DRAFT FINAL
Human Health Risk Assessment

Tar Creek Superfund Site

Operable Unit No. 4
Ottawa County, Oklahoma

Response Action Contract No. 68-W6-0025
Work Assignment No. 233-RKED-06JW
DCN 06-8499

Prepared for:
U.S. Environmental Protection Agency



Prepared by:
CH2MHILL

February 2006

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Table of Contents

Acronyms and Abbreviations	v

Executive Summary	vii

Source Materials	vii

Chemicals of Potential Concern	viii

Exposure Evaluation	viii

Current Residential Exposures	viii

Future Residential	ix

Recreational Activities	x

1.0 Introduction	1-1

1.1	General Obj ectives of the HHRA	1-2

1.2	Overview of the Superfund HHRA Process	1-2

1.3	Geographic Area Considered in the HHRA	1-4

1.4	Demographics of the Population	1-4

2.0 Chemicals of Potential Concern	2-1

2.1	General	2-1

2.2	Source Materials	2-2

2.2.1	Chat	2-2

2.2.2	Chat Base	2-3

2.2.3	Fine Tailings	2-3

2.3	Soils	2-5

2.4	Ground Water	2-6

2.5	Edible Plants	2-6

2.6	Fish	2-7

2.7	Selection of Chemicals of Potential Concern	2-7

3.0 Exposure Assessment	3-1

3.1	Potential Exposure Pathways and Receptors	3-1

3.2	Exposure Point Concentrations	3-1

3.2.1	Chat and Tailings	3-3

3.2.2	Soils	3-3

3.2.3	Ground Water	3-4

3.2.4	Edible Plants	3-4

3.2.5	Fish	3-4

3.2.6	Ambient Air	3-5

3.2.7	Beef	3-5

3.2.8	Small Game	3-5

3.2.9	Aquatic Life	3-6

3.2.10	Milk	3-6

3.3	Intake Estimates	3-7

4.0 Toxicity Assessment	4-1

4.1	For Non-carcinogens Other Than Lead	4-1

4.2	For Lead	4-1

4.3	For Carcinogens (Cadmium)	4-2

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5.0 Risk Characterization	5-1

5.1	Approach for Carcinogens	5-1

5.2	Approach for Non-carcinogens Other than Lead	5-1

5.3	Approach for Lead	5-2

5.4	Results	5-3

5.4.1	Current Child Resident (General Public)	5-3

5.4.2	Current Adult Resident (General Public)	5-4

5.4.3	Current Child Resident (Native American)	5-5

5.4.4	Current Adult Resident (Native American, High-Fish and
High-Beef Diets)	5-5

5.4.5	Current Adult Resident (More Typical Native American)	5-6

5.4.6	Current/Future Recreator	5-6

5.4.7	Future Child Resident (General Public and Native American)	5-6

5.4.8	Future Adult Resident (General Public)	5-7

5.4.9	Future Adult Resident (Native American)	5-8

6.0 Blood Lead Studies in Tar Creek	6-1

6.1	Datasets Reviewed	6-1

6.2	Percentage of Elevated BLLs and Geometric Mean of BLLs	6-2

6.3	Picher/Cardin in Comparison with the Tar Creek Superfund

Site as a Whole	6-3

6.4	Characteristics of Children With Elevated BLLs	6-3

6.5	Data Limitations	6-3

6.6	Interventions	6-4

6.7	Conclusions	6-4

7.0 Uncertainties	7-1

7.1	Data Evaluation	7-1

7.2	Exposure Assessment	7-1

7.2.1	Exposure Point Concentrations	7-2

7.2.2	Estimated Intakes	7-4

7.3	Toxicity Assessment	7-6

7.4	Risk Characterization	7-6

8.0 Preliminary Remediation Goals	8-1

8.1	Groundwater	8-1

8.2	Rural Residential Soil	8-2

8.2.1	General Public Rural Residential Use	8-2

8.2.2	Native American Rural Residential Land Use	8-5

8.3	Rural Non-Residential Soil/Source Material	8-8

8.3.1	Recreational Use	8-8

8.3.2	Pastureland	8-10

8.4	Food Items	8-12

8.4.1	Fish	8-12

8.4.2	Plants	8-12

8.4.3	Evaluation of Correlation Between Edible Plants and Soil	8-13

8.5	Other Rural Areas	8-16

8.6	Uncertainties in PRGs	8-17

8.7	Conclusions	8-18

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9.0 Conclusions and Recommendations
10.0 References	

,.9-1
10-1

List of Tables

Table 1-1
Table 5-1
Table 5-2
Table 5-3
Table 8-1

Table 8-2

Table 8-3

Table 8-4

Table 8-5

Table 8-6

Table 8-7

Table 8-8

Table 8-9

Table 8-10

Table 8-11
Table 8-12

Table 8-13

Table 8-14

Table 8-15

Table 8-16
Table 8-17

List of Figures

Figure 1
Figure 2

Ottawa County, Oklahoma Towns and Population, 2001
Risk Summary - General Public Exposures
Risk Summary - Native American Exposures
Risk Summary - Recreator Exposures

Cadmium - Soil PRGs Based on General Public Consumption of Homegrown
Produce

Zinc - Soil PRGs Based on General Public Consumption of Homegrown
Produce

Lead - Soil PRGs Based on General Public Adult Consumption of
Homegrown Produce

Lead - Soil PRGs Based on General Public Adult Consumption of Beef from
Cattle Grazing on Rural Residential Property

Lead - Soil PRGs Based on General Public Child Consumption of 10% of
Beef and Milk from Cattle Grazing on Rural Residential Property
Cadmium - Soil PRGs Based on Tribal Adult Consumption of Homegrown
Produce

Zinc - Soil PRGs Based on Tribal Adult Consumption of Homegrown
Produce

Lead - Soil PRGs Based on Tribal Adult Consumption of Homegrown
Produce

Lead - Soil PRGs Based on Tribal Adult Consumption of Beef from Cattle
Grazing on Rural Residential Property

Lead - Soil PRGs Based on Tribal Child Consumption of 50% of Beef and
Milk from Cattle Grazing on Rural Residential Property
Lead - Source Material PRGs Based on Recreational Adolescent Scenario
Lead - Soil PRGs Based on General Public Child Consumption of Milk from
Cattle Grazing on Pastureland

Lead - Soil PRGs Based on General Public Child Consumption of Beef from
Cattle Grazing on Pastureland

Lead - Soil PRGs Based on General Public Child Consumption of 10% of
Beef and Milk from Cattle Grazing on Pastureland

Cattail and Root Soil Correlation - Regression and Correlation Statistics for
Predictive Equations

Cattail and Root Soil Correlation - Excluded Plant-Soil Data Pairs
Mean Root Soil Concentrations at Edible Plant Sampling Locations

Tar Creek Vicinity

Residential Yard Sampling Locations

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List of Appendices

Appendix A	Split and Supplemental Sampling Summary

Appendix B	Fish Tissue Metals Analysis in the Tri-State Mining Area

Appendix C	RAGS Part D Tables

Appendix D	Air Emissions Modeling

Appendix E	Air Modeling

Appendix F	Biota Modeling

Appendix G	IEUBK Modeling

Appendix H	Adult Lead Modeling

Appendix I	Future Blood Lead Level Modeling

Appendix J	Statistical Evaluation of Future Soil Concentrations

Appendix K	Typical Native American Risk Calculations

Appendix L	ProUCL Output

Appendix M	Report to Congress

Appendix N	Preliminary Remediation Goal Calculations

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Acronyms and Abbreviations

|im

micrometer

ALM

Adult Lead Methodology

ANOVA

Analysis of Variance

AOC

Administrative Order on Consent

ARAR

Applicable or Relevant and Appropriate Requirements

ATSDR

Agency for Toxic Substances and Disease Registry

ATV

All Terrain Vehicle

BAF

Bioaccumulation Factor

BCF

Bioconcentration Factor

bgs

below ground surface

BIA

Bureau of Indian Affairs

BLL

blood lead level

CDC

U.S. Centers for Disease Control and Prevention

CDI

chronic daily intake

CERCLA

Comprehensive Environmental Response, Compensation, and Liability Act

CFR

Code of Federal Regulations

CHAMP

Community Health Action and Monitoring Program

CLPPSS

Childhood Lead Poisoning Prevention Program Surveillance System

COC

Chemical of Concern

COPC

Chemical of Potential Concern

ELCR

excess lifetime cancer risk

EPA

U.S. Environmental Protection Agency

EPC

exposure point concentration

ERA

Ecological Risk Assessment

HEAST

Health Effects Assessment Summary Tables

HHRA

Human Health Risk Assessment

HI

Hazard Index

HQ

Hazard Quotient

IEUBK

Integrated Exposure Uptake Biokinetic

IRIS

Integrated Risk Information System

LOAEL

lowest-observed-adverse-effect level

MCL

Maximum Contaminant Level

MSSL

Medium-Specific Screening Level

NCEA

National Center for Environmental Assessment

NCP

National Oil and Hazardous Substances Pollution Contingency Plan

NHANES

National Health and Nutrition Examination Surveys

NOAEL

no-ob served-adverse-effect level

OCHD

Ottawa County Health Department

OCLPPP

Ottawa County Lead Poisoning Prevention Program

ODEQ

Oklahoma Department of Environmental Quality

OSDH

Oklahoma State Department of Health

OU4

Operable Unit No. 4

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ppm

parts per million

PPRTV

Provisional Peer-Reviewed Toxicity Values

PRG

Preliminary Remediation Goal

PSCS

Preliminary Site Characterization Study

QAPP

Quality Assurance Project Plan

RfC

reference concentration

RfD

reference dose

RI/FS

Remedial Investigation/Feasibility Study

RME

reasonable maximum exposure

SF

Slope Factor

TAL

Target Analyte List

TEAL

Tribal Efforts Against Lead

UCL95

95% Upper Confidence Limit

WIC

Women, Infants, and Children

WP

Work Plan

TAR CREEK SUPERFUND SITE
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Executive Summary

On December 9, 2003, the United States Environmental Protection Agency (EPA) entered
into an Administrative Order on Consent (AOC) with the Respondents for Operable Unit 4
(OU4) at the Tar Creek Superfund Site (the Site) in Ottawa County, Oklahoma (EPA, 2003).
The site is shown on Figure 1, which has been provided by the Respondents in their Data
Gaps Analysis Report (AATA, 2004). As part of this agreement, EPA agreed to complete the
Baseline Risk Assessment that included a Human Health Risk Assessment (HHRA) and an
Ecological Risk Assessment (ERA). Under the agreement, the Respondents were responsible
for completing a Remedial Investigation/Feasibility Study (RI/FS) of OU4 that also included
providing EPA with data necessary to complete the risk assessments.

The AOC defines OU4 as the:

"noncontiguous, asymmetrical parts of the Site (both urban and rural) that are not
presently usedfor residential purposes or which are sparsely usedfor residential
purposes, where mine and mill residues and smelter waste have been deposited,
stored, disposed of, placed, or otherwise come to be located as a result of mining,
milling, smelting or related operations. OU4 includes residential yards located in
Ottawa County outside of city or town limits except for those residential yards that
have been addressed under Operable Unit 2 (OU2)."

CH2M HILL was contracted by EPA to complete the HHRA for OU4 under Contract No.
68-W6-0025. The ERA was to be performed by others at EPA's direction. The HHRA work
was completed through an approved project work plan (WP) and subsequent work plan
revisions under Work Assignment No. 233-RKED-06JW (CH2M HILL, 2004, 2005a, and
2005b). Under this work assignment, CH2M HILL was directed to perform additional
activities associated with the Respondents' RI/FS, which are further discussed in Appendix A.

This HHRA considers potential hazards to current residents (both general public and Native
American), and possible limitations on future residential or recreational activities within OU4.

Source Materials

Several residual mining materials in the area have been shown to have elevated
concentrations of metals - particularly lead, cadmium, and zinc. Levels of these chemicals
of potential concern (COPCs) in source materials frequently exceed values that are
considered protective for residential uses. These materials (mine tailings, chat) are
distributed within the OU4 Area, and in some cases, these materials have been used as fill
material on rural residential properties. The primary waste areas (chat piles, millponds, and
chat bases) are located throughout OU4, covering approximately 10 percent of the land in this
area.

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Chemicals of Potential Concern

Lead is the primary COPC. Cadmium and zinc have also been identified as COPCs in the
AOC. Lead and/or cadmium exceeded residential screening values at only eight residential
yards evaluated during the RI, and one residential yard (at the former smelter) was
subsequently remediated. Zinc concentrations were less than residential screening values in
residential yard samples.

In 10 percent of the samples, Target Analyte List (TAL) metals were analyzed. Although six
metals were detected in soil above their Medium-Specific Screening Level (MSSL), they are
either primarily associated with the smelter area, were only detected at a few locations above
their MSSLs and background concentrations, or do not appear to be mining-related. These
data support the focus on the COPCs, and specifically lead. Children are particularly
sensitive to lead exposure and, historically, elevated blood lead levels in children have been
measured in the Tar Creek area.

Exposure Evaluation

The potential hazards for residents in the OU4 area are dependent on their proximity to
source areas (where elevated concentrations of lead have been identified) and their activities
in these areas. At rural residential properties, the public may be exposed directly through
breathing airborne contaminants or contacting contaminated soil. Increased exposures are
associated with Native American exposure scenarios due to their cultural practices of
hunting, gathering, ceremonial practices, and use of natural resources for crafts, medicines,
and foods.

While data have been collected to evaluate properties that are currently under residential land
use, it is clear that elevated lead concentrations in waste source areas make them unsuitable
as future rural residential areas in their current condition. Impacted areas of soil near these
source areas generally decrease with distance; however, over time, redistribution of the waste
to a larger area may occur with physical activities in the area.

Current Residential Exposures

Each residential property sampled for the Tar Creek OU4 investigation was evaluated for
contact with impacted soil, ground water (if a private well is present), and ambient air. The
primary exposure occurs through contact with soil.

•	Only seven homes were associated with one or more surface soil (0-1 inch or 0-6
inch) samples with concentrations above the lead remedial goal of 500 mg/kg for
private properties. Four of these were clearly associated with likely sources:

o One was immediately adjacent to the former Ottawa smelter (and this

residential yard was subsequently remediated in November 2005)
o Three others showed visible chat fragments.

•	The homes with the highest soil concentrations were not located near each other, and
in some cases, nearby homes did not show elevated concentrations.

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• At some locations, an elevated lead concentration was present in an isolated sample;
further evaluation may be needed to clarify if the lead-impacted soil sample is
attributable to mining sources.

For the general public scenarios evaluated, cadmium and zinc concentrations were within
acceptable risk levels, but for the Native American residents, the concentrations exceeded
acceptable risk levels due to estimated intakes from food items. Lead concentrations
exceeded the target blood lead level (BLL) at four individual residences, but the
neighborhood average BLL is within the target range. The residence with the highest
exceedance (at the former smelter) was subsequently remediated in November 2005.

Concentrations of lead, cadmium, and zinc at many of the rural residential properties
sampled were similar to background. In all cases, lead was the primary COPC. Cadmium
concentrations were elevated above residential screening levels at only four properties, and
one property (the same home at the former smelter, mentioned above) was subsequently
remediated in November 2005. With the exception of one property, lead concentrations were
also elevated at these properties and associated sources were identified. Zinc did not exceed
soil screening values at any location.

Modeled air lead concentrations at the 46 residences were all below the National Ambient
Air Quality Standard (NAAQS) (1.5 |ig/m3), and were a minor contributor to the overall
estimate of hazard at these homes.

Ground water samples were collected at locations where shallow private wells were being
used, not necessarily where homes were located near source areas. Of the 13 residential
wells sampled, two slightly exceed tap water MSSLs for lead (i.e., the maximum detected
concentration was 0.028 |ig/L versus 0.015 |ig/L). These properties were located near each
other, but homes sampled in these areas did not show elevated concentrations of lead in soil.
Cadmium and lead were detected above background in these wells, suggesting potential
mining-related impacts. Exposures to groundwater were quantified in the HHRA by both
general public and Native American residents. The HHRA does not address future uses of
impacted shallow groundwater at locations other than those sampled as part of OU4, and
restrictions on potable use of shallow groundwater may be warranted in other locations.

There is the potential for future concentrations in the wells to increase. If concentrations
remain low, no additional risks will be identified. However, because lead concentrations are
currently above the MCL at two wells, the cause of the elevated levels and the need for an
alternative water supply should be evaluated.

Native American lifestyle differences, including gathering plants grown on, or hunting
animals that feed near, source areas will increase exposure to COPCs in soils. These
activities may not be suitable in locations with elevated concentrations of lead that may
otherwise be protective using assumptions appropriate for the general public.

Future Residential

Many areas in OU4 are not suitable for future residential development without remedial
actions to decrease surface concentrations of lead. The challenge for the Tar Creek OU4 area
is that waste materials are distributed in many locations throughout this large area, and may

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comprise up to 10 percent of the total land area based on current data showing the
distribution of waste and associated contaminated soils nearby (i.e., transition zone soils). In
addition, it is likely that some changes in soil impacts will occur over time. It is also possible
that chat has been used in localized areas as fill material, and would not clearly be identified
by the proximity of these areas to current locations of chat piles or mill ponds.

The following assumptions are made regarding possible future residential development
within the OU4 area:

•	Waste materials will continue to contain elevated levels of lead, cadmium, and zinc
(unsuitable for residential use).

•	Areas near waste sources will show elevated soil concentrations; modeling indicates
that soil lead concentrations could be as high as 18,900 parts per million (ppm) and air
concentrations could be as high as 0.18 |ig/m3; air concentrations do not exceed the
NAAQS and are not a concern.

•	If the waste piles remain, over time, the impacted area of soils may increase if physical
activities distribute source materials.

•	The closer that homes are placed to source areas, the more the likelihood increases that
these materials may be more accessible, particularly for adolescents who may play in
these areas.

Current data suggest that typically within 300 feet of a source area, soil concentrations
significantly decrease. The 56 soil samples collected from non-residential rural areas in
December 2005 indicate that lead concentrations are near background at locations not
immediately adjacent to source materials.

Recreational Activities

Assuming daily recreational activities on chat piles, chat bases, and mill ponds when weather
permits, BLLs exceed EPA's target level. Potential hazards associated with waste materials
are reduced if activities in these areas are less frequent. Therefore, areas that may not be
suitable for residential use (350 days/year for 30 years) may be within acceptable risk levels
for less frequent recreational activities.

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1.0 Introduction

On December 9, 2003, the United States Environmental Protection Agency (EPA) entered
into an Administrative Order on Consent (AOC) with the Respondents for Operable Unit 4
(OU4) at the Tar Creek Superfund Site (the Site) in Ottawa County, Oklahoma (EPA, 2003).
The site is shown in Figure 1, which has been provided by the Respondents in their Data
Gaps Analysis Report (AATA, 2004). As part of this agreement, EPA agreed to complete the
Baseline Risk Assessment that included a Human Health Risk Assessment (HHRA) and an
Ecological Risk Assessment (ERA). Under the agreement, the Respondents were responsible
for completing a Remedial Investigation / Feasibility Study (RI/FS) of OU4 that also
included providing EPA with data necessary to complete the risk assessments.

The AOC defines OU4 as the:

"noncontiguous, asymmetrical parts of the Site (both urban and rural) that are not
presently usedfor residential purposes or which are sparsely usedfor residential
purposes, where mine and mill residues and smelter waste have been deposited,
stored, disposed of, placed, or otherwise come to be located as a result of mining,
milling, smelting or related operations. OU4 includes residential yards located in
Ottawa County outside of city or town limits except for those residential yards that
have been addressed under Operable Unit 2 (OU2)."

The remedial objectives of the 1984 ROD were to mitigate the potential threat to public
health and the environment by preventing contamination of the Roubidoux Aquifer, and by
minimizing damage to Tar Creek from acid mine drainage. The remedy selected in the 1984
ROD included diversion of surface flows at three mine collapse features, and also included
the plugging of 66 Roubidoux wells (later increased to 83 during construction). The scope of
the 1984 ROD did not address public health concerns related to direct exposure to the mining
waste located on the ground surface as addressed in this risk assessment.

CH2M HILL was contracted by EPA to complete the HHRA for OU4 under Contract No.
68-W6-0025. The ERA was to be performed by others at EPA's direction. The HHRA work
was completed through an approved project work plan (WP) and subsequent work plan
revisions under Work Assignment No. 233-RKED-06JW (CH2M HILL, 2004, 2005a, and
2005b). Under this work assignment, CH2M HILL was directed to perform the following
additional activities associated with the Respondents' RI/FS, which are further discussed in
Appendix A:

•	Perform limited oversight of the Respondents' sampling efforts.

•	Collect split samples of the Respondents' samples.

•	Collect supplemental samples in support of the HHRA and, to a limited extent, the
ERA.

•	Collect edible plant samples requested by the Quapaw Tribe.

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1.1	General Objectives of the HHRA

The objectives of an HHRA are two-fold: first, to estimate the level of risk to human health
associated with concentrations of environmental contaminants; and second, if that risk is
found to be unacceptable, to calculate media-specific cleanup levels that will protect human
health.

Risks are estimated for current uses of a site as well as foreseeable future uses. All
contaminated media are considered (such as soil and water) if individuals are likely to be
exposed to the media. All relevant routes of exposure are also considered, including direct
contact (inhalation, ingestion, dermal exposure) and indirect contact (exposure to food items
that have accumulated contaminants through the soil).

Cleanup levels are calculated based on the relationship between contaminants and risk as
defined in the risk assessment and a policy decision (risk management) about the level of risk
that is considered acceptable. As a result, cleanup levels for a single contaminant can vary
from one site to another either because the relationship between environmental levels and
risk differs or because different policy decisions have been made concerning the level of
acceptable risk.

For this specific HHRA, the general public and Native American cultural practices (via a
subsistence receptor scenario) are addressed in the risk estimates.

1.2	Overview of the Superfund HHRA Process

An HHRA typically is described as including four steps: data collection and analysis,
exposure assessment, toxicity assessment, and risk characterization. The first step includes
collecting data on the characteristics of the site and the COPCs.

The second step in an HHRA involves exposure assessment, including identifying the
populations of individuals exposed to hazards at the specific site and how those exposures
may occur. At OU4, the HHRA identifies the general public and local Native Americans as
primary populations of concern for lead, cadmium, and zinc exposure. Potential pathways of
exposure are defined, such as children ingesting soil and house dust, and Native Americans
eating locally-grown foods within their tribal jurisdictions. In addition to identifying the
potential pathways of exposure, this step involves defining several parameters (for which
there are insufficient measured data) that govern the estimated risk from each exposure
pathway. These assumptions, or default values, are assumed to be representative of a
population, although they often include a conservative safety factor. These parameters
include things such as time spent indoors and outdoors.

The third step is toxicity assessment, or identifying and quantifying a chemical's intrinsic
toxic properties. Again, at this point in the development of risk assessment, based on
numerous controlled animal and/or human experiments and on epidemiological studies,
toxicity parameters have been established by EPA and other agencies for many chemicals. At
times, when a great deal of information is known about a chemical's toxicity, this step
involves examining an EPA database for the chemical-specific cancer slope factor (SF) or
reference dose.

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The fourth step, risk characterization, combines the results of the first three steps into an
estimate of risk. The estimated risk is then compared with a level of risk deemed
"acceptable" according to risk management decisions (see below) and the site is thereby
identified as either having acceptable risk levels or in need of remedial measures.

All the risk assessment steps described above inherently incorporate uncertainty. Each of the
steps generally involves extrapolation from observations in one set of circumstances (such as
the effect of known, high doses of a chemical given to laboratory animals over a short
period) to the circumstances of interest (such as the potential effects of unknown, small doses
of a mixture including the tested chemical on humans over a lifetime). Each such
extrapolation introduces qualitative and quantitative uncertainties; and an adequate HHRA
describes qualitatively, and if possible quantitatively, the sizes and types of such
uncertainties.

EPA's preferred focus is on the individual with reasonable maximum exposure (RME). .
EPA defines RME as the highest exposure that is reasonably expected to occur at a site. The
RME risk is compared with the acceptable level of risk when determining whether remedial
measures are needed.

If risks are found to be unacceptable, thus requiring remediation, then the models used in the
risk assessment are also used to determine acceptable concentrations of contaminants,
equated to "cleanup levels." It is important to note that a cleanup level calculated in this way
is applicable over the same geographic area as was assessed in the risk calculation and
represents the same mathematical formulation used for the concentration term in the risk
assessment. For example, if the chronic risk to a child exposed over several years to the
average contaminant concentration in his/her yard is found to be unacceptable, then a cleanup
level derived from the corresponding risk equation will represent the acceptable average
concentration for soil in the yard. As a further example, if a risk calculation focused solely on
a heavily-used play area finds unacceptable risk, the cleanup level calculated from that risk
equation will represent the acceptable average concentration for the play area. However, the
derivation of an actual cleanup level is typically controversial, partly due to the uncertainties
associated with each piece of information that goes into the mathematical derivation of the
cleanup number.

Finally, a distinction needs to be drawn between risk assessment and risk management.
Simply put, risk assessment is scientific and involves identifying pathways of exposure and
some mathematical calculations; risk management involves policy and societal values.
Cleanup levels are calculated on the basis of a policy decision about the level of acceptable
risk as well as on the basis of the mathematical risk assessment. Further, the assessment of
uncertainty in a risk assessment may lead to the development of more than one possible
cleanup level, or a range of cleanup levels. A risk manager will choose a cleanup level from
the range, after considering other site characteristics such as technical feasibility of the
remediation, public desires, and so forth. As a result, a cleanup level may not be directly
linked to an actual risk calculation, but it is generally expected that the cleanup level chosen
during the risk management process will fall within a range developed in the course of the
risk assessment.

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1.3 Geographic Area Considered in the HHRA

The Site is a former lead and zinc mining area located in the northern portion of Ottawa
County, Oklahoma. This area is part of the Tri-State Mining District located at the junction
of Oklahoma, Kansas, and Missouri. The Site has no clearly defined boundaries, but occupies
approximately 40 square miles consisting of the Ottawa County, Oklahoma, portion of the
Picher Field mining region and any area where a hazardous substance from mining or milling
in Ottawa County has been stored or disposed. The Site is bound to the north by the State of
Kansas. The principal communities include Cardin, Commerce, North Miami, Picher, and
Quapaw. Approximately 19,556 people live onsite in the mining area and in communities in
proximity to the mining area (EPA, 2004). Additional information regarding the Site history
is presented in the AOC under Section VI - EPA's Findings of Fact (EPA, 2003).

As a result of mining and milling operations, large quantities of tailings were deposited on
the surface of the ground in piles, locally known as "chat piles" (some of which rise to a
height of 200 feet) and in ponds, or "flotation ponds." Most of the flotation ponds are now
dry. Figure 1 presents the Site boundaries and topography (AATA, 2004).

AATA (2004) summarized residual mining materials remaining on soils (source materials) as
follows:

Source
Material

Chat Piles

Number

83

Approximate
Area (Acres)

767

Chat Base

243

2080

Tailing Ponds 63

820

Comment

Chat is the larger particle sized tailings from the gravity
separation milling process used in the Tri-State Mining
District and consists of mainly fine gravel to coarse
sand sized rock fragments plus minor amount smaller
intermingled material such as medium to fine sands,
silt, and clay. Chat was typically deposited in large
piles, collectively referred to as "chat piles."

Area that was once occupied by a chat pile. Chat
bases can be either vegetated or non-vegetated, and
generally have little or no relief. Thickness of
remaining chat range from inches to a few feet
(average estimated at 2 feet)

Flotation tailings were generated during the metal
extraction process or milling; washed fines were
generated later as a by-product during washing of chat
for commercial aggregate sale. Almost all the flotation
tailings at the Site are covered with washed fines, and
portions contain only washed fines.

1.4 Demographics of the Population

The Respondents have researched the demographics of the Site and presented them in the
approved Data Gaps Analysis Report (AATA, 2004). Below are excerpts taken directly from
the report:

The Tar Creek Task Force (2000), the State of Oklahoma Web site, and the US Census
Bureau Web site were the primary sources of data consulted for the demography section.

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Ottawa County has a land area of 471 square miles. The Site is about 40.6 square miles
(about 8.6 percent of the county) located in the northeast corner of the county. The Site is
mostly used for agriculture and is sparsely populated.

The U.S. Census Bureau estimates that the population of Ottawa County in 2001 was 33,046
people (U.S. Census Bureau, 2004). Table 1-1 provides a list of the primary towns in
Ottawa County and their populations in 2001.

Table 1-1

Ottawa County, Oklahoma Towns and Population, 2001
Tar Creek OU4 Superfund Site

Town

Population

Afton

945

Cardin

175

Commerce

2,451

Fairland

904

Miami

12,760

N. Miami

448

Peoria

151

Picher

1,674

Quapaw

985

Wyandotte

361

Rural**

12,192

Total for Ottawa County

33,046

* Source: State of Oklahoma Web site: www.state.ok.us/osfdocs/cities.html
** Source: Result of subtracting urban population from total population.

The 2000 census results indicate that 72.9 percent of the population in Ottawa
County were Caucasian, 16.5 percent were Native American, 3.2 percent were
Hispanic / Latino, 0.6 percent were African American, and 0.3 percent were Asian
(U.S. Census Bureau, 2004). Most people (nearly 75 percent) own their own
home in Ottawa County (U.S. Census Bureau, 2004). The median household
income for Ottawa County in 1999 was $27,507 (U.S. Census Bureau, 2004).

Land use for the Site has been summarized by Luza (1986) and Brown and Root
(1995). Land uses within the Site include agriculture, residential, light industry,
commercial activities or businesses, and recreational uses, with agriculture being
the dominant land use. Brown and Root (1995) classified the primary land uses at
the Site to include the following:

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1.	Agricultural, including crop farming and pasture grazing;

2.	Residential, including homes, schools, nursing homes, government housing,
churches, playgrounds, day care center, others;

3.	Industrial, including chat mining, asphalt plants, sand and gravel plants, light
industrial and fabrication plants;

4.	Commercial, including small businesses such as grocery stores, florists,
numerous retail shops;

5.	Recreational, including ball fields, dirt bike riding, fishing, hunting, and golf.

In the mid-1980s, approximately 2,900 acres of the land surface of the Site (about
11.2 percent) was covered by mine and mill residue (Luza, 1986), as discussed in
Section 2.4.

Recreational land use in Ottawa County include fishing, hunting, golf, Softball,
soccer, and dirt bike riding (some on areas with chat piles) (Brown and Root,
1995). Southeast of the Site is Grand Lake, or Lake o' the Cherokees, a
swimming, boating, camping, and outdoor recreation area. Brown and Root (1995)
summarized the land ownership of the Site as (1) private, (2) government, or
(3) Native American-owned. Figure 18 of the Data Gaps Analysis Report presents
a map of the Bureau of Indian Affairs (BIA) trust lands within the Site, provided
by EPA. The land owned by Native Americans accounts for approximately 18.2
percent of the overall area of the Site. A much higher percentage of land (40 to
50 percent) upon which mining residues remain is Native American-owned
(Brown and Root, 1995).

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2.0 Chemicals of Potential Concern

The Final Data Gaps Analysis Report approved by EPA (AATA, 2004) stated "The mining
and milling of lead and zinc ores since the late 1800s has generated mining and milling
residue that contain elevated concentrations of lead, cadmium, and zinc." These three metals
have remained a focus of subsequent investigations characterizing impacts from mining
activities.

This section provides an overview of the data collected and used to evaluate potential risks
associated with receptors in OU4. This includes a discussion of the overall approach and data
collection / evaluation process, a summary of results by environmental medium, and
documentation that lead, cadmium, and zinc remain the COPCs.

2.1 General

Data used in support of the HHRA were obtained from the Respondents' Draft Preliminary
Site Characterization Summary (PSCS) Report (AATA, 2005) and supplemental sampling
and analysis performed by EPA. A description of the Respondent's sampling program, as
well as a comparison to EPA's split and supplemental sampling program, is summarized in
Appendix A.

In accordance with the project WP and the Quality Assurance Project Plan (QAPP), all
analytical data obtained in support of this project were validated according to EPA's National
Functional Guidelines for Inorganic Data Review (EPA, 2004). Sample results were assigned
data qualifiers in the validation process to express the degree of usability based upon overall
data quality. In cases where serious quality control failures were encountered, the data were
rejected and were not used to support project decisions.

The database of environmental chemical analyses available for the HHRA process was
extensive and included hundreds of analyses of metals in chat, tailings, soil, ground water,
fish, and edible wild plants (asparagus, willow, and cattail) in the Tar Creek area. The
following activities are consistent with the approved WPs:

•	The geographic location for each sample was documented.

•	Concentrations of cadmium, lead, and zinc were typically measured.

•	For 10 percent of the samples, a more extensive TAL of metals was analyzed.

For surficial samples to be used for risk estimates, samples were sieved to obtain soil
particles less than 250 micrometer (|im) in diameter prior to chemical analysis. Pre-sieving is
justified by the observation that fine particles preferentially adhere to hands (Duggan et al.
1985; Duggan and Inskip 1985; Sheppard and Evenden 1994; Kissel et al., 1996) and the
assumption that they are, therefore, more likely to be ingested. This is a primary
consideration in decisions regarding what data is to be used in the HHRA for characterizing
potential current risk from incidental ingestion.

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The available data provide a substantial and representative environmental database for the
risk assessment process. However, because of the large geographic area, additional studies of
specific areas may be required as remediation proceeds or land use changes are considered.

Not all substances present at sites pose a human health risk. For example, some of the metals
present in environmental samples from the Tar Creek OU4 are essential nutrients, including
zinc. Yet even zinc, in excess, can pose health risks. Thus, EPA has developed guidelines for
selecting a group of COPCs based on their toxicity, concentration, and other factors (EPA,
1989). Typically, applicable or relevant and appropriate requirements (ARARs) are used to
compare the observed concentration of a substance in an environmental sample with some
screening value, threshold, or legally-defined concentration in that environmental medium.
For example, the ARARs for drinking water at this site are actually the EPA maximum
contaminant levels (MCLs)—concentrations of substances in drinking water above which
unacceptable health risks to the public may occur. The only ARAR for substances in air that
is relevant at this site is that for lead—the National Ambient Air Quality Criterion for lead.
There are no ARARs at this site for substances in chat, tailings, soil, or biota.

The HHRA considers which COPCs might pose a human health risk for each medium of
possible exposure: chat, tailings, soil, tap water, air, fish, edible aquatic organisms, beef,
milk, small game, and three edible plants (asparagus, willow, and cattail). The process used
was very typical of any HHRA at sites where chemical exposures might occur. It also
considers possible risks due to the ingestion of wild asparagus, willow, and cattail, culturally-
important food sources for Native Americans in the area. Because a "screening value" for
chemicals in edible plants is not known, cadmium, lead, and zinc were evaluated as
chemicals with possible risk, a decision consistent with the evaluation of other food
substances.

In summary, the HHRA appropriately identified COPCs for each potential source of
exposure. However, no effort was made to identify the particular chemical species of lead (or
other metal) in any of these sources. The absence of chemical speciation is less than ideal
because the bioavailability and toxicity of particular chemical species of the same metal can
vary substantially. However, the bioavailability of lead in soil was evaluated at the Jasper
County, Missouri Superfund Site, a similar site to Tar Creek OU4 in terms of waste sources
and environmental conditions (Casteel et al., 1996). Results indicate bioavailability in the
range of 29 to 40 percent. Therefore, the default bioavailability (30 percent) used in this
HHRA is expected to be an appropriate estimate for the site.

The following sections summarize data used in the HHRA by medium.

2.2 Source Materials

2.2.1 Chat

Samples that were representative of chat, or chat piles, were collected by the Respondents as
part of their sampling program. A total of 20 chat piles were sampled. The Respondents
defined chat material as bulk chat or surface chat, depending on the depth at which the
samples were collected. Bulk chat (160 samples) were collected 1 foot below ground surface
(bgs), while surface chat (14 samples) were collected from 0 to 1 inch. Bulk chat and surface

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chat samples were prepared or processed differently before analysis. Bulk chat samples were
crushed and ground to pass through a #100 mesh sieve prior to analysis. These data were not
used to characterize current risks associated with receptors contacting these materials;
however, they were used in estimating emission factors for air quality modeling.

Concentrations of lead in these 168 bulk samples ranged from 210-4,980 mg/kg; cadmium 41.3
to 199 mg/kg, and zinc from 10,200 to 40,300 mg/kg.

Surface chat samples were sieved using a #60 mesh sieve, and the material passing the sieve
was analyzed. These 14 surface chat samples were used in support of the HHRA due to the
depth at which they were collected and the method by which they were prepared (for
example, sieving using a #60 mesh) prior to analysis. Lead concentrations in these 14
samples ranged from 355 to 1,730 mg/kg; cadmium from 40 to 133 mg/kg; and zinc from
8,990 to 29,900 mg/kg.

Sixty-four supplemental samples of chat were collected by EPA and were collected from 0 to
6 inches. The samples were sieved using a #60 mesh sieve and the material passing the sieve
was analyzed. These samples were used in support of the HHRA due to the depth at which
they were collected and the method by which they were prepared (sieving using a #60 mesh)
prior to analysis. Lead, cadmium, and zinc were detected in each of these samples. Lead
concentrations in these 64 samples ranged from 162 to 6,410 mg/kg; cadmium from 38.4 to
346 mg/kg; and zinc from 6,260 to 100,000 mg/kg.

2.2.2	Chat Base

Samples that were representative of chat base, or the former remnants of larger chat piles,
were collected by the Respondents as part of their sampling program. A total of six chat
bases were sampled. 22 chat base samples were collected by the Respondents at 1 foot bgs
and were crushed and ground to pass through a #100 mesh sieve prior to analysis. These
samples were not used in the HHRA because of the depth at which they were collected and
the methods by which they were processed.

Twenty-four supplemental samples of chat base were collected by EPA and were collected
from 0 to 6 inches. These 24 samples were sieved using a #60 mesh sieve and the material
passing the sieve was analyzed. These samples were used in support of the HHRA due to the
depth at which they were collected and the method by which they were prepared (sieving
using a #60 mesh) prior to analysis. Concentrations of lead in these samples ranged from 552
to 9,600 mg/kg; cadmium from 36.8 to 172 mg/kg; and zinc from 5,690 to 54,300 mg/kg.

2.2.3	Fine Tailings

Fine tailings, also commonly referred to as "tailing ponds" or "mill ponds," were sampled by
the Respondents as part of their sampling program. The fine tailings that were collected were
categorized as washed fines, flotation tailings, or surface fine tailings, based upon the
material collected and the depth of sample collection. Definitions of each are presented in the
Respondents' Draft PSCS Report (AATA, 2005). A total of 169 fine tailings samples were
collected by the Respondents, which included 96 washed fines samples, 53 flotation tailings
samples, and 13 surface fine tailings samples.

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2.2.3.1	Washed Fines

The Respondents collected depth-integrated composite samples of washed fines from 10 fine
tailings ponds. These 96 samples were not used in the HHRA because they were collected as
a composite over a depth interval (usually 1 foot or more) and were not sieved using a #60
mesh sieve prior to analysis. Concentrations of lead in the washed fines ranged from 220 to
26,600 mg/kg, cadmium ranged from 10 to 320 mg/kg, and zinc ranged from 1,730 to 70,000
mg/kg.

Supplemental samples of washed fines were collected by EPA from 0 to 6 inches. The
samples were sieved using a #60 mesh sieve and the material passing the sieve was analyzed.
These 38 samples were used in support of the HHRA due to the depth at which they were
collected and the method by which they were prepared (sieving using a #60 mesh) prior to
analysis. Concentrations of lead in these 38 samples ranged from 306 to 24,500 mg/kg;
cadmium from 11.5 to 214 mg/kg; and zinc from 1,760 to 43,300 mg/kg.

2.2.3.2	Flotation Tailings

The Respondents collected depth-integrated composite samples of flotation tailings from 10
fine tailings ponds. These 53 samples were not used to estimate risks from direct contact
exposures in the HHRA because they were collected as a composite over a depth interval
(usually 1 foot or more) and were not sieved using a #60 mesh sieve prior to analysis. These
data were considered in the emissions estimates for air modeling. Lead concentrations in
these 53 flotation tailing samples ranged from 1,130 to 17,800 mg/kg; cadmium from 26.3 to
450 mg/kg; and zinc from 4,690 to 103,000 mg/kg.

Supplemental samples of flotation tailings were collected by EPA from 0 to 6 inches. The
samples were sieved using a #60 mesh sieve and the material passing the sieve was analyzed.
These samples were used in support of the HHRA due to the depth at which they were
collected and the method by which they were prepared (sieving using a #60 mesh) prior to
analysis.

2.2.3.3	Surface Fine Tailings

The Respondents collected surface fine tailings as part of their sampling program. These
samples were collected from 0 to 1 inch and were sieved using a #60 mesh prior to analysis;
therefore, these 13 samples were used in support of the HHRA. In general, the surface fine
tailing samples collected by the Respondents were of washed fines, which are typically found
overlying flotation tailings at the Site. Concentrations of lead in these 38 samples ranged
from 306 to 24,500 mg/kg; cadmium from 11.5 to 214 mg/kg; and zinc from 1,760 to 43,300
mg/kg.

Supplemental samples of surface fine tailings were collected by EPA from 0 to 6 inches. The
34 samples were sieved using a #60 mesh sieve and the material passing the sieve was
analyzed. These samples were used in support of the HHRA due to the depth at which they
were collected and the method by which they were prepared (sieving using a #60 mesh) prior
to analysis. Concentrations of lead in these 34 samples ranged from 360 to 24,600 mg/kg;
cadmium from 27.9 to 301 mg/kg; and zinc from 3,800 to 59,500 mg/kg.

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2.3 Soils

The Respondents collected background, transition zone, smelter-affected, and rural
residential yard soil samples as part of their sampling program. Complete details regarding
their soil sampling efforts are provided in their Draft PSCS Report (AATA, 2005). In
addition, supplemental samples were collected by EPA in non-residential rural areas, away
from source materials.

2.3.1.1	Background Soils

The Respondents collected seven soil samples to evaluate background concentrations for
metals. These samples were collected from 0 to 6 inches and were not sieved. The
background values determined by the Respondents are considered in the HHRA. The average
background concentrations were used for data comparisons in the screening process, and for
use in bio-uptake modeling (Appendix F). These were 0.73 mg/kg for cadmium; 31.25
mg/kg for lead, and 83.25 mg/kg for zinc.

2.3.1.2	Transition Zone Soils

The Respondents collected soil samples along transects that extended from the base of chat
piles outward. Transects were generally located on the north and south sides of the pile and
extended as far as 300 feet away from the pile. Transects were established at a total of five
chat piles, with two transects per pile. The soil samples were collected at varying depths that
included 0 to 1 inch, 6 inches, 12 inches, and 24 inches. Samples from the 0 to 1 inch interval
were sieved using a #60 mesh sieve and the fraction passing the sieve was analyzed. The 0 to
1 inch samples were used in support of the HHRA.

Supplemental samples of transition zone soils were collected by EPA from 0 to 6 inches. The
samples were sieved using a #60 mesh sieve and the material passing the sieve was analyzed.
These samples were used in support of the HHRA due to the depth at which they were
collected and the method by which they were prepared (sieving using a #60 mesh) prior to
analysis.

2.3.1.3	Smelter-Affected Soils

The Respondents collected soil samples along transects that extended from the origin of the
former Ottawa smelter area outward. Transects were located to the north and south sides of
the smelter area, with the south transect extending 5,000 feet. Transects to the north were
extended until physical obstructions or limitations prevented further extension. All samples
were collected from 0 to 1 inch and were not sieved prior to analysis. Although the samples
were not sieved, they were used in support of the HHRA due to the need for additional
samples to characterize the area.

Supplemental samples of smelter-affected soils were collected by EPA from 0 to 6 inches.
The samples were sieved using a #60 mesh sieve and the material passing the sieve was
analyzed. These samples were used in support of the HHRA due to the depth at which they
were collected and the method by which they were prepared (sieving using a #60 mesh) prior
to analysis.

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2.3.1.4	Rural Residential Yard Soil

The Respondents collected soil samples at rural residential properties—44 on private land
and two on BIA land (Figure 2). The samples were collected from 0 to 1 inch and 0 to 6
inches. The samples collected from 0 to 1 inch were sieved using a #60 mesh sieve and
therefore were utilized in support of the HHRA. The samples from 0 to 6 inch depths were
not sieved and, therefore, were not used in the HHRA. It is noted that in some cases, higher
concentrations of lead and zinc were identified in the 0-6 inch interval samples (Appendix
A). Supplemental samples of rural residential yard soil were not collected by EPA.

The highest lead concentration in surface soil samples (8,200 mg/kg) was reported from
61220 East 20 Road, which is located immediately adjacent to the former Ottawa smelter.
Smelter-affected surface soil at this location was remediated in November 2005 and no
longer remains at this location. Therefore, the samples from this location were excluded from
the data used in the updated risk calculations (Appendix C).

Furthermore, the Respondents collected soil samples at one additional residential yard (1301
S. 592 RD) in October 2005. The samples were collected from 0 to 1 inch and 0 to 6 inches.
The samples collected from 0 to 1 inch were sieved using a #60 mesh sieve and, therefore,
were used in support of the HHRA. These additional samples were also included in the data
used in the updated risk calculations (Appendix C).

2.3.1.5	Rural Area Soil

EPA collected 56 soil samples from non-residential rural areas away from potential source
materials in December 2005 to characterize area-wide soil concentrations across the site
(Appendix A). Samples were collected from 0 to 1 inch. The samples were sieved using a
#60 mesh sieve prior to analysis. The fraction passing the sieve was analyzed for lead only
by an outside laboratory (EMAX). These samples were used in support of the HHRA in the
updated risk calculations (Appendix C).

2.4	Ground Water

Fourteen shallow private wells were identified in OU4. The Respondents collected ground
water from 13 rural, shallow domestic wells from residences located within the Site
boundaries, 12 on private land and one on BIA land. These samples were used in support of
the HHRA. Twelve wells were originally sampled during the RI (and presented in the
original risk calculations in Appendix C). The one additional well sampled in October 2005
was not incorporated into the updated risk calculations since concentrations were low (e.g.,
lead concentrations were 1.6 |ig/L or less) and would not impact results of the HHRA.
Supplemental samples of rural domestic wells were not collected by EPA.

2.5	Edible Plants

Native Americans gather various culturally-significant edible plants in the Tar Creek Area,
including berries and fruit, herbs, food, and nuts. Edible plant samples were not collected by
the Respondents. However, samples of three edible plant species (asparagus, willow, and
cattail) were collected from BIA land and private land in support of the HHRA. A total of 57

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plants were sampled. Four samples were collected from each plant—washed roots, unwashed
roots, washed leaves, and unwashed leaves—for a total of 228 biota samples. In addition, a
collocated soil sample was collected from each plant. It should be noted that "washed" root
and leaf samples simply had deionized water poured over them, and visible dirt remained on
the samples. Details of the plant sampling efforts are provided in Appendix A.

2.6	Fish

Fish samples were not collected by the Respondents during the RI. However, the Oklahoma
Department of Environmental Quality (ODEQ) collected fish samples from four ponds (chat
pile ponds or mill ponds) and two rivers (Neosho River and Spring River) in 2002, as
presented in Fish Tissue Metals Analysis in the Tri-State Mining Area (Appendix B; ODEQ,
2003). A total of 80 composite fish samples representing eight species were collected and
analyzed using three preparation methods: fillets, whole-uneviscerated fish, and whole-
eviscerated fish. Collocated sediment and surface water samples were also available from
these water bodies and used in the study. The edible fish tissue data, and conclusions of the
study were used in the HHRA.

2.7	Selection of Chemicals of Potential Concern

EPA's Finding of Facts in the AOC identifies that mine and mill residues and smelter waste
dumped and disposed on the surface soil at OU4 contain hazardous substances including,
without limitation, cadmium, lead, and zinc. The AOC Scope of Work identifies that
cadmium, lead, and zinc are the COPCs for OU4 (EPA, 2003). As part of the HHRA, a
review of available analytical data for other metals detected in chat pile and mill pond
surface materials, soil, and ground water was performed (Appendix C, Table 2). The results
of this review indicate that six metals (arsenic, antimony, iron, manganese, nickel, and
thallium) exceed the background average and applicable EPA Region 6 Medium-Specific
Screening Levels (MSSLs) for residential soil. However, these metals were not selected as
COPCs for the following reasons:

•	Arsenic: detected at only one residence (unsieved, 0 to 6 inches at the former smelter)
above the background range, at 34.1 ppm; this yard was subsequently remediated in
November 2005; also detected above 20 ppm in only 2 transition zone samples,
smelter-affected soil area, and chat pile/tailings pond material.

•	Antimony: detected at only one residence (unsieved, 0 to 6 inches at the former
smelter) above the MSSL; this yard was subsequently remediated in November 2005;
also detected only in smelter-affected soil above the MSSL.



Iron: detected at only one residence (unsieved, 0 to 6 inches), chat pile/tailing pond
material, and in smelter-affected soil above the MSSL; it is an essential nutrient.

Manganese: detected above its MSSL in one transition zone sample.

Nickel: detected below its MSSL at all locations except 3 transition zone samples, a
few chat pile/tailing pond material samples, and one smelter-affected soil sample.

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• Thallium: detected below its MSSL at all locations except one chat pile/tailing pond
material sample.

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3.0 Exposure Assessment

After identifying which chemicals might pose hazards to human health, potential human
exposures were characterized and are summarized in the Conceptual Site Model in Figure 3-
1.

3.1	Potential Exposure Pathways and Receptors

Five receptor categories (general public adult and child resident, recreator, and Native
American adult and child resident) were identified for OU4 and the possible pathways of
exposures to cadmium, lead, and zinc that might occur under several scenarios were
identified (Appendix C, Table 1). This approach represents an acceptable first step in
estimating potential intakes for current and future exposures. The current exposure pathways
that were quantified in the HHRA are indicated in Appendix C, Table 1, and are
summarized below.

•	General public child resident - Surface soil, drinking water, and ambient air

•	General public adult resident - Surface soil, drinking water, and ambient air

•	Native American child resident - Surface soil, drinking water, ambient air, and dairy
milk

•	Native American adult resident - Surface soil, drinking water, ambient air, fish, beef,
edible plants, aquatic life (such as mussels, crawfish), and small game animals

•	Recreator - surface waste materials (such as in chat pile and mill pond material)

The future exposure pathways that were quantified are indicated in Appendix C, Table 1.
For the general public child and adult, as well as the Native American child and adult,
potential exposures to surface soil and ambient air were evaluated.

There may be Native American residents at Tar Creek with a high-game diet rather than a
high-beef diet. Based on available literature (Nagy, 2001), the bioconcentration factors for
large game (e.g., elk) are similar to beef cattle. Therefore, risks to Native Americans with a
high-game diet can be estimated by the risks calculated for a Native American with a high-
beef diet.

3.2	Exposure Point Concentrations

To estimate possible risks of adverse health outcomes, it is necessary to estimate the
cadmium, lead, and zinc concentrations in each environmental medium to which a receptor
may be exposed. EPA guidelines (EPA 1991a; 1992a) state that this concentration term
(exposure point concentration; EPC) should represent the average concentration to which one
is exposed for the relevant portion of one's lifetime. Because of the obvious uncertainty in
estimating the true average concentration from measurements of samples, EPA recommends

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using the 95 percent upper confidence limit (UCL95) of the mean as a conservative estimate
of the EPC, as this is associated with only a 5 percent probability of underestimating the true
average (EPA 1991a, 1992b, 1993a). In addition to the concentrations in each environmental
medium, it is necessary to estimate the pathway-specific intakes from that medium to
ultimately estimate exposures. In this HHRA, intakes were estimated using RME
assumptions, illustrating a high exposure scenario that may occur.

In the HHRA, EPCs were estimated (Appendix C, Table 3) and potential intakes were
calculated for surface soil, tap water, ambient air, milk, biota (edible plants, aquatic food,
fish, small game, and beef), and waste materials. The following data were used for evaluating
potential current exposures by the indicated receptors:

•	General Public Resident - Three data sets

o 2 Measured - Surface soil (44 yards on private land) and tap water (11 wells
on private land); the dataset used in the original risk calculations is presented
in Appendix C, Table 2, while the updated dataset is presented in Appendix
C, Table 2. In the updated dataset, soil samples from one yard that was
subsequently remediated in November 2005 were removed, and soil samples
from one additional home sampled in October 2005 were added.

o 1 Modeled - Ambient air (Appendices D and E)

•	Native American Resident - 11 data sets

o 6 Measured - Surface soil (two yards on BIA land), tap water (one well on
private land), fish (Appendix B), asparagus, willow, and cattail

o 5 Modeled - Ambient air (Appendices D and E), three biota categories (small
game, beef, and milk) using biotransfer factors, and aquatic organisms using a
regression model (Appendix F)

•	Recreator - Two data sets

o 2 Measured - Chat pile, tailings

o Modeled - None

In the HHRA, all future environmental media concentrations were assumed to remain the
same as present, with the exception of surface soil for the general public and Native
American residents. Future surface soil concentrations were modeled assuming a 30-year
deposition period (Appendices D and E). Future exposures by general public and Native
American residents to soil and air were quantified using the range of modeled future soil and
air concentrations (see Section 3.3).

In some cases, fewer than 10 measurements were available for a data grouping of cadmium
or zinc analyses (Appendix C, Table 3); in these cases, the maximum value was used in
place of the UCL95. Because the formula used to calculate UCL95s appropriately depends
on the distribution of the data, EPA's ProUCL program was used to examine the shape of the
distributions and then perform these calculations (Appendix L).

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The major assumptions associated with the EPCs for each environmental medium used in the
HHRA are described below.

3.2.1	Chat and Tailings

Analytical results from chat samples (piles or bases) and tailings ponds were used for
quantifying potential exposures to recreators, and for input into the ambient air model and air
deposition model. Sieved (250 |im) surface samples (0 to 1 inch or 0 to 6 inches) were
available from a total of 20 chat piles, six chat bases, and 10 tailing ponds, and were assumed
to represent surface concentrations that may be contacted during activities in the source areas
in Tar Creek OU4. The EPCs for these samples were 93 mg/kg cadmium, 18,400 mg/kg zinc,
and 3,461 mg/kg lead.

3.2.2	Soils

Analytical results from residential yard soil were used for quantifying potential exposures to
residents (both general public and Native American) were used as starting soil concentrations
in the future air deposition model (Appendices D and E), and were used in the biota uptake
modeling (for beef, small game animals, and dairy milk) (Appendix F). The dataset used in
the original risk calculations is presented in Appendix C, Table 2, while the updated dataset
is presented in Appendix C, Table 2. In the updated dataset, soil samples from one general
public yard (at the former smelter) that was subsequently remediated in November 2005 were
removed, and soil samples from one additional general public home sampled in October 2005
were added.

Of the 46 rural residential yards sampled, 44 were from residences on private land, while two
were on BIA land. For each yard, the average sieved (250 |im) surface soil (0 to 1 inch) lead
concentration detected at that yard was used as the EPC for the blood lead models
(Appendices G and H). It should be noted that a few samples from the 0 to 6 inch interval at
a few residences displayed higher lead concentrations, but were not used in the models since
they were not sieved samples. The maximum detected concentrations of cadmium and zinc
were used to evaluate exposures on private land and BIA land, separately. The EPCs for
cadmium and zinc are presented below:

•	cadmium - 48 mg/kg (general public) and 9.6 mg/kg (Native American)

•	zinc - 7,700 mg/kg (general public) and 1,940 mg/kg (Native American).

For those residences where yard soil samples were not collected during the OU4 RI but
where ground water samples were collected, if the residence was part of OU2, the soil lead
concentration at these residences was not addressed in this HHRA. For those residences that
were not part of OU2, the average lead concentration detected at the 46 residential yards (as a
group) was used for input in the lead models for these residences (Appendices G and H).

In addition to the residential yard soil, analytical results from transition zone surface soil (0
to 1 inch or 0 to 6 inches and sieved [250 |im]) at five chat piles were used as starting soil
concentrations in the future air deposition model (Appendices D and E) and were used in the
biota uptake modeling for beef, small game animals, and dairy milk (Appendix F). In the
original calculations, an incorrect soil concentration of 515 ppm cadmium was incorporated
into the air modeling and biota uptake modeling in Appendices E and F. However, in the

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updates to these appendices, this cadmium concentration was replaced with the reanalyzed
sample concentration (5 ppm).

Additionally, analytical results from smelter-affected surface soil (0 to 1 inch or 0 to 6
inches) were used as starting soil concentrations in the future air deposition model
(Appendices D and E) and were used in the biota uptake modeling for beef, small game
animals, and dairy milk (Appendix F).

* As mentioned previously, 56 samples were collected from non-residential rural areas in
October 2005. Although not available for the original risk calculations, air deposition
modeling, and biota uptake modeling (Appendices C, E, and F, respectively), these
samples were used as starting soil concentrations in the updated future air deposition
modeling and biota uptake modeling in Appendices E and F, and reflected in the updated
risk calculations (Appendix C).

3.2.3	Ground Water

Analytical results from shallow, private wells were used for quantifying potential exposures
to residents (both general public and Native American). Of the 12 wells sampled, 11 were
from residences on private land, while one was on BIA land. Multiple samples were available
from some wells. For each residence, the average measured lead concentration in ground
water at that residence was used as the EPC in the Integrated Exposure Uptake Biokinetic
(IEUBK) model (Appendix G). Homes without wells are assumed to be supplied with
municipal drinking water or withdraw water from the deeper aquifer, and the default lead
concentration in ground water that was embedded in the IEUBK model was used. The
maximum detected concentrations of cadmium and zinc were used to evaluate exposures on
private land and BIA land separately. The EPCs for cadmium and zinc are presented below:

•	cadmium - 0.003 mg/L (general public); cadmium was non-detect in the well on BIA
land;

•	zinc - 1.11 mg/L (general public) and 0.22 (Native American).

3.2.4	Edible Plants

Analytical results from unwashed plants (both root and aboveground portions) were used for
quantifying potential exposures by adult Native American residents. Three types of culturally
significant foods were available (asparagus, willow, and cattail). For each plant, the
concentrations in both the root and aboveground portion were used since it is assumed that a
Native American would ingest both portions of the plant. Unwashed samples (rather than
washed samples) were used since some Native Americans may not wash plants prior to
ingestion. It should be noted that unwashed samples had visible dirt on the sample surface.

3.2.5	Fish

Analytical results from fish samples collected by ODEQ in 2002 were used for quantifying
potential exposures to adult Native American residents. Concentrations from eight fish
species were available (ODEQ, 2003) and average concentrations were assumed to represent
fish concentrations that may be contacted over an extended time period if eating fish from

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millponds or rivers in Tar Creek OU4. These concentrations are 0.17 mg/kg for cadmium, 21
mg/kg for zinc, and 0.427 mg/kg for lead.

3.2.6	Ambient Air

Ambient air concentrations were modeled from potential source areas (chat and tailings
ponds), and were used in quantifying potential exposures to current and future residents
(general public and Native American; Appendices D and E). For evaluating potential current
exposures, ambient air concentrations were modeled at each of the 46 rural residential yards
sampled, and at the additional residences where shallow rural wells were sampled but soil
was not collected (and they were not part of OU2). For use in the lead models, ambient air
concentrations were evaluated for each home separately. For cadmium and zinc, the UCL95
of the individual ambient air concentrations modeled at the 46 homes was used.

For evaluating potential future exposures, ambient air concentrations across the Tar Creek
area were modeled (Appendices D and E) and the range was used in quantifying potential
exposures. The modeled concentrations were assumed to represent ambient air
concentrations that may be contacted when inhaling ambient air in Tar Creek OU4.

3.2.7	Beef

Beef concentrations were modeled from uptake of soil in potential grazing areas (transition
zone soil, smelter-affected soil, and residential yard soil), and were used in quantifying
potential exposures to adult Native American residents (Appendix F). The approach and
chemical-specific biotransfer factors presented in EPA's Combustion Guidance (EPA,
2005a) were used. The modeled concentrations were assumed to represent beef
concentrations that Native Americans may encounter when eating beef from cattle grazing in
Tar Creek OU4.

In the original calculations, an incorrect soil concentration of 515 ppm cadmium in a
transition zone sample was incorporated into the biota uptake modeling in Appendix F.
However, in the update to this appendix, this cadmium concentration was replaced with the
reanalyzed sample concentration (5 ppm).

In addition, as mentioned previously, the rural area soil samples were not available for the
original risk calculations and biota uptake modeling (Appendices C and F, respectively).
However, these samples were used in the updated biota uptake modeling in Appendix F, and
reflected in the updated risk calculations (Appendix C). The potential grazing area soil data
were divided into two data groupings to evaluate the impact of smelter-affected soil on the
overall risk estimates:

•	transition zone soil, updated residential yard soil, rural area soil, and background
soil; and

•	smelter-affected soil.

3.2.8	Small Game

Small game (e.g., squirrel, rabbit, deer, duck, geese, quail, and turkey) are commonly hunted
in the area. Potential concentrations in small herbivore mammals (e.g., rabbit) were modeled

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from uptake of soil in potential foraging/grazing areas (transition zone soil, smelter-affected
soil, and residential and yard soil), and were used in quantifying potential exposures to adult
Native American residents (Appendix F). The chemical-specific bioconcentration factors
(BCFs) presented in the Tar Creek OU4 ERA (EPA, 2005b) were used. The modeled
concentrations were assumed to represent small game concentrations that may be contacted
by Native American residents when eating small game caught in Tar Creek OU4.

In calculating the original EPCs and the associated risk estimates, an incorrect assumption
regarding wet weight versus dry weight was used, resulting in overestimates of risk; this was
corrected in the updated biouptake modeling in Appendix F. In addition, in the original
calculations, an incorrect soil concentration of 515 ppm cadmium in a transition zone sample
was incorporated into the biota uptake modeling in Appendix F. However, in the update to
this appendix, this cadmium concentration was replaced with the reanalyzed sample
concentration (5 ppm).

As mentioned previously, the rural area soil samples were not available for the original risk
calculations and biota uptake modeling (Appendices C and F, respectively). However, these
samples were used in the updated biota uptake modeling in Appendix F, and reflected in the
updated risk calculations (Appendix C). The potential grazing area soil data were divided
into two data groupings to determine the impact of smelter-affected soil on the overall risk
estimates:

•	transition zone soil, updated residential yard soil, rural area soil, and background
soil; and

•	smelter-affected soil.

3.2.9	Aquatic Life

Native Americans gather mussels, crawfish, and turtles from creeks and rivers in the area.
Aquatic biota (such as mussels and crawfish) concentrations were modeled from uptake of
sediment in mill ponds or rivers (as presented in ODEQ, 2003), and were used in quantifying
potential exposures to adult Native American residents. A regression model was used with
average sediment concentrations to estimate concentrations that may be ingested over a
chronic exposure period by Native American residents when eating aquatic biota collected in
Tar Creek OU4 (Appendix F). Cadmium and zinc EPCs were estimated at 2 mg/kg. In
calculating the original EPCs and the associated risk estimates, an incorrect assumption
regarding wet weight versus dry weight was used, and there was an error in the regression
equation, resulting in overestimates of risk for cadmium and lead; this was corrected in the
updated bio-uptake modeling in Appendix F.

3.2.10	Milk

Dairy milk concentrations were modeled from uptake of soil in potential cattle grazing areas
(transition zone soil, smelter-affected soil, and residential yard soil), and were used in
quantifying potential exposures to child Native American residents (Appendix F). The
approach and chemical-specific biotransfer factors presented in EPA's Combustion Guidance
(EPA, 2005a) were used. The modeled concentrations were assumed to represent milk

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concentrations that may be contacted by Native American residents when drinking milk from
cows grazing in Tar Creek OU4.

In the original calculations, an incorrect soil concentration of 515 ppm cadmium in a
transition zone sample was incorporated into the biota uptake modeling (and resulting milk
concentrations) in Appendix F. However, in the update to this appendix, this cadmium
concentration was replaced with the reanalyzed sample concentration (5 ppm).

In addition, as mentioned previously, the rural area soil samples were not available for the
original risk calculations and biota uptake modeling (Appendices C and F, respectively).
However, these samples were used in the updated biota uptake modeling (and resulting milk
concentrations) in Appendix F, and reflected in the updated risk calculations (Appendix C).
For dairy cattle, the potential grazing area soil data were divided into two data groupings to
determine the impact of smelter-affected soil on the overall risk estimates:

•	transition zone soil, updated residential yard soil, rural area soil, and background
soil; and

•	smelter-affected soil.

3.3 Intake Estimates

The exposure models used were straightforward and took into account a variety of behavioral
and physiological factors, including exposure frequency and duration, contact rate, EPC,
body weight, and averaging time for the general public, Native American residents, and
recreators (Appendix C, Table 4). An example of one of these models, which estimated
exposure via the consumption of ground water as a drinking source, is shown below:

Chemical intake (mg/kg/day) = Cw x SIFw x CF (1)

and

SIFw = IRw x EF x ED/(BW x AT)	(2)

Where

Cw = chemical concentration in tap water (|ig/L)

SIFw = summary intake factor for ingestion of tap water (L/kg/day)

IRw = ingestion rate for tap water (L/day)

EF = exposure frequency (days/year)

ED = exposure duration (years)

CF = conversion factor (mg/|ig)

BW = body weight (kg)

AT = averaging time (days).

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The intake parameters used to solve such equations (in this case, IRw, EF, ED, BW, and AT)
for children and adults were obtained from previous EPA guidance for such calculations
(EPA 1989,1991a, 1993a). In the example presented, the intake parameters are known with
a relatively high degree of certainty (for example, ingestion rate for tap water). In other
equations, such as those related to exposure from asparagus, intake parameters are less
certain (for example, vegetable ingestion rates, gastrointestinal and dermal absorption
factors) but represent conservative estimates of current scientific evidence.

The exposure frequency for a recreator (on chat piles, chat bases, and mill ponds) was based
on the average number of days without rain and above freezing in Tar Creek. This
information was obtained from the Miami University of Oklahoma Mesonet station
(www.mesonet.org). The most recent data that was available for a 5-year period was 1999 to
2003, and is presented below.

Year

# of Days

1999

189

2000

184

2001

189

2002

111

2003

182

Average 184.2

Standard default exposure factors were used for evaluating potential exposures by the general
public. However, for evaluating Native American residential exposures representative of the
tribal way of life, exposure factors presented in "The Spokane Tribe's Multipathway
Subsistence Exposure Scenario and Screening Level RME" (Harper et al., 2002) were used.
Three sets of exposure factors were used: child, adult with a high-fish diet, and adult with a
high-beef diet. Best professional judgment was used in identifying exposure factors for the
adolescent recreator scenario.

Potential future exposures to soil and ambient air by residents (general public and Native
American) were evaluated using the following combinations of modeled soil/air
concentrations in the original risk estimates (Appendix C):

•	Maximum soil and maximum air;

•	Mean soil and maximum air;

•	Mean soil and mean air; and

•	75th percentile soil and maximum air.

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Three combinations of modeled soil/air concentrations were used in the updated risk
estimates (Appendix C):

•	Maximum soil and maximum air;

•	Median soil and maximum air; and

•	Mean soil (same value as 75th percentile) and maximum air.

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4.0 Toxicity Assessment

Much of the following general discussion was excerpted from Snperfund and Mining
Megasites - Lessons from the Coeur d'Alene River Basin (EPA, 2005c).

After identifying the chemical hazards, and estimating the human exposures to each, the next
step in an HHRA involves evaluating the scientific evidence from animal and human
epidemiologic studies that have examined dose-response relationships for cancer and non-
cancer health outcomes. The fundamental tenet of toxicology is that the dose determines the
effect.

The following hierarchy of sources was used to obtain toxicity data for COPCs:

•	Integrated Risk Information System (IRIS) (EPA, 2005d)

•	Provisional Peer-Reviewed Toxicity Values (PPRTVs) (EPA, 2005e)

•	Other Sources (e.g., EPA Health Effects Assessment Summary Tables [HEAST; EPA,
1995] and the National Center for Environmental Assessment [NCEA]).

4.1	For Non-carcinogens Other Than Lead

For noncancer outcomes, a chronic reference dose (RfD) is derived from the no-observed-
adverse-effect level (NOAEL) or lowest-observed-adverse-effect level (LOAEL) in animals
or humans. RfDs are derived by dividing the NOAEL or LOAEL by an uncertainty factor
that represents a combination of various sources of uncertainty associated with the database
for that particular chemical. EPA's IRIS database and NCEA served as the source of RfDs
for the COPCs at Tar Creek, except for lead (discussed below), for which there is no IRIS
RfD and for which other sources of toxicity data were used.

Dermal RfDs are not available in IRIS, PPRTVs, or HEAST. Equations presented in EPA
guidance (EPA, 1989) were used to calculate dermal RfDs for cadmium and zinc. An
inhalation reference concentration (RfC) was not available for zinc. Note that cadmium also
has potential cancer effects and has its own IRIS SF via the inhalation pathway. Non-cancer
toxicity values used in the HHRA are presented in Appendix C, Table 5.

4.2	For Lead

Of the three COPCs, the adverse health effects of lead are best characterized in human
populations. Risk assessments for lead therefore differ from those for other noncarcinogens
in that they rely on observed or predicted blood lead levels (BLLs), as BLLs have been
directly related to adverse outcomes in adults and children. In studies conducted around the
world, population average BLL have been found to be associated with adverse effects on
average measures of cognitive and behavioral development in young children. In short, dose-
response relationships between BLL and adverse health outcomes in children are sufficiently
well described that community BLL can be used to estimate risk. Community BLL can be

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determined precisely through appropriately designed surveys, or they can be estimated from
environmental data through modeling techniques. The estimation of BLL through modeling,
which involves environmental rather than biological measurements, is presented in Section
5, and detailed input and output calculations using the IEUBK and Adult Lead Model are
presented in Appendices G and H, respectively. Historic BLL measurements collected in
the Tar Creek area are presented in Section 6.

4.3 For Carcinogens (Cadmium)

For cancer outcomes, the dose-response information is condensed into a SF, in units of
(mg/kg-day) ', which expresses excess lifetime cancer risk (ELCR) as a function of (lifetime
average) daily dose. EPA maintains an online database, IRIS (EPA, 2005d), which contains
SFs that are based on the current weight of toxicologic evidence. Of the three COPCs
identified at Tar Creek, only cadmium was evaluated for carcinogenic risk since it was the
only identified potential carcinogen. Cancer toxicity values are provided in Appendix C,
Table 6.

The following information regarding the carcinogenicity of cadmium was excerpted from the
IRIS database (EPA, 2005d).

The EPA has concluded that cadmium is a Class B1 carcinogen (probable human
carcinogen) via the inhalation pathway. This is based on limited evidence from
occupational epidemiologic studies of cadmium, which is consistent across
investigators and study populations.

A two-fold excess risk of lung cancer was observed in cadmium smelter workers (602
white males employed in production work a minimum of 6 months during the years
1940-1969). Urine cadmium data available for 261 workers employed after 1960
suggested a highly exposed population. As the standardized mortality rates observed
were low and there is a lack of clear-cut evidence of a causal relationship of the
cadmium exposure only, this study is considered to supply limited evidence of human
carcinogenicity.

Four studies of workers exposed to cadmium dust or fumes provided evidence of a
statistically significant positive association with prostate cancer (Kipling and
Waterhouse, 1967; Lemen et al., 1976; Holden, 1980; Sorahan and Waterhouse,
1983), but the total number of cases was small in each study. The Thun et al. (1985)
study is an update of an earlier study (Lemen et al., 1976) and does not show excess
prostate cancer risk in these workers. Studies of human ingestion of cadmium are
inadequate to assess carcinogenicity.

The unit risk for cadmium should not be used if the air concentration exceeds 6
|ig/m3, since above this concentration the unit risk may not be appropriate.

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5.0 Risk Characterization

Risk characterization, the last step in an HHRA, strives to combine the estimates of chemical
exposure with the estimates of potential human hazard (based on known dose-response
relationships) to estimate the actual or potential risks to human health at the site. At the Tar
Creek OU4 site, EPA estimated cancer and non-cancer health risks for RME conditions
(Appendix C, Tables 7 and 9, with updated calculations in Appendix C). The RME is a
conservative estimate intended to be the highest exposure that can reasonably be expected to
occur. Risks were estimated separately for different segments of the population, such as the
general public (children and adults), adolescent recreators, and Native American residents
(children and adults) representing the tribal way of life.

5.1	Approach for Carcinogens

To characterize potential carcinogenic effects, statistical probabilities are estimated from
calculated intakes and toxicity values that a hypothetical person will develop cancer over a
lifetime as a result of assumed exposures. Using the SF for cadmium, estimated daily intakes
averaged over a lifetime of exposure were converted to incremental risks of a hypothetical
person developing cancer. The following formulae were used to estimate potential ELCR
from inhalation exposures:

Risk=Intake x SF

EPA's target range for carcinogenic risk associated with Comprehensive Environmental
Response Compensation, and Liability Act (CERCLA) sites and specified in the National Oil
and Hazardous Substances Pollution Contingency Plan (NCP) (40 Code of Federal
Regulations [CFR] 300.430) is l-in-10,000 (1 x 10"4) to l-in-1,000,000 (1 x 10"6). That is, the
risk associated with site-related exposures should not exceed this target range.

5.2	Approach for Non-carcinogens Other than Lead

Estimates of potential non-carcinogenic health risks were developed by calculating a Hazard
Quotient (HQ) for each COPC by exposure route. The HQ was calculated as the ratio of the
estimated intake to the RfD as follows:

,,,, Intake

If the estimated daily intake for any COPC exceeded its RfD, the HQ exceeded 1. An HQ
that exceeds 1 indicates that there is a potential for adverse health effects associated with
exposure to that COPC, but it does not indicate the actual level of health effect.

A hazard index (HI) approach was used to evaluate non-carcinogenic health risks posed by
one or more COPCs to which a receptor may be exposed by one or more exposure routes.
The HI approach assumes that simultaneous sub-threshold exposures to several COPCs or

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exposure routes are additive. The HI is equal to the sum of the HQs, and is calculated as
follows:

Total HI = (/, /RfD, ) + (/2 /RJD.) ¦ ... ¦ (I: / RfDi)

Where:

I = Intake level [chronic daily intake [CDI] (mg/kg-day)

RfD = Chronic reference dose (mg/kg-day)

I; = Intake level (intake) for the 7th chemical
RfD; = Reference dose for the 7th chemical

The HI approach was used to estimate potential non-cancer health effects associated with
COPCs. When the sum of HQs for a receptor exceeds unity (one), there may be concern for
potential non-cancer health effects, assuming that the cumulative effect of multiple sub-
threshold exposures is additive, and may result in an adverse health effect to a particular
target organ.

The Tar Creek OU4 HHRA estimated HQs separately for the following receptors:

•	General public child

•	General public adult

•	Adolescent recreator

•	Native American child

•	Native American adult with high-fish diet

•	Native American adult with high-game diet

Risk assessment of non-lead COPCs followed EPA guidelines. Residential soil EPCs (for
cadmium and zinc) were the maximum detected concentrations for all 46 yards sampled. The
fraction of ingested soil that a child typically obtains from areas other than his or her own
yard is essentially unknown. The consequences of using maximum detected EPC values is to
overestimate risk for all residents except for those living at the residence with the maximum
detected concentration.

5.3 Approach for Lead

As mentioned in Section 4.2, risk assessments for lead rely on observed or predicted BLLs in
a community, as BLLs have been directly related to adverse outcomes in adults and children.
In 1991, the U.S. Centers for Disease Control and Prevention (CDC) promulgated specific
guidelines aimed at reducing BLLs in individual children (CDC, 1991). These are
summarized in Table 5-1.

Because vast quantities of lead have been distributed throughout Tar Creek due to historical
mining-related activities, the HHRA devoted substantial effort to characterizing the risks of

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lead toxicity. The IEUBK model was used to estimate risks to children from lead exposure
from soil and other media. The EPA's Adult Lead Model (ALM) was used to evaluate
residential adult and adolescent recreator exposures to lead in soil.

At sites like Tar Creek, EPA policies seek to protect the health of the most vulnerable
populations, namely children and women of childbearing age. EPA policy (EPA, 1994)
strives to reduce soil lead levels so that no child would have more than a 5 percent chance of
exceeding a BLL of 10 |ig/dL.

5.4 Results

Potential ELCRs, His, and BLLs were calculated using RME assumptions for the general
public, Native American residents, and recreators for the exposure pathways identified in
Section 3.1. The following potential risks were calculated. Current intakes and risks are
presented in Appendix C, Table 7, and summarized in Table 9 (and updated in Appendix
C), while current BLLs are calculated in Appendices G and H. Future intakes, risks, and
BLLs are presented in Appendix I, and a statistical evaluation of the future modeled soil
concentrations is presented in Appendix J. A summary of the risk estimates is also
presented in Tables 5-1 through 5-3, and includes both the original risk estimates and the
updated risk estimates provided in Appendix C.

5.4.1 Current Child Resident (General Public)

Ingestion and dermal contact exposures to surface soil/dust from residential yards (44 homes
with measured surface soil data), ground water ingestion, and inhalation of ambient air were
quantified for a general public residential child.

Children were the most sensitive receptors when quantifying risks for COPCs. For cadmium
and zinc, the maximum target organic-specific HI is 1 based on the maximum detected
concentration of cadmium and zinc in the 0-1 inch surface soil samples and ground water,
and the modeled UCL95 air concentrations. Approximately 60 percent of the estimated risks
were associated with incidental ingestion of soils.

Of the 44 homes where surface soil samples (0-1 inch or 0-6 inches) were collected, six
homes had one or more soil samples with lead concentrations above 500 mg/kg. Using the
average surface soil sample concentration (from the 0-1 inch interval) and default ground
water concentration of 4 |ig/L (or measured concentration if available for that residence),
potential BLL exceeding 10 |ig/dl for children were estimated for four homes.

For the six homes with measured ground water concentrations but not soils, the percentage of
the population with BLLs exceeding 10 |ig/dl were within acceptable levels.

At the 50 (44 plus 6) private rural residential properties, the percentage of the child
population with a BLL exceeding 10 |ig/dl ranged from 0.002 percent to 99.536 percent.
Based on averaging the probabilities at all 52 residences (50 plus the two properties on BIA
land), the average percentage of the "neighborhood" with a BLL exceeding 10 |ig/dl is 2.98
percent. Four individual residences on private (non-BIA) land exceed the EPA's target.

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No COPCs exceeded an individual HI of 1. Therefore, risks associated with cadmium and
zinc are within acceptable levels and lead was identified as the only chemical of concern
(COC) for this receptor.

Overall risk estimates for the current child resident on non-BIA land did not change when
calculations were performed based on the updated soil dataset. The COPC concentrations in
soil at the newly sampled (October 2005) residential property were below their respective
screening levels. The risk estimates based on maximum detected concentrations of cadmium
and zinc remained the same. After eliminating soil samples from the home at the former
smelter, the maximum percentage of the population with a BLL exceeding 10 |ig/dl
decreased to 21.6 percent and the number of homes exceeding the EPA's target concentration
decreased to five.

Based on the updated soil dataset, the average percentage of the "neighborhood" with a BLL
exceeding 10 |ig/dl is less than 5 percent. Three individual residences on non-BIA land
exceed the EPA's target.

5.4.2 Current Adult Resident (General Public)

Ingestion and dermal contact exposures to surface soil from residential yards, ground water
ingestion, and inhalation of ambient air were quantified for a general public residential adult.
An ELCR of 8xl0"8 and maximum target organ-specific HI of 0.2 were calculated.

At the 44 public rural residential properties, the percentage of the population with a BLL
exceeding 10 |ig/dl ranged from 1.3 percent to 73.8 percent. Two individual residences
exceed the EPA's target.

No COPCs exceeded an individual ELCR of lxlO"6 or HI of 1. Therefore, risks associated
with cadmium and zinc are within acceptable levels and lead was identified as the only COC
for this receptor.

The ODEQ fish study concluded that fillets of fish caught in ponds within the Tar Creek
Superfund Site and the Spring and Neosho Rivers are safe to eat at rates up to six 8-ounce
meals per month. Whole-uneviscerated and whole-eviscerated portions of all fish from the
Oklahoma sections of the Spring and Neosho Rivers downstream to Grand Lake and ponds in
the Tri-State Mining Area should not be consumed due to lead concentrations. The higher
fish tissue lead concentrations are positively correlated to lead concentrations in the
sediments of the area waters (ODEQ, 2003; Appendix B).

Overall risk estimates for current adult residents on non-BIA land did not change when
calculations were performed on the updated soil dataset. The COPC concentrations in soil at
the newly sampled (October 2005) residential property were within their respective screening
levels. The risk estimates based on the maximum detected concentrations of cadmium and
zinc remained the same. After eliminating soil samples from the home at the former smelter,
the maximum percentage of the population with a BLL exceeding 10 |ig/dl decreased to 6.7
percent and only one home exceeded EPA's target concentration.

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5.4.3	Current Child Resident (Native American)

Ingestion and dermal contact exposures to surface soil/dust from the two residential yards
sampled on BIA land, ground water ingestion, inhalation of ambient air, and ingestion of
dairy milk were quantified for a Native American child. For cadmium and zinc, the
maximum calculated target organ-specific HI is 0.33 based on the maximum detected
concentration of cadmium and zinc in the 0-1 inch surface soil samples and ground water,
and the modeled UCL95 air concentrations. Approximately 75 percent of the estimated risks
were associated with incidental ingestion of soils.

Using the average surface soil sample concentration (from the 0-1 inch interval) detected at
these two residences and default ground water concentration of 4 |ig/L (or measured
concentration if available for that residence), potential BLL exceeding 10 |ig/dl for children
were estimated for the two homes. The percentage of the child population with a BLL
exceeding 10 |ig/dl ranged from 0.011 percent to 0.036 percent. Based on averaging the
probabilities at all 52 residences (two on BIA land plus the 50 on non-BIA land), the average
percentage of the "neighborhood" with a BLL exceeding 10 |ig/dl is 2.98 percent. Neither
home on BIA land had soil samples above 500 mg/kg.

No COPCs exceeded an individual HI of 1. Therefore, risks associated with cadmium and
zinc are within acceptable levels and lead was identified as the only COC for this receptor.

Risk estimates for the current Native American child resident did not change when
calculations were performed based on the updated soil dataset, except for the slight decrease
in risks associated with ingestion of milk.

5.4.4	Current Adult Resident (Native American, High-Fish and High-Beef Diets)

Ingestion and dermal contact exposures to surface soil from residential yards on BIA land,
ground water ingestion, inhalation of ambient air, and ingestion of biota (fish, small game,
beef, aquatic food, asparagus, willow, and cattail) were quantified. An ELCR of 2xl0"7 (both
high-fish diet and high-beef diet) and maximum target organ-specific His of 700 and 600
were calculated for the high-fish diet and high-beef diet, respectively.

At the two rural residential properties on BIA land (Res_3 and Res_5), the percentage of the
population with a BLL exceeding 10 |ig/dl was 100 percent at both homes (Appendix H).

Cadmium and zinc exceeded an individual HI of 1 due to the asparagus, willow, and cattail
ingestion pathways. In addition, cadmium exceeded an individual HI of 1 from the aquatic
food ingestion and fish ingestion pathways. Therefore, risks associated with cadmium and
zinc exceed acceptable levels, and lead, cadmium, and zinc were identified as COCs for this
receptor.

Additional evaluation was conducted using the updated soil dataset including transition zone
soil, updated residential yard soil, rural area soil, and background soil, for the BUM. Overall
risk estimates for Native American adult resident did not change based on the updated soil
dataset. An ELCR of 2xl0"7 and maximum target organ-specific HI of 600 were calculated
for both high-fish diet and high-beef diet. The percentage of the population with a BLL
exceeding 10 |ig/dl (100 percent) did not change at the two rural residential properties.
Overall risk estimates did not change for cadmium and zinc based on the updated soil dataset.

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5.4.5	Current Adult Resident (More Typical Native American)

Using more typical exposure factors for Native American subsistence residents as presented
in EPA's Exposure Factors Handbook (EPA, 1997), ingestion of biota (beef, small game,
fish, aquatic food, asparagus, willow, and cattail) were quantified. The maximum target
organ-specific HI was 300, driven by the edible plant exposures. However, aquatic food
exposures also posed an unacceptable HI.

At the two rural residential properties on BIA land, the percentage of the population with a
BLL exceeding 10 |ig/dl was 100 percent (Appendix K)

Cadmium and zinc exceeded an individual HI of 1. Therefore, risks associated with cadmium
and zinc exceed acceptable levels, and cadmium, lead, and zinc were identified as COCs for
this receptor.

An additional evaluation was conducted using the updated soil dataset including transition
zone soil, updated residential yard soil, rural area soil, and background soil for the BUM.
Overall risk estimates did not change for cadmium and zinc based on the updated soil dataset.
The percentage of the population with a BLL exceeding 10 |ig/dl (100 percent) did not
change at the two rural residential properties.

5.4.6	Current/Future Recreator

Ingestion and dermal contact exposures to surface materials on chat piles, chat bases, and
tailings ponds were quantified. The maximum target organ-specific HI was 0.1. The
percentage of the population with a BLL exceeding 10 |ig/dl is 22.3 percent (Appendix H).

No COPCs exceeded an individual HI of 1. Therefore, risks associated with cadmium and
zinc are within acceptable levels and lead was identified as the only COC for this receptor.

5.4.7	Future Child Resident (General Public and Native American)

Ingestion and dermal contact exposures to surface soil/dust and inhalation of ambient air at
any future location within the Tar Creek area (except on chat piles, chat bases, or mill ponds)
were evaluated based on the range of potential future soil concentrations modeled assuming
airborne deposition with depletion and the modeled air concentrations (Appendices D, E,
and J). Since the same exposure factors were used for evaluating soil and air exposures for
child residents, the general public child and Native American resident child are addressed
together here. Based on the maximum modeled soil and ambient air concentration for the Tar
Creek area, the maximum HI is 0.08 (Appendix C, Table 9). Therefore, cadmium and zinc
were not identified as COCs for these receptors.

Based on the combination of the maximum modeled soil and maximum modeled ambient air
concentration for the Tar Creek area, the percentage of the child population with a BLL
exceeding 10 |ig/dl was 100 percent (Appendix I). For purposes of comparison, three other
soil and air concentration combinations were evaluated, and the percent of the population
with a BLL above 10 |ig/dL is indicated:

•	Mean soil (370 mg/kg) and maximum air (0.18 |ig/m3) - 6.5 percent;

•	Mean soil (370 mg/kg) and mean air (0.011 |ig/m3) - 5.9 percent;

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• 75th percentile soil (291 mg/kg) and maximum air (0.18 |ig/m3) - 3.5 percent.

Therefore, lead was identified as the only COC for these receptors.

An additional evaluation was conducted for a future child resident based on the updated
future soil dataset. Based on the maximum modeled soil and ambient air concentrations for
the Tar Creek area, the maximum HI is 0.2 (Appendix C, Table 9). Therefore, cadmium
and zinc were not identified as COCs for these receptors.

Based on the combination of the maximum modeled soil and maximum modeled ambient air
concentration for the Tar Creek area, the percentage of the child population with a BLL
exceeding 10 |ig/dl was 100 percent (Appendix I). For purposes of comparison, another
evaluation was conducted using mean soil (131 mg/kg) and maximum air (0.18 |ig/m3)
concentrations, and the percent of the population with a BLL above 10 |ig/dL was 0.094
percent. It should be noted that the mean and 75th percentile soil concentrations were the
same. Therefore, lead was identified as the only COC for these receptors.

5.4.8 Future Adult Resident (General Public)

Ingestion and dermal contact exposures to surface soil and inhalation of ambient air at any
future location within the Tar Creek area (except on chat piles, chat bases, or mill ponds)
were evaluated based on the range of potential future soil concentrations modeled assuming
airborne deposition with depletion and the modeled air concentrations (Appendices D, E,
and J). Based on the maximum modeled soil and ambient air concentration for the Tar Creek
area, the maximum ELCR is 4xl0"6 and maximum HI is 0.02 (Appendix C, Table 9). Since
cadmium poses an individual ELCR exceeding lxlO"6, cadmium was identified as a COC for
this receptor.

Based on the maximum modeled future soil lead concentration (33,066 mg/kg) for the Tar
Creek area, the percentage of the population with a BLL exceeding 10 |ig/dl was 99 percent
(Appendix I). For purposes of comparison, the mean soil concentration (370.6 mg/kg) was
evaluated; the percentage of the population with a BLL above 10 |ig/dL is 3.9 percent, which
is an acceptable level. Therefore, the 75th percentile and median soil concentrations, which
are lower than the mean concentration, will also be within acceptable levels. Lead was also
identified as a COC for this receptor.

An additional evaluation was conducted for future adult residents based on the updated future
soil dataset. Based on the maximum modeled soil and ambient air concentrations for the Tar
Creek area, the maximum ELCR is 4xl0"6 and maximum HI is 0.03 (Appendix C, Table 9).
Since cadmium poses an individual ELCR exceeding lxlO"6, cadmium remained as a COC
for this receptor. Based on the maximum modeled future soil lead concentration (18,900
mg/kg) for the Tar Creek area, the percentage of the population with a BLL exceeding 10
|ig/dl was 95.4 percent (Appendix I). For purposes of comparison, the mean soil
concentration (131 mg/kg) was evaluated with the maximum modeled ambient air
concentration; the percentage of the population with a BLL above 10 |ig/dL is 2.0 percent,
which is an acceptable level. Lead also remained as a COC for this receptor.

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5.4.9 Future Adult Resident (Native American)

Ingestion and dermal contact exposures to surface soil and inhalation of ambient air at any
future location within the Tar Creek area (except on chat piles, chat bases, or mill ponds)
were evaluated based on the range of potential future soil concentrations modeled assuming
airborne deposition with depletion and the modeled air concentrations (Appendices D, E,
and J). Based on the maximum modeled soil and ambient air concentration for the Tar Creek
area, the maximum ELCR is lxlO"5 and maximum HI is 0.04 (Appendix C, Table 9). Since
cadmium poses an individual ELCR exceeding lxlO"6, cadmium was identified as a COC for
this receptor.

Based on the maximum modeled future soil lead concentration (33,066 mg/kg) for the Tar
Creek area, the percentage of the population with a BLL exceeding 10 |ig/dl was 100 percent
(Appendix I). For purposes of comparison, the mean and median soil concentrations (370.6
and 110.6 mg/kg, respectively) were evaluated; the percentages of the population with a BLL
above 10 |ig/dL are 37.5 and 9.5 percent, respectively. These percentages exceed the target
level. Lead was also identified as a COC for this receptor.

An additional evaluation was conducted for a future adult resident based on the updated
future soil dataset. Based on the maximum modeled soil and ambient air concentrations for
the Tar Creek area, the maximum ELCR is lxlO"5 and maximum HI is 0.03 (Appendix C,
Table 9) Since cadmium poses an individual ELCR exceeding lxlO"6, cadmium remained as
a COC for this receptor.

Based on the maximum modeled future soil lead concentration (18,900 mg/kg) for the Tar
Creek area, the percentage of the population with a BLL exceeding 10 |ig/dl was 100 percent
(Appendix I). For purposes of comparison, the mean and median soil concentrations (131
and 45.6 mg/kg, respectively) were evaluated with the maximum modeled ambient air
concentration; the percentages of the population with a BLL above 10 |ig/dL are 11.6 and 3.8
percent, respectively. The percentage based on the mean exceeds the target level. Therefore,
lead also remained as a COC for this receptor.

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Table 5-1

Risk Summary - General Public Exposures
Tar Creek OU4 Superfund Site

Scenario
Timeframe

Exposure
Point

Receptor
Population

Receptor
Age

Exposure
Route

Chemical of
Potential Concern

Exposure Point Concentration (EPC)

Hazard
Index (HI)

Excess Lifetime
Cancer Risk
(ELCR)

Value

Units

Basis

Rationale

Current

Surface Soil (0-1 inch)

Resident
(General Public)

Adult

Ingestion

CADMIUM

4.8E+01

mg/kg

Max

(1)

7.E-02

--

ZINC

7.7E+03

mg/kg

Max

(1)

4.E-02

-

Dermal

CADMIUM

4.8E+01

mg/kg

Max

(1)

1.E-02

-

ZINC

7.7E+03

mg/kg

Max

(1)

1.E-04

--

Child

Ingestion

CADMIUM

4.8E+01

mg/kg

Max

(1)

6.E-01

-

ZINC

7.7E+03

mg/kg

Max

(1)

3.E-01

--

Dermal

CADMIUM

4.8E+01

mg/kg

Max

(1)

7.E-02

--

ZINC

7.7E+03

mg/kg

Max

(1)

9.E-04

-

Ambient Air

Adult

Inhalation

CADMIUM

8.08E-05

ug/m3

95% UCL

(2)

4E-04

--

Child

8.08E-05

ug/m3

95% UCL

(2)

9E-04

--

Adult/Child

8.08E-05

ug/m3

95% UCL

(2)

--

7.6E-08

Current/Future

Private wells

Adult

Ingestion

CADMIUM

3.0E-03

mg/L

Max

(1)

2.E-01

--

ZINC

1.1E+00

mg/L

Max

(1)

1.E-01

--

Child

CADMIUM

3.0E-03

mg/L

Max

(1)

4.E-01

-

ZINC

1.1E+00

mg/L

Max

(1)

2.E-01

--

Future

Surface Soil (0-1 inch)

Adult

Ingestion

CADMIUM

2.2E+00
(4.6E+00)

mg/kg

Max

(3)

3E-03
(6E-03)

--

ZINC

4.0E+02
(8.5E+02)

mg/kg

Max

(3)

2E-03
(4E-03)

--

Dermal

CADMIUM

2.2E+00
(4.6E+00)

mg/kg

Max

(3)

5E-04
(1E-03)

--

ZINC

4.0E+02
(8.5E+02)

mg/kg

Max

(3)

7E-06
(2E-05)

--

Child

Ingestion

CADMIUM

2.2E+00
(4.6E+00)

mg/kg

Max

(3)

3E-02
(6E-02)

--

ZINC

4.0E+02
(8.5E+02)

mg/kg

Max

(3)

2E-02
(4E-02)

--

Dermal

CADMIUM

2.2E+00
(4.6E+00)

mg/kg

Max

(3)

3E-03
(7E-03)

--

ZINC

4.0E+02
(8.5E+02)

mg/kg

Max

(3)

5E-05
(1E-04)

--

Ambient Air

Adult

Inhalation

CADMIUM

4.3E-06

mg/m3

Max

(4)

2E-02

-

Child

4.3E-06

mg/m3

Max

(4)

5E-02

--

Adult/Child

4.3E-06

mg/m3

Max

(4)

-

4.0E-06



Scenario
Timeframe

Exposure
Point

Receptor
Population

Receptor
Age

Exposure
Route

Chemical of
Potential Concern

Exposure Point Concentration (EPC)

No. of Homes
with BLL
Exceeding
Criterion

Percent Above
Target BLL
of 10 ug/dl

Value or Range

Units

Basis

Rationale

Current

Surface Soil (0-1 inch)

Resident
(General Public)

Adult

Ingestion

Lead

12.6-7470
(12.6-643)

mg/kg

Mean

(5)

4/44
(3/44)

--

Surface Soil (0-1 inch)

Child

Ingestion

12.6-7470
(12.6-643)

mg/kg

Mean

(5)

4/52
(3/44)

--

Private wells

0.65 - 26.2

ug/L

Mean

(6)

Indoor Dust

Determined using lEUBK's Multiple Source Analysis

Ambient Air

Inhalation

1.6e-7-8.1e-6

mg/m3

Point

(7)

Future

Surface Soil (0-1 inch)

Adult

Ingestion

3.31 E+04
(1.89E+04)a

mg/kg

Max

(8)

--

99.0
(95.4)

3.71 E+02
(1.31E+02)a

mg/kg

Mean

(8)

--

3.9
(2.0)

Surface Soil (0-1 inch)

Child

Ingestion

3.31 E+04
(1.89E+04)a

mg/kg

Max

(9)



99.9
(99.9)

Ambient Air

Inhalation

1.80E-01

ug/m3

Max

(9)

Private wells

Ingestion

Default Groundwater Concentration of 4 ug/L is used.

Indoor Dust

Determined using lEUBK's Multiple Source Analysis

Surface Soil (0-1 inch)

3.71 E+02
(1.31E+02)a

mg/kg

Mean

(9)



6.535
(0.094)

Ambient Air

Inhalation

1.80E-01

ug/m3

Max

(9)

Private wells

Ingestion

Default Groundwater Concentration of 4 ug/L is used.

Indoor Dust

Determined using lEUBK's Multiple Source Analysis

Surface Soil (0-1 inch)

2.92E+02
(1.31E+02)a

mg/kg

75th Percentile

(9)



3.468
(0.094)

Ambient Air

Inhalation

1.80E-01

ug/m3

Max

(9)

Private wells

Ingestion

Default Groundwater Concentration of 4 ug/L is used.

Indoor Dust

Determined using lEUBK's Multiple Source Analysis

Surface Soil (0-1 inch)

3.71 E+02

mg/kg

Mean

(9)



5.87

Ambient Air

Inhalation

1.10E-02

ug/m3

Mean

(9)

Private wells

Ingestion

Default Groundwater Concentration of 4 ug/L is used.

Indoor Dust

Determined using lEUBK's Multiple Source Analysis

EPC Rationale:

(1)	Highest average detected concentration at the 44 individual residences on non-BIA land; demonstrates acceptable risk associated with the range of measured residential concentrations.

(2)	Calculated using EPA's ProUCL software based on the modeled concentrations at the 44 individual residences.

(3)	Maximum modeled concentration after 30 years in residential, transition zone, and smelter-affected soil areas; demonstrates acceptable risk associated with the range of modeled concentrations.

(4)	Maximum modeled concentration in ambient air in residential, transition zone, and smelter-affected soil areas; demonstrates acceptable risk associated with the range of modeled concentrations.

(5)	Mean (average) measured concentration at 44 individual residences; evaluation was conducted for each individual residence.

(6)	Mean (average) measured concentration at individual residential wells; evaluation was conducted for each individual residence.

(7)	Modeled concentration at each home.

(8)	Two sets of statistical values based on modeled future concentrations in soil (0-1") after 30 years in residential, transition zone, and smelter-affected soil areas.

(9)	Four sets of statistical values based on modeled future concentrations in soil (0-1") after 30 years in residential, transition zone, and smelter-affected soil areas and in ambient air.

Note:

EPCs and risk estimates presented in parentheses are those revised in the Addendum,
a - EPCs and risk estimates are based on the modeled future soil data.

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Table 5-2

Risk Summary - Native American Exposures
Tar Creek OU4 Superfund Site

Scenario

Exposure

Receptor

Receptor

Exposure

Chemical of

Exposure Point Concentration (EPC)

Hazard

Excess Lifetime

Timeframe

Point

Population

Age

Route

Potential Concern

Value

Units

Basis

Rationale

Index (HI)

Cancer Risk
(ELCR)

Current

Surface Soil (0-1 inch)



Adult

Ingestion

CADMIUM

9.6E+00

mg/kg

Measured

(1)

5.E-02

-











ZINC

1.9E+03

mg/kg

Measured

(1)

4.E-02

-









Dermal

CADMIUM

9.6E+00

mg/kg

Measured

(1)

2.E-03

-











ZINC

1.9E+03

mg/kg

Measured

(1)

4.E-05

-







Child

Ingestion

CADMIUM

9.6E+00

mg/kg

Measured

(1)

3.E-01

-











ZINC

1.9E+03

mg/kg

Measured

(1)

2.E-01

-





Native American



Dermal

CADMIUM

9.6E+00

mg/kg

Measured

(1)

1.E-02

-





(Subsistence)





ZINC

1.9E+03

mg/kg

Measured

(1)

2.E-04

-



Small Game



Adult

Ingestion

CADMIUM

3.58E+01
(2.74E+01)a
(6.22E+01)b

mg/kg

95% UCL

(2)

2E-03
(4E-04)a

-



(e.g., Rabbit)









5.31 E+03







2E-04
(7E-05)a













ZINC

(5.39E+03)a
(2.95E+03)b

mg/kg

95% UCL

(2)

—



Beef (Cattle)







CADMIUM

3.58E+01
(2.74E+01)a
(6.22E+01)b

mg/kg

95% UCL

(2)

2E-08
(2E-08)a

-



* high fish diet







ZINC

5.31 E+03
(5.39E+03)a
(2.95E+03)b

mg/kg

95% UCL

(2)

6E-09
(7E-09)a

-



Beef (Cattle)







CADMIUM

3.58E+01
(2.74E+01)a
(6.22E+01)b

mg/kg

95% UCL

(2)

2E-07
(2E-07)a

-



* high beef diet







ZINC

5.31 E+03
(5.39E+03)a
(2.95E+03)b

mg/kg

95% UCL

(2)

6E-08
(6E-08)a

-



Milk (Dairy)



Child

Ingestion

CADMIUM

3.58E+01
(2.74E+01)a
(6.22E+01)b

ug/L

95% UCL

(2)

6E-02
(5E-02)a

-











ZINC

5.31 E+03
(5.39E+03)a
(2.95E+03)b

ug/L

95% UCL

(2)

5E-02
(6E-02)a

-



Asparagus



Adult

Ingestion

CADMIUM

5.5E+00

mg/kg

95% UCL

(3)

2E+01

-



(above ground)







ZINC

1.4E+02

mg/kg

95% UCL

(3)

2E+00

-



Asparagus







CADMIUM

1.2E+01

mg/kg

95% UCL

(3)

5E+01

-



(root)







ZINC

1.4E+03

mg/kg

95% UCL

(3)

2E+01

-



Willow







CADMIUM

1.8E+01

mg/kg

95% UCL

(3)

7E+01

-



(above ground)







ZINC

4.7E+02

mg/kg

95% UCL

(3)

6E+00

-



Willow







CADMIUM

5.0E+01

mg/kg

95% UCL

(3)

2E+02

-



(root)







ZINC

4.6E+03

mg/kg

95% UCL

(3)

6E+01

-



Cattail







CADMIUM

2.0E+01

mg/kg

95% UCL

(3)

8E+01

-



(above ground)







ZINC

2.6E+03

mg/kg

95% UCL

(3)

3E+01

-



Cattail







CADMIUM

6.1E+01

mg/kg

95% UCL

(3)

2E+02

-



(root)







ZINC

4.4E+03

mg/kg

95% UCL

(3)

6E+01

-



Ambient Air



Adult

Inhalation

CADMIUM

8.08E-05

ug/m3

95% UCL

(4)

6E-04

2E-07







Child



CADMIUM

8.08E-05

ug/m3

95% UCL

(4)

1E-03

3E-08

Current/Future

Private wells



Adult

Ingestion

ZINC

2.2E-01

mg/L

Max

(1)

4.E-02

-







Child



ZINC

2.2E-01

mg/L

Max

(1)

5.E-02

-



Aquatic Foods



Adult

Ingestion

CADMIUM

4.0E+00

mg/kg

Mean

(5)

7E+00
(4E+00)

-



(e.g., Mussels)







ZINC

3.6E+02

mg/kg

Mean

(5)

2E-01
(7E-01)

-



Fish







CADMIUM

1.7E-01

mg/kg

Mean

(6)

2E+00

-



* high fish diet







ZINC

2.1E+01

mg/kg

Mean

(6)

9E-01

-



Fish







CADMIUM

1.7E-01

mg/kg

Mean

(6)

2E-01

-



* high beef diet







ZINC

2.1E+01

mg/kg

Mean

(6)

8E-02

-

Future

Surface Soil (0-1 inch)



Adult

Ingestion

CADMIUM

2.2E+00
(4.6E+00)

mg/kg

Max

(7)

1E-02
(3E-02)

-











ZINC

4.0E+02
(8.5E+02)

mg/kg

Max

(7)

7E-03
(2E-02)

-









Dermal

CADMIUM

2.2E+00
(4.6E+00)

mg/kg

Max

(7)

5E-04
(1E-03)

-











ZINC

4.0E+02
(8.5E+02)

mg/kg

Max

(7)

7E-06
(2E-05)

-







Child

Ingestion

CADMIUM

2.2E+00
(4.6E+00)

mg/kg

Max

(7)

6E-02
(1E-01)

-











ZINC

4.0E+02
(8.5E+02)

mg/kg

Max

(7)

3E-02
(7E-02)

-









Dermal

CADMIUM

2.2E+00
(4.6E+00)

mg/kg

Max

(7)

3E-03
(6E-03)

-











ZINC

4.0E+02
(8.5E+02)

mg/kg

Max

(7)

5E-05
(1E-04)

-



Ambient Air



Adult

Inhalation

CADMIUM

4.3E-06

mg/m3

Max

(8)

3E-02

-







Child





4.3E-06

mg/m3

Max

(8)

5E-02

-







Adult/Child





4.3E-06

mg/m3

Max

(8)

-

1E-05

008384

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Table 5-2

Risk Summary - Native American Exposures
Tar Creek OU4 Superfund Site

Scenario
Timeframe

Exposure
Point

Receptor
Population

Receptor
Age

Exposure
Route

Chemical of
Potential Concern

Exposure Point Concentration (EPC)

Hazard
Index (HI)

Excess Lifetime
Cancer Risk
(ELCR)

Value

Units

Basis

Rationale

Scenario
Timeframe

Exposure
Point

Receptor
Population

Receptor
Age

Exposure
Route

Chemical of
Potential Concern

Exposure Point Concentration (EPC)

No. of Homes
with BLL
Exceeding
Criterion

Percent Above
Target BLL
of 10 ug/dl

Value or Range

Units

Basis

Rationale

Current

Surface Soil (0-1 inch)

Native American
(Subsistence)

Adult

Ingestion

Lead

29.1 -88.4

mg/kg

Mean

(9)

2/2
(2/2)

100
(100)

Small Game

3.10E+03
(4.41 E+02)a
(2.01 E+04)b

mg/kg

95% UCL

(2)

Beef

3.10E+03
(4.41 E+02)a
(2.01 E+04)b

mg/kg

95% UCL

(2)

Aquatic Foods

2.90E+01

mg/kg

Mean

(5)

Fish

4.27E-01

mg/kg

Mean

(6)

Asparagus (above ground)

1.88E+01

mg/kg

Mean

(10)

Asparagus (root)

5.58E+02

mg/kg

Mean

(10)

Willow (above ground)

1.09E+01

mg/kg

Mean

(10)

Willow (root)

1.02E+03

mg/kg

Mean

(10)

Cattail (above ground)

2.87E+02

mg/kg

Mean

(10)

Cattail (root)

1.08E+03

mg/kg

Mean

(10)

Surface Soil (0-1 inch)

Child

Ingestion

29.1 -88.4

mg/kg

Mean

(9)

0/2
(0/2)

-

Private wells

0.42 - 4

ug/L

Mean

(11)

Milk

(1.01 E-01)a

mg/kg

95% UCL

(2)

Indoor Dust

Determined using lEUBK's Multiple Source Analysis

Ambient Air

Inhalation

3.7e-7 - 4.2e-7

mg/m3

Point

(12)

Future

Surface Soil (0-1 inch)

Adult

Ingestion

3.31 E+04
(1.89E+04)c

mg/kg

Max

(13)

-

100
(100)

3.71E+02
(1.31 E+02)c

mg/kg

Mean

(13)

-

37.5
(11.6)

1.10E+02
(4.56E+01)c

mg/kg

Median

(13)

-

9.5

(3.8)

EPC Rationale:

(1)	Highest average detected concentration at the 2 individual residences currently on BIA land; demonstrates acceptable risk associated with the range of measured residential concentrations.

(2)	Calculated using EPA's ProUCL software and measured concentrations in surface soil (residential, smelter, transition zone) - used to model concentrations in biota; soil concentrations presented.

(3)	Calculated using EPA's ProUCL software based on the measured concentrations in these plants.

(4)	Calculated using EPA's ProUCL software and modeled concentrations at 46 rural residential properties.

(5)	Mean detected sediment concentrations used to model concentrations in aquatic biota - obtained from ODEQ's fish tissue study (ODEQ, 2003); sediment concentration presented.

(6)	Mean detected concentrations in fish tissue obtained from ODEQ's fish tissue study (ODEQ, 2003).

(7)	Maximum modeled concentration after 30 years in residential, transition zone, and smelter-affected soil areas; demonstrates acceptable risk associated with the range of modeled concentrations.

(8)	Maximum modeled concentration in ambient air in residential, transition zone, and smelter-affected soil areas; demonstrates acceptable risk associated with the range of modeled concentrations.

(9)	Mean (average) measured concentration at 2 individual residences on BIA land; evaluation was conducted for each individual residence.

(10)	Mean (average) measured concentrations.

(11)	Mean (average) measured concentration at 2 individual residential wells; for the 1 home without a well, the default concentration of 4 ug/L was used.

(12)	Modeled concentration at each home.

(13)	Three sets of statistical values based on modeled future concentrations in soil after 30 years in residential, transition zone, and smelter-affected soil areas.

Note:

EPCs and risk estimates presented in parentheses are those revised in the Addendum.

a - EPCs and risk estimates are based on the soil data collected from residential properties, rural areas, and transition zone,
b - EPCs are based on the soil data collected from smelter-affected areas,
c - EPCs and risk estimates are based on the modeled future soil data.

