SOURCE TEST AT U.S. STEEL
CLAIRTON COKE OVENS
CLAIRTON, PENNSYLVANIA
by
M. W. HARTMAN
Contract No. 68-02-2812
Assignment No. 23
EPA Technical Manager: Gene Riley
Prepared for:
U. S. Environmental Protection Agency
Emission Standards and Engineering Division
Emission Measurements Branch
Research Triangle Park, NC 27711
TRW Environmental Engineering Division
3200 E. Chapel Hill Rd./Nelson Hwy.
P. 0. Box 1300D
Research Triangle Park, NC 27709
-------
GLOSSARY
BaP - Benz-a-Pyrene
BSO - Benzene Soluble Organ!cs
DSCM - Dry Standard Cubic Meters
GC - Gas Chromatograph
MeCl - Methylene Chloride
MS - Mass Spectrophometer
PAH - Polynuclear Aromatic Hydrocarbons
POM - Polycyclic Organic Matter
SASS - Source Assessment Sampling System
SAMPLE LABELING GLOSSARY
CD - Module Condensate
CICD - Impinger Contents
CIMC - Methylene Chloride Impinger Rinse
MR - Module Rinse Methylene Chloride
NMC - MeCl Nozzle Rinse
NPR - Nozzle Probe/Filter Rinse
P - Combined Probe
PF - Filter
PIB - Probe/Impinger Benzene Rinse
PICD - Probe/Impinger Condensate
PR - Probe/Filter Rinse
V - Vent Rinse
VB - Benzene Vent Rinse
VMC - Vent Rinse Methylene Chloride
XR - XAD-2 Resin
-------
TABLE OF CONTENTS
PAGE
1.0 INTRODUCTION 1
2.0 SUMMARY ..... 2
3.0 DESCRIPTION OF RESULTS . 5
4.0 PROCESS DESCRIPTION ....... 8
5.0 LOCATION OF SAMPLING POINTS ...... 12
6.0 TEST PROCEDURES 14
APPENDIX A: COMPLETE RESULTS AND SAMPLE CALCULATIONS
APPENDIX B: LABORATORY RESULTS
APPENDIX C: FIELD DATA SHEET
APPENDIX D: TEST LOG
APPENDIX E: PROJECT PARTICIPANTS
-------
1.0 INTRODUCTION
During the week of July 30 through August 6, 1978, TRW Environ-
mental Engineering Division, under Contract No, 68-02-2812, with the
Environmental Protection Agency's Emission Measurement Branch, tested a
battery of coke ovens at U.S. Steel's Clairton, Pennsylvania plant. The
purpose of this sampling was two-fold; 1) to provide data associated
with emissions of polycyclic organic matter from topside leaks and 2) to
verify that a reduction in visible topside emissions would result in an
emissions reduction of polycyclic organic material.
Sampling was conducted in order to determine the emission rate
(mg/min) of pollutants from a simulated coke oven topside leak; two
different size leaks were tested. In addition, background ambient
samples were taken from battery topside. The leaks were simulated by
modifying an oven port lid to include a vent tube which utilized a ball
valve for controlling the leak rate. Samples were collected by placing
the nozzle of the sampling train probe directly above the vent tube.
Pollution emission rates were determined for Benzene Soluble Organics
(BSO), Polycyclic Organic Matter (POM), and Benz-a-Pyrene {BaP); determi-
nation of a Benzene emission rate was attempted but was not successful.
1
-------
2.0 SUMMARY
During the week of testing at the Clairton Coke Works, seven sam-
ples of BSO/POM were taken from the simulated oven leaks on Battery
Number 1. In addition, two ambient air samples were taken at the
battery topside to provide information on the background pollutant
level. During each run the simulated leak was adjusted to give either a
large leak (approximately a three to six-foot visible plume) or a small
leak (approximately a one-foot visible plume). Tests one through four
were taken during a large leak while tests five through seven were taken
during a small leak. Photographs of the sampling apparatus and the
simulated leaks were taken during the test program for EPA by U.S. Steel
personnel; these photographs are on file at the EPA. All sampling was
done on the number one coke oven battery at the Clairton Plant. In
order to minimize problems with taking the sampling equipment onto the
hot battery topside, the ovens closest to the pinion wall were selected
for testing. In all cases, the oven lid closest to the push side of the
battery was used. Sampling was begun between the first and second hours
after the oven was charged. The ambient samples were taken on battery
topside past the pinion wall (i.e., between oven A-l, and the end of the
battery); this position was approximately 40 feet from the simulated
leak. A more detailed discussion of the sampling locations is presented
in Section 5. A Summary of Results are shown in Table 2.1.
Separate sampling trains were used for the BSO and the POM/BaP
sampling. In order to obtain comparable BSO/POM data, a common nozzle
was used so that both trains could simultaneously sample the same leak
The sampling rates were adjusted so that approximately half of the leak
went to each train. Both trains were of a modified Source Assessment
Sampling System (SASS); SASS trains were used in order to obtain a high
sample rate.
-------
¥
1
2
3
4
5
6
7
5ft
58
7A
5A
SB
i
SUMMARY OF RESULTS
ISO
£
&
h"
in
te
M
5
a
us
h-
s
S
U!
_4
12:50
8/2
^ III
Larne
14:23
8/2
A I
Large
8:35
8/3
A V
Large
10:16
8/3
A VII
Large
12:53
8/4
A 11
Small
21:32
8/4
A I
Small
16:45
8/5
A I
Small
12:33
8/4
Ambient
None
21:12
8/4
Ambient
None
15:07
8/5
Ambient
None
24
6
15
8
16
15
15
56
55
70
784
1700
881S
1618
458
714
1312
9.3
9.0
283.33
587.93
202.25
28.63
47.60
87.47
0.084
l«r.fi4
0.118
1.069
0.148
0.672
0.730
0.604
9.988
0.128 6.709
30
9
15
10
15
15
15
55
55
69
2189
511
7.6
218,9
34.0
1,873
0.131
0.637
0.404
0.823
0.880
0.803
9.608
0.11 6.347
35.83 3.58
17.91 1.19
0.12 0.0017
Collected During Run 5
Collected During Run 6
Table 2.1. SUMMA.PY OF RESULTS
-------
POLTCYCLIC ORGANIC MATERIAL ANALYSES
BAP 4
BAP 7
BAP 7A
COMPOUND
MOLECULAR WT.
MASS (tug}
EMISSION
RATE (mg/min)
MASS (mg)
EMISSION
RATE (mg/min)
MASS (mg)
EMISSION
RATE (mg/mii)
NAPHTHALENE
128
320.2
32.0
138.8
9.2
DIPHENYL
154
13.6
1.4
3,1
0.2
DIMETHYLNAPHTHALENES
156
10.1
1.0
1.6
0.1
ACENAPHTHYLENE
152
128.8
12.3
DIBENZOFURAN
168
71.8
7.2
FlUORENE
166
81.0
8.1
15.4
1.0
DIMETHYLSI PHENYLS
182
18.3
1.8
DIBENZOTHIOPHENE
184
21.2
2.1
2.0
0.1
PHENANTHRENE
178
374.0
37.4
55.2
3.7
3.1
0.045
BENZO(h)QUINOLINE
179
4.4
0.4
CARBANZOLE
167
44.§
4.5
METHYLPHENANTHRENE
192
33.8
3.4
4.3
0.3
4H-CYCL0PENTA
(def) PHENANTHRENE
190
32.0
3.2
PHENYLNAPHTHALENE
204
9.2
0.9
PYRENE-
202
153.8
15,4
31.9
2.1
1.4
0.020
FLUORANTHENE
202
146.2
14.6
30.0
2.0
0.7
0.010
BENZO(a)FLUORENE
216
26.6
2.7
5.9
0.4
METHYLPYRENES
216
46.2
4.6
10.2
0.7
BENZO(ghi)FLUORANTHENE
226
9.8
1.0
CHRYSENE
228
8.5
0.8
65.9
4.4
BENZ0(3)ANTHRAcENE
228
150.0
15.0
TERPHENYL "
230
5.4
0.5
METHYLBENZOANTHRALENES
242
29.4
2.9
10.6
0.7
BENZOTHIOPHENE
240
18.7
1.9
BEN20PYRENES
242
296.1
29.6
135.7
9.0
BENZOPERYLENES
276
109.8
11.0
2.4
0.035
DI8ENZ0ANTHRACENE
278
24.7
2.5
TOTAL POM
2188.5
218.8
j 510.6
33.9
7.6
o. no
TABLE 2.2. POM ANALYSIS
-------
The BSO fraction was passed through a dry impinger into a filter at
125°F. The filter and first impinger contents were extracted with
benzene; the extract was dried and the BSO determined gravimetrically.
The filtered gas flow proceeded through three more impingers containing
water and finally through silica gel before being measured at the meter
box. The impingers were extracted with benzene which was dried and
weighed.
The POM/BaP fraction was collected on a filter at 125°F and a solid
adsorbent resin (XAD-2) which were both extracted with methylene chloride
(MeCl). The gas then passed through a series of impingers containing
water and silica gel before being measured on the gas meter. The re-
covered water was extracted with MeCl. POM analysis was conducted on a
Gas Chromatograph/Mass Spectrometer (GC/MS) - by TRW's West Coast Ana-
lytical Department. The BaP analysis was conducted at the EPA1s Research
Triangle Park location by thin layer chromatography/f 1 uorescence. Only
runs 4, 7 and 7A were analyzed for POM/BaP. For the remaining runs the
samples were extracted and the extract retained for possible future
analysis.
An integrated bag was taken after the filter from the BSO stream.
It was analyzed on-site for benzene with a gas chromatograph. The
benzene results are missing from this report since it was determined
that the high concentrations of the volatile organic matter present in
the sample made the determination of benzene impossible. The gas chro-
matography column utilized in the field on the integrated bag sample did
not perform an adequate separation of benzene from the interfering
compounds.
5
-------
3.0 DISCUSSION OF RESULTS
Upon arrival at the plant the van was set up next to the coke
ovens. Generators were rented in order to provide power for the SASS
trains. The vent pipe was placed on an oven lid. The orifice plate
(Section 6) in the vent pipe not only caused a flow restriction but also
provided a flat surface on which tar formed a viscous layer resulting in
complete plugging of the vent in a short period of time. The orifice
plate was removed and a larger steadier flow resulted. All tests were
conducted without an orifice plate. Prior to the first run a problem
was encountered with plugging of the leak vent which seemed to be caused
by particles of coal fines. A new vent was placed on the lid and the
first test conducted. Although the leak vent did not totally plug
during the test* the flow appeared to be somewhat restricted. The
determination was made that this problem of flow restriction due to coal
fines would occur only during the first hour of testing, therefore
subsequent tests were begun one hour after oven charging. The partial
plugging of the vent is reflected in the results. The first test was of
longer duration (24 minutes) and collected less mass than the subsequent
tests at the large leak rate. The first test was considered an experiment
and three more complete tests were conducted. During the sampling the
probe nozzle was placed one half inch above the vent outlet to permit
visual monitoring of the leak. The observation of the leak assured that
plugging of the vent did not occur during the tests runs.
SASS trains were used to collect the sample. The POM/BaP train and
the BSO train used a common nozzle which was placed above the
simulated leak. After a photograph of the leak was taken, the
test was initiated. The pumping rate was adjusted so that each train
6
-------
sampled an equal amount and the entire leak was captured. The tests
were of a short duration due to the plugging of the filters on each
train. The runs were discontinued when the filters were overloaded.
The flow rates were adjusted by timing the volume and observing the
meter orifice pressure differential. This was not an accurate process;
therefore, the volumes collected were not exactly equal. The valve that
adjusted the leak was a coarse ball valve which only permitted approx-
imately the desired leak rate. The variability in the leak rate accounted
for the different sampling times.
The filter was placed on the wrong side of the supporting screen
during run 3 in the BSO train. This accounts for the large sampling
volume and mass collected. The sample volumes of run 4 disagree by a
factor of four. No apparent reason is known for this other than they
were both low volumes and this type of variance in flow rate could
easily have resulted from the flow approximating method.
Methylene chloride was to have been used as an impinger solvent,
however, during the first attempted leak check it was found to be
freezing the impingers at the tips and causing plugging. Water was
substituted and used in all the tests.
The ambient trains were operated approximately 40 feet away from
the oven lids. The ambient test runs were started before the BSO/POM
tests and were stopped after the sampling. Duration and volume sampled
were greater than the lid leak tests in an attempt to produce a measureable
sample.
Immediately following each test the samples were recovered. The
recovered samples were transported to TRW's west coast facilities where
the splitting, combining, extraction and analysis took place. MeCl was
used to rinse the sampling equipment as well as for the extraction of
the POM train filter and Resin. The complete results of the GC/MS
analysis are contained in Appendix B. Only samples 4, 7 and 7A were
analyzed for POM/BaP. The sample splits of these samples were sent to
EPA at Research Triangle Park, North Carolina. Where thin layer chromato-
graphy /spectroscopy for Benz-a-Pyrene analysis were performed. These
results are 1isted in Appendix B. For all other runs the samples were
extracted and the extract retained for possible future analysis.
7
-------
During testing, an integrated bag was collected from the BSO train
after the filter. This bag was analyzed on site for benzene utilizing
an 0V-101 column on a dual flame ionization detector gas chromatograph.
The resulting chromatogram displayed numerous peaks in the retention
time frame of benzene. These peaks made it impossible to discern which
peak was benzene or if benzene was masked by the interfering peaks.
Although different column conditions were attempted, the high concentrations
of volatile organic matter present in the sample rendered separation
impossible. No benzene results are presented here.
Multiple extractions were performed on the BSO samples (filter) to
determine the efficiency of the first and subsequent extractions. The
average of the first extractions were 98.8% of the total with the remaining
1.2% present in the second extraction. No weight gains were recorded
for the third extraction. Complete results are listed in Appendix B.
Multiple extractions with Methylene chloride were conducted on filters
and resins for several POM samples in order to determine the efficiency
of extraction. The first extraction contained 99.9% of the measurable
POMs and the second extract the remaining 0.1%. The third extractions
were below detection limits. Furthermore, cyclohexane extractions were
conducted on several samples after the MeCl extraction to determine the
efficiency of the MeCl extraction. The BaP cyclohexane extractions were
below the detection limits.
8
-------
4.0 PROCESS DESCRIPTION
Battery 1 is one of three batteries (1, 2, 3) of a coke overi oper-
ating facility located at the Clairton works. Table 1 lists design
parameters of Battery 1.
During the testing, Battery 1 was operated in a normal manner. The
average gross coking time was 18 hours. Table 2 lists the production
rates for each day of testing. Table 3 lists coal analyses (conducted
by U.S. Steel) for each day of testing.
9
-------
TABLE 1
COKE OVEN BATTERY DESCRIPTION"
1
Type
Number of ovens
Date of initial operation
Date of last pad up rebuild
Approximate oven width (average)
Approximate oven height (floor to roof)
Approximate oven length (between doors)
Free space above coal
Calculated capacity (cubic foot coal)
Charging holes
Charging hole diameter
Number of collecting mains
Type of oven doors
Type of charging
Wilputte
64
1918
1955
18.5 inches
11 feet 10 inches
37 feet 4 inches
13 inches
626
4 per oven
18 inches
2
self-sealing
gravity feed stage charging
1Information from letter of September 6, 1974 from John G. Munson,
Assistant to Vice President of U.S. Steel, to Reid Iversen, EPA.
10
-------
TABLE 2
PRODUCT INFORMATION
l
Date Ovens Charged Per Da.y Gross Coking Time (hrs)
8/1/78
81
19.0
8/2/78
83
18.5
8/3/78
73
21.0
8/4/78
83
18.5
8/5/78
82
18.7
19.1
i
Information from letter of September 18, 1978 from R.J. Weiskircher
of U.S. Steel to C.E. Riley, U.S. EPA.
11
-------
TABLE 3: COAL ANALYSIS1
Screen Size
%H„0
%Sulphur
%Ash
CTolatiles
+.500
+.250
+ .125
-.125
C
inch
inch
inch
inch
8/1/78
6.5
1.15
7.45
28.80
4.6
14.8
17.1
63.5
8/2
6.3
1.21
7.75
28.75
3.0
14.9
16.3
65.8
8/3
6.2
1.14
7.65
29.60
4.3
13.6
16.7
65.4
8/4
5.9
1.15
7.80
29.40
5.7
14.2
15.4
64.7
8/5
6.8
1.16
8.25
29.15
4.7
15.0
15.3
65.0
information from letter of September 18, 1978 from R.J. Weiskircher of U.S. Steel to C.E. Riley,
U.S. EPA.
-------
5.0 LOCATION OF SAMPLING POINTS
All sampling points were located on the topside of the number one
coke oven battery at the Clairton Works. The oven charging port closest
to the push side was chosen for sampling. One end of the oven battery
was chosen because it would least disturb the normal operation of the
charging trolley. All samples were taken from ovens Aj through A^,
depending upon the daily charging sequence. The ambient samples were
taken from topside at a location past the pinion wall. Figure 5.1 is a
schematic of the battery topside indicating the sampling locations.
13
-------
•SAMPLE POINT
O
o
o
o
PUSHING
SIDE
O
o
o
EXHAUST FUME
COLLECTOR
AfiO
«4 0
A3 (ft
A2(£
A,®
1
OVERHEAD TROLLEY
O
o
o
o
G
O
o
o
o
o
G
O
G
G
3
ROOF HEIGHT-30' ABOVE GROUND LEVEL
PINION WALL
AMBIENT SAMPLE •
SAMPLE TRAIN
PREPARATION AREA
G
O
O
G
("")
V_-r'
G
o
4
C2qG
o
o
o
COKING SIDE
40'
FIGURE 5.1 : BATTERY 1 (TOPSIDE VIEW)
1A
-------
6.0 TEST PROCEDURES
During the testing, the oven was charged with the overhead trolley
and the lids replaced and sealed by U.S. Steel personnel; a special lid
modified with a valve and vent pipe was replaced on one of the oven
ports (see Figure 6.1). After the lids had been sealed, a simulated
leak was attempted at the desired plume length. Condensation occurred
in the vent forming a viscous substance; consequently, the plume was
monitored continuously to assure clogging of the vent did not occur.
Once the plume was determined to be the correct size, the nozzle was
placed over the vent and the sampling trains were started. During
sampling, the vent was visually monitored continuously to assure that
the sampling rate was sufficient to assure total capture of the leak.
Sampling was continued until plugging in the vent occurred or until the
loading on the sample train filter caused an excessive decrease in the
sampling rate. The sampling rates of the BSO and POM sampling systems
were evenly maintained in order to evenly split the sample between the
two trains.
The sampling was conducted in accordance with the draft methods--
Determination of Benz-a-Pyrene Emissions from Stationary Sources and
Determination of Benzene Soluble Organics. Both of these methods were
supplied by EPA and both are draft procedures. Several exceptions to
the procedures of these Methods were made. SASS sampling trains were
substituted for the regular Method 5 trains and the two sampling trains
shared a common nozzle (see Figure 6.2). The ambient air sampling
system was a Method 5 train modified to accept the XAD-2 adsorbing
module; no nozzle was used for this train. Methylene chloride was not
used in the impingers because of a problem in freezing due to the heat
loss inherent in volatile organic compounds. This was determined during
the first run. Subsequent impinger fractions used water as a collection
15
-------
medium. Methylene chloride was used for cleanup and extraction of the
POM train in lieu of cyclohexane.
The basic sample train components are diagrammed in Figure 6.3.
All the components used were standard source assessment sampling system
(SASS) parts. A simulated leak was created by the pressure in the oven
flowing through the valve to the atmosphere. After visually measuring
the leak a nozzle common to both trains was positioned over the leak.
The nozzle was not connected but just positioned over the leak. The
train's pumps were adjusted to provide approximately half the leak to
each sample train. Some excess air was also sampled to insure all of
the vent gases were captured. The probe and heated oven were maintained
at 125°F for the BaP/POM train while only the probe was heated to 100°F
for the BSO train. The BaP/POM train filtered the sample to remove the
particulate matter. The non-particulate gases were then collected by
passing the gas sample through an XAD-2 absorbent resin maintained at
70-90°F. Cooled impingers and silica gel were used to collect the
remaining moisture prior to the pumps and the gas flow meters. The
BSO train collected the particulate in the first impinger and on the
filter. A dry impinger was placed prior to the filter in order to
minimize plugging. During the sampling, an integrated Tedlar bag was
taken after the impingers but before the silica gel on the BaP/POM
train. A sample identification log is contained in Appendix C. This
log lists each sample fraction and the solvent used in clean up and
recovery. They are generally shown in the following table. The GC/MS
analysis was performed according to the procedures outlined in Analysis
of Polynuclear Aromatic Hydrocarbons from Coke Oven Effluents by R. E.
Beimar, September, 1978 (EPA report 78-CK0-12). The Column utilized was
a Dexel 300 packed column for the separation of POMS!
16
-------
j ! S i \
common nozzle
l/2"Stain1ess Steel Tube
(Insulated)
1" Nipple Threaded
Into Oven Port
A
1" Stainless Steel Ball Valve
Figure 6.1 Sampling Vent/Probe Configuration
-------
Probe
Filter
Modified
Batelle Trap
Adsorbent
Sampler
XAD-2
lingers
¦N i
Pump Thermostated
1WF"
(HoO)
Inclined Manometer
laQ
Pump
Iry Gas Meter
FIGURE 6.2 AMBIENT TRAIN
-------
BSO TRAIN
To
Common Probe
Nozzle ^
(Knock Out
Impinger
^>To Integrated Sampling Bag
Blank silip.
Inningers
Pumps
and
Control
Module
U3
To
Common
Nozzle
Probe
T
U
: Filter
XAD-2
Adsorbent
Module
POM/BaP Train
Inpi oners
Figure 6-3. SASS SAMPLING TRAINS
-------
Field Recovery of BSO Train
Component
Probe, Knock-out Impinger, Filter Housing
Filter
X
Impingers
Recovery Steps
Condensate collected
Acetone Rinse
Benzene Rinse
Collected
Condensate collected
Acetone Rinse
Benzene Rinse
Component
Vent Pipe
Common Nozzle
Field Recovery of BSQ/BaP Trains
(Common Components)
Recovery Steps
Methylene Chloride Rinse
Benzene Rinse
Methylene Chloride Rinse
Benzene Rinse
Field Recovery of BaP Train
Component
Probe, Front of Filter Holder
Filter
XAD-2 Resin
Back of Filter Holder and Module
1
Impingers
Recovery Steps
Methylene Chloride Rinse
Collected
Collected
Condensate Collected
Methylene Chloride Rinse
Condensate Collected
Acetone Rinse
Methylene Chloride Rinse
1
Some Impingers contained activated charcoal which was not recovered
after each test. The same is true of the silica gel.
20
-------
Laboratory Sample Preparation
(BaP/BSO Common Fractions)
1. Nozzle - Methylene Chloride Rinse - Split1
Benzene Rinse - Split1
2. Vent - Methylene Chloride Rinse split (A B C)
Benzene Rinse
Laboratory Sample Preparation
(BSO Fractions) ~
3
1. Nozzle Benzene Rinse , Probe, and
Knock-out Impinger Benzene Rinse Combine(j and Spm4 (D>E)
and Nozzle Methylene Chrloride Fraction
2. Probe Knock-out Impinger Acetone Rinse - Split (D,E)
3. Filter Benzene Extraction and Split (D,E)
4. Impinger Liquid - Split (D,E)
5. Impinger Acetone Rinse - Split (D,E)
6. Impinger Benzene Rinse - Split (D,E)
7. Knock-out Impinger Condensate - None in most cases
*The rinses split in a ratio to correspond to the sampled gas volumes of
the BaP/BSO trains for each test.
2
Nozzle fraction (Methylene Chloride) after being brought to dryness
and re-extracted with Benzene.
3Nozz1e fraction derived from the BaP/BSO common fractions.
4The samples were split in half. The "D" fractions were dried and
weighted gravimetrically by TRW. The "E" fractions were sent to EPA
and from EPA to U. S. Steel.
21
-------
laboratory Sample Preparation (continued)
(BaP/POM Sample Fractions)
5
*1. Nozzle - Methylene Chloride Rinse g
Combined and Split (A,B,C)
Probe Front of Filter Holder Methylene Chloride Rinse
*2. Filter - First Methylene Chloride Extraction and Split (A,B,C)
- Second Methylene Chloride Extraction and Split (A,B,C)
- Third Cyclohexane Extraction and Split (A,B,C)
*3. XAD-2 Resin - First Methylene Chloride Extraction and Split (A,B,C)
- Second Methylene Chloride Extraction and Split (A,B,C)
- Third Cyclohexane Chloride Extraction and Split
' (A.BjC)
*4. Module Condensate - Cyclohexane Extraction and Split (A,B,C)
*5. Module Back of Filter Holder - Methylene Chloride Rinse and Split
(A,B,C)
6. Impinger Liquid Cyclohexane Extraction and Split (A,B,C)
7. Impinger Rinse Acetone Rinse Combined and Split (A,B,C)
Methylene Chloride Rinse
5
From BaP/BSO common fractions.
£?
"A" which was half of the volume was aliquoted and GC/MS'd by TRW
(see note *.)
"B" which was a quarter of the volume was sent to EPA.
"C" which was a quarter of the volume was retained.
~Equal aliquots from the "A" fractions of the split for each section of
the sampling train were combined, except the samples derived from the
impingers, to provide a solution for GC/MS analysis. GC/MS was used
for runs BaP4, BaP7, and BaP 7A, the results are reported. Samples
from the other runs were kept but not analyzed.
22
-------
APPENDIX A
COMPLETE RESULTS AND SAMPLE CALCULATIONS
-------
1. (ex.)
Where: 45.4 »g
ml
Sample Calculations
Polyclclic Organic Material (Table 2,2)
Total Weight (mg of Dibenzofuran, Run 4
=71.8 mg
45.4 uQ X 1582 ml X
ml 1000 yg
m.
1582 ml
2. (ex.)
Where: 71.8 mg
10 min,
3. (ex.)
Where: 1383.4uq
ml
1582 ml
10 miri.
4. (ex.)
Where 35.83 mg
10 min
5. (ex.)
Where: 1.618 g
= GC/MS Analysis of Composite Sample Fraction of
BAP-4 from Smith Report
= Total Sample Volume of BAP-4
Emission Rate (mg/min.) of Dibenzofuran, Run 4
71.8 mg = 7.18 mg/min.
