737

187660

187660

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.737

187660

1362001

13C7-PFUnDA IS

5.0000

7.1534

ng/mL

NMeFOSA

Auto

8.530

3818

442983

d3-NMeFOSA IS

0.1000

0.0935

nq/mL

dB-NMeFOSA IS

Auto

8.524

442983

442983

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.524

442983

1362001

13C7-PFUnDA IS

5.0000

5.3338

nq/mL

d7-N-MeFOSE IS

Auto

8.490

307214

307214

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.490

307214

1362001

13C7-PFUnDA IS

5.0000

6.6008

nq/mL

NEtFOSA

M

8.792

7950

474251

d5-NEtFOSA IS

0.1000

0.1143

ng/mL

PFTrDA

Auto

8.325

28963

968474

13C-PFTeDA IS

0.1000

0.0984

nq/mL

PFTeDA

Auto

8.626

32380

968474

13C-PFTeDA IS

0.1000

0.0934

ng/mL

13C-PFTeDA IS

Auto

8.626

968474

968474

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.626

968474

1362001

13C7-PFUnDA IS

5.0000

4.4506

ng/mL

11CI-PFBOUdS

Auto

7.810

9282

395663

13C-PFOS IS

0.0940

0.1024

nq/mL

9CI-PF30NS

Auto

7.138

18870

395663

13C-PFOS IS

0.0930

0.0966

ng/mL

L-PFDoS

Auto

8.275

3039

395663

13C-PFOS IS

0.0970

0.1153

nq/mL

NaDONA

Auto

6.402

29287

1622638

13C-PFNA IS

0.0940

0.0855

ng/mL

PFHxDA

Auto

9.154

32145

2931903

13C2-PFHxDA IS

0.1000

0.0987

nq/mL

PFODA

Auto

9.687

14744

2931903

13C2-PFHxDA IS

0.1000

0.0985

ng/mL

1BC2-PFHxDA IS

Auto

9.155

2931903

2931903

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.155

2931903

1362001

13C7-PFUnDA IS

5.0000

4.2525

ng/mL

13C7-PFUnDA IS

Auto

7.658

1362001

1362001

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.626

33961

395663

13C-PFOS IS

0.0920

0.0946

ng/mL

PFBSA

Auto

6.134

22215

441101

13C-FOSA IS

0.1000

0.0966

nq/mL

PFHxSA

Auto

6.962

18255

1622638

13C-PFNA IS

0.1000

0.0911

ng/mL

CHARGE

ND(W/B)

	

	

1362001

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 4.6915
1.49e5 Q 217.20>172.30 (-)

PFBA

Cone. 0.0840
1.49e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
3.52e3 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.4227
4.09e5 Q 267.90>223.00 (-)

r A=677857
RT=4.207

O.OeO

O.OeO



II
<



RT=4.208

J

L



4.0e5

1026645
T= 5.366

O.OeO

4.00 4.25 4.50 4.00	4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS PFBS

Cone. 0.1086	Cone. 4.6500	Cone. 4.0866 Cone. 0.0867

4.0e5

1026645
T= 5.366

O.OeO

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)

7.24e3 ISTD 301.80>80.00 (-)

=416272
T= 5.496

1.50e5 Q 301.80>80.00 (-)
1.5e5 -i

R#1 298.80>99.00 75.22 (68.21)

1.50e5 Q 299.00>80.00 (-)	2.01e3 ISTD 332.10>287.10 (-)	1.07e5

1

A=416272
*T= 5.496

_ R1 75.22 (-

5.6 5.8
RT (min)

5.6 5.8
RT (min)

fA=252960
RT=6.096

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

272

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:12

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 5.0184

Q 332.10>287.10 (-)
1.0e5 -

A=252960
fl"=6.096

HFPO DA

Cone. 0.1005

R#1 329.00>285.10 112.53 (71.09)
Q 329.00>169.00 (-)	1.46e3

- R1 112.53

O.OeO -

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 0.1032

R#1 313.00>119.10 1.18 (2.21)
Q 313.00>269.00 (-)	1.75e4

fA=37640

]R1 1.18 (- \iT=5.951

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

13C-PFHpA_IS

Cone. 5.0000

13C-PFHpA

Cone. 4.4175

ISTD 366.90>322.10 (-)	5.82e5 Q 366.90>322.10 (-)

JA= 13534;
fIt=6.356

4.0e5 -

A=1353437
'T=6.356

6.6

RT (min)

13C2-6 2-FTS IS

Cone. 4.7500

13C2-6 2-FTS

Cone. 3.6779

ISTD 428.90>409.00 (-)

^=175501
=6.657

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

7.52e4 Q 428.90>409.00 (-)

6.0e4 i
4.0e4 i
2.0e4 i
O.OeO 1, i i

^=175501
=6.657

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

13C-PFOA

Cone. 4.4837

7.12e5 Q416.80>372.05 (-)

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

^=1707734
=6.673

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

^=1707734
=6.673

6.8 7.0
RT (min)

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 26.07 (25.06)

I STD 329.00 > 309.15 (-)	6.89e4

~ A= 167768

^R1 26-07 (-ft RT= 5.897

O.OeO , , \rnr~.

5.8 6.0 6.2
RT (min)

13C-PFHxA

Cone. 4.3521

5.49e5 Q 314.90>270.10 (-)



'A=1372622



—I
II

Id

1 /

vv

6.2
RT (min)

180-PFHxS IS

Cone. 4.7250

5.82e5 ISTD 402.70>84.05 (-)

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

T^=4

i RT='

427429
6.363

6.6

RT (min)

6.2

w

6.8 7.0
RT (min)

13C-4 2-FTS

Cone. 3.6829

R#1 329.00>81.00 26.07 (25.06)
Q 329.00>309.15 (-)	6.89e4

TA= 167768

6.0e4^R1 2607	5.897

4.0e4 ^

2.0e4 ^

O.OeO -

5.49e5

6.0 6.2

RT (min)

180-PFHxS

Cone. 4.1813

1.86e5 Q 402.70>84.05 (-)

^.SeSz_

^.0eS1_

5.0e4 i
O.OeO 1 . .

A=427429
'T=6.363

6.4 6.6

RT (min)

PFHpS

Cone. 0.0988

R#1 449.00>99.20 73.51 (55.18)
Q 449.00>80.15 (-)	2.54e3

6.2

6.4

O.OeO

6.6 6.8

RT (min)

PFOS

Cone. 0.0905

R#1 499.00>99.00 87.19 (93.90)
Q 499.00>80.00 (-)	1.08e3

A=3728
1.0e3 —IR1 87.19 (--J4t=6.960

A=98
RT=7.128

13C-PFOS IS

Cone. 4.7750

6.75 7.00 7.25

RT (min)

ISTD 502.8
1.5e5^
1.0e5^
5.0e4 ^
O.OeO 4=

105 (-)

TA=395663
RT=6.959



4-2-FtS

Cone. 0.0949

R#1 327.00>81.10 23.05 (17.01)
Q 327.00>307.05 (-)	1.62e3

A=3777
5.900

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 0.1000

R#1 349.00>99.00 66.54 (89.24)
Q 349.00>79.95 (-)	2.55e3

f A=6025

:R1 66.54 {-\hj= 5.991

6.0 6.2
RT (min)

PFHxS

Cone. 0.1002

R#1 399.00 >99.00 77.08 (92.93)
Q 399.00>80.00 (-)	2.05e3

2.0e3 -

R1 77.08 (-

6.2

RT (min)

O.OeO

6.6
RT (min)

PFHpA

Cone. 0.1049

R#1 362.90 >169.00 19.67 (16.60)
Q 362.90>319.00 (-)	1.80e4

6.6
RT (min)

6-2-FTS

Cone. 0.1200

R#1 427.00>80.90 23.62 (29.85)
Q 427.00>407.00 (-)	1.56e3

: R1 23.62 (-f\-RT=6.654

6.6
RT (min)

PFOA

Cone. 0.0969

R#1 413.00 > 169.10 29.67 (28.84)
Q 413.00>369.00 (-)	1.95e4

y A=44991

-R1 29.67 (-1-^=6.674

RT (min)

13C-PFOS

Cone. 3.8554

Q 502.8
1.5e5^
1.0e5^
5.0e4 ^
O.OeO :

105 (-)

7.2

RT (min)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

278

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:12

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0885

R#1 463.00>219.00 15.55 (19.07)
Q 463.00>418.90 (-)	1.40e4

- R1 15.55 (

A=34302
R"fl=6.978

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)
3.0e4 -

2.0e4 :
1.0e4:
O.OeO :

A=80588
Rli 7.308



d3-N-MeFOSAAJS

Cone. 5.0000

ISTD 572.80>419.05 (-)
2.0e5 -

1.0e5 -

13C-PFUnDA

Cone. 4.8231

Q 564.80>519.95 (-)
6.0e51

3.0e3 :
2.0e3 ^
1.0e3 ^
O.OeO :

f A=7563

R1 0.00 (-- RT=7.741

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

6.0e5 ^



R"lJ=6.978

4.0e5 ^





2.0e51





0 0<=>0 -





7.2

RT (min)

13C-8 2-FTS

Cone. 3.5849

3.12e4 Q 528.80> 509.00 (-)

3.0e4 :
2.0e4 :
1.0e4:
O.OeO :

~ A=80588

D

RTt 7.308



7.6
RT (min)

d3-N-MeFOSAA

Cone. 5.2925

Q 572.80>419.05 (-)
2.0e5 -

1.0e5 -

O.OeO

7.6 7.8
RT (min)

626678
7.658

7.8 8.0
RT (min)

PFOSA

Cone. 0.0800

R#1 498.20>64.10 0.00 (0.11)
Q 498.20>78.00 (-)	3.10e3

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

1.5e5 ^

1.0e5 ^

5.0e4 ^

O.OeO 1 r . r

7.8 8.0

RT (min)

13C-PFNA

Cone. 4.7933

PFNS

Cone. 0.1013

R#1 549.00>99.00 41.05 (69.83)
Q 549.00>79.95 (-)	3.83e3

8-2-FTS

Cone. 0.0815

R#1 527.20>487.00 3.29 (6.24)
Q 527.10>506.90 (-)	5.03e2

f A=1226

IR1 3.29 ( \-Rtf7.305

7.2
RT (min)

PFDA

Cone. 0.0912

R#1 512.90>219.00 14.53 (17.97)
Q 512.90>469.00 (-)	1.23e4

7.6
RT (min)

7.4 7.6 7.8

RT (min)

PFUnDA

Cone. 0.0949

R#1 563.00>219.00 13.26 (12.92)
Q563.00>518.90 (-)	1.15e4

30219

10e4^R1 13-26fjRT= 7.658

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

13C-FOSA

Cone. 4.9202

1.72e5 Q 506.00>78.05 (-)

1.5e5 ^

1.0e5 ^

5.0e4 ^
== O.OeO 1r .

7.8 8.0

RT (min)

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDAJS

Cone. 5.0000

13C-PFDA

Cone. 4.5069

ISTD 514.80>469.95 (-)

6.89e5 Q 514.80>469.95 (-)

*A= 1727182
Rl>7.313

O.OeO

7.6
RT (min)

NMeFOSAA

Cone. 0.0951

R#1 570.20 > 512.00 46.81 (38.98)
Q 570.20>419.00 (-)	3.37e3

~ A= 11167

IR1 46.81 (-4-^=7.493

O.OeO -



A=1727182
RTp7.313

7.2

7.4

7.6
RT (min)

PFDS

Cone. 0.0874

R#1 599.00>99.00 69.76 (59.45)
Q 599.00>80.10 (-)	2.13e3

2.0e3_Rl 69.761^-^1=17 624

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

626678
7.658

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 5.4008

Q 588.80>419.00 (-)	2.30e5

f A=643438
2.0e5 -|	I RT=7.669

O.OeO

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.1011

R#1 584.20>526.10 58.88 (51.48)
Q 584.20>418.95 (-)	3.54e3

7.8 8.0
RT (min)

: R1 58.88 (-

Rl|=7.677





7.8 8.0
RT (min)

PFDoA

Cone. 0.0947

R#1 613.05> 169.00 13.11 (17.39)
Q 613.05>569.00 (-)	1.31e4

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

6.61 e5

7.8 8.0

RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

27S

-------
Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:12

L0.1ppb_230323 (continued)

13C-PFDoA

Cone 5.1923

Q 614.80>569.95 (-)	6.61e5

RT (min)

NEtFOSE

Cone. 0.0825

Q 629.50> 59.10 (-)	6.00e3

RT (min)

d3-NMeFOSA

Cone. 5.3338

Q 515.10>169.00 (-)	1.71e5

RT (min)

PFTeDA

Cone. 0.0934

R#1 713.00 >169.30 9.07 (10.00)
Q 713.00>668.90 (-)	1.15e4

RT (min)

L-PFDoS

Cone. 0.1153

R#1 698.80>98.80 46.33 (75.26)
Q 698.80>80.10 (-)	1.36e3

RT (min)

10-2-FtS

Cone. 0.0898

R#1 626.50>81.05 54.47 (57.89)
Q 626.50>607.05 (-)	8.60e2

RT (min)

d9-EtFOSE IS

Cone. 5.0000

ISTD 638.90> 59.10 (-)	7.08e4

RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

I STD 623.00 >59.00 (-)	1.21e5

RT (min)

13C-PFTeDA IS

Cone. 5.0000

I STD 714.80 >669.80 (-)	3.60e5

RT (min)

NaDONA

Cone. 0.0855

Q 377.10>251.20 (-)	1.28e4

RT (min)

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)	1.84e5

RT (min)

d9-EtFOSE

Cone. 7.1534

Q 638.90> 59.10 (-)	7.08e4

RT (min)

d7-N-MeFOSE

Cone. 6.6008

Q 623.00> 59.00 (-)	1.21e5

RT (min)

13C-PFTeDA

Cone. 4.4506

Q 714.80>669.80 (-)	3.60e5

RT (min)

PFHxDA

Cone. 0.0987

Q 812.90>769.00 (-)	1.36e4

RT (min)

d5-NEtFOSA

Cone. 5.1631

Q 531.10>169.10 (-)	1.84e5

RT (min)

NMeFOSA

Cone. 0.0935

R#1 512.10>219.20 45.06 (76.68)
Q 512.10> 169.20 (-)	1.71e3

RT (min)

NEtFOSA

Cone. 0.1143

R#1 526.50>219.20 47.89 (65.87)
Q 526.50>169.10 (-)	3.22e3

RT (min)

11CI-PF30UdS

Cone. 0.1024

Q 631.00>451.10 (-)	3.73e3

RT (min)

PFODA

Cone. 0.0985

Q 912.80>869.00 (-)	5.27e3

RT (min)

NMeFOSE

Cone. 0.1035

Q 616.10>58.90 (-)	2.10e3

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)	1.71e5

RT (min)

PFTrDA

Cone. 0.0984

R#1 663.10> 169.10 21.43 (18.12)
Q 663.10>618.90 (-)	1.08e4

RT (min)

9CI-PF30NS

Cone. 0.0966

Q 531.00>351.10 (-)	7.53e3

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

I STD 815.00 > 770.00 (-)	1,25e6

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

276

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)

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:12

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 4.2525

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 0.0966

PFecHS

Cone. 0.0946
R#1 461.00>99.10 36.28 (38.19)

1,25e6 ISTD 569.80> 524.90 (-)	5.02e5 Q 461.00>381.00 (-)	1,39e4 Q 298.00>78.00 (-)

362001
7.658

O.OeO

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

A=22215
RT=6.134

PFHxSA

Cone. 0.0911

8.78e3 Q 397.90>78.00 (-)	7.34e3

A= 18255

6.4 6.6 6.8

RT (min)

6.0 6.2 6.4
RT (min)

^ I

RT=6.962

^ I



i | i iAi

i i i i i i i i

6.8

7.0 7.2



RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

27B

-------
Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:17

CCV3-230428

Sample ID: CCV3-230428

Date Acquired: 4/30/2023 6:30:52 AM

Acquired by: System Administrator

Data File: 230428242

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.209

676515

676515

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.209

676515

1517711

13C7-PFUnDA IS

5.0000

4.2018

nq/mL

PFBA

Auto

4.209

877500

676515

13C-PFBA IS

5.0000

5.8014

nq/mL

13C-PFPeA IS

Auto

5.367

1195035

1195035

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.367

1195035

1517711

13C7-PFUnDA IS

5.0000

4.6199

nq/mL

PFPeA

Auto

5.367

1161282

1195035

13C-PFPeA IS

5.0000

5.2778

nq/mL

13C-PFBS IS

Auto

5.497

474653

474653

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.497

474653

1517711

13C7-PFUnDA IS

4.6500

4.1816

nq/mL

PFBS

Auto

5.496

319411

474653

13C-PFBS IS

4.4200

4.3348

nq/mL

13C HFPO DA IS

Auto

6.095

309618

309618

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.095

309618

1517711

13C7-PFUnDA IS

5.0000

5.5123

nq/mL

HFPO DA

Auto

6.096

224967

309618

13C HFPO DA IS

5.0000

4.9676

nq/mL

13C-4 2-FTS IS

Auto

5.897

203999

203999

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.897

203999

1517711

13C7-PFUnDA IS

4.6700

4.0188

nq/mL

4-2-FtS

Auto

5.897

230204

203999

13C-4 2-FTS IS

4.6700

4.7561

nq/mL

PFHxA

Auto

5.951

2170626

1574479

13C-PFHxA IS

5.0000

5.1885

nq/mL

13C-PFHxA IS

Auto

5.951

1574479

1574479

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

5.951

1574479

1517711

13C7-PFUnDA IS

5.0000

4.4800

nq/mL

PFPeS

Auto

5.993

331072

481334

180-PFHxS IS

4.6900

4.8823

nq/mL

PFHxS

Auto

6.361

244679

481334

180-PFHxS IS

4.5500

3.9998

nq/mL

13C-PFHpA IS

Auto

6.355

1519571

1519571

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.355

1519571

1517711

13C7-PFUnDA IS

5.0000

4.4509

nq/mL

180-PFHxS IS

Auto

6.362

481334

481334

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.362

481334

1517711

13C7-PFUnDA IS

4.7250

4.2256

ng/mL

PFHpA

Auto

6.356

2337685

1519571

13C-PFHpA IS

5.0000

5.1578

ng/mL

13C2-6 2-FTS IS

Auto

6.655

195344

195344

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.655

195344

1517711

13C7-PFUnDA IS

4.7500

3.6737

ng/mL

PFHpS

Auto

6.665

314498

481334

180-PFHxS IS

4.7600

4.2990

nq/mL

6-2-FTS

Auto

6.655

178860

195344

13C2-6 2-FTS IS

4.7400

4.6069

nq/mL

PFOA

Auto

6.673

2523623

1847241

13C-PFOA IS

5.0000

5.0258

nq/mL

13C-PFOA IS

Auto

6.673

1847241

1847241

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.673

1847241

1517711

13C7-PFUnDA IS

5.0000

4.3524

nq/mL

PFOS

Auto

6.959

219132

446046

13C-PFOS IS

4.6400

4.7165

nq/mL

13C-PFOS IS

Auto

6.959

446046

446046

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

6.959

446046

1517711

13C7-PFUnDA IS

4.7750

3.9004

nq/mL

PFNA

Auto

6.979

1881421

1773699

13C-PFNA IS

5.0000

4.4426

nq/mL

13C-PFNA IS

Auto

6.979

1773699

1773699

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.979

1773699

1517711

13C7-PFUnDA IS

5.0000

4.7020

nq/mL

PFNS

Auto

7.282

517903

446046

13C-PFOS IS

4.8000

4.8500

nq/mL

8-2-FTS

Auto

7.307

102071

94962

13C-8 2-FTS IS

4.7900

4.5285

nq/mL

13C-8 2-FTS IS

Auto

7.308

94962

94962

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.308

94962

1517711

13C7-PFUnDA IS

4.7900

3.7909

nq/mL

PFDA

Auto

7.312

1767520

1907179

13C-PFDA IS

5.0000

4.8937

m

13C-PFDA IS

Auto

7.312

1907179

1907179

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.312

1907179

1517711

13C7-PFUnDA IS

5.0000

4.4660

m

d3-N-MeFOSAA IS

Auto

7.487

652037

652037

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.487

652037

1517711

13C7-PFUnDA IS

5.0000

5.2367

m

NMeFOSAA

Auto

7.491

632317

652037

d3-N-MeFOSAA IS

5.0000

4.8860

nq/mL

PFDS

Auto

7.620

358618

446046

13C-PFOS IS

4.8200

4.5567

m

13C-PFUnDA IS

Auto

7.659

1831433

1831433

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.659

1831433

1517711

13C7-PFUnDA IS

5.0000

4.8731

m

PFUnDA

Auto

7.659

1661476

1831433

13C-PFUnDA IS

5.0000

4.6343

nq/mL

d5-N-EtFOSAA IS

Auto

7.670

710344

710344

	

5.0000

5.0000

m

d5-N-EtFOSAA

Auto

7.670

710344

1517711

13C7-PFUnDA IS

5.0000

5.3507

nq/mL

NEtFOSAA

M

7.677

655990

710344

dS-N-EtFOSAA IS

5.0000

4.6684

m

PFOSA

Auto

7.745

440026

463878

13C-FOSA IS

5.0000

4.4270

nq/mL

13C-FOSA IS

Auto

7.745

463878

463878

	

5.0000

5.0000

m

13C-FOSA

Auto

7.745

463878

1517711

13C7-PFUnDA IS

5.0000

4.6434

nq/mL

PFDoA

Auto

8.001

1771769

1895533

13C-PFDoA IS

5.0000

4.1837

nq/mL

13C-PFDoA IS

Auto

8.001

1895533

1895533

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

278

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:17

CCV3-230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.001

1895533

1517711

13C7-PFUnDA IS

5.0000

5.1421

nq/mL

10-2-FtS

Auto

8.012

122580

94962

13C-8 2-FTS IS

4.8200

5.0815

ng/mL

d5-NEtFOSA IS

Auto

8.781

510075

510075

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.781

510075

1517711

13C7-PFUnDA IS

5.0000

4.9834

ng/mL

NMeFOSE

Auto

8.504

265490

300901

d7-N-MeFOSE IS

5.0000

5.4035

nq/mL

NEtFOSE

Auto

8.756

779170

196754

d9-EtFOSE IS

5.0000

3.9920

ng/mL

d9-EtFOSE IS

Auto

8.737

196754

196754

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.737

196754

1517711

13C7-PFUnDA IS

5.0000

6.7306

ng/mL

NMeFOSA

Auto

8.529

207695

486742

d3-NMeFOSA IS

5.0000

4.6312

nq/mL

dB-NMeFOSA IS

Auto

8.524

486742

486742

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.524

486742

1517711

13C7-PFUnDA IS

5.0000

5.2594

nq/mL

d7-N-MeFOSE IS

Auto

8.489

300901

300901

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.489

300901

1517711

13C7-PFUnDA IS

5.0000

5.8018

nq/mL

NEtFOSA

Auto

8.790

371239

510075

d5-NEtFOSA IS

5.0000

4.9612

ng/mL

PFTrDA

Auto

8.326

1621715

1023279

13C-PFTeDA IS

5.0000

5.2170

nq/mL

PFTeDA

Auto

8.626

1757452

1023279

13C-PFTeDA IS

5.0000

4.7969

ng/mL

13C-PFTeDA IS

Auto

8.626

1023279

1023279

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.626

1023279

1517711

13C7-PFUnDA IS

5.0000

4.2200

ng/mL

11CI-PFBOUdS

Auto

7.812

518063

446046

13C-PFOS IS

4.7100

5.0690

nq/mL

9CI-PF30NS

Auto

7.139

1113465

446046

13C-PFOS IS

4.6600

5.0566

ng/mL

L-PFDoS

Auto

8.277

162002

446046

13C-PFOS IS

4.8400

5.4510

nq/mL

NaDONA

Auto

6.400

1669222

1773699

13C-PFNA IS

4.7100

4.4586

ng/mL

PFHxDA

Auto

9.155

1188166

3367243

13C2-PFHxDA IS

5.0000

4.4919

nq/mL

PFODA

Auto

9.687

857999

3367243

13C2-PFHxDA IS

5.0000

4.9923

ng/mL

13C2-PFHxDA IS

Auto

9.155

3367243

3367243

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.155

3367243

1517711

13C7-PFUnDA IS

5.0000

4.3828

ng/mL

13C7-PFUnDA IS

Auto

7.658

1517711

1517711

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.624

1968400

446046

13C-PFOS IS

4.6100

4.8624

ng/mL

PFBSA

Auto

6.134

1205390

463878

13C-FOSA IS

5.0000

4.9864

nq/mL

PFHxSA

Auto

6.961

1013715

1773699

13C-PFNA IS

5.0000

4.6278

ng/mL

CHARGE

ND(W/B)

	

	

1517711

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 4.2018
1.72e5 Q 217.20>172.30 (-)

PFBA

Cone. 5.8014
1.72e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
1.91 e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.6199
4.54e5 Q 267.90>223.00 (-)

A=877500
RT=4.209

=1195035
T= 5.367

0.0e0-

4.00 4.25 4.50	4.00 4.25 4.50	4.00 4.25 4.50

RT (min)	RT (min)	RT (min)

PFPeA	13C-PFBS IS	13C-PFBS	PFBS

Cone. 5.2778	Cone. 4.6500	Cone. 4.1816	Cone. 4.3348

=1195035
T= 5.367

0.0e0-

5.6	5.2 5.4 5.6

RT (min)	RT (min)

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)
4.0e5 H

4.09e5 ISTD 301.80>80.00 (-)

k=1161282
fl"= 5.367

^=474653
RT= 5.497

1.75e5 Q 301.80>80.00 (-)

1.5e5 ^

1.0e5 ^

5.0e4 ^

O.OeO 4=

R#1 298.80>99.00 69.95 (68.21)

1.75e5 Q 299.00>80.00 (-)	1.18e5 ISTD 332.10>287.10 (-)	1.32e5

A=474653
*T= 5.497

- R1 69.95 (-

A=309618
fl"=6.095

5.6 5.8
RT (min)

5.6 5.8
RT (min)

5.6 5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

278

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:17

CCV3-230428 (continued)

13C HFPO DA

Cone. 5.5123

Q 332.10>287.10 (-)

O.OeO -

6.0

7.5e5
5.0e5
2.5e5
O.OeO

rA=2170626

1R1 "I (-- $1=5.951

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)
6.0e5 ^

4.0e5 ^

2.0e5 ^

O.OeO 1 . . ,

A= 1519571
'T=6.355

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)
7.5e4 -

5.0e4 ^

2.5e4 ^

O.OeO 1, i i

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

=1847241
6.673

HFPO DA

Cone. 4.9676

R#1 329.00>285.10 73.13 (71.09)
Q 329.00>169.00 (-)	9.83e4



A=224967

-R1 73.13 (-

"^"=6.096

/



6.2 6.4
RT (min)

PFHxA

Cone. 5.1885

R#1 313.00 > 119.10 2.61 (2.21)
Q 313.00>269.00 (-)	8.89e5

6.2 6.4
RT (min)

13C-PFHxA IS

Cone. 5.0000

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 25.92 (25.06)

ISTD 329.00>309.15 (-)	8.32e4

TA=203999
7.5e4^1 25.92 (-|f]fr= 5.897

5.0e4 :

2.5e4 :

O.OeO:

5.8 6.0 6.2
RT (min)

13C-PFHxA

Cone. 4.4800

6.2
RT (min)

6.6

RT (min)

13C2-6 2-FTS

Cone. 3.6737

Q 428.90>409.00 (-)
7.5e4 -

5.0e4 ^

2.5e4 ^

O.OeO 1, i i

RT (min)

RT (min)

13C-PFOA

Cone. 4.3524

7.63e5 Q 416.80>372.05 (-)

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

A

L

6.8 7.0
RT (min)

6.8 7.0
RT (min)

13C-4 2-FTS

Cone. 4.0188

R#1 329.00>81.00 25.92 (25.06)
Q 329.00>309.15 (-)	8.32e4

TA=203999
7.5e4^1 25.92 ("1-^7=5.897

5.0e4 ^

2.5e4 ^

O.OeO -

180-PFHxS

Cone. 4.2256

Q 402.70>84.05 (-)
2.0e5 -

T^=4
I£r=-

O.OeO -

481334
6.362

6.2 6.4 6.6

RT (min)

PFHpS

Cone. 4.2990

R#1 449.00>99.20 63.31 (55.18)
Q 449.00>80.15 (-)	1.33e5

1 A=314498

JR1 63.31 (-[^=6.665

O.OeO , ,

6.6 6.8

RT (min)

PFOS

Cone. 4.7165

R#1 499.00>99.00 95.06 (93.90)
Q 499.00>80.00 (-)	6.47e4

fA=219132
6.0e4 - R1 95.06 (~J -*T=6.959

4.0e4 :
2.0e4 :
O.OeO :

6.2

6.4

6.0e4 -
4.0e4z_
2.0e4z_
O.OeO -

f A= 178860

HR1 26.78 (-|-hT=6.655

13C-PFOS IS

Cone. 4.7750

105 (-)

6.75 7.00 7.25

RT (min)

1.5e5-
We5z_
5.0e4 ^
O.OeO -

4-2-FtS

Cone. 4.7561

R#1 327.00>81.10 14.48 (17.01)
Q 327.00>307.05 (-)	9.52e4

~ A=230204

= R1 14.48 (4^=5.897

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 4.8823

R#1 349.00>99.00 76.99 (89.24)
Q 349.00>79.95 (-)	1.39e5

f A=331072
jR1 76.99 (-Ht=5.993

7.5e4 -
5.0e4z_
2.5e4z
O.OeO -

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 3.9998

R#1 399.00>99.00 95.65 (92.93)
Q 399.00>80.00 (-)	8.80e4

7.5e4
5.0e4:
2.5e4:
O.OeO :

- R1 95.65 (-

jy.

A=244679
m=6.361

6.2

RT (min)

6.2

6.4

6.6
RT (min)

PFHpA

Cone. 5.1578

R#1 362.90 >169.00 17.11 (16.60)
Q 362.90>319.00 (-)	9.95e5

6.6
RT (min)

6-2-FTS

Cone. 4.6069

R#1 427.00>80.90 26.78 (29.85)
Q 427.00>407.00 (-)	7.30e4

O.OeO

6.4 6.6

RT (min)

PFOA

Cone. 5.0258

R#1 413.00 > 169.10 27.68 (28.84)
Q 413.00>369.00 (-)	1.05e6

f A=2523623

1.0e6-R1 27.68 (M=6.673



RT (min)

6.6 6.8 7.0
RT (min)

13C-PFOS

Cone. 3.9004

1.84e5 Q 502.80>80.05 (-)

1.5e5-
^.0eSz
5.0e4 ^
O.OeO -

Y A=446046
RT=6.959

1

7.2

RT (min)

6.8 7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

2S0

-------
A

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:17

CCV3-230428 (continued)

PFNA

Cone. 4.4426

R#1 463.00>219.00 20.52 (19.07)
Q 463.00>418.90 (-)	7.57e5

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 4.7020

7.18e5 Q 467.80>423.00 (-)

7.2

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 3.7909

3.58e4 Q 528.80> 509.00 (-)

3.0e4 :
2.0e4 :
1.0e4:
O.OeO :

'A=94962
Rli 7.308



7.6
RT (min)

d3-N-MeFOSAAIS

Cone. 5.0000

ISTD 572.80>419.05 (-)

d3-N-MeFOSAA

Cone. 5.2367

2.43e5 Q 572.80>419.05 (-)

13C-PFUnDA

Cone. 4.8731

Q 564.80>519.95 (-)

O.OeO

7.6 7.8
RT (min)

PFUnDA

Cone. 4.6343

R#1 563.00>219.00 11.87 (12.92)
Q563.00>518.90 (-)	6.19e5

661476
7.659

- R1 38.78 (-

R"|=7.491

J\J

i iA i i i

-!!-*¦—

7.25 7.50 7.75

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

7.8 8.0
RT (min)

PFOSA

Cone. 4.4270

R#1 498.20>64.10 0.15 (0.11)
Q 498.20>78.00 (-)	1.74e5

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

13C-FOSA

Cone. 4.6434

1.82e5 Q 506.00>78.05 (-)

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

j R1 0.15 (—

i RT=7.745

^ /

L

7.8 8.0

RT (min)

7.8 8.0

RT (min)

PFNS

Cone. 4.8500

R#1 549.00 >99.00 66.92 (69.83)
Q 549.00>79.95 (-)	2.07e5

2.0e5

8-2-FTS

Cone. 4.5285

R#1 527.20>487.00 7.66 (6.24)
Q 527.10>506.90 (-)	3.8

7.2
RT (min)

PFDA

Cone. 4.8937

R#1 512.90>219.00 17.55 (17.97)
Q 512.90>469.00 (-)	7.06e5



r a=

102071

: R1 7.66 (-!



=7.307

I



s.T

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 4.4660

ISTD 514.80>469.95 (-)

7.62e5 Q 514.80>469.95 (-)

]

RT^7.312



it

A=1907179
Rli 7.312

7.6
RT (min)

NMeFOSAA

Cone. 4.8860

R#1 570.20>512.00 38.78 (38.98)
Q 570.20>419.00 (-)	2.01 e5

2.0e5-

7.2

7.4

7.6
RT (min)

PFDS

Cone. 4.5567

R#1 599.00>99.00 62.93 (59.45)
Q 599.00>80.10 (-)	1.38e5

6.0e5
4.0e5
2.0e5
O.OeO

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

831433
7.659

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 5.3507

2.50e5 Q 588.80>419.00 (-)

O.OeO -

7.8 8.0
RT (min)

NEtFOSAA

Cone. 4.6684

R#1 584.20>526.10 56.46 (51.48)
Q 584.20>418.95 (-)	1.98e5

~ A=655990

- R1 56.46 (-W=7.677

O.OeO -



U

7.8 8.0
RT (min)

7.6

7.8 8.0
RT (min)

PFDoA

Cone. 4.1837

R#1 613.05> 169.00 16.24 (17.39)
Q 613.05>569.00 (-)	6.68e5

4.0e5 :
2.0e5 :
O.OeO :

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

7.16e5



f A=1771769

	

j-RT"^

o
o

CO

: I



~

7.8 8.0

RT (min)

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

28ffi

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:17

CCV3-230428 (continued)

13C-PFDoA

Cone. 5.1421

Q614.80>569.95 (-)

NEtFOSE

Cone. 3.9920

Q 629.50>59.10 (-)
3.0e51

d3-NMeFOSA

Cone. 5.2594

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

6.0e5 -
4.0e5 -
2.0e5 -
O.OeO -

A= 1757452
~Rt=8.626

8.6

O.OeO



fA= 162002

: R1 73.74

("RT"^ 8.277

I

Li

10-2-FtS

Cone. 5.0815

R#1 626.50>81.05 60.45 (57.89)
Q 626.50>607.05 (-)	4.37e4

TA= 122580
4.0e4 - R1 60.45(1-Rj-jk oi2

RT (min)

d9-EtFOSE IS

Cone. 5.0000

3.03e5 ISTD 638.90> 59.10 (-)

O.OeO -

1,87e5 I STD 623.00 > 59.00 (-)

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 4.7969

R#1 713.00 >169.30 9.86 (10.00)
Q 713.00>668.90 (-)	6.55e5

13C-PFTeDA IS

Cone. 5.0000

I STD 714.80 >669.80 (-)

3.0e5 -
2.0e5 -
1.0e5-
O.OeO -

.8 9.0
RT (min)

L-PFDoS

Cone. 5.4510

R#1 698.80>98.80 73.74 (75.26)
Q 698.80>80.10 (-)	6.53e4

4.0e4 :
2.0e4 :

NaDONA

Cone. 4.4586

Q 377.10>251.20 (-)

6.0e5 i
4.0e5 ^

2.0e5 i
O.OeO 1 . . .

A=1669222
T=6.400

8.4 8.6
RT (min)

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 4.9834

1.98e5 Q 531.10> 169.10 (-)

NMeFOSE

Cone. 5.4035

1.98e5 Q 616.10>58.90 (-)
1.0e5-

RT (min)

B.8 9.0

RT (min)

d9-EtFOSE

Cone. 6.7306

7.61e4 Q 638.90> 59.10 (-)

6.0e4 i
4.0e4 ~

2.0e4 ~

— O.OeO 1 . .

8.6 8.8 9.0

RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

8.6 8.8 9.0

RT (min)

d7-N-MeFOSE

Cone. 5.8018

1.18e5 Q 623.00> 59.00 (-)

RT (min)

13C-PFTeDA

Cone. 4.2200

3.81 e5 Q714.80>669.80 (-)

9.0
RT (min)

PFHxDA

Cone. 4.4919

7.46e5 Q 812.90>769.00 (-)

6.6

RT (min)

RT (min)

11CI-PF30UdS

Cone. 5.0690

Q 631.00>451.10 (-)
2.0e5 -

Y A=518063
RN7.812

8.6 8.8 9.0
RT (min)

PFODA

Cone. 4.9923

Q 912.80>869.00 (-)
3.0e5 -i

9.0 9.2 9.4

RT (min)

9.0
RT (min)

NMeFOSA

Cone. 4.6312

R#1 512.10>219.20 78.78 (76.68)
Q 512.10> 169.20 (-)	7.85e4

f A=207695

?-5e4:R1 78.78 (- RT=8.529

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

8.4 8.6

RT (min)
NEtFOSA

Cone. 4.9612

R#1 526.50>219.20 66.45 (65.87)
1.18e5 Q 526.50> 169.10 (-)	1.43e5

f A=371?39

-|R1 66.45 (-Uj=8.790

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 5.2170

R#1 663.10> 169.10 18.35 (18.12)
Q 663.10>618.90 (-)	6.30e5

621715
6.0e5^Ri 18.35 ^.326

4.0e5 :

9CI-PF30NS

Cone. 5.0566

Q 531.00>351.10 (-)

,	TAjii

x n.r :	Rl=7.

13465
Rt=7.139



RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

3.03e5 I STD 815.00 > 770.00 (-)

A=3367243
RT=9L155



9.8 10.0

RT (min)

9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

282

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:17

CCV3-230428 (continued)

13C2-PFHxDA

Cone. 4.3828

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

1.42e6 ISTD 569.80>524.90 (-)

PFBSA

Cone. 4.9864

O.OeO -

9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

PFecHS

Cone. 4.8624
R#1 461.00>99.10 38.38 (38.19)

5.67e5 Q 461.00>381.00 (-)	7.91 e5 Q 298.00>78.00 (-)

f A=1968400

7-5e5^Rl 38.38 (-^T=6.624

5.0e5 :

2.5e5 :

O.OeO :

8.0
RT (min)

6.4 6.6 6.8

RT (min)

PFHxSA

Cone. 4.6278

Q 397.90>78.00 (-)
4.0e51

A=1013715
RT=6.961

L

6.2 6.4
RT (min)

7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

282

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1st /S/AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/Integration
Printed 5/2/2023 17:38:56

L0.1ppb_230323

Sample ID: L0.1ppb_230323

Date Acquired: 4/30/2023 9:02:11 AM

Acquired by: System Administrator

Data File: 230428253

Vial: 4 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone. Cone.