008385

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Table 5-3

Risk Summary - Recreator Exposures
Tar Creek OU4 Superfund Site

Scenario
Timeframe

Exposure
Point

Receptor
Population

Receptor
Age

Exposure
Route

Chemical of
Potential Concern

Exposure Point Concentration (EPC)

Hazard
Index (HI)

Excess Lifetime
Cancer Risk
(ELCR)

Value

Units

Basis

Rationale

Current/Future

Chat and Tailings
Material

Recreator

Adolescent

Ingestion

CADMIUM

9.3E+01

mg/kg

95% UCL

(1)

1.E-01



ZINC

1.8E+04

mg/kg

95% UCL

(1)

6.E-02



Dermal

CADMIUM

9.3E+01

mg/kg

95% UCL

(1)

1.E-02



ZINC

1.8E+04

mg/kg

95% UCL

(1)

2.E-04



























Scenario
Timeframe

Exposure
Point

Receptor
Population

Receptor
Age

Exposure
Route

Chemical of
Potential Concern

Exposure Point Concentration (EPC)

Percent Above
Target BLL
of 10 ug/dl



Value

Units

Basis

Rationale

Current/Future

Chat and Tailings
Material

Recreator

Adolescent

Ingestion

Lead

3.46E+03

mg/kg

Mean

(2)

22.3%



EPC Rationale:

(1)	Calculated using EPA's ProUCL software and measured concentrations in sieved (250 um) samples collected from 0-1 inch or 0-6 inches.

(2)	Mean (average) measured concentration in chat and tailings samples collected from 0-1 inch or 0-6 inches and sieved.

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DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

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6.0 Blood Lead Studies in Tar Creek

The following text was excerpted from Report to Congress - Tar Creek Snperfund Site
(ATSDR, 2004; Appendix I)

6.1 Datasets Reviewed

The Agency for Toxic Substances and Disease Registry (ATSDR) reviewed and analyzed
data on the BLLs of children living at the site from January 1995 through February 2004
(Appendix M, Figure 3). The Ottawa County Sunshine Clinic, the Ottawa County Lead
Poisoning Prevention Program (OCLPPP) managed by the Ottawa County Health
Department (OCHD), Tribal Efforts Against Lead (TEAL) and Community Health Action
and Monitoring Program (CHAMP) surveys, Tribal Health Clinics, private physicians, and
other private and public clinics collect blood from children and test for lead. These programs
send data to the Oklahoma State Department of Health (OSDH) Childhood Lead Poisoning
Prevention Program Surveillance System (CLPPSS), which then transmits aggregate data to
the CDC and Prevention's Childhood Blood Lead Surveillance Program.

The most useful data sources for assessing BLLs of children living at the site were the 1995—
2002 OSDH CLPPSS, the 1997 and 2000 TEAL survey, and the 1999-2004 OCLPPP
screening data (Appendix M, Tables 4 and 5). Children were considered to live at the site if
their medical records indicated that they lived at addresses in the northeast Oklahoma towns
of Cardin, Commerce, North Miami, Picher, or Quapaw. For this analysis, all children with
addresses from North Miami were included as living at the site—even though a portion of
North Miami is outside the site boundaries (Appendix M, Figure 1). ATSDR included this
portion of North Miami in the estimates for the population or number of children living at the
site.

OCLPPP provides blood lead testing free of charge to children living at the site and to all
other children, including tribal children, living in Ottawa County. Families with young
children who may be at risk for lead poisoning are highly encouraged to participate in the
voluntary program. OCLPPP personnel offer testing on site at the OCHD and conduct regular
screening efforts at schools, preschools, daycare centers, Head Start programs, and local
shopping areas. OCLPPP also conducts identification and screening efforts in coordination
with the Women, Infants, and Children (WIC) program and with other public health
programs. In addition, OCLPPP provides on-location testing services to potential high-risk
areas, as warranted (13).

ATSDR used the OCLPPP data as the source for 2003 BLLs for tested children living at the
site because those data incorporate:

• The most recent and current data available at the time of this analysis;

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•	A substantial number of children tested (40% of the estimated population of children,
aged 1 to 5 years, living at the site—based on 2000 census block data analysis for
population estimate);

•	Numerous BLL tests throughout the year (total of 308 for children, aged 1 to 5 years,
living at the site in 2003);

•	A high level of test result recording accuracy (a check of existing BLL entries with
actual patient paper records showed only four errant electronic entries in 390 follow-
up patient records that contain up to 14 entries each);

•	BLLs reported to the 10th |ig/dL (OSDH CLPPSS data were rounded to the nearest
whole number) with consistent application of non-detect values (statistical values
assigned to test results when lead in a blood sample is too low to be detected);

•	Data based on results obtained from consistent testing protocols and analysis criteria;
and

•	Targeted testing for potentially higher risk children (Head Start programs, siblings of
children with elevated BLLs, WIC).

The OCLPPP data system is the largest contributor of data to the OSDH CLPPSS system.
Both OSDH CLPPSS and OCLPPP datasets are comprised primarily of capillary blood lead
testing data (under OCLPPP, a confirmatory venous test is provided after an elevated
capillary test result). Both the OSDH CLPPSS and OCLPPP datasets consist of convenience
samples rather than representative samples. All TEAL survey blood lead tests were venous,
and TEAL used a door-to-door sampling method. In calculating geometric means for the
OSDH CLPPSS and OCLPPP data for each year, ATSDR used the highest test of each child
tested in the respective year.

The simple arithmetic mean is not suitable for representing "average" conditions when a
large proportion of the observations are clustered at one end of the data range. This is often
the situation with blood lead levels. The occurrence of a few high numbers would result in a
perceived "average" far higher than a number that would be reflective of actual conditions. In
such situations, the geometric mean is a more appropriate measure of central tendency than
the arithmetic mean. The result represents a more accurate estimate of common or typical
conditions.

6.2 Percentage of Elevated BLLs and Geometric Mean of BLLs

Among tested children aged 1-5 years living in the Tar Creek Superfund site, the percentage
of BLL elevations and the geometric BLL mean declined from 1995-2003 (Appendix M,
Figures 4 and 6). In 1996, OSDH CLPPSS data showed that among tested children aged 1-5
years living at the site, 31.2 percent (67/215) had BLL at or above 10 |ig/dL and the
geometric mean was 6.65 |ig/dL. In 2003, OCLPPP data showed that among tested children
aged 1-5 years living at the site, 2.8 percent (7/250) had elevated BLLs, and the geometric
mean was 3.04 |ig/dL. These 2003 statistics are slightly higher than the findings of the
National Health and Nutrition Examination Surveys (NHANES) for children living in the

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DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

United States as a whole. NHANES data indicate that among U.S. children aged 1-5 years
during 1999-2000, 2.2 percent had elevated BLLs, and the geometric mean was 2.2 |ig/dL.

6.3	Picher/Cardin in Comparison with the Tar Creek Superfund
Site as a Whole

Of the children in Picher and Cardin who were tested for blood lead, the percentage with
elevated BLLs and the geometric mean declined from 1995-2003 (Appendix M, Figures 5
and 7). In 1996, OKCLPPSS data showed that among tested children aged 1-5 years living in
Picher and Cardin, 44.6 percent (41/92) had elevated BLLs and the geometric mean was 9.17
|ig/dL. In 2003, the OCLPPP data showed that among tested children aged 1-5 years living in
Picher and Cardin, 3.4 percent (3/88) had elevated BLLs, and the geometric mean was 3.82
M-g/dL.

In 1996, the percentage of children identified with elevated BLLs and the geometric BLL
mean for all children tested were higher in the combined areas of Picher and Cardin than at
the site as a whole. However, these differences have diminished in recent years.

6.4	Characteristics of Children With Elevated BLLs

From January 2000 to March 2004, 37 children under 6 years of age living at the site were
identified with elevated BLLs (at or above 10 |ig/dL) by the OCHD. Of these children 41
percent (15/37) were from five households. This could suggest that high-risk behaviors were
shared by these family members or that common exposure sources were present.

In 2003, OCLPPP identified seven children aged 1 to 5 years living at the site as having
elevated BLLs. The OCLPPP program conducted or received data from environmental
assessments of the residences of six of these children at various points in time (some prior to
2003). The potential sources of lead exposure found to be present at the respective residences
are described in Appendix M, Table 7 in the appendix and include lead-based paint, lead-
containing floor dust (at or above 10 ng/fb), and soil with elevated lead levels (above 500
mg/kg).

6.5	Data Limitations

Any comparisons of the OCLPPP data with NHANES U.S. data should be viewed with
caution because the NHANES data are based on a representative sample of the United States
(1, 14), and the OCLPPP data comprises a convenience sample rather than representative
samples of the site area. As shown in Appendix M, Tables 4 and 5, the OKCLPPSS, TEAL,
and OCLPPP data samples include a substantial proportion but not all of the estimated
population of children, aged 1 to 5 years, living at the site.

NHANES data are generalized to the U.S. population and were not intended to provide
estimates for smaller areas or for specific populations where the risk for elevated BLLs is
high (14). Furthermore, all NHANES blood lead tests are collected by venous sampling (14),
whereas the OSDH CLPPSS and OCLPPP programs primarily collect blood through
capillary sampling.

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DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

Because sample contamination of a capillary test can over-estimate BLLs (15, 16) and
because ATSDR used each tested child's highest BLL to calculate geometric means,
geometric means of the OSDH CLPPSS and OCLPPP datasets probably overestimate actual
geometric means.

The 1997 and 2000 TEAL surveys measured lead from venous blood. Given the relatively
high availability of free screening in the area, it is not known if the use of venous testing and
the presence of incentives to participant families could have resulted in higher relative TEAL
participation in areas of lower median income and among children with higher risk factors
for lead poisoning.

Many other relative factors could be explored, including the prevalence of pre-1950 housing
units and poverty at the site area as compared to that of the United States (Appendix M,
Table 3). An updated NHANES blood lead survey might show a further decline in national
BLLs since 1999-2000. BLLs in U.S. children have been declining (14).

6.6	Interventions

Many activities may have been instrumental in reducing elevated BLLs at the site. In 1995,
after the confirmation of elevated BLLs, ATSDR funded the OSDH to conduct extensive
blood lead testing throughout Ottawa County. OSDH determined that 28.3% of children
tested had BLLs at or above 10 |ig/dL. Several projects implemented over the past several
years have increased community knowledge of exposure and the harmful effects of lead.
Some of those include CHAMP and TEAL. Beginning in 1995, EPA began testing and
remediating residential soils and areas where children play (such as school and city parks and
playgrounds, ball fields, and daycare centers). Since 1998, the OCHD has conducted
extensive blood lead screening, and community and health provider education. OCHD has
distributed HEPA vacuums to area households who have children with elevated BLLs. The
area also received U.S. Housing and Urban Development funds for lead abatement in homes.

These activities, combined, may have helped to reduce BLLs in Ottawa County. BLLs of
children living at or near the site might increase without these interventions.

6.7	Conclusions

Two potential sources were found for lead in children in the Tar Creek site area: mine
tailings and lead-based paint. Both could contribute lead to house dust and soil, which most
likely are the points of exposure for children. The relative contributions of exposure to mine
tailings and exposure to lead-based paint on the BLLs of people living at the site cannot be
determined from existing information.

The evidence available to ATSDR indicates that mine tailings in the residential area soil
exposure pathway may have been a primary source of the lead in children's blood before
EPA remediated the Tar Creek residential areas. Exposure to mine tailings still could occur
because Tar Creek area residents, especially those in Picher and Cardin, remain near tailings
piles, ponds, and embankments and can readily access these tailings deposits. Additionally,
the close proximity of these tailings to residences increases the risk for recontamination of
residential soil because of blowing dust or residential or commercial use of the tailings.

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A decline in the average BLLs among tested children aged 1 to 5 years living at the site from
1995-2003 has been observed, as was a decrease in the percentage of tested children with
elevated BLLs from 1995 to 2003. The average BLLs and the percentage of elevated BLLs
among tested children living at the site in 2003 were slightly higher than for children living
in the United States as a whole in 1999-2000 (1). However, this comparison should be
viewed with caution because the U.S. data are based on a representative sample of the United
States (1), the Tar Creek data is from a convenience sample and not a representative sample,
and U.S. child BLLs also may have declined since 2000.

Declining BLLs among tested children living at the site should not be interpreted to mean
that existing interventions in the Tar Creek area are no longer needed. Potential lead sources,
including unremediated yards, chat piles, tailings ponds, and residential lead-based paint,
remain at the site.

Existing programs should be evaluated to determine how they may have contributed to this
decline. The OCHD should continue existing blood lead screening and public health
education efforts. Ongoing screening efforts are needed to confirm and monitor trends.
Ongoing public health education reinforces the need for adult, parental, and child behaviors
that may reduce exposure to lead and subsequent health effects.

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7.0 Uncertainties

This section presents a discussion of the assumptions and procedures that introduce the
greatest amount of uncertainty in the HHRA, as well as their effect on the estimates of
potential risk. The discussion of their effect is qualitative because in many instances not
enough information exists to quantify the magnitude of these uncertainties.

Calculated RME ELCRs presented in Section 5.4 are estimates of potential upper-bound
risks that are useful in regulatory decision-making. It is improper to consider these assumed
risks as representative of the actual risk to potentially exposed individuals because they were
estimated by making numerous conservative assumptions (i.e., assumptions that overestimate
potential exposure and potential risk). Thus, they have uncertainty associated with them.
Some of the assumptions have a firm scientific basis while others do not.

Some level of uncertainty is introduced into the risk assessment process every time an
assumption is made. In regulatory risk assessment, the methodology dictates that
assumptions err on the side of overestimating potential exposure and risk. The effect of using
numerous assumptions, each of which overestimates potential risk, is to exaggerate estimates
of potential risk. Such estimates do not provide a realistic estimate of the potential health
impacts associated with a site.

This uncertainty analysis is divided into subsections that correspond to the four steps in the
HHRA process described by EPA.

7.1	Data Evaluation

The purpose of data evaluation is to determine which chemicals are present at the site at
concentrations requiring evaluation in the risk assessment. Uncertainty with respect to data
evaluation can arise from many sources, such as the quality of the data used to characterize
the site and the process used to select data included in the risk assessment. Analytical
parameters were selected based upon knowledge of historical site activities (mining).

There is some uncertainty associated with the size of the Tar Creek study area and the limited
number of samples that were collected from the various media. However, the data are
expected to represent the range of concentrations that may be contacted in the various media
within the Tar Creek area. Use of this data is not expected to affect the conclusions of the
HHRA significantly, but adds uncertainty to the locations that may warrant risk management.

7.2	Exposure Assessment

An exposure assessment consists of two basic elements: estimation of potential EPCs and
estimation of potential intakes. The following sections discuss important sources of
uncertainty associated with these two elements.

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7.2.1 Exposure Point Concentrations

The following concentrations were used as EPCs for cadmium and zinc in the intake
calculations:

•	current residential yard soil - maximum detected concentrations;

•	current/future ground water - maximum detected concentrations;

•	current ambient air - UCL95 of modeled concentrations at 46 yards where soil
samples were collected;

•	future soil -maximum modeled concentrations for the Tar Creek Area;

•	future ambient air - maximum modeled concentrations for the Tar Creek Area;

•	current/future chat pile material/tailings - UCL95 of detected concentrations;

•	current/future edible plants - UCL95 of detected concentrations for each plant
species;

•	current/future small game - modeled using UCL95 of detected concentrations from
soils in residential yards, smelter area, transition zone, and rural areas, and
bioaccumulation factor (BAF) from soil to small game;

•	current/future beef - modeled using UCL95 of detected concentrations from soils in
residential yards, smelter area, transition zone, and rural areas, and biotransfer from
soil/plants to beef;

•	current/future dairy milk - UCL95 of detected concentrations from soils in residential
yards, smelter area, transition zone, and rural areas, and biotransfer from soil/plants to
milk;

•	current/future fish - mean detected concentrations from the ODEQ (ODEQ, 2003)
study; and

•	current/future aquatic food - modeled using mean detected concentrations in
sediments from the ODEQ (2003) study.

In addition, the following concentrations were used as EPCs for lead in the intake
calculations:

•	current residential yard soil - average detected concentration at each yard; if a soil
sample was not collected but a ground water sample was collected and the residence
was addressed under OU2, 500 ppm (the OU2 cleanup level) was assumed; if a
ground water sample was collected and the residence was not addressed under OU2,
the average detected concentration at all residential yards on public land was used
(since the ground water samples [without accompanying soil samples] were collected
on public land).

•	Current residential indoor dust - the default dust-to-soil ratio provided in the IEUBK
model was used; although four indoor dust samples were collected in October 2005

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from four properties where residential yard concentrations exceeded 500 ppm, the
dust sample size was small (lead was detected in only two of the four samples) and
the outdoor soil-to-indoor dust correlation was not strong; the observed correlation
was therefore not applied to the rural residential properties in Tar Creek.

•	current/future ground water - average detected concentration at each home where
measured; if a well was not present, the default ground water concentration in the
IEUBK model was used;

•	current ambient air - modeled concentration at each residence;

•	future soil - (original calculations: maximum, mean, median, and 75th percentile
modeled concentrations for the Tar Creek Area); updated calculations included the
maximum and mean (same as 75th percentile) modeled concentrations for the Tar
Creek Area;

•	future ambient air - maximum and mean modeled concentrations for the Tar Creek
Area;

•	current/future chat pile material/tailings - UCL95 of detected concentrations;

•	current/future edible plants - average detected concentrations for each plant species;

•	current/future small game - modeled using UCL95 of detected concentrations from
soils in residential yards, smelter area, and transition zone, and BAF from soil to
small game; the updated EPC incorporated a lower cadmium concentration in
transition zone soil and additional samples from rural areas.

•	current/future beef - modeled using UCL95 of detected concentrations from soils in
residential yards, smelter area, and transition zone, and biotransfer from soil/plants to
beef; the updated EPC incorporated a lower cadmium concentration in transition zone
soil and additional samples from rural areas.

•	current/future dairy milk - UCL95 of detected concentrations from soils in residential
yards, smelter area, and transition zone, and biotransfer from soil/plants to milk; the
updated EPC incorporated a lower cadmium concentration in transition zone soil and
additional samples from rural areas.

•	current/future fish - mean detected concentrations from the ODEQ (ODEQ, 2003)
study; and

•	current/future aquatic food - modeled using mean detected concentrations in
sediments from the ODEQ (2003) study.

This will likely lead to an overestimation of actual exposure because receptors are assumed
to be exposed to the maximum or UCL95 concentration for the entire exposure duration. As
the data indicate, COPCs were detected in environmental media within a large range of
concentrations. In addition, cadmium and lead were not detected in most fish samples
collected by ODEQ (2003). Thus, the assumption that all potential exposures are to the
maximum or UCL95 concentrations will likely result in an overestimation of actual
exposures and estimates of potential risk.

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For all media except soil, the future concentrations were assumed to be unchanged.

However, materials currently situated within chat piles may be removed from the Tar Creek
area in the future, lowering potential soil and ambient air concentrations. Therefore, this is
expected to be a conservative approach to evaluating future exposures. Since the chat piles
and tailings ponds have been located in this area for many years, it is expected that ground
water concentrations detected in private wells will not increase significantly over those
concentrations detected during the RI.

The concentrations in plants consumed by beef cattle during grazing were modeled using soil
uptake information presented in EPA guidance (EPA, 2005a) and the UCL95 concentration
in soil from yards, smelter-affected soil, transition zones, and rural areas. Use of the model
may overestimate or underestimate potential plant concentrations for some cattle depending
on the specific chemical, resulting in under- or overestimation of risks from beef and milk
ingestion. Maximum detected concentrations in composite plant samples (on which cattle
graze: Blue Stem, Bermuda, Red Clover, Yellow Hop, White Clover, Crab Grass, Fescue,
Lespidiza, and Switch Grass) collected from the smelter area and the modeled plant
concentrations are indicated below:

•	lead - 28.6 ppm (detected) versus 0.045 ppm (modeled);

•	cadmium - 3 ppm (detected) versus 13 ppm (modeled); and

•	zinc - 193 ppm (detected) versus 1300 ppm (modeled).

Homegrown vegetable samples were not collected during the RI for OU4, although they were
collected for OU2. The HHRA prepared for OU2 included an evaluation of soil and
homegrown produce at various homes in Picher, and analytical results from the homegrown
produce were used to evaluate potential risks in the OU2 HHRA. Soil and dust ingestion
accounted, on average, for 82% of the estimated total lead uptake within the study group.
The contribution of diet to total lead uptake was substantially lower (16%). Most of the
estimated dietary lead uptake was derived from default dietary lead intake and a smaller
portion from homegrown produce. Therefore, although homegrown produce intakes were
not quantified in the OU4 HHRA, it is not expected to affect the results of the HHRA
significantly.

7.2.2 Estimated Intakes

Significant uncertainty exists in assumptions used to calculate chemical intakes from
exposure to various media (e.g., rate of ingestion, frequency and duration of exposure,
absorption efficiency). Conservative exposure factors (i.e., health-protective) are used when
available information is limited. This may result in an overestimation of risk.

This HHRA follows EPA guidance and estimates ELCRs and His for a theoretical RME
individual. For example, the Native American resident is assumed to contact soil dermally
350 days per year for 70 years. An individual Native American resident is unlikely to contact
soil at this frequency and duration, but 350 days per year is expected to be a conservative
estimate. Actual risks are likely to be less than the potential risks presented in this HHRA.

Significant uncertainty exists in assumptions used to calculate chemical intake from exposure
to various media (e.g., rate of ingestion, frequency and duration of exposure, absorption

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efficiency). Conservative (i.e., health-protective) exposure factors were used since site-
specific values were not available. This is expected to result in an overestimation of potential
risk for the COPCs and exposure pathways quantified in the HHRA.

There are uncertainties in the modeling used to estimate lead exposures by adolescent
recreators. The more significant uncertainties include the use of the ALM for an adolescent
population, the potential for a lead higher absorption factor (i.e., up to 30%), the potential for
a higher soil ingestion rate (e.g., 200 mg/day), the potential for a lower exposure frequency
(e.g., 78 days/year), and a potential lower baseline BLL than that assumed in the risk
calculations. However, a potentially higher absorption factor and lower baseline BLL are
likely to cancel each other out in the lead exposure calculations.

The food intakes assumed for a high-beef diet and high-fish diet Native American resident
were obtained from the Spokane Tribe study, which may not be applicable for the Native
American residents at the Tar Creek Superfund Site. The ingestion rates that were assumed
include approximately 2.6 pounds of meat/fish and approximately 3.5 pounds of vegetables
per day, all grown on impacted soil. It was also assumed that cattail, willow, and asparagus
comprise 100 percent of their diet, which is unrealistic. The EPA Exposure Factors
Handbook presents intake rates for the Native American scenario that are much lower than
the Spokane Tribe rates assumed in this HHRA. Therefore, the risks presented in this HHRA
for the Native American resident are expected to be overestimated and are likely better
represented by the assumptions for more typical Native Americans (in the Exposure Factors
Handbook).

There is uncertainty associated with the inputs used in the ambient air modeling and
deposition modeling based on limited data from chat piles and mill ponds. Thirty years of
deposition are assumed to be extrapolated to the entire Tar Creek Area, including those areas
where samples have not been collected. Kreiging was used to estimate concentrations at
locations where no soil data were available.

Exposure to COPCs via the breastmilk pathway were not evaluated due to the lack of
available bioaccumulation data. Therefore, the risks associated with this pathway were not
addressed and are underestimated.

The bioavailability of lead in soil at the Tar Creek site was not measured. However, the
bioavailability of lead in soil was evaluated at the Jasper County, Missouri Superfund Site, a
similar site to Tar Creek OU4 in terms of waste sources and environmental conditions
(Casteel et al., 1996). Three soil samples from the site (composites from different areas of
the site) were used in a study to measure the gastrointestinal absorption of lead from soil.
Concentrations in the three soil samples ranged from 4,050 to 10,800 ppm lead. The amount
of lead absorbed by each animal was evaluated by measuring the amount of lead in the blood,
liver, kidney, and bone. Results indicate bioavailability in the range of 29 to 40 percent.
Therefore, the default bioavailability factor of 30% used in the IEUBK model seems to fall
within the ballpark of the actual bioavailability for the site soil and, as such, the assumed
bioavailability does not over- or underestimate site risk.

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7.3	Toxicity Assessment

Dermal toxicity values are not available in the standard toxicity references. Therefore, dermal
toxicity values were calculated using oral toxicity values and available oral absorption
efficiencies for the study animals for which oral RfDs were derived. Depending on the
quality of the data available for absorption efficiencies, and depending on whether or not
dermal exposures result in the same type of target effect (as observed in the oral study), this
may result in underestimation or overestimation of risk.

7.4	Risk Characterization

Generally, the goal of a baseline HHRA is to estimate an upper-bound, but reasonable,
potential risk. Such an upper-bound estimate can be derived in several ways, depending on
how conservative one wants the final estimate. In the baseline HHRA, several upper-bound
assumptions and numerous exposure pathways were combined to estimate potential risks.

Most of the assumptions about exposure and toxicity used in the HHRAs are representative
of statistical upper-bounds or even maximums for each parameter. The result of combining
several such upper-bound assumptions is that the final estimate of potential exposure or
potential risk is conservative.

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8.0 Preliminary Remediation Goals

The risk calculations presented in Section 7 indicate unacceptable risks from the COPCs for
the receptors and exposure routes indicated below:

•	General Public Child and Adult Resident - lead (soil and groundwater) for both child
and adult; cadmium (soil) for adult;

•	General Public Adolescent Recreator - lead (source materials); and

•	Native American Adult Resident - cadmium and zinc (vegetables and edible plants)
and lead (the specific media driving the risk were not identified).

This section further evaluates key pathways to estimate target concentrations (Preliminary
Remediation Goals or PRGs) that are protective for persons residing in OU4 based on
various possible exposure scenarios. Lead has been shown to be the primary COC such that
PRGs focused on protective concentrations of lead will also be protective for cadmium and
zinc exposures. The target % of the population with BLL >10 |ig/dl is 5. Both the ALM and
IEUBK model were used for calculating RGs for lead. PRGs for cadmium and zinc were
estimated based on a target Hazard Index (HI) of 1 (unity). Since they have different target
organs, the PRGs for these chemicals were developed independently.

The PRGs, which are presented in Appendix N, address the following media:

•	Groundwater

•	Rural residential soil

•	Source materials (chat piles, chat bases, tailing ponds)

o Recreational use

•	Rural non-residential soil

o Pastureland (for game animals or beef cattle)

•	Food Items

8.1 Groundwater

The lead concentration in two shallow rural residential wells exceeds the Federal Action
Level of 15 |ig/L for protection of drinking water. In the future, if additional shallow wells
are installed in other areas of Tar Creek for rural residential purposes, groundwater
concentrations may pose unacceptable risks. The remedial goal for lead in groundwater is
15 ng/L.

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8.2 Rural Residential Soil

Residential properties are assumed to be less than 0.5 acres, with more frequent contact of
soils occurring near the home. Of the potential routes of exposure, incidental ingestion of soil
by children is commonly the primary exposure pathway. Exposure may also occur via indoor
dust. An attempt was made to correlate indoor dust concentrations with outdoor soil
concentrations. However, an insufficient quantity of data was available and the statistical
evaluation indicated that the correlations between indoor dust and outdoor soil concentrations
were not strong (Appendix N, Figures 1-6). Therefore, the default ratio embedded in the
IEUBK model was used. If there is additional dietary intake of COPCs (e.g., eating beef and
drinking milk from cows grazing on impacted pastureland), soil PRGs that are more
conservative may be needed. The PRGs are discussed below for rural residential soils for
General Public and Native American populations.

8.2.1 General Public Rural Residential Use

Unacceptable concentrations of lead (defined as one or more samples at concentrations above
500 ppm) were identified at six of 46 current rural residential properties. One of these
residences (a home at the former smelter) was subsequently remediated in November 2005.
In addition, if additional properties were used for rural residential purposes in the future, soil
concentrations of cadmium and lead on some properties would pose unacceptable risks. The
PRG for lead in residential soil that was developed for OU2 (500 mg/kg) was identified as
the PRG for rural residential soil in OU4. The EPA Region 6 MSSL for cadmium of 39
mg/kg on residential properties was identified as the PRG for cadmium.

Potential modification of these PRGs was considered for rural residential properties where
homegrown produce may be ingested. The PRGs protective for ingestion of homegrown
produce (including incidental ingestion of soil) were estimated based on four assumptions
regarding dietary intake percentages of homegrown produce (i.e., 10, 25, 50, and 100%)
using the biotransfer factors presented in EPA's Combustion Guidance (EPA, 2005a) and are
presented in Tables 8-1 through 8-3.

The HHRA prepared for OU2 included an evaluation of soil and homegrown produce at
various homes in Picher, and analytical results from the homegrown produce were used to
evaluate potential risks. Soil and dust ingestion accounted, on average, for 82% of the
estimated total lead uptake within the study group. The contribution of diet to total lead
uptake was substantially lower (16%). Most of the estimated dietary lead uptake was derived
from default dietary lead intake and a smaller portion from homegrown produce. Therefore,
the remedial goal for lead in soil at OU2 (500 mg/kg) was based on exposures to soil/dust.
Consequently, soil lead concentrations at 500 mg/kg are considered protective of homegrown
vegetable exposures.

This type of produce data was not specifically collected for OU4, and the conclusion for OU2
is recommended. This is considered protective at OU4 for several reasons:

• Lead, the primary COC, does not significantly accumulate in common homegrown
produce.

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•	Child exposures are not significantly increased because they do not typically perform
gardening and have limited intake of these homegrown produce.

•	Food ingestion from small residential gardens reflects only a relatively small
percentage of a person's total diet.

Table 8-1

Cadmium - Soil PRGs Based on General Public Consumption of Homegrown Produce
Tar Creek OU4 Superfund Site

Adult

Child

Soil PRG
(mg/kg)

Plant Cone,
(mg/kg)

% of Plants
Eaten

Soil PRG
(mg/kg)

Plant Cone,
(mg/kg)

% of Plants
Eaten

9.4

1.18

10

4.86

0.608

10

3.8

0.474

25

2.02

0.253

25

1.9

0.237

50

1.02

0.128

50

0.95

0.119

100

0.515

0.0644

100

Table 8-2

Zinc - Soil PRGs Based on General Public Consumption of Homegrown Produce
Tar Creek OU4 Superfund Site

Adult

Child

Soil PRG
(mg/kg)

Plant Cone,
(mg/kg)

% of Plants
Eaten

Soil PRG
(mg/kg)

Plant Cone,
(mg/kg)

% of Plants
Eaten

3580

351

10

1830

179

10

1450

142

25

767

75.2

25

726

71.2

50

390

38.2

50

364

35.7

100

197

19.3

100

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Table 8-3

Lead - Soil PRGs Based on General Public Adult Consumption of

Homegrown Produce

Tar Creek OU4 Superfund Site

Soil PRG (mg/kg)

Plant Cone, (mg/kg)

% of Plants Eaten

112

1.52

10

52

0.71

25

28

0.38

50

14

0.19

100

(Note: A highly conservative biotransfer factor from soil to plants was used in the calculations; it is overly conservative
based on results of produce sampling in OU-2).

Additionally, the PRGs protective for ingestion of beef from cattle grazing on the residential
property (and incidental ingestion of residential soil) were estimated based on four
assumptions regarding dietary intake percentages of beef from cattle raised on their yards for
general public adults (Table 8-4).

Assuming children on a rural residential property consume 10% of their milk and beef from
cows raised on their land, a range of soil PRGs (31 to 350 mg/kg) was evaluated in terms of
the associated lead concentrations in milk and beef calculated using the biotranser factors
presented in EPA's Combustion Guidance (EPA, 2005a). The IEUBK model results indicate
that a soil PRG of approximately 300 mg/kg is protective of these additional dietary sources
(Table 8-5)

Table 8-4

Lead - Soil PRGs Based on General Public Adult Consumption of
Beef from Cattle Grazing on Rural Residential Property
Tar Creek OU4 Superfund Site

Soil PRG (mg/kg)

Beef Cone, (mg/kg)

% of Meat Eaten

455

0.13

10

448

0.12

25

436

0.12

50

414

0.11

100

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Table 8-5

Lead - Soil PRGs Based on General Public Child
Consumption of 10% of Beef and Milk from Cattle Grazing on
Rural Residential Property
Tar Creek OU4 Superfund Site

Soil. PRG
(mg/kg)

Grazing
Plant
Cone,
(mg/kg)

Beef

Cone.(mg/kg)

Milk

Cone.(mg/kg)

%of

Population
with a BLL
above 10
1-ig/dL

31

1.4

0.0083

0.0077

0.026

50

2.3

0.013

0.012

0.055

100

4.5

0.027

0.025

0.26

150

6.8

0.040

0.037

0.78

200

9

0.054

0.050

1.8

250

11

0.067

0.062

3.3

300

13

0.081

0.075

5.4

350

16

0.094

0.087

8.0

(Note: 5% is the target % of the population with a BLL above 10 pg/dL.)

8.2.2 Native American Rural Residential Land Use

Unacceptable concentrations of COPCs were not identified in soil or groundwater at the two
current rural residential properties on BIA land. However, if additional BIA land is used for
rural residential purposes in the future, soil concentrations on some properties could pose
unacceptable risks.

For the general public, the lead soil PRG of 500 mg/kg is based on protection of children
and/or the fetus of adult pregnant women using default assumptions for incidental ingestion
of soil. Native American residents may have higher exposures based on higher intake
estimates for ingestion of soil as well as additional exposure pathways.

Assuming modification of the soil ingestion rates only with no additional sources of COPCs:

•	The most sensitive receptor of soil ingestion for cadmium and zinc is a child. If the soil
ingestion rates were assumed to increase from 200 to 400 mg/day (a highly conservative
soil ingestion rate from Harper, et al.), the soil PRGs would be 38 mg/kg and

11,250 mg/kg for cadmium and zinc, respectively.

•	For lead, if the average soil ingestion rate (100 mg/day) in the IEUBK Model is
hypothetically changed for Native American children to 400 mg/day (i.e., 4 times higher),
the PRG for a child would decrease to approximately 102 mg/kg. It should be noted that
the ingestion rates embedded in the IEUBK model are not supposed to be changed.

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The ALM is not intended for residential use. However, using a soil ingestion rate of 400
mg/day results in an estimated PRG of 110 mg/kg. The ALM is based on protection of the
fetus of a pregnant woman, and it is likely overly conservative to estimate this soil intake for
365 days per year at this higher level. The ALM recommends a soil ingestion rate of 50
mg/day, with 100 mg/day considered a reasonable upper-bound intake for an adult in an
industrial scenario. Using 100 mg/day, a PRG of 441 mg/kg is estimated (assuming a
homogeneous population of receptors with this type of exposure).

The impact of additional dietary intakes on the estimating additional PRGs for rural
residential soil is complex. Similar to the general public, the PRGs protective for ingestion of
soil and homegrown produce were estimated based on four assumptions regarding dietary
intake percentages of homegrown produce (i.e., 10, 25, 50, and 100%) using the biotransfer
factors presented in EPA's Combustion Guidance (EPA, 2005a) and are presented in Tables
8-6 through 8-8. It is important to note that the default biotransfer factors in the EPA
Combustion Guidance appear to overestimate plant concentrations (especially homegrown
vegetables) by several orders of magnitude based on the soil/plant correlation observed
during sampling at OU-2.

Table 8-6

Cadmium - Soil PRGs Based on Tribal Adult Consumption of

Homegrown Produce

Tar Creek OU4 Superfund Site

Soil PRG (mg/kg)

Plant Cone, (mg/kg)

% of Plant Eaten

7.84

0.980

10

3.22

0.403

25

1.63

0.203

50

0.817

0.102

100

Table 8-7

Zinc - Soil PRGs Based on Tribal Adult Consumption of Homegrown
Produce

Tar Creek OU4 Superfund Site

Soil PRG (mg/kg)

Plant Cone, (mg/kg)

% of Plant Eaten

2960

290

10

1230

120

25

621

60.8

50

312

30.6

100

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Table 8-8

Lead - Soil PRGs Based on Tribal Adult Consumption of Homegrown
Produce

Tar Creek OU4 Superfund Site

Soil PRG (mg/kg)

Plant Cone, (mg/kg)

% of Plant Eaten

33

0.45

10

16

0.22

25

9

0.12

50

5

0.062

100

Additionally, the PRGs protective for ingestion of beef from cattle grazing on the rural
residential property (and incidental ingestion of residential soil) were estimated based on four
assumptions regarding dietary intake percentages of beef from cattle raised on their yards for
Native American adults (Table 8-9). If beef grazing on the rural residential property are
consumed, it is estimated that the PRG for an adult consuming 400 mg soil/day is decreased
to 107 mg/kg. This is based on a daily intake of approximately 0.4 lbs of beef, with 25
percent from the property. For the assumption of soil ingestion at 100 mg/day, the PRG of
441 mg/day would be reduced to 395 mg/kg for the same assumptions for beef ingestion.

Table 8-9

Lead - Soil PRGs Based on Tribal Adult Consumption of Beef from Cattle
Grazing on Rural Residential Property
Tar Creek OU4 Superfund Site

Soil PRG (mg/kg)

Beef Cone, (mg/kg)

% of Meat Eaten

109

0.030

10

107

0.030

25

104

0.029

50

99

0.027

100

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Table 8-10

Lead - Soil PRGs Based on Tribal Child Consumption of 50% of Beef
and Milk from Cattle Grazing on Rural Residential Property
Tar Creek OU4 Superfund Site

Soil
PRG

(mg/kg)

Grazing
Plant
Cone,
(mg/kg)

Beef Cone,
(mg/kg)

Milk

Cone.

(mg/kg)

% of Population
with a BLL
above 10 j^ig/dL

31

1.395

0.0083

0.0077

0.078

50

2.25

0.0134

0.0124

0.237

100

4.5

0.02688

0.02485

1.686

150

6.75

0.0403

0.0373

5.269

200

9

0.05376

0.0497

10.958

250

11.25

0.0672

0.0621

18.09

300

13.5

0.0806

0.0746

25.878

350

15.75

0.094

0.0869

33.714

(Note: 5% is the target % of the population with a BLL above 10 pg/dL.)

Assuming children on a rural residential property consume 50% of their milk and beef from
cows raised on their land, a range of soil PRGs (31 to 350 mg/kg) was evaluated in terms of
the associated lead concentrations in milk and beef calculated using the biotranser factors
presented in EPA's Combustion Guidance (EPA, 2005a). The IEUBK model results indicate
that a soil PRG of approximately 150 mg/kg is protective of these additional dietary sources
(Table 8-10)

Additional considerations of dietary intake of edible plants grown regionally are presented in
Section 8.4.2,

8.3 Rural Non-Residential Soil/Source Material

8.3.1 Recreational Use

Outside of the rural residential properties, the public may be exposed to COPCs in source
areas during recreational activities such as driving all-terrain vehicles (ATVs) on chat piles
and millponds. Unacceptable BLLs were identified for this scenario in the HHRA.

To estimate the PRG protective for an adolescent recreator, the ALM was adopted as
recommended by the Technical Review Workgroup for metals and asbestos (TRW) in their
Frequently Asked Questions document (EPA, 2005f). The target receptor for this PRG is an
adolescent; however, the ALM is targeted for protection of the most sensitive receptor (a
fetus). Therefore, use of the ALM assumes that the receptor is a pregnant woman. In
addition, the assumption that the receptor plays in the source areas each day that weather

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permits is highly unrealistic. Therefore, the PRGs for lead in rural non-residential soils or
source materials were also calculated assuming an exposure frequency of three days per
week for 26 weeks. The PRGs were evaluated based on various possible exposure
assumptions (model parameters) presented below. The estimated PRGs range from 350 to
1,047 mg/kg.

Table 8-11

Lead - Source Material PRGs Based on Recreational Adolescent Scenario
Tar Creek OU4 Superfund Site

GSD

Baseline PbB ((ig/dL)

Ingestion
Rate

(mg/day)

Absorption
fraction

Exposure
frequency
(days/yr)

PRG

(mg/kg)

2.3 (default)

1.7 (default)

200

0.12
(default)

78c

547

2.3 (default)

1.7 (default)

100

0.12
(default)

78

1,095

2.1 (NHANES
HI)

1.16 (NHANES III)

100

0.30a

184b

350

2.1 (NHANES
HI)

1.16 (NHANES III)

100

0.30

78

826

2.1 (NHANES
HI)

1.16 (NHANES III)

200

0.30

78

413

2.1 (NHANES
III)

1.16 (NHANES III)

200

0.20

78

620

a High-end absorption value.

b 184 sunny days above freezing temperature based on a yearly average of weather
meteorological monitoring data collected between 1999 and 2004.

c 78 days (3 days per week for 26 weeks) or approximately 2.6 summer months.

GSD = Geometric standard deviation of baseline blood lead level.

Some chat piles are close to rural residential areas and there is a potential for younger
children to desire to play on them. In addition, adolescents playing on the chat will likely
come in contact with unvegetated fine source materials at a higher rate than on sodded soil
materials and are therefore expected to have a higher-end ingestion rate. The proposed lead
PRG of 500 mg/kg is between two PRGs (413 and 547 mg/kg) based on the high-end
ingestion rate (200 mg/kg), realistic exposure frequency (78 days/yr), and two different
absorption factions (the upper and lower estimates).

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8.3.2 Pastureland

If beef or game that graze on rural non-residential property (pastureland) are consumed, a
soil PRG may be estimated based on models that correlate soil concentration with
concentrations in beef. The correlations used to develop PRGs are based on the values
presented in the EPA Combustion Guidance (EPA, 2005a) and are assumed to be the same
for beef and game.

Assuming approximately 50 percent of a person's dietary intake of meat (170 g/day or
approximately 0.4 lbs/day) is from animals grazing on pastureland, an average soil
concentration in the pastureland of approximately 1,600 mg/kg is estimated that would be
protective for an adult using reasonably conservative intake estimates.

The PRGs for lead in pastureland soil combined with PRGs for rural residential soil were
developed. Identifying a PRG for one soil area (e.g., rural residential soil) allows calculation
of the PRG for pastureland soil. For example, if a PRG of 335 mg/kg lead is used for rural
residential soils, then the PRG for pastureland soil is 31 mg/kg (background concentration).
Because of this relationship between the rural residential yard soils and the pastureland soils,
the PRG is presented as a paired set of PRGs for a variety of lead concentrations.

Beef and milk samples were collected for the Jasper Superfund Site in Missouri, a site with
mining wastes similar to Tar Creek. These data were reviewed for their usefulness in
developing PRGs for Tar Creek OU4. Based on the available information, the following
issues were identified:

•	The concentration ranges in the grazing areas (pastureland) for the cattle were
not provided.

•	The sample size was very small (only two individual samples for beef, liver, and
milk were collected, one from each of two grazing areas).

•	Appropriate QA/QC documentation was lacking (local residents collected the
beef, liver, and milk samples, stored the food products in their freezer, and then
provided the samples to a third party for submittal to the laboratory; it appeared
that chain-of-custody backup was lacking.)

Therefore, the data were not concluded to be useful for developing soil PRGs for pastureland
at Tar Creek OU4.

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Table 8-12

Lead - Soil PRGs Based on General Public Child Consumption of Milk from Cattle

Grazing on Pastureland

Tar Creek OU4 Superfund Site

Rural Residential
Yard PRG
(mg/kg)

Pastureland
PRG

(mg/kg)

Grazing
Plant Cone,
(mg/kg)

Milk

Cone.

(mg/kg)

% of Milk
Consumed

50

3430

154

0.78

10

325

741

33.3

0.17

10

50

1360

61.2

0.312

25

325

297

13.4

0.068

25

Table 8-13

Lead - Soil PRGs Based on General Public Child Consumption of Beef from Cattle

Grazing on Pastureland

Tar Creek OU4 Superfund Site

Rural Residential
Yard PRG
(mg/kg)

Pastureland
PRG

(mg/kg)

Grazing
Plant Cone,
(mg/kg)

Beef

Cone.

(mg/kg)

% of Meat
Eaten

50

6910

311

1.9

10

300

836

37.6

0.23

10

50

2730

123

0.75

25

300

363

13.5

0.10

25

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Table 8-14

Lead - Soil PRGs Based on General Public Child Consumption of 10% of Beef and Milk
from Cattle Grazing on Pastureland
Tar Creek OU4 Superfund Site

Rural

Residential
Yard PRG
mg/kg)

Pasture-land
PRG

(mg/kg)

Grazing
Plant
Cone,
(mg/kg)

Beef

Cone.

(mg/kg)

Milk

Cone.

(mg/kg)

%of

Population
with a BLL
above 10
1-ig/dL

31

2000

90

0.5376

0.497

5.047

335

31

1.395

0.0083

0.0077

5.111

200

900

40.5

0.2419

0.2236

5.055

(Note: 5% is the target % of the population with a BLL above 10 pg/dL.)

8.4 Food Items

Remedial actions are focused on abiotic media (e.g., soil or groundwater) that may protect
public health based on direct ingestion/contact or secondary exposures based on transfer of
COPCs from soil to food. The above discussions considered the relationship between soil and
beef, milk, and homegrown produce. This section considers other dietary intakes.

8.4.1	Fish

Previous studies have indicated elevated risk levels associated with fish and aquatic biota
ingestion exposures by residents in the Tar Creek area. However, ecological PRGs for
protection of fish populations will generally be more conservative for these COPCs. The
ODEQ has identified safe consumption levels for fish from rivers and ponds in the Tar Creek
Area (ODEQ, 2003) PRGs for surface water and sediment are not evaluated as part of OU4.

8.4.2	Plants

Native American diet may include a variety of plants (e.g., asparagus, cattail, willow) that
grow in the region. Some of these plants, like cattails, have higher uptake of metals than
many other plants. The baseline HHRA assumed that any of these individual plant types
might be a substantial portion of the entire diet. However, it should be noted that most of the
plants that were collected were growing in source material areas, not growing within typical
soils of the Tar Creek area.

A soil PRG that would reduce plant tissue concentrations to levels where these may be the
primary diet for adults were not estimated. In part, this is because a simple correlation
between plants and soils was not identified (see Section 8.4.3), Even concentrations near
background suggested that plant intake might be unacceptable if these plants constitute the
entire diet, which is not a realistic assumption.

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Root concentrations were much higher than aboveground plant concentrations by a factor of
nearly 4 for cadmium and nearly 70 for lead. Based on the open literature (e.g., Hansel,
2001; Newville, 2004), many of the metals in roots of plants like cattails may be highest on
the outer surface, such that peeling these roots would significantly reduce intake of metals
like lead.

However, in general, consumption of roots should be restricted, particularly if these are eaten
without removing the outer surface.

8.4.3 Evaluation of Correlation Between Edible Plants and Soil

During preparation of the HHRA, an evaluation of the correlation between the sampled
edible plants and their associated root soil was performed. Plant concentrations were
obtained from 19 samples from each of three plant types (asparagus, cattail, and willow). For
each plant type, both root and aboveground tissue were submitted for analysis in both washed
and unwashed states. It should be noted that the "washed" state was not washed clean, but
was lightly rinsed with deionized water in the field. These samples were analyzed for
cadmium, lead, and zinc. A discrete sample (rather than composite) was obtained from soil
in contact with each root sample. An evaluation was performed to determine an appropriate
set of paired plant-soil data to develop an equation predicting soil concentrations from plant
concentrations.

For each COPC, there were 12 different scenarios (3 plant types, unwashed and washed,
roots, and aboveground tissue) for evaluating the correlation between plant and soil
concentrations. This evaluation included calculations of the Pearson correlation coefficient
(the most widely used measure of paired correlation) and a nonparametric version (based on
ranks), the Spearman correlation coefficient. Both of these values range from -1 to 1 where 1
represents perfect correlation, -1 represents perfect inverse correlation, and 0 represents no
correlation. Another well-known measure of correlation, R2, was also calculated. This value
is merely the square of the Pearson correlation coefficient and thus ranges from 0 to 1 where
increasing correlation or inverse correlation is indicated by higher R2 values.

Thus, concentration data from unwashed plants (aboveground), unwashed roots, washed
plants (aboveground), and washed roots were evaluated with regard to correlation with the
corresponding root soil concentration data. This evaluation was performed for each of the
three plant types (asparagus, cattail, and willow).

Review of all cases (and some additional scenarios including combined plant types, etc.)
revealed that the data sets for cattail roots offered the most promising correlation between
plant and soil concentrations. The chosen plant type for cadmium and zinc was washed
roots, while the chosen plant type for lead was unwashed roots. The calculated measures of
correlation are presented in Table 8-15 with the estimates for the regression coefficient and
intercept; plots are presented in Appendix N, Figures 1-6. If the correlation is deemed to be
adequately strong, the soil concentration is calculated using the following equation:

Soil Concentration = (Plant Concentration * Regression Coefficient) + Intercept

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Table 8-15

Cattail and Root Soil Correlation - Regression and Correlation Statistics for Predictive Equations
Tar Creek OU4 Superfund Site

Plant
Type

Plant
Media

COPC

Regression
Coefficient

Intercept

Pearson
Correlation
Coefficient

Spearman
Correlation
Coefficient

R2

Cattail

Washed
Root

Cadmium

4.031

19.42

0.651

0.547

0.424

Cattail

Unwashed
Root

Lead

3.836

190.9

0.836

0.576

0.698

Cattail

Washed
Root

Zinc

8.19

3070

0.710

0.493

0.504

One issue in calculating measures of correlation is that some individual data pairs (plant-soil
concentration pairs) might be highly influential on the calculated correlation (although the
nonparametric Spearman correlation coefficient is more robust toward influence by
individual data pairs). Indeed, the cases presented in Table 8-15 were first evaluated for such
influential pairs, some of which were excluded prior to calculating these regression and
correlation statistics.

In data plots, such influential pairs can be visually identified, but it is also prudent to perform
a mathematical test to ensure that this identification is consistent for all scenarios. The
mathematical parameter termed "Cook's distance" was calculated for each scenario (Draper,
1998) A large value for Cook's distance indicates that the estimates of a regression equation
will change substantially if the data pair is removed.

For each case in Table 8-15, the chosen data for calculating the regression equation involved
the exclusion of two data pairs. The excluded data are presented in Table 8-16. The exact
Cook's distance required for data exclusion is not a firm value, although some practitioners
suggest an F distribution value for probability of 0.50 (Graybill and Iyer, 1994). With the
19 sample pairs initially available, this value is 0.47. As seen in Table 8-16, the Cook's
distance for each of these values exceeds 0.47.

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Table 8-16

Cattail and Root Soil Correlation - Excluded Plant-Soil Data Pairs
Tar Creek OU4 Superfund Site

Station ID

COPC

Plant
Type

Plant Media

Plant
Concentration,
mg/kg

Soil
Concentration,
mg/kg

Cook's
distance

TC4-BIO-
21D

Cadmium

Cattail

Washed Root

32.27

1520

0.76

TC4-BIO-

44D

Cadmium

Cattail

Washed Root

110.22

764

17

TC4-BIO-

09C

Lead

Cattail

Unwashed
Root

2759.77

3980

0.86

TC4-BIO-

54C

Lead

Cattail

Unwashed
Root

1.95

8680

0.52

TC4-BIO-
21D

Zinc

Cattail

Washed Root

1514.27

117000

0.58

TC4-BIO-

34D

Zinc

Cattail

Washed Root

3604.6

5410

0.89

More important than an exact threshold, the calculation of Cook's distances allows a
consistent measure of the influence of any given data pair on the regression equation. The
excluded pairs can be visualized in Appendix N, Figures 1, 3, and 5 for cadmium, lead, and
zinc, respectively. In these figures, the excluded data pairs are marked with an X symbol.
The remaining data are better viewed in Appendix N, Figures 2, 4, and 6 for cadmium, lead,
and zinc, respectively. These figures also provide a visual presentation of the regression line
drawn as a best fit through the data (the same regression line described by the regression
coefficients and intercept in Table 8-15).

The cattail data was initially deemed promising due to superior correlations relative to the
other plant types. The higher soil concentrations associated with the cattail concentrations
reinforced this decision. In Table 8-17, the mean concentrations for each COPC and each
plant type is provided for 1) all soil data, 2) the soil data associated with unwashed roots after
data exclusions (based on the Cook's distance calculations), and 3) the soil data associated
with washed roots after data exclusions. These means show that cattail data are either
associated with the highest typical soil concentration or, at least, a soil concentration almost
as high as the other plant types (e.g., cadmium concentration associated with roots). Use of
these higher soil concentrations associated with cattail are expected to bring an increased
level of conservatism since they lead to higher soil concentrations being predicted by the
regression equations. However, the correlations are not adequately strong for use in
predicting plant concentrations and therefore were not used in PRG calculations.

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Table 8-17

Mean Root Soil Concentrations at Edible Plant Sampling Locations
Tar Creek OU4 Superfund Site



All Soil Data



Asparagus

Cattail

Willow

Cadmium

34

161

56

Lead

884

1550

1256

Zinc

5889

14748

8412

Soil Data Associated with
Unwashed Roots

After Data Exclusions

Cadmium

32

47

52

Lead

668

987

828

Zinc

5096

7565

7006

Soil Data Associated with Washed

Roots

After Data Exclusions

Cadmium

32

46

49

Lead

737

1154

828

Zinc

5366

9283

6973

8.5 Other Rural Areas

The soil samples collected from rural areas (i.e., not currently used for residential land use
and not in the vicinity of source materials) indicate low concentrations near background
levels. Therefore, PRGs do not need to be developed for the rural areas that comprise most
of the land in OU4.

For purposes of evaluation here, rural residential yard soil samples were combined with rural
area surface soil, transition zone soil, and background soil samples. Collectively, these soil
samples were considered to be representative of the lead contamination in rural surface soil
for Tar Creek OU4. These surface soils were sampled as part of the effort for characterizing
the OU4 site and for developing the HHRA for the site.

A one-way analysis of variance (ANOVA) was run on the soil lead data from four separate
areas (background, rural residential, rural, and transition zone) to determine if there was a
statistically significant difference between the soil data collected from the four areas. Due to
the large number of samples available, the results using untransformed data were used even
though the residuals from the ANOVA were found to be not normally distributed. This

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analysis showed that there was not a statistical significant difference between the soil data
collected from different areas except for the transition zone soil ( The F-ratio for this analysis
had p-value of 0.6266). Therefore, the surface soil data without the transition zone data were
combined in one group to represent the general rural soil and the transition zone soil data was
separated to represent surface soil in the areas adjacent to chat piles or chat bases. The
surface soil other than the transition zone soil data were found to range between 0.0125 and
1,160 mg/kg. The data were found to be not normally or lognormal distributed. The ProUCL
program was used to calculate the UCL95 on the arithmetic mean of the data. A Chebyshev
95% non-parametric UCL was calculated to be 141 mg/kg. This is a substantial reduction
over the UCL95 of 422 mg/kg prior to remediation of the home at the former smelter.

About 2.5 percent of the data (after remediation of the home at the former smelter) were
above 500 mg/kg lead. If these data points above 500 mg/kg were replaced with clean fill
containing 31 mg/kg lead (assuming areas above 500 mg/kg lead were excavated and
replaced with clean fill), the UCL95 on the arithmetic mean for the surface soil would
decrease from 141 mg/kg to 101 mg/kg (about 3 times the background concentration of 31
mg/kg) and the average median value would be 35 mg/kg, which is very close to the average
background level of 31 mg/kg.

For transition zone soil, the soil lead data ranged between 16.9 and 4,450 mg/kg. The data
were found to be not normally or lognormally distributed. The Chebyshev 95% non-
parametric UCL was calculated to be 1,573 mg/kg using the ProUCL program. About 37
percent of the data were above 500 mg/kg. If we replace data points above 500 mg/kg lead
with clean fill containing 31 mg/kg lead, the UCL95 on the arithmetic mean for the data
decreases from 1,573 mg/kg to 123 mg/kg. However, recall that the percentage of soil
samples above 500 mg/kg in our dataset was high, about 37 percent.

These evaluations indicate that if the current sampling locations above 500 mg/kg lead are
remediated and replaced with soil at background concentrations of lead, the average lead
concentration in the Tar Creek area will be near background concentrations.

8.6 Uncertainties in PRGs

There are various uncertainties in the derivation of the PRGs. By presenting a range of
PRGs, some of those uncertainties are mitigated. The soil, beef, milk, and vegetable
ingestion rates vary by person. Additionally, the amount of food eaten from an impacted
area varies by person. Further, the chemical concentration in the food item will vary based
on the type of food item, the source of the food item, the part of the food item eaten (e.g.,
above-ground or below-ground portion of the plant, body part of the animal) and the food
preparation method. In addition, it was assumed that the chemical uptakes into beef, milk,
and vegetables were adequately represented by the biotransfer factors presented in EPA's
Combustion Guidance. Additionally, in most cases, upperbound estimates of ingestion rates
(e.g., 95th percentile values) were used to calculate PRGs.

It is important to note that the default biotransfer factors in the EPA Combustion Guidance
that were used to calculate PRGs appear to overestimate plant concentrations (especially
homegrown vegetables) by several orders of magnitude based on the soil/plant correlation
observed during sampling at OU-2.

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8.7 Conclusions

PRGs were identified for rural residential and recreational scenarios. The lowest PRGs were
identified for soil used for growing vegetables. The PRGs are provided for EPA Risk
Managers for their use in selecting the final remedial goals for the site.

Based on results of the HHRA, the most significant risks are associated with ingestion of
edible plants in the Tar Creek area. If locally-grown edible plants are a significant portion of
a person's diet, unacceptable risks may result. Therefore, it is recommended that edible plant
intakes be limited.

The locations with elevated cadmium and zinc concentrations occur at areas where elevated
lead concentrations are also present. Therefore, remediating specific locations for lead will
also address the areas where cadmium and zinc risks are unacceptable.

The elevated risk levels calculated for OU4 are driven by exposure to the source materials
(i.e., chat piles, chat bases, tailings ponds, and smelter area) and the transition zones around
the piles/bases. Most of the lead concentrations on rural land in OU4 (represented by the
rural area samples collected in December 2005) are at concentrations near background.
Therefore, if source areas are remediated to PRGs, the area-wide residual risks in the OU4
area are expected to be at acceptable levels.

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9.0 Conclusions and Recommendations

An HHRA was conducted for OU4 of the Tar Creek Superfund Site. The site is
approximately 40 square miles in size and is an area of former mining activities, with waste
materials (chat piles, chat bases, tailings ponds) present on approximately 10% of the land
within the 40 square mile area. Residences are present throughout this area, on both public
land and land owned by the BIA. On BIA land, 10 Native American tribes are represented,
and it is reasonable to assume that Native Americans are enjoying cultural practices
currently, and will in the future in at least some of these areas. Soil samples collected from
non-residential rural areas indicate concentrations near background levels.

It is assumed that in the future, the waste materials will remain in the Tar Creek area and
residential use will continue on both private and Indian lands. Based on the AOC, the COPCs
at the site are cadmium, lead, and zinc; analytical data for additional metals supports the
selection of these three COPCs as those of primary concern at the site from mining activities.
Two sets of residential receptors were evaluated: general public and Native American
(representing the tribal way of life). Both adult and child receptors were evaluated within
these scenarios. Additionally, a recreator scenario was evaluated for adolescents who may
play on chat piles and tailings ponds when the weather permits.

It is assumed that a general public resident would be exposed to surface soil, ground water,
and ambient air using exposure assumptions considered conservative for a typical residential
setting (e.g., exposures at 350 days/year for 30 years). For the Native American resident,
exposures to surface soil, ground water, ambient air, milk, beef, fish, aquatic food, small
game, asparagus, willow, and cattail were quantified using conservative exposure
assumptions presented in the Spokane Tribe Study (Harper et al., 2002), with much higher
intakes than those for the general public. In addition, food ingestion rates presented in the
EPA Exposure Factors Handbook (EPA, 1997) for Native Americans were used for
comparison. Sieved (250 |im) soil samples collected from a depth of 0-1 inch were used to
evaluate exposures to residential yard soil. It was assumed that an adolescent recreator may
contact surface materials (0-6 inches) on chat piles and tailings ponds during outdoor
activities.

Previous studies have indicated that while areas of the shallow aquifer have been impacted,
the deeper aquifer has not. Of the 14 shallow, private wells that were identified in the study
area, 13 were sampled during the RI. Maximum detected concentrations of lead were only
slightly higher than the EPA Action Level for drinking water (28 |ig/L versus 15 |ig/L) in
two wells located near each other on the eastern portion of OU4. Cadmium and lead were
detected above background in these wells, suggesting potential mining-related impacts.
Exposures to ground water were quantified in the HHRA by both general public and Native
American residents. The HHRA does not address future uses of impacted shallow ground
water at locations other than those sampled as part of OU4, and restrictions on potable use of
shallow ground water may be warranted in other locations.

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There is the potential for future concentrations in the wells to increase. If concentrations
remain low, no additional risks will be identified. However, because lead concentrations are
currently above the MCL at two wells, the cause of the elevated levels and the need for an
alternative water supply should be evaluated.

The following estimated risks were identified, as summarized in Tables 5-1 through 5-3:

•	Current Child Resident (General Public) - maximum HI of 1; six homes with lead
concentrations above 500 mg/kg; potential BLL exceeding 10 |ig/dl for children at
four homes; 2.98 percent of the "neighborhood" with a BLL exceeding 10 |ig/dl; lead
was identified as the only COC for this receptor. Based on the updated soil dataset,
risks remained the same for cadmium and zinc; five homes had lead concentrations
above 500 mg/kg; less than 5 percent of the "neighborhood" had a BLL exceeding 10
|ig/dl; lead remained as the COC for this receptor.

•	Current Adult Resident (General Public) - maximum HI of 0.2; potential BLL
exceeding 10 |ig/dl at two homes; lead was identified as the only COC for this
receptor. Based on the updated soil dataset, risks remained the same for cadmium and
zinc; potential BLLs exceeded 10 |ig/dl at one home; lead remained as the COC for
this receptor.

•	Current Child Resident (Native American) - maximum HI of 0.3; neither of two
homes with lead concentrations above 500 mg/kg; potential BLL exceeding 10 |ig/dl
for neither home; lead was identified as the only COC for this receptor. Based on the
updated soil dataset, risks remained the same for cadmium and zinc, and lead risks
were lower.

•	Current Adult Resident (Native American, High-Fish and High-Beef Diets) - ELCR
of 2xl0"7, maximum His of 700 and 600 (for high-fish diet and high-beef diet,
respectively); 100 percent of the population with a BLL exceeding 10 |ig/dl;
cadmium and zinc exceeded HI of 1 due to the asparagus, willow, and cattail
ingestion pathways. Cadmium exceeded an individual HI of 1 from the aquatic food
ingestion and fish ingestion pathways. Lead, cadmium, and zinc were identified as
COCs for this receptor. Based on the updated soil dataset, ELCR of 2xl0"7, maximum
His of 600 for both high-fish diet and high-beef diet; 100 percent of the population
with a BLL exceeding 10 |ig/dl; cadmium and zinc exceeded HI of 1 due to the
asparagus, willow, and cattail ingestion pathways. Cadmium exceeded an individual
HI of 1 from the aquatic food ingestion and fish ingestion pathways. Lead, cadmium,
and zinc remained as COCs for this receptor.

•	Current Adult Resident (More Typical Native American) - estimated risks are lower
for a Native American resident with more typical Native American exposures than
those estimated using the Spokane Tribe exposure factors; however, estimated risks
still exceed acceptable levels, driven by the edible plant exposures. Based on the
updated soil dataset, the original risk estimates were unchanged.

•	Current/Future Recreator - maximum HI of 0.1; 22.3 percent of the population with a
BLL exceeding 10 |ig/dl; lead was identified as the only COC for this receptor.

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•	Future Child Resident (General Public and Native American) - maximum HI is 0.08;
maximum and mean modeled future soil concentrations exceed acceptable BLLs,
although 75th percentile soil concentrations yield acceptable BLLs. Maximum
modeled air concentrations are below NAAQS. Lead was identified as the only COC
for these receptors. Based on the updated future soil dataset, maximum HI is 0.1;
maximum modeled future soil concentration exceeds acceptable BLLs, although
mean and 75th percentile soil concentrations yield acceptable BLLs. Maximum
modeled air concentrations are below NAAQS. Lead remained as the only COC for
these receptors.

•	Future Adult Resident (General Public) - maximum ELCR is 4xl0"6 and maximum HI
is 0.02; maximum modeled future soil concentration exceeds the target, although the
mean soil concentrations yield acceptable BLLs. Maximum modeled air
concentrations are below NAAQS. Lead and cadmium were identified as COCs for
this receptor. Based on the updated future soil dataset, maximum ELCR is 4xl0"6 and
maximum HI is 0.03; maximum modeled future soil concentration exceeds the target,
although the mean and 75th percentile soil concentrations yield acceptable BLLs.
Maximum modeled air concentrations are below NAAQS. Lead and cadmium
remained as COCs for this receptor.

•	Future Adult Resident (Native American) - maximum ELCR is lxlO"5 and maximum
HI is 0.04. Maximum, mean, and median modeled future soil lead concentrations
exceed the target population with a BLL above 10 |ig/dL. Lead and cadmium were
identified as COCs for this receptor. Based on the updated future soil dataset,
maximum ELCR is lxlO"5 and maximum HI is 0.02; maximum, mean and 75th
percentile modeled future soil concentrations exceed acceptable BLLs, although
median soil concentration yields acceptable BLLs. Lead and cadmium were
identified as COCs for this receptor.

Historically, BLL measurements have been collected for children living in the Tar Creek
area. BLLs have been decreasing since 1996, and are now within the target level on a
neighborhood-scale. However, individual children and locations remain at concentrations of
concern. Exposures should be limited in areas with elevated lead concentrations.
Additionally, remaining sources in the Tar Creek area should be considered during future
remedial activities in Tar Creek.

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10.0 References

AATA International, Inc. (AATA), 2004. Final Data Gap Analysis Report, Tar Creek OU4
RI/FSProgram. September 2004.

AATA International, Inc. (AATA), 2005. Draft Preliminary Site Characterization Summary,
Tar Creek OU4 RI/FS Program. September 2005.

Agency for Toxic Substances and Disease Registry (ATSDR), 2004. Report to Congress.
Tar Creek Superfund Site, Ottawa County, Oklahoma. October 2004.

Casteel, Stan W., Weis, Christopher, Brattin, William, and Hammon, Tracy. Bioavailability
of lead in Soil Samples From the Jasper County, Missouri Superfund Site. May.

CH2M HILL, 2004. Work Plan, Tar Creek Superfund Site OUNo. 4, Ottawa County,
Oklahoma. July 2004.

CH2M HILL, 2005a. Work Plan Revision Request 01, Tar Creek Superfund Site OU No. 4,
Ottawa County, Oklahoma. February 2005.

CH2M HILL, 2005b. Work Plan Revision Request 02, Tar Creek Superfund Site OU No. 4,
Ottawa County, Oklahoma. August 2005.

Draper, N.R. and H. Smith.. Applied Regression Analysis. John Wiley & Sons, New York,
1998.

Duggan, et al., 1985. lead in playground dust and on the hands of schoolchildren. Sci. Total
Environ. 44(l):65-79.

Duggan, M.J., and M.J. Inskip, 1985. Childhood exposure to lead in surface dust and soil: A
community health problem. Public Health Rev. 13(1-2): 1-54.

Graybill, F.A. and H.K. Iyer, Regression Analysis: Concepts and Applications, Duxbury
Press, 1994.

Hansel, C.M., Fendorf, S., Sutton, S., Newville, M. 2001. Characterization of Fe plaque and

associated metals on the roots of mine-waste impacted aquatic plants. Department of
Geological and Environmental Sciences, Stanford University, California 94305, USA.
October 2001.

Harper, Barbara L., Brian Flett, Stuart Harris, Corn Abeyta, and Fred Kirschner, 2002. The
Spokane Tribe's Multipathw ay Subsistence Exposure Scenario and Screening level
RME. Risk Analysis, Vol. 22, No. 3.

Holden, H, 1980. Farther mortality studies on workers exposed to cadmium fumes. Presented
at Seminar on Occupational Exposure to Cadmium. March 20, 1980, London,
England.

Kipling, M.D. and J.A.H. Waterhouse. 1967. Cadmium and prostatic carcinoma. Lancet. 1:
730.

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Kissel, J.C., K.Y. Richter, and R.A. Fenske, 1996. Factors affecting soil adherence to skin in
hand-press trials. Bull. Environ. Contam. Toxicol. 56(5):722-728.

Lemen, R. A., J.S. Lee, J.K. Wagoner and H.P. Blejer, 1976. Cancer mortality among cadmium
production workers. Ann. N.Y. Acad. Sci. 271: 273.

Nagy, 2001. Food requirements of wild animals: Predictive equations for free living-

mammals, reptiles, and birds. Nutrition Abstracts and Reviews, Series B 71: 21R-
32R.

Newville, Matthew, Peter Eng, Steve Sutton, Mark Rivers. 2004. GSECARS X-ray

Microprobe for Earth and Environmental Science. Presentation to the Consortium for
Advanced Radiation Sources (CARS). University of Chicago, Chicago, IL January
2004.

Oklahoma Department of Environmental Quality (ODEQ), 2003. Fish Tissue Metals

Analysis in the Tri-State Mining Area. FY03 Section 106 Water Quality Management
Program, 1-006400-01. July 2003.

Oklahoma Mesonet. www.mesonet.org.

Parker, G.H. and J. Hamr, 2001. Metal Levels in body tissues, forage and fecal pellets of elk
(Cervus elaphus) living near the ore smelters at Sudbury, Ontario. Environmental
Pollution. 113:347-355.

Sheppard, S.C., and W.G. Evenden, 1994. Contaminant enrichment and properties of soil
adhering to skin. J. Environ. Qual. 23(3):604-613.

Sorahan, T. and J.A.H. Waterhouse, 1983. Mortality study of nickel-cadmium battery

workers by the method of regression models in life tables. Br. J. Ind. Med. 40: 293-
300.

U.S. Census Bureau, 2004. http://factfinder.census.gov. 2004.

U.S. Centers for Disease Control and Prevention (CDC), 1991.

U.S. Environmental Protection Agency (EPA), 1989. Risk Assessment Guidance for

Superfund (RAGS): Volume I - Human Health Evaluation Manual (HHEM) (Part A,
Baseline Risk Assessment). EPA540-189-002.

U.S. Environmental Protection Agency (EPA), 1991a. Risk Assessment Guidance for

Superfund (RAGS): Volume I - Human Health Evaluation Manual (HHEM) (PartB,
Development of Risk-Based Preliminary Remediation Goals). EPA540-R92-003.
OSWER Directive 9285.7-01B.

U.S. Environmental Protection Agency (EPA), 1992a. Data Quality Objectives Process for
Superfund, Interim Final Guidance. Office of Solid Waste and Emergency Response,
Washington, DC. EPA540-R93-071. OSWER Directive 9355.9-01.

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U.S. Environmental Protection Agency (EPA), 1992b. Supplemental Guidance to RAGS:
Calculating the Concentration Term. Publication. No. 9285.7-081. PB92-963373.

U.S. Environmental Protection Agency (EPA), 1993a. Preliminary review draft: Superfund's
Standard Default Exposure Factors for the Central Tendency and Reasonable
Maximum Exposure. 1993.

U.S. Environmental Protection Agency (EPA), 1994. Revised Interim Soil Lead Guidance for
CERCLA Sites andRCRA Corrective Action Facilities. Memorandum: OSWER
Directive 9355.4-12. Office of Solid Waste and Emergency Response, U.S.
Environmental Protection Agency, Washington, DC [online]. Available:
http://www.epa.gov/superfund/programs/lead/products/oswerdir.pdf.

U.S. Environmental Protection Agency (EPA), 1995a. EPA Risk Characterization Program.
Memorandum from Administrator Carol Browner. Office of the Administrator,
Washington, DC. March 21, 1995.

U.S. Environmental Protection Agency, 1997. Exposure Factors Handbook Volume II.

Food Ingestion Factors. Office of Research and Development. EPA/600/P-95/002Fb.
August 1997.

U.S. Environmental Protection Agency (EPA), 2000. Short Sheet: TRW Recommendations
for Sampling and Analysis of Soil at Lead Sites. OSWER Directive 9285.7-38.
Prepared for EPA by Technical Review Workgroup for Lead. April 2000.

U.S. Environmental Protection Agency (EPA), 2003. Administrative Order on Consent for
RI/FSfor OU4. December 2003.

U.S. Environmental Protection Agency (EPA), 2005a. Human Health Risk Assessment
Protocol for Hazardous Waste Combustion Facilities. EPA530-R-05-006.

September 2005.

U.S. Environmental Protection Agency (EPA), 2005b. Draft Ecological Risk Assessment for
Tar Creek OU4, Ottawa County, Oklahoma.

U.S. Environmental Protection Agency (EPA), 2005c. Superfund and Mining Megasites,
Lessons Learnedfrom the Coeur d' Alene River Basin. July 2005.

U.S. Environmental Protection Agency (EPA), 2005d. Integrated Risk Information System
(IRIS). Available online.

U.S. Environmental Protection Agency (EPA), 2005e. Provisional Peer Reviewed Toxicity
Values. Available online.

U.S. Environmental Protection Agency (EPA), 2005f. Frequently Asked Questions From
Risk Assessors on the Adult Lead Methodology (ALM). Updated November 4.
Available online.

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Figures

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RS2417-30

RS2417-41

RS2417-31

RS2318-16

GW 2420-6(A,B)

RS2419-45 GW 2420-2(A,B)

\ "¦ —©
GW 2429-3(A.B)

GW 2417-5(A,B)

iRS2429-43
GW 2429-9(A.B)

RS2431-44

GW2429-8(A,B) I

RS2429-37
GW 2429-4(A,B)

GW 2431-12(A,B)

RS2431-22

RS2406-21

RS2301-19

RS23Q1-34

RS2301-33

RS2406-2Q

RS2301^7j

RS2406-38

RS2406-40

iPWRieA*;
RS2301-18

. "4,

GW2301-1 (A,B,D)  500 ppm Lead

O	Shallow Aquifer Well Samples

O	Shallow Aquifer Well Samples Exceeding MCLfor Lead (0.015 mg/L)

Site Boundary
Tribal Lands (2005)

N

A

I Miles

0.5

FIGURE 2

Tar Creek OU4
Rural Residential Sampling Summary

•AERIAL PHOTOGRAPHY PROVIDED BY:
A ATA INTERNATIONAL INC.

Fort Collins. Colorado. USA


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Appendix A

Split and Supplemental Sampling Summary

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CH2MHILL

Appendix A

Technical Memorandum
Split and Supplemental Sampling Summary
Tar Creek Superfund Site, Operable Unit No. 4
Ottawa County, Oklahoma

PREPARED FOR:
PREPARED BY:
PREPARED UNDER:

DATE:

DCN NUMBER::

Ursula Lennox/USEPA Region 6 RPM
CH2M HILL, Inc.

EPA Region 5 Response Action Contract No. 68-VV6-0025,
Work Assignment No. 233-RKED-06JW
October 21, 2005

05-8225

1.0 Background

This Technical Memorandum (TM) summarizes the sampling and analytical activities
completed by CH2M HILL. These activities were completed in support of U.S.
Environmental Protection Agency's (EPA's) efforts under Operable Unit 4 (OU4) at the
Tar Creek Superfund Site located in Ottawa County, Oklahoma. This work was
completed under Contract No. 68-W6-0025, and the approved project work plan (WP)
and subsequent work plan revisions under Work Assignment No. 233-RKED-06JW
(CH2M HILL 2004, 2005a, and 2005b)

The Respondents are responsible for completing a Remedial Investigation and Feasibility
Study (RI/FS) of OU4 under an Administrative Order on Consent (AOC) that was
executed on December 9, 2003 (EPA, 2003a). As part of this agreement, EPA is
responsible for completing the Human Health Risk Assessment (HHRA) and the
Ecological Risk Assessment (ERA).

Under this work assignment, CH2M HILL was directed by EPA to complete the HHRA
and perform the following activities associated with the RI/FS:

•	Perform limited oversight of the Respondents' sampling efforts.

•	Collect split samples of Respondents' samples.

•	Collect supplemental samples in support of the HHRA and to a limited extent, for
the Ecological Risk Assessment (ERA) being completed by EPA.

•	Collect plant samples that were requested by Quapaw Tribe.

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APPENDIX A: SPLIT AND SUPPLEMENTAL SAMPLING SUMMARY TM

Sampling activities were completed in accordance with the approved Field Sampling Plan
(FSP), the Quality Assurance Project Plan (QAPP), and the Health and Safety Plan (HSP)
(CH2M Mil l . 2005c, 2005d, and 2005e) Field oversight and split and supplemental
sampling activities were completed during the following timeframes:

•	May 16 to May 26, 2005: Collection of chat and chat base samples.

•	June 13 to June 30, 2005: Collection of tailings, transition zone soils, and plant
samples.

•	July 11 to July 22, 2005: Collection of smelter area samples and residential
samples.

2.0	Sampling Summary

2.1	Split Samples

In accordance with the project WP, FSP, and QAPP, split samples were collected from up
to 20-percent of the Respondents' RI samples for solid media and up to 10-percent of the
Respondents' RI samples for liquid media. All split samples were analyzed through
EPA's Contract Laboratory Program (CLP) or through EPA's Regional Laboratory in
Houston, Texas. At a minimum, all samples were analyzed for the three Contaminants of
Concern (COCs); cadmium, lead, and zinc. In most cases, the samples were analyzed for
the full Target Analyte List (TAL) of metals, including mercury. Split samples were
collected for all media that the Respondents collected and analyzed samples with the
exception of surface water and aquatic macrophyte vegetation.

2.2	Supplemental Samples

In accordance with the project WP, FSP, and QAPP, supplemental samples were
collected from site media to support the risk assessments. All samples were analyzed
through EPA's CLP or through EPA's Regional Laboratory in Houston, Texas. At a
minimum, all samples were analyzed for the three COCs; cadmium, lead, and zinc. In
most cases, the samples were analyzed for the full TAL of metals, including mercury.

Select samples of chat, chat base, and fine tailings were submitted for off-site
geotechnical testing and analysis. This included determination of particle size

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	APPENDIX A: SPLIT AND SUPPLEMENTAL SAMPLING SUMMARY TM

distribution by American Society of Testing and Materials (ASTM) Method D-422 and
analysis of material passing through select sieve sizes. Specifically, samples were sieved
and analyzed in the following fashion:

•	Passing #60/retained on the #140

•	Passing #140/retained on the #200

•	Passing #200/retained in the pan

These samples were analyzed for cadmium, lead, and zinc, with 10% of the samples
being analyzed for the TAL of metals, including mercury.

Tables A-l through A-8 present a summary of the Respondents' sampling efforts and
associated split and supplemental samples that were collected.

2.2.1 Plant Sampling

At the request of EPA and the Quapaw Tribe, plant samples were collected as part of the
supplemental sampling activities. Five samples were associated with each individual
plant that consisted of washed roots, unwashed roots, washed leaves, unwashed leaves,
and co-located soil samples. A total of 57 plants were sampled this way, for a total of
285 individual samples. The Quapaw Tribe assigned a representative to our sampling
team to determine which areas would be sampled, locate each individual plant sampling
location, and identify the plants in the field.

As directed by EPA, only three plant species were to be selected by the Quapaw Tribe for
sampling and analysis. The plants selected included willow, cattail, and asparagus. In
general, at each sampling area, the three plant species were usually found growing very
close together and were sampled as a group. Coordinates for each sampling location
were determined using Global Positioning System (GPS) equipment and were used to
plot the locations on Figure A-l. Each plant sampling location was photographed.
Additionally, a soil pH reading was taken from the soil growing around each plant's
roots. Sampling procedures and methodologies were completed in accordance with the
approved FSP and QAPP.

The plant samples were submitted to CLP for analysis of TAL metals, including mercury.

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	APPENDIX A: SPLIT AND SUPPLEMENTAL SAMPLING SUMMARY TM

3.0	Data Usability Evaluation

3.1	Data Validation

In accordance with the project WP and the QAPP, all analytical data obtained in support
of this project were validated according to EPA's National Functional Guidelines for
Inorganic Data Review (EPA 2004).

Analytical data provided by CLP laboratories were validated by the EPA Region 6
Environmental Services Assistance Team (ESAT). The CH2M HILL project chemist
then reviewed the findings of the ESAT validation. All non-CLP analytical data were
validated by the CH2M HILL project chemist.

Sample results were assigned data qualifiers in the validation process to express the
degree of usability based upon overall data quality. In cases where serious quality control
failures were encountered the data were rejected and were not used to support project
decisions.

3.2	Field Duplicate Analysis

In our evaluation with the CH2M HILL data, field duplicate sample results were
excluded, whereas the associated "normal" samples were retained for all analyses. Only
one sample from each duplicate pair can be included to ensure that the data set consists of
independent results. The duplicate result pairs are presented in Table A-9 to document
that this straightforward choice did not accidentally bias the data used in the HHRA.

The HHRA focuses on the average concentration, so it would take a consistent bias of
results to impart a significant bias on calculated values. By the nature of field duplicates,
which are treated as other samples by the analyzing laboratory, such a consistent bias
would seem very unlikely. Inspection of the paired values and the relative percent
difference (RPD) values in Table A-10 indicate that this data set, as expected, is not
biased by simple exclusion of the field duplicate member of the duplicate pairs. (An
RPD is a percentage of the actual difference between two values relative to the average of
the two values.)

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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT

	APPENDIX A: SPLIT AND SUPPLEMENTAL SAMPLING SUMMARY TM

The information from the field duplicate pairs was used, however, in the quality control
process. Concentrations associated with a precision (measured as the RPD) outside
stated criteria, were qualified as estimated.

3.3 Split Sample Analysis

A split sampling program was pursued between the Respondents and CH2M HILL data
sets. As discussed previously, the split samples from the Respondents and CH2M HILL
data sets are not pure splits since there were some intentional differences in the sample
make-up, primarily due to different sieving protocol. Regardless of these differences, it
is obviously still expected that samples from a split pair carry greater similarity than a
random Respondent and CH2M HILL sample. For this reason, it is beneficial to maintain
this paired relationship through the evaluation.

EPA's Superfund Lead-Contaminated Residential Sites Handbook (EPA, 2003b)
considers split analyses with varying make-up (such as depth) and suggests a paired t test
for comparison. A paired t test does not pool all results from the two populations (i.e.
CH2M HILL and Respondent populations) into two groups, but rather considers the
population of differences between the paired results. It answers the question of whether
or not the observed differences indicate a significant deviation from zero. If there is a
significant deviation, then the conclusion that the two populations are not equivalent is
drawn. The results of this testing are presented in Table A-10.

This test carries an assumption of normality which was either rejected (when a healthy
number of differences, say 20, was available and the p-value for normality was less than
0.05) or not well defended (when a fewer number of differences was available). Thus,
the nonparametric version of the paired t test, the Wilcoxon Signed Rank Test, was used
to compare the two populations. The p-values from this testing were compared to a
significance level of 0.05 (which ensured that cases where the two populations were
actually equivalent would only be determined to be different 5% of the time, or less).
When the p-value was not less than 0.05, the conclusion is drawn that the two
populations are statistically equivalent. If the p-value is below 0.05, the conclusion is
drawn that the two populations are statistically different.

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT

	APPENDIX A: SPLIT AND SUPPLEMENTAL SAMPLING SUMMARY TM

The analysis via the Wilcoxon Signed Rank Test indicates that splits for Chat Base, Chat
Pile, and Washed Fines data are not significantly different (between CH2M HILL and
Respondent data). Split data for Fine Tailings, Residential Yard Soil, and Transition
Zone Soil are, however, significantly different.

For those cases where there appears to be a statistical difference between the splits (via
the Wilcoxon Signed Rank test), the actual differences still appear rather small. The
RPDs of the mean concentrations for these cases are presented in Table A-ll. They are
seen to range from 16% to 30%. These low RPDs suggest that these differences,
although statistically significant due to relatively low variability in the data, have limited
practical significance in accessing environmental risks, etc.

4.0 References

CH2M HILL, 2004. Work Plan, Tar Creek Superfund Site OU No. 4, Ottawa County,
Oklahoma. July 2004.

CH2M HILL, 2005a. Work Plan Revision Request 01, Tar Creek Superfund Site OU No. 4,
Ottawa County, Oklahoma. February 2005.

CH2M HILL, 2005b. Work Plan Revision Request 02, Tar Creek Superfund Site OU No. 4,
Ottawa County, Oklahoma. August 2005.

CH2M HILL, 2005c. Field Sampling Plan, Tar Creek Superfund Site OU No. 4, Ottawa
County, Oklahoma. May 2005.

CH2M HILL, 2005d. Quality Assurance Project Plan, Tar Creek Superfund Site OU No. 4,
Ottawa County, Oklahoma. May 2005.

CH2M HILL, 2005e. Revised Health and Safety Plan, Tar Creek Superfund Site OU No. 4,
Ottawa County, Oklahoma. September 2005.

U.S. Environmental Protection Agency (EPA), 2003a. Administrative Order on Consent for
Tar Creek RI/FSfor OU4. December 2003.

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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT

	APPENDIX A: SPLIT AND SUPPLEMENTAL SAMPLING SUMMARY TM

U.S. Environmental Protection Agency (EPA), 2003b. Saperfand Lead-Contaminated
Residential Sites Handbook. Office of Emergency and Remedial Response.

2003.

U. S Environmental Protection Agency (EPA), 2004. USEPA Contract Laboratory
Program National Functional Guidelines for Inorganic Data Review.
EPA/540/R-04/004. October, 2004

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DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX A: SPLIT AND SUPPLEMENTAL SAMPLING SUMMARY TM

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Tables

008440


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX A: SPLIT AND SUPPLEMENTAL SAMPLING SUMMARY TM

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Table A-1

Chat Summary

Tar Creek Superfund Site

Ottawa County, Oklahoma





Primary Media

Chat (Chat Piles)



Respondents Sub Media Definition

Bulk Chat

Surface Chat





Sample Depth

1 foot below surface

0-6 inches

0-1 inch



Sample Preparation Method

Note 1

Note 2

Note 2

Note 2





Pile





Respondents



HHRA

Respondents



HHRA

Quantity

Location

Local Pile Name

Rl Samples

Rl Split

Supplemental(3>

Rl Samples

Rl Split

Supplemental

1

T29N-R22E-13-1

Bird Dog

8

1

5

0

0

0

2

T29N-R22E-23-1

Adams-Mudd (Barret)

8

2

0

0

0

0

3

T29N-R22E-25-9

Pioneer

8

1

5

0

0

0

4

T29N-R23E-13-2

Semple

8

2

0

0

0

0

5

T29N-R23E-16-1

Sooner

8

2

0

2

0

0

6

T29N-R23E-17-12

Howe

8

2

0

0

0

0

7

T29N-R23E-17-9

Ottawa

8

2

0

2

0

0

8

T29N-R23E-18-5

Gordon

8

1

5

0

0

0

9

T29N-R23E-19-7

Western (Anna Beaver)

8

2

0

0

0

0

10

T29N-R23E-19-8

Western (John Beaver)

8

2

0

2

0

0

11

T29N-R23E-20-11

OKO

8

2

0

2

0

0

12

T29N-R23E-20-16

Kenoyer

8

2

0

2

0

0

13

T29N-R23E-20-8

St. Joe

8

2

0

0

0

0

14

T29N-R23E-21-1

Fisher (Mahutska)

8

2

4

0

0

0

15

T29N-R23E-21-11

Royal (Thompson)

8

0

0

2

0

0

16

T29N-R23E-28-12

Lawyers

8

1

5

0

0

0

17

T29N-R23E-29-14

Admiralty

8

2

0

0

0

0

18

T29N-R23E-29-8

Skelton

8

2

0

0

0

0

19

T29N-R23E-30-13

Blue Goose

8

1

0

2

0

0

20

T29N-R23E-30-1

Pearl (Bill Baily)

8

2

5

0

0

0

21

T29N-R23E-22-7

Atlas (Tulsa)

0

0

5

0

0

0

Totals

160

33

34

14

0

0

NOTES:

1	= Samples crushed and ground so that all material passes through #100 mesh sieve.

2	= Samples sieved using #60 mesh sieve.

3	= Sample quantities include samples collected for grain size distribution and subsequent analysis.

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA1_Ch at
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Tar Creek Superfund Site
Ottawa County, Oklahoma

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Table A-2

Chat Base Summary
Tar Creek Superfund Site
Ottawa County, Oklahoma





Primary Media

Chat Base



Respondents Sub Media Definition

None





Sample Depth

1 foot below surface

0-6 inches



Sample Preparation Method

Note 1

Note 2

Note 2

Pile





Respondents



HHRA

Quantity

Location

Local Pile Name

Rl Samples

Rl Split

Supplemental(3>

1

T29N-R22E-25-9

Pioneer

4

1

5

2

T29N-R23E-18-5

Gordon

4

1

5

3

T29N-R23E-20-16

Kenoyer

4

2

0

4

T29N-R23E-20-8

St. Joe

2

0

0

5

T29N-R23E-28-12

Lawyers

4

1

5

6

T29N-R23E-30-13

Blue Goose

4

1

5

Totals

22

6

20

NOTES:

1	= Samples crushed and ground so that all material passes through #100 mesh sieve.

2	= Samples sieved using #60 mesh sieve.

3	= Sample quantities include samples collected for grain size distribution and subsequent analysis.

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA2_ChatBase

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Tar Creek Superfund Site
Ottawa County, Oklahoma

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OCTOBER 2005


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Table A-3

Tailings Summary

Tar Creek Superfund Site

Ottawa County, Oklahoma





Primary Media

Fine Tailings



Respondents Sub Media Definition

Washed Fines

Flotation Tailings

Surface Fine Tailings





Sample Depth

Depth Integrated Composite

0-6 inches

Depth Integrated Composite

0-6 inches

0-1 inch



Sample Preparation Method

None

None

Note 1

None

None

Note 1

None

Pile
Quantity

Location

Local Pile Name

Respondents
Rl Samples**

Rl Split

HHRA
Supplemental<2>

Respondents
Rl Samples **

Rl Split

HHRA
Supplemental<2>

Respondents Rl
Samples **

1

T29N-R22E-13-1

Bird Dog

10

2

4

6

2

5

3

2

T29N-R22E-25-9

Pioneer

10

2

4

5

2

1

1

3

T29N-R23E-13-2

Semple

11

2

0

4

1

0

1

4

T29N-R23E-17-9

Ottawa

11

2

2

5

2

0



5

T29N-R23E-19-8

Western (John Beaver)

10

0

0

7

4

2

1

6

T29N-R23E-28-12

Lawyers

10

2

4

4

2

1

1

7

T29N-R23E-31-1

Central Mill Pond

11

2

5

5

2

0

1

8

T29N-R23E-29-8

Skelton

11

3

1

6

2

0

1

9

T29N-R23E-30-13

Blue Goose

10

2

2

8

2

0

1

10

T29N-R23E-22-7

Atlas (Tulsa)

7

2

2

5

2

2

1

Totals

101

19

24

55

21

11

13

NOTES:

** = Quantity includes duplicate samples.

1	= Samples sieved using #60 mesh sieve.

2	= Sample quantities include samples collected for grain size distribution and subsequent analysis.

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA3_FineTailings

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Tar Creek Superfund Site
Ottawa County, Oklahoma

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Table A-4

Smelter Waste Summary
Tar Creek Superfund Site
Ottawa County, Oklahoma



Primary Media

Smelter Waste



Respondents Sub Media Definition

Slag

Clinker



Sample Depth

Surface

Surface



Sample Preparation Method

None

None



None

None



Respondents





Respondents



HHRA

Respondents



HHRA

Sample ID

Waste Type

Location

Rl Samples**

Rl Split

Supplemental

Rl Samples

Rl Split

Supplemental

SM2324-1

Clinker (85%) + Slag (15%)

T29N-R2E-24

0

0

0

1

1

0

SM2324-2

Slag (massive)

T29N-R2E-24

1

1

0

0

0

0

SM2324-3

Slag (pellets)

T29N-R2E-24

2

0

0

0

0

0

SM2324-4

Clinker (50%) + Slag (50%)

T29N-R2E-24

0

0

0

1

0

0

SM2324-5

Slag (massive)

T29N-R2E-24

1

0

0

0

0

0

Totals

4

1

0

2

1

0

NOTES:

** = Quantity includes duplicate samples.

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA4_SmelterWaste
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Tar Creek Superfund Site
Ottawa County, Oklahoma

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Table A-5

Soils - Background Summary
Tar Creek Superfund Site
Ottawa County, Oklahoma



Primary Media

Soils

Respondents Sub Media Definition

Background



Sample Depth

0-6 inches



Sample Preparation Method

None

None







Respondents Rl



HHRA

Respondents Sample ID

Site No.

Samples **

Rl Split

Supplemental

BS2318-1

1

1

0

0

BS224-2/BS224-8

2

2

1

0

BS2236-3

3

1

0

0

BS2325-4

4

1

1

0

BS2327-5

5

1

0

0

BS2332-6

6

1

0

0

BS2419-7

7

1

0

0

Totals

8

2

0

NOTES:

** = Quantity includes duplicate samples.

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\	PAGE 1 OF 1

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA5_Soils-Background
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Tar Creek Superfund Site
Ottawa County, Oklahoma

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008451

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Table A-6

Soils - Transition Zone
Tar Creek Superfund Site
Ottawa County, Oklahoma

Primary Media
Sub Media
Sample Depth
Sample Preparation

Soils

Transition Zone (1)

0-1 Inch

6-inch

12-inch

24-inch



None

None

None

Pile
Quantity

Location

Local Pile Name

Respondents Rl
Samples

Respondents
Rl Samples

Respondents
Rl Samples

Respondents
Rl Samples

1

T29N-R22E-23-1

Adams-Mudd (Barrett)









2

T29N-R22E-25-9

Pioneer









3

T29N-R23E-21 -11

Royal (Thompson)









4

T29N-R23E-22-7

Atlas (Tulsa)









5

T29N-R24E-30-1

Pearl (Bill Baily)









Totals

65

58

55

46



Primary Media
Sub Media
Sample Depth
Sample Preparation

Soils

Transition Zone'1'

0-1 Inch

6-inch

12-inch

24-inch

Note 2

Note 2

None

None

Pile
Quantity

Location

Local Pile Name

Rl Split

Rl Split

Rl Split

Rl Split

1

T29N-R22E-23-1

Adams-Mudd (Barrett)

3

3

6

6

2

T29N-R22E-25-9

Pioneer

3

3

6

7

3

T29N-R23E-21 -11

Royal (Thompson)

0

0

0

0

4

T29N-R23E-22-7

Atlas (Tulsa)

5

5

5

2

5

T29N-R24E-30-1

Pearl (Bill Baily)

4

3

5

6

Totals

15

14

22

21





Primary Media

Soils





Sub Media

Transition Zone'1'





Sample Depth

0-6 inches





Sample Preparation

Note 2

Pile







Quantity

Location

Local Pile Name

HHRA Supplemental

1

T29N-R22E-23-1

Adams-Mudd (Barrett)

2

2

T29N-R22E-25-9

Pioneer

2

3

T29N-R23E-21 -11

Royal (Thompson)

0

4

T29N-R23E-22-7

Atlas (Tulsa)

2

5

T29N-R24E-30-1

Pearl (Bill Baily)

2

Totals

8

NOTES:

(1) = Samples collected at determined distances away from the pile along north and south transects.
2 = Samples sieved using #60 mesh sieve.

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA6_Soils-TZ

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Tar Creek Superfund Site
Ottawa County, Oklahoma

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008453

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Table A-7

Soils - Rural Residential Yard Summary
Tar Creek Superfund Site
Ottawa County, Oklahoma

Primary Media
Respondents Sub Media Definition
Sample Depth
Sample Preparation Method

Soils

Rural Residential Yard

0-1 inch

0-1 inch

0-6 inch

0-6 inch

Note 1

Note 1

None

Note 1



Respondents Rl
Samples **

Rl Split

Respondents Rl
Samples **

Rl Split

Totals

179

8

179

24

NOTES:

** = Quantity includes duplicate samples.
1 = Samples sieved using #60 mesh sieve.

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA7_Soils-Yard
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Tar Creek Superfund Site
Ottawa County, Oklahoma

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008455

OCTOBER 2005


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Table A-8

Soils - Smelter Affected
Tar Creek Superfund Site
Ottawa County, Oklahoma

Primary Media
Respondents Sub Media Definition
Sample Depth
Sample Preparation Method

Soils

Smelter-Affected

0-1 inch

0-1 inch

0-6 inch

None

Note 1

Note 1



Respondents Rl
Samples

Rl Split

HHRA
Supplemental

Transect Totals

35

8

2

Smelter Pasture Land

0

0

4

NOTES:

1 = Samples sieved using #60 mesh sieve.