10 min,
= Total Weight of Dibenzofuran
= Total Run Time
Summary of Results (Table 2.1)
POM Emission Rate (mg/min), Run 4
¦ 1383.4 uq X 1582 ml = 218.85 mg/min
ml 10 min.
= Total weight of constituents in BAP-4 Run (see
Table 4.1: GC/MS Analysis - Smith Report)
= Total Sample Volume of BAP-4 Run
= Total Run Time of BAP-4
BAP Emission Rate (mg/min.), Run 4
= 35.83 mg = 3.58 mg/min.
10 min.
= Total mass of fractions from BAP-4 Run (see Clairton
Coke Oven Samples Benz-a-Pyrene Analysis - Rogers
Report)
= Total Run Time of BAP-4
BS0 Emission Rate (mg/min.) of Run 4
= 1*618 g X 1000 mg = 202.25 mg/min.
8 min. g
= Total Mass of BS0-4 fractions from Gravimetric
Analysis in Smith's Report:
-------
i I K.
Sample Calculation (continued)
Fraction Mass (Grams)
BS0-4-PF (First Filter Extraction) 0.8687
BS0-4-PF (Second Filter Extraction) 0.0108
BS0-4-CICD Impinger Condensate 0.0117
BS0-4-CIA Impinger Acetone Rinse 0.0059
BS0-4-PIA Probe Acetone Rinse 0.7151
BS0-4-CIB Impinger Benzene Rinse 0.0011
BS0-4-PIB Probe Benzene Rinse 0.0047
Total BS0-4 Mass
8 min. = Total run time of BSO-4
1.618 Grams
-------
wob SHEkt
A//
/m
«/•/. /wr/
se^
v
Mp-i
7/- 73/
Z?,?Z
.36
loi
fpfoJ'f
13 AP- "L
5.oy/
"2?. 3Z
* /o
to (t>
1.6Z
T
23.^5
Zf.ZZ.
• to
*7
ZZ.Vl
/ 5^-7/
19, 2L
» "2_
9Y
JV. "O
RAP^S
3®.£S5"
2?, Jo
.15
sr
29.07
3»?-6
32 ,2/
29. Jo
. 37
? r
3/.o?
BfiP-1
tl.Hl
7^.3*
• 3
5' ®
BSo -/
AV.H
1%32.
.7
/off
5s.?y
BSo -
¥.53
^9."52.
.Z
to*J
V./7
8je>-3
3%9r
%CJ
37.75
B5c> - y
5.6>C>
29,1*-
. X.
??
S.1V
B56-S
zy.
7/7-
. 1
*y
23.73
BSo-C
2.6 • £ o
-Z-9.*o
. 3
7^
i$.?7
BS o-l
zz./r
29.3o
.3
i?
BSO-$ fig
mi* hi
2-t.3o
l>°
S?
*«.«?
Rso - ift
*
p
h a
136.5?
35-^0/
t.o
S3
33?./?
Bfip ~in
19, ?t>
he>
13
7-VLcL
Fofrnu.icK
/7-?/
y, l/rtf
( Pfa*
j4if>
¦# /
V 7Vn
f
J - (//
f 5' -
-------
TECHNICAL DIRECTIVE
PREPARATION OF BAP/POM AND BSO SAMPLES
CLAIRTON COKE WORKS
The attached schedule outlines the specific details of how each
sample collected at the Clairton Coke Works is to be prepared and split
for analysis. The schedule is detailed as follows:
I. Splitting nozzle/vent samples.
II. Combining nozzle/probe rinse samples for BAP.
III. BAP sample preparation and splitting.
IV. Combining BAP sample fractions.
V. Re-extraction of filter and resin with cyclohexane.
VI. Combining BSO probe/nozzle samples.
VII. Splitting BSO sample fractions.
VIII. List of samples to be sent to EPA for TLC analysis.
IX. List of samples to be sent to EPA for transmittal to U.S. Steel
Corp.
X. List of samples for GC/MS analysis.
XI. List of samples for BSO analysis.
XII. List of samples to be retained for possible analysis at a future
date.
NOTES:
Prior to conducting this work, blank run analysis were conducted on MeCL,
cyclohexane and benzene to assure contamination was not present.
1. Assure that splitting of the samples is done accurately to the
indicated fractions since split samples will be recombined before analysis
is conducted.
2. Assure that samples are homogeneous prior to splitting. Use
ultrasonic agitation if necessary.
-------
3. Prepare POM/BAP samples according to procedures outlined in
the draft test method for BAP except that methylene chloride shall be
used instead of cyclohexane (filter and solid resin extraction).
4. Prepare and analyze BSO samples according to procedures
outlined in the draft test method for benzene soluble organics.
5. Extract filter and resin according to procedures established
in the BAP method, paragraph 4.3, except that methylene chloride, in
lieu of cyclohexane, is to be used. Split the methylene chloride
extract; retain the filter and solid resin for re-extraction with
cyclohexane according to the procedures of paragraph 4.3 of the BAP
method.
6. Extract the condensate according to the extraction procedures
of paragraph 4.3.3. of the BSO test method substituting cyclohexane
for benzene. (Do not filter or bring to dryness).
7. Evaporate the sample to dryness and then redissolve the sample
residue^enzene. Combine this benzene solution as indicated.
-------
©
^ p 1 '-"Y ^ ? I'r I sfjz|AJT S
C P £
s •**-->
•r?;M
fif*3
wy^
'it
k *i+«HrC
•He C
^Jc.2
Ie
1 f N-"5
<>
A^l; '-v\
jO I *1.
6tP/<¥,c
B/vyss
£>(•¦? jn$ o
i a^/ds
%.
t { *l / C i
/>
$ /^'A
J-5 /vW :
¦:? -A-'iB.
o -r-/tvi
0-£-A&
o - 7-*>6
\*-)tv sA
b!A>/<
/-,/hpi £
(\*
e
<*> - /-//«<
V -w\'
3
h ~f^/vf.;c
kr-^/'i c
C F S»v
;« f=
PrePsv2Ar7'6rJ
h/
>/«. /* *¦/>'
' *Wt£.
G/\
/J a
*S5o - / -.^<3
a
fcv)
.2-
ai"c> - 2
<6"^- i*
&£& -
A/i?
/vS
^Aj/O - f/- AS{Z (
&S&- (f
3#/*-s
£ ££>• S'
&So~G ¦
SAP - rJ\
/2 so -r;-
SAP- /.
ezo-i
BAP- S?~
ISo -3 -
'}*/>' 3 •
QZO-- 3-
,3/? A»- '/ -
/jso-y~,
/?*p-£-
4so-S~-
*1 >~< A »r>i
/ /s*#' /#>»
-/r.
JT'
^ ,1
(j )
lf,4^ >
/V. / . , \
U / '• y
I
¦ff*
'A/'i L[ fi/'T>%)
~J ~/Ui3 ;! A/; -r /¦: ^
V^i)
-<"<3
*/v/2
/v/g
-a"3. (
A''i
/urn c.
0*0 i
V' 1 ": ;
i-'V'
r
y>
//¦-/' ,
£ /,!- A
/ /' If- J
y.ft > "i
A/mC (/i/'^^)
vm c ('\/*
/I'I C-
umc
d//II £
sum c
tJf.-iC
sV/i ( c_
s^ n t £
/)/As fr~-
x A A !
;V1 f (•
ji/ffss)
'> /* /I •* /.' \
i ' ^ ^
^ ///•/ />•")
$ £S ^
-_)
U
-------
J
J i/c/oT
&
(tOrSl. -2^
Cjvh
£ ikl
M£
AM
:l-t,
?.(«v
V^-^/Lnv^C.
/V
A^UIUf
flKOfilL
&(*/•>&
-G -^t
• 9 -/vrnc1
&M»/a
kfrpjfh&b
0>fiP/Q&
>o -3-VE
^ -re
o-3-Vwc.
o -O'T,
P<-
< i> at-
A.
L 4^*51—
,4lhrt£fc-'
t4>r--nL
tY f~) /m~c^
mo-a
-Asm c.
SSo - Cr '
/urh c
Qrifi - V
vvm c_
AP-
BQP -
/> So -
£-./V'a-
W-
aso-
- \rg -
B.- \r&
v-
(v^:A
( "
])
/<¦*<%
S-&
y~a
K (/-
(%
C 'ti
(^
/
3- ma-fi lf-u
r~r* c j-G> jju) '
3 - |TA l £ ^ /d <
/" An CJ-e C'(f )
7 —V/MC * f •• '
)
^1
i
I
-------
C& hA^> (/a Jtr /Ma--? y It. pr o.(«, [i
S»*Vv A
y~ <**i\ <¦
t-E
tl. e> C
1 S'
/,
Jn />>^v jM fe *
«%f"» 0 -2. -
GaP-2
&ap-2
ftAf>-3
A^UC
- Ae
A/^V\ O
f>fl
~N iv\ C
ii^.r->~H
?J i'A i
p/2.
a i^ - X1
- /JtV\£^
fl'V - 4T- p/l
th>k-fi — (p
corA c
J.-K»M
a ftp-.2 -/V/V2
6ap
3-AJp/l
P> A- A "
& *P'
A'1
ii ^
-------
&
/?) A » 5l°rw\P l£-
>
SiVye^ £.
r f p iV^fr-n 6 »-> Pi <-
5 C
j i
¦ 1 />;«*'< ft
2j_ $ »&* jn
&A#-/-A!PIL
/11C
" I '~^C * ' ^
f 3 r*~*,^fc Jj / Jil{-
/V© * * ( 5.
I r* V %.** -< T *
* ^ ftdifAAi /?
/~v*p«
6 'V'-Vsi//?/*
&/)£- ,2- /t/Wl
$40- -
F'fy-tr
/JwyLij.
j wrn
£--A>f$~
fia-m
A r/t
A
t\f\ s
/>r
I
V
,TC
IVjC^'S.c.e-^
\| p I O Aa V
! 0 'i-
'm - I
A'N-f
\!
^4/° - t^Pd- A , | (^jh ^
&9P-3~-ajP£-£ |(/v)
aAP-±-fiJPQrC | (//)
(/-u)
£/*/>*%-C /r ).
£/)*>-3
$AP~ 3
-A/P/2-S
AJPit- S3
&S/>- V- a^4-/?
&/}P-V4jftl- S
CM
CM)
( '/-*-)
v/y)
c&)
i ?Y)
CM
AQ-f/Z-A ('/-)
(>/y)
\*a~m~k C'/vJ
n/ip-6>-sjP/? -A
' & *&? -/2
&/} P-ir-fSfiil-Q.
K
i ;
CM
(¦/y)
-------
S i 1 PfchC^i A
Slt**N^W AiakL<^.
L.
i
s)
ft
(*
i
/s*. *VA
A * /•
Sfl^rk
T
fi*%t1
• #Ki.
'/f/A
H '")$ C/^T r*~-j
Fv tk>^
r,/ik
a£»
p, //,
FJ
)n^v
a&p- i-A/p/i
/3$P->yA~M
-J- - P?
6M-
¦Z-PfiZ
/z$p-£y
$np- y-
s
14***-%
+i^.
£y-fn* cT ua i
6M jf},£-r fc-
/kt fV\.e TT+®.cl
V^pr.^(Vi^vys^/s (-/, "Jj'
(S-eC /wHV *£T"
D
/3&A
&A0- 0-
&/9P- i
y-
M-A
P/2-C
^/3P~ 9-/>/2 - /I
Vy
00
J~
SfiP
£/9P'^
/$#P"£-
•w~ A
-s3/^- &
P/Z" c.
(H-i
ow
-------
\ * f
*31/ *>/» /3>AA (c/w£ r^)
&
frW.pl
fnAt-h
6?
AJomW
Pr* |>
• AAKVit^
a
Pl //v
W-a
$£-£c-
MP-a
pp
f*/"
/*>#/>- m~P/~
-
>*/£
\jVV«.%
|ftc-v o->
d
Vl
a -r.
£Ap-£
bpp
Bltf" -Sf
m-pr-ih (X)
^ 0^'
jW
6-
S/9P-6-
BPP-6,
BSP-9-
&PP-O
&fiP-rh
\/2*Pp-
f}&^/>/=~
M-/1
pP~ &
PP~C
pp
/SAP-
Ev "tff to »"L
£"1 <_ I
-^^Lrty 'J.y ty;.a e-T —
f(l<.r* ^ H-cst *-
V A+H*«w_ -ey-^A-of
ScP~
60P-
'/ZAP
f / I
v /r|
C&)
m- i
O1
pp~/i C'A)
/v-£
c
p , t \
I ^)
2 - X/? - /?
(//)
(/y
?~yvz
<9
*
-------
(y
<^L
"jM>-i (U$..
gM
mv*
B&P-&
nflp~£?m-7c/i
ry/L '
ki\P-0fi
fcAP-i
8$p~Z
2
A
fAr^frry.
ZjtL
-"iJL
Cb
CO
-C.L3
<£>c4rftcf
c*- $.^1
( f* Si-
vy <*{ lw M-it.
t f
u4m-
v-yz-fr
ti&P
£S)P~ { fr j
MP'^/>&- ><>?-
£--
~v
s*j€>
-WL-A
- X>2. -C-
¦ e/o
OH
W)
t'/4
C'/f)
Of
;
-x«.-A- C'M
•xt-e ('//I
cl
«
V
l-C0-j\ C^i
'-«-!« W-J
I - CD-
> ^."O
o S ' i~
-------
L>
'c
file*C*jw£l
Mob{{((
M«,C
Ft»v4~>
\/nJs *
"*V .
sap-
&f\&
6 a/*
6#P-£*
/0*>
y-ca
S--C6
Jfm-c#
Ai-CC>
•Cd
-C£>
4 hP-OA
Q>f\P- t-Htt
Z-
Mftfi- 1
&f}p~ it-M/L
£frP~&
5
tfl/l
Mfl
¦ frtfl
"<43 -ftf/l
Pr
/}CA-C>e*
\Ja I tfr
^ ~ > 4t> rva
y«
V&w"
J
* B ft-?'
V
M>Kl ^cP He/-jy.6-c0
d
i»-»i
k
/
Cc<" 4' -' ''
Ajc
A/o
fOO
£#P
Sft-P-
&/)£>\
mp- z
$$P~?L
/Z/\P-v
3
4fiP - J
6PP- *
p- '/
g'tf-r^js r^_
€.4 «\£ £ J ¦/"?)«- ^ I
<•11 ifk ijr! ^--Tftfi- f%h A'.
I
*— !
f s_|
i-nM-/} { '/-
i
/ & (/yj
/- l'*t/Z-
¦p?/Z ~/9
-/wZ - /g
c C '/c)
CO
(•A)
'>t'i - c ; (^V)
(/-.)
-ntfi'fi
-A
-AM-C
- Afctf- /?
- / t'/v~~ £
tW-C
£- wl - /¦} (J/t)
£/9/>-s\- att
%4P-s-
&fP-s
Titt- c
Bfip^s-f
>2-Afft "O
JY)
(y^
L- r i
-------
&
p/P»«-"fl
MeXu—Ll
5P«v^*'
^•e C L-
Jfc
?eA
IL-a4C
CjA^^uJ
ft t*J£
~ Lf M/X. M-o^ur^ Ud(u>~-4-
*)
-Mrt-
oaA-i»C
B*#- ^cjfO
(W-
-Mil
| (cyi'"t <'<
i \e' j i- / » f
jdit'i!. -j
s^f rt
S7-c/c^
7- C11A(_
OAP'S^'Cf
5** *
< A"»w<
A a,
0A£-
J A# -
A A/-6
tlh&~r
B,P^- *>'
#VA- «>-
- >M £ - !y C'/z-j)
'/M/2 - 4 f/y ]
A*Afl- ./ AJ 4
r '* *
4
«v«- 4 ^)
f\KL
fV\-f A*
y«(u
A '
o
V"i ( o
^rs.
ir-
"f£>r
ua
£firP\
&*fi-
MA-A
aA/I- c
'trK /c (J
\*7-C(C0
7-Ctco
-S~'y* -f
we-
6^'
,j .
6/9^
& * £
/2 ftp ¦
(¦3')'%
t2&P
sj/j ¦ r
7 )
• Jy j
is f,/f
¦b { f y
*1~NC- tvk'/i '
ttit - C (V
I \>'ffj
fiitc - r- \[:
(Me - /!' ('a
' Wc
4 c/
Y
-------
fcg) CrmLlV,-,
5=
Sw^nl £
Ftfic-tt
•»*>S
rrt
p**r
Snwv^Lg
G> p\P — 3.
GAP-i-
A/fl- ft
-
&AP-.!¦.*£- ft
Bap - j. t w/l-A
fefi?- i
-2_-
art P - 3-
P*fip>-ZL
&/yP - z
ft. ft A -3-
&AP-3-
fb*rP-!>
6^-3
apyp- tf-
5AP~H-
h*p~ «/-
QfrP'H-
¦Cjj~f\
AJPt'fK
Pf-h
- *
-------
J
I A? | X/^
^ ^ p> Cp Anrv\p / S . "2 ^)
£ C VS -+<*4^ 5
U
F r Pr^tTlfcAJS
5-y-i'h
6 frP- STt
kfiP-S*
ma-fit
(hf*P - -T«&- PtZ-ft
iff
PF-fi
frtf t>rf^hor^
6-yfi-/v
feA-P-6
£rv#- g,
Q,Pr?-~ 6 -
GAP- *7-
¦>
A Af>- *> ¦
(4 r** -fjA
SAP'^:
£*f-
0ftP -/)/
- y>^/v
HPiL-k
pF-ft
lift - A
A
-fr-A
¥"*' v-*^ 45
j9aa
:• U
tr~%. ft
sA&^ft
| i
Gftrf* A; |
£>#v^""
-------
E.*niAc-i
fr, fIcsj'-i C^cl. Uju^i-
dP
(U£
tYfl* *1
P i |
f> l*_
^ Pr P 4
tW -
0 ifrP ¦
0 A P -
0AP -
8- »•> <*'
»3 rt.* -
{>#'» £ •
^»VP-
it- fp
%»
3 « P.F
I/-
.r- f3/-"-
6- - /> r-
>- Pf
fJVi-ft'
ft A
fcAf> -*31
r-; AP -
5a-/5-
fhft P~5' - -%fl
O) (\ P " it - ~/ifL
i% ft P~ ^jA ~ f &
- TH
¦ %(L
r^ft
PA^.
\ -CY.iy7M.if
f*U tl^
'iTt r\ c -i ,
{& )vc-7(A
tV.
/^sr\ ¦
rihfi- A-fP -dlf
{ f\
< FmJ
a)
ft C y-
IV, eC
- 0 brPF -T//
^ N
.» i
ll A C T
|
¦f//l -C
0-Y/2-C.
/3& &' s~&Q-)/L/2-
3/*>P -
g
w
•//
//
//
!T/t/
-------
ow L i fj
Co**'"*^ ' ¦*'*'*/
J7fr'-'/ ij/fc—
T
$Pr~Y
Leflkv-nj &"2ttAl
LCe,fr «/i*4 M-fC.IL
V ^
rvj? V-r
Fhfrt-h
&¦>
5 &-r*if>{
C L
6So-
C.SO -
QjSo-
aso-
3-V&
3- ymc
»7r \TB
fj-rmc
fWc L
P^ ^»V yfc />) /> -C-*.
P^W J3;
L.o«-» » V*~o.-V»r;J
aso- /
Q>SO-;
&SO-
&S0
S56
GSO-
aso
6so -
$50 -
6so
I
:L
/Sso
<5So
^Sc>
fiSo-
65o
H Ak
f)r/.
; *W* 7
Gr«o^jo<;
• , !'
V
-AJCL
/- /vMc
fr'3>
/UHA C
-S»rw-<
/*
^/¦V £f
. /0d1
¦f>2» A tm
o-rp ^*7
^rE |«0
\ -&rj
/Uut/: >' I*/
/V u~"
0> So - / - P
/2SC
<3jTO -3
/S51
•^-z3
0 — //— /0
/3^- -/=
-------
^Uvv^-WvO. ^»SE> A^JtCbt S T>~\p ^S
(C^t.-O r
S F/^i?'Vi
5/^/!
AJo w\
fir
r t pr^MTi^
&S0
/3.So
ffi&'Aig
\&—A/tfiC
sJO "f'i.
£>$>*>
13>5ȣ>~~ C
&so- &
(*> S©-
&S& - <}
B?£> — */
BSo " r/
£»So- ^
ioa
AJWC
#•113,
7-/J&
7 - WMt
— t^/js2.
A-/&
<>TTE
l7
^it\.
^SV?d-yA
A so
£sa- 9-^
-------
Ttr-fritji
STO
r¦*•> 6—'
1-vWtl^
/?e-m t<*~
Wt-fwt
" £-C I-P
V*5> .
ft.
nJe^T ftUs««,
~frh
J),
£ry-*4~
a~fU~
S -fe* {
¦+» /iV
ia Tli
7'
V- ^>S
SfKyvp^. i
'"tW.. !
~"Cyi5
6~f -C*'-^" £
C-^v-—¦>—J
£/Vl
!tU
X-c?
/,
fC —
r
4-^
C^""l C ° O*
-e
feSo- '
asd- ^
fc.
«¦' «
£a<*ik i Attti*
.P < t
*fo
t-w-i-e
-\j—
vC
4 ~«p
yf-#/? /IS s»
¦ A/*iff *"i
OA x !
S lri/> j>
y^M. y$-s''
i<
,^r/ /c
Pfj>L<*. ^ A'rtt ^
P<-C f fill P,^tl6/~> '.
A>S£~
SSc '
6>So -
-
/2>So
& So
/3>Sc>
/3> So
£So~ J/l-/^
iy^
& SO"
n>so -
&S6 -
Kso ¦
/3so ¦
&S& ¦"
BSo -
££",
KMjil
¦ "hr
"t.
¦z.-/6
3-P
*/-/>
S~ -/>
¦ jT/5^'
^-Z5
C--T fls
f
fP
Pf
f F
PF~
Sr*8-f*^
%
'Z-
3
y
r
A,
**«. (0
r <>•
>e /^W
^ " W
£$<>-
/3So ¦
ruj)
r> £ /X
S/£)/'
• £f-Tj» rJ
ry~P/=
9/1
f
iTx ^
f
f'f
-------
Pro k-t
*
£J X
£rlr-
ivyyjp**
JVt"N
> j>Tf>r-frnt>~.± ; A^'
2 ^
Vrt
-PiB
£t*
fm
¦>o - ' < / //A
G?So - i—Pi ft
&So- X
eso- 2|.
BSo ' 3
6 so
SO
a
- /v/*
fiih
oSb- £ S)/Z~ P/A,
i}£C - 7/* - PJ fit
^ TA i/p ^ /
3- m^>
I A.
3-
1-
BSo-f)A
Ac
n»so
BSD -
-•^C-a 77^
— 3"
"? ¦
* • .< o - OA
X «v «3i
11
&
(2,
&
I sr
-^yOt,,
SJ
IT-
is,
C\
c
c
«;*»SATll
i-fm-e.
CD
Cfl
C£
Ac-i
s
Cr tft
C '/A
-cm
G/
j> A-T"/•« Ai ',
1>c»~ 3- e- i £
sc>- n-c t&
So — ^ "C /^
f w\ joi — e
i>*r^
ISO
&5>0
rbSO" £fr&~ ChZA)C
yV
¦>
OA-
C£
-to
u4-o^^
~i'fy~-L /?
4vT*
<-U-Tl
Xlbr>~t>
I
tur~*
-------
Se/°T +t> Efii\ ¦£»'* • TL-C (&fVA^
V • . i / " ' •
BfitP- A-
BPP~ i-
BfiP - £
£$P~ A
/3> ftp - £-
ASPJL-&
Pr-B
m-B
wi-£
jvPfl- Q
e#p> -p. ¦ Pp -&
GfiP-g. -
Gap-P-
GfiP-Z-
%€- &
/»/l~/2
A/fiA - £
GfiP-3-Pp - &
$rfP~3- X
£»P-3-
a#p~ ¥
ft - &
WP&-&
&PP-V- Pf-&
G/)P-'/- ~/P-£
BPP'Y ,yj/2.~&
%fiP'Jr-/*p/l~g
/ZfiP-S'-p/*
S/fP-s-
£PP~S
GAP-&
G»p-6
e#p- &
m-s
/m -&
tVPP~£
-PF~g
Y* -S
BPP-C*
e*&p- 0
/Spp-O-
m^-'L2
¦a!P(1 ~£
P/*-&
-------
4-fc JL* C*
. "z.^
e*/°- 9
a ftp- i-
bftf ~jr/j,
O firms'ft
/3#*-Jr/i
aw'jrfit,
a&p-in
&lV»-/>£-
Gap* OA
ftrfP- 3-
S/?P-S
£*?P~ 7
W'*l~
£/4J*' ?/
/}/}/*-9/
/3/9P-3
QfirP — tJ
AAP- i
0AP-5f,
fi*P- j*>
J
/»1/2 -&
6 -Pr-L\
B - y4'-
As©/<2
fra-1
-P- X£
if*} wm
-------
*>0AJT 4"Z> ^ -blKiJi. t* 4% U»C . ^ "t« t ( (j%
^ f\y^p L/t_ A^»> ov^tx^v.
""~f »V- *
—^- ;—r
/r- rr^h.'^
a^- i--A/^-c
6/VP-JL-/V -O
&&P- j_
y£- c-
B ap- 4-m£-c.
SAP- OrpF-C-
-*2
Bap -z
B^p-3-
&A#- 3-
&PrP-2-
O.AP-3
BAP- 4-
G/s^- M -
P~ tf-
fi^P- '/-
&/w> ~i»
5 Af'5
- -/e-c
M/L-C
/Jf/l-C
PF-C.
¦>?£. - C
- AA/l-C
NP£~ C
pf- c
i^a- c-
A1/2.-C-
- /W>,2-c
- P#=-C
%j2~C.
- £»
feiM* -G —
&**»-&-
6
&Ap- ^ -
VPfL-C~
iV-C.
*X£~C
- rAfl-c,
rJP/l~C
PF - O
- Co«v\,lJ .*»~ ^ /«*
tf- .j1* 4 - Fi l-K -ey.-r^.
.d - I? T i ,>- C-/1
I? u«* ^ ,L — ^4^1 r- A^O
ft
w f-J 1
I?