Unit

13C-PFBA IS

Auto

4.200

677815

677815

	

—- 5.0000

nq/ml

13C-PFBA

Auto

4.200

677815

220

13C7-PFUnDA IS

—- 6.2936

ng/mL

PFBA

Auto

4.202

10674

677815

13C-PFBA IS

—- 0.0704

ng/mL

13C-PFPeA IS

Auto

5.357

983779

'.¦'779

	

—- 5.0000

ng/mL

13C-PFPeA

Auto

5.357

983779

1015220

13C7-PFllnDA IS

—- 5.6856

ng/mL

PFPeA

Auto

5.358

19115

983779

13C-PFPeA IS

—- 0.1055

ng/mL

13C-PFBS IS

Auto

5.488

371798

371798

	

—- 4.6500

ng/mL

13C-PFBS

Auto

488

371798

1015220

13C7-PFUnDA IS

—- 4.8967

ng/mL

PFBS

Auto

5.492

5013

371798

13C-PFBS IS

—- 0.0868

nq/mL

13C HFPO DA IS

Auto

388

236987

236987

	

300

ng/mL

FPO DA

Auto

6.088

!7

1015220

13C7-PFllriDA IS

—- 6.3075

ng/mL

HFPO DA

Auto

6.085

3255

987

13C HFPO DA IS

—- 0.0939

ng/mL

13C-4 2-FTS IS

Auto

5.889

168024

168024

	

—- 4.6700

ng/mL

13C-4 2-FTS

Auto

5.889

168024

220

13C7-PFUnDA IS

—- 4.9485

na/mL

4-2-FtS

Auto

5.886

4045

168024

13C-4 2-FTS IS

—- 0.1015

ng/mL

PFHxA

Auto

5.942

39502

1341425

13C-PFHxA

—- 0.1108

ng/mL

13C-PFHxA IS

Auto

5.942

I 34 14-">

1341425

	

—- 5.0000

ng/mL

13C-PFHxA

Auto

5.942

1341425

- ¦'¦220

13C7-PFUnDA IS

—- 5.7060

ng/mL

PFPeS

Auto

5.984

5754

368

180-PFHxS IS

—- 0.1068

nq/mL

PFHxS

Auto

6.352

)2

382368

180-PFHxS

307

ng/mL

13C-PFHpA IS

Auto

6.348

1309099

1309099

	

—- 5.0000

ng/mL

13C-PFHpA

Auto

6.348

1309099

1015220

13C7-PFUnDA IS

—- 5.7322

ng/mL

kV PI H\s IS

Auto

6.354

382368

382368

	

—- 4.7250

ng/mL

180-PFHxS

Auto

6.354

382368

220

13C7-PFUnDA IS

182

nq/mL

PFHpA

Auto

6.348

38621

1309099

13C-PFHpA IS

—- 0.0989

ng/mL

5 2-FTS IS

Auto

6.648

153415

415

	

—- 4.7500

ng/mL

2- F

Auto

6.648

153415

1015220

13C7-PFUnDA IS

—- 4.3132

ng/mL



Auto

6.658

5820

382368

180-PFHxS IS

—- 0.1001

ng/mL

6-2-FTS

Auto

6.650

3795

153415

13C2-6 2-FTS IS

—- 0.1245

ng/mL

PFOA

Auto

6.665

46696

1611458

13C-PF ¦

—- 0.1066

ng/mL

13C-PFOA IS

Auto

6.665

1611458

1611458

	

—- 5.0000

ng/mL

13C-PFOA

Auto

6.665

' ' ':>8

1015220

1;

—- 5.6762

ng/mL

PFOS

M

6.952

to

379806

13C-PFOS IS

—- 0.0955

ng/mL

FOS IS

Auto

6.951

379806

379806

	

750

nq/mL

13C-PFOS

Auto

6.951

379806

1015220

13C7-PFUnDA IS

550

ng/mL

PFNA

Auto

6.971

25749

1520889

13C-PFNA IS

—- 0.0709

ng/mL

13C-PFNA IS

Auto

6.971

1520889

1520889

	

—- 5.0000

ng/mL

13C-PFNA

Auto

6.971

1520889

"'¦220

13C7-PFUnDA IS

—- 6.0274

ng/mL

PFNS

Auto

7.273

7705

379806

13C-PFOS IS

—- 0.0847

ng/mL

8-2-FTS

Auto

7.302

1126

78631

13C-8 2-FTS IS

—- 0.0779

ng/mL

13C-8 2-FTS IS

Auto

7.300

78631

78631

	

—- 4.7900

ng/mL

13C-8 2-FTS

Auto

7.300

78631

1015220

13C7-PFUnDA IS

—- 4.6926

ng/mL

PFDA

Auto

7.304

28770

1476540

13C-PFDA IS

—- 0.1029

ng/mL

13C-PFDA IS

Auto

7.305

1476540

1476540

	

300

ng/mL

13C-PFDA

Auto

7.305

1476540

1015220

'FUnDA IS

590

ng/mL

d3-N-MeFOSAA IS

Auto

7.480

,)2

535292

	

300

nq/mL

d3-N-MeFOSAA

Auto

7.480

535292

1015220

13C7-PFUnDA IS

—- ,> 4,'o>5

ng/mL

NMeFOSAA

M

7.484

8679

535292

d3-N-MeFOSAA IS

—- 0.0817

ng/mL

PFDS

M

7.614

5153

379806

13C-PFOS IS

	 ,l,l/ba

ng/mL

13C-PFUnDA IS

Auto

7.651

1478219

1478219

	

—- 5.0000

ng/mL

13C-PFUnDA

Auto

7.651

1478219

1015220

13C7-PFUnPA IS

—- 5.8801

L

PFUnDA

Auto

7.651

23198

1478219

13C-PFUnDA IS

—- 0.0802

ng/mL

(IS- N- EtFOSAA IS

Auto

7.662

616595

616595

	

—- 5.0000

L

d5-N-EtFOSAA

Auto

7.662

616595

1015220

13C7-PFUnDA IS

—- 6.9434

ng/mL

NEtFOSAA

M

7.670

11083

595

dS-N-EtFOSAA IS

—- 0.0909

nq/mL

PFOSA

Auto

7.737

8488

520

13C-FC

—- 0.1004

ng/mL

3SA IS

Auto

7.739

394520

394520

	

—- 5.0000

L

13C-FOSA

Auto

7.739

394520

1015220

13C7-PFUnDA IS

—- 5.9038

ng/mL

PFDoA

Auto

7.991

28576

1397127

13C-PFDoA IS

—- 0.0915

L

13C-PFDoA IS

Auto

7 990

1397127

1397127

	

300

nq/mL

I iv. PFl'On

Auto

7



1015220

13C7-PFUnDA IS	

=	5.6659

ng/mL

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal.iproc

288

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1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 17:38:56

L0.1ppb_230323 (continued)

(Table continued from previous page)

Name	Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone. Cone. Unit

10-2-FtS

Auto

7.999

1400

78631

13C-8 2-FTS IS

—- 0.0701

nq/mL

d5-NEtFOSA IS

Auto

8.770

470462

470462

—

—- 5.0000

nq/mL

d5-NEtFOSA

Auto

8.770

470462

1015220

13C7-PFUnDA IS

—- 6.8715

nq/mL

NMeFOSE

Auto

8.496

4790

255688

d7-N-MeFOSE IS

—- 0.1147

nq/mL

NEtFOSE

Auto

8.745

14981

181146

d9-EtFOSE IS

—- 0.0834

nq/mL

d9-EtFOSE IS

Auto

8.726

181146

181146

—

—- 5.0000

nq/mL

d9-EtFOSE

Auto

8.726

181146

1015220

13C7-PFUnDA IS

—- 9.2637

nq/mL

NMeFOSA

Auto

8.517

3711

426767

d3-NMeFOSA IS

—- 0.0944

nq/mL

dB-NMeFOSA IS

Auto

8.513

426767

426767

—

—- 5.0000

nq/mL

dB-NMeFOSA

Auto

8.513

426767

1015220

13C7-PFUnDA IS

—- 6.8938

nq/mL

d7-N-MeFOSE IS

Auto

8.479

255688

255688

—

—- 5.0000

nq/mL

d7-N-MeFOSE

Auto

8.479

255688

1015220

13C7-PFUnDA IS

—- 7.3702

nq/mL

NEtFOSA

Auto

8.781

6738

470462

d5-NEtFOSA IS

—- 0.0976

nq/mL

PFTrDA

Auto

8.317

21219

452612

13C-PFTeDA IS

—- 0.1543

nq/mL

PFTeDA

Auto

8.614

23265

452612

13C-PFTeDA IS

—- 0.1436

nq/mL

13C-PFTeDA IS

Auto

8.614

452612

452612

—

—- 5.0000

nq/mL

1BC-PFTeDA

Auto

8.614

452612

1015220

13C7-PFUnDA IS

—- 2.7905

nq/mL

11CI-PF30UdS

Auto

7.803

10484

379806

13C-PFOS IS

—- 0.1205

nq/mL

9CI-PFBONS

Auto

7.130

15252

379806

13C-PFOS IS

—- 0.0813

nq/mL

L-PFDoS

Auto

8.266

2579

379806

13C-PFOS IS

—- 0.1019

nq/mL

NaDONA

Auto

6.392

31308

1520889

13C-PFNA IS

—- 0.0975

nq/mL

PFHxDA

Auto

9.145

9704

2638382

13C2-PFHxDA IS

—- 0.0050

nq/mL

PFODA

Auto

9.678

6719

2638382

13C2-PFHxDA IS

—- 0.0499

nq/mL

13C2-PFHxDA IS

Auto

9.145

2638382

2638382

—

—- 5.0000

nq/mL

1BC2-PFHxDA

Auto

9.145

2638382

1015220

13C7-PFUnDA IS

—- 5.1339

nq/mL

13C7-PFUnDA IS

Auto

7.651

1015220

1015220

—

—- 5.0000

nq/mL

PFecHS

Auto

6.617

30971

379806

13C-PFOS IS

—- 0.0898

nq/mL

PFBSA

Auto

6.127

22590

394520

13C-FOSA IS

—- 0.1099

nq/mL

PFHxSA

Auto

6.954

20020

1520889

13C-PFNA IS

—- 0.1066

nq/mL

CHARGE

ND(W/B)

	

	

1015220

13C7-PFUnDA IS

	 	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 6.2936
1.51e5 Q 217.20>172.30 (-)

PFBA

Cone. 0.0704
1.51e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
3.43e3 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 5.6856
3.88e5 Q 267.90>223.00 (-)

O.OeO

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 0.1055

Q263.05>219.10 (-)

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

7.09e3 I STD 301.80 > 80.00 (-)

4.00 4.25 4.50

RT (min)

13C-PFBS

Cone. 4.8967

1.32e5 Q 301.80>80.00 (-)

5.6

RT (min)

PFBS

Cone. 0.0868
R#1 298.80>99.00 81.03 (68.21)

1.32e5 Q 299.00>80.00 (-)	1.78e3 ISTD 332.10>287.10 (-)

13C HFPO DA IS

Cone. 5.0000

f A=5013
R1 81.03 (-|-^r=5.492

5.6 5.8
RT (min)

1.0e5

5.6 5.8
RT (min)

6.2 6.4
RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal.iproc

28§

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 17:38:56

L0.1ppb_230323 (continued)

13C HFPO DA

Cone. 6.3075

Q 332.10>287.10 (-)
1.0e5 -i	T

=236987
[T=6.088

HFPO DA

Cone. 0.0939

R#1 329.00>285.10 93.75 (71.09)
Q 329.00>169.00 (-)	1.46e3

~ A=3255
:R1 93.75 (#-Rt=6.085

O.OeO -



13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 26.31 (25.06)

ISTD 329.00>309.15 (-)	6.75e4

fA= 168024
6.0e4 - R1 2631 ("«-Rfr= 5.889

4.0e4 :
2.0e4 :
O.OeO :

13C-4 2-FTS

Cone. 4.9485

R#1 329.00>81.00 26.31 (25.06)
Q 329.00>309.15 (-)	6.75e4

fA= 168024

6.0e4:R1 2631 C-i"Fdr=5.889

4.0e4 -
2.0e4 ^
O.OeO -

4-2-FtS

Cone. 0.1015

R#1 327.00>81.10 16.90 (17.01)
Q 327.00>307.05 (-)	1.82e3

J

1.5e3-
1.0e3:
5.0e2 :
O.OeO :

f A=4045

I R1 16.90 (- -Rt= 5.886

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 0.1108

R#1 313.00> 119.10 1.97 (2.21)
Q 313.00>269.00 (-)	1.56e4

~ A=39502

1-5e4:Ri 1.97 fcT=5942

6.2 6.4
RT (min)

6.0 6.2
RT (min)

13C-PFHxA IS

Cone. 5.0000

13C-PFHxA

Cone. 5.7060

ISTD 314.90>270.10 (-)

5.42e5 Q 314.90>270.10 (-)

~ A= 1341425
Rp"= 5.942

5.8 6.0 6.2
RT (min)

PFPeS

Cone. 0.1068

R#1 349.00>99.00 66.70 (89.24)
Q 349.00>79.95 (-)	2.47e3

f A=5754
- R1 66 70 (-fi-^T= 5.984

5.8 6.0 6.2
RT (min)

PFHxS

Cone. 0.1007

R#1 399.00 >99.00 97.17 (92.93)
Q 399.00>80.00 (-)	1.72e3

y A=4892

1 5e3-R1 9717 ("il#=6.352

6.6
RT (min)

PFHpA

Cone. 0.0989

R#1 362.90 >169.00 17.20 (16.60)
Q 362.90>319.00 (-)	1.60e4

~ A=38621
1.5e4~ R1 17.20 (4-^=6.348

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)
6.0e4 -

T A= 153415
RT=6.648

4.0e4 :
2.0e4 :
O.OeO :

:|=6.6.

L

13C2-6 2-FTS

Cone. 4.3132

6.30e4 Q 428.90>409.00 (-)
6.0e4 -
4.0e4 ^

2.0e4 :

RT (min)

13C-PFOA IS

Cone. 5.0000

O.OeO -

13C-PFOA

Cone. 5.6762

6.6
RT (min)

PFHpS

Cone. 0.1001

R#1 449.00>99.20 57.05 (55.18)
Q 449.00>80.15 (-)	2.50e3

f A=5820
IR1 57.05 (-|-r)t=6.658

O.OeO -

6.6
RT (min)

6-2-FTS

Cone. 0.1245

R#1 427.00>80.90 18.45 (29.85)
Q 427.00>407.00 (-)	1.71e3

fA=3795
1.5e3-R1 1845 6.650

1.0e3~
5.0e2 :
O.OeO :

6.6
RT (min)

PFOA

Cone. 0.1066

R#1 413.00 > 169.10 30.47 (28.84)
Q 413.00>369.00 (-)	1.82e4

^ A=46696
:R1 30.47 (i-Rjr=6.665

RT (min)

6.6 6.8

RT (min)

PFOS

Cone. 0.0955

R#1 499.00>99.00 83.55 (93.90)
Q 499.00>80.00 (-)	1.20e3

f A=3780
, « . "R1 83 55 ("J4t=6.952



RT (min)

13C-PFOS IS

Cone. 4.7750

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

ISTD 502.8
1.5e5-

1.0e5-j

5.0e4 ^

O.OeO 4=

105 (-)

fA=379806
RT=6.951



Q 502.8
1.5e5-

1.0e5^

5.0e4 ^

O.OeO :

105 (-)

~ A=379806
RT=6.951

4

7.2

RT (min)

7.2

RT (min)

C:\LabSolutions\Data\LCMS1~230428\LCMS1~230428B-537MOD_OldCal.iproc

286

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 17:38:56

L0.1ppb_230323 (continued)

PFNA

Cone. 0.0709

R#1 463.00>219.00 25.30 (19.07)
Q 463.00>418.90 (-)	1.04e4

TA=25749

1-0e4."R1 25.30 (^6.97!

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)
6.0e5 -

Y A= 1520889
Rl> 6.971

vL

13C-PFNA

Cone. 6.0274

Q 467.80>423.00 (-)
6.0e5 -
4.0e5 ^

2.0e5 ^

O.OeO 1 . .

PFNS

Cone. 0.0847

R#1 549.00 >99.00 91.16 (69.83)
Q 549.00>79.95 (-)	2.97e3

f A=7705
IR1 91.16 7.273

7.2

RT (min)

6.8

7.0

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

13C-8 2-FTS

Cone. 4.6926

2.90e4 Q 528.80> 509.00 (-)

A=78631
Rli 7.300

A=78631
Rli 7.300

7.2
RT (min)

PFDA

Cone. 0.1029

R#1 512.90>219.00 17.86 (17.97)
Q 512.90>469.00 (-)	1.17e4

~ A=28770
1 n~A -R1 1786 ("RTi7.304

8-2-FTS

Cone. 0.0779

R#1 527.20>487.00 0.00 (6.24)
Q 527.10>506.90 (-)	4.26e2

~ A=1126
4-0e2- R1 0.00 K-Rtl7.302

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA IS

Cone. 5.0000

13C-PFDA

Cone. 5.1690

ISTD 514.80>469.95 (-)

5.87e5 Q 514.80>469.95 (-)

O.OeO -

u

A=1476540
RTl 7.305

7.6
RT (min)

7.6
RT (min)

7.2

7.4

d3-N-MeFOSAAJS

Cone. 5.0000

ISTD 572.80>419.05 (-)
2.0e5 -i

d3-N-MeFOSAA

Cone. 6.4269

Q 572.80>419.05 (-)
2.0e5 -i

O.OeO -

7.6
RT (min)

NMeFOSAA

Cone. 0.0817

R#1 570.20>512.00 33.06 (38.98)
Q 570.20>419.00 (-)	2.77e3

f At 8679
IR1 33.06 (-{-r&L7.484

O.OeO

7.6
RT (min)

PFDS

Cone. 0.0769
R#1 599.00>99.00 62.49 (59.45)

Q 599.00>80.10 (-)	1.88e3 ISTD 564.80>519.95 (-)

f A=5153

: R1 62-49,: Wi 7.614

13C-PFUnDA IS

Cone. 5.0000

7.6 7.8
RT (min)

7.4

7.25 7.50 7.75

13C-PFUnDA

Cone. 5.8801

d5-N-EtFOSAA IS

Cone. 5.0000

Q 564.80>519.95 (-)

7.6 7.8
RT (min)

PFUnDA

Cone. 0.0802
R#1 563.00>219.00 16.25 (12.92)

5.49e5 Q563.00>518.90 (-)	8.36e3 ISTD 588.80>419.00 (-)

J A=23198
7.5e3 - R1 16-25 {rt =17.651

RT (min)

RT (min)

d5-N-EtFOSAA

Cone. 6.9434

2.29e5 Q 588.80>419.00 (-)

O.OeO

8.0
RT (min)

PFOSA	13C-FOSAJS

Cone. 0.1004	Cone. 5.0000

R#1 498.20>64.10 0.00 (0.11)

Q 498.20>78.00 (-)	3.73e3 ISTD 506.00>78.05 (-)

O.OeO

'

rA=616595

:

RT=7.662



vl

I I fl I I I'	

O.OeO

7.8 8.0
RT (min)

NEtFOSAA

Cone. 0.0909

R#1 584.20>526.10 67.44 (51.48)
Q 584.20>418.95 (-)	3.16e3

~ A= 11083
3.0e3 - ri 67.44 (J^=7 67Q

8.0
RT (min)

7.6

3.0e3 -
2.0e3 :
1.0e3-j
O.OeO :

TA=8488
I RI 0 00 (—:"hT=7.737

1.5e5 -
1.0e5-j
5.0e4 :
O.OeO :

13C-FOSA

Cone. 5.9038

Q 506.00>78.05 (-)
1.5e5 -
1.0e5-j
5.0e4 ^

O.OeO 1. . . .

7.8 8.0
RT (min)

PFDoA

Cone. 0.0915
R#1 613.05> 169.00 15.34(17.39)

1.58e5 Q 613.05>569.00 (-)	1.13e4 ISTD 614.80>569.95 (-)

7.50 7.75 8.00

RT (min)

13C-PFDoA IS

Cone. 5.0000

5.29e5

1.0e4-R1 1531

TA=28576
(RT=V.991

8.0
RT (min)

7.8 8.0

RT (min)

8.0
RT (min)

O.OeO , , ^

RT (min)

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal.iproc

280

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 17:38:56

L0.1ppb_230323 (continued)

13C-PFDoA

Cone. 5.6659

Q614.80>569.95 (-)

f A=1397127
RT=7.990

NEtFOSE

Cone. 0.0834

Q 629.50>59.10 (-)

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

lA=4

RT=.

426767
RT=8.513

10-2-FtS

Cone. 0.0701

R#1 626.50>81.05 55.72 (57.89)
Q 626.50>607.05 (-)	7.69e2

f A=1400

: R1 55.72! (rt=J?I.999

6.0e2 :
4.0e2 :
2.0e2 :
O.OeO :

RT (min)

d9-EtFOSE IS

Cone. 5.0000

5.87e3 ISTD 638.90> 59.10 (-)

~ A= 14981
RT=8.745

O.OeO -

8.6 8.8 9.0

RT (min)

d3-NMeFOSA

Cone. 6.8938

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

A=181146
RT=8.726

d7-N-MeFOSE IS

Cone. 5.0000

1.64e5 I STD 623.00 >59.00 (-)
1.0e5 -|

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 0.1436

R#1 713.00 >169.30 16.07 (10.00)
Q 713.00>668.90 (-)	8.65e3

13C-PFTeDA IS

Cone. 5.0000

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 6.8715

1.82e5 Q 531.10> 169.10 (-)

fj A=470462
RT=8.770

RT (min)

6.94e4 Q 638.90> 59.10 (-)

9.0
RT (min)

d7-N-MeFOSE

Cone. 7.3702

Q 623.00>59.00 (-)
1.0e5 -|

RT (min)

13C-PFTeDA

Cone. 2.7905

RT (min)

11CI-PF30UdS

Cone. 0.1205

NMeFOSE

Cone. 0.1147

Q 616.10>58.90 (-)
2.0e3 -

8.6 8.8 9.0

RT (min)

NMeFOSA

Cone. 0.0944

R#1 512.10>219.20 99.14(76.68)
Q 512.10> 169.20 (-)	1.28e3

TA=3711

:R1 99.14 (—^1=8.517

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)
1.5e5

O.OeO

8.4 8.6

RT (min)

NEtFOSA

Cone. 0.0976

R#1 526.50>219.20 53.89 (65.87)
Q 526.50>169.10 (-)	2.79e3

% A=6738
:R1 53.89 (-1^7=8.781

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 0.1543

R#1 663.10> 169.10 28.53 (18.12)
Q 663.10>618.90 (-)	7.60e3

fA=21219

: R1 28-53J(rt^8.317

6.0e3 :
4.0e3 :
2.0e3 :
O.OeO :

8.6

RT (min)

9CI-PF30NS

Cone. 0.0813

L-PFDoS

Cone. 0.1019

R#1 698.80>98.80 73.10 (75.26)
Q 698.80>80.10 (-)	1.06e3

ISTD 714.80>669
1.5e5
1.0e5
5.0e4
O.OeO

Q 377.10>251.20 (-)	1.34e4

Q 714.80>669.80 (-)
1.5e5
1.0e5
5.0e4
O.OeO

9.0
RT (min)

Q 812.90>769.00 (-)	4.29e3

PFODA

Cone. 0.0499

Q 912.80>869.00 (-)

B.O

RT (min)

Q 531.00>351.10 (-)

6.0e3 -

4.0e3 ^

2.0e3 ^

O.OeO ip

7.0 7.2

13C2-PFHxDAJS

Cone. 5.0000

ISTD 815.00>770.00 (-)

7.4

RT (min)

.80 (-)	1.68e5

8.8 9.0
RT (min)

Q 631.00>451.10 (-)	4.26e3

NaDONA

Cone. 0.0975

PFHxDA

Cone. 0.0050

A= 10484
RT=7.803

*A=2579
1.0e3-Ri 73.14(^.266

f A=31308
RT=6.392

8.4 8.6
RT (min)

_ Vt

9.4

RT (min)

A=2638382
RT=9145

9.8 10.0

RT (min)

9.2 9.4

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal.iproc

288

-------
1st /S/ AO 05/02/23
2nd IS/ AO 05/03/23

Insight Report
Quantitation/lntegration
Printed 5/2/2023 17:38:56

L0.1ppb_230323 (continued)

13C2-PFHxDA

Cone. 5.1339

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 0.1099

Q 815.00>770.00 (-)

PFecHS

Cone. 0.0898
R#1 461.00>99.10 38.72 (38.19)

1.12e6 ISTD 569.80>524.90 (-)	3.69e5 Q461.00>381.00 (-)	1.25e4 Q 298.00>78.00 (-)

O.OeO -

TA=2638382
RT=9.145



9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

~ A=30971

IR1 38.72 ("I"l4r=6.617

6.4 6.6 6.8

7.5e3 :
5.0e3 :
2.5e3 :
O.OeO :

RT (min)

f A=22590
I RT=6.127

6.0 6.2 6.4
RT (min)

PFHxSA

Cone. 0.1066

8.66e3 Q 397.90>78.00 (-)

6.0e3 ~

4.0e3 ~

2.0e3 ~

O.OeO 1 . . .

6.8 7.0 7.2

RT (min)

C:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal.iproc

288

-------
Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:20

CCV4-230428

Sample ID: CCV4-230428

Date Acquired: 4/30/2023 9:15:55 AM

Acquired by: System Administrator

Data File: 230428254

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.206

784537

784537

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.206

784537

1171432

13C7-PFUnDA IS

5.0000

6.3131

nq/mL

PFBA

Auto

4.206

840059

784537

13C-PFBA IS

5.0000

4.7892

nq/mL

13C-PFPeA IS

Auto

5.362

1162756

1162756

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.362

1162756

1171432

13C7-PFUnDA IS

5.0000

5.8239

nq/mL

PFPeA

Auto

5.363

1140304

1162756

13C-PFPeA IS

5.0000

5.3263

nq/mL

13C-PFBS IS

Auto

5.493

430570

430570

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.493

430570

1171432

13C7-PFUnDA IS

4.6500

4.9146

nq/mL

PFBS

Auto

5.493

319074

430570

13C-PFBS IS

4.4200

4.7736

nq/mL

13C HFPO DA IS

Auto

6.093

280226

280226

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.093

280226

1171432

13C7-PFUnDA IS

5.0000

6.4637

nq/mL

HFPO DA

Auto

6.092

222629

280226

13C HFPO DA IS

5.0000

5.4316

nq/mL

13C-4 2-FTS IS

Auto

5.894

202112

202112

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

5.894

202112

1171432

13C7-PFUnDA IS

4.6700

5.1586

nq/mL

4-2-FtS

Auto

5.894

216933

202112

13C-4 2-FTS IS

4.6700

4.5237

nq/mL

PFHxA

Auto

5.948

2056172

1519090

13C-PFHxA IS

5.0000

5.0942

nq/mL

13C-PFHxA IS

Auto

5.948

1519090

1519090

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

5.948

1519090

1171432

13C7-PFUnDA IS

5.0000

5.6001

nq/mL

PFPeS

Auto

5.990

314279

438925

180-PFHxS IS

4.6900

5.0824

nq/mL

PFHxS

Auto

6.359

237822

438925

180-PFHxS IS

4.5500

4.2633

nq/mL

13C-PFHpA IS

Auto

6.353

1516175

1516175

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.353

1516175

1171432

13C7-PFUnDA IS

5.0000

5.7537

nq/mL

180-PFHxS IS

Auto

6.360

438925

438925

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.360

438925

1171432

13C7-PFUnDA IS

4.7250

4.9923

ng/mL

PFHpA

Auto

6.353

2257039

1516175

13C-PFHpA IS

5.0000

4.9910

ng/mL

13C2-6 2-FTS IS

Auto

6.654

187984

187984

—-

4.7500

4.7500

ng/mL

13C2-6 2-FTS

Auto

6.654

187984

1171432

13C7-PFUnDA IS

4.7500

4.5804

ng/mL

PFHpS

Auto

6.663

308959

438925

180-PFHxS IS

4.7600

4.6313

nq/mL

6-2-FTS

Auto

6.653

176010

187984

13C2-6 2-FTS IS

4.7400

4.7109

nq/mL

PFOA

Auto

6.672

2410732

1791962

13C-PFOA IS

5.0000

4.9491

nq/mL

13C-PFOA IS

Auto

6.671

1791962

1791962

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.671

1791962

1171432

13C7-PFUnDA IS

5.0000

5.4703

nq/mL

PFOS

Auto

6.957

209957

444610

13C-PFOS IS

4.6400

4.5337

nq/mL

13C-PFOS IS

Auto

6.957

444610

444610

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

6.957

444610

1171432

13C7-PFUnDA IS

4.7750

5.0371

nq/mL

PFNA

Auto

6.977

1648149

1709390

13C-PFNA IS

5.0000

4.0382

nq/mL

13C-PFNA IS

Auto

6.976

1709390

1709390

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

6.976

1709390

1171432

13C7-PFUnDA IS

5.0000

5.8711

nq/mL

PFNS

Auto

7.280

498911

444610

13C-PFOS IS

4.8000

4.6872

nq/mL

8-2-FTS

Auto

7.305

83594

96693

13C-8 2-FTS IS

4.7900

3.6150

nq/mL

13C-8 2-FTS IS

Auto

7.306

96693

96693

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.306

96693

1171432

13C7-PFUnDA IS

4.7900

5.0011

nq/mL

PFDA

Auto

7.310

1679366

1758695

13C-PFDA IS

5.0000

5.0422

m

13C-PFDA IS

Auto

7.310

1758695

1758695

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.310

1758695

1171432

13C7-PFUnDA IS

5.0000

5.3357

m

d3-N-MeFOSAA IS

Auto

7.485

618359

618359

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.485

618359

1171432

13C7-PFUnDA IS

5.0000

6.4342

m

NMeFOSAA

Auto

7.490

576202

618359

d3-N-MeFOSAA IS

5.0000

4.6949

nq/mL

PFDS

Auto

7.619

353091

444610

13C-PFOS IS

4.8200

4.5010

m

13C-PFUnDA IS

Auto

7.657

1666201

1666201

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.657

1666201

1171432

13C7-PFUnDA IS

5.0000

5.7440

m

PFUnDA

Auto

7.657

1312292

1666201

13C-PFUnDA IS

5.0000

4.0233

nq/mL

d5-N-EtFOSAA IS

Auto

7.668

674153

674153

	

5.0000

5.0000

m

d5-N-EtFOSAA

Auto

7.668

674153

1171432

13C7-PFUnDA IS

5.0000

6.5792

nq/mL

NEtFOSAA

M

7.675

559542

674153

dS-N-EtFOSAA IS

5.0000

4.1958

m

PFOSA

Auto

7.744

433230

431529

13C-FOSA IS

5.0000

4.6854

nq/mL

13C-FOSA IS

Auto

7.744

431529

431529

	

5.0000

5.0000

m

13C-FOSA

Auto

7.744

431529

1171432

13C7-PFUnDA IS

5.0000

5.5965

nq/mL

PFDoA

Auto

8.000

1640204

1648651

13C-PFDoA IS

5.0000

4.4530

nq/mL

13C-PFDoA IS

Auto

8.000

1648651

1648651

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

280

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Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:20

CCV4-230428 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.000

1648651

1171432

13C7-PFUnDA IS

5.0000

5.7944

nq/mL

10-2-FtS

Auto

8.011

70581

96693

13C-8 2-FTS IS

4.8200

2.8735

ng/mL

d5-NEtFOSA IS

Auto

8.781

486934

486934

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.781

486934

1171432

13C7-PFUnDA IS

5.0000

6.1636

ng/mL

NMeFOSE

Auto

8.504

245711

266054

d7-N-MeFOSE IS

5.0000

5.6559

nq/mL

NEtFOSE

Auto

8.755

764352

190687

d9-EtFOSE IS

5.0000

4.0406

ng/mL

d9-EtFOSE IS

Auto

8.737

190687

190687

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.737

190687

1171432

13C7-PFUnDA IS

5.0000

8.4512

ng/mL

NMeFOSA

Auto

8.529

196699

452572

d3-NMeFOSA IS

5.0000

4.7171

nq/mL

dB-NMeFOSA IS

Auto

8.524

452572

452572

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.524

452572

1171432

13C7-PFUnDA IS

5.0000

6.3357

nq/mL

d7-N-MeFOSE IS

Auto

8.489

266054

266054

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.489

266054

1171432

13C7-PFUnDA IS

5.0000

6.6464

nq/mL

NEtFOSA

Auto

8.791

350260

486934

d5-NEtFOSA IS

5.0000

4.9033

ng/mL

PFTrDA

Auto

8.326

1253104

564757

13C-PFTeDA IS

5.0000

7.3041

nq/mL

PFTeDA

Auto

8.625

1390932

564757

13C-PFTeDA IS

5.0000

6.8788

ng/mL

13C-PFTeDA IS

Auto

8.625

564757

564757

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.625

564757

1171432

13C7-PFUnDA IS

5.0000

3.0176

ng/mL

11CI-PFBOUdS

Auto

7.811

539518

444610

13C-PFOS IS

4.7100

5.2960

nq/mL

9CI-PF30NS

Auto

7.136

984157

444610

13C-PFOS IS

4.6600

4.4838

ng/mL

L-PFDoS

Auto

8.277

153968

444610

13C-PFOS IS

4.8400

5.1974

nq/mL

NaDONA

Auto

6.398

1736413

1709390

13C-PFNA IS

4.7100

4.8125

ng/mL

PFHxDA

Auto

9.148

462846

3066722

13C2-PFHxDA IS

5.0000

1.8971

nq/mL

PFODA

Auto

9.674

446911

3066722

13C2-PFHxDA IS

5.0000

2.8552

ng/mL

1BC2-PFHxDA IS

Auto

9.149

3066722

3066722

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.149

3066722

1171432

13C7-PFUnDA IS

5.0000

5.1716

ng/mL

13C7-PFUnDA IS

Auto

7.657

1171432

1171432

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.622

1880300

444610

13C-PFOS IS

4.6100

4.6598

ng/mL

PFBSA

Auto

6.131

1193596

431529

13C-FOSA IS

5.0000

5.3077

nq/mL

PFHxSA

Auto

6.959

986122

1709390

13C-PFNA IS

5.0000

4.6711

ng/mL

CHARGE

ND(W/B)

	

	

1171432

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 6.3131
1.72e5 Q 217.20>172.30 (-)

PFBA

Cone. 4.7892
1.72e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
1,79e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 5.8239
4.39e5 Q 267.90>223.00 (-)

A=840059
RT=4.206

fA= 1162756
RT= 5.362

O.OeO -*=£¦

4.00 4.25 4.50

RT (min)

PFPeA

Cone. 5.3263

4.00 4.25 4.50

RT (min)

13C-PFBS IS

Cone. 4.6500

O.OeO

4.00 4.25 4.50

RT (min)

13C-PFBS

Cone. 4.9146

fA= 1162756
RT= 5.362

O.OeO -

5.2

5.4

Q263.05>219.10 (-)

A=1140304

3.84e5 ISTD 301.80>80.00 (-)
1.5e5H

1.54e5 Q 301.80>80.00 (-)

5.6

RT (min)

PFBS

Cone. 4.7736
R#1 298.80>99.00 68.97 (68.21)

1.54e5 Q 299.00>80.00 (-)	1.12e5 ISTD 332.10>287.10 (-)

5.6

RT (min)

13C HFPO DA IS

Cone. 5.0000

A=430570
?T= 5.493

5.6 5.8
RT (min)

1.0e5

5.0e4

O.OeO

5.4

O.OeO

6.0

5.8
RT (min)

6.2 6.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

29ffi

-------


Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:20

CCV4-230428 (continued)

13C HFPO DA

Cone. 6.4637

Q 332.10>287.10 (-)

HFPO DA

Cone. 5.4316

R#1 329.00>285.10 81.49 (71.09)
Q 329.00>169.00 (-)	9.19e4

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 27.29 (25.06)

ISTD 329.00>309.15 (-)	7.99e4

13C-4 2-FTS

Cone. 5.1586

R#1 329.00>81.00 27.29 (25.06)
Q 329.00>309.15 (-)	7.99e4

A=280226
fl"=6.093

O.OeO -

J

4-2-FtS

Cone. 4.5237

R#1 327.00>81.10 16.96 (17.01)
Q 327.00>307.05 (-)	8.52e4

~ A=216933

-W-iL-_5 894

6.0

6.2 6.4
RT (min)

PFHxA

Cone. 5.0942

R#1 313.00> 119.10 2.69 (2.21)
Q 313.00>269.00 (-)	8.12e5

13C-PFHxA IS

Cone. 5.0000

I STD 314.90 >270.10 (-)
6.0e51

A= 1519090

Q 314.90>270.10 (-)
6.0e51

6.0 6.2
RT (min)

PFPeS

Cone. 5.0824

R#1 349.00>99.00 80.81 (89.24)
Q 349.00>79.95 (-)	1.27e5

A= 1519090

f A=314279

i-lh=

6.6

RT (min)

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

13C2-6 2-FTS

Cone. 4.5804

7.72e4 Q 428.90>409.00 (-)

6.0e4 ~

4.0e4 ~

2.0e4 ~

=== O.OeO 1. . .

187984
=6.654

6.6
RT (min)

PFHpS

Cone. 4.6313

R#1 449.00>99.20 65.78 (55.18)
Q 449.00>80.15 (-)	1.30e5

[A=308959

I6578 (~I~FfT=6.663

O.OeO -

6.0e4
4.0e4:
2.0e4:
O.OeO :

: R1 26.65 (

Mr.1.

176010
6.653

RT (min)

RT (min)

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

13C-PFOA

Cone. 5.4703

7.37e5 Q 416.80>372.05 (-)

6.6 6.8

RT (min)

PFOS

Cone. 4.5337

R#1 499.00>99.00 91.62 (93.90)
Q 499.00>80.00 (-)	6.29e4

13C-PFOS IS

Cone. 4.7750

105 (-)

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

A=1791962
RT=6.671

L

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

A=1791962
RT=6.671

L

6.0e4
4.0e4
2.0e4
O.OeO

r A=209957
!R1 91.62 (-|4t=6.957

6.8 7.0
RT (min)

6.8 7.0
RT (min)

6.75 7.00 7.25

RT (min)

1.5e5-
1.0e5i
5.0e4 ^
O.OeO -

6.0 6.2
RT (min)

PFHxS

Cone. 4.2633

R#1 399.00 >99.00 99.30 (92.93)
Q 399.00>80.00 (-)	8.28e4

~ A=237822
6.359

6.6
RT (min)

PFHpA

Cone. 4.9910

R#1 362.90>169.00 17.57 (16.60)
Q 362.90>319.00 (-)	9.47e5

: R1 17.57 (

It'

2257039
6.353

6.6
RT (min)

6-2-FTS

Cone. 4.7109

R#1 427.00>80.90 26.65 (29.85)
Q 427.00>407.00 (-)	7.11e4

6.2

6.4

6.6
RT (min)

PFOA

Cone. 4.9491

R#1 413.00 > 169.10 29.67 (28.84)
Q 413.00>369.00 (-)	9.94e5

fA=2410732

- R1 29.67 (-l-Ffr=6.672

RT (min)

6.8 7.0
RT (min)

13C-PFOS

Cone. 5.0371

1.87e5 Q 502.80>80.05 (-)

TAr4
rI='

1.5e5-
1.0e5i
5.0e4 ^
O.OeO -

444610
RT=6.957

\L

7.2

RT (min)

7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

292

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^ALsS

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:20

CCV4-230428 (continued)

PFNA

Cone. 4.0382

R#1 463.00>219.00 23.05 (19.07)

Q 463.00 		6.72e5

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

A=1648149
RT=6.977

i & i

ISTD 528.80> 509.00 (-)

3.0e4 :
2.0e4 :
1.0e4:
O.OeO :

f A=96693
I RT^ 7.306

=* i

	

ISTD 572.80>419.05 (-)

f A=618359
I RT^7.485

13C-PFUnDA

Cone. 5.7440

Q 564.80>519.95 (-)
6.0e5 -

4.0e5 ^

2.0e5 ^

O.OeO , ,

1666201
=7.657

1.5e5 -

1.0e5:
5.0e4 :
O.OeO :

f A=433230
I RT=7.744

13C-PFNA IS

Cone. 5.0000

13C-PFNA

Cone. 5.8711

ISTD 467.80>423.00 (-)	7.00e5 Q 467.80>423.00 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

f A=1709390
| Rli=6.976

6.8 7.0 7.2

RT (min)

13C-82-FTSJS

Cone. 4.7900

6.8 7.0 7.2

RT (min)

13C-82-FTS

Cone. 5.0011

3.61e4 Q 528.80> 509.00 (-)

3.0e4 :
2.0e4 :
1.0e4:
O.OeO :

f A=96693
M RT^ 7.306

sfe I



7.2 7.4 7.6

RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

2.30e5

2.0e5 -

RT47.485

7.8
RT (min)

_

7.6 7.8 8.0
RT (min)

PFOSA

Cone. 4.6854

R#1 498.20 >64.10 0.17 (0.11)

Q 498.20>78.00 (-)	1.67e5

13C-FOSAJS

Cone. 5.0000

ISTD S0G.00>78.05 (-;
1.5e5 ^

1.0e5 ^

5.0e4 ^

O.OeO 4:----:--

7.8 8.0

RT (min)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

f A=1709390
I R"tI=6.976

PFNS

Cone. 4.6872

R#1 549.00>99.00 67.88 (69.83)

Q 549.0'"	""	1.97e5

~ A=498911
\"RTj= 7.280

6.8

7.0

7.2

RT (min)

PFDA

Cone. 5.0422

R#1 512.90>219.00 18.20 (17.97)

3.61e4 Q 512.90>469.00 (-)	6.72e5 ISTD 514.80>469.95 (-;

13C-PFDAJS

Cone. 5.0000

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

~ A=1679366
RtA7 310



7.2 7.4 7.6

RT (min)

d3-N-MeFOSAA

Cone. 6.4342

Q 572.80>419.05 (-)	2.30e5

|A=618359

7.2

7.4

7.6 7.8
RT (min)

1.5e5 -

1.0e5-
5.0e4 ¦
O.OeO -

TAf5
il r|=

576202
7.490

7.25 7.50 7.75

PFUnDA

Cone. 4.0233

R#1 563.00>219.00 14.94(12.92)

Q 563.00>518.90 (-)	4.81e5

1312292
^7.657

d5-N-EtFOSAAIS

Cone. 5.0000

ISTD 588.80>419.00 (-;

O.OeO -

7.8 8.0
RT (min)

A=431529
RT=7.744

1.5e5 -

1.0e5 ^
5.0e4 ^
O.OeO 4p

ft DT=7

7.8 8.0

RT (min)

6.0e5 -

4.0e5:
2.0e5:
O.OeO :

r A=1758695
I RT^7.310

7.6
RT (min)

NMeFOSAA

Cone. 4.6949

R#1 570.20>512.00 42.38 (38.98)
Q 570.20>419.00 (-)	1.75e5

7.2

7.4

=?53091
| RTj7 619

RT (min)

d5-N-EtFOSAA

Cone. 6.5792

2.36e5 Q 588.80>419.00 (-)	2.36e5

f A=674153
I RT=|7.668

O.OeO-

7.6 7.8 8.0
RT (min)
13C-FOSA

Cone. 5.5965

Q 506.00>78.05 (-)	1.69e5

f A=431529

7.6

6.0e5 -
4.0e5 -
2.0e5 -
O.OeO

f A=1640204
I RT^b.OOO

7.6 7.8 8.0

RT (min)

8-2-FTS

Cone. 3.6150

R#1 527.20>487.00 8.58 (6.24)

Q 527.1 		3.15e4

3.0e4 -
2.0e4 ^
1.0e4^
O.OeO :

F A=83594
Rti7.305

7.4 7.6
RT (min)

7.4 7.6

RT (min)

13C-PFDA

Cone. 5.3357

Q 514.80>469.95 (-)

¥A=1758695
6.0e5 ^	RT |=7.310

4.0e5 i	I

2.0e5i	i

O.OeO4r-T--T-^,' ,

7.6
RT (min)

PFDS

Cone. 4.5010

R#1 599.00>99.00 59.77 (59.45)

Q 599.00>80.10 (-)	1.36e5

7.6
RT (min)

13C-PFUnDAJS

Cone. 5.0000

ISTD 564.80>519.95 (-;
6.0e5 i

A=1666201
RT^7.657

4.0e5 -

2.0e5:
O.OeO -

RT (min)

8.0
RT (min)

NEtFOSAA

Cone. 4.1958

R#1 584.20>526.10 61.14 (51.48)

Q 584.20>418.95 (-)	1.68e5

fA=559542

1.5e5 -

1.0e5 ^
5.0e4 ^
O.OeO1

-u

7.8 8.0
RT (min)

PFDoA

Cone. 4.4530

R#1 613.05>169.00 17.48 (17.39)
Q 613.0	6.05e5

7.50 7.75 8.00

RT (min)

13C-PFDoA_IS

Cone. 5.0000

ISTD 614.80> 569.95 (-;
6.0e5 H

6.18e5

yA= 1648651
RT=b.000

4.0e5 :
2.0e5:
O.OeO :

RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

293

-------


Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:20

CCV4-230428 (continued)

13C-PFDoA

Cone. 5.7944

Q614.80>569.95 (-)
6.0e5 H

NEtFOSE

Cone. 4.0406

Q 629.50>59.10 (-)

d3-NMeFOSA

Cone. 6.3357

Q 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4 -
O.OeO -

O.OeO -



8.6

O.OeO



fA=1

53968

: R1 68.34

r

B.277

: i

I

r

10-2-FtS

Cone. 2.8735

R#1 626.50>81.05 94.73 (57.89)
Q 626.50>607.05 (-)	2.63e4

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 6.1636

1.94e5 Q 531.10>169.10 (-)

NMeFOSE

Cone. 5.6559

1.94e5 Q 616.10>58.90 (-)

RT (min)

d9-EtFOSE IS

Cone. 5.0000

2.97e5 ISTD 638.90> 59.10 (-)

6.0e4 i
4.0e4 i
2.0e4 i
— O.OeO 1 . . .

7.30e4 Q 638.90> 59.10 (-)

6.0e4 i
4.0e4 i
2.0e4 i
— O.OeO 1 . . .