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA8_Soils-Smelter
008456

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Tar Creek Superfund Site
Ottawa County, Oklahoma

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008457

OCTOBER 2005


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Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Arsenic

Residential Yard Soil

Residential Location #14

TC4-RS-14A

3

3.1

3

Arsenic

Residential Yard Soil

Residential Location #8

TC4-RS-08B

3.8

3.7

3

Arsenic

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

53.3

55.3

4

Arsenic

Biota Associated Soil

Plant #10

TC4-BIO-10E

2.5

3.7

39

Arsenic

Biota Associated Soil

Plant #20

TC4-BIO-20E

4.5

5.8

25

Arsenic

Biota Associated Soil

Plant #30

TC4-BIO-30E

1.9

1.7

11

Arsenic

Biota Associated Soil

Plant #40

TC4-BIO-40E

6.8

7

3

Arsenic

Biota Associated Soil

Plant #50

TC4-BIO-50E

2.9

3.4

16

Arsenic

Biota Associated Soil

Plant #56

TC4-BIO-56E

2.1

2.4

13

Arsenic

Chat Base

Gordon

TC4-SO-16G

5.6

6.1

9

Arsenic

Chat Base

Pioneer

TC4-SO-04H

2.4

3.5

37

Arsenic

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

7.7

7.5

3

Arsenic

Chat Pile

Bird Dog

TC4-SO-01B

5.7

5.5

4

Arsenic

Chat Pile

Pioneer

TC4-SO-04C

3.3

3.2

3

Arsenic

Fine Tailings

Bird Dog

TC4-SO-01H

10.9

10.6

3

Arsenic

Fine Tailings

Bird Dog

TC4-SO-01N

13.2

15.1

13

Arsenic

Fine Tailings

Pioneer

TC4-SO-04M

10.5

10.8

3

Arsenic

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

3.5

3.6

3

Arsenic

Biota

Plant #10

TC4-BIO-10B

0.2

0.3

40

Arsenic

Biota

Plant #10

TC4-BIO-10C

1.1

1.1

0

Arsenic

Biota

Plant #10

TC4-BIO-10D

0.67

0.53

23

Arsenic

Biota

Plant #20

TC4-BIO-20A

0.27

0.2

30

Arsenic

Biota

Plant #20

TC4-BIO-20B

0.31

0.29

7

Arsenic

Biota

Plant #20

TC4-BIO-20C

2.6

2.3

12

Arsenic

Biota

Plant #20

TC4-BIO-20D

2

2.7

30

Arsenic

Biota

Plant #30

TC4-BIO-30A

0.39

0.26

40

Arsenic

Biota

Plant #30

TC4-BIO-30B

0.43

0.34

23

Arsenic

Biota

Plant #30

TC4-BIO-30C

0.57

1

55

Arsenic

Biota

Plant #30

TC4-BIO-30D

0.48

0.55

14

Arsenic

Biota

Plant #40

TC4-BIO-40A

0.53

1

61

Arsenic

Biota

Plant #40

TC4-BIO-40B

0.43

0.88

69

Arsenic

Biota

Plant #40

TC4-BIO-40C

3.7

4.1

10

Arsenic

Biota

Plant #40

TC4-BIO-40D

0.85

1.4

49

Arsenic

Biota

Plant #50

TC4-BIO-50C

1.7

1.1

43

Arsenic

Biota

Plant #50

TC4-BIO-50D

0.63

0.82

26

Arsenic

Biota

Plant #56

TC4-BIO-56A

5.7

0.21

186

Arsenic

Biota

Plant #56

TC4-BIO-56B

0.19

0.38

67

Arsenic

Biota

Plant #56

TC4-BIO-56C

0.34

0.66

64

Arsenic

Biota

Plant #56

TC4-BIO-56D

0.61

0.38

46

Aluminum

Residential Yard Soil

Residential Location #14

TC4-RS-14A

4630

4890

5

Aluminum

Residential Yard Soil

Residential Location #8

TC4-RS-08B

3740

4130

10

Aluminum

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

4710

3980

17

Aluminum

Biota Associated Soil

Plant #10

TC4-BIO-10E

790

546

37

Aluminum

Biota Associated Soil

Plant #20

TC4-BIO-20E

4630

4070

13

Aluminum

Biota Associated Soil

Plant #30

TC4-BIO-30E

303

253

18

Aluminum

Biota Associated Soil

Plant #40

TC4-BIO-40E

2820

2840

1

Aluminum

Biota Associated Soil

Plant #50

TC4-BIO-50E

342

626

59

Aluminum

Biota Associated Soil

Plant #56

TC4-BIO-56E

1080

1340

21

Aluminum

Chat Base

Gordon

TC4-SO-16G

564

663

16

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 1 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008458


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma











Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Aluminum

Chat Base

Pioneer

TC4-SO-04H

556

508

9

Aluminum

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

441

436

1

Aluminum

Chat Pile

Bird Dog

TC4-SO-01B

613

602

2

Aluminum

Chat Pile

Pioneer

TC4-SO-04C

327

364

11

Aluminum

Fine Tailings

Bird Dog

TC4-SO-01H

1200

1010

17

Aluminum

Fine Tailings

Bird Dog

TC4-SO-01N

3900

3420

13

Aluminum

Fine Tailings

Pioneer

TC4-SO-04M

943

994

5

Aluminum

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

4910

5200

6

Aluminum

Biota

Plant #10

TC4-BIO-10A

24.5

41.5

52

Aluminum

Biota

Plant #10

TC4-BIO-10B

25

32.2

25

Aluminum

Biota

Plant #10

TC4-BIO-10C

226

265

16

Aluminum

Biota

Plant #10

TC4-BIO-10D

125

112

11

Aluminum

Biota

Plant #20

TC4-BIO-20A

31.1

29.4

6

Aluminum

Biota

Plant #20

TC4-BIO-20B

48.8

27.7

55

Aluminum

Biota

Plant #20

TC4-BIO-20C

2310

1820

24

Aluminum

Biota

Plant #20

TC4-BIO-20D

2140

2040

5

Aluminum

Biota

Plant #30

TC4-BIO-30A

32.2

37.1

14

Aluminum

Biota

Plant #30

TC4-BIO-30B

48.5

43.2

12

Aluminum

Biota

Plant #30

TC4-BIO-30C

70.1

115

49

Aluminum

Biota

Plant #30

TC4-BIO-30D

52.1

65.5

23

Aluminum

Biota

Plant #40

TC4-BIO-40A

303

415

31

Aluminum

Biota

Plant #40

TC4-BIO-40B

291

278

5

Aluminum

Biota

Plant #40

TC4-BIO-40C

1660

1800

8

Aluminum

Biota

Plant #40

TC4-BIO-40D

419

531

24

Aluminum

Biota

Plant #50

TC4-BIO-50A

25.9

22.1

16

Aluminum

Biota

Plant #50

TC4-BIO-50B

31.6

22.4

34

Aluminum

Biota

Plant #50

TC4-BIO-50C

784

507

43

Aluminum

Biota

Plant #50

TC4-BIO-50D

200

181

10

Aluminum

Biota

Plant #56

TC4-BIO-56A

3300

137

184

Aluminum

Biota

Plant #56

TC4-BIO-56B

114

146

25

Aluminum

Biota

Plant #56

TC4-BIO-56C

177

254

36

Aluminum

Biota

Plant #56

TC4-BIO-56D

203

147

32

Ant

mony

Residential Yard Soil

Residential Location #14

TC4-RS-14A

0.39

0.35

ND

Ant

mony

Residential Yard Soil

Residential Location #8

TC4-RS-08B

0.5

0.5

ND

Ant

mony

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

304

366

19

Ant

mony

Biota Associated Soil

Plant #30

TC4-BIO-30E

0.24

0.35

ND

Ant

mony

Biota Associated Soil

Plant #40

TC4-BIO-40E

1.4

1.4

0

Ant

mony

Chat Base

Gordon

TC4-SO-16G

0.75

0.87

15

Ant

mony

Chat Base

Pioneer

TC4-SO-04H

0.435

3

ND

Ant

mony

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

3

3

ND

Ant

mony

Chat Pile

Bird Dog

TC4-SO-01B

0.8

0.89

11

Ant

mony

Chat Pile

Pioneer

TC4-SO-04C

3

3

ND

Ant

mony

Fine Tailings

Bird Dog

TC4-SO-01H

1.8

1.5

18

Ant

mony

Fine Tailings

Bird Dog

TC4-SO-01N

0.64

1.2

61

Ant

mony

Fine Tailings

Pioneer

TC4-SO-04M

1

1.2

18

Ant

mony

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

0.325

0.355

ND

Ant

mony

Biota

Plant #10

TC4-BIO-10A

0.165

0.305

ND

Ant

mony

Biota

Plant #10

TC4-BIO-10B

0.14

0.255

ND

Ant

mony

Biota

Plant #10

TC4-BIO-10C

0.305

0.475

ND

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 2 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008459


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma













Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Ant

mony

Biota

Plant #10

TC4-BIO-10D

0.375

0.445

ND

Ant

mony

Biota

Plant #20

TC4-BIO-20A

0.215

0.265

ND

Ant

mony

Biota

Plant #20

TC4-BIO-20B

0.415

0.2

ND

Ant

mony

Biota

Plant #20

TC4-BIO-20C

0.365

0.28

ND

Ant

mony

Biota

Plant #20

TC4-BIO-20D

0.225

0.305

ND

Ant

mony

Biota

Plant #30

TC4-BIO-30A

0.28

0.21

ND

Ant

mony

Biota

Plant #30

TC4-BIO-30B

0.415

0.3

ND

Ant

mony

Biota

Plant #30

TC4-BIO-30C

0.405

0.22

ND

Ant

mony

Biota

Plant #30

TC4-BIO-30D

0.295

0.335

ND

Ant

mony

Biota

Plant #50

TC4-BIO-50A

0.335

0.375

ND

Ant

mony

Biota

Plant #50

TC4-BIO-50B

0.26

3

ND

Ant

mony

Biota

Plant #50

TC4-BIO-50C

0.31

0.29

ND

Ant

mony

Biota

Plant #50

TC4-BIO-50D

0.165

0.145

ND

Ant

mony

Biota

Plant #56

TC4-BIO-56A

0.12

0.185

ND

Ant

mony

Biota

Plant #56

TC4-BIO-56B

0.22

0.13

ND

Ant

mony

Biota

Plant #56

TC4-BIO-56C

0.13

3

ND

Ant

mony

Biota

Plant #56

TC4-BIO-56D

3

3

ND

Bar

um

Residential Yard Soil

Residential Location #14

TC4-RS-14A

102

102

0

Bar

um

Residential Yard Soil

Residential Location #8

TC4-RS-08B

92.2

93

1

Bar

um

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

77.7

80.3

3

Bar

um

Biota Associated Soil

Plant #10

TC4-BIO-10E

12

10.2

16

Bar

um

Biota Associated Soil

Plant #20

TC4-BIO-20E

91.5

77.4

17

Bar

um

Biota Associated Soil

Plant #30

TC4-BIO-30E

1.9

1.3

ND

Bar

um

Biota Associated Soil

Plant #40

TC4-BIO-40E

77.3

76.2

1

Bar

um

Biota Associated Soil

Plant #50

TC4-BIO-50E

4.4

7

46

Bar

um

Biota Associated Soil

Plant #56

TC4-BIO-56E

10.7

15.1

34

Bar

um

Chat Base

Gordon

TC4-SO-16G

4.3

4.8

11

Bar

um

Chat Base

Pioneer

TC4-SO-04H

15.6

5.1

101

Bar

um

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

58.9

52.4

12

Bar

um

Chat Pile

Bird Dog

TC4-SO-01B

10

10.05

ND

Bar

um

Chat Pile

Pioneer

TC4-SO-04C

5.2

5.1

2

Bar

um

Fine Tailings

Bird Dog

TC4-SO-01N

43.6

41

6

Bar

um

Fine Tailings

Pioneer

TC4-SO-04M

20.2

18.6

8

Bar

um

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

72.4

74.4

3

Bar

um

Biota

Plant #10

TC4-BIO-10A

4.3

4.1

5

Bar

um

Biota

Plant #10

TC4-BIO-10B

4.5

4

12

Bar

um

Biota

Plant #10

TC4-BIO-10C

3.7

7

62

Bar

um

Biota

Plant #10

TC4-BIO-10D

5.1

3.8

29

Bar

um

Biota

Plant #20

TC4-BIO-20A

2.95

3.2

ND

Bar

um

Biota

Plant #20

TC4-BIO-20B

6.55

3.65

ND

Bar

um

Biota

Plant #20

TC4-BIO-20C

49.7

32.9

41

Bar

um

Biota

Plant #20

TC4-BIO-20D

55.7

42.7

26

Bar

um

Biota

Plant #30

TC4-BIO-30A

2.4

2.7

12

Bar

um

Biota

Plant #30

TC4-BIO-30B

3.3

2.7

20

Bar

um

Biota

Plant #30

TC4-BIO-30C

1.3

1.6

21

Bar

um

Biota

Plant #30

TC4-BIO-30D

0.83

1.9

78

Bar

um

Biota

Plant #40

TC4-BIO-40A

26.6

32.2

19

Bar

um

Biota

Plant #40

TC4-BIO-40B

27

25.8

5

Bar

um

Biota

Plant #40

TC4-BIO-40C

41

32.1

24

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 3 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008460


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma

Parameter

Media Grouping

Location F2L

Station ID

Normal
Result

FD
Result

RPD,

%

Barium

Biota

Plant #50

TC4-BIO-50A

2.65

2.4

ND

Barium

Biota

Plant #50

TC4-BIO-50B

2.65

1.9

ND

Barium

Biota

Plant #50

TC4-BIO-50C

49.8

41.7

18

Barium

Biota

Plant #50

TC4-BIO-50D

47.2

32.7

36

Barium

Biota

Plant #56

TC4-BIO-56A

9

4.5

ND

Barium

Biota

Plant #56

TC4-BIO-56B

4

4.45

ND

Barium

Biota

Plant #56

TC4-BIO-56C

1.4

1.6

ND

Barium

Biota

Plant #56

TC4-BIO-56D

1.55

1.05

ND

Beryll

um

Residential Yard Soil

Residential Location #14

TC4-RS-14A

0.42

0.42

0

Beryll

um

Residential Yard Soil

Residential Location #8

TC4-RS-08B

0.46

0.48

4

Beryll

um

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

0.53

0.55

4

Beryll

um

Biota Associated Soil

Plant #10

TC4-BIO-10E

0.13

0.12

8

Beryll

um

Biota Associated Soil

Plant #20

TC4-BIO-20E

0.59

0.6

2

Beryll

um

Biota Associated Soil

Plant #30

TC4-BIO-30E

0.1

0.09

11

Beryll

um

Biota Associated Soil

Plant #40

TC4-BIO-40E

0.44

0.46

4

Beryll

um

Biota Associated Soil

Plant #50

TC4-BIO-50E

0.0465

0.065

ND

Beryll

um

Biota Associated Soil

Plant #56

TC4-BIO-56E

0.06

0.07

ND

Beryll

um

Chat Base

Gordon

TC4-SO-16G

0.24

0.27

12

Beryll

um

Chat Base

Pioneer

TC4-SO-04H

0.083

0.086

4

Beryll

um

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

0.2

0.2

0

Beryll

um

Chat Pile

Bird Dog

TC4-SO-01B

0.25

0.25

ND

Beryll

um

Chat Pile

Pioneer

TC4-SO-04C

0.096

0.1

4

Beryll

um

Fine Tailings

Bird Dog

TC4-SO-01H

0.165

0.155

ND

Beryll

um

Fine Tailings

Bird Dog

TC4-SO-01N

0.91

0.76

18

Beryll

um

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

0.44

0.43

2

Beryll

um

Biota

Plant #10

TC4-BIO-10A

0.125

0.25

ND

Beryll

um

Biota

Plant #10

TC4-BIO-10B

0.125

0.25

ND

Beryll

um

Biota

Plant #10

TC4-BIO-10C

0.0115

0.023

ND

Beryll

um

Biota

Plant #10

TC4-BIO-10D

0.0135

0.25

ND

Beryll

um

Biota

Plant #20

TC4-BIO-20A

0.25

0.25

ND

Beryll

um

Biota

Plant #20

TC4-BIO-20B

0.25

0.25

ND

Beryll

um

Biota

Plant #20

TC4-BIO-20C

0.16

0.125

ND

Beryll

um

Biota

Plant #20

TC4-BIO-20D

0.14

0.155

ND

Beryll

um

Biota

Plant #30

TC4-BIO-30A

0.25

0.25

ND

Beryll

um

Biota

Plant #30

TC4-BIO-30B

0.25

0.25

ND

Beryll

um

Biota

Plant #30

TC4-BIO-30C

0.01

0.0165

ND

Beryll

um

Biota

Plant #30

TC4-BIO-30D

0.25

0.25

ND

Beryll

um

Biota

Plant #40

TC4-BIO-40C

0.24

0.25

4

Beryll

um

Biota

Plant #40

TC4-BIO-40D

0.05

0.071

35

Beryll

um

Biota

Plant #50

TC4-BIO-50A

0.25

0.25

ND

Beryll

um

Biota

Plant #50

TC4-BIO-50B

0.25

0.25

ND

Beryll

um

Biota

Plant #50

TC4-BIO-50C

0.096

0.057

51

Beryll

um

Biota

Plant #50

TC4-BIO-50D

0.027

0.014

63

Beryll

um

Biota

Plant #56

TC4-BIO-56B

0.0065

0.00445

ND

Beryll

um

Biota

Plant #56

TC4-BIO-56C

0.0075

0.009

ND

Beryll

um

Biota

Plant #56

TC4-BIO-56D

0.009

0.006

ND

Cadm

um

Residential Yard Soil

Residential Location #14

TC4-RS-14A

3.1

3.5

12

Cadm

um

Residential Yard Soil

Residential Location #8

TC4-RS-08B

0.38

0.4

5

Cadm

um

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

101

95

6

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 4 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008461


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Cadmium

Biota Associated Soil

Plant #10

TC4-BIO-10E

31.5

32.3

3

Cadmium

Biota Associated Soil

Plant #20

TC4-BIO-20E

26.3

48.7

60

Cadmium

Biota Associated Soil

Plant #30

TC4-BIO-30E

29.2

29.9

2

Cadmium

Biota Associated Soil

Plant #40

TC4-BIO-40E

87.4

98

11

Cadmium

Biota Associated Soil

Plant #50

TC4-BIO-50E

88.6

82

8

Cadmium

Biota Associated Soil

Plant #56

TC4-BIO-56E

27.3

25.4

7

Cadmium

Chat Base

Gordon

TC4-SO-16G

79.1

92.5

16

Cadmium

Chat Base

Pioneer

TC4-SO-04H

54.3

61.2

12

Cadmium

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

78.9

76.8

3

Cadmium

Chat Pile

Bird Dog

TC4-SO-01B

77

83.2

8

Cadmium

Chat Pile

Pioneer

TC4-SO-04C

85.6

84.7

1

Cadmium

Fine Tailings

Bird Dog

TC4-SO-01H

100

104

4

Cadmium

Fine Tailings

Bird Dog

TC4-SO-01N

88.8

102

14

Cadmium

Fine Tailings

Pioneer

TC4-SO-04M

114

108

5

Cadmium

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

3.9

3.9

0

Cadmium

Biota

Plant #10

TC4-BIO-10A

5

4.6

8

Cadmium

Biota

Plant #10

TC4-BIO-10B

5.9

6.4

8

Cadmium

Biota

Plant #10

TC4-BIO-10C

24.4

28.7

16

Cadmium

Biota

Plant #10

TC4-BIO-10D

22.6

17.9

23

Cadmium

Biota

Plant #20

TC4-BIO-20A

6.6

8.7

27

Cadmium

Biota

Plant #20

TC4-BIO-20B

15

8

61

Cadmium

Biota

Plant #20

TC4-BIO-20C

39.4

46

15

Cadmium

Biota

Plant #20

TC4-BIO-20D

39.7

38.2

4

Cadmium

Biota

Plant #30

TC4-BIO-30A

18

11.6

43

Cadmium

Biota

Plant #30

TC4-BIO-30B

13.9

19.9

36

Cadmium

Biota

Plant #30

TC4-BIO-30C

41.4

34.8

17

Cadmium

Biota

Plant #30

TC4-BIO-30D

57.3

36.5

44

Cadmium

Biota

Plant #40

TC4-BIO-40A

6.2

6.3

2

Cadmium

Biota

Plant #40

TC4-BIO-40B

5.6

4.8

15

Cadmium

Biota

Plant #40

TC4-BIO-40C

73

69.9

4

Cadmium

Biota

Plant #40

TC4-BIO-40D

40.9

48.3

17

Cadmium

Biota

Plant #50

TC4-BIO-50A

37.2

35

6

Cadmium

Biota

Plant #50

TC4-BIO-50B

40

30.5

27

Cadmium

Biota

Plant #50

TC4-BIO-50C

118

113

4

Cadmium

Biota

Plant #50

TC4-BIO-50D

139

97

36

Cadmium

Biota

Plant #56

TC4-BIO-56A

54.7

14.1

118

Cadmium

Biota

Plant #56

TC4-BIO-56B

6.4

6.1

5

Cadmium

Biota

Plant #56

TC4-BIO-56C

15.1

17.5

15

Cadmium

Biota

Plant #56

TC4-BIO-56D

17.8

11.5

43

Calcium

Residential Yard Soil

Residential Location #14

TC4-RS-14A

2190

2220

1

Calcium

Residential Yard Soil

Residential Location #8

TC4-RS-08B

2150

2180

1

Calcium

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

19300

22400

15

Calcium

Biota Associated Soil

Plant #10

TC4-BIO-10E

5230

7270

33

Calcium

Biota Associated Soil

Plant #20

TC4-BIO-20E

3380

6410

62

Calcium

Biota Associated Soil

Plant #30

TC4-BIO-30E

22300

16400

30

Calcium

Biota Associated Soil

Plant #40

TC4-BIO-40E

8680

8750

1

Calcium

Biota Associated Soil

Plant #50

TC4-BIO-50E

5930

8970

41

Calcium

Biota Associated Soil

Plant #56

TC4-BIO-56E

5220

9480

58

Calcium

Chat Base

Gordon

TC4-SO-16G

34100

33700

1

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 5 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008462


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Calcium

Chat Base

Pioneer

TC4-SO-04H

19600

25200

25

Calcium

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

51300

51000

1

Calcium

Chat Pile

Bird Dog

TC4-SO-01B

36000

34900

3

Calcium

Chat Pile

Pioneer

TC4-SO-04C

29000

30300

4

Calcium

Fine Tailings

Bird Dog

TC4-SO-01H

27300

25700

6

Calcium

Fine Tailings

Bird Dog

TC4-SO-01N

28100

36900

27

Calcium

Fine Tailings

Pioneer

TC4-SO-04M

30900

32400

5

Calcium

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

3680

3530

4

Calcium

Tailing Ponds

Gordon

TC4-SO-16K

84.1





Calcium

Tailing Ponds

Gordon

TC4-SO-16K

90





Calcium

Tailing Ponds

Lawyers

TC4-SO-33S

214





Calcium

Tailing Ponds

Lawyers

TC4-SO-33S

217





Calcium

Tailing Ponds

Woodchuck

TC4-SO-41A

103





Calcium

Tailing Ponds

Woodchuck

TC4-SO-41A

103





Calcium

Biota

Plant #10

TC4-BIO-10A

16500

17200

4

Calcium

Biota

Plant #10

TC4-BIO-10B

11900

10400

13

Calcium

Biota

Plant #10

TC4-BIO-10C

4120

5510

29

Calcium

Biota

Plant #10

TC4-BIO-10D

5570

4690

17

Calcium

Biota

Plant #20

TC4-BIO-20A

5930

4890

19

Calcium

Biota

Plant #20

TC4-BIO-20B

10600

5620

61

Calcium

Biota

Plant #20

TC4-BIO-20C

3830

4420

14

Calcium

Biota

Plant #20

TC4-BIO-20D

4160

3560

16

Calcium

Biota

Plant #30

TC4-BIO-30A

10700

11700

9

Calcium

Biota

Plant #30

TC4-BIO-30B

12500

9420

28

Calcium

Biota

Plant #30

TC4-BIO-30C

4990

7550

41

Calcium

Biota

Plant #30

TC4-BIO-30D

4150

5030

19

Calcium

Biota

Plant #40

TC4-BIO-40A

16600

21000

23

Calcium

Biota

Plant #40

TC4-BIO-40B

16400

15900

3

Calcium

Biota

Plant #40

TC4-BIO-40C

5450

5000

9

Calcium

Biota

Plant #40

TC4-BIO-40D

2950

4010

30

Calcium

Biota

Plant #50

TC4-BIO-50A

6910

6530

6

Calcium

Biota

Plant #50

TC4-BIO-50B

7300

5960

20

Calcium

Biota

Plant #50

TC4-BIO-50C

21900

24600

12

Calcium

Biota

Plant #50

TC4-BIO-50D

29500

32500

10

Calcium

Biota

Plant #56

TC4-BIO-56A

4200

11000

89

Calcium

Biota

Plant #56

TC4-BIO-56B

10300

9990

3

Calcium

Biota

Plant #56

TC4-BIO-56C

1550

1760

13

Calcium

Biota

Plant #56

TC4-BIO-56D

1840

1270

37

CHROMIUM, TOTAL

Residential Yard Soil

Residential Location #14

TC4-RS-14A

9.9

10.1

2

CHROMIUM, TOTAL

Residential Yard Soil

Residential Location #8

TC4-RS-08B

5.9

6.2

5

CHROMIUM, TOTAL

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

9

6.9

26

CHROMIUM, TOTAL

Biota Associated Soil

Plant #10

TC4-BIO-10E

2.2

2.4

9

CHROMIUM, TOTAL

Biota Associated Soil

Plant #20

TC4-BIO-20E

7.9

9.5

18

CHROMIUM, TOTAL

Biota Associated Soil

Plant #30

TC4-BIO-30E

2.5

2

22

CHROMIUM, TOTAL

Biota Associated Soil

Plant #40

TC4-BIO-40E

8.1

8

1

CHROMIUM, TOTAL

Biota Associated Soil

Plant #50

TC4-BIO-50E

2

2.5

22

CHROMIUM, TOTAL

Biota Associated Soil

Plant #56

TC4-BIO-56E

5.6

4.5

22

CHROMIUM, TOTAL

Chat Base

Gordon

TC4-SO-16G

5.9

8.4

35

CHROMIUM, TOTAL

Chat Base

Pioneer

TC4-SO-04H

3

4.6

42

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 6 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008463


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

CHROMIUM, TOTAL

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

7.3

7.9

8

CHROMIUM, TOTAL

Chat Pile

Bird Dog

TC4-SO-01B

6.7

8.1

19

CHROMIUM, TOTAL

Chat Pile

Pioneer

TC4-SO-04C

4.4

4.8

9

CHROMIUM, TOTAL

Fine Tailings

Bird Dog

TC4-SO-01H

7.1

6.2

14

CHROMIUM, TOTAL

Fine Tailings

Bird Dog

TC4-SO-01N

17.2

17.4

1

CHROMIUM, TOTAL

Fine Tailings

Pioneer

TC4-SO-04M

7.2

7.5

4

CHROMIUM, TOTAL

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

6.4

6.8

6

CHROMIUM, TOTAL

Biota

Plant #10

TC4-BIO-10C

1.8

2.1

15

CHROMIUM, TOTAL

Biota

Plant #20

TC4-BIO-20A

0.185

0.175

ND

CHROMIUM, TOTAL

Biota

Plant #20

TC4-BIO-20B

0.205

0.145

ND

CHROMIUM, TOTAL

Biota

Plant #20

TC4-BIO-20C

4

4.2

5

CHROMIUM, TOTAL

Biota

Plant #20

TC4-BIO-20D

3.7

5

30

CHROMIUM, TOTAL

Biota

Plant #30

TC4-BIO-30A

0.15

0.205

ND

CHROMIUM, TOTAL

Biota

Plant #30

TC4-BIO-30C

1.1

2.1

63

CHROMIUM, TOTAL

Biota

Plant #40

TC4-BIO-40A

1.2

1.5

22

CHROMIUM, TOTAL

Biota

Plant #40

TC4-BIO-40B

1.1

1.1

0

CHROMIUM, TOTAL

Biota

Plant #40

TC4-BIO-40C

5.8

5.8

0

CHROMIUM, TOTAL

Biota

Plant #40

TC4-BIO-40D

1.7

2.2

26

CHROMIUM, TOTAL

Biota

Plant #50

TC4-BIO-50A

0.19

0.17

ND

CHROMIUM, TOTAL

Biota

Plant #50

TC4-BIO-50B

0.065

0.05

ND

CHROMIUM, TOTAL

Biota

Plant #50

TC4-BIO-50C

3.6

2.2

48

CHROMIUM, TOTAL

Biota

Plant #50

TC4-BIO-50D

0.36

0.49

ND

CHROMIUM, TOTAL

Biota

Plant #56

TC4-BIO-56B

0.28

0.26

ND

CHROMIUM, TOTAL

Biota

Plant #56

TC4-BIO-56C

1.3

2.3

56

CHROMIUM, TOTAL

Biota

Plant #56

TC4-BIO-56D

1.5

1.3

14

Cobalt

Residential Yard Soil

Residential Location #14

TC4-RS-14A

6

6.2

3

Cobalt

Residential Yard Soil

Residential Location #8

TC4-RS-08B

5.9

6

2

Cobalt

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

11.6

10.3

12

Cobalt

Biota Associated Soil

Plant #10

TC4-BIO-10E

1.4

1.5

7

Cobalt

Biota Associated Soil

Plant #20

TC4-BIO-20E

7.2

8.7

19

Cobalt

Biota Associated Soil

Plant #30

TC4-BIO-30E

1.1

0.9

20

Cobalt

Biota Associated Soil

Plant #40

TC4-BIO-40E

5

4.8

4

Cobalt

Biota Associated Soil

Plant #50

TC4-BIO-50E

0.65

1.1

51

Cobalt

Biota Associated Soil

Plant #56

TC4-BIO-56E

1.3

1.7

27

Cobalt

Chat Base

Gordon

TC4-SO-16G

2.5

2.8

11

Cobalt

Chat Base

Pioneer

TC4-SO-04H

1.6

1.4

13

Cobalt

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

2.5

2.3

8

Cobalt

Chat Pile

Bird Dog

TC4-SO-01B

3.3

3.1

6

Cobalt

Chat Pile

Pioneer

TC4-SO-04C

2.2

2

10

Cobalt

Fine Tailings

Bird Dog

TC4-SO-01H

3.5

3.5

0

Cobalt

Fine Tailings

Bird Dog

TC4-SO-01N

4.9

5.4

10

Cobalt

Fine Tailings

Pioneer

TC4-SO-04M

4.7

5.1

8

Cobalt

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

4.9

4.8

2

Cobalt

Biota

Plant #10

TC4-BIO-10B

0.074

0.15

68

Cobalt

Biota

Plant #10

TC4-BIO-10C

0.56

1

56

Cobalt

Biota

Plant #10

TC4-BIO-10D

0.55

0.43

24

Cobalt

Biota

Plant #20

TC4-BIO-20A

2.5

2.5

ND

Cobalt

Biota

Plant #20

TC4-BIO-20C

3.2

2.3

33

Cobalt

Biota

Plant #20

TC4-BIO-20D

2.8

3

7

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 7 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008464


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Cobalt

Biota

Plant #30

TC4-BIO-30A

2.5

2.5

ND

Cobalt

Biota

Plant #30

TC4-BIO-30B

0.097

0.13

29

Cobalt

Biota

Plant #30

TC4-BIO-30C

0.37

0.55

39

Cobalt

Biota

Plant #30

TC4-BIO-30D

0.39

0.38

3

Cobalt

Biota

Plant #40

TC4-BIO-40A

0.66

0.88

29

Cobalt

Biota

Plant #40

TC4-BIO-40B

0.62

0.52

18

Cobalt

Biota

Plant #40

TC4-BIO-40C

2.7

3.1

14

Cobalt

Biota

Plant #40

TC4-BIO-40D

0.91

1.3

35

Cobalt

Biota

Plant #50

TC4-BIO-50A

0.62

0.66

6

Cobalt

Biota

Plant #50

TC4-BIO-50B

0.52

0.44

17

Cobalt

Biota

Plant #50

TC4-BIO-50C

1.3

0.91

35

Cobalt

Biota

Plant #50

TC4-BIO-50D

0.61

0.44

32

Cobalt

Biota

Plant #56

TC4-BIO-56A

5.4

0.27

181

Cobalt

Biota

Plant #56

TC4-BIO-56B

0.28

0.2

33

Cobalt

Biota

Plant #56

TC4-BIO-56C

0.27

0.32

17

Cobalt

Biota

Plant #56

TC4-BIO-56D

0.29

0.23

23

Copper

Residential Yard Soil

Residential Location #14

TC4-RS-14A

13

12.3

6

Copper

Residential Yard Soil

Residential Location #8

TC4-RS-08B

5.6

5.7

2

Copper

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

89.7

108

19

Copper

Biota Associated Soil

Plant #10

TC4-BIO-10E

21.1

19.2

9

Copper

Biota Associated Soil

Plant #20

TC4-BIO-20E

19.1

30.2

45

Copper

Biota Associated Soil

Plant #30

TC4-BIO-30E

31.7

28.7

10

Copper

Biota Associated Soil

Plant #40

TC4-BIO-40E

52

52.7

1

Copper

Biota Associated Soil

Plant #50

TC4-BIO-50E

40.1

39.1

3

Copper

Biota Associated Soil

Plant #56

TC4-BIO-56E

11.9

11.9

0

Copper

Chat Base

Gordon

TC4-SO-16G

54.6

62.8

14

Copper

Chat Base

Pioneer

TC4-SO-04H

35.7

69.3

64

Copper

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

71.6

70.1

2

Copper

Chat Pile

Bird Dog

TC4-SO-01B

104

107

3

Copper

Chat Pile

Pioneer

TC4-SO-04C

48.6

48.3

1

Copper

Fine Tailings

Bird Dog

TC4-SO-01H

286

291

2

Copper

Fine Tailings

Bird Dog

TC4-SO-01N

824

712

15

Copper

Fine Tailings

Pioneer

TC4-SO-04M

233

219

6

Copper

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

19.3

17.9

8

Copper

Biota

Plant #10

TC4-BIO-10A

6.3

6.3

0

Copper

Biota

Plant #10

TC4-BIO-10B

7.6

8.7

13

Copper

Biota

Plant #10

TC4-BIO-10C

13.4

18.7

33

Copper

Biota

Plant #10

TC4-BIO-10D

12.8

11.4

12

Copper

Biota

Plant #20

TC4-BIO-20C

20.6

23.6

14

Copper

Biota

Plant #20

TC4-BIO-20D

16.2

18

11

Copper

Biota

Plant #30

TC4-BIO-30A

6.6

5.7

15

Copper

Biota

Plant #30

TC4-BIO-30B

6.9

7.4

7

Copper

Biota

Plant #30

TC4-BIO-30C

17.4

22.3

25

Copper

Biota

Plant #30

TC4-BIO-30D

20.5

18.4

11

Copper

Biota

Plant #40

TC4-BIO-40A

7

7.4

6

Copper

Biota

Plant #40

TC4-BIO-40B

6.9

6.7

3

Copper

Biota

Plant #40

TC4-BIO-40C

37

37.7

2

Copper

Biota

Plant #40

TC4-BIO-40D

17.1

21.4

22

Copper

Biota

Plant #50

TC4-BIO-50A

4

4

0

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 8 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008465


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Copper

Biota

Plant #50

TC4-BIO-50B

4.1

3.5

16

Copper

Biota

Plant #50

TC4-BIO-50C

50

35.2

35

Copper

Biota

Plant #50

TC4-BIO-50D

23.5

13.5

54

Copper

Biota

Plant #56

TC4-BIO-56A

9

6.7

29

Copper

Biota

Plant #56

TC4-BIO-56B

6.2

6.5

5

Copper

Biota

Plant #56

TC4-BIO-56C

4.6

5

8

Copper

Biota

Plant #56

TC4-BIO-56D

5.4

3.8

35

Iron

Residential Yard Soil

Residential Location #14

TC4-RS-14A

7600

7800

3

Iron

Residential Yard Soil

Residential Location #8

TC4-RS-08B

7550

7830

4

Iron

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

19300

20800

7

Iron

Biota Associated Soil

Plant #10

TC4-BIO-10E

3330

4260

25

Iron

Biota Associated Soil

Plant #20

TC4-BIO-20E

9200

13400

37

Iron

Biota Associated Soil

Plant #30

TC4-BIO-30E

2740

2620

4

Iron

Biota Associated Soil

Plant #40

TC4-BIO-40E

10000

10100

1

Iron

Biota Associated Soil

Plant #50

TC4-BIO-50E

2520

3360

29

Iron

Biota Associated Soil

Plant #56

TC4-BIO-56E

4720

5040

7

Iron

Chat Base

Gordon

TC4-SO-16G

5490

5990

9

Iron

Chat Base

Pioneer

TC4-SO-04H

3910

5100

26

Iron

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

6930

6610

5

Iron

Chat Pile

Bird Dog

TC4-SO-01B

7060

7120

1

Iron

Chat Pile

Pioneer

TC4-SO-04C

4500

4450

1

Iron

Fine Tailings

Bird Dog

TC4-SO-01H

11000

10900

1

Iron

Fine Tailings

Bird Dog

TC4-SO-01N

17700

17200

3

Iron

Fine Tailings

Pioneer

TC4-SO-04M

13800

14300

4

Iron

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

9310

9340

0

Iron

Biota

Plant #10

TC4-BIO-10A

61.6

67

8

Iron

Biota

Plant #10

TC4-BIO-10B

60.8

55.6

9

Iron

Biota

Plant #10

TC4-BIO-10C

3990

1350

99

Iron

Biota

Plant #10

TC4-BIO-10D

622

492

23

Iron

Biota

Plant #20

TC4-BIO-20A

62.2

53.4

15

Iron

Biota

Plant #20

TC4-BIO-20B

117

71.8

48

Iron

Biota

Plant #20

TC4-BIO-20C

4560

3810

18

Iron

Biota

Plant #20

TC4-BIO-20D

3650

5020

32

Iron

Biota

Plant #30

TC4-BIO-30A

75.6

67.1

12

Iron

Biota

Plant #30

TC4-BIO-30B

89.9

82.6

8

Iron

Biota

Plant #30

TC4-BIO-30C

496

1030

70

Iron

Biota

Plant #30

TC4-BIO-30D

329

445

30

Iron

Biota

Plant #40

TC4-BIO-40A

811

1060

27

Iron

Biota

Plant #40

TC4-BIO-40B

768

719

7

Iron

Biota

Plant #40

TC4-BIO-40C

5700

5970

5

Iron

Biota

Plant #40

TC4-BIO-40D

1480

1700

14

Iron

Biota

Plant #50

TC4-BIO-50A

45.3

44

3

Iron

Biota

Plant #50

TC4-BIO-50B

45.7

33

32

Iron

Biota

Plant #50

TC4-BIO-50C

2170

1270

52

Iron

Biota

Plant #50

TC4-BIO-50D

421

397

6

Iron

Biota

Plant #56

TC4-BIO-56A

10500

381

186

Iron

Biota

Plant #56

TC4-BIO-56B

315

365

15

Iron

Biota

Plant #56

TC4-BIO-56C

598

860

36

Iron

Biota

Plant #56

TC4-BIO-56D

656

455

36

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 9 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008466


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Lead

Residential Yard Soil

Residential Location #14

TC4-RS-14A

73.8

75.6

2

Lead

Residential Yard Soil

Residential Location #8

TC4-RS-08B

16

16.9

5

Lead

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

70800

42200

51

Lead

Biota Associated Soil

Plant #10

TC4-BIO-10E

1070

1380

25

Lead

Biota Associated Soil

Plant #20

TC4-BIO-20E

537

1180

75

Lead

Biota Associated Soil

Plant #30

TC4-BIO-30E

898

737

20

Lead

Biota Associated Soil

Plant #40

TC4-BIO-40E

1090

1100

1

Lead

Biota Associated Soil

Plant #50

TC4-BIO-50E

296

486

49

Lead

Biota Associated Soil

Plant #56

TC4-BIO-56E

468

558

18

Lead

Chat Base

Gordon

TC4-SO-16G

1680

1940

14

Lead

Chat Base

Pioneer

TC4-SO-04H

754

1660

75

Lead

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

769

727

6

Lead

Chat Pile

Bird Dog

TC4-SO-01B

6070

6410

5

Lead

Chat Pile

Pioneer

TC4-SO-04C

3220

3140

3

Lead

Fine Tailings

Bird Dog

TC4-SO-01H

37700

38600

2

Lead

Fine Tailings

Bird Dog

TC4-SO-01N

7040

9380

29

Lead

Fine Tailings

Pioneer

TC4-SO-04M

4490

4350

3

Lead

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

79.7

79.5

0

Lead

Biota

Plant #10

TC4-BIO-10A

9.1

9.4

3

Lead

Biota

Plant #10

TC4-BIO-10B

14.6

11.1

27

Lead

Biota

Plant #10

TC4-BIO-10C

448

599

29

Lead

Biota

Plant #10

TC4-BIO-10D

307

244

23

Lead

Biota

Plant #20

TC4-BIO-20A

2.3

2.2

4

Lead

Biota

Plant #20

TC4-BIO-20B

9.8

2.7

114

Lead

Biota

Plant #20

TC4-BIO-20C

566

661

15

Lead

Biota

Plant #20

TC4-BIO-20D

322

547

52

Lead

Biota

Plant #30

TC4-BIO-30A

10.9

11.8

8

Lead

Biota

Plant #30

TC4-BIO-30B

9.9

6.5

41

Lead

Biota

Plant #30

TC4-BIO-30C

211

453

73

Lead

Biota

Plant #30

TC4-BIO-30D

205

242

17

Lead

Biota

Plant #40

TC4-BIO-40A

42.1

53.5

24

Lead

Biota

Plant #40

TC4-BIO-40B

39.6

37.8

5

Lead

Biota

Plant #40

TC4-BIO-40C

596

690

15

Lead

Biota

Plant #40

TC4-BIO-40D

203

254

22

Lead

Biota

Plant #50

TC4-BIO-50C

550

352

44

Lead

Biota

Plant #50

TC4-BIO-50D

211

122

53

Lead

Biota

Plant #56

TC4-BIO-56A

159

29.2

138

Lead

Biota

Plant #56

TC4-BIO-56B

26.8

27.3

2

Lead

Biota

Plant #56

TC4-BIO-56C

113

162

36

Lead

Biota

Plant #56

TC4-BIO-56D

158

92.1

53

Magnesium

Residential Yard Soil

Residential Location #14

TC4-RS-14A

532

566

6

Magnesium

Residential Yard Soil

Residential Location #8

TC4-RS-08B

395

419

6

Magnesium

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

915

731

22

Magnesium

Biota Associated Soil

Plant #10

TC4-BIO-10E

810

848

5

Magnesium

Biota Associated Soil

Plant #20

TC4-BIO-20E

1140

2640

79

Magnesium

Biota Associated Soil

Plant #30

TC4-BIO-30E

2630

2080

23

Magnesium

Biota Associated Soil

Plant #40

TC4-BIO-40E

2150

3280

42

Magnesium

Biota Associated Soil

Plant #50

TC4-BIO-50E

2010

3120

43

Magnesium

Biota Associated Soil

Plant #56

TC4-BIO-56E

1320

1220

8

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 10 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008467


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Magnesium

Chat Base

Gordon

TC4-SO-16G

10100

9910

2

Magnesium

Chat Base

Pioneer

TC4-SO-04H

3470

3760

8

Magnesium

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

11700

11700

0

Magnesium

Chat Pile

Bird Dog

TC4-SO-01B

5080

5070

0

Magnesium

Chat Pile

Pioneer

TC4-SO-04C

8030

8370

4

Magnesium

Fine Tailings

Bird Dog

TC4-SO-01H

5150

4920

5

Magnesium

Fine Tailings

Bird Dog

TC4-SO-01N

4330

5340

21

Magnesium

Fine Tailings

Pioneer

TC4-SO-04M

2470

2290

8

Magnesium

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

584

617

5

Magnesium

Tailing Ponds

Gordon

TC4-SO-16K

8.24





Magnesium

Tailing Ponds

Gordon

TC4-SO-16K

8.4





Magnesium

Tailing Ponds

Lawyers

TC4-SO-33S

15.8





Magnesium

Tailing Ponds

Lawyers

TC4-SO-33S

16.4





Magnesium

Tailing Ponds

Woodchuck

TC4-SO-41A

10.3





Magnesium

Tailing Ponds

Woodchuck

TC4-SO-41A

10.4





Magnesium

Biota

Plant #10

TC4-BIO-10A

1970

2130

8

Magnesium

Biota

Plant #10

TC4-BIO-10B

1380

1260

9

Magnesium

Biota

Plant #10

TC4-BIO-10C

709

902

24

Magnesium

Biota

Plant #10

TC4-BIO-10D

584

534

9

Magnesium

Biota

Plant #20

TC4-BIO-20A

1510

1380

9

Magnesium

Biota

Plant #20

TC4-BIO-20B

3020

1410

73

Magnesium

Biota

Plant #20

TC4-BIO-20C

1060

1260

17

Magnesium

Biota

Plant #20

TC4-BIO-20D

1120

1200

7

Magnesium

Biota

Plant #30

TC4-BIO-30A

1690

1530

10

Magnesium

Biota

Plant #30

TC4-BIO-30B

1950

1940

1

Magnesium

Biota

Plant #30

TC4-BIO-30C

667

1240

60

Magnesium

Biota

Plant #30

TC4-BIO-30D

332

746

77

Magnesium

Biota

Plant #40

TC4-BIO-40A

1490

1630

9

Magnesium

Biota

Plant #40

TC4-BIO-40B

1650

1520

8

Magnesium

Biota

Plant #40

TC4-BIO-40C

2090

1770

17

Magnesium

Biota

Plant #40

TC4-BIO-40D

1010

1220

19

Magnesium

Biota

Plant #50

TC4-BIO-50A

1970

1910

3

Magnesium

Biota

Plant #50

TC4-BIO-50B

1960

1810

8

Magnesium

Biota

Plant #50

TC4-BIO-50C

1700

1300

27

Magnesium

Biota

Plant #50

TC4-BIO-50D

1080

1140

5

Magnesium

Biota

Plant #56

TC4-BIO-56A

1510

1550

3

Magnesium

Biota

Plant #56

TC4-BIO-56B

1400

1230

13

Magnesium

Biota

Plant #56

TC4-BIO-56C

216

234.5

ND

Magnesium

Biota

Plant #56

TC4-BIO-56D

202.5

183.5

ND

Manganese

Residential Yard Soil

Residential Location #14

TC4-RS-14A

445

450

1

Manganese

Residential Yard Soil

Residential Location #8

TC4-RS-08B

387

387

0

Manganese

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

470

447

5

Manganese

Biota Associated Soil

Plant #10

TC4-BIO-10E

53.6

38.5

33

Manganese

Biota Associated Soil

Plant #20

TC4-BIO-20E

303

417

32

Manganese

Biota Associated Soil

Plant #30

TC4-BIO-30E

135

93.6

36

Manganese

Biota Associated Soil

Plant #40

TC4-BIO-40E

275

295

7

Manganese

Biota Associated Soil

Plant #50

TC4-BIO-50E

28.1

50.7

57

Manganese

Biota Associated Soil

Plant #56

TC4-BIO-56E

115

128

11

Manganese

Chat Base

Gordon

TC4-SO-16G

148

151

2

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 11 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008468


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Manganese

Chat Base

Pioneer

TC4-SO-04H

128

84.3

41

Manganese

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

167

165

1

Manganese

Chat Pile

Bird Dog

TC4-SO-01B

152

151

1

Manganese

Chat Pile

Pioneer

TC4-SO-04C

107

108

1

Manganese

Fine Tailings

Bird Dog

TC4-SO-01H

149

143

4

Manganese

Fine Tailings

Bird Dog

TC4-SO-01N

150

158

5

Manganese

Fine Tailings

Pioneer

TC4-SO-04M

99.6

114

13

Manganese

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

368

366

1

Manganese

Biota

Plant #10

TC4-BIO-10A

41.8

43.7

4

Manganese

Biota

Plant #10

TC4-BIO-10B

26.4

20.8

24

Manganese

Biota

Plant #10

TC4-BIO-10C

23.9

96.4

121

Manganese

Biota

Plant #10

TC4-BIO-10D

35.7

32.8

8

Manganese

Biota

Plant #20

TC4-BIO-20A

28.9

24.6

16

Manganese

Biota

Plant #20

TC4-BIO-20B

72

27.7

89

Manganese

Biota

Plant #20

TC4-BIO-20C

147

106

32

Manganese

Biota

Plant #20

TC4-BIO-20D

125

123

2

Manganese

Biota

Plant #30

TC4-BIO-30A

75.8

72.7

4

Manganese

Biota

Plant #30

TC4-BIO-30B

105

73.1

36

Manganese

Biota

Plant #30

TC4-BIO-30C

33.2

69.2

70

Manganese

Biota

Plant #30

TC4-BIO-30D

14.9

61.1

122

Manganese

Biota

Plant #40

TC4-BIO-40A

85.1

104

20

Manganese

Biota

Plant #40

TC4-BIO-40B

79.8

74.7

7

Manganese

Biota

Plant #40

TC4-BIO-40C

180

157

14

Manganese

Biota

Plant #40

TC4-BIO-40D

67.3

92.1

31

Manganese

Biota

Plant #50

TC4-BIO-50A

246

260

6

Manganese

Biota

Plant #50

TC4-BIO-50B

326

271

18

Manganese

Biota

Plant #50

TC4-BIO-50C

159

166

4

Manganese

Biota

Plant #50

TC4-BIO-50D

162

153

6

Manganese

Biota

Plant #56

TC4-BIO-56A

319

107

100

Manganese

Biota

Plant #56

TC4-BIO-56B

124

116

7

Manganese

Biota

Plant #56

TC4-BIO-56C

16.4

19.8

19

Manganese

Biota

Plant #56

TC4-BIO-56D

16.8

12.2

32

Mercury

Residential Yard Soil

Residential Location #8

TC4-RS-08B

0.05

0.05

ND

Mercury

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

0.17

0.27

45

Mercury

Biota Associated Soil

Plant #10

TC4-BIO-10E

0.26

0.21

21

Mercury

Biota Associated Soil

Plant #20

TC4-BIO-20E

0.065

0.15

79

Mercury

Biota Associated Soil

Plant #30

TC4-BIO-30E

0.016

0.047

98

Mercury

Biota Associated Soil

Plant #40

TC4-BIO-40E

0.44

0.47

7

Mercury

Biota Associated Soil

Plant #50

TC4-BIO-50E

0.012

0.06

ND

Mercury

Biota Associated Soil

Plant #56

TC4-BIO-56E

0.044

0.05

ND

Mercury

Chat Base

Gordon

TC4-SO-16G

0.18

0.19

5

Mercury

Chat Base

Pioneer

TC4-SO-04H

0.4

0.2

67

Mercury

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

0.16

0.2

22

Mercury

Chat Pile

Bird Dog

TC4-SO-01B

0.16

0.18

12

Mercury

Chat Pile

Pioneer

TC4-SO-04C

0.4

0.33

19

Mercury

Fine Tailings

Bird Dog

TC4-SO-01H

0.47

0.51

8

Mercury

Fine Tailings

Bird Dog

TC4-SO-01N

0.19

0.27

35

Mercury

Fine Tailings

Pioneer

TC4-SO-04M

0.73

0.58

23

Mercury

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

0.005

0.005

ND

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 12 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008469


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Mercury

Biota

Plant #10

TC4-BIO-10A

0.05

0.05

ND

Mercury

Biota

Plant #10

TC4-BIO-10B

0.05

0.05

ND

Mercury

Biota

Plant #10

TC4-BIO-10C

0.015

0.05

108

Mercury

Biota

Plant #10

TC4-BIO-10D

0.05

0.05

ND

Mercury

Biota

Plant #20

TC4-BIO-20A

0.05

0.05

ND

Mercury

Biota

Plant #20

TC4-BIO-20B

0.05

0.05

ND

Mercury

Biota

Plant #20

TC4-BIO-20C

0.0225

0.045

ND

Mercury

Biota

Plant #20

TC4-BIO-20D

0.01

0.0275

ND

Mercury

Biota

Plant #30

TC4-BIO-30A

0.05

0.05

ND

Mercury

Biota

Plant #30

TC4-BIO-30B

0.05

0.05

ND

Mercury

Biota

Plant #30

TC4-BIO-30C

0.05

0.05

ND

Mercury

Biota

Plant #30

TC4-BIO-30D

0.05

0.05

ND

Mercury

Biota

Plant #40

TC4-BIO-40C

0.05

0.06

18

Mercury

Biota

Plant #50

TC4-BIO-50A

0.0075

0.01

ND

Mercury

Biota

Plant #50

TC4-BIO-50B

0.0075

0.0075

ND

Mercury

Biota

Plant #50

TC4-BIO-50C

0.03

0.0175

ND

Mercury

Biota

Plant #50

TC4-BIO-50D

0.0125

0.015

ND

Mercury

Biota

Plant #56

TC4-BIO-56A

0.0375

0.0125

ND

Mercury

Biota

Plant #56

TC4-BIO-56B

0.0125

0.0125

ND

Mercury

Biota

Plant #56

TC4-BIO-56C

0.015

0.0125

ND

Mercury

Biota

Plant #56

TC4-BIO-56D

0.0075

0.0175

ND

Nickel

Residential Yard Soil

Residential Location #14

TC4-RS-14A

5.6

5.7

2

Nickel

Residential Yard Soil

Residential Location #8

TC4-RS-08B

6.1

6.3

3

Nickel

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

13.5

14.7

9

Nickel

Biota Associated Soil

Plant #10

TC4-BIO-10E

5.1

6.4

23

Nickel

Biota Associated Soil

Plant #20

TC4-BIO-20E

8.3

14.1

52

Nickel

Biota Associated Soil

Plant #30

TC4-BIO-30E

5.1

4.8

6

Nickel

Biota Associated Soil

Plant #40

TC4-BIO-40E

11.4

11.6

2

Nickel

Biota Associated Soil

Plant #50

TC4-BIO-50E

2.9

4.3

39

Nickel

Biota Associated Soil

Plant #56

TC4-BIO-56E

4.2

4.4

5

Nickel

Chat Base

Gordon

TC4-SO-16G

12.1

14.5

18

Nickel

Chat Base

Pioneer

TC4-SO-04H

6

9.3

43

Nickel

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

13.9

13.3

4

Nickel

Chat Pile

Bird Dog

TC4-SO-01B

15.2

15.3

1

Nickel

Chat Pile

Pioneer

TC4-SO-04C

11.6

11.3

3

Nickel

Fine Tailings

Bird Dog

TC4-SO-01H

19.1

18.9

1

Nickel

Fine Tailings

Bird Dog

TC4-SO-01N

36.6

33.6

9

Nickel

Fine Tailings

Pioneer

TC4-SO-04M

22.4

22.9

2

Nickel

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

7

6.8

3

Nickel

Biota

Plant #10

TC4-BIO-10A

0.12

0.125

ND

Nickel

Biota

Plant #10

TC4-BIO-10B

0.15

0.21

ND

Nickel

Biota

Plant #10

TC4-BIO-10C

1.3

1.5

ND

Nickel

Biota

Plant #10

TC4-BIO-10D

1

0.75

ND

Nickel

Biota

Plant #20

TC4-BIO-20A

0.11

0.175

ND

Nickel

Biota

Plant #20

TC4-BIO-20B

0.225

0.12

ND

Nickel

Biota

Plant #20

TC4-BIO-20C

4.8

4.9

2

Nickel

Biota

Plant #30

TC4-BIO-30A

0.225

0.22

ND

Nickel

Biota

Plant #30

TC4-BIO-30B

0.255

0.245

ND

Nickel

Biota

Plant #30

TC4-BIO-30C

0.75

1.35

ND

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 13 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008470


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Nickel

Biota

Plant #30

TC4-BIO-30D

0.95

0.85

ND

Nickel

Biota

Plant #40

TC4-BIO-40A

0.4

0.465

ND

Nickel

Biota

Plant #40

TC4-BIO-40B

0.365

0.37

ND

Nickel

Biota

Plant #40

TC4-BIO-40C

6.7

7.5

11

Nickel

Biota

Plant #40

TC4-BIO-40D

1.05

1.3

ND

Nickel

Biota

Plant #50

TC4-BIO-50A

0.96

1

4

Nickel

Biota

Plant #50

TC4-BIO-50B

0.89

0.8

11

Nickel

Biota

Plant #50

TC4-BIO-50C

5

3.5

35

Nickel

Biota

Plant #50

TC4-BIO-50D

2.4

1.7

34

Nickel

Biota

Plant #56

TC4-BIO-56A

9.4

0.58

177

Nickel

Biota

Plant #56

TC4-BIO-56B

0.51

0.54

6

Nickel

Biota

Plant #56

TC4-BIO-56C

0.86

1.4

48

Nickel

Biota

Plant #56

TC4-BIO-56D

0.99

0.79

22

Potassium

Residential Yard Soil

Residential Location #14

TC4-RS-14A

655

673

3

Potassium

Residential Yard Soil

Residential Location #8

TC4-RS-08B

321

344

7

Potassium

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

251

248.5

ND

Potassium

Biota Associated Soil

Plant #10

TC4-BIO-10E

79.5

82.5

ND

Potassium

Biota Associated Soil

Plant #20

TC4-BIO-20E

206.5

176

ND

Potassium

Biota Associated Soil

Plant #30

TC4-BIO-30E

135

101

ND

Potassium

Biota Associated Soil

Plant #40

TC4-BIO-40E

175

186

ND

Potassium

Biota Associated Soil

Plant #50

TC4-BIO-50E

65

100

ND

Potassium

Biota Associated Soil

Plant #56

TC4-BIO-56E

98.5

114.5

ND

Potassium

Chat Base

Gordon

TC4-SO-16G

250.5

250.5

ND

Potassium

Chat Base

Pioneer

TC4-SO-04H

250.5

250.5

ND

Potassium

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

250

250.5

ND

Potassium

Chat Pile

Bird Dog

TC4-SO-01B

250

251

ND

Potassium

Chat Pile

Pioneer

TC4-SO-04C

251.5

251

ND

Potassium

Fine Tailings

Bird Dog

TC4-SO-01H

239.5

237

ND

Potassium

Fine Tailings

Bird Dog

TC4-SO-01N

1560

1370

13

Potassium

Fine Tailings

Pioneer

TC4-SO-04M

704

699

1

Potassium

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

219

227.5

ND

Potassium

Biota

Plant #10

TC4-BIO-10A

4990

6090

20

Potassium

Biota

Plant #10

TC4-BIO-10B

6670

9960

40

Potassium

Biota

Plant #10

TC4-BIO-10C

6410

7300

13

Potassium

Biota

Plant #10

TC4-BIO-10D

7830

8060

3

Potassium

Biota

Plant #20

TC4-BIO-20A

14000

14000

0

Potassium

Biota

Plant #20

TC4-BIO-20B

13000

14000

7

Potassium

Biota

Plant #20

TC4-BIO-20C

4030

4370

8

Potassium

Biota

Plant #20

TC4-BIO-20D

5940

5230

13

Potassium

Biota

Plant #30

TC4-BIO-30A

19900

20300

2

Potassium

Biota

Plant #30

TC4-BIO-30B

22200

22500

1

Potassium

Biota

Plant #30

TC4-BIO-30C

11200

8640

26

Potassium

Biota

Plant #30

TC4-BIO-30D

10800

10800

0

Potassium

Biota

Plant #40

TC4-BIO-40A

19300

19800

3

Potassium

Biota

Plant #40

TC4-BIO-40B

20900

20400

2

Potassium

Biota

Plant #40

TC4-BIO-40C

6980

7420

6

Potassium

Biota

Plant #40

TC4-BIO-40D

8670

10200

16

Potassium

Biota

Plant #50

TC4-BIO-50A

8250

8490

3

Potassium

Biota

Plant #50

TC4-BIO-50B

8910

8390

6

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 14 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008471


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Potassium

Biota

Plant #50

TC4-BIO-50C

2360

3250

32

Potassium

Biota

Plant #50

TC4-BIO-50D

3420

3480

2

Potassium

Biota

Plant #56

TC4-BIO-56A

1560

16500

165

Potassium

Biota

Plant #56

TC4-BIO-56B

17700

17400

2

Potassium

Biota

Plant #56

TC4-BIO-56C

10600

8700

20

Potassium

Biota

Plant #56

TC4-BIO-56D

9780

9370

4

Selenium

Residential Yard Soil

Residential Location #14

TC4-RS-14A

0.37

0.57

43

Selenium

Residential Yard Soil

Residential Location #8

TC4-RS-08B

0.58

0.52

11

Selenium

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

7

7.6

8

Selenium

Biota Associated Soil

Plant #20

TC4-BIO-20E

0.95

0.68

33

Selenium

Biota Associated Soil

Plant #30

TC4-BIO-30E

0.14

0.14

ND

Selenium

Biota Associated Soil

Plant #40

TC4-BIO-40E

0.75

0.56

29

Selenium

Biota Associated Soil

Plant #50

TC4-BIO-50E

0.16

0.14

ND

Selenium

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

1.75

1.75

ND

Selenium

Chat Pile

Bird Dog

TC4-SO-01B

1.75

1.75

ND

Selenium

Chat Pile

Pioneer

TC4-SO-04C

1.6

1.6

0

Selenium

Fine Tailings

Bird Dog

TC4-SO-01H

2.6

2.3

12

Selenium

Fine Tailings

Bird Dog

TC4-SO-01N

2.3

2.3

ND

Selenium

Fine Tailings

Pioneer

TC4-SO-04M

1.5

1.7

13

Selenium

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

0.71

0.97

31

Selenium

Biota

Plant #10

TC4-BIO-10A

1.1

1.2

9

Selenium

Biota

Plant #10

TC4-BIO-10B

1

0.98

2

Selenium

Biota

Plant #10

TC4-BIO-10C

1.2

0.67

57

Selenium

Biota

Plant #10

TC4-BIO-10D

0.82

0.64

25

Selenium

Biota

Plant #20

TC4-BIO-20A

0.7

0.7

ND

Selenium

Biota

Plant #20

TC4-BIO-20B

0.7

0.65

ND

Selenium

Biota

Plant #20

TC4-BIO-20C

0.45

0.445

ND

Selenium

Biota

Plant #20

TC4-BIO-20D

0.48

0.47

ND

Selenium

Biota

Plant #30

TC4-BIO-30A

0.96

1.6

50

Selenium

Biota

Plant #30

TC4-BIO-30B

1

1.2

18

Selenium

Biota

Plant #30

TC4-BIO-30C

1

0.67

40

Selenium

Biota

Plant #30

TC4-BIO-30D

1.1

0.86

24

Selenium

Biota

Plant #40

TC4-BIO-40A

1

1.3

26

Selenium

Biota

Plant #40

TC4-BIO-40B

1.3

1.3

0

Selenium

Biota

Plant #40

TC4-BIO-40C

0.6

0.82

31

Selenium

Biota

Plant #40

TC4-BIO-40D

0.85

0.91

7

Selenium

Biota

Plant #50

TC4-BIO-50A

0.75

0.65

ND

Selenium

Biota

Plant #50

TC4-BIO-50B

0.7

0.48

ND

Selenium

Biota

Plant #50

TC4-BIO-50C

0.75

0.65

ND

Selenium

Biota

Plant #50

TC4-BIO-50D

0.75

0.65

ND

Selenium

Biota

Plant #56

TC4-BIO-56A

0.81

1.3

46

Selenium

Biota

Plant #56

TC4-BIO-56B

1.4

1.5

7

Selenium

Biota

Plant #56

TC4-BIO-56C

1.1

1.1

0

Selenium

Biota

Plant #56

TC4-BIO-56D

1.2

0.95

23

Sodium

Residential Yard Soil

Residential Location #14

TC4-RS-14A

1380

1520

10

Sodium

Residential Yard Soil

Residential Location #8

TC4-RS-08B

309

334

8

Sodium

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

11400

11300

1

Sodium

Biota Associated Soil

Plant #10

TC4-BIO-10E

15300

14600

5

Sodium

Biota Associated Soil

Plant #20

TC4-BIO-20E

8910

18600

70

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 15 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008472


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma











Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Sod

um

Biota Associated Soil

Plant #30

TC4-BIO-30E

15800

18500

16

Sod

um

Biota Associated Soil

Plant #40

TC4-BIO-40E

33800

36400

7

Sod

um

Biota Associated Soil

Plant #50

TC4-BIO-50E

37200

27800

29

Sod

um

Biota Associated Soil

Plant #56

TC4-BIO-56E

12200

9670

23

Sod

um

Chat Base

Gordon

TC4-SO-16G

43000

51100

17

Sod

um

Chat Base

Pioneer

TC4-SO-04H

250.5

250.5

ND

Sod

um

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

34000

33200

2

Sod

um

Chat Pile

Bird Dog

TC4-SO-01B

250

251

ND

Sod

um

Chat Pile

Pioneer

TC4-SO-04C

251.5

251

ND

Sod

um

Fine Tailings

Bird Dog

TC4-SO-01H

68900

67700

2

Sod

um

Fine Tailings

Bird Dog

TC4-SO-01N

330.5

326.5

ND

Sod

um

Fine Tailings

Pioneer

TC4-SO-04M

43900

42100

4

Sod

um

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

1480

1500

1

Sod

um

Biota

Plant #10

TC4-BIO-10A

706

713

1

Sod

um

Biota

Plant #10

TC4-BIO-10B

698

686

2

Sod

um

Biota

Plant #10

TC4-BIO-10C

5520

7900

35

Sod

um

Biota

Plant #10

TC4-BIO-10D

4160

3710

11

Sod

um

Biota

Plant #20

TC4-BIO-20A

174

172.5

ND

Sod

um

Biota

Plant #20

TC4-BIO-20C

9070

10800

17

Sod

um

Biota

Plant #20

TC4-BIO-20D

5240

8220

44

Sod

um

Biota

Plant #30

TC4-BIO-30A

762

744

2

Sod

um

Biota

Plant #30

TC4-BIO-30B

825

682

19

Sod

um

Biota

Plant #30

TC4-BIO-30C

3320

6280

62

Sod

um

Biota

Plant #30

TC4-BIO-30D

3720

3440

8

Sod

um

Biota

Plant #40

TC4-BIO-40A

1320

1620

20

Sod

um

Biota

Plant #40

TC4-BIO-40B

1230

1210

2

Sod

um

Biota

Plant #40

TC4-BIO-40C

23500

24600

5

Sod

um

Biota

Plant #40

TC4-BIO-40D

7910

10100

24

Sod

um

Biota

Plant #50

TC4-BIO-50A

47.9

42.6

ND

Sod

um

Biota

Plant #50

TC4-BIO-50B

17.15

17.45

ND

Sod

um

Biota

Plant #50

TC4-BIO-50C

250

250

ND

Sod

um

Biota

Plant #50

TC4-BIO-50D

250

250

ND

Sod

um

Biota

Plant #56

TC4-BIO-56B

49.65

42.75

ND

Sod

um

Biota

Plant #56

TC4-BIO-56C

87.5

42.75

ND

Sod

um

Biota

Plant #56

TC4-BIO-56D

61

65

ND

Silver

Residential Yard Soil

Residential Location #14

TC4-RS-14A

0.3

0.305

ND

Silver

Residential Yard Soil

Residential Location #8

TC4-RS-08B

0.305

0.305

ND

Silver

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

0.41

0.41

0

Silver

Biota Associated Soil

Plant #20

TC4-BIO-20E

0.1

0.11

ND

Silver

Biota Associated Soil

Plant #30

TC4-BIO-30E

0.09

0.09

ND

Silver

Biota Associated Soil

Plant #40

TC4-BIO-40E

0.28

0.27

4

Silver

Biota Associated Soil

Plant #50

TC4-BIO-50E

0.1

0.085

ND

Silver

Biota Associated Soil

Plant #56

TC4-BIO-56E

0.09

0.085

ND

Silver

Chat Base

Gordon

TC4-SO-16G

0.5

0.5

ND

Silver

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

0.5

0.5

ND

Silver

Chat Pile

Bird Dog

TC4-SO-01B

1.4

1.4

0

Silver

Fine Tailings

Bird Dog

TC4-SO-01H

0.085

0.085

ND

Silver

Fine Tailings

Bird Dog

TC4-SO-01N

3.3

3.2

3

Silver

Fine Tailings

Pioneer

TC4-SO-04M

0.085

0.085

ND

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 16 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008473


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Silver

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

0.085

0.085

ND

Silver

Biota

Plant #10

TC4-BIO-10A

0.25

0.5

ND

Silver

Biota

Plant #10

TC4-BIO-10B

0.25

0.095

ND

Silver

Biota

Plant #10

TC4-BIO-10C

0.5

0.5

ND

Silver

Biota

Plant #10

TC4-BIO-10D

0.11

0.5

ND

Silver

Biota

Plant #20

TC4-BIO-20B

0.11

0.5

ND

Silver

Biota

Plant #20

TC4-BIO-20C

0.5

0.5

ND

Silver

Biota

Plant #20

TC4-BIO-20D

0.5

0.5

ND

Silver

Biota

Plant #30

TC4-BIO-30A

0.5

0.5

ND

Silver

Biota

Plant #30

TC4-BIO-30B

0.24

0.18

29

Silver

Biota

Plant #30

TC4-BIO-30C

0.19

0.21

10

Silver

Biota

Plant #30

TC4-BIO-30D

0.5

0.5

ND

Silver

Biota

Plant #40

TC4-BIO-40A

0.11

0.5

ND

Silver

Biota

Plant #40

TC4-BIO-40D

0.5

0.5

ND

Silver

Biota

Plant #50

TC4-BIO-50A

0.3

0.27

11

Silver

Biota

Plant #50

TC4-BIO-50B

0.5

0.5

ND

Silver

Biota

Plant #50

TC4-BIO-50C

0.39

0.23

52

Silver

Biota

Plant #50

TC4-BIO-50D

0.043

0.066

42

Silver

Biota

Plant #56

TC4-BIO-56B

0.105

0.08

ND

Silver

Biota

Plant #56

TC4-BIO-56C

0.085

0.1

ND

Silver

Biota

Plant #56

TC4-BIO-56D

0.085

0.075

ND

Thallium

Residential Yard Soil

Residential Location #14

TC4-RS-14A

0.77

0.77

0

Thallium

Residential Yard Soil

Residential Location #8

TC4-RS-08B

0.53

0.45

16

Thallium

Biota Associated Soil

Plant #10

TC4-BIO-10E

0.19

0.19

ND

Thallium

Biota Associated Soil

Plant #20

TC4-BIO-20E

0.215

0.235

ND

Thallium

Biota Associated Soil

Plant #30

TC4-BIO-30E

0.185

0.19

ND

Thallium

Biota Associated Soil

Plant #40

TC4-BIO-40E

0.195

0.195

ND

Thallium

Biota Associated Soil

Plant #50

TC4-BIO-50E

0.215

0.185

ND

Thallium

Biota Associated Soil

Plant #56

TC4-BIO-56E

0.185

0.185

ND

Thallium

Chat Base

Gordon

TC4-SO-16G

1.25

1.25

ND

Thallium

Chat Base

Pioneer

TC4-SO-04H

1.25

1.25

ND

Thallium

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

1.25

1.25

ND

Thallium

Chat Pile

Bird Dog

TC4-SO-01B

1.25

1.25

ND

Thallium

Chat Pile

Pioneer

TC4-SO-04C

1.25

1.25

ND

Thallium

Fine Tailings

Bird Dog

TC4-SO-01H

0.18

0.18

ND

Thallium

Fine Tailings

Bird Dog

TC4-SO-01N

1.65

1.65

ND

Thallium

Fine Tailings

Pioneer

TC4-SO-04M

0.18

0.18

ND

Thallium

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

0.185

0.185

ND

Thallium

Biota

Plant #10

TC4-BIO-10A

0.65

1.25

ND

Thallium

Biota

Plant #10

TC4-BIO-10B

0.65

1.25

ND

Thallium

Biota

Plant #10

TC4-BIO-10C

1.25

1.25

ND

Thallium

Biota

Plant #10

TC4-BIO-10D

1.25

1.25

ND

Thallium

Biota

Plant #20

TC4-BIO-20A

1.25

1.25

ND

Thallium

Biota

Plant #20

TC4-BIO-20B

1.25

1.25

ND

Thallium

Biota

Plant #20

TC4-BIO-20C

1.25

1.25

ND

Thallium

Biota

Plant #20

TC4-BIO-20D

1.25

1.25

ND

Thallium

Biota

Plant #30

TC4-BIO-30A

1.25

1.25

ND

Thallium

Biota

Plant #30

TC4-BIO-30B

1.25

1.25

ND

Thallium

Biota

Plant #30

TC4-BIO-30C

1.25

1.25

ND

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 17 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008474


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma









Normal

FD

RPD,

Parameter

Media Grouping

Location F2L

Station ID

Result

Result

%

Thallium

Biota

Plant #30

TC4-BIO-30D

1.25

1.25

ND

Thallium

Biota

Plant #40

TC4-BIO-40A

1.25

1.25

ND

Thallium

Biota

Plant #40

TC4-BIO-40B

1.25

1.25

ND

Thallium

Biota

Plant #40

TC4-BIO-40C

1.25

1.25

ND

Thallium

Biota

Plant #40

TC4-BIO-40D

1.25

1.25

ND

Thallium

Biota

Plant #50

TC4-BIO-50A

1.25

1.25

ND

Thallium

Biota

Plant #50

TC4-BIO-50B

1.25

1.25

ND

Thallium

Biota

Plant #50

TC4-BIO-50C

1.25

1.25

ND

Thallium

Biota

Plant #50

TC4-BIO-50D

1.25

1.25

ND

Thallium

Biota

Plant #56

TC4-BIO-56A

1.25

1.25

ND

Thallium

Biota

Plant #56

TC4-BIO-56B

1.25

1.25

ND

Thallium

Biota

Plant #56

TC4-BIO-56C

1.25

1.25

ND

Thallium

Biota

Plant #56

TC4-BIO-56D

1.25

1.25

ND

Vanadium

Residential Yard Soil

Residential Location #14

TC4-RS-14A

14.1

14.5

3

Vanadium

Residential Yard Soil

Residential Location #8

TC4-RS-08B

14.6

14.9

2

Vanadium

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

17.2

13.4

25

Vanadium

Biota Associated Soil

Plant #10

TC4-BIO-10E

3.3

3

10

Vanadium

Biota Associated Soil

Plant #20

TC4-BIO-20E

16.2

20.4

23

Vanadium

Biota Associated Soil

Plant #30

TC4-BIO-30E

2.2

1.9

15

Vanadium

Biota Associated Soil

Plant #40

TC4-BIO-40E

10.1

10.2

1

Vanadium

Biota Associated Soil

Plant #50

TC4-BIO-50E

2

2.9

37

Vanadium

Biota Associated Soil

Plant #56

TC4-BIO-56E

6.6

6.2

6

Vanadium

Chat Base

Gordon

TC4-SO-16G

4.9

5.3

8

Vanadium

Chat Base

Pioneer

TC4-SO-04H

4.7

3.5

29

Vanadium

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

6

6.1

2

Vanadium

Chat Pile

Bird Dog

TC4-SO-01B

2.5

2.5

ND

Vanadium

Chat Pile

Pioneer

TC4-SO-04C

4.3

4.5

5

Vanadium

Fine Tailings

Bird Dog

TC4-SO-01H

6.7

5.7

16

Vanadium

Fine Tailings

Bird Dog

TC4-SO-01N

14.7

13.8

6

Vanadium

Fine Tailings

Pioneer

TC4-SO-04M

5.3

5.3

0

Vanadium

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

14.6

15.1

3

Vanadium

Biota

Plant #10

TC4-BIO-10C

0.455

0.55

ND

Vanadium

Biota

Plant #10

TC4-BIO-10D

0.275

0.225

ND

Vanadium

Biota

Plant #20

TC4-BIO-20A

0.12

0.17

34

Vanadium

Biota

Plant #20

TC4-BIO-20C

7.8

6

26

Vanadium

Biota

Plant #20

TC4-BIO-20D

6.6

8

19

Vanadium

Biota

Plant #30

TC4-BIO-30A

0.12

0.099

19

Vanadium

Biota

Plant #30

TC4-BIO-30B

0.15

0.14

7

Vanadium

Biota

Plant #30

TC4-BIO-30C

0.47

0.86

59

Vanadium

Biota

Plant #30

TC4-BIO-30D

0.27

0.47

54

Vanadium

Biota

Plant #40

TC4-BIO-40A

1.3

1.7

27

Vanadium

Biota

Plant #40

TC4-BIO-40B

1.2

1.1

9

Vanadium

Biota

Plant #40

TC4-BIO-40C

5.9

6.2

5

Vanadium

Biota

Plant #50

TC4-BIO-50A

0.3

0.25

18

Vanadium

Biota

Plant #50

TC4-BIO-50B

2.5

2.5

ND

Vanadium

Biota

Plant #50

TC4-BIO-50C

2.9

1.8

47

Vanadium

Biota

Plant #50

TC4-BIO-50D

0.66

0.58

13

Vanadium

Biota

Plant #56

TC4-BIO-56A

15.9

0.59

186

Vanadium

Biota

Plant #56

TC4-BIO-56B

0.53

0.54

2

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028V\PPENDICIES\	PAGE 18 OF 19	OCTOBER 2005

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008475


-------
Table A-9

Field Duplicate Comparisons for CH2M HILL Tar Creek OU4 Data
Tar Creek Superfund Site
Ottawa County, Oklahoma

Parameter

Media Grouping

Location F2L

Station ID

Normal
Result

FD
Result

RPD,

%

Vanadium

Biota

Plant #56

TC4-BIO-56C

0.78

1.1

34

Vanadium

Biota

Plant #56

TC4-BIO-56D

0.87

0.59

38

Z

nc

Residential Yard Soil

Residential Location #14

TC4-RS-14A

525

585

11

Z

nc

Residential Yard Soil

Residential Location #8

TC4-RS-08B

87.2

91.2

4

z

nc

Smelter- Affected Soil

South Smelter Transect

TC4-SO-46K

4230

4160

2

z

nc

Biota Associated Soil

Plant #10

TC4-BIO-10E

6460

6090

6

z

nc

Biota Associated Soil

Plant #20

TC4-BIO-20E

3950

7740

65

z

nc

Biota Associated Soil

Plant #30

TC4-BIO-30E

6180

7110

14

z

nc

Biota Associated Soil

Plant #40

TC4-BIO-40E

15300

16600

8

z

nc

Biota Associated Soil

Plant #50

TC4-BIO-50E

16500

9830

51

z

nc

Biota Associated Soil

Plant #56

TC4-BIO-56E

4970

4010

21

z

nc

Chat Base

Gordon

TC4-SO-16G

20400

23400

14

z

nc

Chat Base

Pioneer

TC4-SO-04H

13400

16100

18

z

nc

Chat Pile

Atlas (Tulsa)

TC4-SO-31D

16500

16300

1

z

nc

Chat Pile

Bird Dog

TC4-SO-01B

20900

21500

3

z

nc

Chat Pile

Pioneer

TC4-SO-04C

27700

27100

2

z

nc

Fine Tailings

Bird Dog

TC4-SO-01H

35100

31400

11

z

nc

Fine Tailings

Bird Dog

TC4-SO-01N

11000

14000

24

z

nc

Fine Tailings

Pioneer

TC4-SO-04M

21200

24100

13

z

nc

Transition Zone Soil

Adams-Mudd (Barret)

TC4-SO-02U

639

645

1

z

nc

Biota

Plant #10

TC4-BIO-10A

304

321

5

z

nc

Biota

Plant #10

TC4-BIO-10B

271

257

5

z

nc

Biota

Plant #10

TC4-BIO-10C

2370

3530

39

z

nc

Biota

Plant #10

TC4-BIO-10D

1670

1360

20

z

nc

Biota

Plant #20

TC4-BIO-20A

131

147

12

z

nc

Biota

Plant #20

TC4-BIO-20B

255

171

39

z

nc

Biota

Plant #20

TC4-BIO-20C

3920

4610

16

z

nc

Biota

Plant #20

TC4-BIO-20D

2320

3600

43

z

nc

Biota

Plant #30

TC4-BIO-30A

326

325

0

z

nc

Biota

Plant #30

TC4-BIO-30B

355

281

23

z

nc

Biota

Plant #30

TC4-BIO-30C

1480

2800

62

z

nc

Biota

Plant #30

TC4-BIO-30D

1640

1560

5

z

nc

Biota

Plant #40

TC4-BIO-40A

576

699

19

z

nc

Biota

Plant #40

TC4-BIO-40B

520

511

2

z

nc

Biota

Plant #40

TC4-BIO-40C

8830

9270

5

z

nc

Biota

Plant #40

TC4-BIO-40D

3360

4250

23

z

nc

Biota

Plant #50

TC4-BIO-50A

863

845

2

z

nc

Biota

Plant #50

TC4-BIO-50B

975

780

22

z

nc

Biota

Plant #50

TC4-BIO-50C

3790

2930

26

z

nc

Biota

Plant #50

TC4-BIO-50D

2230

1610

32

z

nc

Biota

Plant #56

TC4-BIO-56A

1050

328

105

z

nc

Biota

Plant #56

TC4-BIO-56B

253

302

18

z

nc

Biota

Plant #56

TC4-BIO-56C

799

983

21

z

nc

Biota

Plant #56

TC4-BIO-56D

847

586

36

ND = No RPD was calculated since the normal or field duplicate result (or both) was non-detect.

P:\ll SEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICI ES\

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA9_FieldDuplicate
008476

PAGE 19 OF 19

OCTOBER 2005


-------
Tar Creek Superfund Site
Ottawa County, Oklahoma

(This page intentionally left blank.)

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\APPENDIXA\TABLES
008477

OCTOBER 2005


-------
Table A-10

Wilcoxon Signed Rank (paired) Test Results for Comparing CH2M HILL / Respondents Split Data
Tar Creek Superfund Site
Ottawa County, Oklahoma

Media Grouping

Parameter

CH2M HILL
Mean

PRP Mean

CH2M HILL
Median

PRP Median

Mean of
Differences
(CH2M HILL -
PRP)

Median of
Differences
(CH2M HILL -
PRP)

Number of
Data Pairs

Wilcoxon Signed
Rank p-value

Normality
p-value (of
difference
s)

Chat Base

Cadmium

92.6

95

86.6

94

-2.4

-12.7

6

0.563

0.272

Chat Base

Lead

2280

1860

2115

1955

420

-50

6

0.844

0.066

Chat Base

Zinc

25300

22500

21100

23150

2820

-1850

6

0.844

0.040

Chat Pile

Aluminum

431

840

396.5

810

-409

-413.5

4

0.125

0.936

Chat Pile

Antimony

1.05

0.225

0.86

0.25

0.828

0.71

4

0.125

0.537

Chat Pile

Arsenic

5.83

13.4

6

11.3

-7.55

-6.7

4

0.375

0.496

Chat Pile

Barium

5.59

13.5

4.7

6

-7.91

-2.3

4

0.625

0.158

Chat Pile

Beryllium

0.161

0.75

0.16

0.75

-0.589

-0.588

4

0.125

0.488

Chat Pile

Cadmium

98.4

92.6

71.65

87

5.84

-11.95

32

0.355

0.000

Chat Pile

Calcium

41800

48300

39900

46300

-6450

-6400

4

0.375

0.096

Chat Pile

Chromium

6.48

7.13

5.45

8

-0.65

-0.35

4

0.875

0.899

Chat Pile

Cobalt

2.78

3.75

2

3.75

-0.975

-0.5

4

0.250

0.207

Chat Pile

Copper

135

82.5

131.5

82.5

52.6

34

4

0.250

0.428

Chat Pile

Iron

7000

5440

6790

5440

1560

840

4

0.250

0.137

Chat Pile

Lead

1390

1380

1445

1465

10.3

-36.5

32

0.634

0.071

Chat Pile

Magnesium

13200

11700

12600

11700

1470

2190

4

0.375

0.330

Chat Pile

Manganese

229

163

232

140

66.3

40.5

4

0.250

0.289

Chat Pile

Mercury

0.508

0.158

0.325

0.165

0.35

0.19

4

0.125

0.099

Chat Pile

Nickel

9.55

7.63

8.45

7.5

1.93

3.55

4

0.375

0.065

Chat Pile

Potassium

251

475

251.25

500

-224

-248.75

4

0.250

0.799

Chat Pile

Selenium

1.32

20.8

1.32

20.55

-19.5

-19.235

4

0.125

0.034

Chat Pile

Silver

0.475

2

0.3

2

-1.53

-1.7

4

0.125

0.266

Chat Pile

Sodium

47600

125

50850

125

47500

50725

4

0.125

0.649

Chat Pile

Thallium

1.25

0.62

1.25

0.28

0.63

0.97

4

0.250

0.029

Chat Pile

Vanadium

4.9

6.75

5.15

6.5

-1.85

-1.6

4

0.125

0.551

Chat Pile

Zinc

28400

23300

23650

23000

5120

650

32

0.322

0.000

Fine Tailings

Cadmium

122

146

109

145

-23.8

-9

21

0.004

*

0.000

Fine Tailings

Lead

4930

6280

3870

4720

-1350

-850

21

0.000

*

0.000

Fine Tailings

Zinc

24500

33100

25200

29100

-8580

-7000

21

0.000

*

0.000

Residential Yard Soil

Cadmium

3.62

4.25

0.59

1.45

-0.634

-0.495

28

0.000

*

0.000

Residential Yard Soil

Lead

858

1090

25.2

35

-231

-7.4

29

0.000

*

0.000

Residential Yard Soil

Zinc

501

639

133

244

-138

-72

29

0.000

*

0.000

Transition Zone Soil

Aluminum

3320

5620

3323.5

5615

-2290

-2291.5

2





P:\U SEPAX317950\T7\RA04\DRAFT_2005-1028WPPEN DICIESX
APPEN DIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA10 JVSRT

008478

PAGE 1 OF 2

OCTOBER 2005


-------
Table A-10

Wilcoxon Signed Rank (paired) Test Results for Comparing CH2M HILL / Respondents Split Data
Tar Creek Superfund Site
Ottawa County, Oklahoma

Media Grouping

Parameter

CH2M HILL
Mean

PRP Mean

CH2M HILL
Median

PRP Median

Mean of
Differences
(CH2M HILL -
PRP)

Median of
Differences
(CH2M HILL -
PRP)

Number of
Data Pairs

Wlcoxon Signed
Rank p-value

Normality
p-value (of
difference
s)

Transition Zone Soil

Antimony

0.233

0.15

0.2325

0.15

0.0825

0.0825

2





Transition Zone Soil

Arsenic

4

5.2

4

5.2

-1.2

-1.2

2





Transition Zone Soil

Barium

56

65

56

64.95

-8.95

-8.95

2





Transition Zone Soil

Beryllium

0.275

0.4

0.275

0.4

-0.125

-0.125

2





Transition Zone Soil

Cadmium

13.1

16.9

0.89

2.1

-3.79

-1.2

65

0.000 *

0.000

Transition Zone Soil

Calcium

14700

16800

14665

16840

-2180

-2175

2





Transition Zone Soil

Chromium

7.5

11

7.5

11

-3.5

-3.5

2





Transition Zone Soil

Cobalt

3

2.75

3

2.75

0.25

0.25

2





Transition Zone Soil

Copper

26

25.5

26

25.5

0.5

0.5

2





Transition Zone Soil

Iron

7580

9130

7580

9130

-1550

-1550

2





Transition Zone Soil

Lead

175

229

20.95

26

-53.9

-6.2

66

0.000 *

0.000

Transition Zone Soil

Magnesium

4320

5380

4321.5

5380

-1060

-1058.5

2





Transition Zone Soil

Manganese

253

280

253

279.5

-26.5

-26.5

2





Transition Zone Soil

Mercury

0.0455

0.085

0.0455

0.085

-0.0395

-0.0395

2





Transition Zone Soil

Nickel

6.7

7.5

6.7

7.5

-0.8

-0.8

2





Transition Zone Soil

Potassium

174

600

173.5

600

-427

-426.5

2





Transition Zone Soil

Selenium

0.563

0.525

0.5625

0.525

0.0375

0.0375

2





Transition Zone Soil

Silver

0.085

0.5

0.085

0.5

-0.415

-0.415

2





Transition Zone Soil

Sodium

11100

37.5

11110

37.5

11100

11072.5

2





Transition Zone Soil

Thallium

0.183

0.11

0.1825

0.11

0.0725

0.0725

2





Transition Zone Soil

Vanadium

10.9

13.9

10.85

13.9

-3.05

-3.05

2





Transition Zone Soil

Zinc

2350

3040

144

227

-691

-40.9

66

0.000 *

0.000

Washed Fines

Cadmium

90.2

95.4

80.6

78.1

-5.14

-0.4

19

0.860

0.000

Washed Fines

Lead

3460

4050

2590

2370

-597

-121

19

0.196

0.000

Washed Fines

Zinc

17600

20500

11000

15200

-2830

-1200

19

0.066

0.001

NOTES:

BOLD = COPCs

* = Wilcoxon Signed Rank p-value is significant at the 0.05 significance level.

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA10_WSRT

008479

PAGE 2 OF 2

OCTOBER 2005


-------
Table A-11

Comparison of Means for Cases Where CH2M HILL / Respondents Splits are Significantly Different (per the Wilcoxon

Signed Rank test)

Tar Creek Superfund Site

Ottawa County, Oklahoma





CH2M



RPD





HILL

Respondents

Between

Media Grouping

Parameter

Mean

Mean

Means

Fine Tailings

Cadmium

122

146

18%

Fine Tailings

Lead

4930

6280

24%

Fine Tailings

Zinc

24500

33100

30%

Residential Yard Soil

Cadmium

3.62

4.25

16%

Residential Yard Soil

Lead

858

1090

24%

Residential Yard Soil

Zinc

501

639

24%

Transition Zone Soil

Cadmium

13.1

16.9

25%

Transition Zone Soil

Lead

175

229

27%

Transition Zone Soil

Zinc

2350

3040

26%

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\	PAGE 1 OF 1

APPENDIX A\TC_HHRA_DraftRA_AppendixA_Tables.xls\TA11_WSRT_significant

008480

OCTOBER 2005


-------
Tar Creek Superfund Site
Ottawa County, Oklahoma

(This page intentionally left blank.)

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\APPENDIXA\TABLES
008481

OCTOBER 2005


-------
Figures

008482


-------
TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX A: SPLIT AND SUPPLEMENTAL SAMPLING SUMMARY TM

(This page intentionally left blank.)

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
APPENDIXATC_HHRA_DRAFTRA_APPENDIXA.DOC
008483

OCTOBER 2005


-------
Plant #57,

Plant #56

Plant #55

.<•: 'Plant#9

Plant #7.

- Plant #54]

" ' 1

Plant #8

Plant #48

Plant #47

Plant #46

Plant #23

Plant #45

Plant #43

Plant #44

Plant #22

Plant #18

Plant #13

Plant #14'

Plant #17,

Plant #30

Plant #15

Plant #16

Plant #27.

Plant #19

Plant #20

Plant #12 Hi

- v >-

Plant #3

Plant #25

Plant #1

Plant #29

Plant #10

Plant #42

Plant #6'

Plant #40

Plant #411

Plant #35

Plant #37

Plant #34

Plant #36

Plant #38

Plant #32

Plant #39

Plant #31

/u • -j'





CH2MHILL

• Plant Locations
Site Boundary

N

LEGEND

A

\\chuckwagon\GIS\NWOFiles\TarCreek\MXD\Bird_Dog.mxd 10\6\05 S Daigle	0	0.375	0.75

008484

FIGURE A-1

Tar Creek OU4
Plant Sampling Locations

¦ Miles
1.5

•AERIAL PHOTOGRAPHY PROVIDED BY:
AATA INTERNATIONAL INC.
Fort Collins, Colorado, USA


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX A: SPLIT AND SUPPLEMENTAL SAMPLING SUMMARY TM

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P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
APPENDIXATC_HHRA_DRAFTRA_APPENDIXA.DOC
008485

OCTOBER 2005


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Appendix B

Fish Tissue Metals Analysis in the Tri-State

Mining Area

008486


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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

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USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
008487

FEBRUARY 2006


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STATE OF OKLAHOMA

DEPARTMENT OF ENVIRONMENTAL QUALITY
(DEQ)

CUSTOMER SERVICES DIVISION

FY03 Section 106 Water Quality Management Program
1-006400-01
FY03/04 Carryover Project #8 (Task 600)

Fish Tissue Metals Analysis in the Tri-State Mining Area

FY 2003

Final Report

Submitted by:

Oklahoma Department of Environmental Quality
Customer Services Division
707 North Robinson
P. O. Box 1677
Oklahoma City, OK 73101-1677
Telephone: (405)702-1000

Effective: July 1, 2003

008488


-------
Acknowledgements

The Oklahoma Department of Environmental Quality wishes to thank the US Fish
and Wildlife Service for their help in the collection of fish as well as advice and
counsel on development of sample preparation and analysis methods for this
study.

008489


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Executive Summary

The Customer Services Division (CSD) of the Oklahoma Department of
Environmental Quality (ODEQ) performed a study to determine the safety of
consuming fish caught in Oklahoma waters affected by runoff from the Tri-State
Mining Area and the Tar Creek Superfund Site. Responding to concerns by local
residents and tribes, this study was designed to determine levels of metals in fish
tissue that would be harmful to human health if consumed in excess amounts.
Local tribes from the Tar Creek area indicated traditional customs involve eating
whole fish, including bones, which have been canned by means of pressure-
cooking. Since metals are known to accumulate in the bones and organs offish,
there was a concern that these traditional methods of preparation would be
unsafe. Local tribes advised ODEQ they believed fish consumption rates were
higher among tribal members than among the general public.

CSD field personnel worked cooperatively with the US Fish and Wildlife Service
to collect fish from the Neosho and Spring Rivers and local ponds receiving mine
waste runoff. The State Environmental Laboratory developed sample
preparation and analysis methods specifically for this study. CSD risk
assessment personnel used EPA guidance to develop safe levels for cadmium
and zinc in fish, and utilized the Integrated Exposure Uptake Biokinetic (IEUBK)
Model for evaluating lead concentrations in fish that would be safe for the public
to consume.

Results of this study conclude that fillets of fish caught in ponds within the Tar
Creek Superfund Site and the Spring and Neosho Rivers are safe to eat at rates
up to 6 8-ounce meals per month based on laboratory reporting limits. Whole-
uneviscerated and whole-eviscerated portions of all fish from the Oklahoma
sections of the Spring and Neosho Rivers downstream to Grand Lake and ponds
in the Tri-State Mining Area should not be consumed. Fish from these waters
have higher concentrations of lead than fish collected in a national study. The
higher fish tissue lead concentrations are positively correlated (R2= 86%) to lead
concentrations in the sediments of the area waters.

A follow-up study is recommended to verify these results and to determine the
downstream extent of problems. Future studies should incorporate lower
analytical reporting limits.

008490


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Table of Contents

Background and Statement of Issues	1

Monitoring Methods

Sample Collection	2

Laboratory Analysis	2

Quality Assurance	4

Results	5

Data Analysis

Determination of Safe Consumption Levels	5

Cadmium and Zinc	5

Lead	7

Comparison of Fish Concentrations to Allowable Levels	11

Comparison of Preparation Methods	14

Relationship of Tissue Concentrations to Sediment and

Water Concentrations	17

Comparison to Historic Data	19

Comparison to National Data	19

Conclusions and Recommendations	21

References	23

Appendix A: Data Summary	25

Figures and Tables

Figure 1. Sampling Locations	3

Figure 2. Boxplot Construction Legend	14

Figure 3. Boxplot of Cadmium by Preparation	15

Figure 4. Boxplot of Lead by Preparation	15

Figure 5. Boxplot of Zinc By Preparation	15

Figure 6. Regression Plots	18

Figure 7. Boxplot Comparing Cadmium Results for	20

NCBP and Tri-State Studies

Figure 8. Boxplot Comparing Lead Results for	20

NCBP and Tri-State Studies

Figure 9. Boxplot Comparing Zinc Results for	21
NCBP and Tri-State Studies

008491


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Table 1. Site Locations	2

Table 2. IEUBK Inputs	8

Table 3. Percentage of Samples Exceeding Allowable	10

Contaminant Concentration Levels at Standard
Consumption Rates (1 meal per week)

Table 4. Percentage of Samples Exceeding Allowable	12

Contaminant Concentration Levels at Elevated
Consumption Rates (2 meal per week)

Table 5. Regression Results	18

008492


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Background and Statement of Issues

The Tri-State Mining District located in northeast Oklahoma, southeast Kansas,
and southwest Missouri was once a major provider of lead and zinc ores in the
early to mid 20th century. Since the cessation of mining in the area, the mines
remain closed and abandoned. Metals located both in the mines and in waste
ore on the surface can become mobilized under low pH conditions and be
transported by ground and surface waters. Water has been discharging from the
closed mines since the 1970's and is a major source of contamination to Tar
Creek, a tributary of the Neosho River.

The Spring and Neosho Rivers and their tributaries (particularly Tar Creek) have
been impacted by runoff from these abandoned lead and zinc mines.

Additionally, the percolation of rainwater through chat piles mobilizes metals into
solution, which flows into local ponds, many of which are millponds at abandoned
ore processing sites. Fish caught locally in these rivers and ponds constitute a
significant portion of the diets of the citizens of the area. Furthermore, area tribal
members report that fish are prepared and consumed using a pressure cooker to
can and preserve whole fish including bones. These methods would potentially
increase the ingestion of metals that might accumulate in fish. Additionally, local
tribes advised that they believed fish consumption rates were higher among tribal
members than the general public. Questions have been raised about the safety
of eating fish from these waters.

The consumption offish containing elevated levels of metals is a concern
because chronic exposure to heavy metals can cause health problems. Chronic
lead exposure has been linked to anemia, neurological dysfunction and renal
impairment. Chronic cadmium exposure has been linked to renal damage,
hypertension, and cardiovascular effects. Although zinc is an essential nutrient
required for proper growth and development, the presence of zinc can affect the
body's metabolism of other metals.

This study evaluates the potential human health effects associated with the
ingestion offish from the Tri-State Mining Area in Oklahoma. In addition, an
evaluation of possible relationships between metals concentrations in fish tissue
and metals concentrations in water and sediment was done. Fish tissue
concentrations were also compared to values from the National Contaminant
Biomonitoring Program conducted by the U.S. Fish and Wildlife Service.

008493

1


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Monitoring Methods

Sample Collection

Fish were collected from 4 ponds and 6 river sites in 2002 (Figure 1, Tablel).
The river sites were evenly split with 3 sites on Spring River and 3 sites on the
Neosho River. Two of the pond sites were millponds at former ore processing
locations and 2 pond sites were adjacent to and received runoff from chat piles.
The pond sites are located in the Tar Creek Superfund area while the stream
sites are outside the Superfund area proper but within the larger Tri-state Mining
District.

Table 1. Site Locations

Site ID

Site Name

Latitude

Longitude

TC-MPACP

Atlas Chat Pile Pond

36°58.867'

94°48.332'

TC-MPBG

Blue Goose Mill Pond

36°58.102'

94°51.784'

TC-MPNWWC

Northwest Western Chat Pile Pond

36°59.081'

94°51.349'

TC-MPWCP

Western Chat Pile Mill Pond

36°58.920'

94°51.436'

TC-NRCB

Neosho River at Conners Bridge

36°47.949'

94°49.165'

TC-NRECC

Neosho River at Elm Creek Confluence

36°53.470'

94°55.677'

TC-NRRP

Neosho River at Riverview Park

36°51.944'

94°52.728'

TC-SRBH

Spring River at Blue Hole

36°56.096'

94: 44.765"

TC-SRMB

Spring River at Mocassin Bend

36°52.3ir

94°45.933'

TC-SRTB

Spring River at Twin Bridges State Park

36°48.174'

94°45.213'

A total of 80 composite fish samples representing 8 species were collected using
various combinations of electrofishing, gill nets, and rod and reel. Species
targeted for collection and analysis were carp, channel catfish and white crappie.
At sites where those species were not available in sufficient numbers, other
commonly consumed species were collected. These include white bass, spotted
bass, largemouth bass, bluegill sunfish and smallmouth buffalo. Because
comparisons were to be made between different preparation methods, an
attempt was made to collect consistent size ranges within species at all sites.

Laboratory Analysis

Fish collections were delivered to ODEQ's State Environmental Laboratory
where they were sorted by site, species, and size. Fish were then sorted into
composites consisting of 3 to 8 individuals with the smallest fish in the composite
at least 75 percent of the length of the largest fish in the composite. Composite
samples of similar mean length were assembled for different preparation
methods: fillets, whole-uneviscerated fish, and whole-eviscerated fish. Sufficient
numbers offish were available to perform analyses using the 3 preparation
methods for carp and channel catfish at the 6 river sites, white crappie at 5 of the
river sites, and largemouth bass at the 4 pond sites. In addition, 25 composite
samples consisting of other commonly consumed species were assembled.

008494


-------
Figure!. Sampling Locations

Tri-State Mining District Fish Tissue Study Area

A sample preparation technique1 was developed to prevent cross-contamination
between samples as metals are found in both the mucous and scales offish.

Only stainless steel cutting utensils were used and the preparation surfaces were

3

008495


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sheeted in polyethylene. All utensils and equipment were thoroughly cleaned
and polyethylene sheeting replaced between the preparation of each sample.

Fish were skinned and filleted, simply eviscerated, or kept whole as appropriate.
A commercial grade food grinder with stainless steel cutting blades was used to
mascerate samples. The ground tissue was then homogeneously mixed before
being sent through the food grinder a second time. A subsample of the ground
tissue was then collected for analysis.

A microwave digestion technique2 was developed to prepare the subsamples for
analysis. One gram subsamples were digested in 10 milliliters of concentrated
nitric acid (HNO3) brought to 200° C under pressure in a four-step temperature
ramping process. Samples were held at 200° C for 10 minutes and then allowed
to cool for 15 minutes. All tissue, including bones if present, was at that point
dissolved into the HNO3. Digested sample aliquots were then diluted with ultra-
pure water to a volume of 50 mis and allowed to rest.

EPA Method 200.73 for the analysis of metals was used to analyze the fish tissue
samples. Digested samples were diluted again by 50 percent to create a 10%
HNO3 solution just before analysis on an inter-coupled plasma (ICP) Trace®
Analyzer. A 10 mil. aliquot of the digested sample was injected into the ICP and
3 readings of each element were recorded. The mean of the 3 readings as well
as the standard deviation was calculated. If the percent of the standard deviation
relative to the mean of the 3 readings exceeded 20 percent, the sample results
were rejected. The mean of the readings was used to calculate the amount of
each element in the 1-gram aliquot of digested fish flesh. This value was then
converted to mg/kg units and entered into the AQUARIUS laboratory information
system.

Quality Assurance

A total of 4 field replicate samples were submitted for fish. These consisted of
duplicate composite samples of the same species, similar in size, collected at the
same site. Each of the sample preparation methods was represented by a field
replicate. Precision values were all 0 percent for cadmium (all values below the
laboratory reporting limit), 7 to 14 percent for zinc, and 0 to 4 percent for lead. All
precision values fall within acceptable limits for field replicate samples as outlined
the Quality Assurance Project Plan4 for this study.

A total of 8 laboratory duplicate samples of fish tissue were prepared. These
consisted of duplicate subsamples of the ground composited tissue. These were
digested and analyzed alongside the rest of the samples. Precision values were
all 0 percent for cadmium (all values below the reporting limit), 1 to 25 percent for
zinc, and 0 to 18 percent for lead. All precision values fall within acceptable
limits for laboratory duplicates as outlined in the Quality Assurance Project Plan
for this study.

4

008496


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Results

Results for all analyses are included in Appendix A.

Data Analysis
Determination of Safe Consumption Levels

The determination of safe fish consumption levels for lead, zinc, and cadmium
was performed using 2 different methods. Zinc and cadmium levels were
determined by using methods described in the U.S. EPA document Guidance For
Assessing Chemical Contaminant Data For Use in Fish Advisories5. This method
utilizes Reference Dose values (RfDs) to calculate contaminant exposure levels
that would likely not result in an appreciable risk of adverse heath effects over a
lifetime. The level for lead was determined using EPA's Integrated Exposure
Uptake Biokinetic (IEUBK) Model for Lead6. This model considers total
environmental lead exposure and predicts the blood lead levels for children up to
84 months of age. A method similar to one utilized by the Washington State
Department of Health7 was used to establish the allowable levels of lead in fish
tissue. Since children are more sensitive to the deleterious effects of lead, the
consumption recommendations for lead are based on the protection of children.
It is assumed that levels that are protective of children are also protective of
adults.

To address the issue of elevated consumption rates among tribal members, safe
consumption levels were calculated using two different consumption rates: 1
meal per week as the Standard Consumption Rate and 2 meals per week as the
Elevated Consumption Rate.

Cadmium and Zinc

For cadmium and zinc safe consumption levels were calculated using the
following equations:

Cm= (RfD x BW)/CR|im

Where

Cm = measured concentration of chemical contaminant m in a given

species of fish (mg/kg)

RfD = reference dose (mg/kg-day)

BW = Consumer body weight (kg)

CR|jm = maximum allowable fish consumption rate (kg/d)

5

008497


-------
and:
Where

CR|jm — (CRmw x MS)/Tap

CRmw= maximum allowable fish consumption rate (meals/week)

MS = meal size (kg fish/meal)

Tap = time averaging period (days/week)

Combining equations yields:

Cm = (RfD x BW x Tap)/(CRmw x MS)

Reference dose values were obtained from the EPA Integrated Risk Information
System (IRIS) database8,9. Default values obtained from EPA's Guidance For
Assessing Chemical Contaminant Data For Use in Fish Advisories5 were used for
body weight and meal size. Equation inputs are as follows:

Reference Dose	Cadmium = 0.001 mg/kg-day

Zinc = 0.3 mg/kg-day
Body weight	Children = 14.5 kg (32lb)

Adults = 70 kg (154 lb)

Meal Size	0.227 kg (8 oz)

Consumption Rate	Standard Rate = 1 meal/week

Elevated Rate = 2 meals/week
Time averaging Period 7 days/week

From this, the following allowable fish contaminant concentrations were
calculated:

Standard Rate:

Cadmium
Zinc

Children
0.45 mg/kg
135 mg/kg

Adults
2.2 mg/kg
650 mg/kg

Elevated Rate:

Cadmium
Zinc

Children
0.22 mg/kg
67 mg/kg

Adults
1.1 mg/kg
325 mg/kg

The State Environmental Laboratory's reporting limit for cadmium (0.30 mg/kg) is
above the safe concentration calculated using the elevated consumption rate for
children. Because of this, either the meal size or the consumption rate could be
adjusted to determine safe levels of consumption offish based on results at the

6

008498


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reporting limit. Calculations of safe consumption levels based on a fish
concentration of 0.30 mg/kg are as follows:

For a meal size of 0.227 kg (8 oz):

CRmw = (RfD X BW X Tap)/(Cm x MS)

= (0.001 x 14.5 x 7)/(0.30 x 0.227)

= 1.5 meals/week

For a consumption rate of 2 meals per week:

MS = (RfD x BW x Tap)/(Cm x CRmw)

= (0.001 x 14.5 x 7)/(0.30 x 2)

= 0.169 kg (6 oz) fish meal

Lead

Safe fish concentration levels for lead were calculated using the IEUBK model
which predicts the distribution of blood lead levels for children age 84 months
and younger. The model generates a protective level at which no more than 5
percent of modeled blood lead levels exceed the EPA Intervention Level10 of 10
ug/dl (micrograms/deciliter). Blood lead concentrations above the Intervention
Level indicate action should be taken to determine the cause of the elevated
concentration. This risk assessment methodology is more conservative than that
used for cadmium and zinc in that total lead exposure is accounted for through
estimates of exposure through soil, house dust, air, water, and diet. EPA default
values were used for all inputs into the IEUBK except for soil and house dust
lead concentrations, and factors related to fish consumption and concentration.

Soil lead concentrations were determined by computing the 95% upper
confidence level(UCL) of the mean of yard soil concentrations11 and high access
area concentrations12. Residential yards and high access areas(HAAs) such as
parks, schools and playgrounds have been sampled for lead concentration as
part of the cleanup activities in the Tar Creek area. If yard or HAA soil
concentrations were found to have soil lead levels greater than 500 mg/kg, the
soil was removed and replaced with low lead concentration borrow fill soil from
outside the area. Yard and HAA replacement activities are nearing completion at
the time this report is being written.

Yard lead data indicate that 3257 of 7977 samples (41%) exceed 500 mg/kg.
These areas were replaced with borrow fill having a mean lead concentration of
18.1 mg/kg13. The mean value of the yards after remediation was calculated

7

008499


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after replacing those values greater than 500 mg/kg in the dataset with values of
18.1 mg/kg. The resulting mean of the post-remediation yards is 140.9 mg/kg.
The 95% UCL for the mean is 144.2 mg/kg.

A total of 28 high access areas were sampled in the towns of Picher, Cardin,
Quapaw, Commerce, and North Miami. Ten of the 28 eight sites (36%) averaged
greater than 500 mg/kg soil lead level. The soil at these sites was removed and
replaced with borrow fill having a mean lead value of 18.1 mg/kg. The mean
value of the HAAs after remediation was calculated after replacing the values of
sites that were greater than 500 mg/kg with 18.1 mg/kg. The resulting mean of
the post-remediated HAAs was 134.7 mg/kg. The 95% UCL for the mean was
163.8 mg/kg

Based on this information it was decided to use a soil concentration input of 165
mg/kg. The IEUBK default for soil concentration to house dust concentration is
0.7. Using this, the house dust concentration was calculated to be 115 mg/kg.
Inputs into the IEUBK model are given in Table 2.

Table 2. IEUBK Inputs

Input

Value

Drinking Water

4.00 ug/L (EPA default value)

Soil

165 mg/kg (based on the 95% UCL of the mean
of yard soil levels and high access area soil
levels)

House Dust

115 ug/g (based on soil level)

Paint

0 per day (EPA default)

Maternal Blood Contribution

2.5 ug/dl (default in the infant model)

Outdoor Air Concentration

0.100 ug/rn^ (EPA default)

Indoor Air

30% of outdoor air concentration (EPA default)

Time Outdoors

1 to 4 hours per day (EPA defaults based on
age)

Ventilation Rates

2 to 7 m3/day (EPA defaults based on age
range)

Lung Absorption

32 percent (EPA default)

Diet Uptake

50% (EPA default varies slightly with age)

Water Uptake

0.36 to 1.13 ug/day (EPA default, varies with
age)

Soil and Dust Uptake

5.1 to 5.67 ug/day (EPA default varies with age)

Percentage of Meat Intake
Consisting of Locally Caught
Fish

Standard Consumption Rate: 32 percent
Elevated Consumption Rate: 64 percent
(based on one or two 8-ounce meals per week
as a percentage of median EPA default daily
meat consumption of 101.57 g/day based on
age)

008500


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The allowable lead concentration in fish was determined by setting the model
inputs to those described in Table 2 and manipulating the Lead in Fish
concentration to a level that results in just less than 5 percent of the target
population with a blood lead level of 10 ug/dl.

For example, in the case of the Standard Consumption Rate of one 8-ounce
meal per week, the model was initially run with the Percentage of Meat Intake
Consisting of Locally Caught Fish input at 32 percent and the Lead in Fish
concentration set to 0 mg/kg resulting in 0.44 percent of the target population
with a blood lead level greater than 10 ug/dl. The Lead in Fish concentration was
incrementally increased until just below 5 percent of the target population had a
blood lead level of more than 10 mg/dl. That final Lead in Fish concentration was
0.36 mg/kg.

This process was repeated for an Elevated Consumption Rate of two 8-ounce
meals per week of locally caught fish. The resulting allowable lead level was
0.18 mg/kg.

Allowable fish contaminant concentrations based on either one or two 8-ounce
meals per week are as follows:

Contaminant

Children

Standard
Consumption
Rate

Children

Elevated
Consumption
Rate

Adults

Standard
Consumption
Rate

Adults

Elevated
Consumption
Rate

Lead

Cadmium

Zinc

0.36 mg/kg
0.45 mg/kg
135 mg/kg

0.18 mg/kg
0.22 mg/kg
67 mg/kg

0.36 mg/kg
2.2 mg/kg
650 mg/kg

0.18 mg/kg
1.1 mg/kg
325 mg/kg

As in the case of cadmium, the allowable lead in fish concentration at the
Elevated Consumption Rate of two 8-ounce meals per week was less than the
State Environmental Laboratory's reporting limit of 0.25 mg/kg. To determine a
safe consumption level based on the SEL's reporting limit, the Lead in Fish
concentration was set to 0.25 mg/kg and the Percentage of Meat Intake
Consisting of Locally Caught Fish input was initially set at 64 percent (two 8-
ounce meals per week.) This resulted in 7.8 percent of the target population with
a blood level exceeding 10 ug/dl. The Percentage of Meat Intake Consisting of
Locally Caught Fish input was then incrementally reduced until just under 5
percent of the target population had an acceptable blood lead level. That final
level was 47%.

Allowable fish consumption based on the SEL's reporting limit of 0.25 mg/kg was
calculated as follows:

9

008501


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CRum = (Mdi X Pf X TapX 0.0353 ounces/gram)/8 ounces/meal where
CRum = Consumption rate in meals/month

Mdi = median daily consumption of meat by children younger than 8
Pf = Proportion of meat intake consisting of locally caught fish

CRLim= (101.57 g/day X 0.51 X 7 days/week X 0.0353 oz/g)/8 oz/meal
= 1.5 meals/week

or for a consumption rate of 2 meals per week:

MS = (CRLim X PF X Tap X 0.0353 oz/g)/2 meals/week

= (101,57g/day X 0.51 X 7 days/week X 0.0353 oz/g) / 2 meals/week
= 5.9 oz. fish meal

Comparison of Collected Fish Concentrations to Allowable Levels

Fish were collected at 3 sites on Spring River, 3 sites on the Neosho River, 2
ponds near chat piles and 2 millponds at former ore processing sites. Sample
analysis was performed on whole-uneviscerated fish, whole-eviscerated fish and
fillets of carp and channel catfish at the 6 river sites, white crappie at 5 of the
river sites, and largemouth bass at the 4 pond sites. In addition, 25 samples of
various other commonly consumed species were performed using the various
preparation methods.

Table 3 lists the percentage of samples (by preparation method and species)
exceeding the allowable fish contaminant concentrations at the Standard
Consumption Rate. Table 4 lists the percentage of samples exceeding the
allowable fish contaminant concentrations at the Elevated Consumption Rates.

Table 3. Percentage of Samples Exceeding Allowable Contaminant
Concentration Levels at Standard Consumption Rates (1 meal perw

Preparation

Number

Cadmium

Cadmium

Lead

Zinc

Zinc



of

Children

Adults

Children

Children

Adults



Samples

(percent
exceeding
0.45 mg/kg)

(percent
exceeding
2.2 mg/kg)

and Adults

(percent
exceeding
0.36 mg/kg)

(percent
exceeding
135 mg/kg)

(percent
exceeding
650 mg/kg)

All Species













All

80

3

0

27

0

0

FL

25

0

0

0

0

0

WE

25

0

0

24

0

0

WU

30

7

0

50

0

0

Smallmouth













Buffalo













All

4

0

0

100

0

0

FL

0

0

0

0

0

0

WE

0

0

0

0

0

0

WU

4

0

0

100

0

0



10

008502


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Preparation

Number

Cadmium

Cadmium

Lead

Zinc

Zinc



of

Children

Adults

Children

Children

Adults



Samples

(percent
exceeding
0.45 mg/kg)

(percent
exceeding
2.2 mg/kg)

and Adults

(percent
exceeding
0.36 mg/kg)

(percent
exceeding
135 mg/kg)

(percent
exceeding
650 mg/kg)

Carp













All

18

11

0

56

0

0

FL

6

0

0

0

0

0

WE

6

0

0

67

0

0

WU

6

33

0

100

0

0

Channel













Catfish













All

18

0

0

17

0

0

FL

6

0

0

0

0

0

WE

6

0

0

0

0

0

WU

6

0

0

33

0

0

Bluegill
Sunfish













All

5

0

0

40

0

0

FL

1

0

0

0

0

0

WE

1

0

0

0

0

0

WU

3

0

0

66

0

0

Largemouth
Bass













All

13

0

0

15

0

0

FL

4

0

0

0

0

0

WE

4

0

0

25

0

0

WU

5

0

0

20

0

0

Spotted
Bass













All

3

0

0

0

0

0

FL

1

0

0

0

0

0

WE

1

0

0

0

0

0

WU

1

0

0

0

0

0

White Bass













All

2

0

0

0

0

0

FL

0

0

0

0

0

0

WE

0

0

0

0

0

0

WU

2

0

0

0

0

0

White













Crappie













All

15

0

0

0

0

0

FL

5

0

0

0

0

0

WE

5

0

0

0

0

0

WU

5

0

0

0

0

0

Preparation Codes:

ALL-All Sample Preparations
FL-Fillet

WE - Whole-eviscerated
WU - Whole-uneviscerated

008503

11


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Table 4. Percentage of Samples Exceeding Allowable Contaminant
Concentration Levels at Elevated Consumption Rates (2 meal per week).

Preparation

Number

Cadmium

Cadmium

Lead

Zinc

Zinc



of

Children

Adults

Children

Children

Adults



Samples

(percent
exceeding
0.22 mg/kg)

(percent
exceeding
1.1 mg/kg)

and Adults

(percent
exceeding
0.18 mg/kg)

(percent
exceeding
67 mg/kg)

(percent
exceeding
325 mg/kg)

All Species













All

80

6

0

36

1

0

FL

25

0

0

4

0

0

WE

25

0

0

36

0

0

WU

30

20

0

60

3

0

Smallmouth













Buffalo













All

4

0

0

100

0

0

FL

0

0

0

0

0

0

WE

0

0

0

0

0

0

WU

4

0

0

100

0

0

Carp













All

18

28

0

66

6

0

FL

6

0

0

17

0

0

WE

6

0

0

83

0

0

WU

6

83

0

100

17

0

Bluegill
Sunfish













All

5

0

0

40

0

0

FL

1

0

0

0

0

0

WE

1

0

0

0

0

0

WU

3

0

0

66

0

0

Channel













Catfish













All

18

0

0

28

0

0

FL

6

0

0

0

0

0

WE

6

0

0

33

0

0

WU

6

0

0

50

0

0

Largemouth
Bass













All

13

0

0

23

0

0

FL

4

0

0

0

0

0

WE

4

0

0

50

0

0

WU

5

0

0

20

0

0

Spotted
Bass













All

3

0

0

0

0

0

FL

1

0

0

0

0

0

WE

1

0

0

0

0

0

WU

1

0

0

0

0

0

White Bass













All

2

0

0

0

0

0

FL

0

0

0

0

0

0

WE

0

0

0

0

0

0

WU

2

0

0

0

0

0

12

008504


-------
Preparation

Number

Cadmium

Cadmium

Lead

Zinc

Zinc



of

Children

Adults

Children

Children

Adults



Samples

(percent
exceeding
0.22 mg/kg)

(percent
exceeding
1.1 mg/kg)

and Adults

(percent
exceeding
0.18 mg/kg)

(percent
exceeding
67 mg/kg)

(percent
exceeding
325 mg/kg)

White













Crappie













All

15

0

0

13

0

0

FL

5

0

0

0

0

0

WE

5

0

0

0

0

0

WU

5

0

0

40

0

0

Preparation Codes:

ALL-All Sample Preparations
FL-Fillet

WE - Whole-eviscerated
WU - Whole-uneviscerated

From the two tables the following can be discerned:

•	A single fillet sample of carp exceeded allowable levels for lead and the
Elevated Consumption Rate. No other fillet portions of any fish exceeded
laboratory reporting limits. No fillet portions exceed allowable levels for
any metal tested at the Standard Consumption Rate.

•	Allowable levels for cadmium at the Elevated Consumption Rate for
children were exceeded only in samples of whole-uneviscerated carp.

•	The allowable level for Zinc at the Elevated Consumption Rate for
Children was exceeded by a single whole fish sample.

•	Allowable levels for lead at the elevated consumption rate were exceeded
in 36 percent of all whole-eviscerated samples and 60 percent of all whole
fish samples.

•	Allowable levels of lead at the Standard Consumption Rate of 1 meal per
week were exceeded in 5 species:

¦	33 percent of whole-uneviscerated channel catfish

¦	17 percent of whole-eviscerated channel catfish

¦	100 percent of whole-uneviscerated smallmouth buffalo

¦	100 percent of whole-uneviscerated carp

¦	67 percent of whole-eviscerated carp.