' "?L
*? a- **
FuaJ ^
n ww ^
feu-**- r
Cr*-c"^
/"Av
*-cTT
.1MT"
6 <^«S ^ S
A k«
-------
SH~fks W ^ U O.z
Si'i« (cr-A-Z.)
^ »>«» f
L A!o« t~.
$/*>-*¦> ^
¦"T- /"S^
—
a* p -/
B.KP- £
6flf - J
Sftp-X
ftAj>-
G*f - *1i
£aP - 0
J
6/)^- a
i>.'\->~ £
Afip' 3
Afp-Z 9/
/i;V- :
GAP-3
t^-C
- fA(l-t
rA&-f£
'p>&~ Pf
ifi&'Wt
J\5. - Mj2
V - #/L - £.
V - Pf-£
V -
% • W- c
- cD-C
•7* eict
>/j- em
y- c / /<> c
•€//>?£
-vT/v\ c
•
C
-c
- c
- c.
*
#
- c
<>- c
~c
t>
-a
Ry^ 41 -
f? i/*J ¦
s"/*& Jf
ir/- PWv
¦i v*^' Siw>*
I4!—
'V
/
-------
f
5 lt£
F^ttl
*> A»
1
-
I
kfirfi ' 1
fcWP - 3
&\Yf> - 3
&tP - ~C
G&P-&
0-
&&P- t
fethft- £
£/]f- S
BMP
'<%
•fi>PrP—o
G>ftP~0
as & jm
(I*? j f
45^*
t-A
l-yft
i-A n
>
, - A \
.-*& /
-A ^
-A v
r~ )cfi /
— "je3 n
s — ti
*
~XA
'A '
*¦* X<*9
~Jo *~
"/?«£ -N1
A.*- /)
-1
p— IXC
-pa - *
-1 ~*/-/i.
\ ©
)> ©
> ©
> &
> &
y&.
y&
>
-(£?>
(ID
X -A (
V (
yv ^
*
X-
Js?
•ncv,
Tj>
VT)
s>
* w<
M ^
-f-o
fvJ fvp
K
JL
»s«j^ Vs
As of *i c.
Wvti J V
-}x-> C
¦*3 C_e
C *""\
p c s. 1 r
!u s*~c C>
\jEtf u 'A>
-------
^ Prwp \
** \-tr
& )\ ^
f U
/OvJi^toL /*
^ l*rr-v>p !
£
r t *'¦ >
(b^O'Z
£>>o -7
fb»^>o
n>$ o
6 So - 5
/bto -1/
;p
-N|~
-\T
i- P
- ft
¦f
3
i.\<--.
5//
&So-
/ir-r. - 6
';:.J.c - 7"
/>££>
/V-o- J
££G - 5
/> ?0 ' 5
/S:'u
f}Ao- C •
/J
?./>
- />r
-z5^
•/V"
/•v-
-/>/-
/>/^
/MO
eso
/bSo
&$G- '<
tL~6 - A-
3S$ - .«
/3*cj -
{-
'.'/¦¦
-i
11 V->"
- f/A
-ft#
-tf/t
/¥A
,-^ /*//>
"/>/V4
Nl -IJtVs*/
*>*?€
^ *
fVr^
S~*-'
a>
Se<
2.0 o AV
'{ C. r ...«.
^pe>.~sf'A i
'0
' i/—s v «^| / »iy3,~'
drw"^?»
t. 'Z *z
A-
-4' « ' V
^ fJa-i -t •
p, t4
/
Six
$**/?
fi-*
c<
/
r»
ft //*0<-v ^
-------
r
•Ctn
eso-9-
7/?
6S0-3
^Ssa -J?
&£0~>?/
/b&£>
r>5-o - 9
r>so *¦ *
as®
/>So - ^
C,S*- s'
-9- C
- *~] t
G>$o -O - \*ihi>»-4.
<2&o - o -,
/3So J & *.
fi>So - £>
f.
»#V*V[
r^-
~m
¦c/c/>
¦C/C/>
'-€/€/)
5- C M
c (A
C fA
3 r£
- c f'l
c /<*>
1&- C 1 C£;
0
-t £>
3/>
-z.
> -/*«
f"Z£.-l
££0- ©~2l
6*%
O
&$> Cj&of-
&pp
-»»ic£*Q
4
/v*-v y^
Z?~-*r>
5e r
£
(
s /"rti
A
1# #(''*¦>
4o>u ^
1
-£€
d c;
r-sj
c/?
X ~f
C
(VIa^Ic
#1
(k/zV-'fe
/f.
#•
GL
t
>vy>/<--« t *
_/V
6S6.'' / 'Pro -^a -
\>^v
^a»AO!
<*
Sex.
(^>U-/r
£**
x
v«> t.
^ysir/: /*£
3.-2
'/W» *
i»..
a
,-c c,
S«r
5£f
c
f
fK c\ */•»•>•
r*
r+r»..
Q-#-» v^« • .
G'
.V ' »
: J, 3
S*«-"6
?..i
» f
#»
e *%
«* 5- t fC
W
c W 5
% V u<~%
cf /6t*S
J>
A-?. A Gk*
AyJ< S> S.
r%
y,
/. a,sr
4-o c//
<•-».%.& * Si
rr ^
„e-r '.
- C'-
f"
*// J.J»*
^
' -
' ^ J»-ST
^ctv '
•e QecJ'it,
-A
"2
S\ fov l-i ' QfOt-tiv,
(l&-eL*sCU-r~'
- #j?,jr"
i>f
-------
Per P^SS'f (q[F~^4vrr vv, ^ i. j
Gt*p' ^ -tsi-c
&KP- ^Q „??-%{{
a#f-£wB - y/i-tft
afltyaio- j_~tm c.
- J.
'4«
rt#/yes
&/#y&s
o vpj&Ao
&rh*//2sL - 1 C
'M
-------
ft "*">
C~
-u- U'<1
- A
i < t-i
jvV^-
I
r
.v\.
<. A; o
r'' 1
L< /
/3 fi-'/S ~>o — 6
- W
t/via
ir/J
/3 />/» -
p^p -
A ¦
«^>
A "
p. A p
-
-
6ft P **
/'j/-"V.0 -
€>t)P ~~
a*)p -
fr&P - 3
Ira
-3 ~ v7-
tj,
39 ' ex.
39- S £
- 3*7- C
sih-
57 A-s
s"7*- n
5"r/A- C|f
1>V C
XSW -c
1 - C / /•» >
A
ff*
cc
/>rf-s'j fi-c f /»
&*o'
0»5O *
«$so -
/iio •
.'•"£) -
/i5o ¦
/35o-
/3So
/6^ -
lift
ft
-A- A
- /*
'~4
C iC£
-etc
Y- C/c.
"C / Cjt 1>
£79© -C/
¦S -C/r
• C//3
J? -£//?
Z3
'J
,0
^5c - y- c//j
^ -£¦//?
>55^ - jr/»6r
-------
(I e*rft i'a , L4 £u4-«-
aso-
C»S©
&S£>
ftSo •
0S6
eso
&$o
1i
C* - CtA
I - c re,
*Z-~ c
C t il
£~ -Ct4,
(& -C f&!
/2>So~ 3>- 5
I
7/*- sc-
$5aj - ^"Cc.
ASo - ct/ncz - f
&5o - CTt*L&-'Z~
&S& k CJT£j£. - f
&sc -cx&: --z~
SGr&
j'£/>*>-o - \f~£&
/2&e//^0~O~SJ4&Z--
^• e-C|^u j
-j2
^2.
-------
TEL 'Sv^le G>WU.
$
>~k*b
H-
P*tf
pp*rri6f»
<
v>/.'e
&syt
&s?/
*>%«/&>
&sy&
65}>oj£
C*P ~t
&»P~ c
6#P~o
£>PP- o
—C
&0P~ i
\fip- /nc&
v>- SG-a
7p-fi/h
* -yea
£»-o-\rm
f>-0 -xr^£
>/>P-0-M
0-
1
"rtfAg~l
~c/^~ /
3 -£/£ • 2
t
ft /£*.
pt /£%
P/TTl'
:a
nc.£
i <
*2. : £*/
file<
*«T" vaHk
^eT"
UeCL
/2>S>t>//
Bscy<6
/IS
r
L S/ft
&S&
Sso^
&So^
&sy
&!>*>//
/0,g»fc//-
/S.sa/'i.
iS.sc//2/
/
£$*P -0
£/tP-0
AfiP-o
£>/y*~a
&r) P -
&>*& -c
£*¥>-&
I
- M
*-p -
/?,0 - Xf
o'—P/
*
0 -/»/=<
> - />/=/•
/SfiP
/ gfi/* -
&aP~0 -
3^~o -
<5 "•
%rtP—o —
v-3 - o - «
-o - #
/y>' o " *
/>/l/S -
-/^-3 -
v^-3 -
> • M* <2
>- /17'Z/Ci
• m/3 /g
c/3 -&
tri ~ c
-B
S- ^
;- >"l £*3-
V/HC <2-
**34t-/)
"2 (V*
cy*
2 <3 C./a
- /- >? 0/
-/-<£ ^
- 2-/) (
-*-<3 £
06 ^
&
(/*)
CrO
/? (y
2> (!/
¦/9 C^i-
^Ckn
i cyJ
fUVJ
/> C!'i.J
Ci^z J
>
"*.)
r>
,'4j
-------
(Si
G>U . 2.^
1
/i So
Sso
&$o
/2>s>c
&£& *
Qst>
&S-C
&sy
Is. k*?
~o ~/*Ah
-0 -/>/
- & ~P/A
-C/ me
a wee?
-
f>*~>
V2 —21—
£& -/
a-z,
V3
¦ 2 -
'/
-2-
i¥"TT
d?
[1"AP'
i A A
1
oHi
\ rt r^W.
f/2
/A
o - & - i A
o -
'#i
/vt
& -"2 A
H»
-fiicg-A
hp~a ~ mca-4
z
Q/^
f
j
-------
APPENDIX B
LABORATORY RESULTS
-------
ISO RESULTS
Run Number
~Total Mass (GR.)
Meter Volume (DSCF)
BSO-1
0.7843
58.74
BSO-2
1.6997
4.17
BSO-3
8.8190
37.75
BSO-4
1.6180
5.24
BSO-5
0.4578
23.73
BSO-SAB
0.0093
352.58
BSO-6
0.7143
25.77
BSO-7
1.3123
236.84
BS0-7A
0.0090
21.34
*The BSO Grams Total Mass is the sum of the partial
masses for the separate runs as presented in Table 2-1
Gravimetric Analysis of the Smith Report.
-------
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
RESEARCH TRIANGLE PARK, NORTH CAROLINA 27711
DATE: July 25, 1979
subject: Clairton Coke Oven Samples
TO Roy Neulicht
OAQPS, ESED (MD-19)
Attached is the information you requested. If I can be of further
assistance, please call.
Attachment
FROM: Crystal Rogers, Physical Scientist
SFMCS, PAB, EMD, EMSL/RTP (MD-78)
I PA Form 1320-4 (Rev. 3-76)
-------
CLAIRTON COKE OVEN SAMPLES
BENZ-a-PYRENE ANALYSIS
Sample Identification
SflMlPJ.'C. J V
H\f\ Ss C
BaP ng/ml
4-MPR-B
ZiZ
10,520
- 4-PF -B
Ito
]
37,600
4-PF2-B
236.
.j^
225*
4-XR1-B
) (f U
\.t\l
10,920
4-XR2-B
) V, w
O-O^lh
10
4-XR3-B
1 1m
.— BMD**
4-MR -B
}°l In
pTs j
124,240
-3SS3>f
7-NPR-B "
~t U> 1
7,777
10,640
7-PF -B
7 \0
|£.£>36
71,600
7-PF2-B
1(72
iJ1. OH
240
7-XR1-B
nt?
Received Empty
J-XR2-3 -
m
Received Empty
7-XR3-B
}%
BMD
• 7-MR -B
C Lj t\
.*"S
87
Mass Kn/sJ ^
n.l^l
7A-NPR-B
~7t
0.0:-Z I Z.-
72
7A-PF -B !
)°iO
O.OOfl'-T
43
7A-PF2-B
w.
BMD
7A-XR1-B
.
-
BMD
7A-XR2-B
"
—
BMD
7A-XR3-B
Ji
—
BMD
7A-MR -B .
o. i loi-
229
T^u £A P- 7A RarJ
O.ny-i
BSO/BaP MCB-B
BMD
BSO/BaP XRB1-B
BMD
BSO/BaP XRB2-B
BMD
BSO/BaP XRB3-B
BMD
*4-PF2-B was run twice. A 1:1 dilution yielded a result of 225 ng/rnl
while a 1:200 dilution gave a result of 240 ng BaP/ml»
**BMD = Below Minimum Detection. For this case, less than TO ng BaP/ml.
Si ~ Sa^)c Vo'-rri ^ (L^ f" , ' ^ \ ^ ^^
d W
-------
Analysis of U.S. Steel,
Clalrton Works Samples
Aug. 2, 1979
by
T. R. Smith
f rxww
atttHSt Am SMcr systems gmx*
-------
TABLE OF CONTENTS
Page
1.0 INTRODUCTION 1
2.0 GRAVIMETRIC ANALYSIS 2
3.0 SAMPLE SPLITTING AND COMBINATION ... 5
4.0 POLYNUCLEAR AROMATIC HYDROCARBONS .... 8
11
-------
List of Tables
Number Page
2-1 Gravimetric Analysis ..... ......... 2
3-1 Sample Volumes ................. 5
4-1 GC/MS Analysis 8
%
111
-------
1.0 INTRODUCTION
This report represents the analysis performed on the samples originating
from the U.S. Steel, Clalrton Works.
Included are the gravimetric analysis results of the benzene soluble
organtcs tests. The volumes of the samples which were split and combined
are also presented. GC/MS analysis of several combined samples was also
performed and 1s presented In this report.
1
-------
2.0 GRAVIMETRIC ANALYSIS
The results of these analyses are compiled in Table 2-1
were handled in the following manner.
The samples
Sample Fraction
Filter
Sample Designations BSO Test Method Paragraph
BSO-X-PF*
1st Impinger (Acetone)
Probe (Acetone)
1st Impinger (Benzene)
Probe (Benzene)
BSO-X-CICD
BSO-X-PICD
BSO-X-CIA
BSO-X-PIA
BSO-X-CIB
BSO-X-PIB
4.3.2. (two six hour extractions
were performed)
4.3.3
(cyclohexane was substituted
for benzene)
4.3.4
4.3.5
Filter Paper
BS0-1-PF
BS0-2-PF
BS0-3-PF
BS0-4-PF
BS0-5-PF
BS0-5AB-PF
BS0-6-PF
BS0-7-PF
BS0-7A-PF
Table 2-1 GRAVIMETRIC ANALYSIS
First Extract
(grams)
0.4105
1.1766
0.4045
0.8687
0.2209
0.0005
0.2505
0.8682
0.0004
Second Extract
(grams)
0.0085
0.0156
0.0014
0.0108
0.0050
0.0004
0.0041
0.0029
0.0004
Combined Impinger Condensate (1st Impinger Only)
(grams)
BS0-2-CICD
0.0106
BS0-3-CICD
0.0528
BS0-4-CICD
0.0117
BS0-5-CICD
0.0013
BS0-5-CICD2
0.0001
BS0-5AB-CICD
0.0001
BS0-6-CICD
0.0054
* (-X-) Designates sample run number.
2
-------
Combined Implnger Condensate (continued)
(grams)
8SO- 7-CICD 0.0029
BS0-7A-CICD 0.0019
BS0-37-CICD 0.0812
BS0-37A-CICD 0.0142
BS0-1-PICD 0.0019 - Probe/Implnger Condensate
BS0-6-H20 0.0001
Combined Implnger Rinse/Acetone
{grams}
BS0-2-CIA 0.1277
BS0-3-CIA 3.4809
BS0-4-CIA 0.0059
BS0-5-CIA 0.0019
BS0-5AB-CIA 0.0013
BS0-6-CIA 0.0015
BS0-7-CIA 0.0090
BS0-7A-CIA 0.0022
*
Probe/Implnger Rinse/Acetone
(grams)
BS0-1-PIA 0.3390
BS0-2-PIA 0.3213
BS0-3-PIA 3.2108
BS0-4-PIA 0.7151
BS0-5-PIA 0.0042
BS0-5AB-PIA 0.0032
BS0-6-PIA 0.4326
BS0-7-PIA 0.4125
BS0-7A-PIA _ 0.0013
„ ^SO-O-PIAB-l 0.0026
"* JiSO-O-PIAB-2 0.0013
3
Implnger = Greenburg/Smith Implnger
-------
Combined Implnger Rinse/Benzene
(grams)
BS0-1-CIB
0.0002
BS0-2-CIB
0.0017
BS0-3-CIB
1 .4625
BS0-4-CIB
0.0011
BSO-S-CIB
0.0031
BS0-5AB-CIB
0.0023
BS0-6-CIB
0.0007
BS0-7-CIB
0.0014
BS0-7A-CIB
0.0017
Probe Implnger Rinse/Benzene
(grams)
BS0-1-PIB 0.0242
BS0-2-PIB 0.0462
BS0-3-PIB 0.2052
BS0-4-PIB 0.0047
BS0-5-PIB 0.2213
BS0-5AB-PIB 0.0015
BS0-6-PIB 0.0194
BS0-7-PIB 0.0154
BS0-7A-PIB 0.0011
4
-------
3.0 SAMPLE SPLITTING AND COMBINATION
The samples were split and combined according to technical directive
Number 2. A listing of the sample designation and volume is included
as Table 3-1.
Table 3-1 Sample Volumes
e Designation
Volume
(ml)
BAP-1-NMC (MeCl Nozzle Rinse)
85
BS0-1-NMC
75
BAP-2-NMC
58
BS0-2-NMC
52
BAP-3-NMC
46
BS0-3-NMC
78
BAP-4-NMC
114
BS0-4-NMC
42
BAP-5-NMC
18
BAP-5-NMC
15
BAP-6-NMC
48
BS0-6-NMC
39
BAP-7-NMC
29
BS0-7-NMC
21
BA0-1-PR (Probe Rinse)
660
BAP-2-PR
124
BAP-3-PR
104
BAP-4-PR
128
BAP-5-PR
125
BAP-6-PR
138
BAP-7-PR
232
BAP-SAB-PR
52
BAP-7A-PR
72
BAP-l-CD (Module Condensate)
150
BAP-1-PF1 (Filter)
202
1st
BAP-1-PF2
250
2nd
BAP-1-PF3
138
3rd
BAP-2-PF1
228
5
-------
! 1 I
Table 3-1 continued
Sample Designation Volume (ml)
BAP-5-XR2 (XAD-2 Resin) 196
BAP-S-XR3 190
BAP-5AB-XR1 136
BAP-5AB-XR2 200
BAP-5AB-XR3 184
BAP-6-XR1 120
BAP-6-XR2 188
BAP-6-XR3 200
BAP-7-XR1 176
BAP-7-XR2 194
BAP-7-XR3 196
BAP-7A-XR1 160
BAP-7A-XR2 184
BAP-7A-XR3 190
BAP-l-MR (MeCI Module Rinse) 230
BAP-2-MR 64
BAP-3-MR 328
BAP-4-MR 196
BAP-5-MR 484
BAP-5AB-MR 664
BAP-6-MR 912
BAP-7-HR 548
BAP-7A-MR 484
BAP/BS0-3-VMC (MeCI Vent Rinse) 260
BAP/BS0-7-VHC 136
BAP/BS0-3-VB (Benzene Vent Rinse)112
BAP/BS0-7-VB 90
BAP-37-CIMC (MeCI Impinger Rinse) 270
x
6
-------
Table 3-1 continued
Sample Designation Volume (ml)
IAP-2-PF2 (Probe Filter)
244
BAP-2-PF3
130
BAP-3-PF1
184
BAP-3-PF2
242
BAP-3-PF3
116
BAP-4-PF1
188
BAP-4-PF2
236
BAP-4-PF3
184
BAP-5-PF1
204
BAP-5-PF2
204
BAP-5-PF3
132
BAP-6-PF1
214
BAP-6-PF2
198
BAP-6-PF3
236
BAP-7-PF1
210
BAP-7-PF2
202
BAP-7-PF3
214
BAP-7A-PF1
190
BAP-7A-PF2
234
BAP-7A-PF3
226
BAP-1-XR1 (XAD-2 Resin)
160 1st extraction
BAP-1-XR2
180 2nd extraction
BAP-1-XR3
180 3rd extraction
BAP-2-XR1
130
BAP-2-XR2
194
BAP-2-XR3
200
BAP-3-XR1
140
BAP-3-XR2
174 -
BAP-3-XR3
186
BAP-4-XR1
166
BAP-4-XR2
180
BAP-4-XR3
190
BAP-5-XR1
128
7
-------
4.0 POLYNUCLEAR AROMATIC HYDROCARBONS
The GC/MS analysis was performed according to the procedures used
in "Analysis of Polynuclear Aromatic Hydrocarbons from Coke Oven Effluents"
by R. G. Beimer, September, 1978 (EPA Report 78-CK0-12). The results
are listed in Table 4-1.
Table
4-1
GC/MS Analysis
M.W.
BAP 4
BAP 7
yg/mi
yg/ml
Naphthalene
128
202.4
70.4
Biphenyl
154
8.6
1.6
Dimethyl naphthalenes
156
6.4
0.8
Acenaphthylene
152
81.4
Dibenzofuran
168
45.4
Fluorene
166
51.2
Dimethylbiphenyls
182
11.6
Dibenzothiophene
184
13.4
1.0
Phenanthrene
178
236.4
28.0
Benzo(h)quinoline
179
2.8
Carbanzole
167
28.4
Methylphenanthrene
192
21.4
2.2
4H-Cyclopenta
(def)phenanthrene
190
20.2
Phenyl naphthalene
204
5.8
Pyrene
202
97.2
16.2
Fluoranthene
202
92.4
15.2
Benzo{a)fluorene
216
16.8
3.0
Methylpyrenes
216
29.2
5.2
Benzo(ghi)fluoranthene
226
6.2
Chrysene
228
5.4
33.4
Benzo(a)anthracene
228
94.8
Terphenyl
230
3.4
Methylbenzoanthracenes
242
18.6
5.4
Benzothiophene
240
11.8
Benzopyrenes
242
18.72
68.8
Benzoperylenes
276
69.4
Di benzoanthracene
278
15.6
TOTAL
1383.4
8
259.0
BAP7A
yg/ml
1.8
0.8
0.4
1.4
4.4
-------
-------
I
-------
APPENDIX C
FIELD DATA SHEETS
-------
-------
pu*r
DATt
IWlfRt LDCdTH
S0U*CE r.e
Htm HuwrR
Cf>ERAT9K
AIVIEKT TEMPERATURE
MftQNETttrC JMtE«U«
STATIC mSSUKE
mri* ttumiMs)
tzfbfd S* S S FlCfcH I*T*
rrmy ~
UffrJUy
: UWTW MB
mutt i.b,
ss
%»-
6r '"¦
ASSUMED WHtTIJftt; % _
**»"2 *»«.E KWE^r
"ETC* M* m»«tl VTa «
METf*
€ FACTO* '
P*OM HEATf* SETTIl*
en* setting *
HtfEIIEWtE a>
KHEMTIC Of TW*ttll P01HT,
REUS ANB tECMD AU MTK EVERY
COftOTS
^ os-t- o^jerj H-C^VT
trimgs
-------
QfiP-z
SASS FIELD BAT*
Pm« LCN6TN we,
Home I.B,
m
^2-
ss
SAMPLING LOCAT
SOURCE I.B.
nw *vmm
OPCKATO* J
(WWirUT TEMPERATURE.
1AROMETRIC PWSSURE _
•wmf—
Q -
HHT1C «tl5SU«£» tps> . ^ ,. ¦» )
nun «u«»«is) 12
ASSUMED MOISTURE, I
KAO-2 MDCMLf NUKSF*
METER #0* NUMBE*
METER aH.
C FACTOR
PR©«E HEATER SETTING ,
OVER SETT I Iff
•EFtiiNCI ft*-.
2^
SCHEMATIC OP TRAVERSE POlMT^AVOVT
traverse
POINT
NUMBER
ctocn time v
MR clock)
SAMPLfMf
Tfjrtm /ifeZ
fl*S METER READING
(V(»),Ft3
? *
75
?r
6
?fo,
/0(j
$7
MfJ
sa
t/ti
/<%=?-
/o6.
7o
/
/O
\
5*o1f
b
&
*
'¦
}
TOTftL
m
•
m
•
•
m
m
m
m
•
•
•
AVERAGE
m
m
m
•
m
m
#
•
•
•
CQWE8TS
f SelM Gel Pi
/
/
mm?
-------
£ dt/J&'C'tc , / nu.
r GXftOjTQ^
SASS F ICLD DATA
¦MVLIftG LOCATlOl
SENMCf 1.9.
nun mmt*
en**io*
jMVIEttt TCWCBATURC
IAROMCTRIC PRESSIWE
ITATIC WSfOTf, , ...
Hire* mnlil SGI
AJ6 , 3.
PftOK L£f#5TH
MIZZLE KB. .
tsl
ss
ASSUMED NOISTUMC* I
»o-2 mmjLi nvnki
HE Tin »GX NWKft
mre* ah.
€ FACtO* ___
rw)»l NEATI* StTTlUS
onn ^
ifFimWCl AP_
¦>—M-Mp
TiAWftSE
WIKT
HUWEl
a3«)
SNVL1NC.
,H£T *3Xj
s*s nnfi ftCABiws
(wK>#rt5
VELOCITY
Wtncc raESIUMi
OlFFfHEWTiAl
<88*. 1* «2®
STUCK
TIM*E»ATUItt
(f,5,»F
t»T U$ fCTEK
T€Wt*AtU*e
££.
IN N,
OVEH
Ttf»E*ATU*E
°F
iwmsEi
TtRPEMTU*!
Of
SOUKIFt
T»A*
TWE*ATUW
«F
HHHt
tffrEIMTURt
°f
1HLET
(t m
*tm
OUTLET
(T«wit^
S*ST*ED
ACfOAt
2
3%
*?o AVs^
~* .
9/
£
/^3
6 S"
7
*V>
.£^5
?/
<**>
A t
?y
42
*0*
?/
/b">,
69-
vV
asa-
$
44
f/O.s-t
*t6
9r?