9.0
RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

ISTD 623.00>59.00 (-)
1.0e5 -

A=266054
RT=8.489

8.4 8.6 8.8
RT (min)

PFTeDA

Cone. 6.8788

R#1 713.00> 169.30 12.11 (10.00)
Q 713.00>668.90 (-)	5.22e5

A=1390932
RT=8.625

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)
2.0e5

.8 9.0
RT (min)

L-PFDoS

Cone. 5.1974

R#1 698.80>98.80 68.34 (75.26)
Q 698.80>80.10 (-)	6.42e4

4.0e4 :
2.0e4 :

B.2 8.4 8.6

RT (min)

NaDONA

Cone. 4.8125

Q 377.10>251.20 (-)

6.0e5 -
4.0e5 :
2.0e5 :
O.OeO :

f A= 196699

:R1 80.58 (--|-kT=8.529

6.0e4 -
4.0e4z_
2.0e4z_
O.OeO -

9.0
RT (min)

9.0
RT (min)

d7-N-MeFOSE

Cone. 6.6464

Q 623.00>59.00 (-)
1.0e5 -

rA=266054
RT=8.489

IR1 62.11 (-¦

I RT=8.791

:	J-



RT (min)

RT (min)

13C-PFTeDA

Cone. 3.0176

11CI-PF30UdS

Cone. 5.2960

Q 714.80>669.80 (-)
2.0e5

Q 631.00>451.10 (-)
2.0e5 -

8.6 8.8 9.0
RT (min)

9.0
RT (min)

PFHxDA

Cone. 1.8971

PFODA

Cone. 2.8552

7.67e5 Q 812.90>769.00 (-)

1.96e5 Q 912.80>869.00 (-)

6.2 6.4 6.6

RT (min)

9.0
RT (min)

NMeFOSA

Cone. 4.7171

R#1 512.10>219.20 80.58 (76.68)
Q 512.10> 169.20 (-)	7.61 e4

RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

1.5e5-
1.0e5-
5.0e4-
O.OeO -

8.4 8.6 8.8
RT (min)

NEtFOSA

Cone. 4.9033

R#1 526.50>219.20 62.11 (65.87)
Q 526.50> 169.10 (-)	1.37e5

A=350260

8.4 8.6 8.8
RT (min)

PFTrDA

Cone. 7.3041

R#1 663.10> 169.10 22.78 (18.12)
Q 663.10>618.90 (-)	4.89e5

9.0

RT (min)

O.OeO

i.2 8.4 8.6

RT (min)

9CI-PF30NS

Cone. 4.4838

Q 531.00>351.10 (-)
4.0e51

4.06e5

A=984157
RT=7.136



RT (min)

7.4

RT (min)

13C2-PFHxDA IS

Cone. 5.0000

1.57e5 I STD 815.00 > 770.00 (-)

TA=3066722
RT=9149



9.8 10.0

RT (min)

9.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1~230428B-537MOD_OldCal_Corrected.iproc

293

-------
A

Insight Report
Quantitation/lntegration
Printed 10/26/2023 11:05:20

CCV4-230428 (continued)

13C2-PFHxDA

Cone 5.1716

13C7-PFUnDA IS

Cone. 5.0000

Q 815.00>770.00 (-)	1,30e6 ISTD 569.80> 524.90 (-)

fA=3066722

PFecHS	PFBSA

Cone. 4.6598	Cone. 5.3077
R#1 461.00>99.10 40.98 (38.19)

4.21 e5 Q 461.00>381.00 (-)	7.65e5	Q 298.00>78.00 (-)

PFHxSA

Cone. 4.6711

4.78e5 Q 397.90>78.00 (-)

O.OeO -

;



9.0 9.2 9.4

RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	1.00e0

5.0e0 -

0.2
RT (min)

171432

TA= 1880300

=6.622

RT (min)

fA= 1193596
RT=6.131

7.0 7.2

RT (min)

Z:\LabSolutions\Data\LCMS1-230428\LCMS1-230428B-537MOD_OldCal_Corrected.iproc

293

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10/24/2023 5:20:21 PM Page 1 /4

==== Shimadzu LabSolutions Batch Table====

[General]

Start from Continuing Row
[Folder]

Use Current Folder
[Data Filename]

Not Create filename
[ASCII Conversion]

Not Output ASCII Files
[File Conversion]

Not Convert
[QA/QC]

Not Execute QA/QC
[Option Item]

Option 1 Title:

Option 2 Title:

Option 3 Title:

Option 4 Title:

Option 5 Title:

Option 6 Title:

Option 7 Title:

Option 8 Title:

Option 9 Title:

Option 10 Title:

[Bracket]

None
[Startup]

Startup Off
[Shutdown]

Shutdown On
Cool down Time:0min
Degassing Unit Off
LC Pump Off
Column Oven Off
[Comment]

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230503 537M.lcm

230504051.led

0

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230503 537M.lcm

230504052.led

0

5\System\DEFAULT.Isr

3

LLCCV1 -230504-WI

LLCCV1-230504-WI

2:Control

CMS1 230503 537M.lcm

230504053.led

1

5\System\DEFAULT.Isr

4

CCV1-230504-WI

CCV1-230504-WI

2:Control

CMS1 230503 537M.lcm

230504054.led

2

5\System\DEFAULT.Isr

16

CCV1-230504

CCV1-230504

2:Control

CMS1 230503 537M.lcm

230504055.led

5

5\System\DEFAULT.Isr

16

CCV1-230504

CCV1-230504

2:Control

CMS1 230503 537M.lcm

230504056.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230503 537M.lcm

230504057.led

0

5\System\DEFAULT.Isr

3

L0.05ppb_230502

L0.05ppb_230502

1:Standard:(l)

CMS1 230503 537M.lcm

230504058.led

1

5\System\DEFAULT.Isr

4

L0.1 ppb_230502

L0.1 ppb_230502

1:Standard

CMS1 230503 537M.lcm

230504059.led

2

5\System\DEFAULT.Isr

5

L0.5ppb_230502

L0.5ppb_230502

1:Standard

CMS1 230503 537M.lcm

230504060.led

3

5\System\DEFAULT.Isr

296

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD.Icb

-------
10/24/2023 5:20:21 PM Page 2 / 4

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

6

L1ppb_230502

L1ppb_230502

1:Standard

CMS1 230503 537M.lcm

230504061.led

4

5\System\DEFAULT.Isr

7

L2.5ppb_230502

L2.5ppb_230502

1:Standard

CMS1 230503 537M.lcm

230504062.led

8

5\System\DEFAULT.Isr

8

L5ppb_230502

L5ppb_230502

1:Standard

CMS1 230503 537M.lcm

230504063.led

5

5\System\DEFAULT.Isr

9

L10ppb_230502

L10ppb_230502

1:Standard

CMS1 230503 537M.lcm

230504064.led

6

5\System\DEFAULT.Isr

10

L15ppb_230502

L15ppb_230502

1:Standard

CMS1 230503 537M.lcm

230504065.led

7

5\System\DEFAULT.Isr

2

LBLK 230502

LBLK 230502

0:Unknown

CMS1 230503 537M.lcm

230504066.led

0

5\System\DEFAULT.Isr

11

Branched Mix 230323

Branched Mix 230321

3:Unspiked

CMS1 230503 537M.lcm

230504067.led

0

5\System\DEFAULT.Isr

12

ICV1-230504

ICV1-230504

2:Control

CMS1 230503 537M.lcm

230504068.led

4

5\System\DEFAULT.Isr

12

ICV1-230504

ICV1-230504

2:Control

CMS1 230503 537M.lcm

230504069.led

4

5\System\DEFAULT.Isr

2

LBLK 230502

LBLK 230502

0:Unknown

CMS1 230503 537M.lcm

230504070.led

0

5\System\DEFAULT.Isr

28

23042199-14A

23042199-14A

0:Unknown

CMS1 230503 537M.lcm

230504071.led

0

5\System\DEFAULT.Isr

29

23042199-19A

23042199-19A

0:Unknown

CMS1 230503 537M.lcm

230504072.led

0

5\System\DEFAULT.Isr

30

23042199-22A

23042199-22A

0:Unknown

CMS1 230503 537M.lcm

230504073.led

0

5\System\DEFAULT.Isr

31

23042199-26A

23042199-26A

0:Unknown

CMS1 230503 537M.lcm

230504074.led

0

5\System\DEFAULT.Isr

32

23042199-30A

23042199-30A

0:Unknown

CMS1 230503 537M.lcm

230504075.led

0

5\System\DEFAULT.Isr

33

23042199-34A

23042199-34A

0:Unknown

CMS1 230503 537M.lcm

230504076.led

0

5\System\DEFAULT.Isr

34

23042199-38A

23042199-38A

0:Unknown

CMS1 230503 537M.lcm

230504077.led

0

5\System\DEFAULT.Isr

35

23042199-40A

23042199-40A

0:Unknown

CMS1 230503 537M.lcm

230504078.led

0

5\System\DEFAULT.Isr

36

23042199-41A

23042199-41A

0:Unknown

CMS1 230503 537M.lcm

230504079.led

0

5\System\DEFAULT.Isr

37

23042199-42A

23042199-42A

0:Unknown

CMS1 230503 537M.lcm

230504080.led

0

5\System\DEFAULT.Isr

16

CCV2-230504

CCV2-230504

2:Control

CMS1 230503 537M.lcm

230504081.led

5

5\System\DEFAULT.Isr

16

CCV2-230504

CCV2-230504

2:Control

CMS1 230503 537M.lcm

230504082.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230503 537M.lcm

230504083.led

0

5\System\DEFAULT.Isr

38

23042199-43A

23042199-43A

0:Unknown

CMS1 230503 537M.lcm

230504084.led

0

5\System\DEFAULT.Isr

39

23042199-44A

23042199-44A

0:Unknown

CMS1 230503 537M.lcm

230504085.led

0

5\System\DEFAULT.Isr

28

MBLK-215208

MBLK-215208

0:Unknown

CMS1 230503 537M.lcm

230504086.led

0

5\System\DEFAULT.Isr

29

LCS-WI-215208

LCS-WI-215208

0:Unknown

CMS1 230503 537M.lcm

230504087.led

0

5\System\DEFAULT.Isr

1

23041906-14AMS

23041906-14AMS

0:Unknown

CMS1 230503 537M.lcm

230504088.led

0

5\System\DEFAULT.Isr

2

23041906-14AMSD

23041906-14AMSD

0:Unknown

CMS1 230503 537M.lcm

230504089.led

0

5\System\DEFAULT.Isr

30

23041906-21AMS

23041906-21 AMS

0:Unknown

CMS1 230503 537M.lcm

230504090.led

0

5\System\DEFAULT.Isr

31

23041906-21AMSD

23041906-21 AMSD

0:Unknown

CMS1 230503 537M.lcm

230504091.led

0

5\System\DEFAULT.Isr

32

23041906-21A

23041906-21A

0:Unknown

CMS1 230503 537M.lcm

230504092.led

0

5\System\DEFAULT.Isr

33

23041906-20A

23041906-20A

0:Unknown

CMS1 230503 537M.lcm

230504093.led

0

5\System\DEFAULT.Isr

16

CCV3-230504

CCV3-230504

2:Control

CMS1 230503 537M.lcm

230504094.led

5

5\System\DEFAULT.Isr

16

CCV3-230504

CCV3-230504

2:Control

CMS1 230503 537M.lcm

230504095.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230503 537M.lcm

230504096.led

0

5\System\DEFAULT.Isr

34

23041906-22A

23041906-22A

0:Unknown

CMS1 230503 537M.lcm

230504097.led

0

5\System\DEFAULT.Isr

35

23041906-23A

23041906-23A

0:Unknown

CMS1 230503 537M.lcm

230504098.led

0

5\System\DEFAULT.Isr

46

23041906-34A

23041906-34A

0:Unknown

CMS1 230503 537M.lcm

230504112.led

0

5\System\DEFAULT.Isr

47

23041906-35A

23041906-35A

0:Unknown

CMS1 230503 537M.lcm

230504113.led

0

5\System\DEFAULT.Isr

48

23041906-36A

23041906-36A

0:Unknown

CMS1 230503 537M.lcm

230504114.led

0

5\System\DEFAULT.Isr

290

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD.Icb

-------
10/24/2023 5:20:21 PM Page 3 / 4

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

49

23041906-37A

23041906-37A

0:Unknown

CMS1 230503 537M.lcm

230504115.led

0

5\System\DEFAULT.Isr

50

23042109-01G

23042109-01G

0:Unknown

CMS1 230503 537M.lcm

230504116.led

0

5\System\DEFAULT.Isr

51

23042374-01G

23042374-01G

0:Unknown

CMS1 230503 537M.lcm

230504117.led

0

5\System\DEFAULT.Isr

50

23042109-01G

23042109-01G

0:Unknown

CMS1 230503 537M.lcm

230504118.led

0

5\System\DEFAULT.Isr

51

23042374-01G

23042374-01G

0:Unknown

CMS1 230503 537M.lcm

230504119.led

0

5\System\DEFAULT.Isr

16

CCV4-230504

CCV4-230504

2:Control

CMS1 230503 537M.lcm

230504107.lcd

5

5\System\DEFAULT.Isr

16

CCV4-230504

CCV4-230504

2:Control

CMS1 230503 537M.lcm

230504108.lcd

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230503 537M.lcm

230504109.lcd

0

5\System\DEFAULT.Isr

30

23041906-21AMS

23041906-21 AMS

0:Unknown

CMS1 230503 537M.lcm

230504123.led

0

5\System\DEFAULT.Isr

31

23041906-21AMSD

23041906-21 AMSD

0:Unknown

CMS1 230503 537M.lcm

230504124.led

0

5\System\DEFAULT.Isr

1

MBLK-215318

MBLK-215318

0:Unknown

CMS1 230503 537M.lcm

230504125.led

0

5\System\DEFAULT.Isr

2

LCS-WI-215318

LCS-WI-215318

0:Unknown

CMS1 230503 537M.lcm

230504126.led

0

5\System\DEFAULT.Isr

4

23041906-21A MS

23041906-21A MS

0:Unknown

CMS1 230503 537M.lcm

230504127.led

0

5\System\DEFAULT.Isr

5

23041906-21 AMSD

23041906-21 AMSD

0:Unknown

CMS1 230503 537M.lcm

230504128.led

0

5\System\DEFAULT.Isr

6

23041906-21A

23041906-21A

0:Unknown

CMS1 230503 537M.lcm

230504129.led

0

5\System\DEFAULT.Isr

28

MBLK-215502

MBLK-215502

0:Unknown

CMS1 230503 537M.lcm

230504130.lcd

0

5\System\DEFAULT.Isr

29

LCS-WI-215502

LCS-WI-215502

0:Unknown

CMS1 230503 537M.lcm

230504131.led

0

5\System\DEFAULT.Isr

48

23042494-01A

23042494-01A

0:Unknown

CMS1 230503 537M.lcm

230504132.lcd

0

5\System\DEFAULT.Isr

16

CCV5-230504

CCV5-230504

2:Control

CMS1 230503 537M.lcm

230504133.lcd

5

5\System\DEFAULT.Isr

16

CCV5-230504

CCV5-230504

2:Control

CMS1 230503 537M.lcm

230504134.lcd

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230503 537M.lcm

230504135.lcd

0

5\System\DEFAULT.Isr

49

23042494-02A

23042494-02A

0:Unknown

CMS1 230503 537M.lcm

230504136.lcd

0

5\System\DEFAULT.Isr

50

23042494-03A

23042494-03A

0:Unknown

CMS1 230503 537M.lcm

230504137.lcd

0

5\System\DEFAULT.Isr

51

23042494-04A

23042494-04A

0:Unknown

CMS1 230503 537M.lcm

230504138.lcd

0

5\System\DEFAULT.Isr

16

CCV6-230504

CCV6-230504

2:Control

CMS1 230503 537M.lcm

230504139.lcd

5

5\System\DEFAULT.Isr

16

CCV6-230504

CCV6-230504

2:Control

CMS1 230503 537M.lcm

230504140.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230503 537M.lcm

230504141.led

0

5\System\DEFAULT.Isr

16

CCV6-230504

CCV6-230504

2:Control

CMS1 230503 537M.lcm

230504142.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230503 537M.lcm

230504143.led

0

5\System\DEFAULT.Isr

1

MBLK-215318

MBLK-215318

0:Unknown

CMS1 230503 537M.lcm

230504144.led

0

5\System\DEFAULT.Isr

2

LCS-WI-215318

LCS-WI-215318

0:Unknown

CMS1 230503 537M.lcm

230504145.led

0

5\System\DEFAULT.Isr

4

23041906-21A MS

23041906-21A MS

0:Unknown

CMS1 230503 537M.lcm

230504146.led

0

5\System\DEFAULT.Isr

5

23041906-21 AMSD

23041906-21 AMSD

0:Unknown

CMS1 230503 537M.lcm

230504147.led

0

5\System\DEFAULT.Isr

6

23041906-21A

23041906-21A

0:Unknown

CMS1 230503 537M.lcm

230504148.led

0

5\System\DEFAULT.Isr

28

MBLK-215502

MBLK-215502

0:Unknown

CMS1 230503 537M.lcm

230504149.led

0

5\System\DEFAULT.Isr

29

LCS-WI-215502

LCS-WI-215502

0:Unknown

CMS1 230503 537M.lcm

230504150.lcd

0

5\System\DEFAULT.Isr

16

CCV7-230504

CCV7-230504

2:Control

CMS1 230503 537M.lcm

230504151.led

5

5\System\DEFAULT.Isr

16

CCV7-230504

CCV7-230504

2:Control

CMS1 230503 537M.lcm

230504152.lcd

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230503 537M.lcm

230504153.lcd

0

5\System\DEFAULT.Isr

48

23042494-01A

23042494-01A

0:Unknown

CMS1 230503 537M.lcm

230504154.lcd

0

5\System\DEFAULT.Isr

49

23042494-02A

23042494-02A

0:Unknown

CMS1 230503 537M.lcm

230504155.lcd

0

5\System\DEFAULT.Isr

298

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD.Icb

-------
10/24/2023 5:20:21 PM Page 4 / 4

Vial#

Sample Name

Sample ID

Sample Type

Method File

Data File

Level#

Report Format File

50

23042494-03A

23042494-03A

0:Unknown

CMS1 230503 537M.lcm

230504156.lcd

0

5\System\DEFAULT.Isr

51

23042494-04A

23042494-04A

0:Unknown

CMS1 230503 537M.lcm

230504157.lcd

0

5\System\DEFAULT.Isr

49

23042494-02A

23042494-02A

0:Unknown

CMS1 230503 537M.lcm

230504158.lcd

0

5\System\DEFAULT.Isr

50

23042494-03A

23042494-03A

0:Unknown

CMS1 230503 537M.lcm

230504159.lcd

0

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230503 537M.lcm

230504160.led

0

5\System\DEFAULT.Isr

16

CCV8-230504

CCV8-230504

2:Control

CMS1 230503 537M.lcm

230504161.led

5

5\System\DEFAULT.Isr

16

CCV8-230504

CCV8-230504

2:Control

CMS1 230503 537M.lcm

230504162.led

5

5\System\DEFAULT.Isr

2

LBLK 230323

LBLK 230323

0:Unknown

CMS1 230503 537M.lcm

230504163.led

0

5\System\DEFAULT.Isr

1

MEOH

MEOH

0:Unknown

CMS1 230503 537M.lcm

230504164.led

0

5\System\DEFAULT.Isr

1

MEOH

MEOH

0:Unknown

CMS1_230503_537M.lcm

230504165.led

0

5\System\DEFAULT.Isr

298

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD.Icb

-------


Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:01:55

ICV1-230504

Sample ID: ICV1-230504

Date Acquired: 5/4/2023 6:48:02 PM

Acquired by: System Administrator

Data File: 230504069

Vial: 12 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone.

Cone. Unit

13C-PFBA IS

Auto

4.378

1264196

1264196

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.378

1264196

2347341

13C7-PFUnDA IS

5.0000

5.0898

nq/mL

PFBA

Auto

4.379

226719

1264196

13C-PFBA IS

1.0000

0.7760

nq/mL

13C-PFPeA IS

Auto

5.549

2329941

2329941

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.549

2329941

2347341

13C7-PFUnDA IS

5.0000

5.2953

nq/mL

PFPeA

Auto

5.549

434079

2329941

13C-PFPeA IS

1.0000

0.9532

nq/mL

13C-PFBS IS

Auto

5.671

855697

855697

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.671

855697

2347341

13C7-PFUnDA IS

4.6500

4.8784

nq/mL

PFBS

Auto

5.672

124860

855697

13C-PFBS IS

0.8840

0.8215

nc

13C HFPO DA IS

Auto

6.263

637193

637193

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.263

637193

2347341

13C7-PFUnDA IS

5.0000

5.3659

nc

HFPO DA

Auto

6.262

97378

637193

13C HFPO DA IS

1.0000

0.8946

nq/mL

13C-4 2-FTS IS

Auto

6.069

327466

327466

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

6.069

327466

2347341

13C7-PFUnDA IS

4.6700

4.6903

nq/mL

4-2-FtS

Auto

6.069

79403

327466

13C-4 2-FTS IS

0.9340

0.9473

nq/mL

PFHxA

Auto

6.122

872179

3088123

13C-PFHxA IS

1.0000

0.9588

nq/mL

13C-PFHxA IS

Auto

6.121

3088123

3088123

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

6.121

3088123

2347341

13C7-PFUnDA IS

5.0000

5.1917

nq/mL

PFPeS

Auto

6.157

127745

885261

180-PFHxS IS

0.9380

0.8756

nq/mL

PFHxS

Auto

6.515

99964

885261

180-PFHxS IS

0.9100

0.7942

nq/mL

13C-PFHpA IS

Auto

6.512

3215247

3215247

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.512

3215247

2347341

13C7-PFUnDA IS

5.0000

5.3842

nq/mL

180-PFHxS IS

Auto

6.515

885261

885261

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.515

885261

2347341

13C7-PFUnDA IS

4.7250

5.0138

nq/mL

PFHpA

Auto

6.512

964147

3215247

13C-PFHpA IS

1.0000

0.9583

nq/mL

13C2-6 2-FTS IS

Auto

6.806

358049

358049

	

4.7500

4.7500

nq/mL

13C2-6 2-FTS

Auto

6.806

358049

2347341

13C7-PFUnDA IS

4.7500

4.9317

nq/mL

PFHpS

Auto

6.812

127865

885261

180-PFHxS IS

0.9520

0.9308

nq/mL

6-2-FTS

Auto

6.806

78705

358049

13C2-6 2-FTS IS

0.9480

1.0303

nq/mL

PFOA

Auto

6.823

1001914

3503911

13C-PFOA IS

1.0000

0.9251

nq/mL

13C-PFOA IS

Auto

6.823

3503911

3503911

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.823

3503911

2347341

13C7-PFUnDA IS

5.0000

5.3181

nq/mL

PFOS

Auto

7.120

91299

798410

13C-PFOS IS

0.9280

0.8916

nq/mL

13C-PFOS IS

Auto

7.120

798410

798410

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

7.120

798410

2347341

13C7-PFUnDA IS

4.7750

4.9952

nq/mL

PFNA

Auto

7.144

765350

3203159

13C-PFNA IS

1.0000

0.9770

nq/mL

13C-PFNA IS

Auto

7.144

3203159

3203159

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.144

3203159

2347341

13C7-PFUnDA IS

5.0000

5.1887

nq/mL

PFNS

Auto

7.455

204926

798410

13C-PFOS IS

0.9600

0.9225

nq/mL

8-2-FTS

Auto

7.483

38007

140450

13C-8 2-FTS IS

0.9580

1.0370

nq/mL

13C-8 2-FTS IS

Auto

7.484

140450

140450

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.484

140450

2347341

13C7-PFUnDA IS

4.7900

4.8518

nq/mL

PFDA

Auto

7.488

740504

3486274

13C-PFDA IS

1.0000

0.9625

nq/mL

13C-PFDA IS

Auto

7.488

3486274

3486274

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.488

3486274

2347341

13C7-PFUnDA IS

5.0000

5.3136

nq/mL

d3-N-MeFOSAA IS

Auto

7.668

1074810

1074810

	

5.0000

5.0000

nq/mL

d3-N-MeFOSAA

Auto

7.668

1074810

2347341

13C7-PFUnDA IS

5.0000

5.2147

nq/mL

NMeFOSAA

Auto

7.672

221669

1074810

d3-N-MeFOSAA IS

1.0000

0.9114

nq/mL

PFDS

Auto

7.797

139959

798410

13C-PFOS IS

0.9640

0.9198

nq/mL

13C-PFUnDA IS

Auto

7.838

3039533

3039533

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.838

3039533

2347341

13C7-PFUnDA IS

5.0000

5.0462

nq/mL

PFUnDA

Auto

7.838

612788

3039533

13C-PFUnDA IS

1.0000

0.9757

nq/mL

d5-N-EtFOSAA IS

Auto

7.852

1207083

1207083

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.852

1207083

2347341

13C7-PFUnDA IS

5.0000

5.1821

nq/mL

NEtFOSAA

Auto

7.859

213997

1207083

dS-N-EtFOSAA IS

1.0000

0.8968

nq/mL

PFOSA

Auto

7.903

218817

951555

13C-FOSA IS

1.0000

0.9444

nq/mL

13C-FOSA IS

Auto

7.903

951555

951555

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.903

951555

2347341

13C7-PFUnDA IS

5.0000

5.3502

nq/mL

PFDoA

Auto

8.177

746349

2833437

13C-PFDoA IS

1.0000

0.9925

nq/mL

13C-PFDoA IS

Auto

8.176

2833437

2833437

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

200

-------
A

(ALS)

Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:01:55

ICV1 -230504 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.176

2833437

2347341

13C7-PFUnDA IS

5.0000

5.1440

nq/mL

10-2-FtS

Auto

8.189

31806

140450

13C-8 2-FTS IS

0.9640

0.9994

ng/mL

d5-NEtFOSA IS

Auto

8.906

1048015

1048015

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.906

1048015

2347341

13C7-PFUnDA IS

5.0000

5.2730

ng/mL

NMeFOSE

Auto

8.636

86321

460160

d7-N-MeFOSE IS

1.0000

0.9893

nq/mL

NEtFOSE

Auto

8.879

254318

249471

d9-EtFOSE IS

1.0000

0.9441

ng/mL

d9-EtFOSE IS

Auto

8.862

249471

249471

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.862

249471

2347341

13C7-PFUnDA IS

5.0000

5.1527

ng/mL

NMeFOSA

Auto

8.663

93373

930872

d3-NMeFOSA IS

1.0000

0.9761

nq/mL

dB-NMeFOSA IS

Auto

8.657

930872

930872

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.657

930872

2347341

13C7-PFUnDA IS

5.0000

5.2226

nq/mL

d7-N-MeFOSE IS

Auto

8.620

460160

460160

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.620

460160

2347341

13C7-PFUnDA IS

5.0000

5.2832

nq/mL

NEtFOSA

Auto

8.916

146790

1048015

d5-NEtFOSA IS

1.0000

0.9695

ng/mL

PFTrDA

Auto

8.493

671281

1268543

13C-PFTeDA IS

1.0000

1.0363

nq/mL

PFTeDA

Auto

8.783

676090

1268543

13C-PFTeDA IS

1.0000

1.0750

ng/mL

13C-PFTeDA IS

Auto

8.783

1268543

1268543

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.783

1268543

2347341

13C7-PFUnDA IS

5.0000

4.7084

ng/mL

11CI-PFBOUdS

Auto

7.987

237290

798410

13C-PFOS IS

0.9420

0.9328

nq/mL

9CI-PF30NS

Auto

7.307

415151

798410

13C-PFOS IS

0.9320

0.8831

ng/mL

L-PFDoS

Auto

8.442

57118

798410

13C-PFOS IS

0.9680

0.8670

nq/mL

NaDONA

Auto

6.555

691315

3203159

13C-PFNA IS

0.9420

0.9191

ng/mL

PFHxDA

Auto

9.293

261082

6085870

13C2-PFHxDA IS

1.0000

0.9224

nq/mL

PFODA

Auto

9.884

200700

6085870

13C2-PFHxDA IS

1.0000

0.8834

ng/mL

13C2-PFHxDA IS

Auto

9.293

6085870

6085870

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.293

6085870

2347341

13C7-PFUnDA IS

5.0000

5.1578

ng/mL

13C7-PFUnDA IS

Auto

7.838

2347341

2347341

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.772

671469

798410

13C-PFOS IS

0.9200

0.7946

ng/mL

PFBSA

Auto

6.307

520621

951555

13C-FOSA IS

1.0000

0.9534

nq/mL

PFHxSA

Auto

7.116

420715

3203159

13C-PFNA IS

1.0000

0.9866

ng/mL

CHARGE

ND(W/B)

	

	

2347341

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 5.0898
2.96e5 Q 217.20>172.30 (-)

PFBA

Cone. 0.7760
2.96e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
6.70e4 ISTD 267.90>223.00 (-)

RT (min)

RT (min)

PFPeA

Cone. 0.9532

13C-PFBS IS

Cone. 4.6500

13C-PFBS

Cone. 4.8784

~ A=855697
RT= 5.671

5.8 6.0
RT (min)

13C-PFPeA

Cone. 5.2953
8.74e5 Q 267.90>223.00 (-)

JA=2329941
RT= 5.549

5.4

=F
5.6

A=2329941
RT= 5.549

RT (min)

13C HFPO DA IS

Cone. 5.0000

5.8

RT (min)

PFBS

Cone. 0.8215
R#1 298.80>99.00 68.31 (71.09)

3.24e5 Q 299.00>80.00 (-)	4.78e4 ISTD 332.10>287.10 (-)

f A= 124860

-R1 68.31 (fRt= 5.672

6.0
RT (min)

6.4 6.6
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

20®

-------


Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:01:55

ICV1 -230504 (continued)

13C HFPO DA

Cone. 5.3659

Q 332.10>287.10 (-)

J A=637193
RT=6.263

HFPO DA

Cone. 0.8946

R#1 329.00>285.10 87.27 (79.97)
Q 329.00>169.00 (-)	4.42e4

| A=97378
4.0e4- 87.27 (f-Rt=6.262

O.OeO -

6.2

6.4 6.6
RT (min)

PFHxA

Cone. 0.9588

R#1 313.00> 119.10 2.51 (2.85)
Q 313.00>269.00 (-)	3.88e5

3.0e5 :
2.0e5 i
1.0e5 -i
O.OeO :

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)



^A=872179

: R1 2.51 (-

HT=6.122

I

J

I

A=3088123
RT=6.121

6.2 6.4

RT (min)

13C-PFHpA_IS

Cone. 5.0000

ISTD 366.90>322.10 (-)
1.5e6 -i

1.0e6 -
5.0e5 :
O.OeO -

A=3215247
RT=6.512

13C-PFHpA

Cone. 5.3842

Q 366.90>322.10 (-)
1.5e6 -i

A=3215247
RT=6.512

6.6 6.8
RT (min)

13C2-6 2-FTS IS

Cone. 4.7500

13C2-6 2-FTS

Cone. 4.9317

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
1.5e6 -
1.0e6 ^

5.0e5 ^

O.OeO 1. . .

Q 416.80>372.05 (-)
1.5e6 -
1.0e6 -j
5.0e5 ^

O.OeO 1. . . .

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00 >81.00 27.89 (26.74)

ISTD 329.00>309.15 (-)	1.45e5

IR1 27.89 (•

A=327466
ftt=6.069

13C-PFHxA

Cone. 5.1917

1.36e6 Q 314.90>270.10 (-)

JA=3088123
RT=6.121

6.2 6.4

RT (min)

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)
4.0e51

A=885261
RT=6.515

6.6 6.8
RT (min)

O.OeO -

7.0
RT (min)

6.6

6.8

IR1 95.71 (--

M

f A=91299
RT=7.120

13C-4 2-FTS

Cone. 4.6903

R#1 329.00>81.00 27.89 (26.74)
Q 329.00>309.15 (-)	1.45e5

I R1 27.89 (

4-2-FtS

Cone. 0.9473

R#1 327.00>81.10 16.52 (16.29)
Q 327.00>307.05 (-)	3.52e4

A=79403

ftt=6.069

O.OeO

6.2 6.4
RT (min)

6.2 6.4
RT (min)

PFPeS

Cone. 0.8756

R#1 349.00>99.00 87.14 (74.42)
Q 349.00>79.95 (-)	5.37e4

I R1 87.14 (J

fA= 127745
"Rt=6.157

6.2 6.4

RT (min)

180-PFHxS

Cone. 5.0138

Q 402.70>84.05 (-)
4.0e51

' A=885261
RT=6.515

O.OeO

6.6 6.8
RT (min)

PFHpS

Cone. 0.9308

R#1 449.00>99.20 65.01 (66.82)
Q 449.00>80.15 (-)	5.76e4

[A= 127865

-R1 65.01 (-if#=6.812

7.0
RT (min)

PFOS

Cone. 0.8916

R#1 499.00>99.00 95.71 (93.96)
Q 499.00>80.00 (-)	2.93e4

105 (-)

RT (min)

RT (min)

6.75 7.00 7.25 7.50

RT (min)

3.0e5 -
2.0e5 :
1.0e5:
O.OeO :

f A=798410
RT=7.120

6.2 6.4
RT (min)

PFHxS

Cone. 0.7942

R#1 399.00 >99.00 103.41 (95.46)
Q 399.00>80.00 (-)	3.82e4

jR1 10341 (-[™45

O.OeO

6.25 6.50 6.75 7.00
RT (min)

PFHpA

Cone. 0.9583

R#1 362.90>169.00 17.10 (17.56)
Q 362.90>319.00 (-)	4.39e5

f A=964147
4.0e5 -| R1 17.10 (• |-^r=6.512

O.OeO

6.6 6.8
RT (min)

6-2-FTS

Cone. 1.0303

R#1 427.00>80.90 25.60 (28.57)
Q 427.00>407.00 (-)	3.69e4

f A=78705

JR1 25.60 (-fl-^r=6.a
3.0e4 -

2.0e4z_

1.0e4z

O.OeO

6.6 6.8 7.0

RT (min)

13C-PFOS IS

Cone. 4.7750

O.OeO

6.6 6.8
RT (min)

PFOA

Cone. 0.9251

R#1 413.00> 169.10 27.48 (28.52)
Q 413.00>369.00 (-)	4.52e5

fA=1001914

4.0e5^R1 2748 H"feT=6.823

O.OeO -

6.6 6.8 7.0 7.2
RT (min)

13C-PFOS

Cone. 4.9952

3.61 e5 Q 502.80>80.05 (-)

3.0e5 ^

2.0e5 ^

^.0eS1_

O.OeO

3.61 e5

fA=798410
RT=7.120

7.2 7.4
RT (min)

7.2 7.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

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Printed 10/25/2023 16:01:55

ICV1-230504 (continued)

PFNA

Cone. 0.9770

R#1 463.00>219.00 22.64 (21.80)
Q 463.00>418.90 (-)	3.46e5

3.0e5
2.0e5
1.0e5
O.OeO

fA=765350
iR1 22.64 (~fUT=7.144

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)
6.0e41

4.0e4 :
2.0e4 ^
O.OeO -

A= 140450
RT=7.484

7.4

ISTD 572.80>419.05 (-)
4.0e5

8.0
RT (min)

13C-PFUnDA

Cone. 5.0462

Q 564.80>519.95 (-)

O.OeO

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 5.1887

1,44e6 Q 467.80>423.00 (-)

fA=3203159
RT=7.144

7.2 7.4

RT (min)

O.OeO -

7.0

7.2

13C-8 2-FTS

Cone. 4.8518

Q 528.80>509.00 (-)
6.0e4 -

4.0e4 ^

2.0e4 ^

O.OeO -

A= 140450
RT=7.484

_Y

3.0e5
2.0e5
1.0e5
O.OeO

fA=740504

R1 17-39 (-/U=7.488

7.6 7.8
RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

7.6 7.8
RT (min)

7.4

d3-N-MeFOSAA

Cone. 5.2147

4.19e5 Q 572.80>419.05 (-)
4.0e5

O.OeO -

6.0e4 :
4.0e4 :
2.0e4 :
O.OeO :

f A=221669

:R1 38.41 (-{)rt=7.672

-AJ!

7.6

7.8 8.0
RT (min)

PFUnDA

Cone. 0.9757
R#1 563.00>219.00 14.57 (14.10)

1.26e6 Q563.00>518.90 (-)	2.60e5 ISTD 588.80>419.00 (-)

7.25 7.50 7.75 8.00

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

4.92e5

O.OeO

7.8 8.0

RT (min)

PFOSA	13C-FOSAJS

Cone. 0.9444	Cone. 5.0000
R#1 498.20>64.10 0.12 (0.10)

Q 498.20>78.00 (-)	9.79e4	ISTD 506.00>78.05 (-)

f A=1207083
RT=7.852

RT (min)

RT (min)

13C-FOSA

Cone. 5.3502

[A=218817

(" l RT=7.903

VT

' | i i i i | Ai 'iii i i i i | i i i i

7.6 7.8 8.0 8.2

RT (min)

4.0e5 -

'A=951555
RT=7.903

Q 506.00>78.05 (-)	4.15e5

4.0e5 H

PFNS

Cone. 0.9225

R#1 549.00 >99.00 67.94 (66.39)
Q 549.00>79.95 (-)	8.58e4

7.4
RT (min)

PFDA

Cone. 0.9625

R#1 512.90>219.00 17.39 (17.77)
Q 512.90>469.00 (-)	3.12e5

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

A=3486274
RT=7.488

7.6 7.8
RT (min)

NMeFOSAA

Cone. 0.9114

R#1 570.20>512.00 38.41 (35.13)
Q 570.20>419.00 (-)	7.28e4

O.OeO -



fA=746349

- R1 16.82 (-

pT=8.177

: /



8.0 8.2
RT (min)

8-2-FTS

Cone. 1.0370

R#1 527.20>487.00 7.38 (7.71)
Q 527.10>506.90 (-)	1.52e4

: R1 7.38 (-- =7.483

RT (min)

7.6 7.8
RT (min)

13C-PFDA

Cone. 5.3136

1.47e6 Q 514.80>469.95 (-)

O.OeO -

7.6 7.8
RT (min)

PFDS

Cone. 0.9198

R#1 599.00>99.00 56.87 (55.44)
Q 599.00>80.10 (-)	5.77e4

f A= 139959

- R1 5687 RT=7.797

O.OeO i ! , ,

7.6 7.8 8.0

RT (min)

d5-N-EtFOSAA

Cone. 5.1821

Q 588.80>419.00 (-)	4.92e5

4.0e5 -

7.6 7.8
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

O.OeO

7.8 8.0

RT (min)

NEtFOSAA

Cone. 0.8968

R#1 584.20>526.10 56.62 (56.68)
Q 584.20>418.95 (-)	7.90e4

f A=213997
7.5e4- R-] 56.62 (—|)rj=7.859

5.0e4 -
2.5e4 -

O.OeO -



7.8 8.0

RT (min)

PFDoA

Cone. 0.9925

R#1 613.05> 169.00 16.82 (16.48)
Q 613.05>569.00 (-)	3.06e5

7.50 7.75 8.00 8.25

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

1.20e6

B.2 8.4

RT (min)

B.O 8.2 8.4

RT (min)

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ICV1 -230504 (continued)

13C-PFDoA

Cone 5.1440

Q 614.80>569.95 (-)

10-2-FtS

Cone. 0.9994

R#1 626.50>81.05 67.38 (72.12)
1.20e6 Q 626.50>607.05 (-)	1.30e4

f A=2833437
RT=8.176

NEtFOSE

Cone. 0.9441

Q 629.50>59.10 (-)
1.0e5 -

5.0e4 -

rA=254318
RT=8.879

O.OeO -

FH

Q 515.10> 169.00 (-)

3.0e5 ~

2.0e5 ~

^.0eSz

f A=930872
RT=8.657

O.OeO -

8.6

- R1 11.75 (-

A=676090

O.OeO -

8.6

fA=31806
HR1 67.38 (-Mt=8.189



8.4

RT (min)

d9-EtFOSE IS

Cone. 5.0000

1.10e5 ISTD 638.90>59.10 (-)
1.0e5 -

8.6 8.8 9.0 9.2

RT (min)

d3-NMeFOSA

Cone. 5.2226

d7-N-MeFOSE IS

Cone. 5.0000

3.88e5 ISTD 623.00> 59.00 (-)

1.5e5 -
1.0e5-j
5.0e4 :
O.OeO :

RT (min)

PFTeDA

Cone. 1.0750

R#1 713.00>169.30 11.75 (12.52)
Q 713.00>668.90 (-)	2.89e5

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

A=1268543
RT=8.783

9.0
RT (min)

L-PFDoS

Cone. 0.8670

R#1 698.80 >98.80 66.77 (62.67)
Q 698.80>80.10 (-)	2.48e4

Jf A=57118

_R1 66.77 (-4 RT=8.442

RT (min)

d5-NEtFOSA IS

Cone. 5.0000

d5-NEtFOSA

Cone. 5.2730

ISTD 531.10> 169.10 (-)	4.64e5 Q 531.10> 169.10 (-)

TA= 1048015

I RT=8.906	inot;-

NMeFOSE

Cone. 0.9893

4.64e5 Q 616.10>58.90 (-)

3.2 8.4

RT (min)

A=86321
RT=8.636

3.8 9.0 9.2
RT (min)

d9-EtFOSE

Cone. 5.1527

Q 638.90>59.10 (-)
1.0e5 -

RT (min)

RT (min)

d7-N-MeFOSE

Cone. 5.2832

1.89e5 Q 623.00> 59.00 (-)

^.SeSz_

^.0eSz_

5.0e4 ~
== O.OeO -I. . .

RT (min)

RT (min)

13C-PFTeDA

Cone. 4.7084

5.14e5 Q 714.80>669.80 (-)

A=1268543
RT=8.783

O.OeO

O.OeO -

9.0 9.2
RT (min)

NMeFOSA

Cone. 0.9761

R#1 512.10>219.20 70.06 (75.56)
Q 512.10> 169.20 (-)	3.90e4

fA=93373

- R1 70.06 (- |-^T=8.663

O.OeO -

8.4 8.6 8.8 9.0
RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

3.88e5

A=930872
RT=8.657

8.4 8.6 8.8 9.0

RT (min)

NEtFOSA

Cone. 0.9695

R#1 526.50>219.20 62.63 (61.76)
Q 526.50>169.10 (-)	6.27e4

f A= 146790

6.0e4- R-| 62.63 (- | RT=8.916

RT (min)

PFTrDA

Cone. 1.0363

R#1 663.10> 169.10 21.85 (21.32)
Q 663.10>618.90 (-)	3.02e5

;R1 21.85 (-

8.6 8.8 9.0 9.2

RT (min)

11CI-PF30UdS

Cone. 0.9328

RT (min)

9CI-PF30NS

Cone. 0.8831

Q 631.00>451.10 (-)
1.0e5 —|

1.01e5 Q 531.00>351.10 (-)

A=415151
RT=7.307

3.6 8.8 9.0

RT (min)

PFHxDA

Cone. 0.9224

Q 812.90>769.00 (-)	1.21e5

T A=261082
I RT=9.293

9.2 9.4 9.6
RT (min)

RT (min)

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ICV1 -230504 (continued)

13C2-PFHxDA

Cone. 5.1578

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 0.9534

3.25e6 ISTD 569.80>524.90 (-)

PFecHS

Cone. 0.7946
R#1 461.00>99.10 41.17 (38.58)

9.85e5 Q 461.00>381.00 (-)	2.89e5 Q 298.00>78.00 (-)

PFHxSA

Cone. 0.9866

2.24e5 Q 397.90>78.00 (-)

9.4 9.6
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

fA=2347341
I RT=7.8

- R1 41.17 (•

RT (min)

7.0

RT (min)

| A= 520621
RT=6.307



1.5e5-
^.0eSz
5.0e4z_
O.OeO -

6.6
RT (min)

7.4
RT (min)

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^AILS)

Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:00

CCV2-230504

Sample ID: CCV2-230504

Date Acquired: 5/4/2023 9:46:54 PM

Acquired by: System Administrator

Data File: 230504082

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone.