¦	66 percent of whole-uneviscerated bluegill

¦	20 percent of whole-uneviscerated largemouth bass

¦	25 percent of whole-eviscerated largemouth bass

•	Allowable levels of lead at the Elevated Consumption Rate of 2 meals per
week were exceeded in 5 species:

¦	50 percent of whole-uneviscerated channel catfish

¦	33 percent of whole-eviscerated channel catfish

13

008505


-------
¦	20 percent of whole-uneviscerated largemouth bass

¦	50 percent of whole-eviscerated largemouth bass

¦	66 percent of whole-uneviscerated bluegill sunfish

¦	40 percent of whole-eviscerated white crappie

¦	17 percent of carp fillets

¦	83 percent of whole-eviscerated carp

¦	100 percent of whole-uneviscerated carp

¦	100 percent of whole-uneviscerated smallmouth buffalo

Based on this information ODEQ recommends children living in the Tar Creek
area consume no more than six 8-ounce fillet meals per month offish caught in
ponds within the Tar Creek Superfund Site and the Spring and Neosho Rivers
above Grand Lake. All adults and children should avoid eating all species of
whole-eviscerated or whole-uneviscerated fish caught in these waters.

Comparison of Preparation Methods

Fish samples were analyzed using 3 different preparation methods: fillets, whole-
eviscerated, and whole-uneviscerated. There are 23 instances in the data set
where analyses were performed using the three preparation methods on the
same species from the same site. These data were pooled and statistical tools
were applied to determine if significant differences exist between the preparation
methods in relation to tissue metals concentration. Figures 3-5 illustrate boxplots
of results from the 3 preparation methods vs. metals concentration. Figure 2 is a
legend defining boxplot construction as used in this report.

Figure 2. Boxplot construction legend.

*-<	Outlier

*-

I

-<	Highest value within the

limit: Q3+1.5(Q3-Q1)

	
-------
Figure 3. Boxplots of cadmium concentration by sample preparation (all species
pooled.)

Boxplot of Cadmium by Preparation

(means are indicated by solid circles)

0.9
0.8 -

0.7 -

|	—.0.6-

¦ —	o>

£

~o	o) 0.5 —

TO <=

O vS

0.4 -
0.3
0.2
0.1

Whole
Eviscerated

Whole
Uneviscerated

Figure 4. Boxplots of lead concentration by sample preparation (all species
pooled.)

3.5 -
3.0
2.5 -
' 2.0-
>1.5-
1.0
0.5 -
0.0

Boxplot of Lead by Preparation Method

(means are indicated by solid circles)

Fillet

Whole
Eviscerated

Whole
Uneviscerated

Figure 5. Boxplots of zinc concentration by sample preparation (all species
pooled.)

Boxplot of Zinc by Preparation

(means are indicated by solid circles)

Eviscerated	Uneviscerated

15

008507


-------
These plots indicate some differences between the whole-eviscerated and the
whole-uneviscerated preparations while illustrating generally lower
concentrations in fillet samples. To confirm these observations, a Kruskal-Wallis
test14 was applied to the data. The Kruskal-Wallis test uses median values and
average ranks to determine if the observed differences in 2 or more populations
are statistically significant, that is, of a greater magnitude than would be expected
to occur by chance. The Kruskal-Wallis test is an extension of the Wilcoxon
Rank Sum test and does not require the distribution of the data to be normal or
symmetric. For this test all values below the laboratory reporting limit were set to
one-half the reporting limit. The results are as follows:

H0: The medians of the preparation methods are all equal.

Ha. At least one of the medians is larger or smaller than at least one of the other

medians,
a = 0.05

For Cadmium:

Preparation

Number of

Median

Average

Z Statistic



Samples



Rank



Fillet

23

0.15

32.5

-0.73

Whole

23

0.15

32.5

-0.73

Eviscerated









Whole

23

0.15

40.0

1.46

Uneviscerated









Overall

69



35.0



H Statistic = 10.61	Degrees of Freedom = 2 p = 0.005 (adjusted for

ties)

For Lead:

Preparation

Number of

Median

Average

Z Statistic



Samples



Rank



Fillet

21

0.125

22.6

-2.87

Whole

21

0.125

35.0

0.93

Eviscerated









Whole

21

0.250

38.6

1.93

Uneviscerated









Overall

63



32.0



H Statistic = 12.14	Degrees of Freedom = 2 p = 0.002 (adjusted for

ties)

16

008508


-------
For Zinc:
Preparation

Number of
Samples

Median

Average
Rank

13.0
45.9

Z Statistic

Fillet
Whole-

23
23

6.54
21.2

-6.45
3.18

Eviscerated
Whole-
Uneviscerated
Overall

23

69

19.9

46.5

35.0

3.27

H Statistic = 41.65

Degrees of Freedom = 2 p = < 0.001

These results indicate that in each case the null hypothesis is rejected in favor of
the alternative hypothesis: at least one of the preparation methods differs from at
least one of the other preparation methods. The Z statistic indicates how the
mean rank for the group differs from the mean rank for all the observations.

From this information and the boxplots one can conclude that in the case of
cadmium, the whole-uneviscerated portion is significantly higher than both fillets
and whole-eviscerated preparations. For lead, fillet concentrations are
significantly less than concentrations in whole-uneviscerated and whole-
eviscerated portions. For zinc, fillet concentrations are also significantly lower
than both whole-eviscerated and whole-uneviscerated portions.

Relationship of Tissue Concentrations to Sediment and Water
Concentrations.

The relationship of tissue metals concentrations to water and sediment levels
was explored through linear regression analysis. To be consistent and to provide
the most unbiased data, metals concentrations from whole-uneviscerated carp
samples (the response variable) were plotted versus water and sediment
concentrations (predictor variables). The regression equation was computed
along with values for R2 and S. R2 is the percentage of variation in the response
variable due to the predictor variable and S is an estimator of the standard
deviation around the regression line.

Regression analysis was not run for total and dissolved fractions of lead and
cadmium in water because all results were less than the reporting limit. For all
other fractions, values less than the reporting limit were set to one-half of the
reporting limit.

Of the various combinations of tissue concentration vs. media concentration, only
lead in fish vs. lead in sediment yielded a result indicating a solid relationship
between the two. The results are given in Table 3 and shown in Figure 5.

17

008509


-------
Table 5. Regression Results

Test

Regression Equation

S

R2

Cadmium in Fish vs.

Cd(fjsh) = 0.253 + 0.069 Cd(sed)

0.231

31.0 %

Cadmium in Sediment





Lead in Fish vs.

Pb(fish) = 0.132 + 0.063 Pb(sed)

0.497

86.3 %

Lead in Sediment





Zinc in Fish vs.

Zn(fish) = 50.3 + 0.133 Zn^ss)

9.175

20.1 %

Dissolved Zinc in Water





Zinc in Fish vs.

Zn(fish) = 52.1 + 0.056 Zn(jot)

9.170

20.2 %

Total Zinc in Water





Zinc in Fish vs.

Zn(fish) = 53.2 + 0.010 Zn(sed)

9.594

12.6 %

Zinc in Sediment





Figure 6. Regression Plots

18

008510


-------
Comparison to Historic Data

ODEQ intended to compare data collected for this study to data collected from
the region in 1982 by the Oklahoma State Department of Health15 to determine if
tissue values were changing over time. However, an examination of the 1982
data revealed that all samples were fillets analyzed only for lead and all results
were below the reporting limit at the time of 1.0 mg/kg compared to a reporting
limit of 0.25 mg/kg for this study. This makes a comparison of the 2 time periods
unsuitable due to the differing reporting limits and the censoring of all 1982 data.

Comparison to National Data

Whole-uneviscerated fish data from this study was compared to data collected
for the U.S. Fish and Wildlife Service National Contaminant Biomonitoring
Program16 (NCBP) to determine if tissue metals concentrations in fish collected
from the Tri-State Mining District differed from values offish collected nationwide.
The NCBP data was queried to select concentration values representing the
same species and size ranges within those species as was collected for the Tri-
State Mining District study. Data were labeled as to study and were pooled into
a single database.

One of the difficulties in comparing the 2 data groups was the difference in
reporting limits for lead and cadmium. The NCBP study used varying reporting
limits of 0.001 to 0.05 mg/kg for cadmium and 0.008 to 0.1 mg/kg for lead. The
Tri-State Mining District study used reporting limits of 0.3 mg/kg for cadmium and
0.25 mg/kg for lead. For this comparison, all cadmium values below 0.3 mg/kg
were set to 0.29 mg/kg and all lead values below 0.25 mg/kg were set to 0.24
mg/kg. The Kruskal-Wallis test was run on the pooled data to determine if there
were statistical differences between the 2 study populations.

The results are as follows and boxplots illustrating the data are as follows:

H0: The medians of the 2 study populations are equal.

Ha. One of the medians is larger or smaller than the other median.

a = 0.05

For Cadmium:

Preparation Number of Median	Average Z Statistic

NCBP

Tri-State

Overall

Samples

409
29
438

<0.30
<0.30

Rank

217.2
251.6
219.5

-1.41

H Statistic = 1.99	Degrees of Freedom = 1 p = 0.158

H Statistic(adjusted for Degrees of Freedom = 1 p = <0.001
ties) = 27.13

19

008511


-------
Figure 7. Boxplot comparing cadmium results for NCBP and Tri-State studies.


-------
For Zinc:

Preparation Number of	Median Average Z Statistic

Samples	Rank

NCBP 148	15.96 86.4	-1.52

Tri-State 29	20.00 102.2

Overall 177	219.5

H Statistic = 2.30	Degrees of Freedom = 1 p = 0.129

Figure 9. Boxplot comparing Zinc results for NCBP and Tri-State studies.

o
c

N

100

; 90
, 80
• 70
60
50
40
30
20
10
0

NCBP

Study

r

Tri-State

These results indicate the median level for lead in fish tissue collected from
waters in the Tri-State Mining District is significantly higher than what would one
would expect to find in fish from other waters. The results for cadmium are
inconclusive due to the high proportion of censored data. While the calculated
median value for zinc is higher in the Tri-State Study, it is not statistically
significant at the 95% confidence level.

008513

21


-------
Conclusions and Recommendations

In comparison to fish collected in the National Contaminant Biomonitoring
Program, the fish from Oklahoma waters in the Tri-State Mining Area have lead
concentrations higher than one would expect to find in fish from waters
elsewhere in the United States. The elevated levels of lead in the fish positively
correlate to the concentration of lead in the sediments of these waters. The
consumption of whole-eviscerated or whole-uneviscerated fish from these waters
is discouraged. However, the consumption of fillets from fish in this area is safe
at rates at least as high as six 8-ounce meals per month based on the laboratory
reporting limit.

Further study is needed to validate these findings and to determine the
downstream extent of the metals uptake in fish species. Specifically, fish from
Grand Lake need to be tested for tissue lead concentrations. Additionally, due to
local fish harvesting practices, other bottom dwelling fish such as various species
of suckers should be included in a follow-up study. Laboratory analytical
techniques should be modified to lower reporting limits to levels in the 0.15 mg/kg
range for lead and cadmium.

008514

22


-------
References

1.	Oklahoma Department of Environmental Quality. 2002. Standard Operating
Procedure for the Tri-State Mining Area Fish Collection and Preparation.
Customer Service Division, Oklahoma Department of Environmental
Quality, Oklahoma City, OK.

2.	CEM Corporation. 1999. Mars Microwave Accelerated Reaction System
Operation Manual, Microwave Sample Preparation Note: 5BI-8. CEM
Corporation, Mathews, NC.

3.	U.S. EPA. 1991. EPA Method 200.7 Revision 3.3, Determination of Metals
and Trace Elements By Inductively Coupled Plasma-Atomic Emission
Spectroscopy. U.S. EPA, Washington, DC.

4.	Oklahoma Department of Environmental Quality. 2001. Fish Tissue
Analysis in the Tri-State Mining Area Quality Assurance Project Plan.
Customer Service Division, Oklahoma Department of Environmental
Quality, Oklahoma City, OK.

5.	U.S. EPA. 2000. Guidance For Assessing Chemical Contaminant Data For
Use in Fish Advisories, Volume II: Risk Assessment and Fish Consumption
Limits. U.S. EPA, Washington, DC.

6.	U.S. EPA. 1994. Guidance Manual For The Integrated Exposure Uptake
Biokinetic Model for Lead in Children. U.S. EPA, Washington, DC.

7.	Washington State Department of Health. 2001. Evaluation of Cadmium,
Lead, and Zinc Contamination of Spokane River Fish. Spokane,
Washington.

8.	U.S. EPA. 1994. IRIS: Cadmium. CASRN 7440-43-9. U.S. EPA,
Washington, DC.

9.	U.S. EPA. 1992. IRIS: Zinc and Compounds. CASRN 7440-66-6. U.S. EPA,
Washington, DC.

10.	U.S. CDC(Centers for Disease Control). 1985. Preventing lead poisoning in
young children: a statement by the Centers for Disease Control. CDC report
no. 99-2230, Atlanta, GA.

11.	Morrison Knudson Corporation. 1999. Data from residential yard samples in
the Tar Creek Superfund area. Boise, ID.

12.	Ecology & Environment, Inc. 1995. Tar Creek High Access Areas.

Summary of Response Activities. Dallas, TX.

23

008515


-------
13.	Cates, David, 2003. Background concentrations of soils in Ottawa County.
Memo to Tar Creek File. ODEQ, Oklahoma City, OK.

14.	Kruskal, W.H. 1952. A non-parametric test for the several sample problem.
The Annuls of Mathematical Statistics, 23, 525-540(5.2).

15.	Oklahoma State Department of Health. 1982. An Environmental Health
Evaluation of the Tar Creek Area. OSDH. Oklahoma City, OK.

16.	Schmitt, C.J. and Brumbaugh, W.G. 1990. National Contaminant
Biomonitoring Program: concentrations of arsenic, cadmium, copper, lead,
mercury, selenium, and zinc in fresh water fishes of the United States,
1976-1984. Archives of Environmental Contamination and Toxicology, 19:
731-747. (Data online at http://www.cerc.usgs.gov/data/ncbp/fish.htm

008516

24


-------
Appendix A: Data Tables

Site: TC-MPACP Atlas Chat Pile Pond

Dissolved pH Specific	Vv&ter	Total Total

Gggn	Gnlrtams TenpactLie j%Jinily Brctess

(mg/1)	(umhos/cm)	(deg C)	(mg/1) (mg/1)

Sdids, Dissdved Total Dissdved Total Dissdved Total fMrinm, Lead, Zuc,
SigHifed Qdriim Ckhiun kad kad 2nc(igl) 2rc Sbtoat Sainerl Sbdnol

(mgl/1)	(ug/1) (ug/1) (ug/1) (ug/1)	(ug/1) (mg/kg) (mg/kg) (mg/kg)

6.48 7.57

2639

20.6

Spades

Man
Length
(inches)

Man

Weight
(grams)

Sarnie
Reparation

QVGtegry

Ckiriumin

Hsh (mg/kg)

Lead in

Hsh
(mg/kg)

ZicinRsh
(mg/kg)

Bass, large mouth
Bass, lai'ge mouth
Bass, lai'ge moutii

10.25
10.94
11.63

194
269
300

Fillet	Sample

Whole Eviscerated	Sample

Whole Uneviscerated Sample

<	0.30

<	0.30

<	0.30

< 0.25
0.28
0.70

11

30
32

Site: TC-MPBG

B lue Goose M ill Pond

Dissdved pH Specific	Water Total Total Solids,

Cfcygai	Conductance Temperature Alkalinity Hardness Suspended

(irg/1)	(umhos/cm) (deg Q (mg/1) (rqg/1) (mgl/1)

Dissdved Total Dissdved Total Dissdved Total Cadmium, Lead, Zinc,
Cadmium Cadmium Lead Lead Zinc (ug/1) 2nc Sediment Sediment Sediment
(ug/1) (ug/1) (ug/1) (ug/1)	(ug/1) (mg/kg) (mg/kg) (mg/kg)

7.54 7.74

1409

23.6

Species

Mfean
Length
(indies)

Nfean
Weight
(grams)

Sample
Reparation

QA Category

Cadmiumin
Hsh (mg/kg)

Lead in
Hsh
(mg/kg)

ZincinRsh
tog/kg)

Bass, lai'ge moutii
Bass, lai'ge moutii
Bass, lai'ge moutii

11.56
13.19
13.56

329
482
541

Fillet	Sample

Whole Eviscerated	Sample

Whole Uneviscerated Sample

<	0.30

<	0.30

<	0.30

<	0.25

<	0.25

<	0.25

4.3
17
17

25

008517


-------
Site: TC-MPNWWC

Northwest W estern Chat Pile Pond

Dissolved pH

Specific

Water

Total

Total

Solids,

Dissolved

Total

Dissolved

Total Dissolved

Total Cadmium,

Lead,

Zinc,

Cfcygai

Cbnductance

Temperature

Alkalinity

Hardness

Suspended

Cadmium

Cadmium

Lead

Lead 2nc(ug/l)

Zinc Sediment

Sediment

Sediment

(n«/l)

(umhos/cm)

(degQ

(nsfl)

(ns/1)

(mgJ/l)

(ugfl)

(ugfl)

(ugfl)

(ugfl)

(ugfl) (mg/kg)

(mgftg)

(mg/kg)

11.3 8.48

521

24.2





















Species



Nfean

Nfean



Sample



QA Categcry



Cadmium in

Lead in

Zinc in Hsh







Length

Weight



Reparation







Ksh(ngfeg)

Hsh

(mg/kg)







(inches)

(grams)













(mgfcg)





Bass, large mouth



12.58

450



Fillet



Sample



< 0.30

< 0.25

5.5



Bass, large mouth



13.83

614



Whole Eviscerated

Sample



< 0.30

0.38

15



Bass, large mouth



15.33

889



Whole Uneviscerated

Sample



< 0.30

< 0.25

7.9



Bass, large mouth



15.33

889



Whole Uneviscerated

Lab Duplicate

< 0.30

< 0.25

10



Site:

TC-M PW CP



W estern Chat Pile M ill Pond













Dissolved pH

Specific

Water

Total

Total

Solids,

Dissolved

Total

Dissolved

Total Dissolved

Total Cadmium,

Lead,

Zinc,

Oxygen

Conductance

Temperature

Alkalinity

Hardness

Suspended

Cadmium

Cadmium

Lead

Lead Z5nc(ug/1)

Zinc Sediment

Sediment

Sediment

(mgfl)

(unta/cni)

(dqgQ

(mgfl)

(ns/D

(ngW)

(ugfl)

(ug/D

(ugfl)

(ugfl)

(ugfl) (mg/kg)

(rqg/kg)

(mg/kg)

7.58 7.70

1739

23.4





















Species



Mfean

tyfean



Sample



QA Category



Cadmium in

Lead in

Zinc in Hsh







Length

Weight



Reparation







Hsh(ngfkg)

Hsh

(mg/kg)







(indies)

(grams)













(mg/kg)





Bass, large mouth



8.67

140



Fillet



Sample



< 0.30

< 0.25

5.0



Bass, large mouth



9.50

176



Whole Eviscerated

Sample



< 0.30

< 0.25

16



Bass, large mouth



9.58

190



Whole Uneviscerated

Sample



< 0.30

< 0.25

15



Sunfish, Bluegill



7.80

138



Whole Uneviscerated

Sample



< 0.30

0.37

49



26

008518


-------
Site: TC-NRCB Neosho River @ Conners Bridge

Dissolved pH
Qxygai

to®

Specific
Gnductance
(urrhos/cm)

Water
Temperature
(degQ

Total
Alkalinity
(mg/1)

Total
Hairiness
(irg/1)

Solids,
Suspended
«

Dissolved
Cadmium

(ug/1)

Total
Cadmium
(ugfl)

Dissolved
Lead
(ugfl)

Total
Lead
(ug/1)

Dissolved
2nc(ugfl)

Total Cadmium,
Zinc Sediment
(ug/1) (mg/kg)

Lead,
Sediment
(mg/kg)

Zinc,
Sediment
(mgfcg)

10.1 7.48

170.6

16.9

33.2

88.2

52

< 5.0

< 5.0

< 10

< 10

23

24 < 1

16

112

Species



Nfcan
Length
Cinches)

Nfean
Weight
(grams)



Sample
Reparation



QACategcry



Cadmium in
Ksh(rqgfcg)

Lead in
Bsh
Ccqg/kg)

ZncinRsh
(mg/kg)



Carp



19.00

1305



Fillet



Sample



<

0.30

< 0.25

7.8



Carp



20.33

1922



Whole Eviscerated

Sample



<

0.30

0.35

66



Carp



21.25

2016



Whole Uneviscerated

Sample



<

0.30

0.53

60



Catfish, Channel



16.17

550



Fillet



Sample



<

0.30

< 0.25

6.4



Catfish, Channel



16.17

550



Fillet



Lab Duplicate

<

0.30

< 0.25

6.5



Catfish, Channel



16.75

673



Whole Eviscerated

Sample



<

0.30

< 0.25

21



Catfish, Channel



17.25

767



Whole Uneviscerated

Sample



<

0.30

< 0.25

20



Crappie, White



7.75

94



Fillet



Sample



<

0.30

< 0.25

6.2



Crappie, White



8.83

145



Whole Eviscerated

Sample



<

0.30

< 0.25

13



Crappie, White



9.58

215



Whole Uneviscerated

Sample



<

0.30

< 0.25

12



008519

27


-------
Site: TC-NRECC Neosho River @ Elm Creek Confluence

Dissolved pH
Oxygai
(rpg/1)

Specific
Qnductanoe
(unhos/cm)

Water
Temperature
(degQ

Total
Alkalinity
(nqg/1)

Total
Hardness
(n$l)

Solids,
Suspended
(ngW)

Dissolved
Cadmium
(ugfl)

Total
Cadmium
(ugfl)

Dissolved
Lead
(ug/0

Total
Lead
(ug/0

Dissolved
Znc(ugfl)

Total Cadmium,
2nc Sediment
(ug/1) (mg/kg)

Lead,
Sediment
(mg/kg)

Zinc,
Sediment
(mg/kg)

9.18 8.10

263.4

13.5

79.0

138

52

< 5.0

< 5.0

< 10

< 10

18

13 < 1

14

43

Species



Nfean
Length
Cinches)

Nfean
Weight
(grams)



Sample
Reparation



QA Categay



Cadmium in
Esh(rqg/kg)

Lead in
Bsh
(ngfeg)

2ncinRsh
(mg/kg)



Buffalo, Smallmouth



18.30

1524



Whole Uneviscerated

Sample



<

0.30

0.51

15



Caip



17.33

1146



FL



Sample



<

0.30

0.28

8.7



Caip



19.08

1297



Wiole Eviscerated

Sample



<

0.30

0.93

54



Caip



19.76

1484



Wiole Uneviscerated

Sample



0.30

0.61

43



Catfish, Channel



15.75

442



Fillet



Sample



<

0.30

< 0.25

7.5



Catfish, Channel



15.75

442



Fillet



Lab Duplicate

<

0.30

< 0.25

6.7



Catfish, Channel



17.17

616



Wiole Eviscerated

Sample



<

0.30

< 0.25

16



Catfish, Channel



18.17

802



Wiole Uneviscerated

Sample



<

0.30

0.35

19



Crappie, White



10.17

236



Fillet



Sample



<

0.30

R

6.5



Crappie, Wliite



10.58

259



Wiole Eviscerated

Sample



<

0.30

< 0.25

19



Crappie, Wliite



11.08

317



Wiole Uneviscerated

Sample



<

0.30

0.27

16



008520

28


-------
Lead,

Sediment

(ngfljg)

< 10

2ucinF

(mgfe

6.9

38

61

6.1

6.2

23

18

4.7

11

13

11

Neosho River @ Riverview Park

Water

Total

Total

Solids,

Dissolved

Total

Dissolved

Total

Dissolved

Total

Cadmium,

Tenperature

Alkalinity

Hardness

Suspended

Cadmium

Cadmium

Lead

T pfyj

Zinc (ug/l)

Znc

Sediment

(degQ

(M©

(nefl)

(rqgl/1)

(ugfl)

(ug/l)

(ugfl)

(ug/l)



(ug^l)

(mg/kg)

17.9

30.7

98.9

72

< 5.0

< 5.0

< 10

< 10

22

15

< 1

Mfean	IVfean Sample

Length	Weight Reparation

(indies)	(grams)

17.81	1254	Fillet

19.56	1470	Whole Eviscerated

20.88	1867	Whole Uneviscerated

14.08	338	Fillet

14.08	338	Fillet

15.17	394	Whole Eviscerated

15.83	475	Whole Uneviscerated

9.92	207	Fillet

10.08	248	Whole Eviscerated

10.92	299	Whole Uneviscerated

10.92	299	Whole Uneviscerated

QACategory	Qdniumin	Leadin

Rsh(mgftg)	Fish
(mg/kg)

Sample	< 0.30	<	0.25

Sample	< 0.30	<	0.25

Sample 0.30	0.36

Sample	< 0.30	<	0.25

Lab Duplicate	< 0.30	<	0.25

Sample	< 0.30	0.28

Sample	< 0.30	<	0.25

Sample	< 0.30	<	0.25

Sample	< 0.30	<	0.25

Sample	< 0.30	<	0.25

Lab Duplicate	< 0.30	<	0.25


-------
Site: TC-SRBH Spring River @ Blue Hole

Dissolved

PH

Specific

Water

Total

Total

Solids,

Dissolved

Total

Dissolved

Total

Dissolved

Total

Cadmium,

Lead,

Zinc,

Oxygai



Conductance

Temperature

Alkaliiiity

Hairiness

Suspended

Cadmium

Cadmium

Lead

Lead

2nc(ugfl)

Znc

Sediment

Sediment

Sediment

to®



(urrhosfcm)

(degQ

(mg/1)

(PS©

fatf/D

(ug/0

(ugfl)

(ugfl)

(ug/0



(ug/0

(mg/kg)

(mg/kg)

(mgfcg)

8.20

7.74

220

15.4

77.2

106

46

< 5.0

A
O

< 10

< 10

90

186

4

39

754

Species

IVfean
Length
Cinches)

Nfean
Weight
(grams)

Sample
Reparation

QA Category

Cadmium in
Ksh(rqgftg)



Lead in
Ksh
(mg/kg)

Zncifl
fag/

Bass, Spotted

7.17

70

Fillet

Sample

<

0.30

<

0.25

8.0

Bass, Spotted

7.58

85

Whole Eviscerated

Sample

<

0.30

<

0.25

33

Bass, Spotted

8.00

105

Whole Uneviscerated

Sample

<

0.30

<

0.25

20

Buffalo, Smallmouth

17.40

1180

Whole Uneviscerated

Sample

<

0.30



2.5

48

Buffalo, Smallmouth

17.40

1180

Whole Uneviscerated

Lab Duplicate

<

0.30



2.1

42

Carp

18.00

1196

Fillet

Sample

<

0.30

<

0.25

16

Carp

19.08

1522

Whole Eviscerated

Sample

<

0.30



1.0

62

Carp

19.92

1762

Whole Uneviscerated

Sample



0.84



1.7

70

Catfish, Channel

14.92

407

Fillet

Sample

<

0.30

<

0.25

3.5

Catfish, Channel

14.92

407

Fillet

Lab Duplicate

<

0.30

<

0.25

4.1

Catfish, Channel

16.08

503

Whole Eviscerated

Sample

<

0.30



R

20

Catfish, Channel

16.92

650

Whole Uneviscerated

Sample

<

0.30



0.88

38

008522

30


-------
Site: TC-SRMB Spring River @ Mocassin Bend

Dissolved pH

Specific

Water

Total

Total

Solids,

Dissolved

Total

Dissolved

Total

Dissolved

Total

Cadmium,

Lead,

Zinc,

Oxygen

Cfriductanoe

Temperature

Alkalinity

Hardness

Suspended

Cadmium

Cadmium

Lead

Lead

Zinc(ugfl)

Zinc

Sediment

Sediment

Sediment

(rpg/1)

(unhos/oq)

(degQ

(mg/l)

fafl)

(mgl/1)

(ug/1)

(ug/1)

(ugtt)

(ug/1)



(ug/1)

(msfeg)

(mgfeg)

(mg/kg)

7.34 7.86

223

14.0

92.3

119

45

< 5.0

A
O

< 10

< 10

73

136

3

53

725

Species

Wean

IVfean

Sample

QA Category

Cadmium in

Lead in

ZncinRsh



Length

Weight

Reparation



Ksh(mgfeg)

Ksh

(mg/kg)



(indies)

(grams)







(mgftg)



Bass, White

14.80

746

Wiole Uneviscerated

Sample

< 0.30

< 0.25

16

Buffalo, Smallmouth

16.45

1105

Wiole Uneviscerated

Sample

< 0.30

0.88

21

Caip

19.33

1584

Fillet

Sample

< 0.30

< 0.25

4.2

Carp

20.08

1763

Wiole Eviscerated

Sample

< 0.30

1.9

62

Carp

22.33

2070

Wiole Uneviscerated

Sample

0.56

3.5

53

Catfish, Channel

15.88

501

Fillet

Sample

< 0.30

< 0.25

6.7

Catfish, Channel

16.88

660

Wiole Eviscerated

Sample

< 0.30

0.50

16

Catfish, Channel

18.13

868

Wiole Uneviscerated

Sample

< 0.30

0.42

30

Crappie, White

10.75

294

Fillet

Sample

< 0.30

< 0.25

6.0

Crappie, Wiite

10.75

294

Fillet

Lab Duplicate

< 0.30

< 0.25

5.4

Crappie, Wiite

11.50

379

Wiole Eviscerated

Sample

< 0.30

< 0.25

27

Crappie, Wliite

13.31

585

Wiole Uneviscerated

Sample

< 0.30

0.26

21

Sunfish, Bluegill

6.05

67

Wiole Uneviscerated

Sample

< 0.30

0.57

32

008523

31


-------
Site: TC-SRTB Spring River @ Twin Bridges SP

Dissolved pH
Oxygen

fa®

Specific
Conductance
(umhos/cm)

Water
Temperature

(degQ

Total
Alkalinity

One®

Total
Hardness
(mg/1)

Solids, Dissolved
Suspended Cadmium
(mgl/1) (ug/1)

Total Dissolved
Cadmium Lead
(ug/1) (ug/1)

Total
Lead
(ug®

Dissolved
Zinc (ug/1)

Total Cadmium,
Znc Sediment
(ug/1) (mg/kg)

Lead,
Sediment
(mg/kg)

7mc,
Sediment
(mgfeg)

6.90 7.85

178.2

16.1

58.0

85.9

54 < 5.0

< 5.0 < 10

< 10

61

115 5

23

507

species



Nfean
Length
Cinches)

IVfean
Weight
(grams)



Sample
Preparation

QA Category

Cadniumin
Ksh (mg/kg)

Leadin
Rsh
(mg/kg)

2ncinHsh
(ti®/kg)



Bass, White



15.15

696



Whole Uneviscerated

Sample

<

0.30

< 0.25

23



Bass, large mouth



15.45

1016



Whole Uneviscerated

Sample

<

0.30

< 0.25

9.8



Buffalo, Smallmouth



17.45

1349



Whole Uneviscerated

Sample

<

0.30

0.95

19



Carp



18.19

1273



Fillet

Sample

<

0.30

< 0.25

10



Carp



18.75

1362



Whole Eviscerated

Sample

<

0.30

1.8

55



Carp



20.00

1568



Whole Uneviscerated

Sample



0.30

1.9

53



Catfish, Channel



13.17

272



Fillet

Sample

<

0.30

< 0.25

6.7



Catfish, Channel



13.17

272



Fillet

Lab Duplicate

<

0.30

< 0.25

4.8



Catfish, Channel



13.50

308



Whole Eviscerated

Sample

<

0.30

< 0.25

10



Catfish, Channel



16.08

558



Whole Uneviscerated

Sample

<

0.30

0.33

20



Crappie, White



10.45

265



Fillet

Sample

<

0.30

< 0.25

5.4



Crappie, White



10.85

317



Whole Eviscerated

Sample

<

0.30

< 0.25

8.1



Crappie, White



11.65

399



Whole Uneviscerated

Sample

<

0.30

< 0.25

14



Sunfish, Bluegill



5.25

42



Fillet

Sample

<

0.30

< 0.25

8.3



Sunfish, Bluegill



5.08

37



Fillet

Field Replicate

<

0.30

< 0.25

7.2



Sunfish, Bluegill



5.08

37



Fillet

Lab Duplicate

<

0.30

< 0.25

7.9



Sunfish, Bluegill



5.50

50



Whole Eviscerated

Field Replicate

<

0.30

< 0.25

23



Sunfish, Bluegill



6.00

65



Whole Eviscerated

Sample

<

0.30

0.25

25

3:

008524


-------
Site: TC-SRTB Spring River @ Twin Bridges SP (cont.)

Swedes Afean	Nfean	Sample	QACategcry CadmLumin	Leadin	2ncinHsh

Length	Weight	Rneparation	Ksh(mgfeg)	Hsh	(mgfeg)

(inches)	(grams)	(mgftg)

Sunfish, Bluegill 6.75 98	Whole Uneviscerated	Sample	< 0.30	< 0.25	17

Sunfish, Bluegill 6.25 80	Whole Uneviscerated	Field Replicate	< 0.30	0.27	19

008525

33


-------
Appendix C
RAGS Part D Tables

008526


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
008527

FEBRUARY 2006


-------
TABLE 1

SELECTION OF EXPOSURE PATHWAYS
Tar Creek - Miami, OK

Scenario
Timeframe

Medium

Exposure
Medium

Exposure
Point

Receptor
Population

Receptor
Age

Exposure
Route

Type of
Analysis

Rationale for Selection or Exclusion
of Exposure Pathway

Current

Surface Soil

Surface Soil

Surface Soil (0-1 inch)



Adult/Child

Ingestion

Quant (1)

Resident may contact COPCs in soil.





(Yards)



Resident



Dermal

Quant

Resident may contact COPCs in soil.





Dust

Indoor Dust

(General Public)

Child

Ingestion

Quant (2)

Child resident may contact lead in indoor dust.

Current/Future

Groundwater

Groundwater

Private wells



Adult/Child

Ingestion

Quant (4)

Resident may drink water from shallow well impacted by COPCs.

Current/Future

Fish Tissue

Fish Tissue

Fish



Adult/Child

Ingestion

Qual (5)

This pathway previously evaluated (ODEQ, 2003); will be discussed in the Risk
Characterization Section.

Current/Future

Chat Pile Material and
Tailings

Ambient Air

Ambient Air



Adult/Child

Inhalation

Quant

Residents may contact COPCs in ambient air

Future

Chat pile, tailings,
residential soil, smelter
soil, transition zone soil

Surface Soil (Yards)

Surface Soil (0-1 inch)



Adult/Child

Ingestion

Quant (8)

Future residents may contact COPCs in soil as a results of 30 years of airborne
deposition.













Dermal

Quant (8)



Current

Surface Soil

Surface Soil

Surface Soil (0-1 inch)



Adult/Child

Ingestion

Quant

Resident may contact COPCs in soil.





(Yard)







Dermal

Quant





Dust

Indoor Dust

Resident

Child

Ingestion

Quant (2)

Child resident may contact lead in indoor dust.

Current

Surface Soil

Animal Tissue

Small Game
(Bird, Rabbit)

(Subsistence)

Adult

Ingestion

Quant (6, 10)

Subsistence resident may ingest plants grown on, and meat from animals



(residential, smelter,
transition zone)



Large Game
(Deer, Elk)







Qual (9, 12)

grazing on, soil in the area.







Beef (cattle)







Quant (6, 11)







Milk (dairy)

Milk (dairy)



Child

Ingestion

Quant (11)



Current/Future

Chat Pile Material and
Tailings

Ambient Air

Ambient Air



Adult/Child

Inhalation

Quant

Residents may contact COPCs in ambient air

Current/Future

Groundwater

Groundwater

Private wells



Adult/Child

Ingestion

Quant (4)

Residents may drink water from shallow well impacted by COPCs; includes
potential impact from sweat lodge.

Current/Future

Aquatic Biota

Fish Tissue

Fish



Adult

Ingestion

Quant (6,7,10)







Aquatic Food
(Mussels etc.)

Aquatic Tissue















Unwashed

Asparagus
(above ground plant & root)









Residents may ingest fish & aquatic organisms caught in the Tar Creek area, as
well as plants grown in the vicinity of chat piles.

Current

Transition Zone Soil

Plant

Willow

(above ground plant & root)















(Leaf & Root)

Cattail

(above ground plant & root)















Washed

Asparagus
(above ground plant & root)











Current

Transition Zone Soil

Plant

Willow

(above ground plant & root)



Adult

Ingestion

Qual

Exposures to unwashed plants are addressed in the HHRA; washed plants wiii
be addressed in the uncertainty section of the HHRA.





(Leaf & Root)

Cattail

(above ground plant & root)











Future

Chat Pile and Tailings

Surface Soil (Yards,
Smelter-Affected
Soil, Transition
Zone Soil)

Surface Soil (0-1 inch)



Adult/Child

Ingestion

Quant (8)

Future residents may contact COPCs in soil as a results of 30 years of airborne
deposition.













Dermal

Quant (8)



Current/Future

Chat and Tailings

Surface Material

Chat & Tailings Ponds
surface (0-6 inch)

Recreator

Adolescent

Ingestion

Quant

Recreators may drive recreational vehicles atop chat piles, chat bases, and miii
ponds



Material









Dermal

Quant

* Noncarcinogenic hazard evaluated separately for adult and child receptors, combined lifetime carcinogenic risk evaluated on an age-adjusted basis for residential scenario.

(1)	Surface soil is evaluated for each individual home for lead; the maximum concentrations of all yards in Tar Creek are used for evaluation of cadmium and zinc.

(2)	Risk associated with dust is evaluated for lead using the default soil/dust ratio in the IEUBK model.

(3)	Risk associated with inhalation of ambient air (particulate emission) is evaluated for lead using the IEUBK model.

(4)	Groundwater is evaluated for each shallow well at an individual home for lead; the maximum concentrations of groundwater for all shallow wells sampled are used for evaluation of cadmium and zinc.

(5)	Risk associated with ingestion offish by general public have been evaluated by ODEQ (2003) and is not re-evaluated.

(6)	Two adult subsistence scenarios (1 -high fish diet and 2-high beef diet) are evaluated based on the exposure assumptions presented in the Spokane Tribe study (Harper et. al., 2002).

(7)	Fish concentrations presented in the ODEQ study are used (ODEQ, 2003).

(8)	The range of future soil concentrations are evaluated via air deposition modeling.

(9)	The difference in bioconcentration between beef and large game animals, and the affect on risk estimates, are presented in the Risk Characterization section.

(10)	Bioconcentration factors for aquatic food were obtained from the Tar Creek Ecological Risk Assessment.

(11)	Bioconcentration factors were obtained from EPA Combustion Guidance.

(12)	Bioconcentration factors were obtained from the open literature.

008528

1 of 1


-------
Table 2.1

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Medium: Chat and Tailings Material
Exposure Medium: Surface Material

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(4)







(5)

Chat Pile & Tailings Ponds

7429-90-5

ALUMINUM

102

11500 J,B

mg/kg

FT2331-1-7S

94/94

1.1 -27.5

11500

9183

7.62E+04 N

NA



No

BSL

Surface (0-6 inch)

7440-36-0

ANTIMONY

0.2 J,-

3.1 L,J

mg/kg

TC4-SO-01E

60/94

0.2-8.3

3.1

0.25

3.13E+01 N

NA



No

BSL



7440-38-2

ARSENIC

2.4

26.4 J,B

mg/kg

FT2322-13-7S

90/94

0.17-5

26.4

6.3

3.90E-01 C

NA



No

BKG



7440-39-3

BARIUM

2.6 L,J

58.9

mg/kg

TC4-SO-31D01

79/94

0.021 - 27.5

58.9

97.6

5.47E+03 N

NA



No

BSL



7440-41-7

BERYLLIUM

0.0065 L,J

1 J

mg/kg

FT2331-1-7S

67/94

0.017-4

1

0.54

1.54E+02 N

NA



No

BSL



7440-43-9

CADMIUM

10.4

197

mg/kg

TC4-SO-01P

97/97

0.029 - 0.69

197

0.73

3.90E+01 N

NA



Yes

ASL



7440-70-2

CALCIUM

7400

99900

mg/kg

FT2322-7-7S

94/94

2-689

99900

1715

NA

NA



No

NUT



7440-47-3

CHROMIUM, TOTAL

2.5 J,v

50 J,+

mg/kg

FT2322-13-7S

86/94

0.099-10

50

18

2.11E+02 C

NA



No

BSL



7440-48-4

COBALT

0.68 L,J

23.3

mg/kg

TC4-SO-161

76/94

0.092-20

23.3

6.5

9.03E+02 C

NA



No

BSL



7440-50-8

COPPER

28.5 J,v

824 J,v

mg/kg

TC4-SO-01N01

94/94

0.1 -3.4

824

4.88

2.91 E+03 N

NA



No

BSL



7439-89-6

IRON

2690

22700 J,B

mg/kg

FT2322-13-7S

94/94

1.4- 13.8

22700

14011

2.25E+04 N

NA



No

NUT



7439-92-1

LEAD

175

39600

mg/kg

FT2322-13-7S

97/97

0.14-2.7

39600

31.25

4.00E+02 AL

NA



Yes

ASL



7439-95-4

MAGNESIUM

1980

24800

mg/kg

TC4-SO-45F

94/94

1.3 - 689

24800

688

NA

NA



No

NUT



7439-96-5

MANGANESE

53.1

413

mg/kg

TC4-SO-16I

94/94

0.02-2.1

413

515

3.24E+03 N

NA



No

BSL



7487-94-7

MERCURY

0.01 L,J,v

1.4

mg/kg

TC4-SO-14H

90/94

0.01 -0.14

1.4

0.045

2.35E+01 N

NA



No

BSL



7487-94-7

NICKEL

5.1 J,v

50 J

mg/kg

FT2322-13-7S

90/94

0.051 -10

50

0.045

2.35E+01 N

NA

-

No

NS



7440-09-7

POTASSIUM

174 L,J,v

3340 J,+

mg/kg

FT2322-13-7S

34/94

0.6-689

3340

625

NA

NA

-

No

NUT



7782-49-2

SELENIUM

0.34 L,J

19

mg/kg

FT2322-13-7S

50/94

0.27-10

19

0.34

3.91 E+02 N

NA

-

No

BSL



7440-22-4

SILVER

0.18 L,J

3.4

mg/kg

TC4-SO-01P

20/94

0.17-20

3.4

1

3.91 E+02 N

NA

-

No

BSL



7440-23-5

SODIUM

50 J

90900 J,v

mg/kg

TC4-SO-14H

59/94

33.7 - 689

90900

21.88

NA

NA

-

No

NUT



7440-28-0

THALLIUM

0.05 J

30.7 J

mg/kg

FT2322-13-7S

25/94

0.36 - 3.4

30.7

0.15

6.26E+00 N

NA

-

No

SD



7440-62-2

VANADIUM

2.3 L,J,v

40 J,+

mg/kg

FT2322-13-7S

81/94

0.096-6.9

40

32.45

7.82E+01 N

NA

-

No

BSL



7440-66-6

ZINC

2200 J,v

42200 J,v

mg/kg

TC4-SO-14H

97/97

0.044 - 30.2

42200

83.25

2.35E+04 N

NA



Yes

ASL

(1)

(2)

(3)

(4)

(5)

Definition of the Qualifier codes used for the "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.
Maximum concentration is used for screening.

Mean background values obtained from the Preliminary Site Characterization Summary prepared by AATA International Inc. (2005).
EPA Region 6 Medium-Specific Screening Levels (MSSL) 2004-2005 for Residential Soil (December, 2004).

Rationale Codes

Selection Reason: Above Screening Level (ASL)

Deletion Reason: Below Screening Level (BSL)

Essential Nutrient (NUT)

Not Significantly Above Typical Background (BKG)

Not Significantly Above Screening Level and Not Widespread (NS)

Single Detection Above Screening Level (SD)

COPC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/
To Be Considered

C = Carcinogenic
N = Noncarcinogenic
NA = Not available

Page 1 of 1

008529


-------
Table 2.2

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
(Supplemental Table for residential and transition zone soil only)

Tar Creek, Miami, OK

Scenario Timeframe: Current/Future

Medium: Surface Soil (residential, rural areas, and transition zone)
Exposure Medium: Animal Tissue	

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(4)







(5)

Small Game (Bird, Rabbit),

7440-99-9

ALUMINUM

723

18500 J

mg/kg

TZ2321-11N-4A

40/40

1.1-1.2

18500

9183

7.62E+04 N

NA



No

BSL

Beef (Cattle), and Milk (Dairy)

7440-99-9

ANTIMONY

0.2

0.9

mg/kg

RS2332-14FS

18/40

0.38 - 0.4

0.9

0.25

3.13E+01 N

NA

-

No

BSL



7440-99-9

ARSENIC

2.6

37.9

mg/kg

TZ2223-1S-4A

40/40

0.17-0.18

37.9

6.3

3.90E-01 C

NA

-

No

SW



744-03- 9

BARIUM

8.9

878

mg/kg

TZ2223-1S-4A

40/40

0.021 - 0.022

878

97.6

5.47E+03 N

NA

-

No

BSL



744-04- 1

BERYLLIUM

0.15 L,J

2.4

mg/kg

TZ2321-11S-3A*

39/40

0.017-0.018

2.4

0.54

1.54E+02 N

NA

-

No

BSL



744-04- 3

CADMIUM

0.5 J

248

mg/kg

TZ2223-1S-3A

249 / 261

0.029-0.031

248

0.73

3.90E+01 N

NA

-

Yes

ASL



744-07- 0

CALCIUM

570

33800

mg/kg

TZ2321-11S-3A*

40/40

2-2.1

33800

1715

NA

NA

-

No

NUT



7440-47-3

CHROMIUM, TOTAL

4.4 J,v

40

mg/kg

TZ2321-11S-3A*

40/40

0.099-0.11

40

18

2.11E+02 C

NA

-

No

BSL



744-04- 8

COBALT

1.2 L,J

370

mg/kg

TZ2223-1S-4A

39/40

0.092-0.1

370

6.5

9.03E+02 C

NA

-

No

BSL



744-05- 0

COPPER

4 J

202

mg/kg

TZ2321-11S-3A*

40/40

0.1 -0.11

202

4.88

2.91 E+03 N

NA

-

No

BSL



7439-89-6

IRON

5760

104000

mg/kg

TZ2223-1S-4A

40/40

1.4 - 1.5

104000

14011

2.25E+04 N

NA

-

No

NUT



743-99- 2

LEAD

10.5

4450

mg/kg

TZ2321-11N-7A

316/317

0.14-0.20

4450

31.25

4.00E+02 AL

NA

-

Yes

ASL



743-99- 5

MAGNESIUM

478 L,J

16600

mg/kg

TZ2321-11S-3A*

40/40

1.3-4.5

16600

688

NA

NA

-

No

NUT



7439-96-5

MANGANESE

110

69000

mg/kg

TZ2223-1S-4A

40/40

0.02-0.021

69000

515

3.24E+03 N

NA

-

No

SD



7440-99-9

MERCURY

0.015 L,J

1.75 J

mg/kg

TZ2321-11S-3A*

14/40

0.01 -0.011

1.75

0.045

2.35E+01 N

NA

-

No

BSL



744-00- 2

NICKEL

3 J

1430

mg/kg

TZ2223-1S-4A

40/40

0.051 - 0.054

1430

0.045

2.35E+01 N

NA

-

No

TD



744-00- 9

POTASSIUM

370

3000

mg/kg

TZ2321-11S-3A*

33/40

0.6 - 0.64

3000

625

NA

NA

-

No

NUT



778-24- 9

SELENIUM

0.44 L,J

6.2 J,B,+

mg/kg

TZ2321-11S-3A*

19/40

0.27-0.29

6.2

0.34

3.91 E+02 N

NA

-

No

BSL



7440-99-9

SILVER

20 J

20 J

mg/kg

TZ2223-1S-4A

1 /40

0.17-0.18

20

1

3.91 E+02 N

NA

-

No

BSL



744-02- 3

SODIUM

30 J

25300

mg/kg

TC4-SO-45Y

20/40

33.7-35.9

25300

21.88

NA

NA

-

No

NUT



744-02- 8

THALLIUM

0.06 J

0.7

mg/kg

TZ2321-11S-3A*

32/40

0.36-0.38

0.7

0.15

6.26E+00 N

NA

-

No

BSL



744-06- 2

VANADIUM

4.1 L,J

40.9

mg/kg

BS2318-1

40/40

0.096-0.1

40.9

32.45

7.82E+01 N

NA

-

No

BSL



744-06- 6

ZINC

38 J,B

39200

mg/kg

TZ2321-11S-4A, TZ2430-1N-1A

260 / 261

0.044 - 0.047

39200

83.25

2.35E+04 N

NA

-

Yes

ASL

(1)

(2)

(3)

(4)

(5)

Definition of the Qualifier codes used for the "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.
Maximum concentration is used for screening.

Mean background values obtained from the Preliminary Site Characterization Summary prepared by AATA International Inc. (2005).
EPA Region 6 Medium-Specific Screening Levels (MSSL) 2004-2005 for Residential Soil (December, 2004).

Rationale Codes

Selection Reason: Above Screening Level (ASL)

Deletion Reason: Below Screening Level (BSL)

Smelter Waste (SW)

Essential Nutrient (NUT)

Single Detection Above Screening Level (SD)

Two Detections Above Screening Level (TD)

COPC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/
To Be Considered

AL = Action Level
C = Carcinogenic
N = Noncarcinogenic
NA = Not available

Revised 02/09/2006

008530

Page 1 of 1


-------
Table 2.2A

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
(Supplemental Table for smelter affected soil only)

Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Medium: Surface Soil (smelter affected soil)
Exposure Medium: Animal Tissue	

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(4)







(5)

Small Game (Bird, Rabbit),

7440-99-9

ALUMINUM

3670

10200

mg/kg

TC4-SO-46M

6/6



10200

9183

7.62E+04 N

NA



No

BSL

Beef (Cattle), and Milk (Dairy)

7440-99-9

ANTIMONY

1.4 J,-

4600

mg/kg

TC4-SO-46M

20/21



4600

0.25

3.13E+01 N

NA

-

No

SW



7440-99-9

ARSENIC

2.3

285

mg/kg

TC4-SO-46M

6/6



285

6.3

3.90E-01 C

NA

-

No

SW



744-03- 9

BARIUM

47.5

1040

mg/kg

TC4-SO-46M

6/6



1040

97.6

5.47 E+03 N

NA

-

No

BSL



744-04- 1

BERYLLIUM

0.53

1.7

mg/kg

TC4-SO-46M

4/6



1.7

0.54

1.54E+02 N

NA

-

No

BSL



744-04- 3

CADMIUM

0.35 L,J

139

mg/kg

SS2324-1N-1

21 / 21



139

0.73

3.90E+01 N

NA

-

Yes

ASL



744-07- 0

CALCIUM

549

25400

mg/kg

TC4-SO-46M

6/6



25400

1715

NA

NA

-

No

NUT



7440-47-3

CHROMIUM, TOTAL

4.9

20.5

mg/kg

TC4-SO-46M

6/6



20.5

18

2.11E+02 C

NA

-

No

BSL



744-04- 8

COBALT

2.2 L,J

11.6

mg/kg

TC4-SO-46K01

6/6



11.6

6.5

9.03E+02 C

NA

-

No

BSL



744-05- 0

COPPER

4.5 J,v

307 J,v

mg/kg

TC4-SO-46M

6/6



307

4.88

2.91 E+03 N

NA

-

No

BSL



7439-89-6

IRON

4460

44800

mg/kg

TC4-SO-46M

6/6



44800

14011

2.25E+04 N

NA

-

No

NUT



743-99- 2

LEAD

31.4

70800

mg/kg

TC4-SO-46K01

21 / 21



70800

31.25

4.00E+02 AL

NA

-

Yes

ASL



743-99- 5

MAGNESIUM

261 L,J,v

3100 J,v

mg/kg

TC4-SO-46L

6/6



3100

688

NA

NA

-

No

NUT



7439-96-5

MANGANESE

119

470

mg/kg

TC4-SO-46K01

6/6



470

515

3.24E+03 N

NA

-

No

BSL



7440-99-9

MERCURY

0.02 L,J

0.23

mg/kg

TC4-SO-46L

4/6



0.23

0.045

2.35E+01 N

NA

-

No

BSL



744-00- 2

NICKEL

7.7

41.2

mg/kg

TC4-SO-46M

5/6



41.2

0.045

2.35E+01 N

NA

-

No

TD



744-00- 9

POTASSIUM

595

1250

mg/kg

TC4-SO-46M

3/6



1250

625

NA

NA

-

No

NUT



778-24- 9

SELENIUM

0.3 L,J

7

mg/kg

TC4-SO-46K01

6/6



7

0.34

3.91 E+02 N

NA

-

No

BSL



7440-99-9

SILVER

0.41 L,J

1.2

mg/kg

TC4-SO-46M

3/6



1.2

1

3.91 E+02 N

NA



No

BSL



744-02- 3

SODIUM

183 L,J

24700

mg/kg

TC4-SO-46M

6/6



24700

21.88

NA

NA



No

NUT



744-02- 8

THALLIUM

0.46 L,J

1.4 L,J

mg/kg

TC4-SO-46M

3/6



1.4

0.15

6.26 E+00 N

NA



No

BSL



744-06- 2

VANADIUM

12.2

30.3

mg/kg

TC4-SO-46M

6/6



30.3

32.45

7.82E+01 N

NA



No

BSL



744-06- 6

ZINC

46.1

7980

mg/kg

TC4-SO-46M

21 / 21



7980

83.25

2.35 E+04 N

NA



Yes

AOC

(1)

(2)

(3)

(4)

(5)

Definition of the Qualifier codes used forthe "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.
Maximum concentration is used for screening.

Mean background values obtained from the Preliminary Site Characterization Summary prepared by AATA International Inc. (2005).
EPA Region 6 Medium-Specific Screening Levels (MSSL) 2004-2005 for Residential Soil (December, 2004).

Rationale Codes

Selection Reason: Above Screening Level (ASL)

Administrative Order on Consent (AOC)

Deletion Reason: Below Screening Level (BSL)

Essential Nutrient (NUT)

Within Background Range (BKG)

COPC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/
To Be Considered

AL = Action Level
C = Carcinogenic
N = Noncarcinogenic
NA = Not available

Revised 02/09/2006

008531

Page 1 of 1


-------
Table 2.3

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
Tar Creek, Miami, OK

Scenario Timeframe: Current

Medium: Surface Soil

Exposure Medium: Surface Soil (Yards)

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(4)







(5)

Surface Soil

7440-99-9

ALUMINUM

6800 J

12600 J

mg/kg

RS2417-30BS

16/16



12600

9183

7.62E+04 N

NA



No

BSL

(General Public)

7440-99-9

ANTIMONY

0.2

0.9

mg/kg

RS2332-14FS

5/16



0.9

0.25

3.13E+01 N

NA



No

BSL

(0-1 inch)

7440-99-9

ARSENIC

2.6

9.1

mg/kg

RS2332-14FS

16/16



9.1

6.3

3.90 E-01 C

NA



No

BKG



744-03- 9

BARIUM

52.9

177

mg/kg

RS2429-27SS

16/16



177

97.6

5.47 E+03 N

NA



No

BSL



744-04- 1

BERYLLIUM

0.4 J

0.9 J

mg/kg

RS2406-40NS, RS2417-30BS

16/16



0.9

0.54

1.54E+02 N

NA



No

BSL



744-04- 3

CADMIUM

0.5 J

47.5

mg/kg

RS2332-14FS

164/172



47.5

0.73

3.90E+01 N

NA



Yes

ASL



744-07- 0

CALCIUM

1850

11800

mg/kg

RS2419-45NS

16/16



11800

1715

NA

NA



No

NUT



7440-47-3

CHROMIUM, TOTAL

8

21

mg/kg

RS2406-40NS, RS2417-30BS

16/16



21

18

2.11E+02 C

NA



No

BSL



744-04- 8

COBALT

3 J

8

mg/kg

RS2420-35NS

16/16



8

6.5

9.03 E+02 C

NA



No

BSL



744-05- 0

COPPER

4 J

61

mg/kg

RS2332-14FS

16/16



61

4.88

2.91 E+03 N

NA



No

BSL



7439-89-6

IRON

6580

17800

mg/kg

RS2431-22SS

16/16



17800

14011

2.25 E+04 N

NA



No

BSL



743-99- 2

LEAD

10.9 J

822

mg/kg

RS2318-16BS

171 /172



822

31.25

4.00E+02 AL

NA



Yes

ASL



743-99- 5

MAGNESIUM

610

2840

mg/kg

RS2419-45NS

16/16



2840

688

NA

NA



No

NUT



7439-96-5

MANGANESE

184

706

mg/kg

RS2420-35NS

16/16



706

515

3.24 E+03 N

NA



No

BSL



7440-99-9

MERCURY

0.08

0.38

mg/kg

RS2236-9BS

4/16



0.38

0.045

2.35E+01 N

NA



No

BSL



744-00- 2

NICKEL

3 J

15

mg/kg

RS2431-22SS

16/16



15

0.045

2.35E+01 N

NA



No

BSL



744-00- 9

POTASSIUM

530

1710

mg/kg

RS2301-17NS

16/16



1710

625

NA

NA



No

NUT



778-24- 9

SELENIUM

0.6 J

1.3

mg/kg

RS2332-14FS

3/16



1.3

0.34

3.91 E+02 N

NA



No

BSL



744-02- 3

SODIUM

30

130

mg/kg

RS2226-5NS

6/16



130

21.88

NA

NA



No

NUT



744-02- 8

THALLIUM

0.06 J

0.21 J

mg/kg

RS2417-30BS

16/16



0.21

0.15

6.26 E+00 N

NA



No

BSL



744-06- 2

VANADIUM

15.7

24

mg/kg

RS2417-30BS

16/16



24

32.45

7.82E+01 N

NA



No

BSL



744-06- 6

ZINC

38 J,B

7700

mg/kg

RS2332-14FS

171 /172



7700

83.25

2.35 E+04 N

NA



Yes

AOC

(1)	Definition of the Qualifier codes used for the "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.

(2)	Maximumcon centrati onisusedforscreening.

(3)	Mean background values obtained from the Preliminary Site Characterization Summary prepared by AATA International Inc. (2005).

(4)	EPA Region 6 Medium-Specific Screening Levels (MSSL) 2004-2005 for Residential Soil (December, 2004).

(5)	Rationale Codes

Selection Reason: Above Screening Level (ASL)

Administrative Order on Consent (AOC)

Deletion Reason: Below Screening Level (BSL)

Essential Nutrient (NUT)

Within Background Range (BKG)

CO PC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/
To Be Considered

AL = Action Level
C = Carcinogenic
N = Noncarcinogenic
NA = Not available

Revised 02/09/2006

008532

Page 1 of 1


-------
Table 2.4

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
Tar Creek, Miami, OK

Scenario Timeframe: Current

Medium: Surface Soil

Exposure Medium: Surface Soil (Yards)

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(4)







(5)

Surface Soil

7429-90-5

ALUMINUM

14600 J

14600 J

mg/kg

RS2406-20BS

1/1



14600

9183

7.62E+04 N

NA



No

BSL

(Subsistence)

7440-36-0

ANTIMONY

0.3

0.3

mg/kg

RS2406-20BS

1/1



0.3

0.25

3.13E+01 N

NA

-

No

BSL

(0-1 inch)

7440-38-2

ARSENIC

8.1

8.1

mg/kg

RS2406-20BS

1/1



8.1

6.3

3.90E-01 C

NA

-

No

BKG



7440-39-3

BARIUM

142

142

mg/kg

RS2406-20BS

1/1



142

97.6

5.47E+03 N

NA

-

No

BSL



7440-41-7

BERYLLIUM

0.8 J

0.8 J

mg/kg

RS2406-20BS

1/1



0.8

0.54

1.54E+02 N

NA

-

No

BSL



7440-43-9

CADMIUM

0.6 J

9.6

mg/kg

RS2431-44FS

6/9

0.5-0.5

9.6

0.73

3.90E+01 N

NA

-

Yes

AOC



7440-70-2

CALCIUM

1520

1520

mg/kg

RS2406-20BS

1/1



1520

1715

NA

NA

-

No

NUT



7440-47-3

CHROMIUM, TOTAL

27

27

mg/kg

RS2406-20BS

1 /1



27

18

2.11E+02 C

NA



No

BSL



7440-48-4

COBALT

11

11

mg/kg

RS2406-20BS

1 /1



11

6.5

9.03 E+02 C

NA



No

BSL



7440-50-8

COPPER

7

7

mg/kg

RS2406-20BS

1 /1



7

4.88

2.91 E+03 N

NA



No

BSL



7439-89-6

IRON

16900

16900

mg/kg

RS2406-20BS

1 /1



16900

14011

2.25E+04 N

NA



No

BSL



7439-92-1

LEAD

26.6 J

135

mg/kg

RS2431-44FS

9/9



135

31.25

4.00 E+02 AL

NA



Yes

AOC



7439-95-4

MAGNESIUM

1080

1080

mg/kg

RS2406-20BS

1 /1



1080

688

NA

NA



No

NUT



7439-96-5

MANGANESE

621

621

mg/kg

RS2406-20BS

1 /1



621

515

3.24E+03 N

NA



No

BSL



7487-94-7

NICKEL

11

11

mg/kg

RS2406-20BS

1 /1



11

0.045

2.35E+01 N

NA



No

BSL



7440-09-7

POTASSIUM

1460

1460

mg/kg

RS2406-20BS

1 /1



1460

625

NA

NA



No

NUT



7782-49-2

SELENIUM

0.5

0.5

mg/kg

RS2406-20BS

1 /1



0.5

0.34

3.91 E+02 N

NA



No

BSL



7440-28-0

THALLIUM

0.17 J

0.17 J

mg/kg

RS2406-20BS

1 /1



0.17

0.15

6.26E+00 N

NA



No

BSL



7440-62-2

VANADIUM

34.3

34.3

mg/kg

RS2406-20BS

1 /1



34.3

32.45

7.82E+01 N

NA



No

BSL



7440-66-6

ZINC

47 J,B

1940

mg/kg

RS2431-44FS

9/9



1940

83.25

2.35 E+04 N

NA



Yes

AOC

(1)	Definition of the Qualifier codes used for the "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.

(2)	Maximumcon centrati onisusedforscreening.

(3)	Mean background values obtained from the Preliminary Site Characterization Summary prepared by AATA International Inc. (2005).

(4)	EPA Region 6 Medium-Specific Screening Levels (MSSL) 2004-2005 for Residential Soil (December, 2004).

(5)	Rationale Codes

Selection Reason: Administrative Order on Consent (AOC)

Deletion Reason: Below Screening Level (BSL)

Essential Nutrient (NUT)

Within Background Range (BKG)

CO PC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/
To Be Considered

C = Carcinogenic
N = Noncarcinogenic
NA = Not available

008533

Page 1 of 1


-------
Table 2.5

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Medium: Groundwater
Exposure Medium: Groundwater

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(4)







(5)

Private Wells

7440-43-9

CADMIUM

0.0001 J

0.003

mg/L

GW 2429-4A

16/25

0.0001 - 0.0006

0.003

NA

5.00E-03 MCL

5.00E-03

MCL

Yes

AOC

(General Public)

7440-70-2

CALCIUM

9.2

87

mg/L

GW 2406-7 B

21 / 25

0.2-0.2

87

NA

NA

NA

-

No

NUT



7439-89-6

IRON

0.3 J,B

0.85

mg/L

GW 2420-2A

3/25

0.02-0.2

0.85

NA

1.10E+01 N

NA

-

No

BSL



7439-92-1

LEAD

0.0002 J

0.028

mg/L

GW 2429-4A

20/25

0.0001 - 0.0001

0.028

NA

1.50E-02 MCL

1.50E-02

MCL

Yes

ASL



7439-95-4

MAGNESIUM

1.5

11.5

mg/L

GW 2307-10B

20/25

0.2-0.2

11.5

NA

NA

NA

-

No

NUT



7440-66-6

ZINC

0.02 J,+

1.11

mg/L

GW 2429-4 B

22/25

0.01 - 0.01

1.11

NA

1.10E+01 N

NA



Yes

AOC

(1)	Definition of the Qualifier codes used for the "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.

(2)	Maximum concentration is used for screening.

(3)	Background values not available.

(4)	Federal Maximum Contaminants Level (MCL). When MCL is not available, EPA Region 6 Medium-Specific Screening Levels (MSSL)
2004-2005 for Tap Water (December, 2004) are used.

(5)	Rationale Codes

Selection Reason:

Deletion Reason:

Above Screening Level (ASL)
Administrative Order on Consent (AOC)
Below Screening Level (BSL)
NUT (Essential Nutrient)

COPC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/
To Be Considered

C = Carcinogenic

N = Noncarcinogenic

NA = Not available

MCL = Maximum Contaminant Level

008534

Page 1 of 1


-------
Table 2.6

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Medium: Groundwater
Exposure Medium: Groundwater

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(4)







(5)

Private Wells

7440-70-2

CALCIUM

134

140

mg/L

GW 2431-12A

2/3

0.2-0.2

140

NA

NA

NA



No

NUT

(Subsistence)

7439-89-6

IRON

1.22

1.25

mg/L

GW 2431-12A

2/3

0.02-0.02

1.25

NA

1.10E+01 N

NA

-

No

BSL



7439-92-1

LEAD

0.0004 J

0.0008 J

mg/L

GW 2431-12A

2/3

0.0001 - 0.0001

0.0008

NA

1.50E-02 MCL

1.50E-02

MCL

Yes

AOC



7439-95-4

MAGNESIUM

7.6

7.9

mg/L

GW 2431-12A

2/3

0.2-0.2

7.9

NA

NA

NA



No

NUT



7440-66-6

ZINC

0.19

0.22

mg/L

GW 2431-12A

2/3

0.01 - 0.01

0.22

NA

1.10E+01 N

NA



Yes

AOC

(1)	Definition of the Qualifier codes used for the "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.

(2)	Maximum concentration is used for screening.

(3)	Background values not available.

(4)	Federal Maximum Contaminants Level (MCL). When MCL is not available, EPA Region 6 Medium-Specific Screening Levels (MSSL)
2004-2005 for Tap Water (December, 2004) are used.

(5)	Rationale Codes

Selection Reason: Above Screening Level (ASL)

Administrative Order on Consent (AOC)

Deletion Reason: Below Screening Level (BSL)

NUT (Essential Nutrient)

COPC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/
To Be Considered

C = Carcinogenic

N = Noncarcinogenic

NA = Not available

MCL = Maximum Contaminant Level

008535

Page 1 of 1


-------
Table 2.7

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Medium: Transition Zone Soil
Exposure Medium: Unwashed Plant (Leaf)

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(2)







(4)

Asparagus

7440-99-9

Aluminum

7.2712 J,v

1287

MG/KG

TC4-BIO-56A

19/19

3.09-8.7

NA

NA

NA

NA



No



(Above Ground)

7440-99-9

Antimony

0.14473 L,J

0.24779 L,J

MG/KG

TC4-BIO-25A

5/19

0.927-2.61

NA

NA

NA

NA

-

No

-



7440-99-9

ARSENIC

0.05488 L,J

2.223

MG/KG

TC4-BIO-56A

14/19

0.1545-0.435

NA

NA

NA

NA

-

No

-



744-03- 9

BARIUM

0.30711 L,J

8.8046

MG/KG

TC4-BIO-40A

14/19

3.09-8.7

NA

NA

NA

NA



No





744-04- 1

BERYLLIUM

0.0030282 L,J

0.2769

MG/KG

TC4-BIO-56A

3/19

0.07725-0.2175

NA

NA

NA

NA



No





744-04- 3

CADMIUM

0.6707 J

21.333

MG/KG

TC4-BIO-56A

19/19

0.07725-0.2175

NA

NA

NA

NA



Yes

AOC



744-07- 0

CALCIUM

1638

6468

MG/KG

TC4-BIO-10A

19/19

77.25-217.5

NA

NA

NA

NA



No





7440-47-3

CHROMIUM, TOTAL

0.06258 L,J

2.262

MG/KG

TC4-BIO-56A

10/19

0.1545-0.435

NA

NA

NA

NA



No





744-04- 8

COBALT

0.025338 L,J

2.106

MG/KG

TC4-BIO-56A

6/19

0.7725-2.175

NA

NA

NA

NA



No





744-05- 0

COPPER

1.6752 J

3.741

MG/KG

TC4-BIO-04A

19/19

0.4017-1.0875

NA

NA

NA

NA



No





7439-89-6

IRON

19.966

4095 J

MG/KG

TC4-BIO-56A

19/19

1.545 - 4.35

NA

NA

NA

NA



No





743-99- 2

LEAD

0.447 J

62.01 J

MG/KG

TC4-BIO-56A

19/19

0.1545-0.435

NA

NA

NA

NA



Yes

AOC



743-99- 5

MAGNESIUM

289.107

987.45

MG/KG

TC4-BIO-04A

19/19

77.25-217.5

NA

NA

NA

NA



No





7439-96-5

MANGANESE

1.5885 J

124.41

MG/KG

TC4-BIO-56A

19/19

0.23175-0.6525

NA

NA

NA

NA



No





744-00- 2

NICKEL

0.11649 L,J

3.666

MG/KG

TC4-BIO-56A

4/19

0.618-1.74

NA

NA

NA

NA



No





744-00- 9

POTASSIUM

608.4 J,v

7024.7 J,v

MG/KG

TC4-BIO-03A

19/19

98 - 309

NA

NA

NA

NA



No





778-24- 9

SELENIUM

0.26885 L,J

0.5364 L,J

MG/KG

TC4-BIO-37A

16/19

0.5562 - 1.5225

NA

NA

NA

NA



No





7440-99-9

Silver

0.05355 L,J

0.663

MG/KG

TC4-BIO-56A

5/19

0.1545-0.435

NA

NA

NA

NA



No





744-02- 3

SODIUM

73.071 L,J,v

1283.1

MG/KG

TC4-BIO-56A

15/19

77.25-217.5

NA

NA

NA

NA



No





744-06- 2

VANADIUM

0.02548 L,J

6.201

MG/KG

TC4-BIO-56A

12/19

0.7725-2.175

NA

NA

NA

NA



No





744-06- 6

ZINC

23.3758 J

409.5 J,A

MG/KG

TC4-BIO-56A

19/19

0.927-2.61

NA

NA

NA

NA



Yes

AOC

(1)	Definition of the Qualifier codes used for the "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.

(2)	No Screening is performed for plant samples

(3)	Background values not available.

(4)	Rationale Codes

Selection Reason: Administrative Order on Consent (AOC)

Deletion Reason:

CO PC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/

To Be Considered
NA = Not available

008536

Page 1 of 1


-------
Table 2.8

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
Tar Creek, Miami, OK

Scenario Timeframe: Current
Medium: Transition Zone Soil
Exposure Medium: Unwashed Plant (Root)

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(2)







(4)

Asparagus

7440-99-9

Aluminum

15.9828

1222.47 J,v

MG/KG

TC4-BIO-43C

19/19

3.41 -8.6

NA

NA

NA

NA



No



(Root)

7440-99-9

Antimony

0.16027 L,J

0.3905 L,J

MG/KG

TC4-BIO-40C

2/19

1.023-2.58

NA

NA

NA

NA



No





7440-99-9

ARSENIC

0.09962 L,J

1.6497

MG/KG

TC4-BIO-43C

19/19

0.1705-0.43

NA

NA

NA

NA



No





744-03- 9

BARIUM

0.2964 L,J

23.9418

MG/KG

TC4-BIO-43C

15/19

3.41 -8.6

NA

NA

NA

NA



No





744-04- 1

BERYLLIUM

0.007514 L,J

0.16497 L,J

MG/KG

TC4-BIO-43C

11 /19

0.08525-0.215

NA

NA

NA

NA



No





744-04- 3

CADMIUM

4.4243

25.915

MG/KG

TC4-BIO-40C

19/19

0.08525-0.215

NA

NA

NA

NA



Yes

AOC



744-07- 0

CALCIUM

454.15

6354.3

MG/KG

TC4-BIO-32C

19/19

85.25-215

NA

NA

NA

NA



No





7440-47-3

CHROMIUM, TOTAL

0.2508

2.2419

MG/KG

TC4-BIO-43C

19/19

0.1705-0.43

NA

NA

NA

NA



No





744-04- 8

COBALT

0.07911 L,J

2.1573

MG/KG

TC4-BIO-43C

16/19

0.8525-2.15

NA

NA

NA

NA



No





744-05- 0

COPPER

1.3478

38.8737

MG/KG

TC4-BIO-43C

19/19

0.4433-1.075

NA

NA

NA

NA



No





7439-89-6

IRON

113.088

3028.68

MG/KG

TC4-BIO-43C

19/19

1.705-4.3

NA

NA

NA

NA



No





743-99- 2

LEAD

19.5048 J

1387.44 J

MG/KG

TC4-BIO-43C

19/19

0.1705-0.43

NA

NA

NA

NA



Yes

AOC



743-99- 5

MAGNESIUM

152.076

1357.02

MG/KG

TC4-BIO-32C

16/19

85.25-215

NA

NA

NA

NA



No





7439-96-5

MANGANESE

4.7538

83.331

MG/KG

TC4-BIO-43C

19/19

0.25575 - 0.645

NA

NA

NA

NA



No





7440-99-9

Mercury

0.0028 L,J,v

0.040185 L,J,v

MG/KG

TC4-BIO-43C

6/17

0.0228-0.043

NA

NA

NA

NA



No





744-00- 2

NICKEL

0.25198 L,J

6.9795

MG/KG

TC4-BIO-43C

11 /19

0.682 - 1.72

NA

NA

NA

NA



No





744-00- 9

POTASSIUM

1340.91 J,v

3475 J,v

MG/KG

TC4-BIO-48C

19/19

85.25-215

NA

NA

NA

NA



No





778-24- 9

SELENIUM

0.20002 L,J

0.4816 L,J

MG/KG

TC4-BIO-37C

16/19

0.6138 - 1.505

NA

NA

NA

NA



No





7440-99-9

Silver

0.04332 L,J

0.30789 L,J

MG/KG

TC4-BIO-53C

4/19

0.1705-0.43

NA

NA

NA

NA



No





744-02- 3

SODIUM

647.36

9432.9

MG/KG

TC4-BIO-43C

15/19

85.25-215

NA

NA

NA

NA



No





744-06- 2

VANADIUM

0.10716 L,J

3.9339

MG/KG

TC4-BIO-43C

17/19

0.8525-2.15

NA

NA

NA

NA



No





744-06- 6

ZINC

234.107 J,A

3578.58 J

MG/KG

TC4-BIO-43C

19/19

1.023-2.58

NA

NA

NA

NA



Yes

AOC

(1)	Definition of the Qualifier codes used for the "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.

(2)	No Screening is performed for plant samples

(3)	Background values not available.

(4)	Rationale Codes

Selection Reason: Administrative Order on Consent (AOC)

Deletion Reason:

CO PC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/

To Be Considered
NA = Not available

008537

Page 1 of 1


-------
Table 2.9

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Medium: Transition Zone Soil
Exposure Medium: Unwashed Plant (Leaf)

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(2)







(4)

Willow

7440-99-9

Aluminum

0.884 L,J

179.52 J,v

MG/KG

TC4-BIO-42A

18/19

5.74-10.86

NA

NA

NA

NA



No



(Above Ground)

7440-99-9

Antimony

0.27789 L,J

0.27789 L,J

MG/KG

TC4-BIO-27A

1 /19

1.722 - 3.258

NA

NA

NA

NA

-

No

-



7440-99-9

ARSENIC

0.0987 L,J

0.2688 L,J

MG/KG

TC4-BIO-42A

9/19

0.287-0.543

NA

NA

NA

NA

-

No

-



744-03- 9

BARIUM

0.29202 L,J

3.6292 L,J

MG/KG

TC4-BIO-17A

9/19

5.74-10.86

NA

NA

NA

NA



No





744-04- 1

BERYLLIUM

0.00574 L,J

0.01104 L,J

MG/KG

TC4-BIO-42A

2/19

0.1435-0.2715

NA

NA

NA

NA



No





744-04- 3

CADMIUM

1.1515

32.2588

MG/KG

TC4-BIO-08A

19/19

0.1435-0.2715

NA

NA

NA

NA



Yes

AOC



744-07- 0

CALCIUM

2041.68

9408

MG/KG

TC4-BIO-42A

19/19

143.5-271.5

NA

NA

NA

NA



No





7440-47-3

CHROMIUM, TOTAL

0.0397 L,J

0.816

MG/KG

TC4-BIO-42A

9/19

0.287 - 0.543

NA

NA

NA

NA



No





744-04- 8

COBALT

0.08949 L,J

1.0005 L,J

MG/KG

TC4-BIO-49A

12/19

1.435-2.715

NA

NA

NA

NA



No





744-05- 0

COPPER

1.608

5.616

MG/KG

TC4-BIO-15A

17/19

0.7462 - 1.3575

NA

NA

NA

NA



No





7439-89-6

IRON

17.964 J

556.8

MG/KG

TC4-BIO-42A

19/19

2.87 - 5.43

NA

NA

NA

NA



No





743-99- 2

LEAD

0.5226 J,A

20.213

MG/KG

TC4-BIO-45A

17/19

0.287 - 0.543

NA

NA

NA

NA



Yes

AOC



743-99- 5

MAGNESIUM

280.308

1200.6

MG/KG

TC4-BIO-49A

19/19

143.5-271.5

NA

NA

NA

NA



No





7439-96-5

MANGANESE

2.556

287.79

MG/KG

TC4-BIO-05A

19/19

0.4305-0.8145

NA

NA

NA

NA



No





744-00- 2

NICKEL

0.28187 L,J

1.0815 L,J

MG/KG

TC4-BIO-51A

5/19

1.148-2.172

NA

NA

NA

NA



No





744-00- 9

POTASSIUM

1953.86 J,v

5253 J,v

MG/KG

TC4-BIO-51A

19/19

143.5-271.5

NA

NA

NA

NA



No





778-24- 9

SELENIUM

0.23632 L,J

0.6188 L,J

MG/KG

TC4-BIO-35A

16/19

1.0332 - 1.9005

NA

NA

NA

NA



No





7440-99-9

Silver

0.072 L,J

0.15965 L,J

MG/KG

TC4-BIO-51A

6/19

0.287 - 0.543

NA

NA

NA

NA



No





744-02- 3

SODIUM

174.041

1506.54

MG/KG

TC4-BIO-17A

12/19

143.5-271.5

NA

NA

NA

NA



No





744-06- 2

VANADIUM

0.05004 L,J

0.1545 L,J,A

MG/KG

TC4-BIO-51A

5/19

1.435-2.715

NA

NA

NA

NA



No





744-06- 6

ZINC

67.445

705.55

MG/KG

TC4-BIO-51A

19/19

1.722-3.258

NA

NA

NA

NA



Yes

AOC

(1)	Definition of the Qualifier codes used for the "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.

(2)	No Screening is performed for plant samples

(3)	Background values not available.

(4)	Rationale Codes

Selection Reason: Administrative Order on Consent (AOC)

Deletion Reason:

CO PC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/

To Be Considered
NA = Not available

008538

Page 1 of 1


-------
Table 2.10

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Medium: Transition Zone Soil
Exposure Medium: Unwashed Plant (Root)

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(2)







(4)

Willow

7440-99-9

Aluminum

17.7804

571.29 J,v

MG/KG

TC4-BIO-42C

19/19

4.45-10.86

NA

NA

NA

NA



No



(Root)

7440-99-9

Antimony

0.19894 L,J

0.35776 L,J

MG/KG

TC4-BIO-02C

3/19

1.335-3.258

NA

NA

NA

NA

-

No

-



7440-99-9

ARSENIC

0.1624 L,J

2.8461

MG/KG

TC4-BIO-45C

19/19

0.2225 - 0.543

NA

NA

NA

NA



No





744-03- 9

BARIUM

0.99 L,J

26.6928

MG/KG

TC4-BIO-50C

12/19

4.45-10.86

NA

NA

NA

NA



No





744-04- 1

BERYLLIUM

0.007725 L,J

0.05784 L,J

MG/KG

TC4-BIO-51C

8/19

0.11125-0.2715

NA

NA

NA

NA



No





744-04- 3

CADMIUM

4.8909

132.818 J

MG/KG

TC4-BIO-27C

19/19

0.11125-0.2715

NA

NA

NA

NA



Yes

AOC



744-07- 0

CALCIUM

1223.75

17935.8

MG/KG

TC4-BIO-45C

19/19

111.25-271.5

NA

NA

NA

NA



No





7440-47-3

CHROMIUM, TOTAL

0.39668 L,J

3.222

MG/KG

TC4-BIO-45C

16/19

0.2225-0.543

NA

NA

NA

NA



No





744-04- 8

COBALT

0.12586 L,J

2.583

MG/KG

TC4-BIO-23C

18/19

1.1125-2.715

NA

NA

NA

NA



No





744-05- 0

COPPER

3.8582

58.032

MG/KG

TC4-BIO-19C

19/19

0.5785 - 1.3575

NA

NA

NA

NA



No





7439-89-6

IRON

127.588

4510

MG/KG

TC4-BIO-23C

19/19

2.225-5.43

NA

NA

NA

NA



No





743-99- 2

LEAD

15.8912

1922.46

MG/KG

TC4-BIO-45C

19/19

0.2225-0.543

NA

NA

NA

NA



Yes

AOC



743-99- 5

MAGNESIUM

228.73

3307.92

MG/KG

TC4-BIO-45C

19/19

111.25-271.5

NA

NA

NA

NA



No





7439-96-5

MANGANESE

6.076

181.251

MG/KG

TC4-BIO-42C

19/19

0.33375-0.8145

NA

NA

NA

NA



No





7440-99-9

Mercury

0.00515 L,J,v

0.24128

MG/KG

TC4-BIO-02C

10/16

0.0382 - 0.0543

NA

NA

NA

NA



No





744-00- 2

NICKEL

2.5296

16.422

MG/KG

TC4-BIO-29C

19/19

0.89-2.172

NA

NA

NA

NA



No





744-00- 9

POTASSIUM

228.578 J,v

2491.16 J,v

MG/KG

TC4-BIO-15C

18/19

111.25-271.5

NA

NA

NA

NA



No





778-24- 9

SELENIUM

0.12172 L,J

1.827

MG/KG

TC4-BIO-46C

16/19

0.801 -1.9005

NA

NA

NA

NA



No





7440-99-9

Silver

0.20904 L,J

0.7518

MG/KG

TC4-BIO-45C

5/19

0.2225-0.543

NA

NA

NA

NA



No





744-02- 3

SODIUM

1152.55 J,v

29578

MG/KG

TC4-BIO-29C

13/19

111.25-271.5

NA

NA

NA

NA



No





744-06- 2

VANADIUM

0.17052 L,J

3.374 J,A

MG/KG

TC4-BIO-51C

14/19

1.1125-2.715

NA

NA

NA

NA



No





744-06- 6

ZINC

466.04

13202 J

MG/KG

TC4-BIO-29C

19/19

1.335-13.8

NA

NA

NA

NA



Yes

AOC

(1)	Definition of the Qualifier codes used for the "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.

(2)	No Screening is performed for plant samples

(3)	Background values not available.

(4)	Rationale Codes

Selection Reason: Administrative Order on Consent (AOC)

Deletion Reason:

CO PC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/

To Be Considered
NA = Not available

008539

Page 1 of 1


-------
Table 2.11

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Medium: Transition Zone Soil
Exposure Medium: Unwashed Plant (Stalk)

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(2)







(4)

Cattail

7440-99-9

Aluminum

3.3912 L,J

83.385

MG/KG

TC4-BIO-55A

19/19

3.11 - 6.74

NA

NA

NA

NA



No



(Above Ground)

7440-99-9

Antimony

0.14079 L,J

1.887 J

MG/KG

TC4-BIO-55A

5/19

0.933-2.022

NA

NA

NA

NA

-

No

-



7440-99-9

ARSENIC

0.03421 L,J

0.714

MG/KG

TC4-BIO-55A

12/19

0.1555-0.337

NA

NA

NA

NA

-

No

-



744-03- 9

BARIUM

0.11362 L,J

2.1905 L,J

MG/KG

TC4-BIO-12A

9/19

3.11-6.74

NA

NA

NA

NA



No





744-04- 1

BERYLLIUM

0.00969 L,J

0.00969 L,J

MG/KG

TC4-BIO-55A

1 /19

0.07775-0.1685

NA

NA

NA

NA



No





744-04- 3

CADMIUM

0.02755 L,J

34.17

MG/KG

TC4-BIO-55A

14/19

0.07775-0.1685

NA

NA

NA

NA



Yes

AOC



744-07- 0

CALCIUM

1154.16

3575

MG/KG

TC4-BIO-41A

19/19

77.75- 168.5

NA

NA

NA

NA



No





7440-47-3

CHROMIUM, TOTAL

0.05838 L,J

0.612

MG/KG

TC4-BIO-55A

11 /19

0.1555-0.337

NA

NA

NA

NA



No





744-04- 8

COBALT

0.023014 L,J

1.9635

MG/KG

TC4-BIO-55A

8/19

0.7775-1.685

NA

NA

NA

NA



No





744-05- 0

COPPER

0.6402 L,J

10.3785

MG/KG

TC4-BIO-55A

17/19

0.4043 - 0.8425

NA

NA

NA

NA



No





7439-89-6

IRON

6.0696 J,A

1932.9 J

MG/KG

TC4-BIO-55A

19/19

1.555 - 3.37

NA

NA

NA

NA



No





743-99- 2

LEAD

0.29 L,J

1366.8 J

MG/KG

TC4-BIO-55A

17/19

0.1555-0.337

NA

NA

NA

NA



Yes

AOC



743-99- 5

MAGNESIUM

117.135 L,J

374.88

MG/KG

TC4-BIO-44A

19/19

77.75-168.5

NA

NA

NA

NA



No





7439-96-5

MANGANESE

4.3924

357.5

MG/KG

TC4-BIO-41A

19/19

0.23325-0.5055

NA

NA

NA

NA



No





744-00- 2

NICKEL

0.1746 L,J

2.601

MG/KG

TC4-BIO-55A

7/19

0.622 - 1.348

NA

NA

NA

NA



No





744-00- 9

POTASSIUM

571.2 J,v

4799.6 J,v

MG/KG

TC4-BIO-44A

19/19

77.75-168.5

NA

NA

NA

NA



No





778-24- 9

SELENIUM

0.1925 L,J

0.3614 L,J

MG/KG

TC4-BIO-24A

17/19

0.5598-1.1795

NA

NA

NA

NA



No





7440-99-9

Silver

0.03421 L,J

0.3825

MG/KG

TC4-BIO-55A

4/19

0.1555-0.337

NA

NA

NA

NA



No





744-02- 3

SODIUM

183.179 J,v

2184.84

MG/KG

TC4-BIO-57A

18/19

77.75-168.5

NA

NA

NA

NA



No





744-06- 2

VANADIUM

0.035 L,J

0.408 L,J

MG/KG

TC4-BIO-55A

6/19

0.7775 - 1.685

NA

NA

NA

NA



No





744-06- 6

ZINC

13.9518

4411.5 J,A

MG/KG

TC4-BIO-55A

19/19

0.933-6.12

NA

NA

NA

NA



Yes

AOC

(1)	Definition of the Qualifier codes used for the "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.

(2)	No Screening is performed for plant samples

(3)	Background values not available.

(4)	Rationale Codes

Selection Reason: Administrative Order on Consent (AOC)

Deletion Reason:

CO PC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/

To Be Considered
NA = Not available

008540

Page 1 of 1


-------
Table 2.12

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Medium: Transition Zone Soil
Exposure Medium: Unwashed Plant (Root)

Exposure

CAS

Chemical

Minimum

Maximum

Units

Location

Detection

Range of

Concentration

Background

Screening

Potential

Potential

COPC

Rationale for

Point

Number



Concentration

Concentration



of Maximum

Frequency

Detection

Used for

Value

Toxicity Value

ARAR/TBC

ARAR/TBC

Flag

Selection or







Qualifier

Qualifier



Concentration



Limits

Screening



(N/C)

Value

Source



Deletion







(1)

(1)









(2)

(3)

(2)







(4)

Cattail

7440-99-9

Aluminum

7.7409

1570.8 J,v

MG/KG

TC4-B10-41C

18/19

2.4 - 9.24

NA

NA

NA

NA



No



(Root)

7440-99-9

Antimony

0.14193 L,J

0.4697 L,J

MG/KG

TC4-BIO-01C

5/19

0.72 - 2.772

NA

NA

NA

NA



No





7440-99-9

ARSENIC

0.11882 L,J

2.9853 J

MG/KG

TC4-BIO-21C

17/19

0.12-0.462

NA

NA

NA

NA



No





744-03- 9

BARIUM

0.4752 L,J

19.3116

MG/KG

TC4-BIO-41C

12/19

2.4-9.24

NA

NA

NA

NA



No





744-04- 1

BERYLLIUM

0.012201 L,J

0.17934 L,J

MG/KG

TC4-BIO-01C

6/19

0.06-0.231

NA

NA

NA

NA



No





744-04- 3

CADMIUM

0.04185 L,J

249.426

MG/KG

TC4-BIO-21C

19/19

0.06-0.231

NA

NA

NA

NA



Yes

AOC



744-07- 0

CALCIUM

709.9

7295.7

MG/KG

TC4-BIO-39C

19/19

60 - 231

NA

NA

NA

NA



No





7440-47-3

CHROMIUM, TOTAL

0.264

8.2236

MG/KG

TC4-B10-41C

17/19

0.12-0.462

NA

NA

NA

NA



No





744-04- 8

COBALT

0.06634 L,J

2.8182

MG/KG

TC4-B10-41C

15/19

0.6-2.31

NA

NA

NA

NA



No





744-05- 0

COPPER

0.341 L,J

65.182

MG/KG

TC4-BIO-09C

19/19

0.3- 1.155

NA

NA

NA

NA



No





7439-89-6

IRON

10.292 J

6447.6 J

MG/KG

TC4-BIO-18C

19/19

1.2-4.62

NA

NA

NA

NA



No





743-99- 2

LEAD

0.8601 J

2759.77 J

MG/KG

TC4-BIO-09C

19/19

0.12-0.598

NA

NA

NA

NA



Yes

AOC



743-99- 5

MAGNESIUM

165.85

2091.37

MG/KG

TC4-BIO-47C

19/19

60 - 231

NA

NA

NA

NA



No





7439-96-5

MANGANESE

7.8752 J

225.811

MG/KG

TC4-BIO-14C

19/19

0.18-0.693

NA

NA

NA

NA



No





7440-99-9

Mercury

0.00395 L,J

0.3289

MG/KG

TC4-BIO-09C

11 /15

0.0155-0.0457

NA

NA

NA

NA



No





744-00- 2

NICKEL

0.06045 L,J

18.603

MG/KG

TC4-BIO-34C

15/19

0.48 - 1.848

NA

NA

NA

NA



No





744-00- 9

POTASSIUM

382.23 J,v

3309.9 J,v

MG/KG

TC4-BIO-24C

19/19

60 - 231

NA

NA

NA

NA



No





778-24- 9

SELENIUM

0.132 L,J

0.7392 L,J

MG/KG

TC4-BIO-41C

15/19

0.42-1.617

NA

NA

NA

NA



No





7440-99-9

Silver

0.027807 L,J

0.7488

MG/KG

TC4-BIO-34C

6/19

0.12-0.462

NA

NA

NA

NA



No





744-02- 3

SODIUM

410.75

48267 J

MG/KG

TC4-BIO-21C

19/19

60-697.5

NA

NA

NA

NA



No





744-02- 8

THALLIUM

0.21528 L,J

0.21528 L,J

MG/KG

TC4-BIO-34C

1/19

0.3-1.155

NA

NA

NA

NA



No





744-06-2

VANADIUM

0.17366 L,J

9.8868

MG/KG

TC4-BIO-41C

13/19

0.6-2.31

NA

NA

NA

NA



No





744-06-6

ZINC

17.825 J,A

18414 J

MG/KG

TC4-BIO-21C

19/19

0.93 - 16.74

NA

NA

NA

NA



Yes

AOC

(1)	Definition of the Qualifier codes used for the "Minimum Concentration" and "Maximum Concentration" is presented in Table 2 Supplement.

(2)	No Screening is performed for plant samples

(3)	Bac kg roundvaluesnot available.

(4)	Rationale Codes

Selection Reason: Administrative Order on Consent (AOC)

Deletion Reason:

COPC = Chemical of Potential Concern

ARAR/TBC = Applicable or Relevant and Appropriate Requirement/

To Be Considered
NA = Not available

008541

Page 1 of 1


-------
Table 2 Supplement

OCCURRENCE, DISTRIBUTION AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Tar Creek, Miami, OK

Qualifier Code

Qualifer Definition

=

Analyte detected at the reported concentration. No QC problems were encountered.

B

Result is between the MDL and the PQL.

J

Result is estimated because of outlying quality control parameters.

J-

Result is estimated with a low bias because of outlying quality control parameters. Actual concentration
may be higher than the concentration reported.

JA

Result is estimated with a high bias because of outlying quality control parameters. Actual concentration
may be lower than the concentration reported.

J+

Result is estimated with a high bias because of outlying quality control parameters. Actual concentration
may be lower than the concentration reported.

JB

Result is between the MDL and the PQL and is estimated because of outlying quality control parameters

JB+

Result is between the MDL and the PQL and is estimated with a high bias because of outlying quality
control parameters. Actual concentration may be lower than the concentration reported.

Jv

Result is estimated with a low bias because of outlying quality control parameters. Actual concentration
may be higher than the concentration reported.

JvW

Result is estimated with a low bias because of outlying quality control parameters. Actual concentration
may be higher than the concentration reported. The result was reported on a dry-weight basis although
the sample did not conform to the EPA office of Water definition of a soil sample because of its high
water content (>70% moisture).

LJ

Result is between the MDL and the CRQL and is estimated because of outlying quality control
parameters

LJA

Result is between the MDL and the CRQL and is estimated with a high bias because of outlying quality
control parameters. Actual concentration may be lower than the concentration reported.

LJv

Result is between the MDL and the CRQL and is estimated with a low bias because of outlying quality
control parameters. Actual concentration may be higher than the concentration reported.

LJvW

Result is between the MDL and the CRQL and is estimated with a low bias because of outlying quality
control parameters. Actual concentration may be higher than the concentration reported. The result was
reported on a dry-weight basis although the sample did not conform to the EPA office of Water definition
of a soil sample because of its high water content (>70% moisture).

LJW

Result is between the MDL and the CRQL and is estimated because of outlying quality control
parameters. The result was reported on a dry-weight basis although the sample did not conform to the
EPA office of Water definition of a soil sample because of its high water content (>70% moisture).

008542


-------
Table 3.1 .RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current/Future
Medium: Chat and Tailings Material
Exposure Medium: Surface Material

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum



Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential







(Qualifier)











Concern









Value

Units

Statistic

Rationale

Chat Pile & Tailings Ponds

CADMIUM

mg/kg

7.62E+01

9.35E+01 NP

1.97E+02

9.35E+01

mg/kg

95% Cheb-m

(5)

Surface (0-6 inch)

ZINC

mg/kg

1.64E+04

1.79E+04 N

4.22E+04 Jv

1.79E+04

mg/kg

95% Stud-t

(2)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).
Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);
99% Chebyshev (mean.std) UCL (99% Cheb-m); 95% modified-t UCL adjusted for skewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);
95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wlk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.

mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"

G = Gamma distribution.	is presented in Table 2 Supplement.

N = Normal distribution.

T = Log-normal distribution.

NP= Non-Parametric distribution.

008543

Page 1 of 1

3.1-3.12_Table 3 draft final.xls
Recr All


-------
Table 3.2.RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current/Future

Medium: Surface Soil (residential, rural areas, and transition zone)
Exposure Medium: Animal Tissue	

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum



Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential







(Qualifier)











Concern









Value

Units

Statistic

Rationale

Small Game (Bird, Rabbit),

CADMIUM

mg/kg

1.36E+01

2.74E+01 NP

2.48E+02

2.74E+01

mg/kg

97.5% Cheb-m

(5)

Beef (Cattle), and Milk (Dairy)

ZINC

mg/kg

2.67E+03

5.39E+03 NP

3.92E+04

5.39E+03

mg/kg

97.5% Cheb-m

(5)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).

Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);

99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted for skewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);

95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wilk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.

mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"

G = Gamma distribution.	is presented in Table 2 Supplement.

N = Normal distribution.

T = Log-normal distribution.

NP = Non-Parametric distribution.

TC_HHRA_DraftFinalRA_AppendixO_3-2.3-2a.3-3_RAGS-D.xls

Revised 02/09/2006	Page 1 of 1	BUM_AII

008544


-------
Table 3.2A.RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current/Future
Medium: Surface Soil (smelter affected soil)
Exposure Medium: Animal Tissue	

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum



Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential







(Qualifier)











Concern









Value

Units

Statistic

Rationale

Small Game (Bird, Rabbit),

CADMIUM

mg/kg

3.66E+01

6.22E+01 G

1.39E+02

6.22E+01

mg/kg

Appo. Gamma

(4)

Beef (Cattle), and Milk (Dairy)

ZINC

mg/kg

1.75E+03

2.95E+03 G

7.98E+03

2.95E+03

mg/kg

Appo. Gamma

(4)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).

Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);

99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted for skewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);

95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wlk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.

mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"

G = Gamma distribution.	is presented in Table 2 Supplement.

N = Normal distribution.

T = Log-normal distribution.

NP = Non-Parametric distribution.

TC_HHRA_DraftFinalRA_AppendixO_3-2.3-2a.3-3_RAGS-D.xls

Revised 02/09/2006	Page 1 of 1	SASO

008545


-------
Table 3.3.RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current

Medium: Surface Soil

Exposure Medium: Surface Soil (Yards)

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum



Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential







(Qualifier)











Concern









Value

Units

Statistic

Rationale

Surface Soil

CADMIUM

mg/kg

4.05E+00

7.52E+00 NP

4.75E+01

4.75E+01

mg/kg

Max

(7)

(General Public) (0-1 inch)

ZINC

mg/kg

6.46E+02

8.26E+02 T

7.70E+03

7.70E+03

mg/kg

Max

(7)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).

Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);

99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted forskewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);

95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wilk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.

(7)	Maximum detected concentration was used as EPC (see text).

mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"

G = Gamma distribution.	is presented in Table 2 Supplement.

N = Normal distribution.

T = Log-normal distribution.

NP = Non-Parametric distribution.

TC_HHRA_DraftFinalRA_AppendixO_3-2.3-2a.3-3_RAGS-D.xls

Revised 02/09/2006	Page 1 of 1	Res_SO_GP

008546


-------
Table 3.3.RME Supplement A
MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Summary of Modeled Ambient Air Concentrations
Tar Creek, Miami, OK

Scenario Timeframe: Current
Medium: Chat Pile Material and Tailings
Exposure Medium: Ambient Air

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum

Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential



















Concern









Value

Units

Statistic

Rationale

Ambient Air

CADMIUM

ug/m3

2.64E-05

8.08E-05 NP

2.00E-04

8.08E-05

ug/m3

99% Cheb-m

(5)



ZINC

ug/m3

5.70E-03

1.75E-02 NP

4.33E-02

1.75E-02

ug/m3

99% Cheb-m

(5)

ProllCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProllCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProllCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).
Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);
99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted for skewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);
95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wilk W Test indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.

(7)	Mean value to be used for lead modeling.

NP = Non-Parametric distribution.

008547


-------
Table 3.4.RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current

Medium: Surface Soil

Exposure Medium: Surface Soil (Yards)

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum



Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential







(Qualifier)











Concern









Value

Units

Statistic

Rationale

Surface Soil

CADMIUM

mg/kg

2.85E+00

6.89E+00 G

9.60E+00

9.60E+00

mg/kg

Max

(7)

(Subsistence)(0-1 inch)

ZINC

mg/kg

5.28E+02

1.34E+03 G

1.94E+03

1.94E+03

mg/kg

Max

(7)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).
Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);
99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted for skewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);
95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wilk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.

(7)	Maximum detected concentration was used as EPC (see text).

mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"

G = Gamma distribution.	is presented in Table 2 Supplement.

N = Normal distribution.

T = Log-normal distribution.

NP = Non-Parametric distribution.	Page 1 of 1

3.1-3.12_Table 3 draft final.xls
Res SO NA

008548


-------
Table 3.5.RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current/Future
Medium: Groundwater
Exposure Medium: Groundwater

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum



Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential







(Qualifier)











Concern









Value

Units

Statistic

Rationale

Private Wells

CADMIUM

mg/L

8.08E-04

2.83E-03 NP

3.00E-03

3.00E-03

mg/L

Max

(7)

(General Public)

ZINC

mg/L

2.07E-01

6.11E-01 T

1.11E+00

1.11E+00

mg/L

Max

(7)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).

Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);

99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted forskewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);

95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wlk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.

(7)	Maximum detected concentration was used as EPC (see text).

mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"

G = Gamma distribution.	is presented in Table 2 Supplement.

N = Normal distribution.

3.1-3.12_Table 3 draft final.xls

T = Log-normal distribution.	Page ^ of ^	Res_GW_GP

NP = Non-Parametric distribution.

008549


-------
Table 3.6.RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current/Future
Medium: Groundwater
Exposure Medium: Groundwater

Exposure Point

Chemical
of

Potential
Concern

Units

Arithmetic
Mean

95% UCL
(N/T/NP/G)

Maximum
Concentration
(Qualifier)

Exposure Point Concentration

Value

Units

Statistic

Rationale

Private Wells
(Subsistence)

ZINC

mg/L

1.38E-01

NA

2.20E-01

2.20E-01

mg/L

Max

(7)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).
Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);
99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted forskewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);
95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wlk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.

(7)	Maximum detected concentration was used as EPC (see text).

mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"

G = Gamma distribution.	is presented in Table 2 Supplement.

N = Normal distribution.

T = Log-normal distribution.

Page 1 of 1

NP = Non-Parametric distribution.

008550

3.1-3.12_Table 3 draft final.xls
Res_GW_NA


-------
Table 3.7.RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current/Future
Medium: Transition Zone Soil
Exposure Medium: Unwashed Plant (Leaf)

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum



Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential







(Qualifier)











Concern









Value

Units

Statistic

Rationale

Asparagus

CADMIUM

mg/kg

3.65E+00

5.48E+00 T

2.13E+01

5.48E+00

mg/kg

App. Gamma

(1)

(Above Ground)

ZINC

mg/kg

1.06E+02

1.42E+02 G

4.10E+02 JA

1.42E+02

mg/kg

App. Gamma

(3,4)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).

Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);

99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted forskewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);

95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wlk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.

mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"

G = Gamma distribution.	is presented in Table 2 Supplement.

N = Normal distribution.

T = Log-normal distribution.

3.1-3.12_Table 3 draft final.xls

NP = Non-Parametric distribution.	Page 1 of 1	ASP AG

008551


-------
Table 3.8.RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current/Future
Medium: Transition Zone Soil
Exposure Medium: Unwashed Plant (Root)

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum



Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential







(Qualifier)











Concern









Value

Units

Statistic

Rationale

Asparagus

CADMIUM

mg/kg

1.02E+01

1.25E+01 G

2.59E+01

1.25E+01

mg/kg

App. Gamma

(3,4)

(Root)

ZINC

mg/kg

1.02E+03

1.40E+03 G

3.58E+03 J

1.40E+03

mg/kg

App. Gamma

(3,4)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).

Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);

99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted forskewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);

95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wlk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.

mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"

G = Gamma distribution.	is presented in Table 2 Supplement.

N = Normal distribution.

T = Log-normal distribution.

3.1-3.12_Table 3 draft final.xls

NP = Non-Parametric distribution.	Page 1 of 1	ASP RT

008552


-------
Table 3.9.RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current/Future
Medium: Transition Zone Soil
Exposure Medium: Unwashed Plant (Leaf)

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum



Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential







(Qualifier)











Concern









Value

Units

Statistic

Rationale

Wllow

CADMIUM

mg/kg

1.20E+01

1.78E+01 G

3.23E+01

1.78E+01

mg/kg

App. Gamma

(3,4)

(Above Ground)

ZINC

mg/kg

4.01 E+02

4.67E+02 N

7.06E+02

4.67E+02

mg/kg

95% Stud-t

(2)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).
Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);
99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted forskewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);
95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wlk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.

mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"

G = Gamma distribution.	is presented in Table 2 Supplement.

N = Normal distribution.

T = Log-normal distribution.

NP = Non-Parametric distribution.	page -| 0f-|

3.1-3.12_Table 3 draft final.xls
WLW AG

008553


-------
Table 3.10.RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current/Future
Medium: Transition Zone Soil
Exposure Medium: Unwashed Plant (Root)

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum



Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential







(Qualifier)











Concern









Value

Units

Statistic

Rationale

Wllow

CADMIUM

mg/kg

3.45E+01

4.97E+01 G

1.33E+02 J

4.97E+01

mg/kg

App. Gamma

(3,4)

(Root)

ZINC

mg/kg

3.02E+03

4.62E+03 G

1.32E+04 J

4.62E+03

mg/kg

App. Gamma

(3,4)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).

Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);

99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted forskewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);

95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wlk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.

mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"

G = Gamma distribution.	is presented in Table 2 Supplement.

N = Normal distribution.

T = Log-normal distribution.

3.1-3.12_Table 3 draft final.xls

NP = Non-Parametric distribution.	Page 1 of 1	WLW RT

008554


-------
Table 3.11.RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current/Future
Medium: Transition Zone Soil
Exposure Medium: Unwashed Plant (Stalk)

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum



Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential







(Qualifier)











Concern









Value

Units

Statistic

Rationale

Cattail

CADMIUM

mg/kg

1.93E+00

1.98E+01 NP

3.42E+01

1.98E+01

mg/kg

99% Cheb-m

(5)

(Above Ground)

ZINC

mg/kg

2.70E+02

2.56E+03 NP

4.41 E+03 JA

2.56E+03

mg/kg

99% Cheb-m

(5)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).
Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);
99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted forskewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);
95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wlk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.
mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"
G = Gamma distribution. is presented in Table 2 Supplement.

N = Normal distribution.

T = Log-normal distribution.

NP = Non-Parametric distribution.	page -| 0f-|

008555

3.1-3.12_Table 3 draft final.xls
CT AG


-------
Table 3.12.RME

MEDIUM-SPECIFIC EXPOSURE POINT CONCENTRATION SUMMARY
Tar Creek, Miami, Oklahoma

Scenario Timeframe: Current/Future
Medium: Transition Zone Soil
Exposure Medium: Unwashed Plant (Root)

Exposure Point

Chemical

Units

Arithmetic

95% UCL

Maximum



Exposure Point Concentration





of



Mean

(N/T/NP/G)

Concentration











Potential







(Qualifier)











Concern









Value

Units

Statistic

Rationale

Cattail

CADMIUM

mg/kg

2.79E+01

6.11E+01 T

2.49E+02

6.11E+01

mg/kg

Adj. Gamma

(3,4)

(Root)

ZINC

mg/kg

2.45E+03

4.36E+03 G

1.84E+04 J

4.36E+03

mg/kg

App. Gamma

(3,4)

For non-detects, 1/2 sample quantitation limit (if available; otherwise RL) was used as a proxy concentration.

ProUCL, Version 3.00.02 used to determine distribution of data using the Shapiro-Wilk WTest. ProUCL used to calculate RME EPC, following recommendations
based on distribution and standard deviation in users guide (USEPA. April 2004. ProUCL, Version 3.0. Prepared by Lockheed Martin Environmental Services).
Statistics: Maximum Detected Value (Max); 95% UCL of Log-transformed Data, H-Statistic (95% UCL-T); 95% Chebyshev (MVUE) UCL (95% Cheb);

99% Chebyshev (MVUE) UCL (99% Cheb); 95% Chebyshev (mean.std) UCL (95% Cheb-m); 97.5% Chebyshev (mean.std) UCL (97.5% Cheb-m);
99% Chebyshev (mean,std) UCL (99% Cheb-m); 95% modified-t UCL adjusted forskewness (95% Mod-t); 95% Student's-T test UCL (95% Stud-t);
95% Hall's Bootstrap UCL (95% Hall); 95% Approximate Gamma (App. Gamma); 95% Adjusted Gamma (Adj. Gamma);

Mean of Log-transformed Data using the Minimum Variance Unbiased Estimate (MVUE) method (Mean-T)

(1)	Shapiro-Wilk WTest indicates data are log-normally distributed.

(2)	Shapiro-Wlk WTest indicates data are normally distributed.

(3)	Anderson-Darling Test indicates data are gamma distributed.

(4)	Kolmogorov-Smirnov Test indicates data are gamma distributed.

(5)	Distribution tests are inconclusive (data are not normal, log-normal, or gamma-distributed).

(6)	The maximum detected concentration was used as the UCL because the value recommended by ProUCL 3.0 was higher than the Max.
mg/kg = milligrams per kilogram	Definition of the Qualifier codes used for the "Maximum Concentration"
G = Gamma distribution. is presented in Table 2 Supplement.

N = Normal distribution.

T = Log-normal distribution.