/
-------
CA.ecA *Ob Of*
fJWPtlM LOil
souae* i.c
«utt mhkr
OPEMTOIt
JIMtINT TEMPERATURE.
IM9KTRTC P«SSU*€
STATIC P«SSU»6, 1**1 ^
FILTER MJMEflfe) /I?
S-kel Ctfrf ^TCI°
l#fTT*wjr
S A S & FIEtO B AT A
MtOlf LfMlTH W*D
wome !<&
£^1
'/VA/r&e
2z2?«%°
«S5W*D KOISTWI, S «"
«*»-? moduli
«*u« box awtem yvr .°F
MY 6AS HETfK
TfMPtSATtIRE
rut*
VACUUM
f» Hf
WfK
TfWtlATUHI
°F
IWIRCEII
TCKPCRATU*!
Of
toaiEprr
1*AW
m*wmm
OF
MOM
TtMttftATURt
<*
¦¦ /'
1WLIT
it9 ><*
*w
OUTLET
Dt5TPED
ACTUAL
tp
/?
*}3
O
$6
*?¥
#,C
'/?*
/*V
93
??d/
r
M
\
/
\
/
\
»*2_
lk
t
TOTftL
•
m
•
•
•
m
m
•
•
m
m
•
AVERAGE
m
•
•
m
•
•
#
m
m
•
cowcnts
TRWk
-------
" &/4./JTr~ —
SUSS M E LI I * r *
Ntitt UWft
ttlZU I
2 3
MVlEirr TIMPtMriPRE
SMOWrilC MCSSMt
itiTtc hhmmae, its).
MLttt NUMiCUCs)
ASSUMES ntlTHK. X „
mo-2 mdmle Runiii.
i«Tf* id* auwtti «...
C F«TQ«
mil *mte* jehiw ,
o¥fn sfrrme
*E*E*t«Ct a»
SCMCfWTfC OP TOAWEME t*W£4jWt
*ea» mo nam au mta ivwr^v HiNtint
ivmm
TKAVCiSI
wht
mmtn
.CLOCK TIME t
m clock)
SAnPtlH*. X
nguiB IgJjj
M H|ttK REA01H6
u i
78J.SS-
VELOCITY
fetfff.i*)
onificf wtfwwE
DirFfWHtlAt
few), t* H2Q
ITAtR
nrntwwt
WIT «A| METE*
TEMPMAT mi -
W
VACUUM
IH Hf
9VCH
TfPrfMTUW
Of
wnwf*
rtl*EKATt*Cf
°F
tMKRt
THAP
fitV|pATWC
' MOM
11l»tlUTORt
®F
1
tmjn
% >®F
"i*
OUTLET
—.
—
,—
75L
PS
ai>»
L^/6
?ly
y«
,"3/6
/Ai
ol\7
O*
SiSJJS
»
4 0pO
.—
9^.
f?
£$*
"3/6
St$T
/C7 7
&§-
¦*
\
~
, >
3o.&SS
-Z5
-
*
TOTAL
•
ink's i
•
•
•l
•
•
m
•
•
•
m
mw&
m
•
•
•
•
m
+
•
•
m
%A*'
TRWB
-------
*£{£? I**-,,s
9UHT
rSL.
IM* MELI 1*7*
Mltwt ItNHUT*!.,
•minit
irirtt {»$)_
flint MMM»(t} -
aut Mi mtam m> mta ti*»?
•Sun
MtZlf I >8-
7!%
MMPCff fOfftuH, I
m»-2 «a*i n#i(i
MITO* Kl %Ptf«
*m «*w
f ncrw ^
jgpItwi
MMC miti* tit? I*H
**m NfViai«
Rmanct et.
TMItttl
#QtNf
WMMt
!!&»
IWUH
"O""
«** mm mam
"sm. /&'
maeifr
0»IFiet HKIIWK
ftlfrtKtRTIM.
ton), I* «20
fTACI
tWfiitill
arr «m «m*
Tt**CM?l*l
4RS«
i«»,
•WBi
iv»tuna«
•f
N*tMCi
mrtMT *t
•f
"SK*
•»
1 mxt
<3
?!
30 0
1
m/5\r
.bo
77
7*
is"
30/
e-4
jot
1
sa/jjh
•
<3(5
7'r
V"
3 <33
§r
Sod
?
830.
7Sr
??
V*
3d*
6y
ZOO
/'
%¥tS) %
.30
7b
?S'
ijtt
tsaa
ffl
V3
£*7*i
/&
7/ j
?
\Z.~L/
.iy
7^
>
i
1
i
i
i
1
I
i
TOTAL
• ¦
•
•
JL
+
• ,
#
m
+
•
•
m
mmi
Lt_j
m
LJL
f
3l
#
JLJ
twm
-------
MTV ± ~ ± ~ / A
•mi
INtilM tOCj
KM»C€ t.»
M« aurtK*
ert**r9* _
CSM
,S*SS P f III HtA
PMM UW* I
mttu i.e. ,
> f«t
3B555CZ
•HTUBI . W>
Milium,
imic pnttim* t»*>
MBWVB "OtlTUH, I
itt-2 «w«u J3» « uocO
TT \
JM WTf* •«*»(¦«
E^J.rt5
€VV.22
~
dfttnet fiitMit
HWHW1 |AL
fc*>, m HjO
•mi
n**(MTM
wm «• mn*
nnufiPi
JR.
!• Hf
mmSmm
%
tmtwm*
T(PP§**T¥M§
*
•kf*
W|wnM
wnurm
¥
tmjti
V
WflUKf
¦iiirt
»crtMt
Z
*4*1
9>S3.%
3c>
^TD
7*7
•?*7
///
¥
4f°,
isstja
M
79
if
**r
-74
)
TOT*
•
•
•
•
*
•
#
m
#
#
+
•
tmm
m
•
•
•
•
#.
•
#
•
• .
tOWCHTS
¦MflMeSM
4r mSSSS^^^
-------
%0Ut h*,l A €2h** ^j|),
riktfi
»» *»,. „„,L, W
M« MttriMl -**-
W*fiWI
Kl«Wit1C IP TMftftttt POWf U»«Vt
«« AM #ItW* au ¦*** «*ftT
CLOC* Tf* %
Ql m ctoei)
SmR. T
b(W T&ZT
EfOO
gfrP TBST
W*L
mim
imtm
im Ktn Kmn
3&L9X
112,
too 7
Cs" m
*- fctfi fli r-i £¦-
>A/ 7a
mscm
fe»{T?i.lfjO
b*L,
i ft ft
Ml*Kt f*t*tllM|
tTmtttm*!.
Can), t» HjO
?«
ixik
izli
¦tact
itmutaat
<»»).%
r>f f*\
Z>
WLt?
<*¦ W
*1*
ountt
-------
ia^b
KMT
UlTf
'A'-k
fc>V«
•3. b"
j£" *"S
$ A S S FIELD CUT*
m*i tewsTH «n»
H0Z2LC r,0,
AMBIfNT TEHF£«MU*tE
¦**W*T*fC FfttfSlJftE
1TATIC Pits Stmt, .
ASSUMES WIITUKE, f
xad-2 pwxile mmtn
NETIA iOK NUMCtfi
KTil At*.
c factor
„OYtPl fRMMRU.
WOK NEATER StTT
cvw SErnws,
WF!»WCt 6f
es:
SCHEMATIC Of TRAVERSE PtHUVV^WT
trvyTi
A-
Wr^sT-
TMVtIS!
FOIMT
MCIR
mini jwfl
TiQfm l^i^F
MS W^rllfRBIIIG
fRATURf
,°F
i»rXts
^PWEAATURE
9V*>
VACUUM
IN Ht
TfUPfRMURE
iwtisST
TlUfMtUll!
°F
TPlfP
ff*»|*ATVRf
TEMPERATURE
•f
IHtfT
fT„ )<*
IB
(WTllT
-------
turn,
¦mi —
HWllM
aswct i
ftp *uMira
ewwro*
P/UM~
r»si f 1111 Mr*
TiM,
S- y- nf
JZA.
Jjjkno?}-
WtRtTUX Q
mm t**t* Mt
¦omt t.t
UMIICKT TinKllf#! ,
Mtwmc .
Itftflc WIWI- (PjU
(MtlMCB t _
**»-2 *b«.i
NITIi Ml WMFt* „
f«TI«
C MtTBI _
£*Sc
r'
vJJC'^ jg1
9mm nmm
WIIWI t».
KMMfftfK V ftlMPW HHW (MVt
I Mi «feei» ALL MTA t*tt* . KJMfYtt
T*AVtWt
POUT
*ll«!t
gr^r
Jf*s»cr£Af
"flssr HI#
0*0 to*
I! ||l ¦ JfcfT*
^nSJ
1
tft8ST,w
«.««>
-Z7
3yF
*?
J2L2
3a
52
*4
4/2
.
IE
W
V7
TJ
2a
M
^7^
M*
mup
111 «f
7
fSMMfHI
' %
>0
TzL.
5L
m
¦7"?
52
7r-y
xJL
22
T
12
Fv
_rs.
72T
P5:
7£~~
/o5
ZdV
W.
12.
54
?/
~J
awtins
-------
85o~t
tMvtti* locati
wwrcf
tUH WMtE* m
WMTM /HSjJ
AftttE*T TfMPIWTIIIIl
MJIOHETKIC ni»UK _
static mssuftt, (PS,
FILTER 1IU«E«C9)
® _
f 43
lEEir~
SASI f I E LB D A t A
5 LPKfX
f»nu i.s. r
ASSUMED HDlSftmt^ I if
sm
\f 1?
WO-? MODULE *
METt* SOK
mete* a*
C FACTOR
Sgg&attwu
WWil HEATCK SETTim
owt* sett me '¦""
•flFERMCt a» '
SCMtWTK 0^ T«A*i*St POlKt LAYQOT
6^
nwrnnc
W>I«T
mraei
Xa's
NV
ua nEti*l^stm
W6A?
VELfiCIT*
ORIFICE pressure
DIFFERENTIAL
, IN %Q
STACK
TfWfBATUfct
tT Sh°p
WIT CAS PCTEt
TifWERATURf
3
w *
VACUUM
IN H|
Of
IIP IMC*
TfWflATUW
"**** 1 MOM
TfJcMTtlftt MWWW««
INLET
(T- ><*
"in
OUTLET
—
$
f c>£>
i
Z^?£
A
/b?
/€>?
IN
ar/t
*%
/®7
(c?S
#
/©I
t
$1
3&7*ZS
/*<
hs
4
s-/
te
zy
-=*_
//c?
ton
M
/Z6
?<3
11
not
3/295
//4>
fx.
/i#
fat>
A
o€
3Z9
A
//f
i^C»
/27
kt^
n
*1
?3tfV5
.f
* ' f
f/S
b&
!?
jXf
1*3
7.<*
&*?
3*/&,/
*7
HIS
//i
k>i
M3
•zz.
//
•&
f/S
fob
"2-/
loo
/«/
"V
zy
&lg
T*. t '3
,7,
} tr.
hi
?y
•—*5-
,
42-
\
/
*
&H.H
•7
fc
H
• i-
1
S'
.
TOTAL
m
•
•
•
•
m
m
•
m
•
•
m
wctiwe
•
m
m
•
•
•
#
•
•
•
CffWENTS
TRWB
-------
: • V-rn^;. - #^-.1 M
a>5c -~l
^-T /p^k
•i*r 4 w
*' I
-,S * S 5 ¥ ? t L B BOTH-
H?
! LCWtM
>MKZU t
MNPlltlt tOCMIOH
SWJRCi l«D..
RUN lltlMKft
0«RA?O*
«•!«? TEHPWTURE fi^,,
iAwwetRic pressure , „
STATIC mssoit, j>«)T%^r "
fiiti* *w«R1ITURE, I S!
-¦r.
**
:'4
**0-2 MQQULC wwwi^ "
KtTER BOX MUWtR ,,yf ^ffqviiti
METER AH. .¦*—» y
C FACTOR ——» , ¦
*3
?!
«K»E HEATER WTT1R6 .
OVEW |ETTI*6_„*bS2.
KFWIWi a» —~
fCHfNATiC Of T*A«RSf ROIRT tATOUT
tRE<® tm REC0RB AUL MTA fVWT PlIPWTf 1
zmiws
TRAVERSE
POINT
HUMMER
CLOCK Tlf* v
m clock)
smitn
«*S PVTCR RUDtM
!*«},ft'
Z$h,»F
MT «*9 METER
TEfVERATURE
*UMP
VACUUM
fR Hy
^Jr*)
°F
*
i TtWERATURf
1 °F '
lOntERT
T**^ 1 t*MR!UT(«f
TWPIRATURl 1 ^
miff
% )0P
•OUTLET
. f j ]
T
DESIRED
ACTUAL
t.
ZS
35$.
*
•1
;{
Ay
hy
/«/
i
71
9
/*/
fa y
*7
m
;
;
4.2
2°f
9&S
iby
2.7
let*
V?
~
%
3/
A
f
M
31
i
< )
ft
3^5
) f
n
31
n
ti
ff
*
J
.
Ze>
! '
#
f
}»
* E
, ,
f.
¦
. /
}
i -
i
TOTftl
•
•
•
•
: •
m
•
•
m
m
•
•
AVERAGE
•
•
•
m
•
•
m
m
•
•
TRWk
-------
r
fa
nmt
1J£
KIHIltl !*!«
Km
t*M»U** LOCI
mmet f.».
mm mamt*
wt**rm
mmn*r 1^
IMMWt N«ll«
mMZ*2##"
r iswm m v+t
mat i»*.
/'¦s.s zr/^o
iMM9 wrtTuftt. t
itt-i km(
mm mi
*|Tf»
e riew
w>yj?J*u-»
nunc hiimki, <»¦>*•- <
»htt»
..ft'tg-
KM ¦*»«• Wt*lM ,
MTT!»« '¦ ""
MftMaCt
KMIWtlC •* IWM^ftSK fIBt UkMVf
i%Urrs
raw«Ts
roirr
MHK*
•••vim ^Sir*!Z.
«i 'wit* atom
4W,3f
matm
torjlw.iqfi
onmt iwiim
(Ml). II *70
9t«Ci
ftPWitilK
tm w *11*
4s.
I* H,
*;_ri
ftMMMfSi
"SB"
iiPPW*Tiw
*»
IMIT
V
t»*at
Ti^wt^F
«? /
Ill®
,mn
y
o ^
MlttttS
ACTUII.
\
r
'1.
{lb
*fi.
OO
<$4
?£
77
z
6%
ft ft
H?
-------
$ A $ $ MELD DATA
PRQU LEN6TH AHO TTPE
MZ2LE I.ft.
SAMHtHe tOCAT^
SW»CE !.B
tttIM NUMtER
OPERATOR „
MVTEirr TEMPERATURC
IAROMETRIC PRESSURE _
STATIC PRESSURE, tF|)_
FILTER WfOERCS^
AS9UNE0 MOISTURE, 1 .
xab-2 udooli ruwber _
METER BOX NUMBER
METER ^
C FACTOR
PRO«E HEATER SfTTIRS _
OVtW SETTtKG .
REFERENCE a»
SCM0WTIC Of TRAVERSE ROlKf UVOUt
READ A«I RECW® ALL DATA EVERY Klfltftt.
^
SAS fKTEft RtA&fW*
—^/C
tm 6AS
|*4#
TRAVERSE
POINT
NUMBER
lAMKim
TinE^niN
T*7 '
fcpJW.H^G
OTITIC? >RES5WF
OITJ^REHTHL
IN HjO
DCSIRED ACTUAL
STACK
Ttf*PERAT||RE
' 6AS WTt*
TEMPERATURE
WUT
(T„ )0F
*!*
OUTLET
ROMP
VACUUM
IK Ha
5 'to
ffX
S-5T
i^Z-
4
/^r
±Jl
±
71.
M
V* -3L V
Jr» C
73
B&t
^L
l£L
IMX
mM-
%3
7F*
f °
no*
Jt-L
%
_5_5_
T7
X5r
&7
&'h
9 7
j$T*
4^.
V-
T-i-m
Q«3
by
TOTAL
AVERAGE
COWWTS
TRWk
-------
«>
B5&-3
»*Te SuE533a
IjMVLIMG LOCATION
teURCE J.Oi ,
SUSS FIELD DATA
Oin%,A— S
m* MW JZ _,
»w«tw i*** frtjgto.£rs
•nMtiit tn«HM»u»t jf
m*o*et*ic wiKunt l.'Q. IX
static messuk, (p.*** * C ** o
MLTC* AOWItls) /9g
mobc tewtit
MNT7LE 1.0
ABtUKft MftllTURt* I
X*0-2 ffiDU.1 «MK*
mn* box now?"
WTM a*.
C FACTO*
*»»» —
P7/^V
noiE HEtrti sums ,
0*t* SCTTIM - -
Atrmwee a*
5^-T /r%
Ch*&
OTftHTS
TtAWiSE
WHAT
KUHiEA
ciocir tip*
^^.(25 vm clock)
#^s
-3
«£<$
%s
O
r
ftR37
17o,/o
#3,
8"?
/o3
7?
6
V/
57$ S<
.V
>
)l /*s
/
\
/
V
\
>
3i.n
m
,'
TQTHL
•
•
•
•
•
m
•
m
•
m
•
•
AVEHA6E
•
•
•
•
•
m
#
m
•
• .
mm4MM#s*
IHW/.-••.
-------
7'W
t/ss-OAtodsZ
PUMIf -
^
*""*¦ rnmmmmamB*^M—nmi Tfo jtj ' Jf —
impum ioc^mi Cintk. J
towcc I.n. B»0~ *7
RiiR f E R j wj1 ^ ~~ s w
onmrm fri t* (it'JfQ (Q%
M«1EKT TtWfMTWf ' ~7G
BJtraxlTflC «E55U»t
itith rmssuaf,
HLTCT «t*«€R(sS
S * S S FIELD BUT*
mom lemtm mrrrt
mailt I.O.
^ 55 iMm$
ASSUMED MOISTURE* I.
w-2 mm.t wiwe*.
I»T|H BO* HUWBEB •—
«m* Alt. »
c rise TOR ——~
_ovem ttmmtd
F*0« m*1IR S£TTI N<6
\
i
V?
H^o^r
7 7
fro
k>
7?
c
K/
193.9$
*Y
f€>
•/£¦»"
6S
7V
•'¦-• ..
€
5?
¥T7.9S
,y
¦
*
to
IS
7i
fa
rc
So ft it€J
7?
9t°
Z\.
<4*7
ii * *
R
5?
?y
zs
77 3
...
t9
3*1
9e la
• t
* t
Ko
Z£
<&7
?
£o 4>,&
• t
*7 f
fo
ZS
^7
7$
|
¦*
*
/
-
it. /r
• 3
f
»
- *.
*¦ it.. -
i
TOTAL
•
•
•
•
•
•
m
m
•
•
•
•
AVERAGE
m
•
•
•
•
m
0 :
•
•
•
i,
¥
% >
i .
*. 1
"%4fc~ '
7WWH
-------
S*SS FIELD DATA
sampling uxat
source r.D
RUN RW«ER
IH»E*ATO» ______
AWtm TfMPE**TUR€
BAROMETRIC PRESSURE —
STATIC PRESSURE, (P*).
flLTfR *U*ER<$)
«»! Lt*6Tn mi type
nomt i.d.
1
I© i
1CMEWTJC Of THAVtUSt POIMT LAYOUT
> AND RECORS ALL DATA i¥f*T MIWTII
ASSUMED MOISTURE, X,
XAB-2 WHILE RUMMER.
METER »0X NUN8CD -
METER AM.
C FACTO*
_OYI* *W*Efc_
P*OK HEATlA SETTIWG ,
over stums
nn9i.nct a«
Ao
No £<,* ^
-ra/r TfPsf/rJ
COKNTS
TRAVERSE
POINT
NUNiER
^v, CLOCK TIME „
~* clock)
SWPL1M-
Tint,MIR
«A5 METER READING
(¥*),rr3
VELOCITY
tcp^f r?. kjo
OR1MCE PRESSURE
BlFFfREtiTfAL
k^yfn H?0
STACK
TEMPERATURE
(TS>,°F
DRY 6*SJ*TfR _>
TJJIRFRATURt ^
PUMP
VACUUM
IN My
1
ii *"!?)
e
tnpiMtt
TEMPERATURE
®F
<;«J
90MHKT
TRAP
TEMPERATURE
n
PiflW
T*MPE»AT«(I«
"F
IRLET
Ct_ >«*
"in
OUTLET
^"our'V
BE*!RED
ACTUAL
O
iW
Q*l,aQ?
h°
f,£>
&
97
2
i*h
i, D
/1 £}
t3
§rZ-
7^-
4/
4
Mhsr
K-4,%0
AO
Jt
ft-
W,& f
ffD
Sr*>
no
€*,
N
n¥C
%$>$(, t
ftp
t,t>
q?
PI
c?
/&t-
A«T?
(,o
l^o
P7
-y-2-
/o7
4<£,
A?//
isn^
Le>
/*&
* t'
r?
9$
l*>("
J*jm
m7
t'°
/fO
ff-L
f2-
1 /n
f W f
\
*
f
\
/
(
/$?.m
hO
V
)
mm
m
•
m
m
•
m
m
•
•
•
m
•
mmt
m
m
m
•
m
•
#
m
m
•
TRW/f
-------
U,5,5t%
A' 7
g5o-y
mwT = ~._i
Mfl 7'
MWUIB LOCATION
SOWCI IiB,
HUM
c«*ator wfv
SASS F I £ t 0 BIT*
¦' * y
JMtfNT TEMPERATURE
iARQMETRIC PRfSSWf - " —_
STATIC PRESIUAE,
fltrtrsLj'&L
no»C LEM6TH M!» TYPE
MOZXLE I.0. — 1 f
ASSUMC0 MOISTURE, I
XAB-? POODLE NUHSCR
METER IOX KUMBE*
METER
C FACTOR ~ r""~
f ' $3
y y n»m mraEK_
asei
WOK Hf^TfR SITTtWS .
ovfN scttin*
*E*E«€*Ct a» — ""*
SCHEMATIC Of TRAVERSE PO!*T UkTOUT
*a*s/T/ /*i
[OWEflTS
TfAVtHSf
POINT
mmi*
\ CLOCK TWf ,
OT ™ cioc«>
MNPlim.
tinman
O \
6AS METE* RtAOfHS
Vo" ^
VELOCITY
, HEAO M _
&pshk>H29
ORIFICE PRESSURE
DIFFERENTIAL
fed), IN HjO
STACK
TEMPERATURE
OUT 6AS METER
TEMPERATURE
m»v>
vacnun
IN Hj
Tf vyi
°F
INMNtCR
TEMPERATURE
«F
S0K9CNT
TRAP
TEMP|RATl*l
MOIt
TCMRIRATUKE
9f
IRL6T
(T,. )QF
n1*
OUTLET
DESIRED
ACTUAL
7
/<£
?5
77
//s"
Do
V
?®
i/Z-1?-
%
lo€>
loe>
}
-<
zV
tfxsfb
*©5
77
n
z?
to
1/1
'I
/
-------
ftWv. It
llss
Am —
IMS FUli PATH
MflK iw?«
*em« i.t .
SW*U»fi lOCj^fCW
•MlftCt I.t. '
M «!»¦•£* ,
CWIT^
*»»C*t Tt«PF*AH*€ .
«t*t:c *«niw»i, fPf>w
#lltt* *iP*€*UJ ,
m
-*a~—:
«cti-«t : ffi.....
mb-2 vei&'it lo-ie*.
dtp Kl 1k"f!« .
i*ti«
« *ACfO« - - *—
•SJ2*
fi*Tfe*f I ooe^ /I -/ tomm «jr pei*t utrwr
* mm mb www «u ivmy , mi
mil «iutm *m;*i
mi tmm •
UriNMCf /»»
NO Hc/ircp
-TtfAtrJ
tlAftllt
*01 *T
NU4KK
.a.<*« tm ,
m ciact)
wwuw
-------
<$'
*JW
% '
¦¦¦¦< ";•
f-'
• 4
%¦
5 A S S F1ELB D«t«
¦i.
*0»t LtlttTH MR) TYFf A
W12LI 1.9.
^5L
ABSENT Tt«PE«ATU*f
iMOHCmiC PRESSURE
itntic memure* (r«)* «S
PJITER NlMBER(l)
AS$W« N91STURE, X.
xao-2 mmu nukbch:
*TER SO* MRRCR;
meter A»h -
€ FACTOR . -—
MORE HEATER SiTTIM
OVER lETTI — ^ 1 "
REFERENCE a—
KttEWme Of TRAVERSE POINT UTOUT
READ AM) RECOR& AU. 6*TA EVERY _ , M1RUTES
.DC* Tiff „
m« eioc*)
SNPUM-
TIHE,MIR^
•3s*
j 1
_ pa_
10TM.
WE RASE
/e_
^SL
-2
££-
~7
./, 5 *7
M3&
JtS.
31 fr?S
_55:
/7<^
05
/s
H2Q
OAS MET!* REA01R6
id
3i%X
1ML
WMSl
¥/$#o
¥*>2 ,0&
M3i
w« r?o
y?s,z
<31. o 0
T-f?. VI-T
VfLOCfTV
fe^«,*20
./
• O
/*€>
f.o
LsSL.
/>e>
// o
t
/,€>
ft&
(tC>
L*.
f ,0
10-
WtrrCE RRESSURE
DIFFERENTIAL
(OH), lit H?0
DESIRED
ACTUAL
STACK
TfJWEAATUHE
¦
MV Mt METER
TEMPERATURE
cv **
ouuit
(T*out^
^z
iQ.
j2A
3X.
:5jL
21
J*
7?
12
0"
il
(o/
_&L
¥
go
-s£2
4. '•
JK. y
gl
«3
gy
m
A
N9-'
' _,>7, ¦
~T/?/*rr£
IS
JL
Ji
OVER
TEMPERATURE
go
J2l
9C *<2,.
ZL
tjL
¥
1
£
Jx
twimcR
TE»f*ATUP«
3S
/. ?./
x-
/ V
&£>,
4r
r
Jd.
4y
4£_
63
& Zd
fORlEWT
TRAP
Tt*f|MYUiE
MIOif
Tif^ERATURt
• V
V
r
I
t-
COWtKTS
rnir^
-------
¦ -§W Number
Simple location
SAMPLE IDENTIFICATION LCK5
Dua
Wtfri
Qo/lei rt>£
-Cow tew t s S^Mf/e.