Cone. Unit

13C-PFBA IS

Auto

4.377

1238450

1238450

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.377

1238450

2102685

13C7-PFUnDA IS

5.0000

5.5663

nq/mL

PFBA

Auto

4.378

1497765

1238450

13C-PFBA IS

5.0000

5.0990

nq/mL

13C-PFPeA IS

Auto

5.548

2288305

2288305

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.548

2288305

2102685

13C7-PFUnDA IS

5.0000

5.8058

nq/mL

PFPeA

Auto

5.548

2199488

2288305

13C-PFPeA IS

5.0000

4.9177

nq/mL

13C-PFBS IS

Auto

5.670

846768

846768

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.670

846768

2102685

13C7-PFUnDA IS

4.6500

5.3892

nq/mL

PFBS

Auto

5.670

655419

846768

13C-PFBS IS

4.4200

4.3578

nc

13C HFPO DA IS

Auto

6.261

617763

617763

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.261

617763

2102685

13C7-PFUnDA IS

5.0000

5.8075

nc

HFPO DA

Auto

6.261

515342

617763

13C HFPO DA IS

5.0000

4.8832

nq/mL

13C-4 2-FTS IS

Auto

6.068

335736

335736

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

6.068

335736

2102685

13C7-PFUnDA IS

4.6700

5.3683

nq/mL

4-2-FtS

Auto

6.067

411132

335736

13C-4 2-FTS IS

4.6700

4.7840

nq/mL

PFHxA

Auto

6.120

4470060

3070523

13C-PFHxA IS

5.0000

4.9422

nq/mL

13C-PFHxA IS

Auto

6.120

3070523

3070523

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

6.120

3070523

2102685

13C7-PFUnDA IS

5.0000

5.7627

nq/mL

PFPeS

Auto

6.156

650736

883345

180-PFHxS IS

4.6900

4.4702

nq/mL

PFHxS

Auto

6.514

514175

883345

180-PFHxS IS

4.5500

4.0938

nq/mL

13C-PFHpA IS

Auto

6.512

3064844

3064844

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.512

3064844

2102685

13C7-PFUnDA IS

5.0000

5.7295

nq/mL

180-PFHxS IS

Auto

6.514

883345

883345

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.514

883345

2102685

13C7-PFUnDA IS

4.7250

5.5851

nq/mL

PFHpA

Auto

6.512

4867931

3064844

13C-PFHpA IS

5.0000

5.0757

nq/mL

13C2-6 2-FTS IS

Auto

6.805

330587

330587

	

4.7500

4.7500

nq/mL

13C2-6 2-FTS

Auto

6.805

330587

2102685

13C7-PFUnDA IS

4.7500

5.0832

nq/mL

PFHpS

Auto

6.812

645277

883345

180-PFHxS IS

4.7600

4.7074

nq/mL

6-2-FTS

Auto

6.805

352169

330587

13C2-6 2-FTS IS

4.7400

4.9932

nq/mL

PFOA

Auto

6.823

5066725

3083868

13C-PFOA IS

5.0000

5.3155

nq/mL

13C-PFOA IS

Auto

6.823

3083868

3083868

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.823

3083868

2102685

13C7-PFUnDA IS

5.0000

5.2252

nq/mL

PFOS

Auto

7.119

456981

762953

13C-PFOS IS

4.6400

4.6703

nq/mL

13C-PFOS IS

Auto

7.120

762953

762953

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

7.120

762953

2102685

13C7-PFUnDA IS

4.7750

5.3288

nq/mL

PFNA

Auto

7.143

3764257

2806915

13C-PFNA IS

5.0000

5.4837

nq/mL

13C-PFNA IS

Auto

7.143

2806915

2806915

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.143

2806915

2102685

13C7-PFUnDA IS

5.0000

5.0759

nq/mL

PFNS

Auto

7.453

1088307

762953

13C-PFOS IS

4.8000

5.1269

nq/mL

8-2-FTS

Auto

7.482

192573

125956

13C-8 2-FTS IS

4.7900

5.8587

nq/mL

13C-8 2-FTS IS

Auto

7.482

125956

125956

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.482

125956

2102685

13C7-PFUnDA IS

4.7900

4.8574

nq/mL

PFDA

Auto

7.488

3557171

3241643

13C-PFDA IS

5.0000

4.9726

nq/mL

13C-PFDA IS

Auto

7.487

3241643

3241643

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.487

3241643

2102685

13C7-PFUnDA IS

5.0000

5.5157

nq/mL

d3-N-MeFOSAA IS

Auto

7.667

1069581

1069581

	

5.0000

5.0000

nq/mL

d3-N-MeFOSAA

Auto

7.667

1069581

2102685

13C7-PFUnDA IS

5.0000

5.7932

nq/mL

NMeFOSAA

Auto

7.671

1206746

1069581

d3-N-MeFOSAA IS

5.0000

4.9857

nq/mL

PFDS

Auto

7.796

748247

762953

13C-PFOS IS

4.8200

5.1461

nq/mL

13C-PFUnDA IS

Auto

7.838

2817510

2817510

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.838

2817510

2102685

13C7-PFUnDA IS

5.0000

5.2219

nq/mL

PFUnDA

Auto

7.838

3133872

2817510

13C-PFUnDA IS

5.0000

5.3830

nq/mL

d5-N-EtFOSAA IS

Auto

7.851

1203232

1203232

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.851

1203232

2102685

13C7-PFUnDA IS

5.0000

5.7666

nq/mL

NEtFOSAA

Auto

7.858

1200604

1203232

dS-N-EtFOSAA IS

5.0000

5.0476

nq/mL

PFOSA

Auto

7.902

1148072

912902

13C-FOSA IS

5.0000

5.1648

nq/mL

13C-FOSA IS

Auto

7.902

912902

912902

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.902

912902

2102685

13C7-PFUnDA IS

5.0000

5.7301

nq/mL

PFDoA

Auto

8.174

3739705

2430558

13C-PFDoA IS

5.0000

5.7974

nq/mL

13C-PFDoA IS

Auto

8.174

2430558

2430558

	

5.0000

5.0000

nq/mL

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CCV2-230504 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.174

2430558

2102685

13C7-PFUnDA IS

5.0000

4.9260

nq/mL

10-2-FtS

Auto

8.185

158153

125956

13C-8 2-FTS IS

4.8200

5.5413

ng/mL

d5-NEtFOSA IS

Auto

8.902

1039464

1039464

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.902

1039464

2102685

13C7-PFUnDA IS

5.0000

5.8385

ng/mL

NMeFOSE

Auto

8.634

437821

467211

d7-N-MeFOSE IS

5.0000

4.9422

nq/mL

NEtFOSE

Auto

8.875

1408464

200088

d9-EtFOSE IS

5.0000

6.5191

ng/mL

d9-EtFOSE IS

Auto

8.857

200088

200088

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.857

200088

2102685

13C7-PFUnDA IS

5.0000

4.6136

ng/mL

NMeFOSA

Auto

8.662

484979

929100

d3-NMeFOSA IS

5.0000

5.0795

nq/mL

dB-NMeFOSA IS

Auto

8.657

929100

929100

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.657

929100

2102685

13C7-PFUnDA IS

5.0000

5.8192

nq/mL

d7-N-MeFOSE IS

Auto

8.620

467211

467211

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.620

467211

2102685

13C7-PFUnDA IS

5.0000

5.9883

nq/mL

NEtFOSA

Auto

8.911

766685

1039464

d5-NEtFOSA IS

5.0000

5.1052

ng/mL

PFTrDA

Auto

8.491

3517018

1206569

13C-PFTeDA IS

5.0000

5.7084

nq/mL

PFTeDA

Auto

8.779

3433075

1206569

13C-PFTeDA IS

5.0000

5.7390

ng/mL

13C-PFTeDA IS

Auto

8.779

1206569

1206569

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.779

1206569

2102685

13C7-PFUnDA IS

5.0000

4.9994

ng/mL

11CI-PFBOUdS

Auto

7.987

1143507

762953

13C-PFOS IS

4.7100

4.7039

nq/mL

9CI-PF30NS

Auto

7.305

2200571

762953

13C-PFOS IS

4.6600

4.8987

ng/mL

L-PFDoS

Auto

8.440

292378

762953

13C-PFOS IS

4.8400

4.6445

nq/mL

NaDONA

Auto

6.555

3541300

2806915

13C-PFNA IS

4.7100

5.3731

ng/mL

PFHxDA

Auto

9.283

1386871

6046923

13C2-PFHxDA IS

5.0000

5.1617

nq/mL

PFODA

Auto

9.869

1070975

6046923

13C2-PFHxDA IS

5.0000

4.7443

ng/mL

1BC2-PFHxDA IS

Auto

9.282

6046923

6046923

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.282

6046923

2102685

13C7-PFUnDA IS

5.0000

5.7211

ng/mL

13C7-PFUnDA IS

Auto

7.837

2102685

2102685

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.772

3833058

762953

13C-PFOS IS

4.6100

4.7469

ng/mL

PFBSA

Auto

6.307

2726344

912902

13C-FOSA IS

5.0000

5.2038

nq/mL

PFHxSA

Auto

7.115

2149513

2806915

13C-PFNA IS

5.0000

5.7522

ng/mL

CHARGE

ND(W/B)

	

	

2102685

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 5.5663
2.93e5 Q 217.20>172.30 (-)

PFBA

Cone. 5.0990
2.93e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
3.58e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 5.8058
8.80e5 Q 267.90>223.00 (-)

RT (min)

RT (min)

PFPeA

Cone. 4.9177

Q263.05>219.10 (-)

13C-PFBS IS

Cone. 4.6500

13C-PFBS

Cone. 5.3892

5.8

RT (min)	RT (min)

PFBS

Cone. 4.3578
R#1 298.80>99.00 65.14 (71.09)

3.36e5 Q 299.00>80.00 (-)	2.61 e5 ISTD 332.10>287.10 (-)

13C HFPO DA IS

Cone. 5.0000

P[A=655419

-R1 65.14 (I Rt= 5.670

5.

RT (min)

6.0
RT (min)

J A=617763
RT=6.261

6.4 6.6
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

200

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:00

CCV2-230504 (continued)

13C HFPO DA

Cone. 5.8075

Q 332.10>287.10 (-)

A=617763
RT=6.261

O.OeO -

6.2



f A=4470060

_ R1 2.74 (-

RT=6.120

I

I

13C-PFHpA_IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

fA=3064844
RT=6.512

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)
1.5e5 -

1.0e5 -
5.0e4 :
O.OeO :

A=330587
RT=6.805

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)

A=3083868
RT=6.823

HFPO DA

Cone. 4.8832

R#1 329.00>285.10 80.18 (79.97)
Q 329.00>169.00 (-)	2.38e5



If A= 515342

-R1 80.18 (¦

"Rt=6.261

I

I

6.4 6.6
RT (min)

PFHxA

Cone. 4.9422

R#1 313.00> 119.10 2.74 (2.85)
Q 313.00>269.00 (-)	2.02e6

2.0e6

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

JA=3070523
RT=6.120

6.2 6.4

RT (min)

13C-PFHpA

Cone. 5.7295

1.41e6 Q 366.90>322.10 (-)

rA=3064844
RT=6.512

6.6 6.8
RT (min)

13C2-6 2-FTS

Cone. 5.0832

Q 428.90>409.00 (-)

TA=3

15651	RT='

1.0e5^

5.0e4 ^

O.OeO 1 . . . . g

330587
RT=6.805

7.0
RT (min)

13C-PFOA

Cone. 5.2252

1.40e6 Q 416.80>372.05 (-)

A=3083868
RT=6.823

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00 >81.00 26.61 (26.74)

ISTD 329.00>309.15 (-)	1.54e5

1.5e5 -

R1 26.61 (•

A=335736
RT=6.068

L

6.4 6.6
RT (min)

13C-PFHxA

Cone. 5.7627

6.2 6.4

RT (min)

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)
4.0e51

6.6 6.8
RT (min)

O.OeO -

7.0
RT (min)

6.6

6.8

13C-4 2-FTS

Cone. 5.3683

R#1 329.00>81.00 26.61 (26.74)
Q 329.00>309.15 (-)	1.54e5

1.5e5-

(A=335736
R1 26.61 (§Rt=6.068

6.2 6.4
RT (min)

Q 314.90>270.10 (-)	1.39e6

*A=3070523
RT=6.120

1.0e6 -

6.2 6.4

RT (min)

180-PFHxS

Cone. 5.5851

Q 402.70>84.05 (-)
4.0e51

O.OeO

6.6 6.8
RT (min)

PFHpS

Cone. 4.7074

R#1 449.00>99.20 64.44 (66.82)
Q 449.00>80.15 (-)	2.96e5

[A=645277
:R1 64.44 (-fl-^r=6.812

7.0
RT (min)

PFOS

Cone. 4.6703

R#1 499.00>99.00 98.56 (93.96)
Q 499.00>80.00 (-)	1.46e5

f A=456981

IR1 98.56 (---|)rt=7.119

105 (-)

RT (min)

RT (min)

6.75 7.00 7.25 7.50

RT (min)

3.0e5 -
2.0e5 :
1.0e5:
O.OeO :

fA=762953
I RT=7.120

4-2-FtS

Cone. 4.7840

R#1 327.00>81.10 16.75 (16.29)
Q 327.00>307.05 (-)	1.84e5

6.0 6.2 6.4
RT (min)

PFPeS

Cone. 4.4702

R#1 349.00>99.00 82.43 (74.42)
Q 349.00>79.95 (-)	2.96e5

rA=650736
1R1 82.43 (i-Rt=6.156

1.5e5-
^.0eSz
5.0e4 ^
O.OeO -

IA=411

Rt=6.C

132
067

6.0

6.2 6.4
RT (min)

PFHxS

Cone. 4.0938

R#1 399.00>99.00 101.64 (95.46)
Q 399.00>80.00 (-)	1.91e5

- R1 101.64 (-

A=514175
~F^T=6.514

O.OeO -

6.25 6.50 6.75 7.00
RT (min)

PFHpA

Cone. 5.0757

R#1 362.90>169.00 17.73 (17.56)
Q 362.90>319.00 (-)	2.24e6

fA=4867931
2.0e6 -|R1 1773 (-™=6.512

O.OeO

6.6 6.8
RT (min)

6-2-FTS

Cone. 4.9932

R#1 427.00>80.90 30.63 (28.57)
Q 427.00>407.00 (-)	1.65e5

[A=352169

1.5e5^R1 30.63 (-|-^r=6.805

1.0e5^

5.0e4 ^

O.OeO

6.6 6.8 7.0

RT (min)

13C-PFOS IS

Cone. 4.7750

O.OeO

6.6 6.8
RT (min)

PFOA

Cone. 5.3155

R#1 413.00> 169.10 28.35 (28.52)
Q 413.00>369.00 (-)	2.28e6

f A= 5066725
2.0e6^R1 2835 H"kT=6.823

O.OeO -

6.6 6.8 7.0 7.2
RT (min)

13C-PFOS

Cone. 5.3288

3.45e5 Q 502.80>80.05 (-)

3.0e5 ^

2.0e5 ^

1.0e5^

O.OeO

3.45e5

f A=762953
RT=7.120

7.2 7.4
RT (min)

7.2 7.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

308

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:00

CCV2-230504 (continued)

PFNA	13C-PFNA IS

Cone. 5.4837	Cone. 5.0000
R#1 463.00>219.00 22.32 (21.80)

Q 463.00>418.90 (-)	1.70e6	ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 5.0759

1.26e6 Q 467.80>423.00 (-)

O.OeO

7.0 7.2 7.4

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

O.OeO -

PFNS

Cone. 5.1269

R#1 549.00>99.00 63.25 (66.39)
Q 549.00>79.95 (-)	4.65e5

f A=1088307

" R1 63.25 (-|-p^r=7.453

7.4
RT (min)

7.0

7.2

13C-8 2-FTS

Cone. 4.8574

ISTD 528.80>509.00 (-)

5.15e4 Q 528.80> 509.00 (-)

A= 125956
RT=7.482

O.OeO -

7.4
RT (min)

PFDA

Cone. 4.9726

R#1 512.90>219.00 17.81 (17.77)
Q 512.90>469.00 (-)	1.49e6

~ A=3557171
IR1 17.81 (--^"=7.488

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

Ssz

7.4

7.6 7.8
RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

O.OeO -

d3-N-MeFOSAA

Cone. 5.7932

ISTD 572.80>419.05 (-)
4.0e5

4.23e5 Q 572.80>419.05 (-)
4.0e5

O.OeO -

A= 1069581
RT=7.667

7.6 7.8
RT (min)

NMeFOSAA

Cone. 4.9857

R#1 570.20>512.00 39.34(35.13)
Q 570.20>419.00 (-)	3.93e5

f A=1206746

-R1 39.34 (-4)rt=7.671

7.4

O.OeO -



7.6

13C-PFUnDA

Cone. 5.2219

Q 564.80>519.95 (-)

O.OeO

7.8 8.0
RT (min)
PFUnDA

Cone. 5.3830

R#1 563.00>219.00 14.47 (14.10)
1.19e6 Q 563.00> 518.90 (-)	1,32e6

f A=3133872

HR1 14-47 (- -^"=7.8

O.OeO

7.25 7.50 7.75 8.00

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

7.8 8.0

RT (min)

PFOSA	13C-FOSAJS

Cone. 5.1648	Cone. 5.0000
R#1 498.20>64.10 0.13 (0.10)

Q 498.20>78.00 (-)	5.05e5 ISTD 506.00>78.05 (-)

ISTD 588.80>419.00 (-)	4.96e5 Q 588.80>419.00 (-)

fA= 1203232
I RT=7.851

fA= 1203232
RT=7.851

RT (min)

RT (min)

13C-FOSA

Cone. 5.7301

fA= 1148072

: R1 °-13 (—IrT=7.902

3.98e5 Q 506.00>78.05 (-)	3.98e5

'A=912902	TA=912902

RT=7.902	-	RT=7.902

8.0 8.2
RT (min)

8-2-FTS

Cone. 5.8587

R#1 527.20>487.00 9.65 (7.71)
Q 527.10>506.90 (-)	7.96e4

5.0e4 -
2.5e4 7
O.OeO :



'A= 192573

: R1 9.65 (--:

"kr=7.482



VT

RT (min)

7.6 7.8
RT (min)

13C-PFDA

Cone. 5.5157

1.36e6 Q 514.80>469.95 (-)

7.6 7.8
RT (min)

PFDS

Cone. 5.1461

R#1 599.00>99.00 58.51 (55.44)
Q 599.00>80.10 (-)	3.13e5

7.6 7.8
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

O.OeO -

=^=F

7.8 8.0

RT (min)

d5-N-EtFOSAA

Cone. 5.7666

4.96e5

7.8 8.0

RT (min)

NEtFOSAA

Cone. 5.0476

R#1 584.20>526.10 58.42 (56.68)
Q 584.20>418.95 (-)	4.13e5

4.0e5 -

fA= 1200604

O.OeO

7.8 8.0

RT (min)

PFDoA

Cone. 5.7974

R#1 613.05 > 169.00 16.31 (16.48)
Q 613.05>569.00 (-)	1.59e6

O.OeO -

R1 58.42 (- RT=7 g



7.50 7.75 8.00 8.25

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)
1.0e6H

1.04e6

.2 8.4

RT (min)

B.2 8.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

208

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:00

CCV2-230504 (continued)

13C-PFDoA

Cone. 4.9260

Q614.80>569.95 (-)
10e6j	!rt\2

10-2-FtS

Cone. 5.5413

R#1 626.50>81.05 60.57 (72.12)
Q 626.50>607.05 (-)	6.71e4

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 5.8385

4.51e5 Q 531.10> 169.10 (-)

2430558
RT=8.174

L

3.2 8.4

RT (min)

2 8.4

RT (min)

NEtFOSE

Cone. 6.5191

Q 629.50>59.10 (-)
6.0e5 -

4.0e5 ^

2.0e5 ^

O.OeO 1	

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 4.6136

6.11e5 ISTD 638.90>59.10 (-)

8.76e4 Q 638.90> 59.10 (-)

rA=1408464
RT=8.875

8.6 8.8 9.0 9.2

RT (min)

d3-NMeFOSA

Cone. 5.8192

RT (min)

RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 5.9883

Q 515.10> 169.00 (-)

3.95e5 ISTD 623.00> 59.00 (-)

1.93e5 Q 623.00> 59.00 (-)

RT (min)

PFTeDA

Cone. 5.7390

R#1 713.00>169.30 11.85 (12.52)
Q 713.00>668.90 (-)	1.45e6

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 4.9994

4.99e5 Q 714.80>669.80 (-)

O.OeO



f A=3433075

- R1 11.85 (-¦

kT=8.779

^ I

I

i

8.6

i.8 9.0

RT (min)

L-PFDoS

Cone. 4.6445

R#1 698.80 >98.80 69.90 (62.67)
Q 698.80>80.10 (-)	1.29e5

NaDONA

Cone. 5.3731

Q 377.10>251.20 (-)

- R1 69.90 (-

A=292378
RT=8.440

1.5e6 -
1.0e6:
5.0e5 :
O.OeO :

~ A=3541300
RT=6.555

PFHxDA

Cone. 5.1617

Q 812.90>769.00 (-)
6.0e5 -	1

4.0e5 ^

2.0e5 ^

O.OeO 1 , , ,

A= 1386871
RT=9.283



RT (min)

6.8

RT (min)

O.OeO -

NMeFOSE

Cone. 4.9422

4.51e5 Q 616.10>58.90 (-)

^.SeSz_

1.0e5~_

S.0e4z_

— O.OeO 1	

9.0 9.2
RT (min)

A=200088
RT=8.857

8.8 9.0 9.2
RT (min)

NMeFOSA

Cone. 5.0795
R#1 512.10>219.20 76.89 (75.56)

Q 512.10 > 169.20 (-)	2.02e5 I STD 515.10 > 169.00 (-)

8.4 8.6 8.8 9.0
RT (min)

d3-NMeFOSA IS

Cone. 5.0000

3.95e5

2.0e5 -

A=484979

R1 76.89 (- kT=8.662

rA=929100
RT=8.657

O.OeO

8.4 8.6 8.8 9.0

RT (min)

NEtFOSA

Cone. 5.1052

R#1 526.50>219.20 61.23 (61.76)
Q 526.50> 169.10 (-)	3.36e5

3 0e5^1 61.23 (-
2.0e5 i
^.0eS1_

O.OeO 4—

Y A=766685
"kT=8.911

8.6 8.8

RT (min)

PFTrDA

Cone. 5.7084

R#1 663.10> 169.10 21.66 (21.32)
Q 663.10>618.90 (-)	1.56e6

A=3517018

IR1 21.66 (- 8.491

8.6 8.8 9.0 9.2

RT (min)

11CI-PF30UdS

Cone. 4.7039

RT (min)

9CI-PF30NS

Cone. 4.8987

4.99e5 Q 631.00>451.10 (-)

4.88e5 Q 531.00>351.10 (-)

fA= 1143507
RT=7.987

3.0 8.2

RT (min)

~ A=2200571
RT=7.305

Vj

_r r
7.4 7.6
RT (min)

PFODA

Cone. 4.7443

13C2-PFHxDA IS

Cone. 5.0000

6.38e5 Q 912.80>869.00 (-)

9.4 9.6
RT (min)

9.8 10.0

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

309

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A

Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:00

CCV2-230504 (continued)

13C2-PFHxDA

Cone 5.7211

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 5.2038

Q 815.00>770.00 (-)	3.24e6 ISTD 569.80> 524.90 (-)

ftA=6046923

7.5e5 :

5.0e5 :

2.5e5 :

O.OeO :

PFecHS

Cone. 4.7469
R#1 461.00>99.10 38.88 (38.58)

8.81 e5 Q 461.00>381.00 (-)	1.68e6 Q 298.00>78.00 (-)

3.0e6 ^



RT=9.282

2.0e6 ^





1.0e6 -





OOpO-





9.2 9.4 9.6
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	1.00e0

5.0e0 -

0.2
RT (min)

|A=3833058
1.5e6 - R1 3888 ("fr^T=6.772

^=F

1.0e6 -
5.0e5 :
O.OeO :

A*

RT (min)

7.0

RT (min)

PFHxSA

Cone. 5.7522

1.19e6 Q 397.90>78.00 (-)

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

6.6
RT (min)

7.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

21®

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('alsS

Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:04

CCV3-230504

Sample ID: CCV3-230504

Date Acquired: 5/5/2023 12:45:45 AM

Acquired by: System Administrator

Data File: 230504095

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone.

Cone. Unit

13C-PFBA IS

Auto

4.370

1316225

1316225

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.370

1316225

2426741

13C7-PFUnDA IS

5.0000

5.1259

nq/mL

PFBA

Auto

4.371

1501000

1316225

13C-PFBA IS

5.0000

4.8094

nq/mL

13C-PFPeA IS

Auto

5.535

2267046

2267046

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.535

2267046

2426741

13C7-PFUnDA IS

5.0000

4.9838

nq/mL

PFPeA

Auto

5.536

2258772

2267046

13C-PFPeA IS

5.0000

5.0977

nq/mL

13C-PFBS IS

Auto

5.658

842138

842138

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.658

842138

2426741

13C7-PFUnDA IS

4.6500

4.6440

nq/mL

PFBS

Auto

5.658

670704

842138

13C-PFBS IS

4.4200

4.4839

nc

13C HFPO DA IS

Auto

6.248

601707

601707

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.248

601707

2426741

13C7-PFUnDA IS

5.0000

4.9013

nc

HFPO DA

Auto

6.248

547332

601707

13C HFPO DA IS

5.0000

5.3247

nq/mL

13C-4 2-FTS IS

Auto

6.054

366665

366665

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

6.054

366665

2426741

13C7-PFUnDA IS

4.6700

5.0799

nq/mL

4-2-FtS

Auto

6.054

428984

366665

13C-4 2-FTS IS

4.6700

4.5707

nq/mL

PFHxA

Auto

6.107

4586063

3009893

13C-PFHxA IS

5.0000

5.1726

nq/mL

13C-PFHxA IS

Auto

6.107

3009893

3009893

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

6.107

3009893

2426741

13C7-PFUnDA IS

5.0000

4.8946

nq/mL

PFPeS

Auto

6.142

687300

838228

180-PFHxS IS

4.6900

4.9755

nq/mL

PFHxS

Auto

6.502

556036

838228

180-PFHxS IS

4.5500

4.6654

nq/mL

13C-PFHpA IS

Auto

6.499

2934137

2934137

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.499

2934137

2426741

13C7-PFUnDA IS

5.0000

4.7527

nq/mL

180-PFHxS IS

Auto

6.502

838228

838228

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.502

838228

2426741

13C7-PFUnDA IS

4.7250

4.5921

nq/mL

PFHpA

Auto

6.499

4973384

2934137

13C-PFHpA IS

5.0000

5.4166

nq/mL

13C2-6 2-FTS IS

Auto

6.792

360108

360108

	

4.7500

4.7500

nq/mL

13C2-6 2-FTS

Auto

6.792

360108

2426741

13C7-PFUnDA IS

4.7500

4.7977

nq/mL

PFHpS

Auto

6.799

676920

838228

180-PFHxS IS

4.7600

5.2040

nq/mL

6-2-FTS

Auto

6.792

361535

360108

13C2-6 2-FTS IS

4.7400

4.7058

nq/mL

PFOA

Auto

6.810

5205627

3583853

13C-PFOA IS

5.0000

4.6994

nq/mL

13C-PFOA IS

Auto

6.810

3583853

3583853

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.810

3583853

2426741

13C7-PFUnDA IS

5.0000

5.2615

nq/mL

PFOS

Auto

7.105

477531

825172

13C-PFOS IS

4.6400

4.5123

nq/mL

13C-PFOS IS

Auto

7.106

825172

825172

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

7.106

825172

2426741

13C7-PFUnDA IS

4.7750

4.9937

nq/mL

PFNA

Auto

7.129

3785410

3327473

13C-PFNA IS

5.0000

4.6518

nq/mL

13C-PFNA IS

Auto

7.129

3327473

3327473

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.129

3327473

2426741

13C7-PFUnDA IS

5.0000

5.2137

nq/mL

PFNS

Auto

7.438

1051718

825172

13C-PFOS IS

4.8000

4.5810

nq/mL

8-2-FTS

Auto

7.465

175319

148856

13C-8 2-FTS IS

4.7900

4.5132

nq/mL

13C-8 2-FTS IS

Auto

7.466

148856

148856

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.466

148856

2426741

13C7-PFUnDA IS

4.7900

4.9740

nq/mL

PFDA

Auto

7.471

3769187

3380806

13C-PFDA IS

5.0000

5.0521

nq/mL

13C-PFDA IS

Auto

7.471

3380806

3380806

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.471

3380806

2426741

13C7-PFUnDA IS

5.0000

4.9843

nq/mL

d3-N-MeFOSAA IS

Auto

7.651

1047306

1047306

	

5.0000

5.0000

nq/mL

d3-N-MeFOSAA

Auto

7.651

1047306

2426741

13C7-PFUnDA IS

5.0000

4.9150

nq/mL

NMeFOSAA

Auto

7.655

1139606

1047306

d3-N-MeFOSAA IS

5.0000

4.8085

nq/mL

PFDS

Auto

7.779

772234

825172

13C-PFOS IS

4.8200

4.9106

nq/mL

13C-PFUnDA IS

Auto

7.821

3120957

3120957

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.821

3120957

2426741

13C7-PFUnDA IS

5.0000

5.0119

nq/mL

PFUnDA

Auto

7.821

3022742

3120957

13C-PFUnDA IS

5.0000

4.6873

nq/mL

d5-N-EtFOSAA IS

Auto

7.834

1166791

1166791

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.834

1166791

2426741

13C7-PFUnDA IS

5.0000

4.8452

nq/mL

NEtFOSAA

Auto

7.841

78

1166791

dS-N-EtFOSAA IS

5.0000

4.8874

nq/mL

PFOSA

Auto

7.886

1072926

924064

13C-FOSA IS

5.0000

4.7685

nq/mL

13C-FOSA IS

Auto

7.886

924064

924064

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.886

924064

2426741

13C7-PFUnDA IS

5.0000

5.0257

nq/mL

PFDoA

Auto

8.158

3817654

3055349

13C-PFDoA IS

5.0000

4.7080

nq/mL

13C-PFDoA IS

Auto

8.158

3055349

3055349

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

312

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:04

CCV3-230504 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.158

3055349

2426741

13C7-PFUnDA IS

5.0000

5.3654

nq/mL

10-2-FtS

Auto

8.170

125421

148856

13C-8 2-FTS IS

4.8200

3.7184

ng/mL

d5-NEtFOSA IS

Auto

8.889

1041761

1041761

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.889

1041761

2426741

13C7-PFUnDA IS

5.0000

5.0700

ng/mL

NMeFOSE

Auto

8.619

448017

451195

d7-N-MeFOSE IS

5.0000

5.2368

nq/mL

NEtFOSE

Auto

8.863

1407297

288221

d9-EtFOSE IS

5.0000

4.5219

ng/mL

d9-EtFOSE IS

Auto

8.845

288221

288221

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.845

288221

2426741

13C7-PFUnDA IS

5.0000

5.7583

ng/mL

NMeFOSA

Auto

8.647

457246

913651

d3-NMeFOSA IS

5.0000

4.8700

nq/mL

dB-NMeFOSA IS

Auto

8.642

913651

913651

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.642

913651

2426741

13C7-PFUnDA IS

5.0000

4.9583

nq/mL

d7-N-MeFOSE IS

Auto

8.604

451195

451195

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.604

451195

2426741

13C7-PFUnDA IS

5.0000

5.0108

nq/mL

NEtFOSA

Auto

8.899

722652

1041761

d5-NEtFOSA IS

5.0000

4.8014

ng/mL

PFTrDA

Auto

8.477

3180613

1137073

13C-PFTeDA IS

5.0000

5.4779

nq/mL

PFTeDA

Auto

8.768

3210010

1137073

13C-PFTeDA IS

5.0000

5.6941

ng/mL

13C-PFTeDA IS

Auto

8.768

1137073

1137073

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.768

1137073

2426741

13C7-PFUnDA IS

5.0000

4.0823

ng/mL

11CI-PFBOUdS

Auto

7.970

1285720

825172

13C-PFOS IS

4.7100

4.8902

nq/mL

9CI-PF30NS

Auto

7.290

2150591

825172

13C-PFOS IS

4.6600

4.4265

ng/mL

L-PFDoS

Auto

8.425

341648

825172

13C-PFOS IS

4.8400

5.0179

nq/mL

NaDONA

Auto

6.542

3722117

3327473

13C-PFNA IS

4.7100

4.7639

ng/mL

PFHxDA

Auto

9.276

949866

5804815

13C2-PFHxDA IS

5.0000

3.6675

nq/mL

PFODA

Auto

9.857

885090

5804815

13C2-PFHxDA IS

5.0000

4.0844

ng/mL

13C2-PFHxDA IS

Auto

9.275

5804815

5804815

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.275

5804815

2426741

13C7-PFUnDA IS

5.0000

4.7587

ng/mL

13C7-PFUnDA IS

Auto

7.821

2426741

2426741

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.759

3853845

825172

13C-PFOS IS

4.6100

4.4128

ng/mL

PFBSA

Auto

6.294

2614918

924064

13C-FOSA IS

5.0000

4.9308

nq/mL

PFHxSA

Auto

7.101

2189736

3327473

13C-PFNA IS

5.0000

4.9431

ng/mL

CHARGE

ND(W/B)

	

	

2426741

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

3.0e5 -
2.0e5 ^

1.0e5 -

13C-PFBA

Cone. 5.1259
3.15e5 Q 217.20>172.30 (-)

f A=1316225
RT=4.370

O.OeO -

PFPeA

Cone. 5.0977

Q263.05>219.10 (-)

7.5e5 -
5.0e5 :
2.5e5 :
O.OeO :

f A=2258772
RT= 5.536

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

RT (min)

13C-PFBS IS

Cone. 4.6500

PFBA

Cone. 4.8094
3.15e5 Q 213.20> 169.10 (-)

A=1316225
RT=4.370

8.87e5 ISTD 301.80>80.00 (-)

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

f A=842138
RT= 5.658

5.8

RT (min)

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

A= 1501000 '
RT=4.371

RT (min)

13C-PFBS

Cone. 4.6440

3.39e5 Q 301.80>80.00 (-)
3.0e5 ^

2.0e5 ^

1.0e5 ^

: O.OeO 4=

13C-PFPeA IS

Cone. 5.0000
3.65e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.9838
8.95e5 Q 267.90>223.00 (-)

A=2267046
RT= 5.535

13C HFPO DA IS

Cone. 5.0000

5.8

RT (min)	RT (min)

PFBS

Cone. 4.4839

R#1 298.80>99.00 71.48 (71.09)

3.39e5 Q 299.00>80.00 (-)	2.70e5 ISTD 332.10>287.10 (-)

f A=842138	TA=670704

RT= 5.658	- R1 71 -48 {\\r1^ 5.658

6.0
RT (min)

6.0
RT (min)



fA=601707

:

RT=6.248

j





6.4 6.6
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

212

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:04

CCV3-230504 (continued)

13C HFPO DA

Cone. 4.9013

Q 332.10>287.10 (-)

A=601707
RT=6.248

O.OeO -

6.2

O.OeO



rA=4586063

- R1 2.74 (-

uRT=6.107

: I



13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

fA=360108
RT=6.792

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
1.5e6 -j
1.0e6 ^

5.0e51

Y,A=3583853
IRT=6.810

O.OeO -



HFPO DA

Cone. 5.3247

R#1 329.00>285.10 84.19 (79.97)
Q 329.00>169.00 (-)	2.58e5

TA= 547332
ZR1 84.19 |U=6.248



6.4 6.6
RT (min)

PFHxA

Cone. 5.1726

R#1 313.00> 119.10 2.74 (2.85)
Q 313.00>269.00 (-)	2.12e6

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

fA=3009893
RT=6.107

6.0 6.2 6.4

RT (min)

13C-PFHpA IS

Cone. 5.0000

ISTD 366.90>322.10 (-)	1,36e6

f A=2934137
RT=6.499

13C-PFHpA

Cone. 4.7527

Q 366.90>322.10 (-)

TA=2934137
RT=6.499

6.6 6.8
RT (min)

13C2-6 2-FTS

Cone. 4.7977

1.70e5 Q 428.90>409.00 (-)

1.5e5 ^

1.0e5 ^

5.0e4 ^

O.OeO "L—r

fA=360108
RT=6.792

7.0
RT (min)

13C-PFOA

Cone. 5.2615

Q 416.80>372.05 (-)

Y|A=3
RT='

1.5e6
1.0e6
5.0e5
O.OeO

3583853
RT=6.810

X-JV

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00>81.00 25.80 (26.74)

I STD 329.00 > 309.15 (-) 1,68e5

1.5e5 ^

R1 25.80

r A=366665
uRT=6.054

1.0e5 ^



I

5.0e4 f





0 0<=>0 -

I

L*

6.4 6.6
RT (min)

13C-PFHxA

Cone. 4.8946

1.40e6 Q 314.90>270.10 (-)

^=3009893
RT=6.107

6.2 6.4

RT (min)

180-PFHxS IS

Cone. 4.7250

1.36e6 ISTD 402.70>84.05 (-)

O.OeO -

6.6 6.8
RT (min)

7.0
RT (min)

6.6

6.8

1.5e5 -
1.0e5 ^
5.0e4 ^
O.OeO :

A=477531

- R1 98.14 (--

RT=7.105

: AJ

)l ~

13C-4 2-FTS

Cone. 5.0799

R#1 329.00>81.00 25.80 (26.74)
Q 329.00>309.15 (-)	1.68e5

1.5e5-
1.0e5:
5.0e4 ^
O.OeO :

'

r.A=366665

: R1 25.80

]Rl)= 6.054

I

i.

6.2 6.4
RT (min)

6.0

3.0e5
2.0e5
1.0e5
O.OeO

rA=687300
]R1 79.79 (fce.142

6.2 6.4

RT (min)

180-PFHxS

Cone. 4.5921

3.91 e5 Q 402.70>84.05 (-)

r.A=838228
I RT=6.502

6.6 6.8
RT (min)

PFHpS

Cone. 5.2040

R#1 449.00>99.20 65.10 (66.82)
Q 449.00>80.15 (-)	3.15e5

fA=676920
3'0e5 -R1 65.10 (AjRt=6.799

2.0e5 :

1.0e5:

O.OeO :

7.0
RT (min)

PFOS

Cone. 4.5123

R#1 499.00>99.00 98.14 (93.96)
Q 499.00>80.00 (-)	1.54e5

13C-PFOS IS

Cone. 4.7750

105 (-)

3.0e5 :
2.0e5 :
1.0e5-j
O.OeO :

RT (min)

RT (min)

6.75 7.00 7.25 7.50

RT (min)

4-2-FtS

Cone. 4.5707

R#1 327.00 >81.10 15.84 (16.29)
Q 327.00>307.05 (-)	1.98e5

T A=428984

-R1 15.84(1^6.054

O.OeO -

6.2 6.4
RT (min)

PFPeS

Cone. 4.9755

R#1 349.00>99.00 79.79 (74.42)
Q 349.00>79.95 (-)	3.10e5

6.0

6.2 6.4
RT (min)

PFHxS

Cone. 4.6654

R#1 399.00>99.00 96.76 (95.46)
Q 399.00>80.00 (-)	2.05e5

2.0e5 -

A= 556036
R1 96.76 (-|^T=6.502

O.OeO -

1



6.4

RT (min)

6.25 6.50 6.75 7.00
RT (min)

PFHpA

Cone. 5.4166

R#1 362.90>169.00 16.43 (17.56)
Q 362.90>319.00 (-)	2.31e6

IA=4973384
Rt=6.499

O.OeO

6.6 6.8
RT (min)

6-2-FTS

Cone. 4.7058

R#1 427.00>80.90 30.53 (28.57)
Q 427.00>407.00 (-)	1.70e5

f A=361535
1.5e5^R1 30"53 ^|]Rt=6.792

1.0e5^

5.0e4 ^

O.OeO -

O.OeO -

Vj

6.4

6.6 6.8
RT (min)

PFOA

Cone. 4.6994

R#1 413.00> 169.10 28.97 (28.52)
Q 413.00>369.00 (-)	2.40e6

TA= 5205627
HR1 28-97 (-jkr=6.810

7.0
RT (min)

ISC-

Cone.

6.6 6.8 7.0 7.2
RT (min)

PFOS

4.9937

3.72e5 Q 502.80>80.05 (-)

3.0e5 i
2.0e5 i
^.0eS1_
^=. O.OeO -U

3.72e5

A=825172
RT=7.106

/ V

7.2 7.4
RT (min)

7.2 7.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

213

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)

Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:04

CCV3-230504 (continued)

PFNA

Cone. 4.6518

R#1 463.00>219.00 21.98 (21.80)
Q 463.00>418.90 (-)	1.70e6

*A=3785410

1.5e6>1 21-98 (-||^=7.129

1.0e6 -
5.0e5 :
O.OeO :

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)
1.5e6 -i

TA=3327473
IrT=7.129

13C-PFNA

Cone. 5.2137

Q 467.80>423.00 (-)
1.5e6 -i

1.0e6 -
5.0e5 ^
O.OeO -

TA=3327473
IrT=7.129

Li

1.0e6 -
5.0e5 ^
O.OeO -

PFNS

Cone. 4.5810

R#1 549.00>99.00 65.93 (66.39)
Q 549.00>79.95 (-)	4.50e5

4.0e5-|R1 6593 7.438

8-2-FTS

Cone. 4.5132

R#1 527.20>487.00 7.53 (7.71)
Q 527.10>506.90 (-)	7.41 e4

175319
7.465

L,

7.2 7.4

RT (min)

7.4
RT (min)

7.0

7.2

13C-8 2-FTSJS

Cone. 4.7900

ISTD 528.80>509.00 (-)
6.0e4

4.0e4 :

2.0e4 ^

O.OeO -



rA= 148856

:

RT=7.466

: I



7.4 7.6 7.8
RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

13C-8 2-FTS

Cone. 4.9740

Q 528.80>509.00 (-)
6.0e4 -

4.0e4 -

2.0e4 -j

O.OeO 4=

7.4
RT (min)

PFDA

Cone. 5.0521

R#1 512.90>219.00 17.51 (17.77)
Q 512.90>469.00 (-)	1.58e6

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

1.42e6 Q 514.80>469.95 (-)

A= 148856
RT=7.466



7.6 7.8
RT (min)

A=3380806
RT=7.471

d3-N-MeFOSAA

Cone. 4.9150

ISTD 572.80>419.05 (-)

4.0e5 -|	T|A=1

RT=

1047306
RT=7.651

4.05e5 Q 572.80>419.05 (-)
4.0e5

7.6 7.8
RT (min)

NMeFOSAA

Cone. 4.8085

R#1 570.20>512.00 37.53 (35.13)
Q 570.20>419.00 (-)	3.69e5

O.OeO

7.6 7.8
RT (min)

PFDS

Cone. 4.9106

R#1 599.00>99.00 53.98 (55.44)
Q 599.00>80.10 (-)	3.25e5



O.OeO

7.6 7.8 8.0	7.6 7.8 8.0

RT (min)	RT (min)

13C-PFUnDA	PFUnDA

Cone. 5.0119	Cone. 4.6873

R#1 563.00>219.00 14.78 (14.10)

1.31 e6 Q 563.00> 518.90 (-)	1,26e6 ISTD 588.80>419.00 (-)

7.25 7.50 7.75 8.00

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

Q 564.80>519.95 (-)

4.76e5 Q 588.80>419.00 (-)

^A=3120957
I RT=7.821

f A=3022742
]R1 14.78 (1^=7.821

O.OeO -

=F

Vy

A= 1166791
RT=7.834

'A= 1166791
RT=7.834

O.OeO -



V.