NP = Non-Parametric distribution.	page -| 0f-|

008556

3.1-3.12_Table 3 draft final.xls
CT RT


-------
TABLE 4.1.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current

Medium: Surface Soil

Exposure Medium: Surface Soil (Yards)

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Ingestion

Resident

Adult

Surface Soil

CS

Chemical Concentration in Soil

See Table 3.3.RME

mg/kg

See Table 3.3.RME

Chronic Daily Intake (CDI) (mg/kg-day) =



(General Public)



(0-1 inch)

IR-S

Ingestion Rate of Soil

100

mg/day

EPA, 1991

CS x IR-S x EF x ED x CF1 x 1/BWx 1/AT









EF

Exposure Frequency

350

days/year

EPA, 1991











ED

Exposure Duration

24

years

EPA, 1991











CF1

Conversion Factor 1

0.000001

kg/mg













BW

Body Weight

70

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

8,760

days

EPA, 1989







Child

Surface Soil

CS

Chemical Concentration in Soil

See Table 3.3.RME

mg/kg

See Table 3.3.RME

CDI (mg/kg-day) =







(0-1 inch)

IR-S

Ingestion Rate of Soil

200

mg/day

EPA, 1991

CSx IR-S x EF x ED x CF1 x 1/BWx 1/AT









EF

Exposure Frequency

350

days/year

EPA, 1991











ED

Exposure Duration

6

years

EPA, 1991











CF1

Conversion Factor 1

0.000001

kg/mg













BW

Body Weight

15

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

2,190

days

EPA, 1989











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989







Child/Adult

Surface Soil

CS

Chemical Concentration in Soil

See Table 3.3.RME

mg/kg

See Table 3.3.RME

CDI (mg/kg-day) =







(0-1 inch)

IR-S-A

Ingestion Rate of Soil, Adult

100

mg/day

EPA, 1991

CS x IR-S-Adj x EF x CF1 x 1/AT









IR-S-C

Ingestion Rate of Soil, Child

200

mg/day

EPA, 1991











IR-S-Adj

Ingestion Rate of Soil, Age-adjusted

114.29

mg-year/kg-day

Calculated

IR-S-Adj (mg-year/kd-day) =









EF

Exposure Frequency

350

days/year

EPA, 1991

(ED-C x IR-S-C / BW-C) + (ED-Ax IR-S-A / BW-A)









ED-A

Exposure Duration, Adult

24

years

EPA, 1991











ED-C

Exposure Duration, Child

6

years

EPA, 1991











CF1

Conversion Factor 1

0.000001

kg/mg













BW-A

Body Weight, Adult

70

kg

EPA, 1991











BW-C

Body Weight, Child

15

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989



008557

Page 1 of 2


-------
TABLE 4.1.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current

Medium: Surface Soil

Exposure Medium: Surface Soil (Yards)

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Dermal

Resident

Adult

Surface Soil

CS

Chemical Concentration in Soil

See Table 3.3.RME

mg/kg

See Table 3.3.RME

CDI (mg/kg-day) =



(General Public)



(0-1 inch)

SA

Skin Surface Area Available for Contact

5,700

cm2

EPA, 2004

CS x SA x SSAF x DABS x CF1 x EF x ED x 1/BW x 1/AT









SSAF

Soil to Skin Adherence Factor

0.07

mg/cm2-day

EPA, 2004











DABS

Dermal Absorption Factor Solids

Chemical specific



EPA, 2000











CF1

Conversion Factor 1

0.000001

kg/mg













EF

Exposure Frequency

350

days/year

EPA, 1991











ED

Exposure Duration

24

years

EPA, 1991











BW

Body Weight

70

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

8,760

days

EPA, 1989







Child

Surface Soil

CS

Chemical Concentration in Soil

See Table 3.3.RME

mg/kg

See Table 3.3.RME

CDI (mg/kg-day) =







(0-1 inch)

SA

Skin Surface Area Available for Contact

2,800

cm2

EPA, 2004

CS x SA x SSAF x DABS x CF1 x EF x ED x 1/BW x 1/AT









SSAF

Soil to Skin Adherence Factor

0.2

mg/cm2-day

EPA, 2004











DABS

Dermal Absorption Factor Solids

Chemical specific



EPA, 2004











CF1

Conversion Factor 1

0.000001

kg/mg













EF

Exposure Frequency

350

days/year

EPA, 1991











ED

Exposure Duration

6

years

EPA, 1991











BW

Body Weight

15

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

2,190

days

EPA, 1989











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989







Child/Adult

Surface Soil

CS

Chemical Concentration in Soil

See Table 3.3.RME

mg/kg

See Table 3.3.RME

CDI (mg/kg-day) =







(0-1 inch)

SA-A

Skin Surface Area Available for Contact, Adult

5,700

cm2

EPA, 2004

CS x DA-Adj x DABS x CF1 x EF x 1/AT









SA-C

Skin Surface Area Available for Contact, Child

2,800

cm2

EPA, 2004











SSAF-A

Soil to Skin Adherence Factor, Adult

0.07

mg/cm2-day

EPA, 2004

DA-Adj (mg-year/kg-day) =









SSAF-C

Soil to Skin Adherence Factor, Child

0.2

mg/cm2-day

EPA, 2004

(ED-C x SA-C x SSAF-C / BW-C) +









DA-Adj

Dermal Absorption, Age-adjusted

361

mg-year/kg-day

Calculated

(ED-A x SA-A x SSAF-A / BW-A)









DABS

Dermal Absorption Factor Solids

Chemical specific



EPA, 2000











CF1

Conversion Factor 1

0.000001

kg/mg













EF

Exposure Frequency

350

days/year

EPA, 1991











ED-A

Exposure Duration, Adult

24

years

EPA, 1991











ED-C

Exposure Duration, Child

6

years

EPA, 1991











BW-A

Body Weight, Adult

70

kg

EPA, 1991











BW-C

Body Weight, Child

15

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989



Sources:

EPA, 1989: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual, Part A. OERR. EPA/540/1-89/002.

EPA, 1991: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual - Supplemental Guidance, Standard Default Exposure Factors
EPA, 2004: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual (Part E, Supplemental Guidance for Dermal Risk Assessment)
EPA Region 4, 2000: Human Health Risk Assessment Bulletins - Supplement to RAGS, Interim.

Page 2 of 2

. Interim Final. OSWER Directive 9285.6-03.
. Final. EPA/540/R/99/005.

008558


-------
TABLE 4.2.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current/Future
Medium: Groundwater
Exposure Medium: Groundwater

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Ingestion

Resident

Adult

Private Wells

CW

Chemical Concentration in Water

See Table 3.5.RME

Mgi

See Table 3.5.RME

Chronic Daily Intake (CDI) (mg/kg-day) =



(General Public)





IR-W

Ingestion Rate of Water

2

liters/day

EPA, 1997

CWx IR-Wx EF x ED x CF2 x 1/BWx 1/AT









EF

Exposure Frequency

350

days/year

EPA, 1991











ED

Exposure Duration

24

years

EPA, 1991











CF2

Conversion Factor 2

0.001

mg/|jg

--











BW

Body Weight

70

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

8,760

days

EPA, 1989







Child

Private Wells

CW

Chemical Concentration in Water

See Table 3.5.RME

Mgi

See Table 3.5.RME

CD I (mg/kg-day) =









IR-W

Ingestion Rate of Water

1

liters/day

EPA, 1997

CWx IR-Wx EF x ED x CF2 x 1/BWx 1/AT









EF

Exposure Frequency

350

days/year

EPA, 1991











ED

Exposure Duration

6

years

EPA, 1991











CF2

Conversion Factor 2

0.001

mg/|jg

--











BW

Body Weight

15

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

2,190

days

EPA, 1989







Child/Adult

Private Wells

CW

Chemical Concentration in Water

See Table 3.5.RME

Mgi

See Table 3.5.RME

CD I (mg/kg-day) =









IR-WA

Ingestion Rate of Water, Adult

2

liters/day

EPA, 1997

CW x I R-W-Adj x EF x CF2 x 1/AT









IR-WC

Ingestion Rate of Water, Child

1

liters/day

EPA, 1997











IR-WAdj

Ingestion Rate of Water, Age-adjusted

1.1

Iiter-year/kg-day

calculated

IR-WAdj (liter-year/kd-day) =









EF

Exposure Frequency

350

days/year

EPA, 1991

(ED-Cx IR-WC/BWC) +









EDA

Exposure Duration, Adult

24

years

EPA, 1991

(ED-Ax IR-WA/BWA)









ED-C

Exposure Duration, Child

6

years

EPA, 1991











CF2

Conversion Factor 2

0.001

mg/|jg

--











BWA

Body Weight, Adult

70

kg

EPA, 1991











BWC

Body Weight, Child

15

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989



Sources:

EPA, 1989:	Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual, Part A. OERR. EPA/540/1-89/002.

EPA, 1991:	Risk Assessment Guidance for Sup erfund. Vol.1: Human Health Evaluation Manual - Supplemental Guidance, Standard Default Exposure Factors. Interim Final. OSWER Directive 9285.6-03.

EPA, 1997:	Exposure Factors Handbook. EPA/600/P-95/002Fa.

Page 1 of 1

008559


-------
TABLE 4.3.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current/Future
Medium: Chat Pile Material and Tailings
Exposure Medium: Ambient Air	

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Inhalation

Resident

Adult

Ambient Air

CA

Chemical Concentration in Air

See Table 3.3.RME

mg/m3

See Table 3.3.RME

CDI (mg/kg-day) =



(General Public)





IN

Inhalation Rate

20

m3/day

EPA, 1991

CA x IN x EF x ED x 1/BWx 1/AT









EF

Exposure Frequency

350

days/year

EPA, 1991











ED

Exposure Duration

24

years

EPA, 1991











BW

Body Weight

70

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

8,760

days

EPA, 1989







Child

Ambient Air

CA

Chemical Concentration in Air

See Table 3.3.RME

mg/m3

See Table 3.3.RME

CDI (mg/kg-day) =









IN

Inhalation Rate

10

m3/day

EPA R6 (1)

CA x IN x EF x ED x 1/BWx 1/AT









EF

Exposure Frequency

350

days/year

EPA, 1991











ED

Exposure Duration

6

years

EPA, 1991











BW

Body Weight

15

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

2,190

days

EPA, 1989







Child/Adult

Ambient Air

CA

Chemical Concentration in Air

See Table 3.3.RME

mg/m3

See Table 3.3.RME

CDI (mg/kg-day) =









IN-A

Inhalation Rate, Adult

20

m3/day

EPA, 1991

CA x I N-Adj x EF x 1/AT









IN-C

Inhalation Rate, Child

10

m3/day

EPA R6 (1)











I N-Adj

Inhalation Rate, Age-adjusted

10.9

m3/hour

calculated

I N-Adj (m3-year/kg-day) =









EF

Exposure Frequency

350

days/year

EPA, 1991

(ED-C x IN-C / BW-C) + (ED-A x IN-A / BW-A)









ED-A

Exposure Duration, Adult

24

years

EPA, 1991











ED-C

Exposure Duration, Child

6

years

EPA, 1991











BW-A

Body Weight, Adult

70

kg

EPA, 1991











BW-C

Body Weight, Child

15

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989



Sources:

EPA, 1989: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual, Part A. OERR. EPA/540/1-89/002.

EPA, 1991: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual - Supplemental Guidance, Standard Default Exposure Factors. Interim Final. OSWER Directive 9285.6-03.
(1) EPA Region 6, Undated: Memorandum, Central Tendency and RME Exposure Parameters.

008560

Page 1 of 1


-------
TABLE 4.4.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current

Medium: Surface Soil

Exposure Medium: Surface Soil (Yards)

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Ingestion

Resident

Adult

Surface Soil

CS

Chemical Concentration in Soil

See Table 3.4.RME

mg/kg

See Table 3.4.RME

Chronic Daily Intake (CDI) (mg/kg-day) =



(Subsistence)



(0-1 inch)

IR-S

Ingestion Rate of Soil

400

mg/day

Harper et al., 2002

CS x IR-S x EF x ED x CF1 x 1/BWx 1/AT









EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

70

years

Harper et al., 2002











CF1

Conversion Factor 1

0.000001

kg/mg













BW

Body Weight

70

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002







Child

Surface Soil

CS

Chemical Concentration in Soil

See Table 3.4.RME

mg/kg

See Table 3.4.RME

CDI (mg/kg-day) =







(0-1 inch)

IR-S

Ingestion Rate of Soil

400

mg/day

Harper et al., 2002

CS x IR-S x EF x ED x CF1 x 1/BWx 1/AT









EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

6

years

EPA, 1991











CF1

Conversion Factor 1

0.000001

kg/mg













BW

Body Weight

15

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

2,190

days

EPA, 1989







Child/Adult

Surface Soil

CS

Chemical Concentration in Soil

See Table 3.4.RME

mg/kg

See Table 3.4.RME

CDI (mg/kg-day) =







(0-1 inch)

IR-S-A

Ingestion Rate of Soil, Adult

400

mg/day

Harper et al., 2002

CS x IR-S-Adj x EF x CF1 x 1/AT









IR-S-C

Ingestion Rate of Soil, Child

400

mg/day

Harper et al., 2002











IR-S-Adj

Ingestion Rate of Soil, Age-adjusted

526

mg-year/kg-day

Calculated

IR-S-Adj (mg-year/kd-day) =









EF

Exposure Frequency

365

days/year

Harper et al., 2002

(ED-C x IR-S-C / BW-C) + (ED-A x IR-S-A / BW-A)









ED-A

Exposure Duration, Adult

64

years

Harper et al., 2002











ED-C

Exposure Duration, Child

6

years

EPA, 1991











CF1

Conversion Factor 1

0.000001

kg/mg













BW-A

Body Weight, Adult

70

kg

EPA, 1991











BW-C

Body Weight, Child

15

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989



008561

Page 1 of 2


-------
TABLE 4.4.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current

Medium: Surface Soil

Exposure Medium: Surface Soil (Yards)

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Dermal

Resident

Adult

Surface Soil

CS

Chemical Concentration in Soil

See Table 3.4.RME

mg/kg

See Table 3.4.RME

CD I (mg/kg-day) =



(Subsistence)



(0-1 inch)

SA

Skin Surface Area Available for Contact

5,700

cm2

EPA, 2004

CS x SA x SSAF x DABS x CF1 x EF x









SSAF

Soil to Skin Adherence Factor

0.07

mg/cm2-day

EPA, 2004

ED x 1/BWx 1/AT









DABS

Dermal Absorption Factor Solids

Chemical specific



EPA, 2000











CF1

Conversion Factor 1

0.000001

kg/mg













EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

70

years

Harper et al., 2002











BW

Body Weight

70

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002







Child

Surface Soil

CS

Chemical Concentration in Soil

See Table 3.4.RME

mg/kg

See Table 3.4.RME

CD I (mg/kg-day) =







(0-1 inch)

SA

Skin Surface Area Available for Contact

2,800

cm2

EPA, 2004

CS x SA x SSAF x DABS xCF1 x EF x EDx 1/BWx 1/AT









SSAF

Soil to Skin Adherence Factor

0.2

mg/cm2-day

EPA, 2004











DABS

Dermal Absorption Factor Solids

Chemical specific



EPA, 2004











CF1

Conversion Factor 1

0.000001

kg/mg













EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

6

years

EPA, 1991











BW

Body Weight

15

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

2,190

days

EPA, 1989







Child/Adult

Surface Soil

CS

Chemical Concentration in Soil

See Table 3.4.RME

mg/kg

See Table 3.4.RME

CD I (mg/kg-day) =







(0-1 inch)

SA-A

Skin Surface Area Available for Contact, Adult

5,700

cm2

EPA, 2004

CS x DA-Adj x DABS x CF1 x EF x 1/AT









SA-C

Skin Surface Area Available for Contact, Child

2,800

cm2

EPA, 2004











SSAF-A

Soil to Skin Adherence Factor, Adult

0.07

mg/cm2-day

EPA, 2004

DA-Adj (mg-year/kg-day) =









SSAF-C

Soil to Skin Adherence Factor, Child

0.2

mg/cm2-day

EPA, 2004

(ED-C x SA-C x SSAF-C / BW-C) +









DA-Adj

Dermal Absorption, Age-adjusted

589

mg-year/kg-day

Calculated

(ED-A x SA-A x SSAF-A / BW-A)









DABS

Dermal Absorption Factor Solids

Chemical specific



EPA, 2000











CF1

Conversion Factor 1

0.000001

kg/mg













EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED-A

Exposure Duration, Adult

64

years

Harper et al., 2002











ED-C

Exposure Duration, Child

6

years

EPA, 1991











BW-A

Body Weight, Adult

70

kg

EPA, 1991











BW-C

Body Weight, Child

15

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989



Sources:

EPA, 1989: Risk Assessment Guidance for Superlund. Vol.1: Human Health Evaluation Manual, Part A. OERR. EPA/540/1-89/002.

EPA, 1991: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual - Supplemental Guidance, Standard Default Exposure Factors. Interim Final. OSWER Directive 9285.6-03.
EPA, 2004: Risk Assessment Guidance for Superlund. Vol.1: Human Health Evaluation Manual (Part E, Supplemental Guidance for Dermal Risk Assessment). Final. EPA/540/R/99/005.

EPA Region 4, 2000: Human Health Risk Assessment Bulletins — Supplement to RAGS, Interim.

Harper et al. 2002. The Spokane Tribe's Multipathway Subsistence Exposure Scenario and Screening Level RME. Risk Analysis. VOL 22. No. 3.

008562

Page 2 of 2


-------
TABLE 4.5.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current/Future

Medium: Surface Soil (residential, smelter, transition zone)

Exposure Medium: Animal Tissue	

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Ingestion

Resident

Adult

Small Game (Bird, Rabbit)

CS

Chemical Concentration in Soil

See Table 3.2.RME

mg/kg

See Table 3.2.RME

Chronic Daily Intake (CDI) (mg/kg-day) =



(Subsistence)





BAF-SMG

Bio-accumulation Factor-Small Game

chemical specific

kg/kg

(1)

(C3-game x IR-SMG + Cbeef x IR-BEEF) x ED x EF x 1/BWx 1/AT



* high fish diet





IR-SMG

Ingestion Rate-Small Game

0.05

kg/day

Harper et al., 2002

Small Game Tissue Concentration (Cs.game) (mg/kg) =









EF

Exposure Frequency

365

days/year

Harper et al., 2002

Cs x BAF-SMG (metals)









ED

Exposure Duration

70

years

Harper et al., 2002











BW

Body Weight

70

kg

EPA, 1991

Beef Tissue Concentration (Cbeef) (mg/kg) will be estimated









AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989

based on concentration in soil in accordance with EPA, 2005.









AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002









Beef

Cbeef

Chemical Concentration in Beef

(2)

mg/kg

(2)









(Cattle)

IR-BEEF

Ingestion Rate - Beef

0.10

kg/day

Harper et al., 2002











EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

70

years

Harper et al., 2002











BW

Body Weight

70

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002



Ingestion

Resident

Adult

Small Game (Bird, Rabbit)

CS

Chemical Concentration in Soil

See Table 3.2.RME

mg/kg

See Table 3.2.RME

Chronic Daily Intake (CDI) (mg/kg-day) =



(Subsistence)





BAF-SMG

Bio-accumulation Factor-Small Game

chemical specific

kg/kg

(1)

(C3-game x IR-SMG + Cbeef x IR-BEEF) x ED x EF x 1/BWx 1/AT



* high beef diet





IR-SMG

Ingestion Rate-Small Game

0.05

kg/day

Harper et al., 2002











EF

Exposure Frequency

365

days/year

Harper et al., 2002

Small Game Tissue Concentration (Cs.game) (mg/kg) =









ED

Exposure Duration

70

years

Harper et al., 2002

Cs x BAF-SMG (metals)









BW

Body Weight

70

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989

Beef Tissue Concentration (Cbeef) (mg/kg) will be estimated









AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002

based on concentration in soil in accordance with EPA, 2005.







Beef

Cbeef

Chemical Concentration in Beef

(2)

mg/kg

(2)









(Cattle)

IR-BEEF

Ingestion Rate - Beef

0.885

kg/day

Harper et al., 2002











EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

70

years

Harper et al., 2002











BW

Body Weight

70

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002



Sources:

EPA, 1989: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual, Part A. OERR. EPA/540/1-89/002.

EPA, 1991: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual - Supplemental Guidance, Standard Default Exposure Factors. Interim Final. OSWER Directive 9285.6-03.
EPA, 2005: Human Health Risk Assessment Protocol for Hazardous Waste Combustion Facilities.

Harper et al. 2002. The Spokane Tribe's Multipathway Subsistence Exposure Scenario and Screening Level RME. Risk Analysis. VOL 22. No. 3.

(1)	Methodology used to estimate chemical concentrations in Small Game is presented in Table 7.4 Supplement A

(2)	Methodology used to estimate chemical concentrations in Beef is presented in Table 7.4 Supplement B

008563

Page 1 of 1


-------
TABLE 4.6.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current/Future

Medium: Surface Soil (residential, smelter, transition zone)

Exposure Medium: Milk (Dairy)	

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Ingestion

Resident

Child

Milk (Dairy)

C-DM

Chemical Concentration in Milk (Dairy)

(1)

Mg/i

(1)

CD I (mg/kg-day) =



(Subsistence)





IR-DM

Ingestion Rate of Milk (Dairy)

0.5

liters/day

Harper et al., 2002

C-DM x IR-DM x EFx ED xCF1 x1/BWx1/AT









EF

Exposure Frequency

365

days/year













ED

Exposure Duration

6

years

EPA, 1991

Concentration in milk (C^k) (mg/kg) will be estimated









CF1

Conversion Factor 1

0.001

mg/|jg



based on concentration in soil in accordance with EPA, 2005.









BW

Body Weight

15

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989











AT-N

Averaging Time (Non-Cancer)

2,190

days

EPA, 1989



Sources:

EPA, 1989: Risk Assessment Guidance for Superlund. Vol.1: Human Health Evaluation Manual, Part A. OERR. EPA/540/1-89/002.

EPA, 1991: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual - Supplemental Guidance, Standard Default Exposure Factors. Interim Final. OSWER Directive 9285.6-03.
EPA, 1997: Exposure Factors Handbook. EPA/600/P-95/002Fa.

EPA, 2005: Human Health Risk Assessment Protocol for Hazardous Waste Combustion Facilities.

Harper et al. 2002. The Spokane Tribe's Multipathway Subsistence Exposure Scenario and Screening Level RME. Risk Analysis. VOL 22. No. 3.

(1) Methodology used to estimate chemical concentrations in Beef is presented in Table 7.4 Supplement B

008564

Page 1 of 1


-------
TABLE 4.7.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current/Future
Medium: Chat Pile material and Tailings
Exposure Medium: Ambient Air	

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Inhalation

Resident

Adult

Ambient Air

CA

Chemical Concentration in Air

See Table 3.7.RME

mg/m3

See Table 3.7.RME

Chronic Daily Intake (CDI) (mg/kg-day) =



(Subsistence)





IN

Inhalation Rate

30

m3/day

Harper et al., 2002

CA x IN x EF x ED x 1/BWx 1/AT









EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

70

years

Harper et al., 2002











BW

Body Weight

70

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002







Child

Ambient Air

CA

Chemical Concentration in Air

See Table 3.7.RME

mg/m3

See Table 3.7.RME

CDI (mg/kg-day) =









IN

Inhalation Rate

10

m3/day

EPA R6 (1)

CAxINx EFxEDx 1/BWx 1/AT









EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

6

years

EPA, 1991











BW

Body Weight

15

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

2,190

days

EPA, 1989







Child/Adult

Ambient Air

CA

Chemical Concentration in Air

See Table 3.7.RME

mg/m3

See Table 3.7.RME

CDI (mg/kg-day) =









IN-A

Inhalation Rate, Adult

30

m3/day

Harper et al., 2002

CA x I N-Adj xEFx 1/AT









IN-C

Inhalation Rate, Child

10

m3/day

EPA R6 (1)











I N-Adj

Inhalation Rate, Age-adjusted

31.4

m3/hour

calculated

I N-Adj (m3-year/kg-day) =









EF

Exposure Frequency

365

days/year

Harper et al., 2002

(ED-C x IN-C / BWC) + (ED-A x IN-A / BWA)









ED-A

Exposure Duration, Adult

64

years

Harper et al., 2002











ED-C

Exposure Duration, Child

6

years

EPA, 1991











BW-A

Body Weight, Adult

70

kg

EPA, 1991











BW-C

Body Weight, Child

15

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989



Sources:

EPA, 1989: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual, Part A. OERR. EPA/540/1-89/002.

EPA, 1991: Risk Assessment Guidance for Sup erfund. Vol.1: Human Health Evaluation Manual - Supplemental Guidance, Standard Default Exposure Factors. Interim Final. OSWER Directive 9285.6-03.
Harper et al. 2002. The Spokane Tribe's Multipathway Subsistence Exposure Scenario and Screening Level RME. Risk Analysis. VOI. 22. No. 3.

(1) EPA Region 6, Undated: Memorandum, Central Tendency and RME Exposure Parameters.

008565

Page 1 of 1


-------
TABLE 4.8.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current/Future
Medium: Groundwater
Exposure Medium: Groundwater

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Ingestion

Resident

Adult

Private Wells

CW

Chemical Concentration in Water

See Table 3.6.RME

Mg/i

See Table 3.6.RME

Chronic Daily Intake (CDI) (mg/kg-day) =



(Subsistence)





IR-W

Ingestion Rate of Water

4

liters/day

Harper et al., 2002

CWx IR-Wx EF x ED x CF1 x 1/BWx 1/AT









EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

70

years

Harper et al., 2002











CF1

Conversion Factor 1

0.001

mg/pg













BW

Body Weight

70

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002







Child

Private Wells

CW

Chemical Concentration in Water

See Table 3.6.RME

Mg/i

See Table 3.6.RME

CDI (mg/kg-day) =









IR-W

Ingestion Rate of Water

1

liters/day

EPA, 1997

CWx IR-Wx EF x ED x CF1 x 1/BWx 1/AT









EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

6

years

EPA, 1991











CF1

Conversion Factor 1

0.001

mg/pg













BW

Body Weight

15

kg

EPA, 1991











AT-N

Averaging Time (Non-Cancer)

2,190

days

EPA, 1989











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989







Child/Adult

Private Wells

CW

Chemical Concentration in Water

See Table 3.6.RME

Mg/i

See Table 3.6.RME

CDI (mg/kg-day) =









IR-W-A

Ingestion Rate of Water, Adult

4

Mg/i

Harper et al., 2002

CWx IR-W-Adj x EF x CF1 x 1/AT









IR-W-C

Ingestion Rate of Water, Child

1

liters/day

EPA, 1997











IR-W-Adj

Ingestion Rate of Water, Age-adjusted

4.1

liter-year/kg-day

calculated

IR-W-Adj (liter-year/kd-day) =









EF

Exposure Frequency

365

days/year

Harper et al., 2002

(ED-C x IR-W-C/BW-C) +









ED-A

Exposure Duration, Adult

64

years

Harper et al., 2002

(ED-Ax IR-W-A/ BW-A)









ED-C

Exposure Duration, Child

6

years

EPA, 1991











CF1

Conversion Factor 1

0.001

mg/pg













BW-A

Body Weight, Adult

70

kg

EPA, 1991











BW-C

Body Weight, Child

15

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989



Sources:

EPA, 1989: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual, Part A OERR. EPA/540/1-89/002.

EPA, 1991: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual - Supplemental Guidance, Standard Default Exposure Factors. Interim Final. OSWER Directive 9285.6-03.
EPA, 1997: Exposure Factors Handbook. EPA/600/P-95/002Fa.

Harper et al. 2002. The Spokane Tribe's Multipathway Subsistence Exposure Scenario and Screening Level RME. Risk Analysis. VOL 22. No. 3.

Page 1 of 1

008566


-------
TABLE 4.9.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current/Future

Medium: Aquatic Biota

Exposure Medium: Fish Tissue/Aquatic Food

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Ingestion

Resident

Adult

Fish Tissue

Cflsh

Chemical Concentration in Fish Tissue

(1)

mg/kg-fish

ODEQ, 2003

Chronic Daily Intake (CDI) (mg/kg-day) =



(Subsistence)





IR-F

Fish Ingestion Rate

0.885

kg-fish/day

Harper et al., 2002

Cfi3h x IR-F x ED x EF x 1/BWx 1/AT



* high fish diet





EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

70

years

Harper et al., 2002











BW

Body Weight

70

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA,1989











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002









Aquatic Food Tissue

CSed

Chemical Concentration in Sediment

(2)

mg/kg-sed

ODEQ, 2003

Chronic Daily Intake (CDI) (mg/kg-day) =







(Mussels etc.)

BAF-AI

Bio-accumulation Factor (Aquatic Invertebrates)

chemical specific

kg/kg-tissue

(2)

CaquaticfGGd x IR-F x ED x EF x 1/BWx 1/AT









IR-AF

Aquatic Food (Mussels, Crayfish) Ingestion Rate

0.175

kg-food/day

Harper et al., 2002

Aquatic Food Concentration (Caquaticfcicid) (mg/kg) =









EF

Exposure Frequency

365

days/year

Harper et al., 2002

Csed x BCF-AI (metals)









ED

Exposure Duration

70

years

Harper et al., 2002











BW

Body Weight

70

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA,1989











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002



Ingestion

Resident

Adult

Fish Tissue

Cflsh

Chemical Concentration in Fish Tissue

(1)

mg/kg-fish

ODEQ, 2003

Chronic Daily Intake (CDI) (mg/kg-day) =



(Subsistence)





IR-F

Fish Ingestion Rate

0.075

kg-fish/day

Harper et al., 2002

Cfi3h x IR-F x ED x EF x 1/BWx 1/AT



* high beef diet





EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

70

years

Harper et al., 2002











BW

Body Weight

70

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA,1989











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002









Aquatic Food Tissue

CSed

Chemical Concentration in Sediment

(2)

mg/kg-sed

ODEQ, 2003

Chronic Daily Intake (CDI) (mg/kg-day) =







(Mussels etc.)

BAF-AI

Bio-accumulation Factor (Aquatic Invertebrates)

chemical specific

kg/kg-tissue

(2)

CaquaticfGGd x IR-F x ED x EF x 1/BWx 1/AT









IR-AF

Aquatic Food (Mussels, Crayfish) Ingestion Rate

0.175

kg-food/day

Harper et al., 2002

Aquatic Food Concentration (Caquaticfood) (m£)/kg) =









EF

Exposure Frequency

365

days/year

Harper et al., 2002

Csed x BCF-AI (metals)









ED

Exposure Duration

70

years

Harper et al., 2002











BW

Body Weight

70

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA,1989











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002



Sources:

EPA, 1989: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual, Part A. OERR. EPA/540/1-89/002.

EPA, 1991: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual - Supplemental Guidance, Standard Default Exposure Factors. Interim Final. OSWER Directive 9285.6-03.
Harper et al. 2002. The Spokane Tribe's Multipathway Subsistence Exposure Scenario and Screening Level RME. Risk Analysis. VOL 22. No. 3.

ODEQ. 2003. Fish Tissue Metals Analysis in theTri-State Mining Area. FY 2003. Final Report.

(1)	Concentrations used for intake calculation are presented in Table 7.4 Supplement E.

(2)	Methodology used to estimate chemical concentrations in Aquatic Invertebrates is presented in Table 7.4 Supplement D

008567

Page 1 of 1


-------
TABLE 4.10.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current/Future

Medium: Transition Zone Soil

Exposure Medium: Unwashed Plant (Leaf & Root)

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Ingestion

Resident

Adult

Asparagus

Cpiantl

Chemical Concentration in Asparagus (above ground)

See Table 3.7.RME

mg/kg



Chronic Daily Intake (CDI) (mg/kg-day) =



(Subsistence)





Cpiant1-root

Chemical Concentration in Asparagus (root).

See Table 3.8.RME

mg/kg

See Table 3.8.RME











IR-P1

Ingestion Rate -Asparagus (above ground)

0.27

kg/day

Harper etal., 2002(1)

Z (Cpiant x IR-P) x ED x EF x 1/BWx 1/AT









IR"P1root

Ingestion Rate -Asparagus (root)

0.27

kg/day

Harper etal., 2002(1)











EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

70

years

Harper et al., 2002











BW

Body Weight

70

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA,1989











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002









Willow

Cpiant2

Chemical Concentration in Willow (above ground)

See Table 3.9.RME

mg/kg

See Table 3.9.RME











Cpiant2-root

Chemical Concentration in Willow (root).

See Table 3.10.RME

mg/kg

See Table 3.10.RME











IR-P2

Ingestion Rate -Willow (above ground)

0.27

kg/day

Harper etal., 2002(1)











IR-P2root

Ingestion Rate -Willow (root)

0.27

kg/day

Harper etal., 2002(1)











EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

70

years

Harper et al., 2002











BW

Body Weight

70

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA,1989











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002









Cattail

Cpiant3

Chemical Concentration in Cattail (above ground)

See Table 3.11.RME

mg/kg

See Table 3.11.RME











Cpiant3-root

Chemical Concentration in Cattail (root).

See Table 3.12.RME

mg/kg

See Table 3.12.RME











IR-P3

Ingestion Rate -Cattail (above ground)

0.27

kg/day

Harper etal., 2002(1)











IR-P3root

Ingestion Rate -Cattail (root)

0.27

kg/day

Harper etal., 2002(1)











EF

Exposure Frequency

365

days/year

Harper et al., 2002











ED

Exposure Duration

70

years

Harper et al., 2002











BW

Body Weight

70

kg

EPA, 1991











AT-C

Averaging Time (Cancer)

25,550

days

EPA,1989











AT-N

Averaging Time (Non-Cancer)

25,550

days

Harper et al., 2002



Sources:

EPA, 1989: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual, Part A. OERR. EPA/540/1-89/002.

EPA, 1991: Risk Assessment Guidance for Sup erfund. Vol.1: Human Health Evaluation Manual - Supplemental Guidance, Standard Default Exposure Factors. Interim Final. OSWER Directive 9285.6-03.
Harper et al. 2002. The Spokane Tribe's Multipathway Subsistence Exposure Scenario and Screening Level RME. Risk Analysis. VOL 22. No. 3.

(1) Composition of Total Plant Intake of 1,600 g/day was equally divided as follows:

Asparagus (above ground) -16.7%, (root) -16.7%

Willow (above ground) -16.7%, (root) -16.7%

Cattail (above ground) -16.7%, (root) -16.7%

008568

Page 1 of 1


-------
TABLE 4.11.RME
VALUES USED FOR DAILY INTAKE CALCULATIONS
REASONABLE MAXIMUM EXPOSURE
Tar Creek - Miami, OK

Scenario Timeframe: Current/Future
Medium: Chat and Tailings Material
Exposure Medium: Surface Material

Exposure Route

Receptor Population

Receptor Age

Exposure Point

Parameter

Parameter Definition

Value

Units

Rationale/

Intake Equation/









Code







Reference

Model Name

Ingestion

Re creator

Adolescent

Chat Pile & Tailings Ponds

CM

Chemical Concentration in Material

See Table 3.1.RME

mg/kg

See Table 3.1.RME

Chronic Daily Intake (CDI) (mg/kg-day) =







Surface (0-6 inch)

IR-S

Ingestion Rate of Material

100

mg/day

EPA, 1991

CM x IR-S x EF x ED x CF1 x 1/BW x 1/AT









EF

Exposure Frequency

184

days/year

(1)











ED

Exposure Duration

11

years

(2)











CF1

Conversion Factor 1

0.000001

kg/mg













BW

Body Weight

47

kg

(3)











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989











AT-N

Averaging Time (Non-Cancer)

4,015

days

EPA, 1989



Dermal

Re creator

Adolescent

Chat Pile & Tailings Ponds

CM

Chemical Concentration in Material

See Table 3.1.RME

mg/kg

See Table 3.1.RME

CDI (mg/kg-day) =







Surface (0-6 inch)

SA

Skin Surface Area Available for Contact

5,300

cm2

EPA, 2004 (4)

CM x SA x SSAF x DABS xCF1 x EF x ED x 1/BW x 1/AT









SSAF

Soil to Skin Adherence Factor

0.07

mg/cm2-day

EPA, 2004 (5)











DABS

Dermal Absorption Factor Solids

Chemical specific



EPA, 2000











CF1

Conversion Factor 1

0.000001

kg/mg













EF

Exposure Frequency

184

days/year

(1)











ED

Exposure Duration

11

years

(2)











BW

Body Weight

47

kg

(3)











AT-C

Averaging Time (Cancer)

25,550

days

EPA, 1989











AT-N

Averaging Time (Non-Cancer)

4,015

days

EPA, 1989



Sources:

EPA, 1989: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual, Part A. OERR. EPA/540/1-89/002.

EPA, 1991: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual - Supplemental Guidance, Standard Default Exposure Factors. Interim Final. OSWER Directive 9285.6-03.
EPA, 2004: Risk Assessment Guidance for Superfund. Vol.1: Human Health Evaluation Manual (Part E, Supplemental Guidance for Dermal Risk Assessment). Final. EPA/540/R/99/005.

EPA Region 4, 2000: Human Health Risk Assessment Bulletins — Supplement to RAGS, Interim.

(1)	Professional Judgment: the average total number of days without rain and above freezing for the years between 1999 and 2003.

(2)	Professional Judgment assuming adolescents from 7 to 18 years of age.

(3)	Body weight is average value for the 7 year old and 18 year old male and female body weight.

(4)	SA includes head, hands, forearms, lower legs, and feet.

(5)	SSAF for children (1-6 year old).

008569

Page


-------
TABLE 5.1

NON-CANCER TOXICITY DATA -- ORAL/DERMAL
Tar Creek - Miami, OK

Chemical
of Potential
Concern

Chronic/
Subchronic

Oral RfD

Oral Absorption
Efficiency for Dermal

(1)

Absorbed RfD for Dermal (2)

Primary
T arget
Organ (s)

Combined
Uncertainty/Modifying
Factors

RfDTarget Organ(s)

Value

Units

Value

Units

Source(s)

Date(s)
(MM/DD/YYYY)

Cadmium (water)

Chronic

5.0E-04

mg/kg-day

0.05

2.5E-05

mg/kg-day

Kidney

10/1

IRIS

10/10/2005

Cadmium (food)

Chronic

1.0E-03

mg/kg-day

0.025

2.5E-05

mg/kg-day

Kidney

10/1

IRIS

10/10/2005

Zinc

Chronic

3.0E-01

mg/kg-day

highly variable

3.0E-01

mg/kg-day

Circulatory

3/1

IRIS

10/10/2005

Footnote Instructions:

(1)	Source: Risk Assessment Guidance for Superfund. Volume 1: Human Health	Definitions: NA = Not Available

Evalution Manual (Part E, Supplemental Guidance for Dermal Risk Assessment (Final).	IRIS = Integrated Risk Information System

Section 4.2 and Exhibit 4-1. USEPA recommends that the oral RfD should not be adjusted to

estimate the absorbed dose for compounds when the absorption efficiency is greater than 50%.

Constituents that do not have oral absorption efficiencies reported on this table

were assumed to have an oral absorption efficiency of 100%.

(2)	See Risk Assessment text for the derivation of the "Absorbed RfD for Dermal"

008570

Page 1 of 1


-------
TABLE 5.2

NON-CANCER TOXICITY DATA-- INHALATION
Tar Creek - Miami, OK

Chemical

Chronic/

Inhalation RfC

Extrapolated RfD (1)

Primary

Combined

RfC : Target Organ(s)

of Potential

Subchronic









Target

Uncertainty/Modifying





Concern



Value

Units

Value

Units

Organ(s)

Factors

Source(s)

Date(s)



















(MM/DD/YYYY)

Cadmium

Chronic

2.0E-04

mg/m3

5.7E-05

mg/kg-day

Kidney

10

NCEA

06/14/1998

Zinc

Chronic

NA

NA

NA

NA

NA

NA

IRIS

10/10/2005

(1) See Risk Assessment text for the derivation of the "Extrapolated RfD"	Definitions: NA = Not Available

IRIS = Integrated Risk Information System

NCEA = National Center for Environmental Assessment

008571

Page 1 of 1


-------
TABLE 6.1

CANCER TOXICITY DATA-- ORAL/DERMAL
Tar Creek - Miami, OK

Chemical

Oral Cancer Slope Factor

Oral Absorption

Absorbed Cancer Slope Factor

Weight of Evidence/

Oral CSF

of Potential





Efficiency for Dermal

for Dermal

Cancer Guideline





Concern

Value

Units

(1)

Value

Units

Description

Source(s)

Date(s)

















(MM/DD/YYYY)

Cadmium

NA

NA

NA

NA

NA

B1

IRIS

10/10/2005

Zinc

NA

NA

NA

NA

NA

D

IRIS

10/10/2005

(1)	Source: Risk Assessment Guidance for Superfund. Volume 1: Human Health	Definitions:	NA = Not Available

Evalution Manual (Part E, Supplemetnal Guidance for Dermal Risk Assessment Final).	IRIS = Integrated Risk Information System

Section 4.2 and Exhibit 4-1. USE PA recommends that the oral RfD should not be adjusted to

estimate the absorbed dose for compounds when the absorption efficiency is greater than 50%.

Constituents that do not have oral absorption efficiencies reported on this table

were assumed to have an oral absorption efficiency of 100%.

(2)	See Risk Assessment text for the derivation of the "Absorbed RfD for Dermal"

Weight of Evidence definitions:

Group A chemicals (known human carcinogens) are agents for which there is sufficient evidence to support the causal association between exposure to the agents in humans and cancer.
Group B1 chemicals (probable human carcinogens) are agents for which there is limited evidence of possible carcinogenicity in humans.

Group B2 chemicals (probable human carcinogens) are agents for which there is sufficient evidence of carcinogenicity in animals but inadequate or a lack of evidence in humans.

Group C chemicals (possible human carcinogens) are agents for which there is limited evidence of carcinogenicity in animals and inadequate or a lack of human data.

Group D chemicals (not classifiable as to human carcinogenicity) are agents with inadequate human and animal evidence of carcinogenicity or for which no data are available.

Group E chemicals (evidence of noncarcinogenicity in humans) are agents for which there is no evidence of carcinogenicity from human or animal studies, or both.

008572

Page 1 of 1


-------
TABLE 6.2

CANCER TOXICITY DATA - INHALATION
Tar Creek - Miami, OK

Chemical

Unit Risk

Inhalation Cancer Slope Factor

Weight of Evidence/

Unit Risk : Inhalation CSF

of Potential









Cancer Guideline





Concern

Value

Units

Value

Units

Description

Source(s)

Date(s)















(MM/DDATYY)

Cadmium

1.8E-03

ftjg/m3)"1

6.3E+00

(mg/kg-day)"1

B1

IRIS

10/10/2005

Zinc

NA

NA

NA

NA

D

IRIS

10/10/2005

Definitions:	NA = Not Available

IRIS = Integrated Risk Information System
Weight of Evidence definitions:

Group A chemicals (known human carcinogens) are agents for which there is sufficient evidence to support the causal association between exposure to the agents in humans and cancer.
Group B1 chemicals (probable human carcinogens) are agents for which there is limited evidence of possible carcinogenicity in humans.

Group B2 chemicals (probable human carcinogens) are agents for which there is sufficient evidence of carcinogenicity in animals but inadequate or a lack of evidence in humans.

Group C chemicals (possible human carcinogens) are agents for which there is limited evidence of carcinogenicity in animals and inadequate or a lack of human data.

Group D chemicals (not classifiable as to human carcinogenicity) are agents with inadequate human and animal evidence of carcinogenicity or for which no data are available.

Group E chemicals (evidence of noncarcinogenicity in humans) are agents for which there is no evidence of carcinogenicity from human or animal studies, or both.

008573

Page 1 of 1


-------
TABLE 7.1.RME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current

Receptor Population: Residential (General Public)

Receptor Age: Adult

Chemical of
Potential Concern

Cancer Risk Calculations

Intake/Exposure Concentration

Non-Cancer Hazard Calculations

e Concentration

Surface Soil (Yards)

Surface Soil
(0-1 inch)

Cadmium

Exp. Route Total

Cadmium

Exposure Point Total

4.8E+01
7.7E+03

MG/KG
MG/KG

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

6.5E-05
1.1E-02

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

4.8E+01
7.7E+03

MG/KG
MG/KG

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

2.6E-07
4.2E-05

mg/kg/day
mg/kg/day

2.5E-05
3.0E-01

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

6.5E-02
3.5E-02

1.0E-02
1.4E-04

Exposure Medium Total

Surface Soil Total

Chat
and Tailings
Material

Inhalation ICadmium

Exposure Point Total

8.1E-08
1.7E-05

MG/M3
MG/M4

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

2.2E-08
4.8E-06

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

Exposure Medium Total

:hat and Tailings Total

Groundwater

Groundwater

Cadmium

Exp. Route Total

Exposure Point Total

3.00E+00
1.11E+03

UG/L
UG/L

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

8.2E-05
3.0E-02

mg/kg/day
mg/kg/day

5.0E-04
3.0E-01

mg/kg/day
mg/kg/day

1.6E-01
1.0E-01

Exposure Medium Total

Groundwater Total

008574


-------
TABLE 7.2.RME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current

Receptor Population: Residential (General Public)

Receptor Age: Child

008575


-------
TABLE 7.3.RME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current

Receptor Population: Residential (General Public)

Receptor Age: Adult/Child

008576


-------
Scenario Timeframe: Current/Future
Receptor Population: Residential (Subsistence)
Receptor Age: Adult	

TABLE 7.4.R ME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Exposure Medium

Exposure Route

Chemical of
Potential Concern

Cancer Risk Calculations

Intake/Exposure Concentration

CSF/Unit Risk

Non-Cancer Hazard Calculations

Intake/Exposure Concentration

Surface Soil (Yards)

Surface Soil
(0-1 inch)

9.6E+00
1.9E+03

MG/KG
MG/KG

7.2E-05
1.5E-02

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

5.5E-05
1.1E-02

mg/ kg/day
mat kg/day

1.0E-03
3.0E-01

mg/kg/day
mg/kg/day

5.5E-02
3.7E-02

Exp. Route Total

Exposure Medium Total

Surface Soil Total

Exposure Point Total

9.6E+00
1.9E+03

MG/KG
MG/KG

5.2E-06
1.0E-03

mg/kgMay
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

5.5E-08
1.1E-05

mg/kg/day
mat kg/day

2.5E-05
3.0E-01

mg/kg/day
mg/kg/day

2.2E-03
3.7E-05

Chat Pile material
and Tailings

8.1E-08
1.7E-05

MG/M3
MG/M3

3.6E-08
7.9E-06

mg/kgMay
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

3.5E-08
7.5E-06

mgl kg/day
mat kg/day

mg/kg/day
mg/kg/day

Exp. Route Total

Exposure Medium Total

Chat Pile Material and Tailings Total

Surface Soil (residential,
smelter, I

Animal Tissue

Exposure Point Total

Small Game
(Bird, Rabbit)

Exposure Point Total

Beef (Cattle)
* high fish diet

Exposure Point Total

Beef (Cattle)
* high beef diet

Exposure Point Total

Exp. Route Total

Exp. Route Total

6.1E+02
2.8E+04

1.3E-02
1.4E+00

1.3E-02
1.4E+00

MG/KG
MG/KG

MG/KG
MG/KG

MG/KG
MG/KG

4.0E-01
1.8E+01

1.7E-05
1.8E-03

1.5E-04
1.6E-02

mg/kgMay
mg/kg/day

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

1/(mg/kg-day)
1/(mg/kg-day)

1/(mg/kg-day)
1/(mg/kg-day)

4.4E-07
2.0E-05

1.6E-10
1.7E-08

mgl kg/day
mat kg/day

mgl kg/day
mat kg/day

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

1.0E-03
3.0E-01

1.0E-03
3.0E-01

mg/kg/day
mg/kgMay

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

4.4E-04
6.7E-05

1.8E-08
6.5E-09

1.6E-07
5.8E-08

Exposure Medium Total (High Fish Diet)

zxposure Medium Total (High Beef Diet)

Surface Soil (residential, smelter,

jne) Total (High Fish Diet)

Surface Soil (residential, smelter,

jne) Total (High Beef Diet)

Revised 02/09/2006

008577

Page 1 of 3


-------
TABLE 7.4.R ME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Receptor Population: Residential (Subsistence)
Receptor Age: Adult	

Exposure Medium

Exposure Route

Chemical of
Potential Concern

Cancer Risk Calculations

Intake/Exposure Concentration

CSF/Unit Risk

Non-Cancer Hazard Calculations

Intake/Exposure Concentration

Transition Zone

Asparagus (above ground)
Asparagus (root)

Ingestion
Ingestion

5.5E+00
1.4E+02
1.2E+01
1.4E+03

MG/KG
MG/KG
MG/KG
MG/KG

1.9E-02
5.0E-01
4.4E-02
4.9E+00

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)
1/(mg/kg-day)
1/(mg/kg-day)

2.1E-02
5.5E-01
4.8E-02
5.4E+00

mg/ kg/day
mat kg/day
mg/kg/day
mg/kg/day

1.0E-03
3.0E-01
1.0E-03
3.0E-01

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

2.1E+01
1.8E+00
4.8E+01
1.8E+01

Exposure Point Total

Exp. Route Total

Willow (above ground)
Willow (root)

Ingestion
Ingestion

1.8E+01
4.7E+02
5.0E+01
4.6E+03

MG/KG
MG/KG
MG/KG
MG/KG

6.3E-02
1.6E+00
1.8E-01
1.6E+01

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)
1/(mg/kg-day)
1/(mg/kg-day)

6.9E-02
1.8E+00
1.9E-01
1.8E+01

mg/kg/day
mg! kg/day
mg! kg/day
mg! kg/day

1.0E-03
3.0E-01
1.0E-03
3.0E-01

mgfkgfday I	6.9E+01

mgfkgfday I	6.0E+00

mgfkgfday I	1.9E+02

mg/kg/day |	5.9E+01

Exposure Point Total

Exp. Route Total

Cattail (above ground)
Cattail (root)

Ingestion
Ingestion

2.0E+01
2.6E+03
6.1E+01
4.4E+03

MG/KG
MG/KG
MG/KG
MG/KG

7.0E-02
9.0E+00
2.2E-01
1.5E+01

mg/kgMay
mg/kg/day
mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)
1/(mg/kg-day)
1/(mg/kg-day)

7.6E-02
9.9E+00
2.4E-01
1.7E+01

mgl kg/day
mat kg/day
mat kg/day
mat kg/day

1.0E-03
3.0E-01
1.0E-03
3.0E-01

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

7.6E+01
3.3E+01
2.4E+02
5.6E+01

| Exp. Route Total

Transition Zone Total

Exposure Medium Total

Fish Tissue/Aquatic Food

Exposure Point Total

Aquatic Food Tissue
(Mussels etc.)

Exposure Point Total

Fish Tissue
* high fish diet

Exposure Point Total

Fish Tissue
* high beef diet

Exposure Point Total

Exposure Medium Total (High Fish Diet)
Exposure Medium Total (High Beef Diet)

|| Exp. Route Total

1.6E+00
7.8E+01

1.7E-01
2.1E+01

1.7E-01
2.1E+01

MG/KG
MG/KG

MG/KG
MG/KG

MG/KG
MG/KG

3.7E-03
1.8E-01

2.0E-03
2.5E-01

1.7E-04
2.1E-02

mg/kgMay
mg/kg/day

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

1/(mg/kg-day)
1/(mg/kg-day)

1/(mg/kg-day)
1/(mg/kg-day)

4.0E-03
2.0E-01

2.2E-03
2.7E-01

1.8E-04
2.3E-02

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

1.0E-03
3.0E-01

1.0E-03
3.0E-01

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

4.0E+00
6.5E-01

2.2E+00
9.0E-01

1.8E-01
7.6E-02

Aquatic Biota (High Fish Diet)
Aquatic Biota (High Beef Diet)

Exposure Point Total

Exposure Medium Total

Groundwater Total	

Receptor Total (High Fish Diet)

REceptor Total (High Beef Diet)

Exp. Route Total

Revised 02/09/2006

008578

Page 2 of 3


-------
TABLE 7.4.R ME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Receptor Population: Residential (Subsistence)
Receptor Age: Adult	

Exposure Medium

Exposure Route

Chemical of
Potential Concern

Cancer Risk Calculations

Intake/Exposure Concentration

CSF/Unit Risk

Non-Cancer Hazard Calculations

Intake/Exposure Concentration

Revised 02/09/2006

008579

Page 3 of 3


-------
Table 7.4.RME Supplement A

Estimation of Chemical Concentrations in Small Game (Bird and Rabbit)
Tar Creek, Miami, OK

Small Mammal

Chemical

Soil Concentration
(mg/kg)1

Soil-Small Mammal
Accumulation Factor
(BAF)

Measure

Measure/Reference

Concentration in
Small Mammal
(mg/kg)

Cadmium

3.6E+01

7.0E+01

Insectivorous & generalist mammal

Sample et al. 1998b

2.49E+03

Lead

3.1E+03

2.7E+00

Insectivorous & generalist mammal

Sample et al. 1998b

8.23E+03

Zinc

5.3E+03

1.6E+01

Herbivorous & generalist mammal

Sample et al. 1998b

8.68E+04

Notes:

1 Soil Exposure Point Concentrations are based on 95% UCL of the mean (see Table 3.2).
mg/kg = Milligrams per kilogram.

Equation:

Concentration in Small Mammal = Soil Concentration x BAF
References:

Sample, B. E., J. J. Beauchamp, R. A. Efroymson and G. W. Suter. 1998b. Development and validation of bioaccumulation models for small mammals.
Oak Ridge, TN: Lockheed Martin Corp.

DRAFT - Discussion Purposes Only

008580

1 of 1

(A Supplements_lntake_Suppl draft final.xls (SmallGame)
10/31/2005 10:17AM


-------
Table 7.4.RME Supplement B

Estimation of Chemical Concentrations in Beef and Milk (dairy)
Tar Creek, Miami, OK

Beef and Milk



Soil Exposure















Point

BTF for

Concentration





Concentration in

Concentration in



Concentration

Forage

in Forage

BTF for Beef

BTF for Milk

Beef

Milk

Chemical

(Cs)1

(Brforaqe)

(Pr)

(Babeef)

(Bami|k)

(Abeef)

(Amilk)

Cadmium

3.6E+01

3.64E-01

1.3E+01

1.2E-04

6.5E-06

1.7E-02

9.0E-04

Lead

3.1E+03

4.50E-02

1.4E+02

3.0E-04

2.5E-04

8.5E-01

7.1E-01

Zinc

5.3E+03

2.50E-01

1.3E+03

9.0E-05

3.3E-05

1.3E+00

4.9E-01

Notes:

1 Soil Exposure Point Concentrations are based on 95% UCL of the mean (see Table 3.2).

Equations:

Abeef = [S (Fi x Qpi x Pr) + Qs x Cs x Bs ] x Babeef x MF
Amilk = [S (Fi x Qpi x Pr) + Qs x Cs x Bs ] x Bamilk x MF
Pr= Csx Br

where:

Abeef	Concentration in beef (mg/kg FW tissue)

Amiik	Concentration in milk (mg/kg milk)

Pr	Concentration in forage due to root uptake (mg/kg)

Fj	Fraction of forage grown on contaminated soil and ingested by the animal (cattle) (unitless)

Qpi	Quantity of forage eaten by the animal (cattle) per day (kg DW plant/day)

Pi	Concentration in each plant type I eaten by the animal (cattle) (mg/kg DW)

Qs	Quantity of soil eaten by the animal (cattle) each day (kg/day)

Cs	Average soil concentration over exposure duration (mg/kg)

Bs	Soil bioavailability factor (unitless)

Babeef	Biotransfer factor for beef (day/kg FW tissue)

Bami|k	Biotransfer factor for milk (day/kg WW tissue)

MF	Metabolism factor (unitless)

Borage	Plant-soil bioconcentration factor for forage (unitless)

Equations and input	parameters are obtained from EPA, 2005.

References:

EPA, 2005: Human Health Risk Assessment Protocol for Hazardous Waste Combustion Facilities.

Calculated

Calculated

1

9.27

Calculated

0.5

EPC (Table 3.2)
1

(see above)
(see above)
1

(see above)

DRAFT - Discussion Purposes Only

008581

1 of 1

7.4 Supplements_lntake_Suppl draft final.xls (Beef-Milk)

10/31/2005 10:17AM


-------
Table 7.4.RME Supplement C

Concentrations Used to Estimate Chemical Intake Through Ingestion of Locally Caught Fish
Tar Creek, Miami, OK

Fish (All sample preparations)1

Chemical

Data Set Used
for the
Analysis

Number of
Detection

Number of
Analysis

Minimum
Detected
Concentration
(mg/kg)

Maximum
Detected
Concentration
(mg/kg)

Mean
Concentration
(mg/kg)2

Cadmium

All

5

77

0.30

0.84

0.17

Lead

All

28

75

0.25

3.50

0.43

Zinc

All

77

77

3.50

70.0

21.3

Notes:

1	All Sample Preparations (Fillet, Whole-eviscerated, Whole-uneviscerated)

2	The Average Concentrations were used as exposure point concentrations,
mg/kg = Milligrams per kilogram.

Reference:

Fish Tissue Metals Analysis in the Tri-State Mining Area FY 2003 Final Report (Oklahoma DEQ, 2003).

008582


-------
Table 7.4.RME Supplement D

Estimation of Chemical Concentrations in Aquatic Food using Log-linear Regression Models for Bioaccumulation Factors
Tar Creek, Miami, OK

Aquatic Biota (Invertebrate)

Chemical

Data Set Used for
the Analysis

Sediment
Concentration
(mg/kg)1'2

B0

B1

Concentration in
Aquatic biota
(mg/kg)

Cadmium

All

4.0E+00

0.0395

0.692

2.72E+00

Lead

All

2.9E+01

-0.776

0.801

6.83E+00

Zinc

All

3.6E+02

1.80

0.208

2.06E+01

Notes:

1	Sediment Concentrations were obtained from ODEQ, 2003.

2	The Average Detected Concentrations were used.

All values are reported as dry weight.

mg/kg = Milligrams per kilogram.

Equation:

Log (Concentration in aquatic biota) = B1*(ln[Site Specific Sediment Concentration]) + BO
where:

BO = Slope.

B1 = Intercept.

References:

Bechtel Jacobs, 1998b. Biota Sediment Accumulation Factors for Invertebrates: Review and Recommendations for the Oak Ridge
Reservation. Prepared for the US Department of Energy Office of Environmental Management. BJC/OR-112. August, 1998.

Fish Tissue Metals Analysis in the Tri-State Mining Area FY 2003 Final Report (Oklahoma DEQ, 2003).

DRAFT - Discussion Purposes Only

008583

1 of 1

7.4 Supplements_lntake_Suppl draft final.xls (Aqualnvert.)

10/31/2005 10:20 AM


-------
TABLE 7.5.RME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Receptor Population: Residential (Subsistence)
Receptor Age: Child

Exposure Medium

Exposure Route

Chemical of
Potential Concern

Cancer Risk Calculations

Non-Cancer Hazard Calculations

e Concentration

CSF/Unit Risk

Intake/Exposure Concentration

Surface Soil (Yards)

Surface Soil
(0-1 inch)

Cadmium

9.6E+00
1.9E+03

MG/KG
MG/KG

2.2E-05
4.4E-03

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

2.6E-04
5.2E-02

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

mg/kg/day
mg/kg/day

Dermal	ICadmium

9.6E+00
1.9E+03

MG/KG
MG/KG

3.1E-08
6.2E-06

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

3.6E-07
7.2E-05

mg/kg/day
mg/kg/day

2.5E-05
3.0E-01

mg/kg/day
mg/kg/day

Surface Soil Total

Exposure Medium Total

Exposure Point Total

Exp. Route Total

Chat Pile material
and Tailings

Cadmium

8.1E-08
1.7E-05

MG/M
MG/M3

4.7E-09
1.0E-06

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

5.4E-08
1.2E-05

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

Exposure Medium Total

Chat Pile Material and Tailings Total

Exposure Point Total

Exp. Route Total

Surface Soil (residential,
smelter, transition zone)

Cadmium

6.90E-04
4.94E-01

UG/L
UG/L

2.0E-06
1.4E-03

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

2.3E-05
1.6E-02

mg/kg/day
mg/kg/day

5.0E-04
3.0E-01

mg/kg/day
mg/kg/day

Exposure Medium Total
Surface Soil (residential, smelter, transition zone) Total

|| Exp. Route Total

Exposure Point Total

Groundwater

Ingestion IZinc

Groundwater Total

Exposure Medium Total

Exposure Point Total

Exp. Route Total

Revised 02/09/2006

008584

Page 1 of


-------
TABLE 7.6.RME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

: ce na rio Ti m e fram e: C urrent/F uture
!eceptor Population: Recreator
;eceptorAge: Adolescent

Chemical of
Potential Concern

Cancer Risk Calculations

e Concentration

CSF/Unit Risk

n-Cancer Hazard Calculations

e Concentration

Chat and Tailings
Material

Surface Material

Chat & Tailings Ponds
Surface (0-6 inch)

9.3E+01
1.8E+04

MG/KG
MG/KG

1.6E-05
3.0E-03

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

1.0E-04
1.9E-02

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

Exp. Route Total

9.3E+01
1.8E+04

MG/KG
MG/KG

5.8E-08
1.1E-05

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

3.7E-07
7.1E-05

mg/kg/day
mg/kg/day

2.5E-05
3.0E-01

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

1.0E-01
6.4E-02

1.5E-02
2.4E-04

e Medium Total

:hat Pile Material and Tailings Total

008585


-------
TABLE 7.7.RME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Future

Receptor Population: Residential (General Public)

Receptor Age: Adult

Exposure Medium

Chemical of
Potential Concern

Cancer Risk Calculations

e Concentration

Non-Cancer Hazard Calculations

e Concentration

Surface Soil (Yards)

Surface Soil
(0-1 inch)

admium

Exp. Route Total

Exp. Route Total

Exposure Point Total

4.6E+00
8.5E+02

MG/KG
MG/KG

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

6.3E-06
1.2E-03

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

4.6E+00
8.5E+02

MG/KG
MG/KG

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

2.5E-08
4.6E-06

mg/kg/day
mg/kg/day

2.5E-05
3.0E-01

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

6.3E-03
3.9E-03

1.0E-03
1.5E-05

Exposure Medium Total

Surface Soil Total

Chat Pile Material
and Tailings

Inhalation ICadmium

Exp. Route Total

Exposure Point Total

4.3E-06
9.5E-04

MG/M
MG/M4

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

1.2E-06
2.6E-04

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

Exposure Medium Total

;hat Pile Material and Tailings Total

Revised 02/09/2006

008586

Page 1 of


-------
TABLE 7.8.RME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Future
R ece pto r Popul ati on: Residential (GeneralPublic)
Receptor Age: Child

Exposure Medium

Exposure Route

Chemical of
Potential Concern

Cancer Risk Calculations

Intake/Exposure Concentration

CSF/Unit Risk

Non-Cancer Hazard Calculations

e Concentration

Surface Soil (Yards)

Surface Soil
(0-1 inch)

Cadmium

Dermal ICadmium

Exp. Route Total

Exposure Point Total

4.6E+00
8.5E+02

MG/KG
MG/KG

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

5.9E-05
1.1E-02

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

mg/kg/day
mg/kg/day

5.9E-02
3.6E-02

4.6E+00
8.5E+02

MG/KG
MG/KG

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

1.7E-07
3.0E-05

mg/kg/day
mg/kg/day

2.5E-05
3.0E-01

mg/kg/day I 6.6E-03
mg/kg/day I 1.0E-04

Exposure Medium Total

Surface Soil Total

Chat Pile Material
and Tailings

Inhalation ICadmium

Exp. Route Total ||

Exposure Point Total

4.3E-06
9.5E-04

MG/M
MG/M4

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

2.7E-06
6.1E-04

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

Exposure Medium Total

;hat Pile Material and Tailings Total

Revised 02/09/2006

008587

Page 1 of


-------
TABLE 7.9.RME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Timeframe: Future
Receptor Population: Residential (General Public)
Receptor Age: Adult/Child

Exposure Medium

Exposure Route

Chemical of
Potential Concern

Cancer Risk Calculations

Intake/Exposure Concentration

CSF/Unit Risk

Non-Cancer Hazard Calculations

Intake/Exposure Concentration

Surface Soil (Yards)

Surface Soil
(0-1 inch)

Cadmium

4.6E+00
8.5E+02

MG/KG
MG/KG

7.2E-06
1.3E-03

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

Dermal ICadmium

4.6E+00
8.5E+02

MG/KG
MG/KG

5.5E-07
1.0E-04

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

Surface Soil Total

Exp. Route Total

Exposure Point Total

Exposure Medium Total

Chat Pile Material
and Tailings

Inhalation ICadmium

4.3E-06
9.5E-04

MG/M
MG/M4

6.4E-07
1.4E-04

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

Exp. Route Total ||

Exposure Point Total

Exposure Medium Total

Chat Pile Material and Tailings Total

Revised 02/09/2006

008588

Page 1 of


-------
TABLE 7.10.RME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Future

Receptor Population: Residential (Subsistence)

Receptor Age: Adult

Exposure Medium

Chemical of
Potential Concern

Cancer Risk Calculations

e Concentration

Non-Cancer Hazard Calculations

e Concentration

Surface Soil (Yards)

Surface Soil
(0-1 inch)

admium

Exp. Route Total

Exp. Route Total

Exposure Point Total

4.6E+00
8.5E+02

MG/KG
MG/KG

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

2.5E-05
4.6E-03

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

4.6E+00
8.5E+02

MG/KG
MG/KG

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

2.5E-08
4.6E-06

mg/kg/day
mg/kg/day

2.5E-05
3.0E-01

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

2.5E-02
1.5E-02

1.0E-03
1.5E-05

Exposure Medium Total

Surface Soil Total

Chat Pile Material
and Tailings

Inhalation ICadmium

Exp. Route Total

Exposure Point Total

4.3E-06
9.5E-04

MG/M
MG/M4

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

1.8E-06
3.9E-04

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

Exposure Medium Total

;hat Pile Material and Tailings Total

Revised 02/09/2006

008589

Page 1 of


-------
TABLE 7.11.RME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Future

Receptor Population: Residential (Subsistence)

Receptor Age: Child

Exposure Medium

Exposure Route

Chemical of
Potential Concern

Cancer Risk Calculations

Intake/Exposure Concentration

CSF/Unit Risk

Non-Cancer Hazard Calculations

e Concentration

Surface Soil (Yards)

Surface Soil
(0-1 inch)

Dermal I Cadmium

Exp. Route Total

Exposure Point Total

4.6E+00
8.5E+02

MG/KG
MG/KG

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

1.2E-04
2.2E-02

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

mg/kg/day
mg/kg/day

1.2E-01
7.2E-02

4.6E+00
8.5E+02

MG/KG
MG/KG

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

1.7E-07
3.0E-05

mg/kg/day
mg/kg/day

2.5E-05
3.0E-01

mg/kg/day I 6.6E-03
mg/kg/day I 1.0E-04

Exposure Medium Total

Surface Soil Total

Chat Pile Material
and Tailings

Inhalation ICadmium

Exp. Route Total ||

Exposure Point Total

4.3E-06
9.5E-04

MG/M
MG/M4

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

2.7E-06
6.1E-04

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

Exposure Medium Total

;hat Pile Material and Tailings Total

Revised 02/09/2006

008590

Page 1 of


-------
TABLE 7.12.RME

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Timeframe: Future
Receptor Population: Residential (Subsistence)
Receptor Age: Adult/Child

Exposure Route

Chemical of
Potential Concern

Cancer Risk Calculations

Intake/Exposure Concentration

CSF/Unit Risk

Non-Cancer Hazard Calculations

Intake/Exposure Concentration

Surface Soil (Yards)

Surface Soil
(0-1 inch)

Cadmium

4.6E+00
8.5E+02

MG/KG
MG/KG

3.3E-05
6.1E-03

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

Dermal ICadmium

4.6E+00
8.5E+02

MG/KG
MG/KG

8.9E-07
1.6E-04

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

Surface Soil Total

Exp. Route Total

Exposure Point Total

Exposure Medium Total

Chat Pile Material
and Tailings

Inhalation ICadmium

4.3E-06
9.5E-04

MG/M
MG/M4

1.9E-06
4.1E-04

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

mg/kg/day
mg/kg/day

mg/kg/day
mg/kg/day

Exp. Route Total ||

Exposure Point Total

Exposure Medium Total

Chat Pile Material and Tailings Total

Revised 02/09/2006

008591

Page 1 of


-------
TABLE 9.1. RME

SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current

Receptor Population: Residential (General Public)

Receptor Age: Adult	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ(s)







Routes Total

Surface Soil

Surface Soil (Yards)

Surface Soil

Cadmium

NA

NA

NA

NA

Kidney

6.5E-02

NA

1.0E-02

7.5E-02





(0-1 inch)

Zinc

NA

NA

NA

NA

Circulatory

3.5E-02

NA

1.4E-04

3.5E-02





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



1.0E-01

NA

1.1E-02

1.1E-01



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



1.0E-01

NA

1.1E-02

1.1E-01

Surface Soil Total

0.0E+00

NA

0.0E+00

0.0E+00



1.0E-01

NA

1.1E-02

1.1E-01

Chat

Ambient Air

Ambient Air

Cadmium

NA

NA

NA

NA

Kidney

NA

3.9E-04

NA

3.9E-04

and Tailings





Zinc

NA

NA

NA

NA

N/A

NA

NA

NA

NA

Material





























Chemical Total

NA

0.0E+00

NA

0.0E+00



NA

3.9E-04

NA

3.9E-04



Exposure Medium Total

NA

0.0E+00

NA

0.0E+00



NA

3.9E-04

NA

3.9E-04

Chat and Tailings Total

NA

0.0E+00

NA

0.0E+00



NA

3.9E-04

NA

3.9E-04

Groundwater

Groundwater

Private Wells

Cadmium

NA

NA

NA

NA

Kidney

1.6E-01

NA

NA

1.6E-01







Zinc

NA

NA

NA

NA

Circulatory

1.0E-01

NA

NA

1.0E-01





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



2.7E-01

NA

0.0E+00

2.7E-01



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



2.7E-01

NA

0.0E+00

2.7E-01

Groundwater Total

0.0E+00

NA

0.0E+00

0.0E+00



2.7E-01

NA

0.0E+00

2.7E-01

Receptor T otal

0.0E+00

0.0E+00

0.0E+00

0.0E+00



3.7E-01

3.9E-04

1.1E-02

3.8E-01

Page 1 of 1

008592

Total Circulatory HI Across Media
Total Kidney HI Across Media =


-------
TABLE 9.2.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current

Receptor Population: Residential (General Public)

Receptor Age: Child	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ(s)







Routes Total

Surfiace Soil

Surfiace Soil (Yards)

Surfiace Soil

Cadmium

NA

NA

NA

NA

Kidney

6.1 E-01

NA

6.8E-02

6.8 E-01





(0-1 inch)

Zinc

NA

NA

NA

NA

Circulatory

3.3E-01

NA

9.2 E-04

3.3 E-01





Exposure Point Total

0.0E+00

NA

O.OE-tOO

0.0E+00



9.4 E-01

NA

6.9E-02

1.0E+00



Exposure Medium Total

0.0E+00

NA

O.OE-tOO

0.0E+00



9.4 E-01

NA

6.9E-02

1.0E+00

Surface Soil Total

0.0E+00

NA

O.OE-tOO

0.0E+00



9.4 E-01

NA

6.9E-02

1.0E+00

Chat

Ambient Air

Ambient Air

Cadmium

NA

NA

NA

NA

Kidney

NA

9.1 E-04

NA

9.1 E-04

and Tailings





Zinc

NA

NA

NA

NA

N/A

NA

NA

NA

NA

Material





























Chemical Total

NA

0.0E+00

NA

O.OE-tOO



NA

9.1 E-04

NA

9.1 E-04



Exposure Medium Total

NA

0.0E+00

NA

O.OE-tOO



NA

9.1 E-04

NA

9.1 E-04

Chat and Tailings Total

NA

0.0E+00

NA

O.OE-tOO



NA

9.1 E-04

NA

9.1 E-04

Groundwater

Groundwater

Private Wells

Cadmium

NA

NA

NA

NA

Kidney

3.8 E-01

NA

NA

3.8 E-01







Zinc

NA

NA

NA

NA

Circulatory

2.4 E-01

NA

NA

2.4 E-01





Exposure Point Total

0.0E+00

NA

O.OE-tOO

O.OE-tOO



6.2 E-01

NA

O.OE-tOO

6.2 E-01



Exposure Medium Total

0.0E+00

NA

O.OE-tOO

O.OE-tOO



6.2 E-01

NA

O.OE-tOO

6.2 E-01

Groundwater Total

0.0E+00

NA

O.OE-tOO

O.OE-tOO



6.2 E-01

NA

O.OE-tOO

6.2 E-01

Receptor Total

0.0E+00

0.0E+00

O.OE-tOO

O.OE-tOO



1.6E-tOO

9.1 E-04

6.9E-02

1.6E+00

Total Circulatory HI Across Media
Total Kidney HI Across Media

6E-01
1E-fOO

008593

Page


-------
TABLE 9.3.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current

Receptor Population: Residential (General Public)

Receptor Age: Adult/Child	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ(s)







Routes Total

Surface Soil

Surface Soil (Yards)

Surface Soil

Cadmium

NA

NA

NA

NA

NA

NA

NA

NA

NA





(0-1 inch)

Zinc

NA

NA

NA

NA

NA

NA

NA

NA

NA





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



NA

NA

0.0E+00

0.0E+00



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



NA

NA

0.0E+00

0.0E+00

Surface Soil Total

0.0E+00

NA

0.0E+00

0.0E+00



NA

NA

0.0E+00

0.0E+00

Chat

Ambient Air

Ambient Air

Cadmium

NA

7.6E-08

NA

7.6E-08

NA

NA

NA

NA

NA

and Tailings





Zinc

NA

NA

NA

NA

NA

NA

NA

NA

NA

Material





























Chemical Total

NA

7.6E-08

NA

7.6E-08



NA

0.0E+00

NA

0.0E+00



Exposure Medium Total

NA

7.6E-08

NA

7.6E-08



NA

0.0E+00

NA

0.0E+00

Chat and Tailings Total

NA

7.6E-08

NA

7.6E-08



NA

0.0E+00

NA

0.0E+00

Groundwater

Groundwater

Private Wells

Cadmium

NA

NA

NA

NA

NA

NA

NA

NA

NA







Zinc

NA

NA

NA

NA

NA

NA

NA

NA

NA





Exposure Point Total

NA

NA

0.0E+00

0.0E+00



NA

NA

0.0E+00

0.0E+00



Exposure Medium Total

NA

NA

0.0E+00

0.0E+00



NA

NA

0.0E+00

0.0E+00

Groundwater Total

NA

NA

0.0E+00

0.0E+00



NA

NA

0.0E+00

0.0E+00

Receptor Total

0.0E+00

7.6E-08

0.0E+00

7.6E-08



0.0E+00

0.0E+00

0.0E+00

0.0E+00

008594

Page 1 of1


-------
TABLE 9.4.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Receptor Population: Residential (Subsistence)
Receptor Age: Adult	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ (s)







Routes Total

Surface Soil

Surface Soil (Yards)

Surface Soil

Cadmium

NA

NA

NA

NA

Kidney

5.5E-02

NA

2.2E-03

5.7E-02





(0-1 inch)

Zinc

NA

NA

NA

NA

Circulatory

3.7E-02

NA

3.7E-05

3.7E-02





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



9.2E-02

NA

2.2E-03

9.4E-02



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



9.2E-02

NA

2.2E-03

9.4E-02

Surface Soil Total

0.0E+00

NA

0.0E+00

0.0E+00



9.2E-02

NA

2.2E-03

9.4E-02

Chat Pile material

Ambient Air

Ambient Air

Cadmium

NA

2.3E-07

NA

2.3E-07

Kidney

NA

6.1 E-04

NA

6.1 E-04

and Tailings





Zinc

NA

NA

NA

NA

N/A

NA

NA

NA

NA





Chemical Total

NA

2.3E-07

NA

2.3E-07



NA

6.1 E-04

NA

6.1 E-04



Exposure Medium Total

NA

2.3E-07

NA

2.3E-07



NA

6.1 E-04

NA

6.1 E-04

Chat Pile Material and Tailings Total

NA

2.3E-07

NA

2.3E-07



NA

6.1 E-04

NA

6.1 E-04

Surface Soil (residential,

Animal Tissue

Small Game

Cadmium

NA

NA

NA

NA

Kidney

4.4E-04

NA

NA

4.4E-04

smelter, transition zone)



(Bird, Rabbit)

Zinc

NA

NA

NA

NA

Circulatory

6.7E-05

NA

NA

6.7E-05





Chemical Total

0.0E+00

NA

NA

0.0E+00



5.0E-04

NA

NA

5.0 E-04





Beef (Cattle)

Cadmium

NA

NA

NA

NA

Kidney

1.8E-08

NA

NA

1.8E-08





* high fish diet

Zinc

NA

NA

NA

NA

Circulatory

6.5E-09

NA

NA

6.5E-09





Chemical Total

0.0E+00

NA

NA

0.0E+00



2.5E-08

NA

NA

2.5E-08





Beef (Cattle)

Cadmium

NA

NA

NA

NA

Kidney

1.6E-07

NA

NA

1.6E-07





* high Beef diet

Zinc

NA

NA

NA

NA

Circulatory

5.8E-08

NA

NA

5.8E-08





Chemical Total

0.0E+00

NA

NA

0.0E+00



2.2E-07

NA

NA

2.2E-07



Exposure Medium Total (High Fish Diet)

0.0E+00

NA

NA

0.0E+00



5.0E-04

NA

NA

5.0 E-04



Exposure Medium Total (High Beef Diet)

0.0E+00

NA

NA

0.0E+00



5.0E-04

NA

NA

5.0 E-04

Surface Soil (residential, smelter, transition zone) Total (High Fish Diet)

0.0E+00

NA

NA

0.0E+00



5.0E-04

NA

NA

5.0 E-04

Surface Soil (residential, smelter, transition zone) Total (High Beef Diet)

0.0E+00

NA

NA

0.0E+00



5.0E-04

NA

NA

5.0 E-04

Revised 02/09/2006	Page 1 of 3

008595


-------
TABLE 9.4.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Receptor Population: Residential (Subsistence)
Receptor Age: Adult	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ (s)







Routes Total



Plant Tissue

Asparagus (above ground)

Cadmium

NA

NA

NA

NA

Kidney

2.1E+01

NA

NA

2.1E+01

Transition Zone





Zinc

NA

NA

NA

NA

Circulatory

1.8E+00

NA

NA

1.8E+00





Asparagus (root)

Cadmium

NA

NA

NA

NA

Kidney

4.8E+01

NA

NA

4.8E+01







Zinc

NA

NA

NA

NA

Circulatory

1.8E+01

NA

NA

1.8E+01





Chemical Total

0.0E+00

NA

NA

0.0E+00



8.9E+01

NA

NA

8.9E+01





Willow (above ground)

Cadmium

NA

NA

NA

NA

Kidney

6.9E+01

NA

NA

6.9E+01







Zinc

NA

NA

NA

NA

Circulatory

6.0E+00

NA

NA

6.0E+00





Willow (root)

Cadmium

NA

NA

NA

NA

Kidney

1.9E+02

NA

NA

1.9E+02







Zinc

NA

NA

NA

NA

Circulatory

5.9E+01

NA

NA

5.9E+01





Chemical Total

0.0E+00

NA

NA

0.0E+00



3.3E+02

NA

NA

3.3E+02





Cattail (above ground)

Cadmium

NA

NA

NA

NA

Kidney

7.6E+01

NA

NA

7.6E+01







Zinc

NA

NA

NA

NA

Circulatory

3.3E+01

NA

NA

3.3E+01





Cattail (root)

Cadmium

NA

NA

NA

NA

Kidney

2.4E+02

NA

NA

2.4E+02







Zinc

NA

NA

NA

NA

Circulatory

5.6E+01

NA

NA

5.6E+01





Chemical Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



4.0E+02

NA

NA

4.0E+02



Exposure Medium Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



8.2E+02

NA

NA

8.2E+02

Transition Zone Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



8.2E+02

NA

NA

8.2E+02

Aquatic Biota

Fish Tissue/

Aquatic Food Tissue

Cadmium

NA

NA

NA

NA

Kidney

4.0E+00

NA

NA

4.0E+00



Aquatic Food

(Mussels etc.)

Zinc

NA

NA

NA

NA

Circulatory

6.5E-01

NA

NA

6.5E-01





Chemical Total

0.0E+00

NA

NA

0.0E+00



4.7E+00

NA

NA

4.7E+00





Fish Tissue

Cadmium

NA

NA

NA

NA

Kidney

2.2E+00

NA

NA

2.2E+00





* high fish diet

Zinc

NA

NA

NA

NA

Circulatory

9.0E-01

NA

NA

9.0E-01





Chemical Total

0.0E+00

NA

NA

0.0E+00



3.0E+00

NA

NA

3.0E+00





Fish Tissue

Cadmium

NA

NA

NA

NA

Kidney

1.8E-01

NA

NA

1.8E-01





* high Beef diet

Zinc

NA

NA

NA

NA

Circulatory

7.6E-02

NA

NA

7.6E-02





Chemical Total

0.0E+00

NA

NA

0.0E+00



2.6E-01

NA

NA

2.6E-01



Exposure Medium Total (High Fish Diet)

0.0E+00

NA

NA

0.0E+00



7.7E+00

NA

NA

7.7E+00



Exposure Medium Total (High Beef Diet)

0.0E+00

NA

NA

0.0E+00



5.0E+00

NA

NA

5.0E+00

Revised 02/09/2006	Page 2 of 3

008596


-------
TABLE 9.4.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Receptor Population: Residential (Subsistence)
Receptor Age: Adult	

Medium

Exposure
Medium

Exposure
Point

Chemical
of Potential

Carcinogenic Risk

Non-Carcinogenic Hazard Quotient







Concern

Ingestion

Inhalation

Dermal

Exposure
Routes Total

Primary
Target Organ (s)

Ingestion

Inhalation

Dermal

Exposure
Routes Total

Aquatic Biota (High Fish Diet)







0.0E+00

NA

NA

0.0E+00



7.7E+00

NA

NA

7.7E+00

Aquatic Biota (High Beef Diet)

0.0E+00

NA

NA

0.0E+00



5.0E+00

NA

NA

5.0E+00

Groundwater

Groundwater

Groundwater

Zinc

NA

NA

NA

NA

Circulatory

4.2E-05

NA

NA

4.2E-05





Exposure Point Total

0.0E+00

NA

NA

0.0E+00



4.2E-05

NA

NA

4.2E-05



Exposure Medium Total

0.0E+00

NA

NA

0.0E+00



4.2E-05

NA

NA

4.2E-05

Medium Total

0.0E+00

NA

NA

0.0E+00



4.2E-05

NA

NA

4.2E-05

Receptor Total (High Fish Diet)

0.0E+00

2.3E-07

0.0E+00

2.3E-07



8.2E+02

6.1 E-04

2.2E-03

8.2E+02

Receptor Total (High Beef Diet)

0.0E+00

2.3E-07

0.0E+00

2.3E-07



8.2E+02

6.1 E-04

2.2E-03

8.2E+02

Total Circulatory HI Across Media (High Fish Diet) =
Total Kidney HI Across Media (High Fish Diet) =

Total Circulatory HI Across Media (High Beef Diet) =
Total Kidney HI Across Media (High Beef Diet) =

6E+Q2

2E+Q2

Revised 02/09/2006

008597

Page 3 of 3


-------
TABLE 9.5.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future

Receptor Population: Residential (Subsistence)

Receptor Age: Child	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ(s)







Routes Total

Surface Soil

Surface Soil (Yards)

Surface Soil

Cadmium

NA

NA

NA

NA

Kidney

2.6E-01

NA

1.4E-02

2.7E-01





(0-1 inch)

Zinc

NA

NA

NA

NA

Circulatory

1.7E-01

NA

2.4E-04

1.7E-01





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



4.3E-01

NA

1.5E-02

4.4E-01



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



4.3E-01

NA

1.5E-02

4.4E-01

Surface Soil Total

0.0E+00

NA

0.0E+00

0.0E+00



4.3E-01

NA

1.5E-02

4.4E-01

Chat Pile material

Ambient Air

Ambient Air

Cadmium

NA

2.9E-08

NA

2.9E-08

Kidney

NA

9.5E-04

NA

9.5E-04

and Tailings





Zinc

NA

NA

NA

NA

N/A

NA

NA

NA

NA





Chemical Total

NA

2.9E-08

NA

2.9E-08



NA

9.5E-04

NA

9.5E-04



Exposure Medium Total

NA

2.9E-08

NA

2.9E-08



NA

9.5E-04

NA

9.5E-04

Chat Pile Material and Tailings Total

NA

2.9E-08

NA

2.9E-08



NA

9.5E-04

NA

9.5E-04

Surface Soil (residential,

Milk (Dairy)

Milk (Dairy)

Cadmium

NA

NA

NA

NA

Kidney

4.6E-02

NA

NA

4.6E-02

smelter, transition zone)





Zinc

NA

NA

NA

NA

Circulatory

5.5E-02

NA

NA

5.5E-02





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



1.0E-01

NA

0.0E+00

1.0E-01



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



1.0E-01

NA

0.0E+00

1.0E-01

Surface Soil (residential, smelter, transition zone) Total

0.0E+00

NA

0.0E+00

0.0E+00



1.0E-01

NA

0.0E+00

1.0E-01

Groundwater

Groundwater

Private Wells

Zinc

NA

NA

NA

NA

Circulatory

4.9E-05

NA

NA

4.9E-05





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



4.9E-05

NA

0.0E+00

4.9E-05



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



4.9E-05

NA

0.0E+00

4.9E-05

Groundwater Total

0.0E+00

NA

0.0E+00

0.0E+00



4.9E-05

NA

0.0E+00

4.9E-05

Receptor Total

0.0E+00

2.9E-08

0.0E+00

2.9E-08



5.3E-01

9.5E-04

1.5E-02

5.4E-01

Revised 02/09/2006

Total Circulatory HI Across Media =
Total Kidney HI Across Media =

Page 1 of 1

008598


-------
TABLE 9.6.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Receptor Population: Recreator
Receptor Age: Adolescent	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

T arget Organ(s)







Routes Total

Chat and Tailings

Surface Material

Chat & Tailings Ponds

Cadmium

NA

NA

NA

NA

Kidney

1.0E-01

NA

1.5E-02

1.2E-01

Material



Surface (0-6 inch)

Zinc

NA

NA

NA

NA

Circulatory

6.4E-02

NA

2.4E-04

6.4E-02





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



1.6E-01

NA

1.5E-02

1.8E-01



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



1.6E-01

NA

1.5E-02

1.8E-01

Chat Pile Material and Tailings Total

0.0E+00

NA

0.0E+00

0.0E+00



1.6E-01

NA

1.5E-02

1.8E-01

Receptor Total

0.0E+00

NA

0.0E+00

0.0E+00



1.6E-01

NA

1.5E-02

1.8E-01

Page 1 of 1

008599

Total Circulatory HI Across Media =
Total Kidney HI Across Media =


-------
TABLE 9.7.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Future

Receptor Population: Residential (General Public)

Receptor Age: Adult	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ (s)







Routes Total

Surface Soil

Surface Soil (Yards)

Surface Soil

Cadmium

NA

NA

NA

NA

Kidney

6.3E-03

NA

1.0E-03

7.3E-03





(0-1 inch)

Zinc

NA

NA

NA

NA

Circulatory

3.9E-03

NA

1.5E-05

3.9E-03





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



1.0E-02

NA

1.0E-03

1.1 E-02



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



1.0E-02

NA

1.0E-03

1.1 E-02

Surface Soil Total

0.0E+00

NA

0.0E+00

0.0E+00



1.0E-02

NA

1.0E-03

1.1 E-02

Chat Pile Material

Ambient Air

Ambient Air

Cadmium

NA

NA

NA

NA

Kidney

NA

2.1 E-02

NA

2.1 E-02

and Tailings





Zinc

NA

NA

NA

NA

N/A

NA

NA

NA

NA





Chemical Total

NA

0.0E+00

NA

0.0E+00



NA

2.1 E-02

NA

2.1 E-02



Exposure Medium Total

NA

0.0E+00

NA

0.0E+00



NA

2.1 E-02

NA

2.1 E-02

Chat Pile Material and Tailings Total

NA

0.0E+00

NA

0.0E+00



NA

2.1 E-02

NA

2.1 E-02

Receptor Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



1.0E-02

2.1 E-02

1.0E-03

3.2E-02

Total Circulatory HI Across Media =
Total Kidney HI Across Media =

4E-03
3E-02

Revised 02/09/2006

008600

Page 1 of 1


-------
TABLE 9.8.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Future

Receptor Population: Residential (General Public)

Receptor Age: Child	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ (s)







Routes Total

Surface Soil

Surface Soil (Yards)

Surface Soil

Cadmium

NA

NA

NA

NA

Kidney

5.9E-02

NA

6.6E-03

6.6E-02





(0-1 inch)

Zinc

NA

NA

NA

NA

Circulatory

3.6E-02

NA

1.0E-04

3.6E-02





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



9.5E-02

NA

6.7E-03

1.0E-01



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



9.5E-02

NA

6.7E-03

1.0E-01

Surface Soil Total

0.0E+00

NA

0.0E+00

0.0E+00



9.5E-02

NA

6.7E-03

1.0E-01

Chat Pile Material

Ambient Air

Ambient Air

Cadmium

NA

NA

NA

NA

Kidney

NA

4.8E-02

NA

4.8E-02

and Tailings





Zinc

NA

NA

NA

NA

N/A

NA

NA

NA

NA





Chemical Total

NA

0.0E+00

NA

0.0E+00



NA

4.8E-02

NA

4.8E-02



Exposure Medium Total

NA

0.0E+00

NA

0.0E+00



NA

4.8E-02

NA

4.8E-02

Chat Pile Material and Tailings Total

NA

0.0E+00

NA

0.0E+00



NA

4.8E-02

NA

4.8E-02

Receptor Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



9.5E-02

4.8E-02

6.7E-03

1.5E-01

Total Circulatory HI Across Media =
Total Kidney HI Across Media =

4E-02
1E-01

Revised 02/09/2006

008601

Page 1 of 1


-------
TABLE 9.9.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Future

Receptor Population: Residential (General Public)

Receptor Age: Adult/Child	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ (s)







Routes Total

Surface Soil

Surface Soil (Yards)

Surface Soil

Cadmium

NA

NA

NA

NA

NA

NA

NA

NA

NA





(0-1 inch)

Zinc

NA

NA

NA

NA

NA

NA

NA

NA

NA





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



NA

NA

0.0E+00

0.0E+00



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



NA

NA

0.0E+00

0.0E+00

Surface Soil Total

0.0E+00

NA

0.0E+00

0.0E+00



NA

NA

0.0E+00

0.0E+00

Chat Pile Material

Ambient Air

Ambient Air

Cadmium

NA

4.0E-06

NA

4.0E-06

NA

NA

NA

NA

NA

and Tailings





Zinc

NA

NA

NA

NA

NA

NA

NA

NA

NA





Chemical Total

NA

4.0E-06

NA

4.0E-06



NA

0.0E+00

NA

0.0E+00



Exposure Medium Total

NA

4.0E-06

NA

4.0E-06



NA

0.0E+00

NA

0.0E+00

Chat Pile Material and Tailings Total

NA

4.0E-06

NA

4.0E-06



NA

0.0E+00

NA

0.0E+00

Receptor Total

0.0E+00

4.0E-06

0.0E+00

4.0E-06



0.0E+00

0.0E+00

0.0E+00

0.0E+00

Revised 02/09/2006

008602

Page 1 of 1


-------
TABLE 9.10.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Future

Receptor Population: Residential (Subsistence)

Receptor Age: Adult	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ (s)







Routes Total

Surface Soil

Surface Soil (Yards)

Surface Soil

Cadmium

NA

NA

NA

NA

Kidney

2.5E-02

NA

1.0E-03

2.6E-02





(0-1 inch)

Zinc

NA

NA

NA

NA

Circulatory

1.5E-02

NA

1.5E-05

1.5E-02





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



4.1 E-02

NA

1.0E-03

4.2E-02



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



4.1 E-02

NA

1.0E-03

4.2E-02

Surface Soil Total

0.0E+00

NA

0.0E+00

0.0E+00



4.1 E-02

NA

1.0E-03

4.2E-02

Chat Pile Material

Ambient Air

Ambient Air

Cadmium

NA

NA

NA

NA

Kidney

NA

3.1 E-02

NA

3.1 E-02

and Tailings





Zinc

NA

NA

NA

NA

N/A

NA

NA

NA

NA





Chemical Total

NA

0.0E+00

NA

0.0E+00



NA

3.1 E-02

NA

3.1 E-02



Exposure Medium Total

NA

0.0E+00

NA

0.0E+00



NA

3.1 E-02

NA

3.1 E-02

Chat Pile Material and Tailings Total

NA

0.0E+00

NA

0.0E+00



NA

3.1 E-02

NA

3.1 E-02

Receptor Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



4.1 E-02

3.1 E-02

1.0E-03

7.3E-02

Total Circulatory HI Across Media =
Total Kidney HI Across Media =

2E-02
6E-02

Revised 02/09/2006

008603

Page 1 of 1


-------
TABLE 9.11.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Future

Receptor Population: Residential (Subsistence)

Receptor Age: Child	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ (s)







Routes Total

Surface Soil

Surface Soil (Yards)

Surface Soil

Cadmium

NA

NA

NA

NA

Kidney

1.2E-01

NA

6.6E-03

1.2E-01





(0-1 inch)

Zinc

NA

NA

NA

NA

Circulatory

7.2E-02

NA

1.0E-04

7.2E-02





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



1.9E-01

NA

6.7E-03

2.0E-01



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



1.9E-01

NA

6.7E-03

2.0E-01

Surface Soil Total

0.0E+00

NA

0.0E+00

0.0E+00



1.9E-01

NA

6.7E-03

2.0E-01

Chat Pile Material

Ambient Air

Ambient Air

Cadmium

NA

NA

NA

NA

Kidney

NA

4.8E-02

NA

4.8E-02

and Tailings





Zinc

NA

NA

NA

NA

N/A

NA

NA

NA

NA





Chemical Total

NA

0.0E+00

NA

0.0E+00



NA

4.8E-02

NA

4.8E-02



Exposure Medium Total

NA

0.0E+00

NA

0.0E+00



NA

4.8E-02

NA

4.8E-02

Chat Pile Material and Tailings Total

NA

0.0E+00

NA

0.0E+00



NA

4.8E-02

NA

4.8E-02

Receptor Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



1.9E-01

4.8E-02

6.7E-03

2.4E-01

Total Circulatory HI Across Media =
Total Kidney HI Across Media =

7E-02
2E-01

Revised 02/09/2006

008604

Page 1 of 1


-------
TABLE 9.12.RME
SUMMARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Future

Receptor Population: Residential (Subsistence)

Receptor Age: Adult/Child	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ (s)







Routes Total

Surface Soil

Surface Soil (Yards)

Surface Soil

Cadmium

NA

NA

NA

NA

NA

NA

NA

NA

NA





(0-1 inch)

Zinc

NA

NA

NA

NA

NA

NA

NA

NA

NA





Exposure Point Total

0.0E+00

NA

0.0E+00

0.0E+00



NA

NA

0.0E+00

0.0E+00



Exposure Medium Total

0.0E+00

NA

0.0E+00

0.0E+00



NA

NA

0.0E+00

0.0E+00

Surface Soil Total

0.0E+00

NA

0.0E+00

0.0E+00



NA

NA

0.0E+00

0.0E+00

Chat Pile Material

Ambient Air

Ambient Air

Cadmium

NA

1.2E-05

NA

1.2E-05

NA

NA

NA

NA

NA

and Tailings





Zinc

NA

NA

NA

NA

NA

NA

NA

NA

NA





Chemical Total

NA

1.2E-05

NA

1.2E-05



NA

0.0E+00

NA

0.0E+00



Exposure Medium Total

NA

1.2E-05

NA

1.2E-05



NA

0.0E+00

NA

0.0E+00

Chat Pile Material and Tailings Total

NA

1.2E-05

NA

1.2E-05



NA

0.0E+00

NA

0.0E+00

Receptor Total

0.0E+00

1.2E-05

0.0E+00

1.2E-05



0.0E+00

0.0E+00

0.0E+00

0.0E+00

Revised 02/09/2006

008605

Page 1 of 1


-------
TABLE 10.1. RME
RISK SUMMARY
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Future

Receptor Population: Residential (Subsistence)

Receptor Age: Adult	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ (s)







Routes Total



Plant Tissue

Asparagus (above ground)

Cadmium

NA

NA

NA

NA

Kidney

2.1E+01

NA

NA

2.1E+01

Transition Zones





Zinc

NA

NA

NA

NA

Circulatory

1.8E+00

NA

NA

1.8E+00





Asparagus (root)

Cadmium

NA

NA

NA

NA

Kidney

4.8E+01

NA

NA

4.8E+01







Zinc

NA

NA

NA

NA

Circulatory

1.8E+01

NA

NA

1.8E+01





Chemical Total

0.0E+00

NA

NA

0.0E+00



8.9E+01

NA

NA

8.9E+01





Willow (above ground)

Cadmium

NA

NA

NA

NA

Kidney

6.9E+01

NA

NA

6.9E+01







Zinc

NA

NA

NA

NA

Circulatory

6.0E+00

NA

NA

6.0E+00





Willow (root)

Cadmium

NA

NA

NA

NA

Kidney

1.9E+02

NA

NA

1.9E+02







Zinc

NA

NA

NA

NA

Circulatory

5.9E+01

NA

NA

5.9E+01





Chemical Total

0.0E+00

NA

NA

0.0E+00



3.3E+02

NA

NA

3.3E+02





Cattail (above ground)

Cadmium

NA

NA

NA

NA

Kidney

7.6E+01

NA

NA

7.6E+01







Zinc

NA

NA

NA

NA

Circulatory

3.3E+01

NA

NA

3.3E+01





Cattail (root)

Cadmium

NA

NA

NA

NA

Kidney

2.4E+02

NA

NA

2.4E+02







Zinc

NA

NA

NA

NA

Circulatory

5.6E+01

NA

NA

5.6E+01





Chemical Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



4.0E+02

NA

NA

4.0E+02



Exposure Medium Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



8.2E+02

NA

NA

8.2E+02

Transition Zone Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



8.2E+02

NA

NA

8.2E+02

Revised 02/09/2006

008606

Page 1 of 2


-------
TABLE 10.1. RME
RISK SUMMARY
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Future

Receptor Population: Residential (Subsistence)

Receptor Age: Adult	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ (s)







Routes Total

Aquatic Biota

Fish Tissue/

Aquatic Food Tissue

Cadmium

NA

NA

NA

NA

Kidney

4.0E+00

NA

NA

4.0E+00



Aquatic Food

(Mussels etc.)

Zinc

NA

NA

NA

NA

Circulatory

6.5E-01

NA

NA

6.5E-01





Chemical Total

0.0E+00

NA

NA

0.0E+00



4.7E+00

NA

NA

4.7E+00





Fish Tissue

Cadmium

NA

NA

NA

NA

Kidney

2.2E+00

NA

NA

2.2E+00





* high fish diet

Zinc

NA

NA

NA

NA

Circulatory

9.0E-01

NA

NA

9.0E-01





Chemical Total

0.0E+00

NA

NA

0.0E+00



3.0E+00

NA

NA

3.0E+00





Fish Tissue

Cadmium

NA

NA

NA

NA

Kidney

1.8E-01

NA

NA

1.8E-01





* high Beef diet

Zinc

NA

NA

NA

NA

Circulatory

7.6E-02

NA

NA

7.6E-02





Chemical Total

0.0E+00

NA

NA

0.0E+00



2.6E-01

NA

NA

2.6E-01



Exposure Medium Total (High Fish Diet)

0.0E+00

NA

NA

0.0E+00



7.7E+00

NA

NA

7.7E+00



Exposure Medium Total (High Beef Diet)

0.0E+00

NA

NA

0.0E+00



5.0E+00

NA

NA

5.0E+00

Aquatic Biota (High Fish Diet)

0.0E+00

NA

NA

0.0E+00



7.7E+00

NA

NA

7.7E+00

Aquatic Biota (High Beef Diet)

0.0E+00

NA

NA

0.0E+00



5.0E+00

NA

NA

5.0E+00

Receptor Total (High Fish Diet)

0.0E+00

2.3E-07

0.0E+00

2.3E-07



8.2E+02

6.1 E-04

2.2E-03

8.2E+02

Receptor Total (High Beef Diet)

0.0E+00

2.3E-07

0.0E+00

2.3E-07



8.2E+02

6.1 E-04

2.2E-03

8.2E+02

Total Circulatory HI Across Media (High Fish Diet) =
Total Kidney HI Across Media (High Fish Diet) =

Total Circulatory HI Across Media (High Beef Diet) =
Total Kidney HI Across Media (High Beef Diet) =

6E+Q2

2E+Q2

Revised 02/09/2006

008607

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Appendix D
Air Emissions

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DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

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CH2MHILL

Appendix D

Technical Memorandum
Air Emissions

Tar Creek Superfund Site, Operable Unit No. 4
Ottawa County, Oklahoma

PREPARED FOR:	Ursula Lennox/USEPA Region 6 RPM

PREPARED BY:	CH2M HILL, Inc.

prepared under:	EPA Region 5 Response Action Contract No. 68-W6-0025,

Work Assignment No. 233-RKED-06JW
DATE:	October 19, 2005

DCN NUMBER::	05-8225

1.0 Background

This Technical Memorandum (TM) summarizes the emissions estimates completed by
CH2M HILL as part of the activities being completed by EPA under Operable Unit 4
(OU4) at the Tar Creek Superfund Site located in Ottawa County, Oklahoma. This work
was completed under Contract No. 68-W6-0025, and the approved project work plan and
subsequent work plan revisions under Work Assignment No. 233-RKED-06JW.

The Respondents are responsible for completing a Remedial Investigation and Feasibility
Study (RI/FS) of OU4 under an Administrative Order on Consent (AOC) that was
executed on December 9, 2003 (EPA, 2003). As part of this agreement, EPA is
responsible for completing the Human Health Risk Assessment (HHRA) and the
Ecological Risk Assessment (ERA). CH2M HILL is working for EPA and is responsible
for the HHRA. Air modeling is an important component of the HHRA for this site
because of potential air concentrations and deposition into soils. Emissions from sources
at the Tar Creek site were used as inputs to the air dispersion modeling analysis for input
to the HHRA.

The HHRA examines impacts from lead, cadmium, and zinc. Emissions of particulate
matter were estimated and site specific data was used to determine the emissions of the
individual compounds.

2.0 Emissions Summary

Table D-l provides a summary of the emissions estimates by individual source, source
category, and pollutant. Figure D-l shows the source locations.

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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIXD: AIR EMISSIONSTM

3.0 Methodology

Air emissions were determined for a total of 21 major chat piles, five of which are
actively used, and 10 flotation tailings ponds (ponds). These sources were selected for
estimating air emissions because they were sampled in the summer of 2005.

Particulate emissions were first estimated for each of the source categories. Emissions of
individual compounds were estimated as a percentage of the total particulate emissions
based on concentrations of these compounds found in the sources.

In the summer of 2005, the respondents, in cooperation with EPA, collected information
on soils in the area as reported in Draft Preliminary Site Characterization Summary
(AATA, 2005). Samples were collected of the bulk chat and surface chat of the existing
chat piles. The fine tailings ponds contain two types of fines - flotation tailings and
washed fines. Typically the flotation tailings are covered by several feet of washed fines.
Samples were collected of both flotation tailings and washed fines. If a fine tailings pond
was found to contain mixed fine tailings (i.e. multiple layers of washed fines and flotation
tailings) at a sampling site, the material near the surface was sampled and called surface
fine tailings. Table D-2 provides a list of source categories and the sampling information
used to estimate emissions.

4.0	Emission Calculations by Source Category

A description of the emissions calculation methodology and example emission
calculations are provided in this section for the following source categories considered:

1.	Loading and handling of chat

2.	Wind erosion from chat piles and flotation ponds

3.	Unpaved and paved roads

4.1	Loading and Handling of Chat

Dust emissions from chat piles result from unloading of material onto piles, equipment
and recreational traffic in the area, and loading material from the piles for reprocessing
were considered. Emissions were estimated using emission factors from AP-42 Section
13.2.4 Aggregate Handling and Storage Piles. These emissions were assumed to only
apply to active piles. The five active piles are Admiralty, Atlas, Fisher, Ottawa, and
Sooner.

The emission factors in AP-42 Section 13.2.4 include emissions from loading and
unloading material at the piles and equipment traffic in the area. Loading/unloading
includes truck dumping or conveyor dumping. The emission factor is for total particulate
matter (PM), given in units of lb/ton of material in the pile, and has an emission factor
rating of "A". The emission factor is based on aerodynamic particle size, mean wind
speed, and material moisture content. Aerodynamic particle size is assumed to be <30
micrometers (pm), the largest particle size range specified. The mean wind speed was
estimated using the same meteorological data used for the air dispersion modeling.

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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIXD: AIR EMISSIONSTM

Material moisture content was estimated to be 4 percent, based on information in the
Draft Preliminary Site Characterization Summary (AATA, 2005). This report indicated
moisture content of bulk chat in the piles to be 4-11 percent. Since the emissions occur
from the surface of the piles and the surface of the piles is drier than the interior, the
lower end of the range was chosen. Cadmium, lead, and zinc emissions were estimated
assuming that the emissions contained the same amount of cadmium, lead, and zinc as the
bulk chat piles. Concentrations of cadmium, lead, and zinc in the piles were based on
individual average bulk chat chemistry information obtained from thq Draft Preliminary
Site Characterization Summary (AATA, 2005).

For material handling of chat piles, the following equations were used:

EF = k x 0.0032 x ((U/5)L3/(M/2)L4)

E= EF x Usage x EFF x CC x (lxlO"6)

Variable Name

Units

Description

E

lb/year

Air emissions of speciated pollutant

Usage

tons/year

Annual quantity of chat handled

EF

lb/ton

Emission factor, pound of pollutant per tons of





material handled

k



Particle size multiplier

U

mph

Wind speed, miles per hour (mph)

EFF

0/

/O

Percent recovery efficiency of cadmium, lead or zinc

M

0/
/o

Material moisture content

CC

mg/kg

Chemical concentration of pollutant in chat material

Reference: AP-42 Compilation of Air Pollutant Emission Factors, EPA, 5th Edition, Chapter 13 (Jan 1995)

Shown below is a sample calculation for material handling of chat located at the Sooner
pile for lead:

Input Data:

k =0.74 (<30 |im, AP-42, Chapter 13.2.4-3)

U =7.77 mph (Based on average of five years of meteorological data)
M = 4%

Usage = 80,000 tons/year

CC = 1,610 mg/kg (The Sooner Pile Bulk Chat Average Lead Concentration)
EFF = 88 %/100% = 0.88 (Based on Exponent report, page 4A-4)
EF = k x 0.0032 x ((U/5)L3/(M/2)L4)

= 0.74 x 0.0032 x ((7.77/5)L3/(4/2)L4)

EF = 0.00159 lb. PM/tons of material

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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
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APPENDIX D: AIR EMISSIONSTM

E = EF x Usage x EFF x CC x (lxlO"6)

= 0.00159 lb/ton x 80,000 tons/ year x 0.88 x 1,610 mg/kg x lxlO"6 kg/mg
= 0.180 lbs, lead/year

4.2 Wind Erosion

Wind erosion of the chat piles and tailings ponds were considered for air emissions.
Emissions were estimated using the equation from Control of Open Fugitive Dust
Sources (EPA, 1988). The maximum pile heights were provided by the Respondent's.
The volume and area (assumed to be the chat pile base area) from the Draft Preliminary
Site Characterization Summary (AATA, 2005), was used to determine the base radius
which was used to calculate the exposed surface area of the pile assuming the pile mimics
a cone shape.

Cadmium, lead and zinc emissions were estimated assuming that the emissions contained
the same amount of cadmium, lead and zinc as the chat pile surface and tailings pond
surface. Concentrations of cadmium, lead, and zinc in the piles and ponds were based on
surface chemistry information obtained from the Draft Preliminary Site Characterization
Summary (AATA, 2005). Specific surface chemistry for each tailings pond was available
and used; however, only seven of the 21 chat piles had surface chemistry data available.
Therefore, the average surface chemistry for the combined seven chat pile surfaces was
used for the 21 chat piles.

For wind erosion of chat piles and tailings ponds, the following equations were used:
EF = 1.7 x (s/1.5) x (365-p/235) x (f/15)

E = EF x SA x CC x (365) x (lxlO"6)

Variable Name

Units

Description

E

lb/year

Air emissions of speciated pollutant

EF

lb/acre-day

Emission factor, pound of pollutant per acre-day

s

0/

/O

Silt content

f

0/
/o

Percent of time that the unobstructed wind speed
exceeds 12 mph at the mean pile height0-1

P

days

Number of days with > 0.01 inches of precipitation
per year

SA

acres

Total exposed surface area of piles or tailings ponds

CC

mg/kg

Chemical concentration of pollutant in surface
material

Reference: Control of Open Fugitive Dust Sources, EPA, 1988.