Comment«
H
rw-i- fa
11 »/
m.
Pgoflfc--Pl2kcftt^2->
//
Ht9
M.
/*
*/
2fc5T~
-Mtlfij/'. A*r
^^•^^mfmrnm^mmtrnrnmhmBhmbW
//
ir4/i^'fl ^«<«b.e
4££-
-«Tl _
vkhJ
vA
fopitd* Wti a/t_
^SttSpScM
IttP-l- P/t
/ 1
UJm-Q^U
>
d t~v
I
r
r 1 7 0
-------
SAHfLtT
Number
B&P^3r~P£
tl
3- Pi-
SAMPLE IDENTIFICATION LOG
1ZAP nnr&r-
Sampl e Location Ron ~baM> Contents
JJL
FAjjbk,
n
f j
2 A
UM
Co/'?'1
Comment;
vX
fey
H -1 - %E
u
Mb-1
~7~
#'
5Z
f#
ki&fkJp. !Lv^i&Ael>Liit^ V
fdk mmI
If
, lZ-4jjd$%tCm
h - j
pf
I
fl
*y
if
J<£
If
ft — Cf~ ^ ct>
tt *. Cf
j fi^b-X (ls^4s*r^
(lieu tuic Ce^^*u>dk
u
If
Kka-^kJk
»/
ft
it
y
-------
-§PA Number
%
Sample location
1-1
£ IDENTIFICATION LOG .
S0 7^r^~ ^ ^
Run
Co/'«< Ted
i
Contents
JkIL
Comment!
n
m
VMsv-S'QHc
>£<&
M.
if -x-i/fi
ft
-S-/M-
(jtvw tnA*^
Mat
SI
21.
I t
.VB
¦R
E
¥
//
K
Xyysriit (L«tan^
HjL
T
ET7"
//
Y*
££A
if
ft ft yf/^sc*
~lo-
- " ^ ' i/6
/'.¦
• < -Sc
// IWt,
At
/1
if
fobyyy^u^-
ff
if
Pmbt'l'C"
r
V
K
~Jfc
/ i
Aw\*jL
11
<*-PF
ff
1L
/
(Ir^JhfiiS L-swiaj3 G**Jbv*ut.Zc^~
fi -u-Qrgj)
ff
«
IT
III
t(
ft '> /&**** Ujfi£t*ju>
-Li-
ft *
/3*>TV\/-rJLS
*/
JL
i£i£
L-vds- 0? ¥
-*£r
f ^ CP /Qcdst^tsvei
-------
StHfLtT
-fM Nvnber
Mh. .. |
M*AM &*+>u MM ,
N*«f Ptctevr
/
TV^^&k'
7f ,"3 / , VjJrr
»-v7- (°&-
" -37- J<9
/i
11
ft
Li£i<€*u> MiX
X"Q*rtJ&r\4ij6c>
iz.
7
h -.37-
„ -37. £T/?
„ 3/- ^
//
He
tt - /!/&i
/ZtyjiVLs
*>
tt
/
u^jl^ au ci
ft
IlSSL
„ - 7^> -?/r
'/
« -it-iK
i/f- ii>
tt
kb&dt —~ ..- ,
AA^Mitdlri^ AfatsL
4
___
//
//
ttese~*>r~
n
JL
It
Nr**~
ZL
_£L
QAaaastJL
1*ȣ.
/- SlA-C. Crt
/$?V&L Qbf A^faL.
it-
<7
'/
d?»ZI
^ 1 &VU4^ &CA&L,
a - 37 A-Qtth
U -> 3>/f~ &T4
iL
3?4~cX&c
it
'totUL:-37
r"J
r^hs-A
-------
AMfLif
-§PA Number
ft fj
SAMPLE IDENTIFICATION LOCI '
*Saiw*r location 9m -Con ten ts fM-
(lotlet
Oe*ir
sjs.
\J
Comment!
li
n
I- V6
h
n
u,
jtvu—
~
I - ^C.
t r
S
/<
-t - PS
i~PTa>
tj_
h_m
it
I t
h
froftto fc*Ah*J€>&/2
//
~
Xj #
/f "
—
/(
/ -/*n
•«
iL
-
/ t
/ /
£
fa /
»f
!1
¦*Kte.*+L4 h-*
xT^TT
isflfe.
it
!-£T&
'f ~ f ~ SG
fore
*7*£L o ^ 7~^&
/f
'ftgh
»f
j!
Pa^l- /t
tf ]&jtt« Co/Zee Ve ) & *
' L
im.
fr
/^nOr
rf£*=.
/fLe^j&rut—•
I# v/
fe/5
M
< /
/ c
//
V
t> y
>wA±£~Z_
ft
*S
T&-1 - to
.-fr- /¦
i»
i»
fij+b- y
J-L
&CL
k
Cfaidhvujdfx^
h '' /l^IL.*.
Af*fo
MIL
mm- * '*& '¦^ X.
GmJ^%AJr~M
i3 ^ '
p4 y
u -a-grgj>
* '#
/ #
/i
#<
/^ *•
/4?c €TZaJz.
wa y
Tti% *''
^)*^r- ftUslA. AA-r^SiJw
A/d
-------
>
.'.V
fl
-fcM Number
ibi
«NPtf IDENTIFICATION LOS
*gS<2-72n£T-3j<}.
Sample Location Runl&m. Contentsf.fapjA
UL
Oe/vrfiPr AteCj*.
Comment!
Co//«u
it
CMCme*
s
* -3- US
(b ihrn^r\£L
bAetG^
JL
~7~
// - 3- //£
Ifog- 3- /gfl
JZ.
~T
H
n
^fkeeltmP i,Ad7
ft
iMl
!<-%- TP
ft
//
h
JL
-CzO>
it
(Ioms]^ TMf -&£A
ti
ft
ii &Ja)sE~ $C£&n2.
~
zf:
n -3-C-XB
//
t(
JL
l/
if
— OytKiXoa I
r
t(
Ck^K f Cock/
^Uvg^" Ao&
it -
PT4
# *
XX
»» 4^1*5
fl
z*fz
r
Btf/ki,-4-
lL
< -v- t/
ff
B$o - 4 - PLA
JL
/t
/
4 - PrB
4- ¥p
H
ft it
/
//
jUL
l.l«M|«ni II Mill, I 1— , nil ¦!¦ IJ.I1M-H II ¦!-.
Q/*U2*+(K'l£*~
/ * //
y/
4- £gp
H
If
* -4- cm
n
/
tt
i/
£-yy*^f#iM~
>,-
-------
TRW
CLIENT
TYPE
REMARKS:
ACCOUNTABILITY LOG
LOCATION
SAMPLE(S) Pstyk- Vl+lf
]?i 3
DATE/TIME
MASTER
CONTROL #
ACTIVITY
INITIALS
YA M
/
s f
s-A/iy
>*9 '• " C#tL~&&[A£
f/i/f-
/' '' " /}%
P^/V
A~
- - - Os&Aa* AW
3 i/'/M
&
A//" /tfL.
W/to
&
U 9 A *r~
vi // " /< " r
7
!' It " /{ 7 A "1
$/
-------
SAMPLE IDENTIFICATION LOG
5»n tk* -
• EPA'Number Samole Location ftwr Contents
m
~
1} 9/
Ct>llec,~i
Comments
jgis
¦Fa£&:(i /
G j4
I'
(5 M-
JL
"0^ j6
0
0
2^Z
£ij£.
)/
AA
JL
0
Q fi
tt
A&
imL t
OA...
II -X/Cg
0
iEl
!/
6#
hA epj
^ (Jj&vxa
^
Qj&jfoAP-c —¦ lJ $C-B
£f&u,'p
5&c,
II
Y6£>
~
I 1
fjr**^~verK> /Jy-^jjLz
tl
VPK6
l/
jijSA
i/
»/ '' m#£-<
tt
i >
* t
¦fer^
|,UJ
1>V
/
It
9*. S
V^W
¥ " '(
ft
I>
7
~L-
It
(r> {f
&-fTAB-l
D *
tfr
B&-1
~1-
»<
n
«...
r/
n
TmcA
n
7. /
UJ
b
i p-^
u -X
(I
H
1 ~
.,-trg
-------
>AMfLiT
Number
Mf- s-- Pi
t i
sample mmmmm log
ft/tP-
Sample Location Runft&Tjr'V Contents
Co//ect£S
-------
-fiPA Number
, ^SAMPLE IDENTIFICATION LOG , '
BSOTmri ^ "M
Sample location Runl>#Zr Contents
Co//f I
-------
WMfLif
~fePA Number
Sample Location
{f)f)0 >£/i/j tl
e
RunPftrzr
Contents
^irkf, All^l 0w-vO^ A
If 7/" &
Comment!
C o(te<-rcii
: Sn-Sfifi-P:TA
U - ./ -/frft
//"*>*( «>
'gg/g-a/g.
-ti-
7^
//
~£zo>
m. C*Jh*+*£?
E2
'
r/Kfl
/!
It
CL/jIcZi. ;
•Ci£&
ti
/*
'' ^e
L/>1rC.
1/
" dc/cj
•£ •S*b * & 94^9
?X
21
//
KAfcxfityu? jfiyt,
9)s£zr iSvi^tl ftcj
Z&-
t'tAJl
'MP-sne-PA
JJ-
tt
*( T/-
((
if
tt
-j1
k
h
X^uL'C,f^fnu^
m
a
!L
Ml
/»
]_!_
ft
M_ i
'wk
J
-------
APPENDIX D
TEST LOG
-------
VIII FIELD TEST SCHEDULE
SATURDAY 7/29
SUNDAY 7/30
MONDAY 7/31
TUESDAY 8/1
WEDNESDAY 8/2
THURSDAY 8/3
FRIDAY 8/4
Personnel
Hartman
Moore
McReynolds
Henry
Carpenter
Wagoner
Hartman, McReynolds fly to Pittsburg. Henry and Carpenter
drive to Pittsburg. Arrive on site approximately 2:00PM
and begin set up of equipment.
Set up continues, blank clean up on trains and prep for
actual testing. Sunday evening Moore and Wagoner arrive
from West Coast.
A. M. Safety meeting, P. M. testing preparation
Test A. M. clean up, test P. M. clean up (pre-test runs)
Test A. M. clean up, test P. M. clean up
Test A. M. clean up, test P. M. clean up
Insure all samples are taken and catalogued, pack up and
go home.
Team Leader, supervisor, trouble shooter
Clean up manager, sample accountability, GC's
Team members-testing, clean up, sample recovery, etc.
-------
APPENDIX E
PROJECT PARTICIPANTS
-------
PROJECT PARTICIPANTS
Names
Company
Purpose
Gene Riley
EPA, Durham
Project Coordinator
Roy Neulight
EPA, Durham
Observe Test
Mike Hartman
TRW
Testing Team Leader
Dave Moor
TRW
Testing
Jim McReynolds
TRW
Testing
Gary Henry
TRW
Testing
Clay Carpenter
TRW
Testing
Dan Wagoner
TRW
Testing
Tyronne Smith
TRW
Testing
-------
(
TRW
CLIENT
TYPE
REMARKS
ACCOUNTABILITY LOG
LOCATION
SAMPLE(S) (32M>y\
DATE/TIME
W5TCK
CONTROL t
ACTIVITY
INITIALS
/
3 Jf Clrkjn^ flsx&f A~
'' '* " $A*er\AP
V/3/^
3
/< '' " PfcJc&s
?/i/^
A
» " " AU-
3 i/y
nA
1
/ /
-
*"
A}*&-'
*-^5^ (hfaiJLtJb/AAiA Ue*d"fz,
*M> £~i- C>
thanspomation and environmental operations of trw inc.
McllAN OFFICE' T6O0 COLSHIRE DRIVE, McLEAN, VIRGINIA 22101 1703) 893-2000
-------
( TRWsystems (
AVOID VERBAL ORDERS
jq iw«- *®®"» DATE
"TirudxM ^-1 O&trtw.* -»•—• Wdf. too** EXT.
FROM
SUBJECT
g\.. «*»*<-. *4^C,
\ *» . ,t .* /itn «'\ «
3j8» "• '
VvCtL
<1 ' - iwt) SH •* k V '» * B
-------
SHIPPER:
Battelle Memorial Institute
COLUMBUS LABORATORIES
505 KING AVENUE
COLUMBUS, OHIO 43201
SHIPPING MEMO
AREA CODE 614 PHONE 424 - 6424
SHIPPER'S k| , nn q
NUMBER N 4009
SHIP TO
/%" / (
ATTENTION OF
STREET ' • " *'
j ; /t
CITY / '
STATE /
JC- ZIP CODE
REFER TO OUR
PURCHASE ORDER NO.
BY WAY OF
^PREPAID
~ COLLECT ~ LETTER ENCLOSED
QUANTITY
DESCRIPTION
INVENTORY NUMBER
i
/ -
'V ' / •
_ _ i __
J
IS THE j
ABOVE SUBSTANCE HAZARDOUS?
YES ^ KO m
OATE
SHIPMENT MADE FOR
O Retti/n and Credit
irs
Q^djurt'merit
~ Replacement
D Other
REMARKS:
REFER TO PHONE CALL BY:
DATE
LETTER BY:
OATE
FREIGHT CARRIER
PRO, NO,
AMOUNT
OATE SENT TO BUSINESS OFFICE
FOR PAYMENT
NUMBER OF PACKAGES
CARTONS
BOXES
CRATES.,
OTHER
WEIGHT
DATE OF SHIPMENT
Shi1?ingTlIrk~—
PACKING LIST
-------
m 3 ~*P S
f £syy»J2J JLeJL —
£», i(Ji c-d*.
J J *jy * 0^"^
3. t- " ~l /" 2f
f, fj*t*> cryy "0%£^k ;CT s*£j/ ysm^"
A* & j^f ^pJ^pj^f
?-
/> /. / , A ^ >'"
.. .--J&
I, J at M*u^ ^ ^<3
y
c
$$~€kJL
/uJid-XL *• /yi-tryyyj^ gry^y^
f> /! ' f
J-'&^JL. J"""1 C^G-c "*-¦
1 / J '* /* $
AjY^M* jc.U'k- ~" /YU-KyK jk & /t A. J*CJi
$Artiy^^xA Z^dtZ-O.. J& aJ a«"2<^. (jusUW Qyr^
fj^r-%/^ 4K/~*V\, P t> ^V, lO/d a£k S'Z
-------
$ —/ -
TKtjX^ -S. -5". <3>~XZ-. .
g & %j£. ^
^ ' <2 ^ Cll / O
£&i-€r\r \^&AS-€>*L^^
45 S- A MSA &S*
kSA ~~ ^ j d
-------
JL ¦¦¦ ^
€t
i- "Ti-^r i {-HZ cd**s^Slc-~ 0^*e<'
**"*^
a., ,/.
-------
C#rd ¦
%~3~ •>?
I
~v ' (~^pr [^rk^LdtSya
b - <>i7~/p^~** X^A
VcM«r dU^& #>-»*'r sry>.
T - C^/i >/a//L c/mA *£ &s*
7M^7^ry^
P' - A- JL-& /^-jUtfL ?*&•
A - -trJn^ 7***- "»
-------
ANALYSIS OF POLYNUCLEAR AROMATIC HYDROCARBONS FROM COKE OVER EFFLUENTS
This paper is a report on the Analysis of Polynuclear Aromatic
Hydrocarbons From Coke Oven Effluents. The program was conducted by TRW
for the Environmental Protection Agency, Emission Measurement Branch,
Research Triangle Park, North Carolina under Contract Number EPA
68-02-2812. Four samples taken from a coke oven at Republic Steel Cor-
poration in Gadsden, Alabama were used for methods development in poly-
nuclear aromatic hydrocarbon determination,
Polynuclear aromatic hydrocarbons (PAH), also referred to as
polycyclic organic matter (POM), are suspected of being serious health
hazards since some of the individual compounds are known carcinogens.
This class of compounds condense on particulate matter and can be inhaled
into the lungs or contacted with the skin. When coal is pyrolyzed by a
burning or coking process, significant amounts of PAHs are produced. In
the burning process most of the organic material is destroyed through
oxidation, producting water and carbon dioxide. In the coking process
however, significant amounts of organics are evolved and emitted to the
atmosphere. Many techniques exist for the determination of polynuclear
aromatic hydrocarbons. Specific compound analysis for PAHs of particular
interest or potency have been developed and are generally better than survey
analysis techniques. As an example, the determination of benzo(a)pyrene
can be accomplished quickly and accurately by thin layer chromatography
(TLC) with quantitation using variable wavelength fluorescence, a method
1
developed by the EPA . Other specific PAHs have been determined by liquid
chromatography using UV and/or fluroescence detection.
For general purpose determination of PAHs in complex mixtures the
use of gas chromatography-mass spectrometry is unexcelled. The gas chromato-
graph Is used to separate the complex mixture into individual component
peaks and the mass spectrometer is used as a detector for both qualitative
Identification of the PAH and for quantitative determination. In simple
cases where only a few PAHs are present, the use of packed gas chromatographic
""New Benzo(a)pyrene Analytical Method; EPA EMSL ACB SFMCS RTP N.C.:
Don Swanson et.al. (no date).
-1-
-------
columns are recommended. Packed columns are generally easier to use, re-
quire a shorter time for analysis, and are cheaper. When highly complex
mixtures of PAHs are present or significant interferences occur, the use
of capillary columns becomes necessary. Capillary column selection is
usually dependent on the volatility and polarity of the PAHs to be deter-
mi ned.
PAHs typically show very strong molecular ions (the mass representa-
tive of molecular weight) in their mass spectra because of the stability of
the aromatic system. The strong molecular ion allows for a very simple
identification of molecular weight even in complex mixtures. PAHs produce
very sensitive spectra when ionized in a mass spectrometer and can be
identified in a complex mixture quite easily. The disadvantage of this
strong molecular ion production is that isomeric PAHs produce spectra which
are virtually identical. The mass spectrometer is a rather poor device for
distinguishing isomers since once ionized the compound will seek its most
thermodynamically stable form. Since isomeric PAHs produce similar or
identical mass spectra the determination of structure is accomplished by
comparison of GC retention time using standards.
The major limitation of the gas chromatograph is the volatility of
compounds to be analyzed. In order to be determined, PAHs must produce
good chromatographic peaks at temperatures below 300°C. Above 300°C even
the most stable GC column liquid phases produce high background in the
mass spectrometer. This GC temperature limitation means that high molecular
weight PAHs (above MW=300) cannot be reliably determined by this technique.
A limited amount of work has been done in the determination of high
molecular weight PAHs using 1iquid chromatography. With a 1iquid chromato-
graph, the need for volatility does not exist and materials of virtually
any molecular weight can be determined. With the proper selection of
columns and the incorporation of a variable wavelength excitation and
detection fluorometer, PAHs can be determined with accuracy. Chromatographic
separation is not always required provided the excitation and detection wave-
length can be selected specifically for PAHs of interest. An example of a
liquid chromatographic determination of polynuclear aromatic hydrocarbons
will be presented.
-2-
-------
GC/MS RESULTS FROM COKE OVEN SAMPLES
(Concentration (mg/ml)
Compound
Molecular
Height
367
371
366
364
Comments
Naphthalene
128
4.2
4.6
6.8
0.34
Fluoranthene
202
1.3
4.2
2.9
0.075
Unknown
202
0.17
0.55
0.55
T
Pyrene
202
0.9
3.0
1.8
T
Chrysene
Triphenylene
228
228
0.3
1.2
0.8
0.028
Chrysene/T rlpheny-
lene unresolved
Unknown
228
0.007
0.09
0.1
T
Benz (a} anthracene
228
0.30
1.0
0.8
0.024
•Benzo (c) phenanthrene
228
0.044
0.14
0.18
T
RRT used for ID
Benzo (a) pyrene
252
0.24
0.7
0.65
0.02
Benzo (e) pyrene
252
0.12
0.3
0.38
0.01
Benzofluoranthene
252
0.47
1.7
1.2
0.043
Unknown
252
0.07
0.27
0.24
T
•Benz (j) aceanthrylene
252
.
-
-
-
No RRT to confirm
Perylene
252
0.14
0.17
0.27
ND
•7,12-Dlmethylbenz (a) anthracene
256
ND
ND
ND
ND
MS should be unique
Mbenzo (c, g) carbazole
267
NO
ND
ND
ND
*3-Methylcholanthrene
268
ND
ND
ND
ND
MS should be unique
Indeno (1,2, 3-cd) pyrene
276
0.10
0.22
0.42
T
Unknown
276
0.055
0.14
0.19
T
Unknown
276
0.01
0.055
0.05
ND
~Dlbenzo (a, h) anthracene
278
0.Q55
0.16
0.23
ND
Have 1, 2, 3, 4 and
*D1benzo (a, j) anthracene
278
0.055
0.80
0.12
ND
1» 2, 5, 6 Standards
Unknown
278
0.018
0.022
0.048
ND
•Dlbenz acrldlne
279
ND
«D
ND
ND
MS unique
•Olbenzo (a, h) pyrene
302
0.12
$
•Otbenzo (a, 1} pyrene
302
0.36
0.50
ND
Unresolved
•Standard not available (Identification based on published RRT and MS)
ND ¦ Not detected < 0.005 mg/ml
T • Trace < .01 Mg/ml but detected
$
-------
1W5.0-1
RECONSTRUCTED GC FROM 60 METER QV-17 GLASS CAPILLARY COLUMN
GC/MS (SAMPLE 367)
2252M.
-------
10^3H DRAFT
$>8-Of *-/J
SOURCE TEST AT U.S. STEEL
CLAIRTON COKE OVENS
CLAIRTON, PENNSYLVANIA
by
M. W. HARTMAN
Contract No. 68-02-2812
Assignment No. 13
EPA Technical Manager: Gene Riley
Prepared for:
Emission Standards and Engineering Division
Emission Measurements Branch
U. S. Environmental Protection Agency
Research Triangle Park, NC 27711
TRW
ENVIRONMENTAL ENGINEERING DIVISION
3200 E. Chapel Hill Rd./Nelson Hwy.
P.O. Box 13000
Research Triangle Park, NC 27709
rough draft
-------
ENVIRONMENTAL ENGINEERING DIVISION
k &
1423.TEE.80.046
August 15, 1980
Mr. J. £. McCarley
Emission Measurement Branch
ESED, Mail Drop 13
Research Triangle Park, NC 27711
O
/
L-^fX 1
Dear Mr. McCarley: (J
Enclosed are four copies of the draft report from the source test
performed at U. S. Steels, Clairton, Pennsylvania Plant, under contract
number 68-02-2812 work assignment 23. A copy of this report has been
sent to Mr. Roy Neulicht of the Test Support Section for his review. If
there are any questions please do not hesitate to call me.
Sincerely, r ,
Wus kA-t- Foi^
"1 it ev\
Tony E,~Eggleston, Manager
Test and Evaluation
TEE/dej
Enclosures
cc: Roy Neulicht w/enclosures
Gene Riley
Linda Harmon
Progress Center
3200 £. Chapel Hill Fid, /Nelson Hwy.
P.O. Box 13000
Research Triangle Park, N.C. 27709 {919)541-9100
-------
SOURCE TEST AT U.S. STEEL
CLAIRTON COKE OVENS
CLAIRTON, PENNSYLVANIA
by
M. W. HARTMAN
Contract No. 68-02-2812
Assignment No. 23
EPA Technical Manager: Gene Riley
Prepared for:
U. S. Environmental Protection Age
Emission Standards and Engineering Divi
Emission Measurements Branch
Research Triangle Park, NC 27711
TRW Environmental Engineering Division
3200 E. Chapel Hill Rd./Nelson Hwy.
P. 0. Box 13000
Research Triangle Park, NC 27709
w A?.
t'V
we*
~V
*c?r'
— €~
-------
PREPARATION OF BAP/POM AND BSO SAMPLES
CLAIRTON COKE WORKS
The attached schedule outlines the specific details of how each
sample collected at the Clairton Coke Works is to be prepared and
split for analysis. The schedule is detailed as follows:
I. Splitting nozzle/vent samples.
II. Combining nozzle/probe rinse samples for BAP.
III.BAP sample preparation and splitting.
IV. Combining BAP sample fractions.
V. Re-extraction of filter and resin with cyclohexane.
VI. Combining BSO probe/nozzle samples.
VII.Splitting BSO sample fractions.
VIII.List of samples to be sent to EPA for TLC analysis.
IX. List of samples to be sent to EPA for transmittal to U.S. Steel Corp.
X. List of samples for GC/MS analysis.
XI. List of samples for BSO analysis.
XII.List of samples to be retained for possible analysis at a future date.
Notes:
Prior to conducting this work run blank analysis on MeCL^cyclohexane,
and benzene to be used in laboratory to assure contamination is not present.
1. Assure that splitting of the samples is done accurately to the
indicated fractions since split samples will be recombined before analysis
is conducted.
2. Assure that samples are homogeneous prior to splitting. Use
ultrasonic agitation if necessary.
-------
3. Prepare POM/BAP samples according to procedures outlined in
the draft test method for BAP except that methylene chloride shall be
used instead of cyclohexane (filter and solid resin extraction).
4. Prepare and analyze BSO samples according to procedures
outlined in the draft test method for benzene soluble organics.
5. Extract filter and resin according to procedures established
in the BAP method, paragraph 4.3, except that methylene chloride, in
lieu of cyclohexane, is to be used. Split the methylene chloride
extract; retain the filter and solid resin for re-extraction with
cyclohexane according to the procedures of paragraph 4.3 of the BAP
method.
6. Extract the condensate according to the extraction procedures
of paragraph 4.3.3. of the BSO test method substituting cyclohexane
for benzene. (Do not filter or bring to dryness).
7. Evaporate the sample to dryness and then redissolve the sample
residue*benzene. Combine this benzene solution as indicated.
-------
©
1
p 1 '"t"* * Aj 6 i
r * V
A— P- =v
> •>' ¦• I -i
/:. />
/- w¦¦
V
- /• /V - ¦' ¦'
A/^
/•"' /*/ /-' ' ~ . '¦ A'
/• • 7-.^'-.
I '
(5
t-
£
•Y-
>'•
V- • f ! '¦ y.
I /; / V "*'
/Jr\
I : f~ /
vr -
/. f>:C
I
i! t'
- A'",*
/ .vU,»-;; ~ \,
? •: f.