O.OeO -

/

V,

7.8 8.0	7.8

RT (min)

PFOSA	13C-FOSAJS

Cone. 4.7685	Cone. 5.0000
R#1 498.20>64.10 0.10 (0.10)

Q 498.20>78.00 (-)	4.67e5	I STD 506.00 > 78.05 (-)

RT (min)

RT (min)

13C-FOSA

Cone. 5.0257

r,A= 1072926

IR1 0.10 (--fpRT=7.a

4.0e5 -

A=924064
RT=7.886

Q 506.00>78.05 (-)
4.0e51

A=924064
RT=7.886





7.6 7.8 8.0 8.2

RT (min)

8.0 8.2
RT (min)

7.8 8.0 8.2
RT (min)

1.5e6-R1 16.74 (
1.0e6^

5.0e5 ^

O.OeO 1, , ,

A=3817654
't=8.158

8.0

7.6 7.8
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

7.8 8.0

RT (min)

d5-N-EtFOSAA

Cone. 4.8452

4.76e5

f A=3120957
l RT=7.821

O.OeO-

7.8 8.0

RT (min)

NEtFOSAA

Cone. 4.8874

R#1 584.20>526.10 60.03 (56.68)
Q 584.20>418.95 (-)	3.75e5

~ A= 1127278

: R1 60.03 (-- kT=7.841

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

J



7.8 8.0

RT (min)

PFDoA

Cone. 4.7080

R#1 613.05> 169.00 16.74 (16.48)
Q 613.05>569.00 (-)	1.60e6

7.50 7.75 8.00 8.25

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

~ A=305;
I	RT=8.1

1.28e6

=3055349
58

L

B.2 8.4

RT (min)

B.O 8.2 8.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

21§

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:04

CCV3-230504 (continued)

13C-PFDoA

Cone. 5.3654

Q614.80>569.95 (-)

A=3055349
RT=8.158

NEtFOSE

Cone. 4.5219

Q 629.50>59.10 (-)
6.0e5 q	]

4.0e5 :

!A=1407297
RT=8.863



rA=913651

:

A RT=8.642





O.OeO -

8.6

1.5e5 -
1.0e5-j
5.0e4 ^
O.OeO :

A=341648

: R1 64.22 (

kt=8.425





d5-NEtFOSA IS

Cone. 5.0000

10-2-FtS

Cone. 3.7184
R#1 626.50>81.05 86.26 (72.12)

1,28e6 Q 626.50>607.05 (-)	5.10e4 ISTD 531.10> 169.10 (-)

TA= 125421

;R1 86.26 (nm"=8.170

d5-NEtFOSA

Cone. 5.0700

4.55e5 Q 531.10> 169.10 (-)

O.OeO -

3.2 8.4

RT (min)

6.02e5 I STD 638.90 > 59.10 (-)

o.oeo

8.6 8.8 9.0 9.2

RT (min)

d3-NMeFOSA

Cone. 4.9583

Q 515.10> 169.00 (-)

3.0e5 :
2.0e5 :
1.0e5-j
O.OeO :

TA=288221
'RT=8.845



d7-N-MeFOSE IS

Cone. 5.0000

3.84e5 I STD 623.00 >59.00 (-)

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

TiA=4
A RT=¦

451195
8.604

L:

8.6 8.8

RT (min)

PFTeDA

Cone. 5.6941

R#1 713.00>169.30 13.54 (12.52)
Q 713.00>668.90 (-)	1.33e6

fA=3210010

- R1 13.54 (-||^r=8.768

13C-PFTeDA IS

Cone. 5.0000

I STD 714.80 >669.80 (-)

i.8 9.0

RT (min)

L-PFDoS

Cone. 5.0179

R#1 698.80 >98.80 64.22 (62.67)
Q 698.80>80.10 (-)	1.52e5

Q 377.10>251.20 (-)

1.5e6:

1.0e6:

5.0e5 :

O.OeO :

A=3722117
RT=6.542



f A= 1041761



p.

I



8.0 8.2 8.4

RT (min)

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 5.7583

1.23e5 Q 638.90> 59.10 (-)

A=288221
RT=8.845

_ Vj

RT (min)

RT (min)

d7-N-MeFOSE

Cone. 5.0108

1.85e5 Q 623.00> 59.00 (-)

^.SeSz_

^.0eSz_

5.0e4 i
O.OeO ^pr-

'A=451195
RT=8.604

L:

RT (min)

RT (min)

13C-PFTeDA

Cone. 4.0823

4.72e5 Q 714.80>669.80 (-)

TA= 1137073
RT=8.768

O.OeO

8.6 8.8 9.0

RT (min)

NaDONA

Cone. 4.7639

A=1137073
RT=8.768

NMeFOSE

Cone. 5.2368

4.55e5 Q 616.10>58.90 (-)

r A= 1041761
I RT=8.889

3.8 9.0 9.2
RT (min)

O.OeO -





A=457246

1

: R1 73.83 (-

|RT=8.647



Vv

4.72e5 Q 631.00>451.10 (-)

f A=1285720
I RT=7.970

O.OeO

8.6 8.8 9.0

RT (min)

PFHxDA

Cone. 3.6675

Vo

PFODA

Cone. 4.0844

1.5e5-
^.0eSz
5.0e4z_
O.OeO -

A=448017
RT=8.619

L,

8.8 9.0 9.2
RT (min)

NMeFOSA

Cone. 4.8700

R#1 512.10>219.20 73.83 (75.56)
Q 512.10> 169.20 (-)	1.91e5

8.4 8.6 8.8 9.0
RT (min)

d3-NMeFOSA IS

Cone. 5.0000

iSTD 515.10> 169.00 (-)

3.84e5

r A=913651
| RT=8.642

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

8.4 8.6 8.8 9.0

RT (min)

NEtFOSA

Cone. 4.8014

R#1 526.50>219.20 63.10 (61.76)
Q 526.50> 169.10 (-)	3.17e5

rA=722652

3.0e5- R-] 63.10 (-4ter=8.£

2.0e5 :
1.0e5:
O.OeO :

8.6

RT (min)

PFTrDA

Cone. 5.4779

R#1 663.10> 169.10 22.56 (21.32)
Q 663.10>618.90 (-)	1.41e6

- R1 22.56 (

^,A=3180613
r\=8.477

8.6 8.8 9.0 9.2

RT (min)

11CI-PF30UdS

Cone. 4.8902

RT (min)

9CI-PF30NS

Cone. 4.4265

5.57e5 Q 531.00>351.10 (-)

A=2150591
RT=7.290

8.2

RT (min)

7.4 7.6
RT (min)

13C2-PFHxDA IS

Cone. 5.0000

1.79e6 Q 812.90>769.00 (-)
4.0e5 -

2.0e5 -

4.44e5

RT (min)

6.4 6.6 6.8

RT (min)

9.2 9.4 9.6
RT (min)

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

316

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CCV3-230504 (continued)

13C2-PFHxDA

Cone. 4.7587

Q 815.00>770.00 (-)
3.0e6 ^

2.0e6 ^

1.0e6:

O.OeO 4=

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 4.9308

TA= 5804815
IRT=9.275

L:

3.21 e6 ISTD 569.80> 524.90 (-)
1,0e6 -i

9.2 9.4 9.6
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

A=2426741
RT=7.821



PFecHS

Cone. 4.4128
R#1 461.00>99.10 40.68 (38.58)

1.00e6 Q 461.00>381.00 (-)	1.72e6 Q 298.00>78.00 (-)

fA=3853845
1 5e6 ^R1 40-68 (][Rt=6.759

1.0e6 -
5.0e5 :
O.OeO :

PFHxSA

Cone. 4.9431

1.17e6 Q 397.90>78.00 (-)

RT (min)

7.0

RT (min)

f A=2614918
I RT=6.294

6.6
RT (min)

f A=2189736
\ RT=7.101

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

310

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:08

CCV4-230504

Sample ID: CCV4-230504

Date Acquired: 5/5/2023 3:30:45 AM
Acquired by: System Administrator
Data File: 230504107
Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5















Name

Mode ID Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.371

1227393

1227393

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.371

1227393

2829903

13C7-PFUnDA IS

5.0000

4.0990

nq/mL

PFBA

Auto

4.371

1503732

1227393

13C-PFBA IS

5.0000

5.1651

nq/mL

13C-PFPeA IS

Auto

5.538

2195016

2195016

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.538

2195016

2829903

13C7-PFUnDA IS

5.0000

4.1380

nq/mL

PFPeA

Auto

5.539

2168286

2195016

13C-PFPeA IS

5.0000

5.0540

nq/mL

13C-PFBS IS

Auto

5.661

860664

860664

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.661

860664

2829903

13C7-PFUnDA IS

4.6500

4.0700

nq/mL

PFBS

Auto

5.661

673801

860664

13C-PFBS IS

4.4200

4.4077

nc

13C HFPO DA IS

Auto

6.252

618571

618571

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.252

618571

2829903

13C7-PFUnDA IS

5.0000

4.3208

nc

HFPO DA

Auto

6.252

570919

618571

13C HFPO DA IS

5.0000

5.4027

nq/mL

13C-4 2-FTS IS

Auto

6.058

369939

369939

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

6.058

369939

2829903

13C7-PFUnDA IS

4.6700

4.3951

nq/mL

4-2-FtS

Auto

6.059

428151

369939

13C-4 2-FTS IS

4.6700

4.5214

nq/mL

PFHxA

Auto

6.111

4669089

2976861

13C-PFHxA IS

5.0000

5.3247

nq/mL

13C-PFHxA IS

Auto

6.111

2976861

2976861

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

6.111

2976861

2829903

13C7-PFUnDA IS

5.0000

4.1512

nq/mL

PFPeS

Auto

6.146

707214

858551

180-PFHxS IS

4.6900

4.9984

nq/mL

PFHxS

Auto

6.505

554033

858551

180-PFHxS IS

4.5500

4.5385

nq/mL

13C-PFHpA IS

Auto

6.503

2962941

2962941

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.503

2962941

2829903

13C7-PFUnDA IS

5.0000

4.1156

nq/mL

180-PFHxS IS

Auto

6.506

858551

858551

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.506

858551

2829903

13C7-PFUnDA IS

4.7250

4.0334

nq/mL

PFHpA

Auto

6.503

4931180

2962941

13C-PFHpA IS

5.0000

5.3184

nq/mL

13C2-6 2-FTS IS

Auto

6.797

366706

366706

	

4.7500

4.7500

nq/mL

13C2-6 2-FTS

Auto

6.797

366706

2829903

13C7-PFUnDA IS

4.7500

4.1896

nq/mL

PFHpS

Auto

6.804

661905

858551

180-PFHxS IS

4.7600

4.9681

nq/mL

6-2-FTS

Auto

6.797

379988

366706

13C2-6 2-FTS IS

4.7400

4.8570

nq/mL

PFOA

Auto

6.815

5308022

3382291

13C-PFOA IS

5.0000

5.0774

nq/mL

13C-PFOA IS

Auto

6.814

3382291

3382291

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.814

3382291

2829903

13C7-PFUnDA IS

5.0000

4.2581

nq/mL

PFOS

Auto

7.111

476595

794973

13C-PFOS IS

4.6400

4.6745

nq/mL

13C-PFOS IS

Auto

7.111

794973

794973

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

7.111

794973

2829903

13C7-PFUnDA IS

4.7750

4.1256

nq/mL

PFNA

Auto

7.135

4220302

3337864

13C-PFNA IS

5.0000

5.1701

nq/mL

13C-PFNA IS

Auto

7.135

3337864

3337864

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.135

3337864

2829903

13C7-PFUnDA IS

5.0000

4.4849

nq/mL

PFNS

Auto

7.444

1061027

794973

13C-PFOS IS

4.8000

4.7971

nq/mL

8-2-FTS

Auto

7.472

213539

150782

13C-8 2-FTS IS

4.7900

5.4269

nq/mL

13C-8 2-FTS IS

Auto

7.472

150782

150782

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.472

150782

2829903

13C7-PFUnDA IS

4.7900

4.3205

nq/mL

PFDA

Auto

7.477

3807328

3453650

13C-PFDA IS

5.0000

4.9956

nq/mL

13C-PFDA IS

Auto

7.478

3453650

3453650

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.478

3453650

2829903

13C7-PFUnDA IS

5.0000

4.3663

nq/mL

d3-N-MeFOSAA IS

Auto

7.657

1058928

1058928

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.657

1058928

2829903

13C7-PFUnDA IS

5.0000

4.2616

nq/mL

NMeFOSAA

Auto

7.662

1190132

1058928

d3-N-MeFOSAA IS

5.0000

4.9665

nq/mL

PFDS

Auto

7.786

740767

794973

13C-PFOS IS

4.8200

4.8894

nq/mL

13C-PFUnDA IS

Auto

7.828

3273187

3273187

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.828

3273187

2829903

13C7-PFUnDA IS

5.0000

4.5075

nq/mL

PFUnDA

Auto

7.828

3568855

3273187

13C-PFUnDA IS

5.0000

5.2768

nq/mL

d5-N-EtFOSAA IS

Auto

7.841

1172753

1172753

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.841

1172753

2829903

13C7-PFUnDA IS

5.0000

4.1762

nq/mL

NEtFOSAA

Auto

7.849

1227337

1172753

dS-N-EtFOSAA IS

5.0000

5.2941

nq/mL

PFOSA

Auto

7.893

1074702

946168

13C-FOSA IS

5.0000

4.6648

nq/mL

13C-FOSA IS

Auto

7.893

946168

946168

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.893

946168

2829903

13C7-PFUnDA IS

5.0000

4.4128

nq/mL

PFDoA

Auto

8.167

4022455

3241709

13C-PFDoA IS

5.0000

4.6754

nq/mL

13C-PFDoA IS

Auto

8.167

3241709

3241709

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

318

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A

Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:08

CCV4-230504 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.167

3241709

2829903

13C7-PFUnDA IS

5.0000

4.8817

nq/mL

10-2-FtS

Auto

8.178

191287

150782

13C-8 2-FTS IS

4.8200

5.5987

ng/mL

d5-NEtFOSA IS

Auto

8.898

1020772

1020772

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.898

1020772

2829903

13C7-PFUnDA IS

5.0000

4.2601

ng/mL

NMeFOSE

Auto

8.626

463633

499717

d7-N-MeFOSE IS

5.0000

4.8932

nq/mL

NEtFOSE

Auto

8.871

1400597

291671

d9-EtFOSE IS

5.0000

4.4472

ng/mL

d9-EtFOSE IS

Auto

8.853

291671

291671

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.853

291671

2829903

13C7-PFUnDA IS

5.0000

4.9970

ng/mL

NMeFOSA

Auto

8.654

483075

939575

d3-NMeFOSA IS

5.0000

5.0031

nq/mL

dB-NMeFOSA IS

Auto

8.648

939575

939575

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.648

939575

2829903

13C7-PFUnDA IS

5.0000

4.3725

nq/mL

d7-N-MeFOSE IS

Auto

8.611

499717

499717

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.611

499717

2829903

13C7-PFUnDA IS

5.0000

4.7591

nq/mL

NEtFOSA

Auto

8.907

748114

1020772

d5-NEtFOSA IS

5.0000

5.0727

ng/mL

PFTrDA

Auto

8.485

3884127

1714434

13C-PFTeDA IS

5.0000

4.4367

nq/mL

PFTeDA

Auto

8.775

3843120

1714434

13C-PFTeDA IS

5.0000

4.5214

ng/mL

13C-PFTeDA IS

Auto

8.775

1714434

1714434

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.775

1714434

2829903

13C7-PFUnDA IS

5.0000

5.2782

ng/mL

11CI-PFBOUdS

Auto

7.977

1228418

794973

13C-PFOS IS

4.7100

4.8497

nq/mL

9CI-PF30NS

Auto

7.296

2330648

794973

13C-PFOS IS

4.6600

4.9793

ng/mL

L-PFDoS

Auto

8.435

321331

794973

13C-PFOS IS

4.8400

4.8988

nq/mL

NaDONA

Auto

6.546

3439832

3337864

13C-PFNA IS

4.7100

4.3889

ng/mL

PFHxDA

Auto

9.285

1854067

6096200

13C2-PFHxDA IS

5.0000

6.8620

nq/mL

PFODA

Auto

9.867

1449631

6096200

13C2-PFHxDA IS

5.0000

6.3698

ng/mL

13C2-PFHxDA IS

Auto

9.285

6096200

6096200

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.285

6096200

2829903

13C7-PFUnDA IS

5.0000

4.2856

ng/mL

13C7-PFUnDA IS

Auto

7.828

2829903

2829903

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.763

3928806

794973

13C-PFOS IS

4.6100

4.6695

ng/mL

PFBSA

Auto

6.298

2663589

946168

13C-FOSA IS

5.0000

4.9053

nq/mL

PFHxSA

Auto

7.106

2167349

3337864

13C-PFNA IS

5.0000

4.8773

ng/mL

CHARGE

ND(W/B)

	

	

2829903

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 4.0990
2.90e5 Q 217.20>172.30 (-)

A=1227393
RT=4.371

RT (min)

PFPeA

Cone. 5.0540

13C-PFBS IS

Cone. 4.6500

PFBA

Cone. 5.1651
2.90e5 Q 213.20> 169.10 (-)

A=1227393
RT=4.371

8.33e5 ISTD 301.80>80.00 (-)

3.0e5 -
2.0e5 :
1.0e5:
O.OeO :

TA=860664
RT= 5.661

5.8

RT (min)

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

A= 1503732
RT=4.371

RT (min)

13C-PFBS

Cone. 4.0700

3.39e5 Q 301.80>80.00 (-)

3.0e5 ^

2.0e5 ^

1.0e5 ^

O.OeO 4=

13C-PFPeA IS

Cone. 5.0000
3.56e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 4.1380
8.43e5 Q 267.90>223.00 (-)

A=2195016
RT= 5.538

13C HFPO DA IS

Cone. 5.0000

5.8

RT (min)	RT (min)

PFBS

Cone. 4.4077

R#1 298.80>99.00 71.70 (71.09)

3.39e5 Q 299.00>80.00 (-)	2.66e5 ISTD 332.10>287.10 (-)

TA=860664	TA=673801

I RT = 5.661	- R1 7170 irRT^= 5.661

6.0
RT (min)

6.0
RT (min)

6.0
RT (min)

6.4 6.6
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

218

-------


Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:08

CCV4-230504 (continued)

13C HFPO DA

Cone. 4.3208

Q 332.10>287.10 (-)

A=618571
RT=6.252

O.OeO -



6.2



f,A=4669089

- R1 2.70 (-

W

ii

I



13C-PFHpA_IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

tA=2962941
RT=6.503

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

fA=366706
l RT=6.797

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
1.5e6 -i

1.0e6 -
5.0e5 ^
O.OeO :

A=3382291
RT=6.814

HFPO DA

Cone. 5.4027

R#1 329.00>285.10 82.08 (79.97)
Q 329.00>169.00 (-)	2.67e5

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00 >81.00 26.37 (26.74)

ISTD 329.00>309.15 (-)	1,68e5

TA=570919

Ifl

13C-4 2-FTS

Cone. 4.3951

R#1 329.00>81.00 26.37 (26.74)
Q 329.00>309.15 (-)	1.68e5

A=369939

6.4 6.6
RT (min)

PFHxA

Cone. 5.3247

R#1 313.00> 119.10 2.70 (2.85)
Q 313.00>269.00 (-)	2.14e6

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)

1.35e6 Q 314.90>270.10 (-)

f A=2976861
I RT=6.111

6.2 6.4

RT (min)

13C-PFHpA

Cone. 4.1156

1.37e6 Q 366.90>322.10 (-)

P*jA=2962941
RT=6.503

L

6.6 6.8
RT (min)

13C2-6 2-FTS

Cone. 4.1896

1.72e5 Q 428.90>409.00 (-)

1.5e5 ^

^.0eS1_

5.0e4 ^

O.OeO 1 . .

;A=366706
RT=6.797

7.0
RT (min)

13C-PFOA

Cone. 4.2581

Q 416.80>372.05 (-)
1.5e6 -

1.0e6 -j

5.0e5 ^

O.OeO 1. . .

A=3382291
RT=6.814

f A=2976861
I RT=6.111

6.2 6.4

RT (min)

180-PFHxS IS

Cone. 4.7250

ISTD 402.70>84.05 (-)
4.0e5 -i

A=858551
RT=6.506

O.OeO 1 , , , 2 rr=

6.6 6.8
RT (min)

3.0e5 :
2.0e5 :
1.0e5:
O.OeO -

R1 64.82 (-

A=661905
"Rt=6.804

L

7.0
RT (min)

6.6

6.8

1.5e5 -
1.0e5 ¦;
5.0e4 -
O.OeO:

R1 98.61 (--

~ A=476595
kT=7.111

M

3.0e5 - R1 77.80 (j
2.0e5 ^

1.0e5-j
O.OeO 1 . . .

A=707214
RT=6.146

i,

6.2 6.4

RT (min)

6.0

180-PFHxS

Cone. 4.0334

Q 402.70>84.05 (-)
4.0e5 -i	I

A=858551
RT=6.506

6.4 6.6 6.8
RT (min)

PFHpS

Cone. 4.9681

R#1 449.00>99.20 64.82 (66.82)
Q 449.00>80.15 (-)	3.09e5

O.OeO -

Ai I

6.4

1.5e5
1.0e5
5.0e4
O.OeO

f!A=379988

: R1 26.96 (: -Rt=6.797

I' i

7.0
RT (min)

PFOS

Cone. 4.6745

R#1 499.00>99.00 98.61 (93.96)
Q 499.00>80.00 (-)	1.56e5

13C-PFOS IS

Cone. 4.7750

105 (-)

3.0e5 :
2.0e5 :
1.0e5-j
O.OeO :

YjA=794973
^ RT=7.111

RT (min)

RT (min)

6.75 7.00 7.25 7.50

RT (min)

4-2-FtS

Cone. 4.5214

R#1 327.00>81.10 17.50 (16.29)
Q 327.00>307.05 (-)	1.91e5

fA=428151

-I R1 17-50 #RT)=6.059

6.2 6.4
RT (min)

PFPeS

Cone. 4.9984

R#1 349.00>99.00 77.80 (74.42)
Q 349.00>79.95 (-)	3.18e5

6.0 6.2 6.4
RT (min)

PFHxS

Cone. 4.5385

R#1 399.00>99.00 95.94 (95.46)
Q 399.00>80.00 (-)	2.07e5

2.0e5 -

fA= 554033

R1 95.94 (--fl kT=6.505

O.OeO -

6.4

RT (min)

6.25 6.50 6.75 7.00
RT (min)

PFHpA

Cone. 5.3184

R#1 362.90>169.00 16.83 (17.56)
Q 362.90>319.00 (-)	2.28e6

fA=4931180

2.0e6-|R1 16'83 (f|Rt=6.503

O.OeO -

6.6 6.8
RT (min)

6-2-FTS

Cone. 4.8570

R#1 427.00>80.90 26.96 (28.57)
Q 427.00>407.00 (-)	1.78e5

7.0
RT (min)

6.4 6.6 6.8
RT (min)

PFOA

Cone. 5.0774

R#1 413.00> 169.10 28.85 (28.52)
Q 413.00>369.00 (-)	2.45e6

F[A= 5308022
JR1 28.85 (-kT=6.815

O.OeO

6.6 6.8 7.0 7.2
RT (min)

13C-PFOS

Cone. 4.1256

3.61 e5 Q 502.80>80.05 (-)

3.0e5 ^

2.0e5 ^

^.0eS1_

O.OeO

3.61 e5

f A=794973
I RT=7.111

7.2 7.4
RT (min)

7.2 7.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

220

-------


Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:08

CCV4-230504 (continued)

PFNA

Cone. 5.1701

R#1 463.00>219.00 20.34 (21.80)
Q 463.00>418.90 (-)	1.90e6

: R1 20.34 (-

1.5e6 -
1.0e6:
5.0e5 :
O.OeO :

A=4220302
1^T=7.135

Il*_

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)
6.0e41

A= 150782
RT=7.472

4.0e4 :
2.0e4 :
O.OeO -

7.4

ISTD 572.80>419.05 (-)
4.0e5

TA= 1058928
RT=7.657

13C-PFUnDA

Cone. 4.5075

Q 564.80>519.95 (-)

O.OeO -

=F

~ A= 1074702

RT=7

- 0.16 ( RT=7.893

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 4.4849

1.50e6 Q 467.80>423.00 (-)

*A=3337864
I RT=7.135

1.0e6 -
5.0e5 ^
O.OeO -

7.4

RT (min)

7.4
RT (min)

13C-8 2-FTS

Cone. 4.3205

Q 528.80>509.00 (-)
6.0e41

~ A= 150782
RT=7.472

4.0e4 :
2.0e4 :
O.OeO -

7.6 7.8
RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

d3-N-MeFOSAA

Cone. 4.2616

4.08e5 Q 572.80>419.05 (-)
4.0e5

O.OeO -

TA= 1058928
RT=7.657



7.8 8.0
RT (min)

7.6

7.8 8.0
RT (min)

PFUnDA

Cone. 5.2768

R#1 563.00>219.00 13.34(14.10)
Q563.00>518.90 (-)	1.49e6

IR1 13.34 (

1.0e6 -
5.0e5 ^
O.OeO -

A=3568855
|"Rt=7.828

7.8 8.0

RT (min)

PFOSA

Cone. 4.6648

R#1 498.20>64.10 0.16 (0.10)
Q 498.20>78.00 (-)	4.73e5

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)
4.0e5 H

A=946168
RT=7.893

L

7.6 7.8 8.0 8.2

RT (min)

1.0e6 -
5.0e5 :

;A=3337864
RT=7.135

6.14e4 Q 512.90>469.00 (-)

fA=3807328
1-5e6^R1 17.17 (JJ-Rt =1 All

1.0e6 -
5.0e5 :
O.OeO :

7.6 7.8
RT (min)

7.4

: R1 38.85 (--

3.0e5 :
2.0e5 i
1.0e5:

.-A.

A=1190132
kT=7.662

O.OeO i i ,a'i ..............

7.25 7.50 7.75 8.00

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

ISTD 588.80>419.00 (-)

4.0e5 -

fA= 1172753
RT=7.841

RT (min)

RT (min)

13C-FOSA

Cone. 4.4128

Q 506.00>78.05 (-)	4.10e5

fA=946168

8.0 8.2
RT (min)

PFNS

Cone. 4.7971

R#1 549.00>99.00 65.62 (66.39)
Q 549.00>79.95 (-)	4.47e5

~ A= 1061027

4.0e5-R1 6562 (fl RT=7.444

O.OeO	—,—

7.0 7.2 7.4

RT (min)

PFDA

Cone. 4.9956

R#1 512.90>219.00 17.17 (17.77)



13C-PFDA IS

Cone. 5.0000

1.59e6 ISTD 514.80>469.95 (-)

A=3453650
RT=7.478

O.OeO -



7.6 7.8
RT (min)

NMeFOSAA

Cone. 4.9665

R#1 570.20>512.00 38.85 (35.13)
Q 570.20>419.00 (-)	3.85e5

7.4

4.73e5 Q 588.80>419.00 (-)

f A= 1172753
RT=7.841

O.OeO -

8.0 8.2
RT (min)

8-2-FTS

Cone. 5.4269

R#1 527.20>487.00 7.62 (7.71)
Q 527.10>506.90 (-)	8.62e4

f A=213539

7.5e4 f

R1 7.62 (-¦

RT=7.472

5.0e4z_





2.5e4z_





0 0<=>0 -

I

_

RT (min)

7.6 7.8
RT (min)

13C-PFDA

Cone. 4.3663

1.47e6 Q 514.80>469.95 (-)

tA=3453650
\ RT=7.478

7.6 7.8
RT (min)

PFDS

Cone. 4.8894

R#1 599.00>99.00 61.35 (55.44)
Q 599.00>80.10 (-)	3.15e5

f A=740767

3'0e5^R1 61.35 (-|-r^=7.786

2.0e5 :

1.0e5:

O.OeO :

7.6 7.8
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

A=3273187
RT=7.828

7.6 7.8 8.0

RT (min)

d5-N-EtFOSAA

Cone. 4.1762

O.OeO -

^n=F

L

4.73e5

7.8 8.0

RT (min)

NEtFOSAA

Cone. 5.2941

R#1 584.20>526.10 55.30 (56.68)
Q 584.20>418.95 (-)	4.17e5

4.0e5 -

O.OeO



[A= 1227337

H

kT=7.849

; J



7.8 8.0

RT (min)

PFDoA

Cone. 4.6754

R#1 613.05> 169.00 16.25 (16.48)
Q 613.05>569.00 (-)	1.70e6

7.50 7.75 8.00 8.25

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

1.35e6

A=3241709
RT=8.167



.2 8.4

RT (min)

B.2 8.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

22®

-------


Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:08

CCV4-230504 (continued)

13C-PFDoA

Cone. 4.8817

Q614.80>569.95 (-)

fA=3241709
RT=8.167

NEtFOSE

Cone. 4.4472

Q 629.50>59.10 (-)

6.0e5 -i	IA=1

I	RT=.

4.0e5 -

2.0e5 -

O.OeO -

1400597
8.871

L

Q 515.10> 169.00 (-)

3.0e5 ~

2.0e5 ~

^.0eSz_

O.OeO 4==

fA=939575
RT=8.648

10-2-FtS

Cone. 5.5987

R#1 626.50>81.05 61.66 (72.12)
Q 626.50>607.05 (-)	7.99e4



rA= 191287

:R1 61.66 (-

y^T=8.178

^ I

Lt

3.2 8.4

RT (min)

d9-EtFOSE IS

Cone. 5.0000

6.00e5 ISTD 638.90> 59.10 (-)

'A=291671
RT=8.853

8.6 8.8 9.0 9.2

RT (min)

d3-NMeFOSA

Cone. 4.3725

d7-N-MeFOSE IS

Cone. 5.0000

3.88e5 I STD 623.00 > 59.00 (-)
2.0e5 -

A=499717
RT=8.611

8.6 8.8

RT (min)

PFTeDA

Cone. 4.5214

R#1 713.00>169.30 11.62 (12.52)
Q 713.00>668.90 (-)	1.61e6

13C-PFTeDA IS

Cone. 5.0000

I STD 714.80 >669.80 (-)

A= 1714434
RT=8.775

L

9.0
RT (min)

L-PFDoS

Cone. 4.8988

R#1 698.80 >98.80 71.33 (62.67)
Q 698.80>80.10 (-)	1.40e5

f A=321331

jR1 71.33 (-1 RT=8.435

NaDONA

Cone. 4.3889

Q 377.10>251.20 (-)

~ A=3
RT='

1.5e6
1.0e6
5.0e5
O.OeO

3439832
RT=6.546

d5-NEtFOSA IS

Cone. 5.0000

I STD 531.10> 169.10 (-)
4.0e5 -

A=1020772
RT=8.898

d5-NEtFOSA

Cone. 4.2601

Q 531.10> 169.10 (-)
4.0e5

O.OeO

:

RT=8.898

:	J-

L

NMeFOSE

Cone. 4.8932

4.41 e5 Q 616.10> 58.90 (-)

^.SeSz_

1.0e5z
5.0e4 i

O.OeO 1	~

t A=463633
RT=8.626

L

3.2 8.4

RT (min)

3.8 9.0 9.2
RT (min)

d9-EtFOSE

Cone. 4.9970

1.23e5 Q 638.90> 59.10 (-)

8.8 9.0 9.2
RT (min)

NMeFOSA

Cone. 5.0031

R#1 512.10>219.20 71.70 (75.56)
Q 512.10> 169.20 (-)	2.01 e5

8.4 8.6 8.8 9.0
RT (min)

d3-NMeFOSA IS

Cone. 5.0000

f A=291671
I RT=8.853

2.0e5 -

~ A=483075

JR1 71.70 (--f|-^T=8.654

O.OeO -

iSTD 515.10> 169.00 (-)

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

3.88e5

RT (min)

RT (min)

d7-N-MeFOSE

Cone. 4.7591

Q 623.00>59.00 (-)
2.0e5 -

8.4 8.6 8.8 9.0

RT (min)

NEtFOSA

Cone. 5.0727

R#1 526.50>219.20 60.61 (61.76)
Q 526.50> 169.10 (-)	3.30e5

8.6

RT (min)

PFTrDA

Cone. 4.4367

R#1 663.10> 169.10 20.45 (21.32)
Q 663.10>618.90 (-)	1.74e6

A=3884127
1^1"=8.485

RT (min)

13C-PFTeDA

Cone. 5.2782

8.6 8.8 9.0 9.2
RT (min)	RT (min)

11CI-PF30UdS

Cone. 4.8497

RT (min)

9CI-PF30NS

Cone. 4.9793

7.14e5 Q 714.80>669.80 (-)

7.14e5 Q 631.00>451.10 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

'A=1714434
RT=8.775

*A= 1228418
fll RT=7.977

5.25e5 Q 531.00>351.10 (-)
1.0e6H

O.OeO -

A=2330648
RT=7.296

u

9.0

RT (min)

8.6 8.8 9.0

RT (min)

PFHxDA

Cone. 6.8620

7.8 8.0 8.2

RT (min)

PFODA

Cone. 6.3698

7.4 7.6
RT (min)

13C2-PFHxDA IS

Cone. 5.0000

1.65e6 Q 812.90>769.00 (-)

7.5e5 ^

5.0e5 ^

2.5e5 ^

O.OeO 1 , , ,

8.52e5 Q 912.80>869.00 (-)

5.16e5

A=1854067
RT=9.285

r A= 1449631
RT=9.867

RT (min)

6.8

RT (min)

9.2 9.4 9.6
RT (min)

¦ Ail
9.8 10.0

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

322

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)

Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:08

CCV4-230504 (continued)

13C2-PFHxDA

Cone. 4.2856

Q 815.00>770.00 (-)
3.0e6
2.0e6
1.0e6
O.OeO

13C7-PFUnDA IS

Cone. 5.0000

3.27e6 ISTD 569.80>524.90 (-)

PFBSA

Cone. 4.9053

PFecHS

Cone. 4.6695
R#1 461.00>99.10 39.55 (38.58)

1.16e6 Q 461.00>381.00 (-)	1.72e6 Q 298.00>78.00 (-)

PFHxSA

Cone. 4.8773

1.19e6 Q 397.90>78.00 (-)



A=6096200

: |

RT=9.285





9.2 9.4 9.6
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

A=3928806

RT (min)

jA=2663589
RT=6.298

7.5e5 :
5.0e5 i
2.5e5 :
O.OeO :

6.6
RT (min)

A=2167349
RT=7.106

L

7.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

222

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ifkiLS^

Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:12

CCV5-230504

Sample ID: CCV5-230504

Date Acquired: 5/5/2023 6:29:32 AM

Acquired by: System Administrator

Data File: 230504133

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone.

Cone. Unit

13C-PFBA IS

Auto

4.380

1355074

1355074

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.380

1355074

1975302

13C7-PFUnDA IS

5.0000

6.4832

nq/mL

PFBA

Auto

4.381

1505811

1355074

13C-PFBA IS

5.0000

4.6871

nq/mL

13C-PFPeA IS

Auto

5.552

2171633

2171633

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.552

2171633

1975302

13C7-PFUnDA IS

5.0000

5.8651

nq/mL

PFPeA

Auto

5.553

2181145

2171633

13C-PFPeA IS

5.0000

5.1387

nq/mL

13C-PFBS IS

Auto

5.675

770177

770177

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.675

770177

1975302

13C7-PFUnDA IS

4.6500

5.2179

nq/mL

PFBS

Auto

5.675

659952

770177

13C-PFBS IS

4.4200

4.8243

nc

13C HFPO DA IS

Auto

6.266

573692

573692

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.266

573692

1975302

13C7-PFUnDA IS

5.0000

5.7410

nc

HFPO DA

Auto

6.265

535125

573692

13C HFPO DA IS

5.0000

5.4601

nq/mL

13C-4 2-FTS IS

Auto

6.072

355318

355318

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

6.072

355318

1975302

13C7-PFUnDA IS

4.6700

6.0478

nq/mL

4-2-FtS

Auto

6.072

406939

355318

13C-4 2-FTS IS

4.6700

4.4743

nq/mL

PFHxA

Auto

6.125

4462596

2977272

13C-PFHxA IS

5.0000

5.0885

nq/mL

13C-PFHxA IS

Auto

6.124

2977272

2977272

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

6.124

2977272

1975302

13C7-PFUnDA IS

5.0000

5.9481

nq/mL

PFPeS

Auto

6.160

662663

820741

180-PFHxS IS

4.6900

4.8993

nq/mL

PFHxS

Auto

6.519

525483

820741

180-PFHxS IS

4.5500

4.5030

nq/mL

13C-PFHpA IS

Auto

6.516

2944202

2944202

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.516

2944202

1975302

13C7-PFUnDA IS

5.0000

5.8589

nq/mL

180-PFHxS IS

Auto

6.519

820741

820741

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.519

820741

1975302

13C7-PFUnDA IS

4.7250

5.5239

nq/mL

PFHpA

Auto

6.516

48047%

2944202

13C-PFHpA IS

5.0000

5.2151

nq/mL

13C2-6 2-FTS IS

Auto

6.809

339025

339025

	

4.7500

4.7500

nq/mL

13C2-6 2-FTS

Auto

6.809

339025

1975302

13C7-PFUnDA IS

4.7500

5.5491

nq/mL

PFHpS

Auto

6.815

630362

820741

180-PFHxS IS

4.7600

4.9493

nq/mL

6-2-FTS

Auto

6.809

364991

339025

13C2-6 2-FTS IS

4.7400

5.0462

nq/mL

PFOA

Auto

6.827

5087136

3349217

13C-PFOA IS

5.0000

4.9141

nq/mL

13C-PFOA IS

Auto

6.827

3349217

3349217

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.827

3349217

1975302

13C7-PFUnDA IS

5.0000

6.0407

nq/mL

PFOS

Auto

7.125

462254

802423

13C-PFOS IS

4.6400

4.4918

nq/mL

13C-PFOS IS

Auto

7.125

802423

802423

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

7.125

802423

1975302

13C7-PFUnDA IS

4.7750

5.9659

nq/mL

PFNA

Auto

7.150

3499014

3183121

13C-PFNA IS

5.0000

4.4948

nq/mL

13C-PFNA IS

Auto

7.149

3183121

3183121

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.149

3183121

1975302

13C7-PFUnDA IS

5.0000

6.1274

nq/mL

PFNS

Auto

7.460

1033885

802423

13C-PFOS IS

4.8000

4.6310

nq/mL

8-2-FTS

Auto

7.490

156980

143012

13C-8 2-FTS IS

4.7900

4.2063

nq/mL

13C-8 2-FTS IS

Auto

7.490

143012

143012

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.490

143012

1975302

13C7-PFUnDA IS

4.7900

5.8708

nq/mL

PFDA

Auto

7.494

3569298

3082116

13C-PFDA IS

5.0000

5.2478

nq/mL

13C-PFDA IS

Auto

7.494

3082116

3082116

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.494

3082116

1975302

13C7-PFUnDA IS

5.0000

5.5824

nq/mL

d3-N-MeFOSAA IS

Auto

7.674

1022008

1022008

	

5.0000

5.0000

nq/mL

d3-N-MeFOSAA

Auto

7.674

1022008

1975302

13C7-PFUnDA IS

5.0000

5.8925

nq/mL

NMeFOSAA

Auto

7.679

1152463

1022008

d3-N-MeFOSAA IS

5.0000

4.9831

nq/mL

PFDS

Auto

7.803

738666

802423

13C-PFOS IS

4.8200

4.8303

nq/mL

13C-PFUnDA IS

Auto

7.845

2889617

2889617

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.845

2889617

1975302

13C7-PFUnDA IS

5.0000

5.7009

nq/mL

PFUnDA

Auto

7.845

2698293

2889617

13C-PFUnDA IS

5.0000

4.5192

nq/mL

d5-N-EtFOSAA IS

Auto

7.858

1153374

1153374

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.858

1153374

1975302

13C7-PFUnDA IS

5.0000

5.8841

nq/mL

NEtFOSAA

Auto

7.865

1040925

1153374

dS-N-EtFOSAA IS

5.0000

4.5655

nq/mL

PFOSA

Auto

7.910

1059224

888834

13C-FOSA IS

5.0000

4.8942

nq/mL

13C-FOSA IS

Auto

7.910

888834

888834

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.910

888834

1975302

13C7-PFUnDA IS

5.0000

5.9389

nq/mL

PFDoA

Auto

8.184

3511131

2630290

13C-PFDoA IS

5.0000

5.0298

nq/mL

13C-PFDoA IS

Auto

8.184

2630290

2630290

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

223

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:12

CCV5-230504 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.184

2630290

1975302

13C7-PFUnDA IS

5.0000

5.6746

nq/mL

10-2-FtS

Auto

8.195

85020

143012

13C-8 2-FTS IS

4.8200

2.6236

ng/mL

d5-NEtFOSA IS

Auto

8.915

1038704

1038704

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.915

1038704

1975302

13C7-PFUnDA IS

5.0000

6.2105

ng/mL

NMeFOSE

Auto

8.643

438052

402461

d7-N-MeFOSE IS

5.0000

5.7404

nq/mL

NEtFOSE

Auto

8.888

1386842

280148

d9-EtFOSE IS

5.0000

4.5846

ng/mL

d9-EtFOSE IS

Auto

8.870

280148

280148

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.870

280148

1975302

13C7-PFUnDA IS

5.0000

6.8761

ng/mL

NMeFOSA

Auto

8.671

464030

901352

d3-NMeFOSA IS

5.0000

5.0097

nq/mL

dB-NMeFOSA IS

Auto

8.666

901352

901352

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.666

901352

1975302

13C7-PFUnDA IS

5.0000

6.0095

nq/mL

d7-N-MeFOSE IS

Auto

8.628

402461

402461

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.628

402461

1975302

13C7-PFUnDA IS

5.0000

5.4911

nq/mL

NEtFOSA

Auto

8.924

719100

1038704

d5-NEtFOSA IS

5.0000

4.7918

ng/mL

PFTrDA

Auto

8.500

2733815

638326

13C-PFTeDA IS

5.0000

8.3872

nq/mL

PFTeDA

Auto

8.791

2658269

638326

13C-PFTeDA IS

5.0000

8.3997

ng/mL

13C-PFTeDA IS

Auto

8.791

638326

638326

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.791

638326

1975302

13C7-PFUnDA IS

5.0000

2.8155

ng/mL

11CI-PFBOUdS

Auto

7.994

1209234

802423

13C-PFOS IS

4.7100

4.7296

nq/mL

9CI-PF30NS

Auto

7.312

1905694

802423

13C-PFOS IS

4.6600

4.0336

ng/mL

L-PFDoS

Auto

8.449

326983

802423

13C-PFOS IS

4.8400

4.9387

nq/mL

NaDONA

Auto

6.559

3832139

3183121

13C-PFNA IS

4.7100

5.1272

ng/mL

PFHxDA

Auto

9.299

418158

5608127

13C2-PFHxDA IS

5.0000

1.6423

nq/mL

PFODA

Auto

9.889

460686

5608127

13C2-PFHxDA IS

5.0000

2.2005

ng/mL

13C2-PFHxDA IS

Auto

9.299

5608127

5608127

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.299

5608127

1975302

13C7-PFUnDA IS

5.0000

5.6481

ng/mL

13C7-PFUnDA IS

Auto

7.844

1975302

1975302

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.775

3666749

802423

13C-PFOS IS

4.6100

4.3176

ng/mL

PFBSA

Auto

6.312

2711891

888834

13C-FOSA IS

5.0000

5.3164

nq/mL

PFHxSA

Auto

7.121

2159063

3183121

13C-PFNA IS

5.0000

5.0949

ng/mL

CHARGE

ND(W/B)

	

	

1975302

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

A=1355074

13C-PFBA

Cone. 6.4832
3.13e5 Q 217.20>172.30 (-)

PFBA

Cone. 4.6871
3.13e5 Q 213.20> 169.10 (-)

13C-PFPeA IS

Cone. 5.0000
3.49e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 5.8651
8.22e5 Q 267.90>223.00 (-)

3.0e5

fA=2171633
RT= 5.552

iAi i I

5.4

5.6

RT (min)

RT (min)

RT (min)

PFPeA

Cone. 5.1387

13C-PFBS IS

Cone. 4.6500

13C-PFBS

Cone. 5.2179

8.31 e5 ISTD 301.80>80.00 (-)

A=770177
RT= 5.675

3.04e5 Q 301.80>80.00 (-)
3.0e5 -i

5.8

RT (min)

PFBS	13C_HFPO_DA_IS

Cone. 4.8243	Cone. 5.0000

R#1 298.80>99.00 72.25 (71.09)

3.04e5 Q 299.00>80.00 (-)	2.59e5 ISTD 332.10>287.10 (-)

fA=659952
|"Rt=5.675

6.0
RT (min)

f A= 573692
RT=6.266

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

22§

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:12

CCV5-230504 (continued)

13C HFPO DA

Cone 5.7410

Q332.10>287.10 (-)

HFPO DA

Cone. 5.4601

R#1 329.00>285.10 80.60 (79.97)
2.66e5 Q 329.00> 169.00 (-)	2.51 e5

O.OeO -

O.OeO

: R1 80.60 (-

RT=6.265

I

L

6.2

6.2

6.4 6.6
RT (min)

PFHxA

Cone. 5.0885
R#1 313.00>119.10 2.91 (2.85)

Q 313.00>269.00 (-)	2.03e6 ISTD 314.90>270.10 (-)

13C-PFHxA IS

Cone. 5.0000

2.0e6

13C-PFHpA_IS

Cone. 5.0000

I STD 366.90 >322.10 (-)

fA=2944202
I RT=6.516

13C2-6 2-FTS IS

Cone. 4.7500

I STD 428.90>409.00 (-)
1.5e5 -

A=339025
RT=6.809

1.0e5 -
5.0e4 :
O.OeO :

13C-PFOA IS

Cone. 5.0000

I STD 416.80 >372.05 (-)
1.5e6 -

1.0e6 ^

5.0e5 ^

O.OeO 1. . . .

f A=2977272
RT=6.124

6.2 6.4

RT (min)

13C-PFHpA

Cone. 5.8589

1.35e6 Q 366.90>322.10 (-)

6.6 6.8
RT (min)

13C2-6 2-FTS

Cone. 5.5491

1.57e5 Q 428.90>409.00 (-)
1.5e5 -
1.0e5-j
5.0e4 ^

O.OeO 1 . . .