(1) The unobstructed wind speed is correlated to the mean pile height using available meteorological data.
The mean pile height is half of the maximum pile height where the maximum pile height is provided by the
Respondent's.

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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIXD: AIR EMISSIONSTM

Shown below is a sample calculation for wind erosion of the Sooner chat pile for lead:
Input Data:

s = 10 (Table 13.2.2-1 of AP-42 Section 13.2.2)
p = 100 (Figure 13.2.2-1 of AP-42 Section 13.2.2)
f =24.5%/100% = 0.245
SA =90.92 acres
CC = 829 mg/kg
EF = 1.7 x (s/1.5) x (365-p/235) x (f/15)

= 1.7 x (10/1.5) x (365-100/235) x (0.245/15)

EF = 0.2087 lb/acre-day
E = EF x SA x CC x (365) x (lxlO"6)

= 0.2087 lb/acre day x 90.92 acres x 829 mg/kg x 365 days/yr x lxlO"6 kg/mg
= 5.74 lb of lead/year

4.3 Unpaved and Paved Roads

This source category includes emissions caused by vehicles on unpaved and paved roads
transporting raw material from chat piles to some off-site area for processing. Emission
factors from AP-42 Section 13.2.2 Unpaved Roads were used to estimate dust emissions
from unpaved roads while emission factors from AP-42 Section 13.2.1 Paved Roads were
used to estimate dust emissions from paved roads. The emissions are dependent upon
volume of traffic, silt and moisture content of road material, and vehicle weight.

Emission factors for PM-30 (Total Suspended Particulate [TSP] Matter) are given. These
emission factors were adjusted to account for annual precipitation as discussed below.

Different equations were used for vehicles traveling on unpaved and paved surfaces. The
equation for unpaved roads was used to estimate emissions from when the vehicle loaded
the chat from the chat pile to when a paved road was encountered while the equation for
paved roads estimated emissions from when the paved road was encountered to when the
vehicle passed the site boundary. It was assumed that vehicles traveling these roads are
hauling chat (i.e. the vehicle weight is based upon a hauling vehicle weight) and that the
road is a public road. Assuming the road is a public road used more conservative and
higher factors, thereby calculating higher emissions.

The emission factors for publicly accessible roads are dependent on silt content, mean
vehicle weight, and mean vehicle speed. Table 13.2.2-1 in AP-42 identifies typical silt
content values of surface material on unpaved sites. Since lead mining and processing is
not among the industries listed in the table, the silt content value given for stone
quarrying and processing plant road was used. Mean vehicle weight and speed were
estimated. Mean vehicle weight was estimated at 11 tons, typical for a hauling vehicle,
and mean vehicle speed was estimated at 45 mph for unpaved and paved roads.

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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX D: AIR EMISSIONSTM

The emission factors were adjusted to account for rainfall and other precipitation based
on Figure 13.2.2-1 of AP-42 Section 13.2.2(100 days per year with 0.01 inches or more
of precipitation).

The resulting emission factors are in units of lbs/vehicle mile traveled (VMT). Average
VMT on unpaved roads was estimated based on the distance from the chat pile to the
paved road while the average VMT on paved roads was estimated based on the distance
from the paved road to the nearest site boundary. Distances were obtained through review
of aerial photographs.

Cadmium, lead, and zinc emissions were estimated by assuming that PM emissions had
the same cadmium, lead, and zinc content as the road material. All unpaved roads were
assumed to be made of chat and the surface of the paved roads was covered by chat. The
lead, zinc, and cadmium content of the chat was estimated based on average
concentrations of bulk chat, surface chat, washed fines, flotation tailings, and surface
tailings chemistry data as shown in Table D-3, and was obtained from the Draft
Preliminary Site Characterization Summary (AATA, 2005).

The following equations were used for unpaved public roads:

EF = k(s/12)a(S/30))d - C

(M/0.5)c

VMT = (Chat processed/10 tons per load) * miles/trip * 2 trips/load
EFext = EF [(365 - p)/365]

E = EFext * VMT *wt%

Variable Name

Units

Description

E

lb/year

Air emissions of speciated pollutant

EF

lb/VMT

Emission factor

EFext

lb/VMT

Emission factor corrected for natural mitigation

VMT

miles

Vehicle miles traveled (VMT)

k

6.0 lb/VMT

Particle Size Multiplier, pounds per vehicle mile
travel (VMT)(1)

s

%

Surface material silt content

S

mph

Mean vehicle speed in miles per hour (mph)

P

days

Number of days with >0.01 inches of precipitation
per year

wt%

%

Weight % of pollutant in soil

a

1.0

Unitless Empirical Constant0-1

c

0.3

Unitless Empirical Constant0-1

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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX D: AIR EMISSIONSTM

Variable Name

Units

Description

d

0.3

Unitless Empirical Constant0-1

C

lb/VMT

Emission factor for 1980s vehicle fleet exhaust,





brake wear and tire wear

Reference: AP-42 Compilation of Air Pollutant Emission Factors, EPA, 5th Edition, Chapter 13.2.2 (Dec
2003).

(1) Uses the highest provided values from the reference (Table 13.2.2-2) for conservatively estimating
emissions of Total Suspended Particulate Matter (TSP) which assumes vehicles are traveling on publicly
accessible roads.

The following equations were used for paved roads:

EF = k(sL/2)°'65(W/3)L5 -C

VMT = (Ore Processed/10 tons per load)* miles/trip * 2 trips/load
EFext = EF [(N-p)/(N)]

E = EFext * VMT *wt%

Variable Name

Units

Description

E

lb/year

Air emissions of speciated pollutant

EF

lb/VMT

Emission factor

EFext

lb/VMT

Emission factor corrected for natural mitigation

VMT

miles

Vehicle miles traveled (VMT)

k

0.082 lb/VMT

Particle Size Multiplier, pounds per vehicle mile
travel (VMT)(1)

sL

g/m2

Road surface silt loading

W

tons

Mean vehicle weight

P

days

Number of days with >0.01 inches of precipitation
per year

N

days

Number of days in the averaging period (e.g., 365
for annual)

wt%

%

Weight % of pollutant in soil

C

lb/VMT

Emission factor for 1980s vehicle fleet exhaust,
brake wear and tire wear

Reference: AP-42 Compilation of Air Pollutant Emission Factors, EPA, 5th Edition, Chapter 13.2.1 (Dec
2003).

(1) Uses value provided by reference (Table 13.2.1-1) for Total Suspended Particulate Matter (TSP).

Shown below is a sample calculation for an unpaved public road from the Sooner chat
pile:

Input Data:

k = 6.0 (based on constant for PM-30 assuming vehicles are traveling on publicly
accessible roads, Table 13.2.2-2)

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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIXD: AIR EMISSIONSTM

s = 10% (based on plant roads for stone quarrying and processing, Table 13.2.2.-

1)

W = 11 tons

a = 1 (based on constant for PM-30 assuming vehicles are traveling on publicly
accessible roads, Table 13.2.2-2)

c = 0.3 (based on constant for PM-30 assuming vehicles are traveling on publicly
accessible roads, Table 13.2.2-2)

d = 0.3 (based on constant for PM-30 assuming vehicles are traveling on publicly
accessible roads, Table 13.2.2-2)

S= 45 mph

M = 4%

C = 0.00047 lb/VMT (based on constant for PM-30, Table 13.2.2-4)
wt% = 0.0038 lead
EF = k(s/12)a(S/30))d-C
(M/0.5)c

= 6.0 (10/12)1(45/30)0'3 - 0.00047 lbs/VMT
(4/0.5)03
EF =3.026 lbs/VMT
VMT = (80,000 tons/10)*0.5 miles/trip*2 trips

= 8,000 miles
E = EF x [(365 - p)/365] x VMT x wt%

= 3.026 lbs/VMT * [(365-100)/365] x 8,000 miles * 0.0038
E = 66.58 lbs. of lead/year

Shown below is a sample calculation for a paved public road from the Sooner chat pile:
Input Data:

k = 0.082 (based on constant for PM-30, Table 13.2.1-1)

W = 11 tons

sL= 0.015 g/m2 (based on constant for limited access roadways, Table 13.2.1-3)
C = 0.00047 lb/VMT (based on constant for PM-30, Table 13.2.1-2)
wt% = 0.0038 lead

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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIXD: AIR EMISSIONSTM

EF = k(sL/2)°'65(W/3)L5 -C

= 0.082 (0.015/2)0.65(11/3)1.5-0.00047
= 0.023 lb/VMT

VMT = (80,000 tons/10)*0.375 miles/trip*2 trips
= 6,000 miles

E = EF x [1 - p/ (4N)] x VMT x wt%

= 0.0231b/VMT*(l-(100/(4*365)))*6,000 miles*0.0038
= 0.497 lbs, of lead/year

5.0 References

AATA International, Inc. (AATA), 2005. Draft Preliminary Site Characterization
Summary, Tar Creek OU4 RIFS Program. September 2005.

U.S. Environmental Protection Agency (EPA), 1988. Control Of Open Fugitive Dust
Sources. EPA-450/3-88-008,C. Prepared by Cowherd, et al. September 1988.

U.S. Environmental Protection Agency (EPA), 2003. Administrative Order on Consent
for RIFS for OU4. December 2003.

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Tables

008620


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APPENDIXD: AIR EMISSIONSTM

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Table D-1

Summary of Emissions Estimates
Tar Creek Superfund Site
Ottawa County, Oklahoma

Emissions Estimates

Cadmium Lead	Zinc

Source Category (Ib/yr) (Ib/yr)	(Ib/yr)

Loading and Handling of Chat 0.05 0.91	12.51

Wind Erosion from Chat Piles 2.61 29.00	612.76

Wind Erosion from Flotation Tailings Ponds 2.10 310.28	380.01

Unpaved Roads 7.97 332.90	1,752.19

Paved Roads 0.23 9.61	50.56

Estimated Emissions, Loading and
Handling of Chat

Cadmium Lead	Zinc

Source Name (Ib/yr) (Ib/yr)	(Ib/yr)

Flotation Tailing Ponds

Ottawa
Bird Dog
Pioneer
Lawyers
Semple
John Beaver
Skelton
Atlas

Blue Goose
Central Mill
Chat Piles

Atlas	0.008	0.08	1.70

Bird Dog

Adams-Mudd (Barret)

Pioneer

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Estimated Emissions, Wind Erosion

Estimated Emissions, Roads

Cadmium	Lead	Zinc	Cadmium Lead	Zinc

(Ib/yr)	(Ib/yr)	(Ib/yr)	(Ib/yr)	(Ib/yr)	(Ib/yr)

0.10

8.72

19.48

1.10

255.58

205.86

0.08

4.06

13.21

0.02

8.08

6.09

0.19

0.86

11.83

0.04

1.25

7.08

0.03

1.39

5.82

0.05

2.90

10.14

0.07

5.08

18.95

0.42

22.35

81.53

0.07
0.01
0.04
0.16

0.83
0.13
0.42
1.80

17.57
2.78
8.85
38.09

OCTOBER 2005


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Table D-1

Summary of Emissions Estimates
Tar Creek Superfund Site
Ottawa County, Oklahoma

Source Category

Loading and Handling of Chat

Wind Erosion from Chat Piles

Wind Erosion from Flotation Tailings Ponds

Unpaved Roads

Paved Roads

Emissions Estimates

Cadmium
(Ib/yr)

0.05

2.61
2.10
7.97
0.23

Lead
(Ib/yr)

0.91

29.00

310.28

332.90

9.61

Zinc
(Ib/yr)

12.51

612.76

380.01

1,752.19

50.56

Estimated Emissions, Loading and
Handling of Chat

Source Name

Semple

Sooner

Howe

Ottawa

Gordon

Western (Anna Beaver)

Western (John Beaver)

OKO

Kenoyer

St. Joe

Fisher (Mahutska)

Royal (Thompson)

Lawyers

Admiralty

Skelton

Blue Goose

Cadmium Lead
(Ib/yr)	(Ib/yr)

0.01

0.01

0.01

0.01

0.15

0.16

0.40

0.10

Zinc
(Ib/yr)

2.38

2.87

3.61

1.95

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICI ES\
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008623

Estimated Emissions, Wind Erosion

Estimated Emissions, Roads

Cadmium
(Ib/yr)

Lead
(Ib/yr)

Zinc
(Ib/yr)

Cadmium Lead Zinc
(Ib/yr) (Ib/yr) (Ib/yr)

0.06

0.64

13.55

-

0.52

5.74

121.32

-

0.05

0.53

11.13

-

0.10

1.16

24.51

-

0.03

0.34

7.09

-

0.27

2.96

62.64

-

0.03

0.31

6.65

-

0.03

0.36

7.68

-

0.12

1.31

27.67

-

0.14

1.56

33.03

-

0.17

1.93

40.74

-

0.02

0.18

3.80

-

0.19

2.09

44.21

-

0.27

3.00

63.45

-

0.17

1.85

39.01

-

0.14

1.57

33.06



OCTOBER 2005


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Table D-1

Summary of Emissions Estimates
Tar Creek Superfund Site
Ottawa County, Oklahoma



Emissions Estimates



Cadmium

Lead

Zinc

Source Category

(Ib/yr)

(Ib/yr)

(Ib/yr)

Loading and Handling of Chat

0.05

0.91

12.51

Wind Erosion from Chat Piles

2.61

29.00

612.76

Wind Erosion from Flotation Tailings Ponds

2.10

310.28

380.01

Unpaved Roads

7.97

332.90

1,752.19

Paved Roads

0.23

9.61

50.56

Estimated Emissions, Loading and
Handling of Chat

Cadmium Lead	Zinc

Source Name	(Ib/yr)	(Ib/yr)	(Ib/yr)

Pearl (Bill Baily)

Unpaved Road From Chat Pile

Atlas

Sooner

Ottawa

Fisher (Mahutska)

Admiralty

Paved Road From Chat Pile

Atlas

Sooner

Ottawa

Fisher (Mahutska)

Admiralty

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\	3

APPENDIXD\TC_HHRA_DRAFTRA_APPENDIXD_TABLED-1.DOC
008624

Estimated Emissions, Wind Erosion	Estimated Emissions, Roads

Cadmium Lead Zinc	Cadmium Lead	Zinc

(Ib/yr) (Ib/yr) (Ib/yr)	(Ib/yr) (Ib/yr)	(Ib/yr)

0.03	0.28	5.93

3.19

133.16

700.87

1.59

66.58

350.44

1.20

49.94

262.83

1.20

49.94

262.83

0.80

33.29

175.22

0.06

2.48

13.08

0.01

0.50

2.62

0.00

0.00

0.00

0.03

1.32

6.97

0.13

5.30

27.90

OCTOBER 2005


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Table D-2

Sampling Information Used to Estimate Lead, Cadmium, and Zinc Emissions
Tar Creek Superfund Site
Ottawa County, Oklahoma

Source Category

Sampling Data Used to Estimate Emissions

Loading and Handling of Chat

Average Bulk Chat Concentrations for Each



Individual Chat Pile

Wind Erosion from Chat Piles

Combined Average Surface Chat Concentrations for



the Seven Chat Piles Sampled

Wind Erosion from Flotation Ponds

Average Surface Fine Tailings Concentrations for



Each Individual Flotation Pond

Unpaved Roads

Combined Average Concentrations of Bulk Chat,



Surface Chat, Washed Fines, Flotation Tailings, and



Surface Tailings

Paved Roads

Combined Average Concentrations of Bulk Chat,



Surface Chat, Washed Fines, Flotation Tailings, and



Surface Tailings

Reference: Draft: Preliminary Site Characterization Summary, Tar Creek OU4 Ri/FS Program, Sept 2005.

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Table D-3

Pollutant Content (weight fraction, wt%) of Unpaved Roads and Surface of Paved Roads
Tar Creek Superfund Site
Ottawa County, Oklahoma

Cadmium

Lead

Zinc

0.0001

0.0038

0.0199

Reference: Draft: Preliminary Site Characterization Summary, Tar Creek OU4 RI/FS Program, Sept 2005.

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APPENDIXD: AIR EMSSIONSTM

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Figures

008630


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APPENDIXD: AIR EMISSIONSTM

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Sooner
118,2, A

Ottawi
46.9, >

Vv*- ¦¦
Bird Dog
156,. a

. Howe

55

Fisher (Mahutska)
102.5, A

(Anna Be£^&r)
127.6%#

Western

's mudd

p43?

Pearl (Billy Baily)

.awyers

Pioneer 'k

98.8

Skelton
102.5

imira!

Central Mill

#

CH2MHILL

\\chuckwagon\GIS\NWOFiles\Tar Creek\MXD\Bird_Dog.mxd 10\6\05 S Daigle

008632

LEGEND

Site Boundary
Chat Pile
Tailings Pond

N

A

Chat Pile Name: Lawyers

Pile Height, Ft: 157.1, A(Active Chat Pile)

¦ Miles

0.4

0.8

1.6

FIGURE D-1

Tar Creek OU4
Modeled Emission Sources

*AERIAL PHOTOGRAPHY PROVIDED BY:
AATA INTER NATIONAL INC.
Fort Collins, Colorado, USA


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Appendix E
Air Modeling

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CH2MHILL

Appendix E

Technical Memorandum
Air Modeling

Tar Creek Superfund Site, Operable Unit No. 4
Ottawa County, Oklahoma

Ursula Lennox/USEPA Region 6 RPM
CH2M HILL, Inc.

EPA Region 5 Response Action Contract No. 68-W6-0025,
Work Assignment No. 233-RKED-06JW
February 3, 2005

05-8225

PREPARED FOR:
PREPARED BY:
PREPARED UNDER:

DATE:

DCN NUMBER::

1.0 Background

This Technical Memorandum (TM) summarizes the air modeling activities completed by
CH2M HILL as part of the activities being completed by U.S. Environmental Protection
Agency (EPA) under Operable Unit 4 (OU4) at the Tar Creek Superfund Site located in
Ottawa County, Oklahoma. This work was completed under Contract No. 68-W6-0025,
and the approved project work plan and subsequent work plan revisions under Work
Assignment No. 233-RKED-06JW.

The Respondents are responsible for completing a Remedial Investigation and Feasibility
Study (RI/FS) of OU4 under an Administrative Order on Consent (AOC) that was
executed on December 9, 2003 (EPA, 2003). As part of this agreement, EPA is
responsible for completing the Human Health Risk Assessment (HHRA) and the
Ecological Risk Assessment (ERA). CH2M HILL is working for EPA and is responsible
for the HHRA. Air modeling is an important component of the HHRA for this site
because of potential air concentrations and deposition to soils.

In Risk Assessment Work Plan Revision Request No. 1 (WPRR01), CH2M HILL defined
the approach and scope for the air modeling to support the HHRA. Task 6.3 of WPRR01
defined the steps in completing the air modeling. This approach included the following
activities:

•	Estimation of emissions

•	Identification of receptor information

•	Development of source treatment method

•	Development of soil depletion method

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APPENDIX E: AIR MODELING TM

•	Execution of dispersion model

•	Result evaluation

The approach used in the air modeling analysis was defined in an October 10, 2005
memorandum from Don Caniparoli (CH2M HILL) to Dr. Ghassan Khoury (EPA). This
memorandum is included as Attachment A of this TM.

The dispersion modeling analysis generated information to be used in the HHRA. Air
concentrations from current sources were determined at the receptors of interest.
Deposition was estimated throughout the receptor grid 30 years from the present. This
30-year deposition rate was estimated by determining the deposition rate through
modeling, adding a background concentration, and depleting this concentration over the
30-year period by using the Raman Health Risk Assessment Protocol for Hazardous
Waste Combustion Facilities (EPA, 2005) as described below.

Three source categories were included in the modeling: (1) loading and handling of chat,
(2) wind erosion from chat piles and flotation ponds, and (3) unpaved and paved roads.
Emissions of lead, cadmium, and zinc were included in the air quality analysis.

2.0 Estimation of Emissions

Emissions were estimated as described in the Air Emissions Estimates Technical
Memorandum, Appendix D. Based on information in the Draft Preliminary Site
Characterization Summary (AATA, 2005), emissions from 21 chat piles and 10 flotation
ponds were modeled. Five of these chat piles were also modeled as active chat piles.
These sources were considered to be representative of current and future emissions.

3.0 Identification of Receptors

For the air concentration analysis, a discrete receptor grid of the 46 houses analyzed in
the draft HHRA was established with 12 receptors corresponding to ground water
monitoring locations. Note that three of the ground water monitoring location receptors
are coincident with the house locations, so a total of 55 receptors were modeled in the
concentration analysis. Locations for these receptors are shown in Figure E-l.

For the deposition analysis, a 500-meter spaced grid was established for the entire OU4
area. In addition, a fine grid of receptors was placed around each source. Some of the fine
receptor grids overlapped due to the proximity of multiple sources. A total of 1,585
receptors were established for the deposition analysis.

The terrain in the Tar Creek area is relatively flat. Because of the low-level sources used
in the analysis and the relatively flat terrain, the model was run in the flat terrain mode
with all receptor elevations set to zero.

4.0 Development of Source Treatment Method

The emissions for the sources included in the modeling were estimated by utilizing a
variety of emission factors as defined in the Air Emissions TM. Each of the chat pile and
tailings pond sources was treated as an individual area source in the model. The height of
the piles was set at the average pile height provided by the Respondents. The tailings

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ponds and unpaved and paved roads were modeled as a series of ground level area
sources. Because the emissions were estimated to be representative of emissions over a
one year time period and were not based on episodic wind conditions, emissions were
modeled as if occurring every hour of the year.

5.0	Soil Depletion

Soil depletion was included in the deposition analysis. Depletion of lead, cadmium, and
zinc over time in the deposited chemicals was calculated using EPA methods as defined
below.

5.1	Soil Depletion Method

Chemicals deposited on the soil become depleted through various physical processes
such as runoff and erosion. Equations in Chapter 5 of the Human Health Risk Assessment
Protocol for Hazardous Waste Combustion Facilities (EPA, 2005) were used to develop
a method for soil depletion. Equation 5-IE of the protocol calculates soil concentration
over exposure duration.

CstD = Ps»[l-Qxp(-ks»tP]
ks

where:

Soil concentration at time tD (mg/kg)

Deposition term (mg COPC/kg soil/yr)

COPC soil loss constant due to all processes (yr"1)

Time period over which deposition occurs (yr)

CStD	-

Ds	=

ks	=

tD	=

5.2 Deposition Term

Results from the deposition modeling, deposition term (mg COPC/kg soil/yr), were used
as the starting point from which to calculate the depletion term.

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APPENDIX E: AIR MODELING TM

5.3 Chemical of Potential Concern Soil Loss Constant

To calculate the Chemical of Potential Concern (COPC) soil loss constant, ks, the COPC-
specific loss resulting from leaching, runoff, erosion, biotic and abiotic degradation, and
volatilization were estimated as shown in Equation 5-2A of the protocol, and presented
below.

ks = ksg + kse + ksr + ksl + ksv
where:

Ks = COPC soil loss constant due to all processes (yr"1)

Ksg = COPC loss constant due to biotic and abiotic degradation (yr"1)

Kse = COPC loss constant due to soil erosion (yr"1)

Ksr = COPC loss constant due to surface runoff (yr"1)

Ksl = COPC loss constant due to leaching (yr"1)

Ksv = COPC loss constant due to volatilization (yr"1)

Equations for each COPC loss constant are provided in Appendix B of the EPA
document. Ksg and Ksv are 0 since the chemicals are metals. Values used for each
parameter are described in Table E-l.

The soil loss constant (ks) is then used to calculate the final deposition with other
physical factors.

6.0	Dispersion Modeling Analysis

Concentration and deposition were analyzed using the same model and similar methods,
as described below.

6.1	Model Selection

The air modeling analysis was conducted using the EPA Industrial Source Complex Short
Term Model (ISC3). The latest version of ISC3 (02035, available from EPA) was used in
the analysis. The ISC3 model is listed as a Preferred/Recommended model in 40 CFR
Part 51 Appendix W, Guideline on Air Quality Models. ISC3 is a steady-state Gaussian
plume model which is used to assess pollutant concentrations from a wide variety of
sources associated with an industrial complex. It is the standard model used to assess air
quality impacts from a number of industrial sources including the area sources present at
the Tar Creek site. The model was run to calculate current air concentrations at the 46
homes of interest plus the ground water well locations, and 30-year dry and wet
deposition. Standard regulatory default modeling options were used, consistent with EPA
policy. A full description of the ISC3 model can be found in the User's Guide.

The model was run to calculate deposition and concentration. The ISC3 model calculates
deposition and concentration and has a depletion option which subtracts the amount

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APPENDIX E: AIR MODELING TM

deposited from the concentration. However, this option is a very computer-intensive
option. Therefore, because of the size of the runs and the resources required to make such
runs, the model was run without use of this depletion option. This approach will slightly
over estimate the modeling results.

6.2	Terrain

The terrain in the Tar Creek area is relatively flat. Because of the low-level sources used
in the analysis and the relatively flat terrain, the model was run in the flat terrain with all
receptor elevations set at zero.

6.3	Land Use

The land use in the Tar Creek Superfund Site OU4 area is mostly rural. Consequently the
model was run using rural dispersion coefficients.

6.4	Meteorology

The modeling analysis was performed using a standard five years of meteorological data
for each time period. The surface meteorological data was obtained from the University
of Oklahoma MESONET network for the Miami, Oklahoma site (www.mesonet.org).
Wind speed, wind direction, temperature, and precipitation values were obtained from
this station. Miami is located approximately 10 kilometers to the southwest of the site.
Cloud cover data were derived from surface observations data obtained from the National
Climatic Data Center (NCDC) for the National Weather Service site in Joplin, Missouri.
These data were used to calculate stability. Joplin is located approximately 15 km to the
northeast of the site. Mixing Height data was obtained from NCDC for the Norman,
Oklahoma, station. Missing data, where possible, were interpolated; otherwise Holzworth
average seasonal mixing heights for Oklahoma City were used as a substitute. Five years
of data from 1999 through 2003 were used in the analysis. Each time-period analysis
used the same five-year set of meteorological data. Regulatory modeling requires the use
of five years of data as it is considered statistically representative of longer-term
meteorological periods. Therefore, it was employed as representative of time periods
throughout the next 30 years in Tar Creek. Wind roses for each of the years and a
composite wind rose are shown in Attachment B to this TM.

6.5	Particle Size Distribution

Deposition modeling is dependent upon the particle size distribution (PSD). Data
collected as part of and reported in Draft: Preliminary Site Characterization Summary,
Tar Creek OU4 RIFS Program, September 2005, was used to determine the PSD. Data
from sources with particle size data was averaged to determine a representative PSD for
all sources at the site.

There were six samples for chat piles and two samples for fine tailings. The particles in
these samples were partitioned into particle size categories ranging from 75,000 microns
(|im) or less to 1.4 |im or less and were represented as percent by dry weight. For the
purposes of this analysis, only those particles which could reasonably become airborne as
a result of wind erosion or disturbance of soils were needed. A particle size of 75 |im was
chosen as the maximum that would become airborne to remain consistent with previous

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APPENDIX E: AIR MODELING TM

studies (Shields, December, 2002). This report maintained that only particles less than
106 |im would become airborne. The sample data was averaged for the chat piles and for
the fine tailings and then was re-weighted to partition the fraction of particles 75 |im and
less to equal 100 percent of the total particulate emissions. The particle size distribution
used in the modeling is shown in Table E-2.

6.6 Existing Soil Concentrations

For the deposition analysis, existing soil concentrations were obtained from data
collected for the RI from residential areas, transition zones, the smelter-affected area,
rural areas, and background. Data were collected from both 0 to 1-inch and 0 to 6-inch
layers. In some cases, multiple samples were taken at a location. These results were
averaged together, regardless of depth, to produce one unique value for each location.
Table 1 presents the number of each type of sample and the number of averaged sample
points used in the analysis.

TABLE 1

Description of Sampling Data Used to Determine Existing Soil Concentrations

Description

Depth of Samples

Number of individual
sample points

Number of sampling
locations

Residential

0-1" and 0-6"

389

46

Transition Zone

0-6"

22

8

Smelter-Affected

0-6"

5

5

Rural Area

0-1"

56

56

Background

0-6"

8

7

Concentrations were interpolated to estimate the existing soil concentrations at locations
spanning the entire modeling domain. A grid with 100-meter resolution was produced to
coincide with results from the deposition model. All points that were interpolated to a
value less than the lowest detected concentration were replaced by the lowest detected
concentration.

The resulting soil concentrations at 100-meter spacing were added to modeled deposition
results to calculate the soil concentration of each COPC. For the model results that
considered depletion, the existing soil concentrations were depleted as well to represent
the soil concentration remaining after 30 years.

6.7 Particle Density

Particle density is a variable required for the deposition analysis. A particle density of
1.35 g/cm3 was used in the analysis for all three COPCs. This is the lower range of

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APPENDIX E: AIR MODELING TM

particle densities for soil. Although the metals would have a higher density, they are only
a fraction of the material which could be emitted into the air along with other background
soils. A higher density would tend to fall out more quickly in the vicinity of the source,
while a lower density would travel a greater distance before becoming deposited to the
soils. The value of 1.35 g/cm3 is considered appropriate for this analysis.

7.0 Presentation of Results

The deposition results (future soil concentrations) are presented in Figures E-2 and E-3
for lead with and without deposition respectively, E-4 and E-5 for zinc with and without
depletion respectively, and E-6 and E-7 for cadmium with and without depletion,
respectively. The ambient air concentrations are presented in Figures E-8, E-9, and E-
10, for lead, zinc, and cadmium, respectively.

8.0 References

AATA International, Inc. (AATA), 2005. Draft Preliminary Site Characterization
Summary, Tar Creek OU4 RI/FSProgram. September 2005.

Oklahoma Mesonet. www.mesonet.org

U.S. Environmental Protection Agency (EPA), 2003. Administrative Order on Consent
for Tar Creek RI/FSfor OU4. December 2003.

U. S Environmental Protection Agency (EPA), 2005. Raman Health Risk Assessment
Protocol for Hazardous Waste Combustion Facilities. EPA530-R-05-006.
September 2005.

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Tables

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Table E-1

Soil Loss Constant Variables as Calculated by EPA and CH2M HILL
Tar Creek Superfund Site OU4
Ottawa County, Oklahoma

COPC
Loss
Constant

Variable

Value Used

Basis for CH2M HILL Value

Ksg

Kse
Ksr, Ksl

Ksl

Ksl
Ksl

Kse

Kse

Kse

Kse

Kse
Kse

Kse

RO, Average annual
surface runoff, cm/yr

Ksr, Ksl Theta, Soil volumetric water
content (ml water/cm3 soil)

Ksr, Ksl Zs, Soil mixing zone, cm

Ksr, Ksl Kds, Soil-water partition
coefficient (ml water/gram
soil)

Ksr, Ksl BD, Soil bulk density, gram

soil/cm soil

P, Annual annual
precipitation, cm/yr

I, Average annual irrigation,
cm/yr

Ev, Average annual
evapotranspiration, cm/yr

RF, USLE rainfall factor yr"

K, USLE erodibility factor,
ton/acre

LS, USLE length-slope
factor

C, USLE cover
management factor
(unitless)

PF, USLE supporting
practice factor (unitless)

a, empirical intercept
coefficient (unitless)

AL, Total watershed area
receiving deposition, m2

0	Because the COPCs are metals, no biodegradation

was assumed.

0	EPA guidance recommends a default value of 0.

12.5	EPA guidance recommends using the map value

from Geraghty et al, 1973.

0.2	EPA guidance recommends a default value of 0.2.

2.5	EPA guidance recommends a default value of 2.

Metal specific Appendix A of the protocol gives recommended
values.

1.7	EPA guidance recommends a default value of 1.5.

100	EPA guidance recommends using site-specific data.

Plate 2 of Geraghty et al, 1973 lists 40 inches per
year in the northeastern corner of Oklahoma.

0 or 33 EPA guidance recommends using site-specific data.

CH2M HILL is not aware of any on-site irrigation.

78	EPA guidance recommends using site-specific data.

Plate 13 of Geraghty et al, 1973 lists 33 inches per
year in the northeastern corner of Oklahoma.

250	Protocol recommends a value in the range of 50 -

300. Site specific value selected based on
Wischmeier and Smith (1978)

0.39	Protocol recommends a default value of 0.39.

1.5	Protocol recommends a default value of 1.5.

0.3	This factor is site-specific. Protocol recommends

values up to 0.1 for dense vegetation, values
between 0.1 to 0.7 for agricultural row crops and
values up to 1 for bare soil.

1	Protocol recommends a default value of 1 for sites

that have no runoff or erosion control.

1.2	The final version of the protocol recommends using

1.2 for total watershed areas between 10 and 100
square miles.

1.036 E8 This variable is site specific. The value used is

equivalent to 40 square miles, the area of the site.

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008646


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Table E-1

Soil Loss Constant Variables as Calculated by EPA and CH2M HILL
Tar Creek Superfund Site OU4
Ottawa County, Oklahoma

COPC
Loss
Constant

Variable

Value Used

Basis for CH2M HILL Value

Kse

b, Empirical slope

0.125

Protocol recommends a default value of 0.125.



coefficient (unitless)





Kse

ER, Soil enrichment ratio

1

Protocol recommends a default value of 1 for



(unitless)



inorganics in the absence of site-specific data.

Notes:

Ksg	COPC loss constant due to biotic and abiotic degradation (yr"1)

Kse	COPC loss constant due to soil erosion (yr1)

Ksr	COPC loss constant due to surface runoff (yr1)

Ksl	COPC loss constant due to leaching (yr1)

P:\USEPA\317950\T7\RA04\DRAFT-FINAL_2006-02\APPENDICIES\	2

APPENDIX E\TC_HHRA_DRAFTFINALRA_APPENDIXE_REVISED_TABLEE-1.DOC

008647

FEBRUARY 2006


-------
Table E-2

Particle Size Distribution
Tar Creek Superfund Site OU4
Ottawa County, Oklahoma

Particle Size (|jm)

Chat Piles

Fine Tailings

75

0.39

0.21

35

0.17

0.17

22

0.13

0.16

13.1

0.10

0.14

9.5

0.08

0.11

6.5

0.06

0.09

3.3

0.04

0.06

1.4

0.02

0.04

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE_TABLEE-2.DOC

008648

1

OCTOBER 2005


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E: AIR MODELING TM

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P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE_TABLEE-2.DOC
008649

2

OCTOBER 2005


-------
Figures

008650


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E: AIR MODELING TM

(This page intentionally left blank.)

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE.DOC
008651

OCTOBER 2005


-------
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008652

Legend

Site Boundary
O Air Modeling Recepter Sites

N

A

0.5

I Miles

FIGURE E-1

Tar Creek OU4
Air Concentration Modeling Receptors

•AERIAL PHOTOGRAPHY PROVIDED BY:
A ATA INTERNATIONAL INC.

Fort Collins. Colorado. USA


-------


CH2MHILL

\\chuckwagon\GIS\NWOFiles\Tar Creek\MXD\leadwith_Dep_1_31_06.mxd 1\31\06 S Daigle

008653

LEGEND

Contour (100 ppm Intervals)

Site Boundary

Modeled Chat Pile Emission Source
Modeled Tailings Pond Emission Source

R! Residential Samples
R! Background Samples
Rural Sampling Sites

N

A

I Miles

0.5

Figure E-2

Tar Creek OU4

Modeled Lead Soil Concentrations After 30 Years
Includes Depletion (in ppm)

*AERIAL PHOTOGRAPHY PROVIDED BY:
AATA INTERNATIONAL INC.
Fort Collins, Colorado, USA


-------


LEGEND

CH2IWHILL

\\chuckwagon\GIS\NWOFiles\Tar Creek\MXD\leadwithout_Dep_1_31_06.mxd 1\31\06 S Daigle

008654

Contour (100 ppm Intervals)

Site Boundary

Modeled Chat Pile Emission Source
Modeled Tailings Pond Emission Source

~ Rl Residential Samples
Rl Background Samples
Rural Sampling Sites

N

A

I Miles

0.5

Figure E-3

Tar Creek OU4

Modeled Lead Soil Concentrations After 30 Years
Without Depletion (in ppm)

*AERIAL PHOTOGRAPHY PROVIDED BY:
AATA INTERNATIONAL INC.
Fort Collins, Colorado, USA


-------
*

CH2MHILL

\\chuckwagon\GIS\NWOFiles\Tar Creek\MXD\Zincwith_Dep_1_31_06.mxd 1\31\05 S Daigle

008655

LEGEND

Contour (50 ppm Intervals)

Site Boundary

Modeled Chat Pile Emission Source
Modeled Tailings Pond Emission Source

Rl Residential Samples
Rl Background Samples
Rural Sampling Sites

0.5

N

A

I Miles

Figure E-4

Tar Creek OU4

Modeled Zinc Soil Concentrations After 30 Years
Includes Depletion (in ppm)

*AERIAL PHOTOGRAPHY PROVIDED BY:
AATA INTERNATIONAL INC.
Fort Collins, Colorado, USA


-------


LEGEND

CH2IV1HILL

Wchuckwagon\GIS\NWOFiles\TarCreek\MXD\Zincwithout_Dep_1_31_06.mxd 1\31\05 S Daigle

008656

Contour (1000 ppm Intervals)

Site Boundary

Modeled Chat Pile Emission Source
Modeled Tailings Pond Emission Source

Rl Residential Samples
Rl Background Samples
Rural Sampling Sites

N

A

I Miles

0.5

Figure E-5

Tar Creek OU4

Modeled Zinc Soil Concentrations After 30 Years
Without Depletion (in ppm)

*AERIAL PHOTOGRAPHY PROVIDED BY:
AATA INTERNATIONAL INC.
Fort Collins, Colorado, USA


-------


CH2MHILL

\\chuckwagon\GIS\NWOFiles\TarCreek\MXD\Cadwith_Dep_1_31_06.mxd 1\31\05 S Daigle

008657

LEGEND

Contour (0.5 ppm Intervals)

Site Boundary

Modeled Chat Pile Emission Source
Modeled Tailings Pond Emission Source

Rl Residential Samples
Rl Background Samples
Rural Sampling Sites

N

A

I Miles

0.5

Figure E-6

Tar Creek OU4

Modeled Cadmium Soil Concentrations After 30 Years
Includes Depletion (in ppm)

*AERIAL PHOTOGRAPHY PROVIDED BY:
AATAINTERNATIONAL INC.
Fort Collins, Colorado, USA


-------


CH2MHILL

\\chuckwagon\GIS\NWOFiles\Tar Creel4MXD\Zincwith_Dep_1_31_06.mxd 1\31\05 S Daigle

008658

LEGEND

Contour (5.0 ppm Intervals)

Site Boundary

Modeled Chat Pile Emission Source
Modeled Tailings Pond Emission Source

Rl Residential Samples
Rl Background Samples
Rural Sampling Sites

N

A

I Miles

0.5

Figure E-7

Tar Creek OU4
Cadmium Soil Concentrations After 30 Years
Without Depletion (in ppm)

*AERIAL PHOTOGRAPHY PROVIDED BY:
AATAINTERNATIONAL INC.
Fort Collins, Colorado, USA


-------
flHMpRM

:r'S5H

:;-v	\	*

, .» 1	. '3

Tl:~'V W£i-:- H '

gsL'-SS * . tf """ ¦¦ '¦¦ IV *

-w " •



LEGEND

CH2MHILL

\\chuckwagon\GIS\NWOFiles\TarCreel4MXD\Bird_Dog.mxd 10\6\05 S Daigle

008659

Contour
Site Boundary

Chat Pile

Tailings Pond

N

A

I Miles

0.4

0.8

1.6

FIGURE E-8

Tar Creek OU4

Modeled Ambient Air Concentrations for Lead

*AERIAL PHOTOGRAPHY PROVIDED BY:
AATA INTER NATIONAL INC.
Fort Collins, Colorado, USA


-------
9

CH2MHILL

\\chuckwagon\GIS\NWOFiles\TarCreel4MXD\Bird_Dog.mxd 10\6\05 S Daigle

008660

LEGEND

Contour
Site Boundary

Chat Pile

Tailings Pond

N

A

I Miles

0.4

0.8

1.6

FIGURE E-9

Tar Creek OU4
Modeled Ambient Air Concentrations for Zinc

*AERIAL PHOTOGRAPHY PROVIDED BY:
AATA INTER NATIONAL INC.
Fort Collins, Colorado, USA


-------
0.002
lti£3 0.0015 |

£0.001 gj?

10.0005

0.0005

0.003

0.001

0.0025

0.0015

0.0005

0.002

L_ssS^B
10.004

fi) 0.003

0.0035

0.0025

<'9 i

0.002 f X

0.0005

0.001

0.003

0.0005

0.0015

|m 0.0025

ft 0.002 ¦

0.001

0.0015

0.0005

0.001

0.0015

CH2MHILL

\\chuckwagon\GIS\NWOFiles\Tar Creek\MXD\Bird_Dog.mxd 10\6\05 SDaigle

008661

LEGEND

Contour
Site Boundary

Chat Pile

Tailings Pond

N

A

¦ Miles

0.4

0.8

1.6

FIGURE E-10

Tar Creek OU4

Modeled Ambient Air Concentrations for Cadmium

*AERIAL PHOTOGRAPHY PROVIDED BY:
AATAINTERNATIONAL INC.
Fort Collins, Colorado, USA


-------
Attachment A
Air Modeling Approach

008662


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E: AIR MODELING TM

(This page intentionally left blank.)

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\
APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE.DOC
008663

OCTOBER 2005


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MEMORANDUM

CH2MHILL

Air Modeling Approach for Tar Creek Human Health
Risk Assessment

TO:	Ghassan Khoury

copies:	Scott Irving

Barrie Selcoe

FROM:	Don Caniparoli

DATE:	October 13, 2005

The following summarizes the approach and key assumptions for the Air Modeling analysis
for the Tar Creek Human Health Risk Assessment (HHRA).

General Approach

Air modeling will rely as much as possible on the approach used for the litigation modeling.
Major differences with the modeling include the time period to be modeled, the receptor
area, and the type of modeling. The litigation modeling looked at past emissions while the
HHRA looks at the present (i.e. 1999 - 2003) and future (i.e. 30-year). The litigation
modeling focused on receptors in the populated area corresponding to OU2 while the
HHRA modeling will focus on the rural areas corresponding to OU4. The litigation
modeling included deposition only while the HHRA modeling will include deposition and
concentration. Information from the Draft preliminary Site Characterization Summary Tar
Creek OU4 FJ/FS Program, September 2005, will be used as the basis for much of the data
used in this analysis.

•	Air concentration will be modeled for lead, cadmium, and zinc for the current
conditions which will be assumed to remain at that concentration for 30 years.

•	Deposition will be modeled (for soil concentration) for the future scenario for lead,
cadmium, and zinc for the 30 year period.

•	Presentation information from the litigation modeling, such as the background maps,
will be used to display modeling results for use in the HHRA.

Emissions Sources

•	Modeling will include the 20 chat piles and 10 tailings ponds that were the focus of the
Operable Unit 4 Remedial Investigation conducted by the Respondents. In addition the
Atlas pile will be modeled which is an active area with chat and tailings. Only these
piles and tailings ponds will be modeled and shall be considered representative of OU4.
All other sources will be considered insignificant in comparison to these.

•	Currently active chat piles will be included in the modeling. We believe this to be the
Sooner, Admiralty No. 4 and Atlas piles.

•	Emission from chat piles will include wind erosion sources and active pile sources.
Emissions from the tailings ponds will include only wind erosion sources. Other
sources will include hauling on unpaved roads associated with active pile sources.

TC_HHRA_DRAFTRA_APPENDIXE_ATTACHMENTA.DOC

COPYRIGHT 2005 BY CH2M HILL, INC. • COMPANY CONFIDENTIAL

008664

1


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AIR MODELING APPROACH FOR TAR CREEK HUMAN HEALTH RISK ASSESSMENT

•	Data from all five years of meteorological data will be used to support the emissions
estimates as needed. Wind speed above 12 mph at mean pile height will be averaged
over the 5 year period. Number of days with rainfall greater than 0.01 inches will be
averaged over the 5 year period.

•	Pile heights will be estimated as current mean pile height and will remain constant over
the 30 year evaluation period. Mean pile height will be estimated by taking the base
area and the volume of material from the site characterization report, and assuming a
cone shape.

•	Volume of material processed from active piles on an annual basis will be estimated
from current volumes being removed on a daily basis.

•	The mean sample concentration from samples collected at a source will be used to
estimate emissions.

•	Emissions sources and source configurations will remain constant over the 30 year
period.

•	Emissions will be estimated using the methods developed in the litigation modeling. It
will not be possible to develop a factor based on wind speeds greater than 12 mph.
Instead, emissions will be assumed to occur all hours of the year.

•	Particle density of the soil for emissions estimation purposes will be assumed to be 1.35
mg/l

•	For each of the active chat piles, the distance to the nearest paved road will be calculated
and only the unpaved road portion will be modeled. It is assumed these conditions will
remain constant over the 30 year period.

Modeling Approach

•	As with the litigation modeling, all modeling will use the ISC3 model with the same five
year meteorological data set

•	Physical characteristics of sources will not change over time (e.g. pile heights and source
dimensions) and active piles will be assumed to be constant over the time period.

•	Particle density will be assumed to be 1.35 milligrams per liter (mg/l) unless
information from the current sampling will lead to a more refined understanding
specific to this area.

•	Particle size will be derived from soil samples presented in the site characterization
report. Information on a particular type of source (i.e. chat base, chat pile), will be
averaged and assumed to be representative of all similar source types

•	Unless a more detailed understanding of loading and unloading activities can be
obtained, CH2M HILL will assume emissions from the hauling activities will occur from
the active chat pile to the closest off-site boundary. CH2M HILL assumes that the
activity of each active chat pile is the same.

•	Receptors will be established on a 500 meter grid throughout the site with a 100 meter
grid placed around the sources. No receptors will be placed on the sources.

•	Deposition will be based on constant emissions over the time period but a depletion
factor will be developed based on the EPA hazardous waste combustion facilities
guidance.

TC_HHRA_DRAFTRA_APPENDIXE_ATTACHMENTA.DOC

COPYRIGHT 2005 BY CH2M HILL, INC • COMPANY CONFIDENTIAL

008665

2


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Attachment B
Wind Roses

008666


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E: AIR MODELING TM

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APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE.DOC
008667

OCTOBER 2005


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E ATTACHMENT B

WIND ROSE PLOT

1999 Wind Rose using Miami, OK Hourly Mesonet Data

Wind Speed (m/s)

| DATE

11/13/2004

COMPANY NAME

> 11-°6 I DISPLAY
8.49- 11.06 Wind Speed

UNIT
m/s

5.40-8.49 AVG. WIND SPEED

3.64 m/s

CALM WINDS

7.46%

1.80 - 3.34 I ORIENTATION

Direction
0.51 -1.80 (blowing from)

| PLOT YEAR-DATE-TIME

1999
| Jan 1 - Dec 31
Midnight - 11 PM

PROJECT/PLOT NO.

WRPLOT View 3.5 by Lakes Environmental Software - www.lakes-enuironmental.com

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\

APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE_ATTACHMENTB_1999WINDROSE.DOC
008668

OCTOBER 2005


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E ATTACHMENT B

(This page intentionally left blank.)

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\

APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE_ATTACHMENTB_1999WINDROSE.DOC
008669

OCTOBER 2005


-------
TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E ATTACHMENT B

WIND ROSE PLOT

2000 Wind Rose Using Miami, OK Hourly Mesonet Data

Wind Speed (m/s)

| DATE

11/13/2004

COMPANY NAME

> 11-°6 I DISPLAY
8.49- 11.06 Wind Speed

UNIT
m/s

5.40-8.49 AVG. WIND SPEED

3.67 m/s

CALM WINDS

5.79%

1.80 - 3.34 I ORIENTATION

Direction
0.51 -1.80 (blowing from)

PLOT YEAR-DATE-TIME
2000
| Jan 1 - Dec 31
Midnight - 11 PM

PROJECT/PLOT NO.

WRPLOT View 3.5 by Lakes Environmental Software - www.lakes-enuironmental.com

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\

APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE_ATTACHMENTB_2000WINDROSE.DOC
008670

OCTOBER 2005


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E ATTACHMENT B

(This page intentionally left blank.)

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\

APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE_ATTACHMENTB_2000WINDROSE.DOC
008671

OCTOBER 2005


-------
TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E ATTACHMENT B

WIND ROSE PLOT

2001 Wind Rose Using Miami, OK Hourly Mesonet Data

Wind Speed (m/s)

| DATE

11/13/2004

COMPANY NAME

> 11-°6 I DISPLAY
8.49- 11.06 Wind Speed

UNIT
m/s

5.40-8.49 AVG. WIND SPEED

3.53 m/s

CALM WINDS

7.23%

1.80 - 3.34 I ORIENTATION

Direction
0.51 -1.80 (blowing from)

PLOT YEAR-DATE-TIME
2001
| Jan 1 - Dec 31
Midnight - 11 PM

PROJECT/PLOT NO.

WRPLOT View 3.5 by Lakes Environmental Software - www.lakes-enuironmental.com

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\

APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE_ATTACHMENTB_2001WINDROSE.DOC
008672

OCTOBER 2005


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E ATTACHMENT B

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P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\

APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE_ATTACHMENTB_2001WINDROSE.DOC
008673

OCTOBER 2005


-------
TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E ATTACHMENT B

WIND ROSE PLOT

2002 Wind Rose Using Miami, OK Hourly Mesonet Data

Wind Speed (m/s)

| DATE

11/13/2004

COMPANY NAME

> 11-°6 I DISPLAY
8.49- 11.06 Wind Speed

UNIT
m/s

5.40-8.49 AVG. WIND SPEED

3.57 m/s

| CALM WINDS

3.83%

1.80 - 3.34 I ORIENTATION

Direction
0.51 -1.80 (blowing from)

PLOT YEAR-DATE-TIME
2002
| Jan 1 - Dec 31
Midnight - 11 PM

PROJECT/PLOT NO.

WRPLOT View 3.5 by Lakes Environmental Software - www.lakes-enuironmental.com

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\

APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE_ATTACHMENTB_2002WINDROSE.DOC
008674

OCTOBER 2005


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E ATTACHMENT B

(This page intentionally left blank.)

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\

APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE_ATTACHMENTB_2002WINDROSE.DOC
008675

OCTOBER 2005


-------
TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E ATTACHMENT B

WIND ROSE PLOT

2003 Wind Rose Using Miami, OK Hourly Mesonet Data

Wind Speed (m/s)

| DATE

11/13/2004

COMPANY NAME

> 11-°6 I DISPLAY
8.49- 11.06 Wind Speed

UNIT
m/s

5.40-8.49 AVG. WIND SPEED

3.68 m/s

CALM WINDS

7.12%

1.80 - 3.34 I ORIENTATION

Direction
0.51 -1.80 (blowing from)

PLOT YEAR-DATE-TIME
2003
| Jan 1 - Dec 31
Midnight - 11 PM

PROJECT/PLOT NO.

WRPLOT View 3.5 by Lakes Environmental Software - www.lakes-enuironmental.com

P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\

APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE_ATTACHMENTB_2003WINDROSE.DOC
008676

OCTOBER 2005


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT
APPENDIX E ATTACHMENT B

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P:\USEPA\317950\T7\RA04\DRAFT_2005-1028\APPENDICIES\

APPENDIX E\TC_HHRA_DRAFTRA_APPENDIXE_ATTACHMENTB_2003WINDROSE.DOC
008677

OCTOBER 2005


-------
Appendix F

Modeled Biota Concentrations Using BCFs

008678


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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

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USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
008679

FEBRUARY 2006


-------
Table 7.4.RME Supplement A

Estimation of Chemical Concentrations in Small Game (Bird and Rabbit)
Tar Creek, Miami, OK

Small Mammal

Chemical

Soil Concentration
(mg/kg)1

Soil-Small Mammal
Accumulation Factor
(BAF)2

Measure

Concentration in
Small Mammal dty
(mg/kg)

Concentration in
Small Mammal wet
(mg/kg)3

Cadmium

2.74E+01

6.96E+01

Insectivorous & generalist mammal

1.91E+03

6.10E+02

Lead

4.41 E+02

2.66E+00

Insectivorous & general ist mammal

1.17E+03

3.75E+02

Zinc

5.39E+03

1.64E+01

Herbivorous & generalist mammal

8.82E+04

2.82E+04

Notes:

1	Soil Exposure Point Concentrations are based on 95% UCL of the mean (see Table 3.2).

2	BAFs are obtained from Sample et al. 1998.

3	Wet Weight based concentrations are estimated assuming a 68% water content (EPA, 1993).
mg/kg = Milligrams per kilogram.

Equation:

Concentration in Small Mammal = Soil Concentration x BAF

Reference:

Sample, B. E., J. J. Beauchamp, R. A. Efroymson and G. W. Suter. 1998b. Development and validation of bioaccumulation models for small mammals.
Oak Ridge, TN: Lockheed Martin Corp.

EPA (U.S. Environmental Protection Agency). 1993. Wildlife Exposure Factors Handbook, Volume I,

EPA/600/R-93/187a, Office of Research and Development, Washington, D.C.

TC_HHRA_DraftFinalRA_AppendixF_Revised_RAGS-D_Table7.4.xls (SmallGame-Rev)
Revised 02/09/2006	1 of 1	02/09/2006 12:34 PM

008680


-------
Table 7.4.RME Supplement B

Estimation of Chemical Concentrations in Beef and Milk (dairy)
Tar Creek, Miami, OK

Beef and Milk



Soil Exposure















Point

BTF for

Concentration





Concentration in

Concentration in



Concentration

Forage

in Forage

BTF for Beef

BTF for Milk

Beef

Milk

Chemical

(Cs)1

(Brforaqe)

(Pr)

(Babeef)

(Bami|k)

(Abeef)

(Amilk)

Cadmium

2.74E+01

3.64E-01

1.0E+01

1.2E-04

6.5E-06

1.27E-02

6.90E-04

Lead

4.41 E+02

4.50E-02

2.0E+01

3.0E-04

2.5E-04

1.21E-01

1.01E-01

Zinc

5.39E+03

2.50E-01

1.3E+03

9.0E-05

3.3E-05

1.37E+00

4.94E-01

Notes:

1 Soil Exposure Point Concentrations are based on 95% UCL of the mean (see Table 3.2).

Equations:

Abeef = [S (Fi x Qpi x Pr) + Qs x Cs x Bs ] x Babeef x MF
Amilk = [S (Fi x Qpi x Pr) + Qs x Cs x Bs ] x Bamilk x MF
Pr = Cs x Br

where:

Abeef	Concentration in beef (mg/kg FW tissue)

Amiik	Concentration in milk (mg/kg milk)

Pr	Concentration in forage due to root uptake (mg/kg)

Fj	Fraction of forage grown on contaminated soil and ingested by the animal (cattle) (unitless)

QPi	Quantity of forage eaten by the animal (cattle) per day (kg DW plant/day)

Pj	Concentration in each plant type I eaten by the animal (cattle) (mg/kg DW)

Qs	Quantity of soil eaten by the animal (cattle) each day (kg/day)

Cs	Average soil concentration over exposure duration (mg/kg)

Bs	Soil bioavailability factor (unitless)

Babeef	Biotransfer factor for beef (day/kg FW tissue)

Bami|k	Biotransfer factor for milk (day/kg WW tissue)

MF	Metabolism factor (unitless)

B^forage	Plant-soil bioconcentration factor for forage (unitless)

Equations and input	parameters are obtained from EPA, 2005.

References:

EPA, 2005: Human Health Risk Assessment Protocol for Hazardous Waste Combustion Facilities.

Calculated

Calculated

1

9.27

Calculated

0.5

EPC (Table 3.2)
1

(see above)
(see above)
1

(see above)

TC_HHRA_DraftFinalRA_AppendixF_Revised_RAGS-D_Table7.4.xls (BeefMilk-Rev)
Revised 02/09/2006	1 of 1	02/09/2006 12:35 PM

008681


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Table 7.4.RME Supplement C

Concentrations Used to Estimate Chemical Intake Through Ingestion of Locally Caught Fish
Tar Creek, Miami, OK

Fish (All sample preparations)1

Chemical

Data Set Used
for the
Analysis

Number of
Detection

Number of
Analysis

Minimum
Detected
Concentration
(mg/kg)

Maximum
Detected
Concentration
(mg/kg)

Mean
Concentration
(mg/kg)2

Cadmium

All

5

77

0.30

0.84

0.17

Lead

All

28

75

0.25

3.50

0.43

Zinc

All

77

77

3.50

70.0

21.3

Notes:

1	All Sample Preparations (Fillet, Whole-eviscerated, Whole-uneviscerated)

2	The Average Concentrations were used as exposure point concentrations,
mg/kg = Milligrams per kilogram.

Reference:

Fish Tissue Metals Analysis in the Tri-State Mining Area FY 2003 Final Report (Oklahoma DEQ, 2003).

008682


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Table 7.4.RME Supplement D

Estimation of Chemical Concentrations in Aquatic Food using Log-linear Regression Models for Bioaccumulation Factors
Tar Creek, Miami, OK

Aquatic Biota (Invertebrate)

Chemical

Data Set Used for
the Analysis

Sediment
Concentration^
(mg/kg)1'2

Sediment
Concentration^
(mg/kg)3

B0

B1

Concentration in
Aquatic Biotadry
(mg/kg)

Concentration in
Aquatic Biota wet
(mg/kg)4

Cadmium

All

4.0E+00

1.0E+01

0.0395

0.692

5.39E+00

1.62E+00

Lead

All

2.9E+01

7.3E+01

-0.776

0.801

5.18E+00

1.55E+00

Zinc

All

3.6E+02

9.1E+02

1.80

0.208

2.60E+02

7.81 E+01

Notes:

1	Sediment Concentrations were obtained from ODEQ, 2003.

2	The Average Detected Concentrations were used.

3	Wet Weight based concentrations are estimated assuming a 40% water content.

4	Wet Weight based concentrations are estimated assuming a 70% water content,
mg/kg = Milligrams per kilogram.

Equation:

Log (Concentration in aquatic biota - dry weight) = B1*(log[Site Specific Sediment Concentration - dry weight]) + BO
where:

BO = Intercept.

B1 = Slope.

References:

Bechtel Jacobs, 1998b. Biota Sediment Accumulation Factors for Invertebrates: Review and Recommendations for the Oak Ridge
Reservation. Prepared for the US Department of Energy Office of Environmental Management. BJC/OR-112. August, 1998.

Fish Tissue Metals Analysis in the Tri-State Mining Area FY 2003 Final Report (Oklahoma DEQ, 2003).

TC_HHRA_DraftFinalRA_AppendixF_Revised_RAGS-D_Table7.4.xls (AquaInvert-Rev)
Revised 02/09/2006	1 of 1	02/09/2006 12:35 PM

008683


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Appendix G
IEUBK Modeling

008684


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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

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008685

FEBRUARY 2006


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Table G Neighborhood-Level Blood Lead Level

Estimate (from IEUBK Model)

008686


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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

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Table G

Neighborhood-Level Blood Lead Level Estimate (from IEUBK Model)
Tar Creek, Miami, OK



Exposure Point Concentrations

IEUBK Model Results

Resident

Modeled Air
Concentration
(ug/m3)

Average Measured
Soil Concentration
(mg/kg)

Average Measured
Groundwater
Concentration
(uq/L)

Statistical Weight

Geo Mean

%Above

1

0.000524

29.6

4(1)

1

1.770

0.011

2

0.000514

31.6

4(1)

1

1.789

0.013

3**

0.000374

29.1

4(1)

1

1.765

0.011

4

0.00044

54.3

4(1)

1

2.003

0.031

5**

0.00042

88.4

0.417

1

2.043

0.036

6

0.003132

34.6

4(1)

1

1.819

0.014

7

0.004144

109

4(1)

1

2.515

0.166

8

0.00163

45.4

4(1)

1

1.921

0.022

9

0.000184

53.3

4(1)

1

1.995

0.030

10

0.00024

44.3

4(1)

1

1.909

0.021

11

0.000242

71

4(1)

1

2.160

0.056

12

0.000158

24.5

4(1)

1

1.721

0.009

13

0.00016

56

4(1)

1

2.020

0.033

14

0.000242

194

4(1)

1

3.280

0.885

15

0.000246

28.8

26.2

1

3.455

1.187

16

0.000268

24

0.85

1

1.464

0.002

17

0.004718

202

4(1)

1

3.352

1.002

18

0.005252

86.3

4(1)

1

2.307

0.090

19

0.001864

17.3

4(1)

1

1.654

0.006

20

0.000278

61.3

4(1)

1

2.069

0.040

21

0.008134

53.8

4(1)

1

2.005

0.031

22

0.001678

54.1

4(1)

1

2.003

0.031

23

0.000444

45.2

4(1)

1

1.918

0.022

24

0.000172

25.3

4(1)

1

1.728

0.009

25

0.000522

18.4

4(1)

1

1.663

0.007

26

0.000424

404.8

4(1)

1

5.061

7.365

27

0.000176

46.8

4(1)

1

1.932

0.023

28

0.000176

72.3

4(1)

1

2.172

0.058

29

0.000506

32.5

4(1)

1

1.798

0.013

30

0.000498

20.2

4(1)

1

1.680

0.007

31

0.000396

86.8

4(1)

1

2.307

0.090

32

0.000396

64

4(1)

1

2.095

0.044

33

0.00328

19.8

4(1)

1

1.679

0.007

34

0.002492

106.9

4(1)

1

2.494

0.157

35

0.003062

63.4

4(1)

1

2.092

0.044

36

0.000334

24.5

4(1)

1

1.721

0.009

38

0.001428

235.8

4(1)

1

3.645

1.588

39

0.002348

491

4(1)

1

5.749

11.943

40

0.004342

348

4(1)

1

4.599

4.919

41

0.004562

643.3

4(1)

1

6.910

21.578

42

0.000312

39

4(1)

1

1.859

0.017

43

0.000864

12.6

4(1)

1

1.608

0.005

44

0.000882

41.9

4(1)

1

1.887

0.019

45

0.000442

90.8

4(1)

1

2.345

0.101

46

0.000446

32.3

4(1)

1

1.795

0.013

GW1

0.000462

171 (2)

1.77

1

2.903

0.425

GW2

0.00019

171 (2)

2.85

1

2.984

0.505

GW3

0.000176

171 (2)

1.35

1

2.871

0.397

GW5

0.00018

171 (2)

0.125

1

2.779

0.322

GW8

0.000258

171 (2)

12.7

1

3.711

1.748

GW11

0.000998

171 (2)

0.65

1

2.819

0.353

Total







51



1.09

Note:

** Resident on BIA land

I Exceeds the blood lead goal as described in the 1994 OSWER.

Directive of no more than 5% of children exceeding 10 ug/dL blood lead.

(1)	Default concentration of 4 ug/L was used for those residents without groundwater samples.

(2)	Average lead concentration of 46 residential yards (171 mg/kg; including the former smelter home) used for those homes without soil samples.

008688


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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

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008689

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RAGS DIEUBK Lead Worksheet

008690


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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

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USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
008691

FEBRUARY 2006


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TABLE G-l (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Resl, 61500 E. 57 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

29.625

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000524

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 61500 E. 57 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 29.6 mg/kg in soil and 0.000524 ug/m3 in
ambient air results in 0.011° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 1.770 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

Res1

008692


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TABLE G-2 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_2,51496 E. 57 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

31.64

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000514

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 51496 E. 57 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 31.64 mg/kg in soil and 0.000514 ug/m3
in ambient air results in 0.013° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level =1.789 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008693


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TABLE G-3 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_3,5671 S. 630 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

29.075

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000374

ug/m3

Modeled from Sources

NA

Milk

1.01

ug/kg

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 263 (December, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G 

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not sieved,
provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 5671 S. 630 Rd.

Where are the output values located in the risk assessment report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.
The updated dietary lead intake estimates from FDA dietary data were
used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input values of 29.07 mg/kg in soil, 0.000374 ug/m3 in
ambient air, and 1.01 mg/kg in milk result in 0.006% of
subsistence children above a blood lead level of 10 ug/dL.
The geometric mean blood lead level = 1.638 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5% of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008694


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TABLE G-4 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_4,62301 E. 57 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

54.25

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.00044

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 62301 E. 57 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 54.25 mg/kg in soil and 0.00044 ug/m3 in
ambient air results in .031° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.003 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008695


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TABLE G-5/GW12 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_5,4200 S. 620 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

88.4

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

0.417

ug/L

Avg Measured at Well

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.00042

ug/m3

Modeled from Sources

NA

Milk

1.01

ug/kg

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 263 (December, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G 

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not sieved,
provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 4200 S. 620 Rd.

Where are the output values located in the risk assessment report?

Appendix G.

Was the model run using default values only?

No; measured soil and groundwater and modeled ambient air and milk
concentrations were used. The updated dietary lead intake estimates
from FDA dietary data were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input values of 88.4 mg/kg in soil, 0.4167 ug/L in
groundwater, 0.00042 ug/m3 in ambient air, and 1.01
mg/kg in milk result in 0.022% of subsistence children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 1.918 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5% of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008696


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TABLE G-6 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_6, 54801 E. 30 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

34.55

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.003132

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 54801 E. 30 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 34.55 mg/kg in soil and 0.003132 ug/m3
in ambient air results in 0.014° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 1.819 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008697


-------
TABLE G-7 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_7, 2811 S. 550 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

109

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.004144

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 2811 S. 550 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 109 mg/kg in soil and 0.004144 ug/m3 in
ambient air results in 0.166% of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.515 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008698


-------
TABLE G-8 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_8,54501 E. 40 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

45.44

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.00163

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 54501 E. 40 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 45.44 mg/kg in soil and 0.00163 ug/m3 in
ambient air results in 0.022° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 1.921 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008699


-------
TABLE G-9 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_9,63040 E. 16 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

53.333333

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000184

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63040 E. 16 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 53.33 mg/kg in soil and 0.000184 ug/m3
in ambient air results in 0.030° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 1.995 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008700


-------
TABLE G-10 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (ReslO, 63470 E. 40 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

44.25

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.00024

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63470 E. 40 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 44.25 mg/kg in soil and 0.00024 ug/m3 in
ambient air results in 0.021% of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 1.909 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008701


-------
TABLE G-ll (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Resll, 63430 E. 40 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

71

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000242

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63430 E. 40 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 71 mg/kg in soil and 0.000242 ug/m3 in
ambient air results in 0.056° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.160 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008702


-------
TABLE G-12 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_12, 63401 E. 10 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

24.5

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000158

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63401 E. 10 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 24.5 mg/kg in soil and 0.000158 ug/m3 in
ambient air results in 0.009° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 1.721 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008703


-------
TABLE G-13 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_13, 63501 E. 10 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

56

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.00016

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63501 E. 10 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 56 mg/kg in soil and 0.00016 ug/m3 in
ambient air results in 0.033° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.020 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008704


-------
TABLE G-14 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_14, 63451 E. 40 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

194.25

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000242

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63451 E. 40 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 194.25 mg/kg in soil and 0.000242 ug/m3
in ambient air results in 0.885° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 3.280 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008705


-------
TABLE G-15 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_15,63400 E. 40 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

28.75

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

26.15

ug/L

Avg Measured at Well

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000246

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63400 E. 40 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 28.75 mg/kg in soil, 26.15 ug/L of
groundwater concentration, and 0.000246 ug/m3 in
ambient air results in 1.187% of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 3.455 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008706


-------
TABLE G-16 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_16, 63150 E. 40 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

24

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

0.85

ug/L

Avg Measured at Well

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000268

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63150 E. 40 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 24 mg/kg in soil, 0.85 ug/L of
groundwater concentration, and 0.000268 ug/m3 in
ambient air results in 0.002° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 1.464 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008707


-------
TABLE G-17 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_17,2501 S. 550 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

202

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.004718

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 2501 S. 550 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 202 mg/kg in soil and 0.004718 in
ambient air results in 1.002° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 3.352 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008708


-------
TABLE G-18 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_18, 2601 S. 550 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

86.3

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.005252

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 2601 S. 550 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 86.3 mg/kg in soil and 0.005252 ug/m3 in
ambient air results in 0.090° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.307 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008709


-------
TABLE G-19 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_19,54600 E. 40 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

17.325

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.001864

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 54600 E. 40 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 17.325 mg/kg in soil and 0.001864 ug/m3
in ambient air results in 0.006° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 1.654 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008710


-------
TABLE G-20 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_20,3800 S. 630 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

61.25

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000278

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 3800 S. 630 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 61.25 mg/kg in soil and 0.000278 ug/m3
in ambient air results in 0.040° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 2.069 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008711


-------
TABLE G-21 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_21,2300 S. 590 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

53.8

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.008134

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 2300 S. 590 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 53.8 mg/kg in soil and 0.008134 ug/m3 in
ambient air results in 0.031° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.005 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008712


-------
TABLE G-22 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_22, 59505 E. 40 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

54.075

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.001678

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 59505 E. 40 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 54.07 mg/kg in soil and 0.001678 ug/m3
in ambient air results in 0.031° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 2.003 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008713


-------
TABLE G-23 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_23, 62401 E. 50 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

45.233333

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000444

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 62401 E. 50 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 45.23 mg/kg in soil and 0.000444 ug/m3
in ambient air results in 0.022° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 1.918 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008714


-------
TABLE G-24 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_24, 63450 E. 30 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

25.25

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000172

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63450 E. 30 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 25.25 mg/kg in soil and 0.000172 ug/m3
in ambient air results in 0.009° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 1.728 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008715


-------
TABLE G-25 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_25,5301 S. 620 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

18.4

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000522

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 5301 S. 620 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 18.4 mg/kg in soil and 0.000522 ug/m3 in
ambient air results in 0.007° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 1.663 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008716


-------
TABLE G-26 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_26,4990 S. 620 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

404.75

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000424

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 4990 S. 620 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 404.75 mg/kg in soil and 0.000424 ug/m3
in ambient air results in 7.365° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 5.061 ug/dL. This
exceeds the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a PRG of 500 ppm is indicated for
soil for this receptor.

008717


-------
TABLE G-27 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_27, 63349 E. 16 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

46.75

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000176

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63349 E. 16 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 46.75 mg/kg in soil and 0.000176 ug/m3
in ambient air results in 0.023° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 1.932 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008718


-------
TABLE G-28 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_28, 63350 E. 16 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

72.25

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000176

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63350 E. 16 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 72.25 mg/kg in soil and 0.000176 ug/m3
in ambient air results in 0.058° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 2.172 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008719


-------
TABLE G-29 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_29,5401 S. 620 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

32.5

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000506

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 5401 S. 620 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 32.5 mg/kg in soil and 0.000506 ug/m3 in
ambient air results in 0.013% of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 1.798 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008720


-------
TABLE G-30 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_30, 5401 S. 620 Rd. (trailer))
Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

20.2

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000498

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 5401 S. 620 Rd. (trailer)

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 20.2 mg/kg in soil and 0.000498 ug/m3 in
ambient air results in 0.007° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 1.680 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008721


-------
TABLE G-31 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_31, 62610 E. 60 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

86.75

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000396

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 62610 E. 60 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 86.75 mg/kg in soil and 0.000396 ug/m3
in ambient air results in 0.090° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 2.307 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008722


-------
TABLE G-32 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_32, 62612 E. 60 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

64

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000396

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 62612 E. 60 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 64 mg/kg in soil and 0.000396 ug/m3 in
ambient air results in 0.044° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.095 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008723


-------
TABLE G-33 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_33,3195 S. 550 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

19.8

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.00328

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 3195 S. 550 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 19.8 mg/kg in soil and 0.00328 ug/m3 in
ambient air results in 0.007° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 1.679 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008724


-------
TABLE G-34 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_34, 56600 E. HWY 69 )

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

106.85

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.002492

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 56600 E. HWY 69

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 106.85 mg/kg in soil and 0.002494 ug/m3
in ambient air results in 0.157% of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 2.494 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008725


-------
TABLE G-35 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_35, 56600 E. HWY 69 )

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

63.433333

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.003062

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 56600 E. HWY 69

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 63.43 mg/kg in soil and 0.003062 ug/m3
in ambient air results in 0.044° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 2.092 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008726


-------
TABLE G-36 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_36, 3750 E. 40 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

24.5

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000334

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 3750 E. 40 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 24.5 mg/kg in soil and 0.000334 ug/m3 in
ambient air results in 0.009° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 1.721 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008727


-------
TABLE G-37 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_37, 61210 E. 20 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

7470

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000486

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 61210 E. 20 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 7470 mg/kg in soil and 0.000486 ug/m3
in ambient air results in 99.536° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 33.962 ug/dL. This
exceeds the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a PRG of 500 ppm is indicated for
soil for this receptor. The model has not been validated at
these levels of environmental exposures.

008728


-------
TABLE G-38 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_38, 55200 E. 50 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

235.75

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.001428

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 55200 E. 50 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 235.75 mg/kg in soil and 0.001428 ug/m3
in ambient air results in 1.588% of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 3.645 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008729


-------
TABLE G-39 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_39, 57995 E. 40 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

491

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.002348

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 57995 E. 40 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 491 mg/kg in soil and 0.002348 ug/m3 in
ambient air results in 11.943% of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 5.749 ug/dL. This
exceeds the blood lead goal as described in the 1994
OSWER Directive of no more than 5% of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a PRG of 500 ppm is indicated for
soil for this receptor.

008730


-------
TABLE G-40 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_40, 56801 E. 20 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

348

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.004342

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 56801 E. 20 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 348 mg/kg in soil and 0.004342 ug/m3 in
ambient air results in 4.919% of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 4.599 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008731


-------
TABLE G-41 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_41, 56900 E. 20 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

643.33333

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.004562

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 56900 E. 20 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 643.33 mg/kg in soil and 0.004562 ug/m3
in ambient air results in 21.578% of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 6.910 ug/dL. This
exceeds the blood lead goal as described in the 1994
OSWER Directive of no more than 5% of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a PRG of 500 ppm is indicated for
soil for this receptor.

008732


-------
TABLE G-42 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_42, 62350 E. 30 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

39

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000312

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 62350 E. 30 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 39 mg/kg in soil and 0.000312 ug/m3 in
ambient air results in 0.017% of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 1.859 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008733


-------
TABLE G-43 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_43,6800 S. 572 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

12.64

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Avg Measured at Yard

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000864

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 6800 S. 572 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 12.64 mg/kg in soil and 0.000864 ug/m3
in ambient air results in 0.005° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 1.608 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008734


-------
TABLE G-44 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_44,6751 S. 572 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

41.853125

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000882

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 6751 S. 572 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 41.85 mg/kg in soil and 0.000882 ug/m3
in ambient air results in 0.019° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 1.887 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008735


-------
TABLE G-45 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_45,4671 S. 620 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

90.8

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000442

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 4671 S. 620 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 90.8 mg/kg in soil and 0.000442 ug/m3 in
ambient air results in 0.101% of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.345 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008736


-------
TABLE G-46 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_46,4631 S. 620 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

32.25

mg/kg

Avg Measured at Yard

400

mg/kg

Recommended Soil Screening
Level

Water

4 (default)

ug/L

Default

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000446

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 4631 S. 620 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 32.25 mg/kg in soil and 0.000446 ug/m3
in ambient air results in 0.013° o of general public
children above a blood lead level of 10 ug/dL. The
geometric mean blood lead level = 1.795 ug/dL. This
meets the blood lead goal as described in the 1994
OSWER Directive of no more than 5°o of children
exceeding 10 ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008737


-------
TABLE G-47 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (GW1,5709 S. 620 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

170.69

mg/kg

Avg Measured at 46 Yards

400

mg/kg

Recommended Soil Screening
Level

Water

1.767

ug/L

Avg Measured at Well

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000462

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 5709 S. 620 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 170.69 mg/kg in soil, 1.767 ug/L of
groundwater concentration, and 0.000462 ug/m3 in
ambient air results in 0.425° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.903 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008738


-------
TABLE G-48 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (GW2, 22099 E. 30 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

170.69

mg/kg

Avg Measured at 46 Yards

400

mg/kg

Recommended Soil Screening
Level

Water

2.85

ug/L

Avg Measured at Well

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.00019

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 22099 E. 30 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 170.69 mg/kg in soil, 2.850 ug/L of
groundwater concentration, and 0.00019 ug/m3 in
ambient air results in 0.505° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.984 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008739


-------
TABLE G-49 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (GW3, 63500 E. 30 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

170.69

mg/kg

Avg Measured at 46 Yards

400

mg/kg

Recommended Soil Screening
Level

Water

1.35

ug/L

Avg Measured at Well

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000176

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63500 E. 30 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 170.69 mg/kg in soil, .1.350 ug/L of
groundwater concentration, and 0.000176 ug/m3 in
ambient air results in 0.397% of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.871 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5% of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008740


-------
TABLE G-50 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (GW5, 63601 E. 30 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

170.69

mg/kg

Avg Measured at 46 Yards

400

mg/kg

Recommended Soil Screening
Level

Water

0.125

ug/L

Avg Measured at Well

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.00018

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63601 E. 30 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 170.69 mg/kg in soil, 0.125 ug/L of
groundwater concentration, and 0.00018 ug/m3 in
ambient air results in 0.322° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.779 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008741


-------
TABLE G-51 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (GW8, 63300 E. 40 Rd.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

170.69

mg/kg

Avg Measured at 46 Yards

400

mg/kg

Recommended Soil Screening
Level

Water

12.683

ug/L

Avg Measured at Well

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000258

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 63300 E. 40 Rd.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 170.69 mg/kg in soil, 12.683 ug/L of
groundwater concentration, and 0.000258 ug/m3 in
ambient air results in 1.748° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 3.711 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008742


-------
TABLE G-52 (RAGS D IEUBK LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (GW11, 201 S. Canary Ln.)

Receptor: Current Residential Child (Age 0 to 84 Months) Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
Used in Model Run

Basis for Lead
Concentration Used
For Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

170.69

mg/kg

Avg Measured at 46 Yards

400

mg/kg

Recommended Soil Screening
Level

Water

0.65

ug/L

Avg Measured at Well

15

ug/L

Recommended Drinking Water
Action Level

Ambient Air

0.000998

ug/m3

Modeled from Sources

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model (version and date) was used?

IEUBKwin vl.O build 262 (September, 2005) 32-bit version

Where are the input values located in the risk assessment report?

Appendix G dEUBKwin OUTPUT>

What range of media concentrations were used for the model?

Refer to RAGS D Table 2.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean value of exposure area; data presented in Appendix
G.

Was soil sample taken from top 2 cm? If not, why?

Yes.

Was soil sample sieved? What size screen was used? If not
sieved, provide rationale.

Yes, 250 microns.

What was the point of exposure/location?

Residential yard at 201 S. Canary Ln.

Where are the output values located in the risk assessment
report?

Appendix G.

Was the model run using default values only?

No; measured soil and modeled ambient air concentrations were used.

Was the default soil bioavailability used?

Yes.

Was the default soil ingestion rate used?

Yes.

If non-default values were used, where are the rationale for the
values located in the risk assessment report?

Appendix G.

3. Final Result

Medium

Result

Comment/PRG 1

Soil

Input value of 170.69 mg/kg in soil, 0.650 ug/L of
groundwater concentration, and 0.000998 ug/m3 in
ambient air results in 0.353° o of general public children
above a blood lead level of 10 ug/dL. The geometric
mean blood lead level = 2.819 ug/dL. This meets the
blood lead goal as described in the 1994 OSWER
Directive of no more than 5° o of children exceeding 10
ug/dL blood lead.

Based on site conditions, a soil lead PRG is not needed for this
receptor.

008743


-------
Lead Models

008744


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
008745

FEBRUARY 2006


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 01
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.001

1-2

2.000

3.000

32.000

0.001

2-3

3.000

5.000

32.000

0.001

3-4

4.000

5.000

32.000

0.001

4-5

4.000

5.000

32.000

0.001

5-6

4.000

7.000

32.000

0.001

6-7

4.000

7.000

32.000

0.001

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res01	10/31/2005 2:14 PM

008746


-------
Average multiple source concentration: 20.790 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

29.625

20.790

1-2

29.625

20.790

2-3

29.625

20.790

3-4

29.625

20.790

4-5

29.625

20.790

5-6

29.625

20.790

6-7

29.625

20.790

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.653

0.000

0.384

1-2

0.000

2.774

0.000

0.960

2-3

0.000

3.125

0.000

1.001

3-4

0.000

3.023

0.000

1.027

4-5

0.000

2.929

0.000

1.072

5-6

0.000

3.096

0.000

1.133

6-7

0.000

3.420

0.000

1.153

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.606

3.643

2.0



1-2

0.963

4.697

2.0



2-3

0.966

5.093

1.9



3-4

0.972

5.021

1.8



4-5

0.724

4.725

1.6



5-6

0.653

4.883

1.5



6-7

0.617

5.191

1.4



Res01	10/31/2005 2:14 PM

008747


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 02
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.001

1-2

2.000

3.000

32.000

0.001

2-3

3.000

5.000

32.000

0.001

3-4

4.000

5.000

32.000

0.001

4-5

4.000

5.000

32.000

0.001

5-6

4.000

7.000

32.000

0.001

6-7

4.000

7.000

32.000

0.001

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res02	10/31/2005 2:14 PM

008748


-------
Average multiple source concentration: 22.199 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

31.640

22.199

1-2

31.640

22.199

2-3

31.640

22.199

3-4

31.640

22.199

4-5

31.640

22.199

5-6

31.640

22.199

6-7

31.640

22.199

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.652

0.000

0.384

1-2

0.000

2.772

0.000

0.959

2-3

0.000

3.123

0.000

1.001

3-4

0.000

3.021

0.000

1.026

4-5

0.000

2.928

0.000

1.072

5-6

0.000

3.095

0.000

1.133

6-7

0.000

3.420

0.000

1.153

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.647

3.682

2.0



1-2

1.028

4.760

2.0



2-3

1.031

5.156

1.9



3-4

1.037

5.085

1.8



4-5

0.773

4.773

1.6



5-6

0.697

4.926

1.5



6-7

0.659

5.232

1.5



Res02	10/31/2005 2:14 PM

008749


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 263
User Name: Hiroshi Awata
Date: 02/01/2006
Site Name: Tar Creek

Operable Unit: Operable Unit 4, Resident 03
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** yyj p ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.

Other Air Parameters:

Age Time Ventilation Lung Outdoor Air



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

3.160

1-2

2.600

2-3

2.870

3-4

2.740

4-5

2.610

5-6

2.740

6-7

2.990

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L

****** Soil & Dust ******

Multiple Source Analysis Used

Average multiple source concentration: 20.390 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700

008750


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 263
User Name: Hiroshi Awata
Date: 02/01/2006
Site Name: Tar Creek

Operable Unit: Operable Unit 4, Resident 03
Run Mode: Site Risk Assessment

Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

29.075

20.390

1-2

29.075

20.390

2-3

29.075

20.390

3-4

29.075

20.390

4-5

29.075

20.390

5-6

29.075

20.390

6-7

29.075

20.390

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

2.580

1-2

2.540

2-3

2.520

3-4

2.490

4-5

2.460

5-6

2.430

6-7

2.410

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

1.515

1.237

0.383

1-2

0.000

1.251

1.222

0.963

2-3

0.000

1.387

1.218

1.005

3-4

0.000

1.331

1.210

1.030

4-5

0.000

1.275

1.202

1.075

5-6

0.000

1.342

1.190

1.136

6-7

0.000

1.466

1.182

1.157

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.594

3.729

2.0



1-2

0.947

4.384

1.9



2-3

0.951

4.563

1.7



3-4

0.956

4.528

1.6



4-5

0.712

4.264

1.5



008751


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 263
User Name: Hiroshi Awata
Date: 02/01/2006
Site Name: Tar Creek

Operable Unit: Operable Unit 4, Resident 03
Run Mode: Site Risk Assessment

5-6	0.643	4.311	1.3

6-7	0.608	4.413	1.3

008752


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 04
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res04	10/31/2005 2:14 PM

008753


-------
Average multiple source concentration: 38.019 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

54.250

38.019

1-2

54.250

38.019

2-3

54.250

38.019

3-4

54.250

38.019

4-5

54.250

38.019

5-6

54.250

38.019

6-7

54.250

38.019

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.639

0.000

0.382

1-2

0.000

2.755

0.000

0.953

2-3

0.000

3.107

0.000

0.996

3-4

0.000

3.008

0.000

1.022

4-5

0.000

2.919

0.000

1.069

5-6

0.000

3.088

0.000

1.130

6-7

0.000

3.413

0.000

1.151

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.103

4.123

2.3



1-2

1.750

5.459

2.3



2-3

1.757

5.860

2.2



3-4

1.769

5.799

2.1



4-5

1.321

5.309

1.8



5-6

1.192

5.411

1.7



6-7

1.127

5.691

1.6



Res04	10/31/2005 2:14 PM

008754


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 263
User Name: Hiroshi Awata
Date: 02/01/2006
Site Name: Tar Creek

Operable Unit: Operable Unit 4, Resident 05
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** yyj p ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.

Other Air Parameters:

Age Time Ventilation Lung Outdoor Air



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

3.160

1-2

2.600

2-3

2.870

3-4

2.740

4-5

2.610

5-6

2.740

6-7

2.990

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 0.420 ug Pb/L

****** Soil & Dust ******

Multiple Source Analysis Used

Average multiple source concentration: 61.922 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700

008755


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 263
User Name: Hiroshi Awata
Date: 02/01/2006
Site Name: Tar Creek

Operable Unit: Operable Unit 4, Resident 05
Run Mode: Site Risk Assessment

Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

88.400

61.922

1-2

88.400

61.922

2-3

88.400

61.922

3-4

88.400

61.922

4-5

88.400

61.922

5-6

88.400

61.922

6-7

88.400

61.922

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

2.580

1-2

2.540

2-3

2.520

3-4

2.490

4-5

2.460

5-6

2.430

6-7

2.410

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

1.500

1.225

0.040

1-2

0.000

1.240

1.211

0.100

2-3

0.000

1.377

1.209

0.105

3-4

0.000

1.323

1.202

0.107

4-5

0.000

1.272

1.199

0.113

5-6

0.000

1.340

1.188

0.119

6-7

0.000

1.465

1.181

0.121

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.788

4.553

2.5



1-2

2.853

5.404

2.3



2-3

2.870

5.561

2.1



3-4

2.888

5.521

2.0



4-5

2.159

4.742

1.7



008756


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 263
User Name: Hiroshi Awata
Date: 02/01/2006
Site Name: Tar Creek

Operable Unit: Operable Unit 4, Resident 05
Run Mode: Site Risk Assessment

5-6	1.950	4.597	1.5

6-7	1.845	4.612	1.3

008757


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 06
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.003

1-2

2.000

3.000

32.000

0.003

2-3

3.000

5.000

32.000

0.003

3-4

4.000

5.000

32.000

0.003

4-5

4.000

5.000

32.000

0.003

5-6

4.000

7.000

32.000

0.003

6-7

4.000

7.000

32.000

0.003

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res06	10/31/2005 2:14 PM

008758


-------
Average multiple source concentration: 24.498 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

34.550

24.498

1-2

34.550

24.498

2-3

34.550

24.498

3-4

34.550

24.498

4-5

34.550

24.498

5-6

34.550

24.498

6-7

34.550

24.498

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.001

2.650

0.000

0.383

1-2

0.001

2.770

0.000

0.959

2-3

0.002

3.121

0.000

1.000

3-4

0.002

3.019

0.000

1.026

4-5

0.002

2.927

0.000

1.071

5-6

0.003

3.094

0.000

1.132

6-7

0.003

3.419

0.000

1.153

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.709

3.743

2.1



1-2

1.127

4.856

2.1



2-3

1.131

5.254

1.9



3-4

1.137

5.185

1.8



4-5

0.848

4.848

1.7



5-6

0.765

4.995

1.5



6-7

0.723

5.297

1.5



Res06	10/31/2005 2:14 PM

008759


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 07
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.004

1-2

2.000

3.000

32.000

0.004

2-3

3.000

5.000

32.000

0.004

3-4

4.000

5.000

32.000

0.004

4-5

4.000

5.000

32.000

0.004

5-6

4.000

7.000

32.000

0.004

6-7

4.000

7.000

32.000

0.004

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res07	10/31/2005 2:14 PM

008760


-------
Average multiple source concentration: 76.714 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

109.000

76.714

1-2

109.000

76.714

2-3

109.000

76.714

3-4

109.000

76.714

4-5

109.000

76.714

5-6

109.000

76.714

6-7

109.000

76.714

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.001

2.607

0.000

0.377

1-2

0.001

2.715

0.000

0.939

2-3

0.003

3.068

0.000

0.983

3-4

0.003

2.975

0.000

1.011

4-5

0.003

2.899

0.000

1.061

5-6

0.004

3.071

0.000

1.124

6-7

0.004

3.396

0.000

1.145

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

2.194

5.178

2.8



1-2

3.472

7.128

3.0



2-3

3.494

7.547

2.8



3-4

3.523

7.512

2.6



4-5

2.640

6.603

2.3



5-6

2.386

6.584

2.1



6-7

2.257

6.802

1.9



Res07	10/31/2005 2:14 PM

008761


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 08
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.002

1-2

2.000

3.000

32.000

0.002

2-3

3.000

5.000

32.000

0.002

3-4

4.000

5.000

32.000

0.002

4-5

4.000

5.000

32.000

0.002

5-6

4.000

7.000

32.000

0.002

6-7

4.000

7.000

32.000

0.002

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res08	10/31/2005 2:14 PM

008762


-------
Average multiple source concentration: 31.971 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

45.440

31.971

1-2

45.440

31.971

2-3

45.440

31.971

3-4

45.440

31.971

4-5

45.440

31.971

5-6

45.440

31.971

6-7

45.440

31.971

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.644

0.000

0.382

1-2

0.001

2.762

0.000

0.956

2-3

0.001

3.113

0.000

0.998

3-4

0.001

3.013

0.000

1.024

4-5

0.001

2.923

0.000

1.070

5-6

0.002

3.091

0.000

1.131

6-7

0.002

3.415

0.000

1.151

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.927

3.954

2.2



1-2

1.472

5.190

2.2



2-3

1.478

5.590

2.1



3-4

1.487

5.525

2.0



4-5

1.110

5.103

1.7



5-6

1.001

5.225

1.6



6-7

0.946

5.515

1.5



Res08	10/31/2005 2:14 PM

008763


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 09
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res09	10/31/2005 2:14 PM

008764


-------
Average multiple source concentration: 37.352 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

53.333

37.352

1-2

53.333

37.352

2-3

53.333

37.352

3-4

53.333

37.352

4-5

53.333

37.352

5-6

53.333

37.352

6-7

53.333

37.352

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.639

0.000

0.382

1-2

0.000

2.756

0.000

0.954

2-3

0.000

3.108

0.000

0.996

3-4

0.000

3.008

0.000

1.022

4-5

0.000

2.920

0.000

1.069

5-6

0.000

3.088

0.000

1.130

6-7

0.000

3.413

0.000

1.151

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.084

4.105

2.3



1-2

1.720

5.430

2.3



2-3

1.728

5.831

2.2



3-4

1.739

5.770

2.0



4-5

1.298

5.287

1.8



5-6

1.172

5.390

1.7



6-7

1.108

5.671

1.6



Res09	10/31/2005 2:14 PM

008765


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 10
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res10	10/31/2005 2:14 PM

008766


-------
Average multiple source concentration: 30.999 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

44.250

30.999

1-2

44.250

30.999

2-3

44.250

30.999

3-4

44.250

30.999

4-5

44.250

30.999

5-6

44.250

30.999

6-7

44.250

30.999

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.644

0.000

0.383

1-2

0.000

2.763

0.000

0.956

2-3

0.000

3.114

0.000

0.998

3-4

0.000

3.014

0.000

1.024

4-5

0.000

2.923

0.000

1.070

5-6

0.000

3.091

0.000

1.131

6-7

0.000

3.416

0.000

1.152

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.901

3.929

2.2



1-2

1.431

5.150

2.2



2-3

1.437

5.549

2.1



3-4

1.446

5.484

1.9



4-5

1.079

5.072

1.7



5-6

0.973

5.196

1.6



6-7

0.920

5.487

1.5



Res10	10/31/2005 2:14 PM

008767


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 11
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res11	10/31/2005 2:14 PM

008768


-------
Average multiple source concentration: 49.724 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

71.000

49.724

1-2

71.000

49.724

2-3

71.000

49.724

3-4

71.000

49.724

4-5

71.000

49.724

5-6

71.000

49.724

6-7

71.000

49.724

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.629

0.000

0.380

1-2

0.000

2.743

0.000

0.949

2-3

0.000

3.095

0.000

0.992

3-4

0.000

2.997

0.000

1.018

4-5

0.000

2.913

0.000

1.066

5-6

0.000

3.083

0.000

1.128

6-7

0.000

3.408

0.000

1.149

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.438

4.447

2.4



1-2

2.279

5.972

2.5



2-3

2.291

6.378

2.4



3-4

2.307

6.323

2.2



4-5

1.724

5.704

2.0



5-6

1.557

5.768

1.8



6-7

1.472

6.029

1.7



Res11	10/31/2005 2:14 PM

008769


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 12
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res12	10/31/2005 2:14 PM

008770


-------
Average multiple source concentration: 17.166 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

24.500

17.166

1-2

24.500

17.166

2-3

24.500

17.166

3-4

24.500

17.166

4-5

24.500

17.166

5-6

24.500

17.166

6-7

24.500

17.166

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.656

0.000

0.384

1-2

0.000

2.778

0.000

0.961

2-3

0.000

3.129

0.000

1.003

3-4

0.000

3.026

0.000

1.028

4-5

0.000

2.931

0.000

1.073

5-6

0.000

3.098

0.000

1.134

6-7

0.000

3.422

0.000

1.154

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.501

3.542

1.9



1-2

0.797

4.536

1.9



2-3

0.799

4.931

1.8



3-4

0.804

4.858

1.7



4-5

0.599

4.602

1.6



5-6

0.540

4.771

1.5



6-7

0.510

5.086

1.4



Res12	10/31/2005 2:14 PM

008771


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/26/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 13
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res13	10/31/2005 2:14 PM

008772


-------
Average multiple source concentration: 39.216 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

56.000

39.216

1-2

56.000

39.216

2-3

56.000

39.216

3-4

56.000

39.216

4-5

56.000

39.216

5-6

56.000

39.216

6-7

56.000

39.216

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.638

0.000

0.382

1-2

0.000

2.754

0.000

0.953

2-3

0.000

3.106

0.000

0.995

3-4

0.000

3.007

0.000

1.021

4-5

0.000

2.919

0.000

1.068

5-6

0.000

3.088

0.000

1.130

6-7

0.000

3.412

0.000

1.150

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.138

4.157

2.3



1-2

1.805

5.512

2.3



2-3

1.813

5.914

2.2



3-4

1.825

5.853

2.1



4-5

1.363

5.350

1.8



5-6

1.230

5.447

1.7



6-7

1.163

5.725

1.6



Res13	10/31/2005 2:14 PM

008773


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/26/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 14
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res14	10/31/2005 2:14 PM

008774


-------
Average multiple source concentration: 135.999 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

194.250

135.999

1-2

194.250

135.999

2-3

194.250

135.999

3-4

194.250

135.999

4-5

194.250

135.999

5-6

194.250

135.999

6-7

194.250

135.999

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.560

0.000

0.370

1-2

0.000

2.656

0.000

0.919

2-3

0.000

3.010

0.000

0.965

3-4

0.000

2.926

0.000

0.994

4-5

0.000

2.867

0.000

1.050

5-6

0.000

3.044

0.000

1.114

6-7

0.000

3.370

0.000

1.136

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

3.829

6.759

3.7



1-2

6.037

9.611

4.0



2-3

6.094

10.068

3.7



3-4

6.161

10.081

3.5



4-5

4.643

8.560

3.0



5-6

4.205

8.363

2.6



6-7

3.983

8.490

2.4



Res14	10/31/2005 2:14 PM

008775


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Hiroshi Awata
Date: 10/28/2005
Site Name: Tar Creek

Operable Unit: Operable Unit 4, Resident 15/GW4
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 26.150 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res15	10/31/2005 2:14 PM

008776


-------
Average multiple source concentration: 20.150 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

28.750

20.150

1-2

28.750

20.150

2-3

28.750

20.150

3-4

28.750

20.150

4-5

28.750

20.150

5-6

28.750

20.150

6-7

28.750

20.150

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.593

0.000

2.453

1-2

0.000

2.657

0.000

6.010

2-3

0.000

3.007

0.000

6.300

3-4

0.000

2.921

0.000

6.489

4-5

0.000

2.840

0.000

6.795

5-6

0.000

3.007

0.000

7.194

6-7

0.000

3.329

0.000

7.336

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.575

5.621

3.1



1-2

0.894

9.561

3.9



2-3

0.901

10.208

3.8



3-4

0.911

10.321

3.6



4-5

0.681

10.316

3.4



5-6

0.615

10.817

3.3



6-7

0.583

11.248

3.2



Res15	10/31/2005 2:14 PM

008777


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Hiroshi Awata
Date: 10/28/2005
Site Name: Tar Creek

Operable Unit: Operable Unit 4, Resident 16/GW9
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 0.850 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res16	10/31/2005 2:14 PM

008778


-------
Average multiple source concentration: 16.827 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

24.000

16.827

1-2

24.000

16.827

2-3

24.000

16.827

3-4

24.000

16.827

4-5

24.000

16.827

5-6

24.000

16.827

6-7

24.000

16.827

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.665

0.000

0.082

1-2

0.000

2.796

0.000

0.206

2-3

0.000

3.147

0.000

0.214

3-4

0.000

3.041

0.000

0.220

4-5

0.000

2.944

0.000

0.229

5-6

0.000

3.111

0.000

0.242

6-7

0.000

3.436

0.000

0.246

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.493

3.240

1.8



1-2

0.786

3.788

1.6



2-3

0.788

4.149

1.5



3-4

0.792

4.053

1.4



4-5

0.589

3.763

1.3



5-6

0.531

3.885

1.2



6-7

0.502

4.184

1.2



Res16	10/31/2005 2:14 PM

008779


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/26/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 17
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.005

1-2

2.000

3.000

32.000

0.005

2-3

3.000

5.000

32.000

0.005

3-4

4.000

5.000

32.000

0.005

4-5

4.000

5.000

32.000

0.005

5-6

4.000

7.000

32.000

0.005

6-7

4.000

7.000

32.000

0.005

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res17	10/31/2005 2:14 PM

008780


-------
Average multiple source concentration: 141.872 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

202.000

141.872

1-2

202.000

141.872

2-3

202.000

141.872

3-4

202.000

141.872

4-5

202.000

141.872

5-6

202.000

141.872

6-7

202.000

141.872

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.001

2.555

0.000

0.370

1-2

0.002

2.650

0.000

0.917

2-3

0.003

3.005

0.000

0.963

3-4

0.003

2.921

0.000

0.993

4-5

0.003

2.864

0.000

1.049

5-6

0.004

3.041

0.000

1.113

6-7

0.004

3.368

0.000

1.135

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

3.981

6.907

3.7



1-2

6.274

9.842

4.1



2-3

6.335

10.305

3.8



3-4

6.406

10.323

3.6



4-5

4.831

8.747

3.1



5-6

4.376

8.535

2.7



6-7

4.145

8.653

2.5



Res17	10/31/2005 2:14 PM

008781


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/26/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 18
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.005

1-2

2.000

3.000

32.000

0.005

2-3

3.000

5.000

32.000

0.005

3-4

4.000

5.000

32.000

0.005

4-5

4.000

5.000

32.000

0.005

5-6

4.000

7.000

32.000

0.005

6-7

4.000

7.000

32.000

0.005

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res18	10/31/2005 2:14 PM

008782


-------
Average multiple source concentration: 60.935 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

86.300

60.935

1-2

86.300

60.935

2-3

86.300

60.935

3-4

86.300

60.935

4-5

86.300

60.935

5-6

86.300

60.935

6-7

86.300

60.935

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.001

2.620

0.000

0.379

1-2

0.002

2.731

0.000

0.945

2-3

0.003

3.084

0.000

0.988

3-4

0.004

2.988

0.000

1.015

4-5

0.004

2.907

0.000

1.064

5-6

0.005

3.078

0.000

1.126

6-7

0.005

3.403

0.000

1.147

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.748

4.748

2.6



1-2

2.769

6.448

2.7



2-3

2.785

6.860

2.5



3-4

2.806

6.813

2.4



4-5

2.100

6.074

2.1



5-6

1.897

6.105

1.9



6-7

1.794

6.348

1.8



Res18	10/31/2005 2:14 PM

008783


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/26/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 19
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.002

1-2

2.000

3.000

32.000

0.002

2-3

3.000

5.000

32.000

0.002

3-4

4.000

5.000

32.000

0.002

4-5

4.000

5.000

32.000

0.002

5-6

4.000

7.000

32.000

0.002

6-7

4.000

7.000

32.000

0.002

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res19	10/31/2005 2:14 PM

008784


-------
Average multiple source concentration: 12.314 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

17.325

12.314

1-2

17.325

12.314

2-3

17.325

12.314

3-4

17.325

12.314

4-5

17.325

12.314

5-6

17.325

12.314

6-7

17.325

12.314

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.660

0.000

0.385

1-2

0.001

2.783

0.000

0.963

2-3

0.001

3.134

0.000

1.004

3-4

0.001

3.030

0.000

1.029

4-5

0.001

2.933

0.000

1.074

5-6

0.002

3.100

0.000

1.134

6-7

0.002

3.424

0.000

1.154

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.357

3.403

1.9



1-2

0.568

4.315

1.8



2-3

0.570

4.709

1.7



3-4

0.573

4.634

1.6



4-5

0.427

4.435

1.5



5-6

0.385

4.621

1.4



6-7

0.363

4.944

1.4



Res19	10/31/2005 2:14 PM

008785


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/26/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 20
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res20	10/31/2005 2:14 PM

008786


-------
Average multiple source concentration: 42.903 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

61.250

42.903

1-2

61.250

42.903

2-3

61.250

42.903

3-4

61.250

42.903

4-5

61.250

42.903

5-6

61.250

42.903

6-7

61.250

42.903

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.634

0.000

0.381

1-2

0.000

2.750

0.000

0.952

2-3

0.000

3.102

0.000

0.994

3-4

0.000

3.003

0.000

1.020

4-5

0.000

2.917

0.000

1.068

5-6

0.000

3.086

0.000

1.129

6-7

0.000

3.411

0.000

1.150

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.243

4.259

2.3



1-2

1.972

5.674

2.4



2-3

1.981

6.077

2.3



3-4

1.994

6.018

2.1



4-5

1.490

5.474

1.9



5-6

1.345

5.560

1.7



6-7

1.271

5.832

1.6



Res20	10/31/2005 2:14 PM

008787


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/26/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 21
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.008

1-2

2.000

3.000

32.000

0.008

2-3

3.000

5.000

32.000

0.008

3-4

4.000

5.000

32.000

0.008

4-5

4.000

5.000

32.000

0.008

5-6

4.000

7.000

32.000

0.008

6-7

4.000

7.000

32.000

0.008

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res21	10/31/2005 2:14 PM

008788


-------
Average multiple source concentration: 38.473 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

53.800

38.473

1-2

53.800

38.473

2-3

53.800

38.473

3-4

53.800

38.473

4-5

53.800

38.473

5-6

53.800

38.473

6-7

53.800

38.473

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.002

2.639

0.000

0.382

1-2

0.003

2.755

0.000

0.953

2-3

0.005

3.107

0.000

0.996

3-4

0.005

3.008

0.000

1.022

4-5

0.005

2.919

0.000

1.069

5-6

0.008

3.088

0.000

1.130

6-7

0.008

3.413

0.000

1.151

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.104

4.126

2.3



1-2

1.752

5.464

2.3



2-3

1.759

5.867

2.2



3-4

1.771

5.806

2.1



4-5

1.322

5.315

1.8



5-6

1.193

5.419

1.7



6-7

1.128

5.699

1.6



Res21	10/31/2005 2:14 PM

008789


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/26/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 22
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.002

1-2

2.000

3.000

32.000

0.002

2-3

3.000

5.000

32.000

0.002

3-4

4.000

5.000

32.000

0.002

4-5

4.000

5.000

32.000

0.002

5-6

4.000

7.000

32.000

0.002

6-7

4.000

7.000

32.000

0.002

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res22	10/31/2005 2:14 PM

008790


-------
Average multiple source concentration: 38.020 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

54.075

38.020

1-2

54.075

38.020

2-3

54.075

38.020

3-4

54.075

38.020

4-5

54.075

38.020

5-6

54.075

38.020

6-7

54.075

38.020

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.639

0.000

0.382

1-2

0.001

2.756

0.000

0.953

2-3

0.001

3.107

0.000

0.996

3-4

0.001

3.008

0.000

1.022

4-5

0.001

2.919

0.000

1.069

5-6

0.002

3.088

0.000

1.130

6-7

0.002

3.413

0.000

1.151

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.101

4.122

2.3



1-2

1.747

5.457

2.3



2-3

1.755

5.858

2.2



3-4

1.766

5.797

2.0



4-5

1.319

5.308

1.8



5-6

1.190

5.410

1.7



6-7

1.125

5.690

1.6



Res22	10/31/2005 2:14 PM

008791


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: Shana Alan/CVO
Date: 10/26/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 23
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Res23	10/31/2005 2:14 PM

008792


-------
Average multiple source concentration: 31.708 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

45.233

31.708

1-2

45.233

31.708

2-3

45.233

31.708

3-4

45.233

31.708

4-5

45.233

31.708

5-6

45.233

31.708

6-7

45.233

31.708

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.644

0.000

0.382

1-2

0.000

2.762

0.000

0.956

2-3

0.000

3.113

0.000

0.998

3-4

0.000

3.013

0.000

1.024

4-5

0.000

2.923

0.000

1.070

5-6

0.000

3.091

0.000

1.131

6-7

0.000

3.415

0.000

1.152

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.922

3.948

2.2



1-2

1.463

5.181

2.2



2-3

1.469

5.580

2.1



3-4

1.478

5.515

2.0



4-5

1.103

5.096

1.7



5-6

0.995

5.218

1.6



6-7

0.940

5.508

1.5



Res23	10/31/2005 2:14 PM

008793


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 24
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES24	10/31/2005 2:14 PM

008794


-------
Average multiple source concentration: 17.692 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

25.250

17.692

1-2

25.250

17.692

2-3

25.250

17.692

3-4

25.250

17.692

4-5

25.250

17.692

5-6

25.250

17.692

6-7

25.250

17.692

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.656

0.000

0.384

1-2

0.000

2.777

0.000

0.961

2-3

0.000

3.128

0.000

1.003

3-4

0.000

3.025

0.000

1.028

4-5

0.000

2.930

0.000

1.073

5-6

0.000

3.097

0.000

1.133

6-7

0.000

3.422

0.000

1.154

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.517

3.557

2.0



1-2

0.821

4.559

1.9



2-3

0.823

4.954

1.8



3-4

0.828

4.881

1.7



4-5

0.617

4.620

1.6



5-6

0.556

4.788

1.5



6-7

0.526

5.101

1.4



RES24	10/31/2005 2:14 PM

008795


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 25
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.001

1-2

2.000

3.000

32.000

0.001

2-3

3.000

5.000

32.000

0.001

3-4

4.000

5.000

32.000

0.001

4-5

4.000

5.000

32.000

0.001

5-6

4.000

7.000

32.000

0.001

6-7

4.000

7.000

32.000

0.001

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES25	10/31/2005 2:14 PM

008796


-------
Average multiple source concentration: 12.932 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

18.400

12.932

1-2

18.400

12.932

2-3

18.400

12.932

3-4

18.400

12.932

4-5

18.400

12.932

5-6

18.400

12.932

6-7

18.400

12.932

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.660

0.000

0.385

1-2

0.000

2.783

0.000

0.963

2-3

0.000

3.133

0.000

1.004

3-4

0.000

3.029

0.000

1.029

4-5

0.000

2.933

0.000

1.074

5-6

0.000

3.100

0.000

1.134

6-7

0.000

3.424

0.000

1.154

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.378

3.422

1.9



1-2

0.600

4.346

1.9



2-3

0.602

4.739

1.8



3-4

0.605

4.664

1.7



4-5

0.451

4.458

1.5



5-6

0.406

4.641

1.4



6-7

0.384

4.963

1.4



RES25	10/31/2005 2:14 PM

008797


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 26
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES26	10/31/2005 2:14 PM

008798


-------
Average multiple source concentration: 283.367 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

404.750

283.367

1-2

404.750

283.367

2-3

404.750

283.367

3-4

404.750

283.367

4-5

404.750

283.367

5-6

404.750

283.367

6-7

404.750

283.367

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.451

0.000

0.355

1-2

0.000

2.521

0.000

0.872

2-3

0.000

2.878

0.000

0.922

3-4

0.000

2.813

0.000

0.956

4-5

0.000

2.794

0.000

1.023

5-6

0.000

2.980

0.000

1.091

6-7

0.000

3.309

0.000

1.115

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

7.641

10.447

5.6



1-2

11.943

15.337

6.3



2-3

12.138

15.938

5.9



3-4

12.343

16.112

5.6



4-5

9.426

13.243

4.7



5-6

8.580

12.651

4.0



6-7

8.148

12.572

3.6



RES26	10/31/2005 2:14 PM

008799


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 27
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES27	10/31/2005 2:14 PM