/
-------
•:> f> I ' + t1 ^ o 1 * U I \l f All* S A r • " p I ¦
Vc- .:'
AAeU$ (1 m>o-3-vp
a ,
' 0 /»» '/• >y» - 7 - V mc
A,;
»4wt£-(
^ 0 rJ l • ~
/yv -¦ - >
:•'
r ',
r <, ••
fj.np- -7 - \r<:: -
B>c. 3.- vt.
/3/)/ 7 •¦¦¦/-¦
r,
v..
/;/'/' - ..:; V A" '-A
- 3 - /~rw c -G. ('/>»
/•" '• ,.•; ' - '--c
. ¦, 'y-Y-'MC'* %
ftp - ? - c -e: Vy )
/• •-. « 7 ^VVv'c-r
-------
€/-f- NIC
/ r: f
J - /;v?
H ft r • ' ' l V'
(•> r • - / / :
¦fj fi/'i
•. .> i
I* f- \
" ¦*?(>
pi:
('-¦ l~ P ~ 1 - A ¦ F fi
(¦ >' - ! < . ,/V !->jCl
-------
,\!C ¦* ?'- , ( '/* )
1/.Vxtp/$- /i y<,.
£/}P'V~mM<1 '(K)
-aJW-/l
A/>P-s-ajP£ ~ A
/2/s, i-s ¦ /vP& - cl
'/&.?¦ :
••f .^4- - -•(--
/3/>p-?m ( 'A ': '
' • " !
1 •' . i - > i
/_J/* '• £"/¦*/.? —4> ; yV ^ '
^>9/)- •r»ti . **? • (' >A ,
i - 1
P/)P~&>~ajPP - P* '/-i f
-/s
'4- !
;|
-------
<> Pi\r ^ ^ -6&P '(u.Jt-, -1 )
S I ^ ' r<*^
> 4 ."->
a '/- r
t -V. i /
t4 i
if; *•/ |
C
>>*v~*^V« Alo l», L*».
/7 - fjpa
jUu
f~ \ l£w
r,
rv //.
F",
m-t
/}$£} - ty fi • A£
(bht- X - ^
/2W 5 - <*v*
/J/vx y--
/§/» ^'- ip
P.
f|-r7« ^
i4**rs.
£ y-fttA r1 iju *1,"/W
$tr fAe T-H-oiti \
j'--i
/up-fc^ -* £
1144»
i
; /$#p~ )¦ M-$
\/}ap- o-M~£
i* : ,
j/3/^ >^- c
/J/iP- 9--/V? - /* _
^/Jp- 7- /V?- /g '
GM-s) */>/?¦ c
ss a f~ ¦ i—^
/S/JP- / -i/V*- - /3 : (
G*t ' / "fr " C, ': ''
2.
, >A/'y.
('^7
?
X
'/z >
^ . :
/?/»P - /- /? \ (f/7\
Sap- / - z3^ - -- c
/£/}£)*- £/ —
/?/>/> - */*+>/'-¦ /i
;
*/-. ~\
'/
/V
-------
/'
'71L
c
K ^ &AP r3 )
S ! flf*<'4>.-f
Ft //i-\
7A/)-2 k
s,
| ^ Aiu »v, ^^ v,\
\£B&- fP
¦ZA-X- £> PP
PA
j--Pr¦ *~rP
> p
/%PP- 7/9-P^
P%' ~e ji ft-* P-X its
f= +-r/v t ,^j it*!, __
s/f/ ,"/"*>
p-z+rn-pp~'fs (A-J!
bp p- .stpp - pp\ # (yj
MP - VP*- /M' ¦ C :' .'£•!
//
/ >
/
/?/?'¦-
PPP Cr-S''- A
P/tp-P ¦P'r- u-
/*? />P • / > - //
S-PP' "t\P<
&?»>• '/ &'¦" c
/?/v> 9^ ' PS -A ¦
/
/g,*^ - 7*! -/^ • <5. ; /*"'
r>/1 Ps -Cj. //j'
i ppp -/-M-A (/A )
%AP~ I - Y/Z. J Esf •+« Kei wj li'L
' M E"Tlv_^..C[ , < : |
} ¦" jSpki'ty 4 y a c 7 «- i/?/V */- Jf/i? - /2 ; '/y
1 (fl< t'A ',0 _ " J ,
i| y -£Y •+*•¦ «<>•» $/$PP~ P P*-' ~ C.. ; /
/?-/^- " Y/l
i
P>fiP'2r Y%
/3 /)p - r2 ~ XP - P { 'Al •
/J?>P- 4 - W -/£ :/y )
P*s*P-A' - '>!>:
w
ppp- "?• yp ~'P) ' 'At
#ftP
yps
•/A ¦¦ C,
-------
r
¦-1
0»/\ P (to tA
O ( i f~"
r . $
// v? - A
——
TAC-2 (2 r-s. /
p - - sr/te
>'7<
P' Cnt-yCf'/!
Mel c r
WP-YrCb
p^p" z\-c,a
-& y? ¦ i t f* ;
M ^ p I *t ¦€' •
t
K
flfT'f
C" / j
/J/> -:v- y* -/) { /z_,
/>W>- f-
v ' - -i ¦
l'>s* - C. ( j
& #P - ~X/(-.
{frfp- &' i & .
/SV5/7- • *¦'/:"- C
'¦- //z '.
¦ >Z , ¦¦"
&#*>- £-/k2- »*y? ('/%.)
Sfir*- • y$-" (s
t2/yx q • x>/?- />.. -/*•- /¦}
«?** V* l''/,/ ' <"-»
¦ (>•
"'/
r v'
V' •/
=''/, \
'/V
/.,
P>Af->-/?4" xc-A i.'/t
l^f».')a - '-A-
li#p V/1 -; "*->
> yex~t\.
-------
fir ^
1
- ¦ < J - £ j
F* 4m.
/0.; , >.v (iA-v
- "f '"!
/f;- .3,',,>< -'¦* C-
5 - r/)
frnr-SM C £)
&Af>-&A-CC>
/3#P~ n-cd
%hP~rn-~t&
\<1. ;/>lSV
0?' ¦¦;¦¦¦ i-M/2
fV% t (^,
&^P - 2L~n}/l
/I*?- 'i-mrt
H/'/¦"¦- >¦/
| f')fi~ ~ •*£/Ai\ - f \
Pr-fs*r
*M\-J: a ( >*c
\"},j 1 ¦{¦', v~t
Mt'tf. %,'h^P <-~ v c 0
\U ,,• • I ¦>
>\teh '. V-Vje [.,i:-j - -i f- *• ' v /.
W f
£''''r: p,\ > i >. z v*? 'f., - ; F" I
&*¦*•* ,:-*#!l'v
TA f>
//
'V
..fj /'• ^s-rvj*
,/t^O
/l/'r; ,5^->»r^4 J
^ o ; S* / 'SLj |
/i^\ btW-ft : /t. •
/2fip- / - ri
/- {*f/< \C
8fiP c|-/WV? -¦/**'
$/h > - 7 y mi • A \
%
/S/b"''- «"*: t*?tl €- ; ¦"'- i
A /y3 - "s* si t/i -ft b' '/¦-, y
SAP - J - A-M /-: j/ ,/y )
/j./' /• ' ~" ' *¦ :
*/- Af'i /} i
fz/K>' ' ' 4 l^p'1
ti/t/?* //v
<"*• /li/'i ¦ /? { '/'g
Sl/f-A" $¦ :-/*£<* ^ 'V
/3^/->- •> ;¦ iftj-c V
/?/»A •;#($- M*l • ^
$/¥* S'fvi ¦ /*-Vv " $ *\v
/-V/v"* '"
-------
i .Cc )
S p i v F -~f > f> >
r, &
!*•/< f-A.i,...
^ I >/
fcAb-G- - ft
i Af . r, - Mt2 - 4
6, • ^ # ¦ C
~ "7- M
-------
-f--
r J-
(I P>P- X "Aft
fiap -i p^- ft
bap -1 ^£- A
BftP - ± - mn~ A
t-,? ?¦ - i - ft • f'-
5* P - z - A^Pi - A
P-i* P - s?- A
rsi* P- X - A
&AP - 2 - /Mrt-A
ft ft A ' ^ - AJ«fc-A
&*p- 3-: ft
P - 3 • x C- A
ft * /- - 3 - A
kftjp V" AJPfc- A
- if- pf -ft
a,a/>- c/- y#-. /\
gj* 0 t^/Vyt- A
t*>r*t>-5~-A/pn- Pi
4
$*">/> ' S - PP - Pi
fV i.ptrtn *><*¦>
V l*i| .-V> £
i> *V.>|Pt f
ftflP -4- *
Bbp- i -yft-
flfiP'-Z - A
JJ*P- fe_ A
q *#>->/- A
q np. ty-
(]ap- s"*" A*
-------
(. r '¦
*> v\ p L E
F < p* t. t*i
<*s »
f" i **- p p+fr itor-*
C r. *«¦¦. U«
f- T' f K
z-i/Lii'h \
(iw ' a ; /Vlfl' ^ ;
ftftP - _£*/!>- Pfc-L
{
$>*P- gpfcPt- A
tifip -s^a-ye-a ;
- gfia-M'ti'
6> ft <5- G /° P ^ ** A i
feA-P-6- .£¦*-A-
&rv#« (o - I
I
(Jft-P- 6 1*1 f* - * j
f7- fsjft - h I
»7« pF"- /\ i
fT "" ft
G»Af>-Srt&-A j
Cr ¦•
0 /\P ~~C+- X" A-
7-
- ft
<5 fVp - f> - A* It* - A
(A ^ #>- -rjft
- ff-a
gr^rt1- } A- ^ $
B^-3* I)a - ik
OA ~Xa
-------
e. en-rp.*- c.(¦ 1 I -1 f o-
fL -4 ,'*J IM» - lA. Cy, ^ w^^t. - &AP
p 1 **R
A- fp*
aftf - .7- P*
a p>p ¦ ;!¦ - t> ""¦
5 |A P - 1/- P r-
J j, £ , *> ' 5 - r
t-'j i^r
"/• r
,-ir-
#3-*'" >"' A>V£ T4'
<;' <)A - ^
fipp- 4-- Ti.
f!> Af - *2, - Xr't
f-- (*• i" ¦ ii ¦ •' /.
5 Kv f ¦• if -
Aj a p • « - - • O'-ti?
P • 5
t'-.; r- rv -
vk
/ k
P( ¦ f |V *Vt f" T
i>kr: r .'\U- ¦
Fv » » '* >'. rv tr/#
,.,••'•* v. . rvu nt f, :,J
ff-f • f V ''< :• ' * * ' ' '!* '.
/ ' , \ i-\, f ^ •
<*, #\-t ;\& ¦,
" if.
¦i ;7f, I ' fj
t 1* j* y el f 1
V>L., r
P t N ! ; S ^.-«<"V\ ^ i V*.
-d#f
f< p • 'i ¦ P F' - f P-
ti "%• Pr- -¦€ U
&*p - 4'.. />p -c p
fi* P-.S Pr ¦ r
6'^'
ft*. „. • j
I- t r • V' #•<"••' ,-i
54/i|. /¦« -
/. , •7/) -r//
j (S ap - i - *0. - c':H
*r *i
&AP - '2. ¦ C II
Ci r> ? - -- /. ii - C t
f^AC - Lf-ni/i -C H
fi i:) P ¦ $" " fist ¦ f &
, r>
YA'~C4-
f- ¦ Jr&Q-ttf-'c
3/->P ¦ ?/* - //?- rtf
-------
Oc»k\L>iaJ lt>k It,' ^ i>ct '. ¦? ' '
\H'-t«
\. ••?./:- fW (.
/ * ,-,i >• i ---4 ¦•", >. r
•/ ,-\. *
l"'-- >••¦- U ;
f r< /*'•''"•
6 So - 3-\rfi
n>io -;3- T^cj
Ciso \T6
fiSo- r / - -r^c
/lso- 4. - N6
fiso -X ~N^(L
iu^-j - Pi a
X - Picfi
K rfiw-f*-X bo~>
- ¦¦¦'¦» 1
6 ^
f^,d~X- Amc
G>so -p - pi& 1
Or)*, !.*•
AJ o -rip' & '7
„.Ot-«rv--( A b«vvt.
/^oif ir/
0/-V £ ... .r, «#)
-l' !*7
if.; r <¦ '''
?$<.-•'• • If
•;: h • /vniC i - ,t4ic
/¦*>
6$t - f _/V^
/SS'o ¦ ¥
- '/r
fijC
;*> - '
^6
>
aj /' i r
C <** K* •< '.J''
6so^3-\r*
a S6 ir
/J S 0 - '2 - P
s
»/°
/Is.o - >'/- A
f:,
/
-------
(W.-t.: i
C»»J . ,
- ./¦
'¦( ¦ i "t
\
jbtv^a i »'V\ iji/v
&st\- sna~/oQ
a -
fy>C« - Cje - Nlfs
fi^s- G ¦ "jnAC-
rk-;€- ' - f'*'' -i
>o - * ,aJ <~i
ft. S -*¦ - f) '
• " i - f'tLt,
1 JSC-
^ me
7;^ • a/ r
» > i '•¦ 1 ' ¦ r - •'»
£S6\~ S'rt£~ fi*
&c>
LiO
¦fi
&sp- '/•
J-^SM ¦ •> A - A
-------
j R-ft r H ; r.
SPLA tu ( a (:
/"* * J-.
-f-jr ( i.. *..3 , ^
po r 1 v /•- aJs ^ /" 4-«
<"¦, ;. ;' :
l \ I ¦ #•!•'• ¦
fir i-yx , -J <5 , f
1, VV^Al
.. n . -
0 € S - . S" * (
1 jti ¦*
T7
»• -p
!l:<: ,J?X
¦¦*- ¦ o
r » p w /-i t
< i
f CVi vi.A 1
C-,
<" /
, f
/)
/ i - aJ
,7 :y.T"
r"
V /'V'
f ii'tv ( t .< r" >-<¦
/*?
/¦/••J1, .••;
f >' ' t»k'r ^-T"> t
ft ..
fe.Sc,- 3- vr
. -- ^ ~ vr*
A-Ji . '"n'rf
A
W
AJ
t "< 7* *'(
l,i . , C""^'5 ••""*•' '
Pf r #9?
l-P
Bs- ' 2 - r
^ 1 "iie-1 * -- tK ( frt -»*•• ¦?
*Y /""
• /
w
/ "':.
* ^
• /° ;
'•- p
% So - ry - fi>
F i '
Pffji e>r Pr-Tfc¦ ~A (>
rr ~t*' *t"f" ft "5 /><*' »" /S-'V-y 7 t ejs ¦ t- ,./ J*!
p..,-'-:-' rr ';, C/u^, ¦
Pj S C>- 1 • ^1-
fi S O • 2
JE* x -y- /• K* ~c
/ *
^ <¦" r
$><>c
Pi
r> (~
.-* '
V P >"¦
• /'¦V
%y/
M
f v i-f
{ i ^
>1 s
¦s
^ /
-------
fTf \
_jr—«¦" '
c
r V
D». Pr'o b* 4 »
' /
• |> '-i v A ^ t ® «*• ^
t'--'. 3;
Ac>d - r.- -
- V- /''/». .
i i S C. • '"•! t'f-i t ¦ A
o:- • '7/1 r'^
t'
I)
{•'<$ Cc " £¦'< !
{*t /• j> rV 1 •» »Ai ". Ac^ [ 'f m~£"~
r-. c^c- - *s - c \] c. o
a so - ,y- c ico
B•- ••
A -- <•,. /
I , '4k.
> - C.. tf\
i*:.-,;.' ' ') " <: Vs
ji; ; - J>/i .. ~ /:
/ 4 > ii ¦•" v, f(, f / ,
?• f ^ ! /V" -f /<- -» '. (
-• C I
- ~y i. - - ' f - f ^
-w. ' . - /;• fi 4 f '
I ST" | w\ pi ^ 4 ^.twvd-***' t.
( /Do r*v*r- s^o/.-f- ^
OSO' jfAS- CtCAX
BSO ' > - C A
BS-4) - OA ¦ f 0
-------
c
Sr 'j"i 1 i~xs Eftt\ TL.C (£fVA^
^ p^f\a L. r ^ < i<"-'*j'
Lr
; /g^- +-,vM..g
: /3/V5 - X - /?
J/^/3 - X - M - >5
/3-0/9 - J - aV -
f:j {->(-¦' ' „ /W/<¦'¦• {<
&/¥* ~Z* •: -7?
.k&P*;? /»/i~/3
fJ/4 f&~ /vP/2 - /2 .
z:?/1/--' 3 - /ft/' - s
@r*t>. •* - >-/.* • /?
-j - ft)ft . /£
B&P- ¥- A>Pf'y -
/S/V--- '/- /->"• - A
/>/•'/" ¦'" '/,// /•',
/>/*/"• - jtte ¦ <3
^ ' '3
; /J0P~ Cr ../V/># S
: / ^
& - x/? •
&AP-C- /#'- 0 'dPfc ~ &
flfiP'O- Pr- /}
-------
4 P rt'h ¦> v. JL c * - * §/ •
pi i
^ Crf-*-!^—, ~z.
flft p- 0-
fifip- fif> -sfie - fi$~&
W- s/*<£> - P* ¦¦&
Ow- - /Wi5- /3
/«: / y-' ¦ C' /^ - /V- ~ /-,
fW->)A- - pf-B
0>jfVI6 - ^ -Y.fl.~Q>
BfrP ¦ ¦')$¦ ¦¦ -A
fifty- 2>-pr -c¥
S/fP-3. -K/l-C#
./&P- rj
Pf ~ c •• "j*, ¦ '/ »«' r, —ft
: f - ¦¦. — =*7-- • v •¦'. ',
l :¦ >"• f" '• ,' 1} - &
6.5>o/s^ - r*i& - & :
mp/ #a - &
- ¥££-£,
a^y'&^P ' O- \TA) ce
-someAa -/2
*3^2-d~ -vtt*Z~~ £>
?t;t- r ¦ r ft> h.
-------
1Prwi.p i «f c.
-C ^
4"!? F PA XfeT "/rj VnJS. »m { 4"% ijt
'1-f
f r !
^ f\v»vp Lf rv*~-t.H v
1 -a;^- c'
. i>f* - J. - Pi; - C-
&a#- i - v/?. c,
,3 A p - 4 A W? - C-
a - ^»'-C
; ft* P - -X-pF - c...
, ftAP -"2- -/£"C.
fi^P - ? - /VI/?,-C
c
B./\p-3- pF~e ;
- C .
j -i, i"
jYH'
Sv--t"
SAP- c ^
,; r- !l -:Ff ¦ C
' P- < /- //; - C
ft h P • <¦¦ Aifr?- c
;: K A r> • S " - C
Sap- s - y/2 - ^ .
; «i p - fi - >v> i? - c
$ fir P* •¦ G ¦ nP*> - C-
• c
f->- c
P>f>«"- 6 •• "X (< ¦ C
[ Cr - TAtl- C-
\{lfsp - >y ./JM - C
Pr C
u t
Cr- >v\ W I «•• -r /¦ ,*i t t *( '¦¦( Jf4% j* i ¦¦•¦- St
if '
F I I "!»•*. "f V-r^Jf *- f"'
1/
>• -• t!' H
!'* .>
P w W ^
w v~* ¦ s*p
fw . •» rj
/* *
Pc 4 r .,' #V1 t» C-'C-*. - ¦ 6t /? , "»¦ J» {•
c.
/f't"' «• 11 c >¦•¦-¦ K Z1-
. ^ * ic *N
-------
N
} C
,s "
p • Ct ^ ^ F A"
vff
4
tV/ ^ u.s
, » ? ji|-£ I k ik-t'hr,»,\
- f>L ma- c;
rj ~ § Ai*i. - t't't c
&*P- ^ Ag>.
- s*i>~ x/2,- c
(Jft^-iTiAk - ^ c.
(}>tr rM ^fl - C
. Gap • >yj* - P'1-*- £
;Oftf - «?* '
I i *«¦».»». ¦
jkitp - - *V c
£1A,.) J:. ,-/)- (V
/¦.; ¦
-------
5 )"*•*•*£» I El ,
r t fit, -ft*
nnp - i-a
.. \hP,P- A - x A
'&*#»- 2 • A
A - "2 - X A .
ft*P ~ 3 ~ A x
: fti5* P • 3 -
jV^ ' ' / — A
j3>vp . if* x*fi
¦ '*A ¦
df^cP'- Co - '/¦}
$?¥>-G~XA •
.flBP- 9- />
i/.i/ip. ^-x/2
/J/*/-*' i'/W* /? _
ifi'/-;"'- >"'/*«'~ ' VA
'.£rtP-Oflr XA
»U4j
-^tifrP-o - |
i:, iV - o-X.
jv!.,r,„- ....
-X -4
^ I/-- • - -,
\ *> -, ,.
.CiSa /^P- rvvc4 -A /'si)
j f s. ..¦.—*1
.WJ PF& - h ; .4;
:7g?'
-------
sa_ A { V /vjui-vi fa't
^ £ '
1>NC~ 2:-^*"
f! - . . f?,» ¦>. |—'
&
-------
/
- r
" I, , «• ! - - .•/
t'N
fi>$0 - O-f I ft»)A,-ik" - £-*" r r -*/„.. j>C "?> l/
Acq - £» ~ fit *Z- ; 'f
/ssoy^A/° "
£>So - o- (k/A^k~ >. - ^J.jT
£?Sd - o • />( && - Z ''
G,£o/4Af~ &t% >' <>" r „ < 2-.s
&S>0^ 0fP ji* -A s^r ^cy/5^i Y„ i, 2^-
&*» ofi%m 1 -mcd-C: Qiy?k~ • 0 * £*. * G#ut
•fe 1 (<>--/ protvJ i>r<, *, (5 ^ # ir,^r"
tesa ^/S/V -o-U~Bj8 ' <• ^ Vv */- 3'^C
, a£&» — A- ..Srr S** r '•'/. '/, 3,s,"
. gsy -* ;^l
I ' ' S#t i:,e 'f. X"
/ftfip ~ Q-¦ fit r**L&~ A - : £>*~v. .f A* a ^
-------
PJ\C> ' h
fKh? '; : k
; /vj:
{>£> t"' ¦ i r'
fef: /-•• • • A'; ':¦•
/S*/3- 4. - pp-c w
ft/V -X-M-cu
ii h)? - Z~ - f f - C "
- '2- --//? -0 W
ll fi p - t- f - P f - f, tf
/J//^ " iT" _ /V -f W
/3/tP * iT" _ •<" >v
/$/)P ¦ fa „ /r - c £
*5/^ - 4, - */*.<•£
/Mp - «r>6 . ^«
af*e-$*p& ~ 7/?-c'u
1." ¦ J -r/ll C.
A-''1--' - " C£
&/¥'/,-: -. '-¦'- r^?.-
?•; /' " " - -V f V^ > <
/*/"' " '-" • '•' ¦•"¦¦ ¦'¦ " - '„¦ ' /-
/*> /'VJ' • / V s.:', - -C - {. ' A ' C
-------
%> ' . v
^—**¦" • j
• ; (,: T/\)0.
: ¦ ; ' ' ¦ ft
H tx ? *- T}" S \fi 1
I ' ' , . • : C -1
Q
- • 5 *" < - £, C.
-'[•
i ' ¦" ¦¦ :'' J1'-' f ' - *
¦"* ^ c If)
/-•>: ' ;. • ^ >fL - A
f ; #1 y . i •' *sJ< • /•• . V* ' r '
- : '' f-\ -
" - ¦ ' T'.h fy r -
ft ' tj - C ICQ
'S> J* " f. } C fj)
*>>:' - C / ?""//
- S • f ' c/?
' . - ~r
/ >5 ( a. ~ c / c' /)
£$o - /- c//)
/3so - ,? - c/fi
/2>>o - If ¦ C ¦/*
/:¦¦ "x *? c '^7
¦ >$& ¦
-------
v:
-jCJT
£%*-¦
fl {-' "T3^ > ^ c C
C C/vi 6 "")
vc.
U-.H
/tp-^ t ^ ^-|'\, U& " ' *r ~ C I /X
&S«. - r//j !
f^.o } u • C it*.
fiS0^ SV S<^ I
- *70- Sc— :
-
ftAP-O-C|
0»rH>- D - c ^
-------
(?*l)
JUL ^
i»f»~^ p 1 ^
(% sy/p^- &CA
&So/si*P- tft
P>" f ^
pr a -nft -
fi& o/Qm- $&e>
- ftfb.
~0>/i
~%e£
f> /&¦-*¦ J
f, 1. '¦ f yr^/T
filed,
r rrtt*
.&
tyfyrffay- o -vrfi£
as* /4*P-P'A/*ne-&
kl.of&fp' o- M 0>O>
#>p -6-/^5-1
/irtp- O ~/*U 2.,.
4fiP-o. -thifig-1
I [\
B/fP- O-C/g • 21
/SSo//3>"r° - /»fC^g -/? '' '/* J
.gU^H*9 - f-iT/t! "A : '/$,
- /¦* f C #"Js - <* [ '/j )
A/i f - /?
/? /t*P - /'A *$ - /§
/
iVr r
AScytZfip -j w
4so/4*/> "X^s- &
r/
//
/v,.3m*p~ a - ^7Hc.a *f) f-t
f2j>*/0'*'J *° " ;r"/tf c '* 1 /iJ-
, o- '-ySS -Sf (ft.
o '¦ tr>V*:. *~$ ' f/'c
/- ¦•;; 3//^/v-" - a - c '~i~ /*
&St>//£#P* •€ " '»V/i ! r si ' fi
fit So 0 -fOrm - f
BSt/mstr* ' ^ ' -p^'i
"* ' f 'A,. '
/.£ ¦ \ " \
Af= - o - /-*> fi - ^76 ( Yl
g&f-l - 0 + A'/^ ~ /3t ( '/ -
/3/^:' " 6 r/^f' <€i ' &A f- V.»-
}
>"N
.)
<3^
- • o '- r't' t.i * 7
' •¦ c- 1< t.i " / - ^ ( '/b. )
~5/-> /> - 4* 11' ~ f£ ¦ /-/* 1.