7.0
RT (min)

13C-PFOA

Cone. 6.0407

1.51e6 Q416.80>372.05 (-)
1.5e6 -

1.0e6 ^

5.0e5 ^

— O.OeO 1. . . .

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00 >81.00 26.80 (26.74)

I STD 329.00 > 309.15 (-)	1,58e5

1.5e5 - 26.80 (•
1.0e5^

5.0e4 ^

O.OeO 4=

IA=355318
"Rt=6.072



6.4 6.6
RT (min)

6.0

13C-PFHxA

Cone. 5.9481

1.34e6 Q 314.90>270.10 (-)

f A=2977272
RT=6.124

6.2 6.4

RT (min)

180-PFHxS IS

Cone. 4.7250

1.35e6 I STD 402.70>84.05 (-)

TA=820741
I RT=6.519

—F

6.6 6.8
RT (min)

A=339025
RT=6.809

6.4

O.OeO -

7.0
RT (min)

6.6

6.8

A

13C-4 2-FTS

Cone. 6.0478

R#1 329.00>81.00 26.80 (26.74)
Q 329.00>309.15 (-)	1.58e5

fA=355318

1.5e5HR1 26.80 , rT=6.072

1.0e5-
5.0e4 -j
O.OeO :

_L



6.2 6.4
RT (min)

6.0

I R1 80.77 (

A=662663
~R^"=6.160



6.2 6.4

RT (min)

180-PFHxS

Cone. 5.5239

3.78e5 Q 402.70>84.05 (-)

3.0e5 i
2.0e5 ~

^.0eSz_

O.OeO -

fA=820741
I RT=6.519

6.6 6.8
RT (min)

PFHpS

Cone. 4.9493

R#1 449.00>99.20 69.56 (66.82)
Q 449.00>80.15 (-)	2.93e5

f A=630362
IR1 69.56 (-1-^7=6.815

7.0
RT (min)

PFOS

Cone. 4.4918

R#1 499.00>99.00 99.49 (93.96)
Q 499.00>80.00 (-)	1.47e5

f A=462254

IR1 99.49 (—I)rt=7.125

13C-PFOS IS

Cone. 4.7750

105 (-)

RT (min)

RT (min)

6.75 7.00 7.25 7.50

RT (min)

3.0e5 -
2.0e5 :
1.0e5:
O.OeO :

f A=802423
RT=7.125

4-2-FtS

Cone. 4.4743

R#1 327.00 >81.10 16.67 (16.29)
Q 327.00>307.05 (-)	1.86e5

1.5e5:
^.0eSz
5.0e4z_
O.OeO -

f A=406939

:R1 16.67 (-( -R^=6.072

6.2 6.4
RT (min)

PFPeS

Cone. 4.8993

R#1 349.00>99.00 80.77 (74.42)
Q 349.00>79.95 (-)	2.97e5

6.0

6.2 6.4
RT (min)

PFHxS

Cone. 4.5030

R#1 399.00>99.00 100.94 (95.46)
Q 399.00>80.00 (-)	1.98e5

fA= 525483

HR1 100-94 (-1-^=6.519

O.OeO -

6.4

RT (min)

6.25 6.50 6.75 7.00
RT (min)

PFHpA

Cone. 5.2151

R#1 362.90>169.00 17.29 (17.56)
Q 362.90>319.00 (-)	2.24e6

f A=4804796

2.0e6HR1 1729 (-™=6.516

I i i i i i i i i i

6.4 6.6 6.8
RT (min)

6-2-FTS

Cone. 5.0462

R#1 427.00>80.90 27.04 (28.57)
Q 427.00>407.00 (-)	1.69e5

fA=364991

1.5e5^R1 27-04(-r^T=6.a

O.OeO

6.6 6.8
RT (min)

PFOA

Cone. 4.9141

R#1 413.00> 169.10 29.38 (28.52)
Q 413.00>369.00 (-)	2.31e6

JA= 5087136
2.0e6- R1 2938 ("fkT=6.827

O.OeO -

6.6 6.8 7.0 7.2
RT (min)

13C-PFOS

Cone. 5.9659

3.59e5 Q 502.80>80.05 (-)

3.0e5 ^

2.0e5 ^

1.0e5^

O.OeO 4=

3.59e5

f A=802423
RT=7.125

7.2 7.4
RT (min)

7.2 7.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

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Quantitation/lntegration
Printed 10/25/2023 16:02:12

CCV5-230504 (continued)

PFNA	13C-PFNA IS

Cone. 4.4948	Cone. 5.0000
R#1 463.00>219.00 23.94 (21.80)

Q 463.00>418.90 (-)	1.56e6	ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 6.1274

1.42e6 Q 467.80>423.00 (-)

1.5e6 -
1.0e6:
5.0e5 :
O.OeO :

fA=3499014

R1 23.94 (--| kT=7.150

fA=3183121
I RT=7.149

7.2 7.4

RT (min)

' i ' *¦

7.0 7.2

7.4
RT (min)

13C-8 2-FTS IS

Cone. 4.7900

13C-8 2-FTS

Cone. 5.8708

ISTD 528.80>509.00 (-)
6.0e4 H

A= 143012
RT=7.490

4.0e4 :
2.0e4 :
O.OeO -

6.17e4 Q 528.80> 509.00 (-)
6.0e4 -

4.0e4 ^

2.0e4 ^

O.OeO I,,,

A= 143012
RT=7.490

7.4

7.6 7.8
RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

7.6 7.8
RT (min)

d3-N-MeFOSAA

Cone. 5.8925

ISTD 572.80>419.05 (-)
4.0e5

A=1022008
RT=7.674

4.02e5 Q 572.80>419.05 (-)
4.0e5

O.OeO -

A=1022008
RT=7.674

O.OeO -



7.8 8.0
RT (min)

7.6

13C-PFUnDA

Cone. 5.7009

Q 564.80>519.95 (-)

7.8 8.0
RT (min)

PFUnDA

Cone. 4.5192
R#1 563.00>219.00 16.63 (14.10)

1.19e6 Q 563.00> 518.90 (-)	1.13e6 ISTD 588.80>419.00 (-)

rA=2889617
I RT=7.845

O.OeO

f A=2698293
1.0e6 -|R1 1663 ("I1^T=7.845

f A= 1153374
I RT=7.858

O.OeO -

=^=F

7.8 8.0

RT (min)

PFOSA

Cone. 4.8942
R#1 498.20>64.10 0.13 (0.10)

Q 498.20>78.00 (-)	4.64e5 ISTD 506.00>78.05 (-)

RT (min)

RT (min)

13C-FOSA IS

Cone. 5.0000

13C-FOSA

Cone. 5.9389

3.90e5 Q 506.00>78.05 (-)	3.90e5

f A=1059224

IR1 °-13 'I RT=7.910

f A=888834
RT=7.910

7.6 7.8 8.0 8.2

RT (min)

8.0 8.2
RT (min)

PFNS

Cone. 4.6310

R#1 549.00 >99.00 66.86 (66.39)

1.42e6 Q 549.00>79.95 (-)

f A=1033885
4.0e5HR1 66.86 (- rtfr =7.460

O.OeO

7.4
RT (min)

PFDA

Cone. 5.2478

R#1 512.90>219.00 18.62 (17.77)
Q 512.90>469.00 (-)	1.51e6

A=3569298
IR1 18.62 (-¦§•£1=7.494

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

f A=3082116
I RT=7.494

O.OeO

7.6 7.8
RT (min)

NMeFOSAA

Cone. 4.9831

R#1 570.20>512.00 38.86 (35.13)
Q 570.20>419.00 (-)	3.83e5

[A= 1152463

j]R1 38.86 (---|)RT=7.679
3.0e5 :

2.0e5 :

1.0e5:

O.OeO -

3.0e5

A=738666

: R1 5607 (" 1^T=7.803

7.25 7.50 7.75 8.00

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

4.76e5 Q 588.80>419.00 (-)

f A= 1153374
RT=7.858

O.OeO -

8.0 8.2
RT (min)

8-2-FTS

Cone. 4.2063

R#1 527.20>487.00 9.38 (7.71)

4.29e5 Q 527.10>506.90 (-)

A= 156980
6.0e4 R1 938 <" 'RT=7.490

RT (min)

1.30e6 Q 514.80>469.95 (-)

f A=3082116
RT=7.494

7.4 7.6 7.8
RT (min)

PFDS

Cone. 4.8303

R#1 599.00>99.00 56.07 (55.44)
Q 599.00>80.10 (-)	3.02e5

7.6 7.8
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

f A=2889617
RT=7.845

O.OeO

7.8 8.0

RT (min)

d5-N-EtFOSAA

Cone. 5.8841

4.76e5

O.OeO

7.8 8.0

RT (min)

NEtFOSAA

Cone. 4.5655

R#1 584.20>526.10 62.86 (56.68)
Q 584.20>418.95 (-)	3.59e5

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

: R1 62.86 (—

A=1040925
)RT=7.865

7.8 8.0

RT (min)

PFDoA

Cone. 5.0298

R#1 613.05> 169.00 17.79 (16.48)
Q 613.05>569.00 (-)	1.48e6

f A=3511131

1R1 17.79 (-4-^=8.184

7.50 7.75 8.00 8.25

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)
1.0e6-

1.09e6

A=2630290
RT=8.184

3.0 8.2 8.4

RT (min)

B.O 8.2 8.4

RT (min)

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CCV5-230504 (continued)

13C-PFDoA

Cone. 5.6746

Q614.80>569.95 (-)
1.0e6 -

NEtFOSE

Cone. 4.5846

Q 629.50>59.10 (-)
6.0e5 -

4.0e5 -

2.0e5 -

0.0e0 1	

rA= 1386842
RT=8.888

Q 515.10> 169.00 (-)

3.0e5 ~

2.0e5 i
^.0eSz_

O.OeO ^T-r-r

fA=901352
I RT=8.666

O.OeO -

8.6

L

d5-NEtFOSA IS

Cone. 5.0000

10-2-FtS

Cone. 2.6236
R#1 626.50>81.05 135.27 (72.12)

1.09e6 Q 626.50>607.05 (-)	3.45e4 ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 6.2105

4.55e5 Q 531.10> 169.10 (-)

NMeFOSE

Cone. 5.7404

4.55e5 Q 616.10>58.90 (-)

, A=85020
4.0e4>1 135

O.OeO -

A=1038704
RT=8.915



A=1038704
RT=8.915

3.2 8.4

RT (min)

8.0 8.2 8.4

RT (min)

d9-EtFOSE IS

Cone. 5.0000

3.8 9.0 9.2
RT (min)

O.OeO -



1.5e5-
^.0eSz_
5.0e4 ^
O.OeO -

A=438052
RT=8.643



d9-EtFOSE

Cone. 6.8761

ISTD 638.90> 59.10 (-)	1,22e5 Q 638.90> 59.10 (-)

i TA=Z

RT=<

8.8 9.0 9.2
RT (min)

NMeFOSA

Cone. 5.0097

R#1 512.10>219.20 73.77 (75.56)
Q 512.10> 169.20 (-)	1.93e5

8.4 8.6 8.8 9.0
RT (min)

d3-NMeFOSA IS

Cone. 5.0000

280148
RT=8.870

IA=2

RT=.

280148
8.870

f A=464030

HR1 73.77 (--t)rt=8.671

8.6 8.8 9.0 9.2

RT (min)

d3-NMeFOSA

Cone. 6.0095

V—i

1.5e5-
^.0eSz
5.0e4z
O.OeO -

ISTD 515.10> 169.00 (-)

3.0e5 ~

2.0e5 i
^.0eSz_

O.OeO 1, i i 7

3.70e5

RT (min)

RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 5.4911

3.70e5

8.4 8.6 8.8 9.0

RT (min)

NEtFOSA

Cone. 4.7918

R#1 526.50>219.20 60.64(61.76)
Q 526.50> 169.10 (-)	3.15e5

f A=719100
)RT=8.924

8.6 8.8

RT (min)

PFTeDA

Cone. 8.3997

R#1 713.00>169.30 16.27 (12.52)
Q 713.00>668.90 (-)	1.10e6

JTA=2658269
1.0e6 —|R1 16.27 (-4kr=8.791

8.6 8.8

RT (min)

PFTrDA

Cone. 8.3872

R#1 663.10> 169.10 26.87 (21.32)
Q 663.10>618.90 (-)	1.21e6

fA=2733815

HR1 2687 ("jyfeT=8.500

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

13C-PFTeDA

Cone. 2.8155

8.6 8.8 9.0 9.2
RT (min)	RT (min)

11CI-PF30UdS

Cone. 4.7296

RT (min)

9CI-PF30NS

Cone. 4.0336

2.58e5 Q 714.80>669.80 (-)

2.58e5 Q 631.00>451.10 (-)

5.14e5

~

A=638326



RT=8.791

I



O.OeO -

9.0
RT (min)

L-PFDoS

Cone. 4.9387

R#1 698.80 >98.80 63.81 (62.67)
Q 698.80>80.10 (-)	1.47e5

[A=326983
IR1 63.81 (--|-[^T=8.449

9.0

RT (min)

NaDONA

Cone. 5.1272

Q 377.10>251.20 (-)

1.5e6 ^

1.0e6 ^

5.0e5 ^

O.OeO 1 . .

8.6 8.8 9.0

RT (min)

PFHxDA

Cone. 1.6423

1.82e6 Q 812.90>769.00 (-)

1.90e5

rA=3832139
RT=6.559

rA=418158
I RT=9.299

1.5e5 -
1.0e5-j
5.0e4 :
O.OeO :



RT (min)

6.6 6.8

RT (min)

9.2 9.4 9.6
RT (min)

9.8 10.0

RT (min)

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CCV5-230504 (continued)

13C2-PFHxDA

Cone. 5.6481

Q 815.00>770.00 (-)
3.0e6 -i

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 5.3164

PFecHS

Cone. 4.3176
R#1 461.00>99.10 42.27 (38.58)

8.25e5 Q 461.00>381.00 (-)	1.62e6 Q 298.00>78.00 (-)

A=3666749

1.5e6 H *1 42.27 (-4 rt=6.775

PFHxSA

Cone. 5.0949

1.18e6 Q 397.90>78.00 (-)

9.4 9.6
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	1.00e0

5.0e0 -

RT (min)

0.2
RT (min)

6.6
RT (min)

A=2159063
RT=7.121

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

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Quantitation/lntegration
Printed 10/25/2023 16:02:16

CCV6-230504

Sample ID: CCV6-230504

Date Acquired: 5/5/2023 7:52:06 AM

Acquired by: System Administrator

Data File: 230504139

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.382

1276338

1276338

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.382

1276338

2089912

13C7-PFUnDA IS

5.0000

5.7716

nq/mL

PFBA

Auto

4.383

1474512

1276338

13C-PFBA IS

5.0000

4.8719

nq/mL

13C-PFPeA IS

Auto

5.555

2175981

2175981

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.555

2175981

2089912

13C7-PFUnDA IS

5.0000

5.5545

nq/mL

PFPeA

Auto

5.555

2202087

2175981

13C-PFPeA IS

5.0000

5.1777

nq/mL

13C-PFBS IS

Auto

5.677

799552

799552

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.677

799552

2089912

13C7-PFUnDA IS

4.6500

5.1198

nq/mL

PFBS

Auto

5.678

661136

799552

13C-PFBS IS

4.4200

4.6554

nc

13C HFPO DA IS

Auto

6.268

577136

577136

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.268

577136

2089912

13C7-PFUnDA IS

5.0000

5.4588

nc

HFPO DA

Auto

6.269

530655

577136

13C HFPO DA IS

5.0000

5.3822

nq/mL

13C-4 2-FTS IS

Auto

6.075

353123

353123

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

6.075

353123

2089912

13C7-PFUnDA IS

4.6700

5.6808

nq/mL

4-2-FtS

Auto

6.075

405011

353123

13C-4 2-FTS IS

4.6700

4.4807

nq/mL

PFHxA

Auto

6.127

4519615

3034395

13C-PFHxA IS

5.0000

5.0565

nq/mL

13C-PFHxA IS

Auto

6.127

3034395

3034395

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

6.127

3034395

2089912

13C7-PFUnDA IS

5.0000

5.7297

nq/mL

PFPeS

Auto

6.163

661603

801682

180-PFHxS IS

4.6900

5.0078

nq/mL

PFHxS

Auto

6.522

536880

801682

180-PFHxS IS

4.5500

4.7100

nq/mL

13C-PFHpA IS

Auto

6.520

2955273

2955273

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.520

2955273

2089912

13C7-PFUnDA IS

5.0000

5.5584

nq/mL

180-PFHxS IS

Auto

6.523

801682

801682

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.523

801682

2089912

13C7-PFUnDA IS

4.7250

5.0997

nq/mL

PFHpA

Auto

6.520

4861539

2955273

13C-PFHpA IS

5.0000

5.2569

nq/mL

13C2-6 2-FTS IS

Auto

6.813

342433

342433

	

4.7500

4.7500

nq/mL

13C2-6 2-FTS

Auto

6.813

342433

2089912

13C7-PFUnDA IS

4.7500

5.2976

nq/mL

PFHpS

Auto

6.819

619002

801682

180-PFHxS IS

4.7600

4.9757

nq/mL

6-2-FTS

Auto

6.813

347504

342433

13C2-6 2-FTS IS

4.7400

4.7566

nq/mL

PFOA

Auto

6.831

5265734

3318252

13C-PFOA IS

5.0000

5.1341

nq/mL

13C-PFOA IS

Auto

6.830

3318252

3318252

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.830

3318252

2089912

13C7-PFUnDA IS

5.0000

5.6567

nq/mL

PFOS

Auto

7.129

450041

773967

13C-PFOS IS

4.6400

4.5339

nq/mL

13C-PFOS IS

Auto

7.129

773967

773967

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

7.129

773967

2089912

13C7-PFUnDA IS

4.7750

5.4387

nq/mL

PFNA

Auto

7.153

3497896

3207225

13C-PFNA IS

5.0000

4.4596

nq/mL

13C-PFNA IS

Auto

7.153

3207225

3207225

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.153

3207225

2089912

13C7-PFUnDA IS

5.0000

5.8352

nq/mL

PFNS

Auto

7.464

1023077

773967

13C-PFOS IS

4.8000

4.7511

nq/mL

8-2-FTS

Auto

7.494

158753

142611

13C-8 2-FTS IS

4.7900

4.2657

nq/mL

13C-8 2-FTS IS

Auto

7.493

142611

142611

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.493

142611

2089912

13C7-PFUnDA IS

4.7900

5.5333

nq/mL

PFDA

Auto

7.498

3569173

3140440

13C-PFDA IS

5.0000

5.1502

nq/mL

13C-PFDA IS

Auto

7.498

3140440

3140440

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.498

3140440

2089912

13C7-PFUnDA IS

5.0000

5.3761

nq/mL

d3-N-MeFOSAA IS

Auto

7.679

1042908

1042908

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.679

1042908

2089912

13C7-PFUnDA IS

5.0000

5.6832

nq/mL

NMeFOSAA

Auto

7.684

1156114

1042908

d3-N-MeFOSAA IS

5.0000

4.8987

nq/mL

PFDS

Auto

7.808

686433

773967

13C-PFOS IS

4.8200

4.6538

nq/mL

13C-PFUnDA IS

Auto

7.850

2992788

2992788

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.850

2992788

2089912

13C7-PFUnDA IS

5.0000

5.5806

nq/mL

PFUnDA

Auto

7.850

2724326

2992788

13C-PFUnDA IS

5.0000

4.4055

nq/mL

d5-N-EtFOSAA IS

Auto

7.864

1163063

1163063

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.864

1163063

2089912

13C7-PFUnDA IS

5.0000

5.6081

nq/mL

NEtFOSAA

Auto

7.871

996473

1163063

dS-N-EtFOSAA IS

5.0000

4.3341

nq/mL

PFOSA

Auto

7.915

1035698

849203

13C-FOSA IS

5.0000

5.0088

nq/mL

13C-FOSA IS

Auto

7.915

849203

849203

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.915

849203

2089912

13C7-PFUnDA IS

5.0000

5.3629

nq/mL

PFDoA

Auto

8.188

3529456

2602902

13C-PFDoA IS

5.0000

5.1092

nq/mL

13C-PFDoA IS

Auto

8.188

2602902

2602902

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

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A

<^LS^

Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:16

CCV6-230504 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.188

2602902

2089912

13C7-PFUnDA IS

5.0000

5.3076

nq/mL

10-2-FtS

Auto

8.199

70800

142611

13C-8 2-FTS IS

4.8200

2.1909

ng/mL

d5-NEtFOSA IS

Auto

8.918

1032504

1032504

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.918

1032504

2089912

13C7-PFUnDA IS

5.0000

5.8349

ng/mL

NMeFOSE

Auto

8.648

417990

383920

d7-N-MeFOSE IS

5.0000

5.7420

nq/mL

NEtFOSE

Auto

8.891

1365697

281508

d9-EtFOSE IS

5.0000

4.4929

ng/mL

d9-EtFOSE IS

Auto

8.874

281508

281508

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.874

281508

2089912

13C7-PFUnDA IS

5.0000

6.5306

ng/mL

NMeFOSA

Auto

8.675

465493

883665

d3-NMeFOSA IS

5.0000

5.1260

nq/mL

dB-NMeFOSA IS

Auto

8.671

883665

883665

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.671

883665

2089912

13C7-PFUnDA IS

5.0000

5.5684

nq/mL

d7-N-MeFOSE IS

Auto

8.633

383920

383920

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.633

383920

2089912

13C7-PFUnDA IS

5.0000

4.9509

nq/mL

NEtFOSA

Auto

8.927

703674

1032504

d5-NEtFOSA IS

5.0000

4.7172

ng/mL

PFTrDA

Auto

8.505

2644013

477129

13C-PFTeDA IS

5.0000

10.8522

nq/mL

PFTeDA

Auto

8.795

2621406

477129

13C-PFTeDA IS

5.0000

11.0816

ng/mL

13C-PFTeDA IS

Auto

8.796

477129

477129

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.796

477129

2089912

13C7-PFUnDA IS

5.0000

1.9891

ng/mL

11CI-PFBOUdS

Auto

7.999

1198192

773967

13C-PFOS IS

4.7100

4.8588

nq/mL

9CI-PF30NS

Auto

7.316

1904684

773967

13C-PFOS IS

4.6600

4.1797

ng/mL

L-PFDoS

Auto

8.454

332840

773967

13C-PFOS IS

4.8400

5.2120

nq/mL

NaDONA

Auto

6.562

3796087

3207225

13C-PFNA IS

4.7100

5.0407

ng/mL

PFHxDA

Auto

9.303

339445

5410962

13C2-PFHxDA IS

5.0000

1.3734

nq/mL

PFODA

Auto

9.898

331422

5410962

13C2-PFHxDA IS

5.0000

1.6407

ng/mL

13C2-PFHxDA IS

Auto

9.303

5410962

5410962

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.303

5410962

2089912

13C7-PFUnDA IS

5.0000

5.1507

ng/mL

13C7-PFUnDA IS

Auto

7.850

2089912

2089912

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.779

3637026

773967

13C-PFOS IS

4.6100

4.4401

ng/mL

PFBSA

Auto

6.314

2629322

849203

13C-FOSA IS

5.0000

5.3951

nq/mL

PFHxSA

Auto

7.124

2159673

3207225

13C-PFNA IS

5.0000

5.0580

ng/mL

CHARGE

ND(W/B)

	

	

2089912

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 5.7716
2.80e5 Q 217.20>172.30 (-)

PFBA

Cone. 4.8719
2.80e5 Q 213.20> 169.10 (-)

A= 1474512
3.0e5 - RT=4.383

13C-PFPeA IS

Cone. 5.0000
3.30e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 5.5545
7.71 e5 Q 267.90>223.00 (-)

f A=2175981
I RT= 5.555

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

5.4

=F
5.6

RT (min)

RT (min)

PFPeA

Cone. 5.1777

13C-PFBS IS

Cone. 4.6500

13C-PFBS

Cone. 5.1198

13C HFPO DA IS

Cone. 5.0000

Q263.05>219.10 (-)	7.82e5 ISTD 301.80>80.00 (-)	2.90e5 Q 301.80>80.00 (-)

fA=2202087	fA=799552	fA=799552

7.5e5 :

5.0e5 ^

2.5e5 :

O.OeO -

5.8

RT (min)

5.8

RT (min)	RT (min)

PFBS

Cone. 4.6554
R#1 298.80>99.00 71.70 (71.09)

2.90e5 Q 299.00>80.00 (-)	2.41 e5 ISTD 332.10>287.10 (-)

f A=661136
JR1 71.70 (jUt=5.678

6.0
RT (min)

6.4 6.6
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

23®

-------


Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:16

CCV6-230504 (continued)

13C HFPO DA

Cone. 5.4588

Q 332.10>287.10 (-)

O.OeO -

HFPO DA

Cone. 5.3822

R#1 329.00>285.10 90.28 (79.97)
2.51 e5 Q 329.00> 169.00 (-)	2.29e5

1A= 530655
RT=6.269

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00 >81.00 26.16 (26.74)

ISTD 329.00>309.15 (-)	1,50e5

O.OeO -



1.5e5 -
1.0e5-j
5.0e4 :
O.OeO -

fA=353123

:R1 26.16 (i-R)r=6.075

6.2

6.2

13C-PFHxA IS

Cone. 5.0000

6.4 6.6
RT (min)

PFHxA

Cone. 5.0565
R#1 313.00> 119.10 2.74 (2.85)

Q 313.00 > 269.00 (-)	1.91 e6 I STD 314.90 > 270.10 (-)

fA=4519615

= R1 274(-i-kT=6.127

6.4 6.6
RT (min)

13C-PFHxA

Cone. 5.7297

1.27e6 Q 314.90>270.10 (-)

6.4
RT (min)

13C-PFHpA IS

Cone. 5.0000

I STD 366.90 >322.10 (-)

13C-PFHpA

Cone. 5.5584

1.33e6 Q 366.90>322.10 (-)

180-PFHxS IS

Cone. 4.7250

1.33e6 I STD 402.70>84.05 (-)

f A=2955273
| RT=6.520

6.6 6.8
RT (min)

13C2-6 2-FTS IS

Cone. 4.7500

13C2-6 2-FTS

Cone. 5.2976

I STD 428.90>409.00 (-)
1.5e5 -

A=342433
RT=6.813

1.0e5 -
5.0e4 :
O.OeO :

1.56e5 Q 428.90>409.00 (-)
1.5e5 -
1.0e5-j
5.0e4 ^

O.OeO 1 . . .

RT (min)

A=342433
RT=6.813

: R1 67.65 (-

O.OeO -

A=619002
RT=6.819

L

7.0
RT (min)

7.0
RT (min)

6.6

6.8

13C-PFOA IS

Cone. 5.0000

I STD 416.80 >372.05 (-)

13C-PFOA

Cone. 5.6567

1.46e6 Q 416.80>372.05 (-)

rA=3318252
RT=6.830

rA=3318252
I RT=6.830

13C-4 2-FTS

Cone. 5.6808

R#1 329.00>81.00 26.16 (26.74)
Q 329.00>309.15 (-)	1.50e5

A=353123

6.2 6.4
RT (min)



6.2 6.4

RT (min)

180-PFHxS

Cone. 5.0997

3.52e5 Q 402.70>84.05 (-)

A=801682
RT=6.523

i



6.6 6.8
RT (min)

PFHpS

Cone. 4.9757

R#1 449.00>99.20 67.65 (66.82)
Q 449.00>80.15 (-)	2.77e5

1.5e5-
1.0e5^
5.0e4 -j
O.OeO -

fA=347504
R1 27.44 (4^=6.813

7.0
RT (min)

PFOS

Cone. 4.5339

R#1 499.00>99.00 97.91 (93.96)
Q 499.00>80.00 (-)	1.44e5

f A=450041

13C-PFOS IS

Cone. 4.7750

105 (-)

IR1 97.91 (—

)RT=7.129

3.0e5 ^





2.0e5 ^





1.0e5-

: _aj

L ~

- O.OeO--

A=773967
RT=7.129

RT (min)

RT (min)

6.75 7.00 7.25 7.50

RT (min)

4-2-FtS

Cone. 4.4807

R#1 327.00 >81.10 16.93 (16.29)
Q 327.00>307.05 (-)	1.74e5

fA=405011
:R1 16.93 (-|-|^r=6.075

6.2 6.4
RT (min)

PFPeS

Cone. 5.0078

R#1 349.00>99.00 77.49 (74.42)
Q 349.00>79.95 (-)	2.80e5

f A=661603

JR1 77.49 (-1-^r=6.163

6.0 6.2 6.4
RT (min)

PFHxS

Cone. 4.7100

R#1 399.00>99.00 100.16 (95.46)
Q 399.00>80.00 (-)	1.92e5

f A= 536880

^R1 100.16 (-|-^t=6.522
1.5e5-z

^.0eSz

5.0e4z_

O.OeO -

6.4

RT (min)

6.25 6.50 6.75 7.00
RT (min)

PFHpA

Cone. 5.2569

R#1 362.90>169.00 17.40 (17.56)
Q 362.90>319.00 (-)	2.20e6

fA=4861539

2.0e6-|R1 17.40 ( I-^j=6.520

6.4 6.6 6.8
RT (min)

6-2-FTS

Cone. 4.7566

R#1 427.00>80.90 27.44 (28.57)
Q 427.00>407.00 (-)	1.55e5

7.0
RT (min)

O.OeO

6.6 6.8
RT (min)

PFOA

Cone. 5.1341

R#1 413.00> 169.10 29.19 (28.52)
Q 413.00>369.00 (-)	2.34e6

f A= 5265734
1R1 29.19 (--|-kT=6.831

n "	 mkw

O.OeO -fcpF, i i i A,

6.6 6.8 7.0 7.2

RT (min)

13C-PFOS

Cone. 5.4387

3.44e5 Q 502.80>80.05 (-)

3.44e5

A=773967
RT=7.129

7.2 7.4
RT (min)

7.2 7.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

332

-------


Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:16

CCV6-230504 (continued)

PFNA

Cone. 4.4596

R#1 463.00>219.00 24.91 (21.80)
Q 463.00>418.90 (-)	1.56e6

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 5.8352

1.45e6 Q 467.80>423.00 (-)

1.5e6 -
1.0e6:
5.0e5 :
O.OeO :

R1 24.91 (--

f A=3497896
RT=7.153

Ll

7.0 7.2 7.4

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

13C-8 2-FTS

Cone. 5.5333

ISTD 528.80>509.00 (-)
6.0e4 -i

6.02e4 Q 528.80> 509.00 (-)

A= 142611
RT=7.493

RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

d3-N-MeFOSAA

Cone. 5.6832

ISTD 572.80>419.05 (-)
4.0e5

A=1042908
RT=7.679

4.00e5 Q 572.80>419.05 (-)
4.0e5

O.OeO -

A=1042908
RT=7.679

13C-PFUnDA

Cone. 5.5806

Q 564.80>519.95 (-)

7.8 8.0
RT (min)

A=2992788
RT=7.850

7.6

O.OeO

7.8 8.0

RT (min)

PFOSA

Cone. 5.0088

R#1 498.20>64.10 0.19 (0.10)
Q 498.20>78.00 (-)	4.40e5

k=1035698

Ik

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

4.0e5 -

R1 0.19 (—-

	

RT=7.915





3.0e5 :





2.0e5 :

2.0e5 -



;

O.OeO -

J

1.0e5 :

	 (1 OpO :

A=849203
RT=7.915

L

7.6 7.8 8.0 8.2

RT (min)

O.OeO -

7.4
RT (min)

7.0

7.2

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

7.8 8.0
RT (min)

PFUnDA

Cone. 4.4055

R#1 563.00>219.00 16.85 (14.10)
Q563.00>518.90 (-)	1.15e6

fA=2724326
1.0e6 —IR1 1685 ("|"^T=7.850

ISTD 588.80>419.00 (-)

A= 1163063
RT=7.864

V-T

RT (min)

RT (min)

13C-FOSA

Cone. 5.3629

3.66e5 Q 506.00>78.05 (-)

3.0e5 i
2.0e5 i
1.0e5z_

O.OeO 1. . . .

A=849203
RT=7.915

L

8.0 8.2
RT (min)

PFNS

Cone. 4.7511

R#1 549.00 >99.00 70.14 (66.39)

1.45e6 Q 549.00>79.95 (-)

f A=1023077

4.0e5jR1 70.14(4^t=7.464

7.4
RT (min)

PFDA

Cone. 5.1502

R#1 512.90>219.00 18.65 (17.77)
Q 512.90>469.00 (-)	1.50e6

[A=3569173

;R1 18.65 (-4 rj=7.498

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

fA=3140440
RT=7.498

7.4 7.6 7.8
RT (min)

NMeFOSAA

Cone. 4.8987

R#1 570.20>512.00 38.81 (35.13)
Q 570.20>419.00 (-)	3.82e5

f A=1156114

dR1 38.81 (- )rT=7.684

7.25 7.50 7.75 8.00

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

4.83e5 Q 588.80>419.00 (-)

fA= 1163063
I RT=7.864

7.8 8.0 8.2
RT (min)

1.5e6-
1.0e6^
5.0e5 ^
O.OeO :

=3529456

;R1 17.99 (-

RT=8.188

^ i



8-2-FTS

Cone. 4.2657

R#1 527.20>487.00 9.00 (7.71)

4.28e5 Q 527.10>506.90 (-)

4.0e4 -
2.0e4 7
O.OeO :



A= 158753

: R1 9.00 (—

)RT=7.494



Vv

RT (min)

7.6 7.8
RT (min)

13C-PFDA

Cone. 5.3761

1.32e6 Q 514.80>469.95 (-)

fA=3140440
I RT=7.498

O.OeO

7.6 7.8
RT (min)

PFDS

Cone. 4.6538

R#1 599.00>99.00 55.79 (55.44)
Q 599.00>80.10 (-)	2.88e5

f A=686433

HR1 55-79 ("| ^T=7.8

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)	1.25e6

A=

RT=7.850

1.0e6-

O.OeO

7.8 8.0

RT (min)

d5-N-EtFOSAA

Cone. 5.6081

O.OeO -

^=F



4.83e5

7.8 8.0

RT (min)

NEtFOSAA

Cone. 4.3341

R#1 584.20>526.10 63.83 (56.68)
Q 584.20>418.95 (-)	3.46e5

; R1 63.83 (—

O.OeO

7.8 8.0

RT (min)

PFDoA

Cone. 5.1092

R#1 613.05> 169.00 17.99 (16.48)
Q 613.05>569.00 (-)	1.51e6

/^aJ.

A=996473
|)RT=7.871

7.50 7.75 8.00 8.25

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)
1.0e6-

1.10e6

A=2602902
RT=8.188

B.2 8.4

RT (min)

B.O 8.2 8.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

333

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:16

CCV6-230504 (continued)

13C-PFDoA

Cone. 5.3076

Q614.80>569.95 (-)
1.0e6 -

10-2-FtS

Cone. 2.1909

R#1 626.50>81.05 152.07 (72.12)
Q 626.50>607.05 (-)	2.86e4

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)
4.0e5

2.0e5 -



|TA= 1032504

:

RT=8.918

I



3.2 8.4

RT (min)

NEtFOSE

Cone. 4.4929

Q 629.50>59.10 (-)

TA= 1365697
RT=8.891

O.OeO -



Vj

Q 515.10> 169.00 (-)

3.0e5 i
2.0e5 i
^.0eSz
O.OeO 1, i i

fA=883665
RT=8.671

O.OeO -

8.6

2 8.4

RT (min)

3.8 9.0 9.2
RT (min)

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 6.5306

5.94e5 ISTD 638.90>59.10 (-)

1.21e5 Q 638.90> 59.10 (-)

A=281508
RT=8.874

IA=2

' RT=,

Li

281508
RT=8.874

Li

8.6 8.8 9.0 9.2

RT (min)

d3-NMeFOSA

Cone. 5.5684

RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

d7-N-MeFOSE

Cone. 4.9509

3.67e5

8.6 8.8

RT (min)

PFTeDA

Cone. 11.0816

R#1 713.00>169.30 16.08 (12.52)
Q 713.00>668.90 (-)	1.09e6

fA=2621406

1.0e6-|R1 16.08 (~tt)RT=8.795

RT (min)

13C-PFTeDA IS

Cone. 5.0000

ISTD 714.80>669.80 (-)

1.5e5 -
1.0e5-j
5.0e4 :
O.OeO :

13C-PFTeDA

Cone. 1.9891

1.91e5 Q714.80>669.80 (-)



f A=477129



fA=477129

-

RT=8.796



RT=8.796



1.5e5 -







-\.0e5z_

I



-

5.0e4 -





: /

	 nnpn-



V-T

9.0
RT (min)

L-PFDoS

Cone. 5.2120

R#1 698.80 >98.80 61.83 (62.67)
Q 698.80>80.10 (-)	1.45e5

f A=332840

IR1 61.83 (--f"kT=8.454

9.0

RT (min)

NaDONA

Cone. 5.0407

Q 377.10>251.20 (-)

1.5e6 ^

1.0e6 ^

5.0e5 ^

O.OeO 1 . .

fA=3796087
I RT=6.562

PFHxDA

Cone. 1.3734

Q 812.90>769.00 (-)
1.5e5 -
1.0e5 ^

5.0e4 -j

O.OeO 1-. . . 7.

A=339445
RT=9.303



RT (min)

6.8

RT (min)

d5-NEtFOSA

Cone. 5.8349

Q 531.10> 169.10 (-)
4.0e5

2.0e5 -

O.OeO

:

RT=8.918

I



8.8 9.0 9.2
RT (min)

NMeFOSA

Cone. 5.1260

R#1 512.10>219.20 70.94(75.56)
Q 512.10> 169.20 (-)	1.91e5

/ A=465493

1 R1 70.94 (— )rj=8.675

NMeFOSE

Cone. 5.7420

4.47e5 Q 616.10> 58.90 (-)

^.SeSz
1.0e5~

S.0e4z_

O.OeO 1.~. . . :;

IA=4

RT=.