008800


-------
Average multiple source concentration: 32.743 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

46.750

32.743

1-2

46.750

32.743

2-3

46.750

32.743

3-4

46.750

32.743

4-5

46.750

32.743

5-6

46.750

32.743

6-7

46.750

32.743

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.643

0.000

0.382

1-2

0.000

2.761

0.000

0.955

2-3

0.000

3.112

0.000

0.998

3-4

0.000

3.012

0.000

1.023

4-5

0.000

2.922

0.000

1.070

5-6

0.000

3.091

0.000

1.131

6-7

0.000

3.415

0.000

1.151

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.952

3.977

2.2



1-2

1.511

5.227

2.2



2-3

1.517

5.627

2.1



3-4

1.527

5.562

2.0



4-5

1.139

5.131

1.8



5-6

1.028

5.249

1.6



6-7

0.971

5.538

1.6



RES27	10/31/2005 2:14 PM

008801


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 28
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES28	10/31/2005 2:14 PM

008802


-------
Average multiple source concentration: 50.593 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

72.250

50.593

1-2

72.250

50.593

2-3

72.250

50.593

3-4

72.250

50.593

4-5

72.250

50.593

5-6

72.250

50.593

6-7

72.250

50.593

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.628

0.000

0.380

1-2

0.000

2.742

0.000

0.949

2-3

0.000

3.094

0.000

0.992

3-4

0.000

2.997

0.000

1.018

4-5

0.000

2.912

0.000

1.066

5-6

0.000

3.082

0.000

1.128

6-7

0.000

3.407

0.000

1.149

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.462

4.471

2.4



1-2

2.319

6.010

2.5



2-3

2.330

6.416

2.4



3-4

2.347

6.362

2.2



4-5

1.754

5.733

2.0



5-6

1.584

5.794

1.8



6-7

1.498

6.054

1.7



RES28	10/31/2005 2:14 PM

008803


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 29
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.001

1-2

2.000

3.000

32.000

0.001

2-3

3.000

5.000

32.000

0.001

3-4

4.000

5.000

32.000

0.001

4-5

4.000

5.000

32.000

0.001

5-6

4.000

7.000

32.000

0.001

6-7

4.000

7.000

32.000

0.001

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES29	10/31/2005 2:14 PM

008804


-------
Average multiple source concentration: 22.801 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

32.500

22.801

1-2

32.500

22.801

2-3

32.500

22.801

3-4

32.500

22.801

4-5

32.500

22.801

5-6

32.500

22.801

6-7

32.500

22.801

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.651

0.000

0.384

1-2

0.000

2.772

0.000

0.959

2-3

0.000

3.123

0.000

1.001

3-4

0.000

3.021

0.000

1.026

4-5

0.000

2.927

0.000

1.072

5-6

0.000

3.095

0.000

1.133

6-7

0.000

3.419

0.000

1.153

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.664

3.699

2.0



1-2

1.055

4.786

2.0



2-3

1.059

5.183

1.9



3-4

1.065

5.113

1.8



4-5

0.794

4.793

1.6



5-6

0.716

4.944

1.5



6-7

0.677

5.249

1.5



RES29	10/31/2005 2:14 PM

008805


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 30
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES30	10/31/2005 2:14 PM

008806


-------
Average multiple source concentration: 14.190 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

20.200

14.190

1-2

20.200

14.190

2-3

20.200

14.190

3-4

20.200

14.190

4-5

20.200

14.190

5-6

20.200

14.190

6-7

20.200

14.190

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.659

0.000

0.385

1-2

0.000

2.781

0.000

0.962

2-3

0.000

3.132

0.000

1.004

3-4

0.000

3.028

0.000

1.029

4-5

0.000

2.932

0.000

1.073

5-6

0.000

3.099

0.000

1.134

6-7

0.000

3.423

0.000

1.154

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.414

3.458

1.9



1-2

0.658

4.402

1.9



2-3

0.660

4.796

1.8



3-4

0.664

4.722

1.7



4-5

0.495

4.500

1.5



5-6

0.446

4.680

1.4



6-7

0.421

4.999

1.4



RES30	10/31/2005 2:14 PM

008807


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 31
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES31	10/31/2005 2:14 PM

008808


-------
Average multiple source concentration: 60.765 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

86.750

60.765

1-2

86.750

60.765

2-3

86.750

60.765

3-4

86.750

60.765

4-5

86.750

60.765

5-6

86.750

60.765

6-7

86.750

60.765

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.620

0.000

0.379

1-2

0.000

2.731

0.000

0.945

2-3

0.000

3.084

0.000

0.988

3-4

0.000

2.988

0.000

1.015

4-5

0.000

2.907

0.000

1.064

5-6

0.000

3.078

0.000

1.126

6-7

0.000

3.403

0.000

1.147

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.751

4.749

2.6



1-2

2.773

6.450

2.7



2-3

2.789

6.861

2.5



3-4

2.810

6.814

2.4



4-5

2.103

6.074

2.1



5-6

1.899

6.104

1.9



6-7

1.796

6.347

1.8



RES31	10/31/2005 2:14 PM

008809


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 32
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES32	10/31/2005 2:14 PM

008810


-------
Average multiple source concentration: 44.840 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

64.000

44.840

1-2

64.000

44.840

2-3

64.000

44.840

3-4

64.000

44.840

4-5

64.000

44.840

5-6

64.000

44.840

6-7

64.000

44.840

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.633

0.000

0.381

1-2

0.000

2.748

0.000

0.951

2-3

0.000

3.100

0.000

0.994

3-4

0.000

3.002

0.000

1.020

4-5

0.000

2.916

0.000

1.067

5-6

0.000

3.085

0.000

1.129

6-7

0.000

3.410

0.000

1.150

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.298

4.312

2.4



1-2

2.059

5.758

2.4



2-3

2.068

6.162

2.3



3-4

2.083

6.105

2.2



4-5

1.556

5.539

1.9



5-6

1.405

5.619

1.7



6-7

1.328

5.888

1.7



RES32	10/31/2005 2:14 PM

008811


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 33
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.003

1-2

2.000

3.000

32.000

0.003

2-3

3.000

5.000

32.000

0.003

3-4

4.000

5.000

32.000

0.003

4-5

4.000

5.000

32.000

0.003

5-6

4.000

7.000

32.000

0.003

6-7

4.000

7.000

32.000

0.003

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES33	10/31/2005 2:14 PM

008812


-------
Average multiple source concentration: 14.188 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

19.800

14.188

1-2

19.800

14.188

2-3

19.800

14.188

3-4

19.800

14.188

4-5

19.800

14.188

5-6

19.800

14.188

6-7

19.800

14.188

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.001

2.659

0.000

0.385

1-2

0.001

2.781

0.000

0.962

2-3

0.002

3.132

0.000

1.004

3-4

0.002

3.028

0.000

1.029

4-5

0.002

2.932

0.000

1.073

5-6

0.003

3.099

0.000

1.134

6-7

0.003

3.423

0.000

1.154

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.410

3.454

1.9



1-2

0.651

4.396

1.9



2-3

0.653

4.791

1.8



3-4

0.657

4.717

1.7



4-5

0.489

4.497

1.5



5-6

0.441

4.677

1.4



6-7

0.417

4.997

1.4



RES33	10/31/2005 2:14 PM

008813


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 34
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.002

1-2

2.000

3.000

32.000

0.002

2-3

3.000

5.000

32.000

0.002

3-4

4.000

5.000

32.000

0.002

4-5

4.000

5.000

32.000

0.002

5-6

4.000

7.000

32.000

0.002

6-7

4.000

7.000

32.000

0.002

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES34	10/31/2005 2:14 PM

008814


-------
Average multiple source concentration: 75.044 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

106.850

75.044

1-2

106.850

75.044

2-3

106.850

75.044

3-4

106.850

75.044

4-5

106.850

75.044

5-6

106.850

75.044

6-7

106.850

75.044

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.001

2.608

0.000

0.377

1-2

0.001

2.717

0.000

0.940

2-3

0.002

3.069

0.000

0.984

3-4

0.002

2.976

0.000

1.011

4-5

0.002

2.899

0.000

1.061

5-6

0.002

3.071

0.000

1.124

6-7

0.002

3.397

0.000

1.145

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

2.149

5.135

2.8



1-2

3.402

7.059

3.0



2-3

3.423

7.478

2.8



3-4

3.452

7.441

2.6



4-5

2.586

6.549

2.3



5-6

2.337

6.535

2.0



6-7

2.211

6.755

1.9



RES34	10/31/2005 2:14 PM

008815


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 35
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.003

1-2

2.000

3.000

32.000

0.003

2-3

3.000

5.000

32.000

0.003

3-4

4.000

5.000

32.000

0.003

4-5

4.000

5.000

32.000

0.003

5-6

4.000

7.000

32.000

0.003

6-7

4.000

7.000

32.000

0.003

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES35	10/31/2005 2:14 PM

008816


-------
Average multiple source concentration: 44.707 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

63.430

44.707

1-2

63.430

44.707

2-3

63.430

44.707

3-4

63.430

44.707

4-5

63.430

44.707

5-6

63.430

44.707

6-7

63.430

44.707

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.001

2.633

0.000

0.381

1-2

0.001

2.748

0.000

0.951

2-3

0.002

3.100

0.000

0.994

3-4

0.002

3.002

0.000

1.020

4-5

0.002

2.916

0.000

1.067

5-6

0.003

3.085

0.000

1.129

6-7

0.003

3.410

0.000

1.150

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.290

4.305

2.4



1-2

2.046

5.747

2.4



2-3

2.056

6.152

2.3



3-4

2.070

6.094

2.2



4-5

1.547

5.532

1.9



5-6

1.396

5.613

1.7



6-7

1.320

5.882

1.7



RES35	10/31/2005 2:14 PM

008817


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 36
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES36	10/31/2005 2:14 PM

008818


-------
Average multiple source concentration: 17.183 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

24.500

17.183

1-2

24.500

17.183

2-3

24.500

17.183

3-4

24.500

17.183

4-5

24.500

17.183

5-6

24.500

17.183

6-7

24.500

17.183

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.656

0.000

0.384

1-2

0.000

2.778

0.000

0.961

2-3

0.000

3.129

0.000

1.003

3-4

0.000

3.026

0.000

1.028

4-5

0.000

2.931

0.000

1.073

5-6

0.000

3.098

0.000

1.134

6-7

0.000

3.422

0.000

1.154

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.502

3.542

1.9



1-2

0.797

4.536

1.9



2-3

0.800

4.931

1.8



3-4

0.804

4.858

1.7



4-5

0.599

4.603

1.6



5-6

0.540

4.772

1.5



6-7

0.510

5.086

1.4



RES36	10/31/2005 2:14 PM

008819


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 37
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES37	10/31/2005 2:14 PM

008820


-------
Average multiple source concentration: 5229.050 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

7470.000

5229.050

1-2

7470.000

5229.050

2-3

7470.000

5229.050

3-4

7470.000

5229.050

4-5

7470.000

5229.050

5-6

7470.000

5229.050

6-7

7470.000

5229.050

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

1.232

0.000

0.178

1-2

0.000

1.192

0.000

0.413

2-3

0.000

1.423

0.000

0.456

3-4

0.000

1.453

0.000

0.494

4-5

0.000

1.649

0.000

0.604

5-6

0.000

1.879

0.000

0.687

6-7

0.000

2.171

0.000

0.732

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

70.842

72.252

35.0



1-2

104.227

105.833

40.0



2-3

110.774

112.653

38.3



3-4

117.635

119.582

38.1



4-5

102.684

104.937

33.9



5-6

99.799

102.365

30.2



6-7

98.681

101.585

27.6



Environmental exposures associated with blood lead levels above 30 |jg/dl are above
RES37	10/31/2005 2:14 PM

008821


-------
the range of values that have been used in the calibration and empirical validation of
this model. (Zaragoza, L. and Hogan, K. 1998. The Integrated Exposure Uptake
Biokinetic Model for Lead In Children: Independent Validation and Verification.
Environmental Health Perspectives 106 (supplement 6). p. 1555)

RES37

008822

10/31/2005 2:14 PM


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 38
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.001

1-2

2.000

3.000

32.000

0.001

2-3

3.000

5.000

32.000

0.001

3-4

4.000

5.000

32.000

0.001

4-5

4.000

5.000

32.000

0.001

5-6

4.000

7.000

32.000

0.001

6-7

4.000

7.000

32.000

0.001

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES38	10/31/2005 2:14 PM

008823


-------
Average multiple source concentration: 165.168 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

235.750

165.168

1-2

235.750

165.168

2-3

235.750

165.168

3-4

235.750

165.168

4-5

235.750

165.168

5-6

235.750

165.168

6-7

235.750

165.168

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.537

0.000

0.367

1-2

0.000

2.628

0.000

0.909

2-3

0.001

2.983

0.000

0.956

3-4

0.001

2.903

0.000

0.986

4-5

0.001

2.852

0.000

1.044

5-6

0.001

3.031

0.000

1.109

6-7

0.001

3.358

0.000

1.132

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

4.608

7.512

4.1



1-2

7.251

10.789

4.5



2-3

7.330

11.270

4.2



3-4

7.420

11.310

4.0



4-5

5.608

9.505

3.4



5-6

5.084

9.226

2.9



6-7

4.818

9.309

2.7



RES38	10/31/2005 2:14 PM

008824


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 39
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.002

1-2

2.000

3.000

32.000

0.002

2-3

3.000

5.000

32.000

0.002

3-4

4.000

5.000

32.000

0.002

4-5

4.000

5.000

32.000

0.002

5-6

4.000

7.000

32.000

0.002

6-7

4.000

7.000

32.000

0.002

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES39	10/31/2005 2:14 PM

008825


-------
Average multiple source concentration: 343.935 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

491.000

343.935

1-2

491.000

343.935

2-3

491.000

343.935

3-4

491.000

343.935

4-5

491.000

343.935

5-6

491.000

343.935

6-7

491.000

343.935

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.410

0.000

0.349

1-2

0.001

2.471

0.000

0.855

2-3

0.001

2.827

0.000

0.906

3-4

0.002

2.770

0.000

0.941

4-5

0.002

2.765

0.000

1.012

5-6

0.002

2.955

0.000

1.081

6-7

0.002

3.284

0.000

1.107

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

9.117

11.876

6.4



1-2

14.203

17.530

7.2



2-3

14.472

18.207

6.7



3-4

14.747

18.460

6.4



4-5

11.319

15.097

5.4



5-6

10.323

14.361

4.6



6-7

9.813

14.207

4.1



RES39	10/31/2005 2:14 PM

008826


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 40
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.004

1-2

2.000

3.000

32.000

0.004

2-3

3.000

5.000

32.000

0.004

3-4

4.000

5.000

32.000

0.004

4-5

4.000

5.000

32.000

0.004

5-6

4.000

7.000

32.000

0.004

6-7

4.000

7.000

32.000

0.004

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES40	10/31/2005 2:14 PM

008827


-------
Average multiple source concentration: 244.034 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

348.000

244.034

1-2

348.000

244.034

2-3

348.000

244.034

3-4

348.000

244.034

4-5

348.000

244.034

5-6

348.000

244.034

6-7

348.000

244.034

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.001

2.479

0.000

0.359

1-2

0.001

2.556

0.000

0.884

2-3

0.003

2.912

0.000

0.933

3-4

0.003

2.842

0.000

0.966

4-5

0.003

2.813

0.000

1.030

5-6

0.004

2.997

0.000

1.097

6-7

0.004

3.325

0.000

1.121

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

6.649

9.488

5.1



1-2

10.416

13.857

5.7



2-3

10.568

14.415

5.3



3-4

10.730

14.541

5.1



4-5

8.167

12.012

4.3



5-6

7.424

11.521

3.6



6-7

7.045

11.495

3.3



RES40	10/31/2005 2:14 PM

008828


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 41
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.005

1-2

2.000

3.000

32.000

0.005

2-3

3.000

5.000

32.000

0.005

3-4

4.000

5.000

32.000

0.005

4-5

4.000

5.000

32.000

0.005

5-6

4.000

7.000

32.000

0.005

6-7

4.000

7.000

32.000

0.005

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES41	10/31/2005 2:14 PM

008829


-------
Average multiple source concentration: 450.766 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

643.300

450.766

1-2

643.300

450.766

2-3

643.300

450.766

3-4

643.300

450.766

4-5

643.300

450.766

5-6

643.300

450.766

6-7

643.300

450.766

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.001

2.342

0.000

0.339

1-2

0.002

2.389

0.000

0.827

2-3

0.003

2.744

0.000

0.880

3-4

0.003

2.698

0.000

0.917

4-5

0.003

2.715

0.000

0.994

5-6

0.004

2.912

0.000

1.066

6-7

0.004

3.242

0.000

1.093

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

11.608

14.290

7.6



1-2

17.991

21.208

8.7



2-3

18.407

22.033

8.1



3-4

18.822

22.440

7.8



4-5

14.569

18.281

6.5



5-6

13.329

17.311

5.5



6-7

12.695

17.034

4.9



RES41	10/31/2005 2:14 PM

008830


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 42
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES42	10/31/2005 2:14 PM

008831


-------
Average multiple source concentration: 27.331 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

39.000

27.331

1-2

39.000

27.331

2-3

39.000

27.331

3-4

39.000

27.331

4-5

39.000

27.331

5-6

39.000

27.331

6-7

39.000

27.331

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.648

0.000

0.383

1-2

0.000

2.767

0.000

0.957

2-3

0.000

3.118

0.000

0.999

3-4

0.000

3.017

0.000

1.025

4-5

0.000

2.925

0.000

1.071

5-6

0.000

3.093

0.000

1.132

6-7

0.000

3.417

0.000

1.152

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.796

3.826

2.1



1-2

1.263

4.988

2.1



2-3

1.268

5.385

2.0



3-4

1.276

5.318

1.9



4-5

0.951

4.947

1.7



5-6

0.858

5.083

1.6



6-7

0.811

5.381

1.5



RES42	10/31/2005 2:14 PM

008832


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 43
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.001

1-2

2.000

3.000

32.000

0.001

2-3

3.000

5.000

32.000

0.001

3-4

4.000

5.000

32.000

0.001

4-5

4.000

5.000

32.000

0.001

5-6

4.000

7.000

32.000

0.001

6-7

4.000

7.000

32.000

0.001

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES43	10/31/2005 2:14 PM

008833


-------
Average multiple source concentration: 8.934 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

12.640 i

3.934

1-2

12.640 (

3.934

2-3

12.640 (

3.934

3-4

12.640 (

3.934

4-5

12.640 (

3.934

5-6

12.640 (

3.934

6-7

12.640 (

3.934

******

Alternate Intake ******



Age

Alternate (ug Pb/day)



.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.663

0.000

0.385

1-2

0.000

2.787

0.000

0.964

2-3

0.001

3.137

0.000

1.006

3-4

0.001

3.033

0.000

1.030

4-5

0.001

2.935

0.000

1.074

5-6

0.001

3.102

0.000

1.135

6-7

0.001

3.426

0.000

1.155

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.260

3.309

1.8



1-2

0.414

4.166

1.8



2-3

0.415

4.559

1.7



3-4

0.417

4.481

1.6



4-5

0.311

4.321

1.5



5-6

0.280

4.517

1.4



6-7

0.265

4.846

1.3



RES43	10/31/2005 2:14 PM

008834


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 44
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.001

1-2

2.000

3.000

32.000

0.001

2-3

3.000

5.000

32.000

0.001

3-4

4.000

5.000

32.000

0.001

4-5

4.000

5.000

32.000

0.001

5-6

4.000

7.000

32.000

0.001

6-7

4.000

7.000

32.000

0.001

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES44	10/31/2005 2:14 PM

008835


-------
Average multiple source concentration: 29.385 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

41.853

29.385

1-2

41.853

29.385

2-3

41.853

29.385

3-4

41.853

29.385

4-5

41.853

29.385

5-6

41.853

29.385

6-7

41.853

29.385

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.646

0.000

0.383

1-2

0.000

2.765

0.000

0.957

2-3

0.001

3.116

0.000

0.999

3-4

0.001

3.015

0.000

1.024

4-5

0.001

2.924

0.000

1.070

5-6

0.001

3.092

0.000

1.131

6-7

0.001

3.417

0.000

1.152

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.854

3.883

2.1



1-2

1.356

5.078

2.2



2-3

1.361

5.476

2.0



3-4

1.370

5.410

1.9



4-5

1.022

5.016

1.7



5-6

0.922

5.146

1.6



6-7

0.871

5.440

1.5



RES44	10/31/2005 2:14 PM

008836


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 45
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES45	10/31/2005 2:14 PM

008837


-------
Average multiple source concentration: 63.604 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

90.800

63.604

1-2

90.800

63.604

2-3

90.800

63.604

3-4

90.800

63.604

4-5

90.800

63.604

5-6

90.800

63.604

6-7

90.800

63.604

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.617

0.000

0.379

1-2

0.000

2.728

0.000

0.944

2-3

0.000

3.081

0.000

0.987

3-4

0.000

2.986

0.000

1.014

4-5

0.000

2.905

0.000

1.064

5-6

0.000

3.076

0.000

1.126

6-7

0.000

3.401

0.000

1.147

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

1.831

4.827

2.6



1-2

2.900

6.573

2.8



2-3

2.916

6.985

2.6



3-4

2.939

6.940

2.4



4-5

2.200

6.169

2.1



5-6

1.987

6.190

1.9



6-7

1.880

6.428

1.8



RES45	10/31/2005 2:14 PM

008838


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262
User Name: W. Trevathan
Date: 10/25/2005
Site Name: Tar Creek

Operable Unit: Operable Unit-4, Resident 46
Run Mode: Research

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

RES46	10/31/2005 2:14 PM

008839


-------
Average multiple source concentration: 22.620 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

32.250

22.620

1-2

32.250

22.620

2-3

32.250

22.620

3-4

32.250

22.620

4-5

32.250

22.620

5-6

32.250

22.620

6-7

32.250

22.620

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.652

0.000

0.384

1-2

0.000

2.772

0.000

0.959

2-3

0.000

3.123

0.000

1.001

3-4

0.000

3.021

0.000

1.026

4-5

0.000

2.928

0.000

1.072

5-6

0.000

3.095

0.000

1.133

6-7

0.000

3.419

0.000

1.153

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

0.659

3.694

2.0



1-2

1.047

4.778

2.0



2-3

1.051

5.175

1.9



3-4

1.057

5.104

1.8



4-5

0.788

4.787

1.6



5-6

0.711

4.939

1.5



6-7

0.672

5.244

1.5



RES46	10/31/2005 2:14 PM

008840


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262

User Name: Hiroshi Awata

Date: 10/28/2005

Site Name: Tar Creek

Operable Unit: Operable Unit 4, GW1

Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 1.767 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

GW1	10/31/2005 2:14 PM

008841


-------
Average multiple source concentration: 119.527 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

170.687

119.527

1-2

170.687

119.527

2-3

170.687

119.527

3-4

170.687

119.527

4-5

170.687

119.527

5-6

170.687

119.527

6-7

170.687

119.527

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.578

0.000

0.165

1-2

0.000

2.683

0.000

0.410

2-3

0.000

3.037

0.000

0.430

3-4

0.000

2.949

0.000

0.443

4-5

0.000

2.885

0.000

0.466

5-6

0.000

3.060

0.000

0.495

6-7

0.000

3.387

0.000

0.504

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

3.389

6.132

3.3



1-2

5.360

8.453

3.5



2-3

5.404

8.871

3.3



3-4

5.457

8.850

3.1



4-5

4.106

7.457

2.6



5-6

3.715

7.271

2.3



6-7

3.517

7.408

2.1



GW1	10/31/2005 2:14 PM

008842


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262

User Name: Hiroshi Awata

Date: 10/28/2005

Site Name: Tar Creek

Operable Unit: Operable Unit 4, GW2

Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 2.850 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

GW2	10/31/2005 2:14 PM

008843


-------
Average multiple source concentration: 119.500 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

170.687

119.500

1-2

170.687

119.500

2-3

170.687

119.500

3-4

170.687

119.500

4-5

170.687

119.500

5-6

170.687

119.500

6-7

170.687

119.500

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.575

0.000

0.265

1-2

0.000

2.678

0.000

0.660

2-3

0.000

3.032

0.000

0.692

3-4

0.000

2.944

0.000

0.713

4-5

0.000

2.881

0.000

0.751

5-6

0.000

3.056

0.000

0.797

6-7

0.000

3.382

0.000

0.812

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

3.385

6.226

3.4



1-2

5.348

8.686

3.6



2-3

5.393

9.117

3.4



3-4

5.448

9.105

3.2



4-5

4.099

7.731

2.7



5-6

3.710

7.563

2.4



6-7

3.512

7.707

2.2



GW2	10/31/2005 2:14 PM

008844


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262

User Name: Hiroshi Awata

Date: 10/28/2005

Site Name: Tar Creek

Operable Unit: Operable Unit 4, GW3

Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 1.350 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

GW3	10/31/2005 2:14 PM

008845


-------
Average multiple source concentration: 119.499 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

170.687

119.498

1-2

170.687

119.498

2-3

170.687

119.498

3-4

170.687

119.498

4-5

170.687

119.498

5-6

170.687

119.498

6-7

170.687

119.498

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.579

0.000

0.126

1-2

0.000

2.685

0.000

0.314

2-3

0.000

3.040

0.000

0.329

3-4

0.000

2.951

0.000

0.338

4-5

0.000

2.887

0.000

0.357

5-6

0.000

3.062

0.000

0.378

6-7

0.000

3.388

0.000

0.386

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

3.390

6.096

3.3



1-2

5.364

8.363

3.5



2-3

5.407

8.775

3.3



3-4

5.460

8.750

3.1



4-5

4.107

7.351

2.6



5-6

3.717

7.157

2.3



6-7

3.519

7.293

2.1



GW3	10/31/2005 2:14 PM

008846


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262

User Name: Hiroshi Awata

Date: 10/28/2005

Site Name: Tar Creek

Operable Unit: Operable Unit 4, GW5

Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 0.125 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

GW5	10/31/2005 2:14 PM

008847


-------
Average multiple source concentration: 119.499 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

170.687

119.499

1-2

170.687

119.499

2-3

170.687

119.499

3-4

170.687

119.499

4-5

170.687

119.499

5-6

170.687

119.499

6-7

170.687

119.499

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.582

0.000

0.012

1-2

0.000

2.692

0.000

0.029

2-3

0.000

3.046

0.000

0.031

3-4

0.000

2.957

0.000

0.031

4-5

0.000

2.892

0.000

0.033

5-6

0.000

3.067

0.000

0.035

6-7

0.000

3.393

0.000

0.036

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

3.395

5.989

3.3



1-2

5.376

8.097

3.4



2-3

5.419

8.495

3.2



3-4

5.471

8.459

3.0



4-5

4.115

7.039

2.5



5-6

3.723

6.825

2.2



6-7

3.524

6.953

2.0



GW5	10/31/2005 2:14 PM

008848


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262

User Name: Hiroshi Awata

Date: 10/28/2005

Site Name: Tar Creek

Operable Unit: Operable Unit 4, GW8

Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.000

1-2

2.000

3.000

32.000

0.000

2-3

3.000

5.000

32.000

0.000

3-4

4.000

5.000

32.000

0.000

4-5

4.000

5.000

32.000

0.000

5-6

4.000

7.000

32.000

0.000

6-7

4.000

7.000

32.000

0.000

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 12.683 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

GW8	10/31/2005 2:14 PM

008849


-------
Average multiple source concentration: 119.507 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

170.687

119.507

1-2

170.687

119.507

2-3

170.687

119.507

3-4

170.687

119.507

4-5

170.687

119.507

5-6

170.687

119.507

6-7

170.687

119.507

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.550

0.000

1.170

1-2

0.000

2.628

0.000

2.884

2-3

0.000

2.981

0.000

3.030

3-4

0.000

2.901

0.000

3.125

4-5

0.000

2.842

0.000

3.298

5-6

0.000

3.017

0.000

3.500

6-7

0.000

3.342

0.000

3.572

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

3.352

7.072

3.8



1-2

5.250

10.762

4.4



2-3

5.304

11.315

4.2



3-4

5.368

11.395

4.0



4-5

4.044

10.184

3.5



5-6

3.663

10.180

3.2



6-7

3.470

10.384

2.9



GW8	10/31/2005 2:14 PM

008850


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 262

User Name: Hiroshi Awata

Date: 10/28/2005

Site Name: Tar Creek

Operable Unit: Operable Unit 4, GW11

Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A | y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.001

1-2

2.000

3.000

32.000

0.001

2-3

3.000

5.000

32.000

0.001

3-4

4.000

5.000

32.000

0.001

4-5

4.000

5.000

32.000

0.001

5-6

4.000

7.000

32.000

0.001

6-7

4.000

7.000

32.000

0.001

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

5.530

1-2

5.780

2-3

6.490

3-4

6.240

4-5

6.010

5-6

6.340

6-7

7.000

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 0.650 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

GW11	10/31/2005 2:14 PM

008851


-------
Average multiple source concentration: 119.581 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

170.687

119.581

1-2

170.687

119.581

2-3

170.687

119.581

3-4

170.687

119.581

4-5

170.687

119.581

5-6

170.687

119.581

6-7

170.687

119.581

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.000

2.581

0.000

0.061

1-2

0.000

2.689

0.000

0.151

2-3

0.001

3.043

0.000

0.158

3-4

0.001

2.954

0.000

0.163

4-5

0.001

2.889

0.000

0.172

5-6

0.001

3.065

0.000

0.182

6-7

0.001

3.391

0.000

0.186

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

3.394

6.036

3.3



1-2

5.373

8.213

3.4



2-3

5.415

8.618

3.2



3-4

5.468

8.586

3.0



4-5

4.113

7.175

2.5



5-6

3.722

6.970

2.2



6-7

3.523

7.101

2.0



GW11	10/31/2005 2:14 PM

008852


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

U SEPA\317950\T7\RA04\D RAFT_2005-1028
008853

OCTOBER 2005


-------
Probability Plots

008854


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

U SEPA\317950\T7\RA04\D RAFT_2005-1028
008855

OCTOBER 2005


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 01


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 02


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Res. 03


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 04


-------
Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 1.918	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Research

% Above = 0.022	Comment = Res05

008860


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 06


-------
0	2	4	6

8	10 12 14

16 18 20 22 24

Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 2.515
GSD = 1.600
% Above = 0.166

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 07


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 08


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 09


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 10


-------
0	2	4	6

8	10 12 14

16 18 20 22 24

Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 2.160
GSD = 1.600
% Above = 0.056

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 11


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 12


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 13


-------
Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 3.280	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Research

% Above = 0.885	Comment = Resident 14

008869


-------
Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 3.455	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Site Risk Assessment

% Above = 1.187	Comment = Residentl5/GW4

008870


-------
Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 1.464	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Site Risk Assessment

% Above = 0.002	Comment = Residentl6/GW9

008871


-------
Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 3.352	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Research

% Above = 1.002	Comment = Resident 17

008872


-------
0	2	4	6

8	10 12 14

16 18 20 22 24

Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 2.307
GSD = 1.600
% Above = 0.090

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 18


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 19


-------
Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 2.069	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Research

% Above = 0.040	Comment = Resident 20

008875


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 21


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 22


-------
4	5	6	7

8	9	10 11 12

Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research
Comment = Resident 23


-------
Prob. Distribution (%)

Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 1.728	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Research
% Above = 0.009

008879


-------
Prob. Distribution (%)
100

4 5 6 7 8
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 1.663
GSD= 1.600
% Above = 0.007

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008880


-------
Prob. Distribution (%)

Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 5.061	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Research
% Above = 7.365

008881


-------
Prob. Distribution (%)

Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 1.932	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Research
% Above = 0.023

008882


-------
Prob. Distribution (%)

100r

Comment — Resident 28

8 10 12 14 16 18 20 22 24
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 2.172
GSD= 1.600
% Above = 0.058

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008883


-------
Prob. Distribution (%)
100

4 5 6 7 8
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 1.798
GSD= 1.600
% Above = 0.013

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008884


-------
Prob. Distribution (%)
100

4 5 6 7 8
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 1.680
GSD= 1.600
% Above = 0.007

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008885


-------
Prob. Distribution (%)

100r

Comment ~ Resident 31

8 10 12 14 16 18 20 22 24
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 2.307
GSD= 1.600
% Above = 0.090

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008886


-------
Prob. Distribution (%)
100

4 5 6 7 8
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 2.095
GSD= 1.600
% Above = 0.044

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008887


-------
Prob. Distribution (%)

Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 1.679	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Research
% Above = 0.007

008888


-------
Prob. Distribution (%)

100r

Comment - Resident 34

8 10 12 14 16 18 20 22 24
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 2.494
GSD= 1.600
% Above = 0.157

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008889


-------
Prob. Distribution (%)
100

4 5 6 7 8
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 2.092
GSD= 1.600
% Above = 0.044

ent -r Resident 35
9 10 11 12

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008890


-------
Prob. Distribution (%)
100

4 5 6 7 8
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean =1.721
GSD= 1.600
% Above = 0.009

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008891


-------
Prob. Distribution (%)

Blood Pb Cone (u«® Lament = Resident 37

Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 33.962	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Research

% Above = 99.536

Environmental exposures associated with blood lead levels above 30 ug/dl are above
the range of values that have been used in the calibration and empirical validation of
this model. (Zaragoza, L. and Hogan, K 1998. The Integrated Exposure Uptake
Biokinetic Model for Lead In Children: Independent Validation and Verification.
Environmental Health Perspectives 106 (supplement 6). p. 1555)

008892


-------
Prob. Distribution (%)
100

8 10 12 14 16
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 3.645
GSD= 1.600
% Above =1.588

22 24

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008893


-------
Prob. Distribution (%)

100r

12 15 18 21 24 27
Blood Pb Cone (ug/dL)

30 33

Cutoff = 10.000 ug/dl
Geo Mean = 5.749
GSD= 1.600
% Above =11.943

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008894


-------
Prob. Distribution (%)
100

12 15 18 21 24 27
Blood Pb Cone (ug/dL)

30 33

Cutoff = 10.000 ug/dl
Geo Mean = 4.599
GSD= 1.600
% Above = 4.919

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008895


-------
Prob. Distribution (%)

100r

50

25

Comment ~ Resident II

12 16 20 24 28 32
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 6.910
GSD= 1.600
% Above = 21.578

36 40 44 48

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008896


-------
Prob. Distribution (%)

Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 1.859	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Research
% Above = 0.017

008897


-------
Prob. Distribution (%)

Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 1.608	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Research
% Above = 0.005

008898


-------
Prob. Distribution (%)
100

4 5 6 7 8
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 1.887
GSD= 1.600
% Above = 0.019

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008899


-------
Prob. Distribution (%)

100r

Comment — Resident 45

8 10 12 14 16 18 20 22 24
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 2.345
GSD= 1.600
% Above = 0.101

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008900


-------
Prob. Distribution (%)
100

4 5 6 7 8
Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 1.795
GSD= 1.600
% Above = 0.013

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Research

008901


-------
Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 2.903	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Site Risk Assessment

% Above = 0.425	Comment = GW1

008902


-------
Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 2.984	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Site Risk Assessment

% Above = 0.505	Comment = GW2

008903


-------
Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 2.871	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Site Risk Assessment

% Above = 0.397	Comment = GW3

008904


-------
Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 2.779	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Site Risk Assessment

% Above = 0.322	Comment = GW5

008905


-------
Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 3.711	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Site Risk Assessment

% Above =1.748	Comment = GW8

008906


-------
Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 2.819	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Site Risk Assessment

% Above = 0.353	Comment = GW11

008907


-------
Appendix H
Adult Lead Modeling

008908


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
008909

FEBRUARY 2006


-------
Summary of Blood Lead Concentrations (PbBs)

Risk Estimations

008910


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
008911

FEBRUARY 2006


-------
Table H

Summary of Blood Lead Concentrations (PbBs) Risk Estimations
Tar Creek, Miami, OK

Resident

Geo Mean

%Above

1

1.768

1.4%

2

1.773

1.4%

3 **

58400

100%

4

1.825

1.5%

5 **

58400

100%

6

1.780

1.4%

7

1.951

1.8%

8

1.805

1.5%

9

1.823

1.5%

10

1.802

1.4%

11

1.863

1.6%

12

1.756

1.3%

13

1.829

1.5%

14

2.147

2.4%

15

1.766

1.4%

16

1.755

1.3%

17

2.165

2.5%

18

1.899

1.7%

19

1.740

1.3%

20

1.841

1.5%

21

1.824

1.5%

22

1.824

1.5%

23

1.804

1.5%

24

1.758

1.3%

25

1.742

1.3%

26

2.631

4.2%

27

1.808

1.5%

28

1.866

1.6%

29

1.775

1.4%

30

1.746

1.3%

31

1.900

1.7%

32

1.847

1.6%

33

1.746

1.3%

34

1.946

1.8%

35

1.846

1.6%

36

1.756

1.3%

38

2.243

2.7%

39

2.830

5.0%

40

2.501

3.7%

41

3.181

6.7%

42

1.790

1.4%

43

1.729

1.3%

44

1.796

1.4%

45

1.909

1.7%

46

1.774

1.4%

Note:

** Resident on BIA land

C^Exceeds the blood lead goal as described in the 1994 OSWER
Directive of no more than 5% of children exceeding 10 ug/dL blood lead.

008912


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
008913

FEBRUARY 2006


-------
Table H-1 (Rags D Adult Lead Worksheet)

008914


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
008915

FEBRUARY 2006


-------
TABLE H-l (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Resl, 61500 E. 57 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

29.625

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetric mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

61500 E. 57 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year (central
tendency value obtained from undated EPA Region 6 Memorandum)
was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993) guidance
for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 29.6 mg/kg in soil results in 1.4% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as described
in the 1994 OS WER Directive of no more than 5% of children (fetuses
of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfund's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res1

008916


-------
TABLE H-2 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_2, 51496 E. 57 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

31.64

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetric mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

51496 E. 57 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year (central
tendency value obtained from undated EPA Region 6 Memorandum)
was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993) guidance
for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 31.6 mg/kg in soil results in 1.4% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as described
in the 1994 OS WER Directive of no more than 5% of children (fetuses
of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfund's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res2

008917


-------
TABLE H-3 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_3, 5671 S. 630 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

29.075

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetric mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

5671 S. 630 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year (value
obtained from undated EPA Region 6 Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the ingestion rate of 400 mg/day was based on Harper et al. (2002).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 29.075 mg/kg in soil and ingestion of locally gathered
food items result in 100% of subsistence residents above a blood lead
level of 10 ug/dL. The geometric mean blood lead level = 58,400
ug/dL. This exceeds the blood lead goal as described in the 1994
OSWER Directive of no more than 5% of children (fetuses of exposed
women) exceeding 10 ug/dL blood lead.



Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfund's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

(3)	Flarper et al. 2002. The Spokane Tribe's Multipathway Subsistence Exposure Scenario and Screening Level RME.
Risk Analysis. VOl. 22. No. 3.

Res3

008918


-------
TABLE H-4 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_4, 62301 E. 57 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

54.25

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetric mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

62301 E. 57 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 54.3 mg/kg in soil results in 1.5% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res4

008919


-------
TABLE H-5 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_5, 4200 S. 620 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

88.4

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetric mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

4200 S. 620 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year (value
obtained from undated EPA Region 6 Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the ingestion rate of 400 mg/day was based on Harper et al. (2002).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 88.4 mg/kg in soil and ingestion of locally gathered food
items result in 100% of subsistence residents above a blood lead level of
10 ug/dL. The geometric mean blood lead level = 58,400 ug/dL. This
exceeds the blood lead goal as described in the 1994 OSWER Directive
of no more than 5% of children (fetuses of exposed women) exceeding
10 ug/dL blood lead.



Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfund's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

(3)	Flarper et al. 2002. The Spokane Tribe's Multipathway Subsistence Exposure Scenario and Screening Level RME.
Risk Analysis. VOl. 22. No. 3.

Res5

008920


-------
TABLE H-6 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_6, 54801 E. 30 Rd. )
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

34.55

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetric mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

54801 E. 30 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 34.6 mg/kg in soil results in 1.4% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res6

008921


-------
TABLE H-7 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_7, 2811 S. 550 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

109

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetric mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

2811 S. 550 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 109.0 mg/kg in soil results in 1.8% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 2.0 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res7

008922


-------
TABLE H-8 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_8, 54501 E. 40 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

45.44

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetric mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

54501 E. 40 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 45.4 mg/kg in soil results in 1.5% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res8

008923


-------
TABLE H-9 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_9, 63040 E. 16 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

53.3

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetric mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

63040 E. 16 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 53.3 mg/kg in soil results in 1.5% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res9

008924


-------
TABLE H-10 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (ReslO, 63470 E. 40 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

44.25

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

63470 E. 40 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 44.3 mg/kg in soil results in 1.4% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

ReslO

008925


-------
TABLE H-ll (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Resll, 63430 E. 40 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

71

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

63430 E. 40 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 71.0 mg/kg in soil results in 1.6% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.9 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res11

008926


-------
TABLE H-12 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_12, 63401 E. 10 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

24.5

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

63401 E. 10 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 24.5 mg/kg in soil results in 1.3% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res12

008927


-------
TABLE H-13 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_13, 63501 E. 10 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

56

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

63501 E. 10 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 56.0 mg/kg in soil results in 1.5% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res13

008928


-------
TABLE H-14 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_14, 63451 E. 40 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

194.25

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

63451 E. 40 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 194.3 mg/kg in soil results in 2.4% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 2.1 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res14

008929


-------
TABLE H-15 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_15, 63400 E. 40 Rd. )
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

28.75

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

63400 E. 40 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 28.8 mg/kg in soil results in 1.4% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res15

008930


-------
TABLE H-16 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_16, 63150 E. 40 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

24

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

63150 E. 40 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 24.0 mg/kg in soil results in 1.3% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res16

008931


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TABLE H-17 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_17, 2501 S. 550 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

202

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

2501 S. 550 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 202.0 mg/kg in soil results in 2.5% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 2.2 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res17

008932


-------
TABLE H-18 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_18, 2601 S. 550 Rd. )
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

86.3

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

2601 S. 550 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 86.3 mg/kg in soil results in 1.7% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.9 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res18

008933


-------
TABLE H-19 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_19, 54600 E. 40 Rd. )
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

17.3

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

54600 E. 40 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 17.3 mg/kg in soil results in 1.3% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.7 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res19

008934


-------
TABLE H-20 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_20, 3800 S. 630 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

61.25

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

3800 S. 630 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 61.3 mg/kg in soil results in 1.5% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res20

008935


-------
TABLE H-21 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_21, 2300 S. 590 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

53.8

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

2300 S. 590 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 53.8 mg/kg in soil results in 1.5% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res21

008936


-------
TABLE H-22 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_22, 59505 E. 40 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

54.1

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

59505 E. 40 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 54.1 mg/kg in soil results in 1.5% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res22

008937


-------
TABLE H-23 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_23, 62401 E. 50 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

45.2

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

62401 E. 50 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 45.2 mg/kg in soil results in 1.5% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res23

008938


-------
TABLE H-24 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_24, 63450 E. 30 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

25.25

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

63450 E. 30 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 25.3 mg/kg in soil results in 1.3% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res24

008939


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TABLE H-25 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_25, 5301 S. 620 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

18.4

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

5301 S. 620 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 18.4 mg/kg in soil results in 1.3% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.7 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res25

008940


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TABLE H-26 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_26, 4990 S. 620 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

404.75

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

4990 S. 620 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 404.8 mg/kg in soil results in 4.2% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 2.6 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res26

008941


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TABLE H-27 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_27, 63349 E. 16 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

46.75

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

63349 E. 16 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 46.8 mg/kg in soil results in 1.5% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res27

008942


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TABLE H-28 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_28, 63350 E. 16 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

72.25

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

63350 E. 16 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 72.3 mg/kg in soil results in 1.6% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.9 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res28

008943


-------
TABLE H-29 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_29, 5401 S. 620 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

32.5

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

5401 S. 620 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 32.5 mg/kg in soil results in 1.4% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res29

008944


-------
TABLE H-30 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_30, 5401 S. 620 Rd. (trailer))
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

20.2

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

5401 S. 620 Rd. (trailer)

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 20.2 mg/kg in soil results in 1.3% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.7 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res30

008945


-------
TABLE H-31 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_31, 62610 E. 60 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

86.75

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

62610 E. 60 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 86.8 mg/kg in soil results in 1.7% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.9 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res31

008946


-------
TABLE H-32 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_32, 62612 E. 60 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

64

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

62612 E. 60 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 64.0 mg/kg in soil results in 1.6% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res32

008947


-------
TABLE H-33 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_33, 3195 S. 550 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

19.8

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

3195 S. 550 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 19.8 mg/kg in soil results in 1.3% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.7 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res33

008948


-------
TABLE H-34 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_34, 56600 E. HWY 69 )
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

106.85

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

56600 E. HWY 69

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 106.9 mg/kg in soil results in 1.8% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.9 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res34

008949


-------
TABLE H-35 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_35, 56600 E. HWY 69 )
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

63.4

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

56600 E. HWY 69

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 63.4 mg/kg in soil results in 1.6% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res35

008950


-------
TABLE H-36 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_36, 3750 E. 40 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

24.5

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

3750 E. 40 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 24.5 mg/kg in soil results in 1.3% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res36

008951


-------
TABLE H-37 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_37, 61210 E. 20 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

7470

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

61210 E. 20 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 7470.0 mg/kg in soil results in 73.8% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 18.9 ug/dL. This exceeds the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

500 ppm in accordance with OU 2.

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res37

008952


-------
TABLE H-38 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_38, 55200 E. 50 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

235.75

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

55200 E. 50 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 235.8 mg/kg in soil results in 2.7% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 2.2 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res38

008953


-------
TABLE H-39 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_39, 57995 E. 40 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

491

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

57995 E. 40 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 491.0 mg/kg in soil results in 5.0% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 2.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res39

008954


-------
TABLE H-40 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_40, 56801 E. 20 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

348

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

56801 E. 20 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 348.0 mg/kg in soil results in 3.7% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 2.5 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res40

008955


-------
TABLE H-41 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_41, 56900 E. 20 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

643.3

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

56900 E. 20 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 643.3 mg/kg in soil results in 6.7% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 3.2 ug/dL. This exceeds the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

500 ppm in accordance with OU 2.

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res41

008956


-------
TABLE H-42 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_42, 62350 E. 30 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

39

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

62350 E. 30 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 39.0 mg/kg in soil results in 1.4% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res42

008957


-------
TABLE H-43 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_43, 6800 S. 572 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

12.64

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

6800 S. 572 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 12.6 mg/kg in soil results in 1.3% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.7 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res43

008958


-------
TABLE H-44 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_44, 6751 S. 572 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

41.9

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

6751 S. 572 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 41.9 mg/kg in soil results in 1.4% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res44

008959


-------
TABLE H-45 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_45, 4671 S. 620 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

90.8

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

4671 S. 620 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 90.8 mg/kg in soil results in 1.7% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.9 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res45

008960


-------
TABLE H-46 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4 (Res_46, 4631 S. 620 Rd.)
Receptor: Adult Resident, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

32.25

mg/kg

Avg Measured at Yard

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetic mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

4631 S. 620 Rd.

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; the default residential exposure frequency of 350 days/year
(central tendency value obtained from undated EPA Region 6
Memorandum) was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 32.3 mg/kg in soil results in 1.4% of general public
residents above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 1.8 ug/dL. This meets the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.

Not needed

Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from Phases 1 and 2 of the
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and RME-Draft.

Res46

008961


-------
TABLE H-47 (RAGS D ADULT LEAD WORKSHEET)

Site Name: Tar Creek, Operable Unit 4
Receptor: Adolescent Recreator, Exposure to Media as Described

1. Lead Screening Questions

Medium

Lead Concentration
used in Model Run

Basis for Lead
Concentration Used For
Model Run

Lead Screening
Concentration

Basis for Lead Screening
Level

Value

Units

Value

Units

Soil

3461

mg/kg

Avg Measured

NA

mg/kg

NA

2. Lead Model Questions

Question

Response for Residential Lead Model

What lead model was used? Provide reference and version

EPA Adult Lead Model, Version date 05/19/03

If the EPA Adult Lead Model (ALM) was not used provide
rationale for model selected.

~

Where are the input values located in the risk assessment report?

Appendix H.

What statistics were used to represent the exposure concentration
terms and where are the data on concentrations in the risk
assessment that support use of these statistics?

Arithmetric mean concentration of exposure area; data presented in
Appendix H.

What was the point of exposure and location?

Chat Pile Material and Tailings

Where are the output values located in the risk assessment report?

Appendix H

What GSD value was used? If this is outside the recommended
range of 1.8-2.1), provide rationale in Appendix .

Default GSDs of 2.1 and 2.3 for homogeneous and heterogeneous
population, respectively (EPA, 2002).

What baseline blood lead concentration (PbBO) value was used? If
this is outside the default range of 1.7 to 2.2 provide rationale in
Appendix 

Default PbBO of 1.7 for heterogeneous population (EPA, 2002).

Was the default exposure frequency (EF; 219 days/year) used?

No; 184 days/year, the average total number of days without rain and
above freezing for the years between 1999 and 2003, was used.

Was the default BKSF used (0.4 ug/dL per ug/day) used?

Yes

Was the default absorption fraction (AF; 0.12) used?

Yes

Was the default soil ingestion rate (IR; 50 mg/day) used?

No; the central tendency value was based on U.S. EPA (1993)
guidance for adult (non-contact residential scenario).

If non-default values were used for any of the parameters listed
above, where are the rationale for the values located in the risk
assessment report?

Appendix H.

Medium

Result

Comment/PRG 1

Soil

Input value of 3461 mg/kg in soil results in 22.3% of adolescent
recreators above a blood lead level of 10 ug/dL. The geometric mean
blood lead level = 5.9 ug/dL. This exceeds the blood lead goal as
described in the 1994 OSWER Directive of no more than 5% of
children (fetuses of exposed women) exceeding 10 ug/dL blood lead.



Reference

(1)	EPA. 2002. Blood Lead Concentrations of U.S> Adult Females: Summary Statistics from
National Health and Nutrition Evaluation Survey (NHANES III).

(2)	EPA. 1993. Superfimd's Standard Default Exposure Factors for the Central Tendency and

Recreator

Phases 1 and 2 of the
RME-Draft.

008962


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

U SEPA\317950\T7\RA04\D RAFT_2005-1028
008963

OCTOBER 2005


-------
Calculations of Blood Lead
Concentrations(PbBs)

008964


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

U SEPA\317950\T7\RA04\D RAFT_2005-1028
008965

OCTOBER 2005


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_l

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

29.6

29.6

29.6

29.6

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.8

6.3

4.8

6.3

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.4%

0.4%

1.4%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Resl

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008966


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_2

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

31.6

31.6

31.6

31.6

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.8

6.3

4.8

6.3

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.4%

0.4%

1.4%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_2

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008967


-------
Calculations of Blood Lead Concentrations (PbRs) -Res_3

Revised 02/09/2006

Calculations of Blood Lead Concentrations (PbBs)

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee

Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Harper et al., 2002
(high beef diet)

Harper et al., 2002
(high fish diet)

EFH (EPA, 1996)

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

29.1

29.1

29.1

29.1

29.1

29.1

S PbF*IRF =

X

X

Sum of Food lead concentration times ingestion rate

ug/day

822332.2

822332.2

822583.2

822583.2

344102.5

344102.5

BKSF

X

X

Biokinetic Slope Factor

ug/dL per ug/day

0.4

0.4

0.4

0.4

0.4

0.4

GSDj

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.400

0.400

0.400

0.400

0.400

0.400

afsd

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

0.12

0.12

EFs,d

X

X

Exposure frequency (same for soil and dust)

days/yr

350

350

350

350

350

350

EFf

X

X

Exposure frequency (food ingestion)

days/yr

365

365

365

365

365

365

ATs,d

X

X

Averaging time (same for soil, dust, food ingestion)

days/yr

365

365

365

365

365

365

PbBadult

PbB of adult worker, geometric mean

ug/dL

39,474.0

39,474.2

39,486.0

39,486.2

16,519.0

16,519.2

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

10.0

10.0

P(PbBfetal > PbBt)

Pr obability that fetal PbB > FbB„ assuming lognormal distribution

*

100.0%

100.0%

100.0%

100.0%

100.0%

100.0%

1 Equation 1 does not apportion exposure between soil and dust ingestion (excludes Ws, KSD).
When IRS = IR^d and Ws = 1.0, the equations yield the same PbBfetai>0.95-

* Equation 1, based on Eq. 1, 2 in USEPA (1996).	

I	PbB adult =	(PbS*BKSF*IRs+D*AFs D*EFs/ATs.D) + (PbF*BKSF*IRf*AFf**EFf/ATF) + PbB0

S PbF*IRF =	PbF 1 *IRF1 + PbF2*IRF2 +PbF3 *IRF3 +PbF4*IRF4





EPC

Basis

PbFl

Food lead concentration (Food Item 1 - Small Mammals)

Ug/g or ppm

3.8E+02

Modeled

PbF2

Food lead concentration (Food Item 2 - Beef)

ug/g or ppm

1.2E-01

Modeled

PbF3

Food lead concentration (Food Item 3 - Aquatic Biota)

ug/g or ppm

1.6E+00

Modeled

PbF4

Food lead concentration (Food Item 4 - Fish)

ug/g or ppm

4.3E-01

Mean Measured

PbF5

Food lead concentration (Food Item 5 - Asparagus [above ground])

ug/g or ppm

1.9E+01

Avg Measured

PbF6

Food lead concentration (Food Item 6 - Asparagus [root])

ug/g or ppm

5.6E+02

Avg Measured

PbF7

Food lead concentration (Food Item 7 - Willow [above ground])

ug/g or ppm

1.1E+01

Avg Measured

PbF8

Food lead concentration (Food Item 8 - Willow [root])

ug/g or ppm

1.0E+03

Avg Measured

PbF9

Food lead concentration (Food Item 9 - Cattail [above ground])

ug/g or ppm

2.9E+02

Avg Measured

PbFlO

Food lead concentration (Food Item 10 - Cattail [root])

ug/g or ppm

1.1E+03

Avg Measured



Harper et al., 2002

EFH
(EPA, 1996)

High Beef Diet

High Fish Diet

IRfi

Food Iteml ingestion rate - Small Mammals

g/day

50

50

15.3

irF2

Food Item2 ingestion rate - Beef

g/day

885

100

169.5

IRf3

Food Item3 ingestion rate - Aquatic Biota

g/day

175

175

42.5

IRf4

Food Item4 ingestion rate - Fish

g/day

75

885

127.5

IRf5

Food Item5 ingestion rate - Asparagus [above ground]

g/day

270

270

113.7

IRf6

Food Item6 ingestion rate - Asparagus [root]

g/day

270

270

113.7

IRf7

Food Item7 ingestion rate - Willow [above ground]

g/day

270

270

113.7

IRf8

Food Item8 ingestion rate - Willow [root]

g/day

270

270

113.7

IRf9

Food Item9 ingestion rate - Cattail [above ground]

g/day

270

270

113.7

iRfio

Food Iteml 0 ingestion rate - Cattail [root]

g/day

270

270

113.7

References:

Harper et al. 2002. The Spokane Tribe's Multipathway Subsistence Exposure Scenario and Screening Level RME. Risk Analysis. VOL 22. No. 3.
EPA 1997: Exposure Factors Handbook. EPA/600/P-95/002Fa.

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008968

Printed 02/09/2006 12:47 PM


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_4

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

54.3

54.3

54.3

54.3

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.0

6.5

5.0

6.5

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.5%

0.5%

1.5%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_4

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008969


-------
Calculations of Blood Lead Concentrations (PbRs) -Res_5

Revised 02/09/2006

Calculations of Blood Lead Concentrations (PbRs)

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee

Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Harper et al., 2002
(high beef diet)

Harper et al., 2002
(high fish diet)

EEH (EPA, 1996)

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/gorppm

88.4

88.4

88.4

88.4

88.4

88.4

S PbF*IRF =

X

X

Sum of Food lead concentration times ingestion rate

ug/day

822332.2

822332.2

822583.2

822583.2

344102.5

344102.5

BKSF

X

X

Biokinetic Slope Factor

ug/dL per ug/day

0.4

0.4

0.4

0.4

0.4

0.4

GSDj

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.400

0.400

0.400

0.400

0.400

0.400

afsd

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

0.12

0.12

EFs,d

X

X

Exposure frequency (same for soil and dust)

days/yr

350

350

350

350

350

350

EFf

X

X

Exposure frequency (food ingestion)

days/yr

365

365

365

365

365

365

ATs>d

X

X

Averaging time (same for soil, dust, food ingestion)

days/yr

365

365

365

365

365

365

PbBadult

PbB of adult worker, geometric mean

ug/dL

39,475.1

39,475.3

39,487.1

39,487.3

16,520.0

16,520.2

PbRt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

10.0

10.0

P(PbBfetal > PbBt)

Probability that fetal PbB > PbBt, assuming lognormal distribution

*

100.0%

100.0%

100.0%

100.0%

100.0%

100.0%

1 Equation 1 does not apportion exposure between soil and dust ingestion (excludes Ws, Kgo).
When IRS = IRs+d and Ws = 1.0, the equations yield the same PbBfetal 0.95-

*Equation 1, based on Eq. 1,2 in USEPA (1996).	

I	PbB adult =	(PbS*BKSF*IRs+D*AFs D*EFs/ATs.D) + (PbF*BKSF*IRF*AFf**EFf/ATF) + PbB0

E PbF* IRf =	PbFl *IRF1 + PbF2*IRF2 +PbF3*rRF3 +PbF4 *IRF4





EPC

Basis

PbFl

Food lead concentration (Food Item 1 - Small Mammals)

Ug/gorppm

3.8E+02

Modeled

PbF2

Food lead concentration (Food Item 2 - Beef)

ug/gorppm

1.2E-01

Modeled

PbF3

Food lead concentration (Food Item 3 - Aquatic Biota)

ug/gorppm

1.6E+00

Modeled

PbF4

Food lead concentration (Food Item 4 - Fish)

ug/gorppm

4.3E-01

Mean Measured

PbF5

Food lead concentration (Food Item 5 - Asparagus [above ground])

ug/gorppm

1.9E+01

Avg Measured

PbF6

Food lead concentration (Food Item 6 - Asparagus [root])

ug/gorppm

5.6E+02

Avg Measured

PbF7

Food lead concentration (Food Item 7 - Willow [above ground])

ug/gorppm

1.1E+01

Avg Measured

PbF8

Food lead concentration (Food Item 8 - Willow [root])

ug/gorppm

1.0E+03

Avg Measured

PbF9

Food lead concentration (Food Item 9 - Cattail [above ground])

ug/gorppm

2.9E+02

Avg Measured

PbFlO

Food lead concentration (Food Item 10 - Cattail [root])

ug/gorppm

1.1E+03

Avg Measured



Harper et al., 2002

EFH
(EPA, 1996)

High Beef Diet

High Fish Diet

IRfi

Food Iteml ingestion rate - Small Mammals

g/day

50

50

15.3

irF2

Food Item2 ingestion rate - Beef

g/day

885

100

169.5

IRf3

Food Item3 ingestion rate - Aquatic Biota

g/day

175

175

42.5

IRf4

Food Item4 ingestion rate - Fish

g/day

75

885

127.5

IRf5

Food Item5 ingestion rate - Asparagus [above ground]

g/day

270

270

113.7

IRf6

Food Item6 ingestion rate - Asparagus [root]

g/day

270

270

113.7

IRf7

Food Item7 ingestion rate - Willow [above ground]

g/day

270

270

113.7

IRf8

Food Item8 ingestion rate - Willow [root]

g/day

270

270

113.7

IRf9

Food Item9 ingestion rate - Cattail [above ground]

g/day

270

270

113.7

IRfio

Food Item 10 ingestion rate - Cattail [root]

g/day

270

270

113.7

References:

Harper et al. 2002. The Spokane Tribe's Multipathway Subsistence Exposure Scenario and Screening Level RME. Risk Analysis. VOL 22. No. 3.
EPA 1997: Exposure Factors Handbook. EPA/600/P-95/002Fa.

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008970

Printed 02/09/2006 12:48 PM


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_6

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

34.6

34.6

34.6

34.6

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.8

6.3

4.8

6.3

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.4%

0.4%

1.4%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_6

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008971


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_7

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

109.0

109.0

109.0

109.0

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.8

2.0

1.8

2.0

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.3

6.9

5.3

6.9

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.6%

1.8%

0.6%

1.8%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_7

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008972


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_8

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

45.4

45.4

45.4

45.4

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.9

6.4

4.9

6.4

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.5%

0.5%

1.5%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_8

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008973


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_9

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

53.3

53.3

53.3

53.3

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.9

6.5

4.9

6.5

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.5%

0.5%

1.5%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_9

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008974


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_10

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

44.3

44.3

44.3

44.3

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.9

6.4

4.9

6.4

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.4%

0.5%

1.4%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_10

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008975


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_ll

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

71.0

71.0

71.0

71.0

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.7

1.9

1.7

1.9

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.1

6.6

5.1

6.6

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.6%

0.5%

1.6%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_l 1

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008976


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_12

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

24.5

24.5

24.5

24.5

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.7

6.2

4.7

6.2

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.3%

0.4%

1.3%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_12

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008977


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_13

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

56.0

56.0

56.0

56.0

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.0

6.5

5.0

6.5

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.5%

0.5%

1.5%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_13

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008978


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_14

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

194.3

194.3

194.3

194.3

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.9

2.1

1.9

2.1

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.9

7.6

5.9

7.6

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.9%

2.4%

0.9%

2.4%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_14

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008979


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_15

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

28.8

28.8

28.8

28.8

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.8

6.3

4.8

6.3

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.4%

0.4%

1.4%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_15

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008980


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_16

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

24.0

24.0

24.0

24.0

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.7

6.2

4.7

6.2

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.3%

0.4%

1.3%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_16

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008981


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_17

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

202.0

202.0

202.0

202.0

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

2.0

2.2

2.0

2.2

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

6.0

7.7

6.0

7.7

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

1.0%

2.5%

1.0%

2.5%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_17

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008982


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_18

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

86.3

86.3

86.3

86.3

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.7

1.9

1.7

1.9

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.2

6.7

5.2

6.7

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.6%

1.7%

0.6%

1.7%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_18

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008983


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_19

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

17.3

17.3

17.3

17.3

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.5

1.7

1.5

1.7

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.7

6.2

4.7

6.2

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.3%

0.4%

1.3%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_19

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008984


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_20

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

61.3

61.3

61.3

61.3

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.0

6.5

5.0

6.5

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.5%

0.5%

1.5%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_20

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008985


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_21

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

53.8

53.8

53.8

53.8

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.0

6.5

5.0

6.5

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.5%

0.5%

1.5%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_21

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008986


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_22

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

54.1

54.1

54.1

54.1

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.0

6.5

5.0

6.5

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.5%

0.5%

1.5%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_22

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008987


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_23

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

45.2

45.2

45.2

45.2

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.9

6.4

4.9

6.4

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.5%

0.5%

1.5%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_23

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008988


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_24

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

25.3

25.3

25.3

25.3

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.8

6.2

4.8

6.2

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.3%

0.4%

1.3%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_24

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008989


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_25

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

18.4

18.4

18.4

18.4

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.5

1.7

1.5

1.7

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.7

6.2

4.7

6.2

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.3%

0.4%

1.3%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_25

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008990


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_26

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

404.8

404.8

404.8

404.8

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

2.4

2.6

2.4

2.6

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

7.4

9.3

7.4

9.3

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

2.0%

4.2%

2.0%

4.2%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_26

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008991


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_27

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

46.8

46.8

46.8

46.8

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.9

6.4

4.9

6.4

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.5%

0.5%

1.5%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_27

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008992


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_28

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

72.3

72.3

72.3

72.3

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.7

1.9

1.7

1.9

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.1

6.6

5.1

6.6

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.6%

0.5%

1.6%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_28

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008993


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_29

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

32.5

32.5

32.5

32.5

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.8

6.3

4.8

6.3

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.4%

0.4%

1.4%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_29

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008994


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_30

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

20.2

20.2

20.2

20.2

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.5

1.7

1.5

1.7

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.7

6.2

4.7

6.2

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.3%

0.4%

1.3%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_30

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008995


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_31

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

86.8

86.8

86.8

86.8

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.7

1.9

1.7

1.9

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.2

6.7

5.2

6.7

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.6%

1.7%

0.6%

1.7%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_31

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008996


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_32

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

64.0

64.0

64.0

64.0

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.0

6.5

5.0

6.5

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.6%

0.5%

1.6%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_32

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008997


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_33

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

19.8

19.8

19.8

19.8

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.5

1.7

1.5

1.7

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.7

6.2

4.7

6.2

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.3%

0.4%

1.3%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_33

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008998


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_34

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

106.9

106.9

106.9

106.9

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.7

1.9

1.7

1.9

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.3

6.9

5.3

6.9

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.6%

1.8%

0.6%

1.8%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_34

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

008999


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_35

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

63.4

63.4

63.4

63.4

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.0

6.5

5.0

6.5

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.5%

1.6%

0.5%

1.6%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_35

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009000


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_36

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

24.5

24.5

24.5

24.5

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.7

6.2

4.7

6.2

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.3%

0.4%

1.3%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_36

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009001


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_37

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

7470.0

7470.0

7470.0

7470.0

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

18.7

18.9

18.7

18.9

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

57.0

66.9

57.0

66.9

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

75.8%

73.8%

75.8%

73.8%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes \*/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009002

Res_37

Printed 10/31/2005 2:22 PM


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_38

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

235.8

235.8

235.8

235.8

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

2.0

2.2

2.0

2.2

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

6.2

7.9

6.2

7.9

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

1.1%

2.7%

1.1%

2.7%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_38

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009003


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_39

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

491.0

491.0

491.0

491.0

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

2.6

2.8

2.6

2.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

8.0

10.0

8.0

10.0

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

2.6%

5.0%

2.6%

5.0%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_39

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009004


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_40

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

348.0

348.0

348.0

348.0

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

2.3

2.5

2.3

2.5

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

7.0

8.9

7.0

8.9

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

1.7%

3.7%

1.7%

3.7%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_40

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009005


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_41

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

643.3

643.3

643.3

643.3

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

3.0

3.2

3.0

3.2

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

9.1

11.3

9.1

11.3

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

3.8%

6.7%

3.8%

6.7%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_41

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009006


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_42

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

39.0

39.0

39.0

39.0

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.8

6.3

4.8

6.3

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.4%

0.4%

1.4%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_42

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009007


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_43

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

12.6

12.6

12.6

12.6

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.5

1.7

1.5

1.7

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.7

6.1

4.7

6.1

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.3%

0.4%

1.3%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_43

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009008


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_44

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

41.9

41.9

41.9

41.9

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.9

6.4

4.9

6.4

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.4%

0.4%

1.4%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_44

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009009


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_45

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

90.8

90.8

90.8

90.8

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.7

1.9

1.7

1.9

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

5.2

6.8

5.2

6.8

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.6%

1.7%

0.6%

1.7%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_45

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009010


-------
Calculations of Blood Lead Concentrations (PbBs) - Res_46

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee
Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/g or ppm

32.3

32.3

32.3

32.3

P-fetal/matemal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IR-s+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of II^+D ingested as outdoor soil



-

-

1.0

1.0

K-sd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efs>d

X

X

Exposure frequency (same for soil and dust?

days/yr

350

350

350

350

ats>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBa(iuit

PbB of adult worker, geometric mean

ug/dL

1.6

1.8

1.6

1.8

PbBfetal, 0.95

95th percentile PbB among fetuses of adult workers

ug/dL

4.8

6.3

4.8

6.3

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBj)

Probability that fetal PbB >PbBi, assuming lognormal distribution

%

0.4%

1.4%

0.4%

1.4%

1	Equation 1 does not apportion exposure between soil and dust ingestion (excludes ^/KSD).

When IRg = IRs+d and Ws = 1.0, the equations yield the same PhE^ 0 95.

2	Based on U.S. EPA (1993) guidance for adult (non-contact residential scenario)

"Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult = (PbS*BKSF*IRs+D*AFs,D*EFs/ATs.D) + PbB0



PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)



**Equation 2, alternate approach based on Eq. 1, 2, and A-19 in USEPA (1996).



p|)B _ PbS*BKSF*([(IRs+r,)*AFs*EFs*Ws]+[KSI,*(IRs+I1)*(l-Ws)*AFI*EFI1])/365+PbB„

r UE> adult

PbB f0t,lo95 = PbB„Jllt » (GSD,1 645 » R)

Res_46

Printed 10/31/2005 2:22 PM

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009011


-------
0	3	6	9

12 15 18 21

24 27 30 33 36

Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl
Geo Mean = 4.915
GSD = 1.600
% Above = 6.535

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Site Risk Assessment
Comment = Mean(Soil) - Max(Air)


-------
Prob. Distribution (%)
IOOt

50

25

12 15 18 21
Blood Pb Cone (ug/dL)

24

27

30

33

36

Cutoff = 10.000 ug/dl
Geo Mean = 4.790
GSD = 1.600
% Above = 5.866

Age Range = 0 to 84 months
Time Step = Every 4 Hours
Run Mode = Site Risk Assessment
Comment = Mean(Soil) - Mean(Air)

009013


-------
Appendix I
Future Blood Lead Levels

009014


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
009015

FEBRUARY 2006


-------
Table 1-1

Summary of Health Risks associated with Future Lead Exposure to Residential Child
Tar Creek, Miami, OK

Soil (mg/kg)

Ambient Air (ug/m3)

Geo Mean BLL

% Above Target Level

Maximum

18900

Maximum

0.18

57.42

99.999

Mean
(75th Percentile)

131

Maximum

0.18

2.319

0.094

009016


-------
Table 1-2

Summary of Health Risks associated with Future Lead Exposure to Residential Adult
Tar Creek, Miami, OK



Resident (General Public)

Resident

Subsistence)

Soil (mg/kg)

Geo Mean BLL

% Above Target Level

Geo Mean BLL

% Above Target Level

Maximum

18900

45.2

95.4

349.7

100

Mean

131

2.0

1.98

4.11

11.6

Median

45.6

-

-

2.54

3.82

009017


-------
Calculations of Blood Lead Concentrations (PbBs) - Future General Public (Max)

Revised 02/09/2006

Calculations of Blood Lead Concentrations (PbBs)

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee

Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/gorppm

18900

18900

18900

33066

n

^Metal/m ateraal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokmetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSDj

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IRs+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of IRg+D ingested as outdoor soil



-

-

1.0

1.0

Ksd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efS(D

X

X

Exposure frequency (same for soil and dust)

days/yr

350

350

350

350

ATs>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBaduIt

PbB of adult worker, geometric mean

ug/dL

45.0

45.2

45.0

77.8

PbBfetal( 0 95

95th percentile PbB among fetuses of adult workers

ug/dL

137.2

160.1

137.2

275.6

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBt)

Probability that fetal PbB > PbBt, assuming lognormal distribution

%

97.0%

95.4%

97.0%

99.0%

1 Equation 1 does not apportion exposure between soil and dust ingestion (excludes Ws, KSD).
When IRS = IRS+D and Ws =1.0, the equations yield the same PbEjetal 0 95.

*Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult —

(PbS*BKSF*IRs+D* AFS(D*EFS/ATS.D) + PbB0

PbB fetal 0 95 =

PbB,dult*(GSDiL645 *R)

"""Equation 2, alternate approach based on Eq. 1,2, and A-19 in USEPA (1996).

PbB adult —

PbS*BKSF*([(IRs+D )*AFS*EFS*WS]+[KSD*(IRS+D >*( 1 -Ws )*AFD*EFD] )/365+PbB0

PbB fetal 0 95 =

PbB,dult*(GSDiL645 *R)

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009018

Printed 02/09/2006 12:53 PM


-------
Calculations of Blood Lead Concentrations (PbBs) - Future General Public (Mean/75%)

Revised 02/09/2006

Calculations of Blood Lead Concentrations (PbBs)

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee

Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/gorppm

131

131

131

131

n

^Metal/m ateraal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokmetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSDj

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.050

0.050

-

-

IRs+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.050

0.050

Ws



X

Weighting factor; fraction of IRg+D ingested as outdoor soil



-

-

1.0

1.0

Ksd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efS(D

X

X

Exposure frequency (same for soil and dust)

days/yr

350

350

350

350

ATs>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBaduIt

PbB of adult worker, geometric mean

ug/dL

1.8

2.0

1.8

2.0

PbBfetal( 0 95

95th percentile PbB among fetuses of adult workers

ug/dL

5.5

7.1

5.5

7.1

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBt)

Probability that fetal PbB > PbBt, assuming lognormal distribution

%

0.7%

2.0%

0.7%

2.0%

1 Equation 1 does not apportion exposure between soil and dust ingestion (excludes Ws, KSD).
When IRS = IRS+D and Ws =1.0, the equations yield the same PbEjetal 0 95.

*Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult —

(PbS*BKSF*IRs+D* AFS(D*EFS/ATS.D) + PbB0

PbB fetal 0 95 =

PbB,dult*(GSDiL645 *R)

"""Equation 2, alternate approach based on Eq. 1,2, and A-19 in USEPA (1996).

PbB adult —

PbS*BKSF*([(IRs+D )*AFS*EFS*WS]+[KSD*(IRS+D >*( 1 -Ws )*AFD*EFD] )/365+PbB0

PbB fetal 0 95 =

PbB,dult*(GSDiL645 *R)

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009019

Printed 02/09/2006 12:54 PM


-------
Calculations of Blood Lead Concentrations (PbBs) - Future Subsistence Resident (Max)

Revised 02/09/2006

Calculations of Blood Lead Concentrations (PbBs)

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee

Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/gorppm

18900

18900

18900

18900

n

^Metal/m ateraal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokmetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSDj

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.400

0.400

-

-

IRs+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.400

0.400

Ws



X

Weighting factor; fraction of IRg+D ingested as outdoor soil



-

-

1.0

1.0

Ksd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efS(D

X

X

Exposure frequency (same for soil and dust)

days/yr

350

350

350

350

ATs>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBaduIt

PbB of adult worker, geometric mean

ug/dL

349.5

349.7

349.5

349.7

PbBfetal( 0 95

95th percentile PbB among fetuses of adult workers

ug/dL

1,065.9

1,238.6

1,065.9

1,238.6

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBt)

Probability that fetal PbB > PbBt, assuming lognormal distribution

%

100.0%

100.0%

100.0%

100.0%

1 Equation 1 does not apportion exposure between soil and dust ingestion (excludes Ws, KSD).
When IRS = IRS+D and Ws =1.0, the equations yield the same PbEjetal 0 95.

*Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult —

(PbS*BKSF*IRs+D* AFS(D*EFS/ATS.D) + PbB0

PbB fetal 0 95 =

PbB,dult*(GSDiL645 *R)

"""Equation 2, alternate approach based on Eq. 1,2, and A-19 in USEPA (1996).

PbB adult —

PbS*BKSF*([(IRs+D )*AFS*EFS*WS]+[KSD*(IRS+D >*( 1 -Ws )*AFD*EFD] )/365+PbB0

PbB fetal 0 95 =

PbB,dult*(GSDiL645 *R)

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009020

Printed 02/09/2006 12:54 PM


-------
Calculations of Blood Lead Concentrations (PbBs) - Future Subsistence Resident (Mean)

Revised 02/09/2006

Calculations of Blood Lead Concentrations (PbBs)

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee

Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/gorppm

131

131

131

131

n

^Metal/m ateraal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokmetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSDj

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.400

0.400

-

-

IRs+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.400

0.400

Ws



X

Weighting factor; fraction of IRg+D ingested as outdoor soil



-

-

1.0

1.0

Ksd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efS(D

X

X

Exposure frequency (same for soil and dust)

days/yr

350

350

350

350

ATs>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBaduIt

PbB of adult worker, geometric mean

ug/dL

3.9

4.1

3.9

4.1

PbBfetal( 0 95

95th percentile PbB among fetuses of adult workers

ug/dL

11.9

14.6

11.9

14.6

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBt)

Probability that fetal PbB > PbBt, assuming lognormal distribution

%

8.0%

11.6%

8.0%

11.6%

1 Equation 1 does not apportion exposure between soil and dust ingestion (excludes Ws, KSD).
When IRS = IRS+D and Ws =1.0, the equations yield the same PbEjetal 0 95.

*Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult —

(PbS*BKSF*IRs+D* AFS(D*EFS/ATS.D) + PbB0

PbB fetal 0 95 =

PbB,dult*(GSDiL645 *R)

"""Equation 2, alternate approach based on Eq. 1,2, and A-19 in USEPA (1996).

PbB adult —

PbS*BKSF*([(IRs+D )*AFS*EFS*WS]+[KSD*(IRS+D >*( 1 -Ws )*AFD*EFD] )/365+PbB0

PbB fetal 0 95 =

PbB,dult*(GSDiL645 *R)

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009021

Printed 02/09/2006 12:54 PM


-------
Calculations of Blood Lead Concentrations (PbBs) - Future Subsistence Resident (Median)

Revised 02/09/2006

Calculations of Blood Lead Concentrations (PbBs)

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee

Version date 05/19/03

Exposure
Variable

PbB
Equation1

Description of Exposure Variable

Units

Values for Non-Residential Exposure Scenario

Using Equation 1

Using Equation 2

1*

2**

GSDi = Horn

GSDi = Het

GSDi = Horn

GSDi = Het

PbS

X

X

Soil lead concentration

ug/gorppm

45.6

45.6

45.6

45.6

n

^Metal/m ateraal

X

X

Fetal/maternal PbB ratio



0.9

0.9

0.9

0.9

BKSF

X

X

Biokmetic Slope Factor

ug/dL per
ug/day

0.4

0.4

0.4

0.4

GSDj

X

X

Geometric standard deviation PbB



2.1

2.3

2.1

2.3

PbB0

X

X

Baseline PbB

ug/dL

1.5

1.7

1.5

1.7

IRS

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.400

0.400

-

-

IRs+d



X

Total ingestion rate of outdoor soil and indoor dust

g/day

-

-

0.400

0.400

Ws



X

Weighting factor; fraction of IRg+D ingested as outdoor soil



-

-

1.0

1.0

Ksd



X

Mass fraction of soil in dust



-

-

0.7

0.7

afs>d

X

X

Absorption fraction (same for soil and dust)



0.12

0.12

0.12

0.12

efS(D

X

X

Exposure frequency (same for soil and dust)

days/yr

350

350

350

350

ATs>d

X

X

Averaging time (same for soil and dust)

days/yr

365

365

365

365

PbBaduIt

PbB of adult worker, geometric mean

ug/dL

2.3

2.5

2.3

2.5

PbBfetal( 0 95

95th percentile PbB among fetuses of adult workers

ug/dL

7.1

9.0

7.1

9.0

PbBt

Target PbB level of concern (e.g., 10 ug/dL)

ug/dL

10.0

10.0

10.0

10.0

P(PbBfetal > PbBt)

Probability that fetal PbB > PbBt, assuming lognormal distribution

%

1.8%

3.8%

1.8%

3.8%

1 Equation 1 does not apportion exposure between soil and dust ingestion (excludes Ws, KSD).
When IRS = IRS+D and Ws =1.0, the equations yield the same PbEjetal 0 95.

*Equation 1, based on Eq. 1, 2 in USEPA (1996).

PbB adult —

(PbS*BKSF*IRs+D* AFS(D*EFS/ATS.D) + PbB0

PbB fetal 0 95 =

PbB,dult*(GSDiL645 *R)

"""Equation 2, alternate approach based on Eq. 1,2, and A-19 in USEPA (1996).

PbB adult —

PbS*BKSF*([(IRs+D )*AFS*EFS*WS]+[KSD*(IRS+D >*( 1 -Ws )*AFD*EFD] )/365+PbB0

PbB fetal 0 95 =

PbB,dult*(GSDiL645 *R)

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009022

Printed 02/09/2006 12:54 PM


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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
009023

FEBRUARY 2006


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 263
User Name: Hiroshi Awata
Date: 01/31/2006
Site Name: Tar Creek
Operable Unit: Operable Unit 4
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A j y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.180

1-2

2.000

3.000

32.000

0.180

2-3

3.000

5.000

32.000

0.180

3-4

4.000

5.000

32.000

0.180

4-5

4.000

5.000

32.000

0.180

5-6

4.000

7.000

32.000

0.180

6-7

4.000

7.000

32.000

0.180

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

3.160

1-2

2.600

2-3

2.870

3-4

2.740

4-5

2.610

5-6

2.740

6-7

2.990

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L
****** Soil & Dust ******

Multiple Source Analysis Used

Average multiple source concentration: 13248.000 ug/g
Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Max(s)-Max(a)	Revised 02/09/2006

009024


-------
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

18900.000

13248.000

1-2

18900.000

13248.000

2-3

18900.000

13248.000

3-4

18900.000

13248.000

4-5

18900.000

13248.000

5-6

18900.000

13248.000

6-7

18900.000

13248.000

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

Year

Air

Diet

Alternate

Water



(ug/day)

(ug/day)

(ug/day)

(ug/day)

.5-1

0.038

0.507

0.000

0.128

1-2

0.062

0.391

0.000

0.301

2-3

0.112

0.454

0.000

0.329

3-4

0.120

0.456

0.000

0.353

4-5

0.120

0.508

0.000

0.428

5-6

0.168

0.580

0.000

0.491

6-7

0.168

0.669

0.000

0.528

Year

Soil+Dust

Total

Blood



(ug/day)

(ug/day)

(ug/dL)

.5-1

129.137

129.810

59.6

1-2

192.582

193.337

67.7

2-3

202.259

203.153

64.7

3-4

212.808

213.737

63.8

4-5

184.541

185.598

56.7

5-6

180.654

181.894

50.9

6-7

180.117

181.482

46.9

Environmental exposures associated with blood lead levels above 30 |jg/dl are above
the range of values that have been used in the calibration and empirical validation of
this model. (Zaragoza, L. and Hogan, K. 1998. The Integrated Exposure Uptake
Biokinetic Model for Lead In Children: Independent Validation and Verification.
Environmental Health Perspectives 106 (supplement 6). p. 1555)

Max(s)-Max(a)
009025

Revised 02/09/2006


-------
LEAD MODEL FOR WINDOWS Version 1.0

Model Version: 1.0 Build 263
User Name: Hiroshi Awata
Date: 01/31/2006
Site Name: Tar Creek
Operable Unit: Operable Unit 4
Run Mode: Site Risk Assessment

The time step used in this model run: 1 - Every 4 Hours (6 times a day).

****** A j y ******

Indoor Air Pb Concentration: 30.000 percent of outdoor.
Other Air Parameters:

Age

Time

Ventilation

Lung

Outdoor Ai



Outdoors

Rate

Absorption

Pb Cone



(hours)

(mA3/day)

(%)

(ug Pb/mA3)

.5-1

1.000

2.000

32.000

0.180

1-2

2.000

3.000

32.000

0.180

2-3

3.000

5.000

32.000

0.180

3-4

4.000

5.000

32.000

0.180

4-5

4.000

5.000

32.000

0.180

5-6

4.000

7.000

32.000

0.180

6-7

4.000

7.000

32.000

0.180

****** Qjg^ ******

Age

Diet lntake(ug/day)

.5-1

3.160

1-2

2.600

2-3

2.870

3-4

2.740

4-5

2.610

5-6

2.740

6-7

2.990

****** Drinking Water ******

Water Consumption:
Age Water (L/day)

.5-1 0.200

1-2	0.500

2-3	0.520

3-4	0.530

4-5	0.550

5-6	0.580

6-7	0.590

Drinking Water Concentration: 4.000 ug Pb/L

****** Soil & Dust ******

Multiple Source Analysis Used

Average multiple source concentration: 109.700 ug/g

Mass fraction of outdoor soil to indoor dust conversion factor: 0.700
Mean,75%(s)-Max(a)	Revised 02/09/2006

009026


-------
Outdoor airborne lead to indoor household dust lead concentration: 100.000
Use alternate indoor dust Pb sources? No

Age Soil (ug Pb/g) House Dust (ug Pb/g)

.5-1

131.000

109.700

1-2

131.000

109.700

2-3

131.000

109.700

3-4

131.000

109.700

4-5

131.000

109.700

5-6

131.000

109.700

6-7

131.000

109.700

****** Alternate Intake ******
Age Alternate (ug Pb/day)

.5-1

0.000

1-2

0.000

2-3

0.000

3-4

0.000

4-5

0.000

5-6

0.000

6-7

0.000

****** Maternal Contribution: Infant Model ******

Maternal Blood Concentration: 2.500 ug Pb/dL

*****************************************

CALCULATED BLOOD LEAD AND LEAD UPTAKES:

*****************************************

Year Air	Diet	Alternate Water

(ug/day) (ug/day)	(ug/day) (ug/day)

.5-1

0.038

1.497

0.000

0.379

1-2

0.062

1.226

0.000

0.943

2-3

0.112

1.363

0.000

0.988

3-4

0.120

1.311

0.000

1.014

4-5

0.120

1.264

0.000

1.066

5-6

0.168

1.333

0.000

1.129

6-7

0.168

1.458

0.000

1.151

Year

Soil+Dust

Total

Blood





(ug/day)

(ug/day)

(ug/dL)



.5-1

2.882

4.795

2.6



1-2

4.555

6.785

2.8



2-3

4.588

7.050

2.6



3-4

4.623

7.068

2.5



4-5

3.467

5.917

2.1



5-6

3.135

5.765

1.8



6-7

2.967

5.745

1.7



Mean,75%(s)-Max(a)
009027

Revised 02/09/2006


-------
Prob. Distribution (%)

Cutoff = 10.000 ug/dl
Geo Mean = 2.319
GSD = 1.600
% Above = 0.094

10 12 14 16 18 20 22 24
Blood Pb Cone (ug/dL)

Age Range = 0 to 84 months

Time Step = Every 4 Hours

Run Mode = Research

Comment = Mean, 75%(Soil) - Max(Air)

009028


-------
Prob. Distribution (%)

Blood Pb Cone (ug/dL)

Cutoff = 10.000 ug/dl	Age Range = 0 to 84 months

Geo Mean = 57.420	Time Step = Every 4 Hours

GSD = 1.600	Run Mode = Research

% Above = 99.990	Comment = Max(Soil) - Max(Air)

Environmental exposures associated with blood lead levels above 30 ug/dl are above
the range of values that have been used in the calibration and empirical validation of
this model. (Zaragoza, L. and Hogan, K 1998. The Integrated Exposure Uptake
Biokinetic Model for Lead In Children: Independent Validation and Verification.

Environmental Health Perspectives 106 (supplement 6). p. 1555)

009029


-------
Appendix J
Statistical Elevation of Future Soil

Concentrations

009030


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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

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USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
009031

FEBRUARY 2006


-------
CH2MHILL

Appendix J

Technical Memorandum

Updated Statistical Evaluation of Future Soil Concentrations
Tar Creek Superfund Site, Operable Unit No. 4
Ottawa County, Oklahoma

Ursula Lennox/USEPA Region 6 RPM
CH2M HILL, Inc.

EPA Region 5 Response Action Contract No. 68-W6-0025,

Work Assignment No. 233-RKED-06JW
February 3, 2006

06-8499

The estimated future soil concentrations (with depletion) for cadmium, lead, and zinc were
evaluated for distributional fit and representative values for use in estimating future potential
exposures in the HHRA. Over 14,000 estimated concentrations were available (populating a
100-foot grid pattern over the OU4 area). These data were evaluated using three different
goodness-of-fit tests: the Kolmogorov-Smirnov test, the Cramer-von Mises test, and the
Anderson-Darling test. These were applied to five different distributions: the Normal, the
Lognormal, the Weibull distribution, the Gamma distribution, and the Exponential distribution
(note: the Kolmogorov-Smirnov test was not possible with the Weibull distribution). The results
are presented in Table 1. In each case, the parameters of the distributions were optimized to fit
the data as closely as possible.

Table 1: Goodness-of-Fit Tests for Formal
Distributions

Kolmogorov-

Cramer-von

Anderson-

Smirnov

Mises

Darling

Cadmium

Exponential

< 0.001

< 0.001

< 0.001

Gamma

< 0.001

< 0.001

< 0.001

Lognormal

< 0.01

< 0.005

< 0.005

Normal

< 0.01

< 0.005

< 0.005

Weibull

-

< 0.01

< 0.01

P:\USEPA\317950\T7\RA04\DRAFT FINAL_2006-02\APPENDICIES\	1	FEBRUARY2006

APPENDIXATC_HHRA_DRAFTFINALRA_APPENDIXJ_REVISED.DOC

PREPARED FOR:
PREPARED BY:
PREPARED UNDER:

DATE:

DCN NUMBER::

009032


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT
APPENDIX J: STATISTICAL ELEVATION FOR FUTURE SOIL CONCENTRATIONS

Table 1: Goodness-of-Fit Tests for Formal
Distributions

Kolmogorov-

Cramer-von

Anderson-

Smirnov

Mises

Darling

Lead

Exponential

< 0.001

< 0.001

< 0.001

Gamma

-

-

-

Lognormal

< 0.01

< 0.005

< 0.005

Normal

< 0.01

< 0.005

< 0.005

Weibull

-

< 0.01

< 0.01

Zinc

Exponential

< 0.001

< 0.001

< 0.001

Gamma

< 0.001

< 0.001

< 0.001

Lognormal

< 0.01

< 0.005

< 0.005

Normal

< 0.01

< 0.005

< 0.005

Weibull

-

< 0.01

< 0.01

The goodness-of-fit probabilities for the Gamma distribution are not provided for lead, since that
distribution was sufficiently unsuitable for the data that it was impossible to estimate the
specifics of the distribution, much less calculate goodness of fit. (Actually, this was the case
with all three constituents for the beta distribution, so beta was not included in the table at all).
Although the statistics appear near identical for each metal, they were calculated individually.
Note that all these probabilities are low, certainly all well below a significance level such as 0.05
which might be used to determine whether the distribution was a good fit. This lack of fit is at
least partly due to the very large sample size which makes these tests very powerful against
accepting a distributional assumption. Even given that, however, the distribution that appears to
fit the data best is the Weibull distribution which is described with the following probability
distribution function:

pdf = -]

p{p)

A-l

exp

fxv

P.

\iJ J

Where ? (gamma) is a shape parameter, and B (beta) is a scale parameter. The optimized values
for these two parameters for each metal are presented in Table 2.

Table 2: Parameters for Optimized Weibull Distributions



Cadmium

Lead

Zinc

gamma

1.03

0.690

1.07

beta

0.549

88.7

77.8

This fit can be visualized in the histograms presented in Figures 1, 2, and 3 for cadmium, lead,
and zinc, respectively. The superior fit of the Weibull distribution (bold overlayed curve)

P:\USEPA\317950\T7\RA04\DRAFTFINAL_2006-02\APPENDICIES\
APPENDIXATC_HHRA_DRAFTFINALRA_APPENDIXJ_REVISED.DOC
009033

2

FEBRUARY 2006


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT
APPENDIX J: STATISTICAL ELEVATION FOR FUTURE SOIL CONCENTRATIONS

relative to the normal and lognormal curves can be seen, even though there is some obvious lack
of fit to the data.

In addition to the large sample size, however, there appears to be other factors contributing to the
low goodness-of-fit probabilities, namely multimodal distributions within the data. These can be
viewed in histograms of log-transformed data as presented in Figures 4, 5, and 6 for cadmium,
lead, and zinc, respectively. These histograms suggest at least three distributions combining
together to form the overall data set. Gaining approximate concentrations of each of these three
modes help to portray the distributions. The approximations of these modes, and other overall
statistics of the data for each metal, are presented in Table 3.

Table 3: Summary Statistics (ppm) for Each Data Set



Cadmium

Lead

Zinc

Minimum

0.0206

0.870

3.81

25th Percentile

0.157

19.3

21.0

Median

0.307

45.6

45.4

75th Percentile

0.800

131

110

Maximum

4.61

18900

846



Mean

0.540

131

75.7



First Mode

0.0302

4.06

13.9

Second Mode

0.174

30.0

37.7

Third Mode

1.65

221

217

Given these statistics, and the observed indication of multimodal distributions, the most
trustworthy best estimates of these distributions may simply be the mean and perhaps the median
of these data. These values were used in the HHRA for evaluation of future soils to estimate
risks associated with this overall area.

P:\USEPA\317950\T7\RA04\DRAFT FINAL_2006-02\APPENDICIES\	3

APPENDIXATC_HHRA_DRAFTFINALRA_APPENDIXJ_REVISED.DOC
009034

FEBRUARY 2006


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TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT
APPENDIX J: STATISTICAL ELEVATION FOR FUTURE SOIL CONCENTRATIONS

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APPENDIXATC_HHRA_DRAFTFINALRA_APPENDIXJ_REVISED.DOC

009035


-------
Figures

009036


-------
TAR CREEK SUPERFUND SITE OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT
APPENDIX J: STATISTICAL ELEVATION FOR FUTURE SOIL CONCENTRATIONS

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P:\USEPA\317950\T7\RA04\DRAFT FINAL_2006-02\APPENDICIES\	6	FEBRUARY 2006

APPENDIXATC_HHRA_DRAFTFINALRA_APPENDIXJ_REVISED.DOC

009037


-------
Figure 1: Histogram and Distribution Curves for Cadmium

25

20

§15


-------
Figure 2: Histogram and Distribution Curves for Lead

c


-------
Figure 3: Histogram and Distribution Curves for Zinc

Concentration

Solid Line = Normal Curve; Dashed Line = Lognormal Curve; Bold Line = Weibull Curve

009040


-------
Figure 4: Histogram of Log Transformed Values for Cadmium

-4.00 -3.75 -3.50 -3.25 -3.00 -2.75 -2.50 -2.25 -2.00 -1.75 -1.50 -1.25 -1.00 -0.75 -0.50 -0.25 0.00 0.25 0.50 0.75 1.00 1.25 1.50

Log (Concentration, ppm)


-------
Figure 5: Histogram of Log Transformed Values for Lead

-0.2 0.2 0.6 1.0 1.4 1.8 2.2 2.6 3.0 3.4 3.8 4.2 4.6 5.0 5.4 5.8 6.2 6.6 7.0 7.4 7.8 8.2 8.6 9.0 9.4 9.8

Log (Concentration, ppm)

009042


-------
Figure 6: Histogram of Log Transformed Values for Zinc

11

10'

6
5

1.38 1.63 1.88 2.13 2.38 2.63 2.88 3.13 3.38 3.63 3.88 4.13 4.38 4.63 4.88 5.13 5.38 5.63 5.88 6.13 6.38 6.63

Log (Concentration, ppm)

009043


-------
Appendix K
Native American Risk Calculations

009044


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

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USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
009045

FEBRUARY 2006


-------
TABLE K-1

Comparison of Exposure Factors Used For Subsistence Resident Daily Intake Calculations

Tar Creek - Miami, OK





Exposure Factors

Exposure







Obtained from Harper et al.

Factors



Food Item

Units

High

High



Obtained from







Fish

Beef



EPA's Exposure







Diet

Diet

Note

Factors Handbook

Note

Fish

kg/day

0.885

0.075



0.128

(2)

Aquatic Food (Mussels, Crayfish)

kg/day

0.175

0.175



0.043

(2)

Small Game

kg/day

0.05

0.05



0.015

(3)

Beef

kg/day

0.10

0.885



0.170

(4)

Asparagus (above ground)

kg/day

0.27

0.27

(1)

0.114

(5)

Asparagus (root)

kg/day

0.27

0.27

(1)

0.114

(5)

Willow (above ground)

kg/day

0.27

0.27

(1)

0.114

(5)

Wllow (root)

kg/day

0.27

0.27

(1)

0.114

(5)

Cattail (above ground)

kg/day

0.27

0.27

(1)

0.114

(5)

Cattail (root)

kg/day

0.27

0.27

(1)

0.114

(5)

Units are presented each food item (kg)/day.

References:

Harper etal. 2002. The Spokane Tribe's Multipathway Subsistence Exposure Scenario and Screening Level RME. Risk Analysis. VOL 22. No.
EPA, 1997: Exposure Factors Handbook. EPA/600/P-95/002Fa.

Notes:

(1)	Composition of Total Plant Intake of 1,600 g/day was equally divided as follows:

Asparagus (above ground) -16.7%, (root) -16.7%

Willow (above ground) -16.7%, (root) -16.7%

Cattail (above ground) -16.7%, (root) -16.7%

(2)	Fish /aquatic organisms intake from Section 10.10.4 of EPA, 1997.

170 g/day total - 95th percentile

Assumed 75% fish, 25% aquatic organisms.

Fish: x 0.75 = 127.5 g/day. Aquatic Organisms: x 0.25 = 42.5 g/day.

(3)	small game intake from Table 11-6 of EPA, 1997.

0.255 g/kg-day - 100th percentile
x 60 kg body weight (per EPA, 1997) = 15.3 g/day

(4)	Beef intake from Table 11-3 of EPA, 1997.

2.825 g/kg-day - 95th percentile
x 60 kg body weight (per EPA, 1997) = 169.5 g/day

(5)	Vegetable intake from Table 9-4 of EPA, 1997.

11.37 g/kg-day - 95th percentile

Divide total by 6 for each of the 6 edible plant categories in the Tar
x 60 kg body weight (per EPA, 1997) = 682.2 g/day; divided by 6 =

Creek HHRA (see below).

113.7 g/day for each of 6 edible plant categories

009046

Page 1 of 1


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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

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USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
009047

FEBRUARY 2006


-------
TABLE K-2

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS USING EPA, 1997 ASSUMPTIONS FOR NATIVE AMERICANS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Receptor Population: Residential (Subsistence)
Receptor Age: Adult

Exposure Medium

Exposure Point

Exposure Route

Chemical of
Potential Concern

Cancer Risk Calculations

e Concentration

CSF/Unit Risk

Non-Cancer Hazard Calculations

Intake/Exposure Concentration

Surface Soil (residential,
smelter, transition zone)

Animal Tissue

Small Game
(Bird, Rabbit)

Cadmium

6.1E+02
2.8E+04

MG/KG
MG/KG

1.2E-01
5.5E+00

mg/kg/day
mg/kg/day

1/(mg/kg-day) I
1/(mg/kg-day) I

1.3E-07
6.0E-06

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

Exposure Point Total

Ingestion ICadmium

Exposure Point Total

1 0.0E+00

1.3E-02
1.4E+00

MG/KG
MG/KG

2.8E-05
3.0E-03

mg/kg/day
mg/kg/day

1/(mg/kg-day) I
1/(mg/kg-day) I

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

mg/kg/day
mg/kg/day

1.3E-04
2.0E-05

mg/kg/day I 3.1E-08
mg/kg/day I 1.1E-08

ixposure Medium Total

Surface Soil (residential, smelter, transition zone)Total

Revised 02/10/2006

009048

Page 1 of 2


-------
Timeframe: Current/Future
Receptor Population: Residential (Subsistence)
Receptor Age: Adult

TABLE K-2

CALCULATION OF CHEMICAL CANCER RISKS AND NON-CANCER HAZARDS USING EPA, 1997 ASSUMPTIONS FOR NATIVE AMERICANS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Exposure Medium

Exposure Point

Exposure Route

Chemical of
Potential Concern

Cancer Risk Calculations

e Concentration

CSF/Unit Risk

Non-Cancer Hazard Calculations

Intake/Exposure Concentration

Transition Zones

Asparagus (above ground)
Asparagus (root)

Ingestior
Ingestior

Cadmium
Cadmium

5.5E+00
1.4E+02
1.2E+01
1.4E+03

MG/KG
MG/KG
MG/KG
MG/KG

8.2E-03
2.1E-01
1.9E-02
2.1E+00

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)
1/(mg/kg-day)
1/(mg/kg-day)

8.9E-03
2.3E-01
2.0E-02
2.3E+00

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

1.0E-03
3.0E-01
1.0E-03
3.0E-01

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

Exposure Point Total

| Exp. Route Total

Willow (above ground)
Willow (root)

Ingestior
Ingestior

Cadmium
Cadmium

1.8E+01
4.7E+02
5.0E+01
4.6E+03

MG/KG
MG/KG
MG/KG
MG/KG

2.7E-02
7.0E-01
7.4E-02
6.9E+00

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)
1/(mg/kg-day)
1/(mg/kg-day)

2.9E-02
7.6E-01
8.1E-02
7.5E+00

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

1.0E-03
3.0E-01
1.0E-03
3.0E-01

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

Exposure Point Total

Exp. Route Total

Cattail (above ground)
Cattail (root)

Ingestion ICadmium
Ingestion |Cadmium

2.0E+01
2.6E+03
6.1E+01
4.4E+03

MG/KG
MG/KG
MG/KG
MG/KG

2.9E-02
3.8E+00
9.1E-02
6.5E+00

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)
1/(mg/kg-day)
1/(mg/kg-day)

3.2E-02
4.2E+00
1.0E-01
7.1E+00

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

1.0E-03
3.0E-01
1.0E-03
3.0E-01

mg/kg/day
mg/kg/day
mg/kg/day
mg/kg/day

Exposure Medium Total

Transition Zones Total

Exposure Point Total

Fish Tissue/Aquatic Food

Aquatic Food Tissue
(Mussels etc.)

Ingestion ICadmium

1.6E+00
7.8E+01

MG/KG
MG/KG

9.1E-04
4.4E-02

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

9.9E-04
4.8E-02

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

mg/kg/day
mg/kg/day

Exposure Point Total

Ingestion ICadmium

1.7E-01
2.1E+01

MG/KG
MG/KG

2.8E-04
3.6E-02

mg/kg/day
mg/kg/day

1/(mg/kg-day)
1/(mg/kg-day)

3.1E-04
3.9E-02

mg/kg/day
mg/kg/day

1.0E-03
3.0E-01

mg/kg/day
mg/kg/day

exposure Medium Total

'Vquatic Biota Total

Exposure Point Total

Revised 02/10/2006

009049

Page 2 of 2


-------
TABLE K-3

SUM MARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs USING EPA, 1997 ASSUMPTIONS FOR NATIVE AMERICANS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Receptor Population: Residential (Subsistence)
Receptor Age: Adult	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ (s)







Routes Total

Surface Soil (residential,

Animal Tissue

Small Game

Cadmium

NA

NA

NA

NA

Kidney

1.3E-04

NA

NA

1.3E-04

smelter, transition zone)



(Bird, Rabbit)

Zinc

NA

NA

NA

NA

Circulatory

2.0E-05

NA

NA

2.0E-05





Chemical Total

0.0E+00

NA

NA

0.0E+00



1.5E-04

NA

NA

1.5E-04





Beef (Cattle)

Cadmium

NA

NA

NA

NA

Kidney

3.1 E-08

NA

NA

3.1 E-08







Zinc

NA

NA

NA

NA

Circulatory

1.1 E-08

NA

NA

1.1 E-08





Chemical Total

0.0E+00

NA

NA

0.0E+00



4.2 E-08

NA

NA

4.2E-08



Exposure Medium Total

0.0E+00

NA

NA

0.0E+00



1.5E-04

NA

NA

1.5E-04

Surface Soil (residential, smelter, transition zone) Total

0.0E+00

NA

NA

0.0E+00



1.5E-04

NA

NA

1.5E-04



Plant Tissue

Asparagus (above ground)

Cadmium

NA

NA

NA

NA

Kidney

8.9E+00

NA

NA

8.9E+00

Transition Zones





Zinc

NA

NA

NA

NA

Circulatory

7.7E-01

NA

NA

7.7E-01





Asparagus (root)

Cadmium

NA

NA

NA

NA

Kidney

2.0E+01

NA

NA

2.0E+01







Zinc

NA

NA

NA

NA

Circulatory

7.6E+00

NA

NA

7.6E+00





Chemical Total

0.0E+00

NA

NA

0.0E+00



3.8E+01

NA

NA

3.8E+01





Willow (above ground)

Cadmium

NA

NA

NA

NA

Kidney

2.9E+01

NA

NA

2.9E+01







Zinc

NA

NA

NA

NA

Circulatory

2.5E+00

NA

NA

2.5E+00





Willow (root)

Cadmium

NA

NA

NA

NA

Kidney

8.1E+01

NA

NA

8.1E+01







Zinc

NA

NA

NA

NA

Circulatory

2.5E+01

NA

NA

2.5E+01





Chemical Total

0.0E+00

NA

NA

0.0E+00



1.4E+02

NA

NA

1.4E+02





Cattail (above ground)

Cadmium

NA

NA

NA

NA

Kidney

3.2E+01

NA

NA

3.2E+01







Zinc

NA

NA

NA

NA

Circulatory

1.4E+01

NA

NA

1.4E+01





Cattail (root)

Cadmium

NA

NA

NA

NA

Kidney

1.0E+02

NA

NA

1.0E+02







Zinc

NA

NA

NA

NA

Circulatory

2.4E+01

NA

NA

2.4E+01





Chemical Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



1.7E+02

NA

NA

1.7E+02



Exposure Medium Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



3.4E+02

NA

NA

3.4E+02

Transition Zones Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



3.4E+02

NA

NA

3.4E+02

Revised 02/10/2006	Page 1 of 2

009050


-------
TABLE K-3

SUM MARY OF RECEPTOR RISKS AND HAZARDS FOR COPCs USING EPA, 1997 ASSUMPTIONS FOR NATIVE AMERICANS
REASONABLE MAXIMUM EXPOSURE
Tar Creek, Miami, OK

Scenario Timeframe: Current/Future
Receptor Population: Residential (Subsistence)
Receptor Age: Adult	

Medium

Exposure

Exposure

Chemical



Carcinogenic Risk



Non-Carcinogenic Hazard Quotient







Medium

Point

of Potential

























Concern

Ingestion

Inhalation

Dermal

Exposure

Primary

Ingestion

Inhalation

Dermal

Exposure















Routes Total

Target Organ (s)







Routes Total

Aquatic Biota

Fish Tissue/

Aquatic Food Tissue

Cadmium

NA

NA

NA

NA

Kidney

9.9E-01

NA

NA

9.9E-01



Aquatic Food

(Mussels etc.)