^/•' - C /i/"''4~ / ¦ /? f; ''>)
- £>| - /*>" 'I - *-'3 f'ui\
-------
pF (S A ~ ¦' f'5
( . Z )
Av
|> i {t i-
r
<" t- I. "¦
&SO'\-o
£$o\~0 -/>/&& -/
- £> -*>/&& - 2
- C / mc/s - /
tic * • c//t*r&- 2„
GU> - C /S**.-- /
/JSo-c /A'A - ¦£,.
ILl£
fS/ A ' !, 1 -«
^ U.L
-she&*A
feS fe — o - >vf ( (i« A
JL
O fc> I ¦'<* >Ki
;- 1 ,
f^j.1 ft r>ks
'{*•' •* r "I r-4S
0 P'? fi" (I* i
l^lft A - e> - .& - I J*
(KtSt* * c" " A>rt* <" »V' K^
frt t'l ¦ '/. A y
Cc
t * L» • "" W \»*>. ** I fc
^ - o - if
A- - C — "2L,
-------
i (
ma cmmtm m
7
ya
00 AIL 3KAL?5i»* PER
(un)
(SA1*1
"w—
7. 4 ,*S&c |
1
-------
-------
GOAL MALTSIS 90S
COML CCKVETED OK
t-z-W
(HilS)
¦3%
¦SBHSM IT*! TT
H»H
Jt&i.
ItVl"
««
S4mk
I L
I' 'mriffn
_4J*L 1 I »
ULLl£
£.2
iLi
(n'4 L I £
/ /I
i££
ft-ii
j?
/£.r
J2.
> J
/ /
fr- {
if
U
U
l£b
J>9 fco
.Intti
112.
(nSi.k I to-I
1-13
7'/f
Ml o
( 2 : Li
I > <:J -* (
lI
&L
jal
JLl
/ CO-
l-i V. > ¦ jT
l'5
aL
1M-
JdM.
-------
vi|c/v ¦¦¦'-
GOAL OQHVRB) OK
(BAT*)
m*, ^.v-, j^V<
>i'^y\:r?:>:f^~'^;0';.' ^V/--
-gg^tf iw»
F « ¦«
ram
m
M.M /». I «-!/».
x%t
31
ii-§
a *4
*9
13.1
/5T4 .
L^L I iV
/./£,
7,J?(3
MOO
if
§4
if
S.R
IS.1
14.0
^.r"| S.7
HO
7-K
Jl.fo
it
it
L4-
13.0
tun
bS.y | S.to
/./?
l.U>
MOT
W
OmmI
. /. ?W
£-.7
„ /.V: fX.
l£'4-
L4.l\ S. 9
/¦/£"
m
-------
cmntm m
OOJU. «AtT5IS fQft
u-7i
TmxT
CDAtSE)
-•V '¦ ' . ¦..¦¦•: ¦
- -•¦¦ ' ' """ ¦•" • -..II- " HI • " » ¦' '¦ ' 1 ' — ¦¦¦ •¦¦¦¦'¦ ' ' ;
t stmm mtm . § isnftmnr ~1
#1 nrn
' BWKSS \..
: i **l/8« **I/8V h u I t SIB. € Asa 1
nam*
#
31
12-6
» 3
1. 3 Y-
V !
N.
it.l
4573
CO
US'
oC
-------
'iX"nh*> • ¦ . •. • ¦ 00^1, mrnm-'m : #~^;7er - -'• -
&MSL flIALYSTS VGA . • ' C8*fij :
(DATE)
'
KEGGLAR SAMPLE!
i '
scRcm si« i ^
11 «R
BWKIft
f #l/2* 1 *~!/!»• 1 <*1/8" f-2/a» 1 IM
¦ I " ly mifiiE
fflKJBP
TfflK
•
1
<* i
12-6
i , '-1 /
,5 r
iC, }
/.r 9
/,rr
4 /
/. / /
•r-4
OQ>
O
>?. ; -
!
8-»lt
C 1
/'4 1
IA /
i ^ • ,j«.
j -v
t x /
if*. •* .
ii-12
// :/
- /
-7
' •' /
72.0
^ A
3i
OToni
* f
17
it 4
/ -"/
0^ . b
/ 7
/. .'7
lyn
-------
-------
r
\
USiL Of/IM
P'LAS i t Ci- ulvb
7-31-78
AiMALYSI S Lh GOKk, PKCuUCLL) ON 7-30-7 8
PLUS PLUS PLUS
DAT'iS GH S i Ai v HArtu 3" a" 3/4"
1 -- 3<4
7- U-.h 31 SO.6 67. 0 19. 1 56.3 96. 8
I'iOI S'l SUI. AbH
3.6b 0.96 9 • h U • b b
-------
c
*-s * "Gi. J•• I V
B- 1-7c
¦-.Ni rtL f S 1 b (, e UU\t. Pnt.'L'Uli'.i (, j 7 - o 1 - /
H«Ub PI.Db
B ATI b (an ii | Ml > HAnh
1 - 3v,
/ - 1 i*..; o 1 L'«o» y 7 Ut u 1. >•.
¦--1.. s
/ 4 "
'/<_•« v
"ICIii' iul
3.,5 b 1 . u;
-------
• i i, i j
i r Oi- ulVi
0 — Ci- I
i-. v /-l, t-i' G I. iir.
i; Al'lb c.*r> b'f.'Uj
1 - 3A
/ - 1 . 31
0»M i - ? d
i'Ui-z PUUb
;l 'iHl- •>" i,"
t H • 7 1o7 • 9
HLUb
J / *! 11
96-9
)
i( Ibi bUL A •. H V.vl
-------
"iM/U-Yslb Or UUu
Hi j [-} •; o i . '
i - 3*
t - 1 h.h ji b; .
i^ jjUGKj,- (.;\j t'-- a-V
i'lj 1 j t" j t [ i ;-s ); I, t i
- *1 * i1 3E* ;>/4"
' :0. b.y.i) 96. b
.«..G I S i SUI,
3 • 3 0 U • 9 1'
-------
1
OS'i,
h<->, ULi .
" C°«i P,
C^(jC
B4lT£ ^ %
. Ku&
H^k£)
,
J<4 ..
1 5*
6*-6'
*0-5
-------
r
-------
U i>*l L ULTrf
BLfib'i i* Ut olVb
6-6-7 8
ANALYSIS Ot CQriL PRObVOt^ij ON 8- 5-7 8
HLUb PLOb PLUS
BAT'ib Gh b'i'AB HARL/ 3" a** 3/4 "*
1 - J&
7-1 id A jl b 1 • 4 fcb. 1 19. 1 56.7 96.7
J
>vit I ST SUL Abri V.-I
4.40 0.96 9.90 . 55
-------
\
litei
J
A3
jnm, MRWHTI* <
pscfTirffircMUE «mb tin cnihicii idiks
, //-
/.
v,
PUSH INC 1Q CHARGING REPORT
(WIT Mfl. /
12 Mr*, fteginning 12: 00/ M '
«... 7» »y*7 ^
-------
f. nil
ITITf* STEU MRntATiM
^U(RTM CNI MJ&kl SNlttSftl WRXS
PtiSHINv m CHARGIHG REPORT
PIT Mfl. ¦_
12 *r». 5efif>oin# 12;0
OVCN
J&.
I IMC
PWNED
Itii
CHARMS
NOTES
8VEN
M.
TI BE
PUSHES
T IMC
CMARIIO
NOTES
OVEN
NO.
TtlK
POSHED
TIME
CHARGED
NOTES
/O
2A.
I
'6
\
A'
y.. s
y-'
i
i
fc
£>*l
t Q
11
o
14
J 3
n
u
13
15
IT
*C1
Jm—
_4__
_1_
It
A'/P
13
ill
IJ
*1
iSI
A.
15
ZL
M.
18
I 7
jtmjUm
ll
£L
7 ~ /e
££
17
al£L_
!i
£_Z
Zl
is
if.
tt
J/.
£i_
J#1
21
12,
21
/y 7
ii.
21
&2
jtZ.
3f
23
25
27
/i
*2
JL_a2
ii.
x
&4-
23
ir:
23
*5l
jL3L~
25
o 7
25
/I
He
f6
27
£1
/I
27
x.*-
2a
31
&J-
*L
*1
28
X-il
X
ill
28
31
i.
JJL
31
1£
*J_
jl£
&[j£.
rf
^ v.
JM.
JS.
JL
iJl'jl
i*L
/#
JjL
y* ia
JL
iLfc
ii.
5it
JL
Lt
pgr
aL
*A
JUL
J2_
JUL
Jt£L
18
A£
v
10
10
II
Urn.
12
12
14
14
14
IS
IS
16
11
18
/ c
:«
20
s2tl
20
22
22
22
14
24
24
at
26
28
21
JQ
0 6>
21
a
! C
30
1&.
*3.
fo
4&
30
/*
12
3f
M.
24
M
ll
«. 2
E—
to
m
JL
UL
REMARKS:
33e
-------
ee-i«» m. u«i
JM.001.8W0 .
tmmnm
miw* mi m coil cmeiich wrks
PUSHING CHARGING REPORT
UK IT NO, I
If Nrt, l*ginnin« 12:00/^ M
0*t«, 7 ft* j if
MTTItT HO.
8ATTE&Y HO.
8ATTERY NO.
fVIH
JL
i he
PtHwep
TI kf£
CHANIED
NOTES
OVEN
NO.
TIME
PUSHED
IIHf
CHAMEO
NOTES
OVEN
NO.
TIHE
PUSHED
TINE
CHARGED
NOTES
L £
'/
9 ?
i
r-
1
X
¥S
QO
ft
Cdt
A
lik
ci
u
02
51
QO
io
o3
-yi
to
ii
53
tO
si
96
ft
ll
to
31
JL
A.
30
6
il
30
,o
/S
30
i£
2:
.iT
Tv^:
REMARKS:
-------
rea sngpjifL,
AW mi ClUICli works
PUSH INS .«D CHARGING REPORT
WIT NO. L_
12 Kra. MginniAf 12:
Data 7 -SO" *9
OO^M
mxtm no. f\- l
BATTERY 10. 16 ~ 1
BATTERY NO, " 0
«rt.
F TIME
NSHIO
T t ME
CNM8E8
NOTES
OVEN
NO.
TINE
PUSHED
TIME
CHAR8E0
NOTES
OVEN
NO.
TIME
PUSHED
TINE
CHAR8EO
NOTES
' 1
1
1
3
3
3
1
5
S
. J V
7
7
- -J
•
B
8
1t
11
11
13
13
'X
#
13
>0
>6
15
Oc
15
/a
CQ
3c
,
15
10
1$
AO
17
K)
$D
11
/O
3Q
!
.
17
{0
/
to
18
i2
/
18
/
i
30
18
j
f2,
i
4*
I
21
/
M
1
to
21
I
3*
4
to
21
I
C0
QO
23
1
n
£
3c
23
2
4^
+ e- * V/
23
a
•75
¦ 5
$0
25
Q
33
S
&p
25
3
%
&
25
2
O
3
AO
27
S
3
3o
!
27
3
/a
3
4°
27
%
&
3
50
28
3
?
/*
28
1
4?
4
A**
28
S
5A
v-
¦9*-
f " "' '" '
31
f
y ¦
t*
'f ' '
31
Af
4 £0
31
H
jT
il
£
2
¥
tf
jr~
vhi
2
T
1
2
>
/?
f4
9- /£
4
n,
40
4
i*
,rf
£
4
^r
'
it
B
4
(r
41
8
*
4-
8
#
j*
?
_
At
8
•y/
1
/P
8
4*
f*>
7
S
1
7
J4m
33
10"
I
7*t
7
rir
id
7
*4,'
r
<0
1
sr
i*
J9
12
7
Si
r
af
12
r
a **
r
M
12
jT
it
r
fg
rS
14
r
At
f
14
r
st
1
14
r
f
10
jT/
10
f
*>
t
<3 0
IB
f
*r
18
9
XJ*
• f
ns
SI
ta
n
T
3 J
IB
Q.
ox
£4m
t
18
?
Yf*
n
J " i"
20
t
fS
to
20
16
*1
tp
ft
20
/#
/I
/#
(/.»/
-r>
TU"
y 4 -
-------
•IMM '«<¦ M|I '
03.OOKOfl»#-<» ,
UNITED SUitS ll|CL CttPMATIMj
C L AIR T OM COKE AND CO AI CHEMt CAL WRIS
I
PUSHilib AND CHARGING REPORT
UNIT *0^ L
12 Mrs, B4g£|ftini
P*tB 2y/.Ji t
wniit no.
/
SATTERY iO.
BATTERY NO.
OVEN
M.
TIKC
PUSHED
TIM
CNAMED
NOTES
OVEN
HO.
TIME
ruiMia
TIME
CKAMfO
NOTES
OVEN
NO.
TINE
FUSMEO
TIKE
CHARGED
NOTES
1
(
?>
jf
a
V
1
11
'/
0
11
•/
w
r _
A-
4.. '
'V :
"
fc*>
13
" t
> V
i-
13
' f '
13
¦* t
\
o-y
15
S1
n
/,¦ ¦
%
15
£>
*
X£
15
4
t
/ •
!
V*'
j'-v"
17
(p
->£>
i.
¥9
*
17
4
7
*3
17
f
i/r
7
19
if
7
p3
IB
7
htf
?
?3
IB
7
/*5
^ ¦ p
vy
21
7
21
7
BS
21
7
* t ¦'
?
23
¦
•• ^'
23
/4
k.
23
1
25
tffl
f
i%
25
5*
25
if
/
27
<7
M
/*
*>4
27
36
/j
27
1
?A
¦
28
/*
ps
&
Go
29
A
sS
it
28
>SJ
' )
i ¦*»«
^ i
*
31
, (
S'J
ll
£5
31
//
0%
v or
a
31
/i
f4
2
//
>
2
//
37
2
4
4
4
6
E
8
8
8
8
10
10
10
12
12
'
12
14
14
14
18
IB
18
18
IS
18
20
20
20
22
22
22
24
24
24
/ 3-"
26
/*
26
/J
*3 -yf
V* P
28
tss
' ^
c3\
28
/
$J0
/t
S'J
28
/X
/
C3/
28
ll*
*¦
/
/ ^
30
$s
t
23
3,°,
/
/
IF
30
/
/r
/
V,-*'
1
A
f
A
5 '
t
>7
:•./
*
2
C 2
ll
^0
/
2
~T
% Y-
-------
still CORPORATION
Ml *NO COAL CNEIICAl WIRI
7TJ
SET
PUSHING «N0 chargikg report
WIT HO.
12 tin. I*finnln§ 12: Oof M
battery ho.
BATTERY BO.
BATTERY NO.
mi
m.
TIME
PUSHES
Tine
CMAI8IB
NOTES
OVEN
M.
TIME
PUSNEB
T til
CHARRED
MOTES
OVEN
MO.
TIME
MJSKEO
TIME
CHAB6E0
MOTES
£.
sy
H6
i
0-^
1
p>
JO
ol
to
12
ML
LP
ll
M
th
ta
21
/D
03
/<5
31
M.
31
JL
t±
J±
IL
»&•
II
oH
//
JL
Urn
/i
XL'.
IL
&
li.
IL
so
11
it
ii
u
13
13
13
15
IS
17
17
17
11
18
IS
21
21
21
23
23
23
25
25
25
27
27
27
28
28
29
31
31
£
31
/3
//
/C>
flfl
<>£
f1"
l&M
M
I'JL
Ol
SM
jar
JcstJL
JL
4k
j
5
>r
ii
20
03
S*
JL
J/
03-
18
vi^ "
£
a/
*T
V
5" I
20
5"3
22
j>
/V
V*
22
4
O-
24
3«/
JL
03
at
/5
24
3V
1
il
26
JL
o*r
n
Si
28
JL
QV
28
v/
iL
Sj
28
06
30
l/f
<5"'^
3-0
/*
30
r
3a
/j-
S7
01
3mk-
Of
iJk
REMARKS:
3?
^L/
y o
>/
-------
;r£EL CWPMATIWI
AM COAL CHEIICU IMIS
PUSHING .^0 CHARGING REPORT
UNIT 10. • ,
12 Mrs. Mginninf I2;0O^| N
1 -
BATTERY HO.
BATTERY *0.
^ - I
BATTERY NO.
OVEN
NO.
TINE
fUSNiO
TIME
CMA*BED
NOTES
OVEN
NO.
TIKE
PUSHED
TINE
CHAX6C0
NOTES
OVEN
NO.
TIM
POSHED
TIME
CHARGED
NOTES
t
1
/>
/Ail
IX
f:.
i t
13
15
17
11
/">
L&L
/2
t
jji
3$.
a
11
iA.
XL
IA
fZ
M
±L
13
/JL
X
JJL
ICl
z£:
15
J-
2^
X
sfO
M
17
47>
Jjfc
11
13
IA.
m
> «*»
S~n
£2
X
M
15
X
1C
*
11
oA
±,
IE
,21
JSL.
15-
±
19
. T3i« 3~
iT_Z.
2£
21
JL
36
,ST„r^i
18
21
X_Z£
23
25
JL_-l£
4L-e£
6j2.
23
±iSZ
4^
52.
25
4
VJ£
^-k
23
il
25
AL
ZL
JL
ML
27
12.
27
27
3?
28
&J&.
¥9
28
2^
28
^0
J
tt
/V
31
i?6
29
31
ie>
3&
31
t ¦
bfc
m
j-
jjt
*f a
<{£
(A.
X
11
z
$6
Z
m
3£L
00
X
HI
tl
V4
%
o% -f
11
14
51
%
2Co
o*$
1.
1o
-------
ce-ioufi. ifv. Mftu. • PUSHING aNO CHARGING REPORT
Will NO,
KITED STATES STEEL CWNRATIM „ Mr#. ni0Qf>*
CLAHTO* CORE m COAL CHEMICAL HOIKS % - } _ y
BATTERY ^0. /h - f
BATTERY MO. & ' 1
BATTERY *0. /"? '
mn
M.
TIME
PUSHED
TIME
CNAR6I9
MOTES
SVEN
NO,
t lit
PUSHED
TIME
CMARBE0
NOTES
OVEN
NO.
TIME
PUSHED
TIME
CHARGED
NOTES
1
3
3!
H
/a-
1
3
3*
V
1
3
sf
V
31
3
4
i4
4>
v*
3
-y
24
jr
0 9w
3
V
&
3"
iJL
8
H
SO
$
JX
S
<5*
0*1
5
3Jl
1 8
4"
H
r
i/X
7
5*
2*1
S
r>
7
5*
3H
03
7
5
<0
1$
•
5*
SH
6
S '
0 5
6
1!
9
i*
n
L
Si
11
4
x<\
1
6f
11
6
*tt
1
2a
11
a
~1
ir
13
1
/p
53
13
1
/
/a
13
1
f
a/
13
7
£S
y
IS
r
P
r
*Y
15
r
m
J
1?
f
is'
?
/V
17
f
56
9
ay
17
r
Q &
7
11
J
23
/#
¦^7
/o
ST
23
/#
37
//
25
to
HI
//
/¦>
25
fC
i'7
//
,23
25
//
OS
s/
2?
//
iS
*
27
fi
t
27
//
if
28
28
29
31
31
31
2
"
2
2
4
4
4
8
, •
8
8
B
¦
8
8
10
10
10
12
*
12
12
14
14
14
IB
18
/P
DC
16
tO
C'"i-
11
if
18
/3
1 2B
X
10
2
Sir
«
26
a
^ w
28
<3
"30
3
oo
¦> 1 I 28
3
/&
28
S
30
3
3
*
30
J
o
3
W.
•
30
3
?/
V
0^>
I
C 1
3
yr
•/
•
V
OA
V
2
2
2
REMARKS: f
a
/ -5
a 2,1- > *-
-------
,cs STEEL CMPMITIM
V COKE AN0 COIL CM MICH WRKS
PUSHING aND CHARGING REPORT
UNIT HO.
12 Hra. Beginning 12
Date _ 8-3 - 75?
OOl
BATTERY
M. A ' 1
BATTERY MO.
fi-/
BATTERY NO.
a :j
OVEN
MO.
TIME
PUSHED
TIKE
CKARftED
NOTES
OVEN
NO.
TIME
PUSHES
7 IRE
CHABBfO
NOTES
OVEN
NO.
TINE
PUSHED
THE
CHARGED
NOTES
t
?•
1
•
1
3
.
3
*1
3
IV
8
19
a7
S
II
/-»
3*7
5
j2.
19
/a
7
P1
lt
57
7
/9
P
/
7
/?
1?
/
rt
a
61
i
31
0
j
of
r
3*i
9
1
#>
l
go
n
1
0
11
t
4|
/0
11
/
5£
a) O
13
3
e%
?
%0
13
9
ni
4 i
1 13
a
3Q
?
^3
15
$
"20
3
Ol
IS
3
43
3
I 5
1 15
9
55
v3
jut
17
3
£
17
3
J 7
3
*•»
1 U
3
V
00
IB
W
H
f i-
IB
?
CJ
IS
1
0*
ti
<3>
21
N
if
21
H
25
$
31
L
25
S
X/
I
a.a~
21
(n
0-/
i
27
L
/V
(
27
I
a¥
i
29
L>
3"/
1
OS
29
4
i
IS'
29
6
3/
n
2.1
at
-?
05"
3*1
31
i
i -J
r/
31
f
/<*-
2
"7
f
iV
2
7
f
54
2
r
/V
r
vf
4
r
at*
<1
0/
4
ff
7
~ 3
4
r
9
JUT
8
43
?
3;
6
f
/:T
9
*9
6
9
/O
a
9
5?
/$
t¥
B
9
*57
4**4
-fit/JM
8
/J
/&
3f
10
to
J6
10
/$
jr
//
Q5
10
M
S/
IS
12
ft
3>
12
/(
or
n
sf
12
//
n
i)
Vf
14
l\
3 >/
-------
.tfPWUTIQ*
COAL CHEMICAL NOOKS
PUSHING AND CHARGING REPORT
UNIT NO,
12 Mrs. Beginning 12: QQ/^ M
Date f- "S. - r
.'r
m. A - 1
BATTERY HO. B ~ '
BATTER* NO. /I " -
< PUSHED
TIHE
CHARGED
NOTES
OVEN
MO.
TIME
PUSHED
TIKE
CHARGES
NOTES
OVEN
NO.
TIHE
PUSHED
TIME
HAftGEO
NOTES
JT\
r
33
<,
(f
Ml\
1
r
3f
(f
!
sJ
/
?~ &
3
&
3
§•%
1
3
*>
3T
7
s~.jf
5
*
wT&
1
J-O
*
5
i
o>-
1
5
7
/*
t
vr
&A
1
?
I*
7
r*-
x/"^
7
7,
3>
f
7
7
9
r i
11
1
°f
ai
11
7
o3
"
9
?
: /
//
13
°!
P
oi
13
9
Hi
.55-
"
13
/o
/r
/f
15
&
O"
P
>>
15
m:
15
/o
//
0 5
17
/o
//
!(?
IT
JO
iY
/I
17
//
>/
19
f!
m
)/
19
P/i
u r
i
19
//
%
r
21
//
V7
21
//
n>
21
23
23
23
25
25
25
27
27
27
20
29
29
/ L
31
31
i
31
X
2
2
W
2
/1
4
4
/
4
1
6
\Q y
6
'/
8
i
8
1 1/
6
8
j
10
yi l x
10
Vf
10
i
12
(ic
)12
12
i
14
j2S
a?
i' /
1 14
!^
/ 7
14
S3
»!
16
o^f
ff
IB
?-
%
16
i"
ji*
1
& 3
erf
18
p-
f4
I
/<£>
18
s r
(e
He
18
I
I
r.r - /a!
20
t
/f
(
20
e
A
20
f
If*
¦5" ~ /
22
I
4~Y
\
. i
OO
22
JL.
Hi
3
/£?
22
55
$
r>"/
^ - All
24
1
1
24
J
3
rr
24
3
f
28
3
Sf
f
/
vr-
1
3- '
yf
4r
$0
r
C
2
2
2
REMARKS: ^ ' (<* 1 <* / " IX.
P I'l' <~t
(L- ,'iS" T 11 ~ .TV
-------
CC- 1 02#5 REV. 1161
03.oorjipr'
W1ITID STATES STEEL CWPWATIM
CLAIRTON caffliTC0*l CHEMICAL IMS
PUSHING M CHARGING REPORT
UfilT NO. /
12 Hrs. Bet inning 12; 00
Date f "•*¦ •• ~? ('
BATTERY
,0. t\ 1
BATTERY W0.
t r * '
BATTERY HO.
OVEN
NO.
TIME
PUSHED
HUE
CHARGED
NOTES
OVEN
NO.
TIME
PUSHED
TINE
CHARGED
NOTES
OVEN
NO.
t mi
PUSHED
TIKE
CHAREEC
NOTES
f
1
1
3
3
3
5
5
5
7
7
7
9
3
9
11
It
n
.
13
13
13
15
15
15
17
17
17
It
18
19
;p
i
I
2 1
/ O
/
21
3 —
21
JO
y
2
3
rr
V
4
H
H
4
V
¦¥
*4f
4
Jd
5
"7
!
6
if
sf
C-
'3
8
H
5*"6
5~
JJS"
S
u'i
L'
"1
:
8
5*
/J
4
/Jk
B
S
37
I
! >
8
6"
Vo
^ m
!
10
A
^ ti
4,
Sx
f-/ iij )
10
/V
1
c *
Ik
10
4
»» s/'
1
12
(o
5 V
7
> '?
ft/
12
7
OS
If
&\
12
1
/7
t
K- /
\
1
{
14
7
a ^
r
c?V
14
i
y/
r
/>
I II
14
7
S3
¦r
/
,/j
16
/'
oC
r
J 1
18
1 /
1G
/"
-2/
/ ! c' ''
/ s*
18
31
ci
oa
18
r
f
t'{
\ /
18
7
GT1
i ; ¦ -¦
20
f
;¦ ?
20
<3
i
>
I "
20
;\f
y *
f
" i
1 «
22
9
/
/c
l/0
24
/
-------
CC-10286 REV. 1-111
pa biii oma
1*1 TED STATES STEEL C«M*ATIWI
CLAIRTOM COKE AM COAL CNE1ICIL ttRKS
BATTER* W. I BATTERY (0. $ 3 ~~ /
8ATTERY *0. /i ** - ?—
WEN
M.
TINE
pushco
TIN
CHARBEO
NOTES
OVEN
m.
TIME
PUSHED
IliE
CMItEO
NOTES
OVEN
NO.
TIKE
PUSHED
TIME
CMAtSEO
NOTES
1
J/
I
ft
i
rf
1
w
1
1
/?