417990
8.648



8.4 8.6 8.8 9.0
RT (min)

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

TA=8

! RT=.

3.67e5

1.5e5-
^.0eSz
5.0e4z
O.OeO -

3.0e5 :
2.0e5 :
1.0e5:
O.OeO :

883665
8.671

L

RT (min)

3.0e5 -

8.4 8.6 8.8 9.0

RT (min)

NEtFOSA

Cone. 4.7172

R#1 526.50>219.20 62.66 (61.76)
Q 526.50> 169.10 (-)	3.05e5

8.6

RT (min)

PFTrDA

Cone. 10.8522

R#1 663.10> 169.10 27.25 (21.32)
Q 663.10>618.90 (-)	1.17e6

TA=703674

R1 62.66 (—

)RT=8.927

" R1 27.25 (--

Lr

RT (min)

8.6 8.8 9.0 9.2

RT (min)

11CI-PF30UdS

Cone. 4.8588

A=2644013
kT=8.505

RT (min)

9CI-PF30NS

Cone. 4.1797

1.91e5 Q 631.00>451.10 (-)

5.08e5

9.0

RT (min)

O.OeO

7.8 8.0 8.2

RT (min)

PFODA

Cone. 1.6407

7.4 7.6
RT (min)

13C2-PFHxDA IS

Cone. 5.0000

1.57e5 Q 912.80>869.00 (-)	1.15e5 ISTD 815.00>770.00 (-)

A= 5410962
RT=9.303



9.4 9.6
RT (min)

9.8 10.0

RT (min)

9.4 9.6
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

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CCV6-230504 (continued)

13C2-PFHxDA

Cone. 5.1507

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

2.86e6 ISTD 569.80>524.90 (-)

PFecHS	PFBSA

Cone. 4.4401	Cone. 5.3951
R#1 461.00>99.10 40.88 (38.58)

8.82e5 Q 461.00>381.00 (-)	1.57e6	Q 298.00>78.00 (-)

PFHxSA

Cone. 5.0580

1.08e6 Q 397.90>78.00 (-)

A= 5410962
RT=9.303



CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)
Q 514.80 > 219.10 (+)

5.0e0 -

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

9.4 9.6
RT (min)

0.2
RT (min)

Tp"

RT (min)

f A=2629322
RT=6.314

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

6.6
RT (min)

7.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:20

CCV6-230504

Sample ID: CCV6-230504

Date Acquired: 5/5/2023 8:05:51 AM

Acquired by: System Administrator

Data File: 230504140

Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5

Name

Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone.

Cone. Unit

1BC-PFBA IS

Auto

4.381

1376778

1376778

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.381

1376778

	

13C7-PFUnDA IS

5.0000

ISTD Error

ng/mL

PFBA

Auto

4.382

1509734

1376778

13C-PFBA IS

5.0000

4.6255

nq/mL

13C-PFPeA IS

Auto

5.554

2218362

2218362

	

5.0000

5.0000

ng/mL

13C-PFPeA

Auto

5.554

2218362

—

13C7-PFUnDA IS

5.0000

ISTD Error

nq/mL

PFPeA

Auto

5.555

2250432

2218362

13C-PFPeA IS

5.0000

5.1903

ng/mL

1BC-PFBS IS

Auto

5.677

795850

795850

—

4.6500

4.6500

nq/mL

1BC-PFBS

Auto

5.677

795850

	

13C7-PFUnDA IS

4.6500

ISTD Error

ng/mL

PFBS

Auto

5.677

660316

795850

13C-PFBS IS

4.4200

4.6712

nq/mL

1BC HFPO DA IS

ND(W/B)

	

	

	

	

5.0000

	

ng/mL

13C HFPO DA

ND(W/B)

	

—

	

13C7-PFUnDA IS

5.0000

ISTD Error

nq/mL

HFPO DA

ND(W/B)

	

	

	

13C HFPO DA IS

5.0000

ISTD Error

ng/mL

1BC-4 2-FTS IS

ND(W/B)

	

—

	

	

4.6700

—

nq/mL

13C-4 2-FTS

ND(W/B)

	

	

	

13C7-PFUnDA IS

4.6700

ISTD Error

ng/mL

4-2-FtS

ND(W/B)

	

—

	

13C-4 2-FTS IS

4.6700

ISTD Error

nq/mL

PFHxA

ND(W/B)

	

	

	

13C-PFHxA IS

5.0000

ISTD Error

ng/mL

1 BC-PFHxA IS

ND(W/B)

	

—

	

	

5.0000

—

nq/mL

13C-PFHxA

ND(W/B)

	

	

	

13C7-PFUnDA IS

5.0000

ISTD Error

ng/mL

PFPeS

ND(W/B)

	

—

	

180-PFHxS IS

4.6900

ISTD Error

nq/mL

PFHxS

ND(W/B)

	

	

	

180-PFHxS IS

4.5500

ISTD Error

ng/mL

13C-PFHpA IS

ND(W/B)

	

—

	

—

5.0000

—

nq/mL

13C-PFHpA

ND(W/B)

	

	

	

13C7-PFUnDA IS

5.0000

ISTD Error

ng/mL

180-PFHxS IS

ND(W/B)

	

—

	

—

4.7250

—

nq/mL

180-PFHxS

ND(W/B)

	

	

	

13C7-PFUnDA IS

4.7250

ISTD Error

ng/mL

PFHpA

ND(W/B)

	

—

	

13C-PFHpA IS

5.0000

ISTD Error

nq/mL

13C2-6 2-FTS IS

ND(W/B)

	

	

	

	

4.7500

	

ng/mL

13C2-6 2-FTS

ND(W/B)

	

—

	

13C7-PFUnDA IS

4.7500

ISTD Error

nq/mL

PFHpS

ND(W/B)

	

	

	

180-PFHxS IS

4.7600

ISTD Error

ng/mL

6-2-FTS

ND(W/B)

	

—

	

13C2-6 2-FTS IS

4.7400

ISTD Error

nq/mL

PFOA

ND(W/B)

	

	

	

13C-PFOA IS

5.0000

ISTD Error

ng/mL

13C-PFOA IS

ND(W/B)

	

—

	

—

5.0000

—

nq/mL

13C-PFOA

ND(W/B)

	

	

	

13C7-PFUnDA IS

5.0000

ISTD Error

ng/mL

PFOS

ND(W/B)

	

	

	

13C-PFOS IS

4.6400

ISTD Error

nq/mL

13C-PFOS IS

ND(W/B)

	

	

	

	

4.7750

	

ng/mL

13C-PFOS

ND(W/B)

	

—

	

13C7-PFUnDA IS

4.7750

ISTD Error

nq/mL

PFNA

ND(W/B)

	

	

	

13C-PFNA IS

5.0000

ISTD Error

ng/mL

13C-PFNA IS

ND(W/B)

	

—

	

	

5.0000

—

nq/mL

13C-PFNA

ND(W/B)

	

	

	

13C7-PFUnDA IS

5.0000

ISTD Error

ng/mL

PFNS

ND(W/B)

	

—

	

13C-PFOS IS

4.8000

ISTD Error

nq/mL

8-2-FTS

ND(W/B)

	

	

	

13C-8 2-FTS IS

4.7900

ISTD Error

ng/mL

13C-8 2-FTS IS

ND(W/B)

	

—

	

—

4.7900

—

nq/mL

13C-8 2-FTS

ND(W/B)

	

	

	

13C7-PFUnDA IS

4.7900

ISTD Error

ng/mL

PFDA

ND(W/B)

	

	

	

13C-PFDA IS

5.0000

ISTD Error

nq/mL

13C-PFDA IS

ND(W/B)

	

	

	

	

5.0000

	

ng/mL

13C-PFDA

ND(W/B)

	

	

	

13C7-PFUnDA IS

5.0000

ISTD Error

nq/mL

d3-N-MeFOSAA IS

ND(W/B)

	

	

	

	

5.0000

	

ng/mL

d3-N-MeFOSAA

ND(W/B)

	

	

	

13C7-PFUnDA IS

5.0000

ISTD Error

nq/mL

NMeFOSAA

ND(W/B)

	

	

	

d3-N-MeFOSAA IS

5.0000

ISTD Error

ng/mL

PFDS

ND(W/B)

	

	

	

13C-PFOS IS

4.8200

ISTD Error

nq/mL

13C-PFUnDA IS

ND(W/B)

	

	

	

	

5.0000

	

ng/mL

13C-PFUnDA

ND(W/B)

	

	

	

13C7-PFUnDA IS

5.0000

ISTD Error

nq/mL

PFUnDA

ND(W/B)

	

	

	

13C-PFUnDA IS

5.0000

ISTD Error

ng/mL

d5-N-EtFOSAA IS

ND(W/B)

	

	

	

	

5.0000

	

nq/mL

d5-N-EtFOSAA

ND(W/B)

	

	

	

13C7-PFUnDA IS

5.0000

ISTD Error

ng/mL

NEtFOSAA

ND(W/B)

	

	

	

d5-N-EtFOSAA IS

5.0000

ISTD Error

nq/mL

PFOSA

ND(W/B)

	

	

	

13C-FOSA IS

5.0000

ISTD Error

ng/mL

13C-FOSA IS

ND(W/B)

	

	

	

	

5.0000

	

nq/mL

13C-FOSA

ND(W/B)

	

	

	

13C7-PFUnDA IS

5.0000

ISTD Error

ng/mL

PFDoA

ND(W/B)

	

	

	

13C-PFDoA IS

5.0000

ISTD Error

nq/mL

13C-PFDoA IS

ND(W/B)

	

	

	

	

5.0000

	

ng/mL

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

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CCV6-230504 (continued)









(Table continued from previous page)









Name

Mode ID Found RT

Area ISTD Area ISTD Name

Std. Cone.

Cone.

Unit

13C-PFDoA

NDfW, "

13C7-PFUrtDAJS

-

ISTD Error

ng/mL

10-2-FtS

ND(W/B)

	 13C-8 2-FTS IS

4.8200

ISTD Error

ng/mL

dS-NEtFOSA IS

ND(W/B)

—- —-

5.0000

—-

ng/mL

d5-NEtFOSA

ND(W/B)

____ 13C7-PFUnDA IS

5.0000

ISTD Error

ng/mL

NMeFOSE

ND(W/B)

d7-N-MeFOSE IS

5.0000

ISTD Error

ng/mL

NEtFOSE

ND(W/B)

____ d9-EtFOSE_IS

5.0000

ISTD Error

ng/mL

d9-EtFOSE IS

NDfW, ~

				

5.0000

	

ng/mL

d9-EtFOSE

ND(W/B)

____ 13C7-PFUnDA IS

5.0000

ISTD Error

ng/mL

NMeFOSA

N DfW/B)

d3-NMeFOSAJS

5.0000

ISTD Error

ng/mL

dB-NMeFOSA IS

ND(W/B)

	 ----

5.0000



ng/mL

d3-NMeFOSA

NDfW, ~

13C7-PFUnDAJS

5.0000

ISTD Error

ng/mL

d7-N-MeFOSE IS

ND(W/B)

	 ----

5.0000



ng/mL

d7-N-MeFOSE

N DfW/B!

13C7-PFUnDAJS

5.0000

ISTD Error

ng/mL

NEtFOSA

ND(W/B)

	 d5-NEtFOSA IS

5.0000

ISTD Error

ng/mL

PFTrDA

N DfW/B)

13C-PFTeDA IS

5.0000

ISTD Error

ng/mL

PFTeDA

ND(W/B)

____ 13C-PFTeDA IS

5.0000

ISTD Error

ng/mL

13C-PFTeDA IS

ND(W/B)

	 	 	

5.0000

	

ng/mL

13C-PFTeDA

ND(W/B)

____ 13C7-PFUnDA_IS

5.0000

ISTD Error

ng/mL

11CI-PF30UdS

NDfW, ~

	 13C-PFOS IS

4.7100

ISTD Error

ng/mL

9CI-PF30NS

ND(W/B)

—- 13C-PFOS IS

4.6600

ISTD Error

ng/mL

L-PFDoS

N DfW/B!

13C-PFOS IS

4.8400

ISTD Error

ng/mL

NaDONA

ND(W/B)

____ 13C-PFNAJS

4.7100

ISTD Error

ng/mL

PFHxDA

N DfW/B!

	 13C2-PFHxDAJS

5.0000

ISTD Error

ng/mL

PFODA

ND(W/B)

	 13C2-PFHxDA IS

5.0000

ISTD Error

ng/mL

13C2-PFHxDA IS

N D(W/B)

				

5.0000

	

ng/mL

13C2-PFHxDA

ND(W/B)

____ 13C7-PFUnDA IS

5.0000

ISTD Error

ng/mL

13C7-PFUnDA IS

NDfW, "



_



ng/mL

PFecHS

ND(W/B)

—- 13C-PFOS IS

4.6100

ISTD Error

ng/mL

PFBSA

N DfW/B)

13C-FOSAJS

5.0000

ISTD Error

ng/mL

PFHxSA

ND(W/B)

	 13C-PFNA IS

5.0000

ISTD Error

ng/mL

CHARGE

NDfW, "

13C7-PFUnDA IS





namiL	

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

A=1376778 '
RT=4.381

3.0e5 -

13C-PFBA

Cone. ISTD Error

3.21e5 Q217.20> 172.30 (-)

3.0e5 -

A=1376778 '
RT=4.381

PFBA

Cone. 4.6255

3.21e5 Q 213.20>169.10 (-)

A= 1509734
_ = RT=4.382

13C-PFPeAJS

Cone. 5.0000

3.59e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. ISTD Error

8.51e5 Q 267.90>223.00 (-)

7.5e5 -
5.0e5:
2.5e5:

f A=2218362
I RT= 5.554

7.5e5 -
5.0e5:
2.5e5:

f A=2218362
| RT= 5.554

PFPeA

Cone. 5.1903

RT (min)



13C-PFBSJS

Cone. 4.6500

O.OeO -

O.OeO -

Q 263.05>219.10 (-)	8.58e5 ISTD 301.80>80.00 (-;

f A=2250432
7.5e5 -I	ll RT=5.555

RT (min)

13C-PFBS

Cone. ISTD Error

5.0e5 -
2.5e5:
O.OeO :

3.0e5 :
2.0e5 ^
1.0e5 ^
O.OeO :

3.14e5 Q 301.80>80.00 (-)
3.0e5 -
2.0e5 ^

1.0e5 ^

_ Q.OeO 4--------

5.8
RT (min)

5.8

RT (min)

4.5	5.4 5.6 5.8

RT (min)	RT (min)

PFBS

Cone. 4.6712

R#1 298.80>99.00 72.99 (71.09)

3.14e5 Q299.00>80.00 (-)

fA=795850
RT= 5.677

f A=660316
RT= 5.677

5.8

RT (min)

13C_HFPO_DAJS

Cone. —

2.58e5 ISTD 332.10>287.10 (-)
I.Oel n

7.5e0 -
5.0e0 :
2.5eO^

5.8
RT (min)

'""" i	O.OeO I	

5.8	0.00 0.25 0.50 0.75

RT (min)	RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

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(AILS)

Printed 10/25/2023 16:02:20

CCV6-230504 (continued)

13C HFPO DA

Cone. ISTD Error

G 332.10>287.10 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i i i i i i i i i i

HFPO_DA

Cone. ISTD Error

R#1 329.00>285.10 —- (79.97)

Q329.00>169.00 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

13C-4_2-FTSJS

Cone. —

R#1 329.00 >81.00 — - (26.74)

ISTD 329.00>309.15 (-)

5.0e0 n

13C-4_2-FTS

Cone. ISTD Error

R#1 329.00>81.00 —- (26.74)

O.OOeO G329.00>309.15 (-)

5.0e0 -i

0.00 0.25 0.50 0.75

RT (min)

PFHxA

Cone. ISTD Error

R#1 313.00>119.10 —- (2.85)

Q313.00>269.00 (-)	3.85e2

O.OeO -

0.00 0.25 0.50 0.75

RT (min)

13C-PFHxA_IS

Cone. —

ISTD 314.90>270.10 (-)	S.00e2

6.0e2 -

RT (min)

13C-PFHpAJS

Cone. —

ISTD 366.90>322.10 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

13C2-62-FTSJS

Cone. —

ISTD 428.90>409.00 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

13C-PFOAJS

Cone. —

ISTD 416.80>372.05 (-)	O.OOeO

I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 ^

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

RT (min)

13C-PFHpA

Cone. ISTD Error

G366.90>322.10 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

13C2-62-FTS

Cone. ISTD Error

G428.90>409.00 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i i i i i i i i i i

RT (min)

180-PFHxSJS

Cone. —

ISTD 402.70>84.05 (-)
I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i

0.00 0.25 0.50 0.75

RT (min)

13C-PFOA

Cone. ISTD Error

G416.80>372.05 (-)	O.OOeO

I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 ^

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

4-2-FtS

Cone. ISTD Error

R#1 327.00>81.10 —- (16.29)

O.OOeO G 327.00>307.05 (-)	O.OOeO

5.0e0 n

-5.0e0 -L,—| , | | |—I,!,,,—
5.86 5.88 5.90
RT (min)

13C-PFHxA

Cone. ISTD Error

Q 314.90>270.10 (-)	S.00e2

6.0e2 -

-5.0e0 -L,—| , | | |—I,!,,,—
5.86 5.88 5.90
RT (min)

PFPeS

Cone. ISTD Error

R#1 349.00 >99.00 — - (74.42)

G349.00>79.95 (-)	O.OOeO

0.00 0.25 0.50 0.75

RT (min)

PFHpS

Cone. ISTD Error

R#1 449.00 >99.20 — - (66.82)

Q 449.00>80.15 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

PFOS

Cone. ISTD Error

R#1 499.00 >99.00 — - (93.96)

G499.00>80.00 (-)	O.OOeO

I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 i

5.88 5.90
RT (min)

PFHxS

Cone. ISTD Error

R#1 399.00>99.00 —- (95.46)

G399.00>80.00 (-)	(

I.Oel -
7.5e0i
5.0e0 i
2.5e0 i

O.OeO-

0.00 0.25 0.50 0.75

RT (min)

180-PFHxS

Cone. ISTD Error

G 402.70>84.05 (-)	O.OOeO

I.Oel -
7.5e0i
5.0e0i
2.5e0i

O.OeO —i i i i i i i i i i i i i i i i i i i i

O.OeO -

0.50 0.75

RT (min)

PFHpA

Cone. ISTD Error

R#1 362.90>169.00 —- (17.56)

G 362.90>319.00 (-)	0

I.Oel -
7.5e0i
5.0e0 i
2.5e0 i

O.OeO -

O.OeO -

0.00 0.25 0.50 0.75

RT (min)

0.00 0.25 0.50 0.75

RT (min)

6-2-FTS

Cone. ISTD Error

R#1 427.00>80.90 —- (28.57)

G427.00>407.00 (-)	O.OOeO

I.Oel -
7.5e0i
5.0e0i
2.5e0i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

13C-PFOSJS

Cone. —

ISTD S02.80>80.05 (-)	O.OOeO

I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 ^

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

0.50 0.75

RT (min)

PFOA

Cone. ISTD Error

R#1 413.00> 169.10 —- (28.52)

G413.00>369.00 (-)	0

I.Oel -
7.5e0i
5.0e0 i
2.5e0 i

O.OeO I i i i i i i i
0.00 0.25

13C-PFOS

Cone. ISTD Error

G S02.80>80.05 (-)
I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 ^

O.OeO —i i i i i i i

0.50 0.75

RT (min)

0.50 0.75

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

338

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CCV6-230504 (continued)

PFNA

Cone. ISTD Error

R#1 463.00>219.00 — - (21.80)

Q 463.00>418.90 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i
0.00 0.25 0.50

13C-82-FTSJS

Cone. —

ISTD S28.80>S09.00 (-)

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i
0.00 0.25 0.50

d3-N-MeFOSAA_IS

Cone. —

ISTD 572.80>419.05 (-)

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i
0.00 0.25 0.50

13C-PFUnDA

Cone. ISTD Error

Q 564.80>519.95 (-)

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

PFOSA

Cone. ISTD Error

R#1 498.20 >64.10 —- (0.10)

Q 498.20>78.00 (-)	O.OOeO

I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 ^

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

13C-PFNAJS

Cone. —

ISTD 467.80>423.00 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i
0.00 0.25

13C-82-FTS

Cone. ISTD Error

Q 528.80>509.00 (-
I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i
0.00 0.25 0.50

d3-N-MeFOSAA

Cone. ISTD Error

Q 572.80>419.05 (-)

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

PFUnDA

Cone. ISTD Error

R#1 563.00>219.00 —- (14.10)

Q 563.00>518.90 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i
0.00 0.25

13C-FOSAJS

Cone. —

ISTD 506.00>78.05
I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 ^

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

13C-PFNA

Cone. ISTD Error

Q 467.80>423.00 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

PFDA

Cone. ISTD Error

R#1 512.90>219.00 —- (17.77)

Q 512.90>469.00 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

NMeFOSAA

Cone. ISTD Error

R#1 570.20>512.00 —- (35.13)

Q 570.20>419.00 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i
0.00 0.25 0.50

d5-N-EtFOSAA_IS

Cone. —

ISTD 588.80>419.00 (-)

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i
0.00 0.25 0.50

13C-FOSA

Cone. ISTD Error

G 506.00>78.05 (-)

I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 ^

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

PFNS

Cone. ISTD Error

R#1 549.00 >99.00 — - (66.39)

Q S49.00>79.95 (-)	O.OOeO

I.Oel -
7.5e0i
5.0e0i
2.5e0i

O.OeO —i i i i i i i i i i i
0.00 0.25 0.50

13C-PFDAJS

Cone. —

ISTD 514.80>469.95 (-)

I.Oel -
7.5e0i
5.0e0i
2.5e0i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

PFDS

Cone. ISTD Error

R#1 599.00>99.00 —- (55.44)

Q 599.00>80.10 (-)	O.OOeO

I.Oel -
7.5e0i
5.0e0i
2.5e0i

O.OeO —i i i i i i i i i i i
0.00 0.25 0.50

d5-N-EtFOSAA

Cone. ISTD Error

Q 588.80>419.00 (-)

I.Oel -
7.5e0i
5.0e0i
2.5e0i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

PFDoA

Cone. ISTD Error

R#1 613.05>169.00 —- (16.48)

Q 613.05>569.00 (-)	O.OOeO

I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 ^

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

8-2-FTS

Cone. ISTD Error

R#1 527.20>487.00 —- (7.71)

Q 527.10>506.90 (-)	O.OOeO

I.Oel -
7.5e0i
5.0e0 i
2.5e0i

O.OeO —i i i i i i i
0.00 0.25

13C-PFDA

Cone. ISTD Error

Q 514.80>469.95 (-
I.Oel -
7.5e0i
5.0e0 i
2.5e0i

O.OeO —i i i i i i i i i i i
0.00 0.25 0.50

13C-PFUnDA_IS

Cone. —

ISTD S64.80>S19.95 (-)

I.Oel -
7.5e0i
5.0e0 i
2.5e0i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

NEtFOSAA

Cone. ISTD Error

R#1 584.20>526.10 —- (56.68)

Q 584.20>418.95 (-)	O.OOeO

I.Oel -
7.5e0i
5.0e0 i
2.5e0i

O.OeO —i i i i i i i i i i i
0.00 0.25 0.50

13C-PFDoA_IS

Cone. —

ISTD 614.80>569.95 (-)

I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 ^

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

0.75

RT (min)

0.75

RT (min)

0.75

RT (min)

0.50 0.75

RT (min)

0.75

RT (min)

0.50 0.75

RT (min)

0.75

RT (min)

0.75

RT (min)

0.75

RT (min)

0.75

RT (min)

0.50 0.75

RT (min)

0.75

RT (min)

0.75

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

338

-------
A

Insight Report



Quantitation/lntegration

<4vi^

Printed 10/25/2023 16:02:20

CCV6-230504 (continued)

13C-PFDoA

Cone. ISTD Error

Q 614.80>569.95 (-)
I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i

NEtFOSE

Cone. ISTD Error

Q 629.50>59.10 (-)
I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i

d3-NMeFOSA

Cone. ISTD Error

Q 515.10> 169.00 (-)
I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i

L-PFDoS

Cone. ISTD Error

R#1 698.80>98.80 —- (62.67)

Q 698.80>80.10 (-)

I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 i

O.OeO -

10-2-FtS

Cone. ISTD Error

R#1 626.50>81.05 —- (72.12)

Q 626.50>607.05 (-)	O.OOeO

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

0.50 0.75

RT (min)

ISTD 638.90>59.10 (-)
I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

0.50 0.75

RT (min)

ISTD 623.00> 59.00 (-)
I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

0.00 0.25 0.50 0.75

RT (min)

PFTeDA

Cone. ISTD Error

R#1 713.00>169.30 —- (12.52)

Q 713.00>668.90 (-)	(

I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO —i i i i i i i i i i i i i i i i

ISTD 714.80>669.80 (-)
I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

0.50 0.75

RT (min)

Q 377.10> 251.20 (-)
I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 ^

O.OeO —i i i i i i i i

d5-NEtFOSAIS

Cone. —

ISTD 531.10> 169.10 (-)
I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO I i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

d9-EtFOSE_IS

Cone. —

O.OeO -

0.00 0.25 0.50

d9-EtFOSE

Cone. ISTD Error

Q 638.90>59.10 (-)
I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO I i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

d7-N-MeFOSE_IS

Cone. —

O.OeO -

0.00 0.25 0.50

d7-N-MeFOSE

Cone. ISTD Error

O.OOeO Q623.00> 59.00 (-)
I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO I i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

13C-PFTeDA_IS

Cone. —

O.OeO -

d5-NEtFOSA

Cone. ISTD Error

O.OOeO Q 531.10> 169.10 (-)	(

I.Oel -
7.5e0i
5.0e0i
2.5e0i

	 O.OeO 1	

0.75	0.00 0.25 0.50 0.75

RT (min)	RT (min)

NMeFOSA

Cone. ISTD Error

R#1 512.10>219.20 —- (75.56)

O.OOeO Q 512.10> 169.20 (-)	O.OOeO

I.Oel -
7.5e0i
5.0e0i
2.5e0i

	 O.OeO 1	

0.75	0.00 0.25 0.50 0.75

RT (min)	RT (min)

NEtFOSA

Cone. ISTD Error

R#1 526.50>219.20 —- (61.76)

O.OOeO Q 526.50> 169.10 (-)	O.OOeO

I.Oel -
7.5e0i
5.0e0i
2.5e0i

	 O.OeO 1	

0.00 0.25 0.50

13C-PFTeDA

Cone. ISTD Error

0.75

RT (min)

O.OOeO Q 714.80>669.80 (-)
I.Oel -
7.5e0 i
5.0e0 i
2.5e0 i

O.OeO I i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

NaDONA

Cone. ISTD Error

O.OeO I i i i i i i i i i i i i
0.00 0.25 0.50

PFHxDA

Cone. ISTD Error

Q 812.90>769.00 (-)

I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 i

11CI-PF30UdS

Cone. ISTD Error

Q 631.00>451.10 (-)
I.Oel -
7.5e0i
5.0e0i
2.5e0i

O.OeO —i i i i i i i i

0.75

RT (min)

O.OeO -

PFODA

Cone. ISTD Error

Q 912.80>869.00 (-)
I.Oel n
7.5e0 ^

5.0e0 ^

2.5e0 ^

O.OeO —i i i i i i i i

NMeFOSE

Cone. ISTD Error

Q 616.10>58.90 (-)	O.OOeO

I.Oel -
7.5e0i
5.0e0 i
2.5e0i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

d3-NMeFOSA_IS

Cone. —

ISTD 515.10> 169.00 (-)	O.OOeO

I.Oel -
7.5e0i
5.0e0 i
2.5e0i

O.OeO —i i i i i i i i i i i i i i i i i i i i

0.50 0.75

RT (min)

0.00 0.25 0.50 0.75

RT (min)

PFTrDA

Cone. ISTD Error

R#1 663.10> 169.10 —- (21.32)
Q 663.10>618.90 (-)	O.OOeO

I.Oel -
7.5e0i
5.0e0 i
2.5e0i

O.OeO —i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

9CI-PF30NS

Cone. ISTD Error

Q 531.00>351.10 (-)
I.Oel -
7.5e0i
5.0e0 i
2.5e0 i

0.50 0.75

RT (min)

O.OeO I i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

13C2-PFHxDA_IS

Cone. —

ISTD 815.00>770.00 (-)
I.Oel n
7.5e0 ^

5.0e0 ^

2.5eOz_

O.OOeO

O.OeO -

0.50 0.75

RT (min)

0.00 0.25 0.50 0.75

RT (min)

0.00 0.25 0.50

0.75

RT (min)

0.50 0.75

RT (min)

0.00 0.25 0.50 0.75

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

230

-------


Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:20

CCV6-230504 (continued)

13C2-PFHxDA

Cone. ISTD Error

Q 815.00>770.00 (-)
1.0e11
7.5e0 ~

5.0e0 ~

2.5e0 ~

13C7-PFUnDAJS

Cone. —

O.OOeO ISTD 569.80>524.90 (-)
1.0e1 i
7.5e0 ~

5.0e0 ~

2.5e0 ~

PFecHS	PFBSA

Cone. ISTD Error	Cone. ISTD Error
R#1 461.00>99.10 —- (38.58)

O.OOeO Q 461.00>381.00 (-)	O.OOeO Q 298.00>78.00 (-)

O.OeO I i i i i i i i i i i i i i i i i i i i i
0.00 0.25 0.50 0.75

RT (min)

CHARGE

Cone. ISTD Error

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	1.00e0

5.0e0 -

O.OeO -

0.2
RT (min)

1.0e1 :
7.5e0 :
5.0e0 :
2.5e0 :

O.OeO -

0.00 0.25 0.50 0.75

RT (min)

1.0e1:
7.5e0 :
5.0e0 :
2.5e0 :

PFHxSA

Cone. ISTD Error

O.OOeO Q 397.90>78.00 (-)
1.0e11
7.5e0 ~

5.0e0 ~

2.5e0 ~

O.OeO -

0.00 0.25 0.50 0.75

RT (min)

O.OeO -

0.00 0.25 0.50 0.75

RT (min)

0.00 0.25 0.50 0.75

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

24ffl

-------
Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:28

CCV7-230504

Sample ID: CCV7-230504

Date Acquired: 5/5/2023 11:19:01 AM
Acquired by: System Administrator
Data File: 230504152
Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5















Name

Mode ID Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.374

1151728

1151728

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.374

1151728

3078603

13C7-PFUnDA IS

5.0000

3.5356

nq/mL

PFBA

Auto

4.375

1484402

1151728

13C-PFBA IS

5.0000

5.4325

nq/mL

13C-PFPeA IS

Auto

5.543

2183346

2183346

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.543

2183346

3078603

13C7-PFUnDA IS

5.0000

3.7835

nq/mL

PFPeA

Auto

5.544

2224551

2183346

13C-PFPeA IS

5.0000

5.2129

nq/mL

13C-PFBS IS

Auto

5.666

918905

918905

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.666

918905

3078603

13C7-PFUnDA IS

4.6500

3.9944

nq/mL

PFBS

Auto

5.666

690178

918905

13C-PFBS IS

4.4200

4.2287

nc

13C HFPO DA IS

Auto

6.256

654487

654487

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.256

654487

3078603

13C7-PFUnDA IS

5.0000

4.2024

nc

HFPO DA

Auto

6.257

552737

654487

13C HFPO DA IS

5.0000

4.9436

nq/mL

13C-4 2-FTS IS

Auto

6.063

354573

354573

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

6.063

354573

3078603

13C7-PFUnDA IS

4.6700

3.8723

nq/mL

4-2-FtS

Auto

6.063

420247

354573

13C-4 2-FTS IS

4.6700

4.6303

nq/mL

PFHxA

Auto

6.115

4631107

2930839

13C-PFHxA IS

5.0000

5.3643

nq/mL

13C-PFHxA IS

Auto

6.115

2930839

2930839

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

6.115

2930839

3078603

13C7-PFUnDA IS

5.0000

3.7569

nq/mL

PFPeS

Auto

6.152

688745

893125

180-PFHxS IS

4.6900

4.6795

nq/mL

PFHxS

Auto

6.510

558976

893125

180-PFHxS IS

4.5500

4.4018

nq/mL

13C-PFHpA IS

Auto

6.507

2945807

2945807

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.507

2945807

3078603

13C7-PFUnDA IS

5.0000

3.7612

nq/mL

180-PFHxS IS

Auto

6.510

893125

893125

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.510

893125

3078603

13C7-PFUnDA IS

4.7250

3.8569

nq/mL

PFHpA

Auto

6.508

4902103

2945807

13C-PFHpA IS

5.0000

5.3178

nq/mL

13C2-6 2-FTS IS

Auto

6.802

351893

351893

	

4.7500

4.7500

nq/mL

13C2-6 2-FTS

Auto

6.802

351893

3078603

13C7-PFUnDA IS

4.7500

3.6956

nq/mL

PFHpS

Auto

6.808

657905

893125

180-PFHxS IS

4.7600

4.7469

nq/mL

6-2-FTS

Auto

6.802

367624

351893

13C2-6 2-FTS IS

4.7400

4.8968

nq/mL

PFOA

Auto

6.820

5313611

3377693

13C-PFOA IS

5.0000

5.0896

nq/mL

13C-PFOA IS

Auto

6.820

3377693

3377693

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.820

3377693

3078603

13C7-PFUnDA IS

5.0000

3.9088

nq/mL

PFOS

Auto

7.116

483321

775401

13C-PFOS IS

4.6400

4.8602

nq/mL

13C-PFOS IS

Auto

7.116

775401

775401

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

7.116

775401

3078603

13C7-PFUnDA IS

4.7750

3.6989

nq/mL

PFNA

Auto

7.140

4548043

3398543

13C-PFNA IS

5.0000

5.4721

nq/mL

13C-PFNA IS

Auto

7.140

3398543

3398543

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.140

3398543

3078603

13C7-PFUnDA IS

5.0000

4.1975

nq/mL

PFNS

Auto

7.450

1073885

775401

13C-PFOS IS

4.8000

4.9778

nq/mL

8-2-FTS

Auto

7.478

223755

144198

13C-8 2-FTS IS

4.7900

5.9462

nq/mL

13C-8 2-FTS IS

Auto

7.478

144198

144198

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.478

144198

3078603

13C7-PFUnDA IS

4.7900

3.7981

nq/mL

PFDA

Auto

7.484

3769336

3473548

13C-PFDA IS

5.0000

4.9174

nq/mL

13C-PFDA IS

Auto

7.483

3473548

3473548

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.483

3473548

3078603

13C7-PFUnDA IS

5.0000

4.0367

nq/mL

d3-N-MeFOSAA IS

Auto

7.664

1092639

1092639

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.664

1092639

3078603

13C7-PFUnDA IS

5.0000

4.0420

nq/mL

NMeFOSAA

Auto

7.668

1209778

1092639

d3-N-MeFOSAA IS

5.0000

4.8928

nq/mL

PFDS

Auto

7.792

746096

775401

13C-PFOS IS

4.8200

5.0489

nq/mL

13C-PFUnDA IS

Auto

7.834

3179025

3179025

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.834

3179025

3078603

13C7-PFUnDA IS

5.0000

4.0242

nq/mL

PFUnDA

Auto

7.834

3799934

3179025

13C-PFUnDA IS

5.0000

5.7848

nq/mL

d5-N-EtFOSAA IS

Auto

7.847

1259570

1259570

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.847

1259570

3078603

13C7-PFUnDA IS

5.0000

4.1230

nq/mL

NEtFOSAA

Auto

7.855

1325022

1259570

dS-N-EtFOSAA IS

5.0000

5.3215

nq/mL

PFOSA

Auto

7.899

1136968

965693

13C-FOSA IS

5.0000

4.8353

nq/mL

13C-FOSA IS

Auto

7.899

965693

965693

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.899

965693

3078603

13C7-PFUnDA IS

5.0000

4.1400

nq/mL

PFDoA

Auto

8.173

4116825

3225515

13C-PFDoA IS

5.0000

4.8091

nq/mL

13C-PFDoA IS

Auto

8.174

3225515

3225515

	

5.0000

5.0000

nq/mL

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CCV7-230504 (continued)

(Table continued from previous page)

Name

Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.174

3225515

3078603

13C7-PFUnDA IS

5.0000

4.4649

nq/mL

10-2-FtS

Auto

8.184

194082

144198

13C-8 2-FTS IS

4.8200

5.9399

ng/mL

d5-NEtFOSA IS

Auto

8.904

1060417

1060417

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.904

1060417

3078603

13C7-PFUnDA IS

5.0000

4.0681

ng/mL

NMeFOSE

Auto

8.634

464916

456317

d7-N-MeFOSE IS

5.0000

5.3734

nq/mL

NEtFOSE

Auto

8.877

1413008

292757

d9-EtFOSE IS

5.0000

4.4699

ng/mL

d9-EtFOSE IS

Auto

8.860

292757

292757

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.860

292757

3078603

13C7-PFUnDA IS

5.0000

4.6105

ng/mL

NMeFOSA

Auto

8.661

499850

918981

d3-NMeFOSA IS

5.0000

5.2929

nq/mL

dB-NMeFOSA IS

Auto

8.657

918981

918981

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.657

918981

3078603

13C7-PFUnDA IS

5.0000

3.9312

nq/mL

d7-N-MeFOSE IS

Auto

8.619

456317

456317

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.619

456317

3078603

13C7-PFUnDA IS

5.0000

3.9947

nq/mL

NEtFOSA

Auto

8.914

808556

1060417

d5-NEtFOSA IS

5.0000

5.2776

ng/mL

PFTrDA

Auto

8.492

4173732

1999772

13C-PFTeDA IS

5.0000

4.0873

nq/mL

PFTeDA

Auto

8.782

4088286

1999772

13C-PFTeDA IS

5.0000

4.1235

ng/mL

13C-PFTeDA IS

Auto

8.782

1999772

1999772

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.782

1999772

3078603

13C7-PFUnDA IS

5.0000

5.6594

ng/mL

11CI-PFBOUdS

Auto

7.984

1107035

775401

13C-PFOS IS

4.7100

4.4808

nq/mL

9CI-PF30NS

Auto

7.302

2377846

775401

13C-PFOS IS

4.6600

5.2084

ng/mL

L-PFDoS

Auto

8.441

322999

775401

13C-PFOS IS

4.8400

5.0485

nq/mL

NaDONA

Auto

6.550

3200212

3398543

13C-PFNA IS

4.7100

4.0103

ng/mL

PFHxDA

Auto

9.291

2374780

6495194

13C2-PFHxDA IS

5.0000

8.2600

nq/mL

PFODA

Auto

9.883

1587413

6495194

13C2-PFHxDA IS

5.0000

6.5467

ng/mL

1BC2-PFHxDA IS

Auto

9.291

6495194

6495194

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.291

6495194

3078603

13C7-PFUnDA IS

5.0000

4.1972

ng/mL

13C7-PFUnDA IS

Auto

7.833

3078603

3078603

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.768

4099321

775401

13C-PFOS IS

4.6100

4.9952

ng/mL

PFBSA

Auto

6.302

2721462

965693

13C-FOSA IS

5.0000

4.9105

nq/mL

PFHxSA

Auto

7.111

2246568

3398543

13C-PFNA IS

5.0000

4.9653

ng/mL

CHARGE

ND(W/B)

	

	

3078603

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

13C-PFBA

Cone. 3.5356
2.52e5 Q 217.20>172.30 (-)

PFBA

Cone. 5.4325
2.52e5 Q 213.20> 169.10 (-)

A= 1484402
3.0e51 RT=4.375

13C-PFPeA IS

Cone. 5.0000
3.32e5 ISTD 267.90>223.00 (-)

13C-PFPeA

Cone. 3.7835
7.74e5 Q 267.90>223.00 (-)

A=2183346
RT= 5.543

RT (min)

RT (min)

RT (min)

5.8

RT (min)

PFBS

Cone. 4.2287
R#1 298.80>99.00 68.34 (71.09)

3.32e5 Q 299.00>80.00 (-)	2.45e5 ISTD 332.10>287.10 (-)

13C HFPO DA IS

Cone. 5.0000

A=690178
-Rl= 5.666

TA=654487
RT=6.256

5.

RT (min)

6.0
RT (min)

L

6.4 6.6
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

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Printed 10/25/2023 16:02:28

CCV7-230504 (continued)

13C HFPO DA

Cone. 4.2024

Q 332.10>287.10 (-)

O.OeO -

A=654487
RT=6.256

vj

6.2

13C-PFHpA_IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

fA=2945807
1 RT=6.507

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)
1.5e5 -
1.0e5^

5.0e4 ^

O.OeO 1 . . .

13C-PFOA IS

Cone. 5.0000

ISTD 416.80>372.05 (-)
1.5e6 n

1.0e6 ^

5.0e5 ^

O.OeO 1. . .

HFPO DA

Cone. 4.9436

R#1 329.00>285.10 80.50 (79.97)
Q 329.00>169.00 (-)	2.40e5

TA= 552737
-R1 80.50 (| Rt=6.257

O.OeO -



6.4 6.6
RT (min)

PFHxA

Cone. 5.3643

R#1 313.00> 119.10 2.50 (2.85)
Q 313.00>269.00 (-)	1.97e6

fj A=4631107

-R1 2.50 (-wf^T=6.115

ISTD 314.90>270.10 (-)

6.2 6.4

RT (min)

13C-PFHpA

Cone. 3.7612

1.31e6 Q 366.90>322.10 (-)

TA=2945807
1 RT=6.507

6.6 6.8
RT (min)

13C2-6 2-FTS

Cone. 3.6956

1.59e5 Q 428.90>409.00 (-)
1.5e5 -
1.0e5^

5.0e4 ^
. . . O.OeO 1 . . .

7.0
RT (min)

13C-PFOA

Cone. 3.9088

1.50e6 Q416.80>372.05 (-)
1.5e6 n

1.0e6 ^

5.0e5 ^

— O.OeO 1. . . .

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00 >81.00 27.32 (26.74)

ISTD 329.00>309.15 (-)	1.47e5

IR1 27.32 (

6.2 6.4 6.6
RT (min)

13C-PFHxA IS

Cone. 5.0000

13C-PFHxA

Cone. 3.7569

1.24e6 Q 314.90>270.10 (-)

6.2 6.4

RT (min)

180-PFHxS IS

Cone. 4.7250

1.31e6 ISTD 402.70>84.05 (-)

A=893125
RT=6.510

O.OeO -



6.6 6.8
RT (min)

A=351893
RT=6.802

6.4

IR1 67.80 (-

A=657905
|-R)|"=6.808

O.OeO -

7.0
RT (min)

6.6



jr A=483321

r.



: /J

I .