Zinc

NA

NA

NA

NA

Circulatory

1.6E-01

NA

NA

1.6E-01





Chemical Total

0.0E+00

NA

NA

0.0E+00



1.2E+00

NA

NA

1.2E+00





Fish Tissue

Cadmium

NA

NA

NA

NA

Kidney

3.1 E-01

NA

NA

3.1 E-01







Zinc

NA

NA

NA

NA

Circulatory

1.3 E-01

NA

NA

1.3E-01





Chemical Total

0.0E+00

NA

NA

0.0E+00



4.4 E-01

NA

NA

4.4E-01



Exposure Medium Total

0.0E+00

NA

NA

0.0E+00



1.6E+00

NA

NA

1.6E+00

Aquatic Biota Total

0.0E+00

NA

NA

0.0E+00



1.6E+00

NA

NA

1.6E+00

Receptor Total

0.0E+00

0.0E+00

0.0E+00

0.0E+00



3.5E+02

0.0E+00

0.0E+00

3.5E+02

Total Circulatory HI Across Media (High Fish Diet) =
Total Kidney HI Across Media (High Fish Diet) =

7E+Q1
3E+Q2

Revised 02/10/2006

009051

Page 2 of 2


-------
Appendix L
ProUCL Output

009052


-------
TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
009053

FEBRUARY 2006


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness
MLE Median
MLE 80% Quantile
MLE 90% Quantile

C:\Documents and Settings\hawata\My Documents\Projects\Tar Creek_MSSL\RAGS-D\Rev Table2\Copy of Select AOC ProUCL and Rags D Table 2 051230 (2).xls

CADMIUM

21
0
21
20
0.35
139
36.55
38.51864
1483.686
1.053862
1.188588
NO

N/R
N/R

0.860225
0.908
NOT NORMAL
51.04704

0.668714
0.604929
54.65717
60.42029
28.08598
25.40703
14.92176
0.0383
14.305
0.317309
0.790126
AD GAMMA
0.13484
0.198038
KS GAMMA
GAMMA
62.23305
64.91626

-1.04982
4.934474
2.689102
1.73354
3.005161
N/R
N/R

0.919793
0.908
LOGNORMAL
66.13399
289.7051
4.380578
97.20268
14.71846
63.68466
136.5514

Shapiro Wlk method yields a more accurate result
Shapiro Wlk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wlk method yields a more accurate result
Shapiro Wlk method yields a more accurate result

Data are lognormal at 5% significance level

SASO-Cd

Revised 02/10/2006

009054


-------
MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

254.8756
829.9093
13.69891
56.78836
151.4415
26.42896
276.6166
171.9895
221.8372
319.7532

50.37574
52.70525
51.4104
51.04704
73.18853
89.04206
120.1832

2000
49.8754
54.5279
54.57195
50.57619
50.90476

NO

GAMMA
62.23305

NONE
NONE

95% Approximate Gamma UCL

SASO-Cd

009055

Revised 02/10/2006


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness
MLE Median
MLE 80% Quantile
MLE 90% Quantile

C:\Documents and Settings\hawata\My Documents\Projects\Tar Creek_MSSL\RAGS-D\Rev Table2\Copy of Select AOC ProUCL and Rags D Table 2 051230 (2).xls

LEAD

21
0
21
21
31.4
70800
10002.92
16938.54
2.87E+08
1.693359
2.79791
NO

N/R
N/R

0.611415
0.908
NOT NORMAL
16377.98

0.467323
0.432309
21404.74
23138.39
19.62756
18.15696
9.503008
0.0383
9.023417
0.296865
0.811902
AD GAMMA
0.132303
0.201183
KS GAMMA
GAMMA
19112.13
20127.93

3.446808
11.16761
7.837012
2.086843
4.354915
N/R
N/R

0.946283
0.908
LOGNORMAL
22347.5
195920.4
8.766996
700.1342
2532.626
14770.61
36997.51

Shapiro Wlk method yields a more accurate result
Shapiro Wlk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wlk method yields a more accurate result
Shapiro Wlk method yields a more accurate result

Data are lognormal at 5% significance level

SASO-Pb

Revised 02/10/2006

009056


-------
MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

78422.75
324814.6
2282.049
17156.07
64905.59
9769.247
165415.8
59739.23
78164.99
114358.8

16082.78
18494.19
16754.12
16377.98
26114.69
33086.26
46780.56

2000
15963.43
25781.12
40668.48
16278.62
18935.1

NO

GAMMA
20127.93

NONE
NONE

95% Adjusted Gamma UCL

SASO-Pb

009057

Revised 02/10/2006


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness
MLE Median
MLE 80% Quantile
MLE 90% Quantile

C:\Documents and Settings\hawata\My Documents\Projects\Tar Creek_MSSL\RAGS-D\Rev Table2\Copy of Select AOC ProUCL and Rags D Table 2 051230 (2).xls

ZINC

21
0
21
21
46.1
7980
1751.719
2206.223
4867421
1.259462
1.74508
NO

N/R
N/R
0.75994
0.908
NOT NORMAL
2582.063

0.695616
0.627988
2518.227
2789.413
29.21587
26.37551
15.66698
0.0383
15.03342
0.321814
0.787708
AD GAMMA
0.124356
0.197668
KS GAMMA
GAMMA
2949.035
3073.318

3.830813
8.984694
6.5988
1.504166
2.262515
N/R
N/R

0.966428
0.908
LOGNORMAL
2275.734
6676.562
2.933807
34.05334
734.2137
2617.095
5072.826

Shapiro Wlk method yields a more accurate result
Shapiro Wlk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wlk method yields a more accurate result
Shapiro Wlk method yields a more accurate result

Data are lognormal at 5% significance level

SASO-Zn

Revised 02/10/2006

009058


-------
MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

8718.069
24281.99
695.6162
2056.774
4318.224
813.3438
6945.969
5602.058
7136.105
10149.44

2543.613
2739.509
2612.619
2582.063
3850.256
4758.295
6541.961

2000
2489.911
2969.139
3042.781
2549.476
2676.238

NO

GAMMA
2949.035

NONE
NONE

95% Approximate Gamma UCL

SASO-Zn

009059

Revised 02/10/2006


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness
MLE Median
MLE 80% Quantile
MLE 90% Quantile

BUM-Cd

CADMIUM

261
0

261
110
0.125
248
13.57155
35.77084
1279.553
2.635722
4.546143
NO

0.353493
0.054842
N/A
N/A

NOT NORMAL	Data not normal at 5% significance level

17.22654

0.43473
0.432287
31.21837
31.39477
226.9289
225.6539
191.8772
0.04908
191.706
23.80135
0.837279

NOT AD GAMMA Data not gamma distributed at 5% significance level
0.250532
0.060387

NOT KS GAMMA Data not gamma distributed at 5% significance level

NOT GAMMA	Data not gamma distributed at 5% significance level

15.96059
15.97484

-2.07944
5.513429
1.114368

I.531564
2.345688
0.115702
0.054842

N/A
N/A

NOT LOGNORMAL Data not lognormal at 5% significance level
9.847446
30.25658
3.072531
38.22367
3.047643

II.11771
21.81129

Revised 02/10/2006

009060


-------
MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

37.85605
107.4242
3.033978
9.752941
28.72127
1.334413
12.62019
15.56951
18.08635
23.03019

17.21352
17.87927
17.33039
17.22654
23.22285
27.39897
35.60216

2000
17.2497
18.09729
17.88966
17.50297
17.56073

NO

NON-PARAMETRIC
27.39897

NONE
NONE

97.5% Chebyshev (Mean, Sd) UCL

BUM-Cd

009061

Revised 02/10/2006


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness
MLE Median
MLE 80% Quantile
MLE 90% Quantile

Data not normal at 5% significance level

C:\Documents and Settings\hawata\My Documents\Projects\Tar Creek_MSSL\RAGS-D\Rev Table2\Select AOC ProUCL and Rags D Table 2 051230 rev1.xls

ZINC

261
0

261
235
0.25
39200
2668.832
7040.595
49569974
2.638081
3.781873
NO

0.368811
0.054842
N/A
N/A

NOT NORMAL
3388.226

0.380161
0.378346
7020.266
7053.951
198.4441
197.4965
165.9755
0.04908
165.8166
23.91561
0.850569
NOT AD GAMMA
0.244047
0.060827
NOT KS GAMMA
NOT GAMMA
3175.68
3178.723

-1.38629
10.57643
6.144169
1.721383
2.963159
0.110915
0.054842
N/A
N/A

NOT LOGNORMAL
2050.316
8785.079
4.284745
91.51801
465.9924
1995.676
4256.262

Data not gamma distributed at 5% significance level

Data not gamma distributed at 5% significance level
Data not gamma distributed at 5% significance level

Data not lognormal at 5% significance level

BUM-Zn

Revised 02/10/2006

009062


-------
MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

7909.694
25542.68
463.3546
2022.076
8134.983
330.1959
2766.777
3461.366
4084.149
5307.484

3385.663
3494.67
3405.229
3388.226
4568.449
5390.414
7005.006

2000
3390.531
3555.215
3491.596
3413.467
3451.148

NO

NON-PARAMETRIC
5390.414

NONE
NONE

97.5% Chebyshev (Mean, Sd) UCL

BUM-Zn

009063

Revised 02/10/2006


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness
MLE Median
MLE 80% Quantile
MLE 90% Quantile

Data not normal at 5% significance level

C:\Documents and Settings\hawata\My Documents\Projects\Tar Creek_MSSL\RAGS-D\Rev Table2\Select AOC ProUCL and Rags D Table 2 051230 rev1.xls

CADMIUM

172
0

172
66
0.25
47.5
4.048837
7.285125
53.07304
1.799313
4.023453
NO

0.301026
0.067557
N/A
N/A

NOT NORMAL
4.967506

0.831983
0.821347
4.866491
4.929506
286.2021
282.5435
244.6047
0.048605
244.3094
9.192734
0.791873
NOT AD GAMMA
0.178967
0.07345
NOT KS GAMMA
NOT GAMMA
4.676823
4.682476

-1.38629
3.86073
0.688723
1.07537
1.156422
0.093323
0.067557
N/A
N/A

NOT LOGNORMAL
3.549952
5.239684
1.475987
7.643457
1.991172
4.940227
7.929375

Data not gamma distributed at 5% significance level

Data not gamma distributed at 5% significance level
Data not gamma distributed at 5% significance level

Data not lognormal at 5% significance level

ResSOGP-Cd

Revised 02/10/2006

009064


-------
MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

11.67801
24.28927
1.984489
3.531345
5.101875
0.358491
4.261102
5.093973
5.770123
7.09829

4.96253
5.14462
4.995909
4.967506
6.470143
7.517843
9.575849

2000
4.955484
5.21747
5.199166
4.932558
5.209593

NO

NON-PARAMETRIC
7.517843

NONE
NONE

97.5% Chebyshev (Mean, Sd) UCL

ResSOGP-Cd

009065

Revised 02/10/2006


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness
MLE Median
MLE 80% Quantile
MLE 90% Quantile

Data not normal at 5% significance level

C:\Documents and Settings\hawata\My Documents\Projects\Tar Creek_MSSL\RAGS-D\Rev Table2\Select AOC ProUCL and Rags D Table 2 051230 rev1.xls

LEAD

172
0

172
129
0.0125
822
89.19019
128.5803
16532.88
1.441641
3.155662
NO

0.305207
0.067557
N/A
N/A

NOT NORMAL
105.4044

0.968962
0.955937
92.04715
93.30128
333.3229
328.8425
287.8185
0.048605
287.4975
9.303523
0.78518
NOT AD GAMMA
0.186206
0.07304
NOT KS GAMMA
NOT GAMMA
101.9029
102.0166

-4.38203
6.71174
3.892838
1.139761
1.299056
0.114401
0.067557
N/A
N/A

NOT LOGNORMAL
93.91275
153.3349
1.632738
9.250819
49.04991
128.501
212.1793

Data not gamma distributed at 5% significance level

Data not gamma distributed at 5% significance level
Data not gamma distributed at 5% significance level

Data not lognormal at 5% significance level

ResSOGP-Pb

Revised 02/10/2006

009066


-------
MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

319.8159
695.0077
48.86503
93.33572
148.591
10.24698
114.5383
138.0013
157.3281
195.2919

105.3166
107.8373
105.7976
105.4044
131.9255
150.4171
186.7403

2000
105.0489
109.121
108.1927
106.1443
108.4227

NO

NON-PARAMETRIC
150.4171

NONE
NONE

97.5% Chebyshev (Mean, Sd) UCL

ResSOGP-Pb

009067

Revised 02/10/2006


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness
MLE Median
MLE 80% Quantile
MLE 90% Quantile

Data not normal at 5% significance level

C:\Documents and Settings\hawata\My Documents\Projects\Tar Creek_MSSL\RAGS-D\Rev Table2\Select AOC ProUCL and Rags D Table 2 051230 rev1.xls

ZINC

172
0

172
160
0.25
7700
645.5363
1133.534
1284899
1.755957
3.813788
NO

0.290177
0.067557
N/A
N/A

NOT NORMAL
788.4773

0.743899
0.7348
867.7746
878.5202
255.9011
252.7711
216.9519
0.048605
216.6742
6.194203
0.796474
NOT AD GAMMA
0.132567
0.073725
NOT KS GAMMA
NOT GAMMA
752.1156
753.0795

-1.38629
8.948976
5.664463
1.27813
1.633616
0.050577
0.067557
N/A
N/A

LOGNORMAL
652.8001
1325.42
2.030361
14.46097
288.433
849.3595
1490.489

Data not gamma distributed at 5% significance level

Data not gamma distributed at 5% significance level
Data not gamma distributed at 5% significance level

Data are lognormal at 5% significance level

ResSOGP-Zn

Revised 02/10/2006

009068


-------
MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

2361.345
5638.612
287.0664
647.2655
1268.372
83.24207
825.9889
1010.109
1167.112

1475.514

787.7029
814.559
792.6663
788.4773
1022.281
1185.299

1505.515

2000
786.8043
832.1014
816.8206
790.6003
811.1163

NO

LOGNORMAL
825.9889

NONE
NONE

95% H-UCL

ResSOGP-Zn

009069

Revised 02/10/2006


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\ Working\Table3 Backup\ProUCL input.xls
CADMIUM

9
0
9
7

0.25
9.6
2.85
3.084133
9.511875
1.082152
1.389807
NO

N/R
N/R

0.827359
0.829
NOT NORMAL
4.761698

0.796516
0.605085
3.578084
4.710086
14.33728
10.89152
4.505437
0.02308
3.679105
0.567083
0.749973
AD GAMMA
0.219404
0.288837
KS GAMMA
GAMMA
6.889639
8.437063

-1.386294
2.261763
0.30178
1.459533
2.130236
N/R
N/R

0.847233
0.829
LOGNORMAL
3.923161
10.6843
2.72339
28.36914

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data are lognormal at 5% significance level

SO NA-Cd

009070


-------
MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

1.352263
4.64172
8.822271
14.92013
40.31215
1.199608
3.234613
5.242462
1.627646
38.55269
10.32936
13.39926
19.42949

4.540982
5.049874
4.841074
4.761698
7.331141
9.270134
13.07891

2000
4.432332
5.928511
8.506043
4.505556
4.95

NO

GAMMA
6.889639

NONE
NONE

95% Approximate Gamma UCL

009071

SO NA-Cd


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\ProUCL input.xls
ZINC

9
0
9
8
47
1940
527.8889
635.7323
404155.6
1.204292
1.607372
NO

N/R
N/R

0.783211
0.829
NOT NORMAL
921.9472

0.725462
0.557716
727.6586
946.5198
13.05832
10.03888
3.965233
0.02308
3.201154
0.637796
0.753347
AD GAMMA
0.277486
0.289751
KS GAMMA
GAMMA
1336.47
1655.47

3.850148
7.570443
5.439953
1.496399
2.239211
N/R
N/R

0.835441
0.829
LOGNORMAL
705.9598
2044.351
2.895846
32.97188

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data are lognormal at 5% significance level

SO NA-Zn

009072


-------
MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

230.4313
815.9966
1576.285
2701.411
7484.411
203.1532
574.4162
958.3916
295.9448
7728.495
1864.41
2422.591
3519.029

876.4511
997.77
940.8705
921.9472
1451.587
1851.271
2636.375

2000
851.3017
1279.972
2725.517
896
960.3333

NO

GAMMA
1336.47

NONE
NONE

95% Approximate Gamma UCL

009073

SO NA-Zn


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\ Working\Table3 Backup\ProUCL input.xls
CADMIUM

25
0
25
12

5.00E-05
0.003
0.000808
0.001014
1.03E-06
1.255375
1.421234
NO

N/R
N/R
0.70931
0.918
NOT NORMAL
0.001155

0.744188
0.681552
0.001086
0.001186
37.20939
34.0776
21.72424
0.0395
21.05139
1.214488
0.784005
NOT AD GAMMA
0.182338
0.181374
NOT KS GAMMA
NOT GAMMA
0.001267
0.001308

-9.903488
-5.809143
-7.926212
1.343115
1.803959
N/R
N/R
0.90596
0.918
NOT LOGNORMAL

0.00089
0.002005
2.252475
18.18569

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data not gamma distributed at 5% significance level

Data not gamma distributed at 5% significance level
Data not gamma distributed at 5% significance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not lognormal at 5% significance level

GW_GP-Cd

009074


-------
MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

0.000361
0.001124
0.002029
0.00329
0.008212
0.000348
0.000836
0.001516
0.000271
0.002016
0.002016
0.002527
0.00353

0.001142
0.001203
0.001165
0.001155
0.001692
0.002075
0.002827

2000
0.001141
0.001284
0.001145
0.001152
0.00119

NO

NON-PARAMETRIC
0.002827

NONE
NONE

99% Chebyshev (Mean, Sd) UCL

009075

GW_GP-Cd


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\ProUCL input.xls
ZINC

25
0
25
17
0.005
1.11
0.2074
0.30396
0.092392
1.465576
2.027789
NO

N/R
N/R

0.667525
0.918
NOT NORMAL
0.311408

0.608542
0.562183
0.340815
0.368919
30.42708
28.10916
17.01113
0.0395
16.42232
1.102471
0.796734
NOT AD GAMMA
0.204483
0.183094
NOT KS GAMMA
NOT GAMMA
0.342707
0.354995

-5.298317
0.10436
-2.586335
1.55063
2.404453
N/R
N/R

0.938492
0.918
LOGNORMAL
0.250547
0.795162
3.1737
41.48779

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data not gamma distributed at 5% significance level

Data not gamma distributed at 5% significance level
Data not gamma distributed at 5% significance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data are lognormal at 5% significance level

GW_GP-Zn

009076


-------
MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

0.075296
0.279137
0.552238
0.965076
2.774389
0.071754
0.227978
0.523839
0.087809
0.71083
0.61073
0.776347
1.101669

0.307394
0.333738
0.315517
0.311408
0.472387
0.587046
0.812274

2000
0.304933
0.370323
0.386097
0.3086
0.3284

NO

LOGNORMAL
0.61073

NONE
NONE

95% Chebyshev (MVUE) UCL

009077

GW_GP-Zn


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\ Working\Table3 Backup\ProUCL input.xls
CADMIUM

97
0
97
91
10.4
197
76.23196
38.93794
1516.163
0.510782
1.193111
NO

0.134377
0.08996
N/A
N/A

NOT NORMAL
82.79833

Data not normal at 5% significance level

3.923543
3.809069
19.42937
20.01328
761.1673
738.9594
676.8694
0.047526
675.9821
0.917759
0.756289
NOT AD GAMMA
0.091539
0.091214
NOT KS GAMMA
NOT GAMMA
83.2248
83.33405

2.341806
5.283204
4.200966
0.547492
0.299747
0.122505
0.08996
N/A
N/A

NOT LOGNORMAL
77.54354
45.84377
0.5912
1.980237

Data not gamma distributed at 5% significance level

Data not gamma distributed at 5% significance level
Data not gamma distributed at 5% significance level

Data not lognormal at 5% significance level

Recr All-Cd

009078


-------
MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

66.75077
106.0167
134.8945
164.2829
238.515
66.64771
77.4065
45.44717
4.58555
86.03965
97.39445
106.0433
123.0322

82.73497
83.24672
82.87816
82.79833
93.46508
100.9219
115.5693

2000
82.75868
83.48924
83.37989
82.82887
83.45464

NO

NON-PARAMETRIC
93.46508

NONE
NONE

95% Chebyshev (Mean, Sd) UCL

009079

Recr All-Cd


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation
MLE Skewness

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\ProUCL input.xls
ZINC

97
0
97
86
2200
42200
16388.97
8901.49
79236526
0.543139
0.671467
NO

0.078351
0.08996
N/A
N/A

NORMAL
17890.09

Data are normal at 5% significance level

3.032734
2.945811
5404.025
5563.483
588.3504
571.4873
517.027
0.047526
516.2531
0.355082
0.758649
AD GAMMA
0.0558
0.091502
KS GAMMA
GAMMA
18115.28
18142.43

7.696213
10.65018
9.530529
0.643228
0.413742
0.090656
0.08996
N/A
N/A

NOT LOGNORMAL
16939.45
12126.41
0.715868
2.514463

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Data not lognormal at 5% significance level

Recr All-Zn

009080


-------
MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

13773.88
23719.6
31479.04

39681.46
61492.94
13744.54
16896.17
11974.94
1201.809
19218.85
22134.74

24401.47
28854.02

17875.6
17941.44
17900.36
17890.09
20328.58
22033.26
25381.76

2000
17836.23
18050.32
17942.51
17893.81
17879.38

NO

NORMAL
17890.09

NONE
NONE

95% Student's-t UCL

009081

Recr All-Zn


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\Wet Weight Biota
ProUCL and Table2s for CD-PB-ZN 051028.xls
CADMIUM, Wet Weight Basis

19
0

19
19

0.6707
21.333
3.645237
4.612722
21.2772
1.265411
3.450191
NO

N/R
N/R

0.566188
0.901
NOT NORMAL
5.480276

1.415181
1.226819
2.57581
2.971292
53.77686
46.61911
31.94917
0.03687
30.8882
0.85842
0.759025
NOT AD GAMMA
0.215702
0.202443
NOT KS GAMMA
NOT GAMMA
5.319003
5.501703

-0.399433
3.060255
0.900232
0.823448
0.678067
N/R
N/R

0.954524
0.901
LOGNORMAL
3.453076
3.401
0.984919

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data not gamma distributed at 5% significance level

Data not gamma distributed at 5% significance level
Data not gamma distributed at 5% significance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data are lognormal at 5% significance level

ASP AG-Cd

009082


-------
MLE Skewness

MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

3.910192
2.460174
4.933486
7.087714
9.533426
16.70273
2.416626
3.3752
3.072981
0.691824
5.483135
6.390793
7.695642
10.25877

5.385872
6.28088
5.61988
5.480276
8.257959
10.25389
14.1745

2000
5.345888
8.1932
11.99714
5.445216
6.676116

NO

LOGNORMAL
5.483135

NONE
NONE

95% H-UCL

009083

ASP AG-Cd


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\Wet Weight Biota
ProUCL and Table2s for CD-PB-ZN 051028.xls
ZINC, Wet Weight Basis

19
0

19
19

23.3758
409.5
105.6423
85.47525
7306.018
0.809101
2.641651
NO

N/R
N/R

0.718194
0.901
NOT NORMAL
139.6461

2.233108
1.915599
47.30728
55.14841
84.85809
72.79278
54.14289
0.03687
52.73746
0.602674
0.750962
AD GAMMA
0.184297
0.200637
KS GAMMA
GAMMA
142.0315
145.8165

3.151701
6.014937
4.419752
0.715774
0.512332
N/R
N/R

0.937265
0.901
LOGNORMAL
107.3311
87.80044
0.818034

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data are lognormal at 5% significance level

ASP AG-Zn

009084


-------
MLE Skewness

MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

3.001512
83.07572
152.1065
208.413
269.6703
439.0625
81.96243
105.5912
81.59491
18.50786
156.833
186.265
221.1727
289.742

137.8968
150.595
141.6268
139.6461
191.1175
228.1027
300.753

2000
137.3801
162.4541
301.4031
140.0269
154.2966

NO

GAMMA
142.0315

NONE
NONE

95% Approximate Gamma UCL

009085

ASP AG-Zn


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\Wet Weight Biota
ProUCL and Table2s for CD-PB-ZN 051028.xls
CADMIUM, Wet Weight Basis

19
0

19
19

4.4243
25.915
10.16578
5.64115
31.82257
0.554916
1.772553
NO

N/R
N/R

0.797381
0.901
NOT NORMAL
12.40995

4.535564
3.85451
2.241348
2.637372
172.3514
146.4714
119.4954
0.03687
117.367
0.692881
0.743651
AD GAMMA
0.164039
0.199085
KS GAMMA
GAMMA
12.46069
12.68666

1.487112
3.254822
2.204756
0.468776
0.219751
N/R
N/R

0.943686
0.901
LOGNORMAL
10.12119
5.017559
0.495748

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data are lognormal at 5% significance level

ASP RT-Cd

009086


-------
MLE Skewness

MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

1.609082
9.068034
13.47547
16.56236
19.6071
26.98087
9.015731
10.05744
4.874791
1.115772
12.60478
14.92098
17.02544
21.15923

12.2945
12.85683
12.49766
12.40995
15.80693
18.24786
23.04259

2000
12.24567
13.81046
14.27187
12.35551
12.82011

NO

GAMMA
12.46069

NONE
NONE

95% Approximate Gamma UCL

009087

ASP RT-Cd


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\Wet Weight Biota
ProUCL and Table2s for CD-PB-ZN 051028.xls
ZINC, Wet Weight Basis

19
0

19
19

234.107
3578.58
1021.17
901.7106
813082
0.883017
2.079078
NO

N/R
N/R

0.728782
0.901
NOT NORMAL
1379.89

1.992271
1.71279
512.5659
596.2029
75.7063
65.086
47.51986
0.03687
46.20834
0.637977
0.751899
AD GAMMA
0.172274
0.200849
KS GAMMA
GAMMA
1398.655
1438.352

5.455778
8.182721
6.657217
0.724864
0.525428
N/R
N/R

0.963172
0.901
LOGNORMAL

1012.25
841.5587
0.831374

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data are lognormal at 5% significance level

ASP RT-Zn

009088


-------
MLE Skewness

MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

3.068755
778.3814
1436.159
1975.679
2564.756
4201.729
767.6854
995.3521
780.4031
176.9209
1489.018
1766.532
2100.223
2755.693

1361.435
1466.865
1396.335
1379.89
1922.881
2313.052
3079.467

2000
1358.941
1785.722
3146.537
1367.658
1480.772

NO

GAMMA
1398.655

NONE
NONE

95% Approximate Gamma UCL

009089

ASP RT-Zn


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\Wet Weight Biota
ProUCL and Table2s for CD-PB-ZN 051028.xls
CADMIUM, Wet Weight Basis

19
0

19
19
1.1515
32.2588
12.04075
10.01287
100.2575
0.831582
0.855541
NO

N/R
N/R

0.881934
0.901
NOT NORMAL
16.02408

1.324837
1.15074
9.088475
10.46348
50.3438
43.72811
29.56107
0.03687
28.54353
0.286315
0.761246
AD GAMMA
0.105129
0.202852
KS GAMMA
GAMMA
17.81123
18.44618

0.141065
3.473791
2.065624
1.045095
1.092224
N/R
N/R

0.937549
0.901
LOGNORMAL
13.62268
19.17314
1.407443

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data are lognormal at 5% significance level

WLW_AG-Cd

009090


-------
MLE Skewness

MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

7.010325
7.89022
19.08169
30.22203
44.0271
89.70397
7.666344
13.07086
16.00393
3.516115
26.42137
28.39725
35.029
48.05577

15.81916
16.30091
16.09922
16.02408
22.05361
26.38619
34.89669

2000
15.72547
16.69524
16.01696
15.74878
16.0731

NO

GAMMA
17.81123

NONE
NONE

95% Approximate Gamma UCL

009091

WLW_AG-Cd


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\Wet Weight Biota
ProUCL and Table2s for CD-PB-ZN 051028.xls
ZINC, Wet Weight Basis

19
0

19
19

67.445
705.55
400.7297
167.0303
27899.12
0.416815
0.252928
NO

N/R
N/R

0.959289
0.901
NORMAL
467.1779

4.843729
4.114017
82.73165
97.40593
184.0617
156.3327
128.4228
0.03687
126.2132
0.407739
0.742794
AD GAMMA
0.144998
0.199002
KS GAMMA
GAMMA
487.8193
496.3596

4.211312
6.558978
5.886524
0.530245
0.28116
N/R
N/R

0.859201
0.901
NOT LOGNORMAL
414.5127
236.1869
0.569794

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data are normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not lognormal at 5% significance level

WLW_AG-Zn

009092


-------
MLE Skewness

MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

1.894374
360.1511
563.7331
711.8653
861.5877
1236.294
357.4953
411.0981
227.4641
51.99108
535.2106
637.722
735.7823
928.4028

463.7595
466.1353
467.5485
467.1779
567.76
640.0341
782.0027

2000
463.2602
466.4933
467.0013
462.0852
466.2501

NO

NORMAL
467.1779

NONE
NONE

95% Student's-t UCL

009093

WLW_AG-Zn


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\Wet Weight Biota
ProUCL and Table2s for CD-PB-ZN 051028.xls
CADMIUM, Wet Weight Basis

19
0

19
19

4.8909
132.818
34.46778
31.97573
1022.447
0.927699
1.759641
NO

N/R
N/R

0.786625
0.901
NOT NORMAL
47.18841

1.500287
1.298487
22.97412
26.54456
57.01091
49.34252
34.21303
0.03687
33.11236
0.743366
0.756937
AD GAMMA
0.182362
0.202059
KS GAMMA
GAMMA
49.70992
51.36231

1.587376
4.88898
3.171127
0.885017
0.783255
N/R
N/R

0.941768
0.901
LOGNORMAL
35.26018
38.44143
1.090222

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data are lognormal at 5% significance level

WLW_RT-Cd

009094


-------
MLE Skewness

MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

4.566487
23.83433
50.34836
74.31951
102.2049
186.7323
23.34758
34.31395
34.08254
7.630985
58.9531
67.57664
81.96944
110.2413

46.53399
49.69825
47.68197
47.18841
66.44351
80.27944
107.4574

2000
46.20038
51.89723
56.11224
47.60856
51.09325

NO

GAMMA
49.70992

NONE
NONE

95% Approximate Gamma UCL

009095

WLW_RT-Cd


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\Wet Weight Biota
ProUCL and Table2s for CD-PB-ZN 051028.xls
ZINC, Wet Weight Basis

19
0

19
19

466.04
13202
3017.537
3357.135
11270354
1.112541
1.921427
NO

N/R
N/R

0.753607
0.901
NOT NORMAL
4353.078

1.136297
0.99197
2655.588
3041.965
43.1793
37.69485
24.63453
0.03687
23.71244
0.673637
0.76588
AD GAMMA
0.193424
0.203704
KS GAMMA
GAMMA
4617.324
4796.875

6.144271
9.488124
7.5115
1.013264
1.026704
N/R
N/R

0.944045
0.901
LOGNORMAL

3055.97
4090.721
1.3386

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data are lognormal at 5% significance level

WLW_RT-Zn

009096


-------
MLE Skewness

MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

6.41437
1828.955
4305.757
6724.713
9684.865
19309.5
1780.136
2941.442
3460.515
763.5768
5745.001
6269.796
7709.977
10538.94

4284.37
4647.13
4409.661
4353.078
6374.672
7827.307
10680.73

2000
4248.001
4990.943
5450.668
4308.696
4663.491

NO

GAMMA
4617.324

NONE
NONE

95% Approximate Gamma UCL

009097

WLW_RT-Zn


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\Wet Weight Biota
ProUCL and Table2s for CD-PB-ZN 051028.xls
CADMIUM, Wet Weight Basis

19
0

19
19

0.018535
34.17
1.929388
7.809385
60.98649
4.047596
4.355261
NO

N/R
N/R

0.257606
0.901
NOT NORMAL
5.036129

0.253795
0.24881
7.602157
7.754474
9.644205
9.454769
3.603142
0.03687
3.293088
4.341475
0.863551
NOT AD GAMMA
0.433269
0.217306
NOT KS GAMMA
NOT GAMMA
5.062782
5.539458

-3.988094
3.531348
-2.134677
1.64886
2.71874
N/R
N/R

0.770123
0.901
NOT LOGNORMAL
0.460562
1.733159
3.763138

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data not gamma distributed at 5% significance level

Data not gamma distributed at 5% significance level
Data not gamma distributed at 5% significance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not lognormal at 5% significance level

CT AG-Cd

009098


-------
MLE Skewness

MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

64.57999
0.118283
0.476451
0.984234
1.781931
5.477077
0.110087
0.39892
0.947943
0.181207
1.912974
1.188783
1.530557
2.201906

4.876301
6.78905
5.334479
5.036129
9.738773
13.1179
19.75554

2000
4.781867
212.4849
75.70447
5.500168
7.374327

NO

NON-PARAMETRIC
19.75554

NONE
NONE

99% Chebyshev (Mean, Sd) UCL

009099

CT AG-Cd


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\Wet Weight Biota
ProUCL and Table2s for CD-PB-ZN 051028.xls
ZINC, Wet Weight Basis

19
0

19
19

13.9518
4411.5
269.7441
1003.163
1006337
3.718944
4.356125
NO

N/R
N/R

0.259171
0.901
NOT NORMAL
668.824

0.374906
0.350798
719.4987
768.9449
14.24642
13.33032
6.114415
0.03687
5.691057
5.051205
0.827825
NOT AD GAMMA

0.45319
0.213205
NOT KS GAMMA
NOT GAMMA
588.0815
631.8289

2.635609
8.39197
3.823786
1.202141
1.445143
N/R
N/R

0.6211
0.901
NOT LOGNORMAL
94.2883
169.7833
1.800683

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data not gamma distributed at 5% significance level

Data not gamma distributed at 5% significance level
Data not gamma distributed at 5% significance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not lognormal at 5% significance level

CT AG-Zn

009100


-------
MLE Skewness

MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

11.24069
45.77718
126.4181
214.5487
330.7317
749.9193
44.06575
88.8236
131.1865
28.09326
216.1033
211.2793
264.266
368.348

648.2931
894.0461
707.1565
668.824
1272.907
1706.977
2559.622

2000
634.1924
18462.06
7059.112
728.7642
964.6947

NO

NON-PARAMETRIC
2559.622

NONE
NONE

99% Chebyshev (Mean, Sd) UCL

009101

CT AG-Zn


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\Wet Weight Biota
ProUCL and Table2s for CD-PB-ZN 051028.xls
CADMIUM, Wet Weight Basis

19
0

19
19

0.04185
249.426
27.9128
58.66365
3441.424
2.101676
3.416635
NO

N/R
N/R
0.49694
0.901
NOT NORMAL
51.25046

0.435663
0.401962
64.06967
69.44138
16.5552
15.27456
7.45171
0.03687
6.977314
0.615849
0.815671
AD GAMMA
0.179181
0.211643
KS GAMMA
GAMMA
57.21582
61.10598

-3.173663
5.519162
1.839188
2.100436
4.41183
N/R
N/R

0.936759
0.901
LOGNORMAL
57.11706
515.3852
9.023314

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data are lognormal at 5% significance level

CT RT-Cd

009102


-------
MLE Skewness

MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

761.7499
6.291425
37.11629
93.52676
199.2189
832.8064
5.597965
42.62768
155.798
25.0661
520.2386
151.8883
199.1654
292.0323

50.04984
61.32167
53.00863
51.25046
86.57645
111.9603
161.8218

2000
49.68431
122.5275
132.3307
52.26816
64.9869

NO

GAMMA
61.10598

NONE
NONE

95% Adjusted Gamma UCL

009103

CT RT-Cd


-------
Data File

Variable:

Raw Statistics

Number of Observations

Number of Missing Data

Number of Valid Observations

Number of Distinct Observations

Minimum

Maximum

Mean

Standard Deviation
Variance

Coefficient of Variation
Skewness

Too Few Distinct Observations?

Normal Statistics
Lilliefors Test Statisitic
Lilliefors 5% Critical Value
Shapiro-Wilk Test Statisitic
Shapiro-Wilk 5% Critical Value
5% Normality Test Result
95% Student's-t UCL
Gamma Statistics
k hat

k star (bias corrected)

Theta hat
Theta star
nu hat
nu star

5% Approximate Chi Square Value

Adjusted Level of Significance

Adjusted Chi Square Value

Anderson-Darling Test Statistic

Anderson-Darling 5% Critical Value

Anderson-Darling 5% Gamma Test Result

Kolmogrov-Smirnov Test Statistic

Kolmogrov-Smirnov 5% Critical Value

Kolmogrov-Smirnov 5% Gamma Test Result

5% Gamma Test Result

95% Approximate Gamma UCL

95% Adjusted Gamma UCL

Lognormal Statistics

Minimum of log data

Maximum of log data

Mean of log data

Standard Deviation of log data

Variance of log data

Lilliefors Test Statisitic

Lilliefors 5% Critical Value

Shapiro-Wilk Test Statisitic

Shapiro-Wilk 5% Critical Value

5% Lognormality Test Result

MLE Mean

MLE Standard Deviation
MLE Coefficient of Variation

P:\US Environmental Protection

Agency\168732TarCreek\HHRA\_Working\Table3_Backup\Wet Weight Biota
ProUCL and Table2s for CD-PB-ZN 051028.xls
ZINC, Wet Weight Basis

19
0

19
19
17.825
18414
2448.916
4099.711
16807631
1.674092
3.617535
NO

N/R
N/R

0.532021
0.901
NOT NORMAL
4079.869

0.650501
0.582878
3764.661
4201.421
24.71904
22.14937
12.44871
0.03687
11.81492
0.503688
0.78834
AD GAMMA
0.129583
0.207642
KS GAMMA
GAMMA
4357.235
4590.972

2.880602
9.820867
6.864662
1.697119
2.880213
N/R
N/R

0.881736
0.901
NOT LOGNORMAL
4043.105
16580.7
4.100983

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not normal at 5% significance level

Data follow gamma distribution at 5% signifcance level.

Data follow gamma distribution at 5% signifcance level
Data follow gamma distribution at 5% signifcance level

Shapiro Wilk method yields a more accurate result
Shapiro Wilk method yields a more accurate result

Data not lognormal at 5% significance level

CT RT-Zn

009104


-------
MLE Skewness

MLE Median

MLE 80% Quantile

MLE 90% Quantile

MLE 95% Quantile

MLE 99% Quantile

MVU Estimate of Median

MVU Estimate of Mean

MVU Estimate of Standard Deviation

MVU Estimate of SE of Mean

95% H-UCL

95% Chebyshev (MVUE) UCL

97.5% Chebyshev (MVUE) UCL

99% Chebyshev (MVUE) UCL

Non-parametric Statisitics

95% CLT UCL

95% Adjusted-CLT UCL

95% Modified-t UCL

95% Jackknife UCL

95% Chebyshev (Mean, Sd) UCL

97.5% Chebyshev (Mean, Sd) UCL

99% Chebyshev (Mean, Sd) UCL

Bootstrap Statistics

Number of Bootstrap Runs

95% Standard Bootstrap UCL

95% Bootstrap-t UCL

95% Hall's Bootstrap UCL

95% Percentile Bootstrap UCL

95% BCA Bootstrap UCL

Recommendations

Human Inspection Recommended?

Appropriate Distribution

1st Recommended UCL

2nd Recommended UCL

3rd Recommended UCL

Recommended UCL > Max Data Value

Recommendation Warning!

Alternative UCL

81.27352
957.822
4018.755
8479.949
15621.8
49620.56
887.6495
3458.55
8621.658
1622.23
18102.08
10529.69
13589.37
19599.53

3995.964
4830.015
4209.964
4079.869
6548.627
8322.576
11807.15

2000
3954.936
6803.386
9837.032
4128.391
5200.836

NO

GAMMA
4357.235

NONE
NONE

95% Approximate Gamma UCL

009105

CT RT-Zn


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Appendix M
Report to Congress

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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
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REPORT TO CONGRESS

Tar Creek Superfund Site
Ottawa County, Oklahoma

Julie Louise Gerberding, M.D., M.P.H.

Director, Centers for Disease Control and Prevention
Administrator, Agency for Toxic Substances and Disease Registry

October 2004

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Tar Creek Superfund Site - Report to Congress
Table of Contents

I.	REPORT SUMMARY	4

Purpose	4

Findings	4

Recommendations	5

II.	BACKGROUND	6

History of ATSDR Activities	6

Current ATSDR Activities	7

III.	EXPOSURE PATHWAY EVALUATION	7

Identification of Pathways of Exposure	7

Sources and Exposure Pathways at Tar Creek Superfund Site	8

Major Completed Exposure Pathways	8

Residential Area Soil	8

Mine Tailings	9

Lead-Based Paint	9

Other Exposure Pathways	9

Ingestion of Homegrown Produce	9

Ingestion of Tap Water	10

Airborne Dust	10

Use of Biota by Tar Creek Site Area Tribal Populations	10

Physical Hazards	11

IV.	DISCUSSION	11

Blood Lead Evaluation	12

Datasets Reviewed	12

Percentage of Elevated BLLs and Geometric Mean of BLLs	13

Picher/Cardin in Comparison with the Tar Creek Superfund Site as a Whole	13

Characteristics of Children With Elevated BLLs	14

Data Limitations	14

Interventions	14

V.	CONCLUSIONS	15

VI.	RECOMMENDATIONS	15

VII.	APPENDICES	17

TABLE 1 — MAJOR LEAD EXPOSURE PATHWAYS AT THE TAR CREEK SUPERFUND SITE	18

TABLE 2 — OTHER LEAD EXPOSURE PATHWAYS AT THE TAR CREEK SUPERFUND SITE	19

TABLE 3 — DEMOGRAPHICS IN TAR CREEK SUPERFUND SITE AREA*	20

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TABLE 4 — CHARACTERISTICS OF BLOOD LEAD TESTING DATA AMONG CHILDREN AGED 1-5 YEARS
LIVING WITHIN THE TAR CREEK SUPERFUND SITE—ENTIRE SITE*	21

TABLE 5 — CHARACTERISTICS OF BLOOD LEAD TESTING DATA AMONG CHILDREN AGED 1-5 YEARS
LIVING WITHIN THE TAR CREEK SUPERFUND SITE—PICHER AND CARDIN ONLY*	23

TABLE 6 - EXISTING HEALTH STUDY INFORMATION	25

TABLE 7 — CHILDREN AGED 1-5 YEARS LIVING IN THE TAR CREEK SUPERFUND SITE WITH KNOWN
ELEVATED BLLS IN 2003, RESIDENTIAL ASSESSMENT LEAD EXPOSURE STATUS	26

VIII.	FIGURES	27

IX.	REFERENCES	35

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I. Report Summary
Purpose

The Senate Appropriations Committee directed the Agency for Toxic Substances and Disease
Registry (ATSDR) "to help assess the level of lead poisoning of families, especially children, at
the Tar Creek Superfund Site in Oklahoma. A report to Congress on this assessment is due no
later than July 31, 2004" (Departments of Veterans Affairs and Housing and Urban Development,
and Independent Agencies, Appropriations Bill, 2004, Senate Report 108-143, September 5, 2003,
page 86).

Senator James Inhofe, as a senator from Oklahoma and as the Chairman of the Senate Committee
on Environment and Public Works, expressed his expectations about the directive: "I cannot
emphasize enough the importance of this endeavor to more fully understand the elevated lead
levels we're seeing in this community, particularly in children. As the chairman of the
committee with jurisdiction over both Superfund and ATSDR, I would like to take this
opportunity to elaborate on my expectations of ATSDR in connection with this directive: I am
urging ATSDR, in collaboration with the Oklahoma State Health Department, to work to identify
significant sources and pathways of exposure to lead that may be contributing to elevated blood
lead levels in children at the Tar Creek Superfund site in Oklahoma" (CongressionalRecord,
Senate, January 22, 2004, page S140).

Findings

Mine tailings and lead-based paint are two potential sources contributing to lead exposures in
children residing in the Tar Creek Site area. Children can be exposed to these sources of lead
primarily through contact with household dust and soil.

From 1995 to 2003, a decrease was observed both in the average blood lead levels (BLLs) and
the percentage of elevated BLLs (at or above 10 micrograms per deciliter [|ig/dL]) among
children aged 1 to 5 years who were living at the Tar Creek Superfund site and who were tested
for lead. In 2003, the average BLL and the percentage of elevated BLLs among children who
were tested for lead and who lived at the site were slightly higher than those of children living in
the United States as a whole during 1999 and 2000 (1). This comparison should be viewed with
caution, however, because the U.S. data are based on a representative sample of the United
States (1), and the data collected for tested children at the site are not representative of all
children living at the Tar Creek Superfund site area. Risk behaviors and/or exposure sources
in a limited number of households may have been important factors contributing to the number of
children with elevated BLLs living at the site from January 2000 to February 2004.

Declining BLLs among tested children living at the site should not be interpreted to mean that
existing interventions in the Tar Creek area are no longer needed. Indeed, such ongoing efforts as
soil remediation and an active lead screening and health education program should be evaluated
to determine their contribution to this decline. Meanwhile, these efforts should be continued.
Elimination of the sources of lead contamination will achieve long-term protection of children.
Screening efforts will confirm and monitor blood lead trends, while ongoing public health
education reinforces the need for behaviors that may reduce exposure to lead and its subsequent
health effects among adults and children.

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Recommendations

On the basis of the review of environmental and blood lead screening data, ATSDR is taking a
number of steps to address expressed concerns and has recommended additional actions to
protect the health of Tar Creek area residents:

•	Continue to provide blood lead screening to children living around the site. Currently,
ATSDR provides funds from EPA to the Ottawa County Health Department to
conduct screening activities. EPA is continuing to fund these activities through FY 2005.

•	Continue to provide lead exposure prevention education to people potentially
impacted by the site. Currently, ATSDR provides funds from EPA to the Ottawa
County Health Department to engage in prevention education activities. EPA is
continuing to fund these activities through FY 2005.

•	Recommend that the Oklahoma State Department of Health or the Ottawa County
Health Department support periodic reports of Tar Creek and Ottawa County child
blood lead statistics to the Ottawa County communities. These reports could include
trends and comparisons to state and national levels.

•	Complete remediation of residential properties. EPA funds this activity. According
to EPA, residential remediation is ongoing.

•	Complete the investigation of chat piles, mill and mine residues, and flotation ponds.
According to EPA, these activities are planned for completion next year.

•	Assess the risk for lead exposure from using mine tailings (chat) for commercial and
residential purposes, including processing and transporting the material. ATSDR has
included in its FY 2004 and in the FY 2005 President's Budget request funding for an
ongoing public health assessment regarding public health hazards associated with the
Tar Creek site. The public health assessment will include identification of gaps in
existing data and recommendations regarding further monitoring and other activities
to evaluate risks of lead exposure. ATSDR recommends that any person proposing to
use chat for commercial purposes arrange for an independent assessment of risks
from exposure potentially associated with that use.

•	To address concerns regarding the sources of lead exposure for children who
currently have elevated BLLs, correlate lead isotopes in the environment and in
children's blood. This approach would seek to identify specific environmental
sources contributing to elevated BLLs in children. The measured ratio of lead

206	207	•	•

isotopes Pb and Pb in the blood of children and adults would be compared with
the ratio of 206Pb and 207Pb in environmental sources and biota (2, 3). ATSDR may
conduct a small project to assess the feasibility of this approach.

•	Evaluate the health risks of other site-related contaminants and of physical hazards.
Funding to support this ongoing activity is included in ATSDR's FY 2004 and the
FY 2005 President's Budget.

ATSDR is considering whether to evaluate the effectiveness of activities at the Site, including soil
remediation and tribal and non-tribal health education/blood lead screening programs. Such an
evaluation might result in identification and then strengthening of those activities that have the most
impact on reducing or eliminating lead exposure.

5

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II. Background

The Tar Creek Superfund site (the site) is located in far northeastern Oklahoma (Ottawa County)
near the Oklahoma/Kansas border. The site itself comprises a 40-square mile area but is part of
the larger Tri-State Mining District that includes areas of Kansas and Missouri and 10 Tribal
Nations. The site encompasses portions of several communities, including Quapaw Nation,

Picher, Cardin, Quapaw, North Miami, and Commerce. Approximately 6,400 residents live
within the site boundaries.

From the early 1900s through the late 1970s, the site was mined extensively for lead and zinc
ore. The milling process for the lead and zinc ore resulted in a concentrated form of the original
mined material. It also resulted in mine tailings (chat) that were originally considered a waste
product. The chat was disposed of in piles or in flotation or tailing ponds. Some piles are as high
as 200 feet and contain elevated levels of lead and other heavy metals. The chat in flotation
ponds has not been quantified. The U.S. Geological Survey and the U.S. Army Corps of
Engineers estimate that the site contains 75 million tons of chat. The chat has been sold as a
construction product, similar to limestone gravel, for many years.

The U.S. Environmental Protection Agency (EPA) listed the site on the National Priorities List
(NPL) in September 1983. Initially, EPA addressed surface water contamination, which included
the mine water discharge in Tar Creek and the threat of contamination from open abandoned
wells to the Roubidoux Aquifer. In 1995, EPA began sampling area soils. On the basis of
elevated lead levels in soils, EPA began yard remediation activities that continue today. EPA has
entered into an Administrative Order of Consent with several entities to investigate the site and
provide the information needed to begin cleanup of chat piles, flotation ponds, and mill ponds.

History of ATSDR Activities

In September 1993, ATSDR reviewed the limited environmental data for the site. On the basis of the
review, ATSDR made the following recommendations:

•	Restrict access to any known open mine shafts and cave-ins at the site.

•	Continue sampling of the Roubidoux Aquifer to determine whether acid mine water is
significantly impacting it.

•	Continue monitoring area drinking water wells, especially public water supply wells,
for site-related contaminants.

•	Continue periodic sampling of water and sediments in Tar Creek and other area surface
waters.

•	Consider sampling fish from area surface waters impacted by acid mine drainage.

•	Sample area chat piles and soils near piles (including residential yards and other areas that
children frequent) to determine whether metals are detected at levels of health concern.

•	Review results of any sampling activities conducted in accordance with these
recommendations to determine whether further actions by ATSDR are needed.

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From 1993 to the present time, ATSDR has participated in numerous activities at the Tar Creek
Site. Beginning in spring 1993, ATSDR became aware of blood lead sampling data collected by
the Indian Health Service (IHS). ATSDR and IHS evaluated these data and determined that 35%
of the children tested at the IHS clinic in Ottawa County had elevated blood lead levels (BLLs)
(at or above 10 (j,g/dL). ATSDR initiated a limited investigation to evaluate the lead levels in soil,
paint, dust, and water at nine houses identified by IHS as homes to children with BLLs at or
abovelO (j,g/dL. The results indicated elevated levels of lead in paint and dust/soil in two homes.
In 1995, in a second effort to address exposure, ATSDR provided technical assistance and
resources to the Oklahoma State Department of Health (OSDH) to conduct BLL screening in all
children who lived in Ottawa County.

On the basis of the finding of elevated BLLs, EPA investigated the contamination of residential
yards and play areas. An extensive residential yard cleanup was conducted, and over 2,012
properties were remediated. ATSDR provided health recommendations to EPA on the
remediation plans for residential soils.

In 1997, EPA signed a Record of Decision (ROD) for the residential areas. As part of this ROD,
EPA recommended ongoing blood lead screening and health professional/community health
education. EPA agreed to fund the OSDH/Ottawa County Health Department (OCHD) to
implement a lead screening and education program for the Tar Creek area. EPA originally
committed to funding $1 million, but it continues to fund the project, even though the $1 million
has been expended. Continued funding is determined on an annual basis. EPA has provided
$175,000 of FY2004 monies for work in FY2005.

Current ATSDR Activities

ATSDR has identified data that address the multiple pathways of exposure for the Tar Creek
Site. On the basis of availability of this data, ATSDR is currently preparing a public health
assessment. ATSDR is working collaboratively with OSDH and EPA to evaluate the public
health issues associated with the site. Additionally, OSDH requested that ATSDR assist OSDH
in evaluating the potential health threat posed by the chat piles. ATSDR, with the assistance of
OSDH and EPA, has obtained blood lead and environmental data for completion of this report.

Lead isotopes and isotopic ratios have been used to identify the source of lead poisoning when
multiple sources of lead are present (2). ATSDR is developing a protocol to test this technique
in the Ottawa County Health Department investigations of children with elevated blood lead
levels. This protocol would measure lead isotopes and compare the isotopic ratio of lead in
children with elevated blood lead levels to isotopic ratios of lead present in the child's
environment.

ATSDR will continue to work with OSDH and EPA to complete the public health assessment. A
description of the current evaluation of the sources and pathways of exposure and blood lead
exposure status follows.

III. Exposure Pathway Evaluation
Identification of Pathways of Exposure

ATSDR identifies human exposure pathways by examining environmental and human

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components that might lead to contact with contaminants (4). A pathway analysis considers five
principal elements:

•	Source of contamination

•	Transport through an environmental medium

•	A point of exposure

•	A route of human exposure

•	An exposed population

Completed exposure pathways are those for which the five elements are evident and exposure to
a contaminant has occurred, is occurring, or will occur. ATSDR regards people who come in
contact with contamination as exposed. That exposure can occur through breathing airborne
contaminants, drinking contaminated water, eating contaminated plants or animals, or playing or
digging in contaminated soil. Identification of a completed exposure pathway does not
necessarily mean that health effects will occur. Exposures may or may not be significant. Thus,
even after exposure, human health effects may not necessarily result.

Sources and Exposure Pathways at Tar Creek Superfund Site

ATSDR reviewed site history, site activities, and sampling data for the site. From this review,
ATSDR identified sources and pathways of exposure that warranted consideration (Tables 1 and
2). These pathways are subdivided into the major pathways of exposure and pathways for which
additional data are needed to assess their contribution to exposure.

Major Completed Exposure Pathways

Residential Area Soil

Residential area soil (i.e., residential yards, daycare centers, playgrounds, and parks) is
considered a completed exposure pathway for areas identified (Figure 1) as having soil lead
levels at or above 500 milligrams per kilogram (mg/kg). The main source of lead contamination
in the residential area of the site is mine tailings (5). The tailings were transported to the
residential properties as a result of deposition of airborne dust from tailings piles and ponds and
use of chat as fill and for surfacing driveways. People can ingest soils as an incidental
consequence of typical outdoor activities, such as working in the yard, gardening, and playing.
The soil exposure pathway is especially important for children, who exhibit hand-to-mouth
behavior and consequently have higher soil ingestion rates.

The extent of lead contamination of residential soil has decreased since 1995. Over 2,000
residential yards have been cleaned up by EPA, and EPA continues to address residential
contamination. As of April 2004, over 500 residential properties still need to be sampled. EPA's
system for remediating yards gives top priority to homes with children under 7 years of age.
Because all yards have yet to be remediated, young children may continue to be exposed to lead
from residential soil.

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The tailings also contribute to lead exposures in homes. House dust sampling described in EPA's
1996 Tar Creek Risk Assessment indicate that tailings are present in house dust. Confirming this
finding, the 1997 Tribal Efforts Against Lead (TEAL) investigation also identified house dust as
a point of exposure to lead (6). Household dust is another point of exposure to site-related lead
for children and adults through hand-to-mouth behaviors.

Mine Tailings

Mine tailings are a completed exposure pathway for tailings piles, ponds, and embankments
identified (Figure 2). The locations where mine tailings are found in the Tar Creek site area were
provided to ATSDR by EPA. Adults and children swallow lead-contaminated mine tailings as an
incidental consequence of walking or playing on the tailings piles, ponds, or embankments. The
exposure pathway for mine tailings is especially important for children who live near the tailings
piles, ponds, or embankments. Hand-to-mouth behaviors of children, especially those 6 years of
age or younger, can result in higher soil ingestion rates. At the site, exposure to mine tailings is
especially likely in Picher and Cardin, where many homes are within 250 feet of tailings (Figure
2).

Lead-Based Paint

Some lead found in soil and house dust may have come from lead-based paint (LBP) or other
sources not related to the site. Exposure to LBP occurs in or around homes painted with LBP that
is peeling, chipping, or deteriorating. LBP is an important source of exposure to lead for many
children aged at or under 6 years in the site area. Children are exposed to LBP through ingestion
of dust, soil contaminated with small particles of LBP, or through direct ingestion of paint chips.

Homes most likely to have LBP were those built before 1950, but lead paint also was used in
some homes built during 1950-1978 (7). Use of paint containing lead in homes was banned in
1978, so homes built after 1978 are unlikely to contain LBP. Data from the 2000 Census indicate
that 22% of housing units in the United States were built before 1950. In comparison, ATSDR
found that 32% of the housing in the general Tar Creek Superfund site area and 39% of housing
in the Picher-Cardin area were built before 1950. These statistics for Tar Creek areas are 44%
and 75% higher, respectively, than for the United States as a whole (Table 3) [2000 U.S.

Census], As part of the Tar Creek Risk Assessment, EPA sampled a variety of environmental
media from randomly selected homes in the site area (5). Paint was tested at all of these homes
where chipped or damaged paint was noted outdoors or indoors. Outdoor paint from 28 (65%) of
43 homes contained lead, while indoor paint from four (40%) of 10 homes had lead (8).
Therefore, some of the children living in the Tar Creek site area could be exposed to lead from
LBP.

Other Exposure Pathways
Ingestion of Homegrown Produce

Plants can absorb lead from the soil (9). Lead-contaminated soil can adhere to plant surfaces, and
especially potatoes, carrots, and similar "root" vegetables. Thus, because some Tar Creek
residents grow fruits and vegetables in their home gardens, consumption of plants grown in lead-
contaminated soil could be another source of exposure. In addition, tribal members regularly use
these foods for medicinal and ceremonial purposes, thus increasing their consumption rates.

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Tar Creek Superfund Site - Report to Congress

Recent research indicates that this pathway would be a concern only for children who eat large
amounts (about Vz pound a day) of homegrown produce (10).

Ingestion of Tap Water

Drinking water contaminated with lead is another exposure pathway for people at the site. The
drinking water in most homes comes from municipal water supplies. EPA included tap water in
the environmental samples from 100 randomly selected homes at the site as part of its risk
assessment (5). EPA found a mean of 1.8 parts per billion (ppb) lead in the tap water tested with
a maximum level of 8.3 ppb. EPA's action level for lead in drinking water is 15 ppb. The source
of the lead in drinking water is most likely lead pipes or lead solder.

Airborne Dust

Inhalation of dust contaminated with lead is an additional exposure pathway for people at the site
(Figures 1 and 2). Mine tailings contaminated with lead are found throughout the site. Residents
of Picher and Cardin live near tailings piles, ponds, and embankments. EPA monitored the air for
lead and other contaminants at four locations in the Picher/Cardin area and one control location
in Afton for 3 months (5). The low levels found did not represent a health risk on the basis of
EPA input of the data into the Integrated Exposure Uptake Biokinetic Model for Lead (IEUBK)
model. However, this conclusion has some limitations. First, it is based on monitoring during
mid-April through mid-July 1995 and may not represent exposures during the rest of the year (8).
Second, the IEUBK model evaluated only the health risk for inhalation, not whether airborne
transport of the tailings might eventually recontaminate residential areas. To confirm air
sampling results from 1995, EPA again collected soil samples in August 2003 from properties in
both Picher and Cardin that were remediated during 1997 to early 2000. While this sampling
was limited, it may provide useful information in evaluating the recomtamination of residential
yards.

The Quapaw Tribe is conducting long-term monitoring of the Picher/Cardin area. Also, the EPA
is planning to model air emissions from chat piles and tailing ponds which would include real
time wind speed and directions for five consecutive years. A risk assessment will also be
completed to evaluate the impact of emitted contaminants from chat piles and tailing ponds on
the surrounding communities. These data should provide some valuable information in
addressing whether airborne transport of tailings is recontaminating the residential area soils and
to what extent residents are being exposed to airborne particulates. ATSDR will evaluate this
information to determine whether it addresses these concerns and whether additional sampling is
needed.

Use of Biota by Tar Creek Site Area Tribal Populations

The tribal populations may use biota (i.e., plants and animals) for food and for cultural,
ceremonial, and religious practices. The tribes would use biota as food probably in amounts
much greater than amounts used by other area residents. Native populations can use plant
materials for medicine regularly, further increasing consumption rates for lead. Tribal members
who practice crafts such as basket weaving may spend most of their day sifting the plant through
their teeth, a practice that means they can easily inhale contaminated dust and small soil
particulates bound to plant materials. The biota used and the cultural, ceremonial, and religious
practices may differ among the 10 tribes in the Tar Creek site area. Therefore, this pathway must

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be evaluated by or in close cooperation with the 10 tribes. One issue to be discussed with the
tribes is the recent Oklahoma Department of Environmental Quality fish tissue sampling data
and whether those data address tribal concerns.

Physical Hazards

Although not directly related to BLLs, physical hazards, in particular subsidence issues, play a
significant role in the safety of the site. Approximately 2,540 surface acres of land are
undermined at Tar Creek, including under the communities of Picher and Cardin (9). The largest
form of subsidence occurs when an undermined area collapses. The U.S. Army Corps of
Engineers, as part of the comprehensive watershed management plan, will attempt to identify the
areas most prone to major subsidence and determine when collapses might occur.

IV. Discussion

Residential area soil, lead-based paint, and mine tailings are the primary exposure pathways for
potential lead exposure in the Tar Creek Site area. The points of exposure for the residential soil
and lead-based paint pathways are house dust and yard soil (Table 1). In 1997, TEAL conducted
blood lead testing of children and environmental sampling and administered a questionnaire (12,
6). Lead-based paint, lead-containing floor dust in residences, and lead in yard soil were
identified as sources of elevated BLLs among children living at the site (Table 6).

EPA's Tar Creek Risk Assessment strongly linked house dust and yard soil to elevated BLLs in
children (5). EPA tested a variety of environmental media from a random sample of 100 homes
in the site area. Fifteen homes were sampled in Afton, Oklahoma, a location well away from the
Tar Creek site area and mining activities. House dust, tap water, and soil were obtained from
each house. Soil was obtained from the front and back yards, drip line, play areas, and gardens if
the home had one. Three floor dust samples were obtained from each home sampled: 1) the entry
area, 2) a bedroom (a child's was preferred), and 3) the living room or kitchen. As described
earlier, samples of interior or exterior paint were taken at homes in the sample set where the
paint was damaged or chipped. Samples of home-grown produce were obtained at the 29 homes
in the sample group with gardens. Air was sampled at four locations in the site area and one in
Afton for 3 months. These data were entered into EPA's IEUBK Model.

The results of the IEUBK model predicted that 82% of the total uptake of lead came from house
dust and soil, 16% from diet, and 2% from water (5). The lead uptake from diet was based
mostly on default values from national data, but the lead levels in produce from gardens was
factored into the model.

The IEUBK model predicted that about 22% of children exposed to the lead levels in these
homes in the site area would have BLLs at or abovelO |ig/dL. This prediction is based on
environmental levels in the Tar Creek site area before remediation of the residential areas. The
22% of children with elevated BLLs predicted by the IEUBK model is similar to the 19% of
children with elevated BLLs in the 1997 TEAL survey (12) and elevated BLLs reported to the
OSDH during 1995-1997.

Evidence suggests the plausibility that both mine tailings and lead-based paint could be
contributing to the BLLs of people living in the Tar Creek Superfund site. However, the relative
contributions of exposure to mine tailings and exposure to lead-based paint on the BLLs of
people living at the site cannot be determined with existing information.

11

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Blood Lead Evaluation

Datasets Reviewed

ATSDR reviewed and analyzed data on the BLLs of children living at the site from January 1995
through February 2004 (Figure 3). The Ottawa County Sunshine Clinic, the Ottawa County Lead
Poisoning Prevention Program (OCLPPP) managed by the OCHD, TEAL and Community
Health Action and Monitoring Program (CHAMP) surveys, Tribal Health Clinics, private
physicians, and other private and public clinics collect blood from children and test for lead.
These programs send data to the OSDH Childhood Lead Poisoning Prevention Program
Surveillance System (CLPPSS), which then transmits aggregate data to the Centers for Disease
Control and Prevention's Childhood Blood Lead Surveillance Program.

The most useful data sources for assessing BLLs of children living at the site were the 1995—
2002 OSDH Childhood Lead Poisoning Prevention Program (CLPPSS), the 1997 and 2000
TEAL survey, and the 1999-2004 OCLPPP screening data (Tables 4 and 5). Children were
considered to live at the site if their medical records indicated that they lived at addresses in the
northeast Oklahoma towns of Cardin, Commerce, North Miami, Picher, or Quapaw. For this
analysis, all children with addresses from North Miami were included as living at the site—even
though a portion of North Miami is outside the site boundaries (Figure 1). ATSDR included this
portion of North Miami in the estimates for the population or number of children living at the
site.

OCLPPP provides blood lead testing free of charge to children living at the site and to all other
children, including tribal children, living in Ottawa County. Families with young children who
may be at risk for lead poisoning are highly encouraged to participate in the voluntary program.
OCLPPP personnel offer testing on site at the OCHD and conduct regular screening efforts at
schools, preschools, daycare centers, Head Start programs, and local shopping areas. OCLPPP
also conducts identification and screening efforts in coordination with the Women, Infants, and
Children (WIC) program and with other public health programs. In addition, OCLPPP provides
on-location testing services to potential high-risk areas, as warranted (13).

ATSDR used the OCLPPP data as the source for 2003 BLLs for tested children living at the site
because those data incorporate

•	The most recent and current data available at the time of this analysis;

•	A substantial number of children tested (40% of the estimated population of children,
aged 1 to 5 years, living at the site—based on 2000 census block data analysis for
population estimate);

•	Numerous BLL tests throughout the year (total of 308 for children, aged 1 to 5 years,
living at the site in 2003);

•	A high level of test result recording accuracy (a check of existing BLL entries with
actual patient paper records showed only four errant electronic entries in 390 follow-
up patient records that contain up to 14 entries each);

•	BLLs reported to the 10th |ig/dL (OSDH CLPPSS data were rounded to the nearest
whole number) with consistent application of non-detect values (statistical values
assigned to test results when lead in a blood sample is too low to be detected);

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•	Data based on results obtained from consistent testing protocols and analysis criteria;
and

•	Targeted testing for potentially higher risk children (Head Start programs, siblings of
children with elevated BLLs, WIC).

The OCLPPP data system is the largest contributor of data to the OSDH CLPPSS system. Both
OSDH CLPPSS and OCLPPP datasets are comprised primarily of capillary blood lead testing
data (under OCLPPP, a confirmatory venous test is provided after an elevated capillary test
result). Both the OSDH CLPPSS and OCLPPP datasets consist of convenience samples rather
than representative samples. All TEAL survey blood lead tests were venous, and TEAL used a
door-to-door sampling method. In calculating geometric means for the OSDH CLPPSS and
OCLPPP data for each year, ATSDR used the highest test of each child tested in the respective
year.

The simple arithmetic mean is not suitable for representing "average" conditions when a large
proportion of the observations are clustered at one end of the data range. This is often the
situation with blood lead levels. The occurrence of a few high numbers would result in a
perceived "average" far higher than a number that would be reflective of actual conditions. In
such situations, the geometric mean is a more appropriate measure of central tendency than the
arithmetic mean. The result represents a more accurate estimate of common or typical
conditions.

Percentage of Elevated BLLs and Geometric Mean of BLLs

Among tested children aged 1-5 years living in the Tar Creek Superfund site, the percentage of
BLL elevations and the geometric BLL mean declined from 1995-2003 (Figures 4 and 6). In
1996, OSDH CLPPSS data showed that among tested children aged 1-5 years living at the site,
31.2% (67/215) had BLL at or above 10 |ig/dL and the geometric mean was 6.65 |ig/dL. In 2003,
OCLPPP data showed that among tested children aged 1-5 years living at the site, 2.8% (7/250)
had elevated BLLs, and the geometric mean was 3.04 |ig/dL. These 2003 statistics are slightly
higher than the findings of the National Health and Nutrition Examination Surveys (NHANES)
for children living in the United States as a whole. NHANES data indicate that among U.S.
children aged 1-5 years during 1999-2000, 2.2% had elevated BLLs, and the geometric mean
was 2.2 (j,g/dL.

Picher/Cardin in Comparison with the Tar Creek Superfund Site as a Whole

Of the children in Picher and Cardin who were tested for blood lead, the percentage with
elevated BLLs and the geometric mean declined from 1995-2003 (Figures 5 and 7). In 1996,
OKCLPPSS data showed that among tested children aged 1-5 years living in Picher and Cardin,
44.6% (41/92) had elevated BLLs and the geometric mean was 9.17 (j,g/dL. In 2003, the
OCLPPP data showed that among tested children aged 1-5 years living in Picher and Cardin,
3.4% (3/88) had elevated BLLs, and the geometric mean was 3.82 (j,g/dL.

In 1996, the percentage of children identified with elevated BLLs and the geometric BLL mean
for all children tested were higher in the combined areas of Picher and Cardin than at the site as a
whole. However, these differences have diminished in recent years.

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Characteristics of Children With Elevated BLLs

From January 2000 to March 2004, 37 children under 6 years of age living at the site were
identified with elevated BLLs (at or above 10 |ig/dL) by the Ottawa County Health Department.
Of these children 41% (15/37) were from five households. This could suggest that high-risk
behaviors were shared by these family members or that common exposure sources were present.

In 2003, OCLPPP identified seven children aged 1 to 5 years living at the site as having elevated
BLLs. The OCLPPP program conducted or received data from environmental assessments of the
residences of six of these children at various points in time (some prior to 2003). The potential
sources of lead exposure found to be present at the respective residences are described in Table 7
in the appendix and include lead-based paint, lead-containing floor dust (at or above 10 |ig/ft2),
and soil with elevated lead levels (above 500 mg/kg).

Data Limitations

Any comparisons of the OCLPPP data with NHANES U.S. data should be viewed with caution
because the NHANES data are based on a representative sample of the United States (1, 14), and
the OCLPPP data comprises a convenience sample rather than representative samples of the site
area. As shown in Tables 4 and 5, the OKCLPPSS, TEAL, and OCLPPP data samples include a
substantial proportion but not all of the estimated population of children, aged 1 to 5 years, living
at the site.

NHANES data are generalized to the U.S. population and were not intended to provide estimates
for smaller areas or for specific populations where the risk for elevated BLLs is high (14).
Furthermore, all NHANES blood lead tests are collected by venous sampling (14), whereas the
OSDH CLPPSS and OCLPPP programs primarily collect blood through capillary sampling.
Because sample contamination of a capillary test can over-estimate BLLs (15, 16) and because
ATSDR used each tested child's highest BLL to calculate geometric means, geometric means of
the OSDH CLPPSS and OCLPPP datasets probably overestimate actual geometric means.

The 1997 and 2000 TEAL surveys measured lead from venous blood. Given the relatively high
availability of free screening in the area, it is not known if the use of venous testing and the
presence of incentives to participant families could have resulted in higher relative TEAL
participation in areas of lower median income and among children with higher risk factors for
lead poisoning.

Many other relative factors could be explored, including the prevalence of pre-1950 housing
units and poverty at the site area as compared to that of the United States (Table 3). An updated
NHANES blood lead survey might show a further decline in national BLLs since 1999-2000.
BLLs in U.S. children have been declining (14).

Interventions

Many activities may have been instrumental in reducing elevated BLLs at the site. In 1995, after
the confirmation of elevated BLLs, ATSDR funded the OSDH to conduct extensive blood lead
testing throughout Ottawa County. OSDH determined that 28.3% of children tested had BLLs at
or above 10 (j,g/dL. Several projects implemented over the past several years have increased
community knowledge of exposure and the harmful effects of lead. Some of those include
CHAMP and TEAL. Beginning in 1995, EPA began testing and remediating residential soils and
areas where children play (e.g., school and city parks and playgrounds, ball fields, daycare

14

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centers). Since 1998, the OCHD has conducted extensive blood lead screening, and community
and health provider education. OCHD has distributed HEPA vacuums to area households who
have children with elevated BLLs. The area also received U.S. Housing and Urban Development
funds for lead abatement in homes.

These activities, combined, may have helped to reduce BLLs in Ottawa County. BLLs of
children living at or near the site might increase without these interventions.

V.	Conclusions

Two potential sources were found for lead in children in the Tar Creek site area: mine tailings
and lead-based paint. Both could contribute lead to house dust and soil, which most likely are the
points of exposure for children. The relative contributions of exposure to mine tailings and
exposure to lead-based paint on the BLLs of people living at the site cannot be determined from
existing information.

The evidence available to ATSDR indicates that mine tailings in the residential area soil
exposure pathway may have been a primary source of the lead in children's blood before EPA
remediated the Tar Creek residential areas. Exposure to mine tailings still could occur because
Tar Creek area residents, especially those in Picher and Cardin, remain near tailings piles, ponds,
and embankments and can readily access these tailings deposits. In addition, the close proximity
of these tailings to residences increases the risk for recontamination of residential soil because of
blowing dust or residential or commercial use of the tailings.

A decline in the average BLLs among tested children aged 1 to 5 years living at the site from
1995-2003 has been observed, as was a decrease in the percentage of tested children with
elevated BLLs from 1995 to 2003. The average BLLs and the percentage of elevated BLLs
among tested children living at the site in 2003 were slightly higher than for children living in
the United States as a whole in 1999-2000 (1). However, this comparison should be viewed with
caution because the U.S. data are based on a representative sample of the United States (1), the
Tar Creek data is from a convenience sample and not a representative sample, and U.S. child
BLLs also may have declined since 2000.

Declining BLLs among tested children living at the site should not be interpreted to mean that
existing interventions in the Tar Creek area are no longer needed. Potential lead sources,
including unremediated yards, chat piles, tailings ponds, and residential lead-based paint, remain
at the site.

Existing programs should be evaluated to determine how they may have contributed to this
decline. The Ottawa County Health Department should continue existing blood lead screening
and public health education efforts. Ongoing screening efforts are needed to confirm and monitor
trends. Ongoing public health education reinforces the need for adult, parental, and child
behaviors that may reduce exposure to lead and subsequent health effects.

VI.	Recommendations

ATSDR recommends the following:

• Continue to provide blood lead screening to children living around the site. Currently,
ATSDR provides funds from the EPA to the Ottawa County Health Department to

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conduct screening activities. EPA is continuing to fund these activities through FY
2005.

•	Continue to provide lead exposure prevention education to people potentially
impacted by the site. Currently, ATSDR provides funds from EPA to the Ottawa
County Health Department to engage in prevention education activities. EPA is
continuing to fund these activities through FY 2005.

•	Recommend that the Oklahoma State Department of Health or the Ottawa County
Health Department support periodic reports of Tar Creek and Ottawa County child
blood lead statistics to the Tar Creek Superfund Site and Ottawa County
communities. These reports could include trends and comparisons to state and
national levels.

•	Complete remediation of residential properties. EPA funds this activity. According
to EPA, residential remediation is ongoing.

•	Complete the investigation of chat piles, mill and mine residues, and flotation ponds.
According to EPA, these activities are planned for completion next year.

•	Assess the risk for lead exposure from using mine tailings (chat) for commercial and
residential purposes, including processing and transporting the material. ATSDR has
included in its FY 2004 and in the FY 2005 President's Budget request funding for an
ongoing public health assessment regarding public health hazards associated with the
Tar Creek site. The public health assessment will include identification of gaps in
existing data and recommendations regarding further monitoring and other activities
to evaluate risks of lead exposure. ATSDR recommends that any person proposing to
use chat for commercial purposes arrange for an independent assessment of risks
from exposure potentially associated with that use.

•	To address concerns regarding the sources of lead exposure for children who
currently have elevated BLLs, correlate lead isotopes in the environment and in
children's blood. This approach would seek to identify specific environmental
sources contributing to elevated BLLs in children. The measured ratio of lead

•	206	207 ¦	•	•

isotopes Pb and Pb in the blood of children and adults would be compared with
the ratio of 206Pb and 207Pb in environmental sources and biota (2, 3). ATSDR may
conduct a small project to assess the feasibility of this approach.

•	Evaluate the health risks of other site-related contaminants and of physical hazards.
Funding to support this ongoing activity is included in ATSDR's FY 2004 and FY
2005 President's Budget.

ATSDR is considering whether to evaluate the effectiveness of activities at the Site, including
soil remediation and tribal and non-tribal health education/blood lead screening programs. Such
an evaluation might result in identification and then strengthening of those activities that have
the most impact on reducing or eliminating lead exposure.

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VII. Appendices

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Table 1 — Major Lead Exposure Pathways at the Tar Creek Superfund Site

Pathway Name

Environmental Media
and Transport
Mechanisms

Point Of Exposure

Route Of
Exposure

Exposure
Population

Time

Notes

Complete
Exposure
Pathway?

Residential area
soil

Lead present in soil as a
result of use of tailings as
fill or airborne transport
of tailings from piles or
ponds

Surface soil outside
and house dust
inside homes in Tar
Creek area with soil
leads above 500
mg/kg

Incidental
ingestion,
inhalation

Residents
(particularly
children 6 and
younger)

Past, Present,
Future

Elevated soil lead
concentrations and BLLs
identified in children in Tar
Creek Area prior to the
clean up of residential soil
by EPA. Exposure continues
to occur at any home yet to
be remediated.

Yes

Mine tailings

Lead present in mine
tailings deposited in
tailings piles, ponds, or
embankments

Walking or playing
on the tailings
piles, ponds, or
embankments

Incidental
ingestion,
inhalation

Residents
(particularly
children 6 and
younger)

Past, Present,
Future

Many homes in the Picher
and Cardin area are within
250 feet of tailings deposits.

Yes

Lead-based paint
(LBP) Not site-
related

Lead present in house
dust, soil, and paint chips
due to the use of LBP

House dust, soil,
and paint chips in
or around homes
with deteriorating
LBP

Incidental
ingestion

Residents
(particularly
children 6 and
younger)

Past, Present,
Future

Available data indicate that
30% to 40% of the homes in
the Tar Creek area are likely
to have LBP.

Yes

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Table 2 — Other Lead Exposure Pathways at the Tar Creek Superfund Site

Pathway Name

Environmental Media
and Transport
Mechanisms

Point Of
Exposure

Route Of
Exposure

Exposure
Population

Time

Notes

Complete
Exposure
Pathway?

Ingestion of
homegrown
produce

Uptake of lead from soil
by fruits and vegetables
grown in residential
gardens

Produce
consumption

Ingestion

Residents

Past, Present,
Future

EPA sampling identified low
levels of lead in homegrown
produce.

Yes

Drinking water

Not site-
related

Movement of lead from
lead pipes or solder into
water

Municipal
drinking water

Ingestion

Water supply users

Past, Present,
Future

EPA sampling identified
lead in the tap water of 13
of 100 homes.

Yes

Airborne dust

Airborne transport of mine
tailings from piles, ponds,
and embankments in the
Tar Creek Site Area

Residential areas
near tailings piles,
ponds, and
embankments

Inhalation

Individuals living
near tailings piles,
ponds, and
embankments

Past, Present,
Future

EPA sampling identified low
levels of lead in the air.

Yes

Biota (wild
animals &
plants)

Uptake or ingestion of lead
which had come from
mine tailings in the
environment

Consumption of
animals and plants
contaminated with
lead from the site

Ingestion

Anyone who eats
animals & plants
from site area

Past, Present,
Future

Members of the 9 tribes in
Ottawa County may be at the
greatest risk of exposure to
contaminants in this
pathway.

Unknown

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Table 3 — Demographics in Tar Creek Superfund Site Area*

CHARACTERISTIC

PICHER/CARDIN AREA

TAR CREEK SITE AREA

UNITED STATES

Percent of People in Poverty

26

19

12.4

Percent of Homes Built Prior
to 1950

39

32

22.3

*2000 Census Data

20

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Tar Creek Superfund Site - Report to Congress

Table 4 — Characteristics of Blood Lead Testing Data Among Children Aged 1-5 Years Living within the
Tar Creek Superfund Site*

All Tar Creek Superfund Site (also includes portion of North Miami that is outside the boundaries of Superfund site)

1995	1996	1997	1998	1999	2000	2001	2002	2003	2004

(Jan, Feb only)

Oklahoma Child Lead Poisoning Prevention Program

Total Elevated (>10
Hg/dL) (%)

20(19.4) 67(31.2)

50(22.5)

14(19.2)

9 (9.09)

25 (6.9)

16 (6.4)

11(4.5)

Geometric BLL Mean

4.80 6.65

6.00

5.36

4.93

3.81

3.32

3.05

% Child Tested/Pop
(actual number tested)

16(103) 34(215)

36 (222)

12 (73)

16 (99)

58 (361)

40(249)

39(242)

Sampling Design

Convenience Convenience

Convenience

Convenience

Convenience

Convenience

Convenience

Convenience

TEAL Surveys (Personal Conversation, Malcoe 2004)

Total Elevated (>10
Hg/dL) (%)



26(18.2)





14(8.6)





Geometric BLL Mean



5.77





4.25





% Child Tested/Pop
(actual number tested)



23 (143)





26(162)





Sampling Design



Door-to-door





Door-to-door





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Tar Creek Superfund Site - Report to Congress
Table 4 (Continued)

1995	1996	1997	1998

Ottawa Lead Poisoning Prevention Program

Total Elevated (>10 ng/dL)

(%)

Geometric BLL Mean

% Child Tested/Pop
(actual number tested)

Sampling Design

* n=625 (estimate based on 2000 Census)

009129

1999	2000	2001	2002	2003	2004

(Jan, Feb only)

N/A	13(5.4)	14(8.2)	9(5.7)	7(2.8)	N/A

5.13	3.62	3.15	2.65	3.04	2.21

5(33)	38(240)	27(171)	25(158)	40(250)	9(55)

Convenience Convenience Convenience Convenience Convenience Convenience

22


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Tar Creek Superfund Site - Report to Congress

Table 5 — Characteristics of Blood Lead Testing Data Among Children Aged 1-5 Years Living within the
Tar Creek Superfund Site*

Picher and Card in only

1995	1996	1997	1998	1999	2000	2001	2002	2003	2004

(Jan, Feb
only)

Oklahoma Child Lead Poisoning Prevention Program

Total Elevated (>10 ng/dL) 17(31.5)	41 (44.6)	34(33.7)	5(29.4)	3(9.1)	17(13.2)	7(12.1)	3(7.0)

(%)

Geometric BLL Mean	6.13	9.17	7.66	6.63	5.24	4.30	4.42	4.24

% Child Tested/Pop	36(54)	61 (92)	67(101)	11 (17)	22(33)	86(129)	39(58)	29(43)

(actual number tested)

Sampling Design	Convenience Convenience Convenience Convenience Convenience Convenience Convenience Convenience

TEAL Surveys (Personal Conversation, Malcoe 2004)

Total Elevated (>10 ng/dL)	16(25.0)	10(13.3)

(%)

Geometric BLL Mean	6.63	4.76

% Child Tested/Pop	43 (64)	50 (75)

(actual number tested)

Sampling Design	Door-to-door	Door-to-door

Ottawa Lead Poisoning Prevention Program

Total Elevated (>10 ng/dL)	N/A	6(8.2)	5(12.2)	2(6.67)	3(3.4)	N/A

(%)

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Tar Creek Superfund Site - Report to Congress
Table 5 (Continued)

1995	1996	1997	1998

Geometric BLL Mean

% Child Tested/Pop
(actual number tested)

Sampling Design

* n=150 (estimate based on 2000 Census)

009131

1999	2000	2001	2002	2003	2004

(Jan, Feb
only)

4.99	3.86	4.76	4.64	3.82	2.43

9 (13)	49 (73)	27 (41)	20 (30)	59 (88)	11 (17)

Convenience Convenience Convenience Convenience Convenience Convenience

24


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Tar Creek Superfund Site - Report to Congress
Table 6 - Existing Health Study Information

Factors Associated with
Elevated BLLs*

Teal Study

(Lynch et al. 2000) OR (95% CI)

Teal Study

(Malcoe et al. 2002) OR (95% CI)

Floor lead dust > 10 ug/ft2

8.1 (1.8, 37.8)

11.4(3.5, 37.3)

Yard soil lead

>500 mg/kg

6.4(1.4, 30.7)



>165.3 mg/kg (front yard)



4.1 (1.3, 12.4)

Any interior lead paint

3.0(1.2, 7.8)



Superfund location

3.4(1.3,8.8)

5.6(1.8, 17.8)

Hand-to-mouth behaviors





index 2



7.0 (3.0, 16.5)

index 3



48.9 (8.7, 272.7)

* Blood lead levels

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Tar Creek Superfund Site - Report to Congress

Table 7 — Children Aged 1-5 Years Living in the Tar Creek Superfund Site with Known Elevated BLLs in
2003, Residential Assessment Lead Exposure Status

Child

Known Exposure Status*

Environmental
Testing (Y/N)

Environmental Age in Years
Testing Date

Race

Sex

Residence

Blood Lead
Level

1

Unknown; frequent mover

N

3

W

M

Commerce

13.0

2

Lead-based paint

Y

12/16/2003 2

W

M

Quapaw

11.8

3

Lead-based paint

Y

11/15/2003 3

w

F

Picher

12.1

4

Floor dust, soil, no
electricity or running water

Y

2/9/2001 2

w

F

Picher

17.6

5

Floor dust, soil, no
electricity or running water

Y

2/9/2001 5

w

M

Picher

15.8

6

Lead-based paint, floor
dust, soil

Y

9/12/2002 3

w

M

Quapaw

23.7

7

Lead-based paint, floor
dust, soil

Y

9/12/2002 1

w

F

Quapaw

17.0

* Child may have moved and potential exposure source may have been remediated since testing date.

[Source: Ottawa County Lead Poisoning Prevention Program Data, 2003]







26

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VIII. Figures

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Tar Creek Superfund Site - Report to Congress

Quapav/

Commerce

North

~ Boundaries of Tar Creek Site Area
Soil lead levels by block_all data .shp
No Samples
Less 500 mg/kg
11111 500 - 1,200 mg/kg
mm Greater than 1,200 mg/kg

Figure 1 - Soil Lead Levels in Tar Creek

Residential Area Soil

Agency for Toxic Substances and Disease Registry

Prepared by John R. Crellin, Ph.D-ATSDR: 04202

Baxter Springs, Kansa

o.

Kansas

TAR CREEK SITE
STUDY AREA

LEGEND

Rairoads

a Roads
Boundark

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Tar Creek Superfund Site - Report to Congress

Figure 2 - Tailings in the Picher, Cardin, and Quapaw Area

Agency for Toxic Substances and Disease Registry

Prepared by John R. Crellin, PhD- 04202004

009136

29


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Figure 3

TAR CREEK CREEK SUPERFUND SITE - DATA FLOW FOR CHILD BLOOD LEAD DATA
1995-2004

30

009137


-------
Figure 4

Children Age 1-5 Years Old With Elevated BLLs (> 10 [lgldL)
All Tar Creek Superfund Site

Oklahoma State Childhood Lead Poisoning
Prevention Program Surveillance Data

Ottawa County Lead Poisoning
Prevention Program Data

1995

1996

1997

1998

1999

Year

2000

2001

2002

2003

009138

31


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1995

1996

1997

1998

1999

Year

2000

2001

2002

2003

Figure 5

Children Age 1-5 Years Old With Elevated BLLs (> 10 (jg/dL)

Picherand Cardin Only

Oklahoma State Childhood Lead Poisoning
Prevention Program Surveillance Data

TEAL Survey Data

Ottawa County Lead Poisoning
Prevention Program Data

009139

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Figure 6

Geometric Blood Lead Means of Children Age 1-5 Years Old
All Tar Creek Superfund Site

Oklahoma State Childhood Lead Poisoning

Ottawa County Lead Poisoning
Prevention Program Data

	1	1	1	1	1	1	1	1	1

1995 1996 1997 1998 1999 2000 2001 2002 2003

Year

33


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11

10

9

8

7

6

5

4

3

2

1

0

Figure 7

Geometric Blood Lead Means of Children Age 1-5 Years Old

Picherand Cardin Only

Ottawa County Lead Poisoning
Prevention Program Data

	1	1	1	1	1	1	1	1	1

1995 1996 1997 1998 1999 2000 2001 2002 2003

Year

34


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IX. References

1.	National Center for Health Statistics, National Health and Nutrition Examination Survey.
Hyattsville, Maryland: US Department of Health and Human Services, CDC. Available at:
http://www.cdc.gOv/nceh/lead/research/kidsBLL.htm#National%20surveys.

2.	Jaeger RJ, Weiss AL, Manton WI. Isotope ratio analysis in residential lead-based paint and
associated surficial dust. Journal of Toxicology - Clinical Toxicology, 36(7): 691-703,

1998.

3.	Manton W, Angle C, Stanek L, Reese Y, Kuehnemann A. Acquisition and retention of lead
by young children. Environ Res, 2000; 82:60-80.

4.	Agency for Toxic Substances and Disease Registry. Public health assessment guidance
manual. Atlanta, Georgia: US Department of Health and Human Services, 1992. Available
at http: //atsdr 1. at sdr. cdc. gov: 8080/H AC/H AGM.

5.	Ecology and Environment, Inc. Baseline human health risk assessment of residential
exposures Tar Creek Superfund Site, Ottawa County, Oklahoma. Lancaster, New York:
Ecology and Environment, Inc. Prepared for EPA Region 6. 1996.

6.	Malcoe L, Lynch R, Kegler M, Skaggs V. Lead sources, behaviors, and socioeconomic
factors in relation to blood lead of native American and white children: a community-based
assessment of former mining area. Environmental Health Perspectives; 2002; 110:221-31.

7.	Jacobs DE, Clickner RP, Zhou JY, Viet SM, Marker DA, Rogers JW, et al. The prevalence
of lead-based paint hazards in U.S. housing. Environmental Health Perspect, 2002, 110:
599-606.

8.	Ecology and Environment, Inc. Data evaluation summary report Tar Creek site. Site
assessment/risk assessment. Ottawa County, Oklahoma. Dallas, Texas: Ecology and
Environment, Inc. Prepared for EPA Region 6, December 1995.

9.	Luza, K.V. 1986. A Study of Stability Problems and Hazard Evaluation of the Oklahoma
Portion of the Tri-State Mining Area (3 maps). Oklahoma Geological Survey Circular 88,
6/8/05.

10.	Agency for Toxic Substances and Disease Registry. Toxicological profile for lead. Atlanta,
Georgia: US Department of Health and Human Services, 2001.

11.	Hough RL, Breward N, Young SD, Crout NMJ, Tye AM, Moir AM, et al. Assessing
potential risk of heavy metal exposure from consumption of home produced vegetables by
urban populations. Environ Health Perspect 2004; 1 12:215—21. Available at
http://ehp.niehs.nih.gov/members/2003/5589/5589.html.

12.	Lynch R, Malcoe L, Skaggs V, Kegler M. The relationship between residential lead
exposures and elevated blood-lead levels in a rural mining community. Journal of
Environmental Health; 2000; 63:9-15.

13.	Agency for Toxic Substances and Disease Registry. Ottawa County Blood Lead Testing
Project: Atlanta, Georgia: US Department of Health and Human Services, ATSDR, 1997.

14.	Centers for Disease Control and Prevention. Surveillance for elevated blood lead levels
among children-United States, 1997-2001. MMWR 2003;52:SS-10.

15.	Centers for Disease Control and Prevention. Preventing lead poisoning in young children.
Atlanta, Georgia: US Department of Health and Human Services, CDC, 1991.

16.	Centers for Disease Control and Prevention. Screening young children for lead poisoning:
guidance for state and public health officials. Atlanta, Georgia: US Department of Health
and Human Services, 1997.

35

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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT HUMAN HEALTH RISK ASSESSMENT

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U SEPA\317950\T7\RA04\D RAFT_2005-1028
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Appendix N

Preliminary Remediation Goal Calculations

009144


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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
009145

FEBRUARY 2006


-------
Figure 1: Comparison of All Concentrations
for Cadmium in Washed Root

0 20 40 60 80 100 120
Plant Concentration, mg/kg

X represents data pairs excluded via Cook's distance evaluation.


-------
Figure 2: Regression Analysis of Non-excluded Concentrations

for Cadmium in Washed Root

Plant Concentration, mg/kg

X represents data pairs excluded via Cook's distance evaluation.

009147


-------
Figure 3: Comparison of All Concentrations
for Lead in Washed Root

9000
™ 8000

O)

E

7000
g" 6000
1 5000

0)

o
c

o
O

o
CO

4000
3000
2000
1000
0

X



•

is.

X

0

1000	2000	3000

Plant Concentration, mg/kg

X represents data pairs excluded via Cook's distance evaluation.

009148


-------
Figure 4: Regression Analysis of Non-excluded Concentrations

for Lead in Washed Root

Plant Concentration, mg/kg

X represents data pairs excluded via Cook's distance evaluation.

009149


-------
Figure 5: Comparison of All Concentrations
for Zinc in Washed Root

120000
110000
100000
90000
80000
70000
60000
50000
40000
30000
20000
10000
0

0 1000 2000 3000 4000
Plant Concentration, mg/kg



X

•



• •

•

•



X

I	I	I	I	I

X represents data pairs excluded via Cook's distance evaluation.


-------
Figure 6: Regression Analysis of Non-excluded Concentrations

for Zinc in Washed Root

Plant Concentration, mg/kg

X represents data pairs excluded via Cook's distance evaluation.

009151


-------
Figure 1: Box and Whisker Plot Comparison of Lead Concentrations

5000

4000 -

E 3000

2000 -

1000 -

Background

Residential

Rural

Transition

009152


-------
:igu

1200

1100

1000

900

800

700

600

500

400

300

200

100

0

2: Box and Whisker Plot Comparison of Lead Concentrations

*

*
*

~
*

*
*
*

*
*

s

x

Backg round

Residential

*
*

zc

Rural


-------
Figure 3: Box and Whisker Plot Comparison of Lead Concentration Ranks

400 -

300 -

c

200 -

100 -

o -*			

Background	Residential	Rural	Transition

009154


-------
Figure 4: Box and Whisker Plot Comparison of Lead Concentration Ranks

c

a:

Backg round

Residential

Rural

009155


-------
Table N-1

Soil PRGs for General Public Agriculture On-Property

Tar Creek OU4, Miami, OK

Fl - Veg

Cd

Zn

Adult

Child

Adult

Child

Soil PRG

Plant

Soil PRG

Plant

Soil PRG

Plant

Soil PRG

Plant

(mg/kg)

(mg/kg)

(mg/kg)

(mg/kg)

(mg/kg)

(mg/kg)

(mg/kg)

(mg/kg)

10%

9.40E+00

1.18E+00

4.86E+00

6.08E-01

3.58E+03

3.51 E+02

1.83E+03

1.79E+02

25%

3.79E+00

4.74E-01

2.02E+00

2.53E-01

1.45E+03

1.42E+02

7.67E+02

7.52E+01

50%

1.90E+00

2.37E-01

1.02E+00

1.28E-01

7.26E+02

7.12E+01

3.90E+02

3.82E+01

100%

9.51E-01

1.19E-01

5.15E-01

6.44E-02

3.64E+02

3.57E+01

1.97E+02

1.93E+01

Fl = fraction ingested from impacted source

009156


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Table N-2

Soil PRGs for General Public Agriculture On-Property
Tar Creek OU4, Miami, OK

Adult (General Public)	Child (General Public)



Cadmium

Zinc

Reference

Cadmium

Zinc

Reference

CSon

Concentration in Soil (on property)

mg/kg

1.0

364

EPC

0.5

197

EPC

IR-S

Ingestion Rate of Soil

mg/day

100

100

EPA, 1991

200

200

EPA, 1991

Cveg

Chemical Concentration in Veg

mg/kg

0.1

35.7

Calculated

0.1

19.3

Calculated



slope (a)



8.0

10.2

1/Br (EPA, 1998)

8.0

10.2

1/Br (EPA, 1998)

IR-VEG

Ingestion Rate - Vegetable

kg/day

0.59

0.59

EPA, 1997 (Table 9-4)

0.23

0.23

EPA, 1997 (Table 9-4)

FI-VEG

Fraction Ingested - Veg

%

100%

100%



100%

100%



EF

Exposure Frequency (soil)

days/year

350

350

EPA, 1991

350

350

EPA, 1991

EF

Exposure Frequency (ingestion)

days/year

365

365

EPA, 1997

365

365

EPA, 1997

ED

Exposure Duration

years

24

24

EPA, 1991

6

6

EPA, 1991

BW

Body Weight

kg

70

70

EPA, 1991

15

15

EPA, 1991

AT-N

Averaging Time (Non-Cancer)

days

8,760

8,760

EPA, 1991

2,190

2,190

EPA, 1991



Contribution: Soil



1.3E-06

5.0E-04



6.6E-06

2.5E-03





Soil Intake Factor



1.4E-06

1.4E-06



1.3E-05

1.3E-05





Contribution: Vegetable



1.0E-03

3.0E-01



9.9E-04

3.0E-01





Veg Intake Factor



8.4E-03

8.4E-03



1.5E-02

1.5E-02





Cumulative Intake



1.0E-03

3.0E-01



1.0E-03

3.0E-01



RfD (ing)

Ingestion Reference Dose

mg/kg-day

0.001

0.3

IRIS

0.001

0.3

IRIS



HQ: Soil



1.3E-03

1.7E-03



6.6E-03

8.4E-03





HQ: Vegetable



1.0E+00

1.0E+00



9.9E-01

9.9E-01





Total HI



1.00

1.00



1.00

1.00





Soil PRG (based on Soil)



7.3E+02

2.2E+05

mg/kg (soil only)

7.8E+01

2.3E+04

mg/kg (soil only)







9.5E-01

3.6E+02

mg/kg (plant + soil)

5.2E-01

2.0E+02

mg/kg (plant + soil)

Hl = i 1i

009157


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Table N-3

Soil PRGs for General Public Agriculture and Native American On-Property
Tar Creek OU4, Miami, OK

Soil

Pb

Soil PRG

Adult

460.3 (mg/kg)

Native American

Pb

Soil PRG

IR

Adult

110.4

(mg/kg)

400

(mg/day)

441.4

(mg/kg)

100

(mg/day)

Beef

General Public Agriculture

Fl - Beef

Pb

Adult

Soil PRG

Beef

(mg/kg)

(mg/kg)

10%

455.2

0.13

25%

447.8

0.12

50%

436.0

0.12

100%

414.1

0.11

Native American (IRsoil = 400 mg/day)

Fl - Beef

Pb

Adult

Soil PRG

Beef

(mg/kg)

(mg/kg)

10%

109.1

0.030

25%

107.2

0.030

50%

104.3

0.029

100%

98.8

0.027

Native American (IRsoil = 100 mg/day)

Fl - Beef

Pb

Adult

Soil PRG

Beef

(mg/kg)

(mg/kg)

10%

421.7

0.116

25%

395.3

0.109

50%

357.9

0.098

100%

301.0

0.083

General Public Agriculture
Beef intake from Table 11 -3 of EPA, 1997.
0.648 g/kg-day - 50th percentile (Region-South)
x 60 kg body weight (per EPA, 1997) = 38.88 g/day

Native American

Beef intake from Table 11 -3 of EPA, 1997.
2.825 g/kg-day - 95th percentile
x 60 kg body weight (per EPA, 1997) = 169.5 g/day

Plant

General Public Agriculture

Fl - Plant

Pb

Adult

Soil PRG

Plant

(mg/kg)

(mg/kg)

10%

111.9

1.52

25%

52.4

0.71

50%

27.8

0.38

100%

14.3

0.19

Native American (IRsoil = 400 mg/day)

Fl - Plant

Pb

Adult

Soil PRG

Plant

(mg/kg)

(mg/kg)

10%

33.2

0.45

25%

16.2

0.22

50%

00
CO

0.12

100%

4.6

0.062

General Public Agriculture
Vegetable intake from Table 9-4 of EPA, 1997.
3.66 g/kg-day - 50th percentile (Region-South)
x 60 kg body weight (per EPA, 1997) = 219.6 g/day.

Native American

Vegetable intake from Table 9-4 of EPA, 1997.
11.37 g/kg-day -95th percentile
x 60 kg body weight (per EPA, 1997) = 682.2 g/day.

Fl = fraction ingested from an impacted source.

PRGs were calculated based on the new NHANES GSD of 2.1 and baseline blood lead level of 1.16.

009158


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TAR CREEK SUPERFUND SITE
OPERABLE UNIT NO. 4
DRAFT FINAL HUMAN HEALTH RISK ASSESSMENT

(This page intentionally left blank.)

USEPA\317950\T7\RA04\DRAFT FINAL_2006-02
009159

FEBRUARY 2006


-------
Calculations of Preliminary Remediation Goals (PRGs)

Table N-4

Calculations of Preliminary Remediation Goals (PRGs) - General Public

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee

Version date 05/19/03

Exposure
Variable

PRG

Equation

Description of Exposure Variable

Units

Values for Non-Residential
Exposure Scenario

Using Equation 1

1*

2* *

GSDi = Horn

GSDi = Het

PbBfetal o 95

X

X

95th percentile PbB in fetus

ug/dL

10

10

"D

-^Metal/m aternal

X

X

Fetal/maternal PbB ratio

-

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB

-

2.1

2.1

PbB„

X

X

Baseline PbB

ug/dL

1.16

1.16

iRs

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.100

0.100

afSiD

X

X

Absorption fraction (same for soil and dust)

-

0.12

0.12

EFS D

X

X

Exposure frequency (same for soil and dust)

days/yr

350

350

PbBeef





Chemical Concentration in Beef

mg/kg

1.3.E-01

1.3.E-01

BAFb





Bio-accumulation Factor - Beef

-

2.8E-04

2.8E-04

IRb

X



Beef ingestion rate

g/day

39

39

FIb





Fraction Ingested - Beef

%

0%

0%

AFb

X

X

Absorption fraction (same for soil and dust)

-

0.12

0.12

EFb

X

X

Exposure frequency (ingestion)

days/yr

365

365

I'knil





Chemical Concentration in Plant

mg/kg

6.3

6.3

1/BAF





slope (a) - 1/Br

-

73.5

73.5

IRP

X



Plant ingestion rate

g/day

220

220

FIp





Fraction Ingested - Plant

%

0%

0%

AFP

X

X

Absorption fraction (same for soil and dust)

-

0.12

0.12

EFP

X

X

Exposure frequency (ingestion)

days/yr

365

365

AT

X

X

Averaging time (same for soil and dust)

days/yr

365

365







1.7E+00

1.7E+00







0.0E+00

0.0E+00







0.0E+00

0.0E+00







0.0E+00

0.0E+00

PRG

Preliminary Remediation Goal

ppm

460

460

1 Equation 1 does not apportion exposure between soil and dust ingestion (excludes Ws, KSD).
When IRS = IRS+D and Ws = 1.0, the equations yield the same PRG.

'Equation 1, based on Eq. 4 in USEPA (1996).	

PRG =	([PbB95fetal/(R*(GSDi1 645)] )-PbB0)*AT

BKSF*AF*[(IRs+D*EFSD)+(BAFB*IRB*FlB*EFB)+((IRp*FIp*EFp)/a)]

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil
009160


-------
Calculations of Preliminary Remediation Goals (PRGs)

Table N-5

Calculations of Preliminary Remediation Goals (PRGs) - Native American

U.S. EPA Technical Review Workgroup for Lead, Adult Lead Committee

Version date 05/19/03

Exposure
Variable

PRG

Equation

Description of Exposure Variable

Units

Values for Non-Residential
Exposure Scenario

Using Equation 1

1*

2* *

GSDi = Horn

GSDi = Het

PbBfetal o 95

X

X

95th percentile PbB in fetus

ug/dL

10

10

"D

-^Metal/m aternal

X

X

Fetal/maternal PbB ratio

-

0.9

0.9

BKSF

X

X

Biokinetic Slope Factor

ug/dL per
ug/day

0.4

0.4

GSD;

X

X

Geometric standard deviation PbB

-

2.1

2.1

PbB„

X

X

Baseline PbB

ug/dL

1.16

1.16

iRs

X



Soil ingestion rate (including soil-derived indoor dust)

g/day

0.100

0.100

afSiD

X

X

Absorption fraction (same for soil and dust)

-

0.12

0.12

EFS iD

X

X

Exposure frequency (same for soil and dust)

days/yr

365

365

PbBeef





Chemical Concentration in Beef

mg/kg

8.3.E-02

8.3.E-02

BAFb





Bio-accumulation Factor - Beef

-

2.8E-04

2.8E-04

IRb

X



Beef ingestion rate

g/day

170

170

FIb





Fraction Ingested - Beef

%

100%

100%

AFb

X

X

Absorption fraction (same for soil and dust)

-

0.12

0.12

EFb

X

X

Exposure frequency (ingestion)

days/yr

365

365

I'knil





Chemical Concentration in Plant

mg/kg

4.1

4.1

1/BAF





slope (a) - 1/Br

-

73.5

73.5

IRP

X



Plant ingestion rate

g/day

682

682

FIp





Fraction Ingested - Plant

%

0%

0%

AFP

X

X

Absorption fraction (same for soil and dust)

-

0.12

0.12

EFP

X

X

Exposure frequency (ingestion)

days/yr

365

365

AT

X

X

Averaging time (same for soil and dust)

days/yr

365

365







1.8E+00

1.8E+00







8.2E-01

8.2E-01







0.0E+00

0.0E+00







0.0E+00

0.0E+00

PRG

Preliminary Remediation Goal

ppm

301.0

301.0

1 Equation 1 does not apportion exposure between soil and dust ingestion (excludes Ws, KSD).
When IRS = IRS+D and Ws = 1.0, the equations yield the same PRG.

'Equation 1, based on Eq. 4 in USEPA (1996).	

PRG =	([PbB95fetal/(R*(GSDi1 645)] )-PbB0)*AT

BKSF*AF*[(IRs+D*EFSD)+(BAFB*IRB*FlB*EFB)+((IRp*FIp*EFp)/a)]

Source: U.S. EPA (1996). Recommendations of the Technical Review Workgroup for Lead
for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil

009161


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Table N-6

Soil PRGs for Native American Adult - Vegetables Grown On-Property
Tar Creek OU4, Miami, OK

Fl - Veg

Adult

Cd

Zn

Soil PRG

Plant

Soil PRG

Plant

(mg/kg)

(mg/kg)

(mg/kg)

(mg/kg)

10%

7.84E+00

9.80E-01

2.96E+03

2.90E+02

25%

3.22E+00

4.03E-01

1.23E+03

1.20E+02

50%

1.63E+00

2.03E-01

6.21E+02

6.08E+01

100%

8.17E-01

1.02E-01

3.12E+02

3.06E+01

Fl = fraction ingested from an impacted source.

009162


-------
Table N-7

Soil PRGs for Native American Adult - Vegetables Grown On-Property
Tar Creek OU4, Miami, OK		

Adult (Tribal)



Cadmium

Zinc

Reference

CSon

Concentration in Soil (on property)

mg/kg

0.8170411

312.1175

EPC

IR-S

Ingestion Rate of Soil

mg/day

400

400

Harper et al., 2002

Cveg

Chemical Concentration in Veg

mg/kg

0.1

30.6

Calculated



slope (a)



8.00

10.2

1/Br (EPA, 1998)

IR-VEG

Ingestion Rate - Vegetable

kg/day

0.68

0.68

EPA, 1997 (Table 9-4)

FI-VEG

Fraction Ingested - Veg

%

100%

100%



EF

Exposure Frequency (soil)

days/year

365

365

Harper et al., 2002

EF

Exposure Frequency (ingestion)

days/year

365

365

Harper et al., 2002

ED

Exposure Duration

years

64

64

Harper et al., 2002

BW

Body Weight

kg

70

70

EPA, 1991

AT-N

Averaging Time (Non-Cancer)

days

23,360

23,360

EPA, 1991



Contribution: Soil



4.7E-06

1.8E-03





Soil Intake Factor



5.7E-06

5.7E-06





Contribution: Vegetable



1.0E-03

3.0E-01





Veg Intake Factor



9.7E-03

9.7E-03





Cumulative Intake



1.0E-03

3.0E-01



RfD (ing)

Ingestion Reference Dose

mg/kg-day

0.001

0.3

IRIS



HQ: Soil



4.7E-03

5.9E-03





HQ: Vegetable



1.0E+00

9.9E-01





Total HI



1.00

1.00





Soil PRG (based on Soil)

i



1.8E+02
8.2E-01

i

5.3E+04
3.1E+02

mg/kg (soil only)
mg/kg (plant + soil)

H"i 1i

009163


-------
Table N-8

PRGs for Lead in Soil (General Public Agricultural Child) - Milk from Cows on the Receptor's Yard
Acceptable Concentration in Soil

Soil Cone. Soil Cone.

(on	(off	Cone. In	% of milk

property)	property)	Milk	consumption	Soil concentration 50 mg/kg associated with P10<5 %

50	3.40E+03	0.78	10 slope Cone. Milk % Milk

100	2.92E+03	0.67	10 | 4361 ~|

150	2.44E+03	0.56	10 0.78	10

200	1.96E+03	0.45	10 0.312	25

250	1.44E+03	0.33	10

300	9.59E+02	0.22	10

325	7.41E+02	0.17	10

350	(not calculated - too low)

Soil concentration 100 mg/kg

50	1.36E+03	0.312	25

100	1.17E+03	0.268	25 0.67	10

150	9.77E+02	0.224	25 0.268	25

200	7.85E+02	0.18	25

250	5.76E+02	0.132	25

300	3.84E+02	0.088	25

325	2.97E+02	0.068	25

350	(not calculated - too low)	Soil concentration 150 mg/kg

0.56	10

0.224	25

Soil concentration 200 mg/kg

0.45	10

0.18	25

Soil concentration 250 mg/kg

0.33	10

0.132	25

Soil concentration 300 mg/kg

0.22	10

0.088	25

Soil concentration 325 mg/kg

0.17	10

0.068	25

009164


-------
Soil Cone (property) VS Milk Cone.
Associated with P10<5%

Soil Concentration (on-
property) (mg/kg)

-Milk

Consumption
is 10% of
total milk
consumed

Soil Cone, (property) VS Milk Cone.
Associated with P10<5%

s=

— to 1.5E+03
c ^

.2 o)

g E 1.0E+03

1 >

3 t 5.0E+02
° o

" o. 0.0E+00

W	<§>

Soil Concentration (on-
property) (mg/kg)

¦Milk

Consumption
is 25% of
total milk
consumed

009165


-------
Table N-9

PRGs for Lead in Soil (General Public Agricultural Child) - Beef from Cows on the Receptor's Yara

Soil Cone.

(on
property)

Cone. In
Pasture

Cone. In
Beef

% of meat
consumption

% above (10

ug/dl) slope

Soil concentration 50 mg/kg associated with P10<5 %

50

6.91 E+03

1.9

10

5.321

| 3634 |

conc. Beef % meat

100

5.56E+03

1.53

10

5.04



1.9 10

150

4.36E+03

1.2

10

4.99



0.75 25

200

3.27E+03

0.9

10

5.13





250

2.00E+03

0.55

10

4.96





300

8.36E+02

0.23

10

4.96





325

2.91 E+02

0.08

10

5.02





350

3.63E+00

0.001

10

5.53















Soil concentration 100 mg/kg

50

2.73E+03

0.75

25

5.09





100

2.25E+03

0.62

25

5.08



1.53 10

150

1.78E+03

0.49

25

5.07



0.62 25

200

1.27E+03

0.35

25

4.9





250

8.36E+02

0.23

25

5.03





300

3.63E+02

0.1

25

5





325













350











Soil concentration 150 mg/kg

1.2
0.49

10
25

Soil concentration 200 mg/kg

0.9
0.35

10
25

Soil concentration 250 mg/kg

0.55
0.23

10
25

Soil concentration 300 mg/kg

0.23
0.1

10
25

Soil concentration 325

0.08
0

10
25

009166


-------
Soil Cone. VS Beef Cone. Associated with
P10<5%

7.5E+03

o ^
o)

C

.2

S | 5.0E+03

a) rr

g oJ 2.5E+03
o Q-

o 2

o ^ 0.0E+00

-------