/
9- if
3
t
Z*
(t7
3
I
3
/
jr- xa.'
»
>
p*
ft
S
**>
5
2*>
m
3
h *
1
¥&
3
/r
7
Si,
3
jr
T
3
jr
J¥
1
*
4
rr
9
J
—
9
J
T*r
r<»
t*
It
<3
So
+-
II
r
#*•
\
*t
<34r
11
*
ti
r
f*
U
13
r
r
13
t
ar
13
r
Sf~P
r
Mf
J"*"
19
•r
6 jk*
-3*
15
t*
¦T
• «
r
X*
c
—
ff
IT
y
if
<£»
/O
17
*c
&
MS
17
4
$*¦
a-
A*
19
c
/ >
c
ya
19
L
>2*
€*
II
4
3 ^
9
•JS
21
c
7
/2*
21
6
J*-
7
li
21
?
9*-
7
f€>
U
23
;
/f
r
€ig
23
7
3p
f
4*3
23
?
y>
33
X*
25
r
e
P
25
IS
? ¦
03
25
s
3T
f
'f
21
'*
fr
f
zf
27
7
o*r
7
if
27
t-,
%£>
7
if
21
f
fr>
(??
29
f
/&
/3
29
?
fa
31
1 r1 111 1
/*
e>S
/o
JJ
31
/#
f4~
/*>
f*
31
/*
K
//
Z$
2
/£>
3f
2
/
*>%
28
*r
¦
4?
30
tJL
/f
i*"
ft
30
j/
/
*1
30
/%r
f/
/
*T
/
J
C-1
1
at
/
n
(
1
/
s?
2
2
//
//
VI
2
REMARKS: ,, .. , A .
PUSHING AND CHARGING REPORT
UNIT NO. r
12 Mrs, B*flinning 12:00 fi M
Pate f" ¥' $
-------
, srm mmnm
„•«(£ AND COIL CNEIiCIL «M*S
PUSHING *N0 CHARGING REPORT
UNIT NO. /
# ' " ¦ JBT'
12 Mrs. #«ginning l2:OOf^M
o*f % — ~~ y &
~ZZL
J&h' " J
batter* no.
UTTER Y NO
BATTER* WO. A? - 2Lt
fonn
NO-
TIME
PUJMfO
HUE
CNAI8ED
1 OVEN
notes 1
1 NO.
TIME
PUSHED
TIME
CHAROEO
NOTES
OVEN
M.
TIME
RISNEB
TIME
CHAN6E0
NOTES
• 1
1
**
r
iL
1
•7
3S
' r
•7
j-sr
/
y o
3
r
If
f
3
r
do
f
od
I 3
r
?
; 0
S
r
5V
*7
JO
5
9
03-
J©
1 5
f
/>
7
V©
, 1
9
f
$0
7
9
J>
/0
7
V
/O
a
f
O
/£
S
/£)
O*
/0
9
fo
ti
tP
So
»i
It
if
H
i>s
SI
t*
ft
11
eT>
N
*?
13
//
wr
it
13
ft
13
//
13
if
it
15
t!
J3
15
17
17
17
11
IS
1 18
21
21
21
23
23
23
29
25
25
27
27
27
29
29
28
31
31
31
2
2
2
4
/J
4
/rf
4
J±>
33
8
/ th
(0
/Z!
y#
B
J pr
,2 ^
/
o9
6
/g^,
$S
' /
/*
8
/*
$€
/
A s
8
/
/
6
/
20
/
10
/
/
* ?
10
/
X
0t
10
/
f£
/y
12
/
Mr
12
M
n?f
12
4^
y'y
14
$£>
3
of
14
rZ
V*
3
14
4E>
-X3
IB
3
to
¦3
3 I
IB
i
J
IS
3
is-
5*4
18
3
JO
11
H*
H
<#>-
18
3
ST
y
Ay
20
i
¥
J*
20
V
V
20
y
ac
S"
0 1
22
*4
3f
S
»1
22
V
fo
a i
22
5"
03
s
3/
24
&
#3
f
*\
24
if
X3
2T
S*l
24
33
<*
26
AT
>r
28
L
' C
h
26
L
"7
03
26
L
7
30
6>
5>
1
>4
30
1
ox
30
/%r
f
1
V
7
f5"
F
ijr
Sl
r
d>4
r
2
2
\
2
REM*
IKS;
r,\
/
t
/ /
\ rK\ \ fK\ \f J A \
-------
\
PUSHING AND CHARGING REPORT
UNIT NO. I
TIEl CORMMTIOK (2 Hri ginning 12:00 /5m
COKE UNO COAL CHEMICAL WORKS Date f- f'7f
BATTERY
NO. /' ' 1 |
BATTER* »0.
6 *-/
BATTERY NO.
5»
OVEK
NO.
T (HE
PUSHED
TIME
CHARGED
«»" IT
TIME
PUSHED
TIME
CHARGED
NOTES
OVEN
NO.
1 1 ME
PUSHED
TIME
CHARGED
NOTES
t
1
I
3
3
3
5
5
5
1
7
7
9
9
S
11
11
11
!3
13
13
15
if
XI¥
15
1"
42-
*
15
/r
©
17
9-f
f su
£"6*
17
tP^
3f
1
17
/*"
fS
/ ,
9
19
/ *
£~F
t
n
19
t
/o
/
(-f-Q
18
1
xo
/
/£>'
21
1 .
}o
X
21
I
IfL
x~
jr
I 21
/
pf
>"
3f
23
• *-*
io
23
J-O
£0
23
#0
3
25
a-*
¦f2-
' -3
/
•
25
3o
JJ
2?
3
/2s
3
27
A
X**
3
27
t
,—
.» 9
26
4
*j%>
t'
{%*
29
$
fx*
r
*y
29
6 2*
- T
31
f
n
r
ff
31
*
r
31
Y
3?
'
>7
s~/
2
r
j"
ft
2
*
,r
fJ
•
5
r
jr /
£
<*5"
' ?- ^
4
,r
*
/ 7
4
ff
4
6
£>7
M ¦**
6
1
/?
S3
6
Jl
of
B
C
*9
?
7V-
8
&
ff
7
si
8
7
4?
f/
8
1
tf
7
10
?
r
n
10
1
14
*
£3
10
?
ff
' r
3 3
(D
12
r
t±~
*«
12
*
25"
0
HJ
12
9
/
¦¦?
14
r
*u"
• ¦*
/f
14
, y
ss
f
2f
14
f
< f
*• ¦«¦'
ta
f
uc
<'?
ff
16
f <
f»3
IB
9
e S
/
IB
?
f{€-
ia
M
fjr
, ¦ ^
*% <
18
/r"
20
a*
«A Z*"''
20
S* 1
if
//
o3
5rfv
20
KT
j
* *
/ **
:¦¦***
^ /
22
/*
//
22
//
*4"
//
"4#
A 1 \
22
//
//
SJ
24
//
24
//
-------
- Sfftl CBRPMITiON
.,niOM COKE AM COAL CHEMICAL WORKS
PUSHING AND CHARGING REPORT
UNIT NO.
12 Mrs. Beginning I2:00£ N
Date
> /
BATTERY *0.
BATTERY HO.
Bv I
OVEN
NO.
TIME
PUSHED
TINE
CHAKSEO
NOTES
OVEN
MO.
TIME
PUSHED
TIME
CHARGED
NOTES
QVEM
NO.
T 1 ME
PUSHED
! I HE
CHAREEO
NOTES
1
JV>
2
1
-?
if?
3'
J
1
a ,
to
-
i S*
3
,?
Sfi
*
3
H
i^„S*
3
U
\
5
c
5
H
v
a
5
•
¦
-t
7
3.5'
b
7
i
/5
<0
7
H
5U
9
H
37
ft
a
i
¦
11
/-
&
I
odl
13
13
£
[
13
A
d.
"1
15
L
h
15
£
/
! 5
A
<•0
1
16
i
17
£
&
/
3<
17
7
7
> S
17
7
/f
" i £*%
f
18
7
7
19
/
19
/
k
i?
21
if
3d
21
a?
/
H-9
21
ff
?C,
23
$
&
1
fto
23
, >
/
iH
23
t) 2
/
25
ij
C 4*
y
25
/
3^'
/
*-«' '
*~J% j
25
7
"¦* i
r •*
^ "
¦ y'
27
$
•//
27
/
.9;
27
ot
-/¦
1
I
20
to
- -N
/
, /
29
/o
*¦*
.7
29
/¦"
f **
1
t :;
>' ft
31
tr
^ *
**. /
>
* *
jA
:< I
31
//
//
3*
31
iy
|
2
/:
, ¦*
2
//
-¦ff
2
4
4
4
- /'
B
6
-1, /
6
1
8
8
/*T
8
i
i
10
10
'< /
10
1
1
!
12
12
12
t
14
14
14
7
t
IB
16
16
1
1
18
18
18
20
20
20
22
22
22
24
Si
24
/>
24
28
j$j
/r
. .-*•
28
<3* -
26
7 '<*.
/
, -
2#
/ 2
/
28
/
3'
28
/
¦- -
30
/
o'
(
I 30
/#
*
cv.
30
/
*
39
1
+>
k1
«&•
- >
r*C
H8
•
B
• «
2
k»
ii
5*
—is.
2
BATTERY HO.
JL
REMARKS:
-------
<
SAMPLE IDENTIFICATION LOG
I
- -1W Number
Sample location Run
Sample 1
Contents
Co//e<-rd>
Comment; &Y
BM-i- ?K
Ma.
i
/V*—w
M c.
->-PF
~im XR>
£
Fwfck
L
XAD~L
6Uju^
dhBawakMpw^wbi
£_C£_
r**«Au
t-nfl
3^0
#»
AC
BA-P-l-fA
1±
jQLe
l££.
IK
SdeL
jm.
/sS"&^rffaca
/Hon
*<~ t>-^
.fc
PL*~4aJ\ y%^m^A
M c
5P*
LAP-2-9%
A£_
-P*
Z£-
JJL
Jk
&
JL
JLjkJ&i
/THTT
-<24d3e5s=X.
iL
.JjpL.P'
7kp&«A
9~A> pj^
n c*
„f ' „ TTIL
£>fiP- *•
9R
<*«n—
/¦» c
XE-
JL£
j^2l
?7y
:££.
XSL
eft
ilJL
5~J5"^ I X
F«4irs.
KAP~
H - ^
SLfrdL—*^*
C~J>
. 2> ^
*oS I \5~
^lrfe!?TL
-------
c
0 2- gft °
L
A4^£>+ LJjL~~
¦ J I .'a g^TmimmrnlMSimmmm
8>»P-7.ex
z^r?y
_££.
jUL
£J±
ioA
U *G
2ko$-
nxfr
¦3?- cc.
f £>&
JL
i
si4*+~*a*
h.
A—tr *j£jp»Uk
¦¦MlaptaataMWaiBi
3?-CJCf-
•5~QQ
JL
Jl2=-CZi:
S»t>
i (
J?, CM
3J~*
******
^ r f
At o
-pe:
ra.
/? c-
_2£
XS-
XJI
?Yhflht*iA*
MZ
5->iCC
l ta
tii ^ "X—1\
/?£-
J
JS&A.
'Vp 6
n+juju
XX&-
crftc
JlOO.
JLSJb.
iJSlJsL
x
JL
Cerdlf^pt*^ ¦?vHrfv«
n
^"Ti f
n c
+r
-------
i C JB~ ) ~/3s O
SAMPLE IDENTIFICATION LOG
StitofLlf
-£W Number Samplt location Run
1 id 'jmKjtC.' 1
Contents
, , L A -V,
kJ AvCommenti
ii -
Jj=_£
/-/V
S"0
2L
jk£-
/fC /<5"Q
il
VP
Jt.
/
*
r
II n mi m in
£? Ife
If
**7^
/f C
IzA
£L£sl
£2^=1.
-g^-; -
71 a
mm
•JJzf.
£££.
7QO
¦?t>6
££.
l-C7cfiAH
7c>6
JEJltu*
fa***-!
—x:—
£
CT E
J^A
£ &
l&Q
I
U
mi
¦v
'I
tl£.
ACtdSkm.
CcTr>^>**ry~s SL*~~yjLk
tAtf/fiSf-l.VH'.
jail
/*V4*»V
zro
-Zj^-|£S.
Q
/«
/as
^nwMtn a*~*>
*' it
M
l-NB
^¦1-PZc.h
jmrn
J^IIM ' — I|
Z2A
Pz#
^3*5
¦p^Mx~
/%**n id
A
jc^
<^TA
3b <>
C~££
C lei),
3 O S
\aaLJaX o Q Q
tt
it
¦^¦¦MMMBMVWpaj^PHKiMnPwaKM
fttm.O
>»
-------
4 f
SAMPLE IDENTIFICATION LOfi
^Sfc 2k
5*«0UT ----- -
•fPA Number Sample location Run
Contents
Bsc,
Co//«trc:i>
Continent;
t»r/fite-3-v/tc
¦M/lt
JIM.
2>SQ
t?0
f 5~t>
(t> o
,/tkPVritix.
it
tt
'I
/i c
Jl
C
2
ftb,
£ X. 4S
FF
.4.1 felt
t^SO
¦jiZwClS^^piM^na
-^3*lltiESBdSlL.
- ,ii, & 0.
oo
£svhJc«*J ¦"**-*)
£2£L*Sa£s
^A^dXiSS.
"Iff
JQZA.
n
C-Jg
/liAAry^
J3A
A^CmJjTK-A
jA
"S>
jl
:'P~p41
RMwStaMfeoii
-3^
4*
MmhsJl
Py*
SP*>*Sa
tl C
m
t*o
Se2^6*s*i-
r./W*
16 6
It
JL&
lsljsl
7^
IH6-V- Pi A
ZLA
EE-
? fQ
¦t -to
~a£s
4L*xLijbZr*
A*gaA*&**
C-X ¦$
j,o o t */
/<
*t
JLfkZ^Haaet.
-------
f c
SAMPLE IDENTIFICATION LOG
^ -§PA Number Sample location Run
Contents
pi 3
3 S£>
Coflec rcS
Comment; fey
*=a|Fs5ffc-
/S O
ff*fu /*+***+
i( n tf
tf b
JLXJSk
2
»5—.
JL
&>cs£g*,
(Stth^m
Sst>-SAB-?XJ.
^£D
-P/=
.To
. -^Y1?
// '/ '<
U2JLA.
mj£t I .C^ll ¦
F'sAij**
£
/ȣ>
S
-idtikaeftL
cr#
jSTA.
##
x£le5<2it>
*4-
<*--yv^v.
23"Q
UfrvM /"!¦*«-<*«>
2S
J^2_
2,^6 ^
If
^5&
/? c~
TMc.
.ZiL
CftStettisaeL.
/y fi
-5~&
$4t±zjz£LA
bst>
mil
M.
6
* *"
#•#
££1
je^A
/»c>0
_4.
2 a &
—£jk£Jksim, __
Gtn**$.
ti «f r >
t^*ryUN^
/H-—H
Ay
jL^a.
/,5P
*#
/yw*>
-------
SAMPLE IDENTIFICATION LOG flJ>&
•iWt Number
/*
Sample Location
/
Run
Contents
Comments
tf/tc
/-T6
7
/? ^
-
f
7
1, ti it
- NtlC
/CO
?
Mrvv^
A-. X
/"? cL
- MS
7jf
7
$36~>~ PTA
7
jUmJV* S^J**€A
*jia£o^
2.
7
*' Ta V
P7?
_—-
7 1 F>^A-v
CTCLD
/*>£>b
7
%(9*%M€m A**# «. £*9%J,
ft * &
crA
1 «rn
7
/ • / >iiW-
j»
^Y*r-
C 2*1S
/iT ^
7
f h
/.6
7
JC*4rvho+d x#m '
^ x O
$ 3?. *£
1 ?
&ch-~* aaLl 3^7
S
7
/V*»«-V J >
(Lv*Ja**A tfjT
CI0
S-* D
7
fayh&m i ¦• Ln-A~*t.
H*. £
ca-A
_. /JsP
?
h SU«~C*
/C-e^fo-Ku
rzn
/AD | 7
s&-
7
i —5^ p*
S £r
ct 1 1 7
,S~ •" '5-*1 7
C D 1 -/o
*7
,.3u ^
i i 1
1
>
-------
SAMfLif
-fePA Number
8So~ /-PTcd
¦ (C' ^'7\
SAMPLE IDEffTIFICATION LOR '
----- -
^Saf?p4-e-Location -few
Co//f rc
'Pf-Ofica /iTm^ aJ6*£T/2
/- ftTdf.fr
jf 'f W Mil.
//
/<
/ -/^Tl
/ r
-DJJz,
£N /
n-\-Pr
j±
ft ,** «
/f
»*
iL
^lm*
t
tf
ff
h
fatre*€3r&+£i /
.VwA/w
/ f
q- CX/6
»r
(f
/1
3^7~
jsMmfcZ.
3wl~ i J^ULS
w
/i
V
Afftl
/¦f
«/
l. -i- A/&
r/
"%Q>~ i - Pr,
\t
11
ir
pAiyt^*- Jh
k
M
rlM
r^f-L
J-L
t t / '
d/rvvb"s
isu
in
i *
H
a4 A^Lc^ JJmcx ^
pMNHMJMpakMialNwvMdhlMH^BM^vMP
a - 3 ~Cr/»
/?
-------
4
hfLB
f-§PA Number
SAMPLE IDENTIFICATION LOG
^SO~J2^t~ 3> f
Sample Location Runjfe/^a. Contents
Comment;
4
it fit OeAjr
" -3-1/6
s7s
\)&m~Pjp
A
~
ir
XL
if
//
3-
jL
- li
itMe. /kS^Zi^
\J ia£ 2-
>$£
1- Px ft-
H
H
«r
^5s
//
//
Aifc
/, ^3_
//
//
tf - ^
;/
doMS^&TMf'CoAtftBases' (j)3\
v/
7 / — "2» —
//
/f
ttlAJSET flaZWKL,
n-2-(Lj&
it
ft
n
*> &&Fki**A~
tt
~m~ch*,xo*i
it
Ck^K r CqckJ
r3o£'
*-i-ec»
*>
Uf.
1m %y
l/-T>- PfA
J_l_
tt ~ /2b -Ckgnzaij
li
Asf.
\MK
Med
T
'J0-4- Mfitc.
IL
IL
ifiZL.
• ' -f- 06
Ji-
lt
frrvL-
K)i
'f
M&
*s
if
A
*s
IL£
IL
f ~4- PT&
//
it
fllk-
L->
/
tt
2£l
»
ft i I —1"J 1 h~
y/
¦4- em)
//
tt
a 1u
fr -4- cx/h
n
bcefai
~
i' -4-, £f/3
if
#
1/
>.-
-------
MX*
I
WfLb
-§HA Number
yk
'a
V te<:v~5- mc
Sample Location
CA-a^,\l»rA&A
,i '/
E IDENTIFICATION LOR ¦
S£> -T£g &
Run bfcreL Contents
\Ja*Jt Pi
Comment:
Qe>(t&crc
Bo__
uNmpnhIM^i
//
-s -/J
h)e'ln-iS-
Mm.
m
P/!^- /r.Kpt,us€. fa
(If,AWLS
h
jEs&k
fix
If I
k >
//
> -»
fr&
(f
11
it
V tliiuljj.
„ -g-^ /y
it
if
H
-jf-
-tTte>
/f
n
'TMf/sGtiTL&ii
w
T"
snz*
//
if
A
/fz/SStT
CXB
n
tf
A
i/ -
j-
Ct*b~ X
C^9-
il).
faejssp' L- //.
^ iiii
\)**)z~Pa
"i&jEZ.
i //
"SZ~™
//
//
UL
\j/nty
v.ofe / c^wi£
\Kr
^ML
a
fsvsLG?
/Q^pixM^n^ -- H
L/hJl-^ j/i/[ £?
@L ll^fcrA^- AwM^^2sslJ a J"
-------
iT
*IIQ0>£a/T~~ W>
.. e
-' -SPA Number Sample Location Rup&frrtr
(loffecrc
Contents
^n-sm-PlA)
Pirh> tO-ji-~ AJI-m
Comment'
fe>^
V,
/t
H
@>&A>z£«/e
ir
pr=
j±.
!/
:C£*fr
//
-XXA
/>
It
ft
tl
//
* 0.
LtezL.
" " ^tjrr
Z^JL m*4>
ft
£
KtfxfttHtT Jfl-L/b (jrvc/e.
'ea> Y <
SW **&!
<22
e**'
' "/"I I"" '
fst&bt
77T
-mp-s/>s-pt
f(
ML
¦rAk-
it
n ?f
ft
(/
n
//
tf
tf
XM '?-
ft
/t
w
w
n
Mi
a
1L
U
J
-------
fSAMfLiT
1 -" Number
i ,A .
H -7- PU
f /' ::lr2l
tBjfar-l-yf'm
\\
'SAMPLE I DEf-TT IFI CAT I ON LOB ,
BSDT^ri As*d^yJ-
4
7 A
Sample Location Runl)/#Zf
Collet
-------
)
SAMfib ~ * Itfrrer
- ¦ -feftA Number -Sampl e-Location
f€ >
RAP-1 -fF
SAMPLE IDENTIFICATION LOR
B A?
-Contents Sftnfte
Qoffecra
11
ME+JJL
/<
HH
Comment!
Tt
P£f y - TfW>>
\4l ^
X /"kJ) 3 —»
<&Y
~btf*-bU&
-B4P^t^£r—K-tt-
nfi&
/i
s-ateSzz.
n
yp-A-Pn
/I
ti
/jLtlJjx
il --T- - to
=-^T
$ud*4o
t-Joiu ' <~/ jhA d-
-------
4?~ I
* \ J
SAMPLE IDENTIFICATION LOG f
S-AHfLk" " ^ ^f7_ \
-fePA Number Sample location Run"baJZ- Contents
rt
3- P&
3- /Vf
\ - XI
=-ii.
Qj^£y OV-^Af {} Inf"
JjL
filfrrpNUMl
7»
Comment!
h\tH^LtJb
Co/^trc
uS
^r
//
>/
>/
//
H
Ms&idb {li^u^(^AcLx/\--(Jj^
ff -!> •
if£
ff
t>A£3ZZK
~M£
rf
tf
y
f
hAdJhJk fii&Cfti
~
,/ .. Cf -ML
n
//
-------
- - "fePA Number
/UP- s-- PI
SAMPLE IDEMTIFICATION LOG
JoA-P- Sj>
Sample Location Contents
V
"v
Oo//
-------
/
SAMPLE IDEM
fLb " *
-fePA Number Sample Location
LOR
Coffecta
RAf-n- Pe
CrfaAutn- M-
T£
Contents
Pa/iJjLL &*VUL>
M-C-lln
Comment*
it
~*
<¦-•7- PA
M-
/
7"
x£.
•/
_lL
# —1 ~ <£*>
/r
PmJm*>£sZ
Wt.
N*#S p££t
€S**f
/
//
tr^^4Sik
„ ^7- <" c.
/f
$Ua*
"2Mjp C&rdk*uuJjC>
iL
k '31-
it
H
7
It -37-tj:^
tf
v/
/I ^ ^C
»/
#/ //
//
J
/
fhAtfL- lw*uL— >#/*? £>j
a
f(
fJML
// -74-?F
rf
//
?Z3>
//
Ma
//
//
» LbtM^iAcu
ISM.
&esc.**r
n
?
T
'<
'/
p< C#*M-
// - 57 /?-#£?>
//
3>/f. e!4
iL
37/?-CX&c
M_
/
m*.
j. |i-~i
r
Ae-CJ,,
hl^tL--.
<
lJ-ajsr~
4Cirvrtsb-t*£*J,
s*
/'
5~A-.
-------
SAMPLE IDENTIFICATION LOB
----- ¦-
£PA ilumber Sample Location Rwt • Contents
~M(-A
Me,PA .(U*W
m
~7\
%- f J
Cbll&cTe
Comments
G H
>/
p
J
! ¦>
ll_
i)
6 M-
y
GjtL
/}6
A>
Q ft
?>
£&
J&
//
QL
if ~X£6
0
0
a#
2m
SQjhJrBi
sjj/lAP ——t 1lftc&
^f&Qt'p foUhJk
JL
A^t ePl-
5kc/1
n
V &&
t,
~
I t
<3*1^
2^4
**
n a
/
£
jThAsyrlCOU
^,ui
u &&
&
nil—
/
~j)M
o-Pk 8
tt
~
pA^£jl!b b&J-
'( If 'I
'(
a x
/ - • / ^\,u>
_£J_
2-
't
11
TMCA
tfrgft-/
<*
r h /.
7- ~f
2> ju
rL
TjM
T«c/?
&Wg-/
' I
'/
-> i i—
• X
/ I
M
H
2. vt
'f
iL__l
, wr^-/
/ *4 *(
«/•
7
<8.^
/I -o-
*2_
D f r-»e o->
A
i
-------
&PA Number
I
SAMPLE IDENTIFICATION LOG
"
Sample Location Rwt • Contents
(£A
J iai J &Atnjk
Comments
p&oMp -MCA
>}
G j4
p
¦ v —~j.
GjL
iL
.fF$
0
j'
GjL
/
"ict/)n->sA <
3^/b^p-& m<~-&
if&O.'p fctbhJk
M^dl
5nW
It H
V B&
~
* i
A&S1
tt h)tAt&
/
t
jrKAs-ytenu
%,M
mAA
7
0-
M
u
**f/ltSsWX*** f
S fL»ttz£iM; jjjJ-
G U-
<(
/
/ ^ '" S fh^r^JL,.^
(L CL
jlJLBAzL
n
'/
C &
a
) t
• i
11
"2-
~
ft
ft
CC
K
&£.£> - I
2— / i« 'f ^
i #
1_
cc
6£C^<*~fTAB~l
TX.uJ
JL
_LL
n
2- r 't
Ta4cA
I* "-fXTjg &-/'
iliti
i) ic
7_ ~
Tmc£
MttCS-i
'/
( /
&
• 7.
* i
K
7. VI
T kL&
<, ITM-I
L 4
*2— /j
f (
&/J
'< • < /* <« t *< , '!
^So/fas- & Amm/ 1 fi/3 H€SFn
h
iX-^XS e
^ L&:~A jMt*h
r%£iytk\/jsj}v(^/}£<->i/c
------- |