13C-4 2-FTS

Cone. 3.8723

R#1 329.00>81.00 27.32 (26.74)
Q 329.00>309.15 (-)	1.47e5

I R1 27.3;

O.OeO -

6.2 6.4
RT (min)

6.0

6.2 6.4

RT (min)

180-PFHxS

Cone. 3.8569

3.98e5 Q 402.70>84.05 (-)

A=893125
RT=6.510

O.OeO -

6.6 6.8
RT (min)

PFHpS

Cone. 4.7469

R#1 449.00>99.20 67.80 (66.82)
Q 449.00>80.15 (-)	2.93e5

6.4

-R)r=6.802

i.8 7.0

RT (min)

PFOS

Cone. 4.8602

R#1 499.00>99.00 94.63 (93.96)
Q 499.00>80.00 (-)	1.54e5

1.5e5 -
1.0e5 ^
5.0e4 ^
O.OeO :

13C-PFOS IS

Cone. 4.7750

105 (-)

3.0e5 -
2.0e5 :
1.0e5:
O.OeO :

RT (min)

RT (min)

6.75 7.00 7.25 7.50

RT (min)

4-2-FtS

Cone. 4.6303

R#1 327.00 >81.10 16.45 (16.29)
Q 327.00>307.05 (-)	1.76e5

F[ A=420247

]R1 16.45 (tRt=6.063

6.2 6.4
RT (min)

PFPeS

Cone. 4.6795

R#1 349.00>99.00 81.32 (74.42)
Q 349.00>79.95 (-)	2.83e5

TA=688745
jR1 81.32 (|kt=6.152

6.2 6.4
RT (min)

PFHxS

Cone. 4.4018

R#1 399.00>99.00 98.03 (95.46)
Q 399.00>80.00 (-)	1.98e5

~ A= 558976

-R1 98.03 (-- kT=6.510

O.OeO -

1

6.4

RT (min)

6.25 6.50 6.75 7.00
RT (min)

PFHpA

Cone. 5.3178

R#1 362.90>169.00 16.79 (17.56)
Q 362.90>319.00 (-)	2.19e6

{A=4902103

2.0e6-|R1 16.79 ( |-r^=6.508

O.OeO -

6.6 6.8
RT (min)

6-2-FTS

Cone. 4.8968

R#1 427.00>80.90 30.03 (28.57)
Q 427.00>407.00 (-)	1.65e5

A=367624

6.4 6.6 6.8
RT (min)

PFOA

Cone. 5.0896

R#1 413.00> 169.10 28.38 (28.52)
Q 413.00>369.00 (-)	2.40e6

f A=5313611

-R1 28.38 (-1-^1=6.820

O.OeO

6.6 6.8 7.0 7.2
RT (min)

13C-PFOS

Cone. 3.6989

3.47e5 Q 502.80>80.05 (-)

3.0e5 :

2.0e5 :

1.0e5:
^ O.OeO:

3.47e5

A=775401
RT=7.116

7.2 7.4
RT (min)

7.2 7.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

243

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A

Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:28

CCV7-230504 (continued)

PFNA

Cone. 5.4721

R#1 463.00>219.00 19.74 (21.80)
Q 463.00>418.90 (-)	2.02e6

2.0e6 -

f A=4548043
R1 19.74 ("1-^1=7.140

13C-PFNA IS

Cone. 5.0000

ISTD 467.80>423.00 (-)
1.5e6 -i

13C-PFNA

Cone. 4.1975

Q 467.80>423.00 (-)

A=3398543
RT=7.140

O.OeO -

7.0 7.2 7.4

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

13C-8 2-FTS

Cone. 3.7981

ISTD 528.80>509.00 (-)
6.0e4 -i

6.04e4 Q 528.80> 509.00 (-)

7.4 7.6 7.8
RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

ISTD 572.80>419.05 (-)
4.0e5

4.23e5

A=1092639
RT=7.664

d3-N-MeFOSAA

Cone. 4.0420

Q 572.80>419.05 (-)
4.0e5

O.OeO -

13C-PFUnDA

Cone. 4.0242

Q 564.80>519.95 (-)

8.0	7.6 7.8 8.0

RT (min)	RT (min)

PFUnDA

Cone. 5.7848
R#1 563.00>219.00 12.54(14.10)

1,32e6 Q 563.00> 518.90 (-)	1,59e6 ISTD 588.80>419.00 (-)

f A=3179025
RT=7.834

O.OeO -

=F

TA=3799934

1.5e6-Ri 12.54 ( ]-^r=7.834

1.0e6:

5.0e5 :

O.OeO :

7.8 8.0

RT (min)

PFOSA	13C-FOSAJS

Cone. 4.8353	Cone. 5.0000
R#1 498.20>64.10 0.13 (0.10)

Q 498.20>78.00 (-)	4.98e5 I STD 506.00 > 78.05 (-)

fA= 1259570
RT=7.847

RT (min)

RT (min)

13C-FOSA

Cone. 4.1400

fA= 1136968

IR1 °-13 (—fl)RT=7.8

4.0e5

fA=965693
1 RT=7.8

Q 506.00>78.05 (-)	4.24e5

4.0e5 -

PFNS

Cone. 4.9778

R#1 549.00 >99.00 67.67 (66.39)
Q 549.00>79.95 (-)	4.42e5



fA= 1073885

	

ii

Ul

o

:



7.4
RT (min)

PFDA

Cone. 4.9174

R#1 512.90>219.00 17.83 (17.77)
Q 512.90>469.00 (-)	1.56e6

A=3769336

R1 17.83 (-H-r)t=7.484

13C-PFDA IS

Cone. 5.0000

ISTD 514.80>469.95 (-)

O.OeO -

7.4 7.6 7.8
RT (min)

NMeFOSAA

Cone. 4.8928

R#1 570.20>512.00 39.91 (35.13)
Q 570.20>419.00 (-)	3.87e5

7.4

7.25 7.50 7.75 8.00

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

5.09e5 Q 588.80>419.00 (-)

8.0 8.2
RT (min)

8-2-FTS

Cone. 5.9462

R#1 527.20>487.00 5.76 (7.71)
Q 527.10>506.90 (-)	9.34e4

7.5e4
5.0e4
2.5e4
O.OeO



t A=223755



fkl= 7.478

^ I

I

RT (min)

7.6 7.8
RT (min)

13C-PFDA

Cone. 4.0367

1.46e6 Q 514.80>469.95 (-)

| A=3473548
RT=7.483

7.6 7.8
RT (min)

PFDS

Cone. 5.0489

R#1 599.00>99.00 59.66 (55.44)
Q 599.00>80.10 (-)	3.13e5

[ A=746096

- R1 59.66 (-H-^t=7.792

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)

fA=3179025
RT=7.834

O.OeO -

=^F=F=

7.8 8.0

RT (min)

d5-N-EtFOSAA

Cone. 4.1230

5.09e5

7.8 8.0

RT (min)

NEtFOSAA

Cone. 5.3215

R#1 584.20>526.10 51.55 (56.68)
Q 584.20>418.95 (-)	4.54e5

JA= 1325022
4.0e5-|R1 5155 ("TPRT=7.855

O.OeO

7.8 8.0

RT (min)

PFDoA

Cone. 4.8091

R#1 613.05> 169.00 15.96 (16.48)
Q 613.05>569.00 (-)	1.74e6

A=4116825

R1 15.96 (-f| rt=8.173

O.OeO -I,-



7.50 7.75 8.00 8.25

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)	1.36e6

JA=3225515
RT=8.174

.2 8.4

RT (min)

B.O 8.2 8.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

243

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Printed 10/25/2023 16:02:28

CCV7-230504 (continued)

13C-PFDoA

Cone. 4.4649

Q614.80>569.95 (-)

fA=3225515
RT=8.174

NEtFOSE

Cone. 4.4699

Q629.50>59.10 (-)
6.0e5 -

4.0e5 ^

2.0e5 :

A=1413008
RT=8.877

f A=4088286

1.5e6 ^

R1 10.19 (--j

RT=8.782

-\.0e6z_





5.0e5 ^

I



n Hofi —





U.UcU

h—|—i—rA—r-

| I I I I | I I I



8.6

.8 9.0





RT (min)

L-PFDoS



Cone. 5.0485



R#1 69

3.80 >98.80 66.36 (62.67)

Q 698.8

o
V
CO
p

o

1.42e5





A=322999

- R1 66.36 (-

10-2-FtS

Cone. 5.9399

R#1 626.50>81.05 55.12 (72.12)
Q 626.50>607.05 (-)	8.07e4

fA= 194082

7.5e4^R1 55.12 (--|^j=8.184

5.0e4 :

2.5e4 :

O.OeO :

d5-NEtFOSA IS

Cone. 5.0000

ISTD 531.10> 169.10 (-)

d5-NEtFOSA

Cone. 4.0681

4.55e5 Q 531.10> 169.10 (-)

NMeFOSE

Cone. 5.3734

4.55e5 Q 616.10>58.90 (-)

3.2 8.4

RT (min)

3.2 8.4

RT (min)

3.8 9.0 9.2
RT (min)

O.OeO -

A=464916
RT=8.634

d9-EtFOSE IS

Cone. 5.0000

d9-EtFOSE

Cone. 4.6105

6.06e5 ISTD 638.90> 59.10 (-)

1.26e5 Q 638.90> 59.10 (-)

\ p i i i i |A I i ~i i i i i i i i r

8.6 8.8 9.0 9.2

RT (min)

d3-NMeFOSA

Cone. 3.9312

Q 515.10> 169.00 (-)

8.8 9.0 9.2
RT (min)

NMeFOSA

Cone. 5.2929

R#1 512.10>219.20 75.63 (75.56)
Q 512.10> 169.20 (-)	2.09e5

2.0e5

d3-NMeFOSA IS

Cone. 5.0000

ISTD 515.10> 169.00 (-)

O.OeO



A=499850

_ R1 75.63 (--

-&T=8.661

:



A=918981
RT=8.657

RT (min)

RT (min)

d7-N-MeFOSE IS

Cone. 5.0000

3.86e5 I STD 623.00 > 59.00 (-)

d7-N-MeFOSE

Cone. 3.9947

1.89e5 Q 623.00> 59.00 (-)

8.4 8.6 8.8 9.0

RT (min)

NEtFOSA

Cone. 5.2776

R#1 526.50>219.20 61.42 (61.76)
Q 526.50> 169.10 (-)	3.52e5

RT (min)

PFTrDA

Cone. 4.0873

R#1 663.10> 169.10 18.30 (21.32)
Q 663.10>618.90 (-)	1.84e6

A=4173732
"At=8.492

RT (min)

PFTeDA

Cone. 4.1235

R#1 713.00> 169.30 10.19 (12.52)
Q 713.00>668.90 (-)	1.71e6

RT (min)

RT (min)

13C-PFTeDA IS

Cone. 5.0000

13C-PFTeDA

Cone. 5.6594

8.6 8.8 9.0 9.2

RT (min)

11CI-PF30UdS

Cone. 4.4808

RT (min)

9CI-PF30NS

Cone. 5.2084

8.31 e5 Q 631.00>451.10 (-)

4.71 e5 Q 531.00>351.10 (-)
1.0e6H

A=2377846
RT=7.302

2

RT (min)

7.4 7.6
RT (min)

13C2-PFHxDA IS

Cone. 5.0000

Q 377.10>251.20 (-)

A=3200212
RT=6.550

Q 812.90>769.00 (-)
1.0e6 -

1.09e6 Q 912.80>869.00 (-)

5.55e5 ISTD 815.00>770.00 (-)

=^=F

3.0e6 :
2.0e6 :
1.0e6:
O.OeO :

fA=6495194
RT=9.291

RT (min)

6.8

RT (min)

9.4 9.6
RT (min)

RT (min)

9.4 9.6
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

346

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:28

CCV7-230504 (continued)

13C2-PFHxDA

Cone. 4.1972

Q 815.00>770.00 (-)

3.0e6 ^

2.0e6 i
1.0e6 -

13C7-PFUnDA IS

Cone. 5.0000

3.43e6 ISTD 569.80>524.90 (-)

PFBSA

Cone. 4.9105

PFecHS

Cone. 4.9952
R#1 461.00>99.10 37.46 (38.58)

1.27e6 Q 461.00>381.00 (-)	1.75e6 Q 298.00>78.00 (-)

PFHxSA

Cone. 4.9653

1.13e6 Q 397.90>78.00 (-)

fA=6495194
RT=9.291

O.OeO -

9.4 9.6
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)
Q 514.80 > 219.10 (+)

5.0e0 -

0.2
RT (min)

A=4099321
R>T=6.768

RT (min)

A=2721462
RT=6.302

6.6
RT (min)

| A=2246568
RT=7.111

L

7.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

246

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:37

CCV8-230504

Sample ID: CCV8-230504

Date Acquired: 5/5/2023 1:36:27 PM
Acquired by: System Administrator
Data File: 230504162
Vial: 16 | Inj. Volume: 10.0000uL | Tray: 5















Name

Mode ID Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

13C-PFBA IS

Auto

4.380

1435251

1435251

	

5.0000

5.0000

nq/mL

1BC-PFBA

Auto

4.380

1435251

1259627

13C7-PFUnDA IS

5.0000

10.7683

nq/mL

PFBA

Auto

4.381

1561083

1435251

13C-PFBA IS

5.0000

4.5882

nq/mL

13C-PFPeA IS

Auto

5.554

2237161

2237161

	

5.0000

5.0000

nq/mL

13C-PFPeA

Auto

5.554

2237161

1259627

13C7-PFUnDA IS

5.0000

9.4749

nq/mL

PFPeA

Auto

5.554

2321150

2237161

13C-PFPeA IS

5.0000

5.3084

nq/mL

13C-PFBS IS

Auto

5.677

744144

744144

	

4.6500

4.6500

nq/mL

13C-PFBS

Auto

5.677

744144

1259627

13C7-PFUnDA IS

4.6500

7.9059

nq/mL

PFBS

Auto

5.677

661702

744144

13C-PFBS IS

4.4200

5.0063

nc

13C HFPO DA IS

Auto

6.271

528489

528489

	

5.0000

5.0000

nq/mL

13C HFPO DA

Auto

6.271

528489

1259627

13C7-PFUnDA IS

5.0000

8.2935

nc

HFPO DA

Auto

6.271

547287

528489

13C HFPO DA IS

5.0000

6.0619

nq/mL

13C-4 2-FTS IS

Auto

6.077

370567

370567

	

4.6700

4.6700

nq/mL

13C-4 2-FTS

Auto

6.077

370567

1259627

13C7-PFUnDA IS

4.6700

9.8909

nq/mL

4-2-FtS

Auto

6.077

410252

370567

13C-4 2-FTS IS

4.6700

4.3251

nq/mL

PFHxA

Auto

6.130

4603360

3189248

13C-PFHxA IS

5.0000

4.9001

nq/mL

13C-PFHxA IS

Auto

6.130

3189248

3189248

	

5.0000

5.0000

nq/mL

13C-PFHxA

Auto

6.130

3189248

1259627

13C7-PFUnDA IS

5.0000

9.9917

nq/mL

PFPeS

Auto

6.165

696218

758129

180-PFHxS IS

4.6900

5.5725

nq/mL

PFHxS

Auto

6.525

544218

758129

180-PFHxS IS

4.5500

5.0487

nq/mL

13C-PFHpA IS

Auto

6.523

3003719

3003719

	

5.0000

5.0000

nq/mL

13C-PFHpA

Auto

6.523

3003719

1259627

13C7-PFUnDA IS

5.0000

9.3734

nq/mL

180-PFHxS IS

Auto

6.526

758129

758129

	

4.7250

4.7250

nq/mL

180-PFHxS

Auto

6.526

758129

1259627

13C7-PFUnDA IS

4.7250

8.0016

nq/mL

PFHpA

Auto

6.523

4868515

3003719

13C-PFHpA IS

5.0000

5.1796

nq/mL

13C2-6 2-FTS IS

Auto

6.815

334595

334595

	

4.7500

4.7500

nq/mL

13C2-6 2-FTS

Auto

6.815

334595

1259627

13C7-PFUnDA IS

4.7500

8.5883

nq/mL

PFHpS

Auto

6.821

623717

758129

180-PFHxS IS

4.7600

5.3016

nq/mL

6-2-FTS

Auto

6.815

352405

334595

13C2-6 2-FTS IS

4.7400

4.9367

nq/mL

PFOA

Auto

6.833

5173612

3605476

13C-PFOA IS

5.0000

4.6425

nq/mL

13C-PFOA IS

Auto

6.833

3605476

3605476

	

5.0000

5.0000

nq/mL

13C-PFOA

Auto

6.833

3605476

1259627

13C7-PFUnDA IS

5.0000

10.1976

nq/mL

PFOS

Auto

7.130

461459

814285

13C-PFOS IS

4.6400

4.4187

nq/mL

13C-PFOS IS

Auto

7.130

814285

814285

	

4.7750

4.7750

nq/mL

13C-PFOS

Auto

7.130

814285

1259627

13C7-PFUnDA IS

4.7750

9.4937

nq/mL

PFNA

Auto

7.154

3118596

3313640

13C-PFNA IS

5.0000

3.8484

nq/mL

13C-PFNA IS

Auto

7.154

3313640

3313640

	

5.0000

5.0000

nq/mL

13C-PFNA

Auto

7.154

3313640

1259627

13C7-PFUnDA IS

5.0000

10.0027

nq/mL

PFNS

Auto

7.465

1013189

814285

13C-PFOS IS

4.8000

4.4722

nq/mL

8-2-FTS

Auto

7.494

115557

132421

13C-8 2-FTS IS

4.7900

3.3440

nq/mL

13C-8 2-FTS IS

Auto

7.494

132421

132421

	

4.7900

4.7900

nq/mL

13C-8 2-FTS

Auto

7.494

132421

1259627

13C7-PFUnDA IS

4.7900

8.5246

nq/mL

PFDA

Auto

7.499

3448259

2749878

13C-PFDA IS

5.0000

5.6824

nq/mL

13C-PFDA IS

Auto

7.499

2749878

2749878

	

5.0000

5.0000

nq/mL

13C-PFDA

Auto

7.499

2749878

1259627

13C7-PFUnDA IS

5.0000

7.8105

nq/mL

d3-N-MeFOSAA IS

Auto

7.679

1043415

1043415

	

5.0000

5.0000

nq/mL

cB-N-MeFOSAA

Auto

7.679

1043415

1259627

13C7-PFUnDA IS

5.0000

9.4339

nq/mL

NMeFOSAA

Auto

7.684

1055987

1043415

d3-N-MeFOSAA IS

5.0000

4.4723

nq/mL

PFDS

Auto

7.807

688598

814285

13C-PFOS IS

4.8200

4.4373

nq/mL

13C-PFUnDA IS

Auto

7.849

2620202

2620202

	

5.0000

5.0000

nq/mL

13C-PFUnDA

Auto

7.849

2620202

1259627

13C7-PFUnDA IS

5.0000

8.1064

nq/mL

PFUnDA

Auto

7.850

1967676

2620202

13C-PFUnDA IS

5.0000

3.6344

nq/mL

d5-N-EtFOSAA IS

Auto

7.862

1096892

1096892

	

5.0000

5.0000

nq/mL

d5-N-EtFOSAA

Auto

7.862

1096892

1259627

13C7-PFUnDA IS

5.0000

8.7754

nq/mL

NEtFOSAA

Auto

7.870

859683

1096892

dS-N-EtFOSAA IS

5.0000

3.9647

nq/mL

PFOSA

Auto

7.915

934508

827959

13C-FOSA IS

5.0000

4.6354

nq/mL

13C-FOSA IS

Auto

7.915

827959

827959

	

5.0000

5.0000

nq/mL

13C-FOSA

Auto

7.915

827959

1259627

13C7-PFUnDA IS

5.0000

8.6753

nq/mL

PFDoA

Auto

8.188

3289599

2101670

13C-PFDoA IS

5.0000

5.8977

nq/mL

13C-PFDoA IS

Auto

8.188

2101670

2101670

	

5.0000

5.0000

nq/mL

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

248

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A

Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:37

CCV8-230504 (continued)













(Table continued from previous page)
Name Mode ID

Found RT

Area

ISTD Area

ISTD Name

Std. Cone.

Cone.

Unit

1BC-PFDoA

Auto

8.188

2101670

1259627

13C7-PFUnDA IS

5.0000

7.1103

nq/mL

10-2-FtS

Auto

8.199

16023

132421

13C-8 2-FTS IS

4.8200

0.5340

ng/mL

d5-NEtFOSA IS

Auto

8.920

1033566

1033566

—

5.0000

5.0000

nq/mL

d5-NEtFOSA

Auto

8.920

1033566

1259627

13C7-PFUnDA IS

5.0000

9.6909

ng/mL

NMeFOSE

Auto

8.649

423917

340672

d7-N-MeFOSE IS

5.0000

6.5627

nq/mL

NEtFOSE

Auto

8.893

1391785

336848

d9-EtFOSE IS

5.0000

3.8265

ng/mL

d9-EtFOSE IS

Auto

8.875

336848

336848

—

5.0000

5.0000

nq/mL

d9-EtFOSE

Auto

8.875

336848

1259627

13C7-PFUnDA IS

5.0000

12.9653

ng/mL

NMeFOSA

Auto

8.676

435459

880087

d3-NMeFOSA IS

5.0000

4.8148

nq/mL

dB-NMeFOSA IS

Auto

8.671

880087

880087

	

5.0000

5.0000

ng/mL

dB-NMeFOSA

Auto

8.671

880087

1259627

13C7-PFUnDA IS

5.0000

9.2015

nq/mL

d7-N-MeFOSE IS

Auto

8.634

340672

340672

	

5.0000

5.0000

ng/mL

d7-N-MeFOSE

Auto

8.634

340672

1259627

13C7-PFUnDA IS

5.0000

7.2889

nq/mL

NEtFOSA

Auto

8.929

702565

1033566

d5-NEtFOSA IS

5.0000

4.7049

ng/mL

PFTrDA

Auto

8.506

1403407

128131

13C-PFTeDA IS

5.0000

21.4496

nq/mL

PFTeDA

Auto

8.796

1316609

128131

13C-PFTeDA IS

5.0000

20.7256

ng/mL

13C-PFTeDA IS

Auto

8.796

128131

128131

—

5.0000

5.0000

nq/mL

13C-PFTeDA

Auto

8.796

128131

1259627

13C7-PFUnDA IS

5.0000

0.8862

ng/mL

11CI-PFBOUdS

Auto

7.998

945193

814285

13C-PFOS IS

4.7100

3.6430

nq/mL

9CI-PF30NS

Auto

7.317

1524470

814285

13C-PFOS IS

4.6600

3.1797

ng/mL

L-PFDoS

Auto

8.455

361208

814285

13C-PFOS IS

4.8400

5.3761

nq/mL

NaDONA

Auto

6.565

4034283

3313640

13C-PFNA IS

4.7100

5.1850

ng/mL

PFHxDA

Auto

9.304

108838

4401430

13C2-PFHxDA IS

5.0000

0.5093

nq/mL

PFODA

Auto

9.899

89045

4401430

13C2-PFHxDA IS

5.0000

0.5419

ng/mL

13C2-PFHxDA IS

Auto

9.304

4401430

4401430

—

5.0000

5.0000

nq/mL

13C2-PFHxDA

Auto

9.304

4401430

1259627

13C7-PFUnDA IS

5.0000

6.9514

ng/mL

13C7-PFUnDA IS

Auto

7.849

1259627

1259627

—

5.0000

5.0000

nq/mL

PFecHS

Auto

6.781

3314935

814285

13C-PFOS IS

4.6100

3.8465

ng/mL

PFBSA

Auto

6.317

2731866

827959

13C-FOSA IS

5.0000

5.7493

nq/mL

PFHxSA

Auto

7.126

2210216

3313640

13C-PFNA IS

5.0000

5.0101

ng/mL

CHARGE

ND(W/B)

	

	

1259627

13C7-PFUnDA IS

1.0000

	

nq/mL

13C-PFBA IS

Cone. 5.0000

ISTD 217.20>172.30 (-)

A= 1435251
" RT=4.380

13C-PFBA

Cone. 10.7683
3.89e5 Q 217.20>172.30 (-)

A= 1435251
" RT=4.380

PFPeA

Cone. 5.3084

Q263.05>219.10 (-)
1.0e6 H

A=2321150
RT= 5.554

RT (min)

13C-PFBS IS

Cone. 4.6500

1.03e6 ISTD 301.80>80.00 (-)

PFBA

Cone. 4.5882
3.89e5 Q 213.20> 169.10 (-)

A= 1561083
RT=4.381

5.8

RT (min)

4.0e5 -

13C-PFPeA IS

Cone. 5.0000
4.21 e5 ISTD 267.90>223.00 (-)

RT (min)

13C-PFBS

Cone. 7.9059

3.43e5 Q 301.80>80.00 (-)

f A=744144
RT= 5.677

fA=2237161
RT= 5.554

O.OeO -

Ai I

13C-PFPeA

Cone. 9.4749
Q 267.90>223.00 (-)

rA=2237161
RT= 5.554

O.OeO

5.4

5.6

RT (min)

5.8	5.4 5.6 5.8

RT (min)	RT (min)

PFBS	13C HFPO DAJS

Cone. 5.0063	Cone. 5.0000
R#1 298.80>99.00 72.55 (71.09)

3.43e5 Q 299.00>80.00 (-)	3.05e5	ISTD 332.10>287.10 (-)	2.58e5

3.0e5 -

R1 72.55

A=661702
"Rt= 5.677

5.8 6.0
RT (min)

t A= 528489
RT=6.271

6.4 6.6
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

248

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:37

CCV8-230504 (continued)

13C HFPO DA

Cone. 8.2935

Q 332.10>287.10 (-)

O.OeO -

A= 528489
RT=6.271

6.2

L

13C-PFHpA_IS

Cone. 5.0000

ISTD 366.90>322.10 (-)

fA=3003719
RT=6.523

13C2-6 2-FTS IS

Cone. 4.7500

ISTD 428.90>409.00 (-)
1.5e5 i

1.0e5 -
5.0e4 :
O.OeO -

A=334595
RT=6.815

'•	3

13C-PFOA IS

Cone. 5.0000

HFPO DA

Cone. 6.0619

R#1 329.00>285.10 85.46 (79.97)
Q 329.00>169.00 (-)	2.66e5

f A= 547287

JR1 85.46 (-1 RT=6271

k

6.4 6.6
RT (min)

PFHxA

Cone. 4.9001

R#1 313.00> 119.10 2.81 (2.85)
Q 313.00>269.00 (-)	2.21e6

[A=4603360

2.0e6HR1 2.81 (-4 rj=6.130

13C-PFHxA IS

Cone. 5.0000

ISTD 314.90>270.10 (-)
1.5e6 i

A=3189248
RT=6.130

1.0e6 -
5.0e5 :
O.OeO -

6.2 6.4

RT (min)

13C-PFHpA

Cone. 9.3734

1.42e6 Q 366.90>322.10 (-)

fA=3003719
RT=6.523

6.6 6.8
RT (min)

13C2-6 2-FTS

Cone. 8.5883

Q 428.90>409.00 (-)
1.5e5 -

1.0e5-j

5.0e4 ^

O.OeO 1 . . .

•	i

7.0
RT (min)

13C-PFOA

Cone. 10.1976

13C-4 2-FTS IS

Cone. 4.6700

R#1 329.00 >81.00 26.78 (26.74)

ISTD 329.00>309.15 (-)	1.81 e5

1.5e5 -
1.0e5:
5.0e4 :
O.OeO :

f A=370567
^R1 26.78 (-1-^=6.077

L,

6.4 6.6
RT (min)

13C-PFHxA

Cone. 9.9917

Q 314.90>270.10 (-)
1.5e6 -

1.0e6 -j

5.0e5 -

O.OeO 1. . .

6.2 6.4

RT (min)

180-PFHxS IS

Cone. 4.7250

1.42e6 ISTD 402.70>84.05 (-)

A=758129
RT=6.526



6.6 6.8
RT (min)

A=334595
RT=6.815

O.OeO -



7.0
RT (min)

6.6

6.8

13C-4 2-FTS

Cone. 9.8909

R#1 329.00>81.00 26.78 (26.74)
Q 329.00>309.15 (-)	1.81e5

1.5e5
1.0e5
5.0e4
O.OeO



A=370567

I R1 26.78 (-

"^"=6.077



~

6.2 6.4
RT (min)

A=3189248
RT=6.130

6.0

6.2 6.4

RT (min)

180-PFHxS

Cone. 8.0016

3.67e5 Q 402.70>84.05 (-)

A=758129
RT=6.526

6.4 6.6 6.8
RT (min)

PFHpS

Cone. 5.3016

R#1 449.00>99.20 69.67 (66.82)
Q 449.00>80.15 (-)	2.87e5

fA=623717

HR1 6967 ("Mt=6.821

7.0
RT (min)

PFOS

Cone. 4.4187

R#1 499.00>99.00 94.94 (93.96)
Q 499.00>80.00 (-)	1.52e5

A=461459

O.OeO I | | | |

6.6 6.8

13C-PFOS IS

Cone. 4.7750

105 (-)

rA=814285
RT=7.130

RT (min)

RT (min)

6.75 7.00 7.25 7.50

RT (min)

4-2-FtS

Cone. 4.3251

R#1 327.00 >81.10 17.38 (16.29)
Q 327.00>307.05 (-)	2.03e5

2.0e5

O.OeO



' A=410252

_R1 17.38 (-

"^"=6.077

J

U

6.2 6.4
RT (min)

PFPeS

Cone. 5.5725

R#1 349.00>99.00 77.52 (74.42)
Q 349.00>79.95 (-)	3.38e5

f A=696218

3.0e5^R1 7752 (-™=6.165

2.0e5 :
1.0e5:
O.OeO :

6.0

6.2 6.4
RT (min)

PFHxS

Cone. 5.0487

R#1 399.00>99.00 99.00 (95.46)
Q 399.00>80.00 (-)	2.11e5

fA=544218

2.0e5HRl 99.00 (-- ! rT=6.525

O.OeO -

6.4

RT (min)

6.25 6.50 6.75 7.00
RT (min)

PFHpA

Cone. 5.1796

R#1 362.90>169.00 17.84 (17.56)
Q 362.90>319.00 (-)	2.32e6

f A=4868515

1R1 17.84 ( kT=6.523

6.6 6.8
RT (min)

6-2-FTS

Cone. 4.9367

R#1 427.00>80.90 26.78 (28.57)
Q 427.00>407.00 (-)	1.65e5

fA=352405

1.5e5^R1 26.78 (4^T=6.815

1.0e5-
5.0e4 -

O.OeO

6.6 6.8
RT (min)

PFOA

Cone. 4.6425

R#1 413.00> 169.10 31.62 (28.52)
Q 413.00>369.00 (-)	2.37e6





rA=5173612

2.0e6 -

R1 31.62 (--

-kr=6.833

1.0e6-





OOpO-



iSs*

7.0
RT (min)

ISC-

Cone.

6.6 6.8 7.0 7.2
RT (min)

PFOS

9.4937

3.72e5 Q 502.80>80.05 (-)

3.0e5 i
2.0e5 i
^.0eS1_

O.OeO 4=

3.72e5

f A=814285
RT=7.130

7.2 7.4
RT (min)

7.4
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

230

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)

Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:37

CCV8-230504 (continued)

PFNA	13C-PFNA IS

Cone. 3.8484	Cone. 5.0000
R#1 463.00>219.00 28.88 (21.80)

Q 463.00>418.90 (-)	1.40e6	ISTD 467.80>423.00 (-)

13C-PFNA

Cone. 10.0027

1.49e6 Q 467.80>423.00 (-)



rA=3118596

n

RT=7.154

:

w

O.OeO

7.0 7.2 7.4

RT (min)

13C-8 2-FTS IS

Cone. 4.7900

ISTD 528.80>509.00 (-)

A= 132421
RT=7.494

O.OeO -

7.4

ISTD 572.80>419.05 (-)
4.0e5

A= 1043415
RT=7.679



A=2620202
RT=7.849

w

7.4
RT (min)

13C-8 2-FTS

Cone. 8.5246

5.38e4 Q 528.80> 509.00 (-)

7.6 7.8
RT (min)

d3-N-MeFOSAA IS

Cone. 5.0000

d3-N-MeFOSAA

Cone. 9.4339

4.08e5 Q 572.80>419.05 (-)

O.OeO -

f A= 1043415
RT=7.679



7.6 7.8 8.0
RT (min)

13C-PFUnDA

Cone. 8.1064

Q 564.80>519.95 (-)	1.11e6

1.0e6

5.0e5

O.OeO

7.8 8.0

RT (min)

PFOSA

Cone. 4.6354

R#1 498.20>64.10 0.15 (0.10)
Q 498.20>78.00 (-)	4.03e5

40e5 -|	Y A=934508

' 1r10.15(-- rt=7.915

7.6

7.6 7.8 8.0 8.2

RT (min)

7.8

13C-FOSA IS

Cone. 5.0000

ISTD 506.00>78.05 (-)

3.0e5 ^

2.0e5 ^

1.0e5 ^

O.OeO 1. . . .

fA=3313640
[\ RT=7.154

Vj

5.38e4 Q 512.90>469.00 (-)

fA=3448259

IR1 20.74 ( [1-^1=7.499

7.6 7.8
RT (min)

3.0e5 i

R1 37.80 (—

)RT=7.684

2.0e5 i





^.0eSz
0 0<=>0 -



L,

7.8 8.0
RT (min)

PFUnDA

Cone. 3.6344

R#1 563.00>219.00 22.64(14.10)
Q563.00>518.90 (-)	8.44e5

A=1967676
7.5e51R1 2264 HHt=7.850

ISTD 588.80>419.00 (-)

~ A= 1096892
RT=7.862

V,

RT (min)

RT (min)

13C-FOSA

Cone. 8.6753

3.61 e5 Q 506.00>78.05 (-)

3.0e5 ^

2.0e5 ^

1.0e5 ^
— O.OeO

fA=827959
RT=7.915

L

8.0 8.2
RT (min)

PFNS

Cone. 4.4722

R#1 549.00 >99.00 68.41 (66.39)

1.49e6 Q 549.00>79.95 (-)

f A=1013189

4.0e5HR1 68.41 (-|UT=7.465

O.OeO	jp

7.0 7.2 7.4

RT (min)

PFDA

Cone. 5.6824

R#1 512.90>219.00 20.74(17.77)

L

13C-PFDA IS

Cone. 5.0000

1.46e6 ISTD 514.80>469.95 (-)

O.OeO

7.6 7.8
RT (min)

NMeFOSAA

Cone. 4.4723

R#1 570.20>512.00 37.80 (35.13)
Q 570.20>419.00 (-)	3.55e5

f A= 1055987

O.OeO

/

A=2749878



RT=7.499

I



7.4

7.25 7.50 7.75 8.00

RT (min)

d5-N-EtFOSAA IS

Cone. 5.0000

O.OeO -

7.6 7.8 8.0

RT (min)

d5-N-EtFOSAA

Cone. 8.7754

4.59e5 Q 588.80>419.00 (-)

A=1096892
RT=7.862

O.OeO -



7.8 8.0 8.2
RT (min)

8-2-FTS

Cone. 3.3440

R#1 527.20>487.00 9.41 (7.71)

4.32e5 Q 527.10>506.90 (-)

- R1 9.41 (—

'

RT=7.494





RT (min)

7.6 7.8
RT (min)

13C-PFDA

Cone. 7.8105

1.17e6 Q 514.80>469.95 (-)

fA=2749878
RT=7.499



7.6 7.8
RT (min)

PFDS

Cone. 4.4373

R#1 599.00>99.00 51.59 (55.44)
Q 599.00>80.10 (-)	2.89e5

fA=688598
-R1 51.59 (-4-^1=7.807

7.6 7.8
RT (min)

13C-PFUnDA_IS

Cone. 5.0000

ISTD 564.80>519.95 (-)
1.0e6-

A=2620202
RT=7.849

5.0e5

O.OeO

7.8 8.0

RT (min)
NEtFOSAA

Cone. 3.9647

R#1 584.20>526.10 67.72 (56.68)
4.59e5 Q 584.20>418.95 (-)	3.01e5

3.0e5 :
2.0e5 ^
1.0e5-
O.OeO -

A=859683

1R1 67.72 (-|rT=7.870



L

7.8 8.0

RT (min)

PFDoA

Cone. 5.8977

R#1 613.05> 169.00 18.58 (16.48)
Q 613.05>569.00 (-)	1.40e6

TA=3289599

: R1 18-58 ("frkT=8.188

7.50 7.75 8.00 8.25

RT (min)

13C-PFDoA IS

Cone. 5.0000

ISTD 614.80>569.95 (-)

8.83e5

7.5e5 :
5.0e5 :
2.5e5 :
O.OeO :

A=2101670
RT=8.188

L

B.2 8.4

RT (min)

B.2 8.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

25®

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:37

CCV8-230504 (continued)

13C-PFDoA

Cone. 7.1103

Q614.80>569.95 (-)

7.5e5 i
5.0e5 i
2.5e5 i

O.OeO 1. . . ,

A=2101670
RT=8.188



NEtFOSE

Cone. 3.8265

Q629.50>59.10 (-)
6.0e5 -

4.0e5 -

2.0e5 -

O.OeO 17

TA=1391785
RT=8.893





Q 515.10> 169.00 (-)

3.0e5 i
2.0e5 i
1.0e5i

O.OeO 1, i i r

A=880087
RT=8.671

kj

IR1 34.69 (--

A=1316609
)RT=8.796

O.OeO -



8.6

L

10-2-FtS

Cone. 0.5340

R#1 626.50>81.05 578.46 (72.12)
Q 626.50>607.05 (-)	6.93e3

4.0e4 -

- R1 578.46 (-W--)

A= 16023
RT=8.199

3.2 8.4

RT (min)

d9-EtFOSE IS

Cone. 5.0000

5.99e5 ISTD 638.90> 59.10 (-)

8.6 8.8 9.0 9.2

RT (min)

d3-NMeFOSA

Cone. 9.2015

d7-N-MeFOSE IS

Cone. 5.0000

3.70e5 I STD 623.00 > 59.00 (-)

'A=340672
RT=8.634

8.6 8.8

RT (min)

PFTeDA

Cone. 20.7256

R#1 713.00>169.30 34.69 (12.52)
Q 713.00>668.90 (-)	5.52e5

13C-PFTeDA IS

Cone. 5.0000

I STD 714.80 >669.80 (-)

A= 128131
RT=8.796

V,

9.0
RT (min)

L-PFDoS

Cone. 5.3761

R#1 698.80 >98.80 57.19 (62.67)
Q 698.80>80.10 (-)	1.61e5

fA=361208
1.5e5^R1 57.19 (-f-kT=8.455

1.0e5 -
5.0e4 ^
O.OeO :

NaDONA

Cone. 5.1850

Q 377.10>251.20 (-)

f A=4034283
| RT=6.565

d5-NEtFOSA IS

Cone. 5.0000

d5-NEtFOSA

Cone. 9.6909

I STD 531.10 > 169.10 (-)	4.56e5 Q 531.10> 169.10 (-)

A=1033566

RT=8.920	4.Qe5-

NMeFOSE

Cone. 6.5627

4.56e5 Q 616.10>58.90 (-)



O.OeO -

3.2 8.4

RT (min)

9.0 9.2
RT (min)

d9-EtFOSE

Cone. 12.9653

1.46e5 Q 638.90> 59.10 (-)

RT (min)

d7-N-MeFOSE

Cone. 7.2889

1.39e5 Q 623.00> 59.00 (-)

RT (min)

RT (min)

13C-PFTeDA

Cone. 0.8862

5.54e4 Q 714.80>669.80 (-)

^A=128131
RT=8.796

Q 631.00>451.10 (-)
4.0e5

Vo

'

fA=945193



RT=7.998





9.0

RT (min)

9.0

RT (min)

PFHxDA

Cone. 0.5093

1.99e6 Q 812.90>769.00 (-)

A= 108838
RT=9.304



PFODA

Cone. 0.5419

Q 912.80>869.00 (-)
3.0e4 -

2.0e4 -j

1.0e4^

O.OeO 1 , , ,

RT (min)

6.8

RT (min)

9.4 9.6
RT (min)

A=423917
RT=8.649

8.8 9.0 9.2
RT (min)

NMeFOSA

Cone. 4.8148

R#1 512.10>219.20 70.06 (75.56)
Q 512.10> 169.20 (-)	1.81e5

A=435459

8.4 8.6 8.8 9.0
RT (min)

d3-NMeFOSA IS

Cone. 5.0000

iSTD 515.10> 169.00 (-)

3.70e5



RT=8.671

I



8.4 8.6 8.8 9.0
RT (min)	RT (min)

NEtFOSA

Cone. 4.7049

R#1 526.50>219.20 61.04 (61.76)
1.39e5 Q 526.50> 169.10 (-)	2.98e5

8.6 8.8

RT (min)

PFTrDA

Cone. 21.4496

R#1 663.10> 169.10 48.74 (21.32)
Q 663.10>618.90 (-)	6.21 e5

: R1 48.74 (--

A=1403407
RT=8.506



8.6 8.8 9.0 9.2

RT (min)

11CI-PF30UdS

Cone. 3.6430

RT (min)

9CI-PF30NS

Cone. 3.1797

4.08e5 Q 531.00>351.10 (-)

6.0e5 :
4.0e5 :
2.0e5 :
O.OeO :

r=1

RT=

524470
RT=7.317

/

8.2

RT (min)

7.4 7.6
RT (min)

13C2-PFHxDA IS

Cone. 5.0000

3.10e4 I STD 815.00 > 770.00 (-)

A=4401430
RT=9.304



RT (min)

9.4 9.6
RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

252

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Insight Report
Quantitation/lntegration
Printed 10/25/2023 16:02:37

CCV8-230504 (continued)

13C2-PFHxDA

Cone 6.9514

Q 815.00>770.00 (-)

13C7-PFUnDA IS

Cone. 5.0000

PFBSA

Cone. 5.7493

PFecHS

Cone. 3.8465
R#1 461.00>99.10 45.77 (38.58)

2.28e6 ISTD 569.80> 524.90 (-)	5.31 e5 Q 461.00>381.00 (-)	1,48e6 Q 298.00>78.00 (-)

PFHxSA

Cone. 5.0101

1.24e6 Q 397.90>78.00 (-)

O.OeO

:

RT=9.304



L,

9.2 9.4 9.6
RT (min)

CHARGE

Cone. —

R#1 461.00>99.10 —- (0.00)

Q 514.80 > 219.10 (+)	O.OOeO

5.0e0 -

0.2
RT (min)

fA= 1259627
RT=7.849

fA=3314935

IR1 45.77 I |-^j=6.781

^=F

RT (min)

6.6 6.8 7.0

RT (min)

TA=2731866
RT=6.317

6.6
RT (min)

fA=2210216
RT=7.126

7.2 7.4

RT (min)

Z:\LabSolutions\Data\LCMS1-230504\LCMS1-230504B-537MOD_Corrected.iproc

252

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